Chapter 16 Review WS 11-12 1. What value does Kw have at 25ºC? 1.0 x 10-14 2. What are [H+] and [OH-] in pure water at 25º? 1.0 x 10-7 3. How does [H+] compare to [OH-] in an acidic solution? [H+] > [OH-] 4. How does [H+] compare to [OH-] in a basic solution? [H+] < [OH-] 5. What range of pH values corresponds to acidic solutions? pH < 7 6. What range of pH values corresponds to basic solutions? pH > 7 7. Identify each as an acid or a base: a) H2SO4 acid b) HCl acid c) HNO3 acid d) NaOH base e) H3PO4 acid f) Mg(OH)2 base 8. Classify each solution as neutral, acidic, or basic. a) [H+] = 1 x 10-5 acidic b) [H+] = 1 x 10-7 neutral c) [OH-] = 1 x 10-5 basic 9. A solution has a pH of 3. What is the [H+] concentration? 0.001 M 10. A solution has a [H+] concentration of 1.0 x 10-5. What is the pH? 5.00 11. A solution has a [OH-] concentration of 2.7 x 10-5. What is the pH? 9.43 12. Fill in the blanks. In the reaction of an acid with a base, hydrogen ions and _hydroxide_ ions react to produce _water_ and a salt. This reaction is called _neutralization_. 13. Write the formula for these acids: hydrochloric acid HCl acids_bases_review.doc sulfuric acid H2SO4 phosphoric acid H3PO4 acetic acid HC2H3O2 nitric acid HNO3 Write the equation for the neutralization reactions. 14. Write the equation for the dissociation (breaking up into ions!) of the following acids and bases. a) HCl H+ + Clb) H3PO4 3 H+ + PO43c) NaOH Na+ + OHd) NH4OH NH4+ + OH- 15. 3 HCl + Al(OH)3 AlCl3 + 3 H2O 16. H2SO4 + 2 NaOH Na2SO4 + 2 H2O 17. How many moles of sulfuric acid are needed to react with 3.5 moles of sodium hydroxide? H2SO4 + 2 NaOH Na2SO4 + 2 H2O 3.5 mol NaOH 1 mol H2SO4 = 1.8 mol H2SO4 1 2 mol NaOH 18. How many liters of 0.75 M sodium hydroxide are needed to react with 2.7 L of 0.55 M hydrochloric acid? HCl + NaOH NaCl + H2O 2.7 L HCl 0.55 mol HCl 1 mol NaOH 1 L NaOH = 2.0 L NaOH 1 1 L HCl 1 mol HCl 0.75 mol NaOH 19. How many milliliters of 0.35 M phosphoric acid will completely neutralize 450.0 mL of 0.50 M calcium hydroxide? 2 H3PO4 + 3 Ca(OH)2 Ca3(PO4)2 + 6 H2O 1 L H3PO4 450.0 mL Ca(OH)2 0.50 mol Ca(OH)2 2 mol H3PO4 1L 1000 mL × × × × × = 428.6 mL H3PO 4 1 1000 mL 1 L Ca(OH)2 3 mol Ca(OH)2 0.35 mol H3PO4 1L acids_bases_review.doc
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