City: PICKENS SANGAMO WESTON, INC./TWELVE-MILE CREEK/LAKE HARTWELL PCB CONTAMINATION Site Information: Address: SANGAMO WESTON, INC./TWELVE-MILE CREEK/LAKE HARTWELL PCB CONTAMINATION PICKENS, SC EPA ID: EPA Region: SCD003354412 04 Site Name: Site Alias Name(s): SANGAMO/TWELVE-MILE/HARTWELL PCB SANGAMO WESTON-PICKENS PLANT HAYWOOD RESERVOIR MIDWAY LANDFILL CROSS ROADS CHURCH BREZEAL PROPERTY WELLBORN PROPERTY MAW BRIDGE ROAD NIX, ERNEST PROPERTY SANGAMO ELECTRIC SANGAMO PROPERTY SANGAMO WESTON/TWELVE-MILE/HARTWELL PCB Record of Decision (ROD): ROD Date: Operable Unit: ROD ID: 12/19/1990 01 EPA/ROD/R04-91/100 Media: SOIL SLUDGE DEBRIS GROUND WATER Contaminant: VOCS, PCE, TCE, OTHER ORGANICS, PCBS Abstract: THE 253-ACRE SANGAMO/TWELVE-MILE/HARTWELL PCB SITE CONSISTS OF SEVEN SEPARATE DISPOSAL AREAS IN PICKENS COUNTY, SOUTH CAROLINA. THESE AREAS CONSIST OF THE SANGAMO PLANT AREA AND SIX PRIVATE DISPOSAL AREAS LOCATED OFFSITE OF THE SANGAMO PLANT, WHICH ARE DESIGNATED AS THE BREAZEALE, NIX, DODGENS, CROSS ROADS, JOHN TROTTER, AND WELBORN AREAS. LAND IN THE GENERAL AREA IS PREDOMINANTLY FORESTED, AND THERE ARE SEVERAL NEARBY LAKES AND STREAMS INCLUDING LAKE HARTWELL AND THE TWELVE-MILE CREEK BASIN. SINCE 1955, SANGAMO WESTON, INC., HAS MANUFACTURED ELECTROLYTIC, MICA, AND POWER FACTOR CAPACITORS. PCBS WERE USED AS DIELECTRIC FLUID IN POWER FACTOR CAPACITORS. PRIOR TO 1972, WASTE MATERIALS CONTAINING PCBS WERE LANDFILLED IN THE SEVEN DISPOSAL AREAS. THESE PCB-CONTAMINATED MATERIALS INCLUDED SCRAP CAPACITORS AND ALUMINUM HYDROXIDE SLUDGE FROM AN ONSITE WASTEWATER TREATMENT PLANT. IN THE MID-1970'S, STATE AND FEDERAL ENVIRONMENTAL MONITORING PROGRAMS LED TO THE DETECTION OF PCBS IN THE SEDIMENT OF LAKE HARTWELL, IN ITS TRIBUTARIES, AND IN THE SOIL OF SANGAMO WESTON'S DUMP SITES. IN ADDITION, PCBS WERE DETECTED IN FISH SAMPLES AT TWO SITES IN THE TWELVE-MILE CREEK AREA OF LAKE HARTWELL. IN 1980, SANGAMO WESTON, INC., REMOVED A TOTAL OF 17,711 CUBIC YARDS OF PCB-CONTAMINATED SOIL AND DEBRIS FROM THE NIX AND DODGENS AREAS, AND DISPOSED OF IT IN A LANDFILL ON THE SANGAMO PLANT PROPERTY. IN 1986, A GEOTEXTILE LINER AND SOIL CAP WERE INSTALLED AS AN INTERIM MEASURE TO RETARD THE MIGRATION OF PCB CONTAMINATION FROM THE BREAZEALE SITE. IN 1989, EPA REMOVED OFFSITE 7,285 TONS OF PCB-CONTAMINATED SOIL AND DEBRIS FROM THE SANGAMO PLANT AREA TO A RCRA LANDFILL, AND 6,684 CAPACITORS WERE TAKEN TO AN OFFSITE INCINERATOR. THIS RECORD OF DECISION (ROD) ADDRESSES THE FIRST OF TWO OPERABLE UNITS, AND PROVIDES FOR REMEDIATION OF THE GROUND WATER AND SOURCE CONTAMINATION AT THE SEVEN DISPOSAL AREAS. A FUTURE ROD WILL ADDRESS THE CONTAMINATION OF THE TWELVE-MILE CREEK BASIN AND LAKE HARTWELL. THE PRIMARY CONTAMINANTS OF CONCERN AFFECTING THE SOIL, SLUDGE, DEBRIS, AND GROUND WATER ARE VOCS INCLUDING PCE AND TCE; AND OTHER ORGANICS INCLUDING PCBS. THE SELECTED REMEDIAL ACTION FOR THIS SITE INCLUDES EXCAVATING MATERIALS CONTAMINATED WITH GREATER THAN 1 MG/KG OF PCBS AT THE NIX AND WELBORN AREAS; EXCAVATING MATERIALS CONTAMINATED WITH GREATER THAN 25 MG/KG OF PCBS AT THE SANGAMO PLANT AREA; EXCAVATING MATERIALS CONTAMINATED WITH GREATER THAN 10 MG/KG OF PCBS AT THE BREAZEALE, DODGENS, CROSS ROADS, AND JOHN TROTTER AREAS; TRANSPORTING THE EXCAVATED MATERIALS TO THE SANGAMO PLANT AREA FOR STAGING AND TREATMENT; TREATING ONSITE ALL EXCAVATED MATERIALS USING THERMAL DESORPTION TECHNOLOGY AND CARBON ADSORPTION TO CONTROL OFF-GASES; PLACING THE TREATED SOIL WITHIN THE PLANT AREA; FILLING EACH OF THE PRIVATE AREAS WITH 2 FEET OF CLEAN FILL WHERE CONTAMINATED MATERIALS WITH PCBS GREATER THAN 1 MG/KG REMAIN, SPECIFICALLY THE TROTTER, DODGENS, BREAZEALE, AND CROSS ROADS AREAS; GROUND WATER PUMPING AND ONSITE TREATMENT AT THE DODGENS, BREAZEALE, CROSS ROADS, AND SANGAMO PLANT AREAS USING AIR STRIPPING AND/OR CARBON ADSORPTION; AND DISCHARGING TREATED WATER ONSITE TO SURFACE WATER. THE ESTIMATED PRESENT WORTH COST FOR THIS REMEDIAL ACTION RANGES FROM $47,900,000 TO $63,300,000 DEPENDING ON AQUIFER CHARACTERISTICS AND THE VOLUME OF EXCAVATED SOLIDS. NO O&M COSTS WERE PROVIDED FOR THIS REMEDIAL ACTION. PERFORMANCE STANDARDS OR GOALS; CHEMICAL-SPECIFIC GROUND WATER CLEAN-UP GOALS ARE BASED ON SDWA MCLS AND INCLUDE PCBS 0.0005 MG/L (PROPOSED MCL), PCE 0.005 MG/L (MCL), AND TCE 0.005 MG/L (MCL). CHEMICAL-SPECIFIC CLEAN-UP GOALS FOR SOIL, SLUDGE, AND DEBRIS INCLUDE TREATMENT TO A LEVEL OF PCB 2 MG/KG. SOIL WITH GREATER THAN PCB 1 MG/KG REMAINING AT THE VARIOUS AREAS WILL BE COVERED WITH 2 FEET OF CLEAN FILL. Remedy: THIS OPERABLE UNIT IS THE FIRST OF TWO THAT ARE PLANNED FOR THE SITE. THE FIRST OPERABLE UNIT ADDRESSES THE SANGAMO PLANT SITE AND SIX OTHER DISPOSAL AREAS BY TREATING BOTH SOURCE AND GROUNDWATER CONTAMINATION. THE MAJOR COMPONENTS OF THE SELECTED REMEDY INCLUDE; * EXTRACTION AND TREATMENT BY AIR STRIPPING AND/OR CARBON ADSORPTION OF CONTAMINATED GROUNDWATER AT THE DODGENS, BREAZEALE, CROSS ROADS AND PLANT SITES; * DISCHARGE OF TREATED WATER TO THE NEAREST VIABLE SURFACE WATER BODY IN ACCORDANCE WITH APPLICABLE REGULATIONS; * EXCAVATION OF MATERIALS CONTAMINATED WITH GREATER THAN 1 PPM OF PCBS AT THE NIX AND WELBORN PROPERTIES AND TRANSPORT OF THE MATERIALS TO THE SANGAMO PLANT SITE FOR STAGING AND APPROPRIATE TREATMENT EXCAVATION OF MATERIALS CONTAMINATED WITH GREATER THAN 10 PPM PCBS ON THE REMAINING FOUR PRIVATE PROPERTIES (TROTTER, DODGENS, BREAZEALE AND CROSS ROADS) AND TRANSPORT TO THE SANGAMO PLANT SITE FOR STAGING AND APPROPRIATE TREATMENT; * BACKFILL TWO FEET OF CLEAN FILL AT EACH OF THE PRIVATE PROPERTIES WHERE CONTAMINATED MATERIALS OF GREATER THAN 1 PPM REMAIN (TROTTER, DODGENS, BREAZEALE AND CROSS ROADS); * EXCAVATE MATERIAL CONTAINING GREATER THAN 25 PPM CONCENTRATION OF PCBS ON THE PLANT SITE; * TREAT ALL EXCAVATED MATERIALS TO 2 PPM PCBS USING THERMAL SEPARATION TECHNOLOGY ON THE PLANT SITE. DURING REMEDIAL DESIGN, A TREATABILITY STUDY WILL BE CONDUCTED TO DETERMINE IF ANY OF THE CONTAMINATED MATERIALS WILL REQUIRE ADDITIONAL TREATMENT BEYOND THERMAL SEPARATION IN ORDER TO MEET THE 2 PPM CRITERIA. IF NECESSARY, A ROD AMENDMENT WILL BE COMPLETED TO ACCOUNT FOR THIS REQUIRED TREATMENT; AND * REPLACE REMEDIATED SOIL ON THE PLANT SITE. Text: Full-text ROD document follows on next page. EPA/ROD/R04-91/100 1991 EPA Superfund Record of Decision: SANGAMO WESTON, INC./TWELVE-MILE CREEK/LAKE HARTWELL PCB CONTAMINATION EPA ID: SCD003354412 OU 01 PICKENS, SC 12/19/1990 Text: This ROD has associated ESDs. SITE NAME AND LOCATION SANGAMO WESTON/TWELVE-MILE CREEK/LAKE HARTWELL PCB CONTAMINATION SITE OPERABLE UNIT ONE PICKENS, PICKENS COUNTY, SOUTH CAROLINA #SBP STATEMENT OF BASIS AND PURPOSE THIS DECISION DOCUMENT PRESENTS THE SELECTED REMEDIAL ACTION FOR OPERABLE UNIT ONE OF THE SANGAMO WESTON/TWELVE-MILE CREEK/LAKE HARTWELL PCB CONTAMINATION SITE IN PICKENS, SOUTH CAROLINA, CHOSEN IN ACCORDANCE WITH CERCLA, AS AMENDED BY SARA AND, TO THE EXTENT PRACTICABLE, THE NATIONAL CONTINGENCY PLAN. THIS DECISION IS BASED ON THE ADMINISTRATIVE RECORD FILE FOR THIS SITE. THE STATE OF SOUTH CAROLINA CONCURS WITH THE SELECTED REMEDY. ASSESSMENT OF THE SITE ACTUAL OR THREATENED RELEASES OF HAZARDOUS SUBSTANCES FROM THIS SITE, IF NOT ADDRESSED BY IMPLEMENTING THE RESPONSE ACTION SELECTED IN THIS ROD, MAY PRESENT AN IMMINENT AND SUBSTANTIAL ENDANGERMENT TO PUBLIC HEALTH, WELFARE, OR THE ENVIRONMENT. STATUTORY DETERMINATIONS 1 Order number 940620-103843-ROD -001-001 page 4242 set 4 with 100 of 100 items THE SELECTED REMEDY IS PROTECTIVE OF HUMAN HEALTH AND THE ENVIRONMENT, COMPLIES WITH FEDERAL AND STATE REQUIREMENTS THAT ARE LEGALLY APPLICABLE OR RELEVANT AND APPROPRIATE TO THE REMEDIAL ACTION, AND IS COST-EFFECTIVE. THIS REMEDY UTILIZES PERMANENT SOLUTIONS AND ALTERNATIVE TREATMENT (OR RESOURCE RECOVERY) TECHNOLOGIES TO THE MAXIMUM EXTENT PRACTICABLE AND SATISFIES THE STATUTORY PREFERENCE FOR REMEDIES THAT EMPLOY TREATMENT THAT REDUCES TOXICITY, MOBILITY, OR VOLUME AS A PRINCIPAL ELEMENT. BECAUSE THIS REMEDY WILL NOT RESULT IN HAZARDOUS SUBSTANCES REMAINING ON-SITE ABOVE HEALTH-BASED LEVELS, THO FIVE-YEAR REVIEW WILL NOT APPLY TO THE SOURCE REMEDIAL ACTION. GREER C. TIDWELL REGIONAL ADMINISTRATOR DATE: DECEMBER 19, 1990 SANGAMO WESTON/TWELVE-MILE CREEK/ LAKE HARTWELL PCB CONTAMINATION SITE PICKENS, PICKENS COUNTY, SOUTH CAROLINA #INT INTRODUCTION THE SANGAMO WESTON/TWELVE-MILE CREEK/LAKE HARTWELL PCB CONTAMINATION SITE (SANGAMO WESTON) WAS PROPOSED FOR INCLUSION ON THE NATIONAL PRIORITIES LIST (NPL) IN JANUARY 1987 AND WAS FINALIZED IN FEBRUARY 1990. THE SITE RANKS 553 OUT OF 1218 NPL SITES. #SNL 1.0 SITE NAME AND LOCATION THE SANGAMO WESTON SITE IS LOCATED IN PICKENS COUNTY, SOUTH CAROLINA (FIGURE 1). THE ROD ADDRESSES SEVEN (7) SEPARATE DISPOSAL AREAS. FIVE PRIVATE PROPERTIES AND THE SANGAMO PLANT SITE DISPOSAL AREAS WERE REPORTED TO EPA BY SANGAMO IN THEIR 103(C) NOTIFICATION TO THE AGENCY. THE PRIVATE PROPERTIES ARE; CROSS ROADS SITE, BREAZEALE SITE, DODGENS SITE, WELBORN SITE, AND THE NIX SITE. THE JOHN TROTTER SITE, ALSO ADDRESSED IN THIS RECORD OF DECISION, WAS DISCOVERED BY EPA DURING SUBSEQUENT SAMPLING INVESTIGATIONS. ALL SITES ARE SITUATED IN THE PIEDMONT PHYSIOGRAPHIC PROVINCE OF SOUTH CAROLINA. THE PIEDMONT PROVINCE IS A BROAD PLATEAU RANGING IN ELEVATION FROM 400 TO 1200 FEET ABOVE MEAN SEA LEVEL. THE GEOLOGY OF THE AREA CONSISTS OF GNEISSES AND SCHISTS, INTRUDED BY IGNEOUS ROCKS, E.G., GRANITES. THE BEDROCK IS OVERLAIN BY A LAYER OF SAPROLITE AND SLOPE WASH DEPOSITS, AND ALLUVIAL FILL MATERIAL OF VARIABLE THICKNESS (OVERSTREET, 1965). 1 Order number 940620-103843-ROD -001-001 page 4243 set 4 with 100 of 100 items THE PLATEAU REGION IS DISSECTED BY STREAMS WHICH HAVE DEVELOPED A DENDRITIC DRAINAGE PATTERN. THIS DRAINAGE PATTERN IS CHARACTERIZED BY IRREGULAR BRANCHING OF STREAMS DEVELOPED UPON MATERIALS WITH A UNIFORM RESISTANCE TO EROSION. STREAM FLOW IN THE PROVINCE IS TO THE SOUTHEAST. MAJOR STREAMS IN THE PROVINCE HAVE DEVELOPED IN VALLEY BOTTOMS UPON A SAPROLITE OR SLOPE WASH DEPOSIT BASE. TRIBUTARIES FLOW FROM RIDGE AREAS IN AN IRREGULAR PATTERN TO-THESE MAJOR STREAMS. GROUNDWATER IN THE PIEDMONT PROVINCE OCCURS PRINCIPALLY UNDER UNCONFINED CONDITIONS IN SAPROLITE AND SLOPE WASH DEPOSITS. GROUNDWATER IS THE RESULT OF DIRECT INFILTRATION OF PRECIPITATION, WITH PRINCIPAL RECHARGE AREAS IN TOPOGRAPHICALLY HIGH AREAS (RIDGE TOPS) AND DISCHARGE AREAS NEAR STREAMS IN VALLEY BOTTOMS. THE GROUNDWATER FLOW REGIME IN THE PIEDMONT PROVINCE IS CONTROLLED BY THE DEGREE OF RIDGE AND VALLEY DEVELOPMENT ON THE PLATEAU AREA. GROUNDWATER IN CRYSTALLINE ROCK IS GENERALLY RESTRICTED TO THE UPPER ZONE OF THE BEDROCK WHERE FRACTURES AND JOINTS MOST COMMONLY OCCUR. GROUNDWATER OCCURRENCE IN CRYSTALLINE ROCKS DECREASES WITH INCREASING DEPTH BECAUSE JOINTS AND FRACTURES REDUCE IN SIZE AND NUMBER. NEITHER THE SAPROLITE NOR THE ROCK ARE EXTENSIVELY USED AS WATER SUPPLIES. MOST RESIDENCES AND INDUSTRIAL OR COMMERCIAL ENTERPRISES WITHIN THE PIEDMONT, INCLUDING PICKENS COUNTY, OBTAIN DRINKING WATER FROM SURFACE WATER SOURCES. 1.1 THE SANGAMO WESTON SITE THE SANGAMO WESTON SITE IS APPROXIMATELY 220 ACRES IN SIZE AND IS LOCATED APPROXIMATELY ONE MILE NORTHWEST OF THE TOWN OF PICKENS (FIGURE 2). BASED ON THE PRELIMINARY FIELD INVESTIGATION, THE SANGAMO WESTON PLANT SITE HAS BEEN DIVIDED INTO TEN AREAS. THESE AREAS ARE IDENTIFIED AS A THROUGH H, THE SEPTIC DRAIN FIELD, AND THE WASTEWATER TREATMENT FACILITY IS EXHIBITED ON THE SANGAMO WESTON SITE WITH ELEVATIONS RANGING FROM 930 FEET ABOVE MEAN SEA LEVEL (MSL) AT TOWN CREEK, BORDERING THE SITE TO THE SOUTH, TO ABOUT 1,150 FEET ABOVE MSL ON THE TOP OF A LINEAR EAST-WEST TRENDING RIDGE DISSECTING THE PROPERTY. THE MANUFACTURING BUILDING IS LOCATED ON THE TOP OF THE RIDGE AT AN ELEVATION OF ABOUT 1,100 FEET ABOVE MSL. THE PAVED PARKING AREA FOR THE MANUFACTURING BUILDING IS LOCATED ALONG THE SOUTH FLANK OF THE RIDGE ADJACENT TO THE BUILDING. THE WASTEWATER TREATMENT FACILITY, CONSISTING OF A STABILIZATION LAGOON, AN INACTIVE EQUALIZATION BASIN AND A CONCRETE-LINED EQUALIZATION BASIN, IS LOCATED SOUTH OF THE MANUFACTURING BUILDING. DISCHARGE FROM THE STABILIZATION LAGOON PASSES OVER A CONCRETE SPILLWAY UNDER SANGAMO ROAD AND THEN TO TOWN CREEK. THE DISCHARGE IS REGULATED UNDER AN NPDES PERMIT ISSUED BY THE STATE OF SOUTH CAROLINA TO THE CURRENT OPERATOR OF THE PLANT. 1 Order number 940620-103843-ROD -001-001 page 4244 set 4 with 100 of 100 items THE RIDGE BISECTING THE SANGAMO WESTON SITE ACTS AS A DIVIDE FOR SURFACE AND GROUNDWATER. SURFACE WATER RUNOFF AND GROUNDWATER ON THE SOUTH SIDE OF THE RIDGE FLOWS SOUTHWARD AND DISCHARGES INTO TOWN CREEK. SURFACE WATER RUNOFF AND GROUNDWATER ON THE NORTH SIDE OF THE RIDGE DRAINS NORTHWARD AND DISCHARGES INTO UNNAMED TRIBUTARIES TO TWELVE-MILE CREEK. MOST OF THE SANGAMO WESTON PROPERTY, INCLUDING MANY OF THE INVESTIGATION AREAS, IS FORESTED. THE ONLY UNFORESTED AREAS INCLUDE THE WASTEWATER TREATMENT FACILITY, SEPTIC DRAIN FIELD, AREA A AND AREA F. THE WASTEWATER TREATMENT FACILITY AND SEPTIC DRAIN FIELDS ARE VEGETATED WITH GRASS AND WEEDS. AREA A IS COVERED WITH KUDZU. AREA F IS SURROUNDED WITH FOREST AND IS COVERED WITH TALL GRASS, WEEDS, AND SAPLINGS. THE MANUFACTURING FACILITY, INCLUDING THE PAVED PARKING LOT, IS NOT FORESTED OR VEGETATED. HOWEVER, THE LAWN SURROUNDING THE FACILITY IS GRASSED, WITH TREES. THE SANGAMO WESTON PLANT SITE IS LOCATED IN THE PIEDMONT SECTION OF SOUTH CAROLINA ON THE EASTERN SLOPE OF THE SOUTHERN APPALACHIAN MOUNTAINS. THE FIRST RIDGE OF THE MOUNTAINS IS APPROXIMATELY TEN MILES TO THE NORTH, AND THE MAIN RIDGE IS APPROXIMATELY FORTY MILES TO THE NORTH. THESE MOUNTAINS GENERALLY PROTECT THIS AREA FROM THE FULL FORCE OF COLD FRONTS WHICH MOVE SOUTHEASTWARD TOWARD THIS AREA IN THE WINTER MONTHS. THE TEMPERATURE RISES TO 90 DEGREE FAHRENHEIT OR ABOVE ON ALMOST HALF OF THE DAYS DURING THE SUMMER MONTHS, BUT USUALLY FALLS TO 70 DEGREE FAHRENHEIT OR LOWER DURING THE NIGHT. WINTERS ARE MODERATE, WITH THE TEMPERATURE REMAINING BELOW FREEZING THROUGHOUT THE DAYLIGHT HOURS ONLY THREE TO FOUR TIMES DURING A NORMAL YEAR. APPROXIMATELY TWO FREEZING RAINSTORMS AND TWO OR THREE SMALL SNOWSTORMS OCCUR EACH WINTER. THE MEAN ANNUAL TEMPERATURE FOR THIS AREA IS 60.7 DEGREE FAHRENHEIT. 1.2 THE BREAZEALE SITE THE BREAZEALE SITE IS APPROXIMATELY SEVEN ACRES IN SIZE AND IS LOCATED ABOUT ONE MILE SOUTH-SOUTHWEST OF PICKENS, ON WOLF CREEK ROAD (FIGURE 3). THE SOUTH AND SOUTHWEST PORTION OF THE SITE ARE LOCATED ON THE FLOOD PLAIN OF WOLF CREEK WHICH BORDERS THE SITE TO THE SOUTH. SURFACE ELEVATIONS RANGE FROM 872 FEET ABOVE MSL ALONG WOLF CREEK TO 910 FEET ABOVE MSL AT THE NORTHWEST CORNER OF THE SITE. A DRAINAGE DITCH BORDERS THE SITE TO THE EAST. THIS DITCH DRAINS SOUTHWARD AND DISCHARGES INTO WOLF CREEK AT THE SOUTHEAST CORNER OF THE SITE. WOLF CREEK BORDERS THE SITE TO THE SOUTH. APPROXIMATELY 1,500 FEET TO THE NORTHWEST AND UPSTREAM ON WOLF CREEK IS A DAM FOR A US SOIL CONSERVATION SERVICE LAKE. SEEPAGE FROM THIS DAM CREATES MINOR FLOW IN THE DRAINAGE DITCH ON THE EAST BOUNDARY OF THE SITE. SURFACE WATER RUNOFF ON-SITE OCCURS AS A RESULT OF DIRECT PRECIPITATION. SURFACE WATER ON-SITE DRAINS SOUTH TO SOUTHEAST TOWARD WOLF CREEK WHERE 1 Order number 940620-103843-ROD -001-001 page 4245 set 4 with 100 of 100 items IT DISCHARGES. A SMALLER PORTION OF RUNOFF DRAINS EASTWARD TOWARDS THE DRAINAGE DITCH. THE DRAINAGE DITCH DISCHARGES INTO WOLF CREEK. WOLF CREEK FLOWS SOUTHWESTWARD ALONG THE SOUTH BOUNDARY OF THE SITE. VEGETATION CONSISTS PRIMARILY OF GRASS COVER. STANDS OF TREES, SOME OF WHICH ARE DENSE WITH THICK UNDERGROWTH OCCUR SOUTH OF THE AREA OF WASTE DEPOSITION TO WOLF CREEK. ALONG THE BANKS OF WOLF CREEK ARE SMALL TREES, SHRUBS AND THICK MARSH GRASS. 1.3 THE NIX SITE THE NIX SITE IS APPROXIMATELY 7.5 ACRES IN SIZE AND IS LOCATED APPROXIMATELY TWO MILES NORTHEAST OF PICKENS. THE SITE IS LOCATED JUST WEST OF NORTH CEDAR ROCK ROAD BETWEEN GLASSY MOUNTAIN CHURCH ROAD AND OLD FARRS BRIDGE ROAD (FIGURE 4). A DIRT LOGGING ROAD LEADS FROM NORTH CEDAR ROCK ROAD TO THE SITE AREA. AN UNNAMED TRIBUTARY TO WOLF CREEK IS LOCATED 100 FEET WEST OF THE SITE. SURFACE ELEVATIONS RANGE FROM 1046 FEET ABOVE MSL AT THE WEST END OF THE SITE TO 1,105 FEET ABOVE MSL AT THE EAST END OF THE SITE. THE MOST PROMINENT SURFACE FEATURE ON THE NIX SITE IS A NATURALLY OCCURRING 400 FOOT LONG RAVINE WHICH TRENDS FROM EAST TO WEST. THIS RAVINE IS APPROXIMATELY THIRTY FEET DEEP ON ITS EASTERN END AND BECOMES SHALLOWER TOWARD THE WESTERN END AS IT OPENS UP INTO A MARSH. A SMALL MAN MADE POND IS LOCATED ON THE FAR WEST END OF THE SITE AT THE MOUTH OF THE RAVINE. WATER FEEDING THE POND AND MARSH COMES FROM SMALL SPRINGS AT THE HEAD OF THE MARSH AND FROM SURFACE RUNOFF. TWO STREAMS CREATED BY THE OUT FALL FROM THE MAN MADE POND FLOW INTO THE UNNAMED TRIBUTARY TO WOLF CREEK. VEGETATION AT THE NIX SITE CONSISTS OF A GRASS COVERED PASTURE WITH WOODED PORTIONS SOUTH OF THE RAVINE. TREES, TALL MARSH GRASSES AND KUDZU ARE PRESENT IN THE RAVINE. VEGETATION NORTH OF THE RAVINE CONSISTS OF GRASS, WEEDS, SMALL SHRUBS AND YOUNG TREES. SURFACE WATER RUNOFF OUTSIDE OF THE RAVINE FLOWS WESTWARD AND DISCHARGES DIRECTLY INTO THE UNNAMED TRIBUTARY. SURFACE WATER IN THE UNNAMED TRIBUTARY OF WOLF CREEK, FLOWS SOUTH AND EMPTIES INTO WOLF CREEK APPROXIMATELY ONE-HALF MILE SOUTHWEST OF THE SITE. 1.4 THE DODGENS SITE THE DODGENS SITE IS LOCATED THREE MILES NORTHWEST OF PICKENS AND IS ADJACENT TO THE MIDDLE FORK OF TWELVE-MILE CREEK (FIGURE 5). THE SITE IN ABOUT 6.5 ACRES IN SIZE. THE SITE IS RELATIVELY FLAT WITH SURFACE ELEVATIONS RANGING FROM 940 FEET ABOVE MSL ADJACENT TO THE CREEK TO ABOUT 949 FEET ABOVE MSL AT THE WEST SIDE OF THE SITE; A TOPOGRAPHIC RELIEF OF ABOUT NINE FEET. SHARP RISES IN TOPOGRAPHY OCCUR ALONG THE NORTH, WEST AND SOUTH SIDE OF THE SITE. ELEVATIONS TO THE NORTH AND 1 Order number 940620-103843-ROD -001-001 page 4246 set 4 with 100 of 100 items WEST EXCEED 970 FEET. MIDDLE FORK TWELVE-MILE CREEK FLOWS SOUTHWARD ALONG THE EAST BOUNDARY OF THE SITE. AN UNNAMED TRIBUTARY LOCATED ALONG THE SOUTHERN END OF THE SITE FLOWS INTO THE CREEK. A SMALL MAN-MADE POND IS LOCATED AT THE SOUTH END OF THE SITE. NINE TIMES ROAD EXTENDS IN A NORTHWEST DIRECTION WEST OF THE SITE. A DIRT ROAD LEADS FROM NINE TIMES ROAD TO THE SOUTH END OF THE SITE. THE ROAD TURNS NORTHWARD AND EXTENDS ALONG THE WEST AND NORTH PERIMETER OF THE SITE. VEGETATION AT THE DODGENS SITE CONSISTS OF GRASS COVER. THE HILLS BORDERING THE SITE TO THE NORTH, WEST AND SOUTH ARE COVERED WITH STANDS OF TREES AND UNDERGROWTH. A DENSE STAND OF TREES AND UNDERGROWTH ALSO EXTENDS ALONG THE BANKS OF MIDDLE FORK TWELVE-MILE CREEK AT THE EAST SIDE OF THE SITE. SURFACE WATER RUNOFF ON-SITE OCCURS AS A RESULT OF DIRECT PRECIPITATION. ON-SITE SURFACE WATER DRAINS SOUTHEASTWARD TOWARDS MIDDLE FORK TWELVE-MILE CREEK. THE CREEK FLOWS SOUTHWARD ALONG THE EAST BOUNDARY OF THE SITE AND TURNS EASTWARD AT THE SOUTHEAST CORNER OF THE SITE. A SMALL UNNAMED TRIBUTARY LOCATED ALONG THE SOUTHERN END OF THE SITE FLOWS INTO THE CREEK. A SMALL STREAM ORIGINATING WEST OF THE SITE CROSSES NINE TIMES ROAD, BORDERS THE SOUTHWEST PORTION OF THE SITE AND DISCHARGES INTO THE UNNAMED TRIBUTARY. A PORTION OF SURFACE WATER FLOW FROM THE STREAM IS DIVERTED TO A SMALL MAN-MADE POND LOCATED AT THE SOUTH END OF THE SITE. THE OUTFALL FROM THE POND DISCHARGES INTO THE UNNAMED TRIBUTARY. SURFACE WATER ON THE DODGENS SITE DRAINS DIRECTLY TO MIDDLE FORK TWELVE-MILE CREEK. 1.5 THE CROSS ROADS SITE THE CROSS ROADS SITE IS ABOUT FIVE ACRES IN SIZE AND IS LOCATED APPROXIMATELY THREE MILES SOUTHWEST OF PICKENS (FIGURE 6). THE SITE IS HEAVILY WOODED WITH AN UNNAMED TRIBUTARY TO TWELVE-MILE CREEK ALONG THE SOUTHERN BOUNDARY. SURFACE ELEVATIONS RANGE FROM 11030 FEET MSL, IN THE NORTHWEST PORTION OF THE SITE, TO 960 FEET IL ALONG THE UNNAMED TRIBUTARY BORDERING THE SOUTHERN PORTION OF THE SITE, A TOPOGRAPHIC RELIEF OF APPROXIMATELY SEVENTY FEET. A WIDE VARIETY OF DOMESTIC WASTE, INCLUDING BOTTLES, CANS, AND CAR BODIES ARE DISPOSED THROUGHOUT THE SITE. PENROSE DRIVE EXTENDS IN A NORTHEAST-SOUTHEAST DIRECTION WEST OF THE SITE. AN OLD ROADBED EXTENDS FROM PENROSE DRIVE ACROSS THE NORTHWEST SECTION OF THE SITE. THIS ROAD IS FENCED OFF AT BOTH ENDS WHERE IT EXITS THE SITE. SOUTH OF THE OLD ROADBED, IN THE NORTHWEST PORTION OF THE SITE, IS AN ABANDONED HOME SITE. ALL THAT REMAINS IS AN ABANDONED WELL (APPROXIMATELY FOUR FEET IN DIAMETER X TWENTY FEET DEEP), AN OUTHOUSE AND VARIOUS HOUSEHOLD DEBRIS. THE CROSS ROADS SITE IS HEAVILY 1 Order number 940620-103843-ROD -001-001 page 4247 set 4 with 100 of 100 items WOODED WITH PORTIONS CONTAINING DENSE UNDERGROWTH. DENSE UNDERGROWTH ALSO EXTENDS ALONG THE BANKS OF THE UNNAMED TRIBUTARY OF TWELVE-MILE CREEK. SURFACE WATER RUNOFF ON-SITE OCCURS AS A RESULT OF DIRECT PRECIPITATION. ON-SITE SURFACE WATER DRAINS SOUTHWARD TOWARDS THE UNNAMED TRIBUTARY OF TWELVE-MILE CREEK. THE TRIBUTARY FLOWS EASTWARD ALONG THE SOUTHERN BOUNDARY OF THE SITE AND TURNS NORTHEASTWARD AT THE SOUTHEAST CORNER OF THE SITE. IT THEN CONTINUES IN THIS GENERAL DIRECTION FOR APPROXIMATELY 1,000 FEET WHERE IT DISCHARGES INTO TWELVE-MILE CREEK. 1.6 THE JOHN TROTTER SITE THE JOHN TROTTER SITE IS ABOUT THREE ACRES IN SIZE AND IS LOCATED APPROXIMATELY TWO MILES NORTH-NORTHEAST OF PICKENS NEAR TROTTER HILL ROAD AND TOWN CREEK SCHOOL ROAD (FIGURE 7). THE SITE IS LOCATED BEHIND A MACHINE SHOP. AN UNNAMED TRIBUTARY TO TOWN CREEK BORDERS THE NORTHEASTERN PORTION OF THE SITE. SURFACE ELEVATIONS RANGE FROM 1,074 FEET ABOVE MSL, NEAR TROTTER HILL ROAD, TO 1,030 FEET ABOVE MSL NEAR THE UNNAMED TRIBUTARY TO TOWN CREEK, A TOPOGRAPHIC RELIEF OF ABOUT FORTY-FOUR FEET. A BROAD GRASSED PLAIN IS LOCATED ALONG THE WEST BANKS OF THE TRIBUTARY NORTH OF THE SITE. VEGETATION AT THE JOHN TROTTER SITE CONSISTS OF GRASS COVER SURROUNDING THE MACHINE SHOP ON THE WESTERN END OF THE SITE WITH A DENSELY WOODED AREA CONTAINING THICK UNDERGROWTH ON THE EASTERN END OF THE SITE. THE LOW PLAIN AREA NORTH OF THE SITE IS VEGETATED WITH GRASS. SURFACE WATER RUNOFF ON-SITE OCCURS AS A RESULT OF DIRECT PRECIPITATION. ON-SITE SURFACE WATER DRAINS NORTH-EASTWARD TOWARDS THE UNNAMED TRIBUTARY TO TOWN CREEK. THIS TRIBUTARY FLOWS SOUTH-EASTWARD ALONG THE NORTHEASTERN BOUNDARY OF THE SITE AND EMPTIES INTO ANOTHER UNNAMED TRIBUTARY TO TOWN CREEK. THE SECOND UNNAMED TRIBUTARY CONTINUES SOUTH-SOUTHEAST AND EMPTIES INTO TOWN CREEK, 0.5 MILES SOUTH-SOUTHEAST OF THE SITE. 1.7 THE WELBORN SITE THE WELBORN SITE IS APPROXIMATELY FOUR ACRES IN SIZE AND IS LOCATED ABOUT TWO MILES EAST OF PICKENS NEAR TURNER ROAD (FIGURE 8). THE SITE IS MARKED BY ERODED AREAS WITH RAVINE DEPTHS AS MUCH AS TWENTY-FIVE FEET. SITE ELEVATIONS RANGE FROM 1010 FEET ABOVE MSL, AT THE EAST SIDE OF THE SITE, TO 1075 FEET MSL AT THE NORTHWEST PORTION OF THE SITE, A TOPOGRAPHIC RELIEF OF SIXTY-FIVE FEET. SHARP CHANGES IN TOPOGRAPHY OCCUR ALONG THE SIDES OF THE RAVINES. THERE ARE NO STREAMS IN THE IMMEDIATE AREA OF THE SITE. APPROXIMATELY 600 FEET TO THE EAST IS AN UNNAMED TRIBUTARY OF WOLF CREEK WHICH FLOWS SOUTH. WOLF CREEK IS APPROXIMATELY 1400 FEET SOUTH OF THE SITE AND FLOWS SOUTHWESTWARD. VARIOUS TYPES OF DEBRIS INCLUDING HOUSEHOLD 1 Order number 940620-103843-ROD -001-001 page 4248 set 4 with 100 of 100 items GARBAGE, GLASS, SCRAP METAL, LARGE METAL OBJECTS, (E.G., WASHING MACHINES, AND INDUSTRIAL WASTE MATERIAL) ARE DEPOSITED IN THE RAVINES. #SHEA 2.0 SITE HISTORY AND ENFORCEMENT ACTIVITIES THE EXISTING SANGAMO WESTON PLANT WAS CONSTRUCTED IN THREE PHASES BEGINNING IN 1955 WITH PLANT CONSTRUCTION FOR ELECTROLYTIC CAPACITOR MANUFACTURING. ADDITIONS WERE MADE IN 1956 AND 1961 FOR THE POWER FACTOR AND MICA CAPACITOR MANUFACTURING OPERATIONS. THE MAJOR PRODUCTS MANUFACTURED BY THE SANGAMO WESTON PICKENS PLANT INCLUDED ELECTROLYTIC CAPACITORS, MICA CAPACITORS, POWER FACTOR CAPACITORS, AND POTENTIOMETERS. PCBS WERE USED AS THE DIELECTRIC FLUID IN POWER FACTOR CAPACITORS. AROCLOR 1242, 1254 AND MCS 1016 (PRODUCTS OF THE MONSANTO CORPORATION) WERE USED AS THE DIELECTRIC FLUIDS. IN THE EARLY 1970S, THE FACILITY MADE A SWITCH TO MCS 1016 (A LESS CHLORINATED PCB PRODUCT OF THE MONSANTO CORPORATION), FROM AROCLOR 1242, AS THE PRIMARY DIELECTRIC FLUID. IN 1968, CONSTRUCTION BEGAN ON A 1.4 MILLION GALLON/DAY (MGD) WASTEWATER TREATMENT FACILITY. THE FACILITIES WERE COMPLETED IN 1970. THE SYSTEM CONSISTED OF A PRIMARY SETTLING BASIN AND A LARGE STABILIZATION LAGOON. THE TREATMENT SYSTEM WAS DESIGNED FOR (AMONG OTHER THINGS) THE NEUTRALIZATION OF ACID SOLUTIONS USED IN THE ETCHING AND FORMING PROCESSES AND FOR PRECIPITATION OF DISSOLVED MATERIALS SUCH AS ALUMINUM. THE ALUMINUM PRECIPITATES SETTLED IN A PRIMARY SETTLING BASIN. DURING THE 1970S AND INTO THE 1980S, A NUMBER OF SIGNIFICANT MODIFICATIONS TOOK PLACE TO BOTH GENERAL PLANT OPERATIONS AND THE OPERATION OF THE WASTEWATER TREATMENT FACILITIES. A BENTONITE CLAY LAYER WAS ADDED TO THE STABILIZATION LAGOON TO HELP SETTLE PCB MATERIALS THAT MIGHT BE PRESENT IN THE LIQUID PHASE. IN ADDITION, THE DRAINS FROM THE TWO IMPREGNATION AREAS OF THE POWER FACTOR DIVISION WERE SEALED OFF FROM THE WASTE TREATMENT FACILITIES. THIS ACTION WAS TAKEN TO ELIMINATE THE PATHWAY OF PCB ENTRY INTO THE WASTEWATER SYSTEM. THREE SEPTIC TANK DRAIN FIELD AREAS EXIST ON THE PLANT PROPERTY FOR TREATMENT AND DISPOSAL OF SANITARY WASTEWATERS FROM THE PLANT. TWO DRAIN FIELDS ARE LOCATED ADJACENT TO EACH OTHER IN AN AREA NORTH OF THE BUILDING, A THIRD AREA IS LOCATED SOUTHWEST OF THE PLANT. WASTE MATERIALS FROM PAST PRODUCTION ACTIVITIES HAVE BEEN DEPOSITED IN A NUMBER OF AREAS ON THE SANGAMO WESTON PROPERTY. ON-SITE LANDFILLING ACTIVITIES BEGAN IN THE MID 1950S AND CONTINUED OFF AND ON UNTIL 1972. THE MATERIAL INCLUDED SCRAP CAPACITORS AND ALUMINUM HYDROXIDE SLUDGE AS WELL AS OTHER ASSORTED INDUSTRIAL REFUSE. ON-SITE DISPOSAL OF PLANT WASTE MATERIALS WAS DISCONTINUED IN JULY 1972. 1 Order number 940620-103843-ROD -001-001 page 4249 set 4 with 100 of 100 items PRIOR TO 1972, GENERAL PLANT WASTE WAS ALSO DISPOSED AT PRIVATELY AND PUBLICLY OWNED OFF-SITE AREAS IN THE PICKENS COUNTY AREA. SOME OF THE MATERIALS TAKEN TO OFF-SITE DISPOSAL SITES CONTAINED PCBS. AS PART OF THE MANUFACTURING PROCESS, ALL CAPACITORS WERE INSPECTED AND TESTED. THE CAPACITORS THAT FAILED TO MEET QUALITY CONTROL CRITERIA WERE DISCARDED ALONG WITH OTHER PROCESS AND NON-PROCESS SOLID WASTES. THE SOLID WASTE WAS DISPOSED OF ON PLANT PROPERTY IN SEVERAL LOCATIONS AND AT A NUMBER OF OFF-SITE LOCATIONS. THE OFF-SITE AREAS ADDRESSED IN THIS ROD ARE DESIGNATED AS THE NIX, DODGENS, WELBORN, CROSS ROADS, JOHN TROTTER AND BREAZEALE SITES. IN THE MID-1970S, ENVIRONMENTAL MONITORING PROGRAMS BY EPA AND THE SOUTH CAROLINA DEPARTMENT OF HEALTH AND ENVIRONMENTAL CONTROL (DHEC) LED TO THE DETECTION OF POLYCHLORINATED BIPHENYLS (PCBS) IN THE SEDIMENTS OF LAKE HARTWELL, ITS TRIBUTARIES, AND IN SOILS UNDERLYING FORMER DUMP SITES IN PICKENS COUNTY THAT WERE USED BY THE SANGAMO WESTON, INC. MANUFACTURING PLANT IN PICKENS. THE PCBS IN THE WATER RESOURCES WERE TRACED TO EFFLUENT ASSOCIATED WITH THE SANGAMO PLANT, A PRODUCER OF ELECTRIC CAPACITORS. THE PLANT USED PCBS AS A DIELECTRIC, OR NON-CONDUCTING, FLUID IN CAPACITORS UNTIL 1977, WHEN THE FEDERAL GOVERNMENT IMPOSED A BAN ON THE MANUFACTURE AND USE OF PCBS. SOUTH CAROLINA DHEC FISH STUDY IN 1974, DHEC CONDUCTED A PCB ANALYSIS OF FISH IN SOUTH CAROLINA AND DETECTED PCBS IN A FISH SAMPLE AT TWO SITES IN THE TWELVE-MILE CREEK AREA OF LAKE HARTWELL. FURTHER DHEC SAMPLING IN 1975 AND 1976 DEMONSTRATED ADDITIONAL PCB CONTAMINATION OF SEDIMENT AND OF FISH, ABOVE THE US FOOD AND DRUG ADMINISTRATION (FDA) SAFE TOLERANCE LIMIT OF 5.0 PARTS PER MILLION (PPM). IN AUGUST 1976, DHEC, IN CONSULTATION WITH EPA, INITIATED ANNUAL PCB TESTING OF FISH AND SEDIMENT IN LAKE HARTWELL. THE SAME MONTH, EPA AND DHEC ISSUED A JOINT ADVISORY AGAINST CONSUMING FISH FROM ANY PART OF THE LAKE. IN OCTOBER 1976, THE ADVISORY WAS MODIFIED BASED ON FURTHER STUDY TO INCLUDE ONLY THE SENECA RIVER ARM OF LAKE HARTWELL ABOVE HIGHWAY 24. IN 1984, THE FDA LOWERED THE SAFE TOLERANCE LEVEL FROM 5.0 PPM TO 2.0 PPM. EPA AND DHEC EXPANDED THE EXISTING FISH CONSUMPTION ADVISORY TO INCLUDE ALSO ALL FISH OVER THREE POUNDS CAUGHT ANYWHERE IN THE LAKE. DHEC THEN REASSESSED ITS FISH TISSUE MONITORING PROGRAM AND DEVELOPED MORE RIGOROUS SAMPLING PROCEDURES THAT WOULD ENABLE RESEARCHERS TO ASSESS TRENDS. DHEC'S MONITORING PROGRAM WAS REVISED IN 1985 AND INITIATED IN 1986. FIVE SPECIES OF FISH OF SIMILAR WEIGHTS FOR EACH SPECIES WERE SAMPLED $ROM 3-5 TESTING STATIONS. THE STATIONS WERE SELECTED BASED ON HISTORICAL KNOWLEDGE OF PCBS IN THE LAKE AND WERE CHOSEN TO PROVIDE COMPREHENSIVE COVERAGE. FOR EXAMPLE, SV-107 IN TWELVE-MILE CREEK REPRESENTS THE MOST CONTAMINATED PORTION OF LAKE HARTWELL. THE TWO 1 Order number 940620-103843-ROD -001-001 page 4250 set 4 with 100 of 100 items STATIONS IMMEDIATELY SOUTH OF THIS STATION, SV-532 AND SV-235, REPRESENT A LARGE, OPEN-WATER AREA OF THE LAKE AS FAR REMOVED FROM THE CONTAMINATION SOURCE AS POSSIBLE, AND SV-641 ALLOWS FOR CROSS COMPARISONS BECAUSE IT IS IN THE OTHER MAJOR RIVER TRIBUTARY TO LAKE HARTWELL AND IS NOT SUBJECT TO DIRECT PCB INPUT. THE FISH IN DHEC'S RESEARCH INCLUDE CRAPPIE, LARGE MOUTH BASS AND HYBRID BASS WHICH REPRESENT OVER EIGHTY PERCENT OF THE GAME FISH CAUGHT BY THE PUBLIC. HYBRID BASS MOVE FROM PLACE TO PLACE, POTENTIALLY MOVE IN AND OUT OF CONTAMINATED AREAS AND, THEREFORE, COULD DEMONSTRATE WORST-CASE CONTAMINANT LEVELS IN FISH OUTSIDE THE ADVISORY AREA. WHITE AND CHANNEL CATFISH ALSO ARE INCLUDED IN THE STUDY BECAUSE THEY DWELL ALONG AND FEED OFF LAKE BOTTOMS WHERE PCB MOLECULES TEND TO SETTLE AND FORM HIGH CONCENTRATIONS. CATFISH, THEREFORE, TEND TO INGEST MORE CONTAMINANTS THAN FISH LIVING OR FEEDING IN OTHER LAYERS OF LAKES OR IN STREAMS. DHEC SAMPLED PROPORTIONATE NUMBERS OF EACH OF THE FIVE SPECIES TO ACCOUNT FOR VARIABILITY IN PCB LEVELS IN EACH SPECIES. FOR EXAMPLE, TEN SAMPLES OF EACH OF THE FIRST THREE SPECIES, AND TWO OF EACH CATFISH SPECIES ARE TAKEN AT EACH STATION. FEWER CATFISH ARE REQUIRED BECAUSE THEY HAVE SHOWN THE LEAST VARIABILITY IN STUDY FINDINGS. EACH OF THE FISH ARE STUDIED IN "MODIFIED WHOLE FORM", MINUS THE HEAD AND INTERNAL ORGANS. EXCEPT FOR THE CATFISH, WHICH HAVE TOUGH AND OFTEN UNPALATABLE SKIN, THE FISH ARE TESTED WITH THE SKIN ATTACHED. THE AGENCY USES THIS APPROACH FOR TWO REASONS. FIRST, TESTING THE WHOLE FISH, INCLUDING THE SKIN, PROVIDES A MORE COMPLETE COUNT OF PCBS THAN WOULD TESTING FILLETS. SINCE PEOPLE COMMONLY EAT FISH AS FILLETS, WITHOUT THE SKIN, THIS TESTING PROCEDURE PROVIDES AN ADDED MARGIN OF SAFETY FOR PUBLIC HEALTH. SECOND, DHEC'S METHOD AVOIDS THE DATA VARIATIONS THAT RESULT FROM THE FILLETING PROCEDURES WHICH IS TRICKY. UNLESS EACH CUT IS EXACTLY THE SAME, THE AMOUNT OF FAT INCLUDED IN THE SAMPLE WILL VARY. FAT CELLS ARE PRIME "HOLDERS" OF PCB MOLECULES. TO DATE, EVEN WITH REFINED RESEARCH METHODS, THE DATA OF PCB LEVELS AMONG FISH IN LAKE HARTWELL VARY. DHEC'S 1986 FINDINGS, FOR EXAMPLE, SHOWED THAT LARGE MOUTH BASS FROM THE TWELVE-MILE CREEK PORTION OF THE LAKE, RANGING IN WEIGHT FROM 1.68 - 2.98 POUNDS, DEMONSTRATED A PCB RANGE OF 3.64 PPM TO 130 PPM. WHILE THE FISH STUDY CONTINUES, DHEC AND EPA ASSESS WHETHER THE FISH CONSUMPTION ADVISORY SHOULD REMAIN IN EFFECT. THE MOST CURRENT READINGS SHOW THAT FISH ABOVE HIGHWAY 24 REGISTER AVERAGE PCB LEVELS ABOVE THE FDA LIMIT, FROM 2.22 PP IN CRAPPIE TO 34.06 PPM IN LARGE MOUTH BASS. BELOW HIGHWAY 24, ONLY HYBRID BASS AND CATFISH EXHIBITED THE EXCESS LEVELS AT A RANGE OF 5.48 PPM AND 2.05 PPM, REFLECTIVELY. THE FISH CONSUMPTION ADVISORY REMAINS IN EFFECT. IT AND THE SAMPLING WILL CONTINUE UNTIL LEVELS FALL BELOW THE FDA TOLERANCE LIMIT. BREAZEALE SITE 1 Order number 940620-103843-ROD -001-001 page 4251 set 4 with 100 of 100 items EPA AND SANGAMO ENTERED INTO AN ADMINISTRATIVE ORDER ON CONSENT ON AUGUST 11, 1986 FOR AN IMMEDIATE REMOVAL ACTION ON THE BREAZEALE SITE. IN ITS 103C NOTIFICATION, SANGAMO REPORTED DEPOSITING APPROXIMATELY 24,000 CUBIC FEET OF PCB WASTE FROM THE PLANT. PCB LEVELS AS HIGH AS 27,000 PPM WERE FOUND IN SOIL SAMPLES TAKEN BY EPA IN NOVEMBER 1985. TWO MOBILE HOMES WERE ON THE SITE, BUT ONLY ONE WAS OCCUPIED. AS A RESULT OF THIS ORDER, THE RESIDENTS WERE RELOCATED, THE SURFACE DRAINAGE AT THE SITE WAS REROUTED, FENCING WAS CONSTRUCTED TO RESTRICT SITE ACCESS, AND A GEOTEXTILE LINER AND SOIL CAP WERE ADDED AS AN INTERIM MEASURE TO RETARD THE MIGRATION OF PCB CONTAMINATION. NIX SITE IN ITS 103C NOTIFICATION, SANGAMO REPORTED DEPOSITING APPROXIMATELY 10, 509 CUBIC YARDS OF PCB WASTE FROM THE PLANT. IN 1980, SANGAMO REMOVED A TOTAL (FROM THE MIX AND DODGENS SITES) OF 17,711 CUBIC YARDS OF PCB CONTAMINATED SOIL AND DEBRIS AND DISPOSED OF IT IN A LANDFILL ON THE SANGAMO PLANT PROPERTY. DODGENS SITE IN ITS 103C NOTIFICATION, SANGAMO REPORTED DEPOSITING APPROXIMATELY 6,822 CUBIC YARDS OF PCB WASTE FROM THE PLANT. IN 1980, SANGAMO REMOVED A TOTAL (FROM THE NIX AND DODGENS SITES) OF 17,711 CUBIC YARDS OF PCB CONTAMINATED SOIL AND DEBRIS AND DISPOSED OF IT IN A LANDFILL ON THE SANGAMO PLANT PROPERTY. ON-SITE REMOVAL IN 1989, DURING THE RI, AREA D ON THE PLANT PROPERTY WAS FOUND TO CONTAIN PCB LEVELS AS HIGH AS 77,800 PPM. EPA SUPERVISED THE REMOVAL OF 7,285 TONS OF PCB CONTAMINATED SOIL AND DEBRIS TO THE GSX PERMITTED RCRA LANDFILL IN PINEWOOD, SOUTH CAROLINA. IN ADDITION, 6,684 CAPACITORS OVER 3 POUNDS WERE TAKEN TO AN APPROVED FACILITY FOR INCINERATION. #HCP 3.0 HIGHLIGHTS OF COMMUNITY PARTICIPATION INFORMATION REPOSITORIES FOR THIS SITE WERE ESTABLISHED IN THE PICKENS COUNTY LIBRARY SYSTEM (PICKENS AND EASLEY BRANCHES) AND THE R.M. COOPER LIBRARY AT CLEMSON UNIVERSITY IN CLEMSON, SOUTH CAROLINA. INFORMATION IS ALSO AVAILABLE IN ATLANTA, GEORGIA IN THE EPA REGION IV REGIONAL OFFICE. FACT SHEETS AND PRESS ADVISORIES WERE PREPARED PRIOR TO EACH PUBLIC MEETING. A COMMUNITY RELATIONS PLAN IDENTIFYING A POSITIVE PUBLIC OUTREACH STRATEGY WAS DEVELOPED AT THE DIRECTION OF EPA REGION IV STAFF AND 1 Order number 940620-103843-ROD -001-001 page 4252 set 4 with 100 of 100 items SUBMITTED TO THE INFORMATION REPOSITORIES PRIOR TO THE START OF WORK AT THE SITE. A PUBLIC MEETING WAS HELD IN JUNE 1987 TO PRESENT THE RI/FS WORK PLAN TO THE PUBLIC. FACT SHEETS UPDATING LOCAL CITIZENS ON ACTIVITIES AT THE SITE WERE ISSUED IN MAY 1987, FEBRUARY 1988, NOVEMBER 1988, DECEMBER 1989, JULY 1990 AND SEPTEMBER 1990. THE RI WAS SUMMARIZED IN THE DECEMBER 1989 FACT SHEET, AND AN OPPORTUNITY WAS PROVIDED FOR A PUBLIC MEETING. NO ONE REQUESTED THAT EPA CONDUCT A MEETING AT THAT TIME. EPA HELD A PUBLIC MEETING JULY 10, 1990 AT THE PICKENS COUNTY SENIOR HIGH SCHOOL IN PICKENS, SOUTH CAROLINA TO PRESENT THE FEASIBILITY STUDY RESULTS AND THE EPA'S PROPOSED PLAN FOR THE SITE. EPA PLACED PUBLIC NOTICES OF THE MEETING IN THE GREENVILLE NEWS AND THE PICKENS COUNTY SENTINEL AND DISTRIBUTED FACT SHEETS DESCRIBING EPA'S PROPOSED PLAN TO CITIZENS AND OFFICIALS NOTED ON EPA'S SITE MAILING LIST. IN ADDITION, EPA HELD A BRIEFING FOR LOCAL OFFICIALS PRIOR TO THE MEETING ON JULY 10, 1990. EPA ALSO BRIEFED THE PICKENS COUNTY COUNCIL AT THEIR REGULARLY SCHEDULED MEETING ON SEPTEMBER 17, 1990. IN ADDITION, EPA HELD AN AVAILABILITY SESSION ON SEPTEMBER 20, 1990 IN LIBERTY, SOUTH CAROLINA. A SPECIALIST FROM EPA'S CINCINNATI, OHIO OFFICE PRESENTED INFORMATION ON THERMAL SEPARATION AND THEN EPA RESPONDED TO QUESTIONS AND COMMENTS FROM MEMBERS OF THE AUDIENCE. TRANSCRIPTS OF ALL THE PUBLIC MEETINGS WERE MADE AVAILABLE TO THE PUBLIC THROUGH THE ADMINISTRATIVE RECORD FOR THE SITE. #SROU 4.0 SCOPE AND ROLE OF OPERABLE UNIT THIS RECORD OF DECISION ADDRESSES OPERABLE UNIT ONE OF THE SUBJECT SITE. OPERABLE UNIT ONE CONSISTS OF GROUNDWATER AND SOURCE CONTAMINATION AT THE PLANT SITE AND THE CROSS ROADS, NIX, BREAZEALE, DODGENS, JOHN TROTTER AND WELLBORN SITES. THIS ROD ADDRESSES THE PRINCIPLE THREATS POSED BY CONTAMINATION ASSOCIATED WITH OPERABLE UNIT ONE. OPERABLE UNIT 2 CONSISTS OF THE TWELVE MILE CREEK BASIN AND LAKE HARTWELL. AN RI/FS USING FUND MONEY HAS BEEN INITIATED AT OPERABLE UNIT TWO AS OF SEPTEMBER 30, 1990. #SSC 5.0 SUMMARY OF SITE CHARACTERISTICS 5.1 BREAZEALE PROPERTY A TOTAL OF TWENTY-FIVE WELLS HAVE BEEN INSTALLED AT THE SITE. THE MOST 1 Order number 940620-103843-ROD -001-001 page 4253 set 4 with 100 of 100 items RECENT WELLS, BRMW-2A, 3B, 4A, 8B, 12A, 13, 14, 14A AND 15 WERE INSTALLED AS A PART OF THE RI FROM MAY TO JULY 1988. FIFTEEN WELLS ARE WATER TABLE MONITORING WELLS. TOTAL DEPTHS RANGE FROM 17 TO 40 FEET BELOW LAND SURFACE. ONE WELL WAS DRILLED TO AN INTERMEDIATE DEPTH IN THE SAPROLITE AND EIGHT WELLS WERE DRILLED TO THE TOP OF BEDROCK. DEPTH TO TOP OF BEDROCK AS DETERMINED BY AUGER REFUSAL RANGES FROM 17 FEET BELOW LAND SURFACE AT BRMW-13 TO 87 FEET BELOW LAND SURFACE AT BRMW-2A. TWO WELLS WERE DRILLED 20 FEET INTO BEDROCK. WELLS BRMW-1 TO 15 ARE WATER TABLE MONITORING WELLS. WELL BRMW-5A IS AN INTERMEDIATE DEPTH WELL WITHIN THE SAPROLITE. MONITORING WELLS BRMW-2A, 3A, 4A, 5B, 8A, 12A AND 14A ARE DEEPER WELLS SCREENED ON TOP OF BEDROCK. WATER TABLE WELL BRMW-13 ALSO EXTENDS TO BEDROCK. WELLS BRMW-3B AND BRMW-8B ARE SCREENED FIFTEEN TO TWENTY FEET BELOW TOP OF BEDROCK AND MONITOR BEDROCK GROUNDWATER QUALITY. A TOTAL OF THIRTY-ONE (31) SOIL BORINGS HAVE BEEN INSTALLED AT THE BREAZEALE PROPERTY. TWELVE OF THESE BORINGS PENETRATED WASTE MATERIAL AND WERE USED TO CHARACTERIZE THE WASTE AND DETERMINE ITS VERTICAL EXTENT. SEVENTEEN SOIL BORINGS WERE DRILLED ADJACENT TO THE AREA OF WASTE DEPOSITION TO VERIFY THE BOUNDARIES OF THE WASTE AND LATERAL EXTENT OF PCBS IN SUBSURFACE SOILS. MOST OF THE SITE IS UNDERLAIN BY RESIDUAL SOILS AND SAPROLITE. RESIDUAL SOILS FOUND AT LAND SURFACE CONSIST PRIMARILY OF SANDY AND CLAYEY SILTS, SILTY CLAYS AND MINOR SILTY SANDS APPROXIMATELY 7 TO 12 FEET THICK. THE UNDERLYING SAPROLITE CONSISTS OF SANDS WITH VARIOUS AMOUNTS OF SILT, CLAY AND MICA. THE SOUTH AND SOUTHWEST PORTIONS OF THE SITE BORDERING WOLF CREEK ARE UNDERLAIN BY ALLUVIAL DEPOSITS. THESE DEPOSITS CONSIST OF INTERBEDDED SANDY, SILTY CLAYS AND SILTY, CLAYEY SANDS. THE ALLUVIUM HAS A THICKNESS OF APPROXIMATELY 20 FEET AND IS UNDERLAIN BY SANDY SAPROLITE. GROUNDWATER FLOW DIRECTION IS SOUTH-SOUTHWESTWARD TOWARDS WOLF CREEK. THE HORIZONTAL GROUNDWATER GRADIENT FOR MOST OF THE SITE (INCLUDING THE AREA OF WASTE DEPOSITION) IS 0.05 FEET PER FOOT. IN THE SOUTH TO SOUTHEASTERN PORTION OF THE SITE (IN THE FLOOD PLAIN DEPOSITS) THE GRADIENT IS ABOUT 0.01 FEET PER FOOT. PRIOR TO THE INSTALLATION OF THE GEOTEXTILE LINER AND SOIL CAP (IN JULY AND AUGUST 1987) CAPACITOR DEBRIS WAS EXPOSED AT THE LAND SURFACE. WASTE (SOIL FILL WITH CAPACITOR DEBRIS) IS IN A TRENCH RANGING IN DEPTH FROM 2.5 FEET BELOW THE SOIL CAP AT BORING W-2 TO 11.5 FEET BELOW THE SOIL CAP AT W-10. THE AREA OF WASTE DEPOSITION IS 200 FEET LONG AND 50 FEET WIDE WITH AN AREA OF ABOUT 110 SQUARE YARDS. TOTAL WASTE VOLUME AT THE SITE IS ESTIMATED TO BE 2,500 CUBIC YARDS. TEN SURFACE WASTE SAMPLES WERE COLLECTED AT SITES WI THROUGH W-10 AND ANALYZED FOR PCBS. PCB CONCENTRATIONS RANGE FROM 1.93 PPM AT W-1 TO 1800 PPM IN THE DUPLICATE SAMPLE OF W-5. ANALYTICAL RESULTS FOR THE SURFACE WASTE IS PRESENTED IN TABLE 5-1. ONE WASTE SAMPLE EACH WAS COLLECTED FROM SOIL/WASTE BORINGS W-2 THROUGH 1 Order number 940620-103843-ROD -001-001 page 4254 set 4 with 100 of 100 items 10 (A TOTAL OF NINE SAMPLES) AND WERE ANALYZED FOR PCBS. ANALYTICAL RESULTS FOR WASTE SAMPLES ARE INCLUDED IN TABLE 5-1. SUBSURFACE PCB CONCENTRATIONS RANGED FROM 3.7 PPM, IN SAMPLE W-9 (5.5-7 FEET), TO 1010 PPM IN SAMPLE W-7 (4-5.5 FEET). SOIL/WASTE BORINGS W-11, 12 AND 13 WERE ADVANCED THROUGH THE WASTE INTO THE UNDERLYING SOILS. SPLIT SPOON SAMPLES WERE COLLECTED CONTINUOUSLY. WASTE SAMPLES COLLECTED FROM EACH BORING WERE COMBINED INTO A SINGLE COMPOSITE WASTE SAMPLE, WHICH WAS THEN ANALYZED FOR THE PRIORITY POLLUTANTS. ANALYTICAL RESULTS ARE INCLUDED IN TABLE 5-1. TRICHLOROETHENE AND TETRACHLOROETHENE WERE DETECTED AT 0.0039 PPM AND 0.0058 PPM, RESPECTIVELY. A LEACHING PROCEDURE (EP TOXICITY TEST) WAS PERFORMED ON THE COMPOSITE WASTE SAMPLE FROM W-11, 12, 13 AND THE EXTRACT BEING ANALYZED FOR PRIORITY POLLUTANT VOLATILE ORGANIC COMPOUNDS AND PCBS. THE ONLY PARAMETER DETECTED WAS PCB (AROCLOR 1248) WITH A CONCENTRATION OF 0.0311 PPM. SUBSURFACE SOILS WERE ANALYZED TO DETERMINE THE EXTENT OF PCBS AND OTHER CONSTITUENTS BELOW THE LAND SURFACE ADJACENT TO AND BELOW THE WASTE. SURFACE SOIL SAMPLES WERE COLLECTED AND ANALYZED TO DETERMINE THE EXTENT OF PCBS ON THE LAND SURFACE. FORTY-SIX SURFACE SOIL SAMPLES (BRSS-1 THROUGH 46) HAVE BEEN COLLECTED AT THE BREAZEALE SITE. ALL OF THE SAMPLES WERE ANALYZED FOR PCBS ONLY. TOTAL PCB CONCENTRATIONS ARE SUMMARIZED IN TABLE 5-2. TOTAL PCB CONCENTRATION RANGED FROM NONE DETECTED AT BRSS-5, 7, 12, 26, 42 AND 44 TO 8280 PPM AT BRSS-17. A TOTAL OF THIRTY-EIGHT SUBSURFACE SOIL SAMPLES HAVE BEEN COLLECTED AT THE BREAZEALE SITE. BACKGROUND SOIL SAMPLE W-14 (0-17 FEET) AND THE COMPOSITE SAMPLE OF W-11, 12, 13 COLLECTED BELOW THE WASTE WERE ANALYZED FOR PRIORITY POLLUTANTS. AN EP TOXICITY TEST WAS PERFORMED ON A DUPLICATE SAMPLE FOR W-11, 12, 13 AND ANALYZED FOR PRIORITY POLLUTANT VOCS AND PCBS. SAMPLE BRSB-23 (10-12 FEET) COLLECTED ADJACENT SAMPLES WERE ANALYZED FOR PCBS ONLY. ANALYTICAL RESULTS OF PCBS ARE PRESENTED IN TABLE 5-3. TOTAL PCBS DETECTED BELOW THE WASTE RANGED FROM NONE DETECTED IN SAMPLES W-4 (5.5-7 FEET) AND W-5 (7-8.5 FEET) TO 65 PPM DETECTED IN W-9 (10-11.5 FEET). TWENTY-FOUR SUBSURFACE SOIL SAMPLES WERE COLLECTED ADJACENT TO THE WASTE FROM BORINGS BRSB-15 THROUGH 26. AT LEAST TWO SAMPLES WERE COLLECTED FROM EACH BORING. TOTAL PCB CONCENTRATIONS DETECTED RANGED FROM 0.037 PPM IN BRSB-22 (3-4 FEET) TO 39 PPM DETECTED IN BRSB-24 (2-3 FEET). TOTAL PCB CONCENTRATIONS DECREASED WITH DEPTH IN EACH BORING, USUALLY TO BELOW DETECTION LIMITS. 1 Order number 940620-103843-ROD -001-001 page 4255 set 4 with 100 of 100 items TETRACHLOROETHENE WAS FOUND IN A CONCENTRATION OF 0.0029 PPM IN THE SOIL COMPOSITE FROM BORINGS W-11, 12 AND 13, COLLECTED DIRECTLY BELOW THE WASTE. NO VOCS WERE DETECTED IN THE EP TOXICITY TEST FOR W-11, 12, 13. CONCENTRATIONS OF THE SEMI-VOLATILE ORGANIC, DI-N-BUTYL PHTHALATE, WERE DETECTED IN THE SOIL COMPOSITE OF BORINGS W-11 (12-22.5 FEET), 12 (3.5-20 FEET), 13 (12-18 FEET) AND THE SAMPLE FROM BORING W-14 (TABLE 5-4). BORING W-14 SERVES AS A SOURCE FOR BACKGROUND INFORMATION AS IT WAS INSTALLED OUTSIDE AND UPGRADIENT OF THE AREA OF WASTE DEPOSITION. SEVENTEEN INORGANIC COMPOUNDS WERE DETECTED IN SUBSURFACE SOILS. PCBS WERE NOT DETECTED IN ANY OF THE WELLS. TETRACHLOROETHENE, TRICHLOROETHENE AND TOTAL 1,2-DICHLOROETHENE (INCLUDING TRANS 1,2-DICHLOROETHENE) WERE THE PRIMARY VOLATILE ORGANIC COMPOUNDS DETECTED. VOCS ARE MIGRATING EASTWARD TOWARD WELL BRMW-2 AND THEN SOUTHWEST TOWARD WOLF CREEK. OF THE SEVEN WELL NESTS INSTALLED AT THE BREAZEALE SITE, FOUR (BRMW-2/2A, BRMW-3/3A, BRMW-4/4A, BRMW-5/5A/5B) DISPLAY A DECREASE IN VOC CONCENTRATIONS WITH DEPTH. THE PREDOMINANT TREND IS TO HAVE HIGHER VOC CONCENTRATIONS NEAR THE WATER TABLE SURFACE AND MUCH LOWER VOC CONCENTRATIONS IN THE DEEPER SAPROLITE AND BEDROCK; INDICATING THAT VOCS WITHIN THE GROUNDWATER ARE MIGRATING PRIMARILY HORIZONTALLY TOWARD WOLF CREEK. SEMI-VOLATILE AND PESTICIDE ORGANIC COMPOUNDS WERE NOT DETECTED IN THE THREE WELLS (BRMW-3, 5 AND 11) THAT WERE ANALYZED FOR THESE PARAMETERS. ANALYTICAL RESULTS SUMMARIZING INORGANIC COMPOUNDS DETECTED IN BRMW-3, 5 AND 11 ARE IN TABLE 5-5. WELL BRMW-3 WAS ANALYZED FOR INORGANIC COMPOUNDS. ONLY CADMIUM AND NICKEL WERE FOUND IN WELL BBMW-3. NINE METALS WERE DETECTED IN THE NONFILTERED SAMPLE FOR BRMW-5. ONLY FIVE METALS (MAGNESIUM, MANGANESE, POTASSIUM, ZINC AND SODIUM) WERE IN THE FILTERED-SAMPLE FROM BBMW-5. EIGHT METALS WERE DETECTED IN THE NONFILTERED SAMPLE FOR BRMW-11. ONLY FOUR METALS (MAGNESIUM, MANGANESE, POTASSIUM AND ZINC) WERE DETECTED IN THE FILTERED SAMPLE FROM BRMW-11. STREAM SEDIMENT SAMPLES WERE COLLECTED JULY 30, 1986 FROM TWO LOCATIONS (BRSD-1 AND 2) IN THE DITCH DRAINING THE EAST END OF THE SITE AND FROM THREE LOCATIONS (BRSD-3, 4 AND 5) LOCATED ON WOLF CREEK. SAMPLE SITE BRSD-3 IS LOCATED ON WOLF CREEK UPGRADIENT OF THE DRAINAGE DITCH AND THE SITE. BRSD-4 WAS COLLECTED FROM WOLF CREEK ADJACENT TO THE SITE AND BRSD-5 WAS COLLECTED FROM WOLF CREEK DOWNGRADIENT OF THE SITE. PCB ANALYTICAL RESULTS ARE PRESENTED IN TABLE 5-6. PCBS WERE DETECTED IN SAMPLES BRSD-1 AND 2 AT TOTAL CONCENTRATIONS OF 0.32 PPM AND 1.8 PPM, RESPECTIVELY. NO PCBS WERE DETECTED IN SEDIMENT SAMPLES COLLECTED FROM WOLF CREEK. SEVERAL SURFACE WATER SAMPLES HAVE BEEN COLLECTED FROM THE DRAINAGE DITCH AND WOLF CREEK AT THE SAME LOCATIONS AS STREAM SEDIMENT SAMPLES. A SUMMARY OF DETECTED PARAMETERS IS PRESENTED IN TABLE 5-7. VOCS HAVE NOT BEEN DETECTED IN SAMPLES BRSW-1 AND 2. ONLY SMALL CONCENTRATIONS OF VOCS HAVE BEEN DETECTED IN SAMPLES COLLECTED FROM BRSW-3, 4 AND 5. 1 Order number 940620-103843-ROD -001-001 page 4256 set 4 with 100 of 100 items 5.2 NIX SITE A REMOVAL OF WASTE WAS CONDUCTED IN 1980. SOIL BORINGS WERE DRILLED TO DETERMINE THE HORIZONTAL AND VERTICAL EXTENT OF ANY REMAINING WASTE. NINE SOIL BORINGS WERE DRILLED AT LOCATIONS ON THE SITE. DEPTHS OF SOIL BORINGS RANGED FROM 3.7 TO 7.0 FEET BELOW LAND SURFACE. SOILS UNDERLYING THE NIX SITE ARE RESIDUAL IN NATURE AND CONSIST OF FINE TO COARSE GRAINED SILTY SAND AND CLAYEY SAND WITH ZONES OF SANDY SILT AND CLAYEY SILT. DURING FIELD ACTIVITIES FOR THE REMEDIAL INVESTIGATION, AN AREA CONTAINING WASTE WAS IDENTIFIED ON THE SOUTH BANK OF THE RAVINE NEAR THE WEST END. THE WASTE AT THIS LOCATION INCLUDES FOIL-WRAPPED CAPACITORS, CAPACITOR PAPER AND FOIL FRAGMENTS. THIS WASTE COVERS A SURFACE AREA OF ABOUT 50 SQUARE YARDS. TOTAL VOLUME OF THIS WASTE DEPOSIT IS APPROXIMATELY 20 CUBIC YARDS. DOMESTIC WASTE (FURNITURE PARTS AND OLD ROOFING SHINGLES) IS ALSO DISPOSED IN SEPARATE AREAS OF THE RAVINE. CAPACITOR WASTE, INCLUDING FOIL-WRAPPED CAPACITORS, CAPACITOR PAPER AND FOIL FRAGMENTS, IS SCATTERED ON THE GROUND SURFACE WITHIN THE RAVINE AND ON THE LAND SURFACE 100 FEET TO EITHER SIDE OF THE RAVINE. A SAMPLE OF WASTE WAS TAKEN FROM SOIL BORING NXSB-4, 0.7 TO 0.8 FEET BELOW LAND SURFACE. BECAUSE OF THE LIMITED VOLUME OF SAMPLE AT THIS SITE, SAMPLE NXSB-4 (0.7-0.8) WAS ANALYZED FOR VOCS ONLY. SAMPLE NXSS 22 WAS COLLECTED FROM WASTE PILED AT THE EAST SIDE OF THE RAVINE AND ANALYZED FOR THE HSL PARAMETERS. ANALYTICAL RESULTS FOR WASTE ARE PRESENTED ON TABLE 5-8. THE ONLY VOC DETECTED IN SAMPLE NXSB-4 (0.7-0.8) WAS METHYLENE CHLORIDE AT 0.008 PPM. SAMPLE NXSS-22 ALSO CONTAINED METHYLENE CHLORIDE AT 0.008 PPM. NO SEMI-VOLATILE OR PESTICIDE COMPOUNDS WERE DETECTED. PCBS WERE DETECTED IN THE WASTE SAMPLE NXSS-22 AT A CONCENTRATION OF 13 PPM (AROCLOR 1254). SEVENTEEN OF THE HSL INORGANIC COMPOUNDS WERE DETECTED IN THE WASTE SAMPLE NXSS-22. SURFACE SOIL SAMPLES WERE COLLECTED AND ANALYZED TO DETERMINE THE EXTENT OF PCBS ON THE LAND SURFACE. TWENTY-ONE SURFACE SOIL SAMPLES (NXSS-1 THROUGH NXSS-21) WERE COLLECTED. NXSS-22 WAS AN HSL SAMPLE OF THE WASTE IN THE RAVINE AND IS NOT SURFACE SOIL. SAMPLES NXSS-1 TO 21 WERE ANALYZED FOR PCBS ONLY. ANALYTICAL RESULTS ARE PRESENTED ON TABLE 5-9. PCBS WERE NOT DETECTED IN SIX SAMPLES. TOTAL DETECTED PCB CONCENTRATIONS RANGED FROM 0.130 PPM AT NXSS-2 TO 66 PPM AT NXSS-13. SUBSURFACE SOILS WERE ANALYZED TO DETERMINE THE EXTENT OF PCBS AND OTHER CONSTITUENTS BELOW THE LAND SURF ACE AND BELOW WASTE. TEN SUBSURFACE SOIL SAMPLES WERE COLLECTED DURING THE REMEDIAL INVESTIGATION 1 Order number 940620-103843-ROD -001-001 page 4257 set 4 with 100 of 100 items ACTIVITIES. ONE OF THESE SAMPLES WAS A COMPOSITE COLLECTED FROM BERINGS NXSB-4, 4A AND 4B AND ANALYZED FOR THE HSL PARAMETERS, EXCEPT VOCS, WHICH WERE TAKEN FROM NXSB-4. THE NINE REMAINING SAMPLES WERE ANALYZED FOR PCBS ONLY. TABLE 5-10 PRESENTS RESULTS FOR PCB ANALYSIS OF SUBSURFACE SOILS. TABLE 5-11 PRESENTS THESE HSL PARAMETERS DETECTED IN COMPOSITE SAMPLE NXSB-4, 4A, 4B COLLECTED BELOW THE WASTE. THE COMPOUND STYRENE WAS DETECTED IN SOIL SAMPLE NXSB-4, 4A, 4B AT 0.009 PPM. FOURTEEN INORGANIC COMPOUNDS WERE DETECTED IN COMPOSITE SAMPLE NXSB-4, 4A, 4B AND ARE INCLUDED IN TABLE 5-11. FOUR MONITORING WELLS (NXMW-1, 2, 3 AND 4) WERE INSTALLED AT THE NIX SITE. WELLS NXMW-2 AND NXMW-3 WERE INSTALLED IN THE SAPROLITE ABOVE BEDROCK. WELLS NXMW-1 AND NXMW-4 WERE INSTALLED INTO BEDROCK. WELLS NXMW-1, 2 AND 3 ARE WATER TABLE WELLS. NXMW-1 IS LOCATED UPGRADIENT OF THE SITE AND PROVIDES BACKGROUND GROUNDWATER QUALITY DATA. THE WATER TABLE AT WELL NXMW-1 OCCURS IN BEDROCK. LOCATIONS FOR NXMW-2 AND 3 WERE SELECTED TO MONITOR GROUNDWATER QUALITY ON EITHER SIDE OF THE RAVINE, DOWNGRADIENT OF PAST WASTE DISPOSAL AREAS AND PRESENT SCATTERED WASTE. IN THE AREA OF WELL NXMW-4, THE WATER TABLE IS WITHIN TWO FEET OF THE GROUND SURFACE AND THE TOP OF BEDROCK IS ONLY THREE TO FOUR FEET BELOW LAND SURFACE. FOR THIS REASON, A WATER TABLE WELL COULD NOT BE INSTALLED. THEREFORE, WELL NXMW-4 WAS INSTALLED INTO ROCK AND MONITORS BEDROCK WATER CONDITIONS DIRECTLY DOWNGRADIENT OF THE RAVINE. GROUNDWATER SAMPLES WERE COLLECTED FROM MONITORING WELLS NXMW-1,2,3 AND 4 ON SEPTEMBER 8 AND 9, 1988 AND DECEMBER 6, 1988. FIRST ROUND SAMPLES WERE ANALYZED FOR PCBS, VOCS, PH, SPECIFIC CONDUCTANCE, SUSPENDED SOLIDS, ALKALINITY, HARDNESS, CHLORIDES, AND SULFATE. WELL NXMW-3 WAS ALSO ANALYZED FOR ALL OF THE HSL PARAMETERS. BOTH FILTERED AND NON-FILTERED SAMPLES WERE COLLECTED FOR INORGANIC ANALYSIS. SECOND ROUND SAMPLES WERE ANALYZED FOR PCBS, PH, SPECIFIC CONDUCTANCE, SUSPENDED SOLIDS, ALKALINITY, HARDNESS, CHLORIDES AND SULFATE. TABLE 5-12 SUMMARIZES RESULTS FOR DETECTED PARAMETERS. PCBS WERE NOT DETECTED IN ANY OF THE WELLS DURING BOTH SAMPLING ROUNDS. VOLATILE ORGANIC COMPOUNDS WERE DETECTED IN THE FIRST ROUND GROUNDWATER SAMPLE FOR WELL NXMW-4. SEMI-VOLATILE AND PESTICIDE ORGANIC COMPOUNDS WERE NOT DETECTED IN THE HSL ANALYSIS OF WELL NXMW-3. SAMPLES WERE OBTAINED FROM WELL NXMW-3 FOR INORGANIC ANALYSIS. TEN INORGANIC COMPOUNDS WERE DETECTED IN THE SAMPLE. STREAM SEDIMENT SAMPLES WERE COLLECTED FROM 12 LOCATIONS. SEDIMENT SAMPLE LOCATION NXSD-1 WAS CHOSEN TO DETERMINE PCB CONCENTRATIONS IN SEDIMENTS IN THE EASTERN PORTION OF THE RAVINE. SAMPLE LOCATION NXSD-2 IS LOCATED ADJACENT TO THE AREA OF WASTE DEPOSITION NEAR THE WESTERN END OF THE RAVINE AND PROVIDES PCB CONCENTRATIONS IN SEDIMENTS IN THE DOWNGRADIENT AREA OF THE RAVINE. NXSD-3 AND 4 ARE LOCATED IN THE MARSH 1 Order number 940620-103843-ROD -001-001 page 4258 set 4 with 100 of 100 items IMMEDIATELY DOWNGRADIENT OF THE RAVINE. SEDIMENT SAMPLING LOCATIONS NXSD-4,6,7 AND 8 ARE LOCATED IN VARIOUS AREAS OF THE POND. SAMPLING LOCATIONS FOR NXSB-9 AND 10 ARE LOCATED IN TWO OUTFALL STREAMS DOWNGRADIENT OF THE POND. NXSB-11 IS LOCATED IN THE UNNAMED TRIBUTARY TO WOLF CREEK UPGRADIENT OF THE SITE. THE SAMPLING LOCATION FOR NXSD-12 IS LOCATED ON THE UNNAMED TRIBUTARY TO WOLF CREEK DOWNGRADIENT OF THE SITE. THESE SAMPLES WERE ANALYZED FOR PCBS TO DETERMINE THE PRESENCE AND EXTENT OF PCB MIGRATION ALONG SURFACE DRAINAGE ROUTES. ANALYTICAL RESULTS ARE PRESENTED ON TABLE 5-13. PCBS WERE NOT DETECTED IN SEDIMENT SAMPLE NXSD-1 LOCATED IN THE UPGRADIENT PORTION OF THE RAVINE. TOTAL PCB CONCENTRATION AT NXSD-2 WAS 3.9 PPM. SEDIMENT SAMPLES NXSD-3 AND 4, HAD TOTAL PCB CONCENTRATIONS OF 1.74 AND 1.62 PPM, RESPECTIVELY. PCB CONCENTRATIONS IN THE SEDIMENT SAMPLES NXSD-5, 6, 7 AND 8 RANGED FROM 0.79 PPM AT NXSD-8 TO 1.56 PPM AT NXSD-8. OF THE TWO SEDIMENT SAMPLES TAKEN FROM THE POND OUTFALL STREAMS (NXSD-9 AND NXSD-10), PCBS WERE ONLY DETECTED IN NXSD-9 AT 0.65 PPM. THERE WERE NO PCBS DETECTED AT NXSD-11 AND NXSW-12 LOCATED ON THE UNNAMED TRIBUTARY TO WOLF CREEK LOCATED UP AND DOWNGRADIENT RESPECTIVELY AT THE NIX SITE. ONE ROUND OF SURFACE WATER SAMPLES WAS COLLECTED AT SAMPLES SITES NXSW-2,4,6,9 10,11 AND 12. A SURFACE WATER SAMPLE FROM THE SEDIMENT SAMPLE LOCATION NXSD-1 WAS PROPOSED IN THE RI WORK PLAN. HOWEVER, THERE WAS NO WATER AT NXSD-1 AT THE TIME OF SAMPLING AND A SURFACE WATER SAMPLE COULD NOT BE OBTAINED. SURFACE WATER SAMPLES WERE ANALYZED FOR PCBS, PH AND SPECIFIC CONDUCTANCE. PCBS WERE NOT DETECTED IN ANY OF THE SURFACE WATER SAMPLES. 5.3 DODGENS SITE TWENTY-FOUR SOIL BORINGS WERE DRILLED IN LOCATIONS ON THE DODGENS SITE. SOILS UNDERLYING THE DODGENS SITE CONSIST OF SILTY SANDS, SILTY CLAYS AND CLAYEY SILTS. THIN LAYERS OF CAPACITOR DEBRIS (CAPACITOR PAPER, FOIL) WERE PRESENT IN SOME BORINGS AT SHALLOW DEPTHS (LESS THAN THREE FEET BELOW LAND SURFACE). SOIL BORINGS AND EXPLORATORY BORINGS WERE DRILLED AS PART OF THE REMEDIAL INVESTIGATION TO CONFIRM ACTUAL WASTE PRESENCE AND DETERMINE HORIZONTAL AND VERTICAL EXTENT OF THE AREA OF WASTE DEPOSITION. WASTE SAMPLES WERE ANALYZED TO CHARACTERIZE THE WASTE AND IDENTIFY THE CONSTITUENTS TO BE ADDRESSED FURTHER. WASTE WAS PENETRATED BY BORINGS DGSB-1, 3, 3C, 4A, 4C, SC AND 6. FOLLOWING INSTALLATION OF THE SOIL BORINGS, FIFTY-THREE EXPLORATORY BORINGS WERE DRILLED TO FURTHER DEFINE THE AREA OF WASTE DEPOSITION. WASTE, IN THE FORM OF CAPACITOR DEBRIS (FOIL, PAPER AND MICA PLATES), IS PRESENT IN SIX AREAS THROUGHOUT THE DODGENS SITE. THE SMALLEST AREA, LOCATED AT THE SOUTH END OF THE SITE HAS AN APPROXIMATE AREA OF 20 SQUARE YARDS. THE LARGEST AREA, LOCATED AT THE NORTHEAST END OF THE SITE, HAS AN APPROXIMATE AREA OF 395 CUBIC YARDS. 