Pressure Pressure Relief Relief Valves Valves Technical Technical Manual Manual ANDERSON GREENWOOD flow control Anderson Greenwood Pressure Relief Valves Technical Manual Contents Pressure Relief Valves General Information ........................................................................... Glossary ............................................................................................ 1, 2 3, 4 Valve Sizing Nomenclatures ................................................................................... Valve Data ......................................................................................... Back Pressure and Subsonic Correction............................................ Gas and Vapor.................................................................................... Steam ................................................................................................. Liquid .................................................................................................. Subsonic Flow .................................................................................... Special Applications ........................................................................... Reaction Forces ................................................................................. 5-7 8 - 14 16 - 21 22 - 24 25 - 30 31 - 35 37 - 45 46 - 47 48 Conversion Factors ........................................................................................................... 49 - 55 Fluid Data ........................................................................................................... 56 - 61 ANSI Flange Standards ........................................................................................................... 62 - 76 Valve Installations - Handling Procedures ........................................................................................................... ASME Code Section 77 I1 Excerpts ............................................................................................. 78 - 91 ASME Code Section IV1 Excerpts ............................................................................................. 92 - 97 ASME Code Section VIII1 Excerpts ............................................................................................. 98 - 116 API RP 520 Part I1 Excerpts ............................................................................................117 - 149 API RP 520 Part II1 Pressure Relief Valve Technical Manual NACE MR0175-951 Revised May 1998 Catalog: PRVTM-US.97 API RP 5211 Excerpts ............................................................................................150 - 158 Excerpts ............................................................................................159 - 169 Noise Levels ...................................................................................... 170 API RP 5271 Seat Leakage Requirements ..............................................................171 - 173 Note 1. Some referenced figures, tables, equations, or paragraphs may not be included. Consult original document for complete text. Section 16 Chemical Resistance for Metals ........................................................174 - 180 Section 17 Chemical Resistance for Elastomers/Thermoplastics ........................181 - 205 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 3 Anderson Greenwood Pressure Relief Valves Technical Manual General Information Intro Body Materials Anderson Greenwood is a globally recognized leader in the field of pressure relief device technology. Fundamental to our ability to solve the most challenging application is our belief in understanding all application parameters. As a leader in the field of pressure relief device education, we proudly provide this manual for use as the finest technical source on our technology and the specialized area of these safety devices. The users of this manual will benefit from its completeness as a pressure relief device resource document. Pressure relief valve standard body materials are ASME SA-216 grade WCB or WCC CS, or ASME SA-351 GR. CF8M SS. Also available at additional costs are bodies of special alloys, such as Hastelloy® ‘C’, Monel®, high temperature alloy, duplex SS, Titanium, alloy 20 and others. Castings Valve castings to meet requirements of radiography, magnetic particle, liquid penetrant examination and Charpy Impact tests are available on special order. Our documented quality control can provide complete chemical and physical analysis for all cast materials on request. Standard Flanged Connections (a) All steel flange ratings conform to ANSI B-16.5 – 1977 and are indicated on each orifice selector chart in the applicable product catalog. Heavier outlet flanges are available on application. For back pressure exceeding listed values, consult the factory for valve limitations. Steel raised face flanges are provided with a serrated finish on the flange face. (b) Standard Aluminum valves are manufactured with flat faced flange finish in accordance with commercial practice. The flanges are designated as Class 125 FF, with drilling equal to ANSI Class 150. Copyright Notes 1. © ASME: the American Society of Mechanical Engineers. 2. © NACE: National Association of Corrosion Engineers. 3. © API: American Petroleum Institute. Notes 1. Shop test procedure for temperature compensation available on request. 2. All shop orders will state 100°F [38°C] unless customer’s purchase order states otherwise. 3. Inconel® and Monel® are registered trademarks of the International Nickel Company. 4. KYNAR® is a registered trademark of the Pennwatt Chemical Corporation. 5. Hastelloy® is a registered trademark of Haynes International. (c) All iron flange ratings conform to ANSI B-16.1 – 1977 and to Flange Dimension Table (page 70). Iron flat face flanges are supplied with a smooth surface on flange face. (d) Bronze flange ratings conform to ANSI B-16.24 and to Flange Dimension Table (page 86). Bronze flat face flanges are supplied with a smooth surface on flange face. (e) All ring joint flange facings comply with ANSI B-16.5 – 1977 ring groove. For ring joint facing dimensions, refer to the Flange Dimension Table (page 73). (f) Flange facings different from raised face can be furnished at additional cost. The standard surface finish roughness is 125-250 AARH. DIN, JIS, or other flange finishes may be available on a product-by-product basis. Contact our sales department for availabilities. (g) Drilling of both inlet and outlet flanges always straddles center lines. Offset drilling is available with proper application. Special Flanges Anderson, Greenwood offers a variety of non-standard connection arrangements to meet the most exacting special flange requirement. Spring Materials Pressure relief valve standard spring materials are carbon steel aluminum painted. Spring materials of special alloys, such as tungsten steel, 316 SS, 302 SS, phosphor bronze, K-Monel® and Inconel® and others are all available in many models on request. Spring Assembly Corrosion Protection At additional cost, springs can be furnished with protective finishes of phenolic, plastic, epoxy resin, and nickel plate. Bellows Valves For easy field conversion, the conventional valve – D Series – may be changed to a bellows valve – all orifice sizes from F to T – by installing the bellows assembly and gaskets. Standard material for all bellows is Inconel® 625. KYNAR® coating, Monel® and other materials available at additional cost. Bellows conversions in D and E orifices require a body adapter, stem, guide, gaskets and bellows. Bellows Coating The standard bellows is Inconel® 625. KYNAR® coating of the bellows for additional corrosion protection is available at additional cost. Seating Surfaces Armco 17-4 PH stainless steel hardened to hardfaced equivalence is an optional D Series disc material. The seating surfaces for other models with stainless steel trim can be hardfaced, when specified, at additional cost. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 1 Anderson Greenwood Pressure Relief Valves Technical Manual General Information O-ring Seat Seals Seat Tightness Steam Jacketed Valves Anderson Greenwood offers the most complete line of pressure relief valves with O-ring seat seals. All valves are available – up to the maximum pressure limits – in a variety of O-ring materials. See O-ring Seals Section for complete details and specifications. All metal seated pressure relief valves are tested for seat leakage per API STD 527 and ANSI B147.1. To keep viscous fluids flowing or to prevent lading fluids from becoming solidified, heat is often applied to the valves. Application of heat, to the valves and piping, however, is often a problem. Steam tracing lines and insulation are frequently required, in addition to heating coils. Removal and reinstallation of a valve is expensive, time consuming and can create costly delays in a process application. Trim or Wetted Parts Trim refers to the nozzle or base and the disc in direct spring valves. Consult each product catalog for available materials. Operating and Set Pressure Differentials Optimum performance of a direct spring pressure relief valve protected system is available at operating pressures up to 90% of valve set pressure. Pump and compressor discharge pulsations are offset by the greatest allowable valve set pressure differentials. System pressure pulsations can cause valve malfunctions. Therefore, the pressure relief valve should be set as high as possible above the discharge line pressure. Applications requiring closer system-to-valve pressure differentials may be accommodated by soft seat seal, or Anderson, Greenwood high performance Series 80 or Pilot Operated Valves. Cold Differential Test Pressure Recommendations When pressure relief valves for high temperature service are tested at room temperature, a compensating adjustment is made in the set pressure. High temperature reduces set pressure – lessens spring load – via thermal expansion of spring, body and bonnet. Cold differential test pressure adjustments are also required on unbalanced valves when constant applied back pressure conditions exist. Cold differential test pressure adjustments are indicated on the valve nameplate, and are recorded on the functional test report. The Anderson Greenwood tightness standard for Series 80 and Pilot Operated pressure relief valves soft seated valves is: ‘no leakage at 95% of set pressure for set pressures of 60 psig [4.13 barg] and higher, or no leakage at 3 psig [.21 barg] below the set pressure for set pressures below 60 psig [4.13 barg].’ For all other direct spring, soft-seated pressure relief valves, seat tightness is: ‘no leakage at 90% of set pressure for set pressures 15 psig [1.03 barg], or no leakage at 3 psig [.21 barg] below the set pressure for set pressures below 15 psig [1.03 barg].’ Special Applications Many exacting process applications require specially built valves. When your valve requirements exceed catalog descriptions, Anderson Greenwood invites you to submit the specifications. Design data and quotations will be furnished. Valves for Corrosive Service A design advantage frequently overlooked in corrosive application is the full nozzle inlet option on many of our valve models. Until a valve discharges – an infrequent occurrence – the only contact surfaces are the wetted parts – nozzle and disc. Where standard materials are susceptible to attack, corrosion resistant alloys are recommended. Valves for Low Temperature Service Anderson Greenwood has a wide range of pressure relief devices to meet service temperatures to -450°F [-267°C]. Contact your Anderson Greenwood representative or the factory for more information on Steam Jacketed Valves. Steam Jackets are available in integrally cast or bolt on type for the D and L Series only. Installation and Maintenance Complete installation and maintenance training manuals are available on request. Replacement Valves and Repair Parts Submit valve serial number for exact replacement. Anderson Greenwood will supply a valve with correct materials and dimensions. The serial number for most valves is located on the nameplate and stamped on the perimeter of the outlet or body flange. Proper replacement will be made for valves which have become obsolete. Iron and bronze valves may require the complete model number, located on the nameplate. Repair Tools For proper maintenance of Anderson Greenwood Pressure Relief Valves, nozzle wrenches, lapping discs and lapping plates are available, as are complete operating, installation and maintenance manuals. Set Pressure Lower Limits Minimum set pressure per valve series is listed in the applicable product catalog. © Anderson Greenwood reserves the right to change © 1997 1995 Keystone/Anderson, Greenwood & Co.product designs and specifications without notice. Proper heat transfer to keep viscous fluids in their correct flowing state can be obtained by integrally jacketing the housing of the valve. Piping can be simplified, thus reducing maintenance time and permitting the use of many standard replacement parts. 2 2 Anderson Greenwood Pressure Relief Valves Technical Manual Glossary Accumulation is the pressure increase over the maximum allowable working pressure of the vessel during discharge through the pressure relief device, expressed in pressure units or as a percent. Maximum allowable accumulations are established by applicable codes for operating and fire contingencies. Design Gauge Pressure refers to at least the most severe conditions of coincident temperature and pressure expected during operation. This pressure may be used in place of the maximum allowable working pressure in all cases where the MAWP has not been established. The design pressure is equal to or less than the MAWP. Actual Discharge Area is the measured minimum net area that determines the flow through a valve. Effective Discharge Area or Equivalent Flow Area is a nominal or computed area of a pressure relief valve used in recognized flow formulas to determine the size of the valve. It will be less than the actual discharge area. Back Pressure is the pressure that exists at the outlet of a pressure relief device as a result of the pressure in the discharge system. Balanced Pressure Relief Valve is a spring-loaded pressure relief valve that incorporates a means for minimizing the effect of back pressure on the performance characteristics. Blowdown is the difference between the set pressure and the closing pressure of a pressure relief valve, expressed as a percent of the set pressure or in pressure units. Built-up Back Pressure is the increase in pressure in the discharge header that develops as a result of flow after the pressure relief device opens. Closing Pressure is the value of decreasing inlet static pressure at which the valve disc re-establishes contact with the seat or at which lift becomes zero. Cold Differential Test Pressure is the pressure at which the pressure relief valve is adjusted to open on the test stand. The cold differential test pressure includes corrections for the service conditions of back pressure or temperature or both. Conventional Pressure Relief Valve is a spring-loaded pressure relief valve whose performance characteristics are directly affected by changes in the back pressure on the valve. Curtain Area is the area of the cylindrical or conical discharge opening between the seating surfaces above the nozzle seat created by the lift of the disc. Huddling Chamber is an annular pressure chamber in a pressure relief valve located beyond the seat for the purpose of generating a rapid opening. Inlet Size is the nominal pipe size (NPS) of the valve at the inlet connection, unless otherwise designated. Leak-test Pressure is the specified inlet static pressure at which a seat leak test is performed. Lift is the actual travel of the disc away from the closed position when a valve is relieving. Maximum Allowable Working Pressure (MAWP) is the maximum gauge pressure permissible at the top of a completed vessel in its operating position for a designated temperature. The pressure is based on calculations for each element in a vessel using nominal thicknesses, exclusive of additional metal thicknesses allowed for corrosion and loadings other than pressure. The maximum allowable working pressure is the basis for the pressure setting of the pressure relief devices that protect the vessel. Maximum Operating Pressure is the maximum pressure expected during system operation. Nozzle Area is the cross-sectional flow area of a nozzle at the minimum nozzle diameter. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 3 Anderson Greenwood Pressure Relief Valves Technical Manual Glossary Opening Pressure is the value of increasing inlet static pressure at which there is a measurable lift of the disc or at which discharge of the fluid becomes continuous. Outlet Size is the nominal pipe size (NPS) of the valve at the discharge connection, unless otherwise designated. Overpressure is the pressure increase over the set pressure of the relieving device, expressed in pressure units or as a percent. It is the same as accumulation when the relieving device is set at the maximum allowable working pressure of the vessel, and the inlet pipe pressure loss is zero. Pilot Operated Pressure Relief Valve is a pressure relief valve in which the main valve is combined with and controlled by an auxiliary pressure relief device. Pressure Relief Device is actuated by inlet static pressure and designed to open during an emergency or abnormal conditions to prevent a rise of internal fluid pressure in excess of a specified value. The device also may be designed to prevent excessive internal vacuum. The device may be a pressure relief valve, a nonreclosing pressure relief device, or a vacuum relief valve. Rated Relieving Capacity is that portion of the measured relieving capacity permitted by the applicable code or regulation to be used as a basis for the application of a pressure relief device. Relief Valve is a spring-loaded pressure relief valve actuated by the static pressure upstream of the valve. The valve opens normally in proportion to the pressure increase over the opening pressure. A relief valve is used primarily with incompressible fluids. Rupture Disc Device is a nonreclosing differential pressure relief device actuated by inlet static pressure and designed to function by bursting the pressure-containing rupture disc. A rupture disc device includes a rupture disc and a rupture disc holder. Safety Relief Valve is a spring-loaded pressure relief valve that may be used as either a safety or relief valve depending on the application. Safety Valve is a spring-loaded pressure relief valve actuated by the static pressure upstream of the valve and characterized by rapid opening or pop action. A safety valve is normally used with compressible fluids. Set Pressure is the inlet gauge pressure at which the pressure relief valve is set to open under service conditions. Simmer is the audible or visible escape of compressible fluid between the seat and disc at an inlet static pressure below the set pressure and at no measurable capacity. Spring-loaded Pressure Relief Valve is a pressure relief device designed to automatically reclose and prevent the further flow of fluid. Stamped Capacity is the rated relieving capacity that appears on the device nameplate. The stamped capacity is based on the set pressure or burst pressure plus the allowable overpressure for compressible fluids and the differential pressure for incompressible fluids. Superimposed Back Pressure is the static pressure that exists at the outlet of a pressure relief device before it actuates. It is the result of pressure in the discharge system coming from other sources and may be constant or variable. Relieving Conditions is the term used to indicate the inlet pressure and temperature on a pressure relief device at a specific overpressure. The relieving pressure is equal to the valve set pressure (or rupture disc burst pressure) plus the overpressure. (The temperature of the flowing fluid at relieving conditions may be higher or lower than the operating temperature.) © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 4 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Nomenclature Gas and Steam Flow Symbol Description Inch Pounds Metric Units square inch (in2) square centimeter [cm2] A Orifice area or equivalent flow area. C The gas constant of gas, derived from the specific heat ratio, k. If C is unknown, use C = 315, a conservative value. Refer also to Physical Properties of Selected Gases. — — F´ Subsonic flow factor, based on the ratio of specific heats and pressure drop (differential) across the valve or nozzle. — — k The ratio of specific heats of gas, where k = Cp/Cv. When the value of k is unknown, use k = 1.001, a conservative value. Refer also to Physical Properties of Selected Gases. — — K The valve coefficient to be used where set pressure is 15 psig [1.03 barg] and greater, and in accordance with the requirements of Section VIII, Division 1 of the ASME Boiler and Pressure Vessel Code, ASME I, and ASME III. Valve coefficient K includes the required derating to 90% of actual average measured nozzle coefficient, KD, as required by the ASME Code. Please note that safety valve models available for gas and liquid applications will have differing nozzle coefficients. — — Kb A back pressure correction factor for gas, used when the flow becomes subsonic, occurring when the pressure ratio across the valve nozzle exceeds the critical pressure, PCF/P1. — — KN Steam flow correction factor, from the Napier equation. — — KSH Superheat correction factor for use in the steam formulas. — — M Molecular weight of the flowing gas. Refer to Physical Properties of Selected Gases, or other resources, for listing of M. — — P Set pressure in gauge units. All formulas herein are based on barg or psig. lb/in2 gauge (psig) bar gauge [barg] lb/in2 gauge (psig) bar gauge [barg] Pb Back pressure, under relieving conditions, at valve outlet in gauge pressure units. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 5 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Nomenclature Note Gas and Steam Flow Symbol Description Inch Pounds Metric Units 1. The formulas using this pseudo pressure ratio are valid only for the specified pressure units to the right and for the Series 90 low pressure pilot operated safety valves. P1 Absolute pressure at valve inlet connection under relieving conditions and equal to set pressure, p + overpressure + atmospheric pressure. Atmospheric pressure will be equal to standard sea level pressure, 14.7 psia [1.013 bara], unless otherwise specified. When a local plant site barometric pressure is mentioned, sizing for orifice area should be made with the stated local barometric pressure. lb/in2 absolute (psia) bar absolute [bara] P2 Absolute pressure at valve outlet under relieving conditions; equal to back pressure, pb + atmospheric pressure (as expressed in previous paragraph). lb/in2 absolute (psia) bar absolute [bara] PCF/P1 Critical pressure ratio. The critical pressure ratio is used to determine if the back pressure correction factor Kb shall be applied to the sizing formula. t Relieving temperature, to be evaluated at the valve inlet, under relieving condition. T Absolute relieving temperature, equal to relieving temperature plus base temperature, where: T [°Rankin] = t [°F] + 460 and T [Kelvin] = t [°C] + 273 V Gas flow capacity expressed in volumetric units per time unit. The formulas in this section are based on a sea level atmospheric pressure of 14.7 psia [1.013 bars] and a temperature base of 60°F or 0°C, respectively for metric and inchpound systems. Refer to Gas Flow Conversions for other pressure and temperature bases as well as other units of measure. W Gas flow capacity expressed in weight units per time unit. Refer to Gas Flow Conversions for other units of measure. Z Compressibility factor, correcting for the difference between the physical characteristics of a theoretical gas and the actual gas under consideration. If Z is unknown, use Z = 1.00. P2 lb/in2 absolute (psia) — bar absolute [bara] P1 — degrees Fahrenheit (°F) degrees Celsius [°C] degrees Rankin (°R) degrees Kelvin [°K] Set pressure = 15 psig [1.03 barg] and higher standard cubic feet normal cubic meters per minute per hour (scfm) [Nm3/h] P2 pounds per hour (lb/h) kilograms per hour [kg/h] — — © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. P1 Set pressure is less than 15 psig [1.03 barg] 6 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Nomenclature Notes Liquid Flow 1. Relief valves certified for liquid applica- tions with full lift at 10% overpressure, shall use Kp = 1.00 at 10% and greater overpressure. The 1985 revision to ASME VIII required all liquid relief valves to have certified capacities at 10% overpressure. Therefore, the use of Kp in the sizing formula would apply to non-ASME Code valves only. 2. The maximum permitted values of over- Symbol Description Liquid Safety Valve Type 10% Pilot operated. 10% Conventional and balanced direct spring operated, with certified full lift at 10% overpressure. 25% Conventional and balanced direct spring operated valves not meeting the above requirements. Note: Sizing may be done at 10% overpressure when the correction factor Kp is made equal to 0.60. Metric Units square inch (in2) — square centimeter [cm2] — A Orifice area G Relative density of liquid at flowing temperature, referred to water at 68°F [20°C]. Gwater = 1.00. K Effective or certified nozzle coefficient. The certified nozzle coefficients, when given, are in accordance with the requirements of Section VIII, Division 1 of the ASME Boiler and Pressure Vessel Code, ASME I, and ASME III and include a derating to 90% of actual, as required by the Code. The effective nozzle coefficients, when given, also assume the same derating, but are not certified by the National Board of Boiler and Pressure Vessel Inspectors. Please note that safety valve models available for gas and liquid applications will have differing nozzle coefficients. — — Kp Capacity correction factor due to lift characteristics of conventional and balanced spring operated valves, in liquid service, where full lift is achieved at 25% overpressure. Use Kp = 0.60 for sizing these valve types at 10% overpressure, and Kp = 1.00 for 25% and greater overpressure.1 — — Kv Capacity correction factor due to viscosity. For most applications, viscosity may not be significant, in which case use Kv = 1.00. — — Kw Capacity correction factor for balanced bellows safety valves due to back pressure. Use Kw = 1.00 for conventional (unbalanced) and pilot operated safety valves. — — p1 Upstream pressure under relieving conditions. This is set pressure, plus overpressure.2 lb/in2 gauge (psig) bar gauge [barg] p2 Total back pressure, under relieving conditions, at valve outlet. lb/in2 gauge (psig) bar gauge [barg] — — pressure for various types of liquid safety valves in this manual are as follows: Maximum Overpressure Inch Pounds R Reynolds Number. A dimensionless expression for the flow behavior of fluids and is used to determine the viscosity correction factor Kv. µ Absolute viscosity of the liquid at the relieving temperature. Kinematic viscosity and/or viscosity expressed in other units of measure must be converted to absolute viscosity in centipoise. Most liquid applications need not consider viscosity and should therefore use a Kv = 1.00. The approximate viscosity of water under most conditions is 1 centipoise. When viscosity is given, it should be considered. centipoise centipoise W Liquid flow rate. US gallons per min (US gpm) cubic meters per hour [m3/h] © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 7 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Nozzle Coefficients ASME Nozzle Coefficients – Direct Spring PRVs Valve ASME I Steam Hot Water A Series Steam ASME III Gas, Vapor ASME IV Steam Liquids .975 D Series .878 .878 .700 Steam ASME VIII Gas, Vapor Liquids .878 .878 .710 .878 .878 .700 F Series .798 .878 .878 G Series .840 .878 .878 K Series .878 .878 L Series Y Series .874 .874 .475 .840 15W .874 .874 .878 .878 .475 .975 Model 61 .877 Model 63B .877 Model 83F .847 Model 81, 83 .988 Model 86 .816 .816 Model 81P .720 API Nozzle Coefficients – Direct Spring PRVs Valve ASME I Steam Hot Water A Series Steam ASME III Gas, Vapor ASME IV Steam Liquids Steam ASME VIII Gas, Vapor Liquids .878 D Series .971 .971 .776 .971 .971 F Series .876 .910 .910 G Series .876 .910 .910 K Series .878 L Series Y Series .776 .878 .971 .971 .528 .971 .971 .528 .876 15W .975 Model 61 .877 Model 63B .847 Model 83F .998 Model 81, 83 .816 Model 86 .816 Model 81P .720 Note 1. ASME nozzle coefficient is the actual coefficient recorded by the National Board of Boiler and Pressure Vessel Inspectors. It differs from the API nozzle coefficient. When sizing PRVs using the ASME coefficient, the ASME area must be used. The API nozzle coefficient is an effective coefficient to be used when sizing PRVs using API 526 orifice areas. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 8 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Nozzle Coefficients ASME Nozzle Coefficients – Pilot Operated PRVs Valve Steam ASME VIII Gas, Vapor Liquids 223, 233 .830 423, 433 .830 .650 623, 633 .830 .650 823, 833 .830 .650 923, 933 .830 .650 226 .833 526 .833 .833 576 .809 .809 727 .788 .650 .788 273, 473, 673, 873, 973 .809 91/94 .770 93/93T .845 95 .852 9300 .629 API Nozzle Coefficients – Pilot Operated PRVs Valve Steam ASME VIII Gas, Vapor Liquids 223, 233 .860 423, 433 .860 .670 623, 633 .860 .670 823, 833 .860 .670 923, 933 .860 .670 226 .860 526 .860 .860 576 .860 .860 727 .975 .975 273, 473, 673, 873, 973 .860 91/94 .770 93/93T .845 95 .852 9300 .629 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 9 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Orifice Areas Orifice Areas – Direct Spring PRVs Valve Orifice Designation ASME Area (in2) [cm2] API Area (in2) [cm2] A Series D .1213 .783 .110 .710 A Series E .2157 1.392 .196 1.265 A Series F .3369 2.174 .307 1.981 A Series G .553 3.568 .503 3.245 A Series H .864 5.574 .785 5.065 A Series J 1.415 9.129 1.287 8.303 D Series D .1219 .786 .110 .710 D Series E .2173 1.402 .196 1.265 D Series F .340 2.194 .307 1.981 D Series G .558 3.600 .503 3.245 D Series H .869 5.606 .785 5.065 D Series J 1.427 9.206 1.287 8.303 D Series K 2.036 13.135 1.838 11.858 D Series L 3.160 20.380 2.853 18.406 D Series M 3.987 25.720 3.600 23.230 D Series N 4.807 31.010 4.340 28.030 D Series P 7.070 45.610 6.380 41.160 D Series Q 12.240 73.970 11.050 71.290 D Series R 17.720 114.320 16.000 103.230 D Series T 28.800 185.810 26.000 167.740 Note 1. The ASME area is the actual flow area certified by the National Board of Boiler and Pressure Vessel Inspectors. The API area is the flow area defined per API 526. When sizing PRVs, care should be exercised to not mix API and ASME values. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 10 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Orifice Areas Orifice Areas – Direct Spring PRVs Valve Orifice Designation ASME Area (in2) [cm2] API Area (in2) [cm2] K Series F .307 1.981 .307 1.981 K Series G .503 3.245 .503 3.245 K Series H .785 5.065 .785 5.065 K Series J 1.287 8.303 1.287 8.303 K Series K 1.838 11.858 1.838 11.858 K Series L 2.853 18.406 2.853 18.406 K Series M 3.597 23.200 3.600 23.230 K Series N 4.340 28.030 4.340 28.030 K Series P 6.380 41.160 6.380 41.160 K Series Q 11.045 71.260 11.050 71.290 L Series — .0767 .495 .069 .445 L Series C .150 .968 .135 .871 L Series V .248 1.600 .223 1.439 L Series G .559 3.606 .503 3.245 .110 .710 .110 .710 Model 61 Model 63B 5 .150 .968 .150 .968 Model 63B 7 .437 2.819 .437 2.819 Model 81, 83, 81P -4 .049 .316 .049 .316 Model 81, 83 -6 .110 .710 .110 .710 Model 81, 83, 81P -8 .196 1.265 .196 1.265 Model 81, 83 F .307 1.981 .307 1.981 Model 81, 83, 81P G .503 3.245 .503 3.245 Model 81, 83 H .785 5.065 .785 5.065 Model 81, 83, 81P J 1.287 8.303 1.287 8.303 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 11 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Orifice Areas ASME Orifice Areas – Pilot Operated PRVs Valve Size Type X331 [0.98]2 Type X231 Type X731 Orifice Area, in2 [cm2] Type 226/526 Type 576 Type 727 1” x 2” 11/2” x 2” 0.152 (‘D’) 0.265 (‘E’) [1.71] 0.318 (‘F’) [2.05] — — — — 11/2” x 2” 0.599 (‘G’) [3.86]3 0.817 (‘H’) [5.27]3 1.336 [8.62] — 1.336 [8.62] — 11/2” 0.599 (‘G’) [3.86] 0.817 (‘H’) [5.27] — 0.817 (‘H’) [5.27] — x 3” 2” x 3” 3” x 4” 0.631 (‘G’) [4.07] 0.973 (‘H’) [6.28] 1.448 (‘J’) [9.34] 2.162 (‘K’) [13.95] 1.336 (‘J’) [8.62] 2.530 [16.32] 1.336 (‘J’) [8.62] 2.530 [16.32] 4.369 (‘M’) [28.19] 0.981 (‘H’) [6.33] 1.635 (‘J’) [10.55] 2.985 (‘L’) [19.26] 6.651 [42.91] 2.985 (‘L’) [19.26] 6.651 [42.91] 1.635 (‘J’) [10.55] 2.298 (‘K’) [14.82] 3.557 (‘L’) [22.95] 3.557 (‘L’) [22.95] 3.512 (‘L’) [22.66] 4” x 6” — 0.629 (‘G’) [4.06] 6.651 (‘P’) [42.91] 9.629 [62.12] 6.651 (‘P’) [42.91] 9.629 [62.12] 5.054 (‘N’) [32.61] 4.505 (‘M’) [29.06] 5.425 (‘N’) [35.00] 7.911 (‘P’) [51.04] 6” x 8” 12.350 (‘Q’) [79.68] 16.655 (‘R’) [107.45] 6” x Dual 8” — — 16.655 (‘R’) [107.45] 21.520 [138.84] 13.813 (‘Q’) [89.12] 20.000 (‘R’) [129.03] 22.990 (‘RR’) [148.32] 21.520 [138.84] — — — — 8” x 10” — 27.109 (‘T’) [174.90] — 27.109 (‘T’) [174.90] 44.180 [285.03] 32.500 (‘T’) [209.68] 8” x Dual 8” — — 29.420 [189.81] — — — 8” x Dual 10” 8” x Single 10” — — 44.180 [285.03] — 44.180 [285.03] — Notes 1. Series 200/300/400/600/800/900. 2. Except for liquid service. 3. Threaded body only. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 12 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Orifice Areas API Orifice Areas – Pilot Operated PRVs Valve Size Type X331 Type X231 Type X731 Orifice Area, in2 [cm2] Type 226/526 Type 576 Type 727 1” x 2” 11/2” x 2” 0.110 (‘D’) [0.71]2 0.196 (‘E’) [1.26] 0.307 (‘F’) [1.98] — — — — 11/2” x 2” 0.503 (‘G’) [3.24]3 0.785 (‘H’) [5.06]3 1.257 [8.11] — 1.257 [8.11] — 11/2” 0.503 (‘G’) [3.24] 0.785 (‘H’) [5.06] — 0.785 (‘H’) [5.06] — x 3” 2” x 3” 3” x 4” 0.503 (‘G’) [3.24] 0.785 (‘H’) [5.06] 1.287 (‘J’) [8.30] 1.838 (‘K’) [11.86] 1.287 (‘J’) [8.30] 2.380 [15.35] 1.287 (‘J’) [8.30] 2.380 [15.35] 3.60 (‘M’) [23.22] 2.853 (‘L’) [18.41] 6.257 [40.37] 2.853 (‘L’) [18.41] 6.257 [40.37] 11.05 (‘Q’) [71.29] 6” x Dual 8” 8” x 10” 1.287 (‘J’) [8.30] 1.838 (‘K’) [11.86] 2.853 (‘L’) [18.41] 2.853 (‘L’) [18.41] 6.38 (‘P’) [41.16] 9.058 [58.44] 6.38 (‘P’) [41.16] 9.058 [58.44] 4.34 (‘N’) [28.00] 6” x 8” 0.785 (‘H’) [5.06] 1.287 (‘J’) [8.30] 2.853 (‘L’) [18.41] 4” x 6” — 0.503 (‘G’) [3.24] 3.60 (‘M’) [23.22] 4.34 (‘N’) [28.00] 6.38 (‘P’) [41.16] 16.00 (‘R’) [103.22] — 11.05 (‘Q’) [71.29] 16.00 (‘R’) [103.22] 16.00 (‘R’) [103.22] — — — 20.244 [130.61] — — — — 26.00 (‘T’) [167.74] — 26.00 (‘T’) [167.74] 41.56 [268.13] 26.00 (‘T’) [167.74] 8” x Dual 8” — — 27.675 [178.55] — — — 8” x Dual 10” 8” x Single 10” — — 41.56 [268.13] — 41.56 [268.13] — Notes 1. Series 200/300/400/600/800/900. 2. Except for liquid service. 3. Threaded body only. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 13 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Orifice Areas Orifice Areas - Types 93/93T Valve Size ASME (in2) [cm2] Orifice Areas - Types 91/94 API (in2) [cm2] Valve Size ASME (in2) [cm2] API (in2) [cm2] 2” 2.29 14.77 2.29 14.77 2” 2.92 18.84 2.92 18.84 3” 5.16 33.29 5.16 33.29 3” 6.24 40.26 6.24 40.26 8.74 4” 8.74 56.38 56.38 4” 10.33 66.65 10.33 66.65 6” 19.56 126.93 19.56 126.93 6” 22.22 143.35 22.22 143.35 8” 36.40 234.84 36.40 234.84 8” 39.57 255.29 39.57 255.29 10” 51.00 329.03 51.00 329.03 10” 56.75 366.12 56.75 366.12 12” 84.00 541.93 84.00 541.93 12” 89.87 579.80 89.87 579.80 Orifice Areas - Type 95 Valve Size ASME (in2) [cm2] Orifice Areas - Type 96A API (in2) [cm2] Valve Size ASME (in2) [cm2] API (in2) [cm2] 2” 2.92 18.84 2.92 18.84 2” 11.70 75.48 11.70 75.48 3” 6.25 40.32 6.25 40.32 3” 23.89 154.12 23.89 154.12 4” 10.32 66.58 10.32 66.58 4” 36.80 237.42 36.80 237.42 6” 22.15 142.90 22.15 142.90 6” 80.93 522.12 80.93 522.12 Orifice Areas - Series 9000 Valve Size 2” 3” 4” ASME (in2) [cm2] 3.356 7.393 21.65 47.69 API (in2) [cm2] 3.356 7.393 21.65 47.69 12.73 82.12 12.73 82.12 6” 28.89 186.38 28.89 186.38 8” 50.027 322.71 50.027 322.71 10” 78.854 508.73 78.854 508.73 12” 113.097 729.66 113.097 729.66 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 14 Anderson Greenwood Pressure Relief Valves Technical Manual Back Pressure and Subsonic Flow Correction Factor for Section I and Section VIII Sizing Formulas for Gas, Steam and Liquid © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 15 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Evaluating Back Pressure Correction Kb Factor for Gas and Steam Sources of Back Pressure When any back pressure exists, a test for subsonic flow should be made. If the absolute outlet-to-inlet flowing pressure ratio (P2/P1) is greater than 0.30 a back pressure correction factor Kb may be required subject to the additional commentary below. A pressure relief valve whose outlet is discharging into vent piping or to another pressure vessel or system will encounter one or two types of back pressure: superimposed and/or built-up. The required values of Kb as a function of P outlet/P inlet are determined from the curves presented in this section for both conventional spring operated and pilot operated pressure relief valves. General Whenever flow through a pressure relief valve occurs under sonic conditions, the value of Kb is 1.00. When a pressure relief valve discharges directly to the atmosphere and the set pressure is 15 psig [1.03 barg] or greater, flow is considered to be sonic, therefore Kb remains equal to 1.00. If the pressure relief valve discharges into any piping where the back pressure at the valve outlet under relieving conditions exceeds a definitive limit, flow will be subsonic. The orifice area calculation of a pressure relief valve, flowing under these conditions, must be mathematically adjusted using the back pressure correction factor Kb. Kw Factor for Liquids Whenever back pressure is encountered in bellows and pressure balanced spring operated liquid relief valves, a reduction in flow capacity due to reduced valve lift can result. A Kw factor to correct for this reduction is included in the liquid capacity equation. The required values of Kw based upon P2/P1 are determined from the curves at the back of this section. Superimposed back pressure may come from the vent system due to the discharge of other pressure relief valves into a common manifold or due to the nature of other processes that affect the downstream pressure. The presence of superimposed back pressure may not necessarily create subsonic flow. However the outlet pressure may rise further, due to flow from the pressure relief valve, and may be sufficient to cause subsonic flow. Built-up back pressure occurs as a result of the discharge of fluid through a flowing pressure relief valve with connected downstream piping or equipment. In some instances, relatively short sections of piping connected by the outlet of a pressure relief valve and venting to the atmosphere will be sufficient to create back pressure during a relieving cycle that will cause flow to be subsonic. The result will be a reduction of flow capacity. If this is less than the required relieving capacity, the inlet pressure may rise sufficiently to exceed the permissible accumulation for the application. The problem is compounded when there is also some superimposed back pressure, since built-up back pressure will be additive. Conventional Direct Spring Operated Pressure Relief Valves If a conventional, direct spring operated pressure relief valve is to be applied where any built-up back pressure will be developed, the maximum permissible built-up back pressure shall not exceed 10% of set pressure. Under this limit, no back pressure correction factor need be applied, except as follows: © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 16 • When a conventional pressure relief valve is set to open with a superimposed back pressure sufficiently high to create subsonic flow, the back pressure correction factor may be applied (assuming that the pressure ratio exceeds the critical ratio). • If the valve is known to be tolerant to a greater amount, the back pressure correction factor may be applied. Balanced Pressure Relief Valves The balanced bellows valve is balanced against superimposed back pressure. It is also resistant to a moderate amount of built-up back pressure. Apply the back pressure correction factor Kb. When balanced bellows valves are used, the maximum permissible built-up back pressure should not exceed 40%. Pilot Operated Pressure Relief Valves A properly selected and installed pilot operated pressure relief valve will operate effectively under all combinations of superimposed and built-up back pressure, limited only by the valve pressure rating and practical considerations. Apply the back pressure correction factor Kb, if applicable. Solving for Kb The critical pressure ratio is a function of the value of k, the specific heat ratio of the gas. The value of PCF /P1 varies from 0.444 to 0.607 for a range of k between 1.00 and 2.00. When sizing valve designs for set pressures below 15 psig covered under API 2000, the P outlet/P inlet ratio may be calculated and compared directly to the correct P critical for the gas or vapor k value. The k values for selected gases, the P critical vs. k equation and a set of P critical vs. k curves for frequently encountered k values are presented in the ‘Fluid Data’ section of this manual. Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Superimposed Back Pressure Correction Factors Direct Spring PRVs/Vapor and Gases ASME Section VIII Constant Back Pressure Correction Factor Kb Back Pressure Correction Factor Kb 1.00 .90 .80 .70 .60 .50 .40 .30 .20 .10 0 ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ 0 10 20 30 40 50 60 70 80 90 100 Back Pressure Percentage = Back pressure, psia or bara x 100 Flowing pressure, psia or bara Example: Set pressure = 200 psig [13.79 barg] Constant back pressure = 160 psig [11.03 barg] 160 + 14.7 Back pressure percentage (absolute) = –––––––––––––– x 100 = 74% or 200 + 20 + 14.7 11.03 + 1.013 –––––––––––––––––– = 74% 13.79 + 1.38 + 1.013 Factor Kb = 0.91 (follow dotted line from curve) Capacity with back pressure = 0.91 x rated capacity without back pressure © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 17 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Superimposed and Built Up Back Pressure/Subsonic Flow Correction Factors Capacity with back pressure Variable Back Pressure Correction Factor Kb Capacity with back pressure Back pressure, psig or barg x 100 Set pressure, psig or barg 50 psig [3.44 barg] and over .90 Example: Set pressure = 100 psig [6.89 barg] Back pressure = 0 to 35 psig [2.41 barg] 35 Back pressure percentage (gauge) = ––– 100 x 100 = 35% max. 10% Overpressure .80 15 psig [1.013 barg] .70 Factor Kb = 0.94 (follow dotted line from curve) Capacity with back pressure = 0.94 x rated capacity without back pressure .60 ▲ 0 ▲ 5 ▲ 10 ▲ 15 ▲ 20 ▲ 25 ▲ 30 ▲ 35 ▲ 40 ▲ 45 ▲ 50 Back pressure percentage = Back pressure, psig or barg x 100 Set pressure, psig or barg Variable Back Pressure Correction Factor Kb Example: Set pressure = 100 psig [6.89 barg] Back pressure = 0 to 35 psig [2.41 barg] 35 Back pressure percentage (gauge) = ––– 100 x 100 = 35% max. 50 psig [3.44 barg] and over 1.00 20% Overpressure .90 15 psig [1.013 barg] .80 ▲ 0 ▲ 5 ▲ 10 ▲ 15 ▲ 20 ▲ 25 ▲ 30 ▲ 35 ▲ 40 ▲ 45 Factor Kb = 0.99 (follow dotted line from curve) Capacity with back pressure = 0.99 x rated capacity without back pressure ▲ 50 Kb = Rated capacity without back pressure Back pressure percentage = 1.00 Kb = Rated capacity without back pressure Direct Spring PRVs - Model Designations - Bellows Valves Only/Vapors and Gases ASME Section VIII © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 18 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Superimposed and Built Up Back Pressure/Subsonic Flow Correction Factor (Kb) Back Pressure Correction Factor for Piston Pilot Operated PRVs Gas, Vapor, or Steam 1.000 k = 1.0 0.900 k = 1.2 k = 1.4 0.800 k = 1.6 k = 1.8 Back Pressure Factor, Kb 0.700 k = 2.0 0.600 0.500 0.400 0.300 0.200 0.100 0.000 0.200 0.300 0.400 P2 P1 0.500 0.600 0.700 0.800 0.900 1.000 = Absolute Pressure Ratio at Valve Inlet The above curves are applicable for all pressure ranges and overpressures and accurately predict the reduction on capaci- ty for full lift, API orifice valves. For full bore valves, multiply above ‘Kb’ values by 0.95. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 19 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing - Back Pressure Correction Factor for Type 727 – Gas, Vapor or Steam 1.0 0.98 k = 1.0 0.96 Back Pressure Factor, K b k = 1.2 0.94 k = 1.4 0.92 k = 1.6 0.90 k = 1.8 0.88 k = 2.0 0.86 0.40 0.45 0.50 0.55 0.60 P2 /P1 = Absolute Pressure Ratio at Orifice © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 20 0.65 0.70 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing - Liquid Flow Direct Spring PRVs - Model Designation - Bellows Valves Only/Liquid Service Rated capacity based on Fd Factor Kw = 0.95 (follow dotted line from curve) Capacity with variable back pressure = 0.95 x rated capacity Based on differential pressure Fd Variable or Constant Back Pressure Correction Factor Kw 1.00 .90 .80 .70 .60 ▲ 0 Kw = Example: Set pressure = 100 psig [6.89 barg] Back pressure = 0 to 24 psig [1.65 barg] 24 Back pressure percentage (gauge) = ––– 100 x 100 = 24% max. ▲ 5 ▲ 10 ▲ 20 ▲ 15 ▲ 30 ▲ 25 ▲ 45 ▲ 40 ▲ 35 ▲ 50 Curve to Evaluate Liquid Back Pressure for Series 81P Correction Factor kw 1.00 Kw = Back Pressure Correction Factor Based on 10% Overpressure Back pressure, psig or barg x 100 Set pressure, psig or barg Capacity with variable back pressure Back pressure percentage = 0.90 0.80 Correction Curve for Types 81P - 4 and 81P - 8 0.70 0.60 Correction Curve for Types 81P - G and 81P - J 0.50 0.40 0.30 0.20 0.10 0.00 ▲ 0 ▲ 5 ▲ 10 ▲ 15 ▲ 20 ▲ 25 Percentage Back Pressure = ▲ 30 ▲ 35 ▲ 40 ▲ 45 ▲ 50 ▲ 55 ▲ 60 Back Pressure, psig [barg] x 100 Set Pressure, psig [barg] © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 21 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Gas and Vapor Equations Sizing Information ASME Section I and VIII ASME VIII Gas Flow (Set Pressure ≥ 15 psig [1.03 barg]) U.S. Weight Flow (lb/h) Formula 1 W A = ––––––– CK P1Kb –––– TZ ––– M √ U.S. Volumetric Flow (scfm) Formula 2 –––– V √ MTZ A = –––––––––––– 6.32 CK P1Kb Metric Weight Flow [kg/h] Formula 1M 1.316 W A = ––––––– CK P1Kb After system capacity has been determined, a properly sized pressure relief valve is determined by the following method. –––– TZ ––– M √ Metric Volumetric Flow [Nm3/h] Formula 2M A. From the formulas in this section calculate required orifice area as a function of capacity. The orifice sizes for steam, air, or water may be obtained from the capacity tables catalog. B. Identify the required orifice letter designation, such as D, E, F, etc. Always choose an orifice which is equal to, or greater than the required orifice area. –––– V √ MTZ A = ––––––––––––– 17.02 CK P1Kb C. Specifications exceeding Anderson Greenwood standard catalog descriptions should be referred to our sales department. D. When selecting orifice areas and nozzle coefficients, either select the ASME area and nozzle coefficient, or the equivalent API area and nozzle coefficient. Mixing ASME and API values is incorrect and may result in a dangerous sizing error. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 22 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Gas and Vapor Flow (English Units) Examples for Steam and Gas Applications Example 1 - ASME VIII Gas Solution: Given: Butane, with a required flow rate of 16,000 scfm, set at 88 psig, 10% overpressure, gas temperature of 60°F, discharging to a closed header system. The back pressure (maximum) is 40 psig. Use Formula 1 Find: The required orifice area. ––––– V √ MTZ A = –––––––––––– 6.32 CK P1Kb –––––––––––––– 16,999 √ (58.12)(520)(1) 12.108 A = ––––––––––––––––––––– = –––––– 6.32 (326)(111.5) K Kb K Kb V = 16,000 M = 58.12 C = 326 T = 60 + 460 = 520 Z = 1.0 P1 = 88 (1.1) + 14.7 = 111.5 Kb = 40 = 45% 88 Bellows Valve – Kb = 0.77 Pilot Valve – 40 + 14.7 = 49% 111.5 Kb = 0.98 For the bellows valve, the correct orifice selection would be an 8T10 (26.0 in2). For the case of selecting a POSRV, the correct orifice selection would be 6R8 (16.00 in2). Case 1 - Select a DB Series with K = 0.971, Kb = 0.77, A = 16.19 in2. Case 2 - Select a POSRV with K = 0.86, Kb = 0.98, A = 14.36 in2. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 23 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Gas and Vapor Flow - [Metric Units] Examples for Gas and Steam Applications Solution: Example 2 Use formula 1M and the physical properties found on pages 51-63. Given: Butane, with a required flow rate of 9,000 Nm3/h, set at 5 barg, 10% overpressure, relieving temperature of 15°C, discharging to atmosphere. P1 T M Z Kb = = = = = 5 x (1.1) + 1.013 = 6.513 bara 15 + 273 = 288°K 58.12, C = 326 1.00 (used when no value is given) 1.00 (when back pressure equals atmospheric) Find: –––––––––––––––– 9,000 √ 58.12 x 288 x 1.00 32.22 cm2 A [cm2] = ––––––––––––––––––––––––– = ––––––––– 17.02 x 326 x K x 6.513 x 1.00 K A= The required orifice area for a typical conventional safety valve and the orifice selected. 32.22 = 33.18 cm2 .971 Selecting a valve with a K = 0.971, the orifice to be selected is a 4P6 (41.16 cm2). Solution: The same data is used as in example 2, except use a nozzle coefficient K = 0.809 (from page 9) in formula 2M. –––––––––––––––– 9,000 √ 58.12 x 288 x 1.00 2 A [cm ] = –––––––––––––––––––––––––––– = 39.83 cm2 17.02 x 326 x 0.809 x 6.513 x 1.00 Example 3 Given: Same as example 2. Find: The appropriate size valve for a piston type (Series 200, 300, etc.), pilot operated safety valve. From page 12, the next larger available orifice is 42.91 cm2 corresponding to a ‘fullbore,’ 3-inch x 4-inch valve, Series 273 or 473. Note in this example, ASME not API coefficients are used. Solution: Example 4 The back pressure represents 44% of the set pressure (2.2/5.0). For a Direct Spring SRV, Kb = 0.78, for a 200 Series Pilot Operated PRV, the back pressure represents 49% of the absolute pressure ratio: 2.2 + 1.03 5.0 x 1.1 + 1.03 Given: The same as example 2, except with a built-up back pressure of 2.2 barg. Find: Therefore, the Kb for the Series 200 = 0.985 (from page 19). Again using formula 2M, for the Direct Spring Valve: ––––––––––––––– 9,000 √ 58.12 x 288 x 1.0 A = ––––––––––––––––––––––––––– = 42.54 cm2 17.02 x 326 x 971 x 6.513 x .78 Selecting a direct spring would result in a 6Q8 (71.29 cm2). For the POSRV: A ––––––––––––––– 9,000 √ 58.12 x 288 x 1.0 32.71 cm2 = ––––––––––––––––––––––––––– = –––––––– 17.02 x 326 x K x 6.513 x .985 K Case 1 - Select a Type 223, K = 0.830, A = 39.40 cm2. Case 2 - Select a Type 273, K = 0.809, A = 40.43 cm2. Selecting a pilot valve could either be a 4P6 (42.91 cm2) or a full bore 3 x 4 (42.91 cm2). © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 24 The appropriate size to meet the relieving conditions. Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Steam Flow Sizing Information ASME Section I and VIII After system capacity has been determined, a properly sized pressure relief valve is determined by the following method. A. From the formulas in this section calculate required orifice area as a function of capacity. The orifice sizes for steam, air, or water may be obtained from the capacity tables catalog. B. Identify the required orifice letter designation, such as D, E, F, etc. Always choose an orifice which is equal to, or greater than the required orifice area. C. Specifications exceeding Anderson Greenwood standard catalog descriptions should be referred to our sales department. D. When selecting orifice areas and nozzle coefficients, either select the ASME area and nozzle coefficient, or the equivalent API area and nozzle coefficient. Mixing ASME and API values is incorrect and may result in a dangerous sizing error. ASME I Sonic Steam Flow (Set Pressure ≥ 15 psig [1.03 barg]) U.S. Units (lb/h) Formula 3 Metric Units [kg/h] Formula 3M W A = ––––––––––––––––– 51.45 K P1KSHKNK b W A = ––––––––––––––––– 52.45 K P1KSHKNK b KN = 1.00 for P ≤ 1500 psig KN = 1.00 for P ≤ 103.4 barg 0.1906 P - 1000 KN = ––––––––––––– 0.2292 P - 1061 2.764 P - 1000 KN = ––––––––––––– 3.323 P - 1061 where 1500 psig < P < 3200 psig where 103.4 barg < P < 220.7 barg ASME VIII Sonic Steam Flow (Set Pressure ≥ 15 psig [1.03 barg]) U.S. Units (lb/h) Formula 4 Metric Units [kg/h] Formula 4M W A = –––––––––––––––– 51.5 K P1KSHKNK b W A = –––––––––––––––– 52.5 K P1KSHKNK b KN = 1.00 for P ≤ 1500 psig KN = 1.00 for P ≤ 103.4 barg 0.1906 P - 1000 KN = ––––––––––––– 0.2292 P - 1061 2.764 P - 1000 KN = ––––––––––––– 3.323 P - 1061 where 1500 psig < P < 3200 psig where 103.4 barg < P < 220.7 barg © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 25 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Steam (English Units) Examples for Steam Applications Solution: Example 5 - ASME I Steam W Use Formula 3 Given: Steam, with a required flow rate of 4,050 lb/h, set at 18 psig, is required for an ASME I boiler application. Steam temperature is 420°F. KSH = 0.97 W A= 51.45 K P1KSHKNKb 4050 A = –––––––––––––––––––– = 51.45 K (.97)(1)(34.7)(1) = 4050 KN = 1.00 2.388 –––––– K Kb = 1.00 P1 = 18 + 2 + 14.7 = 34.7 Find: Selecting a valve with a K = 0.878 (K Series), A = 2.66 in2. = in2). Note the overpressure for set This orifice corresponds to an L orifice (2.853 pressures between 15 psig and 70 psig is 3% or 2 psig minimum. Solution: 2.338 K Example 6 - ASME VIII Steam Use Formula 4 W W A= 51.5 K P1KSHKNKb Given: Steam, with a required flow rate of 84,000 lb/h, set at 400 psig, is required for an unfired pressure vessel application. Steam temperature is 448°F. = 84,000 KSH = 1.00 KN = 1.00 84,000 A = –––––––––––––––––––– = 51.5 (K)(1)(1)(454.7)(1) 3.587 –––––– K Kb = 1.00 P1 = 400 (1.1) + 14.7 = 454.7 Selecting a valve with a K = 0.971 (D Series), A = 3.69 in2. This orifice corresponds to a 4N6 orifice (4.34 in2). The approximate flowing capacity can be estimated from the ratio of actual area to required area as follows: W = 84,000 x The required orifice area. 4.34 = 98,796 lb/hr 3.69 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 26 Find: The required orifice area and approximate valve capacity. Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Sonic Flow (English Units) Curve to Evaluate Napier Correction Factor KN for High Pressure Dry Saturated Steam 1.200 1.190 1.180 1.170 1.160 KN = 1.150 where 1500 psig < P < 3200 psig 1.140 Napier Correction Factor, KN 0.1906 P - 1000 (10a) 0.2292 P - 1061 1.130 1.120 1.110 1.100 1.090 1.080 1.070 1.060 1.050 1.040 1.030 1.020 1.010 1.000 ▲ 1500 ▲ 1700 ▲ 1900 ▲ 2100 ▲ 2300 ▲ 2500 ▲ 2700 ▲ 2900 ▲ 3100 ▲ 3300 Steam Relieving Pressure, P1 (psig) © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 27 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Sonic Flow [Metric Units] Curve to Evaluate Napier Correction Factor KN for High Pressure Dry Saturated Steam 1.210 1.200 1.190 1.180 1.170 KN = 2.764 P - 1000 3.323 P - 1061 (10) where 103.4 barg < P < 220.7 barg 1.160 Napier Correction Factor, KN 1.150 1.140 1.130 1.120 1.110 1.000 1.090 1.080 1.070 1.060 1.050 1.040 1.030 1.020 1.010 ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ 100 110 120 130 140 150 160 170 180 190 200 210 220 230 Steam Relieving Pressure, P1 (barg) © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 28 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Steam – Superheat Correction Superheat Correction Factor (KSH) for Superheated Steam Relieving Pressure psia [bara] 50 [3.4] Total Steam Temperature °F [°C] 400 450 500 550 600 650 700 750 800 850 900 950 1000 1050 1100 1150 1200 [204] [232] [260] [288] [316] [343] [371] [399] [427] [454] [482] [510] [538] [566] [593] [621] [649] .987 .957 .930 .905 .882 .861 .841 .823 .805 .789 .774 .759 .745 .732 .719 .708 .696 100 [6.9] .998 .963 .935 .909 .885 .864 .843 .825 .807 .790 .775 .760 .746 .733 .720 .708 .697 150 [10.3] .984 .970 .940 .913 .888 .866 .846 .826 .808 .792 .776 .761 .747 .733 .721 .709 .697 200 [13.8] .979 250 [17.2] .977 .945 .917 .892 .869 .848 .828 .810 .793 .777 .762 .748 .734 .721 .709 .698 .972 .951 .921 .895 .871 .850 .830 .812 .794 .778 .763 .749 .735 .722 .710 .698 300 [20.7] .968 .957 .926 .898 .874 .852 .832 .813 .796 .780 .764 .750 .736 .723 .710 .699 350 [24.1] .968 .963 .930 .902 .877 .854 .834 .815 .797 .781 .765 .750 .736 .723 .711 .699 400 [27.6] .963 .935 .906 .880 .857 .836 .816 .798 .782 .766 .751 .737 .724 .712 .700 450 [31.0] .961 .940 .909 .883 .859 .838 .818 .800 .783 .767 .752 .738 .725 .712 .700 500 [34.5] .961 .946 .914 .886 .862 .840 .820 .801 .784 .768 .753 .739 .725 .713 .701 550 [37.9] .962 .952 .918 .889 .864 .842 .822 .803 .785 .769 .754 .740 .726 .713 .701 600 [41.4] .964 .958 .922 .892 .867 .844 .823 .804 .787 .770 .755 .740 .727 .714 .702 650 [44.8] .968 .958 .927 .896 .869 .846 .825 .806 .788 .771 .756 .741 .728 .715 .702 700 [48.3] .958 .931 .899 .872 .848 .827 .807 .789 .772 .757 .742 .728 .715 .703 750 [51.7] .958 .936 .903 .875 .850 .828 .809 .790 .774 .758 .743 .729 .716 .703 800 [55.2] .960 .942 .906 .878 .852 .830 .810 .792 .774 .759 .744 .730 .716 .704 850 [58.6] .962 .947 .910 .880 .855 .832 .812 .793 .776 .760 .744 .730 .717 .704 900 [62.1] .965 .953 .914 .883 .857 .834 .813 .794 .777 .760 .745 .731 .718 .705 950 [65.5] .969 .958 .918 .886 .860 .836 .815 .796 .778 .761 .746 .732 .718 .705 1000 [69.0] .974 1050 [72.4] .959 .923 .890 .862 .838 .816 .797 .779 .762 .747 .732 .719 .706 .960 .927 .893 .864 .840 .818 .798 .780 .763 .748 .733 .719 .707 1100 [75.9] .962 .931 .896 .867 .842 .820 .800 .781 .764 .749 .734 .720 .707 1150 [79.3] .964 .936 .899 .870 .844 .821 .801 .782 .765 .749 .735 .721 .708 1200 [82.8] .966 .941 .903 .872 .846 .823 .802 .784 .766 .750 .735 .721 .708 1250 [86.2] .969 .946 .906 .875 .848 .825 .804 .785 .767 .751 .736 .722 .709 1300 [89.7] .973 .952 .910 .878 .850 .826 .805 .786 .768 .752 .737 .723 .709 1350 [93.1] .977 .958 .914 .880 .852 .828 .807 .787 .769 .753 .737 .723 .710 1400 [96.6] .982 .963 .918 .883 .854 .830 .808 .788 .770 .754 .738 .724 .710 1450 [100.0] .987 .968 .922 .886 .857 .832 .809 .790 .771 .754 .739 .724 .711 1500 [103.4] .993 .970 .926 .889 .859 .833 .811 .791 .772 .755 .740 .725 .711 1550 [106.9] .972 .930 .892 .861 .835 .812 .792 .773 .756 .740 .726 .712 1600 [110.3] .973 .934 .894 .863 .836 .813 .792 .774 .756 .740 .726 .712 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 29 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Steam – Superheat Correction Superheat Correction Factor (KSH) for Superheated Steam Relieving Pressure psia [bara] Total Steam Temperature °F [°C] 400 450 500 550 600 650 700 750 800 850 900 950 1000 1050 1100 1150 1200 [204] [232] [260] [288] [316] [343] [371] [399] [427] [454] [482] [510] [538] [566] [593] [621] [649] 1650 [113.8] .973 .936 .895 .863 .836 .812 .791 .772 .755 .739 .724 .710 1700 [117.2] .973 .938 .895 .863 .835 .811 .790 .771 .754 .738 .723 .709 1750 [120.7] .974 .940 .896 .862 .835 .810 .789 .770 .752 .736 .721 .707 1800 [124.1] .975 .942 .897 .862 .834 .810 .788 .768 .751 .735 .720 .705 1850 [127.6] .976 .944 .897 .862 .833 .809 .787 .767 .749 .733 .718 .704 1900 [131.0] .977 .946 .898 .862 .832 .807 .785 .766 .748 .731 .716 .702 1950 [134.5] .979 .949 .898 .861 .832 .806 .784 .764 .746 .729 .714 .700 2000 [137.9] .982 .952 .899 .861 .831 .805 .782 .762 .744 .728 .712 .698 2050 [141.4] .985 .954 .899 .860 .830 .804 .781 .761 .742 .726 .710 .696 2100 [144.8] .988 2150 [148.3] .956 .900 .860 .828 .802 .779 .759 .740 .724 .708 .694 .956 .900 .859 .827 .801 .778 .757 .738 .722 .706 .692 2200 [151.7] .955 .901 .859 .826 .799 .776 .755 .736 .720 .704 .690 2250 [155.2] .954 .901 .858 .825 .797 .774 .753 .734 .717 .702 .687 2300 [158.6] .953 .901 .857 .823 .795 .772 .751 .732 .715 .699 .685 2350 [162.1] .952 .902 .856 .822 .794 .769 .748 .729 .712 .697 .682 2400 [165.5] .952 .902 .855 .820 .791 .767 .746 .727 .710 .694 .679 2450 [169.0] .951 .902 .854 .818 .789 .765 .743 .724 .707 .691 .677 2500 [172.4] .951 .902 .852 .816 .787 .762 .740 .721 .704 .688 .674 2550 [175.9] .951 .902 .851 .814 .784 .759 .738 .718 .701 .685 .671 2600 [179.3] .951 .903 .849 .812 .782 .756 .735 .715 .698 .682 .664 2650 [182.8] .952 .903 .848 .809 .779 .754 .731 .712 .695 .679 .664 2700 [186.2] .952 .903 .846 .807 .776 .750 .728 .708 .691 .675 .661 2750 [189.7] .953 .903 .844 .804 .773 .747 .724 .705 .687 .671 .657 2800 [193.1] .956 .903 .842 .801 .769 .743 .721 .701 .684 .668 .653 2850 [196.6] .959 .902 .839 .798 .766 .739 .717 .697 .679 .663 .649 2900 [200.0] .963 .902 .836 .794 .762 .735 .713 .693 .675 .659 .645 2950 [203.4] .902 .834 .790 .758 .731 .708 .688 .671 .655 .640 3000 [206.9] .901 .831 .786 .753 .726 .704 .684 .666 .650 .635 3050 [210.3] .899 .827 .782 .749 .722 .699 .679 .661 .645 .630 3100 [213.8] .896 .823 .777 .744 .716 .693 .673 .656 .640 .625 3150 [217.2] .894 .819 .772 .738 .711 .688 .668 .650 .634 .620 3200 [220.7] .889 .815 .767 .733 .705 .682 .662 .644 .628 .614 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 30 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Liquid Flow ASME VIII Liquids (Set Pressure ≥ 15 psig [1.03 barg]) U.S. Volumetric Flow (gpm @ 10% overpressure) Formula 5 ––– W√ G A = ––––––––––––––––––––– –––––––––– 38 K KvKw √1.10 P - P2 Metric Volumetric Flow [m3/h @ 10% overpressure] Formula 5M ––– 0.19631 W √ G A = –––––––––––––––––– ––––––––– K KvKw √1.10 P - P2 Liquids (Non ASME Certified) U.S. Volumetric Flow (gpm) Formula 6 ––– W√ G A = ––––––––––––––––––– ––––– 38 K KpKvKw √ P - P2 Metric Volumetric Flow [m3/h] Formula 6M ––– 0.19631 W √ G A = –––––––––––––––– ––––– K KpKvKw √ P - P2 Reynolds Number Calculation U.S. Volumetric Flow (gpm) Formula 7 12,700 W R = ––––––––– –– U √A Metric Volumetric Flow [m3/h] Formula 7M 31,313 WG R = ––––––––––– –– µ √A © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 31 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Liquid Flow Viscosity Correction (English) Example 7 When a relief valve is sized for viscous liquid service, it is suggested that it be sized first as for nonviscous-type application in order to obtain a preliminary required discharged area, A. From manufacturers’ standard orifice sizes, the next larger orifice size should be used in determining the Reynold’s number, R, from the following relationship: 12,700 W R = –––––––––– –– µ √ A1 Where: W = required flow rate at the flowing temperature, in U.S. gallons per minute. A1 = effective discharge area, in square inches U = viscosity at the flowing temperature, in Saybolt Universal seconds. After the value of R is determined, the factor Kv is obtained from page 33. Kv is applied to correct the ‘preliminary required discharge area.’ If the corrected area exceeds the ‘chosen standard orifice area,’ the above calculations should be repeated using the next larger standard orifice size. Example: Viscosity - SSU .......10,000 SSU @ 100°F Required Capacity ......................300 GPM Set Pressure.................................100 psig Constant Back Pressure.................15 psig Allowable Overpressure......................10% Specific Gravity......................1.0 @ 100°F Relieving Temperature .....................100°F Step 1 ––– W√ G A = ––––––––––––––––––––– –––––––––– 38 K KvKw √1.10 P - P2 ––– 300 √ 1.0 A = ––––––––––––––––––––– –––––––– 38 (.776)(1) √1.10 - 15 A = 1.043 Preliminary Required Discharge Area A1, Select Standard Orifice Area = 1.287 ‘J ’ Orifice Step 2 12,700 x 300 R = ––––––––––––––– –––––– 10,000 √ 1.287 R= 335.8 Step 3 R= 335.8 correction factor from chart Kv = 0.815 Step 4 Corrected ‘Preliminary Required A Discharge Area’ = –––– Kv = 1.043 –––––– .815 = 1.279 in2 If corrected ‘Preliminary Required Discharge Area’ is greater than selected standard orifice area, select next orifice size and repeat steps 2, 3, and 4. In this example, the corrected orifice area is still within the ‘J’ orifice and therefore is the correct selection. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 32 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Liquid Flow Curve to Evaluate Liquid Viscosity Correction Factor Kv 100,000 50,000 40,000 30,000 20,000 Reynolds Number, R 10,000 5,000 4,000 3,000 2,000 1,000 500 400 300 200 100 50 40 30 20 ▲ 0.20 ▲ 0.30 ▲ 0.40 ▲ 0.50 ▲ 0.60 ▲ 0.70 ▲ 0.80 ▲ 0.90 ▲ 1.00 Liquid Viscosity Correction Factor, KV © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 33 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Liquid Flow (English Units) Examples for Liquid Applications Solution: Example 8 - ASME VIII Liquids Use Formula 5 ––– 69 √ G A = ––––––––––––––––––– –––––––– 38 K KvKw √1.1 P - P2 W = 69 G = 1.115 P = 26 P2 = 4 Given: Ethylene Glycol, with a required flow rate of 69 GPM, set at 26 psig, 10% overpressure, built-up back pressure of 4 psig. Find: KV = 1 KW = 1 The required orifice area and the orifice area to be selected. –––––– .3865 69 √ 1.115 A = ––––––––––––––––––––––– ––––––––– = ––––– 38 K x 1 x 1 x √1.1(26) - 4 K For Direct Spring D Series: K = .776 For POSRV: K = .670 For AGCO D Series: A = .3865 = 0.498, Select 11/2 G 21/2 (0.503 in2) .776 For AGCO 400 Series POSRV: A = .3865 = 0.576, Select 11/2 H3 (0.785 in2) .67 Solution: Example 9 ASME API K for D Series = .700 K for D Series = .776 K for 400 Series = .650 K for 400 Series = .670 Compare the ASME vs API sizing coefficients for the data used in example 8. This example illustrates two important points to consider in valve sizing. For D Series: A= 1. Either ASME or API coefficients may be used, but they may not be mixed. An error results if the ASME area is used with the API coefficient, and vice versa. .3865 = .552, Select 11/2 G 21/2 (0.558 in2) = same orifice selection .700 For 400 Series: A= .3865 = .594, Select 11/2 G 3 (0.599 in2) = smaller orifice may be selected .650 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 34 2. Consider the selection of the 400 Series Pilot Operated PRV. Using averaged API coefficients actually would result in specifying a larger orifice than using the ASME actual data. When a calculated orifice (using API data) is very close to an orifice area selection, a check using ASME actual data may result in a smaller orifice. Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Liquid Flow [Metric Units] Examples for Liquid Applications Example 10 Solution: Given: Water with a required flow rate of 50.0 m3/h, set at 10.0 barg, 10% overpressure, built-up back pressure of 2.0 barg. Use formula 5M and the physical properties found on pages 51-63. Find: The required orifice area for a Type 81P balanced pressure relief valve and the orifice area selected. P G Kp Kw = 10 barg = 1.00 = 1.00 = 1.00 p 2 = 2 barg K = 0.720 Kv = 1.00 ––––– 0.19631 x 50 x √ 1.00 2 A[cm2] = –––––––––––––––––––––––––––––––––– ––––––––– = 4.54 cm 0.720 x 1.00 x 1.00 x 1.00 x √1.1(10) - 2 From page 11, the next available orifice, greater than this is 8.303 cm2, corresponding to a ‘J’ orifice. Example 11 Solution: Given: Same as example 10. The same data is used as in example 10, except use a nozzle coefficient K = 0.776 (from page 8), in formula 5M. The values of Kp, Kv and Kw = 1.00 for this application. Find: The appropriate size valve for a D Series pressure relief valve, suitable for liquid service. A[cm2] ––––– 0.19631 x 50 x √ 1.00 2 = –––––––––––––––––––––––––––––– ––––– = 4.216 cm .776 x 1.00 x 1.00 x 1.00 x √11 - 2 From page 10, the next available larger area is 5.065 cm2, corresponding to an ‘H’ orifice. Example 12 Solution: Given: A liquid with a required flow rate of 72 m3/h, set at 6.5 barg, 10% overpressure, a relative density of 0.95, viscosity of 450 centipoise, a back pressure of 0.75 barg. Use formula 5M and make any adjustment for the effect of viscosity if necessary. Find: The required valve size for a Series 400 pilot operated pressure relief valve. Use API coefficients. P = 6.5 barg K = 0.650 Kw = 1.00 p2 = 0.75 barg Kp = 1.00 Kv = 1.00 for initial sizing calculation, then evaluated in subsequent calculation as explained on page 28. ––––– 0.19631 x 72 x √ 0.95 2 A[cm2] = ––––––––––––––––––––––––––––––––––––– ––––––––––– = x 8.127 cm 0.670 x 1.00 x 1.00 x 1.00 x √1.1(6.5) - .75 From page 13, the next larger, available orifice area is 8.30 cm2. This preliminary orifice area is then used to determine a value for Kv. Calculate R from formula 7M on page 31. 