Why Water is Weird Learning Target I can relate the molecular structure of simple substances to their properties Water is the molecule of life • https://www.youtube.com/watch?v=HVT3Y3_gHGg Water is a polar molecule • Oxygen is a very electronegative atom (you can think of it as being a stronger electron “magnet” than most other elements) • Because oxygen is electronegative, it has a partial negative charge • Because the hydrogens are weaker electron “magnets” than oxygen, they have a partial positive charge • When molecules have an unequal distribution of electron density, we say that they are polar Water has hydrogen bonds • Because they are polar, water molecules attract each other • A positive hydrogen from one water molecule will attract the negative oxygen from another water molecule • This hydrogen to oxygen attraction is called a hydrogen bond • Hydrogen bonds are one type of intermolecular force (acts between molecules) • On the other hand, covalent bonds are a type of intramolecular force (acts within molecules). Cohesion • The hydrogen bonding between water molecules causes water molecules to stick together. This sticking together between water molecules is called cohesion • The cohesion among water molecules causes water to have a high surface tension. In other words, it is elastic and sticky, and tends to clump together in drops rather than spread out in a thin film • High surface tension allows insects (and one lizard) to walk along the surface of the water. https://www.youtube.com/watch?v=45yabrnryXk start at :50 Adhesion & capillary action • Adhesion is the attraction of water molecules to other surfaces • Adhesion can be stronger than cohesion, resulting in capillary action Water is an excellent solvent • Many molecules are polar because the atoms that make it up have different electronegativities • Water can dissolve other polar substances but cannot dissolve nonpolar substances. • Fats/oils are examples of non-polar substances Ice floats in liquid water • Water expands as it freezes because the polar molecules arrange themselves in a crystal structure held together by hydrogen bonds • Water molecules are less dense in solid form than in liquid which is why the solid form of water (ice) floats • Molecules of substances without hydrogen bonding pack more tightly as they freeze, causing the frozen form to sink. Water has a high heat capacity • It requires a great deal of energy to increase the temperature of water. • When the temperatures of a substance increases, it means that the average speed of the particles in the substance increases • To increase the speed of the particles, the attractive forces between the water molecules must be overcome • Breaking the hydrogen bonds between water molecules requires a lot of energy (heat) • On the other hand, when water cools, a great deal of energy is released. • The cooling properties of water are apparent during perspiration (sweating)
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