Great Western Four+ Doctoral Training Partnership (GW4+ DTP) Fate of coloured dissolved organic matter in the ocean PML Supervisors: Drs Gavin Tilstone ([email protected]), Vas Kitidis ([email protected]) and Jo Dixon ([email protected]) University Supervisor: Prof. Richard Evershed (University of Bristol) Background: The global ocean reservoir of dissolved organic matter (DOM) contains approximately 685 x 1015 g C, which is equivalent to the atmospheric carbon pool and represents the second largest pool of carbon in the world. Understanding the bio-availability and transformation of DOM is essential to our knowledge of the effects of climate change on ocean carbon. The coloured component of DOM (CDOM) is a complex mixture of organic molecules some of which are a substrate for microbial growth. Sunlight-induced reactions leading to CDOM breakdown (photobleaching), can release organic nutrients which can enhance microbial growth and climate-active-gases such as carbon dioxide (CO2) and carbon monoxide (CO). Considerable uncertainty remains over the composition of CDOM in the global ocean and which of these components are used by bacteria and which are released as gases. Fluorescence Excitation Emission spectroscopy coupled with Parallel Factorial (PARAFAC) is a powerful technique for studying the composition of the CDOM in the ocean. It p rovides a chemical fingerprint of active fluorescent humic and proteinaceous fractions and combined with the measurement of optical properties of CDOM, can be used to trace the fate and environmental significance of DOM in carbon cycle. The successful PhD student will undertake a unique programme of research by developing and exploiting these techniques on research cruises that cross the Atlantic Ocean from the UK to the Falkland Islands on the Atlantic Meridional Transect (AMT; http://www.amt-uk.org/) which is co-ordinated by PML. The cross-disciplinary nature of this research means that the student will develop expertise in: • • • • • Sea going oceanography Chemical and optical analytical techniques Open ocean biogeochemistry Impact of organic carbon on climate relevant gases Numerical and statistical data analysis They will work in a world class research institutes where they will make use of state-of-the-art field, laboratory, computing and instrumentation facilities available across both institutions and have opportunities to present their work at international conferences. The student should have obtained at least a 2i BSc in environmental, biological, chemical or marine sciences or related field and who can work independently and collaboratively at sea. Patron: James Cameron
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