1 Order number 940620-103843-ROD -001-001 page 4259 set 4 with 100 of 100 items WASTE THICKNESS RANGES FROM TRACES ( LT 0.1 FOOT) AT BORINGS DGEB-21, 26, 38 AND 49 TO 1.0 FEET AT DGEB-50. TOTAL WASTE VOLUME AT THE SITE IS ESTIMATED TO BE APPROXIMATELY 100 CUBIC YARDS. A SAMPLE OF WASTE COLLECTED FROM SOIL BORING DGSB-4C AT 0.5 TO 2.0 FEET BELOW LAND SURFACE DESIGNATED DGSB-4C (0.5-2.0 FEET) AND A COMPOSITE SAMPLE OF WASTE COLLECTED FROM SOIL BORINGS 1, 3C AND 6 DESIGNATED DGSB-1, 3C, 6 WERE ANALYZED FOR THE HSL PARAMETERS (VOC SAMPLES FOR WASTE COLLECTED FROM BORINGS DGSB-1, 3C AND 6 WERE ANALYZED SEPARATELY AND NOT COMPOSITED). ANALYTICAL RESULTS FOR WASTE ARE PRESENTED IN TABLE 5-14 AND THE UPGRADIENT SURFACE SOIL SAMPLE DGSS-1 RESULTS ARE PRESENTED IN TABLE 5-15. FOURTEEN SEMI-VOLATILE COMPOUNDS WERE DETECTED IN THE COMPOSITE WASTE SAMPLE DGSB-1, 3C, 6. PCBS WERE DETECTED IN WASTE SAMPLE DGSB-1, 3C, 6 AND DGSB-4C (0.5-2-2.0 FEET). TOTAL PCBS DETECTED IN COMPOSITE WASTE SAMPLE DGSB-1, 3C, 6 WAS 470 PPM. TOTAL PCBS FOUND IN WASTE SAMPLE DGSB-4C (0.5-2.0 FEET) WAS 30 PPM. THE INORGANIC, CADMIUM, COPPER, IRON, LEAD, MANGANESE, MERCURY, SILVER, VANADIUM AND ZINC WERE FOUND IN THE WASTE. SUBSURFACE SOILS WERE ANALYZED TO DETERMINE THE EXTENT OF PCBS AND OTHER CONSTITUENTS BELOW THE LAND SURFACE AND BELOW THE WASTE. SURFACE SOIL SAMPLES WERE COLLECTED AND ANALYZED TO DETERMINE THE EXTENT OF PCBS ON THE LAND SURFACE. SURFACE SOIL-SAMPLES (DGSS-1 THROUGH DGSS-19) WERE COLLECTED AT VARIOUS LOCATIONS ON THE SITE. DGSS-1 WAS ANALYZED TO DETERMINE THE EXTENT OF PCBS AND OTHER CONSTITUENTS BELOW THE LAND SURFACE AND BELOW THE WASTE. SURFACE SOIL SAMPLES WERE COLLECTED AND ANALYZED TO DETERMINE THE EXTENT OF PCBS ON THE LAND SURFACE. DGSS-1 WAS ANALYZED FOR THE HSL PARAMETERS. ANALYTICAL RESULTS ARE PRESENTED ON TABLE 5-15. SAMPLES DGSS-2 THROUGH DGSS-18 WERE ANALYZED FOR PCBS ONLY. TOTAL PCB CONCENTRATIONS ARE SUMMARIZED IN TABLE 5-16. TOTAL PCB CONCENTRATIONS RANGED FROM 0.2 PPM AT DGSS-8 TO 270 PPM AT DGSS-19. IN ADDITION TO PCBS, UPGRADIENT SURFACE SOIL SAMPLE DGSS-1 HAD SEVERAL INORGANIC COMPOUNDS DETECTED. IN ADDITION TO COMPOSITE WASTE SAMPLE DGSB-11 3C, 6 AND WASTE SAMPLE DGSB-4 (0.5-2.0 FEET), TWENTY-FOUR SUBSURFACE SOIL SAMPLES WERE ANALYZED. ONE SAMPLE DGSB-3C (6-10 FEET) WAS ANALYZED FOR THE HSL PARAMETERS. THE REMAINING TWENTY-FOUR SUBSURFACE SOIL SAMPLES WERE ANALYZED. ONE SAMPLE DGSB-3C (6-10 FEET) WAS ANALYZED FOR THE HSL PARAMETERS. THE REMAINING TWENTY-FIVE SAMPLES WERE ANALYZED FOR PCBS ONLY. ANALYTICAL RESULTS OF PCBS ARE PRESENTED IN TABLE 5-17. ADDITIONAL PARAMETERS DETECTED IN THE HSL ANALYSIS OF SAMPLE DGSB-3C (6-10 FEET) ARE PRESENTED IN TABLE 5-18. THE INORGANIC COMPOUNDS MAGNESIUM AND SILVER, WERE DETECTED IN DGSB-3C (6-10 FEET). TOTAL PCBS 1 Order number 940620-103843-ROD -001-001 page 4260 set 4 with 100 of 100 items DETECTED IN THE WASTE WERE 30 PPM IN DGSB-4C (0.5-2.0 FEET) AND 470 PPM IN THE COMPOSITE WASTE SAMPLE DGSB-1, 3C AND 6. THE HIGHEST CONCENTRATION OF PCBS, 2700 PPM, WAS DETECTED IN BORING DGSB-5 AT THE DEPTH INTERVAL 4-6 FEET BELOW LAND SURFACE. BORING DGSB-5C LOCATED WEST OF DGSB-5 HAD A CONCENTRATION OF 150 PPM IN THE SAMPLE COLLECTED 4 TO 6 FEET BELOW LAND SURFACE. SOIL SAMPLES COLLECTED FROM BORINGS DGSB-3C (3.0-4.5 FEET) AND DGSB-5A (4-6 FEET) HAD TOTAL PCB CONCENTRATION OF 53.7 PPM AND 55 PPM RESPECTIVELY. THE TOTAL PCB CONCENTRATION IN THE SOIL SAMPLE COLLECTED FROM DGSB-3C AT 6 TO 10 FEET BELOW LAND SURFACE WAS 0.4 PPM. THE REMAINING TWENTY-ONE SOIL SAMPLES HAD PCB CONCENTRATIONS RANGING FROM NONDETECTED IN FIVE SAMPLES TO 22 PPM DETECTED IN A SAMPLE COLLECTED FROM BORING DGSB-1 (3.5-5.0 FEET). MULTIPLE SAMPLES (2 OR 3) OF SOIL AND WASTE WERE OBTAINED FROM EACH OF FIVE SOIL BORINGS, DGSB-1, 3C, 4C, SC AND 6. SAMPLES COLLECTED FROM BORING DGSB-4C HAD DECREASING PCB CONCENTRATIONS WITH DEPTH. WASTE COLLECTED AT 0.5 TO 2 FEET BELOW LAND SURFACE (COMPOSITED WITH WASTE COLLECTED FROM BORINGS DGSB-1 AND 6) HAD A TOTAL PCB CONCENTRATION OF 30 PPM. NO PCBS WERE DETECTED IN THE SOIL SAMPLE COLLECTED BELOW THE WASTE AT 3.0 TO 4.5 FEET BELOW LAND SURFACE, AND 0.082 PPM TOTAL PCBS WERE DETECTED IN THE SOIL SAMPLE COLLECTED AT 5.5 TO 7.0 FEET BELOW LAND SURFACE. THE REMAINING FOUR BORE HOLES ALSO EXHIBITED DECREASES IN TOTAL PCB CONCENTRATIONS WITH DEPTH. FIVE MONITORING WELLS WERE INSTALLED AT THE DODGENS SITE. FOUR WELLS (DGMW-1 THROUGH 4), ARE WATER TABLE MONITORING WELLS. WELL DGMW-3A IS A DEEPER WELL AND FORMS A WELL PAIR WITH DGMW-3. THE DODGENS SITE IS SITUATED ON FLOOD PLAIN DEPOSITS OF MIDDLE FORK TWELVE-MILE CREEK. THESE DEPOSITS EXTEND FROM LAND SURFACE TO DEPTHS RANGING FROM NINE FEET BELOW LAND SURFACE AT WELL DGMW-4 TO 18 FEET BELOW LAND SURFACE OF WELL DGMW-3A. WELLS DGMW-1, 2, 3, AND 4 ARE WATER TABLE MONITORING WELLS. DGMW-1 IS LOCATED UPGRADIENT OF THE SITE AND PROVIDES BACKGROUND GROUNDWATER QUALITY DATA. WELLS DGMW-2, 3 AND 4 MONITOR GROUNDWATER IMMEDIATELY DOWNGRADIENT OF THE AREAS OF PAST AND PRESENT WASTE DEPOSITION. WELL DGMW-3A IS A DEEPER WELL SCREENED ON TOP OF BEDROCK AND IS LOCATED ADJACENT TO WELL DGMW-3. WELL DGMW-3A MONITORS DEEPER GROUNDWATER OF THE AREA OF WASTE DEPOSITION. THE WATER TABLE RANGES FROM FIVE TO SEVEN FEET BELOW LAND SURFACE. FIRST ROUND SAMPLES WERE ANALYZED FOR PCBS, VOCS, PH, SPECIFIC CONDUCTANCE, SUSPENDED SOLIDS, ALKALINITY, HARDNESS, CHLORIDES AND SULFATE. BECAUSE SEVERAL SEMI-VOLATILE COMPOUNDS WERE DETECTED IN THE HSL ANALYSIS OF COMPOSITE WASTE SAMPLE DGSB-1, 3C, 6, FIRST ROUND GROUNDWATER SAMPLES WERE ALSO ANALYZED FOR SEMI-VOLATILE COMPOUNDS. WELL DGMW-3 WAS ALSO ANALYZED FOR ALL OF THE HSL PARAMETERS DURING THE 1 Order number 940620-103843-ROD -001-001 page 4261 set 4 with 100 of 100 items FIRST ROUND SAMPLING. BOTH FILTERED AND NON-FILTERED SAMPLES WERE COLLECTED FOR INORGANIC ANALYSIS. TABLE 5-19 SUMMARIZES ANALYTICAL RESULTS FOR DETECTED PARAMETERS. NO VOLATILE ORGANIC COMPOUNDS (VOCS) WERE DETECTED IN GROUNDWATER DURING THE FIRST SAMPLING ROUND IN AUGUST 1988; HOWEVER, VOCS WERE DETECTED IN GROUNDWATER COLLECTED FROM WELLS DGMW-2, 3 AND 4 IN THE SECOND ROUND. TRICHLOROETHENE WAS DETECTED IN WELLS DGMW-2 AND 3 AT CONCENTRATION OF 0.012 PPM AND 0.019 PPM, RESPECTIVELY. TETRACHLOROETHENE WAS DETECTED IN GROUNDWATER COLLECTED FROM WELLS DGMW-2, 3 AND 4 AT CONCENTRATIONS OF 0.005 PPM, 0.005 PPM AND 0.006 PPM, RESPECTIVELY. DURING THE FIRST SAMPLING ROUND, ALL FIVE WELLS WERE ANALYZED FOR THE SEMI-VOLATILE COMPOUNDS. BIS(2-ETHYLHEXYL)-PHTHALATE WAS DETECTED IN WELLS DGMW-1, 3 AND 3A AT CONCENTRATIONS OF 0.011 PPM, 0.012 PPM, AND 0.013 PPM, RESPECTIVELY: DI-N-OCTYLPHTHALATE WAS DETECTED IN THE GROUNDWATER SAMPLE COLLECTED FROM WELL DGMW-3A AT A CONCENTRATION OF 0.012 PPM. DURING THE FIRST SAMPLING ROUND, SAMPLES WERE OBTAINED FROM DOWNGRADIENT WELL DGMW-3 FOR INORGANIC ANALYSIS. TWELVE INORGANIC COMPOUNDS WERE DETECTED IN THE SAMPLE. STREAM SEDIMENT SAMPLES WERE COLLECTED FROM SIX LOCATIONS ON MIDDLE FORD TWELVE-MILE CREEK AND ITS TRIBUTARIES. SAMPLES WERE ANALYZED FOR PCBS. SEDIMENT SAMPLING ANALYTICAL RESULTS ARE PRESENTED IN TABLE 5-20. SAMPLING SITE DGSD-1 IS LOCATED ON MIDDLE FORK TWELVE-MILE CREEK UPSTREAM OF THE DODGENS SITE AND PROVIDES BACKGROUND STREAM SEDIMENT QUALITY. SAMPLE SITE DGSD-2 IS LOCATED ON MIDDLE FORK TWELVE-MILE CREEK ADJACENT TO THE SOUTHEAST CORNER OF THE SITE AND UPGRADIENT TO THE UNNAMED TRIBUTARY BORDERING THE SITE TO THE SOUTH. THIS SAMPLE WAS COLLECTED TO DETERMINE PCB CONCENTRATIONS DOWNGRADIENT OF THE SITE, BUT UPGRADIENT OF THE UNNAMED TRIBUTARY. SAMPLE SITE DGSD-3 IS LOCATED ON THE UNNAMED TRIBUTARY UPSTREAM OF THE POND OUTFALL. SAMPLE SITE DGSD-4 IS LOCATED ON THE UNNAMED TRIBUTARY DOWNSTREAM IN THE SEDIMENT AS A RESULT OF THE POND DISCHARGE. SAMPLE SITE DGSD-5 IS LOCATED ON MIDDLE FORK TWELVE-MILE CREEK DOWNSTREAM OF THE UNNAMED TRIBUTARY AND WAS SAMPLED TO DETERMINE IF PCBS ARE PRESENT DOWNGRADIENT OF ALL SITE DRAINAGE. SEDIMENT SAMPLE SITE DGSD-6 IS LOCATED ON THE POND LOCATED NEAR THE SOUTH END OF THE SITE. NO PCBS WERE DETECTED IN UPSTREAM SEDIMENT SAMPLE DGSD-1. TOTAL PCB CONCENTRATIONS OF 1.0 PPM AND 0.36 PPM (DUPLICATE) WERE DETECTED IN SEDIMENT SAMPLE DGSD-2. THIS SAMPLE SITE IS LOCATED AT A POINT WHERE SURFACE WATER RUNOFF FROM THE SITE DISCHARGES INTO MIDDLE FORK TWELVE-MILE CREEK. NO PCBS WERE DETECTED IN SAMPLE DGSD-5 LOCATED FURTHER DOWNSTREAM. NO PCBS WERE DETECTED AT DGSD-3 AND DGSD-4 LOCATED ON THE UNNAMED TRIBUTARY. A TOTAL PCB CONCENTRATION OF 2.31 PPM WAS DETECTED IN SEDIMENTS IN THE POND (DGSD-6). ONE ROUND OF SURFACE WATER SAMPLES WERE COLLECTED AT SAMPLE SITES DGSW-1 THROUGH 6. THESE SAMPLE POINTS CORRESPOND WITH SEDIMENT SAMPLE POINTS DGSD-1 THROUGH 6. SAMPLES WERE ANALYZED FOR PCBS AND SEMI-VOLATILE 1 Order number 940620-103843-ROD -001-001 page 4262 set 4 with 100 of 100 items COMPOUNDS PH AND SPECIFIC CONDUCTANCE. ARE PRESENTED IN TABLE 5-21. A SUMMARY OF DETECTED PARAMETERS NO PCBS WERE DETECTED IN ANY OF THE SURFACE WATER SAMPLES. NO SEMI-VOLATILE COMPOUNDS WERE DETECTED IN UPGRADIENT SURFACE WATER SAMPLE DGSW-1 AND SAMPLE DGSW-6 COLLECTED FROM THE POND. THE SEMI-VOLATILE COMPOUND BIS (2-ETHYLHEXYL) PHTHALATE WAS DETECTED IN DGSW-2, DGSW-3, DGSW-4, DGSW-5 AND THE DUPLICATE SAMPLE FOR DGSW-6. 5.4 CROSS ROADS SITE SOILS AT THE CROSS ROADS SITE WERE CHARACTERIZED THROUGH EXAMINATION OF SOIL SAMPLES COLLECTED FROM MONITORING WELL BORINGS AND SOIL BORINGS. EIGHTEEN SOIL BORINGS WERE DRILLED TO DETERMINE THE VERTICAL EXTENT OF THE WASTE, TO CHARACTERIZE THE WASTE AND TO DETERMINE THE PRESENCE OF WASTE CONSTITUENTS IN UNDERLYING SOILS. SOILS UNDERLYING THE CROSS ROADS SITE CONSIST OF SILTY SANDS AND SANDY SILTS WITH VARYING AMOUNTS OF CLAY. WASTE, IN THE FORM OF CAPACITORS AND CAPACITOR DEBRIS (PAPER, FOIL, AND MICA PLATES) WERE PENETRATED BY BORING CRSB-3, 4, 5, 7B AND 7C. FOLLOWING THE INSTALLATION OF THE SOIL BORINGS, EIGHTEEN EXPLORATORY BORINGS WERE DRILLED TO FURTHER DETERMINE THE HORIZONTAL AND VERTICAL EXTENT OF THE AREA OF WASTE DEPOSITION. WASTE, IN THE FORM OF CAPACITORS AND CAPACITOR DEBRIS, IS PRESENT IN AN AREA NEAR THE SOUTHERN BORDER OF THE SITE. THIS AREA HAS AN APPROXIMATE AREA OF 1700 SQUARE YARDS. THE NORTHERN EXTENT OF THE WASTE WAS NOT DETERMINED IN THE VICINITY OF EXPLORATORY BORING CREB-18. NORTH OF BORING CREB-18 IS HEAVILY WOODED AND PREVENTED MOVEMENT OF THE DRILL RIG. AS SHOWN ON TABLES 5-22 AND 5-23, WASTE THICKNESS RANGED FROM APPROXIMATELY 0.1 FOOT AT BORINGS CREB-2 AND 18 TO 2.6 FEET AT CRSB-7C. DEPTH TO THE TOP OF WASTE RANGED FROM 0.2 TO 1.8 FEET BELOW LAND SURFACE. THE HORIZONTAL EXTENT OF THE AREAS OF WASTE DEPOSITION WERE USED ALONG WITH WASTE THICKNESS TO DETERMINE THE VOLUME OF WASTE PRESENT AT THE CROSS ROADS SITE. TOTAL VOLUME OF SANGAMO WESTON PROCESS WASTE AT THE SITE IS APPROXIMATELY 400 CUBIC YARDS. A COMPOSITE SAMPLE WAS MADE OF WASTE COLLECTED FROM SOIL BORING CRSB-3, 5, 7B AND 7C AND WAS ANALYZED FOR THE HSL PARAMETERS (VOC SAMPLES FOR WASTE FROM BORINGS CRSB-3, 5 AND 7B WERE ANALYZED SEPARATELY AND NOT COMPOSITED. ADDITIONALLY, A SAMPLE OF WASTE WAS COLLECTED FROM BORING CRSB-4 AND ANALYZED FOR VOCS ONLY. ANALYTICAL RESULTS FOR WASTE ARE PRESENTED IN TABLE 5-24. THE VOLATILE ORGANIC COMPOUNDS, TOTAL 1,2-DICHLOROETHENE AND TRICHLOROETHENE WERE DETECTED. NO SEMI-VOLATILE OR PESTICIDE COMPOUNDS WERE DETECTED IN THE COMPOSITE WASTE SAMPLE. PCBS WERE DETECTED IN THE 1 Order number 940620-103843-ROD -001-001 page 4263 set 4 with 100 of 100 items COMPOSITE WASTE SAMPLE CRSB-3, 5, 78, 7C WITH A TOTAL PCB CONCENTRATION OF 118 PPM. THE INORGANIC COMPOUNDS, CADMIUM, ZINC AND CYANIDE WERE DETECTED. SUBSURFACE SOILS WERE ANALYZED TO DETERMINE THE EXTENT OF PCBS AND OTHER CONSTITUENTS BELOW THE LAND SURFACE AND BELOW THE WASTE. SURFACE SOIL SAMPLES WERE COLLECTED AND ANALYZED TO DETERMINE THE EXTENT OF PCBS ON THE LAND SURFACE. TWENTY-SEVEN SURFACE SOIL SAMPLES (CRSS-1 THROUGH CRSS-27) WERE COLLECTED. CRSS-1 WAS ANALYZED FOR THE HSL PARAMETERS. ANALYTICAL RESULTS ARE PRESENTED ON TABLE 5-25. SAMPLES CRSS-2 THROUGH CRSS-27 WERE ANALYZED FOR PCBS ONLY. TOTAL PCB CONCENTRATIONS ARE SUMMARIZED IN TABLE 5-26. SAMPLE CRSS-9, LOCATED IN THE SOUTH CENTRAL PORTION OF THE AREA OF WASTE DEPOSITION HAD A TOTAL PCB CONCENTRATION OF 410 PPM. IN ADDITION TO COMPOSITE WASTE SAMPLE CRSB-3, 5, 78, 7C AND WASTE SAMPLE CRSB-7B (1.7-2), TWENTY-SEVEN SUBSURFACE SOIL SAMPLES WERE ANALYZED. ONE SAMPLE, CRSB-4 (5-7), WAS ANALYZED FOR THE HSL PARAMETERS. THE REMAINING TWENTY-SIX SAMPLES WERE ANALYZED FOR PCBS ONLY. ANALYTICAL RESULTS OF PCB CONCENTRATIONS ARE PRESENTED IN TABLE 5-27. ADDITIONAL PARAMETERS DETECTED IN THE HSL ANALYSIS OF SAMPLE CRSB-4 (5-7) ARE PRESENTED IN TABLE 5-28. THE PESTICIDE HEPTACHLOR EPOXIDE WAS FOUND IN SAMPLE CRSB-4 (5-7) AT 0.01 PPM. PCB CONCENTRATIONS OF SUBSURFACE SAMPLES RANGED FROM NONE DETECTED IN NINETEEN SAMPLES TO 3.5 PPM DETECTED IN A SAMPLE COLLECTED FROM BORING CRWB-2 (0.0-1.5). 5 5.6 JOHN TROTTER SITE TWENTY-EIGHT SOIL BORINGS WERE DRILLED IN LOCATIONS AT THE JOHN TROTTER SITE. SOILS UNDERLYING THE JOHN TROTTER SITE CONSIST OF SILTY SANDS, SILTY CLAYS AND CLAYEY SILTS. THIN LAYERS OF CAPACITOR WASTE (CAPACITOR PAPER, FOIL) WERE PRESENT IN SOME BORINGS AT SHALLOW DEPTHS (LESS THAN THREE FEET) BELOW LAND SURFACE. SOIL BORINGS AND EXPLORATORY BORINGS WERE DRILLED AS PART OF THE REMEDIAL INVESTIGATION TO CONFIRM ACTUAL WASTE PRESENCE AND DETERMINE HORIZONTAL AND VERTICAL EXTENT OF THE AREA OF WASTE DEPOSITION. WASTE SAMPLES WERE ANALYZED TO CHARACTERIZE THE WASTE AND IDENTIFY THE CONSTITUENTS. WASTE WAS PENETRATED BY BORINGS JTSB-2, 2A, 3, 3A, 58, SC, AND SD. FOLLOWING INSTALLATION OF THE SOIL BORINGS, SIX EXPLORATORY BORINGS WERE DRILLED TO FURTHER DEFINE THE AREA OF WASTE DEPOSITION. WASTE WAS NOT ENCOUNTERED IN ANY OF THE EXPLORATORY BORINGS. WASTE, IN THE FORM OF CAPACITOR FOIL AND PAPER, IS PRESENT IN TWO AREAS ON THE JOHN TROTTER SITE. THE LARGER OF THE TWO WASTE AREAS IS LOCATED 1 Order number 940620-103843-ROD -001-001 page 4264 set 4 with 100 of 100 items IN AN EMBANKMENT ALONG THE NORTH EDGE OF THE GRAVEL ROAD. THE WASTE AREA IS ABOUT 80 FEET LONG AND 15 FEET WIDE AND COMPRISES AN AREA OF ABOUT 135 SQUARE YARDS. WASTE THICKNESS AS INDICATED BY BORINGS JTSB-2, 2A, 3 AND 3A IS ABOUT 0.5 FEET WITH THE TOP OF WASTE ABOUT ONE FOOT BELOW LAND SURFACE. THE SECOND WASTE AREA IS LOCATED ABOUT 25 FEET NORTHEAST OF THE LARGER WASTE AREA IN A LOWER, FLAT TURNAROUND AREA FOR THE GARAGE. THE WASTE AREA IS APPROXIMATELY 18 FEET LONG AND 15 WIDE AND COMPRISES AN AREA OF ABOUT 270 SQUARE FEET WASTE THICKNESS AS INDICATED BY BORINGS JTSB-5B, 5C AND 5D WAS ABOUT 0.5 TO 1 FOOT WITH DEPTH TO THE TOP OF WASTE AT 1.5 TO 2 FEET BELOW LAND SURFACE. TOTAL WASTE VOLUME AT THE JOHN TROTTER SITE IS ESTIMATED TO BE APPROXIMATELY 100 CUBIC YARDS. A COMPOSITE SAMPLE OF WASTE, COLLECTED FROM BORINGS JTSB-2A (1.0 TO 1.5 FEET BELOW LAND SURFACE), JTSB-3A (1.0 TO 1.5 FEET BELOW LAND SURFACE) AND JTSB-5D (1.5 TO 1.9 FEET BELOW LAND SURFACE), DESIGNATED JTSB-2A, 3A, 5D WAS ANALYZED FOR HSL PARAMETERS (VOC SAMPLES OF WASTE COLLECTED FROM BORINGS JTSB-2, 3 AND 5B WERE ANALYZED SEPARATELY AND NOT COMPOSITED). ANALYTICAL RESULTS ARE PRESENTED IN TABLE 5-29. TWO VOLATILE ORGANIC COMPOUNDS, TETRACHLOROETHENE AND TRICHLOROETHENE WERE DETECTED IN THE WASTE. PCBS WERE DETECTED IN THE COMPOSITE WASTE SAMPLE JTSB-2A, 3A, 5D AT A CONCENTRATION OF 750 PPM. FIGHT INORGANIC COMPOUNDS, ANTIMONY, BARIUM, CADMIUM, COPPER, LEAD, SILVER, MERCURY AND ZINC WERE DETECTED AT CONCENTRATIONS ABOVE THE RANGE IN TABLE 5-30. BARIUM AND ZINC ARE WITHIN THE RANGE OF CONCENTRATIONS IN TABLE 5-31. ANTIMONY, CADMIUM AND SILVER ARE NOT INCLUDED IN TABLE 5-31. CHINE SHOP DEBRIS WAS PRESENT ON THE LAND SURFACE ADJACENT TO THE GARAGE. THIRTY-SEVEN SURFACE SOILS SAMPLES (JTSS-1 THROUGH JTSS-37) WERE COLLECTED AT THE SITE. JTSS-1 WAS ANALYZED FOR THE HSL PARAMETERS. TABLE 5-32 SUMMARIZES PARAMETERS DETECTED IN JTSS-1. SAMPLES JTSS-2 THROUGH JTSS-37 WERE ANALYZED FOR VOCS AND PCBS ONLY. VOCS DETECTED ALONG WITH TOTAL PCB CONCENTRATIONS ARE SUMMARIZED IN TABLE 5-33. PCBS WERE DETECTED IN THIRTY TWO OF THE THIRTY-SEVEN SURFACE SOIL SAMPLES COLLECTED. NO PCBS WERE DETECTED IN SAMPLES JTSS-1, 15, 21, 26 AND 35. TOTAL PCB CONCENTRATIONS RANGED FROM 0.053 PPM AT JTSS-24 TO 97 PPM AT JTSS-10. JTSS-10 AND JTSS-30, WITH TOTAL PCB CONCENTRATIONS OF 97 PPM AND 94 PPM, ARE THE ONLY SAMPLES TO EXCEED 50 PPM. THE REMAINING SAMPLES HAD PCB CONCENTRATIONS RANGING FROM 0.053 PPM TO 14 PPM. IN ADDITION TO THE COMPOSITE WASTE SAMPLE JTSB-2A, 3A, 5D, THIRTY SUBSURFACE SOIL SAMPLES WERE ANALYZED. ONE SAMPLE, JTSB-5B (6.5-8.0 FEET) WAS ANALYZED FOR HSL PARAMETERS. THE REMAINING TWENTY-NINE SAMPLES WERE ANALYZED FOR PCBS ONLY. ANALYTICAL RESULTS ARE PRESENTED IN TABLE 5-34. ADDITIONAL PARAMETER DETECTED IN THE HSL ANALYSIS OF SAMPLE JTSB-5B (6.5 - 8 FEET) ARE PRESENTED IN TABLE 5-35. 1 Order number 940620-103843-ROD -001-001 page 4265 set 4 with 100 of 100 items PCBS WERE DETECTED IN FIFTEEN OF THE THIRTY SAMPLES COLLECTED. JTSB-3 HAD A TOTAL PCB CONCENTRATION OF 120 PPM. THIS SAMPLE WAS COLLECTED BELOW THE LARGER WASTE AREA. THE 120 PPM TOTAL PCBS DETECTED IN JTSB-3 (5-6.5 FEET) IS MUCH LOWER THAN DETECTED IN THE OVERLYING WASTE (73 PPM). COMPOSITE WASTE SAMPLE JTSB-2A, 3A, 5D COLLECTED FROM BOTH AREAS OF WASTE DEPOSITION HAD A TOTAL PCB CONCENTRATION OF 730 PPM. SOIL SAMPLES COLLECTED FROM BORINGS JTSB-3 AND JTSB-5B HAD VARYING PCB CONCENTRATIONS WITH DEPTH. JTSB-3 HAD A PCB CONCENTRATION OF 27 PPM AT 2.5 TO 4 FEET BELOW LAND SURFACE (1 TO 2.5 FEET BELOW THE BOTTOM OF WASTE) AND HAD A PCB CONCENTRATION OF 120 PPM AT 5 TO 6.5 FEET BELOW LAND SURFACE (3.5 TO 5 FEET BELOW THE BOTTOM OF WASTE). JTSB-5B HAD A PCB CONCENTRATION OF 0.42 PPM AT 4 TO 5.5 FEET BELOW LAND SURFACE (1 TO 2.5 FEET BELOW WASTE) AND A CONCENTRATION OF 2.7 PPM AT 6.5 TO 8 FEET BELOW LAND SURFACE (3.5 TO 5 FEET BELOW WASTE). GROUND WATER SAMPLES WERE COLLECTED FROM WELLS JTMW-1, 2, 3, 3A, 3B AND 4 IN NOVEMBER 1988 AND FEBRUARY 1989. SAMPLES FROM BOTH SAMPLING ROUNDS WERE ANALYZED FOR PCBS, PH, SPECIFIC CONDUCTANCE, SUSPENDED SOLIDS, ALKALINITY, HARDNESS, CHLORIDES AND SULFATE. ADDITIONALLY, DURING THE FIRST SAMPLING ROUND ALL WELLS WERE SAMPLED FOR VOCS AND WELL JTMW-3 WAS ANALYZED FOR ALL OF THE HSL PARAMETERS. TABLE 5-36 SUMMARIZES ANALYTICAL RESULTS FOR DETECTED PARAMETERS. NO PCBS WERE DETECTED IN ANY OF THE WELLS DURING EITHER SAMPLING EVENT. DURING THE NOVEMBER 1988 SAMPLING, ONLY WELL JTMW-3 WAS ANALYZED FOR HSL PARAMETERS. NO SEMI-VOLATILE OR PESTICIDE COMPOUNDS WERE DETECTED. SEVENTEEN INORGANIC COMPOUNDS WERE FOUND IN THE SAMPLE. INORGANIC COMPOUND CONCENTRATIONS IN THE SAMPLE WERE LOW, THEREFORE, METALS WERE NOT INCLUDED IN THE ANALYTICAL PARAMETERS FOR THE SECOND ROUND OF GROUND WATER SAMPLES COLLECTED IN FEBRUARY 1989. STREAM SEDIMENT SAMPLES WERE COLLECTED IN NOVEMBER 1988 FROM TWO LOCATIONS ON THE UNNAMED TRIBUTARY TO TOWN CREEK. SAMPLES WERE ANALYZED FOR PCBS AND VOLATILE ORGANIC COMPOUNDS. ANALYTICAL RESULTS ARE PRESENTED IN TABLE 5-37. SAMPLING SITE JTSD-1 IS LOCATED ON THE UNNAMED TRIBUTARY TO TOWN CREEK UPSTREAM OF THE JOHN TROTTER SITE AND PROVIDES BACKGROUND STREAM SEDIMENT QUALITY. SEDIMENT SAMPLING SITE JTSD-2 IS LOCATED ON THE UNNAMED TRIBUTARY DOWNSTREAM OF THE SITE AND WAS SAMPLED TO DETERMINE IF PCBS ARE PRESENT DOWNGRADIENT OF SITE DRAINAGE. NO PCBS OR VOLATILE ORGANIC COMPOUNDS WERE DETECTED IN UPSTREAM SEDIMENT SAMPLE JTSD-1. A PCB CONCENTRATION OF 0.092 PPM WAS DETECTED IN JTSD-2 DOWNSTREAM OF THE JOHN TROTTER SITE. THIS PCB CONCENTRATION PROBABLY OCCURRED AS A RESULT OF EROSION OF PCB BEARING SOILS WITH SURFACE WATER RUNOFF ON-SITE. 1 Order number 940620-103843-ROD -001-001 page 4266 set 4 with 100 of 100 items ONE ROUND OF SURFACE WATER SAMPLES WERE COLLECTED IN NOVEMBER 1988 AT SAMPLING SITES JTSW-1 AND 2. THESE SAMPLING POINTS CORRESPOND WITH AND SERVE THE SAME PURPOSE AS SEDIMENT SAMPLING POINTS JTSD-1 AND 2. SURFACE WATER SAMPLES WERE ANALYZED FOR VOCS AND PCBS. NO VOCS OR PCBS WERE DETECTED IN EITHER OF THE SURFACE WATER SAMPLES. 5.7 SANGAMO PLANT SITE 3.2.1 SOURCES AREA A SOIL BORINGS AND EXPLORATORY TRENCHES WERE INSTALLED AS PART OF THE REMEDIAL INVESTIGATION TO DETERMINE ACTUAL WASTE PRESENCE, AND HORIZONTAL AND VERTICAL EXTENT OF THE AREA OF WASTE DEPOSITION IN AREA A. NINE SOIL BORINGS WERE DRILLED IN AREA A. WASTE, IN THE FORM OF ALUMINUM HYDROXIDE SLUDGE, WAS PENETRATED BY BORINGS SASB-1, 2, 2A, 3, 3A AND 48. WASTE WAS NOT FOUND IN THE THREE REMAINING SOIL BORINGS, SASB-4, 4A AND 4C. FOLLOWING INSTALLATION OF THE SOIL BORINGS, TWELVE EXPLORATORY TRENCHES, LABELED SAST-1 THROUGH 12, WERE EXCAVATED TO FURTHER DETERMINE THE HORIZONTAL AND VERTICAL EXTENT OF THE AREAS OF WASTE DEPOSITION. EXPLORATORY TRENCHES WERE EXCAVATED WITH A BACKHOE AND VISUALLY DESCRIBED BY THE ON-SITE RMT GEOLOGIST. THE HORIZONTAL EXTENT OF WASTE WAS DETERMINED BY SOIL BORINGS AND EXPLORATORY TRENCHES. WASTE SLUDGE IS PRESENT IN TWO ADJACENT LOCATIONS AT AREA A. THE NORTHERN AREA OF WASTE DEPOSITION HAS A TOTAL AREA OF 280 SQUARE YARDS AND THE SOUTHERN HAS A TOTAL AREA OF 170 SQUARE YARDS. WASTE THICKNESS RANGES FROM 1 FOOT AT BORING SASB-3 TO 9 FEET ON THE WEST END OF TRENCH SAST-2.THE VOLUME OF WASTE PRESENT IN AREA A IS 500 CUBIC YARDS. WASTE VOLUME CALCULATIONS FOR ALL SITES WERE PRESENTED IN DETAIL IN THE FEASIBILITY STUDY. TWO COMPOSITE SAMPLES OF WASTE WERE COLLECTED FROM AREA A AND ANALYZED FOR HSL PARAMETERS. ONE COMPOSITE SAMPLE WAS OBTAINED FROM SOIL BORINGS SASB-1 AND SASB-2A IN THE NORTHERN WASTE AREA, AND ONE COMPOSITE SAMPLE WAS OBTAINED FROM SOIL BORINGS SASB-3A AND SASB-4B IN THE SOUTHERN WASTE AREA. VOC SAMPLES FOR WASTE COLLECTED FROM BORINGS SASB-1, 3A, 3A AND 4B WERE ANALYZED SEPARATELY AND NOT COMPOSITED. ANALYTICAL RESULTS FOR WASTE ARE PRESENTED IN TABLE 5-38. SEVERAL VOLATILE ORGANIC COMPOUNDS WERE DETECTED. THE VOLATILE ORGANIC COMPOUNDS METHYLENE CHLORIDE AND ACETONE WERE DETECTED IN MOST SAMPLES COLLECTED (WASTE, SOILS, SEDIMENTS AND WATER) AT ALL OF THE SITES. CARBON DISULFIDE WAS ALSO DETECTED IN SEVERAL SAMPLES AT SOME OF THE OFF SITE AREAS. 1 Order number 940620-103843-ROD -001-001 page 4267 set 4 with 100 of 100 items ONLY FOUR OF THE WASTE SAMPLES HAD VOCS OTHER THAN METHYLENE CHLORIDE OR ACETONE. THESE CONCENTRATIONS WERE ALL LESS THAN 1 PPM. THESE COMPOUNDS WERE NOT DETECTED IN ANY OF THE OTHER WASTE SAMPLES. VOCS WERE NOT DETECTED IN WASTE COLLECTED FORM THE NORTH WASTE AREA. PCBS WERE FOUND IN BOTH OF THE COMPOSITE WASTE SAMPLES, SASB-1, 2A AND SASB-3A, 4B. TOTAL PCB CONCENTRATION IN SASB-1, 2A WAS 17.4 PPM. SAMPLE SASB-3A, 4B HAD A TOTAL PCS CONCENTRATION OF 22,900 PPM. AS THE SLUDGE IS FROM THE WASTEWATER TREATMENT FACILITY, THIS IS EXPECTED. TABLE 5-34 PRESENTS HSL INORGANIC COMPOUND CONCENTRATIONS DETECTED IN UPGRADIENT SURFACE SOILS FOR ALL OF THE SITES AND AREAS ADDRESSED IN THE REMEDIAL INVESTIGATION. TABLE 5-31 PRESENTS THE RANGE OF SELECTED INORGANIC COMPOUNDS DETECTED IN SOILS IN GEORGIA, SOUTH CAROLINA AND NORTH CAROLINA OBTAINED FROM "CHEMICAL ANALYSES OF SOILS AND OTHER SURFICIAL MATERIALS OF THE CONTERMINOUS UNITED STATES" (USGS, 1981). THE RANGE OF CONCENTRATIONS ON TABLES 5-30 AND 5-31 ARE USED FOR COMPARISON WITH DOWNGRADIENT WASTE AND SOIL SAMPLES FOR EACH SITE OR AREA. THE INORGANIC COMPOUNDS ALUMINUM, ARSENIC, COPPER MANGANESE AND SILVER WERE FOUND AT CONCENTRATIONS HIGHER THAN THE RANGE OF CONCENTRATIONS DETECTED IN THE UPGRADIENT SURFACE SOIL SAMPLES (TABLE 5-34). COPPER AND MANGANESE WERE BELOW THE RANGE FOR GA, SC AND NC (TABLE 5-31). NINETEEN SURFACE SOIL SAMPLES (SASS-1 THROUGH SASS-19) WERE COLLECTED. SASS-1 WAS ANALYZED FOR THE HSL PARAMETERS. SAMPLES SASS-2 THROUGH SASS-19 WERE ANALYZED FOR PCBS ONLY. ANALYTICAL RESULTS FOR SASS-1 ARE PRESENTED ON TABLE 5-39. PCB CONCENTRATIONS DETECTED IN ALL SURFACE SOIL SAMPLES ARE SUMMARIZED IN TABLE 5-40. PCBS WERE DETECTED IN NINETEEN SURFACE SOIL SAMPLES. TOTAL PCB CONCENTRATIONS RANGED FROM 2.4 PPM AT SASS-18 TO 1880 PPM AT SASS-12. THIRTEEN SURFACE SOIL SAMPLES INCLUDING UPGRADIENT SAMPLE SASS-1, EXCEEDED 50 PPM TOTAL PCBS. TEN OF THESE SAMPLES WERE COLLECTED IN THE IMMEDIATE VICINITY OF THE AREAS OF WASTE DEPOSITION. PCBS WERE ALSO DETECTED IN SURFACE SOIL SAMPLES COLLECTED DOWNGRADIENT AT AREA A, TWO OF WHICH EXCEEDED 50 PPM (SASS-16 AND SASS-19). IN ADDITION TO COMPOSITE WASTE SAMPLES SASB-1, 2A AND SASB-3A, 4B, NINE SUBSURFACE SOIL SAMPLES WERE COLLECTED FROM BELOW OR ADJACENT WASTE, AND ANALYZED FOR PCBS. ADDITIONALLY, ONE SAMPLE COLLECTED BELOW THE WASTE FROM BORING SASB-3A, DESIGNATED SASB-3A (11-13), WAS ANALYZED FOR HSL PARAMETERS. ANALYTICAL RESULTS FOR PCBS ARE PRESENTED IN TABLE 5-41. ADDITIONAL PARAMETERS DETECTED IN THE HSL ANALYSIS OF SAMPLE SASB-3A (11-13) ARE PRESENTED IN TABLE 5-42. TOTAL PCB CONCENTRATIONS ARE ALSO SHOWN ON WASTE RANGED FROM 17.4 PPM IN COMPOSITE SASB-1, 2A, COLLECTED FROM THE NORTH WASTE AREA TO 22,900 PPM IN COMPOSITE SAMPLE SASB-3A, 4B COLLECTED FROM THE SOUTH WASTE AREA. ONLY FOUR SUBSURFACE SOIL SAMPLES, SASB-3 (8-0), SASB-3A (11-13), SASB-4A (4-6) AND SASB-4C (13-15) HAD PCB 1 Order number 940620-103843-ROD -001-001 page 4268 set 4 with 100 of 100 items CONCENTRATIONS EXCEEDING 50 PPM. SOIL SAMPLE SASB-2 (6-8) COLLECTED ADJACENT TO THE NORTH WASTE AREA AND SAMPLES SASB-1 (6-8), SASB-1 (9-11), SASB-2A (6-8) AND SASB-2A (9-11), COLLECTED BELOW THE NORTH WASTE AREA HAD TOTAL PCB CONCENTRATIONS RANGING FROM 0.053 PPM TO 2.67 PPM (MUCH LOWER THAN THE 17 4 PPM DETECTED IN THE WASTE IN THE NORTH AREA). NONE OF THE WASTE OR SUBSURFACE SOIL SAMPLES COLLECTED AT THE NORTH WASTE AREA EXCEEDED 50 PPM TOTAL PCBS. SUBSURFACE SOIL SAMPLE SASB-3A (11-13) COLLECTED BELOW THE WASTE IN THE SOUTH AREA WAS ANALYZED FOR HSS PARAMETERS. NO VOCS OR PESTICIDES WERE DETECTED. ONLY ONE SEMI-VOLATILE COMPOUND, BIS (2-ETHYLHEXYL) PHTHALATE, WAS DETECTED. ONE INORGANIC COMPOUND, COBALT, EXCEEDED THE RANGE OF CONCENTRATIONS ON TABLE 5-31. COBALT WAS DETECTED AT LOWER CONCENTRATIONS IN THE WASTE. SILVER WAS DETECTED ABOVE THE RANGE OF CONCENTRATIONS IN TABLE 5-30. SOIL SAMPLES WERE COLLECTED AT 0 TO 1.5 FEET AND 1.5 TO 3 FEET BELOW LAND SURFACE AT PROPOSED LOCATIONS FOR WELLS SAMW-2 AND SAMW-3 LOCATED ADJACENT TO THE SOUTH AREA OF WASTE DEPOSITION AND ANALYZED FOR PCBS. ANALYTICAL RESULTS ARE ALSO INCLUDED IN TABLE 5-41. TOTAL PCB CONCENTRATION RANGED FROM 13.1 PPM TO 340 PPM. GROUND WATER SAMPLES WERE COLLECTED FROM ALL AREA A WELLS (SAMW-1, 2 AND 3). SAMPLES WERE ANALYZED FOR PCBS, VOCS, PH, SPECIFIC CONDUCTANCE, SUSPENDED SOLIDS, ALKALINITY, HARDNESS, CHLORIDES, AND SULFATE. IN ADDITION, WELL SAMW-3 WAS ANALYZED FOR ALL OF THE HSL PARAMETERS. SAMPLES WERE COLLECTED FOR INORGANIC ANALYSIS. TABLE 5-43 SUMMARIZES ANALYTICAL RESULTS FOR PARAMETERS DETECTED IN ALL SAMPLES. NO PCBS WERE DETECTED IN ANY OF THE AREA A WELLS. TRICHLOROETHENE WAS DETECTED IN ALL THREE WELLS IN JANUARY 1989. TETRACHLOROETHENE WAS ALSO DETECTED IN ALL THREE WELLS AT SIMILAR CONCENTRATIONS, 0.005 PPM TO 0.007 PPM. TOTAL 1,2-DICHLOROETHENE WAS DETECTED IN WELL SAMW-3 AT 0.018 PPM IN OCTOBER 1988, AND 0.022 PPM IN JANUARY 1989. SEMI-VOLATILE AND PESTICIDE COMPOUNDS WERE NOT DETECTED IN THE ONE HSL ANALYSIS OF SAMW-3. DURING THE FIRST SAMPLING ROUND IN OCTOBER 1988, GROUND WATER SAMPLES WERE OBTAINED FROM WELL SAMW-3 AND ANALYZED FOR INORGANIC COMPOUNDS. METAL CONCENTRATIONS WERE LOW; THEREFORE, METALS WERE NOT INCLUDED IN THE ANALYTICAL PARAMETERS FOR THE SECOND ROUND OF GROUND WATER SAMPLES COLLECTED IN JANUARY 1989. EPA WAS NOTIFIED OF THE ELIMINATION OF METALS AND SEMI-VOLATILE COMPOUNDS FROM THE ANALYTICAL PARAMETER LIST IN A LETTER DATED JANUARY 10, 1989. AREA B: 1 Order number 940620-103843-ROD -001-001 page 4269 set 4 with 100 of 100 items SOIL BORINGS, EXPLORATORY BORINGS, AND ONE EXPLORATORY TRENCH WERE INSTALLED AS PART OF THE REMEDIAL INVESTIGATION TO DETERMINE WASTE PRESENCE, AND TO INVESTIGATE THE HORIZONTAL AND VERTICAL EXTENT OF THE AREAS OF WASTE DEPOSITION. A TOTAL OF NINE SOIL BORINGS WERE DRILLED. WASTE IN THE FORM OF CAPACITOR DEBRIS, SLUDGE, RESINOUS MATERIAL, AND DRUMS WAS FOUND IN BORING SBSB-1, SBSB-2B AND SBSB-3A. NO WASTE WAS FOUND IN THE SIX REMAINING SOIL BORINGS. FOLLOWING INSTALLATION OF THE SOIL BORINGS, FIVE EXPLORATORY BORINGS WERE INSTALLED TO FURTHER DETERMINE THE HORIZONTAL AND VERTICAL EXTENT OF WASTE DEPOSITION. AN EXPLORATORY TRENCHING PROGRAM WAS ALSO INITIATED TO FURTHER DEFINE THE WASTE IN AREA B. HOWEVER, DRUMS WERE ENCOUNTERED IN THE FIRST EXPLORATORY TRENCH (SBST-1) AND TRENCHING WAS DISCONTINUED IN ORDER TO AVOID PUNCTURING THE DRUMS. THE VERTICAL EXTENT OF WASTE HAS BEEN ESTIMATED. THE WASTE HAS BEEN DISPOSED IN THREE AREAS: ONE ABOVE-GROUND DISPOSAL AREA AT THE NORTH END OF AREA 5, AND TWO SUBSURFACE DISPOSAL AREAS. WASTE IN THE ABOVE-GROUND DISPOSAL AREA CONSIST OF WOOD PALLETS AND CAPACITOR DEBRIS. THE ABOVE-GROUND WASTE AREA HAS AN APPROXIMATE SURFACE AREA OF 180 SQUARE YARDS. THE NORTH AREA OF SUBSURFACE WASTE HAS AN AREA OF 80 SQUARE YARDS AND AN ESTIMATED VOLUME OF 300 CUBIC YARDS. THE SOUTHERNMOST AREA OF WASTE DEPOSITION HAS A SURFACE AREA OF 95 SQUARE YARDS AND AN ESTIMATED VOLUME OF 250 CUBIC YARDS. A SAMPLE OF WASTE COLLECTED FROM EXPLORATORY TRENCH SBST-1, AND A COMPOSITE SAMPLE OF WASTE COLLECTED FROM SOIL BORINGS 2B AND 3 (DESIGNATED SBSB-2B, 3), WERE ANALYZED FOR THE HSL PARAMETERS. SAMPLES OF WASTE FOR VOC ANALYSIS WERE COLLECTED FROM BORINGS SBSB-2B AND 3 AND ANALYZED SEPARATELY. ANALYTICAL RESULTS FOR WASTE ARE PRESENTED ON TABLE 5-44. SEVERAL VOCS AND SEMI-VOLATILE COMPOUNDS WERE DETECTED IN THE WASTE. TRICHLOROETHENE AND TETRACHLOROETHENE WERE MOST COMMON. PCBS WERE DETECTED IN WASTE SAMPLES SBST-1 AND IN THE COMPOSITE SAMPLE SBSB-2B, 3. TOTAL PCBS DETECTED IN COMPOSITE WASTE SAMPLE SBSB-2B, 3, AND IN THE EXPLORATORY TRENCH WASTE SAMPLE WERE 31 PPM AND 920 PPM, RESPECTIVELY. THE INORGANIC COMPOUNDS ALUMINUM, CALCIUM, LEAD, MAGNESIUM, SILVER AND CYANIDE WERE FOUND IN THE WASTE AT CONCENTRATIONS ABOVE THE RANGE DETECTED IN TABLE 5-30. LEAD AND MAGNESIUM CONCENTRATIONS ARE WITHIN THE RANGE IN TABLE 5-31. TWENTY-TWO SURFACE SOIL SAMPLES, (SBSS-1 THROUGH SBSS-22), WERE COLLECTED IN AREA 5. UPGRADIENT SOIL SAMPLE SBSS-1 WAS ANALYZED FOR HSL PARAMETERS. THE REMAINING SAMPLES WERE ANALYZED FOR PCBS AND VOCS. TABLE 5-45 SUMMARIZES THOSE PARAMETERS DETECTED IN SBSS-1. PCB, SEMI-VOLATILES AND VOC CONCENTRATIONS FOR ALL SURFACE SOIL SAMPLES ARE PRESENT IN TABLE 5-46. PCBS WERE DETECTED IN TWENTY-TWO SAMPLES. TOTAL PCB CONCENTRATIONS RANGED FROM 0.53 PPM AT SBSS-3 TO 32,000 PPM AT SBSS-7. NINE SURFACE SOIL SAMPLES HAVE PCB CONCENTRATIONS EXCEEDING 50 1 Order number 940620-103843-ROD -001-001 page 4270 set 4 with 100 of 100 items PPM. EIGHT OF THESE SAMPLES ARE LOCATED AT AREAS OF WASTE DEPOSITION. SURFACE SOIL SAMPLES SBSS-4, 7, 9 AND 11 WERE COLLECTED ADJACENT TO OR IMMEDIATELY DOWNGRADIENT OF THE ABOVE-GROUND DISPOSAL AREA. SBSS-14 WAS COLLECTED ADJACENT TO THE NORTH SUBSURFACE DISPOSAL AREA. SURFACE SOIL SAMPLES SBSS-17, 18 AND 19 ARE ALL LOCATED IMMEDIATELY DOWNGRADIENT OF THE SOUTH DISPOSAL AREA. SURFACE SOIL SAMPLE SBSS-21 (325 PPM TOTAL PCBS) WAS COLLECTED FROM A DRAINAGE SWALE DOWNGRADIENT OF THE WASTE AREAS IN AREA B. VOLATILE ORGANIC COMPOUNDS WERE DETECTED IN SBSS-7, 11, 16 AND 18 THROUGH 21. SAMPLES SBSS-7 AND SBSS-6 WERE COLLECTED AT AND DOWNGRADIENT OF THE ABOVE-GROUND DISPOSAL AREA, RESPECTIVELY. SAMPLES SBSS-18, 19 AND 20 WERE COLLECTED IMMEDIATELY DOWNGRADIENT OF THE SOUTH SUBSURFACE DISPOSAL AREA. SAMPLE SBSS-21 WAS COLLECTED IN A DRAINAGE SWALE ABOUT FIFTY FEET DOWNGRADIENT OF THE WASTE IN AREA B. THE CONCENTRATIONS OF VOCS ARE ALL LESS THAN 1 PPM. IN ADDITION TO WASTE SAMPLES, FIVE SUBSURFACE SOIL SAMPLES WERE COLLECTED ADJACENT TO OR BELOW THE WASTE AND ANALYZED FOR PCBS. ADDITIONALLY, ONE SAMPLE, SBSB-2B (8-10) WAS ANALYZED FOR THE HSL PARAMETERS. ANALYTICAL RESULTS FOR PCBS ARE PRESENTED IN TABLE 5-47. PARAMETERS DETECTED IN THE HSL ANALYSIS OF SBSB-2B (8-10) ARE SUMMARIZED IN TABLE 5-48. THREE BORINGS SBSB-1, 1A AND 1B WERE INSTALLED ADJACENT TO THE ABOVE-GROUND DISPOSAL AREA AND SAMPLED AT 4 TO 6 FEET BELOW LAND SURFACE. TOTAL PCB CONCENTRATIONS IN THESE SAMPLES WERE 16 PPM, 1.4 PPM AND NONE DETECTED, RESPECTIVELY. TWO SUBSURFACE SOIL SAMPLES SBSB-2B (6-8) AND SBSB-2B (8-10) WERE COLLECTED BELOW THE WASTE IN THE NORTH SUBSURFACE DISPOSAL AREA. THESE SOILS HAD TOTAL PCBS CONCENTRATIONS OF 18 PPM AND 80 PPM, RESPECTIVELY. SBSB-2B (8-10) WAS THE ONLY SUBSURFACE SOIL SAMPLE TO EXCEED 50 PPM TOTAL PCBS. NO VOCS WERE DETECTED IN THE HSL ANALYSIS OF SBSB-2B (8-10). SEVERAL SEMI-VOLATILE COMPOUNDS WERE DETECTED. THREE INORGANIC COMPOUNDS, COPPER, IRON AND VANADIUM EXCEEDED THE RANGE OF CONCENTRATIONS IN TABLE 5-31. CONCENTRATIONS OF COPPER, IRON AND VANADIUM ARE MUCH HIGHER IN THE SOILS THAN IN THE OVERLYING WASTE. THE WASTE IS NOT THE SOURCE OF THESE COMPOUNDS TO SUBSURFACE SOILS. TWO SUBSURFACE SOIL SAMPLES WERE ALSO COLLECTED AT 0 TO 1.5 FEET AND 1.5 TO' 3 FEET BELOW LAND SURFACE OF WELL SBMW-2 LOCATED ABOUT 60 FEET EAST OF THE WASTE IN AREA B. THESE SAMPLES WERE ANALYZED FOR PCBS ONLY. TOTAL PCBS DETECTED IN THESE SAMPLES ARE 16 PPM AND 16.3 PPM, RESPECTIVELY. ANALYTICAL RESULTS ARE INCLUDED IN TABLE 5-47. GROUND WATER SAMPLES WERE COLLECTED FROM WELLS SBMW-1, 2 AND 3 ON OCTOBER 10, 1988 AND JANUARY 18, 1989. FIRST ROUND SAMPLES WERE ANALYZED FOR PCBS, VOCS, PH, SPECIFIC CONDUCTANCE, SUSPENDED SOLIDS, ALKALINITY, HARDNESS, CHLORIDES, AND SULFATE. BECAUSE SEVERAL 1 Order number 940620-103843-ROD -001-001 page 4271 set 4 with 100 of 100 items SEMI-VOLATILE COMPOUNDS WERE DETECTED IN THE HSL ANALYSIS FOR SEMI-VOLATILE COMPOUNDS. WELL SBMW-2 WAS ALSO ANALYZED FOR ALL OF THE HSL PARAMETERS DURING THE FIRST SAMPLING COUNT. SAMPLES WERE COLLECTED FOR INORGANIC ANALYSIS. TABLE 5-49 SUMMARIZES ANALYTICAL RESULTS FOR DETECTED PARAMETERS. PCBS WERE DETECTED IN WELL SBMW-2 IN JANUARY 1989 AT 0.0023 PPM AND 0.003 PPM (DUPLICATE SAMPLE). PCBS WERE NOT DETECTED IN ANY OTHER GROUND WATER SAMPLES FOR AREA B. SEVERAL VOLATILE ORGANIC COMPOUNDS (1,1,1-TRICHLOROETHANE, AND TETRACHLOROETHENE) WERE DETECTED IN GROUND WATER IN AREA B. 1,1,1-TRICHLOROETHANE WAS DETECTED IN UPGRADIENT WELL SBMW-1 (0.008 PPM) DURING THE OCTOBER 1988 SAMPLING AND IS THE ONLY VOC DETECTED IN SBMW-1. 1,1,1-TRICHLOROETHANE, TETRACHLOROETHENE, TRICHLOROETHENE AND 1,2-DICHLOROETHENE WAS DETECTED IN SBMW-2. TRICHLOROETHENE WAS DETECTED IN WELL SBMW-3 IN JANUARY 1989 AT 0.008 PPM. THIS COMPOUND WAS ALSO DETECTED IN THE ASSOCIATED ANALYTICAL BLANK. SAMPLE SBMW-3 WAS ANALYZED THE SAME DAY AS SAMPLES COLLECTED FROM WELLS IN AREA A. THE 0.008 PPM TRICHLOROETHENE DETECTED IN SBMW-3 IS SIMILAR TO THE 0.007 PPM TO 0.008 PPM DETECTED IN AREA A. TETRACHLOROETHENE WAS ALSO DETECTED IN WELL SBMW-3 IN JANUARY 1989 AT 0.025 PPM. WELL SBMW-2, LOCATED IMMEDIATELY DOWNGRADIENT OF THE AREA OF WASTE DEPOSITION IN AREA B, HAD THE HIGHEST CONCENTRATION OF VOCS, 33.886-PPM DETECTED IN OCTOBER 1988, AND 77.1 PPM (77.3 PPM IN A DUPLICATE SAMPLE) DETECTED IN JANUARY 1989. DURING THE FIRST SAMPLING ROUND IN OCTOBER 1988, ALL THREE WELLS WERE ANALYZED FOR THE SEMI-VOLATILE COMPOUNDS. NO SEMI-VOLATILE COMPOUNDS WERE DETECTED IN ANY OF THE WELLS. THEREFORE, SEMI-VOLATILES WERE NOT INCLUDED IN THE LIST OF ANALYTICAL PARAMETERS FOR THE SECOND ROUND SAMPLES COLLECTED IN JANUARY 1989. DURING THE FIRST SAMPLING ROUND IN OCTOBER 1988, SAMPLES WERE OBTAINED FROM DOWNGRADIENT WELL SBMW-3 FOR INORGANIC ANALYSIS. EIGHT COMPOUNDS WERE DETECTED IN THE NON-FILTERED SAMPLE. INORGANIC COMPOUND CONCENTRATIONS IN THE SAMPLE WAS LOW; THEREFORE, METALS WERE NOT INCLUDED IN THE ANALYTICAL PARAMETERS FOR THE SECOND ROUND GROUND WATER SAMPLES COLLECTED IN JANUARY 1989 EPA WAS NOTIFIED THAT INORGANIC, PESTICIDE, AND SEMI-VOLATILE COMPOUNDS WOULD NOT BE INCLUDED ON THE ANALYTICAL PARAMETER LIST FOR SECOND ROUND SAMPLES IN A LETTER DATED JANUARY 10, 1989. AREA C SOIL BORINGS AND EXPLORATORY TRENCHES WERE INSTALLED AS PART OF THE REMEDIAL INVESTIGATION TO CONFIRM ACTUAL WASTE PRESENCE AND DETERMINE 1 Order number 940620-103843-ROD -001-001 page 4272 set 4 with 100 of 100 items HORIZONTAL AND VERTICAL EXTENT OF THE AREAS OF WASTE DEPOSITION. A TOTAL OF TWENTY SOIL BORINGS WERE DRILLED. SPLIT-SPOON REFUSAL WAS ENCOUNTERED ON TOP OF WASTE BETWEEN 1 AND 4 FEET BELOW LAND SURFACE IN BORINGS SCSB-1, 1A, 1B, 1C, 4, 4A AND 5. TO ASSIST IN SAMPLING BELOW THE WASTE, TRENCHES 2, 3 AND 4 WERE EXCAVATED TO REMOVE WASTE AT BORING LOCATIONS SCSB-4, 5 AND 6. BORINGS SCSB-4T, 5T AND 6T WERE ADVANCED THROUGH THE BOTTOM OF THE TRENCHES. WASTE WAS ALSO REMOVED AT SCSB-1 AND BORING SCSB-7T WAS DRILLED THROUGH THE BOTTOM OF THE EXCAVATION. EXPLORATORY TRENCHES INSTALLED IN THESE AREAS, AFTER THE SOIL BORINGS WERE DRILLED, REVEALED THE PRESENCE OF LARGE POWER FACTOR CAPACITORS IN THE AREA OF EACH OF THESE SOIL BORINGS EXCEPT SCSB-5. WASTE, IN THE FORM OF CAPACITOR DEBRIS (METAL, PAPER AND FOIL) WAS ENCOUNTERED BY BORINGS SCSB-1, SCSB-1E, 5A AND 6C. WASTE WAS NOT OBSERVED IN THE REMAINING TWELVE SOIL BORINGS. FOLLOWING INSTALLATION OF THE SOIL BORINGS, FIFTEEN EXPLORATORY TRENCHES WERE INSTALLED TO FURTHER DETERMINE THE HORIZONTAL AND VERTICAL EXTENT OF THE TWO AREAS OF WASTE DEPOSITION. EXPLORATORY TRENCHES WERE EXCAVATED WITH A BACKHOE AND VISUALLY DESCRIBED BY THE ON-SITE RMT GEOLOGIST. THE HORIZONTAL EXTENT OF THE TWO AREAS OF WASTE DEPOSITION WAS DETERMINED BY SOIL BORINGS AND EXPLORATORY TRENCHES. WASTE IN AREA C IS DISPOSED IN TWO PARALLEL TRENCHES ORIENTED IN A NORTHEAST DIRECTION. THE NORTHWEST TRENCH IS 120 FEET LONG AND 5 FEET WIDE. THE SOUTHEAST TRENCH IS 45 FEET LONG AND 12 FEET WIDE. LARGE POWER FACTOR CAPACITORS ARE PRESENT IN THE SOUTHEAST WASTE AREA. CAPACITOR PAPER, FOIL, METAL BANDING, AND POWER FACTOR CAPACITORS ARE PRESENT IN THE NORTHWEST WASTE DEPOSITION AREA. THE NORTHWEST WASTE AREA HAS AN APPROXIMATE SURFACE AREA OF 65 SQUARE YARDS AND THE SOUTHEAST AREA HAS AN APPROXIMATE SURFACE AREA OF 60 SQUARE YARDS. TOTAL WASTE VOLUME AT AREA C IS APPROXIMATELY 200 CUBIC YARDS. A SAMPLE OF WASTE COLLECTED FROM SOIL BORING SCSB-6C AT 0.0 TO 2.0 FEET BELOW LAND SURFACE, AND A COMPOSITE SAMPLE OF WASTE COLLECTED FROM EXPLORATORY TRENCHES SCST-2, 3, AND 4, WERE ANALYZED FOR THE HSL PARAMETERS (SAMPLES OF WASTE FOR VOC ANALYSIS WERE COLLECTED FROM EXPLORATORY TRENCHES SCST-2, 3 AND 4 WERE ANALYZED SEPARATELY, (NOT COMPOSITED). ANALYTICAL RESULTS FOR WASTE ARE PRESENTED ON TABLE 5-50. SEVERAL VOLATILE ORGANIC COMPOUNDS WERE DETECTED IN THE WASTE. HOWEVER, THE CONCENTRATIONS OF VOCS DETECTED ARE NEAR THE DETECTION LIMITS. TRICHLOROETHENE WAS THE MOST COMMONLY FOUND CONSTITUENT. NO SEMI-VOLATILE OR PESTICIDE COMPOUNDS WERE DETECTED IN THE WASTE IN AREA C. PCBS WERE DETECTED IN BOTH WASTE SAMPLES SCSB-6C (0.0-2.0) AND SCST-2, 3, 4 AT 38,000 PPM AND 25,000 PPM TOTAL PCBS. 1 Order number 940620-103843-ROD -001-001 page 4273 set 4 with 100 of 100 items THE INORGANIC COMPOUND COPPER WAS THE ONLY COMPOUND DETECTED IN THE WASTE WITH CONCENTRATIONS ABOVE THE RANGE OF CONCENTRATIONS IN TABLE 5-31. SEVENTEEN SURFACE SOIL SAMPLES (SCSS-1 THROUGH SCSS-17) WERE COLLECTED. SCSS-1 WAS ANALYZED FOR THE HSL PARAMETERS. SAMPLES SCSS-2 THROUGH SCSS-17 WERE ANALYZED FOR PCBS ONLY. TABLE 5-51 SUMMARIZES PARAMETERS DETECTED IN SCSS-1. PCB CONCENTRATIONS ARE SUMMARIZED IN TABLE 5-52. TOTAL PCB CONCENTRATIONS RANGED FROM NONE DETECTED AT SAMPLE SITE SCSS-4 TO 11,000 PPM DETECTED AT SCSS-7. ONLY SEVEN SAMPLES (SCSS-5, 7, 8, 9, 11, 12 AND 13) HAD PCB CONCENTRATIONS GREATER THAN 50 PPM. THESE SAMPLES WERE GROUPED TOGETHER AND LOCATED ALONG AND IMMEDIATELY DOWNGRADIENT AT THE NORTHWEST TRENCH. IN ADDITION TO COMPOSITE WASTE SAMPLE SCST-2, 3 AND 4, AND WASTE SAMPLE SCSB-6C (0-2), TWENTY-THREE SUBSURFACE SOIL SAMPLES WERE COLLECTED AND ANALYZED. THREE SAMPLES, SCSB-5 (5-6.5) SCSB-5A (7.5-9) AND SCST-1 WERE ANALYZED FOR THE HSL PARAMETERS. THE REMAINING TWENTY SAMPLES WERE ANALYZED FOR PCBS ONLY. ANALYTICAL RESULTS FOR PCBS ARE PRESENTED IN TABLE 5-53. ADDITIONAL PARAMETERS DETECTED IN THE HSL ANALYSES ARE PRESENTED IN TABLE 5-54. PCBS WERE DETECTED IN ALL SUBSURFACE SOIL SAMPLES, EXCEPT SCSB-6A (4-6), COLLECTED ADJACENT TO THE NORTHWEST WASTE AREA. OF THE REMAINING SOIL SAMPLES, TWELVE HAD TOTAL PCB CONCENTRATIONS GREATER THAN 50 PPM. SAMPLES SCSB-1D (4-6), WITH A TOTAL PCB CONCENTRATION OF 214 PPM, WAS COLLECTED NEAR THE SOUTH END OF THE SOUTHEAST WASTE AREA. THE REMAINING TEN SAMPLES WITH GREATER THAN 50 PPM TOTAL PCBS WERE COLLECTED FROM BELOW THE WASTE, RANGING FROM 90 PPM AT SCSB-1E (8-9.5), SCSB-1E (10-11.5), SCSB-7T (7-8.5) AND SCSB-7T (9.5-11), WERE COLLECTED BELOW THE WASTE IN THE SOUTHWEST WASTE AREA. TOTAL PCB CONCENTRATIONS IN BOTH BORINGS DECREASED IN CONCENTRATION FROM 90 PPM TO 35 PPM IN SCSB-1E AND FROM 9,303 PPM TO 900 PPM AT BORING SCSB-7T. TOTAL PCBS DETECTED IN SOILS COLLECTED FROM BORING SCSB-6C INCREASED WITH DEPTH FROM 320 PPM TO 4,570 PPM. THE OTHER FOUR BORINGS DEMONSTRATED DECREASES IN TOTAL PCB CONCENTRATIONS IN DEPTH FROM 6,400 PPM TO 1.42 PPM AT SCSB-4T, 7,800 PPM TO 5.8 PPM AT SCSB-5T, 14, 100 PPM TO 3.9 PPM AT SCSB-5A AND 33,000 TO 24,000 AT SCSB-6T. AS SHOWN, THREE OF THESE BORINGS DECREASED IN PCB CONCENTRATIONS TO LESS THAN 50 PPM. THE SUBSURFACE SOIL SAMPLES COLLECTED FROM BORINGS SCSB-2,3,6,6A AND 6B WERE COLLECTED OUTSIDE OF THE WASTE AREAS. TOTAL PCB CONCENTRATIONS IN THESE SAMPLES RANGED FROM NONE DETECTED TO 10 PPM. TWO SUBSURFACE SOIL SAMPLES WERE COLLECTED AT 0.5 TO 2 FEET BELOW LAND SURFACE AND 2 TO 3.5 FEET BELOW LAND SURFACE OF WELL SCMWB-5, AND ANALYZED FOR PCBS. TOTAL PCB CONCENTRATIONS FOR SCWMB-5 (0.5-2) WERE 1.60 PPM AND 1.13 PPM (DUPLICATE SAMPLE). SAMPLE SCMWB-5 (2-3.5) HAD A TOTAL PCB CONCENTRATION OF 0.93 PPM. 1 Order number 940620-103843-ROD -001-001 page 4274 set 4 with 100 of 100 items NO VOCS WERE DETECTED IN SAMPLES SCSB-5 (5-6.5) AND SCSB-5A (7.5-9) COLLECTED BELOW THE NORTHWEST WASTE AREA. SEMI-VOLATILE ORGANIC COMPOUNDS AND PESTICIDE COMPOUNDS WERE NOT DETECTED IN ALL THREE SAMPLES. SEVERAL INORGANIC COMPOUNDS WERE DETECTED IN SAMPLES SCSB-5 (5-6.5), SCSB-5A (7.5-9) AND SCST-1. NONE OF THE CONCENTRATIONS DETECTED EXCEEDED THE RANGE OF CONCENTRATIONS IN TABLES 5-30 AND 5-31. GROUND WATER SAMPLES WERE COLLECTED FROM WELL SCMW-5. THE SAMPLE WAS ANALYZED FOR PCBS, VOCS, PH, SPECIFIC CONDUCTANCE, SUSPENDED SOLIDS, ALKALINITY, HARDNESS, CHLORIDES, AND SULFATE. TABLE 5-54 PRESENTS ANALYTICAL RESULTS FOR BOTH SAMPLING ROUNDS. PCBS WERE DETECTED IN WELL SCMW-5 AT A CONCENTRATION OF 0.0075 PPM ON OCTOBER 20, 1988 AND 0.0058 PPM ON JANUARY 17, 1989. SEVERAL VOLATILE ORGANIC COMPOUNDS WERE DETECTED IN GROUND WATER IN AREA C. TRICHLOROETHENE AND TETRACHLOROETHENE WERE THE MOST COMMON COMPOUNDS AND WERE DETECTED IN TEN WELLS. TOTAL VOC CONCENTRATIONS IN THESE TEN WELLS FOR BOTH SAMPLING ROUNDS ARE INCLUDED ON TABLE 5-55. THE WELL (SCMW-5) HAD MUCH LOWER TOTAL VOC CONCENTRATIONS THAN OTHER AREA WELL WATER SAMPLES. AREA D SOIL BORINGS WERE INSTALLED AS PART OF THE REMEDIAL INVESTIGATION TO CONFIRM ACTUAL WASTE PRESENCE AND TO INVESTIGATE HORIZONTAL AND VERTICAL EXTENT OF THE AREA OF WASTE DEPOSITION. TWELVE TOTAL BORINGS WERE ATTEMPTED AT SEVEN LOCATIONS PROPOSED IN THE WORK PLAN. ALL OF THE BORINGS (EXCEPT SDSB-2,8 AND 10) ARE LOCATED IN AREAS OF SUSPECTED WASTE DEPOSITION. TWO BORINGS WERE INSTALLED IN THE AREA OF SDSB-4, AND THREE BORINGS WERE ATTEMPTED IN THE AREA OF BOTH SDSB-1 AND SDSB-5. BURIED DRUMS WERE ENCOUNTERED WHILE BORING IN THE AREA OF SDSB-1 AND SDSB-4. SUBSURFACE SOIL SAMPLING WAS TERMINATED TO AVOID THE RISK OF PUNCTURING DRUMS. SOIL BORING LOCATIONS ARE SHOWN ON PLATE 3-8, AND LITHOLOGIC LOGS. WASTE, IN THE FORM OF SEMI-SOLID TO SOLID RESINOUS MATERIAL, WAS OBSERVED IN BORINGS SDSB-1B, 4, 4A, AND 7. WASTE WAS NOT OBSERVED IN THE EIGHT REMAINING SOIL BORINGS; HOWEVER, SPLIT-SPOON REFUSAL WAS ENCOUNTERED AT 0.5 FEET BELOW LAND SURFACE IN SDSB-1 AND A VOID WAS ENCOUNTERED AT 3.0 TO 4.5 FEET BELOW LAND SURFACE IN SDSB-1A, INDICATING THAT WASTE MAY BE PRESENT IN THESE AREAS. SINCE THE SOIL BORING PROGRAM COULD NOT BE COMPLETED, THE VERTICAL EXTENT OF WASTE IS UNKNOWN, AND THE HORIZONTAL EXTENT OF THE WASTE HAS BEEN ESTIMATED BASED ON MAGNETIC ANOMALIES DETECTED IN THE PRELIMINARY INVESTIGATION. WASTE IN AREA D HAS AN APPROXIMATE SURFACE AREA OF 1,350 1 Order number 940620-103843-ROD -001-001 page 4275 set 4 with 100 of 100 items SQUARE YARDS. BASED ON A WASTE THICKNESS OF 10 FEET THERE COULD BE 4,500 CUBIC YARDS OF WASTE. AFTER THE BORING PROGRAM WAS TERMINATED AN EXPLORATORY TRENCHING PROGRAM WAS INITIATED. SEVERAL DRUMS WERE UNCOVERED LESS THAN THREE FEET BELOW LAND SURFACE IN THE FIRST TRENCH. EXPLORATORY TRENCHING WAS THEN DISCONTINUED TO AVOID PUNCTURING THE DRUMS. A SAMPLE OF SOIL DESIGNATED SDSB-1 WAS TAKEN FROM THE EXCAVATION AND ANALYZED FOR THE HSL PARAMETERS. WASTE COLLECTED FROM SDSB-7 AT 2.0 TO 2.8 FEET BELOW LAND ANALYTICAL RESULTS FOR PARAMETERS DETECTED IN THE WASTE. SEVERAL VOLATILE ORGANIC COMPOUNDS, WERE DETECTED IN WASTE FOUND IN AREA D. TRICHLOROETHENE AND TETRACHLOROETHENE WERE PREVALENT. NO SEMI-VOLATILE OR PESTICIDE COMPOUNDS WERE DETECTED IN THE WASTE. TOTAL PCBS DETECTED IN SDSB-1 (SURFACE) WERE 77,800 PPM. THIS SOIL SAMPLE WAS COLLECTED IN AN AREA OF SPILLED LIQUID DURING ONE BACKHOE EXCAVATION. ALUMINUM, ARSENIC, IRON, AND VANADIUM WERE THE ONLY INORGANIC COMPOUNDS FOUND IN THE WASTE AT CONCENTRATIONS ABOVE THE RANGE IN TABLE 5-31. SURFACE SOIL SAMPLES WERE COLLECTED AND ANALYZED FOR PCBS AND VOCS TO DETERMINE THE EXTENT OF THESE CONSTITUENTS ON THE LAND SURFACE. FORTY-FOUR SURFACE SOIL SAMPLES (SDSS-1 THROUGH SDSS-44) WERE COLLECTED. IN ADDITION TO PCBS AND VOCS, SAMPLE SDSS-1 WAS ANALYZED FOR THE HSL PARAMETERS. TABLE 5-58 SUMMARIZES PARAMETERS DETECTED IN SDSS-1. ANALYTICAL RESULTS FOR PCBS AND VOCS ARE SUMMARIZED ON TABLE 5-59. TOTAL PCB CONCENTRATIONS ARE ALSO SHOWN ON PLATE 3-13. TOTAL PCB CONCENTRATIONS RANGED FROM NONE DETECTED IN SAMPLE 5055-20 TO 1,010 PPM IN SAMPLE SDSS-11. ONLY TWELVE SAMPLES, (SDSS-2, 3, 4, 6, 7, 11, 18, 21, 22, 24, 29, AND 42) EXCEEDED 50 PPM TOTAL PCBS. THESE SAMPLES ARE GROUPED INTO TWO AREAS LOCATED AT THE EASTERN AND SOUTHERN PORTIONS OF AREA 0. VOCS WERE DETECTED IN SEVEN SAMPLES (SDSS-4, 6, 7, 14, 17, 18 AND 29). TRICHLOROETHENE AND TETRACHLOROETHENE WERE THE MOST COMMON COMPOUNDS DETECTED. TOTAL VOC CONCENTRATIONS IN THESE SEVEN SAMPLES RANGE FROM 0.007 PPM TO 0.4 PPM. SURFACE SOIL SAMPLES SDSS-4, 6, 7, 14 AND 17 ARE GROUPED TOGETHER AT THE EAST END OF AREA D. SUBSURFACE SOIL SAMPLES WERE COLLECTED AND ANALYZED TO DETERMINE THE EXTENT OF PCBS BELOW LAND SURFACE AND BELOW THE WASTE. SUBSURFACE SOIL SAMPLING WAS TERMINATED AFTER DRUMS WERE DISCOVERED. TWELVE SOIL BORINGS WERE DRILLED. BORINGS SDSB-2, 5, 5A, 5B, 8 AND 10 DID NOT PENETRATE WASTE. ONE SOIL SAMPLE WAS COLLECTED FROM EACH BORING AND ANALYZED FOR PCBS. ANALYTICAL RESULTS ARE SUMMARIZED ON TABLE 5-60. PCB CONCENTRATIONS DETECTED WERE LOW, RANGING FROM 0.24 PPM TO 8.9 PPM. BORING SDSB-1A PENETRATED WASTE, AND SOIL SAMPLE SDSB-1A (5-6) WAS COLLECTED BELOW THE WASTE AND ANALYZED FOR HSL PARAMETERS. ANALYTICAL 1 Order number 940620-103843-ROD -001-001 page 4276 set 4 with 100 of 100 items RESULTS ARE PRESENTED IN TABLE 5-61. (5-6) WAS 360 PPM. TOTAL PCBS DETECTED IN SDSB-1A SEVERAL VOLATILE ORGANIC COMPOUNDS WERE DETECTED OF WHICH TRICHLOROETHENE WAS THE PRIMARY CONSTITUENT. BIS (2-ETHYLHEXYL) PHTHALATE WAS THE ONLY SEMI-VOLATILE COMPOUND DETECTED. PESTICIDE COMPOUNDS WERE NOT DETECTED. NONE OF THE INORGANIC COMPOUNDS EXCEEDED THE RANGE OF CONCENTRATIONS IN TABLES 5-30 AND 5-31. IN ADDITION TO SOIL BORINGS IN THE VICINITY OF THE WASTE, TWO SOIL SAMPLES WERE COLLECTED AT EACH OF THE FOUR MONITORING WELL LOCATIONS (SDWB-1 THROUGH 4) AT 0 TO 1.5 FEET BELOW LAND SURFACE AND 1.5 TO 3 FEET BELOW LAND SURFACE. THESE SAMPLES WERE ANALYZED FOR PCBS. NO PCBS WERE DETECTED AT SDWB-2. SAMPLE SDWB-1 (0-1.5) HAD A CONCENTRATION OF 113 PPM JUST BELOW THE LAND SURFACE LAND SURFACE (0-1.5 FEET). HOWEVER, THE SAMPLE DIRECTLY BELOW HAD A PCB CONCENTRATION OF 1.3 PPM. THE CONCENTRATION IN THE UNDERLYING SOIL SDWB-3 (1.5-3) WAS 0.290 PPM. TOTAL PCB CONCENTRATIONS AT SDWB-4 INCREASED WITH DEPTH FROM 2 PPM AT SDWB-4 (0-1.5) TO 23.9 PPM IN SDWB-4 (1.5-3). GROUND WATER SAMPLES WERE COLLECTED FROM WELLS SDMW-1,2,3,4. THE TWO SAMPLING ROUNDS WERE ANALYZED FOR PCBS, VOCS, PH, SPECIFIC CONDUCTANCE, SUSPENDED SOLIDS, ALKALINITY, HARDNESS, CHLORIDES, AND SULFATE. TABLE 5-55 PRESENTS ANALYTICAL RESULTS FOR BOTH SAMPLING ROUNDS. PCBS WERE NOT DETECTED IN THE AREA D WELLS. SEVERAL VOLATILE ORGANIC COMPOUNDS WERE DETECTED IN GROUND WATER IN AREA D. TRICHLOROETHENE AND TETRACHLOROETHENE WERE THE MOST COMMON COMPOUNDS AND WERE DETECTED IN TEN WELLS. TOTAL VOC CONCENTRATIONS IN THESE TEN WELLS FOR BOTH SAMPLING ROUNDS ARE INCLUDED ON TABLE 5-55. THE HIGHEST CONCENTRATIONS OF VOCS WERE DETECTED IN AREA D RANGING FROM 0.356 PPM TO 90.8 PPM. AREA E SOIL BORINGS WERE INSTALLED AS PART OF THE REMEDIAL INVESTIGATION TO DETERMINE IF WASTE IS PRESENT IN AREA E. THREE SOIL BORINGS, SESB-1, 2 AND 3, WERE INSTALLED IN AREA E AT LOCATIONS SHOWN ON PLATE 3-6. TOTAL DEPTHS OF BORINGS WERE 16 FEET BELOW LAND SURFACE FOR SESB-1, 15 FEET BELOW LAND SURFACE FOR SESB-2, AND 12-FEET BELOW LAND SURFACE AT SESB-3. EACH OF THE BORINGS WERE TERMINATED AT LEAST FOUR FEET INTO SAPROLITE (AS DEFINED BY REMNANT ROCK STRUCTURE). NO WASTE WAS FOUND IN ANY OF THE BORINGS IN AREA E. CONSEQUENTLY, NO WASTE SAMPLES WERE COLLECTED. SUBSURFACE SOILS WERE COLLECTED FROM THREE SOIL BORINGS IN AREA E TO DETERMINE IF PCBS ARE PRESENT. ONE SOIL SAMPLE FROM EACH BORING WAS COLLECTED AND ANALYZED FOR PCBS. ANALYTICAL RESULTS ARE PRESENTED IN TABLE 5-62. SAMPLE DEPTHS RANGED FROM 3.5 TO 7 FEET BELOW LAND SURFACE. 