Agenda Jan 19th, 2017 Polyatomic Ions - Pogil, to correct Naming Acids - Special group of compounds 10 Polyatomic Ions Quiz - Preparation Sheet Polyatomic Ions Starting at Model 2 - Common Polyatomic Ions 11. What is the only polyatomic ion that is a cation? 11. What is the only polyatomic ion that is a cation? Ammonium NH4 + 12. How are bicarbonate and carbonate 12related? HCO3 CO3 12. How are bicarbonate and carbonate 12related? HCO3 CO3 Bicarbonate has the same basic formula as carbonate, but with an added hydrogen ion (H+). The charge on the ion has decreased from -2 to -1. 13. Predict the chemical formula and charge for the bisulfate ion Bisulfate sulfate 2- ? SO4 HCO31- CO32- Bicarbonate carbonate 13. Predict the chemical formula and charge for the bisulfate ion Bisulfate HSO4 1- sulfate SO4 2- 14. How are chromate and dichromate related? 14. How are chromate and dichromate related? Both ions have chromium and oxygen atoms, but dichromate has two chromium atoms and more oxygen atoms that chromate. Both have -2 charge. 15. Bromine forms polyatomic ions with structures similar to those of chlorine. Using the chlorine family of polyatomic ions as a model, predict name of BrO4 ion. Which ions in the table are they? 15. Bromine forms polyatomic ions with structures similar to those of chlorine. Using the chlorine family of polyatomic ions as a model, predict name of BrO4ion. Perchlorate, chlorate, chlorite and hypochlorite - which is similar to one above? 15. Bromine forms polyatomic ions with structures similar to those of chlorine. Using the chlorine family of polyatomic ions as a model, predict name of BrO4ion. perchlorate ClO4- vs. BrO4- 15. Bromine forms polyatomic ions with structures similar to those of chlorine. Using the chlorine family of polyatomic ions as a model, predict name of BrO4ion. perchlorate ClO4- perbromate BrO4- 16. Identify the polyatomic ion in each of these ionic compounds. Write out the name and formula of the ions, including charges. a) CaCO3 16. Identify the polyatomic ion in each of these ionic compounds. Write out the name and formula of the ions, including charges. a) CaCO3 carbonate CO32- 16. Identify the polyatomic ion in each of these ionic compounds. Write out the name and formula of the ions, including charges. b) Mg(OH)2 16. Identify the polyatomic ion in each of these ionic compounds. Write out the name and formula of the ions, including charges. b) Mg(OH)2 hydroxide OH1- 16. Identify the polyatomic ion in each of these ionic compounds. Write out the name and formula of the ions, including charges. b) NH4Cl 16. Identify the polyatomic ion in each of these ionic compounds. Write out the name and formula of the ions, including charges. b) NH4Cl ammonium NH41+ Model 3. Ternary Ionic Compounds 17. How are ternary ionic compounds in Model 3 different from binary ionic compounds that you’ve seen previously? Model 3. Ternary Ionic Compounds 17. How are ternary ionic compounds in Model 3 different from binary ionic compounds that you’ve seen previously? Ternary ionic compounds have three or more elements involved, binary compounds only two. Model 3. Ternary Ionic Compounds 18. Consider the compound iron(III) hydroxide in Model 3. Fe(OH)3 a) How many hydroxide ions (OH-) are 3+ combined with an iron(III) ion (Fe )? Model 3. Ternary Ionic Compounds 18. Consider the compound iron(III) hydroxide in Model 3. Fe(OH)3 a) How many hydroxide ions (OH-) are 3+ combined with an iron(III) ion (Fe )? Three hydroxide ions Model 3. Ternary Ionic Compounds 18. Consider the compound iron(III) hydroxide in Model 3. Fe(OH)3 a) Remember the roman numerals us the How manytellhydroxide ions (OH-) are charge on the metal cation 3+ combined withthean ion (Fe )? Iron(III) means ion iron(III) in the compound is Fe3+ Three hydroxide ions Model 3. Ternary Ionic Compounds b) Is your answer to part a the only combination of iron(III) ions and hydroxide ions (OH-) that should exist in nature? Model 3. Ternary Ionic Compounds b) Is your answer to part a the only combination of iron(III) ions and hydroxide ions (OH-) that should exist in nature? Yes, there is only one ratio that will result in a neutral compound. Model 3. Ternary Ionic Compounds 19. Consider the compound barium nitrate in Model 3. a) What