31,313 x 72 x 0.95 R = ––––––––––––––––– = 1652 ––––– 450 √ 8.30 From page 33, Kv = 0.925 8.127 Atrial = –––––– = 8.78 cm2 0.915 This is larger than the preliminary orifice A therefore the next larger orifice must be selected and re-evaluated. The new preliminary orifice is 11.86 cm2. Calculate a new R. 31,313 x 72 x 0.95 R = –––––––––––––––– = 1382 ––––– 450 √ 11.86 From page 33, Kv = 0.925 8.127 Atrial = –––––– = 8.88 cm2 which confirms the selection of a type 423 3K4 size. 0.925 This result is smaller than our last preliminary orifice area of 11.86 cm2, which therefore is satisfactory for the application. Orifice designation ‘K’ is the appropriate choice. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 35 Anderson Greenwood Pressure Relief Valves Technical Manual © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 36 Anderson Greenwood Pressure Relief Valves Technical Manual Subsonic Flow API 2000 and Open Discharge Valves Without Kb Factor © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 37 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Subsonic Flow per API RP 520 Note Gas Flow - Direct Spring Valves with ASME K coefficient1 (Set Pressure < 15 psig [1.03 barg]) U.S. Weight Flow (lb/h) Formula 8 A(in2) W = ––––––– 735 F2K Metric Weight Flow [kg/h] Formula 8M –––––––––––– ZT –––––––––––– MP1(P1 - P2) √ U.S. Volumetric Flow (scfm) Formula 9 A(in2) F2 = –––– V √MTZ = –––––––––––––––––––––– –––––––––– 4645.2 F2K √ P1(P1 - P2) A[cm2] –––– W √ TZ = –––––––––––––––––––––– –––––––––––– 2087 F2K √ MP1(P1 - P2) Metric Volumetric Flow [Nm3/h] Formula 9M A[cm2] ––––– V √ MTZ = –––––––––––––––––––––– ––––––––––– 4892 F2K √ P1 (P1 - P2) ––––––––––––––––––––––– 2 (k - 1) (––) 1 - r k k ––– r k –––––––– k-1 1-r √( ) [ ] k = ratio of specific heats r= P2 P1 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 38 1. Applicable for conventional valves set at pressures below 15 psig [1.03 barg], or when the ratio of back pressure to inlet pressure (P2/P1) exceeds the critical pressure ratio (PCF/P1). For balanced bellows valves that operate in the subsonic flow region, the sonic flow equations should be used with a back pressure correction factor (Kb) particular to this application. Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Subsonic Flow per API RP 520 Examples for Gas Applications Solution: Example 13 (English Units) Given: Methane, with a required flow rate of 1500 scfm, set at 19 psig, flows into a header where the back pressure is 9 psig. The gas temperature is 120°F. Find: The required orifice area. Using formula 9 from page 38: –––– W √MTZ A = –––––––––––––––––––––– –––––––––– 4645.2 F2K √ P1(P1 - P2) V = 1500 P1 = 19 (3 + 14.7) = 36.7 P2 = 9 + 14.7 = 23.7 K = 0.971 (AGCO D Series) r M = 16.04 k = 1.31 T = 120 + 460 = 580°R Z = 1.00 = P2/P1 = 23.7/36.7 = 0.6457 F2 = F2 = –––––––––––––––––––––––––––––––––––– 2 .31 (–––) 1 - .6457 (1.31) 1.31 –––– 0.6457 1.31 –––––––––––– .31 1 -.6547 √( √ [ ) ] ––––––––––––––––––––––––––– 1 - .9016 4.2258 x .5128 –––––––– .3543 [ ] F2 = .7757 A = ––––––––––––– 1500 √ 16.04 x 580 x 1 2 ––––––––––––––––––––––––––––––––––– ––––––––––––––– = 1.893 in 4645.2 x .7757 x .971 √ 36.7 (36.7 - 23.7) Example 14 (Metric Units) Solution: Given: Air, at .78 barg and -15°C, with a required flow rate of 195 Nm3/h, requires a pressure relief valve for protection. The valve is to be installed at 2,000 meters above sea level. Using formula 9M from page 38: A = Find: At 2000 M above sea level, the barometric pressure is 0.793 bara. The required valve size. Also, determine the error using the standard sonic formula for the same conditions given. V = 195 M = 29 –––– V √MTZ ––––––––––––––––––––– –––––––––– 4892 F2K √ P1(P1 - P2) T = -15 + 273 = 258 Z = 1 K = 0.971 P1 = .78 + .2069 + .793 = 1.779 bara P2 = 0.793 = P2/P1 = .793/1.779 = .5227 ––––––––––––––––––––––––––––– 2 .4 (–– ) 1 - r (1.4 ) 1.4 F2 = ––– .5227 1.4 ––––––– .4 1-r r F2 = √( √ [ ) ] –––––––––––––––––––––––– 1 - .8308 3.5 x .3958 –––––––– 1 - .5227 [ ] F2 = .7007 A = ––––––––––– 195 √ 29 x 258 x 1 2 –––––––––––––––––––––––––––––––––––– ––––––––––––––––– = 3.826 cm 4892 x .7007 x .971 √ 1.779 (1.779 - .793) Therefore, the correct valve size would be 11/2H3 (5.064 cm2). Had the standard sonic sizing formula been used, the orifice calculation would have been as follows: –––– –––––––––– V √MTZ 195 √29 x 258 x 1 A = ––––––––––––––– A = –––––––––––––––––––––––––––– = 1.603 cm2 17.02 CKdP1Kb 17.02 x 356 x 971 x 1.779 x 1.00 The resultant error would be the selection of an undersized valve (11/2 F2, with 1.98 cm2). This would create a condition where the pressure relief valve could not control the design overpressure transients. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 39 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing1 – Subsonic Flow per API RP 2000 Pilot Operated PRV Types 91, 93, 94, 95, 9200 and 9300 (Set Pressure < 15 psig [1.03 barg]) U.S. Weight Flow (lb/h) Formula 10 A(in2) 1. A computer sizing program is available. Consult your local representative. Metric Weight Flow [kg/h] Formula 10M ––– W√ TZ = ––––––––––––––– ––– 735 KdP1F √ M A[cm2] U.S. Volumetric Flow (SCFM) Formula 11 A(in2) Note ––––– V√ MTZ = ––––––––––– 4645 KdP1F ––– W√ TZ = ––––––––––––––– –––´ 558 KdP1F √ M Metric Volumetric Flow [Nm3/h] Formula 11M A[cm2] ––––– V√ MTZ = –––––––––––– 12510 KdP1F where: F = ––––––––––––––––––––––––––––––– 2 P2 k + 1 k P 2 –– –––– –––– k – ––– –––– k k-1 P1 P1 √ [( ) ( ) ] Coefficients of Discharge For Type 9200 Kd = 0.756 (P1)0.0517 US units. See page 42. For Type 9200, Kd = 0.8681 (P1)0.0517 Metric units. See page 42. For Type 9300 Kd = 0.650 (P2/P1)-0.349 See page 42. For Type 9200 Vacuum Kd = 0.667. For Type 9300 Vacuum Kd = 0.55. For Types 91, 94, 95 Kd = 0.678 (P2/P1)-0.285 For Type 93 Kd = 0.700 (P2/P1)-0.265 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 40 Anderson Greenwood Pressure Relief Valves Technical Manual Sizing - Series 90 and 9000 .100 .990 .995 1.000 Flow Correction Factor F (For use in subsonic sizing page 39) .095 .090 .550 1.90 .085 .525 1.70 1.60 1.50 1.40 .080 .075 .065 .060 thru 1.90 .450 1.10 1.00 .425 .400 .375 k= 1.9 0 .055 .350 0 .050 .325 k= 1.0 .045 .040 .300 .035 .275 .030 .250 .225 .200 thru 1.90 .175 k = 1.00 .150 .125 Absolute Pressure Ratio .400 .450 .500 .550 .600 .650 .700 .750 .800 .850 .900 .950 .100 1.000 .990 F .475 1.30 1.20 k = 1.00 .070 .500 ( ) © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. P2 P1 41 F Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Subsonic Flow Type 9200 Valve Coefficient (Kd) vs. Relief Pressure Notes (Type 9200 only) .90 1. P = set pressure + overpressure - inlet piping loss + atmospheric pressure (psia). Valve Coefficient (Kd ) .85 2. P = set pressure + overpressure - inlet piping loss + atmospheric pressure (barg). .80 .75 English Units = Kd = 0.756 (P) .0517 1 Metric Units = Kd = 0.756 (P x 14.50) .70 .0517 2 .65 .60 0 .5 0 1 1.5 .05 2 1 2.5 3 .15 3.5 2 4 4.5 .25 5 psig .3 .35 barg Flowing Pressure (P) Type 9300 Valve Coefficient (Kd) vs. Absolute Pressure Ratio Valve Coefficient (Kd ) .90 .85 Kd = 0.650 .80 ( ) P2 -.349 P1 .75 .70 .65 .60 .50 .55 .60 .65 .70 .75 .80 Absolute Pressure Ratio .85 .90 .95 1.00 ( ) P2 P1 Types 91 and 94 Valve Coefficient (Kd) vs. Absolute Pressure Ratio .85 .83 Valve Coefficient (Kd) .81 Kd = .678 .79 ( ) P2 -.285 P1 .77 .75 .73 .71 .69 .67 .65 .50 .55 .60 .65 .70 .75 Absolute Pressure Ratio .80 .85 .90 .95 1.00 ( ) P2 P1 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 42 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Subsonic Flow Type 93 Valve Coefficient (Kd) vs. Absolute Pressure Ratio .85 .83 Valve Coefficient (Kd) .81 Kd = .700 .79 ( ) P2 -.265 P1 .77 .75 .73 .71 .69 .67 .65 .50 .55 .60 .65 .70 .75 .80 Absolute Pressure Ratio .85 .90 .95 1.00 ( ) P2 P1 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 43 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Subsonic Flow (English) Examples for Gas Applications Example 15 Solution: Find: Using the same conditions as stated in Example 13, size for a Type 9300 pilot operated pressure relief valve. Using formula 11 from page 40: –––– V √ MTZ A = –––––––––––– 4645 K d P1F P ___2 = P1 0.6458 ______________ √ F= k ____ k-1 [( 2 ___ P2 ___ P1 k k +1 ____ P2 ___ P1 ) ( ) – k ] _____________ √ F= 1.27 ___ .31 [ 2 ___ 1.31 2.27 ____ 1.31 (.6458) – (.6458) ] F = 0.4616 Kd = 0.650 K = 0.7572 ––––––––––––– 1500 √ 16.04 x 580 x 1 A = ––––––––––––––––––––– (4645) (.7572) (36.7) (.4616) A = 2.4282 in2 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 44 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Special Applications Thermal Relief, Fire and Special Water Example: Step 2 From equation (14) Detailed requirements for fire sizing of pressure relief devices are contained in API RP520 Part I. A summary of sizing equations is given below. What is the total heat input, in BTU/h, to a vertical distillation column 8 feet in diameter by 50 feet long with flat ends, mounted 4 feet above ground and insulated to provide 6 BTU/h x ft x °F conductance with a 1600°F temperature difference? 2 Heat absorption (Q) into a vessel is determined by equation (13). Step 1 Where: P = relieving pressure = Q = 21,000 FA 0.82 (Set Pressure x 1.10) + 14.7 6 F = ––––– 13.33 (70 – 14.7) Set Pressure = ––––––––– 50 psig 1.10 (13) Q = 21,000 FA 0.82 Where: = 0.45 A = wetted surface area of the vessel, in square feet. A= F = an insulation factor. F = 1.0 for an uninsulated vessel corresponding to a heat conductance of 13.33 BTU/h x ft 2 x °F with a 1600°F temperature difference. Where: h equals 25 ft max. minus the height above the ground. F = Actual Conductance (BTU/h x ft 2 x °F) 13.33 For horizontal pressure vessels, use total area in square feet. For vertical vessels, use the area up to 25 feet above ground. For spherical vessels, use height above ground of maximum diameter or 25 feet, whichever is greater. Once the heat input (Q) is determined – in BTU/h from equation (13) – gas flow rate must be determined from the latent heat of the fluid medium. The rate of change from liquid to vapor, or vaporization rate, is a function of both the fluid’s physical/ chemical properties and the relieving pressure value. The vapor mass flow rate, lbs/hr, (Wp) is derived from equation (14). ( ––π4 ) D 2 + (h x πD) Q 1,738,800 Wp = ––– = ––––––––– = 14,490 lbs/h L 120 Step 3 P = 70 psia Determine required orifice area (A) as follows: Step 4 A = A= –––––– ) 8 ( 3.1416 4 2 + (25 - 4) 3.1416 x 8 A = 50.27 ft 2 + 527.79 ft 2 A = 578.06 ft 2 Wp ––––––– CKdPFp √ T –––––––––––– 1 x (400 + 460) ––––––––––– 60 √ 14,490 A = –––––––––––––––– 315 x 0.971 x (70) x 1 Q = 21,000 (0.45) (578.06)0.82 Q = 21,000 (0.45) (184) –––– Z –– A = 2.562 in2 Q = 1,738,800 BTU/h Step 5 Example: Select orifice just in excess of 2.562 in2, orifice L at 2.853 in2. If the vessel contains a liquid with a latent heat of 120 BTU/lb at 70 psia, 400°F and molecular weight of 60, what is the required valve capacity and set pressure? Q (14) Wp = ––– (lbs/h) L Where: Wp = the flow rate in lbs/h Notes Q = the maximum heat input in BTU/h from equation (13). 1. Thermal properties of the specific fluid should be obtained from appropriate sources. L = minimum latent heat of vaporization1, BTU/lb, at the absolute relieving pressure (psia). 2. For vessels with other than flat ends, use the appropriate equations for surface area of the ends. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 45 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Special Applications Valve Sizing for Saturated High Temperature Liquids which Flash to Vapor at Relief Conditions. From the required flow rate, derive the vapor flow and liquid flow from equations as follows: As a hot liquid suddenly increases in volume, such as in flow through a pressure relief valve, part of it expands to vapor or ‘flashes.’ Under these conditions the required flow area for the pressure relief valve is greater than that required for liquid alone. Since enthalpy, or total energy, in the fluid remains constant, and since fluid properties1 are available at saturated liquid and saturated vapor conditions, the amount of liquid which flashes to vapor can be calculated using equation (15). Vapor flow: H1 - H2 (15) % of Flash = ––––––– HFg x (100%) Where: H1 is the maximum enthalpy at the relieving absolute pressure; H2 is the enthalpy of saturated liquid at sonic flow conditions occurring in the nozzle; and HFg is the latent heat of vaporization, or the difference in enthalpy between vapor and liquid states. See Enthalpy graph on page 46. The set pressure (P1) is the accumulated absolute pressure plus the overpressure. The sonic flow pressure, also called the critical pressure, is obtained by using the fluid’s specific heat ratio (k)1 as a term in the following equation. Pcp = P1 ( ) 2 ––––– k+1 k –––– k-1 If k is not known, Pcp P1 = –––– 2 % Flash (16) Wp = ––––––– x Reg. Capacity2 (lbs/h) 100 Determine As and Aw required area for steam and water, respectively. Wp As = ––––––––––– 51.5 KP1Ksh 2731 As = ––––––––––––––––––– = 0.188 in2 51.5 x 0.971 x 289.7 x 1 Liquid flow: (Required Capacity - Wp) (17) W = ––––––––––––––––––––– gpm 500 x G G is the specific gravity of the liquid. ––– W√ G Aw = ––––––––––––––––––––– ––––––––––– 38 K Kv Kw √1.1 P1 - P2 Combine the required flow area values for vapor and liquid and use that value in the area equations on pages 7 and 8. Select the valve orifice area which just exceeds the required combined area. ––––– 384√ 0.892 Aw = ––––––––––––––––––––––––––– ––––––––––– 38 x .776 x 1 x 1 x √1.1 (250) - 0 Example of sizing or flashing service conditions: Aw = .7416 in2 Set Pressure P = 250 psig Required Capacity W = 74,000 lbs/h Thus, total required area, A, is: Temperature T = 380°F A = As + Aw = 0.188 + 0.742 = 0.930 in2 Accumulation = 10% Select orifice 1.287 in2, orifice J . P1= 250 x 1.1 + 14.7 = 289.7 psia Pcp = 289.7 x 0.58 = 168 psia H1 (380°F liquid) = 353.6 BTU/lb H2 (sat. liquid @ 168 psia) = 340.2 BTU/lb HFg (latent heat @ 168 psia) = 855.6 BTU/lb G (specific gravity) @ 168 psia = .892 W - liquid capacity Notes H1 - H2 % of Flash = –––––––– x (100%) HFg 1. Thermal properties of the specific fluid should be obtained form appropriate sources. 353.6 - 340.2 ––––––––––– x (100%) = 1.57% 855.6 2. The required capacity is given for the application by process requirements. WP = 0.0157 x 174000 = 2731 lbs/h, steam WG = 174000 - 2731 = 171269 lbs/h, water lbs/h, water 171269 WG = –––––––––– = –––––––– = 384 gpm 500 x G 500 x 0.892 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 46 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Special Applications Reference Specifications Special Water Sizing Enthalpy Graph Critical Point T1 P1 H1 T2 P2 Hpg Sa tur Liq ated uid d te ra tu Sa ap V P – Pressure, PSIA H2 or H (Enthalpy), BTU/Lb. Notes Standards – Sources ANSI American National Standards Institute Terminology for pressure relief devices: ANSI B95. 1-1977 API American Petroleum Institute ASME American Society of Mechanical Engineers Sample pressure relief valve specification sheet: API–STD-526 NFPA National Fire Protection Association Guide for operating differentials: ASME Section VIII, APP. M Fire Sizing: API-RP-520, Part I NFPA No. 58 Overpressure Boilers: Pressure Vessels: ASME Section I, Par. PG-72 ASME Section VIII, Par. UG - 125 Installation Boiler: Pressure Vessels: ASME Section I, Par. PG-71 ASME Section VIII, Par. UG-135 And Appendix M. API-RP-520, Part II Commercial Seat Tightness: API-STD-527 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 47 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Sizing – Reaction Forces Reaction Forces – Vapors and Gases The discharge from a pressure relief valve exerts a reaction force on the valve or outlet piping. If the discharge piping is unsupported, this force is transmitted to the valve inlet and associated piping. The following formula or chart may be used to determine the reaction force. It is assumed that critical flow of the gas or vapor is obtained at the valve outlet. Under conditions of sub-critical flow, the reaction force will be less than that calculated. The chart is based on a value of k = 1.4. This will provide a conservative value for the reaction force for most applications. However, if more accurate results are desired, the reaction forces can be determined by the following formula (18): ––––––––– kT ––––––– (k + 1)M + Ao x P2 W (18) F = ––––––––––––––– 366 √ ( ) F = reaction force at the point of discharge to the atmosphere, in pounds (newtons) W = flow of any gas or vapor, in pounds per hour (kilograms per second) k = ratio of specific heats (Cp/Cv) Cp = specific heat at constant pressure Cv = specific heat at constant volume T = temperature at inlet, in degrees Rankine (degrees Fahrenheit + 460) M = molecular weight of the process fluid Ao = area of the outlet at the point of discharge, in square inches (square millimeters) P2 = static pressure at the point of discharge, in pounds per square inch gauge (bar gauge) Reference: API RP 520, Part II © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 48 Anderson Greenwood Pressure Relief Valves Technical Manual Conversion Factors Notes This table may be used in two ways: 1. Multiply the unit under column A by the figure under column B; the result is the unit under column C. 2. Divide the unit under column C by the figure under column B; the result is the unit under column A. Equivalents and Conversion Factors A Multiply B By Atmospheres 14.697 Pounds per in2 Atmospheres 1.033 Kilograms per cm2 Atmospheres 29.92 Inches of mercury Atmospheres 760 Millimeters of mercury Atmospheres 407 Inches of water Atmospheres 33.90 Barrels (petroleum) Barrels per day Bars-G 42 0.0292 14.5 C To Obtain Feet of water Gallons Gallons per minute Pounds per in2 Centimeters 0.3937 Inches Centimeters 0.03281 Feet Centimeters 0.01 Meters Centimeters 0.01094 Yards Cubic centimeters 0.06102 Cubic inches Cubic feet 7.48055 Gallons Cubic feet 0.17812 Barrels Cubic feet per second 448.833 Gallons per minute Cubic inches 16.39 Cubic centimeters Cubic inches 0.004329 Gallons Cubic meters 264.17 Gallons Cubic meters per hour 4.4 Gallons per minute Feet 0.3048 Meters Feet 0.3333 Yards Feet 30.48 Centimeters Feet of water 0.882 Inches of mercury Feet of water 0.433 Pounds per in2 Gallons (U.S.) 3785 Cubic centimeters Gallons (U.S.) 0.13368 Gallons (U.S.) 231 Cubic inches Gallons (Imperial) 277.4 Cubic inches Gallons (U.S.) 0.833 Gallons (Imperial) Gallons (U.S.) 3.785 Liters Gallons of water 8.328 Pounds (at 70°F) Gallons of liquid per minute 500 x Sp. Gr. Gallons per minute 0.002228 Horsepower (boiler) 34.5 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. Cubic feet Pounds per hr. liquid (at 70°F) Cubic feet per second Pounds water per hr. evaporation 49 Anderson Greenwood Pressure Relief Valves Technical Manual Conversion Factors Notes Equivalents and Conversion Factors A Multiply B By Horsepower (boiler) 33479 BTU per hour Inches 2.54 Centimeters Inches 0.0833 Feet Inches 0.0254 Meters Inches 0.02778 Yards Inches of mercury 1.133 Feet of water Inches of mercury 0.4912 Pounds per in2 Inches of mercury 0.0345 Kilograms per cm2 Inches of water 0.03613 Pounds per in2 Inches of water 0.07355 Inches of mercury Kilograms 2.205 Kilograms 0.001102 132.3 Pounds per hour 14.22 Pounds per in2 Kilograms per cm2 0.9678 Atmospheres Kilograms per cm2 28.96 Inches of mercury Kilopascals .145 Pounds per in2 1000 0.2642 Cubic centimeters Gallons Liters per hour 0.0044 Gallons per minute Meters 3.281 Feet Meters 1.0936 Meters 100 Meters 39.37 Megapascals Metric Ton 145 1000 Pounds 0.0005 Yards Centimeters Inches Pounds per in2 Kilogram Short tons (2000 lbs.) Pounds 0.4536 Kilograms Pounds 0.000454 Metric tons Pounds 16 Pounds per hour Pounds per hour liquid 6.32/M.W. 0.002/Sq. Gr. Ounces Cubic feet per minute Gallons per minute liquid (at 70°F) Pounds per in2 27.684 Inches of water in2 2.307 Feet of water Pounds per in2 2.036 Inches of mercury in2 0.0703 Kilograms per cm2 Pounds per in2 51.71 Millimeters of mercury Pounds per Pounds per 2. Divide the unit under column C by the figure under column B; the result is the unit under column A. Short tons (2000 lbs.) Kilograms per cm2 Liters 1. Multiply the unit under column A by the figure under column B; the result is the unit under column C. Pounds Kilograms per minute Liters This table may be used in two ways: C To Obtain © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 50 Anderson Greenwood Pressure Relief Valves Technical Manual Conversion Factors Equivalents and Conversion Factors A Multiply Pounds per in2 B By C To Obtain 0.7037 Meters of water Specific Gravity (of gas or vapors) 28.97 Molecular wt. (of gas or vapors) Square centimeters 0.1550 Square inches Square inches 6.452 Square centimeters Tons (short ton, 2000 lbs) 907.2 Kilograms Tons (short ton, 2000 lbs.) 1.102 Metric tons Tons (metric) per day 91.8 Pounds per hour Water (cubic feet) 62.3 Pounds (at 70°F) Yards 0.9144 Meters Yards 91.44 Centimeters © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 51 Anderson Greenwood Pressure Relief Valves Technical Manual Conversion Factors Pressure Conversions1 Given To Find (To find desired value, multiply ‘Given’ value by factor below) mm Hg in wc oz kPa in Hg psig mm wc mb ––– 0.0980 0.735 0.0394 0.0227 0.00980 0.00290 10.21 –––– 0.750 0.4019 0.2320 0.1000 mm Hg (mm Mercury) (32°F or 0°C) 13.61 1.333 –––– 0.5358 0.3094 in wc (in. water column) (60°F or 15.6°C) 25.40 2.488 1.866 –––– oz (oz/in2) 43.99 4.309 3.232 kPa (kilopascal) 102.1 10.00 in Hg (in. Mercury) (60°F or 15.6°C) 344.7 mm wc (mm water column) (60°F or 15.6°C) mb (millibars) kg/cm2 bars 0.001421 1 10010 1 10207 0.0296 0.01450 0.00102 0.00100 0.1333 0.03948 0.01934 0.00136 0.00133 0.5775 0.2488 0.0737 0.03609 0.00254 0.00249 1.732 –––– 0.4309 0.1276 0.0625 or 1/16 0.00439 0.00431 7.501 4.019 2.321 –––– 0.2961 0.1450 0.0102 0.0100 33.77 25.33 13.57 7.836 3.377 –––– 0.4898 0.0344 0.0338 2 psig (lbs/in2) 703.8 68.95 51.72 27.71 16.00 6.895 2.042 –––– 0.0703 0.0689 kg/cm2 (kg/cm2) 10010 980.7 735.6 394.1 227.6 98.07 29.04 14.22 –––– 0.9807 bars 10207 1000 750.1 401.9 232.1 100.0 29.61 14.50 1.020 –––– 3 Notes 1. When pressure is stated in liquid column height, conversions are valid only for listed temperature. 2. Also expressed as torr. 3. Also expressed as kp/cm2 and kgf/cm2. 4. Normal Temperature and Pressure, (NTP) conditions, are at sea level, equal to 1.013 bars (absolute) or 1.033 kg/cm2 a (kilograms force per square centimeter absolute) at base temperature of 32°F [0°C]. This differs slightly from Metric Standard conditions, (MSC), which uses 15°C for the base temperature. Inch-Pound Standard Conditions are at sea level, equal to 14.7 psia (pounds force per square inch absolute), rounded from 14.696 psia, at a base temperature of 60°F [15.6°C]. Temperature conversion: If °F is known, to find °C: °C = (°F/1.8)-17.78 If °C is known, to find °F: °F = (°C+17.78)1.8 Example: Temperature is -20°C, find °F: F = (-20+17.78)1.8 = -2.22 x 1.8 = -4°F © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 52 Anderson Greenwood Pressure Relief Valves Technical Manual Conversion Factors Notes M = molecular weight of gas. Gas Flow Conversions Given To Find (To find desired value, multiply ‘Given’ value by factor below) scfm scfh lb/h kg/h Nm3/h Nm3/min scfm1 –––– 60 M 6.32 M 13.93 1.608 0.0268 scfh1 0.01677 –––– M 379.2 M 836.1 0.0268 0.000447 lb/h2 6.32 M 379.2 M –––– 0.4536 10.17 M 0.1695 M kg/h3 13.93 M 836.1 M 2.205 –––– 22.40 M 0.3733 M Nm3/h4 0.6216 37.30 M 10.17 M 22.40 –––– 0.01667 Nm3/min4 37.30 2238 5.901 M 2.676 M 60 –––– 1. Volumetric flow (per time unit of hour or minute as shown) in standard cubic feet per minute at 14.7 psia, 60°F. 2. Weight flow in pounds per hour. 3. Weight flow in kilograms per hour. 4. Volumetric flow (per time unit of hour or minute as shown) at 1.013 bars absolute, 0°C. This represents the commercial standard, known as the Normal Temperature and Pressure (NTP). Conversions from volumetric to volumetric or to weight flow (and vice versa) may only be done when the volumetric flow is expressed in the standard conditions shown above. If flows are expressed at temperature or pressure bases that differ from those listed above, they must first be converted to the standard base. If flow is expressed in actual volume, such as cfm (cubic feet per minute) or acfm (actual cfm) as is often done for compressors, where the flow is described as displacement or swept volume, the flow may be converted to scfm as follows (or from flow expressed in m3/h to Nm3/h). Inch-Pound Units 14.7 + p 520 scfm = (cfm or acfm) x ––––––– x –––––– 14.7 460 + t Where: p = gauge pressure of gas in psig t = temperature of gas in °F cfm or acfm = displacement or swept volume in cubic feet or actual cubic feet per minute Metric Units 1.013 + p 273 Nm3/h = m3/h x –––––––– x –––––– 1.013 460 + 1 Where: p = gauge pressure of gas in barg t = temperature of gas in °C m3/h = displacement or swept volume in cubic meters/hour © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 53 Anderson Greenwood Pressure Relief Valves Technical Manual Conversion Factors Note Liquid Flow Conversions Given l/h liters/hour To Find (To find desired value, multiply ‘Given’ value by factor below) l/h gpm (US) gpm(Imp) barrels/day m3/h –––– 0.00440 0.003666 0.1510 0.0010 0.8327 34.29 0.2271 gpm (US) US gallons per 227.1 –––– –––– 272.8 1.201 –––– 41.18 0.2728 6.624 0.02917 0.02429 –––– 0.006624 1000 4.403 3.666 151.0 –––– 3.6 x 106 15.850 13.200 543.400 3600 1 G 1 227.1G 1 272.8G 0.151 G 1 1000G minute gpm (Imp) Imperial gallons per minute barrels/day (petroleum) (42 US gallons) m3/h cubic meters per hour m3/s cubic meters per second kg/h kilograms per hour lb/h pounds per hour 1 1 1 1 1 2.205G 500.8G 601.5G 14.61G 2205G © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 54 G = relative density of liquid at its relieving temperature to that of water at 68°F [20°C], where Gwater = 1.00. Anderson Greenwood Pressure Relief Valves Technical Manual Conversion Factors Viscosity Units and Their Conversion When a correction for the effects of viscosity in the liquid orifice sizing formula is needed, the value of viscosity, expressed in centipoise, is required. Since most liquid data for viscosity uses other expressions, a convenient method for conversion is presented below. The viscosity, µ (Greek mu), in centipoise, is correctly known as absolute or dynamic viscosity. This is related to the kinematic viscosity expression, ν (Greek nu), in centistokes as follows: µ (absolute viscosity, centipoise) = ν (kinematic viscosity, centistokes) x ρ (density, grams/cm3) The liquid sizing formula uses the relative density, G, where G = ρliquid / ρwater and where the density of water is accepted (for this manual) as 1g/cm3. The value of G then becomes the density in g/cm3. Substituting G for ρ (Greek rho) in the formula above, gives: µ = ν x G (22), where: µ = absolute viscosity, centipoise ν = kinematic viscosity, centistokes G = relative density (water = 1.00) Most other viscosity units in common usage are also kinematic units and can be related to the kinematic viscosity in centistokes, via the accompanying table. To use this table, obtain the viscosity from data furnished. Convert this to ν, in centistokes, then convert to absolute viscosity µ, in centipoise. The conversions are approximate but satisfactory for viscosity correction in liquid safety valve sizing. Viscosity Conversion Table Seconds Viscosity Centistokes ν Seconds Saybolt Universal ssu Seconds Saybolt Furol ssf Seconds Redwood1 (standard) Seconds Redwood2 (Admiralty) 1.00 31 29.0 2.56 35 32.1 4.30 40 36.2 5.10 7.40 50 44.3 5.83 10.3 60 52.3 6.77 13.1 70 12.95 60.9 7.60 15.7 80 13.70 69.2 8.44 18.2 90 14.4 77.6 9.30 20.6 100 15.24 85.6 10.12 32.1 150 19.30 128.0 14.48 43.2 200 23.5 170.0 18.90 54.0 250 28.0 212.0 23.45 65.0 300 32.5 254.0 28.0 87.60 400 41.9 338.0 37.1 110.0 500 51.6 423.0 46.2 132.0 600 61.4 508.0 55.4 154.0 700 71.1 592.0 64.6 176.0 800 81.0 677.0 73.8 198.0 900 91.0 462.0 83.0 220.0 1000 100.7 896.0 92.1 330.0 1500 150.0 1270.0 138.2 440.0 2000 200.0 1690.0 184.2 550.0 2500 250.0 2120.0 230.0 660.0 3000 300.0 2540.0 276.0 880.0 4000 400.0 3380.0 368.0 1100.0 5000 500.0 4230.0 461.0 1320.0 6000 600.0 5080.0 553.0 1540.0 7000 700.0 5920.0 645.0 1760.0 8000 800.0 6770.0 737.0 1980.0 9000 900.0 7620.0 829.0 2200.0 10000 1000.0 8460.0 921.0 3300.0 15000 1500.0 13700.0 4400.0 20000 2000.0 18400.0 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 55 Anderson Greenwood Pressure Relief Valves Technical Manual Fluid Data Curve to Evaluate Gas Constant C and Gas Specific Heat Ratio k 400 390 380 k C = 520 k+1 k-1 ( ( 2 k+1 Gas Constant, C 370 360 350 340 330 320 310 ▲ 1.00 ▲ 1.10 ▲ 1.20 ▲ 1.30 ▲ 1.40 ▲ 1.50 ▲ 1.60 ▲ 1.70 ▲ 1.80 ▲ 1.90 ▲ 2.00 Gas Specific Heat Ratio, k © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 56 Anderson Greenwood Pressure Relief Valves Technical Manual Fluid Data PCF Curve to Evaluate Critical Pressure Ratio P1 0.610 0.600 PCF 0.590 P1 = (k +2 1) k k-1 0.580 0.570 PCF P1 0.550 Critical Pressure Ratio, 0.560 0.540 0.530 0.520 0.510 0.500 0.490 0.480 0.470 0.460 0.450 0.440 ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ 1.00 1.10 1.20 1.30 1.40 1.50 1.60 1.70 1.80 1.90 2.00 Gas Specific Heat Ratio, k © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 57 Anderson Greenwood Pressure Relief Valves Technical Manual Fluid Data The specific heat ratios listed herein have been obtained from numerous sources. They may vary from values available to the reader. Exercise caution when selecting the specific heat ratio. Please note that the values for C and PCF/P1 are derived from the listed k. Physical Properties for Selected Gases Gas Empirical Formula Molecular Weight M Specific Heat Ratio k Gas Constant C Critical Pressure Ratio PCF/P1 C3H6O 58.08 1.12 329 0.581 C2H2 26.04 1.26 343 0.553 — 28.97 1.40 356 0.528 NH3 17.03 1.31 348 0.544 Ar 39.95 1.67 378 0.487 Benzene (Benzol or Benzole) C6H6 78.11 1.12 329 0.581 Boron Trifluoride BF3 67.82 1.2 337 0.564 Butadiene-1,3 (Divinyl) C4H6 54.09 1.12 329 0.581 Butane (Normal Butane) C4H10 58.12 1.09 326 0.587 Butylene (1-Butene) C4H8 56.11 1.11 328 0.583 Carbon Dioxide CO2 44.01 1.29 346 0.548 Carbon Disulfide (C. Bisulfide) CS2 76.13 1.21 338 0.563 Acetone Acetylene (Ethyne) Air Ammonia, Anhydrous Argon Carbon Monoxide Carbon Tetrachloride Chlorine CO 28.01 1.40 356 0.528 CCI4 153.82 1.11 328 0.583 Cl2 70.91 1.36 353 0.535 Chloromethane (Methyl Chloride) CH3Cl 50.49 1.28 345 0.549 Cyclohexane C6H12 84.16 1.09 326 0.587 Cyclopropane (Trimethylene) C3H6 42.08 1.11 328 0.583 C10H22 142.29 1.04 320 0.598 C4H10O3 106.17 1.07 323 0.591 C2H6O 46.07 1.11 328 0.583 Dowtherm A — 165.00 1.05 321 0.595 Dowtherm E — 147.00 1.00 315 0.607 C2H6 30.07 1.19 336 0.566 C2H6O 46.07 1.13 330 0.578 C2H4 28.05 1.24 341 0.557 Decane-n Diethylene Glycol (DEG) Diethyl Ether (Methyl Ether) Ethane Ethyl Alcohol (Ethanol) Ethylene (Ethene) Ethylene Glycol C2H6O2 62.07 1.09 326 0.587 Ethylene Oxide C2H4O 44.05 1.21 338 0.563 Fluorocarbons: 12, Dichlorodifluoromethane CCI2F2 120.93 1.14 331 0.576 13, Chlorotrifluoromethane CCIF3 104.47 1.17 334 0.570 13B1, Bromotrifluoromethane CBrF3 148.93 1.14 331 0.576 22, Chlorodifluoromethane CHCIF2 86.48 1.18 335 0.568 115, Chloropentafluoroethane C2CIF5 154.48 1.08 324 0.589 C3H8O3 92.10 1.06 322 0.593 Glycerine (Glycerin or Glycerol) © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 58 Anderson Greenwood Pressure Relief Valves Technical Manual Fluid Data Physical Properties for Selected Gases, continued Gas Empirical Formula Molecular Weight M Specific Heat Ratio k Gas Constant C Critical Pressure Ratio PCF/P1 Helium He 4.00 1.67 378 0.487 Heptane C7H16 100.21 1.05 321 0.595 Hexane C6H14 86.18 1.06 322 0.593 H2 2.02 1.41 357 0.527 Hydrogen Chloride, Anhydrous HCl 36.46 1.41 357 0.527 Hydrogen Sulfide H2S 34.08 1.32 349 0.542 Isobutane (2-Methylpropane) C4H10 58.12 1.10 327 0.585 Isobutane (2-Methyl-1,3butadiene) C5H8 68.12 1.09 326 0.587 Hydrogen Isopropyl Alcohol (Isopropanol) Krypton C3H8O 60.10 1.09 326 0.587 Kr 83.80 1.71 380 0.481 CH4 16.04 1.31 348 0.544 Methyl Alcohol (Methanol) CH4O 32.04 1.20 337 0.564 Methylanmines, Anhydrous: Monomethylamine (Methylamine) CH5N 31.06 1.02 317 0.602 Dimethylamine C2H7N 45.08 1.15 332 0.574 Triethylamine C3H9N 59.11 1.18 335 0.568 Methane Methyl Mercapton (Methylamine) CH4S 48.11 1.20 337 0.564 Naphthalene (Naphthaline) C10H8 128.17 1.07 323 0.591 Natural Gas (Relative Density = 0.60) — 17.40 1.27 344 0.551 Neon Ne 20.18 1.64 375 0.491 Nitrogen N2 28.01 1.40 356 0.528 N2O 44.01 1.30 347 0.546 Octane Nitrous Oxide C8H18 114.23 1.05 321 0.595 Oxygen O2 32.00 1.40 356 0.528 Pentane C5H12 72.15 1.07 323 0.591 Propadiene (Allene) C3H4 40.07 1.69 379 0.484 Propane C3H8 44.10 1.13 330 0.578 Propylene (Propene) C3H6 42.08 1.15 332 0.574 Propylene Oxide C3H6O 58.08 1.13 330 0.578 Styrene C8H8 104.15 1.07 323 0.591 Sulfur Dioxide SO2 64.06 1.28 345 0.549 Sulfur Hexafluoride SF6 146.05 1.09 326 0.587 Steam H2O 18.02 1.31 348 0.544 Toluene (Toluol or Methylbenzene) Triethylene Glycol (TEG) Vinyl Chloride Monomer (VCM) Xenon Xylene (p-Xylene) C7H8 92.14 1.09 326 0.587 C6H14O4 150.18 1.04 320 0.598 C2H3Cl 62.50 1.19 336 0.566 Xe 131.30 1.65 376 0.490 C8H10 106.17 1.07 323 0.591 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 59 Anderson Greenwood Pressure Relief Valves Technical Manual Fluid Data Physical Properties for Selected Liquids Fluid Acetaldehyde Empirical Formula Relative Density G: Water = 1 Fluid Temperature ˚C ˚F C2H4 0.779 20 68 Acetic Acid C2H4O2 1.051 20 68 Acetone C3H6O 0.792 20 68 NH3 0.666 20 68 — 0.88-0.94 15.6 60 60 Ammonia, Anhydrous Automotive Crankcase and Gear Oils: SAE-5W Through SAE 150 Beer — 1.01 15.6 Benzene (Benzol) C6H6 0.880 20 68 Boron Trifluoride BF3 1.57 -100 -148 Butadiene-1,3 C4H6 0.622 20 68 Butane-n (Normal Butane) C4H10 0.579 20 68 Butylene (1-Butene) C4H8 0.600 20 68 Carbon Dioxide CO2 1.03 -20 -4 Carbon Disulphide (C. Bisulphide) CS2 1.27 20 68 Carbon Tetrachloride CCl4 1.60 20 68 Chlorine Cl2 1.42 20 68 CH3Cl 0.921 20 68 32.6 Deg API — 0.862 15.6 60 35.6 Deg API — 0.847 15.6 60 40 Deg API — 0.825 15.6 60 48 Deg API — 0.79 15.6 60 C6H12 0.780 20 68 C3H6 0.621 20 68 C10H22 0.731 20 68 Chloromethane (Methyl Chloride) Crude Oils: Cyclohexane Cyclopropane (Trimethylene) Decane-n Diesel Fuel Oils Diethylene Glycol (DEG) Dimethyl Ether (Methyl Ether) 0.82-0.95 15.6 60 C4H10O3 — 1.12 20 68 C2H6O 0.663 20 68 Dowtherm A — 0.998 20 68 Dowtherm E — 1.087 20 68 C2H6 0.336 20 68 Ethane Ethyl Alcohol (Ethanol) C2H6O 0.79 20 68 C2H4 0.569 -104 -155 Ethylene Glycol C2H6O2 1.115 20 68 Ethylene Oxide C2H4O 0.901 20 68 CCl2F2 1.34 20 68 Ethylene (Ethene) Fluorocarbons: R12, Dichlorodifluoromethane R13, Chlorotrifluoromethane CClF3 0.916 20 68 R13B1, Bromtrifluoromethane CBrF3 1.58 20 68 R22, Chlorodifluoromethane CHClF2 1.21 20 68 R115, Chloropentafluoroethane C2ClF5 1.31 20 68 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 60 Anderson Greenwood Pressure Relief Valves Technical Manual Fluid Data Physical Properties for Selected Liquids, continued Fluid Fuel Oils, Nos. 1, 2, 3, 5 and 6 Gasolines Empirical Formula Relative Density G: Water = 1 Fluid Temperature ˚C ˚F — 0.82-0.95 15.6 60 — 0.68-0.74 15.6 60 C3H8O3 1.26 20 68 Heptane C7H16 0.685 20 68 Hexane C6H14 0.660 20 68 Hydrochloric Acid HCl 1.64 15.6 60 Hydrogen Sulphide H2S 0.78 20 68 C4H10 0.558 20 68 Glycerine (Glycerin or Glycerol) Isobutane (2-Methylpropane) Isoprene (2-Methyl-1,3-Butadiene) Isopropyl Alcohol (Isopropanol) Jet Fuel (average) Kerosene Methyl Alcohol (Methanol) C5H8 0.682 20 68 C3H8O 0.786 20 68 — 0.82 15.6 60 0.78-0.82 15.6 60 CH4O — 0.792 20 68 Methylamines, Anhydrous: Monomethylamine (Methylamine) CH5N 0.663 20 68 Dimethylamine C2H7N 0.656 20 68 Trimethylamine C3H9N 0.634 20 68 Methyl Mercapton (Methanethiol) CH4S 0.870 20 68 Nitric Acid HNO3 1.5 15.6 60 N2O 1.23 -88.5 -127 Octane C8H18 0.703 20 68 Pentane C5H12 0.627 20 68 Propadiene (Allene) C3H4 0.659 -34.4 -30 Propane C3H8 0.501 20 68 68 Nitrous Oxide Propylene (Propene) C3H6 0.514 20 C3H6O 0.830 20 68 Styrene C8H8 0.908 20 68 Sulfur Dioxide SO2 1.43 20 68 Sulphur Hexafluoride SF6 1.37 20 68 Propylene Oxide Sulphur Acid: H2SO4 95-100% — 1.839 20 68 60% — 1.50 20 68 20% Toluene (Toluol or Methylbenzene) Triethylene Glycol (TEG) Vinyl Chloride Monomer (VCM) Water, fresh Water, sea Xylene (p-Xylene) — 1.14 20 68 C7H8 0.868 20 68 C6H12O4 1.126 20 68 C2H3Cl 0.985 -20 -4 H2O 1.00 20 68 — 1.03 20 68 C8H10 0.862 20 68 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 61 Anderson Greenwood Pressure Relief Valves Technical Manual ANSI Flange Standards © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 62 Anderson Greenwood Pressure Relief Valves Technical Manual Pressure and Temperature Ratings WCB Temperature ˚F [˚C] 800 [427] 600 [316] 600 400 [204] 30 0 15 0 200 [93] 0 200 [13.8] 400 [27.6] 600 [41.3] 800 [55.1] 1000 [69.0] 1200 [82.7] 1400 [96.5] 1600 [110.2] 5600 [385.8] 6400 [441.0] Pressure - psig [barg] 1000 [538] Temperature ˚F [˚C] 800 [427] 600 [316] 2500 1500 400 [204] 900 200 [93] 0 800 [55.1] 1600 [110.2] 2400 [165.4] 3200 [220.5] 4000 4800 [275.6] [330.7] Pressure - psig [barg] © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 63 Anderson Greenwood Pressure Relief Valves Technical Manual Pressure and Temperature Ratings WC6 1000 [538] Temperature ˚F [˚C] 800 [427] 600 [316] 600 30 0 400 [204] 15 0 200 [93] 0 200 [13.8] 400 [27.6] 600 [41.3] 800 [55.1] 1000 [69.0] 1200 [82.7] 1400 [96.5] 1600 [110.2] 5600 [385.8] 6400 [441.0] Pressure - psig [barg] 1000 [538] Temperature ˚F [˚C] 800 [427] 600 [316] 2500 1500 400 [204] 900 200 [93] 0 800 [55.1] 1600 [110.2] 2400 [165.4] 3200 [220.5] 4000 4800 [275.6] [330.7] Pressure - psig [barg] © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 64 Anderson Greenwood Pressure Relief Valves Technical Manual Pressure and Temperature Ratings Monel 1000 [538] Temperature ˚F [˚C] 800 [427] 600 600 [316] 30 0 400 [204] 15 0 200 [93] 0 200 [13.8] 400 [27.6] 600 [41.3] 800 [55.1] 1000 [69.0] 1200 [82.7] 1400 [96.5] 1600 [110.2] 4000 4800 [275.6] [330.7] 5600 [385.8] 6400 [441.0] Pressure - psig [barg] 1000 [538] Temperature ˚F [˚C] 800 [427] 600 [316] 2500 400 [204] 1500 900 200 [93] 0 800 [55.1] 1600 [110.2] 2400 [165.4] 3200 [220.5] Pressure - psig [barg] © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 65 Anderson Greenwood Pressure Relief Valves Technical Manual Pressure and Temperature Ratings Hastelloy 1000 [538] Temperature ˚F [˚C] 800 [427] 600 600 [316] 30 0 400 [204] 15 0 200 [93] 0 200 [13.8] 400 [27.6] 600 [41.3] 800 [55.1] 1000 [69.0] 1200 [82.7] 1400 [96.5] 1600 [110.2] 5600 [385.8] 6400 [441.0] Pressure - psig [barg] 1000 [538] Temperature ˚F [˚C] 800 [427] 600 [316] 2500 1500 400 [204] 900 200 [93] 0 800 [55.1] 1600 [110.2] 2400 [165.4] 3200 [220.5] 4000 4800 [275.6] [330.7] Pressure - psig [barg] © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 66 Anderson Greenwood Pressure Relief Valves Technical Manual Pressure and Temperature Ratings CF8M 1200 [649] Temperature ˚F [˚C] 1000 [538] 800 [427] 600 600 [316] 30 0 400 [204] 15 0 200 [93] 0 200 [13.8] 400 [27.6] 600 [41.3] 800 [55.1] 1000 [69.0] 1200 [82.7] 1400 [96.5] 1600 [110.2] 4000 4800 [275.6] [330.7] 5600 [385.8] 6400 [441.0] Pressure - psig [barg] 1200 [649] Temperature ˚F [˚C] 1000 [538] 800 [427] 2500 600 [316] 1500 400 [204] 900 200 [93] 0 800 [55.1] 1600 [110.2] 2400 [165.4] 3200 [220.5] Pressure - psig [barg] © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 67 Anderson Greenwood Pressure Relief Valves Technical Manual Pressure and Temperature Ratings WC9 1200 [649] Temperature ˚F [˚C] 1000 [538] 800 [427] 600 600 [316] 30 0 400 [204] 15 0 200 [93] 0 200 [13.8] 400 [27.6] 600 [41.3] 800 [55.1] 1000 [69.0] 1200 [82.7] 1400 [96.5] 1600 [110.2] 4000 4800 [275.6] [330.7] 5600 [385.8] 6400 [441.0] Pressure - psig [barg] 1200 [649] Temperature ˚F [˚C] 1000 [538] 800 [427] 2500 600 [316] 1500 400 [204] 900 200 [93] 0 800 [55.1] 1600 [110.2] 2400 [165.4] 3200 [220.5] Pressure - psig [barg] © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 68 Anderson Greenwood Pressure Relief Valves Technical Manual ANSI Flange Standards Types of Flanges All flange faces and ratings conform to ANSI B16.5-1977. Steel, full nozzle valve inlet flange thickness is equal to or greater than ANSI minimum thickness. The raised face thickness is also equal to or greater than ANSI standard, and inlet thickness ‘D’ dimension should be used for calculating length of stud for inlet bolting on the various available flange faces. Refer to the next two following pages for ANSI dimensions for raised face and ring joint. The drilling of inlet and outlet flanges straddle the centerlines of the valves. For ring joint outlet face and other available similar faces with projections or depressions, the centerline of inlet to face of outlet dimension is increased by the amount of the projection or depression over the ANSI total flange thickness. For outlets furnished with heavier than standard flanges, the centerline of inlet to face of outlet dimension increases by the difference in the ANSI total flange thickness. Raised Face Ring Joint Large Tongue Large Groove Small Male Small Female Small Tongue Small Groove Large Female © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 69 Anderson Greenwood Pressure Relief Valves Technical Manual ANSI Flange Standards Semi-Nozzle Full Nozzle Body Body ASA Raised Face D E Inlet Iron Semi-Nozzle ANSI B16.1 Inlet Iron Full Nozzle ANSI B16.5 Specifications Pipe Size in [mm] Diam. of Flange in [mm] Min. Thk. of Flange in [mm] Diam. of Raised Face in [mm] Diam. of Bolt Circle in [mm] Number of Bolts in [mm] Diam. of Bolts in [mm] 4 [102] 1/2 [13] [102] 5/8 [16] [16] 125 lb. Iron Flange 11/2 [40] 2 5 [50] 6 [127] 9/16 [152] 5/8 [17] [19] 21/2 [65] 7 [178] 11/16 3 [80] 7 1/2 [191] 3/4 [229] 15/16 4 [100] 9 [14] — 3 7/8 — 4 3/4 — — 5 1/2 [140] 4 [102] 5/8 — — 6 [152] 4 [102] 5/8 [16] — 7 1/2 [203] 5/8 [16] [19] — [16] — [24] — [98] [121] 4 [178] 8 6 [150] 11 [279] 1 [25] — — 9 1/2 [241] 8 [203] 3/4 8 [200] 13 1/2 [343] 11/8 [29] — — 11 3/4 [298] 8 [203] 3/4 [19] 4 1/2 [114] 4 [102] 3/4 [19] 250 lb. Iron Flange 11/2 [40] 6 1/8 [156] 13/16 [21] 3 9/16 [90] 2 [50] 6 1/2 [165] 7/8 [22] 4 3/16 [106] 5 [127] 8 [203] 5/8 [16] 21/2 [65] 7 1/2 [191] 1 [25] 4 15/16 [125] 5 7/8 [149] 8 [203] 3/4 [19] [80] 8 1/4 [210] 11/8 [29] 5 11/16 [144] 6 5/8 [203] 3/4 [19] [19] 3 [168] 8 4 [100] 10 [254] 11/4 [32] 6 15/16 [176] 7 7/8 [200] 8 [203] 3/4 6 [150] 12 1/2 [318] 17/16 [37] 9 11/16 [246] 10 5/8 [270] 12 [305] 3/4 [19] 8 [200] 15 [381] 15/8 [41] 11 15/16 [303] 13 [330] 12 [305] 7/8 [22] Pipe Size in [mm] Diam. of Flange Min. Thk. of Flange in in [mm] [mm] Diam. of Raised Face in [mm] Diam. of Bolt Circle in [mm] Number of Bolts in [mm] Diam. of Bolts in [mm] D-Dim Thk. D Series in [mm] E-Dim Thk. D Series in [mm] [102] 1/2 [13] 1 3/16 [30] 1/2 [13] [102] 1/2 [13] 1 5/16 [33] 11/16 [17] [35] 11/16 [17] 150 lb. Steel Flange 1 11/2 [25] [40] 4 1/4 [108] 5 7/16 [11] 2 [127] 9/16 [14] 2 7/8 [51] 3 1/8 [73] 3 7/8 [92] 4 3/4 [79] [98] 4 4 2 [50] 6 [152] 5/ 8 [16] 3 5/8 [121] 4 [102] 5/8 [16] 1 3/8 21/2 [65] 7 [178] 11/16 [17] 4 1/8 [105] 5 1/2 [140] 4 [102] 5/8 [16] — — 3 [80] 7 1/2 [191] 3/ 4 [19] 5 [127] 6 4 [102] 5/8 [16] 1 1/2 [38] 11/16 [17] 9 15/16 [24] 6 3/16 [157] 7 1/2 [203] 5/8 [16] 1 11/16 [43] 11/16 [17] 8 1/2 [216] 9 1/2 [48] 13/16 [21] [51] 13/16 [21] 4 [100] [229] [152] [178] 8 6 [150] 11 1 [25] [241] 8 [203] 3/4 [19] 1 7/8 8 [200] 13 1/2 [343] 11/8 [29] 10 5/8 [270] 11 3/4 [298] 8 [203] 3/4 [19] 2 16 13/16 [30] 12 3/4 14 1/4 [305] 7/8 [22] — 10 [250] [279] [406] [324] © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. [362] 12 70 — — — — — Anderson Greenwood Pressure Relief Valves Technical Manual ANSI Flange Standards Specifications Pipe Size in [mm] Diam. of Flange Min. Thk. of Flange in in [mm] [mm] Diam. of Raised Face in [mm] Diam. of Bolt Circle in [mm] Number of Bolts in [mm] Diam. of Bolts D-Dim D Series E-Dim D Series in [mm] in in [mm] [mm] 300 lb. Steel Flange 1 11/2 [25] 4 7/8 [124] 11/16 [40] 6 1/8 [156] 13/16 [165] 7/8 [17] 2 [21] 2 7/8 [51] 3 1/2 [73] 4 1/2 [89] 4 [114] 4 [102] 5/8 [102] 3/4 [16] 1 7/16 [37] 1/2 [13] [19] 1 5/8 [41] 11/16 [17] [17] 2 [50] 6 1/2 [22] 3 5/8 [127] 8 [203] 5/8 [16] 1 3/4 [44] 11/16 21/2 [65] 7 1/2 [191] 1 [25] 4 1/8 [105] 5 7/8 [149] 8 [203] 3/4 [19] 1 7/8 [48] 11/16 [17] 3 [80] 8 1/4 [210] 1 1/8 [29] 5 [127] 6 5/8 [168] 8 [203] 3/4 [19] 2 [51] 11/16 [17] 1 1/4 [32] 6 3/16 [157] 7 7/8 [19] 2 1/16 [52] 11/16 [17] [37] 8 1/2 [216] [19] 2 5/16 [59] 13/16 [19] [64] 13/16 [19] 4 [100] 10 6 [150] 12 1/2 [318] 1 7/16 15 1 5/8 8 [200] [254] [381] [92] 5 [200] 8 [203] 3/4 10 5/8 [270] 12 [305] 3/4 [22] 2 1/2 [41] 10 5/8 [270] [17] 2 [51] 3 1/2 [22] 2 7/8 [73] 4 1/2 [114] [25] 3 5/8 [92] 5 [127] [105] 5 7/8 [149] [127] 6 5/8 [168] [157] 8 1/2 13 [330] 12 [305] 7/8 [89] 4 [102] 5/8 [16] 1 7/16 [37] 1/2 [13] 4 [102] 3/4 [19] 1 5/8 [41] 11/16 [17] 8 [203] 5/8 [16] 1 3/4 [44] 11/16 [17] 8 [203] 3/4 [19] 1 7/8 [48] 11/16 [17] 8 [203] 3/4 [19] 2 [51] 11/16 [17] 7/8 [22] 2 1/4 [57] 11/16 [17] [25] 2 3/4 [70] 13/16 [19] [25] 2 [51] 11/16 [17] [22] 2 1/4 [57] 11/16 [17] [25] 2 3/8 [60] 11/16 [17] [22] 2 1/4 [57] 11/16 [17] [64] 11/16 [17] 600 lb. Steel Flange [25] 4 7/8 [124] 11/16 11/2 [40] 6 1/8 7/8 2 [50] 6 1/2 [165] 1 21/2 [65] 7 1/2 [191] 1 1/8 [29] 4 1/8 3 [80] 8 1/4 [210] 1 1/4 [32] 5 1 4 [100] 10 3/4 6 [150] 14 [156] [273] 1 1/2 [38] 6 3/16 [356] 1 7/8 [48] 8 1/2 [216] 8 [203] 11 1/2 [292] [216] 12 [305] 1 1 900 lb. Steel Flange 11/2 [40] 7 [178] 1 1/4 [32] 2 7/8 [73] 4 7/8 [124] 4 [102] 2 [50] 8 1/2 [216] 1 1/2 [38] 3 5/8 [92] 6 1/2 [165] 8 [203] 21/2 [65] 9 5/8 [244] 1 5/8 [41] 4 1/8 [105] 7 1/2 [191] 8 [203] 3 [80] 9 1/2 [241] 1 1/2 [38] 5 [127] 7 1/2 [191] 8 [203] 7/8 [292] 1 3/4 [44] 6 3/16 [157] 9 1/4 [29] 2 1/2 [25] 2 [51] 11/16 [17] [22] 2 5/16 [59] 11/16 [17] [17] 4 [100] 11 1/2 7/8 1 [235] 8 [203] 11/8 1 1500 lb. Steel Flange 11/2 [40] 7 [178] 1 1/4 [32] 2 7/8 [73] 4 7/8 [124] 4 [102] 2 [50] 8 1/2 [216] 1 1/2 [38] 3 5/8 [92] 6 1/2 [165] 8 [203] 7/8 3 [80] 4 [100] 10 1/2 [267] 1 7/8 [48] 5 [203] 8 [203] 11/8 [29] 2 5/8 [67] 11/16 12 1/4 [311] 2 1/8 [54] 6 3/16 [157] 9 1/2 [241] 8 [203] 11/4 [32] 2 7/8 [73] 11/16 [17] 1 3/4 [44] 2 7/8 [73] 5 3/4 [146] 4 [102] 11/8 [29] 2 1/2 [64] 11/16 [17] 2 [51] 3 5/8 [92] 6 3/4 [171] 8 [203] 1 2 13/16 [71] 11/16 [17] [127] 8 2500 lb. Steel Flange 11/2 [40] 8 2 [50] 9 1/4 [235] [203] [25] Note 1. Inlet Thickness = Flange Thickness plus Raised Face Thickness. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 71 Anderson Greenwood Pressure Relief Valves Technical Manual ANSI Flange Standards Specifications Pipe Size in [mm] Diam. of Flange in [mm] Min. Thk. of Flange in [mm] Diam. of Raised Face in [mm] Diam. of Bolt Circle in [mm] Number of Bolts in [mm] Diam. of Bolts in [mm] 150 lb. Bronze Flange, ANSI B16.24 1/ 2 [15] 3 1/2 [89] 5/16 [8] — — 2 3/8 [60] 4 [102] 1/2 [13] 3/ 4 [20] 3 7/8 [98] 11/32 [9] — — 2 3/4 [70] 4 [102] 1/2 [13] — 3 1/8 4 [102] 1/2 [13] [89] 4 [102] 1/2 [13] [98] 4 [102] 1/2 [13] 4 [102] 5/8 [16] [16] [25] 4 1/4 [108] 3/8 11/ 4 [32] 4 5/8 [117] 13/32 [10] — — 3 1/2 11/2 [40] 5 [127] 7/16 [11] — — 3 7/8 [152] 1/2 — 4 3/4 1 2 [50] 6 [10] [13] — — [79] [121] 21/2 [65] 7 [178] 9/16 [14] — — 5 1/2 [140] 4 [102] 5/8 3 [80] 7 1/2 [191] 5/8 [16] — — 6 [152] 8 [203] 5/8 [16] 4 [100] 9 [229] 11/16 [17] — — 7 1/2 [191] 8 [203] 5/8 [16] [254] 3/4 — 8 1/2 8 [203] 3/4 [19] [21] — — 9 1/2 [241] 8 [203] 3/4 [19] [24] — — 11 3/4 [298] 12 [305] 3/4 [19] [25] — — 14 1/4 [362] 12 [305] 7/8 [22] 1/2 [13] — — 2 5/8 [67] 4 [102] 1/2 [13] 5 [125] 10 6 [150] 11 [279] 13/16 8 [200] 13 1/2 [343] 15/16 10 [250] 16 [406] 1 [19] — [216] 300 lb. Bronze Flange, ANSI B16.24 1/ 2 [15] 3 3/4 [95] 3/ 4 [20] 4 5/8 [117] 17/32 [13] — — 3 1/4 [83] 4 [102] 5/8 [16] [25] 4 7/8 [124] 19/32 [15] — — 3 1/2 [89] 4 [102] 5/8 [16] — 3 7/8 4 [102] 5/8 [16] [19] 1 1 1/ 4 [32] 5 1/4 [133] 5/8 11/2 [40] 6 1/8 [156] 11/16 [17] — — 4 1/2 [114] 4 [102] 3/4 2 [50] 6 1/2 [165] 3/4 [19] — — 5 [127] 8 [203] 5/8 [16] 21/2 [65] 7 1/2 [191] 13/16 [21] — — 5 7/8 [149] 8 [203] 3/4 [19] [80] 8 1/4 [210] 29/32 — 6 5/8 8 [203] 3/4 [19] [200] 8 [203] 3/4 [19] [235] 8 [203] 3/4 [19] [19] 3 [16] [23] — — 4 [100] 10 [254] 11/16 5 [125] 11 [279] 11/8 6 [150] 12 1/2 [318] 13/16 [30] — — 10 5/8 8 [200] 15 [381] 13/8 [35] — — 13 [98] [168] [27] — — 7 7/8 [29] — — 9 1/4 [270] 12 [305] 3/4 [330] 12 [305] 7/8 [22] © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 72 Anderson Greenwood Pressure Relief Valves Technical Manual ANSI Flange Standards Note Use 1500 psig in sizes 1 to 21/2 for 900 lbs. pressure. The depth of groove is added to minimum thickness of the flange increasing the center line of inlet to face of outlet. Ring Joint inlet Face and other flange facings have the same dimension from center line of outlet to face of inlet as raised inlet flange. Diameter of raised face is stamped with groove number. All dimensions conform to ANSI B16.5-1977. ± 1/64 -0 E 23° ± 1/2° F R ± .008 K P ± .005 Minimum Ring Joint Facings Nominal Pipe Size ANSI Flange Class Groove Groove Dimensions Diameter of Raised Face ‘K’ Pitch ANSI Flange Class Number Dia. Depth Width Radius 300 150 300 600 900 1500 2500 P E F R 150 600 900 1500 2500 in[mm] in[mm] in[mm] in[mm] in[mm] in[mm] in[mm] in[mm] in [mm] in[mm] in [mm] in [mm] in [mm] in [mm] in[mm] 1 [25] 1 [25] 1 [25] 1 [25] 11/2 [40] 1 1/2 [40] 11/2 [40] 3/4 [20] 11/2 [40] 2 [50] 2 [50] 11/2 [40] 2 [50] 2 [50] 21/2 [65] 2 1/2 [65] 2 1/2 [65] 2 [50] 2 1/2 [65] 3 [80] 3 [80] 3 [80] 3 [80] 3 [80] 4 [100] 4 [100] 4 [100] 4 [100] 4 [100] 6 [150] 6 [150] 6 [150] 8 [200] 8 [200] 10 [250] R-15 1 7/8 [48] 1/4 [6] 11/32 [9] 1/32 [1] 21/2 [64] R-16 2 [51] 1/4 [6] 11/32 [9] 1/32 [1] R-19 2 9/16 [65] 1/4 [6] 11/32 [9] 1/32 [1] 3 1/4 [83] R-20 2 11/16 [68] 1/4 [6] 11/32 [9] 1/32 [1] R-22 3 1/4 [83] 1/4 [6] 11/32 [9] 1/32 [1] 4 [102] R-23 3 1/4 [83] 5/16 [8] 15/32 [12] 1/32 [1] R-24 3 /4 [95] 5/16 1/32 [1] 3 [8] 15/32 [12] 23/4 [70] 213/16 [71] 27/8 [73] 39/16 [90] 35/8 [92] 41/4 [108] [1] R-25 4 [102] 1/4 [6] 11/32 [9] 1/32 R-26 4 [102] 5/16 [8] 15/32 [12] 1/32 [1] R-27 4 1/4 [108] 5/16 [8] 15/32 [12] 1/32 [1] R-29 4 1/2 [114] 1/4 [6] 11/32 [9] 1/32 [1] R-31 4 7/8 [124] 5/16 [8] 15/32 [12] 1/32 [1] R-35 5 3/8 [137] 5/16 [8] 15/32 [12] 1/32 [1] R-36 5 7/8 [149] 1/4 [6] 11/32 [9] 1/32 [1] 63/4 [171] R-37 5 7/8 [149] 5/16 [8] 15/32 [12] 1/32 [1] R-39 6 3/8 [162] 5/16 [8] 15/32 [12] 1/32 [1] R-43 7 5/8 [194] 1/4 [6] 11/32 [9] 1/32 [1] 85/8 [219] R-45 8 5/16 5/16 [8] 15/32 [12] 1/32 [1] R-48 9 3/4 [248] 1/4 [6] 11/32 [9] 1/32 [1] 103/4 [273] R-49 10 5/8 [270] 5/16 [8] 15/32 [12] 1/32 [1] R-52 12 1 [211] [305] /4 [6] /32 [9] 11 1 41/2 [114] 47/8 43/4 [124] [121] 51/4 [133] 5 [127] 53/8 [137] 51/4 [133] 53/4 [146] 61/8 [156] 65/8 [168] 67/8 [175] 71/8 [181] 75/8 [194] 91/2 [241] 91/2 [241] 117/8 [302] /32 [1] 13 [330] © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 73 Anderson Greenwood Pressure Relief Valves Technical Manual ANSI Flange Standards Raised Facing and Ring Joint Facing Temperature °F [°C] 150 in [mm] 300 in [mm] 275 [19.0] 720 [49.7] SS (A351 Gr CF8M) 100 [38] ANSI Flange Class 600 900 in [mm] in [mm] 1500 in [mm] 2500 in [mm] Maximum Pressure psig [barg] 1440 [99.3] 2160 [149.0] 3600 [248.3] 6000 [413.8] 200 [93] 240 [16.6] 620 [42.8] 1240 [85.5] 1860 [128.3] 3095 [213.4] 5160 [355.9] 300 [149] 215 [14.8] 560 [38.6] 1120 [77.2] 1680 [115.9] 2795 [192.8] 4660 [321.4] 1540 [106.2] 2570 [177.2] 4280 [295.2] 390 [164.8] 3980 [274.5] 400 [204] 195 [13.4] 515 [35.5] 1030 [71.0] 500 [260] 170 [11.7] 480 [33.1] 955 [65.9] 435 [99.0] 600 [316] 140 [9.7] 450 [31.0] 905 [62.4] 1355 [93.4] 2255 [155.5] 3760 [259.3] 700 [371] 110 [7.6] 430 [29.7] 865 [59.7] 1295 [89.3] 2160 [149.0] 3600 [248.3] 800 [427] 80 [5.5] 415 [28.6] 830 [57.2] 1245 [85.9] 2075 [143.1] 3460 [238.6] 900 [482] 50 [3.4] 395 [27.2] 790 [54.5] 1180 [81.4] 1970 [135.9] 3280 [226.2] 1000 [538] 20 [1.4] 365 [25.2] 725 [50.0] 1090 [75.2] 1820 [125.5] 3030 [209.0] 1100 [593] — — 325 [22.4] 645 [44.5] 965 [66.6] 1610 [111.0] 2685 [185.2] 1200 [649] — — 205 [14.1] 410 [28.3] 620 [42.8] 1030 [71.0] 1715 [118.3] Monel® (A494 Gr M-35-2) 100 [38] 230 [15.9] 600 [41.4] 1200 [82.8] 1800 [124.1] 3000 [206.9] 5000 [344.8] 200 [93] 200 [13.8] 530 [36.6] 1055 [72.8] 1585 [109.3] 2640 [182.1] 4400 [303.4] 300 [149] 190 [13.1] 495 [34.1] 990 [68.3] 1485 [102.4] 2470 [170.3] 4120 [284.1] 400 [204] 185 [12.8] 480 [33.1] 955 [65.9] 1435 [99.0] 2390 [164.8] 3980 [274.5] 500 [260] 170 [11.7] 475 [32.8] 950 [65.5] 1435 [99.0] 2375 [163.8] 3960 [273.1] 600 [316] 140 [9.7] 475 [32.8] 950 [65.5] 1435 [99.0] 2375 [163.8] 3960 [273.1] 700 [371] 110 [7.6] 475 [32.8] 950 [65.5] 1435 [99.0] 2375 [163.8] 3960 [273.1] 750 [399] 95 [6.6] 470 [32.4] 935 [64.5] 1405 [96.9] 2340 [161.4] 3900 [269.0] Hastelloy® C (A494 CW-N12MW) 100 [38] 290 [20.0] 750 [51.7] 1500 [103.4] 2250 [155.2] 3750 [258.6] 6250 [431.0] 200 [93] 260 [17.9] 750 [51.7] 1500 [103.4] 2250 [155.2] 3750 [258.6] 6250 [431.0] 300 [149] 230 [15.9] 730 [50.3] 1455 [100.3] 2185 [150.7] 3640 [251.0] 6070 [418.6] 400 [204] 200 [13.8] 705 [48.6] 1410 [97.2] 2115 [145.9] 3530 [243.4] 5880 [405.5] 500 [260] 170 [11.7] 665 [45.9] 1230 [84.8] 1915 [132.1] 3325 [229.3] 5540 [382.1] 600 [316] 140 [9.7] 605 [41.7] 1210 [83.4] 1815 [125.2] 3025 [208.6] 5040 [347.6] 700 [371] 110 [7.6] 570 [39.3] 1135 [78.3] 1705 [117.6] 2840 [195.9] 4730 [326.2] 750 [399] 95 [6.6] 530 [36.6] 1065 [73.4] 1595 [110.0] 2660 [183.4] 4430 [305.5] © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 74 Anderson Greenwood Pressure Relief Valves Technical Manual ANSI Flange Standards Raised Facing and Ring Joint Facing Temperature °F [°C] 150 in [mm] 300 in [mm] 285 [19.7] 740 [51.0] ANSI Flange Class 600 900 in [mm] in [mm] CS (A216 Grade WCB) 100 [38] in 1500 [mm] in 2500 [mm] 3705 [255.5] 6170 [425.5] Maximum Pressure psig [barg] 1480 [102.1] 2220 [153.1] 200 [93] 260 [17.9] 675 [46.6] 1350 [93.1] 2025 [139.7] 3375 [232.8] 5625 [387.9] 300 [149] 230 [15.9] 655 [45.2] 1315 [90.7] 1970 [135.9] 3280 [226.2] 5470 [377.2] 400 [204] 200 [13.8] 635 [43.8] 1270 [87.6] 1900 [131.0] 3170 [218.6] 5280 [364.1] 500 [260] 170 [11.7] 600 [41.4] 1200 [82.8] 1795 [123.8] 2995 [206.6] 4990 [344.1] 600 [316] 140 [9.7] 550 [37.9] 1095 [75.5] 1640 [113.1] 2735 [188.6] 4560 [314.5] 650 [343] 125 [8.6] 535 [36.9] 1075 [74.1] 1610 [111.0] 2685 [185.2] 4475 [308.6] 700 [371] 110 [7.6] 535 [36.9] 1065 [73.4] 1600 [110.3] 2665 [183.8] 4440 [306.2] 750 [399] 95 [6.6] 505 [34.8] 1010 [69.7] 1510 [104.1] 2520 [173.8] 4200 [289.7] 800 [427] 80 [5.5] 410 [28.3] 825 [56.9] 1235 2060 [142.1] 3430 [236.6] [85.2] Raised Facing and Ring Joint Facing Temperature °F [°C] 150 in [mm] 300 in [mm] 400 in [mm] Chrome-Moly Steel (A217 Grade WC6) 100 ANSI Flange Class 600 900 in [mm] in [mm] in 1500 [mm] 2500 in [mm] Maximum Pressure psig [barg] [38] 290 [20.0] 750 [51.7] 1000 [69.0] 1500 [103.4] 2250 [155.2] 3750 [258.6] 6250 [431.0] 200 [93] 260 [17.9] 710 [49.0] 950 [65.5] 1425 [98.3] 2135 [147.2] 3560 [245.5] 5930 [409.0] 300 [149] 230 [15.9] 675 [46.6] 895 [61.7] 1345 [92.8] 2020 [139.3] 3365 [232.1] 5605 [386.6] 400 [204] 200 [13.8] 660 [45.5] 880 [60.7] 1315 [90.7] 1975 [136.2] 3290 [226.9] 5485 [378.3] 500 [260] 170 [11.7] 640 [44.1] 855 [59.0] 1285 [88.6] 1925 [132.8] 3210 [221.4] 5350 [369.0] 600 [316] 140 [9.7] 605 [41.7] 805 [55.5] 1210 [83.4] 1815 [125.2] 3025 [208.6] 5040 [347.6] 650 [343] 125 [8.6] 590 [40.7] 785 [54.1] 1175 [81.0] 1765 [121.7] 2940 [202.8] 4905 [338.3] 700 [371] 110 [7.6] 570 [39.3] 755 [52.1] 1135 [78.3] 1705 [117.6] 2840 [195.9] 4730 [326.2] 750 [399] 95 [6.6] 530 [36.6] 710 [49.0] 1065 [73.4] 1595 [110.0] 2660 [183.4] 4430 [305.5] 800 [427] 80 [5.5] 510 [35.2] 675 [46.6] 1015 [70.0] 1525 [105.2] 2540 [175.2] 4230 [291.7] 850 [454] 65 [4.5] 485 [33.4] 650 [44.8] 975 [67.2] 1460 [100.7] 2435 [167.9] 4060 [280.0] 900 [482] 50 [3.4] 450 [31.0] 600 [41.4] 900 [62.1] 1350 [93.1] 2245 [154.8] 3745 [258.3] 950 [510] 35 [2.4] 380 [26.2] 505 [34.8] 755 [52.1] 1130 [77.9] 1885 [130.0] 3145 [216.9] 1000 [538] 20 [1.4] 225 [15.5] 300 [20.7] 445 [30.7] 670 [46.2] 1115 [76.9] 1860 [128.3] © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 75 Anderson Greenwood Pressure Relief Valves Technical Manual ANSI Flange Standards Bronze Flange Ratings ANSI B16.24 1971 Temperature °F [°C] ANSI Flange Class 150 300 in [mm] in [mm] Bronze (B62) Maximum Pressure psig [barg] 0 to 150 [-18 to +66] 175 225 [15.5] 500 [34.5] [79] 220 [15.2] 480 [33.1] 200 [93] 210 [14.5] 465 [32.1] 225 [107] 205 [14.1] 445 [30.7] 250 [121] 195 [13.4] 425 [29.3] 275 [135] 190 [13.1] 410 [28.3] 300 [149] 180 [12.4] 390 [26.9] 350 [177] 165 [11.4] 350 [24.1] 400 [204] 406 [208] 422 [217] — — 150 [10.3] — — 315 [21.7] — — 300 [20.7] Iron Flange Ratings ANSI B16.1 Temperature °F [°C] ANSI Flange Class 150 300 in [mm] in [mm] Iron (A126) Maximum Pressure psig [barg] 0 to 150 [-18 to +66] 175 [12.1] 400 [27.6] 200 [93] 165 [11.4] 370 [25.5] 225 [107] 155 [10.7] 355 [24.5] 250 [121] 150 [10.3] 340 [23.4] 275 [135] 145 [10.0] 325 [22.4] 300 [149] 140 [9.7] 310 [21.4] 350 [177] 130 [9.0] 295 [20.3] 375 [191] 125 [8.6] 280 [19.3] 400 [208] — — 265 [18.3] — — 250 [17.2] © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 76 Anderson Greenwood Pressure Relief Valves Technical Manual Valve Installations Valve Installation Precautions 1. No intervening stop valve is permitted between the system and/or piping and its protective relieving valve or valves, except per ASME SEC. VIII UG-135 (E). 2. No intervening stop valve is permitted between the protective relieving valve and discharge port, except per ASME SEC. VIII UG-135 (E). 3. No valve discharge media is permitted to strike other piping, or other equipment, when discharge is to atmosphere. Also, discharge media must be aimed away from personnel platforms and all traffic areas. 4. All set pressure adjustments must be verified as falling within the design range for that valve spring. Consult factory. State laws dictate that valve seals be broken only by persons authorized to do so by ASME and Anderson Greenwood and Co. Otherwise, valve warranties are void and laws breached. Consult factory. 5. When discharging more than one valve into a common header, excessive back pressure must be avoided. See ASME SEC. VIII Appx. M-8 6. The capacity of the relieving valve will always be increased or decreased proportionally with increase or decrease of set pressure. 7. Test Gags Must Be Removed. Failure to do so renders the valve inoperable and, due to overpressure, may damage either the relieving valve or the system, or both. 8. Bonnet vents on all bellows or balanced pressure relief valves must be left open – the shipping plugs must be removed. 9. Pressure relief valves should be mounted in a vertical position. Installing a pressure relief valve in other than a vertical position will adversely affect operation in varying degrees as a result of consequent misalignment of moving parts. Also, warranties may be voided. Upside-down mounted valves should be provided with ample drainage of accumulated liquids from all sections of the valve. 10. Prior to all installations, inlet connections – flanged or threaded – must be cleared of foreign matter. Any dirt entering the valve may damage valve seats. Use only wrench flats when securing threaded valves. 11. Should leakage be detected from a newly installed valve, first assume the cause to be from shipping and handling or installation procedures. Apply pressure to the inlet side equal to 75% of operating pressure so that the lift lever can be manually activated, thus operating the valve. For valves without lift levers, system pressure may be allowed to rise to the point of valve operation. In most instances, the valve will properly reseat and the leakage will stop. 15. Minimum differential between operating pressure and set pressure: 5 psig to 70 psig; set 10% from 71 to 1000 psig; 7% over 1000 psig. See ASME SEC. VIII Appx. M-M11C. 16. ASME-type pressure valves must be equipped with lift levers for all air, steam and hot water (above 140°F [60°C]) service. 17. Upon installation or after repair, the proper valve set pressure must be verified. Also, pressure gauges should be calibrated periodically, insuring proper system readout. 18. Any water leg between the valve and gauge must be compensated for. Otherwise, incorrect pressure readout will result. 19. Pressure relief valves left on-line during extended shutdowns should be inspected and tested before resuming service. Certain conditions or acts which often occur during long, unattended idle periods, such as corrosion, fouling or tampering, may prevent the device from performing properly. Where a change in operating conditions follows a shutdown, the inspection interval must be reviewed. 12. Absolute tightness at seat surfaces is difficult to achieve. Valve manufacturers adhere to a commercial seat tightness standard – API Standard 527. 13. Chatter may result when improper piping at valve inlet or outlet exists, or oversizing the valve. 14. Temperature and corrosion effects on valve materials are very important to any pressure relief valve application. Disregard of these critical considerations may damage or cause malfunction of the pressure relief valve. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 77 Anderson Greenwood Pressure Relief Valves Technical Manual Following is an Excerpt from ASME Code Section I, Section IV, and Section VIII (1995 Addenda) © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 78 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section I, Power Boilers - (1995 Addenda) Safety Valves and Safety Relief Valves1 PG-67 Boiler Safety Valve Requirements steaming capacity as determined by the Manufacturer and shall be based on the capacity of all the fuel burning equipment as limited by other boiler functions. A93 A93 PG-67.1 Each boiler shall have at least one safety valve or safety relief valve and if it has more than 500 sq ft of bare tube water-heating surface, or if an electric boiler has a power input more than 1100 kW, it shall have two or more safety valves or safety relief valves. For a boiler with combined bare tube and extended water-heating surface exceeding 500 sq ft, two or more safety valves or safety relief valves are required only if the design steam generating capacity of the boiler exceeds 4000 lb/hr. Organic fluid vaporizer generators require special consideration as given in Part PVG. PG-67.2.2 The minimum required relieving capacity for a waste heat boiler shall be determined by the Manufacturer. When auxiliary firing is to be used in combination with waste heat recovery, the maximum output as determined by the boiler Manufacturer shall include the effect of such firing in the total required capacity. When auxiliary firing is to be used in place of waste heat recovery, the minimum required relieving capacity shall be based on auxiliary firing or waste heat recovery, whichever is higher. A93 PG-67.2 The safety valve or safety relief valve capacity for each boiler (except as noted in PG-67.4) shall be such that the safety valve, or valves, will discharge all the steam that can be generated by the boiler without allowing the pressure to rise more than 6% above the highest pressure at which any valve is set and in no case to more than 6% above the maximum allowable working pressure. A93 PG-67.2.3 The minimum required relieving capacity for electric boilers shall be in accordance with PEB-15. A93 PG-67.2.4 The minimum required relieving capacity in lb/hr for a high-temperature water boiler shall be determined by dividing the maximum output in Btu/hr at the boiler nozzle, produced by the highest heating valve fuel for which the boiler is designed, by 1000. A93 A93 PG-67.2.1 The minimum required relieving capacity of the safety valves or safety relief valves for all types of boilers shall not be less than the maximum designed PG-67.2.5 The minimum required relieving capacity for organic fluid vaporizers shall be in accordance with PVG-12. A93 PG-67.2.6 Any economizer which may be shut off from the boiler, thereby permitting the economizer to become a fired pressure vessel, shall have one or more safety relief valves with a total discharge capacity, in lbs/hr, calculated from the maximum expected heat absorption in Btu/hr, as determined by the Manufacturer, divided by 1000. This absorption shall be stated in the stamping (PG-106.4). PG-67.3 One or more safety valves on the boiler proper shall be set at or below the maximum allowable working pressure (except as noted in PG-67.4). If additional valves are used the highest pressure setting shall not exceed the maximum allowable working pressure by more than 3%. The complete range of pressure settings of all the saturated-steam safety valves on a boiler shall not exceed 10% of the highest pressure to which any valve is set. Pressure setting of safety relief valves on high-temperature water boilers2 may exceed this 10% range. PG-67.4 For a forced-flow steam generator with no fixed steam and waterline, equipped with automatic controls and protective interlocks responsive to steam pressure, safety valves may be provided in accordance with the above paragraphs or the following protection against overpressure shall be provided: Notes 1. Safety Valve: An automatic pressure relieving device actuated by the static pressure upstream of the valve and characterized by full opening pop action. It is used for gas or vapor service. Relief Valve: An automatic pressure relieving device actuated by the static pressure upstream of the valve which opens further with the increase in pressure over the opening pressure. It is used primarily for liquid service. Safety Relief Valve: An automatic pressureactuated relieving device suitable for use either as a safety valve or relief valve, depending on application. Unless otherwise defined, the definitions relating to pressure relief devices in Appendix I of ASME/ANSI PTC 25.3, Safety and Relief Valves, shall apply. 2. Safety relief valves in hot water service are more susceptible to damage and subsequent leakage, than safety valves relieving steam. It is recommended that the maximum allowable working pressure of the boiler and the safety relief valve setting for high-temperature water boilers be selected substantially higher than the desired operating pressure so as to minimize the times the safety relief valve must lift. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 79 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section I, Power Boilers - (1995 Addenda) PG-67.4.1 One or more power-actuated pressure relieving valves3 shall be provided in direct communication with the boiler when the boiler is under pressure and shall receive a control impulse to open when the maximum allowable working pressure at the superheater outlet, as shown in the master stamping (PG-106.3), is exceeded. The total combined relieving capacity of the poweractuated relieving valves shall be not less than 10% of the maximum design steaming capacity of the boiler under any operating condition as determined by the Manufacturer. The valve or valves shall be located in the pressure part system where they will relieve the overpressure. An isolating stop valve of the outsidescrew-and-yoke type may be installed between the power-actuated pressure relieving valve and the boiler to permit repairs provided an alternate poweractuated pressure relieving valve of the same capacity is so installed as to be in direct communication with the boiler in accordance with the requirements of this paragraph. Power-actuated pressure relieving valves discharging to intermediate pressure and incorporated into bypass and/or startup circuits by the boiler Manufacturer need not be capacity certified. Instead, they shall be marked by the valve manufacturer with a capacity rating at a set of specified inlet pressure and temperature conditions. Power-actuated pressure relieving valves discharging directly to atmosphere shall be capacity certified. This capacity certification shall be conducted in accordance with the provisions of PG-69.3. The valves shall be marked in accordance with the provisions of PG.69.4 and PG-69.5. PG-67.4.2 Spring-loaded safety valves shall be provided, having a total combined relieving capacity, including that of the power-actuated pressure relieving capacity installed under PG-67.4.1, of not less than 100% of the maximum designed steaming capacity of the boiler, as determined by the Manufacturer, except the alternate provisions of PG-67.4.3 are satisfied. In this total, no credit in excess of 30% of the total required relieving capacity shall be allowed for the power-actuated pressure relieving valves actually installed. Any or all of the spring-loaded safety valves may be set above the maximum allowable working pressure of the parts to which they are connected, but the set pressures shall be such that when all of these valves (together with the poweractuated pressure relieving valves) are in operation the pressure will not rise more than 20% above the maximum allowable working pressure of any part of the boiler, except for the steam piping between the boiler and the prime mover. PG-67.4.3 The total installed capacity of spring-loaded safety valves may be less than the requirements of PG-67.4.2 provided all of the following conditions are met. PG-67.4.3.1 The boiler shall be of no less steaming capacity than 1,000,000 lb/hr and installed in a unit system for power generation (i.e., a single boiler supplying a single turbine-generator unit). PG-67.4.3.2 The boiler shall be provided with automatic devices, responsive to variations in steam pressure, which include no less than all the following: PG-67.4.3.2.1 A control capable of maintaining steam pressure at the desired operating level and of modulating firing rates and feedwater flow in proportion to a variable steam output; and PG-67.4.3.2.2 A control which overrides PG-67.4.3.2.1 by reducing the fuel rate and feedwater flow when the steam pressure exceeds the maximum allowable working pressure as shown in the master stamping (PG-106.3) by 10%; and PG-67.4.3.2.3 A direct-acting overpressure-trip-actuating mechanism, using an independent pressure sensing device, that will stop the flow of fuel and feedwater to the boiler, at a pressure higher than the set pressure of PG-67.4.3.2.2, but less than 20% above the maximum allowable working pressure as shown in the master stamping (PG-106.3). PG-67.4.3.3 There shall be not less than two spring-loaded safety valves and the total rated relieving capacity of the springloaded safety valves shall be not less than 10% of the maximum designed steaming capacity of the boiler as determined by the Manufacturer. These spring-loaded safety valves may be set above the maximum allowable working pressure of the parts to which they are connected but shall be set such that the valves will lift at a pressure no higher than 20% above the maximum allowable working pressure as shown in the master stamping (PG-106.3). PG-67.4.3.4 At least two of these springloaded safety valves shall be equipped with a device that directly transmits the valve stem lift action to controls that will stop the flow of fuel and feedwater to the boiler. The control circuitry to accomplish this shall be arrange in a ‘fail-safe’ manner.4 Notes 3. The power-actuated pressure relieving valve is one of whose movements to open or close are fully controlled by a source of power (electricity, air, steam, or hydraulic). The valve may discharge to atmosphere or to a container at lower pressure. The discharge capacity may be affected by the downstream conditions, and such effects shall be taken into account . If the power-actuated pressure relieving valves are also positioned in response other control signals, the control impulse to prevent overpressure shall be responsive only to pressure and shall override any other control function. 4. ‘Fail-safe’ shall mean a circuitry arranged as either of the following: (1) Energize to trip: There shall be at least two separate and independent trip circuits served by two power sources, to initiate and perform the trip action. One power source shall be a continuously charged dc battery. The second source shall be an ac-to-dc converter connected to the dc system to charge the battery and capable of performing the trip action. The trip circuits shall be continuously monitored for availability. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 80 It is not mandatory to duplicate the mechanism that actually stops the flow of fuel and feedwater. (2) De-energize to trip: If the circuits are arranged in such a way that a continuous supply of power is required to keep the circuits closed and operating and such that any interruption of power supply will actuate the trip mechanism, then a single trip circuit and single power supply will be enough to meet the requirements of this subparagraph. Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section I, Power Boilers - (1995 Addenda) PG-67.4.3.5 The power supply for all controls and devices required by PG-67.4.3 shall include at least one source contained within the same plant as the boiler and which is arranged to actuate the controls and devices continuously in the event of failure or interruption of any other power sources. PG-67.4.4 When stop valves are installed in the water-steam flow path between any two sections of a forced-flow steam generator with no fixed steam and waterline: PG-67.4.4.1 The power-actuated pressure relieving valve(s) required by PG-67.4.1 shall also receive a control impulse to open when the maximum allowable working pressure of the component, having the lowest pressure level upstream to the stop valve, is exceeded; and PG-67.4.4.2 The spring-loaded safety valves shall be located to provide the pressure protection requirements in PG67.4.2 or PG-67.4.3. PG-67.4.5 A reliable pressure-recording device shall always be in service and records kept to provide evidence of conformity to the above requirements. PG-67.5 All safety valves or safety relief valves shall be so constructed that the failure of any part cannot obstruct the free and full discharge of steam and water from the valve. Safety valves shall be of the direct spring-loaded pop type, with seat inclined at any angle between 45 degrees and 90 degrees, inclusive, to the center line of the spindle. The coefficient of discharge of safety valves shall be determined by actual steam flow measurements at a pressure not more than 3% above the pressure at which the valve is set to blow and when adjusted for blowdown in accordance with PG-72. The valves shall be credited with capacities as determined by the provisions of PG-69.2 Safety valves or safety relief valves may be used which give any opening up to the full discharge capacity of the area of the opening of the inlet of the valve (see PG69.5), provided the movement of the steam safety valve is such as not to induce lifting of water in the boiler. Deadweight or weighted lever safety valves or safety relief valves shall not be used. For high-temperature water boilers safety relief valves shall be used. Such valves shall have a closed bonnet. For purposes of selection the capacity rating of such safety relief valves shall be expressed in terms of actual steam flow determined on the same basis as for safety valves. In addition the safety relief valves shall be capable of satisfactory operation when relieving water at the saturation temperature corresponding to the pressure at which the valve is set to blow. PG-67.6 A safety valve or safety relief valve over 3-inch in size, used for pressures greater than 15 psig, shall have a flanged inlet connection or weld-end inlet connection. The dimensions of flanges subjected to boiler pressure shall conform to the applicable American National Standards as given in PG-42. The facing shall be similar to those illustrated in the Standard. PG-67.7 Safety valves or safety relief valves may have bronze parts complying with either SB-61 or SB-62, provided the maximum allowable stresses and temperatures do not exceed the values given in Table 1B of Section II, Part D, and shall be marked to indicate the class of material used. Such valves shall not be used on superheaters delivering steam at a temperature over 450°F and 306°F respectively, and shall not be used for high-temperature water boilers. PG-68 Superheater Safety Valve Requirements PG-68.1 Except as permitted in PG58.3.1, every attached superheater shall have one or more safety valves in the steam flow path between the superheater outlet and first stop valve. The location shall be suitable for the service intended and shall provide the overpressure protection required. The pressure drop upstream of each safety valve shall be considered in the determination of set pressure and relieving capacity of that valve. If the superheater outlet header has a full, free steam passage from end to end and is so constructed that steam is supplied to it at practically equal intervals throughout its length so that there is a uniform flow of steam through the superheater tubes and the header, the safety valve, or valves, may be located anywhere in the length of the header. PG-68.2 The discharge capacity of the safety valve, or valves, on an attached superheater may be included in determining the number and size of the safety valves for the boiler, provided there are no intervening valves between the superheater safety valve and the boiler, and provided the discharge capacity of the safety valve, or valves, on the boiler, as distinct from the superheater is at least 75% of the aggregate valve capacity required. PG-68.3 Every independently fired superheater which may be shut off from the boiler and permit the superheater to become a fired pressure vessel shall have one or more safety valves having a discharge capacity equal to 6 lb of steam per hour per square foot of superheater surface measured on the side exposed to the hot gases. In the case of electrically heated superheaters, the safety valve capacity shall be based upon 31/2 lb/hr/kW input. The number of safety valves installed shall be such that the total capacity is at least equal to that required. PG-68.4 Every reheater shall have one or more safety valves, such that the total relieving capacity is at least equal to the maximum steam flow for which the reheater is designed. At least one valve shall be located in the stamp flow path between the reheater outlet and the first stop valve. The location shall be suitable for the service intended and shall provide the overpressure protection required. The pressure drop upstream of each safety valve shall be considered in the determination of set pressure and relieving capacity of that valve. The relieving capacity of that valve shall be not less than 15% of the required total. The capacity of reheater safety valves shall not be included in the required relieving capacity for the boiler and superheater. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 81 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section I, Power Boilers - (1995 Addenda) PG-68.5 A soot blower connection may be attached to the same outlet from the superheater or reheater that is used for the safety valve connection. PG-68.6 Every safety valve used on a superheater or reheater discharging superheated steam at a temperature over 450°F shall have a casing, including the base, body, and bonnet and spindle, of steel, steel alloy, or equivalent heat-resisting material. The valve shall have a flanged inlet connection, or a weld-end inlet connection. It shall have the seat and disk of suitable heat erosive and corrosive resisting material, and the spring fully exposed outside of the valve casing so that it shall be protected from contact with the escaping steam. PG-69 Certification of Capacity of Safety and Safety Relief Valves PG-69.1 Before the Code symbol is applied to any safety or safety relief valve, the valve manufacturer shall have the relieving capacity of his valves certified in accordance with the provisions of this paragraph. PG-69.1.1 Capacity certification tests shall be conducted using dry saturated steam. The limits for test purposes shall be 98% minimum quality and 20°F maximum superheat. Correction from within these limits may be made to the dry saturated condition. PG-69.1.2 Tests shall be conducted at a place which meets the requirements of Appendix A-312. A92 PG-69.1.3 Capacity test data reports for each valve design and size, signed by the manufacturer and Authorized Observer witnessing the tests, together with drawings showing the valve construction, shall be submitted to the ASME designee for review and acceptance.5 measured capacity absolute flow rating pressure, psia PG-69.1.4 Capacity certification tests shall be conducted at a pressure which does not exceed the set pressure by 3% or 2 psi, whichever is greater. Safety and safety relief valves shall be adjusted so that the blowdown does not exceed 4% of the set pressure. For valves set at or below 100 psi, the blowdown shall be adjusted so as not to exceed 4 psi. Safety valves used on forced-flow steam generators with no fixed steam and waterline, and safety relief valves used on high-temperature water boilers shall be adjusted so that the blowdown does not exceed 10% of the set pressure. The reseating pressure shall be noted and recorded. If all slopes derived from the testing do not fall within ±5% of the average slope, the Authorized Observer shall require two additional valves to be tested as replacements for each valve having a slope outside this range, with a limit of four additional valves. Failure of any slope to fall within ±5% of the new average slope, excluding the replaced valve(s), shall be cause to refuse certification of that particular valve design. PG-69.2 Relieving capacities shall be determined using one of the following methods. The rated relieving capacity to be stamped on the valve shall be determined as follows: PG-69.2.1 Three Valve Method. A capacity certification test is required on a set of three valves for each combination of size, design and pressure setting. The capacity of each valve of the set shall fall within a range of ±5% of the average capacity. If one of the three valves tested falls outside this range, it shall be replaced by two valves, and a new average shall be calculated based on all four valves, excluding the replaced valve. Failure of any of the four capacities to fall within a range of ±5% of the new average shall be cause to refuse certification of that particular valve design. rated relieving capacity = 0.90 x average slope x (1.03 x set pressure + 14.7) The rated relieving capacity for each combination of design, size, and test pressure shall be 90% of the average capacity. PG-69.2.2 Four Valve Method. Four valves of each combination of valve inlet size and orifice size shall be tested. These four valves shall be set at pressures covering the range for which the valves will be used or the range available at the certified test facility where tests are conducted. The slope of the actual measured capacity versus the absolute flow rating pressure for each test point shall be calculated and averaged: Slope = All values derived from the testing must fall within ±5% of the average slope. or = 0.90 x average slope x (set pressure + 2 psi + 14.7) whichever is greater. PG-69.2.3 Coefficient of Discharge Method. A coefficient of discharge for the design, K, may be established for a specific valve design according to the following procedure. A. For each design, the safety or safety relief valve manufacturer shall submit for test at least three valves for each of three different sizes (a total of nine valves). Each valve of a given size shall be set at a different pressure, covering the range of pressures for which the valve will be used or the range available at the facility where the tests are conducted. B. Tests shall be made on each safety or safety relief valve to determine its lift at capacity, popping, and blowdown pressures, and actual relieving capacity. Notes 5. Valve capacities are published in ‘Pressure Relief Device Certifications.’ This publication may be obtained from the National Board of Boiler and Pressure Vessel Inspectors, 1055 Crupper Ave., Columbus, OH 43229. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 82 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section I, Power Boilers - (1995 Addenda) An individual coefficient, KD, shall be established for each valve as follows: KD = Actual flow Theoretical flow = Individual coefficient of discharge Where actual flow is determined by test and theoretical flow, WT is calculated by one of the following equations: For 45 degree seat WT = 51.45 x πDLP x 0.707 For flat seat WT = 51.45 x πDLP WT = theoretical flow, defined by the same equation used to determine KD, lb/hr K = coefficient of discharge for the design The coefficient of discharge for the design, K, shall not be greater than 0.975. The coefficient shall not be applied to valves whose beta ratio (ratio of valve throat to inlet diameter) lies outside the range of 0.15 to 0.75, unless tests have demonstrated that the individual coefficient of discharge, KD, for valves at the extreme ends of a larger range, is within ±5% of the coefficient, K. For nozzle WT = 51.45 AP where: WT = theoretical flow, lb/hr A = nozzle throat area, in2 P = (1.03 x set pressure + 14.7), or = (set pressure + 2 + 14.7), whichever is greater, psia L = lift pressure at P, in. D = seat diameter, in. The coefficient of discharge for the design, K, shall be the average of the nine individual coefficients, KD. All individual coefficients of discharge, KD, shall fall within a range of ±5% of the coefficient, K. If a valve fails to meet this requirement, the Authorized Observer shall require two additional valves to be tested as replacements for each valve having an individual coefficient, KD, outside the ±5% range, with a limit of four additional valves. Failure of a coefficient, KD, to fall within ±5% of the new average value, excluding the replaced valve(s), shall be cause to refuse certification of that particular valve design. The rated relieving capacity of all sizes and set pressures of a given design, for which K has been established under the provision of this paragraph, shall be determined by the equation: For designs where the lift is used to determine the flow area, all valves shall have the same nominal lift to seat diameter ratio (L/D). For pressures over 1500 psig and up to 3200 psig, the value of W shall be multiplied by the correction factor: 0.1906P - 1000 0.2292P - 1061 PG-69.3 If a manufacturer wishes to apply the Code symbol to a power-actuated pressure relieving valve under PG-67.4.1, one valve of each combination of inlet pipe size and orifice size to be used with that inlet pipe size shall be tested. The valve shall be capacity tested at four different pressures approximately covering the range of the certified test facility on which the tests are conducted. The capacities, as determined by these four tests, shall be plotted against the absolute flow test pressure and a line drawn through these four test points. All points must lie within ±5% in capacity value of the plotted line and must pass through 0-0. From the plotted line, the slope of the line dW/dP shall be determined and a factor of (0.90/51.45) x (dW/dP) shall be applied to capacity computations in the supercritical region at elevated pressures by means of the isentropic flow equation.6 W = WT x K x 0.9 where: W = rated relieving capacity, lb/hr 0.90 dW W = 1135.8 ––––––– x ––– 51.45 dP –––––– P ––– ν √ Notes 6. The constant 1135.8 is based on a γ factor of 1.30 which is accurate for superheated steam at temperature above approximately 800°F. In interest of accuracy, other meth- where: W = capacity, lb of steam/hr P = absolute inlet pressure, psia ν = inlet specific volume, cu ft/lb dW/dP = rate of change of measured capacity with respect to absolute pressure A92 PG-69.4 Power-actuated pressure relieving valves, having capacities certified in accordance with the provision of PG-69.3 and computed in accordance with the formula contained therein, shall be marked as required by PG-110 with the computed capacity, corresponding to 3% above the full load operating pressure and temperature conditions at the valve inlet when the valve is operated by the controller, and they shall also be stamped with the set pressure of the controller. When the valve is marked as required by this paragraph, it shall be the guarantee by the manufacturer that the valve also conforms to the details of construction herein specified. A92 PG-69.6 When changes are made in the design of a safety or safety relief valve in such a manner as to affect the flow path, lift, or performance characteristics of the valve, new tests in accordance with this Section shall be performed. PG-70 Capacity of Safety Valves A93 PG-70.1 Subject to the minimum number required by PG-67.1, the number of safety valves or safety relief valves required shall be determined on the basis of the maximum designed steaming capacity, as determined by the boiler Manufacturer, and the relieving capacity marked on the valves by the manufacturer. In many cases a greater relieving capacity of safety valves or safety relief valves will have to be provided than the minimum specified by this rule, and in every case the requirements of PG-67.2 shall be met. ods of capacity computations must be used at temperatures below 800°F at supercritical pressures. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 83 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section I, Power Boilers - (1995 Addenda) PG-71 Mounting PG-71.1 When two or more safety valves are used on a boiler, they may be mounted either separately or as twin valves made by placing individual valves on Y-bases, or duplex valves having two valves in the same body casing. Twin valves made by placing individual valves on Y-bases, or duplex valves having two valves in the same body, shall be of approximately equal capacity. to be carried clear from running boards or platforms. Ample provision for gravity drain shall be made in the discharge pipe at or near each safety valve or safety relief valve, and where water of condensation may collect. Each valve shall have an open gravity drain through the casing below the level of the valve seat. For iron- and steel-bodied valves exceeding 21/2-inch size, the drain hole shall be tapped not less than 3/8-inch pipe size. When not more than two valves of different sizes are mounted singly the relieving capacity of the smaller valve shall be not less than 50% of that of the larger valve. Discharge piping from safety relief valves on high-temperature water boilers shall be provided with adequate provisions for water drainage as well as the steam venting. PG-71.2 The safety valve or safety relief valve or valves shall be connected to the boiler independent of any other connection, and attached as close as possible to the boiler or the normal steam flow path, without any unnecessary intervening pipe or fitting. Such intervening pipe or fitting shall be not longer than the face-to-face dimension of the corresponding tee fitting of the same diameter and pressure under the applicable American National Standard listed in PG-42 and shall also comply with PG-8 and PG-39. Every safety valve or safety relief valve shall be connected so as to stand in an upright position, with spindle vertical. On hightemperature water boilers of the watertube forced-circulation type, the valve shall be located at the boiler outlet. The installation of cast iron bodied safety relief valves for high-temperature water boilers is prohibited. PG-71.3 The opening or connection between the boiler and the safety relief valve shall have at least the area of the valve inlet. No valve of any description shall be placed between the required safety valve or safety relief valve or valves and the boiler, nor on the discharge pipe between the safety valve or safety relief valve and the atmosphere. When a discharge pipe is used, the cross-sectional area shall be not less than the full area of the valve outlet or of the total of the areas of the valve outlets, discharging thereinto. It shall be as short and straight as possible and so arranged as to avoid undue stresses on the valve or valves. All safety valve or safety relief valve discharges shall be so located or piped as PG-71.4 If a muffler is used on a safety valve or safety relief valve, it shall have sufficient outlet area to prevent back pressure from interfering with the proper operation and discharge capacity of the valve. The muffler plates or other devices shall be so constructed as to avoid a possibility of restriction of the steam passages due to deposit. Mufflers shall not be used on high-temperature water boiler safety relief valves. When a safety valve or safety relief valve is exposed to outdoor elements which may affect operation of the valve, it is permissible to shield the valve with a satisfactory cover. The shield or cover shall be properly vented and arranged to permit servicing and normal operation of the valve. PG-71.5 When a boiler is fitted with two or more safety relief valves on one connection, this connection to the boiler shall have a cross-sectional area not less than the combined areas of inlet connections of all the safety valves or safety relief valves with which it connects and shall also meet the requirements of PG-71.3. PG-71.6 Safety valves may be attached to drums or headers by welding provided the welding is done in accordance with Code requirements. PG-71.7 Every boiler shall have proper outlet connections for the required safety valve, or safety relief valve, or valves, in- © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 84 dependent of any other outside steam connection, the area of opening to be at least equal to the aggregate areas of inlet connections of all of the safety valves or safety relief valves to be attached thereto. An internal collecting pipe, splash plate, or pan may be used, provided the total area for inlet of steam thereto is not less than twice the aggregate areas of the inlet connections of the attached safety valves. The holes in such collecting pipes shall be at least 1/4-inch in diameter and the least dimension in any other form of opening for inlet of steam shall be 1/4-inch. Such dimensional limitations to operation for steam need not apply to steam scrubbers or driers provided the net free steam inlet area of the scrubber or drier is at least 10 times the total area of the boiler outlets for the safety valves. PG-71.8 If safety valves are attached to a separate steam drum or dome, the opening between the boiler proper and the steam drum or dome shall be not less than required by PG-71.7. PG-72 Operation PG-72.1 Safety valves shall be designed and constructed to operate without chattering and to attain full lift at a pressure no greater than 3% above their set pressure. After blowing down, all valves shall close at a pressure not lower than 96% of their set pressure, except that all drum valves installed on a single boiler may be set to reseat at a pressure not lower than 96% of the set pressure of the lowest set drum valve. The minimum blowdown for springloaded safety or safety relief valves shall be 2% of the set pressure, except that for boilers whose maximum allowable working pressure is less than 100 psi, the valves may be set to reseat between 2 and 4 psi below their set pressure. Safety valves used on forced-flow steam generators with no fixed steam and waterline, and safety relief valves used on high-temperature water boilers may be set and adjusted to close after blowing down not more than 10% of the set pressure. The valves for these special uses must be so adjusted and marked by the manufacturer. Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section I, Power Boilers - (1995 Addenda) PG-72.2 The popping point tolerance plus or minus shall not exceed the following: 2 psi for pressures up to and including 70 psi, 3% for pressures over 70 psi up to and including 300 psi, 10 psi for pressures over 300 psi up to and including 1000 psi, and 1% for pressures over 1000 psi. PG-72.3 The spring in a safety valve or safety relief valve shall not be reset for any pressure more than 5% above or below that for which the valve is marked unless the new setting is within the spring design range established by the manufacturer or is determined to be acceptable to the manufacturer. If the set pressure is to be adjusted within the limits specified above, the adjustment shall be performed by the manufacturer, his authorized representative, or an assembler. An additional valve data tag identifying the new set pressure, capacity, and date shall be furnished and installed, and the valved shall be resealed. PG-72.4 If the set pressure of a valve is changed so as to require a new spring, the spring shall be acceptable to the manufacturer. The spring installation and valve adjustment shall be performed by the manufacturer, his authorized representative, or an assembler. A new nameplate as described in PG-110 shall be furnished and installed, and the valve shall be resealed. PG-73 Minimum Requirements for Safety and Safety Relief Valves PG-73.1 Mechanical Requirements PG-73.1.1 The design shall incorporate guiding arrangements necessary to insure consistent operation and tightness. PG-73.1.2 The spring shall be designed so that the full lift spring compression shall be no greater than 80% of the nominal solid deflection. The permanent set of the spring (defined as the difference between the free height and height measured 10 min after the spring has been compressed solid three additional times after presetting at room temperature) shall not exceed 0.5% of the free height. PG-73.1.3 To provide a means for verifying whether it is free, each safety valve or safety relief valve shall have a substantial lifting device, which when activated will release the seating force on the disk when the valve is subject to pressure of at least 75% of the set pressure. The lifting device shall be such that it cannot lock or hold the valve disk in lifted position when the exterior lifting force is released. Disks of safety relief valves used on high-temperature water boilers shall not be lifted while the temperature of the water exceeds 200°F. If it is desired to lift the valve disk to assure that it is free, this shall be done when the valve is subjected to a pressure of at least 75% of the set pressure. For high-temperature water boilers, the lifting mechanism shall be sealed against leakage. stalled in such a manner as to prevent changing the adjustment without breaking the seal and, in addition, shall serve as a means of identifying the manufacturer, his authorized representative, or the assembler making the adjustment. PG-73.1.4 The seat of a safety valve shall be fastened to the body of the valve in such a way that there is no possibility of the seat lifting. PG-73.2.3 Materials used in bodies and bonnets or yokes shall be listed in Section II, Parts A and B, and identified in Tables 1A and 1B of Section II, Part D, as permitted for Section I construction. Materials used in nozzles, disks, and other parts contained within the external structure of the safety or safety relief valves shall be one of the following categories: PG-73.1.5 A body drain below seat level shall be provided in the valve and this drain shall not be plugged during or after field installation. For valves exceeding 21/2-inch pipe size, the drain hole or holes shall be tapped not less than 3/8-inch pipe size. For valves of 21/2-inch pipe size or smaller, the drain hole shall not be less than 1/4-inch in diameter. PG-73.1.6 In the design of the body of the valve, consideration shall be given to minimizing the effects of water deposits. PG-73.1.7 Valves having screwed inlet or outlet connections shall be provided with wrenching surfaces to allow for normal installation without damaging operating parts. A92 PG-73.1.8 Means shall be provided in the design of all valves for use under this Section, for sealing all external adjustments. Seals shall be installed by the manufacturer, his authorized representative, or an assembler at the time of the initial adjustment. After spring replacement and/or subsequent adjustment, the valve shall be resealed. Seals shall be in- PG-73.2 Material Selections PG-73.2.1 Cast iron seats and disks are not permitted. PG-73.2.2 Adjacent sliding surfaces such as guides and disks or disk holders shall both be of corrosion resistant material. Springs of corrosion resistant material or having a corrosion resistant coating are required. The seats and disks of safety valves or safety relief valves shall be of suitable material to resist corrosion by the lading fluid.7 1. listed in ASME Section II; 2. listed in ASTM Specifications;8 3. controlled by the manufacturer of the safety or safety relief valve by a specification insuring control of chemical and physical properties and quality at least equivalent to ASTM Standards.8 Notes 7. The degree of corrosion resistance, appropriate to the intended service, shall be a matter of agreement between the manufacturer and purchaser. 8. It shall be the manufacturer’s responsibility to insure that the allowable stressed at temperature meet the requirements of Section II, Part D, Appendix 1, Nonmandatory Basis for Establishing Stress Values in Table 1A and 1B. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 85 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section I, Power Boilers - (1995 Addenda) PG-73.3 Inspection of Manufacturing and/or Assembly A92/A93 PG-73.3.1 A manufacturer shall demonstrate to the satisfaction of an ASME designee that his manufacturing, production, and test facilities and quality control procedures will insure close agreement between the performance of random production samples and the performance of those valves submitted for capacity certification. A93 4. Failure of any of the replacement valves to meet the capacity or the performance requirements of this Section shall be cause for revocation within 60 days of the authorization to use the Code symbol on that particular type of valve. During this period, the Manufacturer or assembler shall demonstrate the cause of such deficiency and the action taken to guard against future occurrence, and the requirements of PG-73.3.3 above shall apply. A93 PG-73.3.2 Manufacturing, assembly, inspection, and test operations including capacity, are subject to inspections at any time by an ASME designee. PG-73.3.4 Use of the Code Symbol Stamp by an assembler indicates the use of original unmodified parts in strict accordance with the instructions of the manufacturer of the valve. A92/A93 A93 PG-73.3.3 A Manufacturer or assembler may be granted permission to apply the V Code Symbol to production pressure relief valves capacity-certified in accordance with PG-69, provided the following tests are successfully completed. This permission shall expire on the fifth anniversary of the date it is initially granted. This permission may be extended for 5 year periods if the following tests are successfully repeated within the 6 month period before expiration. PG-73.3.5 In addition to the requirements of PG-110, the same plate marking shall include the name of the Manufacturer and the assembler. The Code Symbol Stamp shall be that of the assembler.9 1. Two sample production pressure relief valves of a size and capacity within the capability of an ASME accepted laboratory shall be selected by an ASME designee. 2. Operational and capacity tests shall be conducted in the presence of an ASME designee at an ASME accepted laboratory. The valve manufacturer or assembler shall be notified of the time of the test and may have representatives present to witness the test. 3. Should any valve fail to relieve at or above its certified capacity or should it fail to meet performance requirements of this Section, the test shall be repeated at the rate of two replacement valves, selected in accordance with PG-73.3.3(1), for each valve that failed. PG-73.4 Testing by Manufacturers or Assemblers PG-73.4.1 Valves exceeding 1-inch inlet size or 300 psig set pressure shall meet the following requirements. Primary pressure containing cast and welded parts of pressure relief valves shall be tested at a pressure at 1.5 times the design pressure of the parts. These tests shall be conducted after all machining operations to the parts have been completed. There shall be no visible signs of leakage. Closed bonnet pressure relief valves designed for discharge to a closed system shall be tested with a minimum of 30 psig air or other gas in the secondary pressure zone. There shall be no visible signs of leakage. PG-73.4.2 Every valve shall be tested with steam by the manufacturer or assembler to demonstrate the popping point, blowdown, tightness, and pressure containing integrity. Valves beyond the capability of production test facilities may be shop tested with air, provided required field tests and applicable adjustments are made. PG-73.4.3 A seat tightness test shall be conducted at maximum expected operating pressure, but at a pressure not exceeding the reseating pressure of the valve. When being tested, a valve exhibiting no visible signs of leakage shall be considered adequately tight. A92 PG-73.4.4 A manufacturer or assembler shall have a documented program for the application, calibration, and maintenance of test gauges. PG-73.4.5 Testing time on steam valves shall be sufficient to assure that test results are repeatable and representative of field performance. A92 PG-73.4.6 Test fixtures and test drums, where applicable, shall be of adequate size and capacity to assure that the observed set pressure is consistent with the stamped set pressure within the tolerance required by PG-72.2. PG-73.5 Design Requirements At the time of submission of valves for capacity certification or testing in accordance with PG-69, the ASME designee has the authority to review design for conformity with the requirements of this Section and to reject or require modification of designs which do not conform, prior to capacity testing. Notes 9. Within the requirements of PG-73.3 and PG73.4, a manufacturer is defined as a person or organization who is completely responsible for design, material selection, capacity certification, manufacture of all component parts, assembly, testing, sealing, and shipping of safety and safety relief valves certified under this Section. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 86 An assembler is defined a person or organization who purchases or receives from a manufacturer the necessary component parts or valves and assembles, adjusts, tests, seals, and ships safety or safety relief valves certified under this Section at a geographical location other than and using facilities other than those used by the manufacturer. Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section I, Power Boilers - (1995 Addenda) PFT-44 Opening Between Boiler and Safety Valve The opening or connection between the boiler and the safety valve shall have at least the area of the valve inlet. In the case of firetube boilers, the openings in the boilers for safety valves or safety relief valves shall be not less than given in Table PFT-44, except firetube boilers used for waste heat purposes only, not equipped for direct firing, need not meet the requirements of Table PFT-44 provid- ed the rated steaming capacity is stamped on the boiler and safety valves or safety relief valves of the required relieving capacity are supplied such that the provisions of PG-67.2 are satisfied. After the boiler Manufacturer provides for the opening required by the Code, a bushing may be inserted in the opening in the shell to suit a safety valve that will have the capacity to relieve all the steam that can be generated in the boiler and which will meet the Code requirements. No valve of any description shall be placed between the required safety valve or safety relief valve or valves and the boiler, or on the discharge pipe between the safety valve or safety relief valve and the atmosphere. When a discharge pipe is used, the cross-sectional area shall be not less than the full area of the valve outlet or of the total of the areas of the valve outlets discharging thereinto and shall be as short and straight as possible and so arranged as to avoid undue stresses on the valve or valves. Table PFT-44 Minimum Total Areas of Openings (in2) in Firetube Boilers for Safety Valve Connections 1, 2 Gauge Press. psi 100 Boiler Heating Surface, sq. ft. 200 300 400 500 600 800 1000 1200 1400 1600 1800 2000 2500 3000 V 16 3.174 6.348 9.522 12.696 15.869 19.043 25.392 31.739 38.086 44.435 50.783 57.130 63.478 79.347 95.216 13.330 25 2.500 5.000 7.499 10.000 12.498 15.000 20.000 24.996 30.000 35.000 40.000 44.992 49.992 62.489 74.987 10.498 50 1.584 3.168 4.752 6.338 7.920 9.504 12.677 15.839 19.007 22.175 25.354 28.510 31.678 39.599 47.517 6.655 75 1.166 2.331 3.497 4.663 5.828 6.995 9.326 11.657 13.989 16.320 18.652 20.983 23.314 29.143 34.972 4.896 100 0.924 1.849 2.773 3.697 4.621 5.546 7.394 9.243 11.092 12.940 14.789 16.637 18.486 23.106 27.729 3.882 125 0.767 1.533 2.300 3.067 3.834 4.600 6.134 7.667 9.201 10.734 12.267 13.800 15.334 19.166 23.000 3.220 150 0.655 1.311 1.966 2.621 3.276 3.932 5.242 6.553 7.863 9.174 10.484 11.795 13.106 16.382 19.658 2.752 175 0.572 1.145 1.718 2.289 2.862 3.435 4.579 5.725 6.870 8.015 9.158 10.305 11.450 14.312 17.175 2.404 200 0.508 1.016 1.525 2.033 2.541 3.049 4.066 5.082 6.099 7.115 8.132 9.148 10.164 12.706 15.247 2.1345 225 0.457 0.913 1.370 1.827 2.284 2.740 3.654 4.567 5.481 6.394 7.308 8.221 9.134 11.417 13.702 1.9183 250 0.415 0.830 1.244 1.659 2.074 2.489 3.318 4.148 4.978 5.807 6.637 7.466 8.296 10.370 12.444 1.7422 Nominal Pipe Size, Inch 1/2 3/4 1 Internal Diameter Internal Area, in2 0.622 0.304 2 2.067 0.824 0.533 21/2 1.049 0.864 3 31/2 11/4 1.380 1.495 11/2 1.610 2.036 Nominal Pipe Internal Size, inch Diameter Internal Area, in2 Nominal Pipe Size, inch Internal Diameter Internal Area, in2 3.355 4 4.026 12.730 2.469 4.788 5 5.047 20.006 3.068 7.393 6 6.065 28.891 3.548 9.886 8 8.071 51.161 Notes 1. Based on formula A = HV/420 where A = total area of openings, in 2 H = boiler heating surface, ft 2 V = specific volume of steam in cu. ft/lb at maximum allowable working pressure. 2. Number and size of openings shall provide for not less than the area given. Intermediate values may be interpolated. With flanged openings, use internal area for determining diameter. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 87 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section I, Miniature Boilers - (1995 Addenda) PMB-15 Safety Valves Each miniature boiler shall be equipped with a sealed spring loaded safety valve of not less than NPS 1/2. without allowing the pressure to rise more than 6% above the maximum allowable working pressure. The minimum relieving capacity of the safety valve shall be determined in accordance with PG-70. In addition to these requirements, the safety valve shall have sufficient capacity to discharge all the steam that can be generated by the boiler All other provisions for safety valves in this Section shall be complied with. ASME Code Section I, Electric Boilers - (1995 Addenda) PEB-15 Safety Valves PEB-15.1 Each electric boiler shall have at least one safety valve or safety relief valve, and if it has a power input more than 1100 kW, it shall have two or more safety valves or safety relief valves. PEB-15.2 The minimum safety valve or safety relief valve relieving capacity for electric boilers shall be 31/2 lb/hr/kW input. ASME Code Section I, Organic Vapor Generator - (1995 Addenda) PVG-12.1 Safety valves shall be of a totally enclosed type so designed that vapors escaping beyond the valve seat shall not discharge into the atmosphere, except through an escape pipe that will carry such vapors to a safe point of discharge outside of the building. A suitable condenser that will condense all the vapors discharged from the safety valve may be used in lieu of piping the vapors to the atmosphere. The safety valve shall not have a lifting lever. The vaporizer shall be designed in accordance with the rules in this Code for a working pressure of at least 40 psi above the operating pressure at which it will be used. Valve body drains are not mandatory. Figure PVG-12 Constant C For Vapor Related to Ratio of Specific Heats (k = Cp/Cv) 400 390 380 Constant, C PVG-12 Safety Valves PVG-12.3.1 The cross-sectional area of the connection to a vaporizer shall be not less than the required relief area of the rupture disk. PVG-12.3.2 Every rupture disk shall have a specified bursting pressure at a specified temperature, shall be marked with a lot number, and shall be guaranteed by its manufacturer to burst within 360 350 Flow Formula Calculations 340 PVG-12.2 Safety valves shall be disconnected from the vaporizer at least once yearly, when they shall be inspected, repaired if necessary, tested, and then replaced on the vaporizer. PVG-12.3 In order to minimize the loss by leakage of material through the safety valve, a rupture disk may be installed between the safety valve and the vaporizer provided the following requirements are met. 370 W = K (CAP 330 C = 520 k M/T) ( k +2 1 ( k+1 k-1 320 ▲ 1.0 ▲ 1.2 ▲ 1.6 ▲ 1.4 ▲ 1.8 ▲ 2.0 k 5% (plus or minus) of its specified bursting pressure. PVG-12.3.3 The specified bursting pressure at the coincident operating temperature shall be determined by bursting two or more specimens from a lot of the same material and of the same size as those to be used. The tests shall be made in a holder of the same form and pressure area dimensions as that with which the disk is to be used. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 88 PVG-12.3.4 A rupture disk may be installed between a safety valve and the vaporizer provided: PVG-12.3.4.1 The maximum pressure of the range for which the disk is designed to rupture does not exceed the opening pressure for which the safety valve is set or the maximum allowable working pressure of the vessel. Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section I, Organic Vapor Generator (1995 Addenda) PVG-12.3.4.2 The opening provided through the rupture disk, after breakage, is sufficient to permit a flow equal to the capacity of the attached valve and there is no chance of interference with the proper functioning of the valve; but in no case shall this area be less than the inlet area of the valve. PVG-12.3.4.3 The space between a rupture disk and the valve should be provided with a pressure gauge, try cock, free vent, or a suitable telltale indicator. This arrangement permits the detection of disk rupture or leakage.1 PVG-12.4 Safety valve discharge capacity shall be determined from the formula: W = (0.90)CKAP –––– √ M/T where: W = flow of vapor, lb/hr C = constant for vapor which is a function of the ratio of Specific Heats k = Cp /Cv (see Fig. PVG-12) Note: Where k is not known, k = 1.001. K = average coefficient of discharge PVG-12.5 Safety valves for organic fluid vaporizers shall be tested and certified under PG-69, and they shall be stamped with the rated relieving capacity in pounds per hour at coincident temperature as determined in PVG-12.4 The fluid identification shall be stamped on the nameplate. PVG-12.6 The required minimum safety valve relieving capacity shall be determined from the formula: W = C x H x 0.75 h where: h = latent heat of heat transfer fluid at relieving pressure, BTU/lb W = weight of organic fluid vapor generated per hour, lb C = maximum total weight or volume of fuel burned per hour, lb or cu ft H = heat of combustion of fuel, BTU/lb or BTU/cu ft (see A-17) The sum of the safety valve capacities marked on the valves shall be equal to or greater than W. A = discharge area of safety valve, in2 P = (set pressure x 1.03) + Atmosphere Pressure, psia M = molecular weight T = absolute temperature at inlet, °F + 460 Note 1. Users are warned that a rupture disc will not burst at its designed pressure if back pressure builds up in the space between the disc and the safety valve which will occur should leakage develop in the rupture disc due to corrosion or other cause. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 89 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section I, Mandatory Appendix A - (1995 Addenda) Safety Valves for Power Boilers A93 A-44 The safety valve capacity of each boiler shall be such that the safety valve or valves will discharge all the steam that can be generated by the boiler without allowing the pressure to rise more than 6% above the maximum allowable working pressure, or more than 6% above the highest pressure to which any valve is set. The minimum safety valve or safety relief valve relieving capacity for other than electric boilers, waste heat boilers, organic fluid vaporizers, and forced-flow steam generators with no fixed steam and waterline, when provided in accordance with PG-67.4.3, shall be determined on the basis of the pounds of steam generated per hour per square foot of boiler heating surface and waterwall heating surface, as given in Table A-44. The minimum safety valve or safety relief valve relieving capacity for electric boilers shall be 31/2 lb/hr/kW input. In many cases, a greater relieving capacity of safety valves or safety relief valves will have to be provided than the minimum specified in Table A-44, in order to meet the requirements of the first paragraph of A-44. A-45 allowable working pressure. The remaining valves may be set within a range of 3% above the maximum allowable working pressure, but the range of setting of all of the saturated steam valves on a boiler shall not exceed 10% of the highest pressure to which any saturated steam valve is set. When boilers of different maximum allowable working pressures with minimum safety valve settings varying more than 6% are so connected that steam can flow toward the lower pressure units, the latter shall be protected by additional safety valve capacity, if necessary, on the lower pressure side of the system. The additional safety valve capacity shall be based upon the maximum amount of steam which can flow into the lower pressure system. The additional safety valves shall have at least one valve set at a pressure not to exceed the lowest allowable pressure and the other valves shall be set within a range not to exceed 3% above that pressure. A-46.1 By making an accumulation test, that is, by shutting off all other steam-discharge outlets from the boiler and forcing the fires to the maximum. The safety valve equipment shall be sufficient to prevent an excess pressure beyond that specified in PG-67.2. This method should not be used on a boiler with a superheater or reheater or on a high-temperature water boiler. A-46.2 By measuring the maximum amount of fuel that can be burned and computing the corresponding evaporative capacity upon the basis of the heating value of the fuel (see A-12 through A-17). A93 A-46.3 By determining the maximum evaporative capacity by measuring the feedwater. The sum of the safety valve capacities marked on the valves shall be equal to or greater than the maximum evaporative capacity of the boiler. This method shall not be used on high-temperature water boilers. A93 A93 A-46 A-48 If the safety valve or safety relief valve capacity cannot be determined or if it is desirable to verify the computations, the capacity may be checked in one of the three following ways, and if found insufficient, additional capacity shall be provided. When operating conditions are changed, or additional heating surface such as water screens or waterwalls is connected to the boiler circulation, the safety valve or safety relief valve capacity shall be increased, if necessary, to meet the new conditions and be in accordance with PG67.2. The additional valves required on account of changed conditions may be One or more safety valves on every boiler shall be set at or below the maximum Table A-44 Note When a boiler is fired only by a gas having a heat value not in excess of 200 BTU/cu ft, the minimum safety valve or safety relief valve relieving capacity may be based on the values given for hand-fired boilers above. Minimum Pounds of Steam Per Hour Per Square Foot of Surface Firetube Boilers Watertube Boilers Boiler heating surface: Hand fired 5 6 Stoker fired 7 8 Oil, gas or pulverized fuel fired 8 10 Hand fired 8 8 Stoker fired 10 12 Oil, gas, or pulverized fuel fired 14 16 Waterwall heating surface © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 90 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section I, Mandatory Appendix A - (1995 Addenda) installed on the piping between the boiler and the main stop valve except when the boiler is equipped with a superheater or other piece of apparatus. In the latter case they may be installed on the piping between the boiler drum and the inlet to the superheater or other apparatus, provided that the piping between the boiler and safety valve (or valves) connection has a cross-sectional area of at least three times the combined areas of the inlet connections to the safety valves applied to it. A-49 No valve of any description shall be place between the safety valve and the boiler, or on the discharge pipe between the safety valve and the atmosphere. When a discharge pipe is used, it shall be not less than the full size of the valve, and the dis- charge pipe shall be fitted with an open drain to prevent water lodging in the upper part of the safety valve or in the pipe. If a muffler is used on a safety valve it shall have sufficient outlet area to prevent back pressure from interfering with the proper operation and discharge capacity of the valve. The muffler plates or other devices shall be so constructed as to avoid any possibility of restriction of the steam passages due to deposit. When an elbow is placed on a safety valve discharge pipe, it shall be located close to the safety valve outlet or the pipe shall be securely anchored and supported. All safety valve discharges shall be so located or piped as to be carried clear from running boards or working platforms used in controlling the main stop valves of boilers or steam headers. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 91 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section IV – Heating Boiler Code (1995 Addenda) Pressure Relieving Devices HG-400 Pressure Relieving Valve Requirements HG-400.1 Safety Valve Requirements for Steam Boilers A. Each steam boiler shall have one or more officially rated safety valves that are identified with the V or HV Symbol of the spring pop type adjusted and sealed to discharge at a pressure not to exceed 15 psi. Seals shall be attached in a manner to prevent the valve from being taken apart without breaking the seal. The safety valves shall be arranged so that they cannot be reset to relieve at a higher pressure than the maximum allowable working pressure of the boiler. Drain holes are not required for valves 3/4-inch and smaller, when the seating surface of the valve is above the lowest portion of the inside diameter of the discharge piping. Means shall be provided for complete drainage of the discharge piping. B. No safety valve for a steam boiler shall be smaller than 1/2-inch. No safety valve shall be larger than 41/2-inch. The inlet opening shall have an inside diameter equal to, or greater than, the seat diameter. C. The minimum relieving capacity of valve or valves shall be governed by the capacity marking on the boiler called for in HG-530. D. The minimum valve capacity in pounds per hour shall be the greater of that determined by dividing the maximum BTU output at the boiler nozzle obtained by the firing of any fuel for which the unit is installed by 1000, or shall be determined on the basis of the pounds of steam generated per hour per square foot of boiler heating surface as given in Table HG-400.1. For cast iron boilers constructed to the requirements of Part HC, the minimum valve capacity shall be determined by the maximum output method. In many cases a greater relieving capacity of valves will have to be provided than the minimum specified by these rules. In every case, the requirement of HG-400.1(E) shall be met. E. The safety valve capacity for each steam boiler shall be such that with the fuel burning equipment installed, and operated at maximum capacity, the pressure cannot rise more than 5 psi above the maximum allowable working pressure. F. When operating conditions are changed, or additional boiler heating surface is installed, the valve capacity shall be increased, if necessary, to meet the new conditions and be in accordance with HG-400.1(E). The additional valves required, on account of changed conditions, may be installed on the outlet piping provided there is no intervening valve. HG-400.2 Safety Relief Valve Requirements for Hot Water Boilers A. Each hot water heating or supply boiler shall have at least one officially rated safety relief valve, of the automatic re- seating type, identified with the V or HV Symbol, and set to relieve at or below the maximum allowable working pressure of the boiler. Safety relief valves officially rated as to capacity shall have pop action when tested by steam. When more than one safety relief valve is used on either hot water heating or hot water supply boilers, the additional valve or valves shall be officially rated and may have a set pressure within a range not to exceed 6 psi above the maximum allowable working pressure of the boiler up to and including 60 psi, and 5% for those having a maximum allowable working pressure exceeding 60 psi. Safety relief valves shall be spring loaded. Safety relief valves shall be set and sealed so that they cannot be reset without breaking the seal. B. No materials liable to fail due to deterioration or vulcanization when subjected to saturated steam temperature corresponding to capacity test pressure shall be used for any part. C. No safety relief valve shall be smaller than 3/4-inch nor larger than 41/2-inch standard pipe size except that boilers having a heat input not greater than 15,000 BTU/hr may be equipped with a rated safety relief valve of 1/2-inch standard pipe size. The inlet opening shall have an inside diameter approximately equal to, or greater than, the seat diameter. In no case shall the minimum opening through any part of the valve be less than 1/4-inch in diameter or its equivalent area. Table HG-400.1 Notes 1. When a boiler is fired only by a gas having a heat value not in excess of 200 BTU/cu ft, the minimum safety valve or safety relief valve relieving capacity may be based on the values given for hand fired boilers above. 2. The minimum safety valve or safety relief valve relieving capacity for electric boilers shall be 31/2 lb/hr/kW input. 3. For heating surface determination, see HG-403. Minimum Pounds of Steam Per Hour Per Square Foot of Heating Surface Firetube Boilers Watertube Boilers Boiler heating surface Hand fired 5 6 Stoker fired 7 8 Oil, gas or pulverized fuel fired 8 10 Waterwall heating surface Hand fired 8 8 Stoker fired 10 12 Oil, gas, or pulverized fuel fired 14 16 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 92 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section IV – Heating Boiler Code (1995 Addenda) D. The required steam relieving capacity, in pounds per hour, of the pressure relieving device or devices on a boiler shall be the greater of that determined by dividing the maximum output in BTU at the boiler nozzle obtained by the firing of any fuel for which the unit is installed by 1000, or shall be determined on the basis of pounds of steam generated per hour per square foot of boiler heating surface as given in Table HG-400.1. For cast iron boilers constructed to the requirements of Part HC, the minimum valve capacity shall be determined by the maximum output method. In many cases a greater relieving capacity of valves will have to be provided than the minimum specified by these rules. In every case, the requirements of HG-400.2(F) shall be met. E. When operating conditions are changed, or additional boiler heating surface is installed, the valve capacity shall be increased, if necessary, to meet the new conditions and shall be in accordance with HG-400.2(F). The additional valves required, on account of changed conditions, may be installed on the outlet piping provided there is no intervening valve. F. Safety relief valve capacity for each boiler with a single safety relief valve shall be such that, with the fuel burning equipment installed and operated at maximum capacity, the pressure cannot rise more than 10% above the maximum allowable working pressure. When more than one safety relief valve is used, the overpressure shall be limited to 10% above the set pressure of the highest set valve allowed by HG400.2(A). HG-400.3 Safety and Safety Relief Valves for Tanks and Heat Exchangers A. Steam to Hot Water Supply. When a hot water supply is heated indirectly by steam in a coil or pipe within the service limitations set forth in HG-101, the pressure of the steam used shall not exceed the safe working pressure of the hot water tank, and a safety relief valve at least 1-inch in diameter, set to relieve at or below the maximum allowable working pressure of the tank, shall be applied on the tank. B. High Temperature Water to Water Heat Exchanger. 1 When high temperature water is circulated through the coils or tubes of a heat exchanger to warm water for space heating or hot water supply, within the service limitations set forth in HG-101, the heat exchanger shall be equipped with one or more officially rated safety relief valves that are identified with the V or HV Symbol, set to relieve at or below the maximum allowable working pressure of the heat exchanger, and of sufficient rated capacity to prevent the heat exchanger pressure from rising more than 10% above the maximum allowable working pressure of the vessel. C. High Temperature Water to Steam Heat Exchanger.1 When high temperature water is circulated through the coils or tubes of a heat exchanger to generate low pressure steam, within the service limitations set forth in HG-101, the heat exchanger shall be equipped with one or more officially rated safety valves that are identified with the V or HV Symbol, set to relieve at a pressure not to exceed 15 psi, and of sufficient rated capacity to prevent the heat exchanger pressure from rising more than 5 psi above the maximum allowable working pressure of the vessel. For heat exchangers requiring steam pressures greater than 15 psi, refer to Section I or Section VIII, Division 1. HG-401 Minimum Requirements for Safety and Safety Relief Valves HG-401.1 Mechanical Requirements A. Bottom guided designs are not permitted on hot water valves. B. Synthetic disk inserts of O-ring or other types if used shall be compatible with the maximum design temperature established for the valve. C. O-rings or other packing devices when used on the stems of hot water safety relief valves shall be so arranged as not to affect their operation or capacity. D. The design shall incorporate guiding arrangements necessary to insure consistent operation and tightness. Excessive lengths of guiding surfaces should be avoided. E. Steam valves shall have a controlled blowdown of 2 psi to 4 psi and this blowdown need not be adjustable. F. The spring shall be designed so that the full lift spring compression shall be no grater than 80% of the nominal solid deflection. The permanent set of the spring (defined as the difference between the free height and height measured 10 min after the spring has been compressed solid three additional times after pre-setting at room temperature) shall not exceed 0.5% of the free height. G. There shall be a lifting device and a mechanical connection between the lifting device and the disk capable of lifting the disk from the seat a distance of at least 1/16-inch with no pressure on the boiler. A-92 H. A body drain below seat level shall be provided by the Manufacturer for all safety valves and safety relief valves, except that the body drain may be omitted when the valve seat is above the bottom of the inside diameter of the discharge piping. For valves exceeding NPS 21/2 the drain hole or holes shall be tapped not less than NPS 3/8. For valves NPS 21/2 or smaller, the drain hole shall not be less than 1/4-inch in diameter. Body drain connections shall not be plugged during or after field installation. In hot water relief valves of the diaphragm type, the space above the diaphragm shall be vented to prevent a buildup of pressure above the diaphragm. Hot water relief valves of the diaphragm type shall be so designed that failure or deterioration of the diaphragm material will not impair the ability of the valve to relieve at the rated capacity. I. In the design of the body of the valve consideration shall be given to minimizing the effects of water deposits. J. Valves shall be provided with wrenching surfaces to allow for normal installation without damaging operating parts. Note 1. Suggested installation practices for the secondary side of heat exchangers. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 93 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section IV – Heating Boiler Code (1995 Addenda) K. The set pressure tolerances, plus or minus, of steam safety valves shall not exceed 2 psi, and for safety relief valves shall not exceed 3 psi for pressures up to and including 60 psi and 5% for pressures above 60 psi. HG-401.2 Material Selection A. Cast iron seats and disks are not permitted. B. Adjacent sliding surfaces such as guides and disks shall both be of corrosion resistant material. C. Springs of corrosion resistant material or having a corrosion resistant coating are required. D. Material for seats and disks should be such as to provide a reasonable degree of resistance to steam cutting. E. Material for valve bodies and bonnets or their corresponding metallic pressure containing parts shall be listed in Section II, except that in cases where a manufacturer desires to make use of materials other than those listed in Section II, he shall establish and maintain specifications requiring equivalent control of chemical and physical properties and quality. A-93 HG-401.3 Manufacture and Inspection A. A Manufacturer shall demonstrate to the satisfaction of an ASME designee that his manufacturing, production, and testing facilities and quality control procedures will insure close agreement between the performance of random production samples and the performance of those valves submitted for capacity certification. B. Manufacturing, inspection, and test operations including capacity are subject to inspection at any time by an ASME designee. C. A Manufacturer may be granted permission to apply the HV Code Symbol to production pressure relief valves capacity certified in accordance with HG-402.3 provided the following tests are successfully completed. This permission shall expire on the fifth anniversary of the date it is initially granted. The permission may be extended for 5 year periods if the following tests are successfully repeated within the 6 month period before expiration. 1. Two sample production pressure relief valves of a size and capacity within the capability of an ASME accepted laboratory shall be selected by an ASME designee. 2. Operational and capacity tests shall be conducted in the presence of an ASME designee at an ASME accepted laboratory. The valve Manufacturer shall be notified of the time of the test and may have representatives present to witness the test. 3. Should the valve fail to relieve at or above its certified capacity or should it fail to meet performance requirements of this Section, the test shall be repeated at the rate of two replacement valves, selected in accordance with HG-401.3(C)(1), for each valve that failed. 