1 Order number 940620-103843-ROD -001-001 page 4277 set 4 with 100 of 100 items PCB CONCENTRATIONS WERE LOW, RANGING FROM 0.26 TO 14 PPM. PAVED, THEREFORE NO SURFACE SOIL SAMPLES WERE COLLECTED. AREA E IS GROUND WATER SAMPLES WERE OBTAINED FROM WELL SEMW-1. FIRST ROUND SAMPLES WERE ANALYZED FOR PCBS, VOCS, PH, SPECIFIC CONDUCTANCE, SUSPENDED SOLIDS, ALKALINITY, HARDNESS, CHLORIDES, AND SULFATE. SAMPLES WERE COLLECTED FOR INORGANICS ANALYSIS. TABLE 5-63 SUMMARIZES ANALYTICAL RESULTS FOR DETECTED PARAMETERS. SECOND ROUND GROUND WATER SAMPLES WERE ANALYZED FOR VOCS, PCBS, PH, SPECIFIC CONDUCTANCE, SUSPENDED SOLIDS, ALKALINITY, HARDNESS, CHLORIDES, AND SULFATES. PCBS WERE DETECTED IN WELLS SWMW-2,3,4,5,6,7 AND 7A IN BOTH SAMPLING ROUNDS WITH TOTAL PCB CONCENTRATIONS RANGING FROM 0.0032 PPM AT SWMW-3 (JANUARY 1989) TO 0.11 PPM IN WELL SWMW-5, ALSO IN JANUARY, 1989. PCBS WERE DETECTED IN WELL SWMW-8 AND 9 ONLY IN THE SECOND ROUND OF SAMPLES WITH TOTAL PCB CONCENTRATIONS OF 0.014 PPM AND 0.038 PPM, RESPECTIVELY. PCBS WERE NOT DETECTED IN AREA E WELL SEMW-1 OR UPGRADIENT WELL SWMW-1 FOR THE WASTEWATER TREATMENT FACILITY. SEVERAL VOLATILE ORGANIC COMPOUNDS (CHLOROFORM, 1,1-DICHLOROETHANE, 1,1-TRICHLOROETHANE, CARBON TETRACHLORIDE, TRICHLOROETHANE, AND TETRACHLOROETHANE) WERE DETECTED IN WELL SEMW-1 LOCATED IN AREA E, UPGRADIENT OF THE WASTEWATER TREATMENT FACILITY. TOTAL VOCS (EXCLUDING ACETONE) DETECTED IN SEMW-1 WERE 0.10 PPM (OCTOBER 1988) AND 0.107 PPM (JANUARY 1989). IN THE WASTEWATER TREATMENT FACILITY WELLS, TOTAL 1,2-DICHLOROETHENE, TRICHLOROETHENE, AND TETRACHLOROETHENE WERE DETECTED IN WELLS SWMW-2 THROUGH SWMW-9 DURING BOTH SAMPLING EVENTS. IN ADDITION, TRICHLOROETHENE AND TETRACHLOROETHENE WERE DETECTED IN BACKGROUND WELL SWMW-1 DURING THE SECOND SAMPLING ROUND IN JANUARY 1989. THE TRICHLOROETHENE CONCENTRATION DETECTED IN SWMW-1 WAS 0.007 PPM. IN ADDITION TO TOTAL 1,2-DICHLOROETHENE, TRICHLOROETHANE AND TETRACHLOROETHENE, SEVERAL OTHER VOCS (VINYL CHLORIDE, 1,1-DICHLOROETHENE, 1,1-DICHLOROETHANE, CHLOROFORM, 1,2-DICHLOROETHANE, CARBON TETRACHLORIDE AND BENZENE) WERE DETECTED AT LESS FREQUENT OCCURRENCES. TOTAL VOC CONCENTRATIONS AND ARE INCLUDED IN TABLE 5-63. TOTAL VOC CONCENTRATIONS RANGED FROM NONE DETECTED DURING THE FIRST SAMPLING ROUND IN WELL SWMW-1 TO 3.306 PPM IN WELL SWMW-2 IN OCTOBER 1988. TOTAL VOC CONCENTRATIONS IN WELL SWMW-9, LOCATED IMMEDIATELY UPGRADIENT OF THE INACTIVE LAGOON, AND WELLS SWMW-2 AND 3, LOCATED IMMEDIATELY DOWNGRADIENT OF THE INACTIVE LAGOON, RANGED FROM 0.608 PPM IN SWMW-3 TO 3.306 PPM IN SWMW-2. WELL SWMW-9 IS LOCATED APPROXIMATELY 45 FEET UPGRADIENT OF THE INACTIVE LAGOON. THE PRESENCE OF VOCS MAY BE THE RESULT OF DIRECT HYDROLOGIC CONNECTION (THROUGH FRACTURES) BETWEEN THE INACTIVE LAGOON AND THE SCREENED PORTION OF WELL SWMW-9. WELL SWMW-4, 1 Order number 940620-103843-ROD -001-001 page 4278 set 4 with 100 of 100 items LOCATED DOWNGRADIENT OF THE INACTIVE LAGOON AND IMMEDIATELY UPGRADIENT OF THE STABILIZATION LAGOON, HAD TOTAL VOC CONCENTRATIONS OF 1.101 PPM, 1.86 PPM AND 1.95 PPM (DUPLICATE SAMPLE). TOTAL VOCS IN WATER TABLE WELLS SWMW-5,6,7 AND 8 RANGED FROM 0.095 PPM IN SWMW-8 TO 2.15 PPM IN SWMW-5 AND SHOW DECREASES IN CONCENTRATION, WITH DISTANCE DOWNGRADIENT FROM THE STABILIZATION LAGOON; HOWEVER, WELL SWMW-7A, SCREENED BELOW THE WATER TABLE ON TOP OF BEDROCK, HAD HIGHER TOTAL VOC CONCENTRATIONS THAN ADJACENT WATER TABLE WELL SWMW-7. DETECTED CONCENTRATIONS IN SWMW-7A (1.96 PPM AND 2.57 PPM) WERE THE HIGHEST OF THE FIVE DOWNGRADIENT WELLS FOR THE RESPECTIVE SAMPLING PERIODS. DURING THE FIRST ROUND SAMPLING IN OCTOBER 1988, WELLS SWMW 4 AND SWMW-6 WERE ANALYZED FOR SEMI-VOLATILE AND PESTICIDE ORGANIC COMPOUNDS. NO SEMI-VOLATILE COMPOUNDS WERE DETECTED. HEPTACHLOR EPOXIDE WAS THE ONLY PESTICIDE ORGANIC COMPOUND DETECTED IN SWMW-4 (0.00021 PPM) AND LOW CONCENTRATIONS. SEMI-VOLATILE AND PESTICIDE ORGANICS COMPOUNDS WERE NOT INCLUDED IN- THE LIST OF ANALYTICAL PARAMETERS FOR SECOND ROUND SAMPLES COLLECTED IN JANUARY 1989. IN OCTOBER 1988, SAMPLES WERE OBTAINED FROM DOWNGRADIENT WELL SWMW-4 AND 6 FOR INORGANIC COMPOUND ANALYSIS. TWELVE COMPOUNDS WERE DETECTED IN THE SAMPLE FOR WELL SWMW-4 (SEE TABLE 5-63). TEN INORGANIC COMPOUNDS WERE DETECTED IN THE SAMPLE FOR SWMW-6. CONCENTRATIONS IN BOTH THE SAMPLES WERE LOW, THEREFORE, METALS WERE NOT INCLUDED IN THE ANALYTICAL PARAMETERS FOR THE SECOND ROUND GROUND WATER SAMPLES COLLECTED IN JANUARY 1989. EPA WAS NOTIFIED OF THE ELIMINATION OF INORGANIC, SEMI-VOLATILE, AND PESTICIDE ORGANIC COMPOUNDS FROM THE ANALYTICAL PARAMETER LIST FOR SECOND ROUND SAMPLES IN A LETTER DATED JANUARY 10, 1989. AREA F SOIL BORINGS AND EXPLORATORY TRENCHES WERE INSTALLED AS PART OF THE REMEDIAL INVESTIGATION TO DETERMINE IF WASTE WAS PRESENT, AND TO DETERMINE THE HORIZONTAL AND VERTICAL EXTENT OF WASTE. A TOTAL OF SIX SOIL BORINGS WERE DRILLED IN AREA F. SOIL BORING LOCATIONS ARE SHOWN ON PLATE 3-8. ALUMINUM HYDROXIDE SLUDGE WAS FOUND IN BORINGS SFSB-2 AND 2A. SLUDGE WAS ALSO FOUND IN THE AREA OFF BORING SFSB-3. NO WASTE WAS FOUND IN BORINGS SFSB-1, 1A AND 1B. FOLLOWING THE INSTALLATION OF SOIL BORINGS, NINE EXPLORATORY TRENCHES WERE EXCAVATED TO FURTHER DETERMINE THE VERTICAL AND HORIZONTAL EXTENT OF SLUDGE IN THE VICINITY OF SFSB-2. TRENCH LOCATIONS ARE SHOWN ON PLATE 3-9. TRENCHES WERE EXCAVATED WITH A BACKHOE WITH DEPTHS RANGING FROM 1.5 TO 9 FEET BELOW LAND SURFACE. THE SLUDGE IS DEPOSITED IN AN ELONGATED AREA APPROXIMATELY 23 FEET WIDE AND 75 FEET LONG COMPRISING AN AREA OF ABOUT 180 SQUARE YARDS. CROSS SECTIONS OF THE AREA OF WASTE 1 Order number 940620-103843-ROD -001-001 page 4279 set 4 with 100 of 100 items DEPOSITION ARE SHOWN ON PLATE 3-9. SLUDGE DEPOSITED IN THE VICINITY OF SFSB-2 IS MOSTLY COVERED WITH SOIL FILL. DEPTH TO THE SLUDGE RANGES FROM LAND SURFACE TO S FEET BELOW LAND SURFACE. SLUDGE THICKNESS RANGED FROM 0.2 TO 5 FEET. THE ESTIMATED VOLUME OF WASTE IN AREA F IS 200 CUBIC YARDS. A SAMPLE OF SLUDGE COLLECTED FROM SOIL BORINGS SFSB-2A AT 4 TO 6 FEET BELOW LAND SURFACE DESIGNATED SFSB-2A (4-6) WAS ANALYZED FOR THE HSL PARAMETERS. ANALYTICAL RESULTS ARE PRESENTED IN TABLE 5-64. TRICHLOROETHENE AND TETRACHLOROETHENE WERE THE ONLY VOLATILE ORGANIC COMPOUNDS DETECTED AND HAD CONCENTRATIONS LESS THAN 1 PPM. SEMI-VOLATILE AND PESTICIDE COMPOUNDS WERE NOT DETECTED. PCBS WERE DETECTED IN THE WASTE WITH A TOTAL PCB CONCENTRATION OF 20,900 PPM. A SAMPLE OF WASTE WAS ALSO COLLECTED 4 TO 6 FEET BELOW LAND SURFACE FROM A BORE HOLE ADJACENT TO SFSB-2A DESIGNATED SFSB-2W (4-6) AND ANALYZED FOR PCBS. AROCLORS 1248 AND 1254 WERE DETECTED WITH A TOTAL PCB CONCENTRATION OF 16,500 PPM. ALUMINUM WAS THE ONLY INORGANIC COMPOUND DETECTED AT CONCENTRATIONS ABOVE THE RANGE IN TABLE 5-31. SUBSURFACE SOILS WERE ANALYZED TO DETERMINE THE PRESENCE OF PCBS AND OTHER CONSTITUENTS BELOW LAND SURFACE AND BELOW THE WASTE. SURFACE SOIL SAMPLES WERE COLLECTED AND ANALYZED TO DETERMINE THE EXTENT OF PCBS ON THE LAND SURFACE. ELEVEN SURFACE SOIL SAMPLES (SFSS-1 THROUGH WAS ANALYZED FOR THE HSL PARAMETERS. TABLE DETECTED IN SFSS-1. SAMPLES SFSS-2 THROUGH ONLY. PCB CONCENTRATIONS ARE SUMMARIZED IN CONCENTRATIONS RANGED FROM NONE DETECTED IN PPM DETECTED IN SFSS-5. ONLY FOUR SAMPLES, 50 PPM. 11) WERE COLLECTED. SFSS-1 5-65 SUMMARIZES PARAMETERS 11 WERE ANALYZED FOR PCBS TABLE 5-66. TOTAL PCB SOIL SAMPLES SFSS-2 TO 632 SFSS-4, S, 6 AND 9, EXCEEDED IN ADDITION TO WASTE SAMPLES SFSB-2A (4-6) AND SFSB-2W (4-6), NINE SUBSURFACE SOIL SAMPLES WERE COLLECTED FOR ANALYSIS. ONE SAMPLE, SFSB-2 (9.5-11.5) COLLECTED BELOW THE WASTE, WAS ANALYZED FOR THE HSL PARAMETERS. THE REMAINING SAMPLES WERE ANALYZED FOR PCBS ONLY. ANALYTICAL RESULTS FOR PCBS ARE PRESENTED IN TABLE 5-67. THE ADDITIONAL PARAMETERS DETECTED IN THE HSL ANALYSIS OF SAMPLE SFSB-2 (9.5-11.5) ARE PRESENTED IN TABLE 5-68. NONE OF THE SUBSURFACE SOIL SAMPLES HAD TOTAL PCB CONCENTRATIONS GREATER THAN 50 PPM. BORINGS SFSB-1, 1A AND 1B WERE DRILLED IN AN AREA OF SUSPECTED WASTE DEPOSITION. NO WASTE WAS OBSERVED IN THESE BOREHOLES. A SOIL SAMPLE WAS COLLECTED AT 4 TO 6 FEET BELOW LAND SURFACE IN EACH BORING AND ANALYZED FOR PCBS. TOTAL PCB CONCENTRATIONS IN THESE SAMPLES WERE 0.077 PPM, 1.45 PPM AND NONE DETECTED, RESPECTIVELY. BORINGS SFSB-2 AND 2A WERE DRILLED THROUGH THE AREA OF WASTE DEPOSITION. SAMPLES SFSB-2 (8-9.5), SFSB-2 (9.5-11.5) AND SFSB-2A (6-8), WERE COLLECTED BENEATH THE WASTE. TOTAL PCB CONCENTRATIONS TO 3.5 FEET BELOW THE WASTE, TO 0.3 PPM IN SAMPLE SFSS-2 1 Order number 940620-103843-ROD -001-001 page 4280 set 4 with 100 of 100 items (9.5-11.5), COLLECTED 3.5 TO 5.5 FEET BELOW THE WASTE. TOTAL PCB CONCENTRATIONS IN BORING SFSB-2A DECREASED FROM 20,900 PPM DETECTED IN THE WASTE TO 24.1 PPM DETECTED IN THE UNDERLYING SOIL SAMPLE. SAMPLE SFSB-3 (3.5-5) WAS COLLECTED IN AN AREA WHERE NON-PCB BEARING WASTE SLUDGE WAS DISPOSED. NO PCBS WERE DETECTED IN THIS SAMPLE. SAMPLES SFWB-6 (0-1.5) AND SFWB(1.5-3) WERE COLLECTED AT THE BORING LOCATION FOR WELL SFMW-6. NO PCBS WERE DETECTED IN THESE SAMPLES. IN ADDITION TO PCBS, SUBSURFACE SOIL SAMPLE SFSB-2 (9.5-11.5) WAS ANALYZED FOR THE HSL PARAMETERS. ANALYTICAL RESULTS FOR DETECTED PARAMETERS ARE INCLUDED IN TABLE 5-68. ONE SEMI-VOLATILE COMPOUND, BIS (2-ETHYLHEXYL) PHTHALATE, WAS DETECTED AT 1.5 PPM. PESTICIDES WERE NOT DETECTED. NONE OF THE INORGANIC COMPOUNDS EXCEEDED THE RANGE OF CONCENTRATIONS IN TABLES 5-30 AND 5-31. GROUND WATER SAMPLES WERE COLLECTED FROM WELL SFMW-6. BOTH SAMPLING ROUNDS WERE ANALYZED FOR PCBS, VOCS, PH, SPECIFIC CONDUCTANCE, SUSPENDED SOLIDS, ALKALINITY, HARDNESS, CHLORIDES, AND SULFATE. TABLE 5-55 PRESENTS ANALYTICAL RESULTS FOR BOTH SAMPLING ROUNDS. PCBS WERE NOT DETECTED IN THE AREA F WELL. SEVERAL VOLATILE ORGANIC COMPOUNDS WERE DETECTED IN GROUND WATER IN AREA F. TRICHLOROETHENE AND TETRACHLOROETHENE WERE THE MOST COMMON COMPOUNDS AND WERE DETECTED IN TEN WELLS. TOTAL VOC CONCENTRATIONS IN THESE TEN WELLS FOR BOTH SAMPLING ROUNDS ARE INCLUDED ON TABLE 5-55 AND SHOWN ON PLATE 3-15. THE WELL HAD MUCH LOWER TOTAL VOC CONCENTRATIONS THAN THE OTHER AREA WELL SAMPLES. AREA G PRELIMINARY CONSTITUENT SOURCE INVESTIGATIONS WERE PERFORMED AND SUSPECTED AREAS OF WASTE DEPOSITION WERE IDENTIFIED. TWENTY-SEVEN SOIL BORINGS WERE DRILLED TO DETERMINE THE VERTICAL AND HORIZONTAL EXTENT OF WASTE, IF PRESENT. NONE OF THE BORINGS PENETRATED WASTE. SOIL BORING LOCATIONS ARE SHOWN ON PLATE 3-8. SOIL BORING DEPTHS RANGED FROM FIVE TO SIX FEET BELOW LAND SURFACE. THERE WERE NO VISIBLE WASTE PRESENT IN ANY OF THE SOIL BORINGS. THREE TRENCHES, SGST-1, 2 AND 3, WERE EXCAVATED WITH A BACKHOE TO VERIFY THAT WASTE IS NOT PRESENT IN AREA G. TRENCHES SGST-1 AND 2 ARE 70 AND 59 FEET LONG, RESPECTIVELY, AND TRANSECT AREA G ACROSS SUSPECTED AREAS OF WASTE DEPOSITION IDENTIFIED IN THE RI WORK PLAN. TRENCH SGST-3 WAS EXCAVATED ACROSS A BERM LOCATED AT THE EAST END OF AREA G. NO VISIBLE SIGNS OF WASTE WERE OBSERVED IN THE TRENCHES. SUBSURFACE SOIL SAMPLES WERE COLLECTED AND ANALYZED TO DETERMINE IF PCBS ARE PRESENT BELOW LAND SURFACE. SURFACE SOIL SAMPLES WERE COLLECTED TO DETERMINE THE EXTENT OF PCBS ON THE LAND SURFACE. 1 Order number 940620-103843-ROD -001-001 page 4281 set 4 with 100 of 100 items TWENTY-NINE SURFACE SOIL SAMPLES (SGSS-1 THROUGH 29) WERE COLLECTED AT LOCATIONS SHOWN ON PLATE 3-13. SGSS-1 WAS ANALYZED FOR THE HSL PARAMETERS. PARAMETERS DETECTED IN SGSS-1 ARE SUMMARIZED IN TABLE 5-69. SAMPLES SGSS-2 THROUGH 29 WERE ANALYZED FOR PCBS ONLY. PCB CONCENTRATIONS ARE SUMMARIZED IN TABLE 5-70 AND PRESENTED ON PLATE 3-13. TOTAL PCB CONCENTRATIONS RANGED FROM NONE DETECTED, IN SAMPLES SGSS-5, 7, 16, 17, 18, TO 3,800 PPM, DETECTED IN SGSS-25. ONLY FOUR SAMPLES, SGSS-15 (50.4 PPM), SGSS-25 (3800 PPM), SGSS-26 (1500 PPM) AND SGSS-29 (99 PPM), EXCEED 50 PPM. SAMPLE SGSS-25 WAS COLLECTED FROM AN EARTHEN BERM THAT EXTENDS EASTWARD FROM AREA G INTO AREA H. THIS BERM APPEARS TO HAVE BEEN FORMED AS A RESULT OF REMOVING SOIL FROM A CLEARED AREA IN AREA H AND THE SOUTHEAST CORNER OF AREA G. SAMPLE SGSS-26 IS LOCATED IN THIS CLEARED AREA. (TEN SURFACE SOILS COLLECTED FROM THE CLEARED AREA IN AREA H ALSO EXCEED 50 PPM TOTAL PCBS.) SURFACE SOIL SAMPLES SGSS-15 AND SGSS-29 ARE LOCATED IN SEPARATE AREAS, AND ARE LOCATED IN THE VICINITY OF SAMPLES WITH MUCH LOWER CONCENTRATIONS. TWENTY-FOUR SUBSURFACE SOIL SAMPLES WERE COLLECTED TO DETERMINE THE PRESENCE OF PCBS AND OTHER CONSTITUENTS IN SUBSURFACE SOILS. TWO SAMPLES, SGSB-5 (4-6) AND TRENCH 3 (2.5-4), WERE ANALYZED FOR THE HSL PARAMETERS. THE REMAINING SAMPLES WERE ANALYZED FOR PCBS ONLY. ANALYTICAL RESULTS FOR PCBS ARE PRESENTED IN TABLE 5-71. ADDITIONAL PARAMETERS DETECTED IN THE HSL ANALYSIS ARE SUMMARIZED IN TABLE 5-72. PCBS WERE DETECTED IN ONLY SEVEN OF THE TWENTY-FOUR SAMPLES COLLECTED. SAMPLES SGSB-11 (4-6), SGSB-11A (4-6) AND TRENCH 3 (2.5-6) HAD TOTAL PCB CONCENTRATIONS OF 74 PPM, 7,000 PPM AND 8,000 PPM AND ARE THE ONLY SAMPLES THAT EXCEEDED 50 PPM TOTAL PCBS. THESE THREE SAMPLES WERE COLLECTED FROM THE BERM. TABLE 5-73 SUMMARIZES ANALYTICAL RESULTS FOR PARAMETERS OTHER THAN PCBS DETECTED IN THE HSL ANALYSIS OF SAMPLES TRENCH-3 (2.5-4) AND SGSB-5 (4-6). SEMI-VOLATILE AND PESTICIDE ORGANIC COMPOUNDS TRICHLOROETHENE AND TETRACHLOROETHENE WERE DETECTED IN SAMPLE TRENCH-3 (2.5-4). THESE COMPOUNDS WERE ALSO DETECTED IN THE ASSOCIATED ANALYTICAL BLANK SAMPLES. THE INORGANIC COMPOUND COPPER EXCEEDED THE RANGE OF CONCENTRATIONS ON TABLES 5-30 AND 5-31. SILVER WAS ONLY 0.1 PPM ABOVE THE RANGE OF CONCENTRATIONS ON TABLE 5-30. THE SILVER CONCENTRATIONS MAY REFLECT NATURALLY OCCURRING CONCENTRATIONS. TWO ADDITIONAL SUBSURFACE SOIL SAMPLES WERE COLLECTED AT 0 TO 1.5 FEE BELOW LAND SURFACE AND 1.5 TO 3 FEET BELOW LAND SURFACE AT WELL BORINGS FOR WELLS SGMW-7, 8 AND 9. THESE SAMPLES WERE ANALYZED FOR PCBS ONLY. ONE SAMPLE, SGMW-7 (0-1.5), HAD A TOTAL PCB CONCENTRATION OF 0.037 PPM, AND IS THE ONLY WELL BORING SAMPLE IN WHICH PCBS WERE DETECTED. GROUND WATER SAMPLES WERE COLLECTED FROM WELLS SGMW-7, 8, 9. BOTH SAMPLING ROUNDS WERE ANALYZED FOR PCBS, VOCS, PH, SPECIFIC CONDUCTANCE, 1 Order number 940620-103843-ROD -001-001 page 4282 set 4 with 100 of 100 items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rder number 940620-103843-ROD -001-001 page 4283 set 4 with 100 of 100 items EIGHT SUBSURFACE SOIL SAMPLES WERE COLLECTED TO DETERMINE IF PCBS AND OTHER CONSTITUENTS ARE PRESENT IN SUBSURFACE SOILS. SAMPLE SHSB-5 (4-5) WAS ANALYZED FOR THE HSL PARAMETERS. THE REMAINING SAMPLES WERE ANALYZED FOR PCBS ONLY. ANALYTICAL RESULTS FOR PCBS ARE PRESENTED IN TABLE 5-76. ADDITIONAL PARAMETERS DETECTED IN THE HSL ANALYSIS OF SHSB-5 (4-5) ARE PRESENTED IN TABLE 5-77. ONLY TWO SAMPLES HAD PCBS DETECTED. SAMPLE SHSB-4 (6-8), COLLECTED IN AN EARTHEN BERM LOCATED NORTH OF THE CLEARED AREA, HAD A TOTAL PCB CONCENTRATION OF 4.4 PPM. SAMPLE SHSB-2 (4-5.5) COLLECTED IN THE CLEARED AREA HAD A CONCENTRATION OF 190 PPM. THIS WAS THE ONLY SAMPLE TO EXCEED 50 PPM TOTAL PCBS. THERE WERE NO SEMI-VOLATILE ORGANIC, PESTICIDE ORGANIC OR PCB COMPOUNDS DETECTED IN THE HSL ANALYSIS OF SAMPLE SHSB-5B (4-5). SILVER WAS THE ONLY INORGANIC COMPOUND TO EXCEED THE RANGE OF CONCENTRATIONS IN TABLE 5-30. GROUND WATER SAMPLES WERE COLLECTED FROM WELL SHMW-10. BOTH SAMPLING ROUNDS WERE ANALYZED FOR PCBS, VOCS, PH, SPECIFIC CONDUCTANCE, SUSPENDED SOLIDS, ALKALINITY, HARDNESS, CHLORIDES, AND SULFATE. TABLE 5-55 PRESENTS ANALYTICAL RESULTS FOR BOTH SAMPLING ROUNDS. PCBS WERE NOT DETECTED IN THE AREA H WELLS. SEVERAL VOLATILE ORGANIC COMPOUNDS WERE DETECTED IN GROUND WATER IN AREA H. TRICHLOROETHENE AND TETRACHLOROETHENE WERE THE MOST COMMON COMPOUNDS AND WERE DETECTED IN TEN WELLS. TOTAL VOC CONCENTRATIONS IN THESE TEN WELLS FOR BOTH SAMPLING ROUNDS ARE INCLUDED ON TABLE 5-55. WELL SHMW-10, LOCATED SOUTH AND DOWNGRADIENT OF AREA H, HAD THE HIGHEST CONCENTRATIONS DETECTED ON TOP OF THE RIDGE OUTSIDE OF AREA D. SEPTIC DRAIN FIELD THERE ARE THREE SEPTIC TANK DRAIN FIELDS ON THE SANGAMO WESTON PROPERTY. TWO FIELDS ARE LOCATED ADJACENT TO EACH OTHER NORTH OF THE MANUFACTURING FACILITY. THESE DRAIN FIELDS ARE ADDRESSED COLLECTIVELY AS THE NORTH DRAIN FIELD. THE THIRD DRAIN FIELD IS LOCATED SOUTH OF THE MANUFACTURING BUILDING AND IS REFERRED TO AS THE SOUTH DRAIN FIELD. THESE DRAIN FIELDS WERE USED FOR DEPOSITION OF SANITARY WASTEWATERS FROM THE PLANT. SUBSURFACE SOILS WERE ANALYZED TO DETERMINE THE PRESENCE OF PCBS AND OTHER CONSTITUENTS BELOW THE SEPTIC DRAIN FIELDS. BORINGS WERE EXTENDED TO TWENTY FEET BELOW LAND SURFACE OR AUGER REFUSAL, WHICHEVER WAS SHALLOWER. SOIL SAMPLES WERE RETAINED AT ABOUT FIVE FEET BELOW LAND SURFACE, TEN FEET BELOW LAND SURFACE, AND THE BOTTOM OF THE BOREHOLE. BORINGS SSSB-2 AND SSSB-2B ENCOUNTERED SHALLOW AUGER REFUSAL; THEREFORE, THESE BOREHOLES WERE SAMPLED AT 4 TO 5 FEET AND 3.5 TO 4 FEET BELOW LAND 1 Order number 940620-103843-ROD -001-001 page 4284 set 4 with 100 of 100 items SURFACE, RESPECTIVELY. SOIL BORINGS SSSB-1, 2, 2B, 3C AND 4B ARE LOCATED IN THE SOUTH DRAIN FIELD. BORINGS SSSB-5, 6C,7,9 AND 9B ARE LOCATED IN THE NORTH DRAIN FIELD. A TOTAL OF TWENTY-FIVE SUBSURFACE SOIL SAMPLES WERE COLLECTED. SAMPLES SSSB-4B (18-20) AND SSSB-7 (17-20) WERE ANALYZED THE HSL PARAMETERS. THE REMAINING SAMPLES WERE ANALYZED FOR PCBS ONLY. TABLE 5-78 SUMMARIZES PCB CONCENTRATIONS DETECTED. HSL PARAMETERS DETECTED IN SSSB-4B (18-20) AND SSSB-7 (17-20) ARE PRESENTED IN TABLE 5-79. PCBS WERE DETECTED IN EIGHT OF THE TEN SAMPLES COLLECTED IN THE SOUTH DRAIN FIELD. WITH THE EXCEPTION OF BORING SSSB-2B, PCBS WERE DETECTED IN THE BOTTOM SAMPLE OF EACH BORING (8 TO 20 FEET BELOW LAND SURFACE). SAMPLE SSSB-4B (18-20) COLLECTED AT 18 TO 20 FEET BELOW LAND SURFACE HAD A PCB CONCENTRATION OF 10 PPM (AROCLOR 1016). THIS WAS THE HIGHEST CONCENTRATION DETECTED. LESS THAN 1 PPM. THE REMAINING SAMPLES HAD PCB CONCENTRATIONS NO PCBS WERE DETECTED IN THE THREE SAMPLES COLLECTED IN BORING SSSB-5 LOCATED IN THE NORTH DRAIN FIELD. SAMPLE SSSB-7 (17-20) WAS THE ONLY SAMPLE IN BORING SSSB-7 THAT HAD PCBS DETECTED. PCBS WERE ALSO DETECTED IN THE ASSOCIATED METHOD BLANK SAMPLE (PREPARED BY THE LABORATORY) AT 0.25 PPM, THUS THIS CONCENTRATION MAY NOT BE REPRESENTATIVE OF THE SAMPLE. PCBS WERE DETECTED IN ONLY ONE SAMPLE IN BORING SSSB-8, AT A DEPTH OF 5-6 FEET. THIS WAS THE SHALLOWEST SAMPLE COLLECTED. PCBS WERE DETECTED IN ALL THREE SAMPLES IN BORING SSSB-9B. PCB CONCENTRATIONS IN THE NORTH DRAIN FIELD WERE ALL WELL BELOW 1 PPM, RANGING FROM NONE DETECTED TO 0.377 PPM. IN ADDITION TO PCBS, SAMPLE SSSB-4B (18-20), COLLECTED FROM THE SOUTH DRAIN FIELD.AND SAMPLE SSSB-7 (17-20), COLLECTED FROM THE NORTH DRAIN FIELD, WERE ANALYZED FOR THE HSL PARAMETERS. THE SEMI-VOLATILE COMPOUND DI-N-BUTYL PHTHALATE WAS DETECTED IN BOTH SAMPLES, AND BIS (ETHYLHEXYL) PHTHALATE WAS DETECTED IN SSSB-4B (18-20). NO PESTICIDE COMPOUNDS WERE DETECTED. THE INORGANIC COMPOUNDS WERE ALL WITHIN THE RANGE OF CONCENTRATIONS IN TABLES 5-30 AND 5-31. WASTEWATER TREATMENT FACILITY THE WASTEWATER TREATMENT FACILITY CONSISTED OF A PRIMARY SETTLING BASIN AND A LARGE STABILIZATION LAGOON. THE TREATMENT SYSTEM WAS PRIMARILY DESIGNED FOR NEUTRALIZATION OF ACID SOLUTIONS USED IN THE ETCHING AND FORMING PROCESS AND FOR THE PRECIPITATION OF DISSOLVED MATERIALS SUCH AS ALUMINUM. THE ALUMINUM PRECIPITATES SETTLED IN THE PRIMARY SETTLING BASIN. THE FACILITY WAS MODIFIED BY REPLACING THE PRIMARY BASIN (NOW REFERRED TO AS THE INACTIVE LAGOON) WITH A CONCRETE LINED EQUALIZATION BASIN. THE INACTIVE LAGOON IS NO LONGER USED FOR WASTEWATER TREATMENT. THE STABILIZATION BASIN IS STILL IN USE. SIX SOIL BORINGS (SWSB-1 THROUGH 6) WERE INSTALLED IN THE INACTIVE 1 Order number 940620-103843-ROD -001-001 page 4285 set 4 with 100 of 100 items LAGOON TO DETERMINE THE VERTICAL EXTENT OF SLUDGE. BORINGS WERE DRILLED USING HOLLOW STEM AUGERS WITH SPLIT SPOON SOIL SAMPLES COLLECTED CONTINUOUSLY. TOTAL DEPTH TO THE BOTTOM OF THE SLUDGE RANGED FROM ELEVEN FEET BELOW LAND SURFACE AT BORING SWSB-1 TO THIRTEEN FEET BELOW LAND SURFACE AT BORING SWSB-5. THE SURFACE AREA OF THE WASTE IS ABOUT 1,380 SQUARE YARDS. THE ESTIMATED TOTAL VOLUME OF SLUDGE IN THE INACTIVE LAGOON IS 4,400 CUBIC YARDS. SLUDGE FROM EACH BORING WAS COMPOSITED INTO ONE SAMPLE AND ANALYZED FOR PCBS. ADDITIONALLY, SLUDGE FROM BORING SWSB-2 WAS ANALYZED FOR THE HSL PARAMETERS. ANALYTICAL RESULTS ARE PRESENTED IN TABLE 5-80. THE COMPOSITE SLUDGE SAMPLE HAD A TOTAL PCB CONCENTRATION OF 23,200 PPM AND 26,400 PPM (DUPLICATE SAMPLE). SAMPLE SWSB-2 (2-6) HAD A TOTAL PCB CONCENTRATION OF 187 PPM. THE VOLATILE ORGANIC COMPOUND TETRACHLOROETHENE WAS DETECTED IN THE WASTE. NO SEMI-VOLATILE OR PESTICIDE COMPOUNDS WERE DETECTED. ALL OF THE INORGANIC COMPOUNDS EXCEPT ALUMINUM AND ARSENIC WERE WELL WITHIN THE RANGE OF CONCENTRATIONS IN TABLES 5-30 AND 5-31. SUBSURFACE SOIL SAMPLES WERE COLLECTED FROM BELOW THE ALUMINUM HYDROXIDE SLUDGE IN THE INACTIVE LAGOON. NINE SUBSURFACE SOIL SAMPLES WERE COLLECTED. SAMPLE SWSB-5A (17-19) WAS ANALYZED FOR THE HSL PARAMETERS. THE REMAINING SAMPLES WERE ANALYZED FOR PCBS ONLY. ANALYTICAL RESULTS FOR PCBS ARE PRESENTED IN TABLE 5-81. HSL PARAMETERS DETECTED IN SWSB-5A (17-19) ARE PRESENTED IN TABLE 5-82. PCBS WERE DETECTED IN ALL NINE SAMPLES, RANGING FROM 23.2 PPM IN SWSB-1 (14-16) TO 34,300 PPM DETECTED IN SWSB-6 (11.5-12). FIVE OF THESE SAMPLES EXCEEDED 50 PPM TOTAL PCBS. IN ADDITION TO PCBS, SAMPLE SWSB-5A (17-19) WAS ANALYZED FOR THE HSL PARAMETERS. TOTAL XYLENE WAS DETECTED AT 0.06 PPM IN A DILUTED SAMPLE. NO VOCS WERE DETECTED IN THE UNDILUTED SAMPLE. NO SEMI-VOLATILE OR PESTICIDE COMPOUNDS WERE DETECTED. ALL OF THE INORGANIC COMPOUNDS DETECTED WERE WITHIN THE RANGE OF CONCENTRATIONS IN TABLES 5-30 AND 5-31. EPA SAMPLED SEDIMENTS IN THE STABILIZATION LAGOON ON MAY 10, 1989. RESULTS OF THAT INVESTIGATION ARE SUMMARIZED IN TABLE 5-83. GROUND WATER SAMPLES WERE OBTAINED FROM WELL SWMW-1. FIRST ROUND SAMPLES WERE ANALYZED FOR PCBS, VOCS, PH, SPECIFIC CONDUCTANCE, SUSPENDED SOLIDS, ALKALINITY, HARDNESS, CHLORIDES, AND SULFATE. WELLS SWMW-4 AND 6 WERE ALSO ANALYZED FOR ALL OF THE HSL PARAMETERS. BOTH FILTERED AND NONFILTERED SAMPLES WERE COLLECTED FOR INORGANICS ANALYSIS. TABLE 5-63 SUMMARIZES ANALYTICAL RESULTS FOR DETECTED PARAMETERS. SECOND ROUND GROUND WATER SAMPLES WERE ANALYZED FOR VOCS, PCBS, PH, SPECIFIC CONDUCTANCE, SUSPENDED SOLIDS, ALKALINITY, HARDNESS, CHLORIDES, AND SULFATES. 1 Order number 940620-103843-ROD -001-001 page 4286 set 4 with 100 of 100 items PCBS WERE DETECTED IN WELLS SWMW-2,3,4,5,6,7 AND 7A IN BOTH SAMPLING ROUNDS WITH TOTAL PCB CONCENTRATIONS RANGING FROM 0.0032 PPM AT SWMW-3 (JANUARY 1989) TO 0.11 PPM IN WELL SWMW-5, ALSO IN JANUARY, 1989. PCBS WERE DETECTED IN WELL SWMW-8 AND 9 ONLY IN THE SECOND ROUND OF SAMPLES WITH TOTAL PCB CONCENTRATIONS OF 0.014 PPM AND 0.038 PPM, RESPECTIVELY. PCBS WERE NOT DETECTED IN AREA E WELL SEMW-1 OR UPGRADIENT WELL SWMW-1 FOR THE WASTEWATER TREATMENT FACILITY. SEVERAL VOLATILE ORGANIC COMPOUNDS (CHLOROFORM, 1,1-DICHLOROETHANE, 1,1,1-TRICHLOROETHANE, CARBON TETRACHLORIDE TRICHLOROETHENE, AND TETRACHLOROETHENE) WERE DETECTED IN WELL SEMW-1 LOCATED IN AREA E, UPGRADIENT OF THE WASTEWATER TREATMENT FACILITY. TOTAL VOCS (EXCLUDING ACETONE) DETECTED IN SEMW-1 WERE 0.10 PPM (OCTOBER 1988) AND 0.107 PPM (JANUARY 1989). IN THE WASTEWATER TREATMENT FACILITY WELLS, TOTAL 1,2-DICHLOROETHENE, TRICHLOROETHENE, AND TETRACHLOROETHENE WERE DETECTED IN WELLS SWMW-2 THROUGH SWMW-9 DURING BOTH SAMPLING EVENTS. IN ADDITION, TRICHLOROETHENE AND TETRACHLOROETHENE WERE DETECTED IN BACKGROUND WELL SWMW-1 DURING THE SECOND SAMPLING ROUND IN JANUARY 1989. THE TRICHLOROETHENE CONCENTRATION DETECTED IN SWMW-1 WAS 0.007 PPM. IN ADDITION TO TOTAL 1,2-DICHLOROETHENE, TRICHLOROETHANE AND TETRACHLOROETHENE, SEVERAL OTHER VOCS (VINYL CHLORIDE, 1,1-DICHLOROETHENE, 1,1-DICHLOROETHANE, CHLOROFORM, 1,2-DICHLOROETHANE, CARBON TETRACHLORIDE AND BENZENE) WERE DETECTED AT LESS FREQUENT OCCURRENCES. TOTAL VOC CONCENTRATIONS ARE INCLUDED IN TABLE 5-63. TOTAL VOC CONCENTRATIONS RANGED FROM NONE DETECTED DURING THE FIRST SAMPLING ROUND IN WELL SWMW-1 TO 3.306 PPM IN WELL SWMW-2 IN OCTOBER 1988. TOTAL VOC CONCENTRATIONS IN WELL SWMW-9, LOCATED IMMEDIATELY UPGRADIENT OF THE INACTIVE LAGOON, AND WELLS SWMW-2 AND 3, LOCATED IMMEDIATELY DOWNGRADIENT OF THE INACTIVE LAGOON, RANGED FROM 0.608 PPM IN SWMW-3 TO 3.306 PPM IN SWMW-2. WELL SWMW-9 IS LOCATED APPROXIMATELY 45 FEET UPGRADIENT OF THE INACTIVE LAGOON. THE PRESENCE OF VOCS MAY BE THE RESULT OF DIRECT HYDROLOGIC CONNECTION (THROUGH FRACTURES) BETWEEN THE INACTIVE LAGOON AND THE SCREENED PORTION OF WELL SWMW-9. WELL SWMW-4, LOCATED DOWNGRADIENT OF THE INACTIVE LAGOON AND IMMEDIATELY UPGRADIENT OF THE STABILIZATION LAGOON, HAD TOTAL VOC CONCENTRATIONS OF 1.101 PPM, 1.86 PPM AND 1.95 PPM (DUPLICATE SAMPLE). TOTAL VOCS IN WATER TABLE WELLS SWMW-5,6,7 AND 8 RANGED FROM 0.095 PPM IN SWMW-8 TO 2.15 PPM IN SWMW-5 AND SHOW DECREASES IN CONCENTRATION, WITH DISTANCE DOWNGRADIENT FROM THE STABILIZATION LAGOON; HOWEVER, WELL SWMW-7A, SCREENED BELOW THE WATER TABLE ON TOP OF BEDROCK, HAD HIGHER TOTAL VOC CONCENTRATIONS THAN ADJACENT WATER TABLE WELL SWMW-7. DETECTED CONCENTRATIONS IN SWMW-7A (1.96 PPM AND 2.57 PPM) WERE THE HIGHEST OF THE FIVE DOWNGRADIENT WELLS FOR THE RESPECTIVE SAMPLING PERIODS. 1 Order number 940620-103843-ROD -001-001 page 4287 set 4 with 100 of 100 items DURING THE FIRST ROUND SAMPLING IN OCTOBER 1988, WELLS SWMW-4 AND SWMW-6 WERE ANALYZED FOR SEMI-VOLATILE AND PESTICIDE ORGANIC COMPOUNDS. NO SEMI-VOLATILE COMPOUNDS WERE DETECTED. HEPTACHLOR EPOXIDE WAS THE ONLY PESTICIDE ORGANIC COMPOUND DETECTED IN SWMW-4 (0.00021 PPM) AND SWMW-6 (0.00066 PPM) DURING FIRST ROUND SAMPLING. THESE ARE EXTREMELY LOW CONCENTRATIONS. SEMI-VOLATILE AND PESTICIDE ORGANICS COMPOUNDS WERE NOT INCLUDED IN THE LIST OF ANALYTICAL PARAMETERS FOR SECOND ROUND SAMPLES COLLECTED IN JANUARY 1989. IN OCTOBER 1988, SAMPLES WERE OBTAINED FROM DOWNGRADIENT WELLS SWMW-4 AND 6 FOR INORGANIC COMPOUND ANALYSIS. TWELVE COMPOUNDS WERE DETECTED IN THE SAMPLE FOR WELL SWMW-4. TEN INORGANIC COMPOUNDS WERE DETECTED IN THE SAMPLE FOR SWMW-6. CONCENTRATIONS IN BOTH THE SAMPLES WERE LOW, THEREFORE, METALS WERE NOT INCLUDED IN THE ANALYTICAL PARAMETERS FOR THE SECOND ROUND GROUND WATER SAMPLES COLLECTED IN JANUARY 1989. EPA WAS NOTIFIED OF THE ELIMINATION OF INORGANIC, SEMI-VOLATILE, AND PESTICIDE ORGANIC COMPOUNDS FROM THE ANALYTICAL PARAMETER LIST FOR SECOND ROUND SAMPLES IN A LETTER DATED JANUARY 10, 1989. SEDIMENT SAMPLES WERE COLLECTED FROM DRAINAGE DITCHES AND SWALES NEAR THE WASTEWATER TREATMENT FACILITY. THESE SAMPLES WERE COLLECTED FROM NINE LOCATIONS (SWSD-3 THROUGH 11) ON JULY 13, 1988. SAMPLES WERE ANALYZED FOR PCBS. ANALYTICAL RESULTS ARE PRESENTED IN TABLE 5-84. SAMPLING SITES SWSD-3 THROUGH 7 ARE LOCATED IN A DRAINAGE DITCH ORIGINATING-NEAR THE PLANT FACILITY AND EXTENDS SOUTHWARD ALONG THE EAST SIDE OF THE INACTIVE LAGOON AND STABILIZATION LAGOON. SEDIMENT SAMPLING POINTS SWSD-8 AND SWSD-9 ARE LOCATED IN A DRAINAGE SWALE DOWNGRADIENT OF AREA 2 AND WERE SAMPLED TO DETERMINE IF PCBS HAVE MIGRATED FROM AREA B TO THE WASTEWATER TREATMENT FACILITY. DRAINAGE IN THIS SWALE ALSO DISCHARGES INTO THE OUTFALL DITCH TO THE STABILIZATION LAGOON. SAMPLES SWSD-10 AND SWSD-11 WERE COLLECTED IN THE OUTFALL DITCH SOUTH OF SANGAMO ROAD, DOWNGRADIENT OF THE WASTEWATER TREATMENT FACILITY. PCBS WERE DETECTED IN NINE SEDIMENT SAMPLES. SAMPLING SITES SWSD-3, 4, 6 AND 8 ARE THE ONLY LOCATIONS WITH PCB CONCENTRATIONS GREATER THAN 50 PPM. SWSD-3, LOCATED UPGRADIENT FROM THE INACTIVE LAGOON, HAS A TOTAL PCB CONCENTRATION OF 1680 PPM. SAMPLING LOCATION SWSD-4, LOCATED ADJACENT TO THE EAST SIDE OF THE INACTIVE LAGOON, HAD A TOTAL PCB CONCENTRATION OF 2,700 PPM. SEDIMENT SAMPLE SWSD-5, LOCATED DOWNGRADIENT OF THE INACTIVE LAGOON, HAD A MUCH LOWER PCB CONCENTRATION OF 22.2 PPM. SWSD-6 AND SWSD-7, LOCATED DOWNSTREAM OF THE INACTIVE LAGOON AND ADJACENT TO THE ACTIVE LAGOON, HAS A TOTAL PCB CONCENTRATION OF 124 PPM AND 6.5 PPM, RESPECTIVELY. A TOTAL PCB CONCENTRATION OF 319 PPM WAS DETECTED AT SWSD-8. TOTAL PCB CONCENTRATIONS DECREASED FURTHER DOWNGRADIENT TO 19.7 PPM DETECTED IN SWSD-9. TOTAL PCB CONCENTRATIONS OF 6.5 PPM AND 7.2 PPM (DUPLICATE SAMPLE) WERE DETECTED IN SWSD-10. A TOTAL PCB CONCENTRATION OF 24.8 PPM WAS DETECTED AT SAMPLING SITE SWSD-11. 1 Order number 940620-103843-ROD -001-001 page 4288 set 4 with 100 of 100 items #SSR 6.0 SUMMARY OF SITE RISKS 6.1 CONTAMINANTS OF CONCERN A BASELINE RISK ASSESSMENT WAS CONDUCTED FOR THE PLANT SITE AND EACH OF THE OFF-SITE AREAS. THE CONTAMINATED MEDIA OF CONCERN ARE GROUNDWATER, SOIL AND SEDIMENT, SOLID WASTE AND SLUDGE. THE CONSTITUENTS OF CONCERN FOR THE MEDIA OF CONCERN IN EACH LOCATION ARE GIVEN IN TABLE 6-1. TABLE 6-2 PROVIDES THE CONCENTRATION RANGES FOR THE CONTAMINANTS OF CONCERN. THE MAJOR CONTAMINANT OF CONCERN AT THE SANGAMO SITE IS PCB. THE SURFACE SOIL PCB EXPOSURE POINT CONCENTRATION FOR EACH SITE WAS BASED ON THE MEAN OF THE DETECTED PCB CONCENTRATIONS FOR THE SURFACE SOIL SAMPLES COLLECTED FOR THAT SITE. THE EXPOSURE POINT CONCENTRATIONS FOR OTHER CARCINOGENIC SURFACE SOIL CONTAMINANTS OF CONCERN ON THE PLANT SITE WERE ALSO BASED ON THE MEAN OF THE DETECTED SAMPLES. THE SURFACE SOIL EXPOSURE POINT CONCENTRATIONS ARE CONTAINED IN TABLE 6-3. THE EXPOSURE POINT CONCENTRATIONS FOR THE SOIL NONCARCINOGENIC CONTAMINANTS OF CONCERN WERE BASED ON THE HIGHEST DETECTED CONCENTRATIONS. LEAD WAS CONSIDERED TO BE A SOIL CONTAMINANT OF CONCERN AT THE WELBORN SITE. THE LEAD EXPOSURE POINT CONCENTRATION WAS BASED ON AN AVERAGE SOIL LEAD CONCENTRATION OF 31.4 MG/KG. THE THREE CONTAMINANTS OF CONCERN AND THE EXPOSURE CONCENTRATIONS FOR THE SPRING LOCATED SOUTH OF THE PLANT SITE ARE TETRACHLOROETHENE (0.00084 MG/L), 1,2-DICHLOROETHENE (0.071 MG/L) AND TRICHLOROETHENE (0.2 MG/L). OTHER GROUNDWATER CONTAMINANTS WERE DETECTED IN THE PLUME ASSOCIATED WITH THE PLANT SITE AND THE OFF SITE AREAS. THE RANGE OF GROUNDWATER CONTAMINANT CONCENTRATIONS FOR THE SITE LOCATIONS IS CONTAINED IN TABLE 6-2. ALTHOUGH THE CONSUMPTION OF GROUNDWATER WAS NOT CONSIDERED TO BE A COMPLETE EXPOSURE PATHWAY IN THE PRP RISK ASSESSMENT, REGION IV DOES NOT AGREE WITH THIS CONCLUSION. SECTIONS 6.2 AND 6.4 CONTAIN MORE DISCUSSION ON THE GROUNDWATER EXPOSURE PATHWAY. 6.2 EXPOSURE ASSESSMENT POTENTIAL EXPOSURE PATHWAYS ARE DIRECT CONTACT WITH CONTAMINATED SOIL AND SEDIMENTS, INHALATION OF CONTAMINATED AIR AND FUTURE CONSUMPTION OF CONTAMINATED GROUNDWATER. AN ADDITIONAL INDIRECT EXPOSURE PATHWAY COULD RESULT FROM LEACHING OF SURFACE AND SUBSURFACE CONTAMINANTS INTO THE GROUNDWATER AND THE SUBSEQUENT CONSUMPTION OF GROUNDWATER. DIRECT CONTACT WITH SURFACE SOIL AND SEDIMENTS IS CONSIDERED TO BE A POTENTIALLY COMPLETE CURRENT EXPOSURE PATHWAY. DUE TO THE REMOTENESS OF THE SITES, DIRECT CONTACT WAS ASSUMED TO OCCUR ON A ONCE-PER WEEK BASIS AT MOST OF THE SITES. THE BREAZEALE SITE IS CONSIDERED A POTENTIAL FUTURE BUILDING SITE, AND THE JOHN TROTTER SITE IS CURRENTLY OCCUPIED, SO INTAKE LEVELS WERE BASED ON A DAILY EXPOSURE SCENARIO FOR THESE TWO 1 Order number 940620-103843-ROD -001-001 page 4289 set 4 with 100 of 100 items SITES. FOR NONCARCINOGENIC EFFECTS, THE DIRECT CONTACT EXPOSURE SCENARIO WAS FOR CHILDREN CONSUMING 0.2 GRAMS OF SOIL PER DAY AND WEIGHING 17 KILOGRAMS. THE CARCINOGENIC DIRECT CONTACT DAILY INTAKE LEVEL WAS BASED ON BOTH THE INGESTION AND DERMAL CONTACT PATHWAYS. THE INGESTION PATHWAY ASSUMED A LIFETIME DAILY CONSUMPTION RATE OF 0.1 GRAMS OF SOIL BY A 70 KILOGRAM ADULT. THE DERMAL PATHWAY ASSUMED A 540 MILLIGRAMS PER EXPOSURE CONTACT RATE AND A 5 PERCENT ABSORPTION RATE OF PCBS THROUGH THE SKIN. VOLATILIZATION OF CONSTITUENTS IS NOT CONSIDERED TO BE A SIGNIFICANT MIGRATION PATHWAY AT THE PLANT SITE OR AT THE OFF SITE AREAS. MEASURED PCB AND VOC CONCENTRATIONS IN AIR WERE BELOW DETECTION LIMITS AT BOTH THE PLANT AND OFF SITE AREAS. FOR THIS REASON, INHALATION WAS NOT CONSIDERED TO BE A COMPLETE EXPOSURE PATHWAY. ONE EXCEPTION TO THIS WAS THE DODGENS OFF SITE AREA. ALTHOUGH THE SITE IS GRASS COVERED AND IN GENERAL FUGITIVE DUST GENERATION IS NOT A SIGNIFICANT EXPOSURE PATHWAY, THE GRASS AT THE SITE IS MOWED WITH A TRACTOR MOWER SEVERAL TIMES A YEAR DURING THE SUMMER MONTHS. THE TRACTOR OPERATOR COULD BE POTENTIALLY EXPOSED TO PCB CONTAINING DUST GENERATED BY THE MOWER. THE EXPOSURE FREQUENCY FOR THIS SCENARIO IS 10 DAYS A YEAR FOR 2 HOURS A DAY. THE BREATHING RATE WAS ASSUMED TO BE 1.3 M3/HOUR, 10 PERCENT FOR THE PERCENTAGE OF INHALED DUST INGESTED AND 30 PERCENT FOR THE PERCENTAGE OF PCBS ABSORBED FROM THE INGESTED DUST. THE CONSUMPTION OF CONTAMINATED GROUNDWATER WAS NOT CONSIDERED TO BE A COMPLETE EXPOSURE PATHWAY IN THE RISK ASSESSMENT BECAUSE NO DOWNGRADIENT GROUNDWATER USERS HAVE BEEN IDENTIFIED AND TREATED WATER IS AVAILABLE TO ALL RESIDENCES DOWNGRADIENT OF THE PLANT SITE. HOWEVER, THE ON-SITE AQUIFER IS CLASSIFIED AS IIA AND THE AQUIFER IN THE OFF SITE AREAS IS CLASSIFIED AS 118, IMPLYING THAT THE ON-SITE AQUIFER IS CONSIDERED TO BE A CURRENT DRINKING WATER SOURCE AND THE OFF SITE AQUIFER IS A POTENTIAL SOURCE OF DRINKING WATER. THE CLASS II STATUS OF THE AQUIFER IN THE VICINITY OF THE SITE INDICATES THAT A FUTURE SCENARIO FOR THE CONSUMPTION OF GROUNDWATER SHOULD HAVE BEEN ADDRESSED IN THE RISK ASSESSMENT. HOWEVER, SINCE THIS WAS NOT DONE, THE NEED FOR GROUNDWATER REMEDIATION WILL BE ADDRESSED IN THE RISK CHARACTERIZATION SECTION OF THIS SUMMARY BY COMPARING GROUNDWATER CONCENTRATIONS FOR THE CONTAMINANTS OF CONCERN WITH THE APPROPRIATE MCLS OR MCLGS. HEALTH BASED NUMBERS ARE PROVIDED IN THE ABSENCE OF GROUNDWATER STANDARDS. THE AREAS OF SOLID WASTE AND SLUDGE DISPOSAL WERE SAMPLED BOTH ON THE SURFACE AND BY SUBSURFACE BORINGS. THE SURFACE SAMPLES WERE INCORPORATED WITH THE OTHER SURFACE SOIL SAMPLES TO DETERMINE SURFACE SOIL EXPOSURE POINT CONCENTRATIONS. THE SUBSURFACE CONTAMINANTS POSE AN INDIRECT EXPOSURE PATHWAY THROUGH LEACHING TO GROUNDWATER AND THE SUBSEQUENT CONSUMPTION OF CONTAMINATED GROUNDWATER. THESE AREAS WILL BE REMEDIATED BASED ON SOIL CLEANUP CONCENTRATIONS FOR THE PROTECTION OF GROUNDWATER. 1 Order number 940620-103843-ROD -001-001 page 4290 set 4 with 100 of 100 items 6.3 TOXICITY ASSESSMENT CANCER POTENCY FACTORS (CPFS) HAVE BEEN DEVELOPED BY EPA'S CARCINOGENIC ASSESSMENT GROUP FOR ESTIMATING EXCESS LIFETIME CANCER RISKS ASSOCIATED WITH EXPOSURE TO POTENTIALLY CARCINOGENIC CHEMICALS. CPFS, WHICH ARE EXPRESSED IN UNITS OF (MG/KG-DAY)1, ARE MULTIPLIED BY THE ESTIMATED INTAKE OF A POTENTIAL CARCINOGEN, IN MG/KG-DAY, TO PROVIDE AN UPPER-BOUND ESTIMATE OF THE EXCESS LIFETIME CANCER RISK ASSOCIATED WITH EXPOSURE AT THAT INTAKE LEVEL. THE TERM "UPPER BOUND" REFLECTS THE CONSERVATIVE ESTIMATE OF THE RISK CALCULATED FROM THE CPF. USE OF THIS APPROACH MAKES UNDERESTIMATION OF THE ACTUAL CANCER RISK HIGHLY UNLIKELY. CANCER POTENCY FACTORS ARE DERIVED FROM THE RESULTS OF HUMAN EPIDEMIOLOGICAL STUDIES OR CHRONIC ANIMAL BIOASSAYS TO WHICH ANIMAL-TO-HUMAN EXTRAPOLATION AND UNCERTAINTY FACTORS HAVE BEEN APPLIED. THE CPFS FOR THE SITE CONTAMINANTS OF CONCERN ARE CONTAINED IN TABLE 6-4. REFERENCE DOSES (RFDS) HAVE BEEN DEVELOPED BY EPA FOR INDICATING THE POTENTIAL FOR ADVERSE HEALTH EFFECTS FROM EXPOSURE TO CHEMICALS EXHIBITING NONCARCINOGENIC EFFECTS. RFDS, WHICH ARE EXPRESSED IN UNITS OF MG/KG-DAY, ARE ESTIMATES OF LIFETIME DAILY EXPOSURE LEVELS FOR HUMANS,INCLUDING SENSITIVE INDIVIDUALS. ESTIMATED INTAKES OF CHEMICALS FROM ENVIRONMENTAL MEDIA (E.G.1 THE AMOUNT OF A CHEMICAL INGESTED FROM CONTAMINATED DRINKING WATER) CAN BE COMPARED TO THE RFD. RFDS ARE DERIVED FROM HUMAN EPIDEMIOLOGICAL STUDIES OR ANIMAL STUDIES TO WHICH UNCERTAINTY FACTORS HAVE BEEN APPLIED (E.G., TO ACCOUNT FOR THE USE OF ANIMAL DATA TO PREDICT EFFECTS ON HUMANS). THESE UNCERTAINTY FACTORS HELP ENSURE THAT THE RFDS WILL NOT UNDERESTIMATE THE POTENTIAL FOR ADVERSE NONCARCINOGENIC EFFECTS TO OCCUR. THE RFDS FOR THE SITE CONTAMINANTS OF CONCERN ARE CONTAINED IN TABLE 6-4. 6.4 RISK CHARACTERIZATION EXCESS LIFETIME CANCER RISKS ARE DETERMINED BY MULTIPLYING THE INTAKE LEVEL WITH THE CANCER POTENCY FACTOR. THESE RISKS ARE PROBABILITIES-HAT ARE GENERALLY EXPRESSED IN SCIENTIFIC NOTATION (E.G.,1 X (10-6) OR 1E-6). AN EXCESS LIFETIME CANCER RISK OF 1 X (10-6) INDICATES THAT, AS A PLAUSIBLE UPPER BOUND, AN INDIVIDUAL HAS A ONE IN A MILLION CHANCE OF DEVELOPING CANCER AS A RESULT OF SITE-RELATED EXPOSURE TO A CARCINOGEN OVER A 70-YEAR LIFETIME UNDER THE SPECIFIC EXPOSURE CONDITIONS AT A SITE. THE AGENCY CONSIDERS INDIVIDUAL EXCESS CANCER RISK IN THE RANGE OF (10-4) TO (10-6) AS PROTECTIVE; HOWEVER THE (10-6) RISK LEVEL IS GENERALLY USED AS THE POINT OF DEPARTURE FOR SETTING CLEANUP LEVELS OF SUPERFUND SITES. POTENTIAL CONCERN FOR NONCARCINOGENIC EFFECTS OF A SINGLE CONTAMINANT IN A SINGLE MEDIUM IS EXPRESSED AS THE HAZARD QUOTIENT (HQ) (OR THE RATIO OF THE ESTIMATED INTAKE DERIVED FROM THE CONTAMINANT CONCENTRATION IN A GIVEN MEDIUM TO THE CONTAMINANT'S REFERENCE DOSE). BY ADDING THE HQS 1 Order number 940620-103843-ROD -001-001 page 4291 set 4 with 100 of 100 items FOR ALL CONTAMINANTS WITHIN A MEDIUM OR ACROSS ALL MEDIA TO WHICH A GIVEN POPULATION MAY REASONABLY BE EXPOSED, THE HAZARD INDEX (HI) CAN BE GENERATED. THE HI PROVIDES A USEFUL REFERENCE POINT FOR GAUGING THE POTENTIAL SIGNIFICANCE OF MULTIPLE CONTAMINANT EXPOSURES WITHIN A SINGLE MEDIUM OR ACROSS MEDIA. THE GREATEST CURRENT SITE RISKS ARE ATTRIBUTABLE TO DIRECT CONTACT WITH PCBS IN THE SURFACE SOIL. THESE RISK LEVELS RANGE FROM 1.2 X (10-5) FOR THE BREAZEALE SITE TO 1.3 X (10-3) FOR AREA B OF THE PLANT SITE. THE CANCER RISK LEVELS ASSOCIATED WITH EXPOSURE TO PCBS IN SURFACE OIL ARE SUMMARIZED ON TABLE 6-5. THE PREDICTED RISK LEVELS FOR EXPOSURE TO SURFACE SOIL VOCS AT AREA B ARE LOW AND DO NOT MAKE A SIGNIFICANT CONTRIBUTION TO THE RISKS ASSOCIATED WITH EXPOSURE TO PCBS. THE HAZARD INDEX FOR DIRECT CONTACT WITH NONCARCINOGENS IN THE SURFACE SOIL AT THE PLANT SITE ARE BELOW UNITY (1.9 X (10-4)). THE BASELINE RISK ASSOCIATED WITH GRASS MOWING FOR THE DODGENS SITE IS 8.2 X (10-8). LEAD WAS DETECTED IN THE SOIL AT CONCENTRATIONS EXCEEDING BACKGROUND AT THE WELBORN SITE. HOWEVER, THE AVERAGE CONCENTRATION (31.4 MG/KG) IS WELL BELOW THE OSWER INTERIM DIRECTIVE (# 9355.4-02) RECOMMENDED RANGE (500 - 1000 MG/KG). IN ADDITION, THIS CONCENTRATION IS ALSO WELL BELOW THE SOIL LEAD CLEANUP CONCENTRATION THAT WOULD BE GENERATED BY USING EXPOSURE DEFAULT VALUES WITH THE EPA BAD UPTAKE/BIOKINETIC MODEL. A BASELINE RISK WAS CALCULATED FOR THE DAILY CONSUMPTION OF WATER FROM A SPRING LOCATED DOWNGRADIENT FROM THE SITE. THE NONCARCINOGENIC RISK, OR HAZARD INDEX, WAS CALCULATED AT 0.11. THE CARCINOGENIC RISK WAS DETERMINED TO BE 7.5 X (10-5). ALTHOUGH THE RISK ASSOCIATED WITH THE FUTURE CONSUMPTION OF CONTAMINATED GROUNDWATER WAS NOT CALCULATED, THE APPROPRIATE GROUNDWATER STANDARDS AND HEALTH BASED NUMBERS ARE CONTAINED IN TABLE 6-6. A COMPARISON OF GROUNDWATER CONCENTRATIONS WITH THE NUMBERS IN THIS TABLE WILL ALLOW A DETERMINATION TO BE MADE CONCERNING WHICH GROUNDWATER CONTAMINANTS WILL REQUIRE REMEDIATION. 6.5 ENVIRONMENTAL RISKS THE ENVIRONMENTAL RECEPTORS AT THE SANGAMO PLANT SITE AND OFF SITE AREAS WOULD PRIMARILY BE AFFECTED THROUGH SOIL AND SURFACE WATER SEDIMENT PATHWAYS. NO ENDANGERED SPECIES OR CRITICAL HABITATS ARE KNOWN TO OCCUR IN THE VICINITY OF THE SITE. THE CONSTITUENTS IN THE SURFACE SOIL COULD IMPACT TERRESTRIAL ANIMALS. BURROWING ANIMALS, SUCH AS RODENTS, REPTILES, AND INSECTS MIGHT BE AFFECTED BY CONTAMINANTS IN THE BURIED WASTES. THE SURFACE WATER DITCHES AT THE PLANT SITE AND THE DITCHES AND CREEKS ADJACENT TO THE OFF SITE AREAS ARE LOW IN VOLUME AND ARE NOT KNOWN TO CONTAIN EDIBLE FISH. 1 Order number 940620-103843-ROD -001-001 page 4292 set 4 with 100 of 100 items #DA 7.0 DESCRIPTION OF ALTERNATIVE 1: NO ACTION 7.1.1 DESCRIPTION THE NO ACTION ALTERNATIVE IS RETAINED AS THE BASELINE CASE FOR RISK COMPARISON. NO REMEDIAL ACTIONS WOULD BE PERFORMED ON ANY OF THE MEDIA OF CONCERN (GROUNDWATER, SOIL, SLUDGE, AND SOLID WASTES) AT EITHER THE PLANT SITE OR THE OFF-SITE AREAS. WASTE DISPOSAL AREAS DEFINED DURING THE RI WOULD REMAIN IN THEIR PRESENT CONDITION. THE ONLY ACTIVE COMPONENT OF THIS ALTERNATIVE IS LONG-TERM GROUNDWATER AND SURFACE SOIL MONITORING. THIS PROGRAM WOULD BE IMPLEMENTED TO ASSESS THE EFFECT OF WASTE CONSTITUENTS ON THE SITE OVER A 30-YEAR DESIGN LIFE. GROUNDWATER QUALITY WOULD BE MONITORED SEMI-ANNUALLY BY SAMPLING AND ANALYSIS FOR VOLATILES, SEMI-VOLATILES, METALS, AND PCBS. ANNUALLY, SAMPLES WOULD BE COLLECTED AND ANALYZED FOR THE VOLATILE, SEMI-VOLATILE FRACTION OF THE TARGET COMPOUND LIST (TCL). DIOXINS AND FURANS WOULD ALSO BE ANALYZED ANNUALLY AT THE PLANT SITE. IF NEW COMPOUNDS ARE DETECTED, THEY WILL BE ADDED TO THE SEMI-ANNUAL MONITORING PROGRAM. HOWEVER, SINCE MANY OF THE GROUNDWATER MONITORING WELLS ARE LOCATED IN FRACTURED BEDROCK, THE WATER QUALITY DETERMINED BY ANALYSES OF SAMPLES FROM THESE FRACTURES MAY NOT INDICATE GROUNDWATER QUALITY IN OTHER UNCONNECTED FRACTURE SYSTEMS. THE GROUNDWATER QUALITY WOULD CHANGE AS NATURAL ATTENUATION DEGRADED THE WASTE CONSTITUENTS PRESENT IN THE WATER. SURFACE SOIL MONITORING WOULD BE PERFORMED ANNUALLY TO EVALUATE MIGRATION OF PCBS. SAMPLES WOULD BE COLLECTED FROM EACH WASTE DISPOSAL LOCATION AT PLANT AND OFF-SITE AREAS. AS WITH THE GROUNDWATER MONITORING, A 30 YEAR PERIOD HAS BEEN USED AS A BASIS FOR COST ESTIMATION. SANGAMO PLANT SITE THIS PROGRAM WOULD INCLUDE EXISTING ON-SITE MONITORING WELLS AND OFF-SITE WELL. EPA HAS CLASSIFIED GROUNDWATER AS CLASS IIA ON THE PLANT PROPERTY. A 30-YEAR PERIOD HAS BEEN USED AS A BASIS FOR COST ESTIMATION. THE MONITORING PROGRAM HAS THE FOLLOWING ELEMENTS: BACKGROUND WELLS: MONITORING OF THE FOLLOWING UPGRADIENT WELLS IS PROPOSED. WELLS SAMW-1, SBMW-1, AND SWMW-1 ARE LOCATED NEAR AREAS A, B, AND THE WASTEWATER TREATMENT FACILITY. AREAS C, D, E F, G, AND H ARE ON TOP OF A RIDGE AND NO UPGRADIENT WELLS ARE TOPOGRAPHICALLY POSSIBLE. BACKGROUND WELLS WILL SERVE AS POINTS OF COMPARISON FOR WATER QUALITY MONITORING RESULTS FROM THE WASTE DISPOSAL AREAS. ON-SITE MONITORING WELLS: EXISTING WELLS SAMW-2 AND 3, SBMW-2 AND 3, 1 Order number 940620-103843-ROD -001-001 page 4293 set 4 with 100 of 100 items SDMW-1, 2, 3, AND 4, SCMW-5, SFMW-6, SGMW-7, 8, AND 9, SHMW-10, SEMW-1, SWMW-2, 3, 4, 5, 6, 7, 7A, 8, AND 9 ARE PROPOSED FOR LONG-TERM MONITORING. THESE WELLS ARE DOWNGRADIENT OF WASTE DISPOSAL AREAS. OFF-PROPERTY MONITORING WELLS: SEVERAL WELLS (SPMW 1, 1A, 1B, 2, 3, 3A, 3B, 4, 5, AND 6) ARE PROPOSED FOR LONG-TERM DETECTION MONITORING. MONITORING WELLS SPMW-1, 1A, AND 1B WILL COMPRISE A NEST LOCATED SOUTH OF THE SITE ON THE SOUTH SIDE OF TOWN CREEK. WELL SPMW-2 WILL BE A BEDROCK WELL LOCATED BETWEEN AREAS C, D, F, G, AND H AND THE NIX SPRING. THE REMAINING WELLS WILL BE LOCATED NORTH OF THE SITE. MONITORING WELLS SPMW-3, 3A, AND 3B, WILL COMPRISE A MONITORING WELL NEST ON THE NORTH SIDE OF THE UNNAMED TRIBUTARY TO TWELVEMILE CREEK. WELLS SPMW-4, 5, AND 6 ARE BEDROCK WELLS AND WILL BE LOCATED IN DRAINAGE SWALES DOWNGRADIENT OF SITES C, D, F, G, AND H. WELL NESTS WILL CONSIST OF SHALLOW AND DEEP WELLS FOR MONITORING GROUNDWATER IN THE SAPROLITE AND ONE WELL TO MONITOR GROUNDWATER IN BEDROCK. THE SELECTION OF MONITORING WELLS FOR LONG-TERM MONITORING OF VARIOUS WASTE DISPOSAL AREAS IS BASED ON LOCATION. WELLS ARE GENERALLY LOCATED DOWNGRADIENT OF THE WASTE DISPOSAL AREAS. EACH CAN BE USED TO MONITOR CONSTITUENT CONCENTRATIONS DOWNGRADIENT OF THE WASTE DISPOSAL AREAS. FOR THE NO ACTION ALTERNATIVE, SAMPLES WOULD BE COLLECTED SEMIANNUALLY AND ANALYZED FOR PCBS, TRICHLOROETHENE, TETRACHLOROETHENE, TOTAL 1,2-DICHLOROETHENE, 1,1,1-TRICHLOROETHANE, 1,1-DICHLOROETHENE, 1,1-DICHLOROETHANE, CHLOROFORM, BENZENE, AND 1,2,-DICHLOROETHANE. AS PART OF THE MONITORING PROGRAM, WATER LEVELS WOULD BE MEASURED TO ASSESS THE GROUNDWATER FLOW DIRECTION. THE MONITORING AND WELL MAINTENANCE PERIOD IS ASSUMED TO BE 30 YEARS. EPA HAS CLASSIFIED GROUNDWATER AS CLASS IIB AT THE OFF-SITE AREAS. BREAZEALE SITE A GROUNDWATER MONITORING PROGRAM WOULD BE IMPLEMENTED TO ASSESS THE EFFECT OF WASTE CONSTITUENTS AT THE BREAZEALE SITE ON GROUNDWATER OVER A 30-YEAR DESIGN LIFE. THIS PROGRAM WOULD INCLUDE EXISTING ON-SITE MONITORING WELLS. A 30-YEAR PERIOD HAS BEEN USED FOR COST ESTIMATION. THE MONITORING PROGRAM HAS THE FOLLOWING ELEMENTS: BACKGROUND WELL: MONITORING OF UPGRADIENT WELL BRMW-1 IS PROPOSED. THIS WELL IS LOCATED TO THE NORTHWEST OF THE SITE AND WOULD SERVE AS A POINT OF COMPARISON FOR WATER QUALITY MONITORING RESULTS FROM THE SITE. ON-SITE MONITORING WELLS: EXISTING WELLS BRMW-2, 2A, 3, 3A, 3B, 4, 4A, 5, 5A, 5B, 8, 8A, 10, 11, 12, 12A, 14, AND 14A ARE PROPOSED FOR LONGTERM MONITORING. THESE WELLS ARE LOCATED DOWNGRADIENT OF THE AREA OF WASTE DEPOSITION. ON-SITE DETECTION MONITORINA WELLS: WELLS BRMW-7, 9, AND 13 ARE PROPOSED 1 Order number 940620-103843-ROD -001-001 page 4294 set 4 with 100 of 100 items FOR LONG-TERM DETECTION MONITORING. THESE WELLS ARE LOCATED TO THE EAST, WEST, AND SOUTH OF THE VOC PLUME. WELLS SELECTED FOR LONG-TERM MONITORING OF THE BREAZEALE SITE ARE GENERALLY LOCATED DOWNGRADIENT OF THE AREA OF WASTE DEPOSITION. THE SAMPLING PROGRAM FOR THE NO ACTION ALTERNATIVE WOULD BE PERFORMED ON A SEMI-ANNUAL BASIS AND THE RESULTS WOULD BE SUBMITTED IN SEMI-ANNUAL REPORTS. CHEMICAL ANALYSES ARE PROPOSED FOR PCBS, TRICHLOROETHENE, TETRACHLOROETHENE, BENZENE, TOLUENE, TOTAL 1,2-DICHLOROETHENE, 1,1,2,2-TETRACHLOROETHANE, BIS (2-ETHYLHEXYL) PHTHALATE, AND 1,1,1,-TRICHLOROETHANE. AS PART OF THE MONITORING PROGRAM, WATER LEVELS IN MONITORING WELLS WOULD BE MEASURED TO ASSESS THE GROUNDWATER FLOW DIRECTION. FOR COST ESTIMATING, THE WELL MONITORING AND MAINTENANCE PERIOD IS ASSUMED TO BE 30 YEARS. NIX SITE A GROUNDWATER MONITORING PROGRAM WOULD BE IMPLEMENTED TO ASSESS THE EFFECT OF WASTE CONSTITUENTS AT THE NIX SITE ON GROUNDWATER OVER A 30-YEAR DESIGN LIFE. THIS PROGRAM WOULD INCLUDE EXISTING ON-SITE MONITORING WELLS. A 30-YEAR PERIOD HAS BEEN USED FOR COST ESTIMATION. THE MONITORING PROGRAM HAS THE FOLLOWING ELEMENTS: BACKGROUND WELL: MONITORING OF UPGRADIENT WELL NXMW-1 IS PROPOSED. THIS WELL IS LOCATED TO THE NORTHEAST OF THE SITE AND WOULD SERVE AS A POINT OF COMPARISON FOR WATER QUALITY MONITORING RESULTS FROM THE SITE. ON-SITE DETECTION MONITORING WELLS: WELLS NXMW 2, 3, AND 4 ARE PROPOSED FOR LONG-TERM DETECTION MONITORING. THESE WELLS ARE LOCATED TO THE NORTH, SOUTHEAST, AND WEST OF THE AREA OF WASTE DEPOSITION, RESPECTIVELY. THE SAMPLING PROGRAM FOR THE NO ACTION ALTERNATIVE WOULD BE PERFORMED ON A SEMI-ANNUAL BASIS AND THE RESULTS WOULD BE SUBMITTED IN A SEMI-ANNUAL REPORTS. CHEMICAL ANALYSES ARE PROPOSED FOR PCBS. AS PART OF THE MONITORING PROGRAM, WATER LEVELS IN MONITORING WELLS WOULD BE MEASURED TO ASSESS THE GROUNDWATER FLOW DIRECTION. FOR COST ESTIMATING, THE WELL MONITORING AND MAINTENANCE PERIOD IS ASSUMED TO BE 30 YEARS. DODGENS SITE A GROUNDWATER MONITORING PROGRAM WOULD BE IMPLEMENTED TO ASSESS THE EFFECT OF WASTE CONSTITUENTS AT THE DODGENS SITE ON GROUNDWATER OVER A 30-YEAR DESIGN LIFE. THIS PROGRAM WOULD INCLUDE EXISTING ON-SITE MONITORING WELLS. A 30 YEAR PERIOD HAS BEEN USED FOR COST ESTIMATION. THE MONITORING PROGRAM HAS THE FOLLOWING ELEMENTS: BACKGROUND WELL: MONITORING OF UPGRADIENT WELL DGMW-1 IS PROPOSED. THIS WELL IS LOCATED TO THE WEST OF THE SITE AND WOULD SERVE AS A POINT OF COMPARISON FOR WATER QUALITY MONITORING RESULTS FROM THE SITE. 1 Order number 940620-103843-ROD -001-001 page 4295 set 4 with 100 of 100 items ON-SITE MONITORING WELLS: EXISTING WELLS DGMW-2, 3, AND 4 ARE PROPOSED FOR LONG-TERM MONITORING. THESE WELLS ARE LOCATED DOWNGRADIENT OF THE AREA OF WASTE DEPOSITION. ON-SITE DETECTION MONITORING WELLS: WELL DGMW-3A IS PROPOSED FOR LONG-TERM DETECTION MONITORING. THIS WELL IS LOCATED TO THE EAST OF THE AREA OF WASTE DEPOSITION NEAR MIDDLE PORK TWELVEMILE CREEK. WELLS SELECTED FOR LONG-TERM MONITORING OF THE DODGENS SITE ARE LOCATED DOWNGRADIENT OF THE AREA OF WASTE DEPOSITION. THE SAMPLING PROGRAM FOR THE NO ACTION ALTERNATIVE WOULD BE PERFORMED ON A SEMI-ANNUAL BASIS AND THE RESULTS WOULD BE SUBMITTED IN SEMI-ANNUAL REPORTS. CHEMICAL ANALYSES ARE PROPOSED FOR PCBS, TRICHLOROETHENE, TETRACHLOROETHENE, BIS (2-ETHYLHEXYL) PHTHALATE, CADMIUM, COPPER, LEAD, AND SILVER. AS PART OF THE MONITORING PROGRAM, WATER LEVELS IN MONITORING WELLS WOULD BE MEASURED TO ASSESS THE GROUNDWATER FLOW DIRECTION. FOR COST ESTIMATING, THE WELL MONITORING AND MAINTENANCE PERIOD IS ASSUMED TO BE 30 YEARS. CROSS ROADS SITE A GROUNDWATER MONITORING PROGRAM WOULD BE IMPLEMENTED TO ASSESS THE IMPACT OF THE CROSS ROADS SITE ON GROUNDWATER OVER A 30-YEAR DESIGN LIFE THIS PROGRAM WOULD INCLUDE EXISTING AND PROPOSED MONITORING WELLS. A 30-YEAR PERIOD HAS BEEN USED FOR COST ESTIMATION. THE MONITORING PROGRAM HAS THE FOLLOWING ELEMENTS: BACKGROUND WELL: MONITORING OF UPGRADIENT WELL CRMW-1 IS PROPOSED. WELL IS LOCATED NORTH OF THE SITE AND WILL SERVE AS A POINT OF COMPARISON FOR WATER QUALITY MONITORING RESULTS FROM THE SITE. THIS ON-SITE MONITORING WELLS: EXISTING WELLS CRMW-2, 3, AND 3A ARE PROPOSED FOR LONG-TERM MONITORING. THESE WELLS ARE LOCATED DOWNGRADIENT OF THE AREA OF WASTE DEPOSITION. ON-SITE DETECTION MONITORING WELLS: WELL NEST CRMW-4, 4A, AND CRMW-5, 5A ARE PROPOSED FOR LONG-TERM DETECTION MONITORING. THESE WELLS ARE LOCATED SOUTHEAST AND EAST OF THE AREA OF WASTE DEPOSITION, RESPECTIVELY. THE SAMPLING PROGRAM FOR THE NO ACTION ALTERNATIVE WOULD BE PERFORMED ON A SEMI-ANNUAL BASIS AND THE RESULTS WOULD BE SUBMITTED IN SEMI-ANNUAL REPORTS. CHEMICAL ANALYSES ARE PROPOSED FOR PCBS, TRICHLOROETHENE, TETRACHLOROETHENE, TOTAL 1,2-DICHLOROETHENE, SILVER, CADMIUM, AND CYANIDE. AS PART OF THE MONITORING PROGRAM, WATER LEVELS IN MONITORING WELLS WOULD BE MEASURED TO ASSESS THE GROUNDWATER FLOW DIRECTION. FOR COST ESTIMATING, THE MONITORING AND WELL MAINTENANCE PERIOD IS ASSUMED TO BE 30 YEARS. JOHN TROTTER SITE 1 Order number 940620-103843-ROD -001-001 page 4296 set 4 with 100 of 100 items A GROUNDWATER MONITORING PROGRAM WOULD BE IMPLEMENTED TO ASSESS THE IMPACT OF WASTE CONSTITUENTS AT THE JOHN TROTTER SITE ON GROUNDWATER OVER A 30-YEAR PERIOD. THIS PROGRAM WOULD INCLUDE EXISTING ON-SITE MONITORING WELLS. A 30-YEAR PERIOD HAS BEEN USED FOR COST ESTIMATION. THE MONITORING PROGRAM HAS THE FOLLOWING ELEMENTS: BACKGROUND WELL: MONITORING OF UPGRADIENT WELL JTMW-1 IS PROPOSED. WELL IS LOCATED NORTH OF THE SITE AND WOULD SERVE AS A POINT OF COMPARISON FOR WATER QUALITY MONITORING RESULTS FROM THE SITE. THIS ON-SITE DETECTION MONITORING WELLS: JTMW-2, 3, 3A, AND 4 ARE PROPOSED FOR LONG-TERM DETECTION MONITORING. THESE WELLS ARE LOCATED SOUTH OF THE AREA OF WASTE DEPOSITION. WELLS SELECTED FOR LONG-TERM GROUNDWATER MONITORING AT THE JOHN TROTTER SITE ARE LOCATED DOWNGRADIENT OF THE AREA OF WASTE DEPOSITION. THE SAMPLING PROGRAM FOR THE NO ACTION ALTERNATIVE WOULD BE PERFORMED ON A SEMIANNUAL BASIS AND THE RESULTS WOULD BE SUBMITTED IN SEMI-ANNUAL REPORTS. CHEMICAL ANALYSES ARE PROPOSED FOR PCBS, TRICHLOROETHENE, TETRACHLOROETHENE, ANTIMONY, CADMIUM, COPPER, LEAD, AND SILVER. AS PART OF THE MONITORING PROGRAM, WATER LEVELS IN MONITORING WELLS WOULD BE MEASURED TO ASSESS THE GROUNDWATER FLOW DIRECTION. FOR COST ESTIMATING, THE WELL MONITORING AND MAINTENANCE PERIOD IS ASSUMED TO BE 30 YEARS. WELBORN SITE A GROUNDWATER MONITORING PROGRAM WOULD BE IMPLEMENTED TO ASSESS THE EFFECT OF WASTE CONSTITUENTS AT THE WELBORN SITE ON GROUNDWATER OVER A 30-YEAR DESIGN LIFE. THIS PROGRAM WOULD INCLUDE EXISTING ON-SITE MONITORING WELLS. A 30-YEAR PERIOD HAS BEEN USED FOR COST ESTIMATION. THE MONITORING PROGRAM HAS THE FOLLOWING ELEMENTS: BACKGROUND WELL: MONITORING OF UPGRADIENT WELL WBMW-1 IS PROPOSED. THIS WELLS IS LOCATED TO THE NORTHEAST OF THE SITE AND WOULD SERVE AS A POINT OF COMPARISON FOR WATER QUALITY MONITORING RESULTS FROM THE SITE. ON-SITE DETECTION MONITORING WELLS: WELLS WBMW 2, 3, AND 4 ARE PROPOSED FOR LONG-TERM DETECTION MONITORING. THESE WELLS ARE LOCATED TO THE EAST AND SOUTH OF THE AREAS OF WASTE DEPOSITION. WELLS SELECTED FOR LONG-TERM MONITORING OF THE WELBORN SITE ARE GENERALLY LOCATED DOWNGRADIENT OF THE AREA OF WASTE DEPOSITION. THE SAMPLING PROGRAM FOR THE NO ACTION ALTERNATIVE WOULD BE PERFORMED ON A SEMI-ANNUAL BASIS AND THE RESULTS WOULD BE SUBMITTED IN SEMI-ANNUAL REPORTS. CHEMICAL ANALYSES ARE PROPOSED FOR PCBS AND LEAD. AS PART OF THE MONITORING PROGRAM, WATER LEVELS IN MONITORING WELLS WOULD BE MEASURED TO ASSESS THE GROUNDWATER FLOW DIRECTION. FOR COST ESTIMATING, THE WELL MONITORING AND MAINTENANCE PERIOD IS ASSUMED TO BE 30 YEARS. 1 Order number 940620-103843-ROD -001-001 page 4297 set 4 with 100 of 100 items 7.1.2 EFFECTIVENESS THE NO-ACTION ALTERNATIVE WOULD NOT REDUCE THE TOXICITY MOBILITY OR VOLUME OF CONTAMINATED MEDIA AT THE SITE. SINCE MONITORING IS THE ONLY COMPONENT OF THIS ALTERNATIVE, THERE WOULD BE NO INCREASE IN PROTECTIVENESS TO HUMAN HEALTH OR THE ENVIRONMENT. 7.2 ALTERNATIVE 2: LIMITED ACTION 7.2.1 DESCRIPTION THE LIMITED ACTION ALTERNATIVE ESTABLISHES INSTITUTIONAL MEASURES TO LIMIT EXPOSURE PATHWAYS IN THE FOUR AFFECTED MEDIA: GROUNDWATER, SOIL, SLUDGE, AND SOLID WASTES. THESE INSTITUTIONAL MEASURES INCLUDE THE FOLLOWING: * RESTRICTIONS ON GROUNDWATER USE, * FENCING TO LIMIT ACCESS TO AFFECTED SOLID MATERIALS, AND * DEED RESTRICTIONS TO CONTROL FUTURE LAND USE. GROUNDWATER AS PROPOSED IN THIS ALTERNATIVE, LIMITED ACTION ON GROUNDWATER WOULD BE USED ONLY FOR THE PLANT, CROSS ROADS, BREAZEALE, AND DODGENS SITES. LIMITED ACTION AT THESE LOCATIONS WOULD CONSIST OF GROUNDWATER ACCESS RESTRICTIONS, PROVISIONS FOR ONE CONNECTION TO PUBLIC WATER SUPPLY, AND GROUNDWATER MONITORING. ACCESS TO GROUNDWATER WOULD BE CONTROLLED THROUGH DEED RESTRICTIONS. PUBLIC WATER IS AVAILABLE THROUGHOUT THE AREA. LONG-TERM MONITORING WOULD BE PERFORMED AS DESCRIBED IN ALTERNATIVE 1, NO ACTION. SOILS, SOLID WASTES, AND SLUDGE LIMITED ACTION FOR SOILS, SOLID WASTES, AND SLUDGE AT EACH SITE WOULD CONSIST OF ACCESS CONTROL THROUGH FENCING AND DEED RESTRICTIONS. THE AREAS CONTAINING SOILS, SOLID WASTES, AND SLUDGE WITH PCB CONCENTRATIONS EXCEEDING 25 PPM WOULD BE FENCED. THE FENCE WOULD CONSIST OF SIX-FOOT HIGH WELDED WIRE WITH ONE STRAND OF BARBED WIRE EXTENDING ALONG THE TOP. THE SITES WOULD BE POSTED AND GATES WOULD BE KEPT LOCKED. IN ADDITION TO FENCING, LEGAL ACTIONS WOULD BE IMPLEMENTED TO PROVIDE DEED RESTRICTIONS CONCERNING ACCESS AND FUTURE SITE USE. 7.2.2 EFFECTIVENESS FENCES INSTALLED AROUND THE AFFECTED AREAS WOULD PREVENT DIRECT HUMAN CONTACT WITH AFFECTED MATERIAL, BUT WOULD NOT REDUCE POTENTIAL MIGRATION BY SURFACE EROSION. INHALATION OF WASTE CONSTITUENTS WAS NOT FOUND IN 1 Order number 940620-103843-ROD -001-001 page 4298 set 4 with 100 of 100 items THE RI TO BE AN EXPOSURE PATHWAY. LIMITED ACTION ON GROUNDWATER WOULD RESTRICT FUTURE USE AND CONSUMPTION OF GROUNDWATER IN AND AROUND THE AFFECTED AREAS (PLANT, BREAZEALE, DODGENS, AND CROSS ROADS) THROUGH INSTITUTIONAL CONTROLS. AS DISCUSSED IN SECTION 7.1.2, NATURAL ATTENUATION OF WASTE CONSTITUENTS IN FRACTURED BEDROCK MAY CONTINUE TO LOWER THE CONCENTRATIONS OF THOSE CONSTITUENTS AND THOSE OF THEIR DEGRADATION PRODUCTS. 7.3 ALTERNATIVE 3: LIMITED ACTION WITH CONTAINMENT OF SOLIDS 7.3.1 DESCRIPTION THIS ALTERNATIVE COMBINES THE INSTITUTIONAL CONTROLS FOR GROUNDWATER AND SOLID MATERIALS THAT ARE DESCRIBED IN SECTION 7.2.1, WITH CONTAINMENT OF AFFECTED SOLID MATERIALS BY CAPPING. TABLE 7-1 CONTAINS ESTIMATED VOLUMES OF AFFECTED MATERIAL. THIS ALTERNATIVE WOULD CONTAIN IN PLACE THE TOTAL VOLUME OF SOLIDS. THE PURPOSE OF CONTAINMENT IS TO REDUCE CONTACT OF WASTE CONSTITUENTS WITH RECEPTOR POPULATIONS AND THE ENVIRONMENT. REDUCTION WOULD BE ACCOMPLISHED BY MINIMIZING INFILTRATION OF WASTE CONSTITUENTS INTO THE GROUNDWATER, INHIBITING EROSION OF THE CONSTITUENTS, AND BY PROVIDING A BARRIER TO DIRECT CONTACT. CONTAINMENT WOULD LEAVE AFFECTED SOILS IN PLACE. A CAP OVER AFFECTED MATERIALS AT THE SURFACE WOULD REDUCE CONTACT BETWEEN PERCOLATING WATER AND WASTE CONSTITUENTS, THEREBY REDUCING LEACHATE PRODUCTION. IN ADDITION, A CAP INSTALLED OVER THE AFFECTED MATERIALS WOULD PREVENT EROSION OF WASTE CONSTITUENTS BY WIND OR WATER. SITES REQUIRING CONTAINMENT WOULD BE GRADED TO PROVIDE SURFACE DRAINAGE AROUND AND AWAY FROM CONTAINED SOLIDS. A CONTAINMENT COVER WOULD REQUIRE MAINTENANCE AND INSPECTION. THE ALTERNATIVE WOULD BE IMPLEMENTED AT THE PLANT AND OFF-SITE AREAS. THE FOLLOWING TWO DESIGNS ARE BEING CONSIDERED FOR THE COVER: OPTION 3A - COMPOSITE COVER THE COMPOSITE COVER OPTION WOULD INCLUDE A CAP CONSISTING OF THE FOLLOWING COMPONENTS: * 12 INCHES OF TOPSOIL * 2 FEET OF COMPACTED CLAY * A LAYER OF GEOTEXTILE MATERIAL THE CLAY LAYER WOULD BE COMPACTED TO REDUCE PERMEABILITY TO LESS THAN 1 X (10-7) CM/SEC. THE FINAL SURFACE CONTOURS OF THE CAP WOULD BE GRADED TO PROMOTE RUNOFF RATHER THAN INFILTRATION DURING RAINFALL. 