Review – CHEMISTRY Unit Answer Key Periodic Table, Ionic & Molecular Compound 1. Draw a Bohr-Rutherford diagram for sodium: Show nucleus with 11 protons, 1st orbit with 2 electrons, 2nd orbit with 8 electrons and 3rd orbit with 1 electrons. 2. For the following elements, once they gain/lose electrons, identify the ionic charge, whether it’s cation or anion and the ion’s name: Ca: Ca2+ , cation, calcium ion S: S2- , anion, sulfide ion Li: Li1+, cation, lithium ion K: K1+ , cation, potassium ion Cl: Cl1- , anion, chloride ion 3. Identify the product when the following elements combined: Ions formed Formula Name Calcium & oxygen Ca2+ and O2- CaO calcium oxide Potassium & oxygen K1+ and O2- K2O potassium oxide Sodium & fluorine Na1+ and F1- NaF sodium fluoride Aluminum & nitrogen Al3+ and N3- AlN aluminum nitride 4. Complete the missing formula or compound name: Also identify as ionic or molecular compound Formula: PbCl2 Compound name: Lead (II) chloride Compound: Ionic Formula: Fe(NO3)3 Compound name: Iron (III) nitrate Compound: Ionic PCl3 Phosphorus trichloride Molecular P2O5 Molecular FeBr3 Iron (III) bromide Ionic NH4OH Diphosphorus pentaoxide Ammonium hydroxide MnO2 Manganese (IV) oxide Ionic PbO2 Lead (IV) oxide Ionic CuCl2 Copper (II) chloride Ionic PCl5 Molecular NaOH Sodium hydroxide Ionic CuSO4 Phosphorus pentachloride Copper (II) sulfate FeO Iron (II) oxide Ionic SO2 Sulfur dioxide Molecular Fe2(SO4)3 Iron (III) sulfate Ionic H2SO4 Sulfuric acid Molecular SF4 Sulfur tetrafluoride Molecular CuBr Copper (I) bromide Ionic Na2S Sodium sulfide Ionic AgNO2 Silver nitrite Ionic Ionic Ionic Na2SO4 Sodium sulfate Ionic Al(HCO3)3 Aluminum bicarbonate Ionic SnS Tin (II) sulfide Ionic NI3 Nitrogen triiodide Molecular MnO2 Manganese (IV) oxide Ionic Al2S3 Aluminum sulfide Ionic (NH4)2SO4 Ammonium sulfate Ionic N2O4 Dinitrogen tetroxide Molecular Acids Formula: H2S Compound name: Hydrosulfuric acid Base Formula: Ca(OH)2 Compound name: Calcium hydroxide HBr Hydrobromic acid NaHCO3 Sodium bicarbonate H2SO4 Sulfuric acid NH4OH Ammonium hydroxide H2CO3 Carbonic acid Al(OH)3 Aluminum hydroxide HNO3 Nitric acid Mg(OH)3 Magnesium hydroxide 5. State characteristics of acids vs. base (See p. 271 of textbook) Acids are molecular compounds that react with metals. In solutions, acids react with metals, conduct electricity and change blue litmus paper to red colour. Bases are ionic compounds, many are hydroxides. In aqueous solutions they conduct electricity and change red litmus paper to blue colour. Types of reactions & Balancing 1. Identify these types of reaction: AB + C A + CB Single displacement A + B AB Synthesis AB A + B Decomposition AB + CD AD + CB Double displacement 2. For each identify the name of the reactants, the type of reactions, formula and name of products formed and balance the equation: Fe + CuSO4 iron + copper (II) sulfate (Single displacement) FeSO4 + Cu iron (II) sulfate + copper 2 KI + Pb(NO3)2 potassium iodide + lead (II) nitrate (Double displacement) 2 KNO3 + PbI2 potassium nitrate + lead (II) iodide C4H10 + O2 CO2 + H2O (Note: No need to name C4H10 – it’s butane for those that are curious) Butane + oxygen Carbon dioxide + water (Combustion) KClO3 potassium chlorate (Decomposition) KCl + O2 potassium chloride + oxygen Pb(NO3)2 + KI (oops…duplicate question – see above) HCl + NaOH NaCl + H2O hydrochloric acid + sodium hydroxide sodium chloride + water (Acid-base neutralization) CaO + 2 HNO3 Ca(NO3)2 + H2O calcium oxide + nitric acid calcium nitrate + water (Acid-base neutralization – note: CaO is a base) Na2CO3 + Mg(NO3)2 2 NaNO3 + MgCO3 sodium carbonate + magnesium nitrate sodium nitrate + magnesium carbonate (Double displacement) copper (II) chloride is added to magnesium bicarbonate copper (II) bicarbonate + magnesium chloride CuCl2 + Mg(HCO3)2 Cu(HCO3)2 + MgCl2 (Double displacement) lead (II) nitrate is added to potassium iodide (duplicate question… I really like this question obviously!) 3 KOH + H3PO4 K3PO4 + 3 H2O potassium hydroxide + phosphoric acid potassium phosphate + water (Acid-base neutralization) CaCl2 + F2 Calcium chloride + Fluorine (Single displacement) CaF2 + Cl2 calcium fluoride + chlorine calcium hydroxide +phosphoric acid calcium phosphate + water 3 Ca(OH)2 + 2 H3PO4 Ca3(PO4)2 + H2O (Acid-base neutralization) sodium phosphate is added to calcium nitrate sodium nitrate + calcium phosphate 2 Na3PO4 + 3 Ca(NO3)2 6 NaNO3 + Ca3(PO4)2 (Double displacement) silver nitrate is added to sodium hydroxide AgNO3 + NaOH (Double displacement) sodium nitrate + silver hydroxide NaNO3 + AgOH ammonium hydroxide is added to sulfuric acid ammonium sulfate + water 2 NH4OH + H2SO4 (NH4)2SO4 + 2 H2O (Acid-base neutralization) 2 Cu + O2 2 CuO copper + oxygen copper (II) oxide (Combustion) 3 Cu(OH)2 + 2 H3PO4 Cu3(PO4)2 + 6 H2O copper (II) hydroxide + phosphoric acid copper (II) phosphate + water (Acid-base neutralization) Fe(NO3)3 + 3 AgCl FeCl3 + 3 AgNO3 Iron (III) nitrate + silver chloride Iron (III) chloride + silver nitrate (Double displacement) KClO3 KCl + O2 potassium chlorate potassium chloride + oxygen (Decomposition) 2. A small jug containing phosphoric acid was spilled in the lab room. You needed to clean up the mess quickly and checked the chemistry storage unit where you saw three other jugs available: Sodium chloride (aq) Potassium hydroxide (aq) Hydrosulfuric acid (aq) Which solution can you use to clean up your spill? Potassium hydroxide Why did you pick this solution? Because potassium hydroxide is a base. (Remember that base will neutralize acid, producing salt & water as the products.) Write the balanced chemical equation showing both reactants and products of this reaction. Phosphoric acid + potassium hydroxide potassium phosphate + water H3PO4 + 3 KOH K3PO4 + 3 H2O
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