4. Failure of any of the replacement valves to meet the capacity or the performance requirements of this Section shall be cause for revocation within 60 days of the authorization to use the Code Symbol on that particular type of valve. During this period, the Manufacturer shall demonstrate the cause of such deficiency and the action taken to guard against future occurrence, and the requirements of HG-401.3(C) above shall apply. C. Testing time on steam valves shall be sufficient, depending on size and design, to insure that test results are repeatable and representative of field performance. D. Test fixtures and test drums shall be of adequate size and capacity to assure representative pop action and accuracy of blowdown adjustment. E. A tightness test shall be conducted at maximum expected operating pressure, but not at a pressure exceeding the reseating pressure of the valve. HG-401.5 Design Requirements. At the time of the submission of valves for capacity certification, or testing in accordance with this Section, the ASME Designee has the authority to review the design for conformity with the requirements of this Section, and to reject or require modification of designs which do not conform, prior to capacity testing. HG-402 Discharge Capacities of Safety and Safety Relief Valves HG-402.1 Valve Markings. Each safety or safety relief valve shall be plainly marked with the required data by the Manufacturer in such a way that the markings will not be obliterated in service. The markings shall be stamped, etched, impressed, or cast on the valve or on a nameplate which shall be securely fastened to the valve. The markings shall include the following: A. the name or an acceptable abbreviation of the Manufacturer; HG-401.4 Manufacturer’s Testing B. Manufacturer’s design or type number; A. Every steam valve shall be tested to demonstrate its popping point, blowdown, and tightness. Every hot water valve shall be tested to demonstrate its opening point and tightness. Steam valves shall be tested on steam or air and hot water valves on water, steam, or air. When the blowdown is nonadjustable, the blowdown test may be performed on a sampling basis. C. NPS size _____ inch (the nominal pipe size of the valve inlet); B. A Manufacturer shall have a well-established program for the application, calibration, and maintenance of test gauges. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 94 D. set pressure ________psi; E. capacity _________lb/hr, or capacity_________ BTU/hr in accordance with HG-402.3; F. year built or, alternatively, a coding may be marked on the valves such that the valve Manufacturer can identify the year the valve was assembled and tested; G. ASME Symbol as shown in Figure HG402. Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section IV – Heating Boiler Code (1995 Addenda) shall be set at a different pressure. However, safety valves for steam boilers shall have all nine valves set at 15 psig. A coefficient shall be established for each test as follows: KD = HG-402.3 Determination of Capacity to Be Stamped on Valves. The Manufacturer of the valves that are to be stamped with the Code symbol shall submit valves for testing to a place where adequate equipment and personnel are available to conduct pressure and relieving-capacity tests which shall be made in the presence of and certified by an authorized observer. The place, personnel, and authorized observer shall be approved by the Boiler and Pressure Vessel Committee. The valves shall be tested in one of the following three methods. A. Coefficient Method.1 Tests shall be made to determine the lift, popping, and blowdown pressures, and the capacity of at least three valves each of three representative sizes (a total of nine valves). Each valve of a given size = Coefficient of discharge The average coefficient of the tests required shall be taken as the coefficient K of the design, and the stamped capacity for all sizes and pressures of the design shall not exceed the value determined from the following formulas: Figure HG-402 Official Symbol For Stamp to Denote The American Society of Mechanical Engineers’ Standard HG-402.2 Authorization to Use ASME Stamp. Each safety valve to which the Code Symbol (Figure HG-402) is to be applied shall be produced by a Manufacturer and/or Assembler who is in possession of a valid Certificate of Authorization. (See HG-540) Actual steam flow Theoretical steam flow For 45 degree seat, W = (51.45 π DLP x 0.707K ) 0.90 For flat seat, W = (51.45 π DLPK ) 0.90 For nozzle, W = (51.45 APK ) 0.90 Where: W = weight of steam/hr, lb D = seat diameter, inch L = lift, inch P = absolute pressure, psi (accumulated) KD = coefficient of discharge for a single test K = average coefficient of discharge A = nozzle-throat area, in2 the tests. The capacities shall be based on these four tests as follows. 1. The slope (dW/dP ) of the actual measured relieving capacity versus the flow pressure for each test point shall be calculated and averaged: Slope = dW/dP = measured capacity/ absolute flow pressure (psia) All values derived from the testing must fall within ± 5% of the average value: Minimum slope = average slope x 0.95 Maximum slope = average slope x 1.05 If slope values derived from the test do not fall between the minimum and maximum slope values, the authorized observer shall require that additional valves be tested at the rate of two for each value beyond the maximum and minimum values with a limit of four additional valves. 2. The relieving capacity to be stamped on the valve shall not exceed 90% of the average slope times the absolute flow pressure: W ≤ average slope [(stamped set pressure x 1.10) + 14.7] 0.90 B. Slope Method. If a Manufacturer wishes to apply the Code Symbol to a design of pressure relief valves, four valves of each combination of pipe and orifice size shall be tested. These four valves shall be set at pressures that cover the approximate range of pressures for which the valve will be used, or that cover the range available at the certified test facility that shall conduct C. Three-Value Method. If a Manufacturer wishes to apply the Code Symbol to steam safety valves or safety relief valves of one or more sizes of a design set at one pressure, he shall submit three valves of each size of each design set at one pressure for testing and the stamped capacity of each size shall not exceed 90% of the average capacity of the three valves tested.2 side the acceptable limits, as determined by the new average coefficient, a valve of the Manufacturer’s choice must be replaced by two valves of the same size and pressure as the rejected valve. A new average coefficient, including the replacement valves, shall be calculated. If any valve, excluding the two replaced valves, now falls outside the acceptable limits, the tests shall be considered unsatisfactory. 2. The discharge capacity as determined by the test of each valve tested shall not vary by more than ±5% of the average capacity of the three valves tested. If one of the three valve tests falls outside of the limits, it may be replaced by two valves and a new average calculated based on all four valves, excluding the replaced valve. Notes 1. The maximum and minimum coefficient determined by the tests of a valve design shall not vary more than ±5% from the average. If one or more tests are outside the acceptable limits, one valve of the Manufacturer’s choice shall be replaced with another valve of the same size and pressure setting or by a modification of the original valve. Following this test a new average coefficient shall be calculated, excluding the replaced valve test. If one or more tests are now out- © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 95 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section IV – Heating Boiler Code (1995 Addenda) HG-402.4 Pressures at Which Capacity Tests Shall Be Conducted. Safety valves for steam boilers shall be tested for capacity at 5 psi over the set pressure for which the valve is set to operate. Capacity certification tests of safety relief valves for hot water heating and hot water supply boilers shall be conducted at 110% of the pressure for which the valve is set to operate. HG-402.5 Opening Tests of PressureTemperature Relief Valves. For the purpose of determining the set (opening) pressure, the test medium shall be room temperature water. The actual set pressure is defined as the pressure at the valve inlet when the flow rate through the valve is 40 cm3/min. Capacity tests shall be conducted with steam (see HG-402.7) at a pressure 10% above the actual water set pressure. For production capacity check tests, the rated capacity shall be based on the actual water set pressure. HG-402.6 Capacity Tests of PressureTemperature Relief Valves. For the purpose of determining the capacity of pressure-temperature relief valves, dummy elements of the same size and shape as the regularly applied thermal element shall be substituted and the relieving capacity shall be based on the pressure element only. Valves selected to meet the requirements of production testing, HG401.3, shall have their temperature elements deactivated by the Manufacturer prior to or at the time of capacity testing. HG-402.7 Fluid Medium for Capacity Tests. The tests shall be made with dry saturated steam. For test purposes the limits of 98% minimum quality and 20°F maximum superheat shall apply. Correction from within these limits may be made to the dry saturated condition. The relieving capacity shall be measured by condensing the steam or with a calibrated steam flowmeter. A. To determine the discharge capacity of safety relief valves in terms of BTU, the relieving capacity in pounds for steam per hour W is multiplied by 1000. A92 HG-402.8 Where and by Whom Capacity Tests Shall Be Conducted. A. Tests shall be conducted at a place where the testing facilities, methods, procedures, and person supervising the tests (Authorized Observer) meet the applicable requirements of ASME/ANSI PTC 25.3. The tests shall be made under the supervision of and certified by an Authorized Observer. The testing facilities, methods, procedures, and qualifications of the Authorized Observer shall be subject to the acceptance of ASME on recommendation of an ASME Designee. Acceptance of the testing facility is subject to review within each 5 year period. 2. Valve capacities are published in ‘Pressure Relief Device Certifications.’ This publication may be obtained from The National Board of Boiler and Pressure Vessel Inspectors, 1055 Crupper Avenue, Columbus, Ohio, 43229. HG-405 Thermal Elements for Pressure-Temperature Relief Valves The thermal elements for pressure-temperature relief valves shall be so designed and constructed that they will not fail in any manner which could obstruct flow passages or reduce capacities of the valves when the elements are subjected to steam temperatures.4 HG-512 Safety and Safety Relief Valve Accumulation Tests If the safety valve or safety relief valve capacity cannot be computed or if it is desirable to prove the computations, it may be checked in any one of the following ways and, if found insufficient, additional capacity shall be provided: B. Capacity test data reports for each valve model, type, and size, signed by the Manufacturer and the Authorized Observer witnessing the tests, shall be submitted to the ASME Designee for review and acceptance.1,2 A. by making an accumulation test, that is, by shutting off all discharge outlets from the boiler and forcing the fires to the maximum, the safety valve equipment shall be sufficient to prevent an excess pressure beyond that specified in HG-400.1(F) and HG-400.2(F); HG-402.9 Test Record Data Sheet. A data sheet for each valve shall be filled out and signed by the authorized observer witnessing the test. Such data sheet will be the manufacturer’s authority to build and stamp valves of corresponding design B. by measuring the maximum amount of fuel that can be burned, and computing the corresponding evaporative capacity upon the basis of the heating value of the fuel. (See B-100, B-101, and B102.) Notes 1. When changes are made in the design, capacity certification tests shall be repeated. and construction. When changes are made in the design of a safety or safety relief valve in such a manner as to affect the flow path, lift, or performance characteristics of the valve, new tests in accordance with this Section shall be performed.3 3. See HG-512 for safety and safety relief valve accumulation test requirements. See HG-701 for safety and safety relief valve installation requirements. 4. Since the temperature elements are designed for temperatures up to only 250°F, they will fail when subjected to steam pressures with corresponding saturation temperatures in excess of 250°F. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 96 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section IV – Heating Boiler Code (1995 Addenda) Installation Requirements A92 HG-700 Installation Requirements, All boilers HG-701.6 Safety and Safety Relief Valve Discharge Piping A. A discharge pipe shall be used. Its internal cross-sectional area shall be not less than the full area of the valve outlet or of the total of the valve outlets discharging thereinto and shall be as short and straight as possible and so arranged as to avoid undue stress on the valve or valves. A union may be installed in the discharge piping close to the valve outlet. When an elbow is placed on a safety or safety relief valve discharge pipe, it shall be located close to the valve outlet downstream of the union. HG-701 Mounting Safety and Safety Relief Valves HG-701.1 Permissible Mounting. Safety valves and safety relief valves shall be located in the top or side1 of the boiler. They shall be connected directly to a tapped or flanged opening in the boiler, to a fitting connected to the boiler by a short nipple, to a Y-base, or to a valveless header connecting steam or water outlets on the same boiler. Coil or header type boilers shall have the safety valve or safety relief valve located on the steam or hot water outlet end. Safety valves and safety relief valves shall be installed with their spindles vertical. The opening or connection between the boiler and any safety valve or safety relief valve shall have at least the area of the valve inlet. HG-701.2 Requirements for Common Connections for Two or More Valves A. When a boiler is fitted with two or more safety valves on one connection, this connection shall have a cross-sectional area not less than the combined areas of inlet connections of all the safety valves with which it connects. B. When a Y-base is used, the inlet area shall be not less than the combined outlet areas. When the size of the boiler requires a safety valve or safety relief valve larger than 41/2-inch in diameter, two or more valves having the required combined capacity shall be used. When two or more valves are used on a boiler, they may be single, directly attached, or mounted on a Y-base. HG-701.3 Threaded Connections. A threaded connection may be used for attaching a valve. B. The discharge from safety or safety relief valves shall be so arranged that there will be no danger of scalding attendants. The safety or safety relief valve discharge shall be piped away from the boiler to the point of discharge, and there shall be provisions made for properly draining the piping. The size and arrangement of discharge piping shall be independent of other discharge piping and shall be such that any pressure that may exist or develop will not reduce the relieving capacity of the relieving devices below that required to protect the boiler. Note 1. The top or side of the boiler shall mean the highest practicable part of the boiler proper but in no case shall the safety valve be located below the normal operating level and in no case shall the safety relief valve be located below the water level. HG-701.4 Prohibited Mountings. Safety and safety relief valves shall not be connected to an internal pipe in the boiler. HG-701.5 Use of Shutoff Valves Prohibited. No shutoff of any description shall be place between the safety or safety relief valve and the boiler, or on discharge pipes between such valves and the atmosphere. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 97 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section VIII – Division I (1995 Addenda) Pressure Relief Devices UG-125 General A. All vessels within the Scope of this Division, irrespective of size or pressure, shall be provided1 with protective devices in accordance with the requirements of UG-125 through UG-136. Unless otherwise defined in this Division, the definitions relating to pressure relief devices in Appendix I of ASME/ANSI PTC 25.3 Safety and Relief Valves shall apply. B. An unfired steam boiler, as defined in U-1(G), shall be equipped with pressure relief devices required by Section I insofar as they are applicable to the service of the particular installation. C. All pressure vessels other than unfired steam boilers shall be protected by a pressure relieving device that shall prevent the pressure from rising more than 10% or 3 psi, whichever is greater, above the maximum allowable working pressure except as permitted in (1) and (2) below. (See UG-134 for pressure settings.) 1. When multiple pressure relieving devices are provided and set in accordance with UG-134(A), they shall prevent the pressure from rising more than 16% or 4 psi, whichever is greater, above the maximum allowable working pressure. 2. Where an additional hazard can be created by exposure of a pressure vessel to fire or other unexpected sources of external heat, supplemental pressure relieving devices shall be installed to protect against excessive pressure. Such supplemental pressure relieving devices shall be capable of preventing the pressure from rising more than 21% above the maximum allowable working pressure. The same pressure relieving devices may be used to satisfy the capacity requirements of (C) or (C)(1) above and this paragraph provided the pressure setting requirements of UG-134(A) are met. 3. Pressure relief devices, intended primarily for protection against exposure of a pressure vessel to fire or other unexpected sources of external heat installed on vessels having no permanent supply connection and used for storage at ambient temperatures of nonrefrigerated liquefied compressed gases,2 are excluded from the requirements of (C)(1) and (C)(2) above, provided: (a) the relief devices are capable of preventing the pressure from rising more than 20% above the maximum allowable working pressure of the vessels; (b) the set pressure of these devices shall not exceed the maximum allowable pressure of the vessels; (c) the vessels have sufficient ullage to avoid a liquid full condition; (d)the maximum allowable working pressure of the vessels on which these devices are installed is greater than the vapor pressure of the stored liquefied compressed gas at the maximum anticipated temperature3 that the gas will reach under atmospheric conditions; and (e) pressure relief valves used to satisfy these provisions also comply with the requirements of UG-129(A)(5), UG-131(C)(2), and UG-134(D)(2). D. Pressure relieving devices shall be constructed, located, and installed so that they are readily accessible for inspection and repair and so that they cannot be readily rendered inoperative (see Appendix M), and should be selected on the basis of their intended service. E. Pressure relief valves or nonreclosing pressure relief devices4 may be used as protective devices. Nonreclosing pressure relief devices may be used either alone or, if applicable, in combination with safety or safety relief valves on vessels.5 F. Vessels that are to operate completely filled with liquid shall be equipped with liquid relief valves, unless otherwise protected against overpressure. G. The protective devices required in (A) above need not be installed directly on a pressure vessel when the source of pressure is external to the vessel and is under such positive control that the pressure in the vessel cannot exceed the maximum allowable working pressure at the operating temperature except as permitted in (C) above (see UG-98).6 H. Safety and safety relief valves for steam service shall meet the requirements of UG-131(B). UG-126 Pressure Relief Valves 7 A. Safety, safety relief, and relief valves shall be of the direct spring loaded type. Notes 1. Safety devices need not be provided by the vessel manufacturer, but overpressure protection shall be provided prior to placing the vessel in service. 2. For the purpose of these rules, gases are considered to be substances having a vapor pressure greater than 40 psia at 100°F. 3. Normally this temperature should not be less than 115°F. 4. A pressure relief valve is a pressure relief device which is designed to reclose and prevent the further flow of fluid after normal conditions have been restored. A nonreclosing pressure relief device is a pressure relief device designed to remain open after operation. 5. Use of nonreclosing devices of some types may be advisable on vessels containing substances that may render a safety or safety relief valve inoperative, where a loss of valuable material by leakage should be avoided, or where contamination of the atmosphere by leakage of noxious fluids must be avoided. The use of rupture disc devices may also be advisable when very rapid rates of pressure rise may be encountered. 6. Pressure reducing valves and similar mechanical or electrical control instruments, except for pilot operated valves as permitted in UG-126(B), are not considered as sufficiently positive in action to prevent excess pressures from being developed. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 98 7. A safety valve is a pressure relief valve actuated by inlet static pressure and characterized by rapid opening or pop action. A relief valve is a pressure relief valve actuated by inlet static pressure which opens in proportion to the increase in pressure over the opening pressure. A safety relief valve is a pressure relief valve characterized by rapid opening or pop action, or by opening in proportion to the increase in pressure over the opening pressure, depending on application. A pilot operated pressure relief valve is a pressure relief valve in which the major relieving device is combined with and is controlled by a self-actuated auxiliary pressure relief valve. Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section VIII – Division I (1995 Addenda) B. Pilot operated pressure relief valves may be used, provided that the pilot is self-actuated and the main valve will open automatically at not over the set pressure and will discharge its full rated capacity if some essential part of the pilot should fail. C. The spring in a safety valve or safety relief valve shall not be set for any pressure more than 5% above or below that for which the valve is marked, unless the setting is within the spring design range established by the valve manufacturer or is determined to be acceptable to the manufacturer. The initial adjustment shall be performed by the manufacturer, his authorized representative, or an assembler, and a valve data tag shall be provided that identifies the set pressure capacity and date. The valve shall be sealed with a seal identifying the manufacturer, his authorized representative, or the assembler performing the adjustment. D. The set pressure tolerance, plus or minus, of pressure relief valves shall not exceed 2 psi for pressures up to and including 70 psi and 3% for pressures above 70 psi. UG-127 Nonreclosing Pressure Relief Devices A. Rupture Disk Devices 8 1. General (a) Every rupture disk shall have stamped burst pressure established by rules of (A)(1)(b) below with a manufacturing design range9 at a specified disk temperature10 and shall be marked with a lot number. The burst pressure tolerance at the specific disk temperature shall not exceed ±2 psi for stamped burst pressure up to and including 40 psi and ±5% for stamped burst pressure above 40 psi. (b) The stamped bursting pressure within the manufacturing design range at the coincident disk temperature shall be derived by one of the following methods. All the tests of disks for a given lot shall be made in a holder of the same form and dimensions as that with which the disk is to be used. (1) At least two sample rupture disks from each lot of rupture disks, made from the same materials and of the same size as those to be used, shall be burst to verify that the stamped bursting pressure falls within the manufacturing design range at the coincident disk temperature. At least one disk shall be burst at room temperature. The stamped rating at specified disk temperature shall be the average of the bursts at coincident disk temperature. (2) At least four sample rupture disks, but not less than 5%, from each lot of rupture disks, made from the same material and of the same size as those to be used, shall be burst at four different temperatures, distributed over the applicable temperature range for which the disk will be used. These data shall be used to establish a curve of bursting pressure versus temperature for the lot of disks. The stamped rating at the coincident disk temperature shall be interpolated from this curve. (3) For prebulged, solid metal disks or graphite disks only, a curve of percentage ratio at temperatures other than ambient may be establish as in (2) above, using one size of disk for each lot of material. At least four bursts at four different temperatures shall be used to establish the above curve over the applicable temperature range. At least two disks from each lot of disks, made from this lot of material and of the same size as those to be used, shall be burst at ambient temperature to establish the room temperature rating of the lot of disks. The percent change of bursting pressure taken from the above curve shall be used to establish the stamped rating at the coincident disk temperature for the lot of disks. 2. Capacity Rating (a) The calculated capacity rating of a rupture disk device shall not exceed a value based on the applicable theoretical formula (UG-131) for the various media multiplied by K = coefficient = 0.62. The area A (square inches) in the theoretical formula shall be the minimum net area existing after disk burst.11,12 (b) In lieu of the method of capacity rating in (a) above, a Manufacturer may have the capacity of a given rupture disk Notes 8. A rupture disc device is a nonreclosing pressure relief device actuated by inlet static pressure and designed to function by the bursting of a pressure containing disc. A rupture disc is the pressure containing and pressure sensitive element of a rupture disc device. A rupture disc holder is the structure which encloses and clamps the rupture disc in position. Rupture discs may be designed in several configurations, such as plain flat, prebulged or reverse buckling, and may be made of either ductile or brittle material; rupture disc material is not required to conform to an ASME specification. The material of the rupture disc holder shall be listed in Section II and be permitted for use in this Division. 9. The manufacturing design range is a range of pressure within which the average burst pressure of test discs must fall to be acceptable for a particular requirement as agreed upon between the rupture disc Manufacturer and the user or his agent. The disc shall be marked at the average burst pressure of all test discs. 10. The specified disc temperature supplied to the rupture disc Manufacturer shall be the temperature of the disc when the disc is expected to burst. 11. The minimum net flow area is the calculated net area after a complete burst of the disc with appropriate allowance for any structural members which may reduce the net flow area through the rupture disc device. The net flow area for sizing purposes shall not exceed the nominal pipe size area of the rupture disc device. 12. When rupture disc devices are used, it is recommended that the design pressure of the vessel be sufficiently above the intended operating pressure to provide sufficient margin between operating pressure and rupture disc due to fatigue or creep. Application of rupture disc devices to liquid service should be carefully evaluated to assure that the design of the rupture disc device and the dynamic energy of the system on which it is installed will result in sufficient opening of the rupture disc. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 99 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section VIII – Division I (1995 Addenda) device design determined for the KD coefficient in general accordance with the procedures of UG-131, as applicable. 3. Application of Rupture Disks (a) A rupture disk device may be used as the sole pressure relieving device on a vessel. (b) A rupture disk device may be installed between a pressure relief valve13 and the vessel provided: (1) the combination of the spring loaded safety or safety relief valve and the rupture disk device is ample in capacity to meet the requirements of UG-133(A) and (B); (2) the stamped capacity of a spring loaded safety or safety relief valve (nozzle type) when installed with a rupture disk device between the inlet of the valve and the vessel shall be multiplied by a factor of 0.90 of the rated relieving capacity of the valve alone, or alternatively, the capacity of such a combination shall be established in accordance with (3) below; (3) the capacity of the combination of the rupture disk device and the spring loaded safety or safety relief valve may be established in accordance with the appropriate paragraphs of UG-132, Certification of Capacity of Safety and Safety Relief Valves in Combination with nonreclosing Pressure Relief Devices; (4) the space between a rupture disk device and a safety or safety relief valve shall be provided with a pressure gauge, a try cock, free vent, or suitable telltale indicator. This arrangement permits detection of disk rupture or leakage.14 (5) the opening12 provided through the rupture disk, after burst, is sufficient to permit a flow equal to the capacity of the valve [(2) and (3) above], and there is no chance of interference with proper functioning of the valve; but in no case shall this area be less than the area of the inlet of the valve unless the capacity and functioning of the specific combination of rupture disk and valve have been established by test in accordance with UG-132. (c) A rupture disk device may be installed on the outlet side15 of a spring loaded safety relief valve which is opened by direct action of the pressure in the vessel provided: (1) the valve is so designed that it will not fail to open at its proper pressure setting regardless of any back pressure that can accumulate between the valve disk and the rupture disk. The space between the value disk and the rupture disk shall be vented or drained to prevent accumulation of pressure due to a small amount of leakage from the valve.16 stamped bursting pressure of the rupture disk at the coincident operating temperature plus any pressure in the outlet piping exceed the maximum allowable working pressure of the vessel or the set pressure of the safety or safety relief valve. (4) the opening provided through the rupture disk device after breakage is sufficient to permit a flow equal to the rated capacity of the attached safety or safety relief valve without exceeding the allowable overpressure; (5) any piping beyond the rupture disk cannot be obstructed by the rupture disk or fragment; (6) the contents of the vessel are clean fluids, free from gumming or clogging matter, so that accumulation in the space between the valve inlet and the rupture disk (or in any other outlet that may be provided) will not clog the outlet; (7) the bonnet of the safety relief valve shall be vented to prevent accumulation of pressure. B. Breaking Pin Device 17 (2) the valve is ample in capacity to meet the requirements of UG-133(A) and (B); 1. Breaking pin devices shall not be used as single devices but only in combination between the safety or safety relief valve and the vessel. (3) the stamped bursting pressure of the rupture disk at the coincident disk temperature plus any pressure in the outlet piping shall not exceed the design pressure of the outlet portion of the safety or safety relief valve and any pipe or fitting between the valve and the rupture disk device. However, in no case shall the 2. The space between a breaking pin device and a safety or safety relief valve shall be provided with a pressure gauge, a try cock, a free vent, or suitable telltale indicator. This arrangement permits detection of breaking pin device operation or leakage. Notes 13. Use of a rupture disc device in combination with a safety relief valve shall be carefully evaluated to ensure that the media being handled and the valve operational characteristics will result in pop action of the valve coincident with the bursting of the rupture disc. 14. Users are warned that a rupture disc will not burst at its design pressure if back pressure builds up in the space between the disc and the safety or safety relief valve which will occur should leakage develop in the rupture disc due to corrosion or other cause. 15. This use of a rupture disc device in series with the safety or safety relief valve is per- mitted to minimize the loss by leakage through the valve of valuable or of noxious or otherwise hazardous materials, and where a rupture disc alone or disc located on the inlet side of the valve is impracticable, or to prevent corrosive gases from a common discharge line from reaching the valve internals. 16. Users are warned that an ordinary spring loaded safety relief valve will not open at its set pressure if back pressure builds up in the space between the valve and rupture disc. A specially designed valve is required, such as a diaphragm valve or a valve equipped with a bellows above the disc. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 100 17. A breaking pin device is a nonreclosing pressure relief device actuated by inlet static pressure and designed to function by the breakage of a load-carrying section of a pin which supports a pressure containing member. A breaking pin is the load-carrying element of a breaking pin device. A breaking pin housing is the structure which encloses the breaking pin mechanism. The material of the housing shall be listed in Section II and be permitted for use in this Division. Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section VIII – Division I (1995 Addenda) 2. Manufacturer’s design or type number; 3. Each breaking pin device shall have a rated pressure and temperature at which the pin will break. The breaking pin shall be identified to a lot number and shall be guaranteed by the Manufacturer to break when the rated pressure, within the following tolerances, is applied to the device: Rated Pressure, psi Minimum Maximum Tolerance, Plus or Minus, psi 30 150 5 151 275 10 276 375 15 4. The rated pressure of the breaking pin plus the tolerance in psi shall not exceed 105% of the maximum allowable working pressure of the vessel to which it is applied. 5. The rated pressure at the coincident operating temperature18 shall be verified by breaking two or more sample breaking pins from each lot of the same material and the same size as those to be used. The lot size shall not exceed 25. The test shall be made in a device of the same form and pressure dimensions as that in which the breaking pin is to be used. C. Spring Loaded Nonreclosing Pressure Relief Device 1. A spring loaded nonreclosing pressure relief device, pressure actuated by means which permit the spring loaded portion of the device to open at the specified set pressure and remain open until manually reset, may be used provided the design of the spring loaded nonreclosing device will achieve full opening at or below its set pressure. Such a device may not be used in combination with any other pressure relief device. The tolerance on opening point shall not exceed ±5%. 3. NPS size _______ (the nominal pipe size of the valve inlet); 4. set pressure ________ psi; 5. certified capacity (as applicable); Figure UG-129 Official Symbol for Stamp to denote the American Society of Mechanical Engineers’ Standard 2. The calculated capacity rating of a spring loaded nonreclosing pressure relief device shall not exceed a value based on the applicable theoretical formula (see UG-131) for the various media, multiplied by: K = coefficient = 0.62. The area A (square inches) in the theoretical formula shall be the flow area through the minimum opening of the nonreclosing pressure relief device. 3. In lieu of the method of capacity rating (2) above, a Manufacturer may have the capacity of a spring loaded nonreclosing pressure relief device design certified in general accordance with the procedures of UG-131, as applicable. UG-128 Liquid Relief Valve Any liquid relief valve used shall be at least NPS 1/2. UG-129 Marking A. Safety, Safety Relief, Liquid Relief, and Pilot Operated Pressure Relief Valves. Each safety, safety relief, liquid relief and pilot operated valve NPS 1/2 and larger shall be plainly marked by the manufacturer or assembler with the required data in such a way that the marking may be placed on the valve or on a plate or plates that satisfy the requirements of UG-119: 1. the name, or an acceptable abbreviation, of Manufacturer and the Assembler; (a) lb/hr of saturated steam at an overpressure of 10% or 3 psi, whichever is greater for valves certified on steam complying with UG-131(B); or (b) gal/min of water at 70°F at an overpressure of 10% or 3 psi, whichever is greater for valves certified on water; or (c) SCFM (standard cubic feet per minute at 60°F and 14.7 psia), or lb/min, of air at an overpressure of 10% or 3 psi, whichever is greater. Valves that are capacity certified in accordance with UG-131(C)(2) shall be marked ‘at 20% overpressure.’ (d) In addition to one of the fluids specified above, the Manufacturer may indicate the capacity in other fluids (see Appendix 11). 6. year built, or alternatively, a coding may be marked on the valve such that the valve Manufacturer or Assembler can identify the year the valve was assembled or tested; 7. ASME Symbol as shown in Fig. UG129. The pilot of a pilot operated pressure relief valve shall be plainly marked by the Manufacturer or Assembler showing the name of the Manufacturer; the Manufacturer’s design or the type number, the set pressure in pounds per square inch, and the year built, or alternately a coding that the Manufacturer can use to identify the year built. On valves smaller than NPS 1/2, the markings may be made on a metal tag attached by wire or adhesive meeting the requirements of UG-119 or other means suitable for the service conditions. Notes 18. The specified temperature supplied to the breaking pin manufacturer shall be the temperature of the breaking pin when an emergency condition exists and the pin is expected to break. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 101 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section VIII – Division I (1995 Addenda) B. Safety and safety relief valves certified for a steam discharging capacity under the provisions of Section I and bearing the official Code Symbol Stamp of Section I for safety valves may be used on pressure vessels. The rated capacity in term of other fluids shall be determined by the method of conversion given in Appendix 11. [See UG-131(H).] C. Pressure Relief Valves in Combination With Rupture Disk Devices. Pressure relief valves in combination with rupture disk devices shall be marked with the capacity as established in accordance with UG-127(A)(3)(b)(2) (using 0.90 factor) or the combination capacity factor established by test in accordance with UG-132(A) or (B), in addition to the marking of UG-129(A) and (F) below. The marking may be placed on the valve or rupture disk device or on a plate or plates that satisfy the requirements of UG-119 or rupture disk device. The marking shall include the following: 1. name of Manufacturer of valve; 2. design or type number of valve; 3. name of Manufacturer of rupture disk device; 4. design or type number of rupture disk device; 5. capacity or combination capacity factor; 6. name of organization responsible for this marking. This shall be either the vessel user, vessel Manufacturer, rupture disk Manufacturer, or pressure relief valve Manufacturer. D. Pressure Relief Valves in Combination With Breaking Pin Devices. Pressure relief valves in combination with breaking pin devices shall be marked in accordance with (A) above. In addition, the rated pressure shall be marked on the breaking pin and the breaking pin housing. E. Rupture Disk Devices. Every rupture disk shall be plainly marked by the Manufacturer in such a way that the marking will not be obliterated in service. The rupture disk marking may be placed on the flange of the disk or on a metal tab that satisfies the requirements of UG-119. The marking shall include the following: 1. the name or identifying trademark of the Manufacturer; 2. Manufacturer’s design or type number; 3. lot number; 4. disk material; 5. size ________ (NPS designator at valve inlet); 6. stamped bursting pressure _____ psi; 7. coincident disk temperature _____°F; 8. capacity _______ lb of saturated steam/hr, or _______ cu ft of air/min (60°F and 14.7 psia).19 Items (1), (2), and (5) above shall also be marked on the rupture disk holder. F. Spring Loaded nonreclosing Pressure Relief Devices. Spring loaded nonreclosing pressure relief devices shall be marked in accordance with (A) above except that the Code Symbol Stamp is to be applied only when the capacity has been established and certified in accordance with UG-127(C)(3) and all other requirements of UG-130 have been met. UG-130 Use of Code Symbol Stamp Each pressure relief valve 20 to which the Code Symbol (see Fig. UG-129) will be applied shall have been fabricated or assembled by a Manufacturer or Assembler holding a valid Certificate of Authorization (UG-117) and capacity certified in accordance with the requirements of this Division. Notes 19. In addition, the Manufacturer may indicate the capacity in other fluids (see Appendix 11). 20. Vacuum relief valves are not covered by Code Symbol Stamp requirements. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 102 UG-131 Certification of Capacity of Pressure Relief Valves A. Before the Code Symbol is applied to any pressure relief valve, the valve Manufacturer shall have the capacity of his valves certified in accordance with provisions of this paragraph. B. 1. Capacity certification tests for pressure relief valves for compressible fluids shall be conducted on dry saturated steam, or air, or natural gas. When dry saturated steam is used, the limits for test purposes shall be 98% minimum quality and 20°F maximum superheat. Correction from within these limits may be made to the dry saturated condition. Valves for steam service may be rated as above, but at least one valve of each series shall be tested on steam to demonstrate the steam capacity and performance. 2. Capacity certification tests for pressure relief valves for incompressible fluids shall be conducted on water at a temperature between 40°F and 125°F. C. 1. Capacity certification tests shall be conducted at a pressure which does not exceed the pressure for which the pressure relief valve is set to operate by more than 10% or 3 psi, whichever is greater, except as provided in (C)(2) below. Minimum pressure for capacity certification tests shall be at least 3 psi above set pressure. The reseating pressure shall be noted and recorded. 2. Capacity certification tests of pressure relief valves for use in accordance with UG-125(C)(3) may be conducted at a pressure not to exceed 120% of the stamped set pressure of the valve. 3. (a) Pressure relief valves for compressible fluids having an adjustable blowdown construction shall be adjusted prior to testing so that the blowdown does not exceed 5% of the set pressure or 3 psi, whichever is greater. Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section VIII – Division I (1995 Addenda) (b) The blowdown of pressure relief valves for incompressible fluids and pressure relief valves for compressible fluids having nonadjustable blowdown shall be noted and recorded. 4. Capacity certification of pilot operated pressure relief valves may be based on tests without the pilot valve installed, provided prior to capacity tests it has been demonstrated by test to the satisfaction of the Authorized Observer that the pilot valve will cause the main valve to open fully at a pressure which does not exceed the set pressure by more than 10% or 3 psi, whichever is greater, and that the pilot valve in combination with the main valve will meet all the requirements of this Division. D. 1. A capacity certification test is required on a set of three valves for each combination of size, design, and pressure setting. The stamped capacity rating for each combination of design, size, and test pressure shall not exceed 90% of the average capacity of the three valves tested. The capacity for each set of three valves shall fall within a range of ±5% of the average capacity. Failure to meet this requirement shall be cause to refuse certification of that particular safety valve design. 2. If a Manufacturer wishes to apply the Code Symbol to a design of pressure relief valves, four valves of each combination of pipe size and orifice size shall be tested. These four valves shall be set at pressures which cover the approximate range of pressures for which the valve will be used or covering the range available at the certified test facility that shall conduct the tests. The capacities based on these four tests shall be as follows: (a) For compressible fluids, the slope W/P of the actual measured capacity versus the flow pressure for each test point shall be calculated and averaged: W measured capacity slope = ––– = –––––––––––––––––––––– P absolute flow pressure, psia All values derived from the testing must fall within ±5% of the average value: minimum slope = 0.95 x average slope maximum slope = 1.05 x average slope If the values derived from the testing do not fall between the minimum and maximum slope values, the Authorized Observer shall require that additional valves be tested at the rate of two for each valve beyond the maximum and minimum values with a limit of four additional valves. The relieving capacity to be stamped on the valve shall not exceed 90% of the average slope times the absolute accumulation pressure: rated slope = 0.90 x average slope stamped capacity ≤ rated slope (1.10 x set pressure + 14.7) or (set pressure + 3 psi + 14.7), whichever is greater For valves certified in accordance with (C)(2) above, stamped capacity ≤ rated slope (1.20 x set pressure + 14.7) or (set pressure + 3 psi + 14.7), whichever is greater nus discharge pressure) test pressure and a straight line drawn through these four points. If the four points do not establish a straight line, two additional valves shall be tested for each unsatisfactory point, with a limit of two unsatisfactory points. Any point that departs from the straight line by more than 5% should be considered an unsatisfactory point. The relieving capacity shall be determined from this line. The certified capacity shall not exceed 90% of the capacity taken from the line. E. Instead of individual capacity certification as provided in (D) above, a coefficient of discharge K may be established for specific safety valve design according to the following procedure. 1. For each design, the pressure relief valve manufacturer shall submit for test at least three valves for each of three different sizes (a total of nine valves) together with detailed drawings showing the valve construction. Each valve of a given size shall be set at a different pressure. 2. Tests shall be made on each pressure or relief valve to determine its capacity-lift, popping and blowdown pressures, and actual capacity in terms of the fluid used in the test. A coefficient KD shall be established for each test run as follows: KD = Actual flow Theoretical flow coefficient = of discharge (b) For incompressible fluids, the capacities shall be plotted on log-log paper against the differential (inlet mi- © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 103 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section VIII – Division I (1995 Addenda) where actual flow is determined quantitatively by test, and theoretical flow is calculated by the appropriate formula which follows: For tests with dry saturated steam,21 WT = 51.5 AP For tests with air, WT = 356 AP ––––– M ––– T √ For tests with natural gas, ––––– M WT = CAP ––– ZT √ For tests with water, ––––––––– WT = 2407A √ (P-Pd)w where: WT = theoretical flow, lb/hr A = actual discharge area through the valve at developed lift, in2 P = (set pressure x 1.10) plus atmosphere, psia, or set pressure plus atmospheric pressure plus 3 psi, whichever is greater Pd = pressure at discharge from valve, psia M = molecular weight T = absolute temperature at inlet, °F + 460°F C = constant for gas or vapor based on the ratio of specific heats k = Cp /Cv (see Fig.11-1, pg.99) Z = compressibility factor corresponding to P and T w = specific weight of water at valve inlet conditions The average of the coefficients KD of the nine tests required shall be multiplied by 0.90, and this product shall be taken as the coefficient K of that design. The coefficient of the design shall not be greater than 0.878 (the product of 0.9 x 0.975).22 To convert lb/hr of water to gal/min of water, multiply the capacity in lb/hr by 1/500. 3. The official relieving capacity of all sizes and pressures of given design, for which K has been established under the provisions of (E)(2) above, that are manufactured subsequently shall not exceed the value calculated by the appropriate formula in (E)(2) above multiplied by the coefficient K (see Appendix 11). 4. The coefficient shall not be applied to valves whose beta ratio (ratio of valve throat to inlet diameter) lies outside the range of 0.15 to 0.75, unless tests have demonstrated that the individual coefficient of discharge KD for valves at the extreme ends of a larger range is within ±5% of the average coefficient K. For designs where the lift is used to determine the flow area, all valves shall have the same nominal lift-to-seat diameter ratio (L/D). F. Tests shall be conducted at a place where the testing facilities, methods, procedures, and person supervising the tests (Authorized Observer) meet the applicable requirements of ASME/ANSI PTC 25.3. The tests shall be made under the supervision of and certified by an Authorized Observer. The testing facilities, methods, procedures, and qualifications of the Authorized Observer shall be subject to the acceptance of the ASME on recommendation of an ASME Designee. Acceptance of the testing facility is subject to review within each 5 year period. review and acceptance.23 Where changes are made in the design, capacity certification tests shall be repeated. H. For absolute pressures up to 1500 psia, it is permissible to rate safety valves under PG-69.1.2 of Section I with capacity ratings at a flow pressure of 103% of the set pressure, for use on pressure vessels, without further test. In such instances, the capacity rating of the valve may be increased to allow for the flow pressure permitted in (C)(1) and (C)(3) above, namely, 110% of the set pressure, by the multiplier: 1.10p + 14.7 1.03p + 14.7 where: p = set pressure, psi Such valves shall be marked in accordance with UG-129. This multiplier shall not be used as a divisor to transform test ratings from a higher to a lower flow. For steam pressures above 1500 psi, the above multiplier is not acceptable. For steam valves with relieving pressures between 1500 psi and 3200 psi, the capacity shall be determined by using the equation for steam and the correction factor for high pressure steam in (E)(2) above with the permitted absolute relieving pressure (1.10p + 14.7) and the coefficient K for that valve design. I. Rating of nozzle type pressure relief valves, i.e., coefficient KD, greater than 0.90 and nozzle construction, for saturated water shall be according to 11-2. G. Capacity test data reports for each valve model, type, and size, signed by the manufacturer and the Authorized Observer witnessing the tests shall be submitted to the ASME Designee for J. When changes are made in the design of a pressure relief valve in such a manner as to affect the flow path, lift, or performance characteristics of the valve, new tests in accordance with this Division shall be performed. 22. All experimentally determined coefficients KD shall fall within a range of ±5% of the average KD found. Failure to meet this requirement shall be cause to refuse certification of that particular valve design. 23. Valve capacities are published in ‘Pressure Relief Device Certification.’ This publication may be obtained from the National Board of Boiler and Pressure Vessel Inspectors, 1055 Crupper Avenue, Columbus, Ohio 43229. Notes 21. For dry saturated steam pressures over 1500 psig and up to 3200 psig, the value of WT, calculated by the above equation, shall be corrected by being multiplied by the following factors: ( ) 0.1906P –1000 0.2292P –1061 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 104 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section VIII – Division I (1995 Addenda) UG-132 Certification of Capacity of Safety Relief Valves in Combination with Nonreclosing Pressure Relief Devices A. Capacity of Safety or Safety Relief Valves in Combination With a Rupture Disk Device at the Inlet 1. For each combination of safety or safety relief valve design and rupture disk device design, the safety valve manufacturer or the rupture disk device manufacturer may have the capacity of the combination certified as prescribed in (3) and (4) below. 2. Capacity certification tests shall be conducted on saturated steam, air or natural gas. When saturated steam is used, corrections for moisture content of the steam shall be made. 3. The valve manufacturer or the rupture disk device manufacturer may submit for tests the smallest rupture disk device size with the equivalent size of safety or safety relief valve that is intended to be used as a combination device. The safety or safety relief valve to be tested shall have the largest orifice used in the particular inlet size. 4. Tests may be performed in accordance with the following subparagraphs. The rupture disk device and safety or safety relief valve combination to be tested shall be arranged to duplicate the combination assembly design. (a) The test shall embody the minimum burst pressure of the rupture disk device design which is to be used in combination with safety or safety relief valve design. The stamped bursting pressure shall be between 90% and 100% of the stamped set pressure of the valve. (b) The test procedure to be used shall be as follows. The safety or safety relief valve (one valve) shall be tested for capacity as an individual valve, without the rupture disk device at a pressure 10% above the valve set pressure. The rupture disk device shall then be installed ahead of the safety or safety relief valve and the disk burst to operate the valve. The capacity test shall be performed on the combination at 10% above the valve set pressure duplicating the individual safety or safety relief valve capacity test. (c) Tests shall be repeated with two additional rupture disks of the same nominal rating for a total of three rupture disks to be tested with the single valve. The results of the test capacity shall fall within a range of 10% of the average capacity of the three tests. Failure to meet this requirement shall be cause to require retest for determination of cause of the discrepancies. (d) From the results of the tests, a Combination Capacity Factor shall be determined. The Combination Capacity Factor is the ratio of the average capacity determined by the combination tests to the capacity determined on the individual valve. The Combination Capacity Factor shall be used as a multiplier to make appropriate changes in the ASME rated relieving capacity of the safety or safety relief valve in all sizes of the design. The value of the Combination Capacity Factor shall not be greater than one. The Combination Capacity Factor shall apply only to combinations of the same design of safety or safety relief valve and the same design of rupture disk device as those tested. (e) The test laboratory shall submit the test results to the ASME Designee for acceptance of the Combination Capacity Factor. B. Optional Testing of Rupture Disk Devices and Safety or Safety Relief Valves 1. If desired, a valve manufacturer or a rupture disk manufacturer may conduct tests in the same manner as outlined in (A)(4)(c) and (A)(4)(d) above using the next two larger sizes of the design of rupture disk device and safety or safety relief valve to determine a Combination Capacity Factor applicable to larger sizes. If a greater Combination Capacity Factor is established and can be certified, it may be used for all larger sizes of the combination, but shall not be greater than one. 2. If desired, additional tests may be conducted at higher pressures in accordance with (A)(4)(c) and (A)(4)(d) above to establish a maximum Combination Capacity Factor to be used at all pressures higher than the highest tested, but shall not be greater than one. C. Capacity of Breaking Pin Devices in Combination With Safety Relief Valves 1. Breaking pin devices in combination with safety relief valves shall be capacity tested in compliance with UG-131(D) or UG-131(E) as a combination. 2. Capacity certification and Code Symbol stamping shall be based on the capacity established in accordance with these paragraphs. UG-133 Determination of Pressure Relieving Requirements A. Except as permitted in (B) below, the aggregate capacity of the pressure relieving devices connected to any vessel or system of vessels for the release of a liquid, air, steam, or other vapor shall be sufficient to carry off the maximum quantity that can be generated or supplied to the attached equipment without permitting a rise in pressure within the vessel of more than 16% above the maximum allowable working pressure when the pressure relieving devices are blowing. B. Protective devices as permitted in UG125(C)(2), as protection against excessive pressure caused by exposure to fire or other sources of external heat, shall have a relieving capacity sufficient to prevent the pressure from rising more than 21% above the maximum allowable working pressure of the vessel when all pressure relieving devices are blowing. C. Vessels connected together by a system of adequate piping not containing valves which can isolate any vessel may be considered as one unit in figuring the required relieving capacity of © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 105 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section VIII – Division I (1995 Addenda) pressure relieving safety devices to be furnished. D. Heat exchangers and similar vessels shall be protected with a relieving device of sufficient capacity to avoid overpressure in case of an internal failure. E. The official rated capacity of a pressure relieving safety device shall be that which is stamped on the device and guaranteed by the manufacturer. F. The rated pressure relieving capacity of a pressure relief valve for other than steam or air shall be determined by the method of conversion given in Appendix 11. G. To prorate the relieving capacity at any relieving pressure greater than 1.10p, as permitted under UG-125, a multiplier may be applied to the official relieving capacity of a pressure relieving device as follows: P + 14.7 1.10p + 14.7 where: P = relieving pressure, psi p = set pressure, psi For steam pressures above 1500 psi, the above multiplier is not acceptable. For steam valves with relieving pressures greater than 1500 psi and less than or equal to 3200 psi, the capacity at relieving pressures greater than 1.10p shall be determined using the equation for steam and the correction factor for high pressure steam in UG131 (E)(2) with the permitted absolute relieving pressure and the coefficient K for that valve design. UG-134 Pressure Setting of Pressure Relief Devices A. When a single pressure relieving device is used, it shall be set to operate 24 at a pressure not exceeding the maximum allowable working pressure of the vessel. When the required capacity is provided in more than one pressure relieving device, only one device need be set at or below the maximum allowable working pressure, and the additional devices may be set to open at higher pressures but in no case at a pressure higher than 105% of the maximum allowable working pressure, except as provided in (B) below. B. Protective devices permitted in UG125(C)(2) as protection against excessive pressure caused by exposure to fire or other sources of external heat shall be set to operate at a pressure not in excess of 110% of the maximum allowable working pressure of the vessel. If such a device is used to meet the requirements of both UG125(C) and UG-125(C)(2), it shall be set to operate at not over the maximum allowable working pressure. C. The pressure at which any device is set to operate shall include the effects of static head and constant back pressure. D. 1. The set pressure tolerance for pressure relief valves shall not exceed ±2 psi for pressures up to and including 70 psi and ±3% for pressures above 70 psi, except as covered in (D)(2) below. 2.The set pressure tolerance of pressure relief valves which comply with UG125(C)(3) shall be within -0%, +10%. UG-135 Installation A. Pressure relief devices for vapor application shall be connected to the vessel in the vapor space above any contained liquid or to piping connected to the vapor space in the vessel which is to be protected. B. The opening through all pipe and fittings between a pressure vessel and its pressure relieving device shall have at least the area of the pressure relieving device inlet, and the flow characteristics of this upstream system shall be such that the pressure drop will not reduce the relieving capacity below that required or adversely affect the proper operation of the pressure relieving device. The opening in the vessel wall shall be designed to provide direct and unobstructed flow between the vessel © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 106 and its pressure relieving device. (See Appendix M.) C. When two or more required pressure relieving devices are placed on one connection, the inlet internal cross-sectional area of this connection shall be either sized to avoid restricting flow to the pressure relief devices or made at least equal to the combined inlet areas of the safety devices connected to it. The flow characteristics of the upstream system shall satisfy the requirements of (B) above. (See Appendix M.) D. Pressure relief devices for liquid service applications shall be connected below the normal liquid level. E. There shall be no intervening stop valves between the vessel and its protective device or devices, or between the protective device or devices and the point of discharge, except: 1. when these stop valves are so constructed or positively controlled that the closing of the maximum number of block valves possible at one time will not reduce the pressure relieving capacity provided by the unaffected relieving devices below the required relieving capacity; or 2. under conditions set forth in Appendix M. F. The safety devices on all vessels shall be so installed that their proper functioning will not be hindered by the nature of the vessel’s contents. G. Discharge lines from pressure relieving safety devices shall be designed to facilitate drainage or shall be fitted with drains to prevent liquid from lodging in the discharge side of the safety device, and such lines shall lead to a safe place of discharge. The size of the discharge lines shall be such that any pressure that may exist or develop will not reduce the relieving capacity of the Notes 24. Set to operate means the set pressure of a pressure relief valve or a spring loaded nonreclosing device; the bursting pressure of a rupture disc device; or, the breaking pressure of a breaking pin device. Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section VIII – Division I (1995 Addenda) relieving devices below that required to properly protect the vessel. [See UG136(A)(8) and Appendix M.] UG-136 Minimum Requirements for Pressure Relief Valves A. Mechanical Requirements 1. The design shall incorporate guiding arrangements necessary to ensure consistent operation and tightness. 2. The spring shall be designed so that the full lift spring compression shall be no greater than 80% of the nominal solid deflection. The permanent set of the spring (defined as the difference between the free height and height measured 10 min after the spring has been compressed solid three additional times after presetting at room temperature) shall not exceed 0.5% of the free height. 3. Each pressure relief valve on air, water over 140°F, or steam service shall have a substantial lifting device which when activated will release the seating force on the disk when the valve is subjected to a pressure of at least 75% of the set pressure of the valve. Pilot operated pressure relief valves used on these services shall be provided with either a lifting device as described above or means for connecting and applying pressure to the pilot adequate to verify that the moving parts critical to proper operation are free to move. 4. The seat of a pressure relief valve shall be fastened to the body of the valve in such a way that there is no possibility of the seat lifting. 5. In the design of the body of the valve, consideration shall be given to minimizing the effects of deposits. 6. Valves having screwed inlet or outlet connections shall be provided with wrenching surfaces to allow for normal installation without damaging operating parts. 7. Means shall be provided in the design of all valves for use under this Division for sealing all initial adjustments which can be made without disassembly of the valve. Seals shall be installed by the manufacturer or assembler at the time of initial adjustment. Seals shall be installed in a manner to prevent changing the adjustment without breaking the seal. For valves larger than NPS 1/2, the seal shall serve as a means of identifying the manufacturer or assembler making the initial adjustment. 8. If the design of a pressure relief valve is such that liquid can collect on the discharge side of the disk, the valve shall be equipped with a drain at the lowest point where liquid can collect (for installation, see UG-135). 9. For pressure relief valves of the diaphragm type, the space above the diaphragm shall be vented to prevent a buildup of pressure above the diaphragm. Pressure relief valves of the diaphragm type shall be designed so that failure or deterioration of the diaphragm material will not impair the ability of the valve to relieve at the rated capacity. B. Material Selections 1. Cast iron seats and disks are not permitted. 2. Adjacent sliding surfaces such as guides and disks or disk holders shall both be of corrosion resistant material. Springs of corrosion resistant material or having a corrosion resistant coating are required. The seats and disks of pressure relief valves shall be of suitable material to resist corrosion by the fluid to be contained.25 3. Materials used in bodies and bonnets or yokes shall be listed in Section Il and this Division. Carbon and low alloy steel bodies, bonnets, yokes and bolting (UG-20) subject to in-service temperatures colder than -20°F shall meet the requirements of UCS-66, unless exempted by the following. (a) The coincident Ratio defined in Fig. UCS-66.1 is 0.4 or less (b) The material(s) is exempted from impact testing per Fig. UCS-66. 