1 Order number 940620-103843-ROD -001-001 page 4299 set 4 with 100 of 100 items THE COMPOSITE COVER WOULD BE SOWN WITH SHALLOW ROOTED GRASSES TO MINIMIZE CAP EROSION. GRASSES WOULD BE SELECTED THAT PREVENTED PENETRATION OF THE CLAY LAYER BY THE ELEMENTS. OPTION 3B - MULTI-MEDIA COVER THE MULTI-MEDIA COVER OPTION WOULD INCLUDE A CAP CONSISTING OF THE FOLLOWING COMPONENTS: * 6 INCHES OF TOPSOIL * 18 INCHES OF ROOTING ZONE SOIL * 1 LAYER OF GEOTEXTILE * 1 LAYER OF DRAINAGE MATERIAL * 1 LAYER OF FLEXIBLE MEMBRANE LINER * 2 FEET OF CLAY THE MULTI-MEDIA COVER DESIGN COMPLIES WITH SC DHEC REQUIREMENTS FOR HAZARDOUS WASTE COVER SYSTEMS AND WOULD PERFORM IN ACCORDANCE WITH US EPA MINIMUM TECHNOLOGY GUIDANCE. LIKE THE COMPOSITE COVER OPTION, THE MULTI-MEDIA COVER WOULD BE GRADED TO PROMOTE SURFACE DRAINAGE AND SOWN WITH SHALLOW-ROOTED GRASSES. CONTAINMENT OF SLUDGE IN THE ACTIVE LAGOON WOULD BE ACCOMPLISHED BY PLACEMENT OF A BENTONITE COVER. THE BENTONITE COVER WOULD BE APPROXIMATELY SIX INCHES THICK AND WOULD BE PLACED OVER THE ENTIRE SLUDGE LAYER IN THE LAGOON. THIS ACTION WOULD BE TAKEN TO SUPPLEMENT THE EXISTING UNCONSOLIDATED BENTONITE COVER AND WOULD ENABLE THE PRESENT TREATMENT SYSTEM TO CONTINUE OPERATION. SLUDGE IN THE INACTIVE LAGOON WOULD BE COVERED IN THE SAME MANNER. 7.3.2 EFFECTIVENESS THE SHORT-TERM EFFECTIVENESS OF ALTERNATIVE 3 WOULD BE PROVIDED BY USING CONSTRUCTION METHODS AND PRACTICES THAT MINIMIZE THE MOVEMENT OF WASTE CONSTITUENTS. LONG-TERM PROTECTIVENESS WOULD BE PROVIDED THROUGH NATURAL DEGRADATION OF WASTE CONSTITUENTS AND BY CONTROLLING THE FOLLOWING MIGRATION ROUTES: * PARTICULATE RELEASES TO THE AIR, * DIRECT CONTACT WITH AFFECTED MEDIA, * GROUND SURFACE RUNOFF OF AFFECTED MATERIALS, 1 Order number 940620-103843-ROD -001-001 page 4300 set 4 with 100 of 100 items * SURFACE WATER INFILTRATION INTO AFFECTED SOIL OR WASTES AND SUBSEQUENT, MIGRATION THROUGH GROUNDWATER. COMPARED TO A COMPOSITE COVER, THE MULTI-MEDIA COVER PROVIDES GREATER LONG-TERM EFFECTIVENESS BY SUPPLYING A MORE SUBSTANTIAL BARRIER TO INFILTRATION. RESULTS OF THE HYDROLOGIC EVALUATION OF LANDFILL PERFORMANCE (HELP) COMPUTER PROGRAM SHOW THAT OPTION A WOULD REDUCE INFILTRATION BY APPROXIMATELY 92 PERCENT AND OPTION B WOULD REDUCE INFILTRATION BY APPROXIMATELY 99 PERCENT. HOWEVER, SINCE THE PRIMARY OBJECTIVE IS ELIMINATION OF DIRECT CONTACT WITH WASTE CONSTITUENTS, THE SMALL INCREASE IN INFILTRATION ALLOWED BY A COMPOSITE COVER DOES NOT ELIMINATE IT FROM CONSIDERATION. MONITORING EFFLUENT FROM THE LAGOON HAS SHOWN THE COVER TO BE EFFECTIVE IN ELIMINATING MIGRATION OF PCBS THROUGH WATER. PLACEMENT OF ADDITIONAL BENTONITE WOULD BE CARRIED OUT TO SUPPLEMENT THE EXISTING COVER. 7.4 ALTERNATIVE 4: LIMITED ACTION WITH CONTAINMENT OF SOIL AND SLUDGE AND OFF-SITE DISPOSAL OF SOLID WASTES 7.4.1 DESCRIPTION ALTERNATIVE 4 CONSISTS OF THE FOLLOWING COMPONENTS: LIMITED ACTION FOR GROUNDWATER COMBINED WITH CAPPING OF SOIL AND SLUDGE AS DESCRIBED IN SECTIONS 7.2.1 AND 7.3.1 AND OFF-SITE DISPOSAL OF SOLID WASTES. ON THE BASIS OF INFORMATION COLLECTED DURING THE RI PHASE I, APPROXIMATELY 2,900 CUBIC YARDS OF SOLID WASTES WOULD BE EXCAVATED, PRE-PROCESSED, AND TRANSPORTED OFF SITE FOR TREATMENT BY THERMAL DESTRUCTION OR DISPOSAL IN A TSCA SECURE CHEMICAL LANDFILL. USING A TYPICAL DENSITY OF 1.3 TONS/CUBIC YARD, THE TOTAL WEIGHT OF EXCAVATED SOLID WASTE WOULD BE APPROXIMATELY 3,800 TONS. THIS AVERAGE DENSITY WAS APPROXIMATELY THAT OF SOLID WASTES REMOVED FROM AREA D OF THE PLANT SITE. ALL REMAINING SOIL AND SLUDGE VOLUMES WOULD BE CAPPED. THIS ALTERNATIVE INCLUDES OFF-SITE DISPOSAL BY BOTH INCINERATION AND LANDFILLING TO INCREASE IMPLEMENTABILITY THROUGH MAXIMIZING THE POTENTIAL FOR AVAILABLE COMMERCIAL TREATMENT AND DISPOSAL CAPACITY. THERMAL DESTRUCTION OF WASTES WOULD OCCUR IN A PERMITTED ROTARY KILN INCINERATOR OWNED BY A COMMERCIAL VENDOR. TO ANALYZE THIS ALTERNATIVE, AN ASSUMPTION WILL BE MADE THAT APPROXIMATELY TEN PERCENT OF THE SOLID WASTE (380 TONS) WOULD BE HAULED TO AN INCINERATOR. THE INCINERATOR NEAREST THE SITE IS APPROXIMATELY 850 MILES AWAY. AN ASSUMPTION WILL ALSO BE MADE THAT APPROXIMATELY 90 PERCENT (3,400 TONS) OF SOLID WASTES WOULD BE HAULED TO A LANDFILL. THE LANDFILL CONSIDERED IS APPROXIMATELY 500 MILES FROM THE SITE. PERCENTAGES OF SOLID WASTE SUITABLE FOR LANDFILLING AND INCINERATION ARE BASED ON THE CLASSIFICATIONS OF WASTES EXCAVATED FROM AREA D OF THE PLANT SITE. THESE WASTES WERE EXCAVATED AND SEGREGATED ACCORDING TO SIZE AND TYPE. 1 Order number 940620-103843-ROD -001-001 page 4301 set 4 with 100 of 100 items THE SELECTED WASTE HAULER AND DISPOSAL FACILITY WILL BE IN COMPLIANCE WITH APPLICABLE FEDERAL (RCRA AND TSCA) AND APPROPRIATE STATE ENVIRONMENTAL AND PUBLIC HEALTH STATUTES. IF NECESSARY, RCRA MANIFESTS REQUIRED UNDER 40 CFR PARTS 262 AND 263 WILL BE COMPLETED FOR ALL WASTES SHIPPED OFF-SITE. IN ADDITION, THE FACILITY WILL COMPLY WITH APPLICABLE HAZARDOUS WASTE GENERATOR REQUIREMENTS UNDER 40 CFR PART 262. THIS ALTERNATIVE WOULD BE IMPLEMENTED AT THE PLANT AND OFF-SITE AREAS. 7.4.2 EFFECTIVENESS THE EFFECTIVENESS OF LIMITED GROUNDWATER ACTION WAS DISCUSSED IN THE DESCRIPTION FOR ALTERNATIVE 2, AND IS THE SAME FOR THIS ALTERNATIVE. SHORT-TERM EFFECTIVENESS DURING WASTE REMOVAL AND SOIL CAPPING IS PROVIDED BY CONSTRUCTION TECHNIQUES THAT MINIMIZE HANDLING AND REDUCE THE DISPERSION OF WASTE CONSTITUENTS DURING CONTAINMENT AND EXCAVATION ACTIVITIES. EXCAVATION AND MOVEMENT OF SOLID WASTES WOULD RESULT IN A PERIOD DURING WHICH THE POTENTIAL FOR ADDITIONAL EXPOSURE WOULD EXIST. USE OF MEASURES FOR RUN-OFF PREVENTION AND DUST CONTROL WOULD PROVIDE PROTECTION TO HUMAN HEALTH AND THE ENVIRONMENT DURING CONSTRUCTION. NEITHER TOXICITY NOR VOLUME OF GROUNDWATER, SOIL, OR SLUDGE MATERIALS WOULD BE REDUCED BY IMPLEMENTATION OF THIS ALTERNATIVE. OFF-SITE MANAGEMENT OF WASTES BY LANDFILLING WOULD NOT REDUCE THE TOXICITY OR VOLUME OF THE MATERIALS. MOBILITY OF WASTE CONSTITUENTS REMOVED WOULD BE REDUCED. HAULING WASTES OFF-SITE CO POTENTIALLY EXPOSE THOSE PERSONS USING THE SAME ROADS, OR LIVING OR WORKING ALONG THE ROUTE, TO AFFECTED MATERIALS. LONG-TERM EFFECTIVENESS WOULD BE PROVIDED BY PROPER CAP MAINTENANCE AND THE REMEDIATION ACHIEVED BY WASTE REMOVAL AND OFF-SITE TREATMENT OR DISPOSAL. VOLUME AND TOXICITY OF AFFECTED SOIL AND SLUDGE WOULD NOT BE ALTERED BY THE TECHNIQUES USED IN THIS ALTERNATIVE. FOR CONTAINMENT OF SOILS AND SLUDGES, LONG-TERM PROTECTION WOULD BE PROVIDED-THROUGH THE CONTROL OF SEVERAL MIGRATION ROUTES AS FOLLOWS: * PARTICULATE RELEASES TO THE AIR, * DIRECT CONTACT WITH AFFECTED MEDIA, * GROUND SURFACE RUNOFF OF AFFECTED SEDIMENTS, * SURFACE WATER INFILTRATION INTO AFFECTED SOIL OR WASTES AND SUBSEQUENT MIGRATION THROUGH GROUNDWATER. HOWEVER, THIS ALTERNATIVE WOULD NOT CHANGE THE CHARACTERISTICS OF THE AFFECTED SOIL AND SLUDGE AS DESCRIBED IN SECTION 7.3.1. 1 Order number 940620-103843-ROD -001-001 page 4302 set 4 with 100 of 100 items 7.5 ALTERNATIVE 5: LIMITED GROUNDWATER ACTION WITH ON-SITE DISPOSAL OF SOLIDS 7.5.1 DESCRIPTION THE COMPONENTS OF THIS ALTERNATIVE INCLUDE THE MEASURES DESCRIBED IN SECTION 7.2.1 FOR LIMITED ACTION ON GROUNDWATER AND EXCAVATION AND DISPOSAL OF AFFECTED SOLID MATERIALS: SOIL, SLUDGE, AND SOLID WASTES. SLUDGE FROM THE ACTIVE LAGOON WOULD BE DREDGED AND MECHANICALLY DEWATERED. SOILS AND SOLID WASTES CONTAINING GREATER THAN 25 PPM OF PCBS WOULD BE EXCAVATED AND TRANSPORTED TO AN ON-SITE TSCA UNIT DESIGNED AND CONSTRUCTED SPECIFICALLY FOR THE DISPOSAL OF THESE MATERIALS. A LANDFILL CLOSURE WOULD BE IMPLEMENTED AFTER THE DISPOSAL IS COMPLETE. THIS ALTERNATIVE WOULD BE IMPLEMENTED AT ALL LOCATIONS. EVALUATION OF ALTERNATIVE 5 IS BASED ON EXCAVATION AND DISPOSAL OF THE FOLLOWING VOLUMES OF AFFECTED MATERIALS: AN ON-SITE, DOUBLE-LINED LANDFILL WOULD BE CONSTRUCTED FOR DISPOSAL OF AFFECTED SOLIDS FOR A CAPACITY OF 93,000 CUBIC YARDS, WHICH TAKES INTO ACCOUNT A 25 PERCENT EXPANSION OF 74,100 CUBIC YARDS OF SOLIDS AFTER EXCAVATION. LANDFILL DIMENSIONS WOULD BE APPROXIMATELY 400 FEET BY 300 FEET AT GRADE. THE DEPTH OF EXCAVATION BELOW GROUND SURFACE WOULD BE APPROXIMATELY 14 FEET, AND THE BERM HEIGHT AROUND THE LANDFILL WOULD BE APPROXIMATELY 17 FEET. THE LANDFILL WOULD BE CONSTRUCTED ACCORDING TO REGULATORY REQUIREMENTS OF THE STATE OF SOUTH CAROLINA AND THE US EPA. THESE REQUIREMENTS INCLUDE CONSTRUCTION OF A DOUBLE LINER WITH A LEACHATE COLLECTION SYSTEM ABOVE AND BETWEEN THE LINERS. THE TOP LINER MUST PREVENT THE MIGRATION OF WASTE CONSTITUENTS INTO THE LOWER LINER. THE BOTTOM LINER MUST PREVENT MIGRATION OF WASTE CONSTITUENTS. SOUTH CAROLINA CODE R.61-79.264.301 (C) REQUIRES A THREE-FEET THICK LAYER OF RECOMPACTED CLAY OR OTHER NATURAL MATERIAL AS A BOTTOM LINER. THE PERMEABILITY MUST BE NO MORE THAN 1 X (10-7) CENTIMETERS PER SECOND. THE LANDFILL CAP MUST BE LESS PERMEABLE THAN THE SOILS IMMEDIATELY BELOW THE LANDFILL. LANDFILL OPERATION AND MAINTENANCE (O&M) WOULD INCLUDE A NUMBER OF TASKS NECESSARY TO PROTECT THE INTEGRITY OF THE DISPOSAL UNIT. QUARTERLY MAINTENANCE WOULD BE PERFORMED ON THE ACCESS ROAD, THE LEACHATE COLLECTION AND TREATMENT SYSTEM, AND THE LANDFILL, WHICH IS EXPECTED TO COVER APPROXIMATELY THREE ACRES. GROUNDWATER MONITORING WOULD BE PERFORMED SEMIANNUALLY. THE ACTIVE MAINTENANCE PERIOD USED FOR ESTIMATING O&M COSTS IS 30 YEARS. 7.5.2 EFFECTIVENESS THE EFFECTIVENESS OF LIMITED ACTION ON GROUNDWATER WAS DISCUSSED IN SECTION 7.2.2 AND IS SIMILAR TO THAT PROVIDED BY THIS ALTERNATIVE. THE SHORT-TERM EFFECTIVENESS, DURING IMPLEMENTATION OF THIS ALTERNATIVE FOR 1 Order number 940620-103843-ROD -001-001 page 4303 set 4 with 100 of 100 items EXCAVATION AND ON-SITE DISPOSAL OF SOLID MATERIALS, WOULD BE PROVIDED BY THE USE OF EXCAVATION TECHNIQUES THAT MINIMIZE HANDLING AND REDUCE THE DISPERSION OF WASTE CONSTITUENTS. THE LARGE VOLUME OF MATERIAL THAT WOULD BE MOVED WOULD RESULT IN AN EXTENDED PERIOD DURING WHICH THE POTENTIAL FOR EXPOSURE WOULD EXIST. USE OF MEASURES FOR THE PREVENTION OF RUN-OFF AND THE CONTROL OF DUST WOULD PROVIDE SOME PROTECTION TO HUMAN HEALTH AND THE ENVIRONMENT DURING CONSTRUCTION. THE LONG-TERM EFFECTIVENESS OF THIS ALTERNATIVE WOULD BE PROVIDED BY PROPER MAINTENANCE OF THE ON-SITE LANDFILL. NEITHER THE VOLUME NOR THE TOXICITY OF AFFECTED MATERIALS WOULD BE ALTERED BY THE TECHNIQUES USED IN THIS ALTERNATIVE. REMOVAL OF SOURCE MATERIALS WOULD PREVENT FURTHER MIGRATION OF CONTAMINANTS INTO THE AQUIFER. 7.6 ALTERNATIVE 6: LIMITED GROUNDWATER ACTION WITH OFF-SITE DISPOSAL OF SOLIDS 7.6.1 ALTERNATIVE 6 CONSISTS OF LIMITED ACTION ON GROUNDWATER AS DESCRIBED IN SECTION 7.2.1; EXCAVATION OF AFFECTED SOLID MATERIALS, AS DESCRIBED IN SECTION 7.5.1, AND OFF-SITE DISPOSAL IN A SECURE TSCA LANDFILL. THE CONCEPTUAL LAYOUT OF THIS ALTERNATIVE WOULD BE THE SAME AS THAT FOR ALTERNATIVE 5, EXCEPT THAT ONCE EXCAVATED, THE MATERIAL WOULD BE TAKEN OFF-SITE. SOLID MATERIALS WOULD BE EXCAVATED, LOADED DIRECTLY ONTO TRUCKS, AND TRANSPORTED TO THE SELECTED LANDFILL. LAGOON SLUDGE WOULD BE EXCAVATED, DEWATERED, AND STOCKPILED. THE STOCKPILED SLUDGE WOULD THEN BE HAULED OFF-SITE. WATER COLLECTED DURING SLUDGE DEWATERING WOULD BE TRANSPORTED OFF-SITE FOR TREATMENT. THE SELECTED WASTE HAULER AND THE DISPOSAL FACILITY WILL BE IN COMPLIANCE WITH APPLICABLE FEDERAL AND STATE ENVIRONMENTAL AND PUBLIC HEALTH STATUTES. IF NECESSARY, RCRA MANIFESTS REQUIRED UNDER 40 CFR PARTS 262 AND 263 WILL BE COMPLETED FOR ALL WASTES SHIPPED OFF-SITE. IN ADDITION, THE FACILITY WILL COMPLY WITH APPLICABLE HAZARDOUS WASTE GENERATOR REQUIREMENTS UNDER 40 CFR PARTS 262. TRANSPORTING VEHICLES WILL BE APPROVED BY DOT AND WILL DISPLAY THE PROPER DOT PLACARD. FOR ESTIMATED COST, IT IS ASSUMED THAT 90 PERCENT OF THE MATERIAL CAN BE HANDLED BY A FACILITY APPROXIMATELY 500 MILES FROM THE SANGAMO PLANT SITE. THE REMAINING TEN PERCENT OF THE SOLID WASTES WOULD BE TRANSPORTED APPROXIMATELY 850 MILES TO AN INCINERATOR. 7.6.2 EFFECTIVENESS THE EFFECTIVENESS OF EXCAVATION COMBINED WITH LIMITED ACTION ON GROUNDWATER WAS DISCUSSED IN THE DESCRIPTION FOR ALTERNATIVE 5. REMAINS UNCHANGED FOR THIS ALTERNATIVE. IT OFF-SITE MANAGEMENT OF WASTES BY LANDFILLING WOULD NOT REDUCE THE 1 Order number 940620-103843-ROD -001-001 page 4304 set 4 with 100 of 100 items TOXICITY OR VOLUME OF MATERIALS. HOWEVER, LONG-TERM MOBILITY OF WASTE CONSTITUENTS WOULD BE REDUCED. HAULING WASTES OFF-SITE COULD POTENTIALLY EXPOSE THOSE PERSONS USING THE SAME ROADS, OR LIVING OR WORKING ALONG THE ROUTE, TO AFFECTED MATERIALS. 7.7 ALTERNATIVE 7: TREATMENT OF GROUNDWATER WITH ON-SITE DISPOSAL OF SOLIDS 7.7.1 DESCRIPTION ALTERNATIVE 7 IS COMPRISED OF THE FOLLOWING TWO COMPONENTS: 1) SOLID MATERIAL REMEDIATION WHICH INCLUDES EXCAVATION AND DISPOSAL IN A SECURE TSCA LANDFILL CONSTRUCTED ONSITE AS DESCRIBED IN SECTION 7.5.1. THIS REMEDIATION TECHNIQUE HAS BEEN DISCUSSED AND NEEDS NO FURTHER EXPLANATION FOR THE PURPOSES OF THIS ALTERNATIVE. 2) GROUNDWATER REMEDIATION WHICH CONSISTS OF GROUNDWATER COLLECTION, TREATMENT, AND DISCHARGE AT THE PLANT, BREAZEALE, DODGENS AND CROSS ROADS SITES. THE GROUNDWATER REMEDIATION TECHNIQUES DISCUSSED IN THIS SECTION ARE APPLICABLE TO THE PLANT, BREAZEALE, DODGENS AND CROSS ROADS SITES. GROUNDWATER COLLECTION AND TREATMENT IS NOT NECESSARY AT THE JOHN TROTTER, NIX AND WELBORN SITES. A DESCRIPTION OF THE COMPONENTS OF LIMITED GROUNDWATER ACTION THAT WOULD BE PERFORMED AT THESE THREE OFF-SITE AREAS APPEARS IN SECTION 7.2.1. EXCAVATION OF ALL SOLID MATERIALS CONTAINING GREATER THAN 25 PPM PCBS WOULD OCCUR AT EACH AFFECTED LOCATION. AS FORMULATED FOR THIS ALTERNATIVE, GROUNDWATER WOULD BE COLLECTED TO THE EXTENT POSSIBLE BY USE OF RECOVERY WELLS. RECOVERY WELLS WOULD BE INSTALLED DOWNGRADIENT OF THE SITES. BY PUMPING EACH WELL, AN EFFORT WOULD BE MADE TO CREATE A HYDRAULIC BARRIER. WHERE PUMPING OF INDIVIDUAL RECOVERY WELLS IS SUCCESSFUL IN REMOVING AFFECTED GROUNDWATER, IT ACCELERATES THE NATURAL FLUSHING OF WASTE CONSTITUENTS SORBED ON THE SOIL IN THE AQUIFER BY INCREASING THE FLOW RATE OF RELATIVELY CLEAN WATER FROM AREAS UPGRADIENT OF THE CONSTITUENT SOURCE THROUGH THE AFFECTED AREAS. SANGAMO PLANT SITE GROUNDWATER AT THE SANGAMO PLANT SITE OCCURS PRIMARILY WITHIN THE JOINT AND FRACTURE SYSTEM OF THE BEDROCK. GROUNDWATER FLOW WITHIN THE BEDROCK AT THE SANGAMO PLANT SITE IS LIMITED BY THE SIZE, ORIENTATION, AND INTERCONNECTION OF OPEN JOINTS AND FRACTURES. THESE WELLS MAY NOT REMOVE CONSTITUENTS THAT ARE HEAVIER THAN WATER. GROUNDWATER DISCHARGE 1 Order number 940620-103843-ROD -001-001 page 4305 set 4 with 100 of 100 items FROM WELLS SURROUNDING THE RIDGE WOULD CONTAIN PRIMARILY VOCS. THIS WATER WOULD BE TREATED BY AIR STRIPPING. GROUNDWATER DOWNGRADIENT OF AREAS A, B, E, AND THE WASTE WATER TREATMENT FACILITY WOULD BE TREATED BY CARBON ADSORPTION. IN THIS AREA, RI DATA SHOWED PCBS IN GROUNDWATER COLLECTED FROM 10 OF 17 WELLS. VOCS HAVE BEEN DETECTED IN A MAJORITY OF THESE WELLS. TREATED WATER WOULD BE DISCHARGED INTO TOWN CREEK. BREAZEALE SITE THE ASSUMED PUMPING SCHEME FOR THE BREAZEALE SITE CONSISTS OF GROUNDWATER EXTRACTION WELLS SCREENED IN THE SATURATED PORTIONS OF THE SAPROLITE AND FLOODPLAIN DEPOSITS. GROUNDWATER DISCHARGE WOULD CONTAIN VOCS AND WOULD BE TREATED THROUGH AIR STRIPPING. TREATED WATER WOULD BE DISCHARGED INTO WOLF CREEK. DODGENS SITE THE ASSUMED PUMPING SCHEME FOR THE DODGENS SITE CONSISTS OF GROUNDWATER EXTRACTION WELLS SCREENED IN THE SATURATED PORTIONS OF THE SAPROLITE. GROUNDWATER DISCHARGE MAY CONTAIN VOCS AND ONE SEMI-VOLATILE. COLLECTED GROUNDWATER WOULD BE TREATED THROUGH AIR STRIPPING AND CARBON ADSORPTION, IF NECESSARY. TREATED WATER WOULD BE DISCHARGED TO MIDDLE FORK TWELVEMILE CREEK. 7.7.2 EFFECTIVENESS THE EFFECTIVENESS PROVIDED BY THIS ALTERNATIVE IS RELATED TO THREE CRITERIA: * THE EXTENT TO WHICH THE GROUNDWATER COLLECTION SYSTEM IS CAPABLE OF PREVENTING MOVEMENT OF AFFECTED GROUNDWATER FROM THE PLANT, BREAZEALE, CROSS ROADS AND DODGENS SITES, * THE GRADUAL REDUCTION IN THE TOXICITY OF GROUNDWATER BY TREATMENT, * REDUCTION OF VOLUME OF THE AFFECTED MATERIAL, AND * PROPER DESIGN, CONSTRUCTION, AND MAINTENANCE OF THE LAND DISPOSAL UNIT. THE SHORT-TERM EFFECTIVENESS PROVIDED DURING CONSTRUCTION OF THIS ALTERNATIVE FOR GROUNDWATER COLLECTION AND ON-SITE DISPOSAL OF SOLID MATERIALS WOULD BE PROVIDED BY CONSTRUCTION TECHNIQUES AND WELL INSTALLATION METHODS THAT REDUCE THE MIGRATION OF WASTE CONSTITUENTS. THE LARGE VOLUME OF MATERIAL TO BE MOVED DURING EXCAVATION WOULD RESULT IN A PERIOD DURING WHICH A POTENTIAL FOR EXPOSURE WOULD EXIST. USE OF MEASURES FOR THE PREVENTION OF RUN-OFF AND THE CONTROL OF DUST WOULD 1 Order number 940620-103843-ROD -001-001 page 4306 set 4 with 100 of 100 items PROVIDE A MEASURE OF PROTECTION TO HUMAN HEALTH AND THE ENVIRONMENT DURING CONSTRUCTION. THE SOLID MATERIALS WOULD NOT BE REDUCED IN EITHER TOXICITY OR VOLUME BY THE IMPLEMENTATION OF THIS ALTERNATIVE. THE ON-SITE LAND DISPOSAL COMPONENT OF THIS ALTERNATIVE WOULD BE EFFECTIVE IN PROTECTING HUMAN HEALTH AND THE ENVIRONMENT FROM EXPOSURE TO WASTE CONSTITUENTS NEAR THE LAND DISPOSAL UNIT. EFFECTIVENESS WOULD BE MAINTAINED BY USE OF A PROGRAM THAT INCLUDES CAP AND COVER CARE AT THE LANDFILL, GROUNDWATER MONITORING, AND LEACHATE TREATMENT. 7.8 ALTERNATIVE 8: LIMITED GROUNDWATER ACTION WITH ON-SITE TREATMENT AND DISPOSAL OF SOLIDS 7.8.1 DESCRIPTION THIS ALTERNATIVE CONSISTS OF LIMITED ACTION ON GROUNDWATER, AS DESCRIBED IN SECTION 7.2.1, COUPLED WITH THE EXCAVATION OF SOLID MATERIALS AND TREATMENT OF THE MATERIALS IN AN ON-SITE TREATMENT SYSTEM. FOR SCREENING PURPOSES, FOUR TREATMENT TECHNOLOGIES WERE CONSIDERED: THERMAL DESTRUCTION, THERMAL SEPARATION, CHEMICAL DECHLORINATION, AND STABILIZATION. EACH OF THE FOLLOWING REPRESENTATIVE PROCESS OPTIONS HAS BEEN SELECTED BASED ON COMMERCIAL AVAILABILITY AND/OR HISTORY OF PRIOR FULL-SCALE APPLICATION: OPTION 8A: OPTION 8B: OPTION 8C: OPTION 8D: THERMAL DESTRUCTION - ROTARY KILN INCINERATION THERMAL SEPARATION - LOW TEMPERATURE THERMAL STRIPPING CHEMICAL DECHLORINATION - GLYCOLATE DECHLORINATION PHYSICAL STABILIZATION SOLIDIFICATION/FIXATION THE FIRST STEP IN THIS ALTERNATIVE WOULD INCLUDE EXCAVATION OF SOLID MATERIALS AFFECTED WITH GREATER THAN 1 PPM, 10 PPM, OR 25 PPM PCBS AS APPROPRIATE. FOLLOWING EXCAVATION, THE MATERIALS WOULD BE TEMPORARILY STOCKPILED ON THE PLANT SITE. THIS MATERIAL CONSISTS OF 2,900 CUBIC YARDS OF SOLID WASTE AND 48,200 CUBIC YARDS OF SOILS AND SEDIMENTS. SEDIMENTS WOULD BE DREDGED AND DEWATERED PRIOR TO TRANSPORT TO THE TREATMENT AREA. LIQUIDS PRODUCED DURING DEWATERING WOULD BE TEMPORARILY STORED IN TANKS AND THEN TRANSPORTED FOR TREATMENT IN THE LEACHATE TREATMENT UNIT AT THE ON-SITE TSCA LANDFILL. THE AVERAGE HAUL DISTANCE FROM ON-SITE EXCAVATION AREAS SITE WOULD BE LESS THAN APPROXIMATELY ONE-HALF MILE. THE AVERAGE HAUL DISTANCE FROM REMOTE SITE EXCAVATION AREAS WOULD BE APPROXIMATELY 2.5 MILES. THE VOLUME OF THE TREATMENT RESIDUALS WOULD BE DETERMINED DURING A TREATABILITY STUDY. LIMITED FIELD TRIALS MAY BE REQUIRED TO CONFIRM TREATMENT EFFECTIVENESS AND TO CHARACTERIZE TREATMENT RESIDUALS. EACH OF THE TREATMENT PROCESS OPTIONS WOULD REQUIRE PRE-PROCESSING OF THE SOLIDS TO REMOVE OVERSIZED ITEMS AND TO REDUCE THE PARTICLE SIZE. 1 Order number 940620-103843-ROD -001-001 page 4307 set 4 with 100 of 100 items THE COST AND ANALYSIS OF THIS ALTERNATIVE IS BASED IN PART ON THE ASSUMPTION THAT A PORTION OF THE TOTAL MASS OF SOLIDS WOULD BE REJECTED DURING PREPROCESSING. THE ASSUMPTION OF A ONE PERCENT REJECTION RATE IS USED BECAUSE MUCH OF THE AFFECTED AREAS ARE NOT COVERED WITH THICK STANDS OF TREES. THESE MATERIALS WOULD REQUIRE OFF-SITE DISPOSAL AND/OR TREATMENT AS A TSCA REGULATED WASTE IN A PERMITTED LANDFILL. UNDER ALL FOUR TREATMENT OPTIONS, EXCAVATED AREAS WOULD BE BACKFILLED WITH NATIVE SOIL, GRADED, AND RESTORED TO SUPPORT VEGETATION. A LONG-TERM GROUNDWATER MONITORING PROGRAM WOULD BE IMPLEMENTED, AS DESCRIBED IN ALTERNATIVE 1. OPTION 8A: THERMAL DESTRUCTION THIS OPTION INCLUDES USE OF A TRANSPORTABLE ROTARY KILN INCINERATOR THAT WOULD BE LOCATED AT THE SITE BY A COMMERCIAL VENDOR. THE UNIT WOULD MEET THE SUBSTANTIVE REQUIREMENTS OF ALL APPLICABLE PERMITS. THE SYSTEM WOULD CONSIST OF THE FOLLOWING TYPICAL UNIT OPERATIONS: * * * * * * * MATERIAL PREPROCESSING/SORTING ROTARY KILN INCINERATOR ASH HANDLING/STORAGE SECONDARY COMBUSTION OF OFF-GASES BAGHOUSE DUST COLLECTION WET SCRUBBER SCRUBBER WATER TREATMENT START-UP TESTS REQUIRED PRIOR TO FULL-SCALE OPERATION MAY REQUIRE FROM SIX MONTHS TO ONE AND ONE-HALF YEARS. TREATED SCRUBBER WATER COULD BE TEMPORARILY STORED IN A TANK AND TRANSPORTED TO THE LEACHATE TREATMENT SYSTEM LOCATED AT THE ON-SITE DISPOSAL UNIT. COMPLETE SYSTEM DETAILS WOULD BE DEVELOPED AS A REMEDIAL DESIGN TASK. OPTION 8B: THERMAL SEPARATION THERMAL SEPARATION IS A PROCESS OPTION RETAINED FROM THE SCREENING OF THERMAL TREATMENT TECHNOLOGIES. THERMAL SEPARATION IS A PROCESS IN WHICH SOILS OR SLUDGES WITH ORGANIC COMPOUNDS ARE HEATED IN A ROTARY DRYER. VOLATILIZED ORGANICS ARE TRANSFERRED, USING NITROGEN AS THE CARRIER GAS, AND COOLED TO CONDENSE ORGANIC COMPONENTS. THE CONDENSED COMPONENTS ARE THEN COLLECTED FOR FURTHER TREATMENT AT AN APPROPRIATE FACILITY. THE PERMIT REQUIREMENTS FOR THIS SYSTEM ARE STILL BEING DETERMINED BY 1 Order number 940620-103843-ROD -001-001 page 4308 set 4 with 100 of 100 items THE OWNER OF THE EQUIPMENT. HOWEVER, AS A "PROCESSING," RATHER THAN A "DESTRUCTION" METHOD, ATTAINMENT OF THE SUBSTANTIVE REQUIREMENTS OF RCRA OR TSCA PERMITS MAY NOT BE REQUIRED. THIS SYSTEM WOULD CONSIST OF THE FOLLOWING TYPICAL UNIT OPERATIONS: * * * * * * MATERIAL PREPROCESSING/SORTING ROTARY DRYER THERMAL SEPARATION CARBON ADSORPTION UNIT (OR COMBUSTION AFTERBURNER) COOLING AND CONDENSATE TRAIN OFF-GAS HANDLING TRAILER RESIDUALS MANAGEMENT UNIT ON THE BASIS OF PILOT STUDIES, A TREATMENT CAPACITY OF FIVE TONS PER HOUR CAN BE EXPECTED. ASSUMING A TYPICAL DENSITY OF APPROXIMATELY 1.3 TONS PER CUBIC YARD OF MATERIAL, THE ESTIMATED TIME EXPECTED TO COMPLETE TREATMENT WOULD BE APPROXIMATELY TWO YEARS. THIS ESTIMATE IS BASED ON THE USE OF ONE TREATMENT SYSTEM AND 30 PERCENT DOWNTIME. OPTION 8C: CHEMICAL DECHLORINATION THE PROPRIETARY KPEG PROCESS IS USED TO REPRESENT CHEMICAL TREATMENT TECHNOLOGIES APPROPRIATE FOR USE IN TREATING SOILS CONTAINING PCBS AND OTHER SOLIDS. SINCE THE KPEG PROCESS OPERATES UNDER HIGHLY ALKALINE CONDITIONS, ALUMINUM SLUDGE AND POSSIBLY OTHER METALS THAT REACT UNDER THESE CONDITIONS MAY INCREASE THE AMOUNT OF REAGENT REQUIRED BY COMPETING FOR THE KPEG: THEREFORE, THIS PROCESS OPTION IS NOT CONSIDERED APPLICABLE FOR TREATMENT OF SLUDGES. CHEMICAL TREATMENT DIRECTED TOWARD PCBS MAY PROVIDE COINCIDENTAL TREATMENT OF OTHER CHLORINATED VOLATILE ORGANICS. THE CHEMICAL TREATMENT SYSTEM WOULD CONSIST OF THE FOLLOWING TYPICAL OPERATIONS: * * * * * * MATERIAL PREPROCESSING/SORTING REAGENT STORAGE SOLIDS MIXING SOLIDS REACTION DECANT AND SOLIDS WASHING REAGENT RECYCLING AND CONDENSATION PROCESS WASTEWATERS WOULD BE TEMPORARILY STORED IN TANKS AND LATER TRANSPORTED TO THE LEACHATE TREATMENT SYSTEM. THE THE (24 THE PRESENT ESTIMATE BY GALSON RESEARCH CORPORATION (PATENT-HOLDER) OF ACHIEVABLE TREATMENT RATE USING KPEG IS 250 YD3/D. CONTINUOUS HR/D) PROCESSING OF THE ENTIRE VOLUME WOULD REQUIRE OVER ONE YEAR. ESTIMATE ASSUMES A MINIMUM OF 30 PERCENT DOWNTIME FOR THE PROCESS. OPTION 8D: PHYSICAL STABILIZATION 1 Order number 940620-103843-ROD -001-001 page 4309 set 4 with 100 of 100 items PHYSICAL STABILIZATION, OR SOLIDIFICATION/FIXATION WAS CONSIDERED FOR USE AS A TREATMENT PROCESS FOR SOIL AND SLUDGE. THIS TREATMENT WOULD REDUCE THE MOBILITY OF WASTE CONSTITUENTS BY BINDING THE SOIL OR SLUDGE MASS INTO SOLID MATRIX WITH LOW PERMEABILITY THAT RESISTS LEACHING. THIS ALTERNATIVE WOULD INCREASE THE VOLUME OF AFFECTED MATERIAL. THE TREATMENT SYSTEM WOULD CONSIST OF THE FOLLOWING TYPICAL UNIT OPERATIONS: * * * MATERIAL PREPROCESSING/SORTING SETTING AGENT STORAGE PUGMILL MIXING THE EQUIPMENT REQUIRED FOR SOLIDIFICATION/FIXATION WOULD BE SIMILAR TO THAT USED FOR CEMENT MIXING. THE TREATED MATERIAL WOULD BE TRANSPORTED TO THE ON-SITE DISPOSAL UNIT FOR CURING AND DISPOSAL. SINCE THE PROCESSES USED IN SOLIDIFICATION/FIXATION ARE LOGISTICALLY SIMILAR TO THOSE OF CEMENT MIXING, THE TIME REQUIRED TO TREAT THE SOIL AND SLUDGE WOULD NOT VARY SIGNIFICANTLY FROM THAT REQUIRED FOR EXCAVATION. 7.8.2 EFFECTIVENESS THE SHORT-TERM PROTECTIVENESS PROVIDED DURING EXCAVATION AND TREATMENT OF ALL SOLIDS CONTAINING MORE THAN 25 PPM PCBS WOULD BE ACCOMPLISHED BY USE OF CONSTRUCTION METHODS THAT MINIMIZE TRANSPORT. TEMPORARY BERMS AND RUN-OFF CONTROL DITCHES WOULD BE USED TO CONTROL TRANSPORT OF AFFECTED SOILS. LONG-TERM PROTECTION WOULD BE ACCOMPLISHED BY REMOVAL AND DESTRUCTION OF WASTE CONSTITUENTS. TOXICITY, MOBILITY, AND VOLUME OF HAZARDOUS MATERIALS WOULD BE REDUCED BY TREATMENT. ANY POTENTIAL LONG-TERM SURFACE MIGRATION BY THE LOW CONCENTRATIONS OF WASTE CONSTITUENTS THAT REMAIN IN PLACE WOULD BE LIMITED BY PLACEMENT OF CLEAN BACKFILL. GROUNDWATER QUALITY WOULD BE MONITORED BY THE SAMPLING AND ANALYSIS PROGRAM PROPOSED AS PART OF THE LIMITED ACTION RESPONSE. FOUR TREATMENT PROCESSES ARE UNDER CONSIDERATION AS PART OF THIS ALTERNATIVE: ROTARY KILN INCINERATION, THERMAL SEPARATION, GLYCOLATE DECHLORINATION, AND STABILIZATION/FIXATION. EACH PROCESS HAS BEEN SHOWN TO BE EFFECTIVE IN REDUCTION OF AT LEAST ONE OF THREE WASTE CHARACTERISTICS: TOXICITY, MOBILITY OR VOLUME FOR ONE OR MORE OF THE CONSTITUENTS OF CONCERN. THE COMBINATION OF TREATMENT WITH DISPOSAL OF RESIDUALS IN AN ON-SITE SECURE LANDFILL WOULD PROVIDE AN EFFECTIVE MEANS OF REDUCING TOXICITY, MOBILITY, AND VOLUME OF WASTE CONSTITUENTS. OPTION 8A: THERMAL DESTRUCTION (ROTARY KILN) 1 Order number 940620-103843-ROD -001-001 page 4310 set 4 with 100 of 100 items THE EFFECTIVENESS OF INCINERATION AS A TREATMENT PROCESS FOR ORGANIC COMPOUNDS HAS BEEN DEMONSTRATED AT NUMEROUS SITES. THIS TREATMENT PROCESS WOULD AFFECT ALL THREE OF THE CHARACTERISTICS FOR PCBS AND HALOGENATED AND NONHALOGENATED VOLATILES. IT WOULD NOT AFFECT ANY OF THE THREE CHARACTERISTICS FOR AFFECTED MATERIALS CONTAINING METALS. OPTION 8B: THERMAL SEPARATION THERMAL SEPARATION HAS BEEN SHOWN TO HAVE A REMOVAL EFFICIENCY OF GT 99.95 PERCENT FOR PCBS. ITS EFFECTIVENESS FOR TREATMENT OF VOLATILE ORGANIC COMPOUNDS HAS ALSO BEEN DEMONSTRATED. IF RESULTS OF CURRENT TESTS USING THIS PROCESS INDICATE APPLICABILITY AT THIS SITE, A TREATABILITY STUDY WOULD BE PERFORMED ON SAMPLES OF SOIL AND SLUDGE TAKEN FROM THE SANGAMO PLANT AS PART OF THE REMEDIAL DESIGN PHASE OF SITE REMEDIATION. OPTION 8C: GLYCOLATE DECHLORINATION (KPEG) KPEG, WHILE NOT SPECIFICALLY DESIGNED FOR THE TREATMENT OF ORGANICS OTHER THAN PCBS, MAY PROVIDE FURTHER PROTECTION BY REMOVING VOLATILE ORGANIC COMPOUNDS DURING REACTION OR SOIL-WASHING PHASES. IT HAS BEEN USED AT FULL SCALE FOR TREATMENT OF PCBS IN SOIL, BUT IT HAS NOT BEEN USED ROUTINELY FOR TREATMENT OF WASTE CONSTITUENTS LIKE THOSE FOUND AT THE PLANT SITE. THE KPEG PROCESS WOULD NOT AFFECT THE CHARACTERISTICS OF METALS IN SOIL. A TREATABILITY STUDY WILL BE CONDUCTED TO EVALUATE ITS OVERALL EFFECTIVENESS ON THE WASTE CONSTITUENTS PRESENT AT THE SITE. TREATED RESIDUALS FROM EACH OF THE THREE PRECEDING PROCESS OPTIONS WOULD BE ANALYZED FOR THE PRESENCE OF METALS. RESULTS OF THE RI INDICATE THAT CONCENTRATION OF METALS WILL NOT EXCEED PERMISSIBLE LIMITS FOR LAND DISPOSAL. OPTION 8D: PHYSICAL STABILIZATION THIS PROCESS, USED IN THE TREATMENT OF INORGANIC COMPOUNDS, HAS A WELL DOCUMENTED HISTORY OF SUCCESSFULLY IMMOBILIZING WASTE CONSTITUENTS. A LIMIT TO THE EFFECTIVENESS OF THIS PROCESS IS THE QUANTITY OF OIL AND GREASE PRESENT IN AFFECTED MEDIA. THE CONCENTRATIONS OF OIL AND GREASE ARE MORE SIGNIFICANT IN DETERMINING THE APPLICABILITY OF STABILIZATION THAN THE PCB CONCENTRATIONS IN THE AFFECTED MEDIA. A TREATABILITY STUDY WOULD HAVE TO BE PERFORMED TO DETERMINE THE EFFECTIVENESS OF THIS PROCESS ON THE CONCENTRATIONS OF WASTE CONSTITUENTS DETECTED AT THE SITE. 7.9 ALTERNATIVE 9: TREATMENT OF GROUNDWATER, LIMITED ACTION ON SOILS, IN SITU TREATMENT OF SOIL, OFF-SITE TREATMENT AND DISPOSAL OF SOLID WASTES, AND ON-SITE TREATMENT AND DISPOSAL OF SLUDGE 7.9.1 DESCRIPTION 1 Order number 940620-103843-ROD -001-001 page 4311 set 4 with 100 of 100 items SEVERAL DIFFERENT COMPONENTS MAKE UP THIS ALTERNATIVE AND ARE DISCUSSED IN THIS SECTION. THE GROUNDWATER COLLECTION TECHNIQUE FOR THIS ALTERNATIVE IS DISCUSSED IN SECTION 7.7.1. REMEDIATION OF THE 48,200 CUBIC YARDS OF AFFECTED SOIL WOULD BE THROUGH IN-SITU BIODEGRADATION. THIS PROCESS OPTION, COUPLED WITH GROUNDWATER COLLECTION, CAN PROVIDE SUBSTANTIAL REDUCTION IN CONCENTRATIONS OF ORGANIC COMPOUNDS INTO WATER AND CARBON DIOXIDE IN THE PRESENCE OF SUFFICIENT OXYGEN AND NUTRIENTS AND PHOSPHOROUS. TYPICAL UNIT PROCESSES THAT WOULD BE REQUIRED FOR THIS ELEMENT FOLLOW: * * BIOLOGICAL INOCULUM FERMENTER NUTRIENT FEED SYSTEM * * OXYGENATION SYSTEM CHEMICAL/BIOLOGICAL ADDITIVE CONTROL AND FEED SYSTEM SITE SPECIFIC PILOT TESTS WOULD BE REQUIRED TO ESTIMATE A TIME OF COMPLETION FOR REMEDIATION. TREATMENT OF AFFECTED SLUDGE WHICH CONSISTS OF 23,000 CUBIC YARDS, WOULD BE PERFORMED ON-SITE WITH ONE OF THE FOLLOWING PROCESSES: THERMAL DESTRUCTION, THERMAL SEPARATION, GLYCOLATE DECHLORINATION, OR PHYSICAL STABILIZATION. HOWEVER, IF TREATABILITY DATA SO INDICATES, BIOREMEDIATION OF SLUDGE MAY BE APPROPRIATE. THE DESCRIPTIONS FOR THE FIRST FOUR OPTIONS ARE DISCUSSED IN SECTION 7.8.1. THE TREATMENT RESIDUALS WOULD REMAIN ON-SITE FOR DISPOSAL IN A SECURE TSCA LANDFILL. THE VOLUME OF THE TREATMENT RESIDUALS WOULD BE DETERMINED DURING THE TREATABILITY STUDY. IN THIS ALTERNATIVE, SOLID WASTES WOULD BE EXCAVATED THEN TREATED AND DISPOSED OF OFF-SITE IN A TSCA LANDFILL. IF THERMAL DESTRUCTION IS THE OPTION SELECTED FOR SLUDGE TREATMENT, SOLID WASTES WOULD BE TREATED ON-SITE; OTHERWISE, THE 2,900 CUBIC YARDS OF SOLID WASTES WOULD BE SHIPPED OFF-SITE FOR THERMAL DESTRUCTION. THIS RESPONSE ACTION IS DISCUSSED IN SECTION 7.8.1. 7.9.2 EFFECTIVENESS THE SHORT-TERM PROTECTION PROVIDED DURING EXCAVATION AND TREATMENT OF ALL SLUDGES AND SOLID WASTES CONTAINING GREATER THAN 25 PPM PCBS WOULD BE SIMILAR TO THAT DISCUSSED IN SECTION 7.4.2. HOWEVER, IMPLEMENTATION OF THIS ALTERNATIVE WOULD REQUIRE A GREATER VOLUME OF MATERIAL TO BE EXCAVATED THAN THAT INCLUDED IN ALTERNATIVE 4. TEMPORARY BERMS AND RUN-OFF CONTROL DITCHES WOULD BE USED TO CONTROL TRANSPORT OF AFFECTED SOLIDS AT GROUND SURFACE. LONG-TERM PROTECTION WOULD BE ACCOMPLISHED BY REMOVAL AND DESTRUCTION OF SLUDGES AND SOLID WASTES. THE TOXICITY, MOBILITY, AND VOLUME OF THESE 1 Order number 940620-103843-ROD -001-001 page 4312 set 4 with 100 of 100 items MEDIA WOULD BE REDUCED BY TREATMENT. THE LONG-TERM EFFECTIVENESS OF THE GROUNDWATER REMEDIATION SYSTEM IS UNKNOWN. THE LONG-TERM EFFECTIVENESS OF BIODEGRADATION IS POOR IN AREAS WHERE AFFECTED SOILS LIE ABOVE GROUNDWATER. HOWEVER, LIMITED ACTIONS IN THOSE AREAS WOULD SUPPLEMENT BIOREMEDIATION AND INCREASE THE PROTECTION OF HUMAN HEALTH AND THE ENVIRONMENT FROM EXPOSURE TO WASTE CONSTITUENTS. THE EFFECTIVENESS WOULD BE MAINTAINED BY USE OF A PROGRAM INCLUDING INSTITUTIONAL CONTROLS, SURFACE CARE IN BIOREMEDIATION AREAS, AND GROUNDWATER MONITORING. THE ON-SITE LAND DISPOSAL COMPONENT OF THIS ALTERNATIVE WOULD BE EFFECTIVE IN PROTECTING HUMAN HEALTH AND THE ENVIRONMENT FROM EXPOSURE TO WASTE CONSTITUENTS IN THE VICINITY OF THE LAND DISPOSAL UNIT. THE EFFECTIVENESS WOULD BE MAINTAINED BY USE OF A PROGRAM INCLUDING SURFACE CARE AT THE LANDFILL, GROUNDWATER MONITORING, AND LEACHATE TREATMENT. 7.10 ALTERNATIVE 10: LIMITED GROUNDWATER ACTION WITH ON-SITE TREATMENT AND OFF-SITE DISPOSAL OF SOLIDS 7.10.1 DESCRIPTION THE COMPONENTS OF THIS ALTERNATIVE ARE DISCUSSED AS FOLLOWS: 1. GROUNDWATER COMPONENT - LIMITED ACTION, SECTION 7.2.1. 2. EXCAVATION AND TREATMENT OF SOIL, SLUDGE, AND SOLID WASTES - LIMITED GROUNDWATER ACTION WITH ON-SITE TREATMENT AND OFF-SITE DISPOSAL OF SOLIDS, SECTION 7.8.1. THE COMPONENT THAT MAKES THIS ALTERNATIVE DIFFERENT FROM ALTERNATIVE 8 IS OFF-SITE DISPOSAL OF TREATMENT RESIDUALS. 7.10.2 EFFECTIVENESS THE SHORT-TERM PROTECTION PROVIDED DURING EXCAVATION AND TREATMENT OF ALL SOLIDS CONTAINING GREATER THAN 25 PPM PCBS WOULD BE PROVIDED BY USE OF CONSTRUCTION METHODS THAT MINIMIZE TRANSPORT OF AFFECTED MATERIALS. TEMPORARY BERMS AND RUN-OFF CONTROL DITCHES WOULD BE USED TO CONTROL TRANSPORT OF AFFECTED SOLIDS AT GROUND SURFACE. LONG-TERM PROTECTION WOULD BE ACCOMPLISHED BY REMOVAL AND DESTRUCTION OF WASTE CONSTITUENTS. THE TOXICITY, MOBILITY, AND VOLUME OF AFFECTED MATERIALS WOULD BE REDUCED BY TREATMENT. ANY POTENTIAL LONG-TERM MIGRATION AT GROUND SURFACE BY THE LOW CONCENTRATIONS OF WASTE CONSTITUENTS THAT REMAIN IN PLACE WOULD BE LIMITED BY PLACEMENT OF CLEAN BACKFILL. 1 Order number 940620-103843-ROD -001-001 page 4313 set 4 with 100 of 100 items GROUNDWATER QUALITY WOULD BE MONITORED BY THE SAMPLING AND ANALYSES PROPOSED AS PART OF THE NO ACTION RESPONSE DESCRIBED IN SECTION 7.1. THE TREATMENT PROCESSES UNDER CONSIDERATION AS PART OF THIS ALTERNATIVE HAVE BEEN SHOWN TO BE EFFECTIVE IN REDUCING AT LEAST ONE OF THREE WASTE CHARACTERISTICS: TOXICITY, MOBILITY OR VOLUME FOR ONE OR MORE OF THE CONSTITUENTS OF CONCERN. THESE TREATMENT PROCESSES ARE DISCUSSED IN ALTERNATIVE 8. THE COMBINATION OF TREATMENT WITH DISPOSAL OF RESIDUALS IN AN OFF-SITE SECURE TSCA LANDFILL WOULD PROVIDE AN EFFECTIVE MEANS OF REDUCING TOXICITY, MOBILITY, AND VOLUME OF WASTE CONSTITUENTS. 7.11 ALTERNATIVE 11: TREATMENT OF GROUNDWATER WITH ON-SITE TREATMENT AND ON-SITE DISPOSAL OF SOLIDS 7.11.1 DESCRIPTION THE COMPONENTS THAT MAKE UP THIS ALTERNATIVE ARE IDENTICAL TO THOSE OF ALTERNATIVE 8 WITH ONE EXCEPTION: IN THIS ALTERNATIVE, GROUNDWATER WOULD BE REMEDIATED BY COLLECTION, TREATMENT AND DISPOSAL. THIS ACTION FOR GROUNDWATER IS DESCRIBED IN SECTION 7.7.1. 7.11.2 EFFECTIVENESS THE SHORT-TERM PROTECTION PROVIDED DURING EXCAVATION AND TREATMENT OF ALL SOLIDS CONTAINING GREATER THAN 25 PPM PCBS WOULD BE ACCOMPLISHED BY USE OF CONSTRUCTION METHODS THAT MINIMIZE TRANSPORT OF AFFECTED MATERIALS. THE LARGE VOLUME OF MATERIAL TO BE MOVED DURING EXCAVATION WOULD RESULT IN A PERIOD DURING WHICH A POTENTIAL FOR EXPOSURE WOULD EXIST. TEMPORARY BERMS AND RUN-OFF CONTROL DITCHES WOULD BE USED TO CONTROL TRANSPORT OF AFFECTED SOLIDS AT GROUND SURFACE. LONG-TERM PROTECTION WOULD BE ACCOMPLISHED BY REMOVAL AND DESTRUCTION OF WASTE CONSTITUENTS. THE TOXICITY, MOBILITY, AND VOLUME OF HAZARDOUS MATERIALS WOULD BE REDUCED BY TREATMENT. ANY POTENTIAL LONG-TERM MIGRATION AT GROUND SURFACE BY THE LOW CONCENTRATIONS OF WASTE CONSTITUENTS THAT REMAIN IN PLACE WOULD BE LIMITED BY PLACEMENT OF CLEAN BACKFILL. THE TREATMENT PROCESSES UNDER CONSIDERATION AS PART OF THIS ALTERNATIVE INCLUDING INCINERATION, THERMAL SEPARATION, GLYCOLATE DECHLORINATION, AND STABILIZATION/FIXATION, HAVE BEEN SHOWN TO BE EFFECTIVE IN REDUCTION OF AT LEAST ONE OF THREE WASTE CHARACTERISTICS: TOXICITY, MOBILITY, OR VOLUME FOR ONE OR MORE OF THE CONSTITUENTS OF CONCERN. THESE TREATMENT PROCESSES ARE DISCUSSED IN ALTERNATIVE 8. THE COMBINATION OF TREATMENT WITH DISPOSAL OF RESIDUALS IN AN ON-SITE SECURE LANDFILL WOULD PROVIDE AN EFFECTIVE MEANS OF REDUCING TOXICITY, MOBILITY, AND VOLUME OF WASTE CONSTITUENTS. THE ON-SITE LAND DISPOSAL COMPONENT OF THIS ALTERNATIVE WOULD BE 1 Order number 940620-103843-ROD -001-001 page 4314 set 4 with 100 of 100 items EFFECTIVE IN PROTECTING HUMAN HEALTH AND THE ENVIRONMENT FROM EXPOSURE TO WASTE CONSTITUENTS IN THE VICINITY OF THE LAND DISPOSAL UNIT. THE EFFECTIVENESS WOULD BE MAINTAINED BY USE OF A PROGRAM INCLUDING SURFACE CARE AT THE LANDFILL, GROUNDWATER MONITORING, AND LEACHATE TREATMENT. 7.12 ALTERNATIVE 12: TREATMENT OF GROUNDWATER WITH ON-SITE AND OFF-SITE DISPOSAL OF SOLIDS TREATMENT 7.12.1 DESCRIPTION THE COMPONENTS THAT COMPRISE THIS ALTERNATIVE ARE THE SAME AS THOSE THAT MAKE UP ALTERNATIVE 10, WITH ONE EXCEPTION: THIS ALTERNATIVE INCLUDES COLLECTION, TREATMENT, AND DISCHARGE OF GROUNDWATER. THE ELEMENTS THAT WOULD BE USED TO EXCAVATE AND TREAT SOLID MATERIALS ARE DESCRIBED IN SECTION 7.8.1. THE ELEMENTS THAT WOULD BE USED TO TRANSPORT AND DISPOSE THE MATERIALS ARE DESCRIBED IN SECTION 7.6.1. 7.12.2 EFFECTIVENESS THE SHORT-TERM PROTECTION PROVIDED DURING EXCAVATION AND TREATMENT OF ALL SOLIDS CONTAINING GREATER THAN 25 PPM PCBS WOULD BE ACCOMPLISHED BY USE OF CONSTRUCTION METHODS THAT MINIMIZE TRANSPORT OF AFFECTED MATERIALS. EXCAVATION OF ALL SOLIDS WOULD RESULT IN A PERIOD DURING WHICH THE RISK OF EXPOSURE WOULD BE INCREASED. TEMPORARY BERMS AND RUN-OFF CONTROL DITCHES WOULD BE USED TO CONTROL TRANSPORT OF AFFECTED SOLIDS AT THE GROUND SURFACE. ANY WASTES HAULED OFF-SITE COULD POTENTIALLY EXPOSE THOSE PERSONS USING THE SAME ROADS, OR LIVING OR WORKING ALONG THE ROUTE, TO AFFECTED TREATMENT RESIDUALS. LONG-TERM PROTECTION WOULD BE ACCOMPLISHED BY REMOVAL AND DESTRUCTION OF WASTE CONSTITUENTS. THE TOXICITY, MOBILITY, AND VOLUME OF WASTE MATERIALS WOULD BE REDUCED BY TREATMENT. ANY POTENTIAL LONG-TERM MIGRATION AT GROUND SURFACE BY THE LOW CONCENTRATIONS OF WASTE CONSTITUENTS THAT REMAIN IN PLACE WOULD BE LIMITED BY PLACEMENT OF CLEAN BACKFILL AND MONITORED BY THE SAMPLING AND ANALYSES PROPOSED AS PART OF THE LIMITED ACTION PLAN FOR SOLIDS. THE TREATMENT PROCESSES UNDER CONSIDERATION AS PART OF THIS ALTERNATIVE, INCLUDING ROTARY KILN INCINERATION, THERMAL SEPARATION, GLYCOLATE DECHLORINATION, AND STABILIZATION/FIXATION HAVE BEEN SHOWN TO BE EFFECTIVE IN REDUCTION OF AT LEAST ONE OF THREE WASTE CHARACTERISTICS: TOXICITY, MOBILITY OR VOLUME FOR ONE OR MORE OF THE CONSTITUENTS OF CONCERN. THESE TREATMENT PROCESSES ARE DISCUSSED IN ALTERNATIVE 8. THE COMBINATION OF TREATMENT WITH DISPOSAL OF RESIDUALS IN AN OFF-SITE SECURE LANDFILL WOULD PROVIDE AN EFFECTIVE MEANS OF REDUCING TOXICITY, MOBILITY, AND VOLUME OF WASTE CONSTITUENTS. ALTERNATIVE 13: CONSOLIDATED REMEDY/NO ACTION, LIMITED ACTION. EXCAVATION AND TREATMENT OF ACTIVE AND INACTIVE LAGOON SLUDGES 1 Order number 940620-103843-ROD -001-001 page 4315 set 4 with 100 of 100 items 7.13.1 DESCRIPTION THIS ALTERNATIVE INCLUDES REMEDIAL ACTION ELEMENTS PREVIOUSLY DISCUSSED IN THE DESCRIPTIONS OF OTHER ALTERNATIVES AND ADDRESSES EACH SECTION OF THE PLANT AND OFF-SITE AREAS WITH RESPECT TO THE SPECIFIC REMEDIAL REQUIREMENTS OF EACH LOCATION. WHILE A LARGER NUMBER OF TECHNOLOGY COMBINATIONS ARE POSSIBLE, THIS ALTERNATIVE OPTIMIZES THE USE OF MULTIPLE REMEDIAL ACTIONS WITHIN ONE CONSOLIDATED REMEDY. PLANT SITE: NO ACTION ON ALL MEDIA: DRAINFIELD (200 CUBIC YARDS OF SOIL). LIMITED ACTION ON GROUNDWATER WITH CONTAINMENT OF SOLIDS: PLANT AREAS A, B, C, E, F, G/H (15,500 CUBIC YARDS OF SOLID WASTE) LIMITED ACTION ON GROUNDWATER WITH SLUDGE EXCAVATION (18,400 CUBIC YARDS), TREATMENT, AND ON-SITE DISPOSAL OF RESIDUALS: WASTEWATER TREATMENT PLANT - STABILIZATION LAGOON (VOLUME OF TREATMENT RESIDUALS WOULD BE DETERMINED DURING THE TREATABILITY STUDY). LIMITED ACTION ON GROUNDWATER WITH CONTAINMENT OF AFFECTED SOILS (9,700 CUBIC YARDS), AND SLUDGE EXCAVATION (3,800 CUBIC YARDS), TREATMENT, AND ON-SITE DISPOSAL OF WASTE: WASTEWATER TREATMENT PLANT - INACTIVE LAGOON. OFF-SITE AREAS NO ACTION ON ALL MEDIA: NIX AND WELBORN (1200 CUBIC YARDS OF SOLIDS). LIMITED ACTION ON GROUNDWATER AND SOLIDS: CROSSROADS (5,100 CUBIC YARDS OF SOLIDS). LIMITED ACTION ON GROUNDWATER WITH CONTAINMENT OF SOLIDS: BREAZEALE (5,500 CUBIC YARDS OF SOLIDS). NO ACTION ON GROUNDWATER WITH CONTAINMENT OF SOLIDS: DODGENS (2,000 CUBIC YARDS), AND JOHN TROTTER (700 CUBIC YARDS OF SOLIDS). THE TECHNICAL COMPONENTS OF ALL THESE ELEMENTS WERE DISCUSSED IN THE DESCRIPTION SECTION OF PREVIOUSLY ANALYZED ALTERNATIVES. 7.13.2 EFFECTIVENESS IN AREAS WHERE EITHER NO ACTION OR LIMITED ACTION ARE PROPOSED, THIS ALTERNATIVE WOULD NOT CHANGE THE CHARACTERISTICS OF THE WASTE AND AFFECTED MATERIAL. THEREFORE, TOXICITY, MOBILITY, AND VOLUME OF THE 1 Order number 940620-103843-ROD -001-001 page 4316 set 4 with 100 of 100 items MATERIAL WOULD BE REDUCED ONLY TO THE DEGREE PROVIDED BY NATURAL ATTENUATION. LAND USE RESTRICTIONS INSTITUTED AS PART OF LIMITED ACTION WOULD MITIGATE THE POTENTIAL RISK POSED BY DIRECT CONTACT WITH AFFECTED MATERIAL LEFT IN PLACE. WHERE CONTAINMENT IS IMPLEMENTED, THE SHORT-TERM EFFECTIVENESS WOULD BE IMPROVED OVER THAT PROVIDED BY EXCAVATION. THE AFFECTED MATERIAL WOULD BE CAPPED WITH A RELATIVELY SMALL INCREASE IN INHALATION EXPOSURES BY WORKERS AND OFF-SITE POPULATIONS. IN AREA D AT THE PLANT SITE, THE SHORT-TERM EXPOSURES FROM INSTALLING A VACUUM EXTRACTION SYSTEM WOULD BE NO GREATER THAN THAT ASSOCIATED WITH INSTALLATION OF GROUNDWATER MONITORING WELLS. THE LONG-TERM EFFECTS OF VACUUM EXTRACTION OF VOLATILE ORGANICS WOULD BE DECREASES IN MOBILITY OF WASTE CONSTITUENTS AND REDUCTION IN THE TOXICITY AND VOLUME OF THOSE CONSTITUENTS IN THE SOIL PORE SPACE. EXCAVATION, TREATMENT, AND ON-SITE DISPOSAL OF SLUDGE RESIDUALS WOULD CAUSE AN INCREASE IN THE EXPOSURE POTENTIAL OF WASTE CONSTITUENTS DURING CONSTRUCTION. THE LONG-TERM EFFECTS WOULD BE A DECREASE IN THE TOXICITY AND MOBILITY OF AFFECTED MATERIALS. #SCAA 8.0 SUMMARY OF COMPARATIVE ANALYSIS OF ALTERNATIVES OVERALL PROTECTION OF HUMAN HEALTH AND THE ENVIRONMENT GROUNDWATER ALTERNATIVES ALTERNATIVES 7, 9, 11 AND 12 INCLUDE EXTRACTION AND TREATMENT OF CONTAMINATED GROUNDWATER AT THE PLANT SITE, DODGENS, BREAZEALE, AND CROSS ROADS SITES. THESE ALTERNATIVES WOULD PREVENT FURTHER MIGRATION OF THE CONTAMINANT PLUME AND WOULD, THEREFORE PROVIDE THE BEST OVERALL PROTECTION OF HUMAN HEALTH AND THE ENVIRONMENT. THE REMAINING SITES DID NOT APPEAR TO HAVE CONTAMINATION AT LEVELS ABOVE ACCEPTABLE LIMITS. INSTITUTIONAL CONTROLS (I.E. DEED RESTRICTIONS, ORDINANCES BANNING SHALLOW WELLS, FENCES, ETC.) WOULD PROVIDE LIMITED PROTECTION, BUT WOULD NOT PREVENT EVENTUAL CONTAMINATION OF SURFACE WATER AND FURTHER CONTAMINATION OF GROUNDWATER. THE NO ACTION ALTERNATIVE WOULD NOT PROVIDE ANY PROTECTION FOR HUMAN HEALTH OR THE ENVIRONMENT. SOURCE CONTROL ALTERNATIVES ALTERNATIVES 8, 10, 11, AND 12 INCLUDED FOUR TECHNOLOGIES FOR TREATMENT OF CONTAMINATED WASTE AND SOIL WERE EVALUATED IN THE FEASIBILITY STUDY. THESE WERE INCINERATION, LOW-TEMPERATURE THERMAL SEPARATION, GLYCOLATE DECHLORINATION AND SOLIDIFICATION. OF THESE TREATMENTS, THERMAL SEPARATION ON OR OFF-SITE APPEARS TO PROVIDE THE BEST OVERALL PROTECTION OF HUMAN HEALTH AND THE ENVIRONMENT. THERMAL SEPARATION USES AN 1 Order number 940620-103843-ROD -001-001 page 4317 set 4 with 100 of 100 items INDIRECT HEAT SOURCE TO REMOVE CONTAMINATION FROM THE SOIL, THEREBY CONDENSING IT INTO A MORE MANAGEABLE VOLUME. INCINERATION WOULD ALSO PROVIDE PROTECTION FOR HUMAN HEALTH AND THE ENVIRONMENT. GLYCOLATE DECHLORINATION HAS NOT BEEN DEMONSTRATED TO BE EFFECTIVE IN THE FIELD AND IT IS UNCERTAIN HOW PROTECTIVE THIS TREATMENT WOULD BE. SOLIDIFICATION OF THE MATERIALS WOULD BE INEFFECTIVE DUE TO THE PRESENCE OF OILS AND OTHER WASTES THAT WOULD INTERFERE WITH EFFECTIVE SOLIDIFICATION OF THE MATERIALS. OTHER ALTERNATIVES EVALUATED CONTAINMENT OR OFF-SITE DISPOSAL OF CONTAMINATED MATERIALS. IT IS UNLIKELY THESE WOULD PROVIDE ADEQUATE PROTECTION OF HUMAN HEALTH AND THE ENVIRONMENT OVER THE LONG TERM. CAPS DEGRADE AND LANDFILLS ARE SUBJECT TO DEGRADATION-AND/OR LEACHATE PRODUCTION THAT COULD CREATE NEW PROBLEMS. COMPLIANCE WITH ARARS ARARS FOR TREATING OR MANAGING PCB-CONTAMINATED MATERIAL DERIVE PRIMARILY FROM TWO SETS OF REGULATIONS: THE TOXIC SUBSTANCES CONTROL ACT (TSCA) PCB REGULATIONS AND THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) LAND DISPOSAL RESTRICTIONS (LDRS). WHERE PCBS AFFECT GROUND OR SURFACE WATER, THE SAFE DRINKING WATER ACT (SDWA) AND CLEAN WATER ACT (CWA) PROVIDE POTENTIAL ARARS FOR ESTABLISHING REMEDIATION GOALS; I.E., MAXIMUM CONTAMINANT LEVELS (MCLS), MAXIMUM CONTAMINANT LEVEL GOALS (MCLGS), AND WATER QUALITY CRITERIA (WQC). IN ADDITION, THE PCB SPILL POLICY, WHICH IS NOT AN ARAR, ALTHOUGH IT IS PUBLISHED IN THE CODE OF FEDERAL REGULATIONS, HAS BEEN CONSIDERED IN DETERMINING CLEANUP LEVELS AT THE SITE. THE TSCA PCB REGULATIONS OF IMPORTANCE TO SUPERFUND ACTIONS ARE FOUND IN 40 CFR SECTION 761.60 - 761.79, SUBPART D: STORAGE AND DISPOSAL. THEY SPECIFY TREATMENT, STORAGE, AND DISPOSAL REQUIREMENTS FOR PCBS BASED ON THEIR FORM AND CONCENTRATION. TSCA REQUIREMENTS DO NOT APPLY TO PCBS AT CONCENTRATIONS LESS THAN 50 PPM; HOWEVER, PCBS CANNOT BE DILUTED TO ESCAPE TSCA REQUIREMENTS. CONSEQUENTLY, UNDER TSCA, PCBS THAT HAVE BEEN DEPOSITED IN THE ENVIRONMENT AFTER THE EFFECTIVE DATE OF THE REGULATION, FEBRUARY 17, 1978, ARE TREATED, FOR THE PURPOSES OF DETERMINING DISPOSAL REQUIREMENTS, AS IF THEY WERE AT THE CONCENTRATION OF THE ORIGINAL MATERIAL. FOR EXAMPLE, IF PCB TRANSFORMERS LEAKED OIL CONTAINING PCBS AT GREATER THAN 500 PPM, THE SOIL CONTAMINATED BY THE OIL WOULD HAVE TO BE EXCAVATED AND DISPOSED OF AS IF ALL OF THE PCB-CONTAMINATED SOIL CONTAINED PCBS AT GREATER THAN 500 PPM. THIS REFLECTS AN INTERPRETATION OF THE ANTI-DILUTION PROVISIONS IN TSCA (40 CFR 761.1(B)). EPA HAS CLARIFIED THAT TSCA ANTI-DILUTION PROVISIONS ARE ONLY APPLICABLE TO CERCLA RESPONSE ACTIONS THAT OCCUR ONCE A REMEDIAL ACTION IS INITIATED. THE DETERMINATION OF WHETHER CONTAMINATED MATERIAL SHOULD BE CONSIDERED A SOIL OR AN INDUSTRIAL SLUDGE WILL BE MADE SITE SPECIFICALLY DURING REMEDIAL DESIGN CONSISTENT WITH THE CURRENT PROCESS FOR CLASSIFYING MATERIAL SUBJECT TO THE LAND DISPOSAL RESTRICTIONS AS EITHER A PURE WASTE OR A SOIL AND DEBRIS CONTAMINATED WITH A WASTE. 1 Order number 940620-103843-ROD -001-001 page 4318 set 4 with 100 of 100 items THE REQUIREMENTS FOR STORAGE OF PCBS ARE DESCRIBED IN 40 CFR SECTION 761.65. THE REGULATIONS SPECIFY THAT PCBS AT CONCENTRATIONS OF 50 PPM OR GREATER MUST BE DISPOSED OF WITHIN ONE YEAR AFTER BEING PLACED IN STORAGE. THE REGULATIONS ALSO INCLUDE STRUCTURAL REQUIREMENTS FOR FACILITIES USED FOR THE STORAGE OF PCBS AND REQUIREMENTS FOR CONTAINERS USED TO STORE PCBS. PCBS ARE SPECIFICALLY ADDRESSED UNDER RCRA IN 40 CFR 268 WHICH DESCRIBES THE PROHIBITIONS ON LAND DISPOSAL OF VARIOUS HAZARDOUS WASTES. NOTE THAT RCRA REGULATIONS ONLY APPLY TO WASTE THAT IS CONSIDERED HAZARDOUS UNDER RCRA; I.E., LISTED IN 40 CFR 261.3 OR CHARACTERISTIC AS DESCRIBED IN 40 CFR 261.2. PCBS ALONE ARE NOT A RCRA HAZARDOUS WASTE; HOWEVER, IF THE PCBS ARE MIXED WITH A RCRA HAZARDOUS WASTE, THEY MAY BE SUBJECT TO LAND DISPOSAL RESTRICTIONS. PCBS ARE ONE OF THE CONSTITUENTS ADDRESSED BY THE LAND DISPOSAL RESTRICTIONS UNDER THE CALIFORNIA LIST WASTES. THIS SUBSECTION OF WASTES COVERS LIQUID HAZARDOUS WASTES CONTAINING PCBS AT CONCENTRATIONS GREATER THAN OR EQUAL TO 50 PPM AND NON-LIQUID HAZARDOUS WASTES CONTAINING TOTAL CONCENTRATIONS OF HALOGENATED ORGANIC COMPOUNDS (HOCS) AT CONCENTRATIONS GREATER THAN 1000 PPM. PCBS ARE INCLUDED IN THE LIST OF HOCS PROVIDED IN THE REGULATION (APPENDIX III PART 268). AS DESCRIBED IN 40 CFR 268.42(A)(1), LIQUID HAZARDOUS (RCRA LISTED OR CHARACTERISTIC) WASTES CONTAINING PCBS AT CONCENTRATIONS GREATER THAN OR EQUAL TO 500 PPM MUST BE INCINERATED IN A FACILITY MEETING THE REQUIREMENTS OF 40 CFR 761.70. LIQUID HAZARDOUS WASTES CONTAINING PCBS AT CONCENTRATIONS GREATER THAN OR EQUAL TO 50 PPM, BUT LESS THAN 500 PPM MUST BE INCINERATED OR BURNED IN A HIGH EFFICIENCY BOILER MEETING THE REQUIREMENTS OF 40 CFR 761.60. A METHOD OF TREATMENT EQUIVALENT TO THE REQUIRED TREATMENT MAY ALSO BE USED UNDER A TREATABILITY VARIANCE PROCEDURE IF THE ALTERNATE TREATMENT CAN ACHIEVE A LEVEL OF PERFORMANCE EQUIVALENT TO THAT ACHIEVED BY THE SPECIFIED METHOD AS DESCRIBED IN 40 CFR 268.42(B). LIQUID AND NON-LIQUID HAZARDOUS WASTES CONTAINING HOCS IN TOTAL CONCENTRATION GREATER THAN OR EQUAL TO 1000 PPM MUST BE INCINERATED IN ACCORDANCE WITH THE REQUIREMENT OF 40 CFR 264 SUBPART O. AGAIN, A METHOD OF TREATMENT EQUIVALENT TO THE REQUIRED TREATMENT, UNDER A TREATABILITY VARIANCE, MAY ALSO BE USED. ALL EXTRACTED AND TREATED WATER WOULD HAVE TO MEET NPDES REQUIREMENTS PRIOR TO SURFACE WATER DISCHARGE. A DETERMINATION OF THE LOCATION OF THE DISCHARGES, WHICH IS EXPECTED TO BE MADE DURING DESIGN, IS NECESSARY BEFORE AN IDENTIFICATION OF WHETHER THE DISCHARGES ARE OFF-SITE VS ON-SITE AS DEFINED IN THE NCP (40 CFR PART 300.400(E)). GROUNDWATER CLEAN-UP GOALS ARE ESTABLISHED AS MCLS, PROPOSED MCLS (PMCLS) AND CANCER POTENCY FACTORS (CPFS) AND ARE PRESENTED IN TABLE 6-6 1 Order number 940620-103843-ROD -001-001 page 4319 set 4 with 100 of 100 items FOR THE COMPOUNDS IDENTIFIED IN GROUNDWATER. AS DISCUSSED IN SECTION 9.1, A WAIVER MAY EVENTUALLY BE NECESSARY FOR THE GROUNDWATER AS IT IS UNLIKELY MCLS WILL BE MET. THIS IS DUE TO THE PRESENCE OF DENSE NON-AQUEOUS PHASE LIQUIDS IN THE FRACTURE SYSTEM PRESENT AT THE VARIOUS SITES. ALL SOURCE TREATMENT ALTERNATIVES ARE EXPECTED TO MEET ARARS. WHERE EXCAVATION IS REQUIRED, THE REQUIREMENTS OF THE CLEAN AIR ACT UNDER 40 CFR PART 50 CONCERNING PARTICULATES AND VOLATILE ORGANIC EMISSIONS WILL BE REQUIRED TO BE MET. LONG-TERM EFFECTIVENESS AND PERMANENCE GROUND WATER TREATMENT AND DISCHARGE EXTRACTION OF CONTAMINATED GROUNDWATER WILL BE EFFECTIVE IN CONTAINING THE PLUME OVER THE LONG-TERM. IT IS UNLIKELY THAT THE SOURCE OF THE PLUME CAN BE REMOVED IN THIS MANNER. THEREFORE, THE EXTRACTION IS NOT A PERMANENT REMEDY, ALTHOUGH IT DOES ACCOMPLISH THE GOAL OF PREVENTING FURTHER CONTAMINATION OF THE AQUIFER. SOURCE TREATMENT THERMAL SEPARATION AND INCINERATION PROVIDE FOR REMOVAL AND DESTRUCTION OF THE CONTAMINANTS FROM THE WASTE AND SOIL. THESE ARE PERMANENT TREATMENT ALTERNATIVES. OFF-SITE DISPOSAL OF WASTES PROVIDES LONG-TERM EFFECTIVENESS IN ISOLATING WASTES, BUT CONTAINMENT STRUCTURES MAY BE SUBJECT TO FAILURE, SO THAT THIS ALTERNATIVE IS LESS PERMANENT THAN A THERMAL TREATMENT PROCESS. THE POSSIBLE FAILURE OF CONTAINMENT STRUCTURES IS APPLICABLE TO ON-SITE CONTAINMENT FACILITIES AS WELL. IT IS UNKNOWN AS TO THE LONG-TERM EFFECTIVENESS AND PERMANENCE OF BIOREMEDIATION. TO DATE, NO STUDIES ACHIEVING CLEAN-UP CRITERIA HAVE BEEN REPORTED. REDUCTION OF MOBILITY, TOXICITY, OR VOLUME GROUNDWATER TREATMENT EXTRACTION OF CONTAMINATED GROUNDWATER WILL REDUCE THE VOLUME OF CONTAMINANTS IN THE AQUIFER AS WELL AS REDUCE THE MOBILITY OF THOSE CONTAMINANTS REMOVED THROUGH TREATMENT OF THE EXTRACTED WATER. THE NO ACTION ALTERNATIVE OR USE OF INSTITUTIONAL CONTROLS WILL HAVE NO IMPACT ON THE MOBILITY, TOXICITY, OR VOLUME OF CONTAMINATION PRESENT AT THE SITE. SOURCE TREATMENT THERMAL SEPARATION REMOVES THE CONTAMINANTS SO THEY CAN BE DESTROYED IN A MORE CONDENSED, MANAGEABLE STATE. THEREFORE, THERMAL SEPARATION REDUCES THE MOBILITY, TOXICITY AND VOLUME OF THE CONTAMINANTS PRESENT IN THE SOLIDS AT THE SITE. INCINERATION DESTROYS THE CONTAMINANTS, THEREBY 1 Order number 940620-103843-ROD -001-001 page 4320 set 4 with 100 of 100 items ELIMINATING TOXICITY AND MOBILITY, AND REDUCING VOLUME. CONTAINMENT OF WASTES REDUCES THE MOBILITY OF THE CONTAMINANTS, HOWEVER, CONTAINMENT STRUCTURES MAY BE SUBJECT TO FAILURE. GLYCOLATE DECHLORINATION WOULD REDUCE THE TOXICITY OF CONTAMINANTS. SOLIDIFICATION WOULD REDUCE THE MOBILITY OF THE CONTAMINANTS. BIOREMEDIATION MAY REDUCE THE TOXICITY OF CONTAMINANTS OVER THE LONG-TERM. OFF-SITE DISPOSAL OF WASTES DOES NOT AFFECT THE INHERENT TOXICITY, MOBILITY, OR VOLUME OF THE WASTE. SHORT-TERM EFFECTIVENESS GROUND WATER TREATMENT AIR STRIPPING MAY HAVE THE FOLLOWING SHORT-TERM EFFECTS: RISKS TO WORKERS FROM EXPOSURE TO DRILLING FLUIDS AND SOIL DURING THE INSTALLATION OF THE GROUND WATER EXTRACTION WELLS. RISKS TO WORKERS AND ENVIRONMENT FROM RELEASE OF CONTAMINATED WATER BECAUSE OF ACCIDENTAL SPILLAGE. RISKS TO WORKERS, ENVIRONMENT AND NEARBY MEMBERS OF THE PUBLIC FROM UNCONTROLLED EMISSIONS. THE REMEDIAL DESIGN WILL INCLUDE ALL NECESSARY MEASURES TO MINIMIZE POTENTIAL ADVERSE SHORT-TERM EFFECTS ON PUBLIC HEALTH OR THE ENVIRONMENT. INSTITUTIONAL CONTROLS WOULD BE EFFECTIVE IN THE SHORT TERM. THEY WOULD PREVENT THE PUBLIC FROM COMING INTO CONTACT WITH CONTAMINATION OR CONTAMINATED MATERIAL IN THE SHORT TERM. SOURCE TREATMENT ALL ALTERNATIVES REQUIRING EXCAVATION OF CONTAMINATED MATERIALS HAVE SHORT-TERM IMPACTS ON THE ENVIRONMENT DUE TO THE RELEASE OF VOLATILE CONTAMINANTS INTO THE AIR. OFF-SITE DISPOSAL OF CONTAMINATED SOILS OR OFF-SITE INCINERATION OF THESE WASTES INVOLVE TRANSPORTATION OF THE WASTE, INCREASING SHORT-TERM RISK TO POPULATIONS ALONG THE TRANSPORT ROUTE. CONSOLIDATION OF MATERIALS ON THE PLANT SITE ALSO INVOLVES A SHORT-TERM RISK TO POPULATIONS ALONG THE TRANSPORT ROUTE TO THE PLANT SITE. THESE RISKS CAN BE MINIMIZED BY UTILIZING AN EXPERIENCED CONTRACTOR FOR THESE TASKS. IMPLEMENTABILITY GROUND WATER TREATMENT AIR STRIPPING AND CARBON ADSORPTION ARE BOTH PROVEN TECHNOLOGIES. TREATMENT SYSTEMS AND VENDORS ARE READILY AVAILABLE AND NO IMPEDIMENT TO 1 Order number 940620-103843-ROD -001-001 page 4321 set 4 with 100 of 100 items IMPLEMENTATION OF THE ALTERNATIVE IS FORESEEN. SOURCE TREATMENT THERMAL SEPARATION AND ON-SITE INCINERATION ARE FULLY IMPLEMENTABLE. OFF-SITE DISPOSAL OF THE CONTAMINATED SOIL IS IMPLEMENTABLE, AS IS SOLIDIFICATION. EXCAVATION AND OFF-SITE INCINERATION MAY BE DIFFICULT DUE TO AVAILABILITY OF INCINERATOR CAPACITY IN SOUTH CAROLINA. GLYCOLATE DECHLORINATION IS A RELATIVELY NEW TECHNOLOGY AND WOULD, THEREFORE, BE DIFFICULT TO IMPLEMENT AT THE SITE. CONSTRUCTION OF A TSCA LANDFILL WOULD NOT BE POSSIBLE DUE TO SOUTH CAROLINA DEPARTMENT OF HEALTH AND ENVIRONMENTAL CONTROL RESTRICTIONS ON PERMITTING SUCH FACILITIES. COST-EFFECTIVENESS ESTIMATED COSTS FOR EACH ALTERNATIVE ARE AS FOLLOWS: ALTERNATIVE MILLIONS OF DOLLARS NO ACTION ALTERNATIVE 1 $ 5.1 ALTERNATIVES INVOLVING LITTLE OR NO TREATMENT ALTERNATIVE ALTERNATIVE ALTERNATIVE ALTERNATIVE ALTERNATIVE 2 3 4 5 6 $ 5.3 $ 7.9 - 8.6 $10.3 - 11.0 $12.7 $57.0 ALTERNATIVES THAT MINIMIZE THE NEED FOR LONG-TERM MANAGEMENT ALTERNATIVE 8 ALTERNATIVE 10 $14.4 - 57 $27.1 ALTERNATIVE THAT INCLUDES TREATMENT AND REQUIRES LONG-TERM MANAGEMENT ALTERNATIVE 13 $11.2 - 15.1 ALTERNATIVES THAT MINIMIZE THE NEED FOR LONG-TERM TREATMENT ALTERNATIVE 7 $29.4 ALTERNATIVE 11 $34.5 - 78.4 ALTERNATIVE 12 $62.4 - 99.2 ALTERNATIVES THAT REQUIRES LONG-TERM MANAGEMENT ALTERNATIVE 9 $39.6 - 50.6 1 Order number 940620-103843-ROD -001-001 page 4322 set 4 with 100 of 100 items STATE ACCEPTANCE THE STATE OF SOUTH CAROLINA HAS CONCURRED WITH THE SELECTED REMEDY. COMMUNITY ACCEPTANCE TWO PUBLIC MEETINGS WERE HELD DURING THE PUBLIC COMMENT PERIOD AT THE SITE. CITIZENS VOICED SOME CONCERNS OVER THE SELECTED REMEDY BUT APPEARED TO BE SATISFIED BY THE AGENCY'S RESPONSES. WRITTEN COMMENTS RECEIVED DURING THE PUBLIC COMMENT PERIOD WERE IN THE FORM OF REQUESTS FOR MORE INFORMATION. ONE COMMENT RECOMMENDED EPA CONSTRUCT A TSCA LANDFILL AT A "SAFE" SITE IN THE COUNTY. THE COMMENTS WERE ADDRESSED IN THE RESPONSIVENESS SUMMARY. #SR 9.0 THE SELECTED REMEDY THE REMEDY SELECTED FOR OPERABLE UNIT ONE OF THE SANGAMO WESTON/TWELVE MILE CREEK/LAKE HARTWELL PCB CONTAMINATION SITE IS: EXTRACTION AND TREATMENT BY AIR STRIPPING AND/OR CARBON ADSORPTION OF CONTAMINATED GROUNDWATER AT THE DODGENS, BREAZEALE, CROSS ROADS AND PLANT SITES; DISCHARGE OF TREATED WATER TO THE NEAREST VIABLE SURFACE WATER BODY IN ACCORDANCE WITH APPLICABLE REGULATIONS; EXCAVATION OF MATERIALS CONTAMINATED WITH GREATER THAN 1 PPM OF PCBS AT THE NIX AND WELBORN PROPERTIES AND TRANSPORT OF THE MATERIALS TO THE SANGAMO PLANT SITE FOR STAGING AND APPROPRIATE TREATMENT EXCAVATION OF MATERIALS CONTAMINATED WITH GREATER THAN 10 PPM PCBS ON THE REMAINING FOUR PRIVATE PROPERTIES (TROTTER, DODGENS, BREAZEALE AND CROSS ROADS) AND TRANSPORT TO THE SANGAMO PLANT SITE FOR STAGING AND APPROPRIATE TREATMENT; BACKFILL TWO FEET OF CLEAN FILL AT EACH OF THE PRIVATE PROPERTIES WHERE CONTAMINATED MATERIALS OF GREATER THAN 1 PPM REMAIN (TROTTER, DODGENS, BREAZEALE AND CROSS ROADS); EXCAVATE MATERIAL CONTAINING GREATER THAN 25 PPM CONCENTRATION OF PCBS ON THE PLANT SITE; TREAT ALL EXCAVATED MATERIALS TO 2 PPM PCBS USING THERMAL SEPARATION TECHNOLOGY ON THE PLANT SITE. DURING REMEDIAL DESIGN, A TREATABILITY STUDY WILL BE CONDUCTED TO DETERMINE IF ANY OF THE CONTAMINATED MATERIALS WILL REQUIRE ADDITIONAL TREATMENT BEYOND THERMAL SEPARATION IN ORDER TO MEET THE 2 PPM CRITERIA. IF NECESSARY, A ROD AMENDMENT WILL BE 1 Order number 940620-103843-ROD -001-001 page 4323 set 4 with 100 of 100 items COMPLETED TO ACCOUNT FOR THIS REQUIRED TREATMENT; AND REPLACE REMEDIATED SOIL ON THE PLANT SITE THIS REMEDY WILL ATTAIN A (10-6) CANCER RISK LEVEL AS IT REMOVES THE SOURCE OF THE DIRECT CONTACT THREAT AND CONTAINS THE CONTAMINATED GROUNDWATER TO PREVENT FUTURE CONTACT. 