does the subscripted “2” inside the parentheses of the chemical formula tell you about the compound? Ba(NO2)2 Model 3. Ternary Ionic Compounds a) What does the subscripted “2” inside the parentheses of the chemical formula tell you about the compound? Ba(NO2)2 Two oxygen atoms are bonded to a nitrogen atom in the polyatomic nitrite ion. Model 3. Ternary Ionic Compounds b) What does the subscripted “2” outside the parentheses of the chemical formula tell you about the compound? Ba(NO2)2 Model 3. Ternary Ionic Compounds b) What does the subscripted “2” outside the parentheses of the chemical formula tell you about the compound? Ba(NO2)2A ratio of two polyatomic nitrite ions to one barium ion are needed to make a neutral compound. Model 3. Ternary Ionic Compounds 20. How many atoms of each element are in one formula unit of ammonium phosphate? (NH4)3PO4 Model 3. Ternary Ionic Compounds 20. How many atoms of each element are in one formula unit of ammonium phosphate? (NH4)3PO4 3Nitrogen 3x4= 12Hydrgen 1Phosphorus 4Oxygen Model 3. Ternary Ionic Compounds 21. A student writes the chemical formula for the ionic compound calcium hydroxide as CaOH2 (incorrectly) 2+ a) Calcium ion is Ca Hydroxide ion is OH b) Why is the student’s formula wrong? - Model 3. Ternary Ionic Compounds 21. A student writes the chemical formula for the ionic compound calcium hydroxide as CaOH2 Corrected = Ca(OH)2 2+ a) Calcium ion is Ca Hydroxide ion is OH b) We need to show a ratio of 1:2 positive ions to negative ions. Need to use parentheses around the hydroxide ion. - 22. Rule for appropriate use of parentheses in ternary ionic compounds? 22. Rule for appropriate use of parentheses in ternary ionic compounds? Parentheses are used around any polyatomic ion used more than once in a formula unit. 22. Reasons the rest of the statements are not correct. Parentheses are used around any ion used more than once in a formula unit. False - see Al2(CO3)3 Monatomic ions do not have parentheses around them. 22. Reasons the rest of the statements are not correct. Parentheses are used around any polyatomic ion. False - see KNO3 Parentheses are not used if the polyatomic ion is being used only once. 22. Reasons the rest of the statements are not correct. Parentheses are only used around polyatomic anions used more than once in a formula. False - see (NH4)3PO4 Parentheses are also used if a polyatomic cation is used more than once. 23. Write chemical formulas for the following ternary ionic compounds. Be ready to explain how to put the formulas together. a) b) c) d) e) f) Calcium sulfate Copper(II) nitrate Lithium phosphate Potassium permanganate Aluminum sulfite Magnesium bicarbonate 23. Write chemical formulas for the following ternary ionic compounds. Be ready to explain how to put the formulas together. a) b) c) d) e) f) Calcium sulfate CaSO4 Copper(II) nitrate Cu(NO3)2 Lithium phosphate Li3PO4 Potassium permanganate KMnO4 Aluminum sulfite Al2(SO3)3 Magnesium bicarbonate Mg(HCO3)2 24. Name the following ternary ionic compounds. a) b) c) d) e) f) BaSO4 NH4NO3 K2Cr2O7 Fe(NO3)3 Mg(CH3COO)2 Al2(CO3)3 24. Name the following ternary ionic compounds. a) b) c) d) e) f) BaSO4 barium sulfate NH4NO3 ammonium nitrate K2Cr2O7 potassium dichromate Fe(NO3)3 iron(III) nitrate Mg(CH3COO)2 Magnesium acetate Al2(CO3)3 aluminum carbonate NAMING ACIDS - Unique group of chemicals 2 sided worksheet (Pogil) Naming Ionic Compounds Single sided worksheet, Study Guide for Content Mastery, Chemistry Matter and Change, Chapter 8 Both to be turned in at the end of the period. Stay in seats. 10 Polyatomic Ions to Memorize Chromate CrO42- dichromate Cr2O72- carbonate CO32- sulfate SO42- nitrate NO3- phosphate PO43- cyanide CN- ammonium NH4+ hydroxide OHpermanganate MnO4- 5 Acids to Memorize (write on back of Common Ions sheet) Hydrochloric acid HCl(aq) Nitric acid HNO3(aq) Sulfuric acid H2SO4(aq) Carbonic acid H2CO3(aq) Phosphoric acid H3PO4(aq) Homework 1) Complete Naming Acids and Naming Ionic compounds sheet if necessary. 2) Prepare for 10 Polyatomic ions + 5 Common Acids quiz Quiz on Monday. Ideas for studying: 3) a) Make flashcards or a quizlet b) 8 Common polyatomic ions quiz c) Many polyatomic ions quiz - challenge
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