4. Materials used in nozzles, disks, and other parts contained within the external structure of the pressure relief valves shall be one of the following categories: (a) listed in Section II; (b) listed in ASTM Specifications; (c) controlled by the manufacturer of the pressure relief valve by a specification insuring control of chemical and physical properties and quality at least equivalent to ASTM Standards. C. Inspection of Manufacturing and/or Assembly of Pressure Relief Valves 1. A Manufacturer or assembler shall demonstrate to the satisfaction of a designated representative of the ASME that his manufacturing, production, and testing facilities and quality control procedures will insure close agreement between the performance of random production samples and the performance of those valves submitted for Capacity Certification. 2. Manufacturing, assembly, inspection, and test operations including capacity are subject to inspections at any time by an ASME designee. 3. The following schedule of tests ap- Notes 25. The degree of corrosion resistance, appropriate to the intended service, shall be a matter of agreement between the manufacturer and the purchaser. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 107 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section VIII – Division I (1995 Addenda) plies to production pressure relief valves certified under this Division, produced, assembled, tested, sealed, and shipped by the Manufacturer and having a normal scope of size and capacity within the capability of ASME accepted laboratories. Production valves for capacity and operational testing shall be selected by a designated representative of the ASME and the testing shall be carried out in the presence of a representative of the same organization at an ASME accepted laboratory in accordance with the following. (a) Initial capacity certification shall be valid for 1-year during which time two production valves shall be tested for |operation and stamped capacity verification. Should any of these valves fail to relieve at or above its stamped capacity, or should it fail to meet performance requirements, the test shall be repeated at the rate of two valves for each valve that failed. Initial capacity verification may be extended for 1-year intervals until the valve is in production. Valves having an adjustable blowdown construction shall be adjusted by the Manufacturer following successful testing for operation but prior to flow testing so that the blowdown does not exceed 7% of the set pressure or 3 psi, whichever is greater. This adjustment may be made on the flow test facility. (b) Thereafter, two valves shall be tested within each 5-year period of time. The valve manufacturer shall be notified of the time of the test and may have a witness present during the test. Should any of these valves fail to relieve at or above its stamped capacity or should it fail to meet performance requirements of this Division, the test shall be repeated at the rate of two valves for each valve that failed. Valves having an adjustable blowdown construction shall be adjusted by the manufacturer following successful test- ing for operation but prior to flow testing so that the blowdown does not exceed 7% of the set pressure or 3 psi, whichever is greater. This adjustment may be made on the flow test facility. These valves shall be furnished by the manufacturer or assembler. Failure of any of these valves to meet the stamped capacity or the performance requirements of this Division shall be cause for revocation within 60 days of the authorization to use the Code Symbol on that particular type of valve. During this period, the manufacturer shall demonstrate the cause of such deficiency and the action taken to guard against future occurrence, and the requirements of (C)(3)(a) above shall apply. 4. An assembler may be granted permission to use a Code Symbol Stamp after demonstrating to the satisfaction of a designated representative of the ASME that his quality control procedures will insure that the assembled valves meet the requirements of this Division, including the following. (a) Initially, two valves of each type or series to which the Code stamp is to be applied and which have been assembled, tested, and sealed by the assembler shall be selected by a designated representative of the ASME and tested for operation and stamped capacity verification. Should any valve fail to relieve at or above its stamped capacity, or should it fail to meet performance requirements, the test shall be repeated at the rate of two valves for each valve that failed. Valves having an adjustable blowdown construction shall be adjusted by the assembler following successful testing for operation but prior to flow testing so that the blowdown does not exceed 7% of the set pressure or 3 psi, whichever is greater. This adjustment may be made on the flow test facility. (b) Thereafter, within each 5-year period of time, two valves of each type or series shall be selected by a designated representative of the ASME and tested for operation and stamped capacity verification. The assembler shall be notified of the time of the test and may have a witness present during the test. Should any valve fail to relieve at or above its stamped capacity or should it fail to meet performance requirements of this Division, the test shall be repeated at the rate of two valves for each valve that failed. Valves having an adjustable blowdown construction shall be adjusted by the manufacturer following successful testing for operation but prior to flow testing so that the blowdown does not exceed 7% of the set pressure or 3 psi, whichever is greater. This adjustment may be made on the flow test facility. These valves shall be furnished by the assembler. Failure of any valve to meet the performance requirements of this Division shall be cause for revocation within 60 days of the assembler’s authorization to use the Code Symbol on that particular type or series of valve. During this period, the assembler shall demonstrate the cause of such deficiency and the action taken to guard against future occurrence. (c) All tests shall be carried out in the presence of a designated representative of the ASME at an ASME accepted laboratory. (d) Use of the Code Symbol Stamp by an assembler indicates the use of original, unmodified parts in strict accordance with the instructions of the manufacturer of the valve. (e) In addition to the requirements of UG-129, the nameplate marking shall include the name of the manufacturer and the assembler. The Code Symbol Stamp shall be that of the assembler.26 Notes 26. Within the requirements of UG-136(C) and UG-136(D): A manufacturer is defined as a person or organization who is completely responsible for design material selection capacity certification, manufacture of all component parts, assembly, testing, sealing, and shipping of pressure relief valves certified under this Division. An assembler is defined as a person or organization who purchases or receives from a manufacturer the necessary component parts or valves and assembles, adjusts, tests, seals, and ships pressure relief valves certified under this Division, at a geographical location © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 108 other than and using facilities other than those used by the manufacturer. An assembler may be organizationally independent of a manufacturer or may be wholly or partly owned by a manufacturer. Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section VIII – Division I (1995 Addenda) D. Production Testing by Manufacturers and Assemblers 1. Each pressure relief valve to which the Code Symbol Stamp is to be applied shall be subjected to the following tests by the manufacturer or assembler. A manufacturer or assembler shall have a documented program for the application, calibration, and maintenance of gauges and instruments used during these tests. 2. The primary pressure parts of each valve exceeding NPS 1 inlet size or 300 psig set pressure where the materials used are either cast or welded shall be tested at a pressure of at least 1.5 times the design pressure of the parts. These tests shall be conducted after all machining operations on the parts have been completed. There shall be no visible sign of leakage. 3. The secondary pressure zone of each closed bonnet valve exceeding NPS 1 inlet size when such valves are designed for discharge to a closed system shall be tested with air or other gas at a pressure of at least 30 psig. There shall be no visible sign of leakage. 4. Each valve shall be tested to demonstrate its popping or set pressure. Valves marked for steam service or having special internal parts for steam service shall be tested with steam, except that valves beyond the capability of the production steam test facility either because of size or set pressure may be tested on air. Necessary corrections for differentials in popping pressure between steam and air shall be established by the manufacturer and applied to the popping point on air. Valves marked for gas or vapor may be tested with air. Valves marked for liquid service shall be tested with water or other suitable liquid. Test fixtures and test drums where applicable shall be of adequate size and capacity to ensure that valve action is consistent with the stamped set pressure within the tolerances required by UG-134(E). 5. A seat tightness test shall be conducted at a maximum expected operating pressure, but at a pressure not exceeding the reseating pressure of the valve. When testing with either water or steam, a valve exhibiting no visible signs of leakage shall be considered adequately tight. Leakage tests conducted with air shall be in accordance with industry accepted standards. 6. Testing time on steam valves shall be sufficient, depending on size and design, to insure that test results are repeatable and representative of field performance. E. Design Requirements. At the time of the submission of valves for capacity certification, or testing in accordance with (C)(3) above, the ASME Designee has the authority to review the design for conformity with the requirements of UG-136(A) and UG-136(B) and to reject or require modification of designs which do not conform, prior to capacity testing. F. Welding and Other Requirements. All welding, brazing, heat treatment, and nondestructive examination used in the construction of bodies, bonnets, and yokes shall be performed in accordance with the applicable requirements of this Division. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 109 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section VIII – Division I (1995 Addenda) Capacity Conversions For Safety Valves 11.1 The capacity of a safety or relief valve in terms of a gas or vapor other than the medium for which the valve was officially rated shall be determined by application of the following formulas:1 For steam, Ws = 51.5KAP For air, Wa = CKAP ––––– M ––– T √ C = 356 M = 28.97 T = 520 when Wa is the rated capacity For any gas or vapor, W = CKAP These formulas may also be used when the required flow of any gas or vapor is known and it is necessary to compute the rated capacity of steam or air. For hydrocarbon vapors, where the actual value of k is not known, the conservative value, k = 1.001 has been commonly used and the formula becomes ––––– M ––– W = 315 KAP T When desired, as in the case of light hydrocarbons, the compressibility factor Z may be included in the formulas for gases and vapors as follows: √ √ Wa = rated capacity, converted to lb/hr of air at 60°F, inlet temperature W = flow of any gas or vapor, lb/hr C = constant for gas or vapor which is a function of the ratio of specific heats, k = Cp /Cv (see Fig. 11-1) K = coefficient of discharge [see UG-131(D) and (E)] A = actual discharge area of the safety valve, in2 P = (set pressure x 1.10) plus atmospheric pressure, psia M = molecular weight W = CKAP Example 1 √ KA = Ws = 4750 lb/hr Example 2 Given: It is required to relieve 5000 lb/hr of propane from a pressure vessel through a safety valve set to relieve at a pressure of Ps, psi, and with an inlet temperature of 125°F. Solution: Problem: What is the relieving capacity of that valve in terms of air at 100°F for the same pressure setting? Solution: Ws = 51.5KAP 3020 = 51.5KAP KAP = 3020 For propane, W = CKAP ––––– M ––– T √ The value of C is not definitely known. Use the conservative value, C = 315. –––––––––––– 44.09 –––––––– 5000 = 315AP 460 + 125 KAP = 57.7 √ For steam, For steam, = 58.5 Ws = 51.5 KAP = (51.5)(57.7) 51.5 = 2970 lb/hr set to relieve at Ps, psi Notes Official Rating in Steam: √ √ √ Problem: What total capacity in pounds of steam per hour in safety valves must be furnished? ––––– M ––– ZT Given: A safety valve bears a certified capacity rating of 3020 lb/hr of steam for a pressure setting of 200 psi. T = absolute temperature at inlet (°F + 460) 1. Knowing the official rating capacity of a safety valve which is stamped on the valve, it is possible to determine the overall value of KA in either of the following formulas in cases where the value of these individual terms is not known: ––––– M ––– T ––––––––– 28.97 –––––––– = 356 KAP 460 + 100 ––––––– 28.97 = (356) (58.5) –––––– 560 Wa = CKAP Molecular weights of some of the common gases and vapors are given in Table 11-1. ––––– M ––– T where: Ws = rated capacity, lb/hr of steam For air, Official Rating in Air: Wa KA = –––– CP ––––– T ––– M √ This value for KA is then substituted in the above formulas to determine the capacity of the safety valve in terms of the new gas or vapor. 51.5P © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 110 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section VIII – Division I (1995 Addenda) Capacity Conversions For Safety Valves Constant C k 1.00 315 1.38 354 1.02 318 1.40 356 Constant C 1.04 320 1.42 358 1.06 322 1.44 359 1.08 324 1.46 361 1.10 327 1.48 363 1.12 329 1.50 364 1.14 331 1.52 366 1.16 333 1.54 368 1.18 335 1.56 369 1.20 337 1.58 371 1.22 339 1.60 372 1.24 341 1.62 374 1.26 343 1.64 376 1.28 345 1.66 377 1.30 347 1.68 379 1.32 349 1.70 380 1.34 351 2.00 400 1.36 352 2.20 412 Figure 11-1 Constant C for Gas or Vapor Related to Ratio of Specific Heats (k = Cp/Cv) 400 390 380 Constant, C k 370 360 350 Flow Formula Calculations 340 W = K (CAP 330 C = 520 k M/T) ( k +2 1 ( k+1 k-1 320 ▲ 1.2 ▲ 1.0 ▲ 1.6 ▲ 1.4 ▲ 1.8 ▲ 2.0 k Notes 2. Before converting the capacity of a safety valve from any gas to steam, the requirements of UG-131(B) must be met. Example 3 Example 4 Given: It is required to relieve 1000 lb/hr of ammonia from a pressure vessel at 150°F. Given: A safety valve bearing a certified rating of 10,000 cu ft/min of air at 60°F and 14.7 psia (atmospheric pressure). Problem: What is the required total capacity in pounds of steam per hour at the same pressure setting? Solution: Solution: For ammonia, W = CKAP Problem: What is the flow capacity of this safety valve in pounds of saturated steam per hour for the same pressure setting? ––––– M ––– T √ Manufacturer and user agree to use k = 1.33; from Fig. 11-1, C = 350. –––––––––– 17.03 ––––––––– 1000 = 350 CKAP 460 + 150 √ KAP = 17.10 For steam, For air: Weight of dry air at 60°F and 14.7 psia is 0.0766 lb/cu ft. Wa = 10,000 x 0.0766 x 60 = 45,960 lb/hr 45,960 = 356 KAP KAP = 546 –––––––– 28.97 ––––––– 460 + 60 √ For steam,2 Ws = 51.5 KAP = (51.5)(546) = 28,200 lb/hr Ws = 51.5 KAP = 51.5 x 17.10 = 880 lb/hr © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 111 Anderson Greenwood Pressure Relief Valves Technical Manual ASME Code Section VIII – Division I (1995 Addenda) Table 11-1 11.2 Molecular Weights of Gases and Vapors Air 28.97 Freon 22 86.48 Acetylene 26.04 Freon 114 170.90 Ammonia 17.03 Hydrogen Butane 58.12 Hydrogen Sulfide 34.08 2.02 Carbon Dioxide 44.01 Methane 16.04 Chlorine 70.91 Methyl Chloride 50.48 Ethane 30.07 Nitrogen 28.02 Ethylene 28.05 Oxygen 32.00 Freon 11 137.371 Propane 44.09 Freon 12 120.9 Sulfur Dioxide 64.06 Figure 11-2 Flow Capacity Curve for Rating Nozzle Type Safety Valves on Saturated Water (Based on 10% Overpressure) B. To determine the saturated water capacity of a valve currently rated under UG-131 and meeting the requirements of (A) above, refer to Fig. 11-2. Enter the graph at the set pressure of the valve, move vertically upward to the saturated water line and read horizontally the relieving capacity. This capacity is the theoretical, isentropic value arrived at by assuming equilibrium flow and calculated values for the critical pressure ratio. Notes 3. The manufacturer, user, and inspector are all cautioned that for the following rating to apply, the valve shall be continuously subjected to saturated water. If, after initial relief the flow media changes to quality steam, the valve shall be rated as per dry saturated steam. Valves installed on vessels or lines containing steam-water mixture shall be rated on dry saturated steam. 24 Flow capacity x 10-4 (lb/hr/in2) A. Since it is realized that the saturated water capacity is configuration sensitive, the following applies only to those safety valves that have a nozzle type construction (throat to inlet diameter ratio of 0.25 to 0.80 with a continuously contoured change and have exhibited a coefficient KD in excess of 0.90). No saturated water rating shall apply to other types of construction.3 20 16 Saturated water 12 8 4 0 ▲ 0 ▲ 400 ▲ 800 ▲ 1200 ▲ 1600 ▲ 2000 ▲ 2400 ▲ 2800 ▲ 3200 Set pressure, psig © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 112 Anderson Greenwood Pressure Relief Valves Technical Manual Appendix M Installation and Operation – ASME VIII Division I - (1995 Addenda) M-1 Introduction A. The rules in this Appendix are for general information only, because they pertain to the installation and operation of pressure vessels, which are the prerogative and responsibility of the law enforcement authorities in those states and municipalities which have made provision for the enforcement of Section VIII. B. It is permissible to use any departures suggested herein from provisions in the mandatory parts of this Division when granted by the authority having legal jurisdiction over the installation of pressure vessels. M-2 Corrosion A. Vessels subject to external corrosion shall be so installed that there is sufficient access to all parts of the exterior to permit proper inspection of the exterior, unless adequate protection against corrosion is provided or unless the vessel is of such size and is so connected that it may readily be removed from its permanent location for inspection. B. Vessels having manholes, handholes, or cover plates to permit inspection of the interior shall be so installed that these openings are accessible. C. In vertical cylindrical vessels subject to corrosion, to insure complete drainage, the bottom head, if dished, should preferably be concave to pressure. M-3 Marking on the Vessel The marking required by this Division shall be so located that it will be accessible after installation and when installed shall not be covered with insulation or other material that is not readily removable [see UG-116(J)]. M-4 Pressure Relieving Safety Devices The general provisions for the installation of pressure relieving devices are fully covered in UG-135. The following paragraphs contain details in arrangement of stop valves for shutoff control of safety pres- sure relief devices which are sometimes necessary to the continuous operation of processing equipment of such a complex nature that the shutdown of any part of it is not feasible. There are also rules with regard to the design of inlet and discharge piping to and from safety and relief valves, which can only be general in nature because the design engineer must fit the arrangement and proportions of such a system to the particular requirements in the operation of the equipment involved. M-5 Stop Valves Between Pressure Relieving Device and Vessel A. A vessel, in which pressure can be generated because of service conditions, may have a full-area stop valve between it and its pressure relieving device for inspection and repair purposes only. When such a stop valve is provided, it shall be so arranged that it can be locked or sealed open, and it shall not be closed except by an authorized person who shall remain stationed there during that period of the vessel’s operation within which the valve remains closed, and who shall again lock or seal the stop valve in the open position before leaving the station. B. A vessel or system [see UG-133(C)] for which the pressure originates from an outside source exclusively may have individual pressure relieving devices on each vessel, or connected to any point on the connecting piping, or on any one of the vessels to be protected. Under such an arrangement, there may be a stop valve between any vessel and the pressure relieving devices, and this stop valve need not be locked open, provided it also closes off that vessel from the source of pressure. M-6 Stop Valves on the Discharge Side of a Pressure Relieving Device [See UG-135(E)] A full-area stop valve may be placed on the discharge side of a pressure relieving device when its discharge is connected to a common header with other discharge lines from other pressure relieving devices on nearby vessels that are in operation, so that this stop valve when closed will prevent a discharge from any connected operating vessels from backing up beyond the valve so closed. Such a stop valve shall be so arranged that it can be locked or sealed in either the open or closed position, and it shall be locked or sealed in either position only by an authorized person. When it is to be closed while the vessel is in operation, an authorized person shall be present, and he shall remain stationed there; he shall again lock or seal the stop valve in the open position before leaving the station. Under no condition should this valve be closed while the vessel is in operation except when a stop valve on the inlet side of the safety relieving device is installed and is first closed. M-7 Inlet Pressure Drop for High Lift, Top Guided Safety, Safety Relief, and Pilot Operated Pressure Relief Valves in Compressible Fluid Service A. The nominal pipe size of all piping, valves and fittings, and vessel components between a pressure vessel and its safety, safety relief, or pilot operated pressure relief valves shall be at least as large as the nominal size of the device inlet, and the flow characteristics of the upstream system shall be such that the cumulative total of all nonrecoverable inlet losses shall not exceed 3% of the valve set pressure. The inlet pressure losses will be based on the valve nameplate capacity corrected for the characteristics of the flowing fluid. B. When two or more required safety, safety relief, or pilot operated pressure relief valves are placed on one connection, the inlet internal cross-sectional area of this connection shall be either sized to avoid restricting flow to the pressure relief valves or made at least equal to the combined inlet areas of the safety valves connected to it. The flow characteristics of the upstream system shall meet the requirements of (A) above with all valves relieving simultaneously. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 113 Anderson Greenwood Pressure Relief Valves Technical Manual Appendix M Installation and Operation – ASME VIII Division I - (1995 Addenda) M-8 Discharge Lines from Safety Devices A. Where it is feasible, the use of a short discharge pipe or vertical riser, connected through long-radius elbows from each individual device, blowing directly to the atmosphere, is recommended. Such discharge pipes shall be at least of the same size as the valve outlet. Where the nature of the discharge permits, telescopic (sometimes called ‘broken’) discharge lines, whereby condensed vapor in the discharge line, or rain, is collected in a drip pan and piped to a drain, are recommended.1 B. When discharge lines are long, or where outlets of two or more valves having set pressures within a comparable range are connected into a common line, the effect of the back pressure that may be developed therein when certain valves operate must be considered [see UG-135(G)]. The sizing of any section of a common-discharge header downstream from each of the two or more pressure relieving devices that may reasonably be expected to discharge simultaneously shall be based on the total of their outlet areas, with due allowance for the pressure drop in all downstream sections. Use of specially designed valves suitable for use on high or variable back pressure service should be considered. C. The flow characteristics of the discharge system of high lift, top guided safety, safety relief, or pilot operated pressure relief valves in compressible fluid service shall be such that the static pressure developed at the discharge flange of a conventional direct spring loaded valve will not exceed 10% of the set pressure when flowing at stamp capacity. Other valve types exhibit various degrees of tolerance to back pressure and the manufacturer’s recommendation should be followed. D. All discharge lines shall be run as direct as is practicable to the point of final release for disposal. For the longer lines, due consideration shall be given to the advantage of long-radius elbows, avoidance of closeup fittings, and the minimizing of excessive line strains by expansion joints and wellknown means of support to minimize line-sway and vibration under operating conditions. E. Provisions should be made in all cases for adequate drainage of discharge lines.2 M-9 Pressure Drop, Nonreclosing Pressure Relief Devices Piping, valves and fittings, and vessel components comprising part of a nonreclosing device pressure relieving system shall be sized to prevent the vessel pressure from rising above the allowable overpressure. M-10 General Advisory Information on the Characteristics of Safety Relief Valves Discharging into a Common Header Because of the wide variety of types and kinds of safety relief valves, it is not considered advisable to attempt a description in this Appendix of the effects produced by discharging them into a common header. Several different types of valves may conceivably be connected into the same discharge header and the effect of back pressure on each type may be radically different. Data compiled by the manufacturers of each type of valve used should be consulted for information Notes 1. This construction has the further advantage of not transmitting discharge-pipe strains to the valve. In these types of installation, the back pressure effect will be negligible, and no undue influence upon normal valve operation can result. 2. It is recognized that no simple rule can be applied generally to fit the many installation requirements, which vary from simple short lines that discharge directly to the atmosphere to the extensive manifold discharge piping systems where the quantity and rate of the product to be disposed of requires piping to a distant safe place. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 114 relative to its performance under the conditions anticipated. M-11 Pressure Differentials for Pressure Relief Valves Due to the variety of service conditions and the various designs of safety and safety relief valves, only general guidance can be given regarding the differential between the set pressure of the valve (see UG-134) and the operating pressure of the vessel. Operating difficulty will be minimized by providing an adequate differential for the application. The following is general advisory information on the characteristics of the intended service and of the safety or safety relief valves that may bear on the proper pressure differential selection for a given application. These considerations should be reviewed early in the system design since they may dictate the MAWP of the system. A. Consideration of the Process Characteristics in the Establishment of the Operating Margin to Be Provided. To minimize operational problems, it is imperative that the user consider not only normal operating conditions of fluids, pressures, and temperatures, but also start-up and shutdown conditions, process upsets, anticipated ambient conditions, instrument response times, pressure surges due to quick closing valves, etc. When such conditions are not considered, the pressure relieving device may become, in effect, a pressure controller, a duty for which it is not designed. Additional consideration should be given to hazard and pollution associated with the release of the fluid. Larger differentials may be appropriate for fluids which are toxic, corrosive, or exceptionally valuable. Anderson Greenwood Pressure Relief Valves Technical Manual Appendix M Installation and Operation – ASME VIII Division I - (1995 Addenda) B. Consideration of Safety Relief Valve Characteristics. The blowdown characteristic and capability is the first consideration in selecting a compatible valve and operating margin. After a self-actuated release of pressure, the valve must be capable of reclosing above the normal operating pressure. For example, if the valve is set at 100 psig with a 7% blowdown, it will close at 93 psig. The operating pressure must be maintained below 93 psig in order to prevent leakage or flow from a partially open valve. Users should exercise caution regarding the blowdown adjustment of large spring-loaded valves. Test facilities, whether owned by Manufacturers, repair houses, or users, may not have sufficient capacity to accurately verify the blowdown setting. The settings cannot be considered accurate unless made in the field on the actual installation. Pilot-operated valves represent a special case from the standpoints of both blowdown and tightness. The pilot portion of some pilot-operating valves can be set at blowdowns as short as 2%. This characteristic is not, however, reflected in the operation of the main valve in all cases. The main valve can vary considerably from the pilot depending on the location of the two components in the system. If the pilot is installed remotely from the main valve, significant time and pressure lags can occur, but reseating of the pilot assures reseating of the main valve. The pressure drop in the connecting piping between the pilot and the main valve must not be excessive; otherwise, the operation of the main valve will be adversely affected. The tightness of the main valve portion of these combinations is considerably improved above that of conventional valves by pressure loading the main disk or by the use of soft seats or both. Despite the apparent advantages of pilot-operated valves, users should be aware that they should not be employed in abrasive or dirty service, in applications, where coking, polymerization, or corrosion of the wetted pilot parts can occur, or where freezing or condensation of the lading fluid at ambient temperatures is possible. For all applications, the valve Manufacturer should be consulted prior to selecting a valve of this type. Tightness capability is another factor affecting valve selection, whether spring loaded or pilot operated. It varies somewhat depending on whether metal or resilient seats are specified, and also on such factors as corrosion or temperature. The required tightness and test method should be specified to comply at a pressure no lower than the normal operating pressure of the process. A recommended procedure and acceptance standard is given in ANSI B146.1. It should also be remembered that any degree of tightness obtained should not be considered permanent. Service operation of a valve almost invariably reduces the degree of tightness. Application of special designs such as O-rings or resilient seats should be reviewed with the valve Manufacturer. The anticipated behavior of the valves includes allowance for a plus-or-minus tolerance on set pressure which varies with the pressure level. Installation conditions, such as back pressure, variations, and vibrations, influence selection of special types and an increase in differential pressure. C. General Recommendations. The following pressure differentials are recommended unless the safety or safety relief valve has been designed or tested in a specific or similar service and a smaller differential has been recommended by the Manufacturer. A minimum difference of 5 psi is recommended for set pressures to 70 psi. In this category, the set pressure tolerance is ±2 psi [UG-134(D)(1)], and the differential to the leak test pressure is 10% or 5 psi, whichever is greater. A minimum differential of 10% is recommended for set pressures from 71 psi to 1000 psi. In this category, the set pressure tolerance is ±3% and the dif- ferential to the leak test pressure is 10%. A minimum differential of 7% is recommended for set pressures above 1000 psi. In this category, the set pressure tolerance is ±3% and the differential to the leak test pressure should be 5%. Valves having small seat sizes will require additional maintenance when the pressure differential approaches these recommendations. M-12 Installation of Safety and Safety Relief Valves Spring loaded safety and safety relief valves normally should be installed in the upright position with the spindle vertical. Where space or piping configuration preclude such an installation, the valve may be installed in other than the vertical position provided that: A. the valve design is satisfactory for such position; B. the media is such that material will not accumulate at the inlet of the valve; and C. drainage of the discharge side of the valve body and discharge piping is adequate. M-13 Reaction Forces and Externally Applied Loads A. Reaction Thrust. The discharge of a pressure relief valve imposes reactive flow forces on the valve and associated piping. The design of the installation may require computation of the bending moments and stresses in the piping and vessel nozzle. There are momentum effects and pressure effects at steady state flow as well as transient dynamic loads caused by opening. B. External Loads. Mechanical forces may be applied to the valve by discharge piping as a result of thermal expansion, movement away from anchors, and weight of any unsupported piping. The resultant bending moments on a closed pressure relief valve may cause valve leakage and excessive stress in inlet piping. The design of the installation should consider these possibilities. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 115 Anderson Greenwood Pressure Relief Valves Technical Manual Appendix M Installation and Operation – ASME VIII Division I - (1995 Addenda) M-14 Sizing of Pressure Relief Devices for Fire Conditions A. Excessive pressure may develop in pressure vessels by vaporization of the liquid contents and/or expansion of vapor content due to heat influx from the surroundings, particularly from a fire. Pressure relief systems for fire conditions are usually intended to release only the quantity of product necessary to lower the pressure to a predetermined safe level, without releasing an excessive quantity. This control is especially important in situations where release of the contents generates a hazard because of flammability or toxicity. Under fire conditions, consideration must also be given to the possibility that the safe pressure level for the vessel will be reduced due to heating of the vessel material, with a corresponding loss of strength. B. Several formulas have evolved over the years for calculating the pressure relief capacity required under fire conditions. The major differences involve heat flux rates. There is no single formula yet developed which takes into account all of the many factors which could be considered in making this determina- tion. When fire conditions are a consideration in the design of a pressure vessel, the following references which provide recommendations for specific installations may be used: API RP 520, Recommended Practice for the Design and Installation of Pressure-Relieving Systems in Refineries, Part I– Design, 1976, American Petroleum Institute, Washington, DC API Standard 2000, Venting Atmospheric and Low Pressure Storage Tanks (nonrefrigerated and refrigerated), 1973, American Petroleum Institute, Washington, DC AAR Standard M-1002, Specifications for Tank Cars, 1978, Association of American Railroads, Washington, DC Safety Relief Device Standards: S-1.1, Cylinders for Compressed Gases; S-1.2, Cargo and Portable Tanks; and S-1.3, Compressed Gas Storage Containers. Compressed Gas Association, New York NFPA Code Nos. 30, 59, and 59A, National Fire Protection Association, Boston, MA Pressure-Relieving Systems for Marine Cargo Bulk Liquid Containers, 1973, © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 116 National Academy of Sciences, Washington, DC Bulletin E-2, How to Size Safety Relief Devices, Phillips Petroleum Company, Bartlesville, OK A Study of Available Fire Test Data as Related to Tank Car Safety Device Relieving Capacity Formulas, 1971, Phillips Petroleum Company, Bartlesville, OK M-15 Pressure Indicating Device If a pressure indicating device is provided to determine the vessel pressure at or near the set pressure of the relief device, one should be selected that spans the set pressure of the relief device and is graduated with an upper limit that is neither less than 1.25 times the set pressure of the relief device nor more than twice the maximum allowable working pressure of the vessel. Additional devices may be installed if desired. Anderson Greenwood Pressure Relief Valves Technical Manual Following is an Excerpt from API - RP 520 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 117 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries Section 2 – Pressure Relief Devices 2.2.4 Pressure Relief Valves 2.1 General 2.2.4.1 Conventional Pressure Relief Valves Conventional pressure relief valves are used when the discharge is through a short tail pipe that vents to the atmosphere or through a low-pressure manifold system that carries the discharged fluid of one or more valves to a remote location for disposal. Normally, the spring force is the differential between the set pressure and atmospheric pressure. The set pressure will therefore be increased by superimposed back pressure unless the spring force is adjusted accordingly. Built-up back pressure may also affect valve performance; therefore, the impact of downstream pressure when one or more valves discharge into a common manifold should be determined by referring to the appropriate manufacturer’s catalog. This section describes the basic principles, operational characteristics, applications, and selection of pressure relief devices used independently or in combination. These devices include spring-loaded and pilot-operated pressure relief valves, rupture disk devices, and other pressure relief devices. These devices are described in the text and illustrated in Figures 2-17. 2.2 Spring-Loaded Pressure Relief Valves 2.2.1 Safety Valves Safety valves are spring-loaded pressure relief devices designed to provide full opening with minimum overpressure. Static pressure retained in the huddling chamber and the kinetic energy of the gas or vapor are utilized to overcome the spring force on the disc as it lifts, resulting in pop action. The closing pressure will be at a point below the set pressure and will be reached after the blowdown phase is completed. 2.2.2 Relief Valves Relief valves are spring-loaded pressure relief devices designed for use in liquid service. At set pressure, the inlet pressure force overcomes the spring force and the disc begins to lift off the seat. As inlet pressure increases, the disk lift increases to allow an increase in the flow. The closing pressure will be at a point below the set pressure and will be reached after the blowdown phase is completed. Relief valve capacities are usually rated at 10 or 25% overpressure, depending on the application. 2.2.3 Safety Relief Valves Safety relief valves are spring-loaded pressure relief devices that provide the characteristics of a safety valve when used in gas or vapor service and the characteristics of a relief valve when used in liquid service. Safety relief valves are generally provided with bonnets that enclose the spring and provide a pressure-tight housing for use in conventional or balanced types, depending on the effect of back pressure on their performance. The interaction of the forces within the valve and the effects of back pressure on the opening are illustrated in Figure 18. Available conventional pressure relief valves have disks that have a greater disk area, AD, than the nozzle seat area, AN. If the spring bonnet is vented to the atmosphere, the back pressure acts with the vessel pressure to overcome the spring force. This condition makes the opening pressure less than it is when the valve is set with atmospheric pressure on its discharge; however, if the spring bonnet is vented to the valve discharge instead of to the atmosphere, the back pressure acts with the spring force to increase the opening pressure. Variation in the superimposed back pressure will directly affect the opening pressure and should be evaluated in system design. Conventional pressure relief valves, as normally installed, show unsatisfactory performance when excessive built-up back pressure develops from the flow through valve and piping as a result of the same unbalanced forces that affect the set pressure. Performance data observed during the investigation of the built-up back pressure problem are shown in Figure 19. The information is plotted as the ratio of the valve capacity at any given built-up back pressure to the valve capacity without built-up back pressure versus the ratio of the built-up back pressure to © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 118 the valve set pressure. The capacity curve is the result of the balance of forces acting on the disk. As long as the built-up back pressure is less than the overpressure after the valve opens, the valve will remain open and perform satisfactorily under flowing conditions, and it will have flow characteristics that are basically similar to those in a theoretical nozzle performance. If, however, the built-up back pressure is increased at a greater rate than the overpressure, the balance of forces will tend to close the valve, which can become unstable and cause the flow to fall off rapidly. This instability is caused by a dynamic pressure imbalance or a harmonic resonance. The valve may start to flutter or chatter. Flutter refers to the abnormally rapid reciprocating motion of the movable parts of a pressure relief valve in which the disk does not contact the seat. Chatter refers to the motion that causes the disk to contact the seat and damage the valve and associated piping. The allowable built-up back pressure must therefore be considered for each amount of overpressure used. Conventional pressure relief valves should typically not be used when the built-up back pressure is greater than 10% of the set pressure at 10% overpressure. A higher maximum allowable built-up back pressure may be used for overpressure greater than 10%. The combined effect of the superimposed and built-up back pressures on the performance characteristics of the valves must be considered when more than one pressure relief valve discharges into a common manifold at the same time. The theoretical performance for a nozzle is plotted in Figure 20. The curve represents the maximum theoretical flow attainable for any ideal gas that has the specific heat ratio of K = 1.3. The theoretical nozzle maintains flow capacity up to the critical flow pressure and then gradually diminishes to zero. The theoretical rate of flow through the nozzle depends on the absolute upstream pressure and is independent of the downstream pressure when the back pressure is less than the critical flow pressure; Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries 1. This figure conforms with the requirements of Section VIII of the ASME Boiler and Pressure Vessel Code. 2. The pressure conditions shown are for pressure relief valves installed on a pressure vessel. 3. Allowable set-pressure tolerances will be in accordance with the applicable codes. 4. The maximum allowable working pressure is equal to or greater than the design pressure for a coincident design temperature. 5. The operating pressure may be higher or lower than 90. 6. Section VIII, Division 1, Appendix M, of the ASME Code should be referred to for guidance on blowdown and pressure differentials. Figure 1 – Pressure-Level Relationships for Pressure Relief Valves Pressure Vessel Requirements Vessel Pressure Maximum allowable accumulated pressure (fire exposure only) 121 Maximum allowable accumulated pressure for multiple-valve installation (other than fire exposure) 116 Maximum allowable accumulated pressure for single-valve installation (other than fire exposure) 110 Maximum allowable accumulated pressure for design pressure Typical Characteristics of Pressure Relief Valves Maximum relieving pressure for fire sizing 120 Multiple valves maximum relieving pressure for process sizing 115 Single valve maximum relieving pressure for process sizing Percent of maximum allowable working pressure (gauge) Notes Maximum allowable set pressure for supplemental valves (fire exposure) Overpressure (maximum) Maximum allowable set pressure for additional valves (process) 105 100 Simmer (typical) 95 Maximum allowable set pressure for single valve Start to open Blowdown (typical) (see Note 6) Closing pressure for a single valve Maximum expected operating pressure (See Notes 5 and 6) 90 Leak test pressure (typical) 85 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 119 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries Cap Cap Stem (spindle) Stem (spindle) Adjusting Screw Adjusting Screw Spring Spring Bonnet Bonnet Note 1. For corrosion isolation, an unbalancedbellows safety relief valve is available. Vent Bellows Seating Surface Disk Seating Surface Disk Adjusting Ring Body Adjusting Ring Body Nozzle Nozzle Figure 2 – Conventional Safety Relief Valve With a Single Adjusting Ring for Blowdown Control Figure 3 – Balanced-Bellows Safety Relief Valve1 Cap Stem (spindle) Adjusting Screw Stem (spindle) Adjusting Screw Bonnet Cap Spring Spring Bonnet Vent Balanced Piston Bellows Seating Surface Disk Adjusting Ring Body Seating Surface Disk Base, Body Nozzle Figure 4 – Balanced-Bellows Safety Relief Valve With an Auxiliary Balanced Piston Figure 5 – Thermal Relief (Liquid Relief Valve) © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 120 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries however, when the back pressure is increased beyond the critical flow pressure, the flow is reduced. (See 4.3 for information about the sizing of pressure relief valves for critical and subcritical flow.) 2.2.4.2 Balanced Pressure Relief Valves The design of balanced pressure relief valves incorporates means for reducing the effect of back pressure on the set pressure and for minimizing the effect of built-up back pressure on performance characteristics such as opening and closing pressure, lift, and relieving capacity (see Section 4). Balanced valves are of two basic types: the piston and the bellows (see Figure 21). Several variations of the piston valve are manufactured. The guide on the piston is vented so that the back pressure on opposing faces of the valve disk is cancelled. The top face of the piston has an area, Ap, the same as the nozzle seat area, AN, and is subjected to atmospheric pressure by venting the spring bonnet. The vented gas from the bonnets of balanced piston valves should be disposed of safely and with minimum restrictions. Figure 6 – Pop Action Pilot Operated Valve (Flowing Type) Spindle Relief Seat Pilot Exhaust Spacer Rod Pilot-to-Dome Connection Piston Optional Pilot Filter Reseat Seat Backflow Preventor Piston Seat Outlet Remote Pressure Pickup (optional) Main Valve Inlet Figure 7 – Pop Action Pilot Operated Valve (Nonflowing Type) The effective bellows area, AB, of bellows valves is the same as the nozzle seat area, AN. The arrangement of the bellows in the valve prevents the back pressure from acting on the top side of the disk within the effective bellows area, AB. The disk area, AD, extending beyond the bellows and the opposing nozzle seat area cancel the effect of the back pressure on the valve disk so that there are no unbalanced forces under any downstream pressure variations. The bellows additionally serves to isolate the disk guide, spring, and other top works parts from the lading fluid. This feature may be important if the lading fluid is corrosive or may foul the pressure relief valve. Because of physical size limitations, balanced bellows are not available in certain valve designs and sizes. If balanced bellows are not available, unbalanced bellows valves may be specified when corrosion isolation alone is intended. The balanced pressure relief valve makes possible higher pressures in the relief discharge manifolds. Both balanced valves shown in Figure 21 should have bonnet vents large enough to ensure that no Set Pressure Adjusting Screw Seating Surface Spindle Pilot Exhaust Pilot Supply Line External Blowdown Adjustment Optional Pilot Piston Outlet Seat Internal Pressure Pickup Main Valve Inlet © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 121 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries Figure 8 – Modulating Pilot Operated Valve (Flowing Type) Sense Diaphragm Sensitivity Adjustment Sense Chamber Spindle Pilot Supply Line Piston appreciable back pressure exists during flow conditions. If the valve is located where atmospheric venting (usually not a large amount) would present a hazard, the vent should be piped to a safe location that is independent of the valve discharge system. 2.2.4.3 Valve Characteristics Figure 22 shows the disk travel from the set pressure, A, to the maximum relieving pressure, B, during the overpressure incident and to the closing pressure, C, during the blowdown. Seat Optional Pilot Filter Outlet 2.3 Pilot Operated Pressure Relief Valves The two basic types of pilot operated pressure relief valves are the piston type and the diaphragm type. Seat Internal Pressure Pickup Main Valve Inlet The piston type valve consists of the main valve, which encloses a floating piston, and an external pilot valve (see Figures 69). The piston is designed to have a larger effective area on the top than on the bottom. Up to the set pressure, the top and bottom areas are exposed to the same inlet operating pressure. Because of the larger effective area on the top of the piston, the net force holds the piston tightly to the main valve seat. As the operating pressure increases, the net seating force increases and tends to make the valve tighter. At the set point, the pilot vents the pressure from the top of the piston; the resulting net force unseats the piston, and process flow is established through the main valve. After the overpressure incident, the pilot will close the vent from the top of the piston, thereby re-establishing pressure, and the net force will cause the piston to reseat. Figure 9 – Pilot Operated Relief Valve With A Non-flowing Modulating Pilot Valve Vent Valve Filter Test Connection Inlet Valve Seat Piston Outlet The diaphragm type pilot operated relief valve is similar to the piston type except that the piston is replaced by a flexible diaphragm and disk. The diaphragm provides the unbalance function of the piston. The disk, which normally closes the main valve inlet, is integral with a flexible diaphragm (see Figure 10). The external pilot valve serves the same function to sense process pressure, vent the top of Internal Pressure Pickup Main Valve Inlet © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 122 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries The pilots may be either a flowing or nonflowing type. The flowing type allows process fluid to flow through the pilot when the main valve is open; the nonflowing type does not. The user should consult the manufacturer to determine the advantages and disadvantages of either type. A backflow preventor is required when the possibility exists of developing a pressure on the discharge side of the valve that exceeds the inlet pressure of the valve. The differential area will cause the piston to lift, and flow in the valve will be reversed (see Figure 7). Pilot-operated relief valves are available for use in liquid and vapor services. Since the main valve and pilot contain nonmetallic components, process temperature and fluid compatibility can limit their use. In addition, fluid characteristics such as susceptibility to polymerization or fouling, viscosity, the presence of solids, and corrosiveness may affect pilot reliability. The manufacturer should be consulted to ensure that the proposed application is compatible with available valves. 2.4 Rupture Disk Devices The remainder of Section 2 provides definitions, descriptions, and operational characteristics of rupture disk devices. Specific terms and uses are covered within the applicable sections of text and accompanying illustrations (see Figures 11-17). Set Spring Adjustment Spring Sense Diaphragm Boost Diaphragm Sense Cavity Spindle Seat Diaphragm Boost Cavity Pilot Exhaust Optional Pilot Filter Variable Orifice Outlet Main Valve Diaphragm Main Valve Seat Dome Inlet Internal Pressure Pickup Figure 18 – Typical Effects of Superimposed Back Pressure on the Opening Pressure of Conventional Pressure Relief Valves Spring Bonnet Vented To Atmosphere Spring Bonnet Vented To Valve Discharge SpringBonnet Vented Spring-Bonnet Spring Fs The pilot valve that operates the main valve can be either a pop action or modulating action pilot. Figure 23 shows the action of the pop pilot; it shows that pilot operation causes the main valve to lift fully. Figure 24 shows the action of the modulating pilot; it shows that pilot operation opens the main valve only enough to satisfy the required relieving capacity. Figure 10 – Low-Pressure Pilot Operated Valve (Diaphragm Type) Spring Fs the diaphragm at set pressure, and reload the diaphragm once the process pressure returns to normal. As with the piston valve, the seating force increases proportionally with the operating pressure because of the differential exposed area of the diaphragm. Disk Guide PB PB PB PB PB Disk Disk PB Piston Vent PB PB PV PV Ap = AN Back Pressure Decreases Set Pressure Back Pressure Increases Set Pressure PVAN = FS-PB (AD-AN) PVAN = FS+PBAN AD>AN AD = disk area. AN = nozzle seat area. FS = spring force. PV = vessel pressure in pounds per square inch gauge. PB = superimposed back pressure, in pounds per square in gauge. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 123 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries Figure 20 – Theoretical Performance for a Nozzle Discharging a Gas That Has a Specific Heat Ratio of 1.3 100 Figure 19 – Typical Effects of Builtup Back Pressure on the Capacity of Conventional Pressure Relief Valves 90 70 Percent (C1/C2) x 100 Theoretical nozzle flow 60 50 40 30 20 10 0 ▲ ▲ ▲ ▲ ▲ ▲ 0 10 20 30 40 50 Percent = ▲ ▲ ▲ ▲ ▲ 60 70 80 90 100 PB PS + PO Conventional pressure relief valve with spring bonnet vented to valve discharge Valve (stable) 90 80 70 60 50 40 30 P´ PS x 100 P´ less than overpressure Balanced Disk and Vented Bellows Type SpringBonnet Vent Fs Fs SpringBonnet Vent PB Piston Piston Vent PB PB Bellows Vent PB Disk Disk PB Vent PB PV AB = effective bellows area AD = disk area AN = nozzle seat area AP = piston area (top) FS = spring force PV = vessel gauge pressure Vented Bellows Ap = AN PV AB = AN PB = superimposed back pressure in pounds per square inch gauge PS = set pressure, in pounds per square inch gauge Note: In this figure, P V = PS; (P V)(AN) = FS (typical); and PS = FS/AN. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. P´greater than overpressure C1 = capacity with back pressure C2 = capacity with zero back pressure P´ = built-up back pressure PS = set pressure Figure 21 – Typical Effects of Back Pressure on the Set Pressure of Balanced Pressure Relief Valves Balanced Disk and Vented Piston Type Valve (flutter chatter) 100 Percent (C1/C2) x 100 C1 = capacity with back pressure C2 = capacity with zero back pressure PB = back pressure, in pounds per square inch absolute PS = set pressure, in pounds per square inch absolute PO = overpressure, in pounds per square inch 80 124 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries Figure 22 – Typical Relationship Between Lift of Disk in a Pressure Relief Valve and Vessel Pressure 100 Lift of disk, percent 0 Closing 100 Lift of disk, percent B Figure 23 – Typical Relationship Between Lift of Disk in a PopAction Pilot Operated Relief Valve and Vessel Pressure Blowdown Set pressure 0 Overpressure Closing Blowdown Overpressure Maximum relieving pressure Set pressure Maximum relieving pressure Figure 24 – Typical Relationship Between Lift of Disk in a Modulating-Action Pilot Operated Relief Valve and Vessel Pressure Lift of disk, percent 100 0 Closing Blowdown Set pressure © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. Overpressure Maximum relieving pressure 125 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries 4.1 Determination of Relief Requirements To establish the size of a pressure relief device for any application, the designer must first determine the conditions for which overpressure protection may be required. Reasonable care should be exercised in establishing the various contingencies that could result in overpressure. The contingencies that may cause overpressure must be evaluated in terms of the pressures generated and the rates at which fluids must be relieved. The process flow diagram, material balance, piping and instrument diagrams, equipment specification sheets, and design basis for the facility are needed to calculate the individual relieving rates for each pressure relieving device. Process equipment vendor data is also helpful if available. Appendix D provides relieving flow rates for fire conditions. Table 1 lists a number of common operational conditions for which overpressure protection may be required. This list is by no means complete; each plant may have unique features that must be considered in addition to those listed in Table 1. (See API Recommended Practice 521 for a detailed discussion of relief requirements.) Pressure relief valves may be sized using the equations presented in 4.3 through 4.5 as appropriate for vapors, gases, or liquids. These equations are used to calculate the effective nozzle area necessary to achieve a required flow rate through the valve. A valve is then chosen for the application that has an effective area equal to or greater than the calculated required effective area. The effective areas and assumed discharge coefficient, Kd = 0.975, are generally different from actual orifice areas and discharge coefficients that are used to determine certified valve capacities. However, effective areas calculated using the equations in 4.3 through 4.5 will result in the selection of valves with certified capacities that equal or exceed the required capacities. The effective-area concept allows for the selection of valve size independent of the manufacturer. Standard effective orifice areas and corresponding letter designations may be found in API Standard 526. 4.2 Relieving Pressure 4.2.1 General Relieving pressure, shown in P1 in the various sizing equations, is the inlet pressure of the relief device at relieving conditions. The relieving pressure is the total of set pressure plus overpressure plus atmospheric pressure. The examples cited in this section for the determination of relieving pressure refer to pressure relief valves; however, they are also applicable to rupture disk devices. (See Figures 1 and 25 for pressure-level relationships for these types of devices.) Notes 1. The discussion in this section generally cites the ASME Code as the applicable code. Unless stated otherwise, citations refer only to Section VIII of the ASME Code.The designer should be aware of revisions to the ASME Code. If pertinent revisions occur, the discussion in this section should be adjusted accordingly by the designer. Adjustments may also be required by the designer if other (non-ASME) codes apply. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 126 The allowable overpressure is established from the accumulation permitted by the applicable code. The allowable overpressure may vary for different applications depending on the relationship of the set pressure to the maximum allowable working pressure of the vessel or system that is protected. Allowable overpressure is the same as allowable accumulation only when the set pressure is equal to the maximum allowable working pressure.1 Sections 4.2.2 through 4.2.4 discuss methods of determining the relieving pressure for pressure relief valves in gas and vapor service. Standard atmospheric pressure (14.7 pounds per square inch absolute) is used for gauge/absolute pressure conversion in these sections. For design, barometric pressure corresponding to site elevation should be used. Relieving pressure for pressure relief valves in liquid service is determined in a manner similar to that used for vapor service except that the relieving pressure is expressed in gauge rather than absolute units. In the case of ASME-application liquid service valves (that is, for the protection of a liquid-full vessel), maximum accumulated pressure is limited to 110% of the maximum allowable working pressure for operating contingencies – the same constraint as for vapor service. In the case of non-ASME-application liquid service valves (that is, for protection of piping without vessels included), 25% overpressure is generally specified. Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries Table 2 summarizes the maximum accumulation and set pressure for pressure relief valves specified in accordance with the ASME Code. Table 4 shows an example determination of relieving pressure for a multiple-valve installation in which the set pressure of the first valve is equal to the maximum allowable working pressure of the vessel, and the set pressure of the additional valve is 105% of the vessel’s maximum allowable working pressure. 4.2.2 Operating Contingencies 4.2.2.1 Single-Valve Installation In accordance with the requirements of the ASME Code, accumulated pressure shall be limited to 110% of the maximum allowable working pressure in vessels that are protected by a single pressure relief valve sized for operating (nonfire) contingencies. The set pressure of the valve shall not exceed the maximum allowable working pressure.2 4.2.3 Fire Contingencies 4.2.3.1 General In accordance with the requirements of the ASME Code, accumulated pressure shall be limited to 121% of the maximum allowable working pressure in vessels that are protected by valves sized for fire contingencies. This applies to single-, multiple-, and supplemental-valve installations. Table 3 shows an example determination of relieving pressure for a single valve whose set pressure is less than or equal to the vessel’s maximum allowable working pressure. Single or multiple valves sized for fire may also be utilized for relieving requirements attributed to secondary operating (nonfire) contingencies, if applicable, provided that the constraint of 110% (of the maximum allowable working pressure) accumulated pressure for nonfire contingencies is observed. 4.2.2.2 Multiple-Valve Installation A multiple-valve installation requires the combined capacity of two or more pressure relief valves to alleviate a given overpressure contingency. 4.2.3.2 Single-Valve Installation Where a vessel is protected by a single valve sized for fire, the set pressure shall not exceed the maximum allowable working pressure. In accordance with the requirements of the ASME Code, accumulated pressure shall be limited to 116% of the maximum allowable working pressure in vessels that are protected by multiple valves sized for operating (nonfire) contingencies. The set pressure of the first valve shall not exceed the maximum allowable working pressure. The set pressure of the additional valve or valves shall not exceed 105% of the maximum allowable working pressure.3 Table 5 shows an example determination of relieving pressure for a single valve whose set pressure is less than or equal to the vessel’s maximum allowable working pressure. 4.2.3.3 Multiple-Valve Installation A multiple-valve installation requires the combined capacity of two or more valves to alleviate overpressure from a fire. The set pressure of the first valve to open shall not exceed the maximum allowable working pressure. The set pressure of the last valve to open shall not exceed 105% of the maximum allowable working pressure. Table 6 shows an example determination of relieving pressure for a multiple-valve installation in which the set pressure of the first valve is equal to the vessel’s maximum allowable working pressure, and the set pressure of the additional valve is 105% of the vessel’s maximum allowable working pressure. 4.2.3.4 Supplemental-Valve Installation A supplemental-valve installation provides relieving capacity for an additional hazard created by exposure to fire or other unexpected sources of external heat. The set pressure of a supplemental valve for fire shall not exceed 110% of the maximum allowable working pressure. Supplemental valves are used only in addition to valves sized for operating (nonfire) contingencies. Table 7 shows an example determination of relieving pressure for a supplemental-valve installation in which the set pressure of the first (nonfire) valve does not exceed the vessel’s maximum allowable working pressure (see 4.2.1 for determination of relieving pressure), and the set pressure of the supplemental valve in 110% of the vessel’s maximum allowable working pressure. Table 2 Set Pressure and Accumulation Limits for Pressure Relief Valves4 Contingency Single-Valve Installations Multiple-Valve Installations Set Pressure (percent) Maximum Accumulated Pressure (percent) Set Pressure (percent) Maximum Accumulated Pressure (percent) 100 110 100 116 – – 105 116 100 121 100 121 Additional valve(s) – – 105 121 Supplemental valve – – 110 121 Nonfire only First Valve Additional Valve(s) Notes 2. Allowable accumulation is 3 pounds per square inch when the maximum allowable working pressure is between 15 and 30 pounds per square inch gauge. 3. Allowable accumulation is 4 pounds per square inch when the maximum allowable working pressure is between 15 and 25 pounds per square inch gauge. 4. All values are percentages of the maximum allowable working pressure. Fire only First Valve © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 127 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries Table 3 Table 4 Example Determination of Relieving Pressure for a Single Valve (Operating Contingencies) Characteristic Value Characteristic Valve Set Pressure Less Than MAWP Table 5 Example Determination of Relieving Pressure for a MultipleValve Installation (Operating Contingencies) Value Example Determination of Relieving Pressure for a Single Valve (Fire Contingencies) Characteristic Value Valve Set Pressure Less Than MAWP Protected vessel MAWP, psig 100 First Valve (Set Pressure Equal to MAWP) Protected vessel MAWP, psig 100 Maximum accumulated pressure, psig 110 Protected vessel MAWP, psig 100 Maximum accumulated pressure, psig 121 116 Valve set pressure, psig 90 100 Allowable overpressure, psi 31 Allowable overpressure, psi 16 Relieving pressure, P1, psia 135.7 Relieving pressure, P1, psia 130.7 Valve set pressure, psig 90 Maximum accumulated pressure, psig Allowable overpressure, psig 20 Valve set pressure, psig Relieving pressure, P1, psia 124.7 Valve Set Equal to MAWP Protected vessel MAWP, psig 100 Maximum accumulated pressure, psig 110 Valve set pressure, psig 100 Allowable overpressure, psi 10 Relieving pressure, P1, psia 124.7 Additional Valve (Set Pressure Equal to 105% of MAWP) Protected vessel MAWP, psig 100 Maximum accumulated pressure, psig 116 Valve set pressure, psig 105 Allowable overpressure, psi 11 Relieving pressure, P1, psia 130.7 Table 7 Table 6 Example Determination of Relieving Pressure for a MultipleValve Installation (Fire Contingencies) Example Determination of Relieving Pressure for a Supplemental Valve (Fire Contingencies) Characteristic Value Characteristic Protected vessel MAWP, psig 100 Supplemental Valve (Set Pressure Equal to 110% of MAWP) Maximum accumulated pressure, psig 121 Valve set pressure, psig 100 First Valve (Set Pressure Equal to MAWP) Allowable overpressure, psig 21 Relieving pressure, P1, psia 135.7 Additional Valve (Set Pressure Equal to 105% of MAWP) Protected vessel MAWP, psig 100 Maximum accumulated pressure, psig 121 Valve set pressure, psig 105 Allowable overpressure, psig 16 Relieving pressure, P1, psia 135.7 Protected vessel MAWP, psig Value 100 Maximum accumulated pressure, psig 121 Valve set pressure, psig 110 Allowable overpressure, psig 11 Relieving pressure, P1, psia 135.7 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 128 Valve Set Pressure Equal to MAWP Protected vessel MAWP, psig 100 Maximum accumulated pressure, psig 116 Valve set pressure, psig 100 Allowable overpressure, psi 21 Relieving pressure, P1, psia 135.7 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries 4.2.4 Steam Service Where: Where: Valves for pressure vessels in steam service, excluding boilers designed in accordance with Section I of the ASME Code, should be specified as discussed above, depending on the contingency. Pcf = critical flow throat pressure, in pounds per square inch absolute. A = required effective discharge area of the valve, in square inches (see 1.2.2). 