9.1 DESCRIPTION OF RECOMMENDED ALTERNATIVE GROUNDWATER TREATMENT THE ULTIMATE GOAL OF THIS REMEDIAL ACTION IS TO RESTORE THE GROUNDWATER TO ITS BENEFICIAL USE, WHICH AT THIS SITE IS A DRINKING WATER AQUIFER (SEE TABLE 6.6 FOR GROUNDWATER CLEAN UP CRITERIA). BASED ON THE INFORMATION OBTAINED DURING THE REMEDIAL INVESTIGATION, AND THE ANALYSIS OF ALL REMEDIAL ALTERNATIVES, EPA BELIEVES THAT IT MAY BE POSSIBLE TO ACHIEVE THIS GOAL FOR SELECT AREAS USING THE PLANNED REMEDIAL MEASURES. THE ABILITY TO ACHIEVE CLEAN UP GOALS AT ALL POINTS THROUGHOUT THE AREA OF CONTAMINATION CANNOT BE DETERMINED UNTIL THE EXTRACTION SYSTEM HAS BEEN IMPLEMENTED, MODIFIED AS NECESSARY AND PLUME RESPONSE MONITORED OVER TIME. IF THE SELECTED GROUNDWATER PUMP AND TREAT REMEDY CANNOT MEET THESE HEALTH BASED RESTORATION GOALS, AT ANY OR ALL OF THE MONITORING POINTS DURING IMPLEMENTATION, THE CONTINGENCY MEASURES AND GOALS MAY REPLACE THE SELECTED MEASURES AND GOALS FOR THESE PORTIONS OF THE PLUME. SUCH CONTINGENCY MEASURES WILL, AT A MINIMUM, CONTAIN THE PLUME TO WITHIN THE ZONE CURRENTLY EXCEEDING HEALTH-BASED LEVELS. THESE CONTAINMENT MEASURES ARE STILL CONSIDERED TO BE PROTECTIVE OF HUMAN HEALTH AND THE ENVIRONMENT, AND ARE TECHNICALLY PRACTICABLE UNDER THE CIRCUMSTANCES. THE SELECTED REMEDY WILL INCLUDE GROUND WATER EXTRACTION FOR AN UNKNOWN PERIOD, DURING WHICH TIME THE SYSTEM'S PERFORMANCE WILL BE CAREFULLY MONITORED ON A REGULAR BASIS AND ADJUSTED AS WARRANTED BY THE PERFORMANCE DATA COLLECTED DURING OPERATION. MODIFICATIONS MAY INCLUDE ANY OR ALL OF THE FOLLOWING: A) AT INDIVIDUAL WELLS WHERE CLEANUP GOALS HAVE BEEN ATTAINED, PUMPING MAY BE DISCONTINUED; B) ALTERNATING PUMPING AT WELLS TO ELIMINATE STAGNATION POINTS; C) PULSE PUMPING TO ALLOW AQUIFER EQUILIBRATION AND ENCOURAGE ADSORBED CONTAMINANTS TO PARTITION INTO GROUND WATER; AND D) INSTALLATION OF ADDITIONAL EXTRACTION WELLS TO FACILITATE OR ACCELERATE CLEANUP OF THE CONTAMINANT PLUME. TO ENSURE THAT CLEANUP GOALS CONTINUE TO BE MAINTAINED, THE AQUIFER WILL BE MONITORED AT THOSE WELLS WHERE PUMPING HAS CEASED ON AN OCCURRENCE OF 1 Order number 940620-103843-ROD -001-001 page 4324 set 4 with 100 of 100 items EVERY ONE YEAR FOR A PERIOD OF FIVE YEARS FOLLOWING DISCONTINUATION OF GROUND WATER EXTRACTION. IF, IN EPA'S JUDGEMENT, IMPLEMENTATION OF THE SELECTED REMEDY CLEARLY DEMONSTRATES, IN CORROBORATION WITH STRONG HYDROGEOLOGICAL AND CHEMICAL EVIDENCE, THAT IT WILL BE TECHNICALLY IMPRACTICABLE TO ACHIEVE AND MAINTAIN REMEDIATION GOALS THROUGHOUT THE AREA OF ATTAINMENT, THE CONTINGENCY WILL BE IMPLEMENTED. WHERE SUCH A CONTINGENCY SITUATION ARISES, GROUND WATER EXTRACTION AND TREATMENT WOULD TYPICALLY CONTINUE AS NECESSARY TO ACHIEVE MASS REDUCTION AND REMEDIATION GOALS THROUGHOUT THE REST OF THE AREA OF ATTAINMENT. SANGAMO PLANT SITE GROUNDWATER AT THE SANGAMO PLANT SITE OCCURS PRIMARILY WITHIN THE JOINT AND FRACTURE SYSTEM OF THE BEDROCK. GROUNDWATER DISCHARGE FROM WELLS SURROUNDING THE RIDGE WOULD CONTAIN PRIMARILY VOCS. THIS WATER WOULD BE TREATED BY AIR STRIPPING. GROUNDWATER DOWNGRADIENT OF AREAS A, B, E, AND THE WASTE WATER TREATMENT FACILITY WOULD BE TREATED BY CARBON ADSORPTION. IN THIS AREA, RI DATA SHOWED PCBS IN GROUNDWATER COLLECTED FROM 10 OF 17 WELLS. VOCS HAVE BEEN DETECTED IN A MAJORITY OF THESE WELLS. TREATED WATER WOULD BE DISCHARGED INTO TOWN CREEK. BREAZEALE SITE THE ASSUMED PUMPING SCHEME FOR THE BREAZEALE SITE CONSISTS OF GROUNDWATER EXTRACTION WELLS SCREENED IN THE SATURATED PORTIONS OF THE SAPROLITE AND FLOODPLAIN DEPOSITS. EXTRACTED GROUNDWATER WOULD CONTAIN VOCS AND WOULD BE TREATED THROUGH AIR STRIPPING AND/OR CARBON ADSORPTION (IF NECESSARY). TREATED WATER WOULD BE DISCHARGED INTO WOLF CREEK. DODGENS SITE THE ASSUMED PUMPING SCHEME FOR THE DODGENS SITE CONSISTS OF GROUNDWATER EXTRACTION WELLS SCREENED IN THE SATURATED PORTIONS OF THE SAPROLITE. EXTRACTED GROUNDWATER IS EXPECTED TO CONTAIN VOCS AND AT LEAST ONE SEMI-VOLATILE ORGANIC COMPOUND. COLLECTED GROUNDWATER WOULD BE TREATED THROUGH AIR STRIPPING AND/OR CARBON ADSORPTION (IF NECESSARY). TREATED WATER WOULD BE DISCHARGED TO MIDDLE FORK TWELVEMILE CREEK. CROSS ROADS SITE THE ASSUMED PUMPING SCHEME FOR THE CROSS ROADS SITE CONSISTS OF GROUNDWATER EXTRACTION WELLS SCREENED IN THE SATURATED PORTIONS OF THE SAPROLITE. 1 Order number 940620-103843-ROD -001-001 page 4325 set 4 with 100 of 100 items EXTRACTED GROUNDWATER IS EXPECTED TO HAZARDOUS SUBSTANCE LIST COMPOUNDS. TREATED THROUGH AIR STRIPPING AND/OR TREATED WATER WOULD BE DISCHARGED TO CREEK. CONTAIN VOCS AND POSSIBLY OTHER COLLECTED GROUNDWATER WOULD BE CARBON ADSORPTION (IF NECESSARY). AN UNNAMED TRIBUTARY OF TWELVEMILE SOURCE EXCAVATION AND TRANSPORTATION THE FIRST STEP IN THIS ALTERNATIVE WOULD INCLUDE EXCAVATION OF SOLID MATERIALS AFFECTED WITH GREATER THAN 1 PPM PCBS ON THE NIX AND WELBORN PRIVATE PROPERTIES, GREATER THAN 10 PPM PCBS ON THE TROTTER, DODGENS, BREAZEALE AND CROSS ROADS PROPERTIES AND 25 PPM PCBS AT THE PLANT SITE. FOLLOWING EXCAVATION, THE MATERIALS WOULD BE TEMPORARILY STOCKPILED ON THE PLANT SITE. THE MATERIAL TO BE REMEDIATED CONSISTS OF APPROXIMATELY 2,900 CUBIC YARDS OF SOLID WASTE AND APPROXIMATELY 48,200 CUBIC YARDS OF CONTAMINATED SOIL AND SEDIMENT. THE LAGOON SEDIMENTS WOULD BE DREDGED AND DEWATERED PRIOR TO TRANSPORT TO THE TREATMENT AREA. LIQUIDS PRODUCED DURING DEWATERING WOULD BE TEMPORARILY STORED IN TANKS AND THEN TRANSPORTED FOR TREATMENT IN THE LEACHATE TREATMENT UNIT AT THE ON-SITE TSCA LANDFILL. THE AVERAGE HAUL DISTANCE FROM ON-SITE.EXCAVATION AREAS WOULD BE LESS THAN APPROXIMATELY ONE-HALF MILE. THE AVERAGE HAUL DISTANCE FROM REMOTE SITE EXCAVATION AREAS WOULD BE APPROXIMATELY 2.5 MILES. SOLIDS TREATED TO TWO PPM OR LESS IN THE THERMAL DESORPTION UNIT WOULD BE DISPOSED OF ON-SITE. LIMITED FIELD TRIALS MAY BE REQUIRED TO CONFIRM TREATMENT EFFECTIVENESS AND TO CHARACTERIZE TREATMENT RESIDUALS. EACH OF THE TREATMENT PROCESS OPTIONS WOULD REQUIRE PRE-PROCESSING OF THE SOLIDS TO REMOVE OVERSIZED ITEMS AND TO REDUCE THE PARTICLE SIZE. THE ASSUMPTION OF A ONE PERCENT REJECTION RATE IS USED BECAUSE MUCH OF THE AFFECTED AREAS ARE NOT COVERED WITH THICK STANDS OF TREES. THESE MATERIALS WOULD REQUIRE OFF-SITE DISPOSAL AS A TSCA REGULATED WASTE IN A PERMITTED LANDFILL. EXCAVATED AREAS WILL BE BACKFILLED WITH NATIVE SOIL, GRADED, AND RESTORED TO SUPPORT VEGETATION. ANY POTENTIAL LONG-TERM MIGRATION AT GROUND SURFACE BY THE LOW CONCENTRATIONS OF WASTE CONSTITUENTS THAT REMAIN IN PLACE WOULD BE LIMITED BY PLACEMENT OF CLEAN BACKFILL. SOURCE TREATMENT THERMAL DESORPTION (OR THERMAL SEPARATION) IS A PROCESS OPTION RETAINED FROM THE SCREENING OF THERMAL TREATMENT TECHNOLOGIES. A PROPRIETARY SYSTEM REPRESENTED THE TECHNOLOGY IN THE FEASIBILITY STUDY REPORT ANALYSIS. THIS RECORD OF DECISION IDENTIFIES THERMAL DESORPTION OR SEPARATION AS THE PREFERRED TREATMENT ALTERNATIVE. EXACT DETAILS OF THE PROCESS, INCLUDING TREATABILITY STUDIES WILL BE DEVELOPED AS PART OF THE REMEDIAL DESIGN. 1 Order number 940620-103843-ROD -001-001 page 4326 set 4 with 100 of 100 items THE PROCESS ENVISIONED IS A MOBILE PROCESS IN WHICH SOILS OR SLUDGES WITH ORGANIC COMPOUNDS ARE HEATED IN A ROTARY KILN. VOLATILIZED ORGANICS ARE TRANSFERRED, USING NITROGEN AS THE CARRIER GAS, AND COOLED TO CONDENSE ORGANIC COMPONENTS. THE CONDENSED COMPONENTS ARE THEN COLLECTED FOR FURTHER TREATMENT AT AN APPROPRIATE FACILITY. THIS SYSTEM WOULD CONSIST OF THE FOLLOWING TYPICAL UNIT OPERATIONS: * MATERIAL PREPROCESSING/SORTING * ROTARY KILN THERMAL SEPARATION * CARBON ADSORPTION UNIT (OR COMBUSTION AFTERBURNER) * COOLING AND CONDENSATE TRAIN * OFF-GAS HANDLING TRAILER * RESIDUALS MANAGEMENT UNIT ON THE BASIS OF PILOT STUDIES, A TREATMENT CAPACITY OF FIVE TONS PER HOUR CAN BE EXPECTED. ASSUMING A TYPICAL DENSITY OF APPROXIMATELY 1.3 TONS PER CUBIC YARD OF MATERIAL, THE ESTIMATED TIME EXPECTED TO COMPLETE TREATMENT WOULD BE IN EXCESS OF TWO YEARS. THIS ESTIMATE IS BASED ON THE USE OF ONE TREATMENT SYSTEM AND A MINIMUM OF 30 PERCENT DOWNTIME. 9.2 COST THE COSTS FOR THIS ALTERNATIVE, ARE INCLUDED IN APPENDIX D OF THE FEASIBILITY STUDY REPORT. THE ESTIMATED PRESENT-WORTH COST IS GIVEN BELOW: OPTION 11B: THERMAL SEPARATION - $47,900,000 - 63,300,000 THE COSTS IN THIS ALTERNATIVE HAVE A POTENTIAL TO VARY FROM THE ESTIMATED COSTS DUE TO SEVERAL FACTORS: * UNKNOWN HYDRAULIC CHARACTERISTICS OF THE AQUIFER. IN-FIELD TESTS PRIOR TO AND DURING THE REMEDIAL DESIGN ARE REQUIRED TO FULLY CHARACTERIZE THE SITE HYDROLOGIC PROPERTIES. * UNPREDICTABLE FLOW AND CONSTITUENT REMOVAL RATES. * VOLUME OF EXCAVATED SOLIDS MAY EXCEED THE LANDFILL DESIGN VOLUME. STATUTORY DETERMINATIONS 1 Order number 940620-103843-ROD -001-001 page 4327 set 4 with 100 of 100 items THE SELECTED REMEDY SATISFIES THE REQUIREMENTS OF SECTION 121 OF CERCLA. PROTECTION OF HUMAN HEALTH AND THE ENVIRONMENT: THE SELECTED REMEDY WILL PERMANENTLY TREAT THE GROUNDWATER AND SOIL AND REMOVES OR MINIMIZES THE POTENTIAL RISKS ASSOCIATED WITH THE WASTES. DERMAL, INGESTION, AND INHALATION CONTACT WITH SITE CONTAMINANTS WOULD BE ELIMINATED, AND RISKS POSED BY CONTINUED GROUNDWATER CONTAMINATION WOULD BE REDUCED. ATTAINMENT OF ARARS: THIS ALTERNATIVE WILL COMPLY WITH ARARS. A COMPLETE DISCUSSION OF THE ARARS WHICH ARE REQUIRED TO BE ATTAINED IS INCLUDED IN CHAPTER 8. CHAPTER 8 ALSO DESCRIBES THOSE REQUIREMENTS CONSIDERED AS TBCS (TO BE CONSIDERED). (TABLE 6.6). GROUNDWATER CLEAN-UP CRITERIA ARE ADDRESSED IN CHAPTER 6 COST-EFFECTIVENESS: THE GROUNDWATER AND SOURCE REMEDIATION TECHNOLOGIES ARE MORE COST-EFFECTIVE THAN THE OTHER ALTERNATIVES CONSIDERED PRIMARILY BECAUSE THEY PROVIDE GREATER BENEFIT FOR THE COST. UTILIZATION OF PERMANENT SOLUTIONS AND ALTERNATIVE TREATMENT TECHNOLOGIES OR RESOURCE RECOVERY TECHNOLOGIES TO THE MAXIMUM EXTENT PRACTICABLE THE SELECTED REMEDY REPRESENTS THE MAXIMUM EXTENT TO WHICH PERMANENT SOLUTIONS AND TREATMENT CAN BE PRACTICABLY UTILIZED FOR THIS ACTION. OF THE ALTERNATIVES THAT ARE PROTECTIVE OF HUMAN HEALTH AND THE ENVIRONMENT AND COMPLY WITH ARARS, EPA AND THE STATE HAVE DETERMINED THAT THE SELECTED REMEDY PROVIDES THE BEST BALANCE OF TRADE-OFFS IN TERMS OF LONG-TERM EFFECTIVENESS AND PERMANENCE, REDUCTION IN TOXICITY, MOBILITY OR VOLUME ACHIEVED THROUGH TREATMENT, SHORT-TERM EFFECTIVENESS, IMPLEMENTABILITY, COST AND ALSO CONSIDERING THE STATUTORY PREFERENCE FOR TREATMENT AS A PRINCIPAL ELEMENT AND ALSO CONSIDERING STATE AND COMMUNITY ACCEPTANCE. PREFERENCE FOR TREATMENT AS A PRINCIPAL ELEMENT THE PREFERENCE FOR TREATMENT IS SATISFIED BY THE USE OF THE LOW TEMPERATURE THERMAL TREATMENT SYSTEM TO REMOVE CONTAMINATION FROM SOIL, SEDIMENTS AND WASTE AT THE SITE AND THE USE OF AIR STRIPPING/CARBON ADSORPTION TO TREAT CONTAMINATED GROUND WATER AT THE SITE. THE PRINCIPAL THREATS AT THE SITE WILL BE MITIGATED BY USE OF THESE TREATMENT TECHNOLOGIES. #TA 1 Order number 940620-103843-ROD -001-001 page 4328 set 4 with 100 of 100 items TABLE 5-9 PCB(1) CONCENTRATIONS DETECTED IN SURFACE SOILS: NIX SITE SAMPLE NO. NXSS-1 NXSS-2 NXSS-3 NXSS-4 NXSS-5 NXSS-6 NXSS-7 NXSS-8 PCB CONCENTRATION AROCLOR 1248 AROCLOR 1254 0.32 ND ND 1.1 ND 0.75 24. 0.538 0.36 0.13 ND 2.5 ND 0.41 16. 0.65 TOTAL 0.68 0.13 ND 3.6 ND 1.16 40. 1.168 NXSS-9 NXSS-10 NXSS-11 NXSS-12 NXSS-13 NXSS-14 NXSS-15 NXSS-16 NXSS-16 DUPLICATE NXSS-17 NXSS-18 NXSS-19 NXSS-20 NXSS-21 NXSS-22 ND (1) 4.1 ND 0.75 ND 19. 13. ND 7.8 8.1 ND ND ND ND ND ND 5.5 ND 2.8 0.26 47. 15. 6.6 15. 15. 0.51 ND ND ND 0.24 13. 9.6 ND 3.55 0.26 66. 28. 6.6 22.8 23. 0.51 ND ND ND 0.24 13. NONE DETECTED. CONCENTRATIONS ARE IN PARTS PER MILLION (DRY WEIGHT). LISTED ARE THE ONLY AROCLORS DETECTED. AROCLORS TABLE 5-10 PCB CONCENTRATIONS DETECTED IN SUBSURFACE SOILS: NIX SITE SAMPLE IDENTIFICATION (BORING NO. & SAMPLE INTERVAL) NXSB-1 (3.5-5.0) NXSB-2 (3.5-5.0) NXSB-3 (4.0-6.0) NXSB-3A (4.0-6.0) NXSB-3B (2.5-4.0) NXSB-3B (5.0-6.5) PCB CONCENTRATION(1) AROCLOR 1248 AROCLOR 1254 TOTAL PCBS ND ND ND ND ND ND ND ND 0.06 ND ND ND ND ND 0.06 ND ND ND 0.4 NA ND ND ND 0.4 NA ND ND ND 1 Order number 940620-103843-ROD -001-001 page 4329 set 4 with 100 of 100 items NXSB-4 (2.0-4.0) NXSB-4 (4.0-4.8) NXSB-4, 4A, 4B NXSB-5 (3.5-5.0) NXSB-5 (3.5-5.0) DUPLICATE ND NA ND ND ND ND - NONE DETECTED ND - NOT ANALYZED (1) CONCENTRATIONS ARE IN PARTS PER MILLION (DRY WEIGHT). AROCLORS LISTED ARE THE ONLY AROCLORS DETECTED. SANGAMO WESTON, INC./TWELVE-MILE CREEK/LAKE HARTWELL PCB CONTAMINATION Site Information: Address: SANGAMO WESTON, INC./TWELVE-MILE CREEK/LAKE HARTWELL PCB CONTAMINATION PICKENS, SC EPA ID: EPA Region: SCD003354412 04 Site Name: Site Alias Name(s): SANGAMO/TWELVE-MILE/HARTWELL PCB SANGAMO WESTON-PICKENS PLANT HAYWOOD RESERVOIR MIDWAY LANDFILL CROSS ROADS CHURCH BREZEAL PROPERTY WELLBORN PROPERTY MAW BRIDGE ROAD NIX, ERNEST PROPERTY SANGAMO ELECTRIC SANGAMO PROPERTY SANGAMO WESTON/TWELVE-MILE/HARTWELL PCB Record of Decision (ROD) - Explanation of Significant Differences (ESD): ROD Date: Operable Unit: ROD ID: 09/10/1991 01 EPA/ESD/R04-91/501 Text: Full-text ROD document follows on next page. EPA/ESD/R04-91/501 1991 EPA Superfund Explanation of Significant Differences: SANGAMO WESTON, INC./TWELVE-MILE CREEK/LAKE HARTWELL PCB CONTAMINATION EPA ID: SCD003354412 OU 01 PICKENS, SC 09/10/1991 1 U.S. ENVIRONMENTAL PROTECTION AGENCY REGION IV SUPERFUND PROGRAM EXPLANATION OF SIGNIFICANT DIFFERENCES SANGAMO WESTON/TWELVE-MILE CREEK/LAKE HARTWELL PCB CONTAMINATION SITE OPERABLE UNIT ONE PICKENS, PICKENS COUNTY, SOUTH CAROLINA Introduction The purpose of this Explanation of Significant Differences (ESD) is to provide factual information to the public regarding a change in remedial activities for the Sangamo Weston/Twelve-Mile Creek/Lake Hartwell PCB Contamination Site, Operable Unit #1, in Pickens County, South Carolina (Site). In addition, this ESD explains the process that the Environmental Protection Agency (EPA) will follow to provide for a remedy which is protective of human health and the environment with respect to inorganic contamination (metals) at the Site. This ESD modifies the existing Record of Decision (ROD) by identifying metals in the soils and in the groundwater that have been found in amounts that may exceed acceptable health based levels. The ESD also modifies the ROD by adding clean up criteria for metals contamination in the groundwater and provides for additional testing and data gathering for metals at the Site. After this data is gathered, EPA will make a future determination regarding the necessity of remedying the metals contamination through an additional ESD or a ROD amendment. This ESD also clarifies the PCBs excavation standard selected in the ROD for two areas of the Site, and explains a response made by EPA to a comment received during a public meeting held to discuss the ROD. This Explanation of Significant Differences (ESD) is issued as an EPA public participation responsibility pursuant to Section 117(c) of the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA), as amended by Superfund Amendments and Reauthorization Act (SARA), and Section 300.435(c)(2)(i) of the National Contingency Plan (NCP) 40 C.F.R. Part 300. The administrative record file for the Site contains the information upon which this ESD was based, and includes the ROD for Operable Unit #1. This ESD will become part of the administrative record which is located at the following locations: Pickens County Library, Pickens S.C. Village Library, Pickens S.C. Hart County Library, Hartwell Ga. R. M. Cooper Library at Clemson University -2Background The remedy for the Sangamo/Weston/Twelve Mile Creek/Lake Hartwell site is presently divided into two Operable Units. Operable Unit #1 (OU-1) will address that portion of the site consisting of the seven parcels of property where PCBs, VOCs and metals were released into the soils and groundwater (the Sangamo/Weston plant property, the Nix, Welborn, Dodgen’s, Breazeale, Trotter and Cross Roads properties). All seven of the properties are located in Pickens County, South Carolina. This ESD modifies only the ROD for OU-1. Throughout this ESD the term Site (upper case) is used to mean the seven properties described above. These locations are identified on the map included as Attachment A. The remedial action for polychlorinated biphenyls (PCBs) and volatile organic compounds (VOCs) contamination at the Site is detailed by EPA in the ROD signed on December 19, 1990. In summary, the remedy selected in the ROD consists of groundwater remediation for PCBs and VOCs using pump and treat technology at the Dodgens, Breazeale, Cross Roads, and Plant properties; and the excavation of PCB and VOC contaminated soils at the Plant property and the six satellite properties. The excavated soils will be treated at the Plant property utilizing thermal separation technology. Site History Sangamo Weston Inc., owned and operated a capacitor manufacturing facility at the Plant property. The Pickens facility began operation in 1955 and continued operating until May 1987, when Sangamo Weston sold the operation and leased the buildings and a portion of the property to another manufacturer. On December 31, 1989, Sangamo Weston merged with Schlumberger Industries, Inc., (SII). SII is the present owner of the plant property portion of the Site. Between approximately 1955 and 1977 the facility manufactured capacitors which used a dielectric fluid that contained PCBs. During the manufacturing process, capacitors were inspected and tested, and those that failed to meet quality control criteria were discarded along with other wastes from the plants operation. Some of these wastes were disposed of on the Site. Description of the Remedy The ROD specifies that soils contaminated with PCBs and VOCs will be excavated and treated through Thermal Separation. This treatment technology consists of a low -3temperature thermal heating unit which vaporizes PCBs and VOCs from the soil and recondenses them into a concentrated form so that they may be properly disposed of at an appropriate facility. PCB and VOC contaminated soils will be excavated from the Site until acceptable health based levels specified in the ROD are reached. All excavated PCB contaminated soil material will be transported to the Plant property and will be treated by the Thermal Separation unit to residual PCB levels of 2 parts per million (ppm) or less. The treated soil will then be disposed of on the plant property. Because Thermal Separation is considered an innovative technology, treatability studies will be performed to determine if the technology will achieve the clean-up level of 2 ppm. If the treatability studies show that Thermal Separation is ineffective for all or a portion of the contaminated soils, EPA may, if necessary, formally amend the ROD to choose a new technology for remediation of the contaminated soils. The remedy selected in the ROD for groundwater contaminated with PCBs and VOCs is to pump contaminated water and treat it using air stripping and/or carbon adsorption technology. Groundwater will be pumped until clean-up levels specified in the ROD are met or until such time as EPA determines that such clean-up levels are impracticable to achieve and that contingency measures should be implemented. Pumped groundwater will be treated to meet all Applicable or Relevant and Appropriate Requirements (ARARS), such as Clean Water Act NPDES effluent limitations, before being discharged to nearby existing water bodies such as creeks, and tributaries. Description of Significant Differences After the ROD was signed EPA determined that the ROD did not address several metals which had been listed as Constituents of Concern in Table 6-1 of the Appendix to the ROD. Upon further review of the sampling data gathered during the initial phases of the Remedial Investigation, EPA has determined that metals contamination at the Site may have been dismissed prematurely during the Remedial Investigation Feasibility Studies (RI/FS) process. EPA has two concerns: 1) whether metals concentrations in the groundwater at the Site exceed maximum contaminant levels (MCLs) established by EPA for groundwater; and 2) whether the concentrations of certain metals in soils and waste at the Site might exceed acceptable health and risk based levels deemed to be protective of human health and the environment. -4A) Groundwater Limited groundwater sampling and analysis from the initial phases of the Remedial Investigation identifies metals in excess of MCLs in the groundwater at five of the satellite properties and at the Plant property. This sampling data is attached as Appendix B. The metals listed on the chart below have been found in groundwater at areas of the Site in levels exceeding MCLs. Through this ESD, EPA is modifying the ROD to add the MCLs for the listed metals as clean-up criteria at the Site. EPA has also determined that further groundwater sampling at all areas of the Site is necessary (including the possible installation of additional monitoring wells) to delineate the nature and extent of the metals contamination and to determine if there is a demonstrated plume of metal contamination requiring remediation. At the properties where pump and treat remedial technology is presently called for in the ROD, groundwater will be pumped until MCLs for the listed metals, as well as the PCB and VOC levels specified in the ROD, are reached. Utilizing the additional sampling data called for in this ESD, EPA will make a future determination as to what addition remedial technology, if any, will be necessary to treat pumped groundwater containing metals. EPA will also determine if groundwater at any additional properties (Nix, Welborn and Trotter) needs to be remediated for metals. EPA will incorporate these determinations into the ROD through an additional ESD or a ROD amendment after a public comment period. The clean-up criteria listed below shall also be incorporated into such additional ESD or ROD amendment. The following chart lists the metals of concern and the appropriate MCL clean-up levels for each metal. METALS MCL CLEAN UP CRITERIA Arsenic 0.050 ppm Beryllium 0.001 ppm Cadmium 0.005 ppm Chromium 0.100 ppm Lead 0.015 ppm(1) Thallium 0.001 ppm -5B) Soils Based on the limited sampling and analysis data presently available regarding metals in the soils at the Site, EPA has determined that metals found in the soils may exceed acceptable health based risk levels. Utilizing existing data, EPA has identified metals in the soils which may require additional remediation, but needs additional information on specific conditions at the Site to calculate acceptable metal concentration levels. Therefore, EPA has determined that additional soil sampling activities for metals will be conducted at the Site. These data gathering activities will enable EPA to develop acceptable levels for metals in the surface and subsurface soils and will allow EPA to determine the geographic extent of the metals soil contamination at the Site. Following review of the new data, EPA will make a determination of what additional soil clean-up criteria and additional remedial technology, if any, will be needed to remediate the metal contaminated soil. EPA will incorporate any new soil clean-up criteria and remedial technology into the ROD through an additional ESD or ROD amendment after a public comment period. EPA will calculate the acceptable subsurface soil concentration criteria utilizing test procedures to establish soil partition coefficients which will establish the mobility of the metals in the soils and subsequently, through modeling, establish a concentration that is protective of groundwater. Acceptable surface soils concentration criteria will be developed based on direct exposure routes.(2) The following chart lists the metals which may exceed acceptable health based levels at the Site. INORGANIC METALS CONTAMINANT Arsenic (3) Chromium (4) Lead (5) Thallium (6) Beryllium (7) Cadmium (8) -6PCB Excavation Levels For The Nix and Welborn Properties This ESD also clarifies the excavation clean-up criteria for PCB contaminated soils at the Nix and Welborn properties. The ROD presently calls for the excavation of all contaminated soils at the Nix and Welborn properties having greater than 1 ppm of PCBs. However, the l ppm level called for in the ROD is based on the concern that at the ravines located on the two properties, erosion factors are too severe to assure that a 2 foot backfill of clean soil would remain in place. Where EPA determines that erosion is not a concern on the two properties, PCB contaminated soils will be excavated to the levels specified in the ROD for the four possible future residential properties (Trotter, Dodgens, Breazeale, and Cross Roads), i.e. requiring excavation to 10 ppm PCBs with a backfill cover of 2 feet of clean soil. The final EPA determination regarding erosion and/or backfilling at the two properties will be made during the Remedial Design phase. Clarification of Prior EPA Response to Public Comments Upon review of the Responsiveness Summary, (ROD Appendix C), EPA identified a response to a question received during a public meeting that may have been unclear. The original comment and response as stated on pages 15 and 16 of the Responsiveness Summary is as follows: An attendee commented that ground-water contamination has existed for ten years and that hazardous waste continues to leach into the ground water. The attendee asked whether it was possible for EPA to conduct a short-term removal action at the site, such as excavating the soil which is leaching into the ground water. EPA RESPONSE: Removals are performed where imminent and substantial endangerment is posed by a hazardous waste site. In this case, no imminent threat exists because no one is drinking the groundwater; no one is exposed at this point. The leaching, to a great extent, has already taken place and is slow. Part of the remedy is to excavate and treat the soil. Excavating and stockpiling it prior to completion and approval of a treatment design, however, could create a problem elsewhere. 7 By this response, EPA did not intend to suggest that an imminent and substantial endangerment to public health and the environment does not exist at the Site. The intent of EPA and the responder was to say that an immediate threat to public health necessitating use of EPA’s removal authority has not been demonstrated by conditions at the Site. Support Agency Comments South Carolina’s Department of Health and Environmental Control has reviewed this ESD and concurs with its contents. Statutory Determinations The modifications made to the ROD by this ESD are designed to assure that the remedy at the Site will be protective of human health and the environment, and will comply with Federal and State requirements that are applicable or relevant and appropriate. After the additional data called for in this ESD has been gathered and evaluated, EPA will use an additional ESD or a ROD amendment to modify the ROD to incorporate any additional necessary clean-up criteria for metals and to choose necessary additional remedial technologies for metals. Any additional ESD or ROD amendment will include a public comment period. 8 FOOTNOTES (1) In reviewing the initial data for lead contamination, EPA used the old MCL of 0.050 ppm. However, EPA Headquarters Superfund Program had set a Superfund Program Action level for lead clean-up at the lower level of .015 ppm. The rationale for this health based clean-up level is explained in memorandum to EPA Region IV, dated June 21, 1990 and attached as Appendix C). (2) Surface soils were sampled for metals at the Welborn property. The Welborn sampling was limited to lead, barium and zinc. The soils data available for the remaining properties are for the waste areas and subsurface soils. Based on this information and data regarding metals found at elevated levels in the groundwater, EPA has determined that the listed metals may be present at levels of concern in surface soils. The surface soil clean-up criteria will be calculated based on direct contact exposure routes. Subsurface soil cleanup concentrations will be calculated to protect groundwater. Should the cleanup criteria for subsurface soils be lower than those calculated for surface soils the lower criteria shall be the clean-up goal for all soils. (3) Based on averaged background levels for the surrounding area. (4) Assumes <10% hexavalent chromium present. Further sampling will be done to confirm this assumption. If EPA can not confirm the percentage of hexavalent chromium at the Site it will determine the acceptable risk levels based on the worst case scenario of the presence of 100% hexavalent chromium. 100% Hexavalent Chromium at the Site would lower the clean-up level. (5) Consistent with SUPERFUND Policy pursuant to OSWER Directive 9355.4-02. (6) Thallium was detected in groundwater at levels exceeding MCLs. It was not detected in unacceptable levels in the existing soil samples. However, because thallium was detected it the groundwater it is listed herein. The surface soil remediation goal for thallium will be based on the chemical-specific noncarcinogenic reference dose for the oral exposure route. The subsurface remediation goal will be set at the level that is protective of groundwater. 9 (7) Beryllium was detected in several waste and subsurface soils exceeding the acceptable risk levels for direct contact through surface soils. The remediation surface soil goal will based on oral and inhalation carcinogenic slope factors. The subsurface soil remediation goal will be set at the level that is protective of the groundwater. (8) Cadmium was detected in groundwater at levels exceeding MCLs. It was not detected in unacceptable levels in existing soil samples. However, because cadmium was detected in the groundwater it is listed herein. The surface soil remediation goal for Cadmium will be based on the chemical-specific noncarcinogenic reference dose for the oral exposure route. The subsurface soil remediation goal will be set to the level that is protective of the groundwater. ATTACHMENT B METAL MCL SAMPLE # CONCENTRATION Arsenic .050 PPM JTMW-3 .213 PPM Beryllium .001 PPM JTMW-3 .007 PPM Cadmium .005 PPM CRMW-3 .011 PPM Chromium .100 PPM JTMW-3 .190 PPM Thallium .001 PPM SWMW-4 .016 PPM Lead .015 PPM WBMW-3 JTMW-3 CRMW-3 DGMW-3 NXMW-3 SWMW-6 .054 .093 .055 .038 .020 .063 PPM PPM PPM PPM PPM PPM ATTACHMENT C UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D.C. 20460 OFFICE OF SOLID WASTE AND EMERGENCY RESPONSE JUN 21 1990 MEMORANDUM SUBJECT: Cleanup Level for Lead in Ground Water FROM: Henry L. Longest, Director Office of Emergency and Remedial Response Bruce M. Diamond, Director Office of Waste Programs Enforcement TO: Patrick M. Tobin, Director Waste Management Division, Region IV PURPOSE This memorandum addresses the issue of a protective cleanup level for lead in ground water usable for drinking water, which is a major concern for several Superfund sites in Region IV. OBJECTIVE The objective of this memorandum is to recommend a final cleanup level for lead in ground water usable for drinking water which will meet the CERCLA requirement that all Superfund remedies be protective of human health and the environment. BACKGROUND The current Maximum Contaminant Level (MCL) for lead is 50 ppb and was promulgated in 1975 as an interim national primary drinking water regulation (NPDWR) under the Safe Drinking Water Act (SDWA). On November 13, 1985, the Agency began the process of revising this standard by proposing a Maximum Contaminant Level Goal (MCLG) as required by the SDWA (50 FR 46936). On August 18, 1988 EPA proposed an MCLG for lead at zero and an MCL of 5 ppb (53 FR 31516). Also, since the primary cause of lead-contaminated drinking water is corrosion of lead-bearing pipes in public water supply (PWS) distribution systems and/or household plumbing, the proposed rule would direct PWSs to meet treatment technique requirements and to deliver public education to reduce and minimize exposures to lead in drinking water. -2These requirements would be triggered when an action level is exceeded at consumers’ taps throughout the water distribution system. The Agency proposed an action level of 10 ppb, on average, to trigger corrosion control and public education. Another lead action level of 20 ppb, measured at the 95 percentile of samples, was proposed as a trigger for public education. The Agency is considering promulgation of treatment technique requirements which may include additional source water treatment, lead service connection replacement, and public education if lead concentrations at the tap exceed an action level. Any such technological treatment targets will provide substantial health protection. A final rule is being worked on, and is scheduled for promulgation in December 1990. DISCUSSION No cancer potency factor or reference dose has been promulgated for lead; therefore, an assessment of protective levels of lead in ground water that may be used for drinking water purposes will be based on current data. The Agency has identified 10 micrograms per deciliter (ug/dl) as a blood lead level of concern in young children. Blood lead levels above 10 ug/dl are associated with increased risks of potentially adverse effects on neurological development and diverse physiological functions. Attached is available data that support the recommended final cleanup level for lead in drinking water at Superfund sites. This information includes the June 15, 1990, EPA draft final report entitled, “Contributions To a Risk Assessment For Lead in Drinking Water” and the June 1986, EPA draft final report entitled, “Air Quality Criteria for Lead” (Volume III of IV, p. 11-129). Based on these data, lead levels in drinking water of 15 ppb and lower should correlate to blood lead levels below the concern level of 10 ug/dl. The Agency estimates that steady exposure to a water lead concentration of 15 ppb would contribute, at most, 2-3 ug/dl to a child’s blood lead. Sources of lead other than drinking water (e.g. food, air, soil, dusts) typically contribute approximately 4-5 ug/dl to children’s blood lead. Accounting for the variability inherent in childhood behavior, nutrition, and physiology, it is estimated that total lead exposure, given 15 ppb in drinking water, would result in blood lead levels below 10 ug/dl in -3roughly 99 percent of young children who are not exposed to excessive lead paint hazards or heavily contaminated soils. Therefore, a 15 ppb cleanup level would provide substantial health protection for the majority of young children. Most of the remaining lead problem will continue to be contaminated soils and old lead-painted housing. In an April 10, 1989, Federal Register notice (54 FR 14316), EPA announced the availability of a guidance document and testing protocol entitled, “Lead in School’s Drinking Water,” to assist schools in determining the source and degree of lead contamination in school drinking water supplies and how to remedy such contamination. That document, which is also attached, recommends that schools take remedial steps whenever the lead level at any drinking water outlet exceeds 20 ppb. RECOMMENDATION Based on a review of these and other studies, it is recommended that a final cleanup level of 15 ppb for lead in ground water usable for drinking water is protective. If water used for drinking purposes subsequent to achieving the cleanup goal in the aquifer may need further treatment to account for lead contributions related to the distribution of water through pipes, the responsibility for this additional treatment or the replacement of lead-bearing water pipes lies with the persons who are using or distributing the water. A concentration of lead of 15 ppb in drinking water should generally correlate with a blood lead level below the concern level of 10 ug/dl. In some situations, lower cleanup levels may be appropriate based on site-specific factors, such as multiple pathways of exposure caused by lead from the site. If the remedial action will include treatment and supplying water directly to the public for drinking water consumption, compliance with a 15 ppb action level should be met at 90 percent of the taps to ensure that the remedy is protective. When the lead NPDWR is promulgated, applicable or relevant and appropriate requirements of that rule should be met. FUTURE GUIDANCE After promulgation of the lead NPDWR, guidance will be issued discussing those provisions of the rule that may be applicable or relevant and appropriate for Superfund actions. For further information, please contact Tish Zimmerman at FTS 382-2461 or Neilima Senjalia at FTS 475-7027. SANGAMO WESTON, INC./TWELVE-MILE CREEK/LAKE HARTWELL PCB CONTAMINATION Site Information: Address: SANGAMO WESTON, INC./TWELVE-MILE CREEK/LAKE HARTWELL PCB CONTAMINATION PICKENS, SC EPA ID: EPA Region: SCD003354412 04 Site Name: Site Alias Name(s): SANGAMO/TWELVE-MILE/HARTWELL PCB SANGAMO WESTON-PICKENS PLANT HAYWOOD RESERVOIR MIDWAY LANDFILL CROSS ROADS CHURCH BREZEAL PROPERTY WELLBORN PROPERTY MAW BRIDGE ROAD NIX, ERNEST PROPERTY SANGAMO ELECTRIC SANGAMO PROPERTY SANGAMO WESTON/TWELVE-MILE/HARTWELL PCB Record of Decision (ROD) - Explanation of Significant Differences (ESD): ROD Date: Operable Unit: ROD ID: 06/18/1993 01 EPA/ESD/R04-93/502 Text: Full-text ROD document follows on next page. EPA/ESD/R04-93/502 1993 EPA Superfund Explanation of Significant Differences: SANGAMO WESTON, INC./TWELVE-MILE CREEK/LAKE HARTWELL PCB CONTAMINATION EPA ID: SCD003354412 OU 01 PICKENS, SC 06/18/1993 U.S. ENVIRONMENTAL PROTECTION AGENCY REGION IV SUPERFUND PROGRAM EXPLANATION OF SIGNIFICANT DIFFERENCES Sangamo Weston/Twelve-Mile Creek/Lake Hartwell PCB Contamination Site Operable Unit One Pickens, Pickens County, South Carolina 1.0 Introduction The purpose of this Explanation of Significant Differences (ESD) is to provide factual information to the public regarding changes in proposed remedial activities for the Sangamo Weston/Twelve-Mile Creek/Lake Hartwell PCB Contamination Site, Operable Unit One, located in Pickens County, South Carolina, hereinafter referred to as the Site. First, this ESD explains the results of EPA’s evaluation of inorganic contamination (metals) at the Site. This evaluation was performed pursuant to a previous ESD dated September 10, 1991. This ESD modifies the existing Record of Decision (ROD) for the Site by concluding that metals contamination of surface soils and ground water does not pose an unacceptable level of risk to human health or the environment. The results of analyses of ground-water and soil samples taken at the seven individual locations which comprise the overall Site are presented. The results of analyses for metals in these samples indicate that metals contaminant concentrations in the ground water do not exceed the appropriate ground-water protection criteria for the Site and that surface soils are not contaminated above health-based criteria established by standard risk assessment procedures. Second, this ESD modifies the existing ROD by updating the ground-water remediation criteria. At the time that the previous ESD was prepared, ground-water remediation criteria for the contaminants beryllium and thallium were both set at 0.001 part per million (ppm), equivalent to 1 part per billion (ppb). These remediation criteria were based upon toxicological data related to health effects caused by exposure to these contaminants, but EPA had not at that time promulgated drinking water standards (known an Maximum Contaminant Levels, or MCLs) for beryllium or thallium. In July, 1992, EPA published in the Federal Register final MCLs for beryllium and thallium. These MCLs are 4 ppb and 2 ppb, respectively. This ESD modifies the existing ROD (as modified in turn by the previous ESD) by adopting the promulgated MCLs as ground-water remediation criteria for beryllium and thallium. Third, this ESD also modifies the existing ROD for the Site by 2 waiving certain specific applicable requirements identified in the ROD for the storage of PCB wastes. Under the terms of the National Contingency Plan (NCP), EPA has established criteria by which the Agency may waive applicable or relevant and appropriate requirements (ARARs) identified during the RI/FS process. EPA has determined that the ARAR requiring the construction of a storage facility complying with the requirements of regulations established pursuant to the authority of the Toxic Substances Control Act (TSCA) should be waived according to these criteria. This ESD is issued as an EPA public participation responsibility pursuant to Section 117(c) of the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA), as amended by the Superfund Amendments and Reauthorization Act (SARA), and Section 300.435(c)(2)(i) of the NCP, 40 CFR Part 300. EPA intends to solicit public comment regarding this ESD for a 30-day period. The administrative record for this Site contains the information upon which this ESD is based, and includes the ROD for Operable Unit One. This ESD will become part of that administrative record which may be found at the following locations: Pickens County Library, Pickens, SC Village Library, Pickens, SC Hart County Library, Hartwell, GA R.M. Cooper Library, Clemson University, Clemson, SC 2.0 Background The remedy for the Site is presently divided into two Operable Units. Operable Unit One (OU1) will address that portion of the Site generally consisting of seven parcels of property where polychlorinated biphenyls (PCBs), volatile organic chemicals (VOCs), and metals were released into the soils and ground water. These seven parcels are the Sangamo Weston plant property and six private parcels located in the vicinity of the town of Pickens, SC, in Pickens County. These six outlying or satellite disposal sites are known as the Breazeale, Crossroads, Dodgens, Nix, Trotter and Welborn sites. This ESD modifies only the ROD for OU1. Throughout this ESD the term Site (upper case) is used to mean the seven properties described above. These locations are identified on the map included as Appendix A. The remedial action for PCBs and VOCs contamination at the Site is described in detail in the ROD signed on December 19, 1990. In summary, the remedy selected in the ROD consists of ground-water remediation for PCBs and VOCs using ground-water extraction and treatment at the Plant, Breazeale, Crossroads and Dodgens sites; and excavation of soils contaminated with PCBs and VOCs at the Plant property and at the six satellite sites. All excavated soils 3 will be treated at the plant property by means of low temperature thermal desorption (LTTD), a thermal separation technology. On September 10, 1991, EPA issued an ESD for OU1 at this Site that identified inorganic contaminants (metals) found during the Remedial Investigation (RI) that may have exceeded criteria based upon the protection of human health. That ESD also modified the ROD by establishing remedial criteria for metals contamination in ground water and by providing for additional testing and data gathering for the purpose of evaluating compliance with those criteria. The previous ESD also clarified the criteria established for PCB excavation at two of the satellite sites, and contained an explanation of a response made by EPA to a comment raised during a public meeting held to discuss the ROD for the Site. Finally, the previous ESD committed EPA to evaluate the data gathered on metals contamination and to make a determination regarding the necessity of providing remediation for metals contamination by means of a future ESD or ROD amendment. 3.0 Site History Sangamo Weston, Inc., owned and operated a capacitor manufacturing facility at the Plant property. This manufacturing activity began in 1955, and was continued by Sangamo Weston until May, 1987, when Sangamo Weston sold the operation and leased the buildings and a portion of the Plant site property to another manufacturer. On December 31, 1989, Sangamo Weston merged with Schlumberger Industries, Inc., (SII). SII is the present owner of the Plant property portion of the Site. During the approximate period l955-1977, the facility manufactured capacitors which used a dielectric fluid which contained PCBs. During the manufacturing process, capacitors were tested and inspected, and those that failed to meet quality control criteria were discarded along with other wastes from the plant operation. Some of these wastes were disposed of in the seven parcels that comprise the Site. 4.0 Description of the Remedy The ROD specifies that soils contaminated with PCBs and VOCs will be excavated and treated by means of LTTD. This treatment technology consists of a low temperature thermal heating unit which vaporizes PCBs and VOCs from contaminated soils and waste materials and recondenses them into a concentrated form so that they may be properly disposed of at an appropriate facility. Soils and waste material contaminated with PCBs and VOCs will be excavated from the Site until acceptable levels, based on the protection of human health as specified in the ROD, are achieved. All excavated soils and waste materials contaminated with PCBs and VOCs will be transported from the six satellite sites to the Plant site and will be treated at that location using the LTTD 4 technology. Excavated soils and waste material from the Plant site will also be treated at this location using the same LTTD system. All contaminated soils and wastes will be treated to a residual PCB concentration of 2 parts per million (ppm) or less. The treated soils will then be disposed of on the Plant site property. Due to the fact that LTTD is considered to be an innovative technology, treatability studies are being performed to determine if the technology can achieve the specified performance standard of 2 ppm residual PCBs. Should the treatability studies demonstrate that LTTD is ineffective for all or a portion of the contaminated soils and waste materials, EPA may, if necessary, amend the ROD to specify an alternative treatment technology for remediation of these media. With respect to contaminated ground waters at the various sites, the remedy selected in the ROD consisted of extraction and treatment to levels meeting ARARs or other criteria determined to be protective of human health. The treatment technology identified in the ROD is a combination of air stripping and/or carbon adsorption as necessary to achieve ARARs for the discharge of treated ground waters to surface waters. Extraction of contaminated ground water will continue until such time as the ground-water remediation criteria specified in the ROD are achieved, or until EPA makes a further determination that it has become technically impracticable to achieve those criteria. After the ROD was signed in 1990, EPA determined that the ROD did not properly address several metals which had been listed as Constituents of Concern in Table 6-1 of the Appendix to the ROD. Upon further review of the sampling data gathered during the RI, EPA likewise determined that metals contamination at the Site may have been prematurely dismissed from consideration during the Remedial Investigation/Feasibility Study (RI/FS) process. As a result, EPA had two primary concerns: (1) whether metals contamination in ground waters at the Site exceed MCLs and/or other criteria established by EPA for the protection of ground water; and (2) whether the concentrations of metals in the Site soils and waste materials result in unacceptable risk to human health based upon standard exposure scenarios. By means of an ESD issued on September 10, 1991, EPA notified the public of these concerns and the steps that would be taken to properly address them. Those steps consisted of: (1) the establishment of remedial criteria for ground waters at the Site for six (6) metals, arsenic, beryllium, cadmium, chromium, lead and thallium; (2) a program of sampling and analysis for the same six metals in Site soils in order to determine the extent, if any, of threat to human health or the environment posed by metals in Site soils; (3) a similar program of sampling and analysis for the same six metals for Site ground waters; and (4) a determination as to what additional remedial technologies, if any, will be necessary to address metals-contaminated soils, waste materials, and ground 5 water. 5.0 Description of Significant Differences 5.1. Metals Contamination in Site Soils and Ground Water In February, 1993, SII submitted reports of sampling and analyses for metals in surficial soils and ground waters at the Site. The sampling and analyses were conducted in accordance with work plans prepared by SII and submitted to EPA for review and approval. One aspect of the approved work plans was that ground-water samples would be obtained by more appropriate sampling techniques than those used during the RI. The sampling techniques used in the more recent efforts were such that the amount of suspended solids in the samples was kept to a minimum. Suspended solids in samples taken from ground-water monitoring wells can contribute to artificially high results when analyzed for metals content. Another aspect of the approved sampling and analysis program was that should these improved sampling techniques indicate that ground-water was not contaminated to unacceptably high levels with metals, no subsurface sampling for metals would be required. The results of these sampling and analysis programs are summarized in Appendix B. At the six satellite sites, out of 798 ground-water samples for metals content, only three samples exceeded any established ground-water protection standard identified in the September 1991 ESD. All three of these exceedances were for one contaminant, lead, and one of the three was in a background well at one of the satellite sites. The other two were in one downgradient well at another satellite site; other samples from that same well were found to be contaminated at levels below the ground-water protection standard for lead. At the Plant site, out of 450 ground-water samples analyzed, only five samples were contaminated at levels which exceeded ground-water protection standards. Of these, three were found to be contaminated at unacceptably high levels for lead, one was for chromium and one for thallium. Again, in each case the well found to be contaminated at such levels was found in at least one other sampling event not to be contaminated. In sampling of surficial soils, similar results were obtained. At the six satellite sites, only one of 522 samples analyzed for metals content was contaminated to a level that would constitute an unacceptable level of risk to human health under standard residential exposure assumptions. This sample was likewise found to be contaminated with lead, and was obtained from the Welborn site. Surficial soils at the Plant site were not submitted to an evaluation based upon residential exposure scenarios due to the low likelihood of such exposure occurring either in the interim before remediation takes place or thereafter. In addition, the surficial soil results were subjected to a 6 statistical evaluation wherein the results of analysis of samples taken from affected areas of the six satellite sites were compared to background levels. This evaluation demonstrated that there was no statistically significant difference between the levels of contamination found in the affected areas of the site and background levels of metals in the surficial soils. These findings indicate that the soils overlying the six satellite disposal sites are essentially the same as naturally-occurring soils in the surrounding areas, suggesting that waste materials disposed of in these satellite disposal sites were covered with at least a thin layer of native soils. Based upon these results, EPA has reached the following determinations: a. Ground-waters at all seven parcels of property which comprise the Site are not significantly contaminated with metals. Only 0.4% of the ground-water samples analyzed from the satellite sites (3 out of 798 samples) and 1.1% of ground-water samples from the Plant site (5 out of 450 samples) exceeded ground-water protection standards identified in the September 1991 ESD. In each case, the exceedance occurred in either a background well or in a well that was found to be uncontaminated in at least one other sampling event. As a result, EPA has determined that ground-water remediation based upon metals contamination will not be performed at any of the seven parcels that comprise the overall Site. Continued monitoring for metals contamination in ground water will be part of the operation and maintenance activities at the Site so that long-term compliance with metals criteria can be evaluated. b. The level of contamination by metals in surficial soils at the six satellite sites is not significantly different than the levels found for the same metals in background surficial soil samples. As a result, surficial soil remediation based solely upon metals criteria will not be performed at the six satellite sites. c. Metals in surficial soils at the six satellite sites do not pose an unacceptable level of risk to human health. The analytical results for surficial soils were compared to benchmark concentrations that would result in a Hazard Index of 1.0 under standard residential exposure scenarios. In all cases, with one exception out of over 500 analyses, the concentrations found in surficial soils were below the benchmark corresponding to a Hazard Index of 1.0. This determination further supports EPA’s determination not to perform any remediation of surficial soils at the satellite sites based solely upon metals criteria. d. Since ground-waters at the Site are not contaminated to 7 unacceptably high levels, subsurface evaluation for metals contamination of the seven parcels that comprise the Site will not be performed. Remediation of subsurface soils for metals contamination would only be appropriate if subsurface metals contamination was found to be contributing to unacceptably high levels of ground-water contamination. Accordingly, no subsurface remediation criteria for the six metals identified in the September 1991 ESD will be established. 5.2. Ground-Water Thallium Remediation Criteria for Beryllium and The previous ESD for this Site, dated September 10, 1991, revised the ROD by adding ground-water remediation criteria for six metals. Two of those metals were beryllium and thallium. The remediation criteria for both of these contaminants were established at 1 ppb. These criteria were based upon the available toxicological data regarding potential health effects resulting from exposure to these two metals. At that time, EPA had not promulgated Maximum Contaminant Level Goals (MCLGs) or Maximum Contaminant Levels (MCLs), for these two metals. MCLGs are criteria established under the authority of the Safe Drinking Water Act (SDWA) which are based solely on protection of human health, without consideration of technical or economic feasibility. They are not enforceable as drinking water standards for public water supplies. MCLs are established under the authority of the SDWA as standards for drinking water quality applicable to public water supply systems. MCLs are established to be protective of human health, taking into account the technical and economic feasibility of achieving compliance with the MCL. The National Contingency Plan (NCP) contains requirements for the remediation of ground waters at Superfund sites, and these requirements include the use of MCLGs and MCLs as remediation criteria. In 40 CFR Part 300.430(e), the NCP requires the use of MCLGs, when available, as remediation criteria, except when the MCLG is set at zero, when the MCLG is relevant and appropriate to the circumstances of the release. When the MCLG is zero, or where the MCLG is otherwise not relevant and appropriate to the circumstances of the release, the MCL is to be used as the remediation criterion. On July 17, 1992, EPA promulgated final MCLGs and MCLs for beryllium and thallium. The MCLGs for beryllium and thallium were set at 4 ppb and 0.5 ppb, respectively. The MCL for beryllium was likewise set at 4 ppb, and the MCL for thallium was set at 2 ppb. Since the MCLG and the MCL for beryllium are both 4 ppb, this concentration is set as the remediation criteria for this contaminant in ground water at the Site. 8 For thallium, EPA promulgated an MCL that is greater than the MCLG, even though the MCLG is not zero. Generally, if the MCLG is not zero, the MCLG and the MCL are set at the same concentration, as in the case of beryllium. In the case of thallium, however, the MCLG of 0.5 ppb is below the Practical Quantification Limit (PQL) for this contaminant. In other words, the MCLG concentration is less than the level at which thallium can be detected and quantified with consistent precision and accuracy by available analytical techniques. As such, using the MCLG as a ground-water remediation criterion is not appropriate to the circumstances of the releases from this Site, since it is not technically feasible to measure compliance with such a low concentration. Since the use of the MCLG is not appropriate, this ESD modifies the existing ROD by setting the MCL of 2 ppb as the ground-water remediation criterion for thallium. The use of the MCL of 2 ppb for thallium remains protective of human health. In the July 17, 1992, Federal Register promulgation of the MCL for thallium, EPA states: (T)he final PQL and MCL for thallium is being set...at 0.002 mg/l....The MCL for thallium is limited by the sensitivity of available analytical methods (i.e., it is being set at the PQL)....However, the Agency has concluded that the promulgated MCL is adequately protective of human health because the MCLG includes a large cumulative safety factor of 3,000. Thus, EPA believes that the health risks of exceeding the MCLG up to the MCL are minimal. (FR Volume 57, No. 138, p. 31815) EPA has therefore determined that the ground-water remediation criteria for beryllium and thallium should be revised. The revised remediation criteria are 4 ppb for beryllium and 2 ppb for thallium. These criteria correspond to the final MCLs promulgated by EPA for these contaminants. 5.3. Waiver of TSCA Storage Requirements Remedial actions to be undertaken at the Sangamo Weston Superfund Site include the transport of waste materials and PCB-contaminated soils from the six uncontrolled satellite disposal sites and storage of those materials at a controlled location, the Plant site, until such time as the LTTD treatment technology can be tested, constructed and placed in operation. EPA had previously determined that TSCA regulations for the storage of wastes contaminated with PCBs were applicable to this remedial action. Sampling of the waste material conducted as part of the remedial design process has shown that the waste materials to be transported contain PCBs in excess of 50 parts per million (ppm), the concentration subject to regulation under the authority of the Toxic Substances Control Act (TSCA). These findings render applicable TSCA regulations governing the storage and disposal of 9 these materials. They are therefore ARARs for the remedial action selected by the ROD. After consideration of these regulations as they would affect the implementation of the selected remedy, EPA has determined that these regulations should be waived in accordance with the requirements of 40 CFR 300.430(f)(1)(ii)(C). The waiver is determined to be appropriate on the basis of the fact that this storage is an interim measure that is part of an overall remedial action that will, when fully implemented, comply with all applicable or relevant and appropriate requirements (ARARs); and that compliance with these ARARs would result in greater risk to health and the environment than would result should they be waived. For example, compliance with the TSCA requirement for construction of an engineered storage facility would result in a substantial delay in removing contaminated soils and waste materials from the six satellite sites. During this delay, releases of contaminants from the satellite would continue, along with continued exposure to those contaminants by human and environmental receptors. It is intended that the contaminated soils and waste materials from the satellite sites will be stockpiled on the plant site in locations that are already similarly contaminated and which will be included in the overall site remediation. Placing the excavated materials from the satellite sites on contaminated areas at the plant that are likewise scheduled for eventual excavation and treatment will prevent additional impacts associated with any potential migration of contaminants that might occur if the materials were stockpiled in uncontaminated areas. Measures will be taken to minimize run-on/runoff of precipitation and infiltration of any leachate to ground water, but those measures would necessarily be of a temporary nature. These measures will include an earthen berm around the storage area to prevent storm water run-on and run-off; a top liner of synthetic material covering the stockpiled soils and waste; a system whereby the liner is anchored into the berm to insure that the stockpile remains covered; and weights (for example, sand bags) placed on the liner to prevent displacement by high winds. A significant period of time may elapse between the time that the material from the six satellite sites is excavated and transported to the Plant site, and the time when treatment of soils and waste materials by LTTD will commence. This is due to the need for treatability studies to be conducted on the various LTTD treatment units that are commercially available, the time necessary to complete design studies, and the time necessary for the PRPs and their technical consultants to prepare specifications and enter into contracts with a vendor for the chosen remedial technology. This period of time could conceivably be as much as two to three years after the material from the satellite sites could be excavated and transported. During this period, the excavated materials will be stored in a controlled access area within the 10 boundaries of the Sangamo Plant site. 5.2.1. ARARs to be Waived The primary regulations recommended for waiver are those related to the storage for disposal of TSCA regulated wastes. Since the proposed interim action will involve only storage of these materials, the final fate of which will be treatment and disposal in a manner consistent with all identified ARARs, there is no need to waive any ARARs directly related to treatment or disposal, such as the TSCA regulations governing the disposal of PCB contaminated wastes. The regulations governing the storage for disposal of PCBs and PCB wastes are found at 40 CFR Part 761, Subpart D. The storage regulations are contained in Section 761.65. The storage requirements for PCBs and PCB Items are presented in detail in Sections 761.65(b)(1)(i-v) and 761.65(c). It has been determined that the requirements of Sections 761.65(b)(1)(i-iv) and 761.65(c) should be waived. Section 761.65(b)(1)(i) requires adequate roof and walls to prevent rain water from reaching stored PCBs and PCB Items. Section 761.65(b)(1)(ii) requires an adequate floor with continuous six inch high curbing. Minimum requirements for the volume encompassed by the floor area and height of curbing are also specified. Section 761.65(b)(1)(iii) requires that the curbed area contain no valves, drains joints or other openings that would permit liquids to escape from the curbed area. Section 761.65(b)(1)(iv) requires that floors and curbing be constructed of continuous smooth impervious materials that minimize penetration of PCBs. Section 761.65(b)(1)(v) requires that the storage facility not be located within a 100-year floodplain. Since the potential storage locations at the plant site are all above the 100-year flood elevation, this section need not be waived. Section 761.65(c) allows PCB Items to be stored on a temporary basis without meeting the structural requirements of Section 761.65(b) described above. PCB Items are defined as any PCB Article, PCB Article Container, PCB Container, or PCB Equipment, that contains or has (as) a part of it any PCB or PCBs. This section limits the storage of these PCB Items to no more than thirty (30) days. Since the waste material at the satellite sites contains “off-spec” PCB capacitors, and perhaps other PCB Items, this ARAR will also have to be waived in order for the storage of 11 PCB Items contained in the satellite site materials to exceed thirty days. Waivers of the requirements for a TSCA waste storage facility, which amount in essence to construction of a permanent structure with a roof, walls and carefully constructed floor, are necessary in order to allow the temporary storage of contaminated wastes and soils from the satellite sites. The nature of the remedial action at Sangamo Operable Unit 1 is that it will be a one-time operation, as opposed to a continuing process. Construction of an engineered storage structure for the contaminated soils and waste materials will result in significant delay in the excavation and removal of these materials from the six satellite sites. Appropriate waivers exist (as discussed below) that allow the remedy to proceed without this unnecessary delay. In addition, the temporary measures described above will be implemented in order to minimize migration of contaminants from the temporary storage facility. Region IV TSCA program personnel concur in the recommendation that these waivers be granted. 5.2.2. Basis of Waiver The regulations that comprise the National Contingency Plan (NCP) are found at 40 CFR Part 300. The NCP was published in final form in the Federal Register (FR) Volume 55, No. 46, dated March 8, 1990. In Section 300.430(f)(ii)(C), six criteria are provided under which ARARs for remedial actions can be waived. In addition, guidance as to the applicability of these six criteria is provided in the preamble to the proposed NCP regulations, published in the FR Volume 53, No. 245, dated December 21, 1988. The recommendation that the TSCA storage regulations cited above should be waived is based upon the waiver criteria found in Sections 300.430(f)(ii)(C)(1) and 300.430(f)(ii)(C)(2), which are, respectively, that the proposed action is an interim measure and will become part of a total remedial action that attains all ARARs, and that compliance with the TSCA storage ARARS will result in greater risk to human health and the environment than would result under the proposed action. These two criteria apply to the recommended waiver for all TSCA ARARs cited above. A. Section 300.430(f)(ii)(C)(1); Interim Measures The excavation of contaminated soils and waste materials from the satellite sites and subsequent storage of these materials at the plant site is an interim measure, i.e,. part of an overall remedy that will when completed in its entirety attain all ARARs. The remedy selected in the ROD includes eventual treatment of all contaminated soils and wastes by low temperature thermal desorption (LTTD). The excavated material from the satellite sites will eventually be subjected to LTTD, along with similarly contaminated 12 materials from the Plant site itself. No permanent storage of PCBcontaminated soils or wastes will occur, and no additional storage of such materials will occur once the remedy is complete (i.e., the storage of contaminated materials will be a one-time event, rather than a recurring event). The interim storage will be necessary so that treatability studies, full-scale design and system start-up activities can take place for the implementation of the selected remedy. These measures are in turn necessary so that the Agency can be assured of adequate performance of the selected treatment technology and so that the PRPs can identify and select a suitable technology vendor. This process is expected to take at least two years, and may take as much as three years. Additional delays could result should the selected soil treatment technology (LTTD) prove to be incapable of achieving the performance criteria set forth in the ROD, necessitating a change in the treatment technology, and an amendment to the ROD. The materials excavated from the satellite sites will be stockpiled in areas that are themselves more heavily contaminated than the excavated and stored soils and wastes. These highly contaminated areas on the plant site are likewise slated for excavation and treatment by LTTD, so that stockpiling the satellite site materials on top of the contaminated plant site areas will have no appreciable effect on environmental conditions. Any leachate that may be generated by infiltrating rainfall will be addressed by the ground-water portions of the overall remedy, and sufficient controls will be placed on the stockpile to insure that any stormwater run-on/runoff and wind-blown dispersion will be minimized and kept on-site. The construction of an engineered storage facility that complies fully with the technical criteria set forth in the TSCA regulations does not appear to be warranted for a one-time, relatively short-term stockpiling operation that is an interim component of an overall remedial action. An engineered storage facility at the Sangamo plant site would never be used again for the storage of TSCA-regulated wastes, the purpose for which it would originally be designed. In the preamble to the proposed NCP, a situation analogous to the one at the Sangamo site is presented as an example of an appropriate use of the interim measures waiver: For example, the selected remedy at a site may include excavation and treatment of the source. However, the treatment method may require treatability testing or time for set-up or construction. During this time, an interim measure involving stabilization of the source, such as by use of a cap, may be appropriate. In such a circumstance, the interim measure waiver would allow the temporary stabilization actions 13 to constitute the initial components of a phased remedial response; these actions would not be required to attain landfill closure ARARs because the response would not be complete. (FR Vol. 53, No. 245, for December 21, 1988, p. 51439) This discussion describes essentially the same circumstances as those found at the Sangamo site; the difference is only that at Sangamo the proposal is to use temporary storage, rather than stabilization, as the interim measure, and that the ARARs to be waived are the TSCA storage regulations rather than the RCRA landfill requirements. This example is a clear indication that the use of the interim measures waiver is an appropriate course of action for the proposed remediation at the Sangamo site. Based upon the interim nature of early soil removal from the satellite site, therefore, a waiver of TSCA storage ARARs is included as part of this ESD. b. Section 300.430(f)(ii)(C)(2); Greater Risk to Health and the Environment. The contaminated soils and materials at the six satellite sites comprising a portion of the overall Sangamo Operable Unit 1 Site are currently in an entirely uncontrolled setting. With the exception of the Breazeale site, there are no engineered controls in place to limit the migration of contaminants from the satellite disposal sites into environmental media, such as ground waters, surface waters, subsurface soils, etc. There is also essentially no control over access to the disposal sites, except that exercised by the individual landowners. The PRP, Schlumberger Industries, Inc., does not own the properties on which the satellite sites are located, and therefore cannot exercise such control over public access to the six satellite sites as they can to the contaminated areas on the Plant site itself. EPA has not required SII to provide access control over the satellite sites because the contamination at the surface of each site does not pose an unacceptable level of risk to occasional occupants or trespassers on the sites. (Please refer to the Baseline Risk Assessment in the Remedial Investigation report for further discussion and to the results of metals analyses discussed above.) The primary source materials, i.e., the PCB-contaminated wastes and soils, are in the subsurface, and persons who might be on-site for short periods of time are not exposed to this highly contaminated PCB source material. This does disturbed treatment possible not insure, however, that the satellite sites may not be at some time between the present and the time when the system will become operational. Should this occur, it is that the highly contaminated subsurface materials will 14 become exposed, creating a situation where greater risks to public health would result. It should also be recognized that, even though the risks posed by the satellite sites via contact with surface soils are not currently outside the acceptable risk range, some risk due to incidental contact is present. Persons who come into contact with the surface soils under the present conditions will be subjected to an increased incremental risk. Even though this risk may be minimal, some finite increase in risk to public health exists under site conditions. Rapid and early removal of the satellite site materials to the controlled environment of the plant site will eliminate these risks. In addition, releases of contaminants from the satellite sites into the environment will continue to occur during the interim between the present and whenever the satellite site soils and waste materials are removed. These releases consist of runoff of contaminated soils into nearby streams, leaching of contaminants into ground waters, and uptake of site contaminants into biological systems (eg., bioaccumulation and/or biomagnification). The sooner that the contamination in the satellite sites is placed into a controlled environment at the plant site, the sooner these releases will cease to occur. Expedited removal of the contaminated materials from the satellite sites will not only limit or minimize the mass of contaminants released into the environment, but will also render the other site-related remedial actions, such as ground-water remediation at some of the satellite sites, more efficient and cost-effective. Obviously, then, any delays in removing the satellite site materials from their present, exposed state to the proposed storage location at the plant site will result in increased exposure of the public to site contaminants and continued and ongoing releases of contaminants into various environmental media and biological systems. Full compliance with the TSCA storage ARARs cited above will require a lengthy process of design, contracting and construction of an engineered storage facility. This process conceivably could take two to three years, whereas if these ARARs are waived, excavation and transport of the satellite site materials could be accomplished as early as late summer, 1993. While it is not possible to quantify the reduction of risk that might be achieved without knowing the delay that would result from full compliance with these ARARs, and while it is reasonable to assume that this risk reduction would be minor in absolute terms, it is clear that greater risk to health and the environment will occur the longer that the satellite sites remain in their current status. Release of contaminants will continue while the materials are stockpiled in temporary storage locations at the plant site, but control measures will be implemented to minimize and control these releases. Release to ground waters will be controlled by overall ground-water remedial actions mandated in the ROD for the plant 15 site disposal areas. Run-on and runoff controls will be implemented for the stockpile. All potential public exposure to contaminated soils and wastes will be eliminated by placing the materials in a controlled access area, within the bounds of the Sangamo industrial facility at the Plant site. By these means, both releases and exposure are reduced and/or eliminated, reducing risks to human health and the environment. Therefore, based on the increased risks to human health and the environment that will result from the delays incurred from full compliance with TSCA storage ARARs, this ESD includes a waiver of those storage requirements as ARARs for the remedial action. 6.0 Support Agency Comments South Carolina Department of Health and Environmental Control (SCDHEC) has reviewed this ESD and concurs in its contents. 7.0 Statutory Determinations The modifications made to the ROD by this ESD are designed to determine a remedy at the Site that will be protective of human health and the environment, and will comply with Federal and State requirements that are either applicable or relevant and appropriate, or alternatively to provide waivers of those requirements in accordance with the provisions of the NCP. This ESD fulfills EPA’s commitment made in the ESD dated September 10, 1991, to determine if any additional criteria for metals are necessary, and to choose any additional remedial technologies for metals as appropriate, based upon the results of the additional sampling and analysis program described in that ESD. EPA has determined that the completed additional sampling and analysis program indicate that such additional criteria and technologies are unnecessary to protect human health and the environment at this Site. A 30-day public comment period will be included as part of this ESD, and a responsiveness summary prepared for any comments received during that period. Any comments on this ESD should be submitted in writing to one of the following persons: Cynthia Peurifoy, Community Relations Coordinator SC Section, North Superfund Remedial Branch U.S. Environmental Protection Agency, Region IV 345 Courtland Street, NE Atlanta, Georgia 30365 or, 16 R. Bernie Hayes, Remedial Project Manager SC Section, North Superfund Remedial Branch U.S. Environmental Protection Agency, Region IV 345 Courtland Street, NE Atlanta, Georgia 30365 SANGAMO WESTON, INC./TWELVE-MILE CREEK/LAKE HARTWELL PCB CONTAMINATION Site Information: Address: SANGAMO WESTON, INC./TWELVE-MILE CREEK/LAKE HARTWELL PCB CONTAMINATION PICKENS, SC EPA ID: EPA Region: SCD003354412 04 Site Name: Site Alias Name(s): SANGAMO/TWELVE-MILE/HARTWELL PCB SANGAMO WESTON-PICKENS PLANT HAYWOOD RESERVOIR MIDWAY LANDFILL CROSS ROADS CHURCH BREZEAL PROPERTY WELLBORN PROPERTY MAW BRIDGE ROAD NIX, ERNEST PROPERTY SANGAMO ELECTRIC SANGAMO PROPERTY SANGAMO WESTON/TWELVE-MILE/HARTWELL PCB Record of Decision (ROD): ROD Date: Operable Unit: ROD ID: 06/28/1994 02 EPA/ROD/R04-94/178 Media: soil, water, aquatic biota Contaminant: PCBs Abstract: Please note that the text in this document summarizes the Record of Decision for the purposes of facilitating searching and retrieving key text on the ROD. It is not the officially approved abstract drafted by the EPA Regional offices. Once EPA Headquarters receives the official abstract, this text will be replaced. The 730-acre Sangamo Weston/Twelve Mile Creek/Lake Hartwell site is located in Pickens County, South Carolina. The site is zoned for industrial use and is currently owned by Schlumberger Industries, Inc. (as a result of a 1989 merger with Sangama Weston.) The site was used for capacitor manufacturing from 1955 to the present. The plant used a variety of dielectric fluids in its manufacturing processes, including ones containing PCBs. Waste disposal practices included land-burial of off-specification capacitors and wastewater treatment sludge on the plant site and at six satellite disposal areas. PCBs were also discharged with effluent directly into Town Creek, which is a tributary of Twelve-Mile Creek. Twelve Mile Creek is a major tributary of Lake Hartwell. Between 1955 and 1977, approximately 400,000 lb. of PCBs were discharged into Town Creek. An unspecified amount was also buried in six off site disposal areas. The use of PCBs was terminated in 1977. South Carolina Dept. of Health and Environmental Control (SCHECD) studied the site in 1976 and found widespread PCB contamination. A health advisory was issued in 1976 that warned against eating fish in the Seneca River Arm of Lake Hartwell and in Twelve Mile Creek. The site was proposed for inclusion in the NPL in 1987 and finalized in February 1990. EPA lead the RI/FS activities that were initiated in September 1990. The site was divided into two OUs; OU 1 covering soil and OU2 covering the surface water, sediment and bioaccumulation. The Final FS report was released in April 1994. This ROD addresses OU2 which discusses PCB contamination in sediment and aquatic biota. The objective of the remedy is to reduce risks associated with exposure to contaminated fish. Institutional controls will be the primary remedy at this site. Remedy: The selected remedial action for this site includes continuing the existing fish consumption advisory; implementing public education programs; continuing monitoring of aquatic biota and sediment; and regulation of Twelve Mile Creek Impoundments to facilitate burial of contaminated sediment. Text: Full-text ROD document follows on next page. EPA/ROD/R04-94/178 1994 EPA Superfund Record of Decision: SANGAMO WESTON, INC./TWELVE-MILE CREEK/LAKE HARTWELL PCB CONTAMINATION EPA ID: SCD003354412 OU 02 PICKENS, SC 06/28/1994 Text: FINAL RECORD OF DECISION for the Sangamo Weston/Twelvemile Creek/Lake Hartwell PCB Contamination Superfund Site - Operable Unit Two Pickens, Pickens County, South Carolina June 1994 Record of Decision Declaration SITE NAME AND LOCATION Sangamo Weston/Twelvemile Creek/Lake Hartwell PCB Contamination Superfund Site - Operable Unit Two Pickens, Pickens County, South Carolina STATEMENT OF BASIS AND PURPOSE This decision document presents the selected remedial action for the Sangamo Weston/Twelvemile Creek/Lake Hartwell PCB Contamination Superfund Site - Operable Unit Two ("Sangamo OU2") in Pickens County, South Carolina, which was chosen in accordance with CERCLA, as amended by SARA, and, to the extent practicable, the National Contingency Plan. This decision is based on the Administrative Record for the Site. The State of South Carolina concurs with the selected remedy. ASSESSMENT OF THE SITE Actual or threatened releases of hazardous substances from this Site, if not addressed by implementing the response action selected in this ROD, may present an imminent and substantial endangerment to public health, welfare, or the environment. DESCRIPTION OF THE REMEDY This Operable Unit is the final action of two Operable Units for the Site. Operable Unit One addressed the land-based source areas which included the Sangamo Weston Plant and six satellite disposal areas. This action, Operable Unit Two, addresses the sediment, surface water, and biological migration pathways downstream from the source areas. This action addresses the primary PCB human exposure pathway by mitigating the consumption of PCB contaminated fish harvested from Lake Hartwell. This major components of the selected remedy include: Continuation of the existing fish consumption advisory on Lake Hartwell; Public education program designed to increase awareness of advisory and methods to prepare/cook fish to reduce quantity of contaminants consumed; Continued monitoring of aquatic biota and sediment to support continuance and/or justify modifications to existing fish advisory; and Regulation of Twelvemile Creek Impoundments that will facilitate burial of contaminated sediment while mitigating adverse impacts to Lake Hartwell water quality. STATUTORY DETERMINATIONS The selected remedy is protective of human health and the environment, complies with federal and state requirements that are legally applicable or relevant and appropriate to the remedial action, and is cost-effective. This remedy utilizes permanent solutions and alternative treatment technologies to the maximun extent practicable. This remedy does not satisfy the preference for treatment as a principal element based upon the excessive costs associated with removal, treatment and disposal of approximately 4.7 million cubic yards of PCB contaminated sediment spread out over approximately 730 acres. Because this remedy will result in hazardous substances remaining onsite above health-based levels, a review will be conducted no less often than every five years after commencement of remedial action to ensure that the remedy continues to provide adequate protection of human health and the environment. _________________________ John H. Hankinson, Jr. Regional Administrator EPA - Region IV ___________ Date TABLE OF CONTENTS SECTION PAGE 1.0 Site Name, Location, and Description.......................1 2.0 Site History and Enforcement Activities....................1 3.0 Highlights of Community Participation......................6 4.0 Scope and Role of Response Action..........................7 5.0 Summary of Site Characteristics............................8 5.1 Summary of Physical Characteristics...................8 5.1.1 Surface Features............................8 5.1.2 Surface Water Hydrology....................10 5.1.2.1 Surface Water Hydrology of Twelvemile Creek Watershed............................11 5.1.2.2 Surface Water Hydrology of Lake Hartwell...13 5.1.3 Meteorology................................14 5.1.4 Demographics...............................15 5.2 Sediment Investigation Summary.......................16 5.2.1 Phase I Investigation......................17 5.2.2 Phase II Investigation.....................18 5.2.3 Field Screening-Modified Spittler Method...18 5.2.4 Nature and Extent of Contamination.........19 5.2.5 Other Contaminants in Sediment.............24 5.2.6 Summary of Surface Water Investigations....28 5.3 Biological Investigation Summary.....................28 5.3.1 Twelvemile Creek Watershed Investigations..29 5.3.2 Lake Hartwell Investigations...............33 5.3.3 Assessment of Resource Use.................38 5.4 Contaminant Fate and Transport.......................40 5.4.1 Future Sedimentation.......................40 5.4.2 Future Sediment and Water Quality Trends...43 5.4.3 Bioaccumulation and Future Fish Concentrations.............................48 6.0 Summary of Site Risks.....................................50 6.1 Contaminants of Concern..............................50 6.2 Exposure Assessment..................................51 6.3 Toxicity Assessment..................................52 6.3.1 Carcinogenic Toxicity of PCBs..............52 6.3.2 Noncarcinogenic Toxicity of PCBs...........53 6.4 Risk Characterization................................53 6.5 Monte Carlo..........................................54 6.6 Ecological Risk Assessment...........................55 6.7 Uncertainty Assessment...............................56 6.8 Summary..............................................56 7.0 Description of Alternatives...............................66 7.1 Final Cleanup Goal for Sediment......................67 7.2 Final Cleanup Goal for Fish..........................68 7.3 Remedial Alternatives................................70 SECTION 8.0 PAGE Summary of the Comparative Analysis of Alternatives.......82 8.1 Overall Protection of Human Health and the Environmental....................................82 8.2 Compliance with ARARs................................83 8.3 Long-Term Effectiveness and Permanence...............84 8.4 Reduction of Toxicity, Mobility, and Volume..........85 8.5 Short-Term Effectiveness.............................86 8.6 Implementability.....................................88 8.7 Cost.................................................88 9.0 The Selected Remedy.......................................89 9.1 Continuation of Existing Health Advisory.............89 9.2 Public Education Program.............................89 9.3 Aquatic Biota and Sediment Monitoring................92 9.3.1 Aquatic Biota Monitoring...................92 9.3.2 Sediment Monitoring........................94 9.4 Regulation of Twelvemile Creek Impoundments..........94 9.5 Five-Year Reviews....................................99 9.6 Cost Estimate........................................99 10.0 Statutory Determinations.................................100 10.1 Protection of Human Health and the Environment......100 10.2 Compliance with ARARS...............................101 10.3 Cost Effectiveness..................................101 10.4 Utilization of Permanent Solutions and Alternative Treatment Technologies to the Maximum Extent Practicable.........................................101 10.5 Preference for Treatment as a Principal Element.....102 11.0 Documentation of Significant Changes.....................102 Appendix - Proposed Plan Fact Sheet LIST OF TABLES TABLE/TITLE PAGE 5-1 Monthly Mean Temperature and Precipitation for Clemson and Pickens, SC...................................15 6-1 PCB Exposure Point Concentrations in Shallow Sediment.....57 6-2 Exposure Point Concentrations in Fish.....................58 6-3 Exposure Parameters for Incidental Ingestion of and Dermal Contact with Sediment (Current/Future Use Scenario).......60 6-4 Exposure Parameters for Ingestion of Fish by Adult Recreational Fisherman (Current/Future Use Scenario)......61 6-5 Potential Direct Contact Risks Associated with PCBs in Sediment...............................................62 6-6 Potential Health Risks Associated with Ingestion of Fish..64 8-1 Time to Achieve Protectiveness............................87 9-1 Sediment Sample Locations in Twelvemile Creek Watershed and Arm of Lake Hartwell..................................98 9-2 Cost Estimate for EPA's Selected Remedy..................100 LIST OF FIGURES FIGURE/TITLE PAGE 1-1 Hartwell Lake and Watershed................................2 1-2 Sangamo OU2 Study Area.....................................3 2-1 Estimate of PCBs Received at the Sangamo Weston Plant......4 2-2 Estimate of PCBs Discharged Into Town Creek................5 5-1 Twelvemile Creek Drainage Basin............................9 5-2 Twelvemile Creek Profile..................................12 5-3 PCB Distribution for Grab Samples.........................25 5-4 Vertical Distribution of Mean PCB Concentration per Transect Interval.........................................26 5-5 Vertical Distribution of Maximum PCB Concentration per Transect Interval.........................................27 5-6 Twelvemile Creek Drainage Sampling Locations..............30 5-7 Lake Hartwell Fish Sampling Stations......................34 5-8 PCB Concentrations in Largemouth Bass Fillets (1990-93)...36 5-9 PCB Concentrations in Channel Catfish (1990-93)...........36 5-10 PCB Concentrations in Hybrid Bass Fillets (1990-93).......37 5-11 Simulated Bed Profile Twelvemile Creek Arm................41 5-12 Predicted Average Sediment Burial Rates...................42 5-13 Initial WASP4 Surface Sediment PCB Concentrations.........44 5-14 WASP4 Surface Sediment PCB Concentrations at 10 Years.....45 5-15 WASP4 Surface Sediment PCB Concentrations at 20 Years.....46 5-16 WASP4 Surface Sediment PCB Concentrations at 30 Years.....47 5-17 Initial and Predicted Concentrations of Selected Biota....49 7-1 FGETS Modeling Results for Selected PCB-Cleanup Goals.....69 7-2 Area to be Capped in Alternative 3A.......................74 7-3 Sediment Control Structure Location of Alternative 3B.....76 FIGURE/TITLE PAGE 7-4 Sediment Control Structure/Axea to be Capped for Alternative 3C............................................78 7-5 Confined Disposal Facility for Alternative 4..............80 9-1 Current Lake Hartwell Fish Advisory.......................90 9-2 Fish Sampling Stations in Lake Hartwell...................93 9-3 Corbicula Basket Sampling Locations in Twelvemile Creek...95 9-4 Sediment Sampling Stations in Lake Hartwell...............96 9-5 Sediment Sampling Stations in Twelvemile Creek............97 Final ROD-Sangamo OU2 June 1994 1.0 SITE NAME, LOCATION, AND DESCRIPTION The Sangamo Weston/Twelvemile Creek/Lake Hartwell Polychlorinated Biphenyl (PCB) Contamination Site - Operable Unit Two (hereinafter referred to as "the Sangamo OU2 site" ) is located in Pickens County, South Carolina. The Sangamo OU2 Site comprises the sediment, surface water, and biological migration routes downstream from the Sangamo Weston Plant and satellite disposal areas that have site related PCB-contamination. The Sangamo Weston Plant and satellite disposal areas constitute Operable Unit one of the Site. Lake Hartwell was constructed by the Savannah District U.S. Army Corps of Engineers (COE) between 1955 and 1963 by damming the Savannah, Seneca, and Tugaloo Rivers. Figure 1-1 provides an illustration of the 56,000 acre Hartwell Reservoir located on the Georgia-South Carolina border. The OU2 study area includes approximately 40 stream miles of Twelvemile Creek and its tributaries, the Twelvemile Creek Arm of Lake Hartwell, and portions of the Keowee and Seneca River Arms of Lake Hartwell down to the Route 37 (Rt. 37) bridge just south of Clemson, South Carolina. Figure 1-2 provides an illustration of the Sangamo OU2 study area. The primary focus of OU2 is centered on this area; however, samples were collected throughout Lake Hartwell during the OU2 investigations including that portion of the reservoir between Rt. 37 and Hartwell Dam. 2.0 SITE BISToRY AND ENPoRCEMENT ACTIVITIES Sangamo Weston, Inc., owned and operated a capacitor manufacturing plant in Pickens, South Carolina from 1955 to 1978, near the headwaters of Lake Hartwell. The plant manufactured several varieties of capacitors, including electrolytic, mica, and power factor capacitors as well as potentiometers. Schlumberger Industries, Inc. (SII) is the current owner of the plant site, as a result of a merger with Sangamo Weston in 1989. The plant used several varieties of dielectric fluids in its manufacturing processes, including PCB-containing dielectric fluids. PCBs reportedly enhanced the performance and durability of the fluids. The PCBs used for this application were primarily Aroclors 1242, 1254, and 1016. Waste disposal practices from the Sangamo Plant included land-burial of off-specification capacitors and wastewater treatment sludges on the plant site and at the six satellite disposal areas. PCBs were also discharged with effluent directly into Town Creek, which is a tributary of Twelvemile Creek. Twelvemile Creek is a major tributary of Lake Hartwell. The use of PCBs was terminated by Sangamo Weston in 1977 prior to an EPA ban on PCB use in January 1978. Estimates of the type and quantities of PCBs received, used, and discharged by Sangamo Weston were derived by reviewing Monsanto Corporation shipping records, Sangamo Weston records, interviews with Sangamo Weston employees, engineering and analytical reports completed by firms under contract to Sangamo Weston, and EPA documents. Figures 2-1 and 2-2 provide a graphical illustration of the PCBs received at the Sangamo Plant and an estimate of PCBs discharged to Town Creek, respectively. <IMG SRC 0494178> <IMG SRC 0494178A> <IMG SRC 0494178B> Final ROD-Sangamo OU2 June 1994 The average quantity of PCBs used by Sangamo Weston ranged from 700,000 to 2,000,000 lbs/yr from 1958 to 1977. Data indicate that an estimated 3 percent of the quantities received and used were discharged to Town Creek. This approach leads to an estimated cumulative discharge of PCBs into Town Creek of over 400,000 lbs through 1977. Historical surficial and core sediment studies of the Twelvemile Creek watershed and Lake Hartwell were conducted by several entities including the South Carolina Department of Health and Environmental Control (SCDHEC), COE, EPA, RMT (for Schlumberger), and several Clemson graduate students. These studies were initiated in 1976 by SCDHEC and occurred intermittently through the mid to late 1980s. PCB concentrations in surficial sediments were highest from samples collected near the plant's discharge point on Town Creek and generally decreased with increasing distance downstream from the Sangamo Weston Plant Site. PCB concentrations in sediment core samples were highest in samples collected from the Twelvemile Creek Arm of Lake Hartwell. PCB concentrations generally increased to maximum at a depth of 10-30 cm. In the mid-1970s, SCDHEC and EPA discovered that fish from certain areas of Lake Hartwell were contaminated with PCBs at levels above the U.S. Food and Drug Administration (FDA) safe tolerance limit of 5 ppm (5 mg/kg). SCDHEC originally issued a health advisory in 1976 that warned the public against eating fish from the Seneca River Arm of Lake Hartwell north of State Highway 24 (Hwy 24) and Twelvemile Creek (Figure 1-1). FDA lowered the PCB tolerance level to 2 ppm (2 mg/kg) in 1984. As a result, SCDHEC modified the original health advisory in 1985 to state the following: 1) All fish taken from the Seneca River Arm of Lake Hartwell north of SC Hwy 24 and Twelvemile Creek should be released and not eaten; 2) All fish larger than three (3) lbs. taken from the remainder of Lake Hartwell should be released and not eaten; and 3) Fishing is not prohibited but SCDHEC advises that these fish not be eaten due to the presence of elevated levels of PCBs. Swimming, boating, and other related activities are not restricted by this advisory. This advisory remains in effect, and signs warning against eating fish have been posted at the majority of the public boat launch and recreation areas in South Carolina since 1987. SCDHEC has conducted studies in Lake Hartwell since 1976 to evaluate the levels of PCB contamination in fish. Their results indicate that PCB concentrations in non-migratory fish (i.e largemouth bass, catfish) collected within the Twelvemile Creek embayment remain above the FDA 2 mg/kg tolerance level with no apparent decrease over time. PCB concentrations in these nonmigratory species generally decreased with increasing distance from the source area. However, migratory species (i.e. Final ROD-Sangamo OU2 June 1994 hybrid/striped bass) collected at all stations in the lake had elevated levels of PCBs which frequently exceeded the 2 mg/kg tolerance level. There was no apparent decrease in migratory fish tissue PCB concentrations over time. In 1987, based upon the EPA Hazard Ranking System, SCDHEC monitoring programs, and accompanying concerns of citizens in the area, the Sangamo Site was proposed for inclusion on the National Priorities List (NPL). The Sangamo Site was finalized on the NPL in February 1990. As a result, EPA issued special notice to SII in April 1990 for performance of a Remedial Investigation and Feasibility Study (RI/FS). Since SII declined to conduct the RI/FS, EPA assumed the lead-role in performing the RI/FS at the Sangamo OU2 Site and formally initiated the process in September 1990. The RI/FS process for OU2 was divided into two separate studies, a Sediment Investigation and Biological Investigation, which were conducted concurrently. The Sediment Investigation was conducted by the Oak Ridge, TN office of Bechtel Environmental under the funding and direction of EPA. The Biological Investigation was conducted by the Savannah District of the U.S. Army COE, under funding and direction provided by EPA. 3.0 HIGHLIGHTS OF COMMUNITY PARTICIPATION EPA held an OU2 RI Kick-Off Public Meeting at the Liberty (South Carolina) Senior High School Cafeteria on May 9, 1991 to present the approach for the Phase I Sediment RI and overall Biological Investigation strategy. On March 3, 1992, a public meeting was held at the Ramada Inn in Clemson, SC to discuss the Phase I Sediment Investigation results, planned approach for the focused Phase II Sediment Investigation, and provide an update on the Biological Investigations. The Final Remedial Investigation Reports (Sediment and Biological components) and a summary fact sheet were released to the public in May 1993. A public meeting was held on June 3, 1993 at the Ramada Inn in Clemson to present the findings from the completed investigations and the Baseline Risk Assessment. The Draft Feasibility Study Report and a summary fact sheet were released to the public in February 1994 in an effort to facilitate greater public involvement in the remedy selection process at the Sangamo OU2 Site. On March 28, 1994, a public forum was held at the Strom Thurmond Institute on the Clemson University Campus to discuss the various remedial alternatives under consideration in the Draft FS Report. The Final FS Report, Proposed Plan Fact Sheet, and all other site-specific documents EPA relied upon to develop the Proposed Plan were arranged in an Administrative Record and released to the public in April 1994. The Administrative Record was maintained and available for public review at the EPA Records Center in Region IV, and the following five information repositories: The Village Library in Pickens, SC; Pickens County Public Library in Easley, SC; R.M. Cooper Library at Clemson University, SC; Hart County Library in Hartwell, GA; and the Final ROD-Sangamo OU2 June 1994 Corps of Engineers Lake Hartwell Natural Resources Management Center near the Dam in Hartwell, GA. Concurrent with the public release of the Proposed Plan, a notice of availability of the Administrative Record was published in the Greenville News and Anderson Independent on April 11, 1994; the Athens Daily, Easley Progress, Hartwell Sun, and Pickens Sentinel on April 13, 1994; and the Clemson Messenger Journal Tribune on April 16, 1994. A public comment period was held from April 11 through May 11, 1994. A Proposed Plan Public Meeting was held on April 19, 1994 at the Ramada Inn in Clemson, SC. At this meeting, representatives from EPA, the Savannah District COE, and SCDHEC discussed the site conditions, the remedial alternatives under consideration and presented the rationale behind the preferred alternative. During this meeting, a request for an extension to the public comment period was made. As a result, the public comment period was extended until June 10, 1994. The notice of this extended public comment period was published in the Greenville News on May 2, 1994. A response to comments received during this 60-day public comment period is included in the Responsiveness Summary, which is attached to this Record of Decision (ROD) as Appendix B. This decision document presents the selected remedial action for the Sangamo OU2 Site in Pickens County, South Carolina, chosen in accordance with CERCLA, as amended by SARA, and in accordance with the National Contingency Plan. The decision for this Site is based on materials in the Administrative Record and comments received during the public comment period. 