4.3 Sizing for Gas or Vapor Relief 4.3.1 Critical Flow Behavior If a compressible gas is expanded across a nozzle, an orifice, or the end of a pipe, its velocity and specific volume increase with decreasing downstream pressure. For a given set of upstream conditions (using the example of a nozzle), the mass rate of flow through the nozzle will increase until a limiting velocity is reached in the throat. It can be shown that the limiting velocity is the velocity of sound in the flowing media at that location. The flow rate that corresponds to the limiting velocity is known as the critical flow rate. The absolute pressure ratio of the pressure in the throat at sonic velocity (Pcf) to the inlet pressure (P1) is called the critical pressure ratio. Pcf is known as the critical flow pressure. Under critical flow conditions, the actual pressure in the throat cannot fall below the critical flow pressure even if a much lower pressure exists downstream. At critical flow, the expansion from throat pressure to downstream pressure takes place irreversibly with the energy dissipated in turbulence into the surrounding fluid. The critical flow pressure in absolute units may be estimated using the ideal gas relationship in Equation 1: Pcf ––– = P1 [ ] 2 –––– k+1 k (k - 1) (1) P1 = upstream relieving pressure, in pounds per square inch absolute. k= ratio of specific heats for any ideal gas. The sizing equations for pressure relief valves in vapor or gas service fall into two general categories depending on whether the flow is critical or subcritical. If the pressure downstream of the throat is less than or equal to the critical flow pressure, Pcf, then critical flow will occur, and the procedures in 4.3.2 should be applied. If the downstream pressure exceeds the critical flow pressure, Pcf, then subcritical flow will occur, and the procedures in 4.3.3 should be applied. (See Table 8 for typical critical flow pressure ratio values.) 4.3.2 Sizing for Critical Flow 4.3.2.1 General Pressure relief valves in gas or vapor service that operate under critical flow conditions (see 4.3.1) may be sized using Equations 2 – 4. Each of the equations may be used to calculate the effective discharge area, A, required to achieve a required flow rate through a pressure relief valve. A valve that has an effective discharge area equal to or greater than the calculated value of A is then chosen for the application. W A = –––––––– CKdP1Kb –––––– TZ ––– M √ (2) ––––– V √ TZM A = –––––––––––– 6.32 CKdP1Kb (3) ––––– V √ TZG A = ––––––––––––– 1.175 CKdP1Kb (4) W = required flow through the valve, in pounds per hour. C = coefficient determined from an expression of the ratio of the specific heats of the gas or vapor at standard conditions. This can be obtained from Figure 26 or Table 9. Kd = effective coefficient of discharge = 0.975 for use in Equations 2 – 4. P1 = upstream relieving pressure, in pounds per square inch absolute. This is the set pressure plus the allowable overpressure (see 4.2) plus atmospheric pressure. Kb = capacity correction factor due to back pressure. This can be obtained from the manufacturer’s literature or estimated from Figure 27. The backpressure correction factor applies to balanced-bellows valves only.5 T = relieving temperature of the inlet gas or vapor, in degrees Rankine (degrees Fahrenheit + 460). Z = compressibility factor for the deviation of the actual gas from a perfect gas, a ratio evaluated at inlet conditions. M = molecular weight of the gas or vapor. Various handbooks carry tables of molecular weights of materials, but the composition of flowing gas or vapor is seldom the same as that listed in tables. This value should be obtained from the process data. Table 8 lists values for some common fluids. V = required flow through the valve, in standard cubic feet per minute at 14.7 pounds per square inch absolute and 60°F. G = specific gravity of gas referred to air = 1.00 for air at 14.7 pounds per square inch absolute and 60°F. Notes 5. See 4.3.3 for applications that involve superimposed back pressure of a magnitude that will cause subcritical flow. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 129 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries The value of the coefficient C can be evaluated from the expression of the ratio of the specific heats of the gas or vapor as shown in Figure 26. Figure 26 - Curve for Evaluating Coefficient C in the Flow Equation From the Specific Heat Ratio Assuming Ideal Gas Behavior 400 The ratio of specific heats of any ideal gas and possibly the ratio of specific heats of a diatomic actual gas can be found in any acceptable reference work. 380 Coefficient, C Table 9 complements Figure 26 where k = Cp/Cv. When k cannot be determined, it is suggested that C = 315. While ideal gas law behavior is generally acceptable for the majority of refinery applications, Appendix E should be referred to for unusual situations in which deviation from ideal behavior is significant. 360 C = 520 k k+1 k+2 ( ( 2 k+1 340 4.3.2.2 Example In this example, the following relief requirements are given: 320 ▲ 1.0 a. Required hydrocarbon vapor flow, W, caused by an operational upset, of 53,500 pounds per hour. ▲ 1.2 ▲ 1.4 ▲ 1.6 ▲ 1.8 ▲ 2.0 Specific heat ratio, k = CP/CV b. Molecular weight of hydrocarbon vapor [a mixture of butane (C4) and pentane (C5)], M, of 65. c. Relief temperature, T, of 627°R (167°F). d. Relief valve set at 75 pounds per square inch gauge, the design pressure of the equipment. e. Back pressure of 0 pounds per square inch gauge. In this example, the following data are derived: a. Permitted accumulation of 10%. b. Relieving pressure, P1, of 75 x 1.1 + 14.7 = 97.2 pounds per square inch absolute. c. Calculated compressibility, Z, of 0.84. (If a calculated compressibility is not available, Z = 1.0 should be used.) The size of a single pressure relief valve is derived from Equation 2 as follows: d. Critical back pressure (from Table 8) of 97.2 x 0.59 = 57.3 pounds per square inch absolute (42.6 pounds per square inch gauge).6 53,500 A = ––––––––––––––– 326 x 0.975 x 97.2 e. Cp/Cv = k (from Table 8) of 1.09. From Table 9, C = 326. f. Capacity correction due to back pressure, Kb, of 1.0. √ in2 See API Standard 526, which also provides a purchase specification sheet for flanged steel safety relief valves (see Figure 28). Select a ‘P’ letter orifice size (6.38 in2). Notes 6. Since the back pressure (0 pounds per square inch gauge) is less than the critical back pressure (42.6 pounds per square inch gauge), the relief valve setting is based on the critical flow equation (see Equation 2 and 4.3.1 and 4.3.2). © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. = 4.93 –––––––––– 627 x 0.84 ––––––––– 65 130 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries Table 8 Properties of Gases Gas Molecular Weight Methane 16.04 Specific Critical Flow Specific Critical Constants Condensation Flammability References Heat Ratio Pressure Gravity at Pressure Temperature Temperature Limits Ratio at at 60°F (psia) (°F) 1 Atmosphere (volume (k = Cp/Cv) at 60°F at 60°F and 1 (°F) percent and 1 and 1 Atmosphere in air Atmosphere Atmosphere mixture) 1.31 0.54 0.300 667 -117 -259 5.0-15.0 1 Ethane 30.07 1.19 0.57 0.356 708 90 -127 2.9-13.0 1 Ethylene 28.05 1.25 0.56 0.139 731 49 -155 2.7-36.0 1 Propane 44.10 1.13 0.58 0.507 615 206 -44 2.0-9.5 1 Proylene 42.08 1.15 0.57 0.518 672 198 -54 2.0-10.6 2, 3 Isobutane 58.12 1.10 0.59 0.563 528 274 11 1.8-8.5 1 n-Butane 58.12 1.09 0.59 0.584 549 306 31 1.5-9.0 1 1-Butane 56.11 1.11 0.58 0.600 586 296 21 1.6-9.3 2, 3 Isopentane 72.15 – – 0.625 490 369 82 1.3-8.0 1 n-Pentane 72.15 – – 0.631 488 386 97 1.4-8.3 1 1-Pentane 70.13 – – 0.646 510 377 86 1.5-8.7 1 n-Hexane 86.18 – – 0.664 437 454 156 1.1-7.7 1 Benzene 78.11 – – 0.882 710 552 176 1.4-7.1 2, 3 n-Heptane 100.20 – – 0.688 397 513 209 1.0-7.0 1 Toluene 92.14 – – 0.874 596 606 231 1.2-7.1 2, 3 n-Octane 114.23 – – 0.707 361 564 258 0.8-6.5 1 n-Nonane 128.26 – – 0.722 332 611 303 0.7-5.6 1 n-Decane 142.28 – – 0.734 305 653 345 0.7-5.4 1 Air 28.96 1.40 0.53 0.875 547 -221 -318 – 2, 3 Ammonia 17.03 1.31 0.54 0.616 1636 271 -28 16.0-25.0 2, 3 Carbon dioxide 44.01 1.29 0.55 0.818 1071 88 -109 – 2, 3 2.02 1.41 0.53 – 190 -400 -423 4.0-75.0 2, 3 Hydrogen sulfide 34.08 1.32 0.54 0.801 1300 213 -77 4.3-45.5 2, 3 Sulfur dioxide 64.06 1.27 0.55 1.394 1143 316 14 – 2, 3 Steam 18.02 – – 1.000 3199 705 212 – 2, 3 Hydrogen Estimated References 1. “Physical Constants of Hydrocarbons C1 to C10,” ASTM Special Technical Publication No. 109A, Philadelphia, Pa., 1963. 2. “International – Critical Tables,” McGraw-Hill Book Co., Inc., New York. 3. “Engineering Data Book,” Gas Processors Suppliers Association, 1977. 4. API Technical Data Book–Petroleum Refining, Fifth edition. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 131 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries 4.3.3 Sizing for Subcritical Flow: Gas or Vapor Other Than Steam 4.3.3.1 General When the ratio of back pressure to inlet pressure exceeds the critical pressure ratio Pcf/P1, the flow through the pressure relief valve is subcritical (see 4.3.1). Equations 5 – 7 may be used to calculate the required effective discharge area for a conventional relief valve that has its spring setting adjusted to compensate for superimposed back pressure and for sizing a pilot-operated relief valve.7 W A = –––––––– 735 F2Kd ––––––––––––– ZT –––––––––––– MP1 (P1 - P2) √ V A = ––––––––––– 4645.2 F2Kd V A = ––––––––––– 863.63 F2Kd Where: (5) W = required flow through the valve, in pounds per hour. ––––––––––– ZTM –––––––––– P1 (P1 - P2) (6) ––––––––––– ZTG –––––––––– P1 (P1 - P2) (7) √ √ F2 = coefficient of subcritical flow (see Figure 28 for values) = ––––––––––––––––––––––– k 1 - r (k-1)k –––– (r)2/k ––––––– k-1 1-r √( ) [ ] k = ratio of the specific heats. r = ratio of back pressure to upstream relieving pressure, P2/P1. Table 9 Values of Coefficient C k C k C k C k C 1.01 317a 1.31 348 1.61 373 1.91 395 1.02 318 1.32 349 1.62 374 1.92 395 1.03 319 1.33 350 1.63 375 1.93 396 1.04 320 1.34 351 1.64 376 1.94 397 1.05 321 1.35 352 1.65 376 1.95 397 1.06 322 1.36 353 1.66 377 1.96 398 1.07 323 1.37 353 1.67 378 1.97 398 1.08 325 1.38 354 1.68 379 1.98 399 1.09 326 1.39 355 1.69 379 1.99 400 1.10 327 1.40 356 1.70 380 2.00 400 1.11 328 1.41 357 1.71 381 – – 1.12 329 1.42 358 1.72 382 – – 1.13 330 1.43 359 1.73 382 – – 1.14 331 1.44 360 1.74 383 – – 1.15 332 1.45 360 1.75 384 – – 1.16 333 1.46 361 1.76 384 – – 1.17 334 1.47 362 1.77 385 – – 1.18 335 1.48 363 1.78 386 – – 1.19 336 1.49 364 1.79 386 – – 1.20 337 1.50 365 1.80 387 – – 1.21 338 1.51 365 1.81 388 – – 1.22 339 1.52 366 1.82 389 – – 1.24 341 1.54 368 1.84 390 – – 1.25 342 1.55 369 1.85 391 – – 1.26 343 1.56 369 1.86 391 – – 1.27 344 1.57 370 1.87 392 – – 1.28 345 1.58 371 1.88 393 – – 1.29 346 1.59 372 1.89 393 – – 130 347 1.60 373 1.90 394 – – a Interpolated A = required effective discharge area of the valve, in square inches (see 1.2.2). value, since C becomes indeterminate as k approaches 1.00. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 132 Kd = effective coefficient of discharge = 0.975 for use in Equations 5 –7. Z = compressibility factor for the deviation of the actual gas from a perfect gas, a factor evaluated at relieving inlet conditions. T = relieving temperature of the inlet gas or vapor, in degrees Rankine (degrees Fahrenheit + 460). M = molecular weight of the gas or vapor. Various handbooks carry tables of molecular weights of materials, but the composition of the flowing gas or vapor is seldom the same as that listed in the tables. This value should be obtained from the process data. Table 8 lists values for some common fluids. P1 = upstream relieving pressure, in pounds per square inch absolute. This is the set pressure plus the allowable overpressure (see 4.2) plus atmospheric pressure, in pounds per square inch absolute. P2 = back pressure, in pounds per square inch absolute. V = required flow through the valve, in standard cubic feet per minute at 14.7 pounds per square inch absolute and 60°F. G = specific gravity of gas referred to air = 1.00 for air at 14.7 pounds per square inch absolute and 60°F. Note 7. Balanced-bellows relief valves that operate in the subcritical region should be sized using Equations 2-4. The back pressure correction factor for this application should be obtained from the valve manufacturer. Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries Figure 27 – Back Pressure Sizing Factor, Kb, for Balanced-Bellows Pressure Relief Valves (Vapors and Gases) 1.00 20% overp ressu Kb = C1/C2 0.90 re C1 = capacity with back pressure. C2 = rated capacity with zero back pressure. PB = back pressure, in pounds per square inch gauge. PS = set pressure, in pounds per square inch gauge. 10 % 0.80 ov er pr 0.70 es su re 0.60 0.50 ▲ 0 ▲ 5 ▲ 10 ▲ 15 ▲ 20 ▲ 25 ▲ 35 ▲ 30 ▲ 45 ▲ 40 ▲ 50 Percent of gauge back pressure = PB/PS x 100 Note make is known, the manufacturer should be consulted for the correction factor. These curves are for set pressures of 50 pounds per square inch gauge and above. They are limited to back pressure below critical flow pressure for a given set pressure. For subcritical flow back pressures below 50 pounds per square inch gauge, the manufacturer must be consulted for values of Kb. Figure 28 – Values of F2 for Subcritical Flow 1.0 0.9 F2 The curves above represent a compromise of the values recommended by a number of relief valve manufacturers and may be used when the make of the valve or the actual critical flow pressure point for the vapor or gas is unknown. When the 0.8 0.7 0.6 ▲ 0.4 k= 1.8 k= 1.6 k= ▲ 0.5 1.4 k= 1.2 k= 1.0 ▲ 0.6 Critical flow line ▲ 0.7 ▲ 0.8 ▲ 0.9 ▲ 1.0 r = P2/P1 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 133 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries See API standard 526, which also provides a purchase specification sheet for flanged steel safety relief valves. Select a ‘P’ letter orifice size (6.38 in2). e. Constant back pressure of 55 pounds per square inch gauge. The spring setting of the valve should be adjusted according to the amount of constant back pressure obtained. 4.3.4 Alternate Sizing Procedure for Subcritical Flow In this example, the following data are derived: 4.3.4.1 General Critical flow Equations may be used to calculate the required discharge area of a pressure relief valve used in subcritical service. The area obtained using this sizing procedure is identical to the area obtained using the subcritical flow equations. (The capacity correction factor due to back pressure is derived by setting the subcritical flow equation equal to the critical flow equation and algebraically solving for Kb.) This alternate sizing procedure allows the designer to use the familiar critical flow equation to calculate the same area obtained with the subcritical flow equation. A graphical presentation of the capacity correction factor, Kb, is given in Figure 30 on page 129. It should be noted that this correction factor is used only for the sizing of conventional (nonbalanced) relief valves that have their spring settings adjusted to compensate for the superimposed back pressure. The correction factor should not be used to size balanced-type valves. a. Permitted accumulation of 10 percent. b. Relieving pressure, P1, of 75 x 1.1 + 14.7 = 97.2 pounds per square inch absolute. c. Calculated compressibility, Z, of 0.84. (If a calculated compressibility is not available, Z = 1.0 should be used.) d. Critical back pressure (from Table 8) of 97.2 x 0.59 = 57.3 pounds per square inch absolute (42.6 pounds per square inch gauge).8 4.4 Sizing for Steam Relief 4.4.1 General Pressure relief valves in steam service may be sized using Equation 8. W A = –––––––––––––– 51.5 P1KdKNKSH (8) Where: A = required effective discharge area, in square inches. W = required flow rate, in pounds per hour. e. Built-up back pressure of 0.10 x 75 = 7.5 pounds per square inch. P1 = upstream relieving pressure, in pounds per square inch absolute. This is the set pressure plus the allowable overpressure plus atmospheric pressure, in pounds per square inch absolute. f. Total back pressure of 55 + 7.5 + 14.7 = 77.2 pounds per square inch absolute. Kd = effective coefficient of discharge = 0.975 for use in Equation 8. g. Cp/Cv = k of 1.09. KN = correction factor for Napier equation (see Reference 1) h. P2/P1 = 77.2 / 97.2 = 0.794. i. Back pressure correction factor, Kb, of 0.88 (from Figure 30 on page 129). = 1 where P1 ≤ 1515 pounds per square inch absolute j. Coefficient determined from an expression of the ratio of the specific heats of the gas or vapor at standard conditions, C, of 326. = (0.1906P1 – 1000) /(0.2292P1 – 1061) where P1 > 1515 pounds per square inch absolute and ≤ 3215 pounds per square inch absolute. 4.3.4.2 Example In this example, the following relief requirements are given: The size of the relief valve is derived from Equation 2 as follows: 9 a. Required hydrocarbon vapor flow, W, caused by an operational upset, of 53,500 pounds per hour. 53,500 A = –––––––––––––––––– 326(0.975)(97.2)(0.88) KSH = superheat steam correction factor. This can be obtained from Table 10 on page 127. For saturated steam at any pressure, KSH = 1.0. b. Molecular weight of hydrocarbon vapor [a mixture of butane (C4) and pentane (C5), M, of 65. ––––––––– 627(0.84) –––––––– 65 √ W = saturated steam at 153,500 pounds per hour at 1600 pounds per square inch gauge set pressure with 10% accumulation. c. Relief temperature, T, of 627°R (167°F). d. Relief valve set at 75 pounds per square inch gauge, the design pressure of the equipment. Notes 8. Since the back pressure (55 pounds per square inch gauge) is greater than the critical back pressure (42.6 pounds per square inch gauge), the sizing of the relief valve is based on subcritical flow. The back pressure correction factor, Kb, should be determined using the critical flow formulas (see Equations 2–4). 4.4.2 Example In this example, the following relief requirements are given: = 5.60 in2 9. This area requirement is the same as that obtained using the subcritical flow equation (see Equation 5). © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 134 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries Table 10 Superheat Correction Factors, KSH Set Pressure (pounds per in2 gauge) Temperature (degrees Fahrenheit) 300 400 500 600 700 800 900 1000 1100 1200 15 1.00 0.98 0.93 0.88 0.84 0.80 0.77 0.74 0.72 0.70 20 1.00 0.98 0.93 0.88 0.84 0.80 0.77 0.74 0.72 0.70 40 1.00 0.99 0.93 0.88 0.84 0.81 0.77 0.74 0.72 0.70 60 1.00 0.99 0.93 0.88 0.84 0.81 0.77 0.75 0.72 0.70 80 1.00 0.99 0.93 0.88 0.84 0.81 0.77 0.75 0.72 0.70 100 1.00 0.99 0.94 0.89 0.84 0.81 0.77 0.75 0.72 0.70 120 1.00 0.99 0.94 0.89 0.84 0.81 0.78 0.75 0.72 0.70 140 1.00 0.99 0.94 0.89 0.85 0.81 0.78 0.75 0.72 0.70 160 1.00 0.99 0.94 0.89 0.85 0.81 0.78 0.75 0.72 0.70 180 1.00 0.99 0.94 0.89 0.85 0.81 0.78 0.75 0.72 0.70 200 1.00 0.99 0.95 0.89 0.85 0.81 0.78 0.75 0.72 0.70 220 1.00 0.99 0.95 0.89 0.85 0.81 0.78 0.75 0.72 0.70 240 – 1.00 0.95 0.90 0.85 0.81 0.78 0.75 0.72 0.70 260 – 1.00 0.95 0.90 0.85 0.81 0.78 0.75 0.72 0.70 280 – 1.00 0.96 0.90 0.85 0.81 0.78 0.75 0.72 0.70 300 – 1.00 0.96 0.90 0.85 0.81 0.78 0.75 0.72 0.70 350 – 1.00 0.96 0.90 0.86 0.82 0.78 0.75 0.72 0.70 400 – 1.00 0.96 0.91 0.86 0.82 0.78 0.75 0.72 0.70 500 – 1.00 0.96 0.92 0.86 0.82 0.78 0.75 0.73 0.70 600 – 1.00 0.97 0.92 0.87 0.82 0.79 0.75 0.73 0.70 800 – – 1.00 0.95 0.88 0.83 0.79 0.76 0.73 0.70 1000 – – 1.00 0.96 0.89 0.84 0.78 0.76 0.73 0.71 1250 – – 1.00 0.97 0.91 0.85 0.80 0.77 0.74 0.71 1500 – – – 1.00 0.93 0.86 0.81 0.77 0.74 0.71 1750 – – – 1.00 0.94 0.86 0.81 0.77 0.73 0.70 2000 – – – 1.00 0.95 0.86 0.80 0.76 0.72 0.69 2500 – – – 1.00 0.95 0.85 0.78 0.73 0.69 0.66 3000 – – – – 1.00 0.82 0.74 0.69 0.65 0.62 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 135 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries Figure 29 - Constant Back Pressure Sizing Factor, Kb, For Conventional Safety Relief Valves (Vapors and Gases Only) 100 90 C1 = capacity with back pressure. 735F2 l - r C 70 Kb = C1/C2 = 80 40 C2 = rated capacity with zero back pressure. k = 1.1 k = 1.3 k = 1.5 k = 1.7 60 Exchange 50 30 20 10 0 ▲ 0 ▲ 10 ▲ 20 ▲ 30 ▲ 40 ▲ 50 Percent of absolute back pressure Set overpressure (MAWP) = 100 pounds per square inch gauge. Overpressure = 10 pounds per square inch. Superimposed back pressure (constant) = 70 pounds per square inch gauge. Spring set = 30 pounds per square inch. Built-up back pressure = 10 pounds per square inch Percent absolute back pressure = (70 + 10 + 14.7) ▲ 60 ▲ 70 ▲ 80 ▲ 90 ▲ 100 PB = x 100 = r x 100 PS + PO Note This chart is typical and suitable for use only when the make of the valve or the actual critical flow pressure point for the vapor or gas is unknown; otherwise, the valve manufacturer should be consulted for specific data. This correction factor should be used only in the sizing of conventional (nonbalanced) pressure relief valves that have their spring setting adjusted to compensate for the superimposed back pressure. It should not be used to size balanced-type valves. x 100 = 76 (100 + 10 + 17.7) Kb (follow dotted line) = 0.89 (from the curve). Capacity with back pressure = 0.89 (rated capacity without back pressure). © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 136 P8 = back pressure, in pounds per square inch absolute. PS = set pressure, in pounds per square inch absolute. PO = overpressure, in pounds per square inch. Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries In this example, the following data are derived: Figure 30 – Capacity Correction Factor, Kw, Due to Back Pressure on Balanced-Bellows Pressure Relief Valves in Liquid Service a. Relieving pressure, P1, of 1600 x 1.1 + 14.7 = 1774.7 pounds per square inch absolute. 1.00 0.90 KW = correction factor due to back pressure. 0.80 0.70 PB = back pressure, in pounds per square inch gauge. d. Superheat steam correction factor, KSH, of 1.0. 0.60 PS = set pressure, in pounds per square inch gauge. The size of the relief valve is derived from equation 8 as follows: 0.50 ▲ 0 c. Correction factor for Napier equation, KN, of [0.1906(1774.7) - 1000] / [0.2293(1774.7) - 1061] = 1.01. KW b. Effective coefficient of discharge, Kd, of 0.975. ▲ 10 ▲ 20 ▲ 30 ▲ 50 ▲ 40 Percent of gauge = (P /P ) x 100 B S back pressure 153,500 A = –––––––––––––––––––––––– 51.5(1774.7)(0.975)(1.01)(1) = 1.705 in2 Note See API Standard 526, which also provides a purchase specification sheet for flanged steel safety relief valves. Select a ‘K’ orifice valve (1.838 in2), that is, a 3K6 safety valve. The curve above represents values recommended by various manufacturers. This curve may be used when the manufacturer is not known. Otherwise, the manufacturer should be consulted for the applicable correction factor. 4.5 Sizing for Liquid Relief: Relief Valves Requiring Liquid Capacity Certification 4.5.1 General Figure 31 – Capacity Correction Factor, Kv, Due to Viscosity Q A = ––––––––– 38KdKwKv –––––––– G ––––––– P1 - P2 √ (9) Where: A = required effective discharge area, in square inches. 1.0 0.9 KV = viscosity correction factor Section VIII, Division I, of the ASME Code requires that capacity certification be obtained for pressure relief valves designed for liquid service. The procedure for obtaining capacity certification includes determining the coefficient of discharge for the design of liquid relief valves at 10% overpressure. Valves that require a capacity in accordance with the ASME Code may be sized using Equation 9. 0.8 0.7 0.6 0.5 0.4 Q = flow rate, in U.S. gallons per minute. Kd = effective coefficient of discharge that should be obtained from the valve manufacturer. For a preliminary sizing estimation, a discharge coefficient of 0.65 can be used. 0.3 ▲ 10 ▲ 20 ▲ ▲ ▲ 40 50 100 ▲ 200 ▲ 400 ▲ ▲ 1000 2000 ▲ ▲ ▲ 20,000 ▲ 100,000 R = Reynolds number © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 137 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries Kw = correction factor due to back pressure. If the back pressure is atmospheric, Kw = 1. Balancedbellows valves in back pressure service will require the correction factor determined in Figure 31 on page 129. Conventional valves require no special correction. Kv = correction factor due to viscosity as determined from page 28. G = specific gravity of the liquid at the flowing temperature referred to water = 1.0 at 70°F. P1 = upstream relieving pressure, in pounds per square inch gauge. This is the set pressure plus allowable overpressure. P2 = total back pressure, in pounds per square inch gauge. When a relief valve is sized for viscous liquid service, it should first be sized as it was for nonviscous-type application so that a preliminary required discharge area, A, can be obtained. From manufacturers’ standard orifice sizes, the next larger orifice size should be used in determining the Reynold’s number, R, from either of the following relationships: Q(2800G) R = ––––––––– µ √–– A (10) U = viscosity at the flowing temperature, in Saybolt Universal seconds. After the value of R is determined, the factor Kv is obtained from page 28. Kv is applied to correct the preliminary required discharge area. If the corrected area exceeds the standard chosen orifice area, the above calculations should be repeated using the next larger standard orifice size. In this example, the following relief requirements are given: Where: Q = flow rate at the flowing temperature, in U.S. gallons per minute. G = specific gravity of the liquid at flowing temperature referred to water = 1.00 at 70°F. µ = absolute viscosity at the flowing temperature, in centipoises. a. Required crude-oil flow caused by blocked discharge, Q, of 1800 gallons per minute. b. Specific gravity, G, of 0.90 (viscosity at the flowing temperature is 2000 Saybolt Universal seconds.) c. Relief valve set at 250 pounds per square inch gauge, the design pressure of the equipment. d. Back pressure variable from 0 to 50 pounds per square inch gauge. In this example, the following data are derived: c. Back pressure of (50/250) x 100 = 20%. A balanced-bellows valve is indicated, since back pressure is variable. (From Figure 31, Kw = 0.97.) The manufacturer’s effective coefficient of discharge K = 0.75. Sizing first for no viscosity correction, (Kv = 1.0), the size of the relief valve is derived from Equation 9 as follows: Notes 10. Equation 11 is not recommended for viscosities less than 100 Saybolt Universal seconds. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. = 4.118 in2 See Equation 11. An area of 4.34 in2 (‘N’ orifice) should be used. 12,700 x 1800 R = –––––––––––– = 5487 –––– 2000 √ 4.34 From page 28, Kv = 0.965. = 4.118 –––––– 0.965 = 4.267 in2 b. Relieving pressure, P1, of 1.10 x 250 = 275 pounds per square inch gauge. (11)10 –––––––– 0.90 ––––––– (275-50) √ 1800 A = ––––––––––––––––––– 38.0 x 0.75 x 0.97 x 1.0 AR A = –––– Kv 4.5.2 Example a. Overpressure of 10%. or 12,700Q R = –––––––– –– U √A A = effective discharge area, in square inches (from manufacturers’ standard orifice areas). 138 Where: AR = required area without viscosity correction. See API Standard 526, which also provides a purchase specification sheet for flanged steel safety relief valves. Select an ‘N’ orifice pressure relief valve (4.34 square inches), that is, a 4N6 pressure relief valve. 4.6 Sizing for Liquid Relief: Relief Valves Not Requiring Capacity Certification Before the ASME Code made provisions for capacity certification, valves were generally sized for liquid service using Equation 12. This method assumes a coefficient of discharge, Kd = 0.62, and 25 percent overpressure. An additional capacity correction factor, KP, was obtained from Figure 33 for relieving pressures other than 25 percent overpressure. This sizing method may be used where capacity certification is not required. Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries –––––––––– G –––––––– 125p - pb √ Q A = –––––––––––– 38 KdKwKvKp (12) Where: A = required effective discharge area, in square inches. Q = flow rate, in U.S. gallons per minute. Kd = effective coefficient of discharge that should be obtained from the valve manufacturer. For a preliminary sizing estimation, a discharge coefficient of 0.62 can be used. Kw = correction factor due to back pressure. If back pressure is atmospheric, Kw = 1. Balancedbellows valves in back-pressure service will require the correction factor determined from Figure 31. Conventional valves require no special correction. Kv = correction factor due to viscosity as determined from page 28. Kp = correction factor due to overpressure. At 25% overpressure, Kp = 1.0. For overpressures other than 25%, Kp is determined from Figure 32. G = specific gravity of the liquid at the flowing temperature referred to water. = 1.0 at 70°F. p = set pressure, in pounds per square inch gauge. p b = total back pressure, in pounds per square inch gauge. 4.7 Sizing for Two-Phase Liquid/Vapor Relief A pressure relief valve handling a liquid at vapor-liquid equilibrium or a homogeneous mixed-phase fluid will produce flashing with vapor generation as the fluid moves through the valve. The vapor generation must be taken into account, since it may reduce the effective mass flow capacity of the valve. Calculations for determining properties and handling liquid/vapor phases are available; see Section 5 for emerging technical literature that can be used to size relieving devices. For information about saturated water, see specifically Section VIII, Appendix 11, of the ASME Code. 4.8 Sizing for Rupture Disk Devices A reasonable, conservative method of sizing for two-phase liquid/vapor relief is as follows: Rupture disk devices may be used alone or in combination with a pressure relief valve in gas or vapor service or in liquid service. The sizing of a rupture disk device used alone is based on the equations applicable for pressure relief valves using for all fluids an effective coefficient of discharge Kd = 0.62. a. Determine the amount of liquid that flashes by an isenthalpic (adiabatic) expansion from the relieving condition either to the critical downstream pressure for the flashed vapor or to the back pressure, whichever is greater. b. Calculate individually the orifice area required to pass the flashed vapor component, using Equations 2 – 7 as appropriate, according to service, type of valve, and whether the back pressure is greater or less than the critical downstream pressure. c. Calculate individually the orifice area required to pass the unflashed liquid component using Equation 9. The pressure drop (P1 – P2) is the inlet relieving pressure minus the back pressure. d. Add the individual areas calculated for the vapor and liquid components to obtain the total orifice area, A, that is required. e. Select a pressure relief valve that has an effective discharge area equal to or greater than the total calculated orifice area. The designer should recheck the back pressure that will exist for the specific relief valve selected, with its particular discharge installation, by examining the vapor generation downstream of the pressure relief valve nozzle. Where appropriate, corrections can be applied to the particular orifice areas previously calculated. Furthermore, selecting a balanced pressure relief valve is often desirable to minimize the effect of flashed vapor on the valve capacity. The designer should also investigate the effect of any auto-refrigeration that may arise from the flashing of liquid. Materials of construction must be adequate for the outlet temperatures involved; in addition, the installation must preclude the possibility of flow blockage occurring from hydrate or possibly solid formation. 4.8.1 Rupture Disk Devices Used Independently The required discharge area, A in square inches, is calculated using the appropriate equation for the flowing medium (see Equations 2– 7 for gas or vapor, Equation 8 for steam, and Equation 9 for liquid). The rupture disk device selected should be the nominal pipe size whose area is equal to or greater than the required discharge area calculated by the appropriate equation. For rupture disk devices that have a structural member (for example, a knife blade or vacuum support) that reduces the effective discharge area after bursting, the projected area of the structural member is deducted from the flow area of the pipe to determine the net discharge area of the burst rupture disk. Users should be aware of the following limitations in using Kd = 0.62 to determine the capacity of a given size of rupture disk, or conversely, the required area for a given flow quantity: a. The rupture disk device is used in a size and pressure range that the manufacturer has determined will give a satisfactory opening for the style of rupture disk in the particular fluid service. b. The rupture disk device is installed in a short piping system that does not add significantly to the flow resistance of the burst rupture disk device. If a rupture disk device discharges into a vent system or a closed relief system, it will usually not contribute significantly to the pressure loss obtained in the discharge piping. The sizing of the inlet and discharge piping becomes a line sizing problem that uses the relieving rate and the maximum allowable inlet pressure defined by the code. In general, a pressure © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 139 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries Figure 32 – Capacity Correction Factors Due to Overpressure for Relief and Safety-Relief Valves in Liquid Service The curve in Fig. 32 shows that up to and including 25 percent overpressure, capacity is affected by the change in lift, the change in orifice discharge coefficient, and the change in overpressure. Above 25 percent, capacity is affected only by the change in overpressure. Valves operating at low overpressures tend to chatter; therefore, overpressures of less than 10 percent should be avoided. 1.10 0.90 Correction factor, Kp Notes 0.70 0.50 0.30 0.10 ▲ ▲ ▲ ▲ ▲ 10 20 30 40 50 Percent overpressure loss through the rupture disk device of approximately 75 pipe diameters may be used. The manufacturer should be consulted if more accurate values are required. This problem is similar to the line sizing of a process line except that the effect of volumetric expansion on the pressure loss must be considered. This will include an acceleration effect (the vapor is exiting the discharge piping at a higher velocity) as well as the effect of changing density. If the vent line subsequently discharges into headers of varying sizes, critical flow restrictions must be considered. 4.8.2 Rupture Disk Devices Used in Combination With Pressure Relief Valves An important application of a rupture disk device is at the inlet of a pressure relief valve. The sizing of the pressure relief valve/rupture disk device combination requires that the pressure relief valve first be sized to meet the required relieving capacity. The certified and published capacity of the pressure relief valve used alone is then multiplied by the combination capacity factor, K c, to determine the capacity of that combination. (See 2.6.2 for further information on the combination capacity factor.) The nominal size of the rupture disk device installed at the inlet of the pressure relief valve must be equal to or greater than the nominal size of the inlet connection of the valve to permit sufficient flow capacity and valve performance. The design of the piping from the protected vessel to the inlet of the pressure relief valve is crucial to the proper functioning of the valve. Users should consult applicable engineering codes for guidance on inlet piping design. Unless the pressure relief device is installed directly on the vessel, a good practice is to analyze the frictional pressure loss from the vessel to the valve inlet at the rated relieving capacity to comply with recommended limits. An inlet pipe sized larger than necessary for the inlet to the pressure relief valve is often required; this may dictate a rupture disk device to match the pipe size. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 140 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries References 1. N.E. Sylvander and D.L. Katz, “Investigation of Pressure Relieving Systems,” Engineering Research Bulletin No. 31, University of Michigan, Ann Arbor, April 1948. 2. Recommended Practice for the Design and Construction of Pressure Relieving Systems for Process Equipment and Pressure Storage in Refineries (tentative), American Petroleum Institute, August 1954. 3. F.J. Heller, “Safety Relief Valve Sizing: API Versus CGA Requirements Plus a New Concept for Tank Cars,” 1983 Proceedings–Refining Department, Volume 62, American Petroleum Institute, Washington, D.C., pp. 123-135. 4. H.R. Wharton, “Digest of Steels for High Temperature Service,” Timken Steel, 1946. 5. J.J. Duggan, C.H. Gilmour, and P.F. Fisher, “Requirements for Relief of Overpressure in Vessels Exposed to Fire,” Transactions of the ASME, 1944, Volume 66, pp. 1-53. 6. I. Heitner, T. Trautmauis and M. Morrissey, “Relieving Requirements for Gas Filled Vessels Exposed to Fire,” 1983 Proceedings–Refining Department, Volume 62, American Petroleum Institute, Washington, D.C., pp. 112-122. 7. J. O. Francis and W.E. Shackelton, “A Calculation of Relieving Requirements of the Critical Region,” 1985 Proceedings–Refining Department, Volume 64, American Petroleum Institute, Washington D.C., pp. 179-182. 8. H.G. Fisher, “DIERS Research Program on Emergency Relief Systems,” Chemical Engineering Progress, August 1985, pp. 33-36. 9. H.K. Fauske and J.C. Leung, “New Experimental Technique for Characterizing Runaway Chemical Reactions,” Chemical Engineering Progress, August 1985, pp. 39-46. 10. M.A. Grolmes and J.C. Leung, “Code Method for Evaluating Integrated Relief Phenomena,” Chemical Engineering Progress, August 1985, pp. 47-52. 11. H.K. Fauske, “Emergency Relief System Design,” Chemical Engineering Progress, August 1985, pp. 53-56. 12. M.A. Grolmes, J.C. Leung, and H.K. Fauske, “Large-Scale Experiments of Emergency Relief Systems,” Chemical Engineering Progress, August 1985, pp. 57-62. 13. Publication 999 (English Edition), Technical Data Book–Petroleum Refining, American Petroleum Institute, Washington, D.C. 14. O. Cox, Jr. and M.L. Weirick, “Sizing Safety Valve Inlet Lines,” Chemical Engineering Progress, November 1980. 15. B.A. Van Boskirk, “Sensitivity of Relief Valves to Inlet and Outlet Line Lengths,” Chemical Engineering, August 1982. 16. C.E. Lapple, “Isothermal and Adiabatic Flow of Compressible Fluids,” Transactions of the American Institute of Chemical Engineers, 1943, Volume 39, pp. 385-432. 17. H.Y. Mak, “New Method Speeds Pressure-Relief Manifold Design,” Oil and Gas Journal, November 20, 1978. 18. P. Kandell, “Program Sizes Pipe and Flare Manifolds for Compressible Flow,” Chemical Engineering, June 29, 1981. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 141 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries D.1 Background The problem of estimating fire-relief requirements for storage tanks was first recognized in 1928 when the National Fire Protection Association (NFPA) requested API to recommend that a table of minimum emergency relief capacities for a series of tank capacities be included in the NFPA Suggested Ordinance Regulating the Use, Handling, Storage and Sale of Flammable Liquids and the Products Thereof. It was later recognized that tank capacities did not provide the best basis for estimating the amount of vapor to be handled. Since the heat was absorbed almost entirely by radiation, the area exposed — not the volume of the tank contents — seemed to be the important factor. Many of the tanks were large and could never be expected to be entirely surrounded by fire; the assumption was therefore made that the larger the area of the container, the less the likelihood that the tank would be fully exposed to radiation. In other words, the larger the surface area of the tank shells, the lower the average unit heat absorption rate from a fire. By 1948 several different equations [1]1 were in general use, prompting the API Subcommittee on Pressure-Relieving Systems to develop an equation for determining the heat absorbed from open fires using the test data available at the time. The resultant equation has remained in general use since its publication in 1954 [2], and its development is documented in a paper presented by F.J. Heller in 1983 [3]. Table D-1 contains data from 16 fire tests and one actual fire. Data from these tests were considered in the development of Equations D-1 and D-2. These data result from tests in which means were provided to measure the total heat absorbed by a vessel by (a) computing the heat required to bring the liquid contents to the boiling range and (b) measuring the amount of liquid contents evaporated in a given time. The unit heat absorption rates in Table D-1 are average rates on the wetted surface. Examinations of detailed reports on these tests indicate that the setup for Tests 4, 5, and 8 was arranged to provide continuous and complete flame envelopment of the small vessels; under these conditions, maximum average heat input rates of 30, 400-32, 500 British thermal units per hour per square foot were realized. The environmental conditions set up for tests 1, 3, 6, 7, 9, and 10 allowed the flame to be subjected to air currents and wind. All other factors were conducive to maintaining maximum heat input, a condition that should not exist in a refinery. Under these conditions, the maximum average heat input rates varied greatly. Test 2 differed from Test 1 in that drainage away from the equipment was provided. The maximum heat input rate is reduced by 60% when drainage is provided; this fact was incorporated in the development of Equations D-1 and D-2. Test 11 gives an indication of the effect of a large area on average heat input during an actual fire. The test reports mentioned in some cases that the tests were delayed until the arrival of a calm day so that the wind would not blow the flames away from the vessel. Copious supplies of fuel were available. In most cases, the fuel was maintained by dikes in a pool beneath the vessel and was not allowed to drain away as it normally would. In the Rubber Reserve Corporation tests, a 2-inch gasoline line, running full, was required to keep the fuel supplied during the test. Without these special adverse conditions, the maximum heat absorption values obtained in these tests are extremely unlikely to occur in an actual refinery fire. D.2 Nature of an Open Fire The nature of an open fire of flammable fluid, as related to test data, is important. Note 1. Numbers in brackets correspond to references in Section 5. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 142 This kind of fire differs from the fire in the firebox of a boiler or still, where the fuel and air are mixed by means other than the convection currents caused by the heated gases. The flame will accordingly have a core of flammable vapor, either unmixed with air or insufficiently mixed to burn. Combustion occurs on the exterior envelope of this core. Because the actual combustion zone is on the rich side, a considerable amount of black smoke is generated. This envelope of soot may serve to mask a considerable portion of the flame. Hot gases from the combustion rise, and the air that supports the combustion flows in at the bottom. The flame mass is quite turbulent; as masses of the burning vapor tumble and billow, the smoky mantle is displaced and the bright flame can be seen intermittently. This flame is not a blazing white, as it would be in a furnace; it is red or orange, indicating a lower temperature than that of a furnace flame. Flames of this type tend to rise because of their temperature; however, they can also be blown aside by the wind and may be blown so far from a vessel that the heating effect on the vessel is small. D.3 Effect of Fire on the Unwetted Surface of a Vessel D.3.1 General Unwetted wall vessels are those in which the internal walls are exposed to a single fluid, vapor, or gas or are internally insulated regardless of the contained fluids. These include vessels that contain separate liquid and vapor phases under normal conditions but become single phase (above the critical) at relieving conditions. Vessels may be designed to have internal insulation. A vessel should be considered internally insulated when the internal wall can become insulated by the deposition of coke or other materials as a result of the contained fluids. Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries Table D-1 Comparison of Heat-Absorption Rates in Fire Tests Test Source Type of Exposure 1 Hottell, average of 36 tests 6-inch thick metal stack Hottell, average 6-inch thick of 13 tests metal stack Standard Oil Co. of California Heating water in drum Standard Oil Co. Heating water of California in tank Underwriters Laboratories, Inc. Water flowing over plate 2 3 4 5 6 7 8 9 10 11a Rubber Reserve Heating water Corp.Test No.17 in tank Rubber Reserve Corp.Test No.17 Generating steam in tank Rubber Reserve Corp.Test No.17 Water flowing in 3/4-inch standard pipe API Project Test No.1 Heating water in tank API Project Heating water Test No. 2 in tank Report to API on 38 ft. butane sphere Plant fire Fuel Gasoline Gasoline Vessel Total Wetted Total Capacity Area Area Heat Input (barrel) (ft2) (ft2) (BTU/Hr) Conning Tower Conning Tower Naphtha 2.6 Naphtha 33 Gasoline Temperature BTU/Hr/Ft2 Refer. of Wetted Surface (°F) 296 123 3,760,000 30,500 1 296 123 2,139,000 17,400 2 26 416,000 16,000 3 206 105 3,370,000 70-212 32,000 3 24 24 780,000 76 32,500 4 300 23,200 5 Gasoline 119 568 400 9,280,000 Gasoline 199 568 400 8,400,000 21,000 5 9.0 9.0 274,000 30,400 5 Gasoline Kerosene 0.88 16.2 6.1 95,800 300 15,700 6 Kerosene 0.88 16.2 6.1 102,500 320 16,800 6 Butane 5,000 4,363 4,363 23,560,000 5,400 7 12 Lauderback Chemical waste 100 100 3,210,000 32,100 8 13 NFPA (Tulsa) Cutback jet fuel 238 773 303 8,736,000 23,000 9 14 Union Carbide (1938) Propane 71.4 242 132 2,300,000 17,400 10 15 Union Carbide (1938) Propane 71.4 242 176 4,993,000 28,400 10 16 Fetterly 7.7 83 57.8 1,350,000 23,300 11 aThis represents an actual fire Liquefied petroleum Wood saturated gas container with kerosene References 1. H.C. Hottell, Private communication to API Subcommittee on Pressure-Relieving Systems, January 1948. 2. H.C. Hottell, Private communication to API Subcommittee on Pressure-Relieving Systems, December 1950. 3. F.L. Maker Private communication to API Subcommittee on Pressure-Relieving Systems regarding 1925 tests, December 22,1950. 4. “Opacity of Water to Radiant Heat Energy,” Research Bulletin 3, Underwriters Laboratory, Inc., 1938. 5. Safety Memorandum 89, Rubber Reserve Corporation, Washington, D.C., May 1944. 6. University of Michigan, Unpublished tests made for API Subcommittee on PressureRelieving Systems, June 1947. 7. Anonymous report to API Subcommittee on Pressure-Relieving Systems regarding a fire (not a test), June 1941. 8. J.J. Duggan, C.H. Gilmour, and P.F. Fisher, “Requirements for Relief of Overpressure on Vessels Exposed to Fire,” Transactions of the ASME, 1944, Volume 66, pp. 1-53. 9. “Large Scale Fire Exposure Tests to Evaluate ‘Unox’ Foam for Fire Exposure Protection,” Fire Research Laboratory Report No. FRL-62, Process Safety Department, Carbide and Carbon Chemicals Co., a Division of Union Carbide and Carbon Corporation, Dec. 8, 1954. 10. Lauderback. 11. National Fire Protection Association. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 143 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries D.3.2 Characteristics A characteristic of a vessel with an unwetted internal wall is that heat flow from the wall to the contained fluid is low as a result of the resistance of the contained fluid or any internal insulating material. Heat input from an open fire to the bare outside surface of an unwetted vessel may, in time, be sufficient to heat the vessel wall to a temperature high enough to rupture the vessel. Figures D-1 and D-2 indicate how quickly an unwetted vessel wall might be heated to rupture conditions. Figure D-1 illustrates the rise in temperature that occurs with time in the unwetted plates of various thicknesses exposed to open fire; for example, an unwetted steel plate 1-inch thick would take about 12 minutes to reach approximately 1100°F and about 17 minutes to reach 1300°F when the plate is exposed to an open fire. Figure D-2 shows the effect of overheating ASTM A 515, Grade 70 steel [4]. The figure indicates that at a stress of 15,000 pounds per square inch, an unwetted steel vessel would rupture in about 7 hours at 1100°F and about 21/2 minutes at 1300°F. D.4 Effect of Fire on the Wetted Surface of a Vessel The surface area wetted by a vessel’s internal liquid contents is effective in generating vapor when the area is exposed to fire. To determine vapor generation, only that portion of the vessel that is wetted by its internal liquid and is equal to or less than 25 feet above the source of flame needs to be recognized. The term source of flame usually refers to ground grade but could be at any level at which a substantial spill or pool fire could be sustained. Various classes of vessels are operated only partially full. Table D-2 gives recommended portions of liquid inventory for use in calculations. Portions higher than 25 feet are normally excluded. gree to which the vessel is enveloped by the flames (a function of vessel size and shape), and fireproofing measures. The following equivalent formulas are used to evaluate these conditions where there are prompt fire-fighting efforts and drainage of flammable materials away from the vessel: q = 21,000FA-0.18 (D-1) 21,000FA0.82 (D-2) Q= Where adequate drainage and fire-fighting equipment do not exist, Equation D-2 becomes the following [3]: Q = 34,500FA0.82 (D-1) Where: q = average unit heat absorption, in British thermal units per hour per square foot of wetted surface. Q = total heat absorption (input) to the wetted surface, in British thermal units per hour. F = environment factor. (Values for various types of insulation are shown in Table D-3.) A = total wetted surface, in square feet (see D.4). (The expression A-0.18, or 1/A0.18, is the area exposure factor or ratio. This ratio recognizes the fact that large vessels are less likely than small ones to be completely exposed to the flame of an open fire.) D.5.2 Heat Absorption Across the Unwetted Surface of a Vessel D.5.2.1 Simple Equations See D.3 for a discussion of the effect of fire on the unwetted surface of a vessel. The discharge areas for pressure relief valves on gas-containing vessels exposed to open fires can be determined using the following formula: F´A´ A = ––––– ––– √P1 (D-3) D.5.1 Heat Absorption Across the Wetted Surface of a Vessel F´ can be determined from the following relationship. The recommended minimum value of F´ is 0.01; when the minimum value is unknown, F´ = 0.045 should be used. The amount of heat absorbed by a vessel exposed to open fire is markedly affected by the type of fuel feeding the fire, the de- 0.1406 F´ = –––––– CKD D-5 Heat Absorption Equations © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. (Tω – T1)1.25 ––––––––––– T10.6506 (D-4) 144 Where: A = effective discharge area of the valve, in square inches. A´ = exposed surface area of the vessel, in square feet. P1 = upstream relieving pressure, in pounds per square inch absolute. This is the set pressure plus the allowable overpressure plus the atmospheric pressure. C = coefficient determined by the ratio of the specific heats of the gas at standard conditions. This can be obtained from Figure 26 or Table 9. KD = coefficient of discharge (obtainable from the valve manufacturer). The maximum allowable KD established by ASME is 0.975. Tω = vessel wall temperature, in degrees Rankine. T1 = gas temperature, absolute, in degrees Rankine, at the upstream pressure, determined from the following relationship: P1 T1 = ––– Tη Pη Where: Pη = normal operating gas pressure, in pounds per square inch absolute. Tη = normal operating gas temperature, in degrees Rankine. The recommended maximum vessel wall temperature for the usual carbon steel plate materials is 1100°F. Where vessels are fabricated from alloy metals, the value for Tω should be changed to a more appropriate recommended maximum. D.5.2.2 Rearrangement of Simple Equations The relief load can be calculated directly in pounds per hour by rearranging Equation 2 and substituting Equations D-3 and D-4, which results in the following equation: W = 0.1406 √MP1 T –T ) (A´ (–––––––––– )(D-5) T ω 1 1.25 1.1506 1 Where: M = molecular weight of the gas. Z and Kb in Equation 2 are assumed to equal 1. Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries Figure D-1 – Average Rate of Heating Steel Plates Exposed to Open Gasoline Fire on One Side Plate 1/8-inch thick (as computed) Plate temperature, degrees Fahrenheit (averaged over 24 square feet) 1600 Plate 1/2-inch thick (as computed) Plate 1/8-inch thick (as observed) 1400 1200 Plate 1/2-inch thick (as computed) 1000 800 600 400 200 0 ▲ 0 ▲ 4 ▲ 8 ▲ 12 ▲ 16 ▲ 20 ▲ 24 Minutes after start of fire © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 145 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries Rupture stress (pounds per square inch x 1000) Figure D-2 – Effect of Overheating Steel (ASTM A 515, Grade 70) 100 900°F 1000°F 1100°F 1200°F 1300°F 10 1400° F Oxida tion e ffect 1.0 0.1 ▲ ▲ ▲ ▲ ▲ ▲ 0.01 0.1 1.0 10 100 1000 Time for rupture (hours at indicated temperature) D.5.2.3 Discussion of Simple Equations The derivation of Equations D-3 and D-5 [5] is based on the physical properties of air and the perfect gas laws. The derivation assumes that the vessel is uninsulated and has no mass, that the vessel wall temperature will not reach rupture stress, and that there is no change in fluid temperature. These assumptions should be reviewed to ensure that they are appropriate for any particular situation. D.5.2.4 More Rigorous Calculations When the assumptions in D.5.2.3 are not appropriate, more rigorous methods of calculation may be warranted. In such cases, the necessary physical properties of the containing fluid may need to be obtained from the actual data or estimated from equations of state. The effects of vessel mass and insulation may need to be considered. The pressure-relieving rate is based on an unsteady state. As the fire continues, the vessel wall temperature and the contained gas temperature and pressure increase with time. The pressure relief valve will open at the set pressure, or if the pressure is set too high, the vessel will rupture. With the loss of fluid on relief, the temperatures will further increase at the relief pressure. If the fire is of sufficient duration, the temperature will increase until vessel rupture occurs. Procedures are available for estimating the changes in average vessel wall and contained fluid temperatures that occur with time and the maximum relieving rate at the set pressure [6, 7]. The procedures require successive iteration. D.5.2.5 Additional Protective Measures The determination may be made that a pressure relief valve will not provide sufficient protection for an unwetted wall vessel, and vessel rupture could occur before or too soon after initial relief. Where a pressure relief valve alone is not adequate, additional protective measures should be considered, including insulation (D.8.3.1), water sprays (D.8.3.3), and depressuring (D.8.2) to avoid vessel rupture. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 146 Where calculations indicate that rupture would not occur prior to relief, a rupture disk device could also be considered. The design should allow sufficient time for operator action and initiation of fire-fighting procedures before possible vessel rupture. Operator action may include depressuring, using water sprays, and employing firewater monitors. D.6 Fluids To Be Relieved A vessel may contain liquids or vapors or fluids of both phases. The liquid phase may be subcritical at operating temperature and pressure and may pass into the critical or supercritical range during the duration of a fire as the temperature and pressure in the vessel increase. The quantity and composition of the fluid to be relieved during a fire depend on the total heat input rate to the vessel under this contingency and on the duration of the fire. Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries Table D-2 Wetted Surface Area of A Vessel Based on Fire Heat Absorbed Class of Vessel Portion of Liquid Inventory Remarks Liquid-full, such as treaters All up to the height of 25 feet — Surge drums, knockout drums, process vessels Normal operating level up to the height of 25 feet — Fractionating columns Normal level in bottom plus liquid holdup from all trays; total wetted surface up to the height of 25 feet Level in reboiler is to be included if the reboiler is an integral part of the column Average inventory level up to For tanks of 15 psig operating pressure the height of 25 feet or less; see API Standard 2000 Up to the maximum horizontal diameter or up to the height of 25 feet, whichever is greater — Working storage Spheres and spheroids The total heat input rate to the vessel may be computed by means of one of the formulas in Section D.5 using the appropriate values for wetted or exposed surfaces and for the environment factor. The latent-heat and molecular-weight values used in calculating the rate of vaporization should pertain to the conditions that are capable of generating the maximum vapor rate. the vessel and from the latent heat of liquid contained in the vessel becomes invalid near the critical point of the fluid, where the latent heat approaches zero and the sensible heat dominates. Once the total heat input rate to the vessel is known, the quantity and composition of the fluid to be relieved can be calculated, provided that enough information is available on the composition of the fluid contained in the vessel. The vapor and liquid composition may change as vapors are released from the system. As a result, temperature and latent-heat values could change, thus affecting the required size of the pressure relief device. On occasion, a multicomponent liquid may be heated at a pressure and temperature that exceed the criticals for one or more of the individual components. For example, vapors that are physically or chemically bound in solution may be liberated from the liquid upon heating. This is not a standard latent-heating effect but is more properly termed degassing or dissolution. Vapor generation is determined by the rate of change in equilibrium caused by increasing temperature. When no accurate latent-heat value is available for these hydrocarbons near the critical point, a minimum value of 50 British thermal units per pound is sometimes acceptable as an approximation. If the fluid contained in the vessel is not completely specified, assumptions must be made to obtain a realistic relief flow rate for the relief device. These assumptions may include the following: a. An estimation of the latent heat of boiling liquid and the appropriate molecular weight of the fraction vaporized. b. An estimation of the thermal expansion coefficient if the relieving fluid is a liquid below its boiling temperature, a gas, or a supercritical fluid. D.6.1 Vapor For pressure and temperature conditions below the critical point, the rate of vapor formation—a measure of the rate of vapor relief required—is equal to the total rate of heat absorption divided by the latent heat of vaporization. The vapor to be relieved is the vapor that is in equilibrium with the liquid under conditions that exist when the valve is relieving at its accumulated pressure. For these and other multicomponent mixtures that have a wide boiling range, a time-dependent model may have to be developed where the total heat input to the vessel not only causes vaporization but also raises the temperature of the remaining liquid, keeping it at its boiling point. Reference 7 gives an example of a timedependent model used to calculate relief requirements for a vessel exposed to fire that contains fluids near the critical range or above. The recommended practice of finding a relief vapor flow rate from the heat input to When pressure-relieving conditions are above the critical point, the rate of vapor discharge depends only on the rate at which the fluid will expand as a result of the heat input. D.6.2 Liquid The hydraulic expansion formula given in Appendix C may be used to compute the initial liquid-relieving rate in a liquid-filled system when the liquid is still below its boiling point. However, this rate is valid for a very limited time, after which vapor generation will become the determining contributor in the sizing of the pressure relief device. There is an interim time period between the liquid expansion and the boiling vapor relief in which mixtures of both phases need to be relieved simultaneously, either as flashing, bubble, slug, froth, or mist flow until sufficient vapor space is available inside the vessel for phase separation. This mixed-phase condition is usually neglected, but for some vessels, particularly overfilled steam drums or polymerization © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 147 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries reactors, the limiting relieving contingency may be the factor that would determine the size of the relieving device. (See D.6.3 for information about mixed-phase flow.) Should a pressure relief device be located in the liquid zone of a vessel exposed to fire conditions, the pressure relief device must be able to pass a volume of liquid equivalent to the displacement caused by vapor generated by the fire. D.6.3 Mixed Phase As stated in D.6.2, mixed-phase flow may sometimes be the limiting relieving contingency and thus will determine the size of the pressure relief device. This is particularly true for reactors during runaway reactions that may be caused by lack of cooling or excess heat input (for example, under fire). The Design Institute for Emergency Relief Systems recently concluded an intensive research program to develop methods for the design of emergency relief systems to handle runaway reactions. The interested reader is advised to study some introductory publications [8-12] on this subject in Chemical Engineering Progress, August 1985. D.7 Data on Latent Heat of Vaporization of Hydrocarbons Different hydrocarbon liquids have different latent heats of vaporization even though hydrocarbons as a group behave similarly to one another. The latent heat of vaporization of a pure single-component liquid decreases as the temperature at vaporization increases and the latent heat becomes zero at the critical temperature and pressure for that liquid. Figure D-3 shows the vapor pressures and latent heats of the pure single-component paraffin-hydrocarbon liquids. This chart is directly applicable to such liquids and applies as an approximation to paraffin-hydrocarbon mixtures composed of two components whose molecular weights vary no more than propane to butane and butane to pentane. The chart may also be applicable to isomer hydrocarbons, aromatic or cyclic compounds, or paraffin-hydrocarbon mixtures of components that have slightly divergent molecular weights. The equilibrium temperature should be calculated. Using the relationship for the calculated temperature versus vapor pressure, the latent heat can then be obtained from Figure D-3. The molecular-weight relationship as shown by the chart is not to be used in such cases; the molecular weight of the vapor should be determined from the vapor-liquid equilibrium calculation. For cases that involve mixtures of components that have a wide boiling range or widely divergent molecular weights, a rigorous series of equilibrium calculations may be required to estimate vapor generation rates, as discussed in D.6.1. Other recognized sources [13] of latentheat data or methods of calculating latent heat of vaporization should be used where Figure D-3 does not apply. D.8 Protecting Vessels Against Fire Exposure The measures described in D.8.1 through D.8.3 for protecting vessels against fire exposure are contingent on proper drainage away from the vessel so that pools of fuel cannot accumulate beneath them. Improper drainage under fire conditions will limit the effectiveness of any of these measures in reducing the intensity of heat absorption by the vessels. Table D-3 Notes Environment Factor Type of Equipment Bare vessel Factor F1 1.0 vessel2 Insulated (These arbitrary insulation conductance values are shown as examples and are in British thermal units per hour per square foot per degree Fahrenheit): 4 0.3 2 0.15 1 0.075 0.67 0.05 0.5 0.0376 0.4 0.03 0.33 0.026 Water-application facilities, on bare vessel3 1.0 Depressurizing and emptying facilities4 1.0 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 148 1. These are suggested values for the conditions assumed in D.5.1. When these conditions do not exist, engineering judgment should be exercised either in selecting a higher factor or in providing means of protecting vessels from fire exposure as suggested in D.8. 2. Insulation shall resist dislodgement by firehose streams. For the examples, a temperature difference of 1600°F was used. These conductance values are based on insulation having thermal conductivity of 4 BTU/hr-Ft2-°F per inch at 1600°F and correspond to various thicknesses of insulation between 1 and 12 inches. 3. See D.8.3.3. 4. See D.8.2. Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part I (July 1991) - Sizing, Selection Excerpts from API - 520 Part I Sizing, Selection, and Installation of Pressure Relieving Devices in Refineries D.8.1 Effectiveness of Pressure Relief Devices as Related to Fire Exposure The effect of fire exposure on the unwetted surface of vessels is described in D.3. A pressure relief device does not prevent weakening and failure of a vessel that becomes locally overheated and overstressed at an unwetted surface. It will only prevent the internal pressure from rising beyond the allowable accumulation pressure. A vessel may be protected against such failure by (a) depressurizing the vessel and (b) limiting the heat input. D.8.2 Depressuring Systems Controlled depressuring of the vessel reduces internal pressure and stress in the vessel walls. It also guards against the potential addition of fuel to the fire should the vessel rupture. The design of depressuring systems should recognize the following factors: a. Manual controls near the vessel may be inaccessible during an emergency. b. Unless anticipated, automatic controls could fail in a direction that would prevent depressuring (for example, valves that fail closed). c. Early initiation of depressuring is desirable to limit vessel stress to acceptable levels commensurate with the vessel wall temperature that results from a fire. d. Safe disposal of vented streams must be provided. e. No credit is recommended when safety valves are being sized for fire exposure. Further information on depressuring is provided in API Recommended Practice 521. D.8.3 Methods of Limiting Heat Input From Fire D.8.3.1 External Insulation Limiting the heat input from fires by external insulation reduces both the rise of the vessel wall temperature and the generation of vapor inside the vessel. Insulation may also reduce the problem of disposing of the vapors and the expense of providing an exceptionally large relieving system to conduct the effluent to a point of disposal. The insulation must be fire resistant and protected from dislodgement by fire-hose streams (see API Recommended Practice 521). Where insulation or fireproofing is applied, the heat absorption can be computed by assuming that the outside temperature of the insulation jacket or other outer covering has reached an equilibrium temperature of 1660°F. With this temperature and the operating temperature for the inside of the vessel, together with the thickness and conductivity of the fire-protection coating, the average heat transfer rate to the contents can be computed. It must be kept in mind that the thermal conductivity of the insulation increases with the temperature, and a mean value should be used. D.8.3.2 Earth-Covered Storage Covering a pressure vessel with earth is another effective method of limiting heat input. The reduction of heat absorption due to the earth cover can be calculated as suggested in D.8.3.1. D.8.3.3 Cooling the Surface of a Vessel With Water Under ideal conditions, water films covering the metal surface can absorb most incident radiation. The reliability of water application depends on many factors. Freezing weather, high winds, clogged systems, undependable water supply, and vessel surface conditions can prevent uniform water coverage. Because of these uncertainties, no reduction in environment factor (see Table D-3) is recommended; however, as stated previously, properly applied water can be very effective. D.8.3.4 Limiting Fire Areas With Diversion Walls Diversion walls can be provided to deflect vessel spills from other vessels. For insulated vessels, the environment factor for insulation becomes the following: k (1660 – Tf) F = –––––––––––– 21,000t Where: k = thermal conductivity of insulation, in British thermal units per hour per square foot per degree Fahrenheit per inch at mean temperature. Tf = temperature of vessel contents at relieving conditions, in degrees Fahrenheit. t = thickness of insulation, in inches. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 149 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part II (July 1991) - Valve Installation Excerpts from API - 520 Part II Installation Section 1 – General 1.1 Scope This recommended practice is intended to cover methods of installation for pressure relief devices for equipment that has a maximum allowable working pressure (MAWP) of 15 pounds per square inch gauge (psig) (1.03 barg) or greater. Pressure relief valves or rupture disks may be used independently or in combination with each other to provide the required protection against excessive pressure accumulation. As used in this recommended practice, the term pressure relief valve includes safety relief valves used in either compressible or incompressible fluid service, and relief valves used in incompressible fluid service. This recommended practice covers gas, vapor, steam, and incompressible service; it does not cover special applications that require unusual installation considerations. 1.2 Definition of Terms The terminology for pressure relief devices that is used in this recommended practice is in general agreement with the definitions given in ASME PTC 25. Section 2 – Inlet Piping 2.1 General Requirements For general requirements for inlet piping, see Figures 1 and 2. 2.1.1 Flow and Stress Considerations Inlet piping to the pressure relief device should provide for proper system performance. This requires design consideration of the flow-induced pressure drop in the inlet piping. Excessive pressure losses in the piping system between the protected vessel and a pressure relief device will adversely affect the system-relieving capacity and can cause valve instability. In addition, the effect of stresses derived from both pressure relief device operation and externally applied loads must be considered. For more complete piping design guidelines, see ASME B31.3. 2.1.2 Vibration Considerations Most vibrations that occur in inlet piping systems are random and complex. These vibrations may cause leakage at the seat of a pressure relief valve, premature opening, or premature fatigue failure of certain valve parts, inlet and outlet piping, or both. Vibration in inlet piping to a rupture disk may adversely affect the burst pressure and life of the rupture disk. Figure 1 – Typical Pressure Relief Valve Installation: Atmospheric (Open) Discharge Detrimental effects of vibrations on the pressure relief device can be reduced by minimizing the cause of vibrations, by additional piping support, by use of either pilot-operated relief valves or soft-seated pressure relief valves, or by providing greater pressure differentials between the operating pressure and the set pressure. Weather cap may be required 2.2 Pressure-Drop Limitations and Piping Configurations For pressure-drop limitations and piping configurations, see Figures 1-4. 2.2.1 Pressure Loss at the Valve Inlet Excessive pressure loss at the inlet of a pressure relief valve can cause rapid opening and closing of the valve, or chattering. Chattering will result in lowered capacity and damage to the seating surfaces. The pressure loss that affects valve performance is caused by non-recoverable entrance losses (turbulent dissipation) and by friction within the inlet piping to the pressure relief valve. Chattering has sometimes occurred due to acceleration of liquids in long inlet lines. 2.2.2 Size and Length of Inlet Piping When a pressure relief valve is installed on a line directly connected to a vessel, the total non-recoverable pressure loss between the protected equipment and the pressure relief valve should not exceed 3 percent of the set pressure of the valve except as permitted in 2.2.3.1 for pilot-operated pressure relief valves. When a pressure relief valve is installed on a process line, the 3 percent limit should be applied to the sum of the loss in the normally non-flowing pressure relief valve inlet pipe and the incremental pressure loss in the process line caused by the flow through the pressure relief valve. The pressure loss should be calculated using the rated capacity of the pressure relief valve. Pressure losses can be reduced materially by rounding the entrance to the inlet piping, by reducing the inlet line length, or by enlarging the inlet piping. Keeping the pressure loss below 3 percent becomes progressively more difficult as the orifice size of a pressure relief valve increases. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 150 Long-radius elbow Pressure relief valve Body drain (See Note 1) Nonrecoverable losses not more than 3 percent of set pressure Normal pipe diameter no less than valve inlet size Support to resist weight and reaction forces Vessel Low-point drain (See Note 2) Notes 1. See Section 6. 2. Orient low-point drain – or weep hole – away from relief valve, structural steel, and operating area. Figure 2 – Typical Pressure Relief Valve Installation: Closed System Discharge Bonnet vent piping for bellows type pressure relief valves, if required (See Note 1) To closed system (self-draining) Flanged spool piece, if required to elevate PRV Nonrecoverable pressure losses not more than 3 percent of set pressure Nominal pipe diameter no less than valve inlet size Vessel Note 1. See Section 5. Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part II (July 1991) - Valve Installation Excerpts from API - 520 Part II Installation Figure 3 – Typical Pressure Relief Valve Mounted on Process Line See 2.2.2 for pressure-loss limitation Vessel The nominal size of the inlet piping must be the same as or larger than the nominal size of the pressure relief valve inlet flange connection as shown in Figure 2. An engineering analysis of the valve performance at higher inlet losses may permit increasing the allowable pressure loss above 3 percent. Pressure Relief Valve Note 1. See 2.2.2 for pressure-loss limitation. Figure 4 – Typical Pressure Relief Valve Mounted on Long Inlet Pipe Pressure Relief Valve Discharge Piping Inlet piping sized so that pressure drop from vessel to pressure relief valve inlet flange does not exceed 3% of valve set pressure 2.2.3.2 Installation Guidelines Remote sensing lines should measure static pressure where the velocity is low. Otherwise, the pilot will sense an artificially low pressure due to the effect of velocity. Ensure that the pilot sensing point is within the system protected by the main valve. When a rupture disk device is used in combination with a pressure relief valve, the pressure-drop calculation must include the additional pressure drop developed by the disk (see 2.6 for additional information on rupture disk devices). For flowing pilots, remote sensing lines shall be sized to limit the pressure loss to 3 percent of the set pressure based on the maximum flow rate of the pilot at 110 percent of set pressure. Consult the manufacturer for recommendations. 2.2.3 Remote Sensing for Pilot Operated Pressure Relief Valves Remote sensing for pilot-operated pressure relief valves can be utilized when there is excessive inlet pipe pressure loss or when the main valve must be located at a pressure source different from the pilot sensing point because of service limitations of the main valve (see Figure 5). For non-flowing pilots, remote sensing lines with a flow area of 0.070 square inches (45 square millimeters) is sufficient since no system medium flows through this type of pilot when the main valve is open and relieving. 2.2.3.1 Inlet Pipe Loss Remote sensing permits the pilot to sense the true system pressure upstream of the piping loss. Remote sensing may eliminate uncontrolled valve cycling or chattering for a pop action pressure relief valve and will permit a modulating action pressure relief valve to achieve full lift at the required overpressure. However, high inlet pressure losses may induce pressure pulsations in the inlet piping that can cause uncontrolled main valve cycling. Some valves incorporate design features to prevent uncontrolled cycling Although remote sensing may eliminate valve chatter or permit a modulating valve to achieve full lift at the required overpressure, the relieving capacity will be reduced by any pressure drop in the inlet pipe. Consider using pipe for remote sensing lines to ensure mechanical integrity. If a block valve is installed in the remote sensing line, the guidelines in Section 4 should be followed. A closed block valve in a remote sense line renders the pressure relief valve inoperative. 2.2.4 Configuration of Inlet Piping for Pressure Relief Valves Avoid the installation of a pressure relief valve at the end of a long horizontal inlet pipe through which there is normally no flow. Foreign matter may accumulate, or liquid may be trapped, creating interference with the valve’s operation or requiring more frequent valve maintenance. The inlet piping system to relief valves should be free-draining from the pressure relief device to prevent accumulation of liquid or foreign matter in the piping. Vessel Note 1. Inlet piping sized so that nonrecoverable pressure losses form vessel to pressure relief valve inlet flange do not exceed 3 percent of valve set pressure. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 151 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part II (July 1991) - Valve Installation Excerpts from API - 520 Part II Installation 2.3 Inlet Stresses That Originate From Static Loads in the Discharge Piping ing moments will cause excessive stresses on any of the components in the system. Improper design or construction of the discharge piping from a pressure relief device can set up stresses that will be transferred to the pressure relief device and its inlet piping. These stresses may cause a pressure relief valve to leak or malfunction or may change the burst pressure of a rupture disk. The pressure relief device manufacturer should be consulted about permissible loads and moments. The magnitude of the reaction force will differ substantially depending on whether the installation is open or closed discharge. When an elbow is installed in the discharge system to direct the fluid up into a vent pipe, the location of the elbow and any supports is an important consideration in the analysis of the bending moments. 2.3.1 Thermal Stresses Fluid flowing from the discharge of a pressure-relieving device may cause a change in the temperature of the discharge piping. A change in temperature may also be caused by prolonged exposure to the sun or to heat radiated from nearby equipment. Any change in the temperature of the discharge piping will cause a change in the length of the piping and may cause stresses that will be transmitted to the pressure relief device and its inlet piping. The pressure relief device should be isolated from piping stresses through proper support, anchoring, or flexibility of the discharge piping. 2.3.2 Mechanical Stresses Discharge piping should be independently supported and carefully aligned. Discharge piping that is supported by only the pressure relief device will induce stresses in the pressure relief device and the inlet piping. Forced alignment of the discharge piping will also induce such stresses. 2.4.1 Determining Reaction Forces in an Open Discharge System The following formula is based on a condition of critical steady-state flow of a compressible fluid that discharges to the atmosphere through an elbow and a vertical discharge pipe. The reaction force (F) includes the effects of both momentum and static pressure; thus, for any gas, vapor, or steam, -------------------kT ––––––– (k + 1)M √ [Metric Units] F = 129 W Main Valve Pilot Integral pressure sensing Optional remote pressure sensing Vessel Note 1. See 2.2.3. English Units W F = –––– 366 Figure 5 – Typical Pilot-Operated Pressure Relief Valve Installation + (AP) -------------------kT ––––––– + 0.1 (AP) (k + 1)M √ Figure 6 – Typical Pressure Relief Valve Installation With Vent Pipe F Ao (crosssection area) Vent Pipe Where: F = reaction force at the point of discharge to the atmosphere, in pounds [newtons]. W = flow of any gas or vapor, in pounds per hour [kilograms per second]. Long-radius Elbow Pressure Relief Valve k = ratio of specific heats (Cp/Cv). 2.4 Inlet Stresses That Originate From Discharge Reaction Forces Cp = specific heat at constant pressure. The discharge of a pressure relief device will impose a reaction force as a result of the flowing fluid (see Figure 6). This force will be transmitted into the pressure relief device and also into the mounting nozzle and adjacent supporting vessel shell unless designed otherwise. The precise magnitude of the loading and resulting stresses will depend on the reaction force and the configuration of the piping system. The designer is responsible for analyzing the discharge system to determine if the reaction forces and the associated bend- T = temperature at inlet, in degrees Rankine [in degrees Kelvin]. Free support to resist weight and reaction forces. Cv = specific heat at constant volume. Vessel M = molecular weight of the process fluid. A = area of the outlet at the point of discharge, in square inches [square millimeters]. P = static pressure within the outlet at the point of discharge, in pounds per square inch gauge [bar gauge]. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 152 Notes 1. The support should be located as close as possible to the centerline of the vent pipe. 2. F = reaction force A = cross-sectional area. Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part II (July 1991) - Valve Installation Excerpts from API - 520 Part II Installation Figure 7 – Typical Rupture Disk Assembly Installed in Combination With a Pressure Relief Valve 2.4.2 Determining Reaction Forces in a Closed-Discharge System Pressure relief devices that relieve under steady-state flow conditions into a closed system usually do not create large forces and bending moments on the exhaust system. Only at points of sudden expansion will there be any significant reaction forces to be calculated. Closed-discharge systems, however, do not lend themselves to simplified analytic techniques. A complex time-history analysis of the piping system may be required to obtain the true values of the reaction forces and associated moments. 2.5 Isolation Valves in Inlet Piping Pressure Gauge Isolation valves located in the inlet piping to pressure relief devices shall be in accordance with the guidelines in Section 4. 2.6 Rupture Disk Devices in Combination with Pressure Relief Valves A rupture disk device may be used as the sole pressure relief device, or it may be installed between a pressure relief valve and the vessel or on the downstream side of a pressure relief valve (see Figure 7). Bleed Valve Rupture disk (See Note 1) Excess Flow Valve (optional) Figure 8 – Installation Avoiding Process Laterals Connected to Pressure Relief Valve Inlet Piping Aviod process laterals (See Note 1) Pressure Relief Valve Vessel For ASME Boiler and Pressure Vessel Code applications, the capacity of a pressure relief valve used in combination with a rupture disk mounted as shown in Figure 7 must be derated by 10 percent unless that particular combination has a capacity factor derived from testing as listed in the National Board of Boiler and Pressure Vessel Inspectors’ publication, Pressure Relief Device Certifications. When a rupture disk device is used between the pressure relief valve and the protected vessel, a pressure indicator, bleed valve, free vent, or suitable telltale indicator should be provided to permit detection of disk rupture or leakage. The user is cautioned that any pressure buildup between the rupture disk and the pressure relief valve will increase the vessel pressure at which the rupture disk will burst. Only non-fragmenting rupture disk devices may be used beneath a pressure relief valve. Rupture disks are not available in all sizes at lower pressures; therefore, for these low-pressure applications the available rupture disk may have to be larger than the nominal size of the inlet piping and pressure relief valve. Refer to API Recommended Practice 520, Part I, paragraphs 2.5 (Rupture DisksGeneral) and 2.6 (Rupture Disks in Combination with Pressure Relief Valves) for additional information. 2.7 Process Laterals Connected to Inlet Piping of Pressure Relief Valves Process laterals should generally not be connected to the inlet piping of pressure relief valves. Exceptions should be analyzed carefully to ensure that the allowable pressure drop at the inlet of the pressure relief valve is not exceeded under simultaneous conditions of rated flow through the pressure relief valve and maximum possible flow through the process lateral (see Figure 8). 2.8 Turbulence in Pressure Relief Device Inlets See 7.3 for information regarding the effects of turbulence on pressure relief valves. Section 3 – Discharge Piping From Pressure Relief Devices 3.1 General Requirements For general requirements for discharge piping, see Figures 1, 2, 6, and 9. The discharge piping installation must provide for proper pressure relief device performance and adequate drainage (freedraining systems are preferred - see Section 6). Consideration should be given to the type of discharge system used, the back pressure on the pressure relief device, and the set-pressure relationship of the pressure relief devices in the system. Auto-refrigeration during discharge can cool the outlet of the pressure relief device and the discharge piping to the point that brittle fracture can occur. Materials must be selected which are compatible with the expected temperature. Note 1. See 2.7. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 153 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part II (July 1991) - Valve Installation Excerpts from API - 520 Part II Installation 3.2 Safe Disposal of Relieving Fluids 3.6 Isolation Valves in the Discharge Piping For a comprehensive source of information about the safe disposal of various relieving fluids, see API Recommended Practice 521. Isolation valves located in the discharge piping system shall be in accordance with the guidelines in Section 4. 3.3 Back Pressure Limitations and Sizing of Pipe Section 4 – Isolation (stop) Valves in Pressure Relief Piping When discharge piping for pressure relief valves is designed, consider the combined effect of superimposed and built-up back pressure on the operating characteristics of the pressure relief valves. The discharge piping system should be designed so that the back pressure does not exceed an acceptable value for any pressure relief valve in the system. 4.1 General When rupture disks are used as the sole relieving device and discharge into a closed system, the effect of the superimposed back pressure on the bursting pressure for the disk must be considered. The rated capacity of the pressure relief valve shall be used to size the discharge line from the pressure relief valve to the relief header. Additional information on sizing of discharge piping systems for vapor or gas service is covered in API Recommended Practice 521. 3.4 Considerations for PilotOperated Pressure Relief Valves Superimposed back pressure that exceeds the inlet pressure of a pilot-operated pressure relief valve can cause the main valve to open, allowing reverse flow through the main valve. For example, backflow can occur if several pressure relief valves have their outlets manifolded into a common discharge header, and one or more of these valves is discharging while another is connected to a system with a lower inlet pressure. An accessory should be specified that will prevent such backflow. 3.5 Stresses that Originate from Discharge Piping The effects of stresses that originate from discharge piping are discussed in 2.3.1 and 2.3.2. Block valves may be used to isolate a pressure relief device from the equipment it protects or from its downstream disposal system. Since improper use of block valve may render a pressure relief device inoperative, the design, installation, and management of these isolation block valves should be carefully evaluated to ensure that plant safety is not compromised. Figure 9 – Typical Pressure Relief Valve Installation with an Isolation Valve Isolation valve with provision for car sealing or locking open (not required for atmosheric discharge) (See Note 1) To closed system or atmoshperic piping Typical blinding points Bleed valve installed on valve body (See Note 3) Bleed valve Isolation valve with provision for car sealing or locking open Nonrecoverable pressure losses not mor than 3 percent of set pressure Flanged spool piece, if required to elevate PRV 4.2 Application If a pressure relief device has a service history of leakage, plugging, or other severe problems which affect its performance, isolation and sparing of the relief device may be provided. This design strategy permits the pressure relief device to be inspected, maintained, or repaired without shutting down the process unit. However, there are potential hazards associated with the use of isolation valves. The ASME Boiler and Pressure Vessel Code, Section VIII, Appendix M, discusses proper application of these valves and the administrative controls which must be in place when isolation block valves are used. Local jurisdictions may have other requirements. Additional examples of isolation valve installations are given in 4.4. 4.3 Isolation Valve Requirements In addition to previously noted inlet and outlet pressure drop restrictions, all isolation valves located in relief system piping shall meet the following requirements: a. Valves shall be full bore. b. Valves shall be suitable for the line service classification. c. Valves shall have the capability of being locked or carsealed open. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 154 Bonnet vent piping for bellows type pressure relief valves, if required (See Note 2) Vessel d. When gate valves are used, they should be installed with stems oriented horizontally or, if this is not feasible, the stem could be oriented downward to a maximum of 45° from the horizontal to keep the gate from falling off and blocking the flow. Consider painting the isolation valves a special color or providing other identification. When isolation valves are installed in pressure relief valve discharge piping, a means to prevent pressure buildup between the pressure relief valve and the isolation valve should be provided (for example, a bleeder valve). Also, the installation of bleed valves should be considered to enable the system to be depressured prior to performing maintenance on the system as shown in Figures 9 through 12. Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part II (July 1991) - Valve Installation Excerpts from API - 520 Part II Installation Figure 10 – Typical Pressure Relief Valve Installation Arrangement for 100 Percent Spare Relieving Capacity To closed (isolation valving required) or atmosheric discharge system Nonrecoverable pressure losses not more than 3 percent of set pressure Typical bleed valve Vessel Consider the installation of an additional relief device, so that 100 percent design relieving capacity is available while any relief device is out of service. Examples of this type of installation are shown in Figures 10 and 11. Consider storing the spare valve until needed to preserve its integrity and allow bench testing just prior to installation. When spare relief devices are provided, a mechanical interlock or interlocking procedure shall be provided which manages proper opening and closing sequences of the isolation valves to ensure that overpressure protection of the vessel or equipment is not compromised. Typically the inlet isolation valves for spare relief valves are closed. Three-way isolation valves are acceptable provided the installation meets the size and inlet pressure drop requirements. 4.4 Examples of Isolation Valve Installations An isolation valve downstream of a pressure relief device may be installed at battery limits of process units. This is illustrated in Figure 12. The purpose of battery limit isolation valves is to allow process units to be removed from service for maintenance while other process units discharging into the main plant flare header remain in service. Similarly, relief system isolation valves may be used for equipment such as compressors, salt dryers, or coalescers, which are spared and need to be shut down for maintenance while spare equipment remains online (see Figure 13). 4.5 Management Procedures Related to Isolation Valves Strict management procedures should be in place that will prohibit the inadvertent closing of isolation valves in relief piping. These procedures should require that the opening and closing of the valves be done by an authorized person. An updated list should be kept of all isolation valve located in relief piping which could isolate relief valves. Documentation of the required position and reason for the lock or seal should be provided. Periodic inspections of isolation valves located in relief piping should be made which verify the position of valves and the condition of the locking or sealing device. Section 5 – Bonnet or Pilot Vent Piping 5.2 Balanced Bellows Valves Balanced bellows valves are utilized in applications where it is necessary to minimize the effect of back pressure on the set pressure and relieving capacity. This is done by balancing the effect of the back pressure on the top and bottom sides of the disk. This requires the spring to operate at atmospheric pressure. The bonnets of bellows valves must always be vented to ensure proper functioning of the valve and to provide a tell tale in the even of a bellows failure. The vent must designed to avoid plugging caused by ice, insects, or other obstructions. When the fluid is flammable, toxic, or corrosive, the bonnet vent may need to be piped to a safe location. 5.3 Balanced Piston Valves Balanced piston valves are utilized in applications to minimize the effect of back pressure, similar to the balanced bellows valve. Proper operation depends on cancellation of the back pressure effect on opposing faces of the valve disk and balance piston. Since the piston area is equal to the nozzle seat area, the spring must operate at atmospheric pressure. Because of the flow of system media past the piston, the bonnets of balanced piston valves should always be vented to atmosphere at a safe location. The amount of flow past the piston into the bonnet depends on the pressure differential between the valve outlet and bonnet. In an installation where superimposed back pressure of built-up back pressure is high, the flow past the piston could be substantial. This factor must be considered in the design of the bonnet venting. 5.1 Conventional Valves The two types of conventional valves are: a. Open spring, often used in steam service. b. Closed spring, where the bonnet enclosing the spring is vented internally to the pressure relief valve discharge. The bonnet normally has a tapped vent that is closed off with a threaded plug. 5.4 Pilot-Operated Valves The pilot is often vented to the atmosphere under operating conditions, since the discharge during operation is small. When vent discharge to the atmosphere is not permissible, the pilot should be vented either to the discharge piping or through a supplementary piping system to a safe location. When vent piping is designed, avoid the possibility of back pressure on the pilot unless the pilot is a balanced design. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 155 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part II (July 1991) - Valve Installation Excerpts from API - 520 Part II Installation Section 6 – Drain Piping 6.1 Installation Conditions that Require Drain Piping Drain piping is normally not required on pressure relief valves at the valve body connection provided for this purpose. The outlet piping to closed systems should be self-draining to a liquid disposal point, thereby eliminating the need for a drain from the valve. Drainage must be provided when the discharge is not self-draining and the valve is located where liquids could accumulate at the valve outlet. 6.2 Safe Practice for Installation of Drain Piping Since drain piping becomes part of the entire venting system, precautions that apply to the discharge system apply similarly to the drain piping. The drain-piping installation must not adversely affect the valve performance, and flammable, toxic, or corrosive fluids must be piped to a safe location. Section 7 – Pressure Relief Device Location and Position 7.1 Inspection and Maintenance For optimum performance, pressure relief devices must be serviced and maintained regularly. Details for the care and servicing of specific pressure relief devices are provided in the manufacturer's maintenance bulletins and in API Recommended Practice 576. Pressure relief devices should be located for easy access, removal, and replacement so that servicing can be properly handled. Sufficient working space should be provided around the pressure relief device. 7.2 Proximity to Pressure Source The pressure relief device should normally be placed close to the protected equipment so that the inlet pressure losses to the device are within the allowable limits. For example, where protection of a pressure vessel is involved, mounting the pressure relief device directly on a nozzle on top of the vessel may be necessary. However, on installations that have pressure fluctuations at the pressure source (as with valves on a positive displacement compressor discharge) that peak close to the set pressure of the pressure relief valve or burst pressure of a rupture disk, the pressure relief device should be located farther from the source and in a more stable pressure region. (See Section 2 for information related to this subject.) Figure 12 – Typical Flare Header Block Valves Battery limit 7.3 Proximity to Other Equipment Pressure relief devices should not be located where unstable flow patterns are present (see Figure 14). The branch entrance where the relief device inlet piping joins the main piping run should have a well-rounded, smooth corner that minimizes turbulence and resistance to flow. To main flare header Pressure relief valve installation (See Note 4) When pressure relief branch connections are mounted near equipment that can cause unstable flow patterns, the branch connection should be mounted downstream at a distance sufficient to avoid the unstable flow. Examples of devices that cause unstable flow are discussed in 7.3.1 through 7.3.3. 7.3.1 Reducing Stations Pressure relief devices are often used to protect piping downstream from pressure reducing valves, where unstable flow usually occurs. Other valves and appurtenances in the system may also disturb the flow. This condition cannot be evaluated readily, but unstable flow at valve inlets tends to generate instability. 7.3.2 Orifice Plates and Flow Nozzles Proximity to orifice plates and flow nozzles may cause adverse operation of the pressure relief devices. 7.3.3 Other Valves and Fittings Proximity to other fittings, such as elbows, may create turbulent areas that could result in adverse performance of pressure relief devices. 7.4 Mounting Position Pressure relief valves should be mounted in a vertical upright position. Installation of a pressure relief valve in other than a vertical upright position may adversely affect its operation. The valve manufacturer should be consulted about any other mounting position, since mounting a pressure relief valve in other positions may cause a shift in the set pressure and a reduction in the degree of seat tightness. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 156 Process unit flare header block valve (See Note 1) Process unit relief header (self draining) Isolation blind point (See Note 2) Pressure vessel A Pressure vessel B Pressure relief valve installation (See Note 3) Notes 1. 2. 3. 4. See 4.4. See Figure 8. See Figures 10 and 11. See Figures 2 and 9. Additionally, another position may permit liquids to collect in the spring bonnet. Solidification of these liquids around the spring may interfere with the valve operation. 7.5 Test or Lifting Levers Test or lifting levers should be provided on pressure relief valves as required by the applicable code. Where simple levers are provided, they should hang downward, and the lifting fork must not contact the lifting nuts on the valve spindle. Uploads caused by the lifting-mechanism bearing on the spindle will cause the valve to open below the set pressure. The lifting mechanism should be checked to ensure that it does not bind on the valve spindle. Where it is necessary to have the test lever in other than a vertical position, or where the test lever is arranged fro remote Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part II (July 1991) - Valve Installation Excerpts from API - 520 Part II Installation Figure 13 – Typical Isolation Block Valves for Spare Compressor Pulsation dampners From spare compressor Isolation block valves (See Note 1) Compressor relief headers Isolation blind points Bleed valve 1 First stage 2 Second stage 3 Process unit flare header Third stage Note 1. See 4.4. manual operation, the lever should be counterbalanced so that the lifting mechanism, unless actuated, does not exert any force on the valve spindle lifting nut. In lieu of lifting levers for pilot-operated pressure relief valves, means may be specified for connecting and applying adequate pressure to the pilot to verify that the moving parts critical to proper operation are free to move. 7.6 Heating Tracing and Insulation For materials which are highly viscous, could result in corrosion upon cooling, or could potentially solidify in pressure relief valves, adequate heat tracing or insulation should be provided for both inlet and outlet piping. Ensure that the valve nameplate and any discharge vent port are not covered when the valve is insulated. Section 8 – Bolting and Gasketing 8.1 Care in Installation Before a pressure relief device is installed, the flanges on the pressure relief valve or rupture disk holder and the mounting noz- zle should be thoroughly cleaned to remove any foreign material that may cause leakage. Where pressure relief devices are too heavy to be readily lifted by hand, the use of proper handling devices will avoid damage to the flange gasket facing. Ring joint and tongue-and-groove facings should be handled with extreme care so that the mating sections are not damaged. 8.2 Proper Gasketing and Bolting for Service Requirements The gasket used must be dimensionally correct for the specific flanges; they must fully clear the pressure relief device inlet and outlet openings. Gaskets, flange facings, and bolting should meet the service requirements for the pressure and temperature involved. This information can be obtained by referring to other national standards and to manufacturers’ technical catalogs. When a rupture disk device is installed in the pressure relief system, the flange gasket material and bolting loads may be critical. The disk manufacturer’s instructions should be followed for proper performance. Section 9 – Multiple Pressure Relief Valves with Staggered Settings Normal practice is to size a single pressure relief valve to handle the maximum relief from a piece of equipment. However, for some systems, only a fraction of that amount must be relieved through the pressure relief valve during mild upsets. If the fluid volume under a pressure relief valve is insufficient to sustain the flow, the valve operation will be cyclic and will result in poor performance. The valve's ability to reseat tightly may be affected. When capacity variations are frequently encountered in normal operation, one alternate is the use of multiple, smaller pressure relief valves with staggered settings. With this arrangement, the pressure relief valve with the lowest setting will be capable of handling minor upsets, and additional pressure relief valves will be put in operation as the capacity requirement increases. For inlet piping to multiple relief valves, the piping which is common to multiple valves must have a flow area which is at least equal to the combined inlet areas of the multiple pressure relief valves connected to it. Refer to API Recommended Practice 520, Part I, to determine set pressure of the pressure relief valves based on maximum allowable pressure accumulation for multiple valve installations. An alternate to the use of multiple pressure relief valves with staggered settings is the use of a modulating pilot-operated relief valve. Section 10 – Preinstallation Handling and Inspection 10.1 Storage and Handling of Pressure Relief Devices Because cleanliness is essential to the satisfactory operation and tightness of a pressure relief valve, take precautions to keep out all foreign materials. Valves should be closed off properly at both inlet and outlet flanges. Take particular care to keep the valve inlet absolutely clean. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 157 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 520 Part II (July 1991) - Valve Installation Excerpts from API - 520 Part II Installation Pressure relief valves should, when possible, be stored indoors on pallets away from dirt and other forms of contamination. Pressure relief devices should be handled carefully and should not be subjected to shocks, which can result in considerable internal damage or misalignment. For valves seat tightness may be adversely affected. Ruptured disks should be stored in the original shipping container. 10.2 Inspection and Testing of Pressure Relief Valves The condition of all pressure relief valves should be visually inspected before installation. Consult the manufacturer’s instruction manuals for details relating to the specific valve. Ensure that all protective material on the valve flanges and any extraneous materials inside the valve body and nozzle are completely removed. Bonnet shipping plugs must be removed from balanced pressure relief valves. The inlet surface must be cleaned, since foreign materials clinging to the inside of the nozzle will be blown across the seats when the valve is operated. Some of these materials may damage the seats or get trapped between the seats in such a way that they cause leakage. Valves should be tested before installation to confirm set pressure. 10.3 Inspection of Rupture Disk Devices All rupture disk devices should be thoroughly inspected before installation, according to the manufacturer’s instruction manuals. The seating surfaces of the rupture disk holder must be clean, smooth, and undamaged. Rupture disks should be checked for physical damage to the seating surfaces or the prebulged disk area. Damaged or dented disk should not be used. Apply the proper installation and torquing procedure as recommended by the rupture disk device manufacturer. Figure 14 – Typical Installation Avoiding Unstable Flow Patterns at Pressure Relief Valve Inlet On reverse-buckling disk that have knifeblade assemblies, the knife blades must be checked for physical damage and sharpness. Nicked or dull blades must not be used. Damaged rupture disk holders must be replaced. 10.4 Inspection and Cleaning of Systems Before Installation Because foreign materials that pass into and through pressure relief valves can damage the valve, the systems on which the valves are tested and finally installed must also be inspected and cleaned. New systems in particular are prone to contain welding beads, pipe scale, and other foreign objects that inadvertently get trapped during construction and will destroy the seating surface when the valve opens. The system should be thoroughly cleaned before the pressure relief valve is installed. Pressure relief devices should be removed or isolated before hydrotesting or pneumatic pressure testing of the system, either by blanking or closing an isolation valve. If an isolation valve is used, the flange at the pressure relief device should be wedged open or a bleed valve provided so that inadvertent leaking through the isolation valve does not damage the pressure relief device. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 158 Inlet flanges Inlet pipe Rounded entry branch connection Run Pipe Flow D Note 1. D is typically not less than 10 pipe diameters from any device that causes unstable flow. Anderson Greenwood Pressure Relief Valves Technical Manual Following is an Excerpt from NACE MR0175-95, API - RP 521, and API - RP 527 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 159 Anderson Greenwood Pressure Relief Valves Technical Manual NACE MR0175-95 Excerpts on Valve Materials Section 3: Ferrous Metals Ferrous metals shall meet the requirements of this section if they are to be exposed to sour environments (defined in Paragraph 1.3). 3.1 General The susceptibility to SSC of most ferrous metals can be strongly affected by heat treatment, cold work, or both. The following paragraphs describe heat treatments for specific materials that have been found to provide acceptable resistance to SSC. 3.2 Carbon and Low-Alloy Steels 3.2.1 All carbon and low-alloy steels are acceptable at 22 HRC maximum hardness provided they (1) contain less than 1% nickel, (2) meet the criteria of Paragraphs 3.2.2, 3.3, and Section 5, and (3) are used in one of the following heat-treat conditions: (a) hot-rolled (carbon steels only); (b) annealed; (c) normalized; (d) normalized and tempered; (e) normalized, austenitized, quenched, and tempered; or (f) austenitized, quenched, and tempered. 3.2.1.1 Forgings produced in accordance with the requirements of ASTM A 105 are acceptable, provided the hardness does not exceed 187 HB maximum. as described in NACE Standard TM0177 are accepted test specimens. Any of these specimens may be used. (2) A minimum of three specimens from each of three different commercially prepared heats must be tested in the (heat-treated) condition balloted for MR0175 inclusion. The composition of each heat and the heat treatment(s) used shall be furnished as part of the ballot. The candidate material’s composition range and/or UNS number and its heattreated condition requested for inclusion in MR0175 must be included with the ballot. (3) The Rockwell hardness of each specimen must be determined and reported as part of the ballot. The average hardness of each specimen shall be the hardness of that specimen. The minimum specimen hardness obtained for a given heat/condition shall be the hardness of that heat/ condition for the purpose of balloting. The maximum hardness requested for inclusion of the candidate material in MR0175 must be specified in the ballot and should be supported by the data provided. (4) Further, in order for the material/ condition to be considered for acceptance, it is required that, for each of the commercial heats tested, stress intensity values, etc. (as applicable to the test method used), of all tests shall also be reported as part of the ballot item when submitted. 3.2.1.2 Acceptance criteria: Wrought carbon and low-alloy steels with a hardness greater than HRC 22 that are not otherwise covered by this materials requirement standard must meet the following minimum criteria for balloting prior to inclusion in this document. These criteria are necessary but may not be sufficient conditions for inclusion in all cases. 3.2.2 The metal must be thermally stress relieved following any cold deforming by rolling, cold forging, or another manufacturing process that results in a permanent, outer fiber deformation greater than 5%. Thermal stress relief shall be performed in accordance with the ASME Code, Section VIII, Division I, except that the minimum stress relief temperature shall be 595°C (1100°F). The component shall have a hardness of 22 HRC maximum. (1) The candidate steel must be tested in accordance with the test procedures established in NACE Standard TM0177 (latest revision). The tensile bar, O-ring, bent beam, and double cantilever beam 3.2.2.1 This requirement does not apply to pipe grades listed in Table 3 or cold work imparted by pressure testing per the applicable code. Cold-rotary straightened © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 160 pipe is acceptable only where permitted in API specifications. Cold-worked line pipe fittings of ASTM A 53 Grade B, ASTM A 106 Grade B, API 5L Grade X-42, or lower-strength grades with similar chemical compositions are acceptable with cold strain equivalent to 15% or less, provided the hardness in the strained area does not exceed 190 HB. 3.2.3 Tubulars and tubular components made of low-alloy steels in the Cr, Mo series (AISI 41XX and its modifications) are acceptable at a 26 HRC maximum hardness, provided they are in the quenched and tempered condition. 3.2.3.1 Careful attention to chemical composition and heat treatment is required to ensure SSC resistance of these alloys at greater than 22 HRC. Accordingly, it is common practice, when using these alloys at above 22 HRC, for the user to conduct SSC tests (in accordance with Paragraph 1.6) to determine that the material is equivalent in SSC performance to similar materials that have given satisfactory service in sour environments. 3.2.3.2 If tubulars and tubular components are cold straightened at or below 510°C (950°F), they shall be stress relieved at a minimum of 480°C (900°F). 3.3 Free Machining Steels 3.3.1. Free-machining steels shall not be used. 3.4 Cast Iron 3.4.1 Gray, austenitic, and white cast irons are not acceptable for use as a pressurecontaining member. These materials may be used in internal components related to API and other appropriate standards, provided their use has been approved by the purchaser. 3.4.2 Ferritic ductile iron ASTM A 395 is acceptable for equipment when API, ANSI, and/or other industry standards approve its use. Anderson Greenwood Pressure Relief Valves Technical Manual NACE MR0175-95 Excerpts on Valve Materials 3.5 Austenitic Stainless Steels1 3.5.1 Austenitic stainless steels with chemical compositions as specified in accordance with the standards listed in Table 1, either cast or wrought, are acceptable at a hardness of 22 HRC maximum in the annealed condition provided they are free of cold work designed to enhance their mechanical properties. 3.5.2 Austenitic stainless steel UNS S20910 is acceptable at 35 HRC maximum hardness in the annealed or hot-rolled (hot/cold-worked) condition, provided it is free of subsequent cold work designed to enhance its mechanical properties. 3.5.3 Austenitic stainless steel alloy UNS N08020 is acceptable in the annealed or cold-worked condition at a hardness level of 32 HRC maximum. 3.5.5 Wrought austenitic stainless steel UNS S31254 is acceptable in the annealed or cold-worked condition at a hardness level of 35 HRC maximum. 3.5.6 Austenitic stainless steel UNS N08367 is acceptable in the absence of free elemental sulfur at 22 HRC or less at temperatures below 150°C (302°F) when the salinity does not exceed 5,000 mg/L and the H2S partial pressure does not exceed 0.31 MPa (45 psia). 3.6 Ferritic Stainless Steels 3.6.1 Ferritic stainless steels are acceptable at a 22 HRC maximum hardness, provided they are in the annealed condition and meet the criteria of Section 5. Acceptable ferritic stainless steels are listed in Table 1. 3.7 Martensitic Stainless Steels 2 3.5.4 Cast CN7M meeting ASTM A 351, A 743, or A 744 is acceptable for nondownhole applications in the following conditions (there are no industry standards that address these melting and casting requirements): (1) solution-annealed at 1121°C (2050°F) minimum or solution-annealed at 1121°C (2050°F) minimum and welded with AWS E320LR or ER320LR; (2) the castings must be produced from argon-oxygen decarburization (AOD) refined heats or remelted AOD refined heats. The use of scraps, such as turnings, chips, and returned materials is prohibited unless melting is followed by AOD refining; (3) the CN7M composition listed in ASTM A 351, A 743, or A 744 shall be further restricted to 0.03 percent maximum carbon, 1.00% maximum silicon, 3.0 to 3.5% copper, 0.015% maximum sulfur, 0.030% maximum phosphorous, and 0.05 percent maximum aluminum; and 3.7.1 Martensitic stainless steels, as listed in Table 1, either cast or wrought, are acceptable at 22 HRC maximum hardness provided they are heat treated per Paragraph 3.7.1.1 and meet the criteria of Section 5. Martensitic stainless steels that are in accordance with this standard have provided satisfactory field service in some sour environments. These materials may, however, exhibit threshold stress levels in NACE Standard TM0177 that are lower than those for other materials included in this standard. 3.7.1.1 Heat-Treat Procedure (Three-Step Process) (1) Normalize or austenitize and quench. (2) Temper at 620°C (1150°F) minimum; then cool to ambient temperature. (3) Temper at 620°C (1150°F) minimum, but lower than the first tempering temperature, then cool to ambient temperature. 3.7.1.2 Subsequent to cold deformation (see Paragraph 3.2.2) the material shall be furnace stress relieved at 620°C (1150°F) minimum to 22 HRC maximum hardness. 3.7.2 Low-Carbon Martensitic Stainless Steels 3.7.2.1 Cast and wrought low-carbon martensitic stainless steels meeting the chemistry requirements of ASTM A 487 Grade CA6NM and UNS S42400 are acceptable to HRC 23 maximum provided they are heat treated per Paragraph 3.7.2.1.1.3 3.7.2.1.1 Heat-Treat Procedure (ThreeStep Process) (1) Austenitize at 1010°C (1850°F) minimum and air or oil quench to ambient temperature; (2) Temper at 648° to 690°C (1200° to 1275°F) and air cool to ambient temperature; (3) Temper at 593° to 620°C (1100° to 1150°F) and air cool to ambient temperature. 3.8 Precipitation-Gardening Stainless Steels 1 3.8.1 Wrought UNS S17400 martensitic precipitation-hardening stainless steel is acceptable at 33 HRC maximum hardness provided it has been heat treated in accordance with Paragraph 3.8.1.1 or Paragraph 3.8.1.2. Precipitation-hardening martensitic stainless steels that are in accordance with this standard have provided satisfactory field service in some sour environments. These materials may, however, exhibit threshold stress levels in NACE Standard TM0177 that are lower than those of other materials included in this standard. (4) at a hardness level of 22 HRC maximum. Notes 1. These materials may be subject to chloride SCC in certain environments. 2. Valve manufacturers generally do not use these material for valve stems or other highly stressed components in sour service. 3. The hardness correlation tabulated in ASTM E 140 does not apply to CA6NM or UNS S42400. When hardness is measured in Brinell units, the permissible BHN limit is 255 maximum, which has been empirically determined to be equivalent to HR 23 for these alloys. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 161 Anderson Greenwood Pressure Relief Valves Technical Manual NACE MR0175-95 Excerpts on Valve Materials 3.8.1.1 Double Age at 620°C (1150°F). (1) Solution anneal; Section 4: Nonferrous Metal 4–6 (1) Solution anneal at 1040°C ± 14°C (1900°F ± 25°F) and air cool, or suitable liquid quench, to below 32°C (90°F). (2) Precipitation harden at 620°C (1150°F) minimum for 4 hours. 4.1 General. (2) Harden at 620°C ± 14°C (1150°F ± 25°F) for 4 hours minimum and cool in air. (3) Cool material to below 32°C (90°F) before the second precipitation-hardening step. (4) Harden at 620°C ± 14°C (1150°F ± 25°F) for 4 hours minimum at temperature and cool in air. 3.8.1.2 Heat-Treat Procedure (Three-Step Process) (1) Solution anneal at 1040°C ± 14°C (1900°F ± 25°F) and air cool, or suitable liquid quench, to below 32°C (90°F). (2) Harden at 760°C ± 14°C (1400°F ± 25°F) for 2 hours minimum at temperature and cool in air to below 32°C (90°F) before second precipitation-hardening step. (3) Precipitation harden at 620°C ± 14°C (1150°F ± 25°F) for 4 hours minimum at temperature and cool in air. 3.8.2 Austenitic precipitation-hardening stainless steel with chemical composition in accordance with UNS S66286 is acceptable at 35 HRC maximum hardness provided it is in either the solution-annealed and aged or solution annealed and double-aged condition. 3.8.3 Wrought UNS S45000 martensitic precipitation-hardening stainless steel is acceptable at 31 HRC maximum hardness provided it has been heat treated per Paragraph 3.8.3.1 3.9 Duplex Stainless Steels1 3.9.1 The wrought duplex (austenitic/ferritic) stainless steels listed in Table 1 are acceptable 28 HRC maximum in the solution-annealed condition. 3.9.2 The cast duplex (austenitic/ferritic) stainless steel Z6CNDU20.08M, NF A 320-55 French National Standard is acceptable at hardness levels of 17 HRC maximum in the annealed and quenched condition provided the ferrite content is 25 to 40%. The annealing shall be at a temperature of 1150°C ± 10°C (2100°F ± 20°F) and shall be followed by a rapid quench to avoid the precipitation of sigma phase. 3.9.3 Wrought duplex stainless steel UNS S32404 (0.1% to 0.2% nitrogen) is acceptable at 20 HRC maximum in the solution-annealed condition. 3.9.4 Solution-annealed and cold-worked UNS S31803 is acceptable for use at any temperature up to 232°C (450°F) in sour environments if the partial pressure of hydrogen sulfide does not exceed 0.002 MPa (0.3 psia), the yield strength of the materials is not greater than 1100 MPa (160 ksi) and its hardness is not greater than 36 HRC. 3.9.5 Wrought duplex stainless steel UNS S32750 is acceptable at 32 maximum in the solution-annealed condition in sour environments up to 232°C (450°F) if the H2S partial pressure does not exceed 0.010 MPa (1.5 psia). 3.8.3.1 Heat-Treat Procedure (Two-Step Process) Notes 4. These materials may be subject to SCC failure when highly stressed and exposed to sour environments or some well-stimulating acids either with or without inhibitors. 5. Some of the materials in the wrought condition may be susceptible to failure by hydrogen embattlement when strengthened by cold work and stressed in the transverse direction. 6. Plastic deformation in service may increase the SSC susceptibility of these alloys. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 162 Nonferrous metal referenced in this section and meeting the stated requirements for both condition and hardness are acceptable for use in sour environments (defined in Paragraph 1.3). See also Table 2. 4.1.1 Nickel-Copper Alloys 4.1.1.1 UNS N04400, ASTM A 494 Grades M-35-1 and M-35-2, and UNS N04405 are acceptable to 35 HRC maximum. 4.1.1.2 UNS N05500 is acceptable to 35 HRC maximum in each of the three following conditions: (1) hot-worked and age-hardened; (2) solution-annealed; and (3) solution-annealed and age-hardened. 4.1.2 Nickel-lron Chromium Alloys 4.1.2.1 UNS N08800 is acceptable to 35 HRC maximum. 4.1.3 Nickel-lron-Chromium-Molybdenum Alloys 4.1.3.1 UNS N08825, UNS N06007, and wrought UNS N06975 are acceptable to 35 HRC maximum; UNS N06950 is acceptable to 38 HRC maximum; and UNS N06985 is acceptable to HRC 39 maximum. 4.1.3.2 UNS N09925 is acceptable in each of the five following conditions: (1) cold-worked to 35 HRC maximum; (2) solution-annealed to 35 HRC maximum; (3) solution-annealed and aged to 38 HRC maximum; (4) cold-worked and aged to 40 HRC maximum; and (5) hot-finished and aged to 40 HRC maximum. 4.1.3.3 UNS N08024 to 32 HRC maximum. Anderson Greenwood Pressure Relief Valves Technical Manual NACE MR0175-95 Excerpts on Valve Materials 4.1.3.4 UNS N08028 in the solution-annealed and cold-worked condition to 33 HRC maximum. N06022 is acceptable in the solutionannealed or solution-annealed plus coldworked conditions to 40 HRC maximum. 4.1.3.5 Nickel-iron-chromium-molybdenum-tungsten alloy UNS N06030 is acceptable in the solution-annealed or solution-annealed plus cold-worked condition to a maximum hardness of HRC 41. 4.1.5.2.1 Alloy UNS N10276 is also acceptable in the cold-worked and unaged condition at 45 HRC maximum when used at a minimum temperature of 121°C (250°F). 4.1.3.6 UNS N07048 is acceptable in the solution annealed, solution-annealed and aged, or direct-aged condition to HRC 4O maximum. 4.1.5.3 Wrought UNS N07718 is acceptable in each of the five following conditions: (1 ) solution-annealed to 35 HRC maximum; (2) hot-worked to 35 HRC maximum; (3) hot-worked and aged to 35 HRC maximum; (4) solution-annealed and aged to 40 HRC maximum; and (5) cast, solution-annealed, and aged condition to 40 HRC maximum. 4.1.3.7 UNS N08535 is acceptable in the solution-annealed and cold-worked condition to 35 HRC maximum. 4.1.3.8 Wrought UNS N08042 is acceptable in the solution-annealed or solution-annealed plus cold-worked conditions to HRC 31 maximum when the service environment does not contain elemental sulfur. 4.1.3.9 UNS N06952 is acceptable in the solution-annealed or solution-annealed plus cold-worked conditions to 35 HRC maximum when the service environment does not contain elemental sulfur. 4.1.4 Nickel-Chromium Alloys 4.1.4.1 UNS N06600 is acceptable to 35 HRC maximum. 4.1.4.2 UNS NO7750 is acceptable to 35 HRC maximum in each of the four following conditions: (1) solution-annealed and aged; (2) solution-annealed; (3) hotworked; and (4) hot-worked and aged. 4.1.5 Nickel-Chromium-Molybdenum Alloys 4.1.5.1 UNS N06002 and UNS N06625 are acceptable to 35 HRC maximum. 4.1.5.2 UNS N10002, UNS N10276, and ASTM A494 Grade CW-12 MW are acceptable in the solution-annealed or solution-annealed plus cold-worked conditions to 35 HRC maximum (except as noted in Paragraph 4.1.5.2.1). Alloy UNS 4.1.5.4 UNS N07031 is acceptable in each of the two following conditions: (1) solution-annealed condition to 35 HRC maximum; and (2) solution-annealed and aged at 760° to 870°C (1400° to 1600°F) for a maximum of 4 hours to 40 HRC maximum. 4.1.5.5 UNS N06110 and wrought UNS N06060 are acceptable in the annealed or cold-worked conditions to 40 HRC maximum. 4.1.5.6 UNS N07716 and wrought UNS N07725 are acceptable to 40 HRC maximum in the solution annealed and aged condition. 4.1.5.7 UNS N07626, totally dense hot compacted by a powder metallurgy process, is acceptable in the solution-annealed (925°C [11700°F] minimum) plus aged condition (525°C to 825°C [1000°F to 1500°F]) or the direct-aged (525°C to 825°C [1000°F to 1500°F]) condition to a maximum hardness of HRC 40 and a maximum tensile strength of 1380 MPa (200 ksi). 4.1.5.8 Cast CW2M meeting ASTM A 494 is acceptable for nondownhole applications in the following conditions (there are no industry standards that currently ad- dress these melting and casting requirements): (1) solution-annealed at 1232 ± 14°C (2250°F ± 25°F) or solution-annealed at 1232°C ± 14 °C (2250°F ± 25°F) and welded with AWS ENiCrMo-7, ERNiCrMo7, ENiCrMo-10, or ERNiCrMo-10; (2) the castings must be produced by argon-oxygen decarburization (AOD) refined heats, remelted AOD refined heats, or virgin remelt stock. The use of scrap, such as turnings, chips, and returned material is prohibited unless followed by AOD refining; (3) the CW2M composition listed in ASTM A 494 shall be further restricted to 0.015% maximum sulfur and 0.05% maximum aluminum; and (4) at a hardness level of 22 HRC maximum. 4.1.6 Cobalt-Nickel-ChromiumMolybdenum Alloys 4.1.6.1 Alloys UNS R30003, UNS R30004, UNS R30035, and British Standard, Aerospace Series HR3 are acceptable at 35 HRC maximum except when otherwise noted. 4.1.6.2 In addition, UNS R30035 is acceptable at 51 HRC maximum in the cold-reduced and high-temperature aged heat-treated condition in accordance with one of the following aging treatments: Minimum Time (hours) Temperature 4 704°C (1300°F) 4 732°C (1350°F) 6 774°C (1425°F) 4 788°C (1450°F) 2 802°C (1475°F) 1 816°C (1500°F) © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 163 Anderson Greenwood Pressure Relief Valves Technical Manual NACE MR0175-95 Excerpts on Valve Materials 4.1.6.3 Wrought UNS R31233 is acceptable in the solution-annealed condition to 22 HRC maximum. 4.2.1.4.5 Wrought UNS L56403 is acceptable in the annealed condition to 36 HRC maximum. 4.1.7 Cobalt- Nickel-Chromium-Tungsten Alloy codes. Welders using this procedure shall be familiar with the procedure and shall be capable of making welds that comply with the procedure. Section 5: Fabrication 5.3.1.1 Tubular products listed in Table 3 with specified minimum yield strength of 360 MPa (52 ksi) or less and pressure vessel steels classified as P-No 1, Group 1 or 2, in Section 9 of the ASME Code and listed in Table 3 meet the requirements of Paragraph 5.3.1 in the as-welded condition. Welding procedure qualifications, per AWS, API, ASME, or other appropriate specifications shall be performed on any welding procedure that is used. 4.1.7.1 UNS R30605 to 35 HRC maximum. 4 .2 Other Alloys 4.2.1 Materials described in this section and listed in Table 2 are acceptable. 4.2.1.1 Aluminum-base alloys 4.2.1.2 Copper alloys 7 4.2.1.3 Commercially pure tantalum. UNS R05200 is acceptable in the annealed and gas tungsten arc-welded annealed conditions to 55 HRB maximum. 4.2.1.4 Titanium alloys. Specific guidelines must be followed for successful applications of each titanium alloy specified in this standard. For example, hydrogen embrittlement of titanium alloys may occur if galvanically coupled to certain active metals (i.e., carbon steel) in H2S-containing aqueous media at temperatures greater than 80°C (176°F). Some titanium alloys may be susceptible to crevice corrosion and/or SCC in chloride environments. Hardness has not been shown to correlate with susceptibility to SSC. However, hardness has been included for alloys with high strength to indicate the maximum testing levels where failure has not occurred. 4.2.1.4.1 UNS R53400 is acceptable in the annealed condition. Heat treatment shall be annealing at 774°C ± 14°C (1425°F ± 25°F) for 2 hours followed by air cool. Maximum hardness to be 92 HRB. 4.2.1.4.2 UNS R58640 is acceptable to 42 HRC maximum. 4.2.1.4.3 UNS R50400 is acceptable to 100 HRB maximum. 4.2.1.4.4 UNS R56260 is acceptable to 45 HRC maximum in each of the three following conditions: (1) annealed; (2) solution-annealed; and (3) solution-annealed and aged. 5.1 General Materials and fabrication processes shall meet the requirements of this section if the material is to be exposed to sour environments (defined in Paragraph 1.3). 5.2 Overlays 5.2.1 Overlays applied to carbon and lowalloy steel or to martensitic stainless steels by thermal processes such as welding, silver brazing, or spray metallizing systems are satisfactory for use in sour environments, provided the substrate does not exceed the lower critical temperature during application. In those cases in which the lower critical temperatures are exceeded, the component must be heat treated or thermally stress relieved according to procedures that have been shown to return the base metal to 22 HRC maximum. 5.2.2 Tungsten-carbide alloys and ceramics are satisfactory, subject to the conditions of Paragraph 5.2.1.8 5.2.3 Joining of dissimilar materials, such as cemented to alloy steels by silver brazing, is acceptable. The base metal after brazing shall meet the requirements of Paragraph 5.2.1. 5.2.4 The materials listed in Sections 3 and 4 are acceptable as weld overlays, provided they meet the provisions of Paragraph 5.2.1. 5.2.5 Overlays of cobalt-chromium-tungsten alloys or nickel-chromium-boron hardfacing alloys are acceptable, subject to the conditions of Paragraph 5.2.1.8 5.3 Welding 5.3.1 Welding procedures shall be used to produce weldments that comply with the hardness requirements specified for the base metal in Sections 3 and 4. Welding procedures shall be qualified per AWS, API, ASME, or other appropriate industry Notes 7. Copper-base alloys may undergo weight loss corrosion in sour oilfield environments, particularly if oxygen is present. 8. Denotes editorial revision. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 164 5.3.1.2 Welding procedure qualifications on carbon steels that use controls other than thermal stress relieving to control the hardness of the weldment shall also include a hardness traverse across the weld, HAZ and base metal to ensure that the procedure is capable of producing a hardness of 22 HRC maximum in the condition in which it is used. 5.3.1.3 Low-alloy steel and martensitic stainless steel weldments shall be stress relieved at a minimum temperature of 620°C (1150°F) to produce a hardness of 22 HRC maximum. 5.3.2 Welding rods, electrodes, fluxes, filler metals, and carbon and low-alloy steel welding consumables with more than 1% nickel are not allowed for welding carbon and low-alloy steels as indicated in Paragraph 3.2.1. 5.4 Identification Stamping 5.4.1 Identification stamping using lowstress (dot, vibratory, and round V) stamps is acceptable. 5.5.2 Conventional sharp V stamping is acceptable in low-stress areas, such as the outside diameter of flanges. Sharp V stamping is not permitted in high-stress areas unless subsequently stress relieved at 595°C (1100°F) minimum. Anderson Greenwood Pressure Relief Valves Technical Manual NACE MR0175-95 Excerpts on Valve Materials 5.5 Threading 6.2.1.1 Class I and Class II Nuts and Bolts Section 8: Special Components 5.5.1 Machine-Cut Threads 6.2.1.1.1 Acceptable nuts and bolting materials shall meet the requirements of Sections 3 and 4. 8.1 General. 5.5.1.1 Machine-cut threading processes are acceptable. 5.5.2 Cold-Formed (Rolled) Threads 5.5.2.1 Subsequent to cold forming threads, the threaded component shall meet the heat-treat conditions and hardness requirements given in either Section 3 or 4 for the parent alloy from which the threaded component was fabricated. 