4.0 SCOPE AND ROLE OF RESPONSE ACTION Due to the size and complexity of the Sangamo Site, and in order to simplify the investigation and response activities, EPA divided the Site into two discrete study areas known as Operable Units (OUs). Operable Unit One (OU1) consists of the land-based source areas, including the Sangamo Weston Plant Site and six satellite disposal areas in Pickens County used for the disposal of solid wastes containing PCBs (Figure 1-2). The six satellite disposal areas are located in rural areas within a 3-mile radius of Pickens and have the following designations: Breazeale, Cross Roads, Dodgens, John Trotter, Nix and Welborn. EPA selected the remedy for OU1 in a ROD signed on December 19, 1990. Under a Consent Decree negotiated with EPA, Schlumberger initiated remedial action at OU1 in November 1993. This included the excavation of waste and PCB contaminated soils from the six satellite disposal areas and transportation of the excavated materials to temporary storage facilities at the former Sangamo Plant Site. A treatment system will be built and tested at the plant at which time the contaminated material will be treated by means of low temperature thermal desorption. In addition, groundwater recovery and treatment systems will be installed at the plant site and at applicable satellite areas. Operable Unit Two (OU2), the subject of this ROD, addresses the PCB-contamination in the sediments and aquatic biota of the study area (Figure 1-2). The exposures associated with ingestion Final ROD-Sangamo OU2 June 1994 of fish contaminated with PCBs from all fish sampling stations in Lake Hartwell exceeded EPA`s acceptable human health risk range. OU2 represents the final response action EPA expects to implement as part of its overall strategy in remediating the Sangamo Site. This response action addresses the principal threat posed at the Site which is ingestion of PCB-contaminated fish. 5.0 SUMMARY OF SITE CHARACTERISTICS Due to the atypical size and complexity of the Sangamo OU2 Site, the Sediment and Biological Investigations generated an immense and extensive data base. In the interest of brevity, this information will not be reiterated in this ROD. This section presents a brief, comprehensive overview of the Sangamo OU2 Site characteristics as assessed during the Remedial Investigation. The reader is referred to the Final Remedial Investigation Report (May 1993), Volumes I and II and/or the Final Biological Investigation Report (February 1994) for a more detailed account of this subject matter. 5.1 SUMMARY OF PHYSICAL CHARACTERISTICS This section presents information concerning the physical characteristics of the study area including its surface features, surface water hydrology, meteorology, and demographics. 5.1.1 Surface Features The Sangamo OU2 study area generally consists of sloping to moderately steep uplands that are dissected by a well-developed drainage system. There are a number of small towns in the area in addition to the city of Clemson. Outside of the towns and the residential developments along the Hartwell lakeshore, the countryside is predominantly rural. Much of the undeveloped area is forested, but significant agricultural tracts can also be found. The northern portion of the Twelvemile Creek watershed is in the foothills of the Blue Ridge Mountains, an area characterized by steep, heavily forested slopes and ridges. Twelvemile Creek originates near 1,920-ft-high Walnut Cove Mountain, in an isolated area approximately 7 miles north-northeast of Pickens, which includes first- and second-order streams with abundant riffles (Figure 5-1). The relief is somewhat lower in the vicinity of Pickens and the OU1 source areas. In this portion of the watershed, Twelvemile Creek occurs as a meandering, relatively slow-moving, fourth-order stream with abundant pools, sand and gravel bars, and broad floodplains that in some reaches exceed 1,000 ft. However, approximately 1 mile south of Pickens, the stream valley narrows and the creek has a large number of sharp bends. In this area, Twelvemile Creek resembles a mountain stream with exposed rocks, swift-moving water, and abundant riffles that in some locations may be considered rapids. Floodplains are generally absent as the creek valley narrows to widths of only 100 to 200 <IMG SRC 0494178C> Final ROD-Sangamo OU2 June 1994 ft., bounded by moderate to steep slopes that are generally covered with trees and other vegetation. Access to the creek is difficult and generally limited to the few bridges in the area. These conditions continue downstream (south) to the headwaters of Hartwell Lake, just upstream of the Maw Bridge (Hwy 337 Bridge). The Twelvemile Creek Arm of Lake Hartwell is characterized by a narrow channel with steep, heavily vegetated shoreline with only limited access. The waters in the upper portion of this arm have been impounded and thus water velocities are greatly reduced. There is a sharp bend in the lake near the Madden Bridge, but otherwise the channel has a linear, northeastsouthwest trend. The lake becomes progressively wider downstream, reflecting the widening of the former Twelvemile Creek floodplain, and the number and size of inlet coves increases. The lakeshore along the Twelvemile Creek Arm is generally undeveloped due to the relief and development restrictions imposed by the COE, which has classified much of the western shoreline and the major inlet coves on the eastern shoreline as a Protected Lakeshore Area. This designation does not necessarily prohibit all development, but has served to greatly limit the type and extent of development within this portion of the lake. In the downstream direction, past the Keowee River confluence, into the Seneca River Arm and finally into Lake Hartwell proper, the shoreline typically becomes more gradually sloped and is more developed with less vegetative cover than the shoreline of the Twelvemile Creek Arm. Relief around the main portion of the lake is much lower, primarily due to the pool elevation, which becomes progressively closer to the hilltops toward the south. Lake Hartwell was formed by the construction of Hartwell Dam across the Savannah River approximately 7 miles below the point where the Tugaloo and Seneca rivers converge to form the Savannah River. Construction of the dam began in 1955 and was completed in 1963. The dam is a concrete and earth structure that spans 18,000 ft across the Savannah River and rises 204 ft above the riverbed at its highest point. At normal pool level, Hartwell Lake extends for 49 miles up the Tugaloo River and 45 miles up the Seneca River and its tributaries (i.e., Twelvemile Creek and the Keowee River). At a normal pool elevation of 660 ft. mean sea level (MSL), the lake has an area of 56,000 acres and large expanses of open water, particularly below the point where Twenty-six Mile Creek meets the Seneca River. Because of the relief and large number of coves, the lake has a shoreline of 962 miles. There are a number of large arms in the main portion of the lake. The major ones include the Tugaloo Arm, Twenty-six Mile Creek Arm, Coneross Creek Arm, and Eighteen Mile Creek arm. 5.1.2 Surface Water Hydrology The Sangamo OU2 study area is defined by hydrologic features; therefore, the surface water hydrology is one of the Final ROD-Sangamo OU2 June 1994 most important physical characteristics of the study area. This section presents an overview of the hydrologic characteristics of the Twelvemile Creek watershed and Lake Hartwell, which are the principal hydrologic units in the study area. 5.1.2.1 Surface Water Hydrology of Twelvemile Creek Watershed The Twelvemile Creek watershed has an area of 140-miý and includes first-, second-, third- and fourth-order streams. The tributaries to Twelvemile Creek are predominantly first- and second-order streams. The major tributaries, Town Creek, Wolf Creek, Rices Creek, and Golden Creek, are third-order streams. Twelvemile Creek is a third order stream above the mouth of Town Creek; below this point, Twelvemile Creek is a fourth-order stream. Twelvemile Creek is the longest stream segment in the watershed, which flows southward for approximately 24 miles until reaching the headwaters of Hartwell Lake. Within this 24-mile reach, approximately 80 tributaries flow into Twelvemile Creek. The gradient of the Twelvemile Creek basin is represented by the longitudinal profile shown in Figure 5-2. The profile extends from the confluence of the Middle and North forks into Hartwell Lake as far as the Rt. 37 Bridge (the downstream limit of the study area in Hartwell Lake). From this figure, it can be seen that the total elevation drop from the confluence of the North and Middle forks to the headwaters of the lake is approximately 200 ft, which over a distance of 17 miles amounts to an average slope of 11.8 ft per mile. The bulk of the stream flow is derived from runoff. Flow data for Twelvemile Creek indicate an average daily flow of 198 cubic feet per second (cfs), with historical daily flow ranging from 30 to 5360 cfs. Sediment in the creek is composed primarily of sand and has a generally low total organic carbon content (TOC), ranging from 0.1 to 3.6 percent. NPDES permit data indicate that Twelvemile Creek receives discharges from sewage treatment plants and a small number of industrial facilities. These discharges average 1 to 2 million gallons per day. During low flow periods, the permitted discharges may comprise 10-13 percent of the flow in the creek; during normal flows, the discharges comprise less than 2 percent of the flow and become negligible during high flow periods. The three impoundments on the lower section of Twelvemile Creek are all of masonry construction. The lowermost impoundment (Woodside II) is the largest of the three, with an upper pool elevation of 722 ft MSL and a lower pool elevation of 684 ft MSL (difference of 38 ft). This impoundment was built in 1905. The middle impoundment (Woodside I) is located in the community of Cateechee and was rebuilt in 1937 after it failed in 1934. The middle impoundment has an upper pool elevation of 760 ft MSL and a lower pool elevation of 736 ft MSL (difference of 24 ft). Both the lower and middle impoundments were constructed by Norris Mills and are currently owned and operated by Consolidated Hydro of Greenville, South Carolina. These two impoundments were renovated in 1983-1985 and currently produce a combined 2.5 million kWh/yr. In 1984, up to 20 ft of sediments were <IMG SRC 0494178D> Final ROD-Sangamo OU2 June 1994 flushed from the pools behind the lower and middle impoundments. In September 1993, an estimated 43,000 cubic yards of sediment were flushed from behind the lowermost impoundment. Currently, sediments are flushed from these pools approximately biannually. The third, or uppermost, impoundment was built in 1926 and is the smallest of the three impoundments, with an upper pool elevation of 783 ft MSL and a lower pool elevation of 763 ft MSL (difference of 20 ft). This upper impoundment was formerly used for generation of hydroelectric power. The impoundment was purchased by the Easley-Central Water District in 1962 and is currently used as the intake point for the Easley-Central Water Plant. Sediments are flushed from behind the upper impoundment quarterly. Approximately 6 ft of sediments are flushed from behind the impoundment during each flushing event. Surface water in the Twelvemile Creek basin is currently utilized for drinking water supply, fishing, and industrial uses. Twelvemile Creek is classified as a Class B stream according to South Carolina Regulations (Regulation 61-68, Water Classifications and Standards). Under the regulations, Class B waters are defined as being suitable for secondary-contact recreation (fishing, boating, wading) and drinking water supply (assuming conventional treatment methods are used) as well as both agricultural and industrial uses. 5.1.2.2 Surface Water Hydrology of Lake Hartwell The surface water hydrology of the Hartwell Lake reservoir is different from that described for the Twelvemile Creek basin because it is an impoundment with a drainage basin 2,088 miý. Hartwell Lake is managed by the COE for flood control and electric power generation, both of which are affected by the storage capacity of the reservoir, which is 2,550,000 acre-feet of water (equivalent to 830 billion gallons). Since its construction, the reservoir has become one of the major recreational lakes in the Southeast. Current management practices therefore consider recreational benefits as well as flood control and power generation. The COE maintains a pool elevation of 660 ft MSL during the recreation season (summer); in mid-October through mid-December the lake level is dropped 4 ft to a level of 656 ft MSL. The lake is drawn down in the fall in anticipation of the increased rainfall that the area usually receives during the winter and spring. The annual fluctuations in the lake commonly exceed 4 ft; peak elevations commonly occur in April or May. The lowest recorded monthly average lake level of 643.3 ft MSL occurred in December 1981. Water flows in the Lake Hartwell system were characterized by the inflow and outflow data provided by the COE. These data consist of 30 years of daily inflow and outflow data collected between 1962 and 1992. The average monthly inflow to the lake for the period 1962-1992 ranged from a low of 2,693 cfs in September to a high of 6,222 cfs in March. Average monthly outflow from Hartwell Dam in the same period ranged from a low of Final ROD-Sangamo OU2 June 1994 3,034 cfs in September to a high of 5,190 cfs in April. On a yearly basis, the average monthly inflow to Hartwell Lake has been 4,090 cfs; outflow has been 3,997 cfs. Given the reported storage capacity of the reservoir (2,550,000 acre-feet or 830 billion gallons), the estimated hydraulic residence time in the lake is 25 days. Lake Hartwell is Class A surface water (South Carolina regulations) suitable for primary contact recreation (swimming, waterskiing), secondary contact recreation (fishing, boating, wading), drinking water supply, and agricultural/industrial uses. The lake currently receives a significant level of point and nonpoint source discharges. NPDES-permitted discharges include industrial facilities, electric power generating stations, and various sewage treatment plants. The permitted industrial discharges include heavy metals, volatile organic compounds, cyanide, phenol, oil and grease, and textile dyes. Permitted discharges comprise only 18 million gallons per day (approximately 200 cfs). Since the reservoir continues to be a source of potable water for a number of communities, these discharges apparently have not had an appreciable impact on water quality in the lake. 5.1.3 Meteorology Pickens County has a temperate climate characterized by mild winters and relatively abundant rainfall. The National Weather Service has two precipitation and temperature gauging stations in the Twelvemile Creek area, one at Pickens and the other at Clemson. Table 5-1 summarizes the monthly mean temperature and precipitation for these two locations. Generally the mean monthly temperature is higher in the summer and winter months in Clemson while in the spring and fall it is higher in Pickens. The average monthly precipitation for the Pickens and Clemson stations ranges between 3.5 in. and 6.1 in. Annual precipitation in both Clemson and Pickens is more or less evenly distributed throughout the year. The average annual precipitation for Pickens from 1951-1992 was 56.04 in. The maximum and minimum annual rainfall events occurred 1964 and 1981, respectively, when 78.46 in. and 33.40 in. were recorded. In Clemson, the average annual precipitation from 1911-1992 was 53.23 in. The maximum and minimum annual rainfall events occurred in 1936 and 1925, respectively, when 73.36 and 34.31 in. of precipitation were recorded. Free water surface evaporation data was obtained for the study area from the Evaporation Atlas for the Contiguous 48 United States (NOAA 1982). These data indicate that annual evaporation from Hartwell Lake should be in the range of 40 to 41 in. With annual precipitation in the area greater than 53 in., Hartwell Lake receives 12 to 13 in. of net precipitation per year. Final ROD-Sangamo OU2 June 1994 TABLE 5-1 Monthly Mean Temperature and Precipitation for Clemson and Pickens, South Carolina1 Month Clemson, SCý Temp. (øF) Precipitation (inches) Pickens, SC3 Temp. (øF) Precipitation (inches) January 42.8 5.01 42.0 5.14 February 45.4 5.01 45.3 5.12 March 51.9 5.65 52.5 6.07 April 60.6 4.31 61.2 4.53 May 68.4 4.12 68.3 4.60 June 75.7 3.95 74.7 4.53 July 78.4 4.86 77.8 4.76 August 77.6 4.57 77.1 4.40 1 2 3 September 72.7 3.54 71.8 3.64 October 61.8 3.68 62.0 4.05 November 51.6 3.49 52.4 4.02 December 44.2 4.98 44.2 4.91 Data Source: National Climatic Data Center Reporting Period 1911-1992 Reporting Period 1951-1992 5.1.4 Demographics Demographics and land use in the Hartwell Lake area are variable, with small towns and rural residential development in the Twelvemile Creek watershed giving way to larger towns and more concentrated development in the areas surrounding Hartwell Lake. According to 1990 census data, approximately 356,000 people live in the six counties that border Hartwell Lake: Anderson, Pickens, and Oconee counties in South Carolina; and Hart, Franklin, and Stephens counties in Georgia. Of this total, an estimated 297,000 people live in the South Carolina counties; 93,894 live in Pickens County alone. The major community in the upper portion of the Twelvemile Creek watershed is Pickens, which had an estimated population of 3,042 in 1990. Two communities are located along Twelvemile Creek: Cateechee (estimated 1990 population of 158) and Norris (estimated 1990 population of 884). The town of Clemson, with an estimated 1990 population of 11,096, is the only large community directly on the shoreline of the lake. Outside of the small towns and communities, the majority of the Twelvemile Creek Final ROD-Sangamo OU2 June 1994 watershed (and Pickens County in general) is undeveloped. Most of the acreage bordering Twelvemile Creek and its tributaries is either forested or cleared for agricultural purposes. The entire Hartwell project, both land and water usage, is managed by the COE Savannah District. Hartwell Dam was constructed by the COE as part of a flood control and hydroelectric power project. In addition to these primary uses, Hartwell Lake has developed into one of the largest and most popular recreational lakes in the southeastern U.S. According to a 1989 COE survey, more than 15 million people visited the lake, making it one of the three most visited COE lakes in the nation. Data from a recreational area on Twelvemile Creek indicates that, out of a total of 301,000 visitors, 125,787 visits were made for fishing, 76,892 for boating, 30,310 for water skiing, and 28,139 for swimming. Development along the shoreline of Lake Hartwell is at least partially controlled through the COE Lakeshore Management Plan (COE 1989). The COE controls 23,566 acres above the normal pool elevation of 660 ft MSL. The COE acreage in effect establishes a buffer zone of variable width around the entire shoreline. This buffer zone enables the COE to restrict access, development, and the types of activities permitted. These restrictions are effected through a system of permits and land use allocations as established in the Shoreline Management Plan. In order to administer the permit program, the shoreline of Hartwell Lake was allocated into four categories: Limited Development Areas, Public Recreation Areas, Protected Shoreline Areas, and Prohibited Access Areas. Surface water supplies the bulk of potable water utilized by the residents of Pickens County and surrounding areas. Currently there are two active water intakes on Twelvemile Creek; these intakes provide potable water supply to the Pickens Water Plant and Easley-Central Water Plant. The Pickens Water Plant intake point is located near the confluence of the Middle and north Forks of Twelvemile Creek. Withdrawals from this intake enable the Pickens Plant to supply 2 to 2.5 mgd of potable water to approximately 4,000 residents in the Pickens area. The intake for the Easley-Central Water Plant is located in the uppermost of the three impoundments on Twelvemile Creek. According to the Easley-Central Water Plant, withdrawals from this intake supply an average of 1.2 mgd of potable water to approximately 1,100 residents in the plant's service area. 5.2 SEDIMENT INVESTIGATION SUMMARY Field investigation activities for the sediment component of the Sangamo OU2 RI were conducted in two seasonal sampling events. The initial, Phase I event was conducted during July and August 1991. The objectives of Phase I were to verify extent-of-contamination data from previous investigations and further characterize the magnitude and distribution of PCB contamination in the Twelvemile Creek watershed and Hartwell Lake. Results of Phase I sampling were used to define a focused Final ROD-Sangamo OU2 June 1994 sampling program for the second, Phase II sampling event. Phase II was conducted during April and May 1992. The objective of Phase II was to address specific data gaps regarding the extent of PCB contamination in sediments of the upper Hartwell Lake reservoir (i.e., Seneca River, Keowee River, and Twelvemile Creek Arms) and the Twelvemile Creek watershed. 5.2.1 Phase I Investigation Phase I field sampling encompassed an area extending some 50 miles, from the Sangamo Weston Plant site and the satellite disposal areas to the Hartwell Dam. A total of 480 samples, exclusive of quality assurance/quality control (QA/QC) samples, were collected during Phase I from Twelvemile Creek, its tributaries, and Hartwell Lake. Phase I samples included 88 surface water, 341 sediment core, and 51 sediment grab samples, at 50 locations throughout Lake Hartwell. An onsite field screening method, the Modified Spittler Method (See Section 5.2.3), and offsite Contract Laboratory Program (CLP) laboratories were used to analyze the samples. A stainless steel ponar grab sampler was used for collecting the surface sediment sample. The depth of sample collected by the grab sampler was approximately 10 to 15 cm. A representative sample from this surface zone was important to adequately characterize the horizontal contamination in the biologically active zone and to determine the quality of sediment that was recently deposited. All 51 grab samples were analyzed by CLP laboratories. Four of these samples were selected for fullscreen Target Compound List (TCL)/Target Analyte List (TCL) analyses. Offsite analyses were also conducted for grain size, TOC, and cation exchange capacity, all which are factors that affect the mobility of PCBs and other contaminants. Sediment core samples were recovered to a maximum depth of 50 cm to characterize the vertical distribution of PCBs in the sediment. In shallow water areas, core samples were collected by driving a stainless steel core tube into the sediment by hand. In deep-water areas, a gravity corer with a stainless steel liner and core catcher was used to collect the subsurface sample. In both cases, sediment was extruded from the top of the core tube at 5-cm intervals and placed in jars marked according to the depth interval. All core samples were analyzed for total PCBs. Split samples were collected from 19 percent of the sediment cores analyzed onsite and sent for offsite PCB analyses at a CLP laboratory. This was done to determine the correlation between field and laboratory analytical results. Surface water samples were collected at all 50 locations. A near-surface water sample was collected at all stations by dipping the mouth of the sample container just beneath the surface of the water. Where water depths exceeded 4 to 6 ft, a near-bottom sample was collected approximately 1 ft above the sediment interface using a peristaltic pump and teflon tubing. All 88 water samples were analyzed for PCBs and TOC at offsite CLP laboratories. Samples from 4 stations received full scan TCL/TAL analyses. Selected surface water samples were also Final ROD-Sangamo OU2 June 1994 analyzed for the following water quality parameters: total dissolved solids (TDS), total suspended solids (TSS), chloride, flouride, sulfate, and nitrate-nitrite. Given the large number of samples collected on the open water of Hartwell Lake, the technical impracticality of conducting an accurate location survey utilizing traditional survey methods, and the importance of precise sample locations in determining the nature and extent of contamination in OU2, sample location coordinates (latitude/longitude) were determined utilizing a hand-held Magellan Global Positioning System (GPS). GPS is a network of 24 satellites orbiting the earth at an altitude of 10,900 miles. The satellites and the hand-held receivers both generate a continuous code which allows the receiver to calculate how long it takes the signal to travel from the satellite, and then to extrapolate the satellites's distance. Once the hand-held receiver gets position information from three satellites, position coordinates are determined by triangulation. 5.2.2 Phase II Investigation During the Phase II study, a more extensive sampling program was conducted in areas determined during the Phase I study to have the highest PCB concentrations. The Phase II field sampling effort focused on the Keowee River, Seneca River and Twelvemile Creek Arms of Hartwell Lake as well as Twelvemile Creek itself. Not including QA/QC samples, 744 samples consisting of 185 surface sediment, 550 sediment core, and 9 storm-event surface water samples were collected and analyzed by field screening and CLP analytical methods. Sample collection and location techniques were as described under Section 5.2.1. Twenty transects with a maximum of five sediment coring stations per transect were established across the lake and creek bed. The sediment core stations along each transect were selected following a review of the bottom depth profile collected with a bathymetric profiler. Sediment grab samples were then collected between each transect location. Sediment was sampled from a total of 374 locations during the Phase II study. Composite surface water samples were collected from the following bridges, which cross Twelvemile Creek and the upper reaches of the Hartwell Lake reservoir: the Maw Bridge (Rt. 337), Madden Bridge (Rt. 15), Hwy 133 Bridge, Hwy 93 Bridge, and Rt. 37 Bridge. Samples were collected from these stations following two significant storm events to evaluate the potential for resuspension of PCBs into the water column. 5.2.3 Field Screening - Modified Spittler Method Both phases of the Sediment Investigation utilized the Modified Spittler Method, a field screening analytical technique, to significantly reduce cost and turnaround time on analyses. Reduced turnaround time (approximately 24 hours) enabled sampling teams to identify locations where additional sampling was warranted and to evaluate data quality on a real time basis. Final ROD-Sangamo OU2 June 1994 The Modified Spittler Method is an EPA-approved field screening technique for quantifying total PCB concentrations in a sediment/soil matrix. The technique employs a gas chromatogram (GC) with an electron capture detector (ECD), and has demonstrated reliability in the quantification of PCB concentrations in excess of 1 ppm (mg/kg). The primary difference in time and cost between the CLP procedure and Spittler Method is incurred in the extraction procedure. Using commonly available laboratory equipment, one analyst can extract 10 to 20 samples in less than 2 hours. The cost of GC/ECD analysis using the Spittler Method is between $50 and $100, compared to approximately $300 for conventional CLP analysis. A total of 122 samples were analyzed for PCBs by both the modified Spittler and CLP methods during Phase I and II. A statistical comparison of the 67 Phase II samples analyzed by both CLP and Spittler was performed by the EPA Environmental Monitoring Systems Laboratory (EMSL) in Las Vegas, Nevada. Twenty-eight of these samples were reported as "non-detect" by both analytical methods. Of the remaining 39 samples, PCB concentrations reported by Spittler were greater than those reported by CLP for 35 samples, 3 samples analyzed by Spittler were less than the concentration reported by CLP, and 1 sample was not detected by Spittler, but was detected by CLP (i.e. false negative). In general, PCBs results obtained by field screening were conservative. Ninety percent of the results were higher than those obtained by the CLP method, and only one false negative was reported. Only one result was an order of magnitude greater than the CLP laboratory result. Although correlation coefficients were low, the data sets were generally in agreement when the factors affecting comparability are taken into consideration. The major reasons for poor statistical correlation in results were attributed to nonhomogeneity of the split samples and the differences in PCB quantitation. Based upon this comparison, the Modified Spittler Method was found to detect PCBs as well as the CLP laboratory. It was concluded that the Spittler Method produces data of Data Quality objective (DQO) Level II/III when compared to DQO Level IV for CLP analyses. However, the level of data quality generated by this field screening technique allowed EPA to cost effectively determine the nature and extent of PCB contamination in a study area that encompassed approximately 40 stream miles and over 1,000 acres of open water. 5.2.4 Nature and Extent of PCB Contaminated Sediment Previous investigations and the Sangamo OU2 RI have delineated in detail the distribution and magnitude of PCB contamination in sediment within the study area. Most of the contaminated sediment lies within the upper portion of Hartwell Lake, specifically the Twelvemile Creek Arm and Seneca River Arm opposite the city of Clemson. Within the Twelvemile Creek watershed, minor levels of PCB contamination have persisted in Town Creek near the Sangamo Weston plant site and in the Final ROD-Sangamo OU2 June 1994 impoundments associated with the 3 small dams on Twelvemile Creek. Within Hartwell Lake, localized accumulations of contaminated sediment have been detected as far downstream as the dam, with concentrations generally decreasing with increasing distance downstream from the Twelvemile Creek Arm. Concentrations have been decreasing since the mid-1980's, reflecting a decline in PCB input to the lake as well as the burial and/or dilution of previously deposited sediment through mixing with clean sediment. A summary of the significant findings regarding PCB contamination in sediment for eight subsections of the study area is presented below. The sediment investigation results are also graphically illustrated on Figures 5-3, 5-4, 5-5 at the end of this section. Bridges and landmarks used in the description of the study area subsections can be found on these figures or Figure 5-1 and 1-2. Upper Twelvemile Creek Watershed - This section includes segments of the principal tributaries of Twelvemile Creek that collect drainage or other discharges from the Sangamo Weston Plant Site and the six satellite disposal areas. This section also includes Hagood Reservoir and tributary reaches associated with the Midway Dump and Easley-Pickens Landfill. Sampling conducted for the RI and previous investigations supports the following conclusions: Sediment contamination in Twelvemile Creek was limited to isolated occurrences between the mouth of Town Creek and the upper (Easley-Central) impoundment; PCB concentrations were typically <1 mg/kg. PCB-contaminated sediments remain in Town Creek downstream of the Sangamo Weston outfall; RI data show concentrations as high as 6.5 mg/kg. The OU1 satellite disposal areas represent insignificant sources of PCB contamination based on the results of sediment sampling from locations downstream of these areas. Town Creek was confirmed as the only tributary contributing PCBs to Twelvemile Creek, further substantiating earlier conclusions that the Sangamo Weston Plant Site has been the principal source of PCB contamination released into the Twelvemile Creek watershed and Twelvemile Creek Arm of Hartwell Lake. Lower Twelvemile Creek Waterahed - This section includes the three small impoundments and the lower reach of Twelvemile Creek to the Lay Bridge (just south of the lowermost impoundment). Sampling in the impounded waters and in close proximity downstream of the 3 small dams in the lower reaches of Twelvemile Creek indicate low levels of PCB contamination have persisted and/or continue to accumulate in this area. Specific conclusions include the following: Final ROD-Sangamo OU2 June 1994 The upper impoundment had the lowest levels of PCB contamination among the 3 impoundments; concentrations were typically below detection limits or <0.5 mg/kg. The middle (Woodside I) impoundment had only low levels of PCB contamination (<1 mg/kg), most of which was detected in core intervals below 10 cm. More highly contaminated sediment has accumulated in the lower (Woodside II) impoundment; most samples had <1 mg/kg but concentrations ranged up to 6 mg/kg in core samples. All 3 of the impoundments are flushed on a periodic basis to remove sediment and the slightly contaminated sediment detected in these impoundments will eventually be released into the Twelvemile Creek Arm of Lake Hartwell. Upper Twelvemile Creek Arm - This section begins at the Lay Bridge and extends south, in a downstream direction, to Madden Bridge (Route 15 Bridge). Historical and RI data indicate that potentially significant quantities of PCB-contaminated sediment have accumulated in the upper portion of the Twelvemile Creek Arm of Hartwell Lake, particularly in the open water section immediately above the Madden Bridge. Specific conclusions include: The most significant accumulations of PCB-contaminated sediment coincided with depositional areas for fine-grained materials; in the upper arm, these areas typically occurred in proximity to the shoreline or in coves. The uppermost portion of the arm, in the vicinity of Maw Bridge, has only minor levels of contamination (1-2 mg/kg) due to the higher water velocities and limited sedimentation. The open water area upstream of the Madden Bridge represents the principal site for deposition of contaminated sediment in the Twelvemile Creek arm; concentrations have ranged as high as 153 mg/kg in historical samples and to a maximum of 61 mg/kg in the RI samples. The magnitude of PCB contamination in the upper arm has declined significantly since the mid-1980's, reflecting the decreased input of PCBs to the lake and, in the open water area, burial of the more highly contaminated sediment through deposition of several feet of sediment with much lower levels of contamination. This burial is consistent with results from the HEC-6 sediment transport modeling discussed in Section 5.4. The vertical extent of contamination in the open water area was not defined. Given that the source of PCB contamination predated the impoundment of the creek and that releases continued for many years thereafter, contaminated sediment probably extends down to the original elevation of the land surface (and former channel). Final ROD-Sangamo OU2 June 1994 Middle Twelvemile Creek Arm - This section begins at Madden Bridge and extends south to the Hwy 133 Bridge. A variable distribution of low to moderate levels of contamination was identified, with higher concentrations generally limited to depositional areas having finer-grained sediment. Specific conclusions include: Sediment PCB concentrations in the middle portion of the arm have varied over time, but since 1985 have consistently been greater than 1 mg/kg and in most cases greater than 3 mg/kg. RI data show surface sediments contaminated with 1-3 mg/kg of PCBs and slightly higher concentrations in deeper sediment from core samples. The more highly contaminated sediment was encountered in samples from depositional areas such as Moore Bend and the open water area upstream of the Highway 133 Bridge. PCB concentrations in samples collected from depositional areas show a downward trend since 1988, indicating decreased input of PCBs into the lake and that more highly contaminated sediments have either been buried, resuspended and transported away, or diluted through mixing with cleaner sediments. Alternating sequences of vertically increasing or decreasing contamination observed in the majority of sediment cores from the Twelvemile Creek arm complicate the interpretation of the vertical extent of contamination. This vertical extent was not defined in the middle segment of the arm. Lower Twelvomile Creek Arm - This section begins at the Hwy 133 Bridge and extends south to the U.S. Hwy 123 Bridge adjacent to Clemson. The lower portion of the Twelvemile Creek arm has also been a depositional area for contaminated sediment, as evidenced by the widespread PCB contamination in this area. A summary of the major findings include: RI data show PCB concentrations in surface sediments generally in the range of 1-2 mg/kg; higher concentrations were detected in core samples, with maximums in the 18-21 mg/kg range. Concentrations generally decreased with increasing distance downstream but localized accumulations of more highly contaminated material were identified. The vertical limits of contamination generally occurred in the upper 30-40 cm of sediment in most of the historical and RI sediment cores. The more highly contaminated sediment in the lower arm was usually detected in samples collected from within or in close proximity to the former submerged channel of Twelvemile Creek. A decline in sediment PCB concentrations was observed at the mouth of Twelvemile Creek, reflecting the influence of the Final ROD-Sangamo OU2 June 1994 Keowee River arm, which has a much higher average flow than Twelvemile Creek. PCB concentrations in the shallow sediment (0-15 cm) of the lower arm have declined significantly, reflecting the decreased input of PCBs and/or that the more highly contaminated sediment detected in previous investigations is getting buried by or diluted through mixing with cleaner sediment. The persistence of relatively high levels in deeper sediment (down to 40 cm) supports conclusions based on the HEC-6 modeling that only limited amounts of sedimentation occur in the lower portion of the Twelvemile Creek arm. Keowee Arm - The Keowee Arm is a branch of Lake Hartwell that meets the Twelvemile Creek Arm just north of Clemson. Historical data and the Phase I/Phase II sampling results from the Keowee River Arm indicate the following: RI data have shown generally low levels of contamination (<2 mg/kg) in the lower part of the Keowee arm, most likely related to hydrodynamic interactions with the Twelvemile Creek or Seneca River arms. Historical data included higher levels of contamination (6-7 mg/kg) in core samples collected from locations farther upstream in the Keowee arm, possibly indicating an additional PCB source in the upstream portion of the Keowee arm. This contamination is probably not related to the Twelvemile Creek source because of its occurrence several miles upstream in the Keowee arm and because flow in the Keowee is several times greater than flow in Twelvemile Creek. Data were insufficient to characterize the magnitude or determine the location of this source. Seneca River Arm/Upper Section of Hartwell Lake - This section begins at the Hwy 123 Bridge and extends south to the Route (Rt) 37 Bridge. PCBs were detected throughout this area as concluded below: Surficial sediments had contamination in the range of 1-2 mg/kg everywhere except the excavated channel opposite the Clemson University diversion structures. Deeper contamination was encountered in the former Seneca River channel and the open water area just upstream from the Highway 37/Southern Railroad embankment. Deposition of more highly contaminated sediment near the Highway 37 embankment was attributed to the hydrodynamic influences associated with the constriction of the channel at this location. Residual PCB contamination likely exists in the former Seneca River channel located on the western edge of the Clemson University campus, behind the diversion structures. Final ROD-Sangamo OU2 June 1994 The vertical extent of contamination was defined and generally limited to depths of 20-40 cm. A good correlation between the depth of contamination in cores collected in 1988 and for the RI (in 1991-1992) indicate that only limited sedimentation has occurred in this portion of the lake during this 3 to 4-year period. Maximum PCB concentrations in sediment core samples declined from levels of 16 to 18 mg/kg in 1988 to concentrations of 5 to 11 mg/kg in 1991/1992; explanations for the decline, if predicted low sedimentation rates are accurate, include spatial variability in the distribution of contamination and continued mixing of the vertical sediment profile. Lake Hartwell Proper - This section includes the remainder of Lake Hartwell, beginning at the Rt 37 Bridge and extending south to the Hartwell dam. Historical sampling in this area indicate that PCB contamination has migrated as far downstream as the Hartwell dam. This was not confirmed during the RI. The occurrence and magnitude of PCB contamination in Lake Hartwell declined significantly downstream of the confluence of the Seneca River Arm and Twenty-six Mile Creek, reflecting the input of significant quantities of uncontaminated sediment from Twenty-six Mile Creek and the various other tributaries. The majority of widespread contamination in the lower part of the lake was limited to concentrations below 1 mg/kg. 5.2.5 Other Contaminants in Sediment A limited number of sediment grab and core samples were collected for full-screen TCL/TAL analyses. No significant contaminants other than PCBs were detected in these analyses. Specific conclusions include: No volatile organic contaminants were detected in any of the samples other than an estimated concentration of acetone (2200J æg/kg) in one duplicate sample. A number of semivolatile organic compounds were detected in one of the samples, mostly in low, estimate concentrations that were not indicative of significant contamination. Several unidentified semivolatile organic compounds were reported in sediments at 4 sampling stations, ranging in concentration from 2 mg/kg to 200 mg/kg. These compounds were most likely petroleum hydrocarbons related to urban run-off or boating discharges of fuel and oil. Several pesticide compounds (DDE, DDD, and DDT) were also detected, in low, estimated concentrations of 0.0024 to 0.053 mg/kg. Metals analyses did not identify any sediment with elevated concentrations of heavy metals; the following metals were not detected: antimony, arsenic, cadmium, mercury, selenium, and thorium. <IMG SRC 0494178E> <IMG SRC 0494178F> <IMG SRC 0494178G> Final ROD-Sangamo OU2 June 1994 5.2.6 Summary of Surface Water Investigations Surface water quality investigations have focused on the presence of PCBs in waters downstream of the Sangamo Weston Plant Site, the OU1 offsite disposal areas, and/or the Midway dump and Easley-Pickens landfill. Relevant conclusions from these historical investigations and the RI studies include: The most frequent and highest levels of PCB contamination (1.7-20.3 æg/l) were detected in surface water samples collected from locations downstream of the Sangamo Weston outfall on Town Creek. PCBs were either not detected or present in concentrations <1 æg/l in surface water samples collected from drainage ditches and tributaries associated with the OU1 offsite disposal areas (Breazeale, Cross Roads, Dodgens, Trotter, and Welborn disposal areas). These areas are apparently not releasing appreciable levels of contamination to Twelvemile Creek or its tributaries. Based upon NPDES data, PCB concentrations in discharge from the Sangamo Weston wastewater treatment plant outfall on Town Creek during the mid-1970's averaged 13 æg/l and ranged as high as 235 æg/l; NPDES monitoring data from this outfall for 1992 reported PCB concentrations in the range 0.4 to 40.3 æg/l. This continued release of PCBs to Town Creek and the downstream portions of OU2 are expected to terminate once the OU1 remedial action at the Sangamo Weston plant site has been completed. PCBs were not detected in any of the surface water samples collected for Phase I of the RI; detection limits for these unfiltered samples ranged from 1.2 to 1.3 æg/l. A limited number of these RI samples were also analyzed for full TCL analyses; no volatile organics, extractable organic compounds, pesticides or cyanide were detected, and inorganic (metals) concentrations were not indicative of contamination. PCBs were not detected in any of the storm event samples collected for Phase II of the RI; detection limits for these unfiltered samples ranged from 1.2 to 1.3 æg/l. 5.3 BIOLOGICAL INVESTIGATION SUMMARY Field activities for the Biological Investigations were conducted by the COE in the Spring 1991, 1992, and 1993. The field activities were divided into two individual study areas; the Twelvemile Creek watershed and Lake Hartwell. The specific methods employed and results from these two investigations are summarized in the following sections. The information gathered from the Biological Investigations conducted in the Twelvemile Creek watershed further support the Final ROD-Sangamo OU2 June 1994 conclusions made in the sediment component of the RI that: 1) the Sangamo Plant Site is the primary source of PCB contamination in Twelvemile Creek; and 2) the contribution of PCB contamination in the Twelvemile Creek watershed from the six satellite disposal areas is negligible. The aquatic biota in Twelvemile Creek appear to have suffered from the influence of man's activities. Although PCBs have likely contributed to these perturbations producing cumulative effects, other factors have no doubt had an additional impact on these animals at the population and community levels. Fish in Lake Hartwell continue to be contaminated with PCBs often at levels that exceed the FDA safe tolerance limit of 2 mg/kg. PCBs appear to be the only pollutant of concern in Lake Hartwell fish. The highest concentrations of PCBs in fish are located in the Twelvemile Creek Arm. PCB concentrations in fish species that are generally non-migratory decrease both downstream and farther from the Twelvemile Creek Arm. Migratory fish species have PCB concentrations that are similar throughout the reservoir and are high enough to be a concern. PCBs were detected at all levels of the food chain in both the Twelvemile Creek watershed and Lake Hartwell. Pathways for PCB uptake in aquatic biota of Lake Hartwell include ingestion through the food chain and contact, most likely through the gills. Exposure results from PCBs being adsorbed to sediments and transported down Twelvemile Creek into Lake Hartwell. The health of fish in Lake Hartwell does not appear to be affected at the population level for fish that have PCB concentrations at the current levels (around 5 mg/kg). However, there is evidence that as concentrations increase to greater than 20 mg/kg fish health can be affected. Largemouth bass was the target species used during these investigations. The sensitivity or tolerance of other fish species to PCB contamination is not known. 5.3.1 Twelvemile Creek Watershed Investigations Field investigations in the Twelvemile Creek watershed were conducted during Spring 1992 to: 1) determine the concentration of PCBs in one primary sport fish species and one bottom feeding species; 2) assess the condition of the fish community by determining the Index of Biotic Integrity (IBI); 3) assess the condition of the macroinvertebrate community by using Benthic Rapid Bioassessment techniques; 4) assess fish health of redbreast sunfish by using bioindicators and the Health Assessment Index (HAI); 5) assess composition and fate of harvest to determine public utilization by using a creel survey; and 6) determine on-going PCB contamination due to transport of drifting organic matter and bioaccumulation by a sediment dwelling, filter feeding organism, the freshwater clam (Corbicula fluminea). Twelve sampling stations were established in Twelvemile Creek and three uncontaminated tributaries. These sample stations are shown in Figure 5-6. The length of each station was <IMG SRC 0494178H> Final ROD-Sangamo OU2 June 1994 from 0.3 to 0.5 miles to encompass gross habitat types and ensure adequate sample size. Stations were permanently marked with "Carsonite" markers located in the creek bank at the upper and lower boundaries. All 12 stations were not involved in each subelement of the overall investigation (i.e. PCB tissue analysis, IBI, HAI). Twenty fish were collected for PCB contaminant analysis from each of the stations in the Twelvemile Creek watershed and one tributary reference site. Redbreast sunfish (Lepomis auritus) were used as a sport fish species for assessment of human health and environmental risk. Redbreast sunfish were chosen based on abundance and likelihood of use by anglers. Ten redbreast were collected per site. Ten northern hogsauckers (Hypentelium nigricans) were collected per site to determine PCB concentrations in a bottom feeding species to assess environmental risk. Northern hogsuckers were selected based on abundance and tropic level. Largemouth bass and bluegill were substituted for redbreast sunfish at three stations. Concentrations of PCBs in fish collected in the Twelvemile Creek watershed were highest in Town Creek and Twelve Mile Creek. Four of the 12 stations sampled had PCB values exceeding 2.0 mg/kg. Three of these stations (5, 8, and 12) were downstream from the Sangamo Plant Site. Station 4, the other station having high PCB values, was located just upstream from the confluence of Town Creek and Twelvemile Creek and was probably affected by fish migrating from both creeks. Stations upstream from station 4 could not be affected by migration due to a low head dam located at the upper boundary of station 4. Mean PCB concentrations ranged from a high of 12.5 mg/kg for northern hogsuckers in Town Creek to a low of 0.88 mg/kg in redbreast sunfish in Twelvemile Creek for stations downstream from the Sangamo Plant Site. The remaining stations located in tributary streams or upstream from the Sangamo Plant Site had lower PCB concentrations in fish than those located downgradient from the plant site. Several non-diagnostic studies which employed a metric/index system were conducted to assess the health or condition of individuals, populations and/or communities in the Twelvemile Creek watershed. The benthic macroinvertebrate community of Twelvemile Creek watershed was evaluated using EPA's rapid bioassessment protocols. Samples were collected at a reference site and the remaining sites shown on Figure 5-6. Eight of the nine stations sampled in the Twelvemile Creek drainage were classified as moderately impaired. Station 11, located upstream of the Sangamo Plant site on Town Creek, was classified as non-impaired and had high values for taxa richness and exhibited an abundance of intolerant taxa. Sites immediately downstream of the Sangamo facility exhibited evidence of greater impairment than did upstream or tributary sites. The Index of Biotic Integrity (IBI) was used to assess the general health of the fish community in the Twelvemile Creek watershed. The IBI index is based on a set of metrics determined from species composition and abundance for a fish community. These metrics focus on basic ecological characteristics of the Final ROD-Sangamo OU2 June 1994 fish fauna and have been used effectively in stream monitoring programs for the past decade. Nine stations in the Twelvemile Creek watershed and three reference sites were sampled. The IBI was effective for ranking the reference sites as expected based on no identifiable impacts at station 1 (IBI 40), known impacts of agricultural runoff at station 2 (IBI 30), and a known point source discharge at station 3 (IBI 12). Therefore, it appeared appropriate to use the IBI to assess the relative health of fish populations in the Twelvemile Creek watershed with confidence. The IBI scores indicated that all stations sampled have been impaired to some degree. Most stations throughout the watershed were classified as either "fair" or "good" indicating moderate negative effects on the fish communities that could have resulted from habitat degradation from man's activities. Only the two reference stations 2 and 3 that were identified as having known impacts and station 5, located in Twelve Mile Creek downstream from Town Creek, were classified as "poor" or "very poor." The IBI classification at station 5 ("poor") and a comparison of relative health between sample stations and reference stations indicated that station 5 has been severely impacted. Both habitat degradation and water quality impacts including PCB contamination likely contributed to this adverse impact. Both the macroinvertebrate and fish communities have been impaired throughout the Twelvemile Creek watershed. Assumably, these impairments have resulted from PCB discharges, habitat degradation, particularly siltation due to erosion from development, siviculture and agriculture, and poor water quality from both point and non-point discharges throughout the watershed. The Health Assessment Index (HAI) was employed to assess the health of redbreast sunfish at selected stations in the Twelvemile Creek drainage and a reference site. HAI is an autopsy based index that uses divergence from the normal of various organs, tissues and blood parameters to evaluate fish health. The HAI scores for redbreast sunfish were variable throughout the watershed ranging from 39.3 to 62.7. Station 12 located in Town Creek immediately downstream from the Sangamo site had the lowest HAI score, 39.3, indicating healthy fish at this site. It is not evident from evaluating the HAI scores that the health of redbreast sunfish has been effected by PCB contamination. HAI scores were variable throughout the drainage. However, scores in the range seen during this investigation were not considered high. It is likely that health problems that would manifest themselves to visual inspection through autopsy do not occur in fish contaminated at the lower PCB concentrations seen in redbreast sunfish in the Twelvemile Creek drainage. Drift net samples were used to collect detritus (floating organic matter) in Town Creek downstream of the Sangamo site and in Twelvemile Creek at Lay Bridge. Additionally, cages of "clean" Corbicula fluminea (fresh water clams) were placed at Final ROD-Sangamo OU2 June 1994 these sites for 28 days to determine rates of bioaccumulation of PCBs by analyzing the muscle tissue. Drift net samples of coarse particulate matter collected from Town Creek, immediately downstream of the Sangamo Plant Site had detectable PCB concentrations ranging from 0.066 to 0.51 mg/kg. PCB concentrations in corbicula collected at this station ranged from 0.75 to 0.88 mg/kg. Corbicula collected from the station immediately downstream of the Lay Bridge had PCB concentrations that ranged from 0.45 to 0.57 mg/kg. From these results, it can be concluded, that even though PCBs have not been detected in water samples collected from the study area, transport of PCBs down Town Creek and Twelvemile Creek is occurring. 