5.6 Cold-Deformation Processes 5.6.1 Cold-deformation processes such as burnishing that do not impart cold work exceeding that incidental to normal machining operations, such as turning or boring, rolling, threading, drilling, etc., are acceptable. 5.6.2 Cold deformation by controlled shot peening is permitted when applied to base materials that meet the requirements of this document and when limited to the use of a maximum shot size of 230 (0.584 mm nominal diameter) and a maximum of 0.356 mm A Almen intensity. The process shall be controlled in accordance with Military Specification MIL-S-13165-B, latest revision. Section 6: Bolting 6.1. General. Materials shall meet the requirements of this section if they are to be exposed to sour environments (defined in Paragraph 1.3). 6.2 Exposed Bolting 6.2.1 Bolting that will be exposed directly to sour environment or that will be buried, insulated, equipped with flange protectors, or otherwise denied direct atmospheric exposure must be of either a Class I or Class II material (see Paragraph 6.2.1.1).9 6.2.1.1.2 Bolting materials that meet the specifications of ASTM A 193 Grade B7M, 550 MPa (80,000 psi) minimum yield strength, and 22 HRC maximum are acceptable. 6.2.1.1.3 Nuts shall meet the specifications of ASTM A 194 Grade 2HM (22 HRC maximum) or Paragraph 6.2.1.1.1. 6.3 Nonexposed Bolting 6.3.1 Class III Bolting 6.3.1.1 Bolting that is not directly exposed to sour environments and is not to be buried, insulated, equipped with flange protectors, or otherwise denied direct atmospheric exposure may be furnished to applicable standards such as ASTM A 193 Grade B7. Section 7: Platings and Coatings 7.1 General 7.1.1. Materials shall meet the requirements of this section if they are to be exposed to sour environments (defined in Paragraph 1.3). 7.1.2 Metallic coatings (electroplated or electroless), conversion coatings, and plastic coatings or linings are not acceptable for preventing SSC of base metals. The use of such coatings for other purposes is outside the scope of this standard. 7.2 Nitriding 7.2.1 Nitriding with a maximum case depth of 0.15 mm (0.006 inch) is an acceptable surface treatment when conducted at a temperature below the lower critical temperature of the alloy system being treated. Its use as a means of preventing SSC is not acceptable. Materials for special components including instrumentation, control devices, seals, bearings, and springs shall meet the requirements of this section if they are directly exposed to sour environments during normal operation of the device. Paragraph 1.3 provides guidelines to determine the applicability of this standard to specific applications. 8.2 Bearings 8.2.1 Bearings directly exposed to sour environments shall be made from materials in Sections 3 and 4. 8.2.2 Nickel-chromium-molybdenum-tungsten alloy UNS N10276 bearing pins, i.e. core roll pins, are acceptable in the coldworked condition to 45 HRC maximum. 8.2.3 Bearings made from other materials must be isolated from the sour environment in order to function properly, except as noted in Paragraph 8.2.2. 8.3 Springs 8.3.1 Springs directly exposed to the sour environment shall be made from materials described in Sections 3 and 4. 8.3.2 Cobalt-nickel-chromium-molybdenum alloy UNS R30003 may be used for springs in the cold-worked and age-hardened condition to 60 HRC maximum. UNS R30035 may be used for springs in the cold-worked and age-hardened condition of 55 HRC maximum when aged for a minimum of 4 hours at a temperature no lower than 648°C (1200°F). 8.3.3 Nickel-chromium alloy UNS N07750 springs are acceptable in the cold-worked and age-hardened condition to 50 HRC maximum. 8.3.4 UNS N07090 may be used for springs for compressor valves in the cold-worked and age-hardened condition to 50 HRC maximum. Notes 9. Designers and users should be aware that it may be necessary to derate the pressure rating in some cases when using lowstrength bolts. For API 6A flanges using Class II bolting, see API Standard 6A. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 165 Anderson Greenwood Pressure Relief Valves Technical Manual NACE MR0175-95 Excerpts on Valve Materials 8.4 Instrumentation and Control Devices the as-cast or solution-annealed condition to 160 HB (83 HRB) maximum. stainless steel with a given ferrite content for each application. 8.4.1 Instrumentation and control device components directly exposed to sour environments shall be made from materials in Sections 3 through 8. 8.6 Snap Rings 8.9 Special Process Parts 11 8.6.1 Snap rings directly exposed to a sour environment shall be made from applicable materials in Sections 3 and 4, except as noted in Paragraph 8.6.2. 8.9.1 Cobalt-chromium-tungsten alloys, whether cast, powder-metallurgy processed, or thermomechanically processed, are acceptable. 8.6.2 Precipitation-hardening stainless steel alloy UNS S15700 snap rings originally in the RH950 solution-annealed and aged condition are acceptable when further heat treated to a hardness of 30 to 32 HRC as follows: 8.9.2 Tungsten carbide alloys, whether cast or cemented, are acceptable. 8.6.2.1 Heat-Treatment Procedure (3-Step Process) 9.1.1 Materials shall meet the requirements of this section if they are to be exposed to sour environments (defined in Paragraph 1.3). 8.4.1.1 Paragraph 3.5.1 is not intended to preclude the use of AISI Type 316 stainless steel compression fittings and instrument tubing even though they won’t satisfy the requirements stated in Paragraph 3.5.1. 1 8.4.2 Diaphragms, Pressure-Measuring Devices, and Pressure Seals.4–6 8.4.2.1 Diaphragms, pressure-measuring devices, and pressure seals directly exposed to a sour environment shall be made from materials in Sections 3 and 4. 8.4.2.2 Cobalt-nickel-chromium-molybdenum alloys UNS R30003 and UNS R30004 for diaphragms, pressure-measuring devices, and pressure seals are acceptable to 60 HRC maximum. 8.4.2.3 Cobalt-nickel-chromium-molybdenum-tungsten alloy UNS R30260 diaphragms, pressure-measuring devices, and pressure seals are acceptable to 52 HRC maximum. 8.4.2.4 Pressure seals shall comply with the requirements of Sections 3 and 4 and Tables 1 and 2 or may be manufactured of wrought cobalt-chromium-nickel-molybdenum alloy UNS R30159 to 53 HRC maximum with the primary load-bearing or pressure-containing direction parallel to the longitudinal or rolling direction of wrought products. 8.5 Seal Rings 8.5.1 Seal rings directly exposed to a sour environment shall be made from materials in Sections 3 and 4. 8.5.2 Austenitic stainless steel API compression seal rings made of centrifugally cast ASTM A 351 Grade CF8 or CF8M chemical compositions are acceptable in (1) Temper at 620°C (1150°F) for 4 hours, 15 minutes. Cool to room temperature in still air. 9.1 General 9.1.2 Valves and chokes shall be manufactured from materials in accordance with Sections 3 through 8. (2) Retemper at 620°C (1150°F) for 4 hours, 15 minutes. Cool to room temperature in still air. 9.2 Shafts, Stems, and Pins (3) Temper at 560°C (1050°F) for 4 hours, 15 minutes. Cool to room temperature in still air. 9.2.1 Shafts, stems, and pins shall be manufactured from materials in accordance with Sections 3 through 8. 8.7 Bearing Pins 8.7.1 Bearing pins, e.g., core roll pins, made from UNS N10276 in the coldworked condition with a maximum hardness of 45 HRC, may be used. 9.2.2 Austenitic stainless steel UNS S20910 is acceptable for valve shafts, stems, and pins at a maximum hardness level of 35 HRC in the cold-worked condition, provided this cold working is preceded by an anneal. 8.8 Duplex Stainless Steel for Wellhead Components10 9.3 Internal Valve and Pressure Regulator Components 8.8.1 Cast duplex (austenitic/ferritic) stainless steel UNS J93345 is acceptable in the solution-treated condition provided that the hardness does not exceeded 223 HB. The material must be restricted to the following products: valve components, compressor components, casting and tubing heads (excluding mandrel hangers), spools, side entry caps, tail pieces, hammer caps, and spider caps. Laboratory tests have shown that duplex stainless steels’ susceptibility to SSC is a function of the percentage of ferrite. The user may determine the acceptability of a duplex 9.3.1 Cast CB7Cu-1 in the H1150 DBL condition per ASTM A 747 is acceptable for non-pressure-containing, internal valve, and pressure regulator components at 310 HB maximum (30 HRC maximum) providing it complies with Paragraph 1.2. Precipitation-hardening martensitic stainless steels that are in accordance with this standard have provided satisfactory field service in some sour environments. These materials may, however, exhibit threshold stress levels in NACE Standard TM0177 that are lower than other materials included in this standard. Notes 10. Aging over 260°C (500°F) may reduce temperature toughness and reduce resistance to environmental cracking. Section 9: Valves and Chokes 11. Some of these materials may be used in wear-resistant applications and can be brittle. Environmental cracking may occur if these materials are subject to tension. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 166 Anderson Greenwood Pressure Relief Valves Technical Manual NACE MR0175-95 Excerpts on Valve Materials Materials listed in this table should be used only under conditions noted in the text of this standard. Table 1 Stainless Steels Acceptable for Direct Exposure to Sour Environments (see Paragraph 1.3) Ferritic Martensitic PrecipitationHardening Austenitic AISI AISI ASTM Duplex (Austenitic /Ferritic)3 (Wrought Condition Only) AISI UNS S31803 1 405 410 A 453 Gr. 660 302 UNS S32550 430 501 A 638 Gr. 6601 304 UNS S32404 304L 305 308 309 310 316 316L 317 321 347 ASTM ASTM UNS S17400 ASTM Cast Duplex A 268 A 217 Gr. CA 15 UNS S45000 A 182 (Austenitic/Ferritic) TP 405, TP 430, A 268 Gr. TP 410 UNS S66286 A 193 2 Stainless steel TP XM 27, TP XM 33 A 743 Gr. CA 15M Gr. B8R, B8RA, B8, Z6CNDU20.08M, NF A A 487 CI CA 15M B8M, B8MA 320-55 French National A 487 CI CA 6NM UNS S42400 A 194 2 Standard Gr. 8R, 8RA, 8A, 8MA A 320 2 Gr. B8, B8M A 351 Gr. CF3, CF8, CF3M, CF8M B463 B473 UNS S20910 UNS N08020 UNS S31254 Notes 1. See Paragraph 3.8.2. 2. Carbide solution-treated. 3. Aging over 260°C (500°F) may reduce low-temperature toughness and reduce resistance to environmental cracking. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 167 Anderson Greenwood Pressure Relief Valves Technical Manual NACE MR0175-95 Excerpts on Valve Materials Materials listed in this table should be used only under conditions noted in the text of this standard. Mechanical properties described in the specifications noted below are not necessarily in accordance with MR0175. Table 2 Nonferrous Materials Acceptable for Direct Exposure to Sour Environments (see Paragraph 1.3) Nickel-Copper Alloys UNS1 N05500 UNS N04400 Nickel-IronChromium Alloys UNS N08800 Nickel-Iron-ChromiumMolybdenum Alloys UNS UNS N06007 N08825 Nickel-Chromium Alloys UNS N06600 Coatings, Overlays, and Special Process Parts UNS N07750 SAE/AMS ASTM SAE/AMS ASTM SAE/AMS ASTM ASTM ASTM SAE/ ASTM SAE/AMS Co-Cr-W Alloys as in AWS 4676 B 127 4544 B 163 5766 B 366 B 163 B 163 AMS B 637 5542 A5.13-80 B 163 4574 B 366 5871 B 581 B 366 B 166 5540 5582 Ni-Cr-B Alloys as in AWS B 164 4575 B 407 B 582 B 423 B 167 5580 5598 A5.13-80 B 366 4730 B 408 B 619 B 424 B 366 5665 5667 Tungsten Carbide Alloys B 564 4731 B 409 B 622 B 425 B 516 7232 5668 Ni-B Alloys as in AMS 4779 7233 B 514 B 626 B 704 B 517 5669 Ceramics B 705 B 564 5670 B 515 B 564 5671 5698 5699 A 494 UNS N09925 Gr. M-35-1 UNS N08024 Gr. M-35-2 UNS N08028 UNS N07048 UNS N08535 UNS N08042 UNS N06952 UNS N04405 Note 1. Unified Numbering System for Metals and alloys: ASTM E527 or SAE J1086. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 168 Anderson Greenwood Pressure Relief Valves Technical Manual NACE MR0175-95 Excerpts on Valve Materials Table 2 – continued…Nickel-Chromium-Molybdenum UNS N006625 UNS 10002 UNS N10276 UNS N07718 UNS N06002 ASTM SAE/ ASTM SAE/ ASTM ASTM SAE/ ASTM SAE/ UNS N06030 B 336 AMS A 597 Gr. 4 AMS B 366 B 637 AMS A 567 AMS UNS N06975 B 443 5581 5388 B 574 B 670 5383 Gr. 5 5390 UNS N07725 B 444 5599 A 494 5389 B 575 5589 B 366 5536 UNS N06985 B 446 5666 Gr. Cw-12MW 5530 B 619 5590 B 435 5587 UNS N06110 B 564 5837 5750 B 622 5596 B 572 5788 UNS N07031 B 626 5597 B 619 5754 UNS N07716 5662 B 622 5798 UNS N06022 5663 B 626 5799 UNS N06060 B 704 B 705 5664 7237 5832 Table 2 – continued… Cobalt-Nickel-ChromiumMolybdenum Alloys UNS R30035 UNS R30003 Cobalt-Nickel-ChromiumTungsten Alloys UNS R30605 Cobalt-Nickel-ChromiumTungsten Alloys UNS R30260 Other Alloys Aluminum Tantalum Titanium Base UNS R05200 Alloys Alloys UNS R03004 UNS R30159 UNS R31233 UNS R50400 Copper UNS R53400 Alloys UNS R58640 UNS R56260 UNS L56403 © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 169 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 521 Noise Excerpts from API - RP 521 Guide for Pressure-Relieving and Depressuring Systems 5.4.4.3 Noise The noise level at 100 feet (30 meters) from the point of discharge to the atmosphere can be approximated by equation (9): L100 (30) = L (from Fig. 12) + 10 log10 (1/2MC 2 ) (9) Figure 12 – Noise Intensity at 100 Feet (30 Meters) From the Stack Tip 70 60 Figure 12 illustrates the noise intensity measured as the sound pressure level at 100 feet (30 meters) from the stack tip versus the pressure ratio across the safety valve. Sound Pressure Level at 50 100 feet [30 meters] from stack tip minus 10 log [1/2 MC2] 40 The following symbols are used in the procedure for calculating the noise level: 30 M = mass flow through the valve, in slugs per second (kilograms per second). 20 ▲ 1.5 ▲ 2 C = speed of sound in the gas at the valve, in feet per second (meters per second). ( T = 560 degrees Rankine ) kT ( –––––––––––––– ) Molecular weight [ 0.5 = ratio of the specific heats in the gas. r = gas temperature, in degrees Rankine (Kelvin). PR = ratio of the upstream to the downstream pressure across the safety valve (absolute). An example of calculating, in English units, the noise level at 100 feet from the point of discharge to the atmosphere is presented below: 1. Calculate 1/2MC 2 in watts. Divide the weight flow (pounds per second) by 32 to obtain M. Multiply 1/2MC 2 (foot-pounds per second) by 1.36 to obtain 1/2MC 2 in watts. = 1159 feet per second 1. 1/2MC 2 = (1/2)(1)(1159)2(1.36) = (9.1)(105). 3. From Figure 12, at PR = 3, the ordinate = 54. 4. L100 at 100 feet = 54 + 60 = 114 decibels 1. Calculate 1/2MC 2 in watts. In metric units, this translates to: 2. Calculate 10 log10(1/2MC 2). 3. In Figure 12, enter PR as the abscissa and read the ordinate. 4. Add Items 2 and 3 to obtain the average sound pressure level at 30 meters, L30, in decibels. Assume the following: M = 14.6 kilograms per second T = 311 kelvins PR = 48/16 = 3 [ 0.5 ] = 353 meters per second 1. 1/2MC 2 = (1/2)(14.6)(353)2 = (9.1)(105). © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. ( ) Lp = L30 - 20 log10 –––r–– 30 (10) (10A) Where: Lp = sound pressure level at distance r, in decibels. r = distance from the sound source (stack tip), in feet (meters). Molecular weight= 29 (1.4) (311) C = 91.2 ––––––––––––– 29 ( ) L100(30) = sound pressure level at 100 feet (30 meters), in decibels. k = 1.4 k = 1.4 Molecular weight = 29 By applying equation (10), the noise level can be adjusted for distances that differ from the 100-foot (30-meter) reference boundary: Lp = L100 - 20 log10 –––r–––100 4. Add Items 2 and 3 to obtain the average sound pressure level at 100 feet, L100, in decibels. Assume the following: M = 1 slug per second = 32 pounds per second Note: These calculations are based on spherical spreading of the sound. If distances much larger than the height of the vent above ground are of concern, add 3 decibels to the calculated result to correct for hemispherical diffusion. An example of calculating, in metric units, the noise level at 30 meters from the point of discharge to the atmosphere is presented below: 2. Calculate 10 log10(1/2MC 2) 3. In Figure 12, enter PR as the abscissa and read the ordinate. ▲ ▲ ▲ ▲ 7 8 9 10 4. L30 at 30 meters = 54 + 60 = 114 decibels. ] 2. 10 log10 ( 1/2MC 2 ) = 60 k ▲ 6 3. From Figure 12, at PR = 3, the ordinate = 54. (1.4) (560) C = 223 ––––––––––––– 29 0.5 Where: ▲ 5 2. 10 log10(1/2MC 2 ) = 60 PR = 48/16 = 3 0.5 kT –––––––––––––– Molecular weight In meters per second, C = 9.12 ▲ 4 Pressure Ratio (PR) Note: In feet per second, C = 223 ▲ 3 170 For distances greater than 1000 feet (305 meters), some credit may be taken for molecular noise absorption. When safety valves prove to be excessively noisy during operation, the sound can be deadened by the application of insulation around the valve body and the downstream pipe up to approximately five pipe diameters from the valve. Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 527 Seat Tightness Excerpts from API - RP 527 (July 1991) Seat Tightness of Pressure Relief Valves Figure 1 – Apparatus to Test Seat Tightness With Air Flanged or threaded outlet adapter for pressure relief valve Tube with outside diameter of 5/16 inch [7.9mm] and wall thickness of 0.035 inch [0.89mm] 1/2 inch [12.7mm] Water Note 1.0 Scope This standard describes methods of determining seat tightness of metal and soft seated pressure relief valves, including those of conventional, bellows and pilot operated designs. The maximum acceptable leakage rates are defined for pressure relief valves with set pressures from 15 psig (103 kPag) to 6,000 psig (41,379 kPag). If greater seat tightness is required, the purchaser shall specify it in the purchase order. The test medium for determining the seat tightness – air, steam or water – shall be the same as that used for determining the set pressure of the valve. 1. See Figure 2 for an example of a device to relieve body pressure in case the valve accidentally pops. For dual-service valves, the test medium – air, steam, or water – shall be the same as the primary relieving medium. Figure 2 - Devise to Relieve Body Pressure Caused by Accidental Popping of the Valve To ensure safety, the procedures outlined in this standard shall be performed by persons experienced in the use and functions of pressure relief valves. Soft Rubber Gasket Attached To Face Of Detector To Prevent Leakage Cup-weld to detector C Clamp Air Pressure Outlet tube cut end smooth and square Water level control hole maintain 1/2 inch [12.7mm] from bottom of tube to bottom of hole 1/2 inch Membrane seals during test and bursts if valve accidentally opens Safety Valve 2.0 Testing with Air 2.1 Test Apparatus A test arrangement for determining seat tightness with air is shown in Figure 1. Leakage shall be measured using a tube with an outside diameter of 5/16 inch (7.9 millimeters) and a wall thickness of 0.035 inch (0.89 millimeter). The tube end shall be cut square and smooth. The tube opening shall be 1/2 inch (12.7 millimeters) below the surface of the water. The tube shall be perpendicular to the surface of the water. Arrangement shall be made to safely relieve or contain body pressure in case the valve accidentally pops (see Figure 2). 2.2 Procedure 2.2.1 Test Medium The test medium shall be air (or nitrogen) near ambient temperature. 2.2.2 Test Configuration The valve shall be vertically mounted on the test stand, and the test apparatus shall be attached to the valve outlet, as shown in Figure 1. All openings–including but not limited to caps, drain holes, vents, and outlets–shall be closed. 2.2.3 Test Pressure For a valve whose set pressure is greater than 50 pounds per square inch gauge (345 kilopascals gauge), the leakage rate in bubbles per minute shall be determined with the test pressure at the valve inlet held at 90 percent of the set pressure. For a valve set at 50 pounds per square inch gauge (345 kilopascals gauge) or less, the test pressure shall be held at 5 pounds per square inch (34.5 kilopascals) less than the set pressure. 2.2.4 Leakage Test Before the leakage test, the set pressure shall be demonstrated, and all valve body joints and fittings should be checked with a suitable solution to ensure that all joints are tight. Before the bubble count, the test pressure shall be applied for at least 1 minute for a valve whose nominal pipe size is 2 inches (50 millimeters) or smaller; 2 minutes for a valve whose nominal pipe size is 21/2, 3, or 4 inches (65, 80, or 100 millimeters); and 5 minutes for a valve whose nominal pipe size is 6 inches (150 millimeters) or larger. The valve shall then be observed for leakage for a least 1 minute. 2.3 Acceptance Criteria For a valve with a metal seat, the leakage rate in bubbles per minute shall not exceed the appropriate value in Table 1. For a soft-seated valve, there shall be no leakage for 1 minute (0 bubbles per minute). 3.0 Testing with Steam 3.1 Procedure 3.1.1 Test Medium The test medium shall be saturated steam. 3.1.2 Test Configuration The valve shall be vertically mounted on the steam test stand. 3.1.3 Test Pressure For a valve whose set pressure is greater than 50 pounds per square inch gauge (345 kilopascals gauge), the seat tightness shall be determined with the test pressure at the valve inlet held at 90 percent of the set pressure. For a valve set at 50 pounds per square inch gauge (345 kilopascals gauge) or less, the test pressure shall be held at 5 pounds per square inch (34.5 kilopascals) less than the set pressure. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 171 Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 527 Seat Tightness Excerpts from API - RP 527 (July 1991) Seat Tightness of Pressure Relief Valves Table 1 Maximum Seat Leakage Rate for Metal Seated Pressure Relief Valves in Bubbles Per Minute Set Pressure (psig) at (60°F) [15.6°C] Effective Orifice Sizes 0.307 inch and Smaller Bubbles Per Minute Effective Orifice Sizes Larger than 0.307 inch Approximate Leakage Rate per 24 Hours Standard Cubic Feet Bubbles Per Minute Standard Cubic Meters Approximate Leakage Rate per 24 Hours Standard Cubic Feet Standard Cubic Meters 15-1000 [.103-6.896 MPA] 40 0.60 0.017 20 0.30 0.0085 1500 [10.5 MPA] 60 0.90 0.026 30 0.45 0.013 2000 [13.0 MPA] 80 1.20 0.034 40 0.60 0.017 2500 [17.2 MPA] 100 1.50 0.043 50 0.75 0.021 3000 [20.7 MPA] 100 1.50 0.043 60 0.90 0.026 4000 [27.6 MPA] 100 1.50 0.043 80 1.20 0.034 5000 [38.5 MPA] 100 1.50 0.043 100 1.50 0.043 6000 [41.4 MPA] 100 1.50 0.043 100 1.50 0.043 3.1.4 Leakage Test Before starting the seat tightness test, the set pressure shall be demonstrated, and the test pressure shall be held for least three minutes. Any condensate in the body bowl shall be removed before the seat tightness test. Air (or nitrogen) may be used to dry condensate. After any condensate has been removed, the inlet pressure shall be increased to the test pressure. Tightness shall then be checked visually using a black background. The valve shall then be observed for leakage for at least one minute. 3.2 Acceptance Criteria For both metal- and soft-seated valves, there shall be no audible or visible leakage for one minute. 4.0 Testing with Water 4.1 Procedure 4.1.1 Test Medium The test medium shall be water near ambient temperature. 4.1.2 Test Configuration The valve shall be vertically mounted on the water test stand. 4.1.3 Test Pressure For a valve whose set pressure is greater than 50 pounds per square inch gauge (345 kilopascals gauge) the seat tightness shall be determined with the test pressure at the valve inlet held at 90% of the set pressure. For a valve set at 50 pounds per square inch gauge (345 kilopascals gauge) or less, the test pressure shall be held at 5 pounds per square inch (34.5 kilopascals) less than the set pressure. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 172 4.1.4 Leakage Test Before starting the seat tightness test, the set pressure shall be demonstrated and the outlet body bowl shall be filled with water, which shall be allowed to stabilize with no visible flow from the valve outlet. The inlet pressure shall then be increased to the test pressure. The valve shall then be observed for 1 minute at the test pressure. 4.2 Acceptance Criteria For a metal-seated valve whose inlet has a nominal pipe size of 1 inch or larger, the leakage rate shall not exceed 10 cubic centimeters per hour per inch of nominal inlet size. For a metal-seated valve whose inlet has a nominal pipe size of less than 1 inch, the leakage rate shall not exceed 10 cubic centimeters per hour. For soft-seated valves, there shall be no leakage for 1 minute. Anderson Greenwood Pressure Relief Valves Technical Manual API - RP 527 Seat Tightness Excerpts from API - RP 527 (July 1991) Seat Tightness of Pressure Relief 5.0 Testing with Air—Alternate Method 5.1 Type of Valve to be Tested Valves with open bonnets–bonnets which cannot be readily sealed, as specified in 2.2.2–may be tested in accordance with this section instead of Section 2. This alternative method shall not be used to test valves in which air bubbles can travel to the open bonnet through any passageway inside the valve guide without being observed at the valve outlet. 5.2 Procedure 5.2.1 Test Medium The test medium shall be air (or nitrogen) near ambient temperature. 5.2.2 Test Configuration The valve shall be vertically mounted on the air test stand. The valve outlet shall be partially sealed with water to about 1/2-inch [12.7 mm] above the nozzle’s seating surface. 5.2.4 Leakage Test Before starting the seat tightness test, the set pressure shall be demonstrated, and the outlet body bowl shall be filled with water to the level of the partial seal. The inlet pressure shall then be increased to the test pressure and held at this pressure for one minute before the bubble count. The valve shall then be observed for leakage for at least one minute. Caution: When looking for leakage, the observer shall use a mirror or some other indirect means of observations so that the observer’s face is not in line with the outlet of the valve, in case the valve accidentally pops. 5.3 Acceptance Criteria For a valve with a metal seat, the leakage rate in bubbles per minute shall not exceed 50 percent of the appropriate value in Table 1. For a soft-seated valve, there shall be no leakage for 1 minute (0 bubbles per minute). 5.2.3 Test Procedure For a valve whose set pressure is greater than 50 pounds per square inch gauge [345 kPag], the leakage rate in bubbles per minute shall be determined with the test pressure at the valve inlet held at 90% of the set pressure. For a valve set at 50 pounds per square inch gauge [345 kilopascals gauge] or less, the test pressure shall be held at 5 pounds per square inch gauge [34.5 kilopascals] less than the set pressure. © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 173 Anderson Greenwood Pressure Relief Valves Technical Manual Section 16 – Chemical Resistance Guide for Metals erations) cannot be realistically duplicated in a controlled laboratory environment. The following table should be used only as a guide for selecting materials for various applications. This table does not imply a guarantee of corrosion resistance due to the fact the complicating factors, (ie; agitation, impurities, aeration and velocity of corrosives encountered in commercial op- Symbol Guide: C = Fair Resistance N = Not Recommended Blank spaces indicate insufficient data A = Excellent Resistance B = Good Resistance Chemical Resistance Guide For Metals Corrosive Media Conditions Gray Iron Ductile Iron CS 304 SS 316 SS 416 SS Material Used 17-4 PH Stellite Inconel® Brass Bronze Copper Monel® Hastelloy® C Acetaldehyde C B B A N B A N N N A A Acetate Solvents (Crude) N N A A B A A C B B A A Acetate Solvents (Pure) N C A A Acetic Acid (Crude) N N B Acetic Acid (Pure) N N A Acetic Acid (30%) N Acetic Acid (Vapors) N B Acetic Anhydride C N Acetone A Acetylene A Air Alcohols A A N B B A N A B A N N B N N B A N B B A A A A A A A A A A A A A A A C B A A B A A B A A Amines B A A C A Ammonia (Anhydrous) B B A A B B Ammonia Solution A B A A Ammonium Oxalate N C B A Ammonium Persulphate A A B A A N N N A B N N N A A N N N A A B N N N A A A N N A B A A N N A A A C N N A B A A A A A A A B B B A A A A N A A B B A N N N B B B C C A B B N N A A B A A N N N Ammonium Phosphate (Mono) N N A A B A A N N N Ammonium Phosphate (Di) B B A A B A C C Ammonium Phosphate (Tri) A A B A B B C C C B N B C B B C B B Ammonium Sulphate N C N B B N B N N N B Ammonium Sulfite C N C B C C N N N N C A Amyl Acetate C C A A B A C N N A B Amyl Alcohol C B B A B B N N N N N N B B N N N A N N N B N B B B N N N C B B B B A Aniline C C B A B B Aniline Dyes C C A A B A Aniline Hydrochloride N N N C N Animal Oil (Lard) A A A A A Arsenic Acid N N B A B B Asphalt A B A A A A B B A Barium Carbonate B B A A A B B B B B Barium Chloride C C C B C C C C A A © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 174 Anderson Greenwood Pressure Relief Valves Technical Manual Section 16 – Chemical Resistance Guide for Metals Chemical Resistance Guide For Metals Corrosive Media Conditions Gray Iron Ductile Iron CS 304 SS 316 SS Barium Hydroxide C C A A Barium Nitrate Barium Sulphate C C A C C B Barium Sulphide C C B A Barium Cyanide B 416 SS Material Used 17-4 PH Stellite Inconel® Brass Bronze Copper Monel® Hastelloy® C A Battery Acid C C C A A C C C A B A A B N N N C B A B N N N B N N N A A A A A Beer (Food) N N A A N A A A B B B A Beet Sugar Liquor B B A A A A A A C C C A Black Sulphate Liquor A A A A B A N N N A Blast Furnace Gas A A A A A A A A Borax (Sodium Borate) B B A A Bordeaux Mixture A A A A Boric Acid N N B B Bromine (Dry) N N N N Bromine (Wet) N N N N Butane B B A A Butanol A A A A Buttermilk C N A A A A A C C C A A A A B C B A C C C N N B B B B N N B A A B A A C A A A A A N N N C B N N N A B A A A A A A N N N A B A A A A A N N B B N B Butyl Acetate C C B A A B Calcium Bisulphite N N C B N C Calcium Carbonate N N A A A B B B B B Calcium Chlorate C C C C B C N N N B A Calcium Chloride C C C B B C B B B A A A Calcium Hydroxide C C A A A A A C C C A A Calcium Hypochlorite N N N N N N C C C C C A A B Calcium Sulphate B B B A A B B B B Cane Sugar Liquors A A A A A A B A A Carbolic Acid N N A A A A C C C B A Carbon Dioxide (Dry) B B A A A A A A A A A A Carbon Dioxide (Wet) C C A A A A A C C C C B Carbon Disulphide B B A A B A A C N N B B Carbon Monoxide A B A A A B B B Carbon Tetrachloride N C C C B C A A A N N N B A C C C A A A A N N N Carbonated Beverages N N A A Carbonic Acid N N A A B B Castor Oil A A A A B Caustic Soda B C A B Casein A A B A B © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 175 Anderson Greenwood Pressure Relief Valves Technical Manual Section 16 – Chemical Resistance Guide for Metals Chemical Resistance Guide For Metals Corrosive Media Conditions CS 304 SS 316 SS B A B A N N N Caustic Potash B C Cellulose Acetate C B B B A A A B Cellulose Nitrate B B B B B B B B Caustic Solutions B 416 SS Material Used 17-4 PH Stellite Inconel® Brass Bronze Copper Monel® Hastelloy® C Gray Iron Ductile Iron China Wood Oil C C A A A B B B Chloracetic Acid N N N C N N N N A Chlorbenzol B B C C C A A A A Chloramine Chlorex A A N Chloric Acid N N N C N A A A N N N N Chlorinated Solvents C C A A A C N N N Chlorinated Water N N N C N C N N N C Chlorine (Dry) C B B B B B A B B B A B Chlorine (Wet) N N N C N N N N N N C A N N B N B N N N B A Citric Acid N N B A C B C B B B A Coconut Oil A A A A N A N N N Chlorosulfonic Acid Cod Liver Oil A Coffee A A A N A N N N A Coke Oven Gas A A A A A A C C C B Corn Oil B B A A A N N N A Cottonseed Oil B B A A A A N N N A Creisike B B A A A A C B B A Cresylic Acid N C A A B A N N N Crude Oil A A A A B A C C C A A A A Diethylamine A A A A A A A A Dowtherm A or E N N A A A A B B B Ethylene Dichloride N C C C Ethylene Glycol B A A A A A B A Ethylene Oxide B C A A Fatty Acids N N B A Ferric Chloride N N N N Ferric Nitrate N N B A Ferric Sulphate N N B A Ferrous Chloride N N N N Ferrous Sulphate N N B A Fish Oils B B A A Flourine Gas N A C B C B N N B A B B B B A B A B A A A A C C C A A A N N N A A N N N N C N N N N C N C B N C C C B N B N N C B B C C C A C © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. A B A C C 176 C C A A Anderson Greenwood Pressure Relief Valves Technical Manual Section 16 – Chemical Resistance Guide for Metals Chemical Resistance Guide For Metals Corrosive Media Conditions 316 SS CS 304 SS Foamite (Acid) N N C Foamite (Alkaline) A A A A Formaldehyde N C A A B A Formic Acid N N C A N C Freon N C C C A C Fruit Juices N N A A C A A A Fuel Oil B A A A Gallic Acid N N A A Gasoline (Natural) A A A A Gasoline (Refined) A A A A Gelatin N N A Glucose B B A Glycerine or Glycerol A A Hydraulic Oil (Petro.) B B Hydraulic Oil (Synthetic) A A Hydrazine 416 SS Material Used 17-4 PH Stellite Inconel® Brass Bronze Copper Monel® Hastelloy® C Gray Iron Ductile Iron C N N N A N N N N A A A A A B B N N N B A B A B B B A B N N N A B B B B A B A B B B A B A A N N N A A A A A A A A A A N A N N N A A A A A A A A A A A A B A A A B A A B A A A A A A B A A A A N N N N N C A N N N N N N N A A N N N B B N N N N N B B N N N A B A A A A A A A A A Hydrobromic Acid N N Hydrochloric Acid N N Hydrocyanic Acid N C A A Hydroflouric Acid N N N N Hydrofluosilic Acid N N N C B N Hydrogen (Gas) A A A A B A Hydrogen Chloride (Dry) B N C A C A C C C Hydrogen Chloride (Wet) N N N N N N N N C A Hydrogen Fluoride (Dry) C N C C N A C B B A B N N B Hydrogen Peroxide N N B B A B B N C C B A Hydrogen Sulphide (Dry) B C B A B B A C N N A B Hydrogen Sulphide (Wet) B C B A C B A C N N B A Kerosene B A A A A A A A A A A B Ketchup N N A A A C Ketones A A A A A A Lacquers and Solvents C C A A A A Lactic Acid N N B B C B Lard A A A Lactose A A B A A A A C C C C B A A A B N Lead Acetate N N B B N N C Lime-Sulfur A A A A B A A N C C Linseed Oil A A A A A A C C C © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. A B B B 177 Anderson Greenwood Pressure Relief Valves Technical Manual Section 16 – Chemical Resistance Guide for Metals Chemical Resistance Guide For Metals Corrosive Media Conditions Material Used 17-4 PH Stellite Inconel® Brass Bronze Copper Monel® Hastelloy® C Gray Iron Ductile Iron CS 304 SS 316 SS 416 SS Lubricating Oil (Petro.) A A A A A A A A A B Lubricating Oil (Synth.) A A A A A A A A A B Magnesium Chloride N C C B C C B A A A A Magnesium Hydroxide N B A A A A B A A A A Magnesium Nitrate N N N N N B Magnesium Sulphate N C A A B A A A B Magnesium Sulphite N N Maleic Acid N C A B A A A A B A C A Mercaptans A A A A Mercuric Chloride N N N N Mercuric Cyanide N N B Methane B A A C C C B B N N N N N N N N N B B B B N N N N B A A A A A B A Methanol B B B B Methyl Chloride C C B B A C B N B B B B B B A A B A B B B B B A Naphtha B A A A A A Naphthalene B A A A A A N N Nickel Chloride N N N C Nickel Nitrate N N B B A B B C A A A A B B B B B B N C C B A C C C B B A B Nickel Sulphate N N B Nitrating Acid N N C Nitric Acid (Crude) N N C B B C N N N N N B Nitric Acid (Pure) N N N A B A N N N N N C Nitrobenzene B A A A A B B B B B Oxalic Acid N N B A C B C B B A B Oxygen A A A A A A A A A A Palmitic Acid C C B A B B C B B B B Paraffin Oils B B A A A B B B A B Petroleum (Sour Crude) B B A A Petroleum (Sweet Crude) A A A A B A B C B B C N N N A C N N A A A A C N N A A A A A A A A B A A A A B Petroleum Oils (Refined) A A A A Phenol N N B B Phosphoric Acid N N B A B N N N B B Potassium Bromide N N C A C A C C C B A Potassium Carbonate B C A A A A C C C A B Potassium Chlorate B B A A A A B B B B B Potassium Chloride C N B B C B A N N N A B Potassium Cyanide N B B B B B B C B B B B C © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. B N 178 Anderson Greenwood Pressure Relief Valves Technical Manual Section 16 – Chemical Resistance Guide for Metals Chemical Resistance Guide For Metals Corrosive Media Conditions CS 304 SS 316 SS Potassium Dichromate C C A A Potassium Hydroxide C C C C Potassium Hypochlorite N N C B Potassium Nitrate B A B B B Potassium Sulphate N N B A B Producer Gas A A A A Propane A B A A A A Rosin B B B B A B Salicylic Acid N N B A Sea (Salt) Water N N A A C A B Shellac N N A A Silver Bromide N N C B C C N Silver Chloride N N N N N C Silver Nitrate N N A A A A Sludge, Acid C C C Sewage C A 416 SS Material Used 17-4 PH Stellite Inconel® Brass Bronze Copper Monel® Hastelloy® C Gray Iron Ductile Iron A B N N N B B C B N N N A B C N N N N B B A A A B B B B A A A A A C C C A A A A A B A B B B A B B B B B A B C B B A B B B B A B B A A A N N N B B N N N N A N N N B A A A B Soap Solutions (Liquid) B A A A C A C C C A Sodium Acetate N N A A C A A B B B B B Sodium Aluminate A A A A A A B B B B B Sodium Bicarbonate B A B B A B A A A A A Sodium Bisulphate N N B A A B N N N A A Sodium Bisulphite N N B A N N N B B Sodium Carbonate A A B B B B A A B A B C Sodium Chlorate B A B B Sodium Chloride C C C B C A Sodium Cyanide C C C B Sodium Fluoride N N C A B B B B N C B C Sodium Hydroxide C C C C A C Sodium Hypochlorite N N C B N C C A B A Sodium Nitrate C B B A Sodium Nitrite B A B B N B C C C B B C B B A A N N N A A C C C A B N C C B B N C C C A C B B B B B B B B B Sodium Perborate C C A A A A A C B B B B Sodium Peroxide C C A A A A A C B B B B Sodium Phosphate (Mono) N N A A B A C C C A B Sodium Phosphate (Di) N N A A B A A A A B B B Sodium Phosphate (Tri) C C A A B A A C C C Sodium Silicate B B A A B A A C B B © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. B B 179 Anderson Greenwood Pressure Relief Valves Technical Manual Section 16 – Chemical Resistance Guide for Metals Chemical Resistance Guide For Metals Corrosive Media Conditions Material Used 17-4 PH Stellite Inconel® Brass Bronze Copper Monel® Hastelloy® C Gray Iron Ductile Iron CS 304 SS 316 SS 416 SS Sodium Sulphate B B B A B B B B A A A B Sodium Sulphide B B C A B C A N N N A B Sodium Sulphite N C A A A C B B B B B Sodium Thiosulphate N N A B A B B B B B B Stannic Chloride N N N N N N N N N C B Stannous Chloride N N N A N B N N N B B Steam, 212°F A A A A B A A A B B B A A Steam, 600° F C C A A B A B A N N N A A Sulfur C C A A A A A C C C C A Sulfur Chloride N N N C N N B N N N B B Sulfur Dioxide (Dry) B B A A A A B C A A B Sulfur Dioxide (Wet) N N B A N B N N B B C B B B B B B N N N B A Sulfur Trioxide B B B B B B Sulfuric Acid, 2% and Less N N C B N C N Sulfuric Acid, 2-40% N N N N N N N B N N N B B Sulfuric Acid, 40% N N N N N N N B N N N B B N Sulfuric Acid, 93-100% B B B B B B Sulfurous Acid N N B B N B B N N N N B C N N N N A A A Tannic Acid C B A A C A B B B B Tar A B A A B A A B A A Tartaric Acid N N B A C B A Tung Oil C C A A N A Turpentine B B A A B A Varnish C C A A A A B A A A A Vegetable Oil C B B C C C A A C B B C A B B B A B B B B B B Water (Acid Mine) N N B B A B B A N N N A Water (Boiler Feed) B B A A A A A A C C C A Water (Distilled) N N A A A A A A N N N A B Water (Fresh) A A A A A A A A C B B A A Water (Salt) N N N C N N A B C B B A Wine and Whiskey N N A A N A A A B B B C A Xylene (Xylol) B B A A A A A A A A A A Zinc Chloride N N N C N N B N B B B B Zinc Sulphate N N A A B A B C B B A B © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 180 Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR Acetaldehyde Acetamide Viton® Silicone Kalrez® Chemraz® Teflon® PEEK X X X X Kel-F® Vespel Urethane X X X X X X X X X X X X X X X X X X X Acetic Acid X Acetic Anhydride X Acetone X X X X X X X Acetophenone X X X X X X X Acetyl Acetone X X X X X X X X X X X X X X X X X X X X X X X X X Acetyl Chloride Acetylene X X X Acetylene Tetrabromide X X X X X Acrylonitrile X X X X X X X X X X X X X X X X X X X X X X Alkyl Alcohol X X X X X X Alkyl Amine X X X X X X X X X X X X X X X X X X Adipic Acid X Air X X Alkazene X X X Alum Solution Aluminum Acetate X X Aluminum Chloride X X X X X X X X X X Aluminum Fluoride X X X X X X X X X X X X X X X X Aluminum Nitrate X X X X X X X X Aluminum Phosphate X X X X X X X X Aluminum Potassium 10% X X X X X X X Aluminum Sulfate X X X X X X X X X Alum-NH3-Cr-K X X X X X X X X X X Aluminum Hydroxide Amines - Mixed X X X X X X X X X Ammonia Anhydrous X X X X X X X X X Ammonia Aqueous Liquid X X X X X X X X Ammonia Gas X X X Ammonium Bifluoride Ammonium Carbonate X X X X X X X X X X X X X X X X X X X X Ammonium Chloride X X X X X X X X Ammonium Hydroxide X X X X X X X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 181 Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR Ammonium Nitrate X X Ammonium Nitrite X X Ammonium Persulphate Viton® Silicone Kalrez® Chemraz® Teflon® PEEK X X X X X X X X X X X X X X X X X X X X X X X X X X X Ammonium Phosphate Tribasic X X X X X X Ammonium Sulfate X X X X X Ammonium Sulfite X X X Amyl Borate X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Amyl Alcohol Vespel Urethane X Ammonium Phosphate Dibasic Amyl Acetate Kel-F® Amyl Chloride X X X X X X X Amyl Chloro Naphthalene X X X X X X X Amyl Naphthalene X Aniline X Aniline Dyes X X X X X X X X X X X X X X X X X X X X Aniline Hydrochloride X X X X X X X X X Animal Fats X X X X Ansul Ether Antimony Trichloride Apple Juice X X Aqua Regia Argon X X X Arochlor(s) X Arsenic Trichloride X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Aromatic Fuels Arsenic Acid X X X X Arsenous Acid X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Askarel X X Asphalt X Astm Oil Automatic Transmission Fluid Barium Carbonate X X X X X X X Barium Chloride X X X X X X X X X X X Barium Hydroxide X X X X X X X X X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 182 Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR Viton® Silicone Kalrez® Chemraz® Teflon® PEEK Barium Nitrate Barium Sulfate X X X X Kel-F® Vespel Urethane X X X X X X X X X X X X X Barium Sulfide X X X X X X X X Beer X X X X X X X X X X X X Beet Juice X X X X X Beet Pulp X X X X X X X Beet Sugar Liquors X Bentonite X Benzaldehyde X X X X X X X X X X X X X X X X X X X X X X X X X Benzene Benzochloride X X X X X X X Benzoic Acid X X X X X X X Benzophenone X X Benzyl Alcohol X X X X X X X X X X X X X X X Benzyl Benzoate X X X X X X X Benzyl Chloride X X X X X X X Beryllium Sulfate X X X X Bichloride of Mercury X X X X X X Bittern X X X X X X Black Liquor X X X X X X Blast Furnace Gas Bleach Liquor X X X X X X X X X X X X X X X X X X X X Bleach Solutions Blood X X Boiler Feed Water Borax X Bordeaux Mixture Boric Acid X Brake Fluid (Non Petroleum) Brine X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Brine, Calcium X X X X X X Brine, Cal. and Sodium Chloride X X X X X X Brine, Cal. and Mag. Chloride X X X X X X Brine, Seawater X X X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 183 Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR Viton® Silicone Kalrez® Chemraz® Teflon® PEEK Kel-F® Vespel Urethane Bromine X X X X X X X Bromine Anhydrous X X X X X X X Bromine Trifluoride X X X X X X X Bromine Water X X X X X X X Bromobenzene X X X X X X X Bromochloro Trifluoroethan X X X X X X X Bunker Oil X X X X X X X X X Butadiene Monomer X X X X X X X X X Butane X X X X X X X X Butane, 2,2-Dimethyl X X X X X X X X Butane, 2,3-Dimethyl X Butanol (Butyl Alcohol) X X Butene, 2-Ethyl X X Butter X X Buttermilk X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Butyl Acetate Butyl Acetyl Ricinoleate Butyl Acid X X X Butyl Acrylate Butyl Alcohol X Butyl Amine or N-Butyl Amine Butyl Carbitol X X X X X Butyl Cellosolve X X X Butyl Chloride Butyl Oleate Butyl Stearate X Butylene X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Calcium Bisulfide Calcium Bisulfite X X X Calcium Carbonate X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 184 X X X Butyric Acid Calcium Chlorate X X X X X X X Butyraldehyde Calcium Acetate X X X X X X Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR Calcium Chloride X X Calcium Cyanide X X Calcium Hydroxide X X Calcium Hypochloride X Viton® Silicone Kalrez® Chemraz® Teflon® PEEK X X Kel-F® Vespel Urethane X X X X X X X X X X X X X X X X X X X X X X X X X X X Calcium Hypochlorite X X X X X X X X X Calcium Nitrate X X X X X X X X X X X Calcium Phosphate X X X X X X X X Calcium Silicate X X X X X X X X X X X X X X X X X X X X X X Calcium Sulfate X Calcium Sulfide X Calgon X X X X Caliche Liquor X X X X Camphor X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Cane Juice Cane Sugar Liquors X Carbamate Carbitol X Carbolic Acid Phenol X X X X X X X X Carbon Bisulfide Carbon Dioxide Dry X X X Carbon Dioxide Wet X X Carbon Disulfide Carbon Monoxide X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Carbon Tetrachloride Dry X X X X X X X Carbon Tetrachloride Wet X X X X X X X X X X X X X X X Carbonate of Soda Carbonic Acid X Casein X Castor Oil X X X X X X X X X X X X X X Catsup X X X X Caustic Manganese X X X X X X Caustic Potash (Aqueous) X X X X X X Caustic Soda (Aqueous) X X X X X X Caustic Sulphide X X X X X X X X X X X X X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 185 Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR Viton® Silicone Kalrez® Chemraz® Teflon® PEEK Caustic (Chloride of Sodium) Kel-F® Vespel Urethane X X X X X X Cellosolve X X X X X X X Cellosolve Acetate X X X X X X X Cellulube X X X X X X X X X X X X X X X X X X Chloride of Lime X X X X X Chloride of Zinc (Aqueous) X X X X X Cetene (Hexadecane) X Chloric Acid X Chlorinated Salt Brine X X X X X X Chlorine, Dry X X X X X X X Chlorine, Wet X X X X X X X Chlorine Dioxide X X X X X X X Chlorine Trifluoride X Chloro 1-Nitro Ethane X X X X X X X X X X X X Chloroacetic Acid X X X X X X Chloroacetone X X X X X X X X X X X X X X X X X X X X X Chlorobenzene Chorobromo Methane X Chlorobutadiene X X X X X X X Chlorododecane X X X X X X X Chloroform X X X X X X X X X X X X Chlorosulfonic Acid Chlorosulfuric Acid Chlorotoluene Chlorox X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Chrome Alum Chrome Plating Solutions X Chromic Acid X X X Chromic Oxide (Aqueous) Citric Acid X X Cobalt Chloride X X Coca Cola Syrup X X X X X X X X X X X X X X X X X X X X X X X X X X Cocoa Butter Coconut Oil X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 186 X X X X X Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid Cod Liver Oil BUNA-N EPR X X Viton® Silicone Kalrez® Chemraz® Teflon® PEEK X X Coffee Extracts Hot Coke Oven Gas X X X X X X X X X X X X X X X X X X Kel-F® Vespel Urethane X X X X Cooking Oil X Copper Acetate X X X X X X X X Copper Chloride X X X X X X X X X X X Copper Cyanide X X X X X X X X X X X X X X X X X X X Copper Nitrate Copper Sulfate X Corn Oil X Cottonseed Oil X Creosote X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Cresol X X X X X X X Cresylic Acid X X X X X X X X X X X X X X X X X X X Crude Oil Sour Crude Oil Sweet X Cumene X X X X X X X X X X X X X X X Cyclohexane X X X X X X X X Cyclohexanol X X X X X X X X X X X X X X Cupric Chloride Cutting Oil Cyclohexanone X Decalin X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Decane X Denatured Alcohol X Detergent, Watered Solution X Developing Solutions X Dexron X X Dextrin X X X Diacetone X X X X X X X Diacetone Alcohol X X X X X X X Dibenzyl Ether X Dibenzyl Sebacate X Dibromoethyl Benzene X X X X X X X X X X X X X X X X X X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 187 Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR Viton® Silicone Kalrez® Chemraz® Teflon® PEEK Kel-F® Vespel Urethane Dibutyl Amine X X X X X Dibutyl Ether X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Dibutyl Phthalate X Dibutyl Sebacate X X Dichloroethane Dichloro-Butane X X Dichloro-Difluromethane X X X Dichloro-Ethyl Ether X X X Dichloro-Isopropyl Ether X Dichloro-Pentane Dicylohexylamine Diesel Oil X X X Diester Synthetic Lubricants X Diethanol-Amine X Diethyl Amine (DEA) X X Diethyl Benzene X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Diethyl Carbonate X X X X X X Diethyl Ether X X X X X X X Diethyl Sebacate X X X X X X X X X X X Diethylene Glycol X X X X X X X X X X X X X X X X X X X X X X X Diethylene Triamine Diisobutylene X X Diisopropyl Benzene X Diisopropyl Ketone X Dimethyl Aniline Dimethyl Formomide (DMF) X X Dimethyl Phthalate X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Dimethyl Terephthalate X X X X X X Dinitrotoluene X X X X X X Dioctyl Amine X X X X X X Dioctyl Phthalate X X X X X X X X Dioctyl Sebacate X X X X X X X X Dioxane X X X X X X X Dioxolane X X X X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 188 Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR Dipentane Dipentene X Diphenyl Diphenyl Oxides Viton® Silicone Kalrez® Chemraz® Teflon® PEEK X Vespel Urethane X X X X X X X X X X X X X X X X X X X X X X X X X X X X Kel-F® X X Dish Water X X X X X X X Dowtherm A X X X X X X X Dowtherm E X X X X X X X X X X X X X X X X X Dye Wood Liquor X X X X X X Enamel X X X X X X X X X X X X X X X X X X X X X X X X X X X X Disodium Phosphate X Dry Cleaning Fluids Drying Oil X Epichlorohydrin Epsom Salt X Essential Oils X Ethan (Methylmethane) Ethane (Ethylene) X Ethanol X X Ethanol Amine X Ethone X X X X X X X X X X X X X X X X X X X X X X X X X Ethyl Acetate-Organic Ester X X X X X X X X Ethyl Acetoacetate X X X X X X X X X X X X X X X X X X X X X X X X Ethyl Acrylate Ethyl Alcohol X Ethyl Benzene Ethyl Benzoate Ethyl Bromide X Ethyl Cellosolve X Ethyl Chloride X Ethyl Chlorocarbonate X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Ethyl Chroroformate Ethyl Ether X X X Ethyl Cellulose Ethyl Cyclopentane X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 189 Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR Ethyl Formate Ethyl Hexanol X X X X X Ethyl Mercaptan Ethyl Oxalate X Ethyl Sulfate X Ethylene Chlorohydrin X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Vespel Urethane X Ethylene Chloride Ethylene Diamine X Kel-F® X Ethyl Pentachlorobenzene Ethyl Silicate Viton® Silicone Kalrez® Chemraz® Teflon® PEEK X X X X X X X X X X X X X X X X X X X X X X X X X X X X Ethylene Dibromide X X X X X X X Ethylene Dichloride X X X X X X X Ethylene Glycol X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Ethylene Oxide Ethylene Trichloride Fatty Acids X Ferric Chloride X X Ferric Chloride Boiling X X X X X X X Ferric Nitrate X X X X X X X X X X X Ferric Sulfate X X X X X X X X X X X Ferrous Chloride X X X X X X X X X X X X X X X X X X X Ferrous Sulfate X Fish Oil X X Florine Gas X X Flue Gases X Fluorinated Cyclic Ethers X X X X X X X X X X Fluorine Gas Dry X X Fluorine (Liquid) X X X X Fluorobenzene X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Fluoroboric Acid X Fluorocarbon Oils Fluorolube X Fluorosilic Acid X Formaldehyde X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 190 X X X X Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR Viton® Silicone Kalrez® Chemraz® Teflon® PEEK X Vespel Urethane Formic Acid X X X X X X Freon 11 X X X X X X X X Freon 112 X X X X X X X X Freon 113 X X X X X X X X Freon 114 X X X X X X X X Freon 114B2 X X X X X X Freon 115 X X X X X X Freon 12 X X X X X X X X X X X Kel-F® Freon 121 X X X X Freon 13 X X X X X X X X X Freon 13B1 X X X X X X X X X Freon 14 X X X X X X X X X Freon 142b X X X X X X Freon 152a X X X X X X X X X X X X X X X X X X X Freon 22 X X X X X X X X Freon 31 X X X X X X X X X X Freon 21 Freon 218 Freon 32 X Freon 502 X X X X X X X X X X X Freon BF X Freon C316 X X X X X X X X X X X Freon C318 X X Freon MF X X X X X X X X X X X Freon TA X X Freon TC X X Freon TF X Freon TMC X X Freon T-P35 X X X Freon T-WD602 X X X X X X X X X X X X X X X X X X X X X X X X X X X X Fruit Juices X X X X X X X X Fuel Oil X X X X X X X Fuel Oil Acidic X X X X X X X X Fuel Oil #6 X X X X X X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 191 Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid Fumaric Acid BUNA-N EPR X X Viton® Silicone Kalrez® Chemraz® Teflon® PEEK X X Furan Kel-F® Vespel Urethane X X X X X X X X X X X X Furfural X X X X X X X Furfuraldehyde X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Furfuran Furfuryl Alcohol X Furyl Carbinol Gallic Acid X X X X Gas, Natural X X X X X Gas, Sour X X X X X Gas Odorizers X X Gas Oil X X X X X X X X X X X X X Gasoline Aviation X X X X X X Gasoline Leaded X X X X X X Gasoline Refined X X X X Gasoline Sour X X X X Gasoline Unleaded Gelatin X X Glauber’s Salt X X X X X X X X X X X X X X X X X X X X X X X Glucose X X X X X X X X X X X Glue X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Glue Sizing Glycerine-Glycerol X X X X Glycol Amine Glycols X X X X Glyoxal Grape Juice Graphite X X Grease Green Sulfate Liquor X X Halothane X X X Halowax Oil X Helium X Heptane X X X X X X X X X X X X X X X X X X X X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. X 192 X X Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR Viton® Silicone Kalrez® Chemraz® Teflon® PEEK Hexamine Kel-F® X X X Hexanol Tertiary X X X X X Hexyl Alcohol X X X X X X X X X X X X X X X X X X X X X X X X X X X X Hops Hydraulic Oil, Petroleum Base X X X Hydraulic Oil, Synthetic Base Hydrazine X Hydrazine Anhydrous X X Hydrobromic Acid Hydrocarbons X X X Hydrochloric Acid over 158°F X X X X X X X X X X X X X X X X X X X X X X X X Hydrocyanic Acid X X X X X X X X X X X X X X X Hydrofluoric Acid Hot X Hydrofluoric Acid-Anhydrous X X X Hydrochloric Acid to 158°F Hydrofluoric Acid Cold Vespel Urethane X X X X X X X X X X X X X Hydrofluosilicic Acid X X X X X X X X Hydrogen Gas X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Hydrogen Peroxide Hydrogen Sulfide Dry Hydrogen Sulfide (Wet) Cold X Hydrogen Sulfide (Wet) Hot Hydroquinone Hydyne X Hypochlorous Acid X X Illuminating Gas X Ink, Newspaper X Iodine X X Iodine Pentafluoride Iodoform X Isobutane X Isobutyl Alcohol X Isobutyl N-Butyrate Isododecane X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 193 Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid Isooctane BUNA-N EPR X Isophorone (Ketone) Isopropanol X X X Isopropyl Acetate Isopropyl Alcohol X X X X X X Isopropyl Chloride Isopropyl Ether Viton® Silicone Kalrez® Chemraz® Teflon® PEEK X X X X JP-3 to JP-10 Kel-F® Vespel Urethane X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Kerosene X X X X X X Ketchup X X X X X X Ketones X X X X X X Lacquer solvents X X X X X X X Lacquers Lactic Acid X Lactones Lard X X X X X Lead Acetate X X Lead Nitrate X X Lead Sulfamate X X Lime Bleach X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Linoleic Acid X X X Linseed Oil X X X Liquid Petroleum Gas (LPG) X X X X X X X X X X X X X X Lithium Bromide X X X X X X Lithium Chloride X X X X X X X X X X X X Lubricating Oils X X X X X Ludox X X X X X Lye Solutions X X X X Magnesium Bisulfate X X X X X Magnesium Bisulfide X X X X X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 194 X X X Lime Water Lindol X X X Lime Liquor Lime Sulfur X X X Latex Lavender Oil X X X X X Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR Viton® Silicone Kalrez® Chemraz® Teflon® PEEK Magnesium Carbonate X Magnesium Chloride X X X X Magnesium Hydroxide X X X X Majamie Resins X Malathion X X Maleic Acid Maleic Anhydride X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Malic Acid X Manganese Carbonate X X X X X Manganese Chloride Manganese Sulfate Mayonnaise X X Mea with Copper Sulfate Mea (Mono Ethanol Amine) X Meat Juices X Menthol X Mercuric Chloride X X X X Vespel Urethane X X Magnesium Nitrate Magnesium Sulfate Kel-F® X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Mercury Salts X X X X X X Mercury Vapors X X X X X X X X X X X X Mercuric Cyanide Mercurous Nitrate Mercury X X Mesityl Oxide (Ketone) X X X X Methane X X Methanol X X Methyl Acetate X Methyl Acetoacetate X X X Methyl Acetone Methyl Acrylate Methyl Alcohol X X X X Methyl Amine Methyl Benzoate Methyl Bromide Methyl Butyl Ketone X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 195 Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR Methyl Carbonate Viton® Silicone Kalrez® Chemraz® Teflon® PEEK X Methyl Cellosolve X Methyl Cellulose Kel-F® Vespel Urethane X X X X X X X X X X X X X X X Methyl Chloride X X X X X X X Methyl Chloroformate X X X X X X X X X X X X X X X X X X X X X X X X X Methyl Chlorosilanes Methyl Cyclopentane Methyl Ether X X X X Methyl Ethyl Ketone (MEK) X X X X X X X Methyl Formate X X X X X X X Methyl Isobutyl Ketone X X X X X X Methyl Isopropyl Ketone X X X X X X X Methyl Mercaptan X X X X X X X X X X X X X Methyl Methacrylate Methyl Oleate X X X X X X X Methyl Salicylate X X X X X X X Methylacrylic Acid X X X X X X X X X X X X Methylene Chloride Milk X X X X X X X X X X X X X X X X X X X X X X X X X X X Molasses X X X X Molybdic Acid X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Milk of Lime Mine Water Mineral Oils X X Mono Bromobenzene Mono Chlorobenzene Mono Ethyl Ether X X Mono Methyl Aniline X Mono Methyl Hydrazine (Hypergol) X X X X Mono Vinyl Acetylene X X X X Mopholine Muriatic Acid X X Mustard Mustard Gas Naphtha X X X X Naphtha Crude X X X X X X X X X X X X X X X X X X X X X X = General acceptability Blank = Not acceptable or no available data 196 X X X X Note © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. X X Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR Naphthalene Viton® Silicone Kalrez® Chemraz® Teflon® PEEK Kel-F® X X X X X X X X X X X X Vespel Urethane X Naphthenic Acid X Natural Gas X X X X X X X Neatsfoot Oil X X X X X X X X X X Neon X X X X X X X X X X X X X X X X X X X X X Neville Acid X Nickel Acetate X Nickel Ammonium Sulfate X X X X X X X X X X X X Nickel Chloride X X X Nickel Cobalt Sulfate X X X X X X X X X X X X X X X X X Nickel Nitrate X Nickel Salts X X X X X X X X X X X X X X Nickel Sulfate X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Nicotine Sulfate Nicotinic Acid Niter Cake X X X Nitric Acid-Concentrated X X X Nitric Acid-Dilute X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Nitric Acid-Red Fuming Nitrobenzene Nitrobenzine Nitroethane Nitrogen X X X X X Nitrogen Tetroxide X Nitropropane X Nitrous Acid X X Nitrous Gases X N-Butyl Acetate X N-Butyl Benzoate X N-Butyl Butyrate N-Heptane X X Nitromethane Nitrous Oxide X X X X N-Hexaldehyde X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X N-Hexane X X X X X X X X X X N-Hexane-1 X X X X X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 197 Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR N-Methyl-2-Pyprolldone Viton® Silicone Kalrez® Chemraz® Teflon® PEEK X N-Octane X N-Pentane X N-Propyl Acetone X X X X X X X X X X X X X X X X X X X X X X X Octadecane X X X X X X Octadene X X X X X X X X X X X X X X Octyl Alcohol X X X X Olefin, Crude Oleic Acid X X X X X X X X X X X X X X X X Oleum Oleum Spirits X Olive Oil X X Orthochloro Ethylbenzene Ortho-Dichlorobenzene Oxalic Acid X X X X X X X X X X X X X X X X X X X X X X X X X X Oxygen Cold X X X Oxygen (-200°F to +400°F) X X X X X X X X X X X X X X X X X X X X X X X X O-Chloronaphthalene X X X X X X X O-Chlorphenol X X X X X X X O-Dlchlorobenzene X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Paint Thinner, Duco Palm Oil X Palmitic Acid X X X X X Paraffin Liquid X X X X X X X X X X X X X X Pectin Liquor X X X X X X Pentachloro Phenol X X X X X X X X X X X X X X X X X X X Paraformaldehyde X Para-dichlorobenzene Peanut Oil Pentane X X X Perchloric Acid X X X X Perchloroethylene X X X X X X X X Petrolatum X X X X X X X X X X X X X X X Petroleum Oil above 250° F Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 198 X X X X X X X X Ozone X X Vespel Urethane X X Octochloro Toluene Kel-F® X X Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid Petroleum Oil below 250° F BUNA-N EPR X Viton® Silicone Kalrez® Chemraz® Teflon® PEEK X X Kel-F® Vespel Urethane X X X X X X Phenol X X X X X X X Phenyl Benzene X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Phenyl Ethyl Ether Phenyl Hydrazine X Phorone X X Phosphate Esters Phosphoric Acid to 158°F X X X X X X X X X X X Phosphoric Anhydride Phosphorous Trichloride Phosphorus Pentoxide X X X Phosphorus Trichloride X X X Photographic Solutions X X X X Phthalic Acid X X X X Phthalic Anhydride X X X X Pickling Solution X X X X X X X X X Picric Acid X X X X X X X Pine Oil X X X X X X X Pineapple Juice X X X X X Pinene X X X X X X X X Piperidine Plating Solutions - Chrome Plating Solutions - Other X Polysulfide Liquor X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Poly Glycols X X X Potash X X X X X X Potash Alum X X X X X X Potash Sulfide Potassium Acetate X X X X X X X X X X X X X X Potassium Bicarbonate X X X X X X Potassium Bichromate X X X X X X X X Potassium Bisulfite X X Potassium Bromide X X X X X X X X Potassium Carbonate X X X X X X Potassium Chlorate X X X X X X X X X X X Potassium Chloride X X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 199 Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR Viton® Silicone Kalrez® Chemraz® Teflon® PEEK Kel-F® Vespel Urethane Potassium Cupro Cyanide X X X X X X X X X X Potassium Cyanide X X X X X X X X X X X X X Potassium Dichromate X X X X X X X Potassium Diphosphate X X X X X X X X Potassium Ferricyanide X X X X X X X Potassium Ferrocyanide X X X X X X X Potassium Hydroxide X X Potassium Hypochlorite X Potassium Iodide X Potassium Nitrate X X X X X X X X X X X X X X X X X X X X X X X Potassium Oxalate X X X Potassium Permanganate X X X X X X X X X X X X X X X Potassium Phosphate Potassium Salts X X X X Potassium Sulphate X X X X X X X X X Potassium Sulphite X X X X X X X X X X X X Potassium (Molten) X Prestone X X Producer Gas X X X X X Propane X X X X X Propane Propionitrile X X X X X X X X Propyl Acetate X Propyl Alcohol X Propyl Bromide X Propyl Nitrate X X X X X Propylene Propylene Glycol X X Propylene Oxide X X Pyridine Pyrogallic Acid Pyroligneous Acid X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Pyrrole P-Cymene X X X X X X X X Pulp Stock Pyranol X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 200 X X X X Pydrauls X X X X X X Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR P-Dichlorobenzene P-Tertiary Butyl Catechol X Viton® Silicone Kalrez® Chemraz® Teflon® PEEK X X X X X X X X X X X X X X X Radiation X X Rapeseed Oil X X Red Oil X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Rosin Rubber Solvents Sal Ammoniac X Salad Oil X Salicylic Acid Vespel Urethane X Quench Oil RP-1 Fuel Kel-F® X X X X X X X X X X X X X X X X Seawater, Saltwater X X X X X X X X X Sewage X X X X X X X X X X Shellac X X X X X Silicate Ethers X X X X X X X X Silicic Acid X X X X X X X X Silicone Greases X X X X X X X X X Silicone Oils X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Salt Cake Silver Bromide Silver Chloride X Silver Cyanide X Silver Nitrate X X X X X Skydrol 500 X Skydrol 7000 X X X Soap Liquors X X X X X X Soap Solutions X X X X X X X X X X Soda Ash X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Sodium Bisulfate X X X X X X X X X X Sodium Bisulfite X X X X X X X X X X Sodium Sodium Acetate X Sodium Aluminate Sodium Bicarbonate Sodium Bichromate X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 201 Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR Sodium Borate X Sodium Bromide X Sodium Carbonate (Caustic) X Sodium Chlorate X Sodium Chloride X Sodium Chromate X X Viton® Silicone Kalrez® Chemraz® Teflon® PEEK X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Sodium Citrate X X X Sodium Cyanamide X X X X X X X X X X Vespel Urethane X Sodium Cyanide X Kel-F® X X Sodium Fluoride X X Sodium Hydrosulfite Sodium Hydroxide X X X X X X X X X X X X X X X X X X X X X X X X X X Sodium Hypochlorate X X X X X X X X X X Sodium Hypochlorite X X X X X X X X X X X X X X X X Sodium Hyposulfite X Sodium Lactate Sodium Metaphosphate X Sodium Metasilicate X X Sodium Nitrate X X Sodium Perborate X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Sodium Peroxide X X X X X X X X X Sodium Phosphate X X X X X X X X X X X X X X X X X X X X X X X X Sodium Plumbite Sodium Silicate Sodium Sulfate X X X X X X X X X X Sodium Sulfide X X X X X X X X X X X X X X X X X X X X X X X X X X X Sodium Sulfite X Sodium Sulfite X X X X X Sodium Tetraborate Sodium Thiosulfate X X X X X X X X X X Sodium Trisulfate X X X X X X X X X X X X X X X X Soybean Oil X X X X X X X X Stannic Chloride X X X X X X X X X X X X X X X X X X X Sorbitol Stannous Chloride X Starch Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 202 X X X Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR Viton® Silicone Kalrez® Chemraz® Teflon® PEEK Kel-F® Steam over 300°F X X X X X X Steam under 300°F X X X X X X X X X X X X X X X X Stearic Acid X Stoddard Solvent X X X X Styrene X X X X X X X X X X X X X Sulfate Liquors X X X X X X Sulfate of Hydrogen X X X X X X Sulfate of Lime X X X X X X Sulfate of Sodium X X X X X X X X X X X X X X X X X X Sucrose Solutions Sulfite Liquors X Vespel Urethane X X X X X X X Sulfite Pulp Sulfur X X X X X X X Sulfur Chloride X X X X X X X Sulfur Dioxide X X X X X X X X X X X X X X X X Sulfur Trioxide X X X X X X X X X Sulfur Trioxide, Dry X X X X X X X X X X X X X X X X X X X Sulfur Hexafluoride X X Sulfuric Acid (20% Oleum) Sulfuric Acid (Concentrated) X Sulfuric Acid (Dilute) Sulfurous Acid X X X X X X X X X X X X Sulphonated Fatty Alcohol X X X X X X Sulphonated Vegetable Oils X X X X X X Syrup X X X X Tall Oil X X X X X X X Tallow X X X X X X Tannic Acid X X X X X X X X X Tar, Bituminous X X X X X X X X X X X X X X X X Tartaric Acid X X X X X X X X X Terpineol X Tar, Pine Tertahydrofuran Tertiary Butyl Alcohol X X X X X X X X X X X X X X X X X X X X X X X X X Tertiary Butyl Mercaptan X X X X X X X Tetrabromoethane X X X X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 203 Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid BUNA-N EPR Tetrabromomethane Tetrabutyl Titanate X X Viton® Silicone Kalrez® Chemraz® Teflon® PEEK Kel-F® Vespel Urethane X X X X X X X X X X X X X X Tetrachloroethane X X X X X X X Tetrachloroethylene X X X X X X X X X X X X X X X X X X X X Tetraethyl Lead X Tetralin Tetraphenyl X X X X X X X X X X X X X Thionyl Chloride X X X X X X Titanium Tetrachloride X X X X X X X X X X X X X X X X X X X Therminol VP-1,44,55,60,66 Toluene Toluene Diisocyanate X Tomato Pulp Transformer Oil X Transmission Fluid Type A X Triacetin X X X X X X X X X X X X X X X X X X X X X X X X X X X X Triaryl Phosphate X X X X X X X X Triaryl Phosphate X X X X X X X X Tributoxyl Ethyl Phosphate X Tributyl Mercaptan Tributyl Phosphate Trichloroacetic Acid X X X X X X X X X X X X X X X X X X X X X X X X X X X X Trichloroethane Trichloroethylene Tricresyl Phosphate X Triethanol Amine X X X X X X X X X X X X X X X X X X X X X X X X X X X Triethyl Aluminum X X X X Triethyl Borane X X X X Trifluoroethane X X X X Trinitrotoluene (TNT) X X X X X Trioctyl Phosphate X X X X X X X Tripoly Phosphate X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Trisodium Phosphate Tung Oil (Chine Wood Oil) X X Turbine Oil X X Turpentine X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 204 X X Anderson Greenwood Pressure Relief Valves Technical Manual Section 17 – Chemical Resistance Guide for Elastomers and Thermoplastics Chemical Resistance Guide For Elastomers and Thermoplastics Fluid Unsym. Dimethyl Hydrazine BUNA-N EPR X Viton® Silicone Kalrez® Chemraz® Teflon® PEEK X Urea and Phenolic Resins Uric Acid Varnish X Vegetable Oil X Versilube X X Vinegar X X Vinyl Chloride X Vinyl Chloride Monomer (VCM) Water Waxes X Whiskey and Wines X X X X X X X X X X X X X X X X X X X X X White Pine Oil X X Zinc Bromide X Zinc Chloride X Zinc Hydrosulfite X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Yeast X X X X X X X X X Xylidenes X X X X Wood Vinegar Zinc Acetate X X X Zeolites X X X Wood Pulp Xylol X X White Water, Paper Mill X X X X X Xylene X X X X X X X X X X White Oil Xenon X X X X X X X X White Liquor Wood Oil X X X X X X X X X Wagner 21B Fluid X X X Vinylidine Chloride Vespel Urethane X X X Kel-F® X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Zinc Nitrate X X X X X X Zinc Phosphate X X X X X X Zinc Salts X X X X X X X X X X Zinc Sulfate X X X X X X X X X X Note X = General acceptability Blank = Not acceptable or no available data © 1997 Anderson Greenwood reserves the right to change product designs and specifications without notice. 205 Pressure Relief Valve Technical Manual Revised May 1998 Catalog: PRVTM-US.97 Anderson Greenwood Anderson Greenwood P.O. Box 944 Stafford, Texas 77497, USA Tel: (281) 274-4400 Fax: (281) 240-1800 International Tel: +1 281 274-4400 International Fax: +1 281 240-1800 Corrie Way, Bredbury Industrial Estate, Stockport, Cheshire SK6 2ST, UK Tel: 0161 494 5363 Fax: 0161 494 5672 Telex: 668379 International Tel: +44 161 494 5363 International Fax: +44 161 494 5672 © 1997 Anderson Greenwood Printed in USA
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