5.3.2 Lake Hartwell Investigations Studies in Lake Hartwell were conducted during Spring 1991, 1992, and 1993 to: 1) determine the concentration of PCBs in primary sport and forage fish species; 2) assess fish health of largemouth bass using bioindicators and HAI; 3) determine PCB concentrations in seston and macroinvertebrates; and 4) assess composition and fate of harvest to determine public utilization using a creel survey. Fish species selected for Lake Hartwell contaminant analysis included: 1) sport and/or commercial species, 2) fishes that seasonally occupy different habitats or exhibit seasonal migrations, and 3) primary forage species. Species selected for collection and analysis were: largemouth bass, hybrid bass, channel catfish, threadfin shad (Dorosoma petenense), gizzard shad (Dorosoma cepedianum), blueback herring (Alosa aestivalis), and bluegill (Lepomis macrochirus). A total of 134, 144, and 144 fish were collected from six locations throughout Lake Hartwell during spring 1991, 1992, and 1993, respectively. These six stations are illustrated on Figure 5-7 and were selected to represent a gradient of PCB contamination in fish ranging from the most impacted (SV-107 in the Twelvemile Creek embayment) to a background location (SV-641) in the Tugaloo Arm. These fish were analyzed for PCB concentrations in standard U.S. FDA fillets with skin on, descaled with rib cage (except for catfish where the skin was removed). Additionally, the 60 largemouth bass collected in 1991 were analyzed for priority pollutants. Composite samples of forage fish, including bluegill, threadfin shad, gizzard shad, and blueback herring, were collected from SV-107 (highly impacted), SV-532 (intermediate zone), and SV-641 (background). PCB concentrations in fish have historically been highest in the Twelvemile Creek Arm of Lake Hartwell (SV-107) and decrease in a downstream direction. This is expected since PCBs enter Lake Hartwell bound to sediments that are transported down Twelvemile Creek, as discussed in Section 5.2 of this ROD. Results of PCB analyses collected from 1990-1993 for largemouth bass, channel catfish, and hybrid bass are graphically illustrated on Figures 5-8, 5-9, and 5-10, respectively. These years were comparable since analyses were completed in the same manner. Although 4 years of data may be insufficient to justify <IMG SRC 0494178I> Final ROD-Sangamo OU2 June 1994 meaningful trend analysis, PCB levels decreased significantly in largemouth bass at SV-107 (Figure 5-8). This trend was not significant at other stations. As in past samples, PCB levels in largemouth bass decreased in a downstream direction. PCB concentrations in channel catfish have also decreased at stations farther from the source in Twelvemile Creek (Figure 5-9). However, there has been little change in the PCB concentrations in channel catfish over the past 4 years The distribution of PCB concentrations in hybrid bass throughout the lake remains a concern. Hybrid bass collected farther from the source in Twelvemile Creek have higher PCB concentrations than other species, often exceeding the FDA tolerance level of 2 mg/kg (Figure 5-10). This is thought to be a result of their migratory behavior and is also seen in the samples of walleye, another migratory species having high concentrations of PCBs (mean 3.48 mg/kg) from SV-642 at Hartwell Dam. Contaminants other than PCBs were not identified at concentrations of concern nor were they widely distributed. A comparison of the priority pollutants to the established USFDA action levels showed that no chemical exceeded any of the safe tolerance standards except PCBs. Priority pollutants having no standards were compared to SCDHEC's fish tissue trend data base. Out of 60 largemouth bass there were 17 different compounds (mostly petroleum and organic solvents) that occurred only once in a single fish and several others that occurred only twice. There was no pattern of contamination and PCBs are considered the only contaminant of concern. Forage fish species had mean PCB concentrations ranging from 3.00 mg/kg in threadfin shad to 12.43 mg/kg in gizzard shad at SV-107. PCB concentrations in forage fish decreased at stations farther from the Twelvemile Creek Arm. This supports the hypothesis that migratory species bioaccumulate PCBs while located in the upper Seneca River rather than through the food chain as forage species migrate out of the more heavily contaminated area. The effects of PCB contamination on fish health and reproductive competence in Lake Hartwell were examined utilizing the HAI, biological indicator analyses, and age and growth analysis. Largemouth bass were the target fish species sampled. Comparisons of fish health using the HAI as the indicator were made among all six stations sampled in Lake Hartwell in 1992 and 1993. Differences in the HAI were seen between stations. Station SV-107 consistently had the highest HAI score for each year sampled. Station SV-106, the closest downstream station, also had high HAI scores. During 1992, these two stations exceeded 80 while stations farther from Twelvemile Creek ranged from 42 to 65. Fish from Twelvemile Creek (SV-107) and Martins Creek (SV-106) had the highest occurrence of fatty liver conditions. Accumulation of fat in the liver can be associated with exposure of fish to PCBs. The remaining stations had a greater percentage of normal livers with little occurrence of fatty livers. Although HAI scores only indicate the relative <IMG SRC 0494178J> <IMG SRC 0494178K> <IMG SRC 0494178L> Final ROD-Sangamo OU2 June 1994 health of fish without indicating cause, decreases in the HAI scores with distance from the source was consistent with declines in PCB concentrations in fish at these stations. Biomonitoring using biological indicators of fish health and reproductive competence was conducted at both Twelvemile Creek and Lake Hartwell study sites. The selected suite of bioindicators measured in this investigation included, among others, organ dysfunction, nutritional status, gonadal analyses, detoxification enzymes, and concentrations of reproductive steriods. The redbreast sunfish was the target species in the Twelvemile Creek watershed, while largemouth bass was the target species in Lake Hartwell. Bioindicator analyses conducted in Twelvemile Creek indicated that PCB contamination probably contributes, but is not the sole cause of impacts on fish health. There was evidence of biochemical and physiological differences between Lake Hartwell stations with largemouth bass collected from SV-107 exhibiting abnormal responses to several bioindicators. The most obvious physiological difference in largemouth bass between stations related to the functions of the liver. Additionally, age and growth analysis indicated that largemouth bass from SV-107 had a slower growth rate and were less plump having lower weights per unit of length. Cages of clean corbicula were deployed for 28 days at two locations in the Twelvemile Creek Arm of Lake Hartwell to evaluate the uptake of PCBs by this filter feeding organism. The two locations were established in the "goose-neck bend" area between the Maw (Hwy 337) and Madden (Hwy 15) Bridges and near the lower end of Twelvemile Creek Arm, just above the Keowee River confluence. PCBs were detected in corbicula muscle tissue at concentrations ranging from 0.48 mg/kg at the lower Twelvemile Creek Arm station to 0.56 mg/kg at the goose-neck bend station. Adult mayflies were also collected from the Twelvemile Creek Arm, just above the Hwy 133 Bridge and were found to have 2.6 mg/kg of PCBs. 5.3.3 Assessment of Resource Use Public utilization of the fishery resources was assessed by creel surveys on Twelvemile Creek and Lake Hartwell. Twelvemile Creek was surveyed at major access points upstream to the confluence of the Middle Fork and North Fork. Lake Hartwell was divided into eight sampling areas that allowed analysis of angler use relative to PCB concentrations in fish within each area. Additionally, interviews provided data from which to evaluate the economic importance of the resource. The interviews also included questions to assess how fishermen used or consumed their harvest and fisherman awareness of the health advisory. These questions were the same for both the Lake Hartwell and the Twelvemile Creek creel survey. Angler use of Twelvemile Creek appeared to be minimal. Only 21 interviews were obtained during this investigation. Some anglers were interviewed more than once indicating there may be a small localized group of anglers that frequent Twelvemile Creek. Most anglers interviewed were located at bridge crossings near Final ROD-Sangamo OU2 June 1994 the confluence of Twelvemile Creek and Lake Hartwell. They were encountered from March through August only. There was evidence of some fishing in more upstream areas from the presence of the types of trash that is customarily associated with bank fishermen. However, anglers were not encountered at these locations indicating low use. Most anglers (66%) do consume fish caught in Twelvemile Creek. Channel catfish and sunfish made up most of the harvest. Consumption estimates for those anglers that indicated they ate fish were higher for Twelvemile Creek (37 g/day) than for Lake Hartwell (28 g/day). However, the total estimated harvest for Twelvemile Creek in 1992 was only 116.2 kg (256 lbs.). Public utilization of the fishery resources in Lake Hartwell was also assessed by creel survey. A total of 415,839 fish were caught in 728,489 angler-hours of effort. A total of 239,726 (58%) were released, while 176,112 fish weighing 115,320 kg (253, 703 lbs.) were harvested. The top five species sought included largemouth bass, anything, striped bass, hybrid bass, and crappie. Largemouth bass and crappie comprised the largest percentage by number of fish harvested, while largemouth bass and hybrid bass comprised the largest percentage by weight. The number of fish harvested was greatest in areas which comprised the Twelvemile Creek, Keowee River, and Seneca River Arms which encompass the most heavily contaminated portion of Lake Hartwell and much of the area under the most extreme advisory. Additionally, the Seneca River Arm area had the highest harvest by weight. By weight, 29% of the largemouth bass, 48% of the hybrid bass, and 66% of the striped bass harvested from Lake Hartwell came from the Seneca River Arm. Despite the advisory concerning fish consumption, anglers continue to harvest the largest portion of fish from Lake Hartwell from the areas most affected by PCB contamination. Eighty-five percent of all anglers responding were aware of the fish consumption advisory. Sixteen percent had stopped eating fish because of the advisory. Sixty-seven percent of anglers interviewed indicated they ate fish from Lake Hartwell. The mean monthly per capita consumption for Lake Hartwell anglers that eat fish was estimated to be 0.85 kg (1.86 lbs). The mean monthly per capita consumption estimate for the Twelvemile Creek Arm, the most contaminated area, was 0.9 kg (2 lbs) near the lake average. The health advisory on fish consumption appeared to influence consumptive habits of less than one-fourth of the anglers interviewed. Most anglers cited other reasons why they had stopped eating fish caught from Lake Hartwell. Most anglers indicated that they practiced catch-and-release, presumably for sport reasons. Some anglers indicated that a stronger advisory, a ban on fishing, seeing people get sick from eating fish and/or documentation of increased contamination would affect their fish consumption habits. Final ROD-Sangamo OU2 June 1994 5.4 CONTAMINANT FATE AND TRANSPORT SUMMARY An integral component of the Sangamo OU2 RI was to develop predictions regarding the continued deposition, migration, and accumulation of PCB contaminants in the sediment, water, and aquatic biota of Lake Hartwell. These predictions were accomplished through the use of specialized numerical-based models that considered the environmental processes and contaminant characteristics that control PCB migration and accumulation as well as the intermedia transfer and degradation of PCBs. This comprehensive modeling effort focused on changes to an approximate 10 mile reach of the Twelvemile Creek Arm of Lake Hartwell over a 30-year period and consisted of: 1) future sediment transport/deposition using the HEC-6 computer model, "Scour and Deposition in Rivers and Reservoirs, Version 4.0", which was developed by the Hydrologic Engineering Center of the COE; 2) future PCB fate and transport using the "Water Quality Analysis Simulation Program (WASP-4), Version 4.0" developed and supported by EPA; and 3) future aquatic bioaccumulation modeling using the "Food and Gill Exchange of Toxic Substances (FGETS), Version 3.0" developed by EPA. The results of these modeling efforts are summarized below. 5.4.1 Future Sedimentation The objective of sediment transport simulation was to determine rates at which presently contaminated sediments would be buried by relatively clean sediments from tributary drainages over the next 30 years. This simulation assumes that the historic hydrologic flow regime and sediments loading to the system remains unchanged. An overview of sedimentation regimes within the Twelvemile Creek Arm and upper Seneca Arm is summarized below. Figure 5-11 provides a bed profile of the Twelvemile Creek Arm. Figure 5-12 provides an illustration of the average sediment burial rates as predicted by the HEC-6 model. The model identified three distinct sediment transport regimes. The first regime extends from just below the Woodside II impoundment (Transect T19) to a point approximately 2,400 ft upstream of the Maw Bridge (Transect T16). This reach is upstream of the backwater influence of the Hartwell impoundment (normal pool elevation of 660 ft MSL) and, therefore, behaves as a river. Energy gradients, bottom shear stresses, and turbulence intensities are relatively large in this reach; sediment transport potential is therefore high and sediments of all sizes, sand included, are carried by the flow aa suspended sediment. The HEC-6 results predict excess sediment transport potential, resulting in a small amount of scour along this reach. The second regime extends from upstream of the Maw Bridge to just above the Hwy 133 bridge; this reach represents a zone of transition from a high energy fluid environment (river) to a low energy environment (lake). As the transition from river to lake occurs, energy gradients, bottom shear stresses, and turbulence <IMG SRC 0494178M> <IMG SRC 0494178N> Final ROD-Sangamo OU2 June 1994 levels all decrease, resulting in high rates of sediment deposition (1.43 to 13.12 cm/yr) as all of the sand and most of the silt coming into the reservoir are deposited (clays remain as suspended sediment and continue downstream). The model predicted a 30-year accumulation of nearly 10 ft of sediment in some areas. Sedimentation in this area results in the formation of a delta that advances into the impoundment over time, moving the headwater location further into the impoundment as well (See Figure 5-11). With a continuous supply of sediment from the watershed, this delta eventually will advance below Madden Bridge. The third regime extends from upstream of the Hwy 133 bridge to the Hwy 37 bridge, which marks the downstream extent of the system modeled. Hydraulically, this portion of the system behaves as an impoundment with low-energy gradients and turbulence levels. This quiescent environment favors sediment deposition; however, only small deposition depths and burial rates are predicted because most of the sand and silt load is deposited upstream, and only slow-settling, clay-sized particles are available for deposition downstream. Most of the clay entering this reach is deposited, resulting in predicted deposition depths ranging from 0 to 54 cm and average burial rates of 0 to 1.8 cm/yr. 5.4.2 Future Sediment and Water Quality Trends Future PCB fate and transport in the Twelvemile Creek/Hartwell Lake system was modeled using the WASP4 code developed by EPA. The modeling was conducted to predict the fate and transport of PCBs in the Twelvemile Creek/Hartwell Lake system over the next 30 years. This work was conducted to assist in the extrapolation of PCB data collected in the present investigation to future conditions. An overview and results of the water quality modeling study are summarized below. Figures 5-13, 5-14, 5-15, and 5-16 provide predicted PCB concentrations in surface sediment initially, at 10 years, 20 years, and 30 years, respectively. Results from the WASP4 simulations reflect a relatively complex cycling of PCBs through the system. Initially, PCB concentrations are relatively high in upstream surface and bottom sediment segments. Over time, clean sediment from the upstream tributary is deposited over the contaminated sediments, which results in burial and dilution of the contaminated sediments. Because sediment resuspension and deposition can occur simultaneously, some contaminated sediments from upstream segments is resuspended in the water column, where advection and dispersion transport them further into the impoundment. These contaminated sediments are then redeposited. Because suspended sediment concentrations decrease with increasing distance into the impoundment, the rate at which redeposited sediments are buried is much smaller than at points upstream where they originated. The net result of these transport processes is (1) a significant reduction in PCB concentrations in the surface and <IMG SRC 0494178O> <IMG SRC 0494178P> <IMG SRC 0494178Q> <IMG SRC 0494178R> Final ROD-Sangamo OU2 June 1994 bed sediments in the upper and middle portions of the system, and (2) an increase in PCB concentrations in surface and bed sediments near the lower end of the system. Surface and bottom sediments upstream of the Hwy 133 bridge, which had initial PCB concentrations ranging from 1,600 to 10,000 æg/L, are predicted to decrease to near zero levels within the first 5 years. This reduction in concentration is due to burial by clean sediments derived from upstream reaches along with removal by sediment resuspension. In the middle reach of the system between the Hwy 133 bridge and the Hwy 93 bridge, PCB concentrations also decrease over time for the same reason but at a much slower rate. Initially, concentrations in this middle reach ranged between 1,800 and 23,000 æg/L. The range is reduced to 400 to 8,000 æg/L after 5 years, 50 to 2,800 æg/L after 10 years, and 0 to 40 æg/L after 30 years. Surface and bottom sediments lying between the Hwy 93 bridge and the Hwy 37 bridge show PCB concentrations increase over time. Initially, concentrations in these segments ranged between 400 and 1,400 æg/L; after 30 years, concentrations in these segments are predicted to range up to 8,800 æg/L. This predicted concentration increase is attributed to hydrodynamic influences associated with the Hwy 37 embankment. 5.4.3 Bioaccumulation and Future Fish Concentrations Aquatic bioaccumulation modeling was conducted to predict future PCB levels in the fish of the Twelvemile Creek/Hartwell Lake system using the FGETS model. This work was conducted to assess: (1) how PCB levels in fish would change over the next 30 years if the contaminated sediments were left unmanaged, and (2) how long it would take for FDA tolerance level of 2 mg/kg of the aquatic bioaccumulation below. Figure 5-17 provides a levels to drop below the current in several species. The results modeling study are summarized graphical summary of this effort. FGETS is a time-dependent model that predicts whole-body fish residues at specified points in time. The outputs of the model are averaged residues for each year of the fish's life. FGETS can predict chemical uptake by fish through two principal pathways: (1) directly from water via respiration, and (2) through consumption of contaminated food and sediments. For hydrophobic organic chemicals, such as PCBs, the second pathway is known to be the more significant one. Application of the FGETS model requires the construction of a conceptual model, which includes selection of a representative food web. Three species of fish were chosen to be included in the representative food web, based on the species present in Hartwell Lake, the availability of data for calibration, and the potential for human exposure. Largemouth bass was selected as the top predator for the food web model, since it is the most frequently harvested species and currently has the highest PCB residues for game (harvest) fish. Gizzard shad and bluegill sunfish were identified as the two most important forage fish for Hartwell Lake largemouth bass. Plankton and benthos composed the lower levels of the food web. Plankton and benthos were assumed <IMG SRC 0494178S> Final ROD-Sangamo OU2 June 1994 to be in chemical equilibrium with the dissolved-phase PCB concentrations of the water column and particulate-phase PCB concentrations of the surficial sediments, respectively, as predicted by the WASP4 water quality model. Actual modeling consisted of a long-term simulation to predict future PCB fish tissue concentrations over the next 30 years. Results show PCB concentrations in all components of the aquatic bioaccumulation model decreased over the 30-year simulation period (Figure 5-17). PCB concentrations in plankton and benthos, assumed to be in chemical equilibrium with the water column and surface sediments, showed a rapid rate of decline consistent with the WASP4 predictions. In response to decreasing water column and surface sediment PCB levels, concentrations in fish declined as well. Mean concentrations in largemouth bass fillets (10.75 mg/kg initially) declined to 5.16 mg/kg by year 5 and fell to 1.74 mg/kg and below the 2.0 mg/kg FDA tolerance level by year 10 (year 2003). Although the mean largemouth bass concentration fell below the FDA limit by year 10, a longer period of time is required for concentrations in older age classes to fall below the FDA limit. PCB concentrations in 10-year-old fish, representing the highest age class and largest fish in the model, required 12 years (year 2005) to fall below the 2.0 mg/kg FDA limit. By year 30, mean concentrations in largemouth bass fillets are expected to be very low, with a mean value of 0.025 mg/kg predicted. 6.0 SUMMARY OF SITE RISKS CERCLA directs EPA to protect human health and the environment from current and potential exposure to hazardous substances at the Sangamo OU2 Site. The Baseline Risk Assessment provides the basis for taking action and indicates contaminants and the exposure pathways that need to be addressed by the Remedial Action. It serves as an indication of what risks the Site poses if no action were taken. A Baseline Risk Assessment was conducted to evaluate the potential current and future human health and ecological impacts associated with exposure to PCBs in sediment and fish. This section of the ROD contains a summary of the results of the Baseline Risk Assessment conducted for this Site. Tables utilized and referenced in this discussion are included at the end of this Section to facilitate the readability of this Section. 6.1 CONTAMINANTS OF CONCERN The Baseline Risk Assessment focused only on PCBs as the chemical of potential concern. As described in Section 5.0, full-screen analyses were conducted on a limited number of sediment and fish tissue (biological) samples. These analyses did not detect appreciable quantities of volatile organic compounds (VOCs), semivolatile organic compounds (SVOCs), pesticides, and/or inorganics (metals). Final ROD-Sangamo OU2 June 1994 The human health exposure pathways that were quantitatively evaluated under this Baseline Risk Assessment were as follows: 1) Ingestion and dermal absorption of PCBs in shallow sediment by a child and an adult at: The upper section of Twelvemile Creek Arm, The upper Twelvemile Creek Watershed, The Hagood Reservoir, and Immediately downgradient of the Sangamo Plant Site. 2) Ingestion of PCB-contaminated fish by a recreational fisherman. Sediment data were divided into two overall categories in order to best define exposure. These included sediment sample locations which were 2.1 m (7 ft) or less below the water surface, and sediment sample locations which were between 2.1 m and 3 m (7-10 ft) below the water surface. As discussed previously, the lake level fluctuates an average of 4 ft, hence exposing additional sediment. The lower interval was developed to evaluate this potential exposure. Table 6-1 summarizes the information used to calculate sediment exposure point concentrations at the four locations. Sediment data is from the Phase I and Phase II Sediment Investigation. The risks posed by the ingestion of PCB-contaminated fish were evaluated at all six Lake Hartwell fish sampling locations (SV-107, SV-106, SV-532, SV-535, SV-642, SV-641). These locations are depicted on Figure 5-7 in Section 5.3 of this ROD. In addition, risks posed by the ingestion of fish caught in the Twelvemile Creek watershed, tributaries of the watershed, and a background location were quantified. Risks were evaluated separately by fish species and also for all species combined to account for both individuals who may eat one specie exclusively and individuals who consume all types of fish. Table 6-2 summarizes the information used to calculate fish tissue exposure point concentrations at these locations. Fish tissue data are from the 1991 and 1992 Biological Investigations prepared in accordance with standard FDA fillet method (i.e. fillet including rib cage and belly flap with skin on/scales off - except catfish where skin is removed). 6.2 EXPOSURE ASSESSMENT For purposes of this Baseline Risk Assessment, it was assumed that in the future the Twelvemile Creek/Lake Hartwell system will continue to exist in its present state. All exposure pathways that are complete under the current land-use conditions were also assumed to be potentially complete under the future land-use scenario. The exposure pathways that were quantitatively evaluated under the current/future use scenarios are described in Section 6.1 of this ROD. EPA employed a reasonable maximum exposure (RME) approach to estimate the potential exposures and associated risks at the Sangamo OU2 Site. The RME is the highest exposure that is Final ROD-Sangamo OU2 June 1994 reasonably expected to occur at the Site. The intent of the RME is to estimate a conservative exposure case that is still within the range of possible exposures. The calculation of risk posed by exposures to PCBs requires the combination of exposure point concentrations with assumptions regarding frequency, duration, and magnitude of receptor contact. RME exposure point concentrations for sediment and fish tissue are listed in Tables 6-1 and 6-2, respectively. The RME exposure parameter assumptions for sediment and fish that were used to characterize risk posed by PCBs are listed in Tables 6-3 and 6-4, respectively. The exposure parameters for ingestion of fish were derived from results the site-specific recreational angler survey discussed in Section 5.3. 6.3 TOXICITY ASSESSMENT For risk assessment purposes, individual chemicals are separated into two categories of chemical toxicity depending on whether they exhibit principally carcinogenic (cancer-causing) or noncarcinogenic effects. The carcinogenic and noncarcinogenic toxicity of PCBs are discussed below. 6.3.1 Carcinogenic Toxicity of PCBs EPA assigns weight of evidence classifications to potential carcinogens. Under this system, chemicals are classified as follows: Group A - Human Carcinogen: Sufficient evidence from human epidemiological studies to support a causal association between a chemical and cancer. Group B1- Probable Human Carcinogen: Limited evidence from human epidemiological studies of carcinogenicity to humans. Group B2- Probable Human Carcinogen: Sufficient evidence of carcinogenicity to animals. Group C - Possible Human Carcinogen: Limited evidence of carcinogenicity in animals and an absence of data on humans. Group D - Not Classified: in animals. Inadequate evidence of carcinogenicity Group E - No Evidence of Carcinogenicity to Humans PCBs are classified as a Class B2 carcinogen, which indicates that there is sufficient evidence from tests on animals to link exposure of PCBs with carcinogenic effects. Slope factors (SFs) have been developed by EPA for estimating excess lifetime cancer risks associated with exposure to potentially carcinogenic contaminants. SFs, which are expressed in units of (mg/kg-day)-1 or risk per milligram per kilogram of dose, are multiplied by the estimated intake of a potential carcinogen, in mg/kg-day, to provide an upper bound Final ROD-Sangamo OU2 June 1994 estimate of the excess lifetime cancer risk associated with exposure at that intake level. The term "upper-bound" reflects the conservative estimate of the risks calculated from the SF. Use of this approach makes underestimation of the actual cancer risk highly unlikely. Slope factors are derived from the results of human epidemiological studies or chronic animal bioassay data to which mathematical extrapolation from high to low dose and from animal to human dose has been applied, as well as statistics to account for uncertainty (e.g. to account for the use of animal data to predict effects on humans). A SF of 7.7 (mg/kg-day)-1 for the PCB Aroclor 1260 was obtained fram the Integrated Risk Information System (IRIS) for use in this Baseline Risk Assessment. 6.3.2 Noncarcinogenic Toxicity of PCBs Reference doses (RfDs) have been developed by EPA for indicating the potential for adverse health effects from exposure to the contaminants exhibiting noncarcinogenic effects. RfDs, which are expressed in units of mg/kg-day, are estimates of daily exposure levels for humans, including sensitive populations, that are likely to be without risk of adverse effect. Estimated intakes of contaminants from environmental media can be compared to the RfD. RfDs are derived from human epidemiological and animal studies to which uncertainty factors have been applied. A chronic RfD of 7 X 10-5 mg/kg-day for the PCB Aroclor 1016 was used in this Baseline Risk Assessment. This daily exposure estimate has been documented in studies conducted on monkeys to produce reproductive effects (reduced birth weights). 6.4 RISK CHARACTERIZATION For carcinogens, risks are estimated as the incremental probability of an individual developing cancer over a life-time as a result of exposure to the contaminants of concern, in this case PCBs. Excess life-time cancer risk is calculated from the following equation: Risk = CDI x SF where: Risk = CDI = SF = a unitless probability (i.e. 2 x 10-5) of an individual developing cancer. chronic daily intake averaged over 70 years (mg/kg-day). slope factor, expressed as (mg/kg-day)-1. These risks are probabilities that are generally expressed in scientific notation (i.e. 1 x 10-6). An excess lifetime cancer risk of 1 x 10-6 indicates that, as a reasonable maximum estimate, an individual has a 1 in 1,000,000 chance of developing cancer as a result of site-related exposure to a carcinogen over a 70 year lifetime under the site-specific exposure conditions for the site. EPA's generally acceptable risk range is 1 x 10-4 to 1 x 10-6. Final ROD-Sangamo OU2 June 1994 The potential for noncarcinogenic effects is evaluated by comparing an exposure level over a specified time period with a reference dose derived for a similar exposure period. The ratio of exposure to toxicity is called a Hazard Quotient (HQ). An HQ<1 indicates that an individual's dose of a single contaminant is less than the RfD, and that the toxic noncarcinogenic effects from that chemical are unlikely. The Hazard Index (HI) is generated by adding the HQs for all chemicals of concern that affect the same target organ within a medium or across all media to which a given population may reasonably be exposed. An HI<1 indicates that, based on the sum of all HQs from different contaminants and exposure routes, toxic noncarcinogenic effects from all contaminants are unlikely. The HQ is calculated as follows: Non-cancer HQ = CDI/RfD where: CDI = RfD = chronic daily intake reference dose CDI and RfD are expressed in the same units (mg/kg-day) and represent the same exposure period. The carcinogenic and noncarcinogenic risks associated with direct contact with or incidental ingestion of PCB contaminated sediment and ingestion of PCB-contaminated fish are summarized in Tables 6-5 and 6-6, respectively. Adverse human health risks resulting from direct contact or incidental ingestion with the sediment are unlikely to occur, however, sediments are a continuing source of contamination in the aquatic biota of the study area. Exposures associated with the ingestion of fish caught from all sampling stations resulted in unacceptable risks ranging from 10-2 to 10-4. The highest cancer risk of 4 x 10-2 was calculated for anglers exclusively consuming largemouth bass from the Twelvemile Creek watershed. The highest cancer risk for ingestion of all species combined, 1 x 10-2, was calculated for the Twelvemile Creek Arm. The lake-wide risk associated with ingestion of all species combined was 5 x 10-3. 6.5 MONTE CARLO The human health risks presented under Section 6.4 are referred to as the deterministic risks. That is, the resultant risk is a single value for a single set of specific exposure parameters. A refined approach to risk assessment can be achieved by taking into account the probability distributions of possible values for each of the exposure parameters rather than relying on discrete parameter values. Such an approach was taken in the Sangamo OU2 risk assessment through Monte Carlo analysis. The advantage of this approach is that it furnishes more information of the variability of the full range of potential risks that may occur. The fish ingestion pathway was chosen for Monte Carlo analysis evaluation because this pathway is associated with the highest potential risks. The potential cancer risk associated Final ROD-Sangamo OU2 June 1994 with exposure to PCBs was evaluated for ingestion of bass (largemouth and hybrids) lake-wide and for ingestion of bass (largemouth and hybrids) caught in the area associated with the highest PCB concentrations (i.e. SV-107). The mode of the risk distribution is of most interest when interpreting the final distribution of risks since it represents the most frequently occurring risk. The most frequently occurring risk in the distribution, or mode, was estimated to be 2 x 10-4 and 3 x 10-4 for ingestion of lake-wide bass and bass at SV-107, respectively. The results of the Monte Carlo analysis indicated that the 1 x 10-ý risk associated with the ingestion of bass from location SV107 represented the 95th percentile of high end of the overall risk distribution, while the 5 x 10-3 risk associated with ingestion of lake-wide bass corresponded to the 90-95th percentile of the overall risk distribution. 6.6 ECOLOGICAL RISK ASSESSMENT An ecological risk assessment was conducted to evaluate the impact PCBs may be having on aquatic receptors (plant, invertebrates, and fish) and terrestrial receptors (birds and mammals) of the Sangamo OU2 study area. The Biological Investigations clearly document PCB contamination at all levels of the aquatic food web. However, although PCBs appear to be impacting the fish and macroinvertebrate communities in Twelvemile Creek, habitat degradation from man's influence is likely causing additional adverse impacts. A 1990 investigation conducted independently of these RI studies provided evidence that fish health and populations can be affected as concentrations in fish increase to an average of 20 mg/kg and greater. Results from the bioindicator analyses support the contention that individual largemouth bass may be impacted at SV-107 and SV-106, areas closest to the Sangamo Plant Site. However, at the present level of PCB concentrations in fish tissue (approximately 5 mg/kg), the data from the Biological Investigations do not support a conclusion that significant impacts to the overall health and the population/community levels to Lake Hartwell fish are occurring. Ecological exposures to surface water were not directly evaluated in the ecological assessment because PCBs were not detected in surface water at detection limits ranging from 1.21.3 æg/L during the RI. Aquatic plants are not likely to suffer adverse impacts from PCB concentrations just below the detection limit. Aquatic invertebrates that are intimately associated with sediments (primarily benthic organisms) may be adversely impacted in the study area based on a comparison of PCB concentrations in sediment to EPA's interim sediment quality criteria for aquatic organisms. Reliable population estimates for avian species (eastern phoebe, green-backed heron, belted kingfisher, osprey) and mammals (mink, otter) that would feed in the study area were not obtainable. Therefore, the certainty of the extent of any population impacts caused by PCBs in the study area is unknown. However, population effects on these terrestrial species is not likely. Final ROD-Sangamo OU2 June 1994 6.7 UNCERTAINTY ASSESSMENT In any risk assessment, there is some degree of uncertainty associated with the estimates of human and ecological risks. The primary sources of uncertainty included environmental sampling, exposure parameter estimation and toxicological data. Typically, these uncertainties are compensated for by employing conservative assumptions. Consequently, the qualitative and quantitative risk estimates for Sangamo OU2 should not be construed as absolute estimates of risk, but rather as conditional estimates based on a number of assumptions regarding exposure and toxicity. 6.8 SUMMARY The primary human health exposure pathway of concern at the Sangamo OU2 Site is the ingestion of fish contaminated with PCBs. Exposures associated with ingestion of fish caught from all sampling locations resulted in unacceptable carcinogenic risks ranging from 10-2 to 104 and HQs greater than 1. As discussed under Section 5.4 (Contaminant Fate and Transport) of this ROD, PCB concentrations in sediment are predicted to decrease over time. The impact of decreasing sediment concentrations on overall risk was evaluated for the ingestion of largemouth bass at SV-107. The output from the food-chain bioaccumulation model (FGETS Section 5.4.3) was utilized in this analysis. It was found that the total modeled risk over a 30-year time frame (2 x 10-3) was not substantially different from the calculated deterministic RME risk of 1 x 10-2. This was largely because risk over this time period is dominated by the very high risks calculated for the first eight years of exposure. In actuality, a period of approximately 22 years appears to be required for one-year risks to drop to the 10-ý risk level. It would require more than 22 years for the entire 30-year risks to decline to < 10-6. With respect to noncancer risks, a period of approximately 20 years appears to be required for the HQ to drop below one. After the next 20-30 years, long-term risk associated with the consumption of fish harvested from Lake Hartwell should be substantially lower. Actual or threatened releases of hazardous substances for the Sangamo OU2 Site, if not addressed by implementing the response action in this ROD, may present an imminent and substantial endangerment to public health, welfare, or the environment. Final ROD-Sangamo OU2 June 1994 TABLE 6-1 PCB Exposure Point Concentrations in Shallow Sediment Area/ Interval PCB Concentration (mg/kg) Meana 95% UCL of Meanb Maximum Detected Concentration RME Exposure Point Concentrationø Upper 12 Mile Creek Arm Beneath 0-2.1 m of Lake Water 0.91 1.65 7.54 1.65 Beneath 0-3 m of Lake Water 1.51 2.93 7.88 2.93 0.76 0.70 Upper 12 Mile Creek Watershed Beneath 0-2.1 m of Lake Water 0.45 0.70 Beneath 0-3 m of Lake Water 0.45 0.72 0.91 0.72 Hagood Reservoir Beneath 0-2.1 m of Lake Water 0.29 0.36 0.33 0.33 Beneath 0-3 m of Lake Water 0.28 0.33 0.33 0.33 3.52 3.52 Downgradient of Sangamo Plant Beneath 0-2.1 m of Creek Water 1.51 --- a) Arithmetic mean concentration (including one-half detection limit for non-detects). b) Value represents 95th percent Upper Confidence Limit (UCL) on the arithmetic mean. c) RMB=Reasonable Maximum Exposure; value listed is the lower value of the 95th percent UCL on the arithmetic mean and the maximum detected concentration. Final ROD-Sangamo OU2 June 1994 TABLE 6-2 Exposure Point Concentrations in Fish Species Mean PCB Concentrations (mg/kg) 95% Maximum RME Exposure UCL of Detected Point Mean Concentration Concentration SV-107 Largemouth Bass 6.8 8.5 19.7 8.5 Hybrid Bass 1.4 2.0 2.3 2.0 Largemouth Bass and Hybrid Bass 5.7 7.9 19.7 7.9 Channel Catfish 5.6 7.8 8.3 7.8 All Species Combined 5.4 7.0 19.7 7.0 SV-106 Largemouth Bass 3.3 3.8 9.2 3.8 Hybrid Bass 4.7 8.0 9.7 8.0 Channel Catfish 2.5 3.9 4.0 3.9 All Species 3.6 Combined SV-532 4.3 9.7 4.3 Largemouth Bass 1.7 3.8 3.5 3.5 Hybrid Bass 3.9 5.9 9.6 5.9 Channel Catfish 1.7 4.4 3.5 3.5 All Species Combined 2.5 4.0 9.6 4.0 0.80 1.3 1.7 1.3 1.8 3.3 3.9 3.3 0.60 0.82 0.90 0.82 1.2 1.7 3.9 1.7 0.56 0.98 1.1 0.98 2.3 3.7 7.0 3.7 0.71 2.6 2.8 2.6 1.3 2.1 7.0 2.1 SV-535 Largemouth Bass Hybrid Bass Channel Catfish All Species Combined SV-642 Largemouth Bass Hybrid Bass Channel Catfish All Species Combined Final ROD-Sangamo OU2 June 1994 TABLE 6-2 Exposure Point Concentrations in Fish Species Mean PCB Concentrations (mg/kg) 95% Maximum RME Exposure UCL of Mean Detected Point Concentration Concentration SV-641 (Lake Background) Largemouth Bass 0.22 Hybrid Bass 2.0 Channel Catfish 0.41 All Species Combined 0.74 0.3 1.2 0.3 2.8 9.3 2.8 1.4 0.8 0.8 1.1 9.3 1.1 All Areas of Lake Hartwell + 12 Mile Creek All Species Combined 3.0 3.9 19.7 3.9 Largemouth Bass 3.2 and Hybrid Bass 4.2 19.7 4.2 25 13.9 13.9 2.2 7.1 2.2 1.2 0.2 12 Mile Creek Watershed Largemouth Bass 4.0 Redbreast Sunfish 1.7 Tributaries of Watershed Watershed Redbreast Sunfish 0.74 ND Background ND 0.2 ND ND Final ROD-Sangamo OU2 June 1994 TABLE 6-3 Exposure Parameters for Incidental Ingestion of and Dermal Contact with Sediment (Current/Future Use Conditions) Parameters Reasonable Maximum Exposure Case Age Period (years) Exposure Frequency (days/year)a Exposure Duration (years) Child 4-12 105 8 Adult >18 75 30b Soil Ingestion Rate (mg/day)c Skin Surface Area Available for Contact (cm)2 Sediment to Skin Adherence Factor (mg/cm2)e Dermal Absorption Fraction (PCBs)f Body Weight (kg)g Averaging Time (years) Carcinogenich Noncarcinogenic a) b) c) d) e) f) g) h) 138 700d 1.0 0.01 27 100 1,230d 1.0 0.01 70 70 8 70 30 For children, assumes that children will swim 7 days/week from Memorial Day to Labor Day (15 weeks) for a total of 105 exposure events/yr. For adults, assumes that adults will swim 5 days/week for same 15 weeks for a total of 75 exposure events/yr. Based upon national upper-bound time at one residence (USEPA 1991a, 1989a). Value for children is a weighted-average ingestion rate, assuming 4, 5, and 6 year olds ingest sediment at a rate of 200 mg/day and older children ingest sediment at 100 mg/day (USEPA 1989a, 1991a). Value for adults is the standard default value recommended by USEPA (1991a, 1989a) Surface area based on 50th percentile values from USEPA (1985) for feet. Values for child and adult are the timeweighted averages. Based on USEPA Region IV guidance (USEPA 1992b). Based on USEPA Region IV guidance (USEPA 1992b). Value for 4-12 year old child is the time-weighted average based on data provided by USEPA (1989b). Value for adult is the standard default value recommended by USEPA (1991a). Based on USEPA (1991a, 1989a) standard assumption for lifetime. Final ROD-Sangamo OU2 June 1994 TABLE 6-4 Exposure Parameters for Ingestion of Fish by Adult Recreational Fisherman (Current/Future Use Conditions) Parameters Fish Ingestion Rate (grams/meal)a Exposure Duration (years)b Exposure Frequency by Sampling Location (meals per year)c Twelvemile Creek Watershed SV-107 SV-106 SV-532 SV-535 SV-642 Reasonable Maximum Exposure Value 357 30 60 30.6 27.6 20.6 22.5 37 SV-641 (Lake Background) Lake-Wide Average Body Weightd Averaging Time (years) Carcinogenice Noncarcinogenic a) b) c) d) e) 22.7 27.6 70 70 30 Based on the arithmetic mean of fish ingestion rates reported for 52 anglers surveyed at Twelvemile Creek on Lake Hartwell. Value is based on the national upper-bound time at one residence (USEPA 1991a, 1989a). Values based on January to December 1992 data obtained from Lake Hartwell Recreational Angler Survey. These values are the arithmetic mean exposure frequency in meals/month, multiplied by 12 months/year reported for a total of 677 anglers surveyed at Twelvemile Creek/Lake Hartwell. Final report of survey stated that some anglers were interviewed more than once, indicating that the survey results may include fishing habits of subsistence fisherman as well as recreational fisherman. Standard default value provided by USEPA (1991a, 1989a). Based on USEPA (1991a, 1989a) standard assumption for lifetime. Final ROD-Sangamo OU2 June 1994 TABLE 6-5 Potential Direct Contact Risks Associated with PCB in Sediment Exposure Pathway Upper Bound Excess Lifetime Cancer HQ for Noncarcinogenic Effectsa Risk INCIDENTAL INGESTION OF SEDIMENT Upper Twelvemile Creek Arm Child (4-12 years) 2 x 10-6 Adult 3 x 10-6 Upper Twelvemile Creek Watershed Child (4-12 years) 9 x 10-7 Adult 7 x 10-7 Immediately Downgradient of Sangamo Plant Site Child (4-12 years) 5 x 10-6 Adult 3 x 10-6 Hagood Reservoir Child (4-12 years) 4 x 10-7 <1 (0.03) <1 (0.01) <1 (0.01) <1 (0.003) <1 (0.06) <1 (0.02) <1 (0.006) Adult 3 x 10-7 <1 (0.001) DERMAL ABSORPTION FROM SEDIMENT Upper Twelvemile Creek Arm Child (4-12 years) 1 x 10-7 Adult 4 x 10-7 Upper Twelvemile Creek Watershed Child (4-12 years) 5 x 10-8 Adult 9 x 10-8 Immediately Downgradient of Sangamo Plant Site Child (4-12 years) 2 x 10-7 Adult 5 x 10-7 Hagood Reservoir Child (4-12 years) 2 x 10-8 Adult 4 x 10-8 <1 (0.002) <1 (0.001) <1 (0.0007) <1 (0.0004) <1 (0.004) <1 (0.002) <1 (0.0003) <1 (0.0002) Final ROD-Sangamo OU2 June 1994 TABLE 6-5 Potential Direct Contact Risks Associated with PCBs in Sediment Exposure Pathway Upper Bound Excess Lifetime Cancer HQ for Noncarcinogenic Effectsa Risk DIRECT CONTACT WITH SEDIMENT (TOTAL) Upper Twelvemile Creek Arm Child (4-12 years) Adult Upper Twelvemile Creek Watershed Child (4-12 years) Adult Immediately Downgradient of Sangamo Plant Site Child (4-12 years) Adult Hagood Reservoir Child (4-12 years) Adult a) 2 x 10-6 3 x 10-6 <1 (0 <1 (0 1 x 10-6 8 x 10-7 <1 (0 <1 (0 5 x 10-6 4 x 10-6 <1 (0 <1 (0 4 x 10-7 3 x 10-7 <1 (0. <1 (O. Hazard Quotient >1 indicates exposure to PCBs may result in adverse health effects. Actual value listed in (). Final ROD-Sangamo OU2 June 1994 TABLE 6-6 Potential Health Risks Associated with the Ingestion of Fish Location/Species Upper Bound Excess Lifetime Cancer Risk HQ for Noncarcinogenic Effectsa SV-107 Largemouth Bass Hybrid Bass Largemouth Bass and Hybrid Bass Channel Catfish All Species Combined 1 3 1 1 1 x x x x x 10-2 10-3 10-2 10-2 10-2 >1 >1 >1 >1 >1 (50) (10) (50) (50) (50) SV-106 Largemouth Bass Hybrid Bass Channel Catfish All Species Combined 5 1 5 5 x x x x 10-3 10-2 10-3 10-3 >1 >1 >1 >1 (20) (40) (20) (20) SV-532 Largemouth Bass Hybrid Bass Channel Catfish All Species Combined 3 6 3 4 x x x x 10-3 10-3 10-3 10-3 >1 >1 >1 >1 (10) (20) (10) (20) Largemouth Bass Hybrid Bass Channel Catfish All Species Combined 1 3 9 2 x x x x 10-3 10-3 10-4 10-3 >1 >1 >1 >1 (6) (10) (4) (8) SV-642 Largemouth Bass Hybrid Bass Channel Catfish All Species Combined 2 6 4 4 x x x x 10-3 10-3 10-3 10-3 >1 >1 >1 >1 (7) (30) (20) (20) SV-535 Final ROD-Sangamo OU2 June 1994 TABLE 6-6 Potential Health Risks Associated with the Ingestion of Fish Location/Species Upper Bound Excess Lifetime HQ for Noncarcinogenic Effectsa Cancer Risk SV-641 (Lake Background) Largemouth Bass Hybrid Bass Channel Catfish All Species Combined 3 3 8 1 All Areas of Lake Hartwell + 12 Mile Creek All Species Combined Largemouth Bass and Hybrid Bass 10-4 1O-3 10-4 10-3 >1 >1 >1 >1 (1) (10) (4) (5) 5 x 10-3 5 x 10-3 >1 (20) >1 (20) Twelvemile Creek Watershed Largemouth Bass Redbreast Sunfish 4 x 10-2 6 x 10-3 >1 (200) >1 (30) Tributaries of Watershed Redbreast Sunfish 6 x 10-4 >1 (20) Watershed Background a) x x x x ND ND Hazard Quotient >1 indicates exposure to PCBs may result in adverse health effects. Actual value listed in (). Final ROD-Sangamo OU2 June 1994 7.0 DESCRIPTION OF ALTERNATIVES Based upon the findings of the RI and associated Baseline Risk Assessment (human health/ecological), EPA developed remedial action objectives to support the identification, development and screening of remedial alternatives. These remedial action objectives were: Mitigate continued migration of PCB-contaminated sediments into Lake Hartwell by eliminating releases of PCBs into Twelvemile Creek. Control or eliminate the downstream migration of PCBcontaminated sediment within the Twelvemile Creek Arm of Hartwell Lake. Limit, to the extent feasible, the transfer of PCB contaminants from sediment to biota. Prevent or minimize exposure to fish with PCB contamination above target risk (or FDA) levels. Protection of human health is considered the primary driver for developing and evaluating remedial action alternatives. Thorough development and evaluation of feasible remedial alternatives for the Sangamo OU2 Site required the derivation of cleanup goals for the media of concern: sediment and fish. Cleanup goals were not developed for surface water since PCBs were not detected in any sample collected during the RI above the detection limits of 1.2 to 1.3 æg/l. Cleanup goals for sediment and fish were also necessary to identify areas to be addressed by the range of remedial alternatives that were evaluated in detail. The Final Cleanup Goals for sediment and fish, and the supporting rationale are presented in Sections 7.1 and 7.2, respectively. The contaminants of concern for the Sangamo OU2 Site are total PCBs. No Aroclor- or congener-specific distinctions are factored into the evaluation of remedial action alternatives. Discharges from the Sangamo Weston Plant into Town Creek included a variety of PCBs consisting predominantly of Aroclors 1242, 1254, and 1016. Analytical data for the RI included both Aroclor-specific concentrations (from offsite CLP analyses) and concentrations of total PCBs (from onsite field screening analyses). However, all of the resulte, findings and conclusions in the RI were discussed in terms of total PCBs. The reasons for this approach are as follows: A majority of the health-based and environmental criteria for PCBs are stated in terms of total PCBs (i.e., FDA tolerance level). EPA uses a carcinogenic slope factor for PCBs that is based on Aroclor 1260; this provides a conservative indicator of potential health effects for all PCB mixtures. Final ROD-Sangamo OU2 June 1994 Evaluation of contamination in terms of total PCBs was costeffective; it permitted collection of a large number of samples and the use of field screening (Modified Spittler Method) for sediment analyses. 7.1 FINAL CLEANUP GOAL FOR SEDIMENT Potential cleanup goals for PCB-contaminated sediment at the Sangamo OU2 Site were determined through an evaluation of available criteria and accepted techniques for calculating cleanup goals in sediment. This approach generated a range of potentially viable cleanup concentrations for the Sangamo OU2 sediment based on the following sources: Existing (published) criteria for PCBs in sediment, typically derived from either geographic-based, background PCB concentrations or biological effects observed or predicted in aquatic organisms. Precedents from other NPL sites where EPA has identified protective sediment cleanup goals for PCBs that have been finalized in RODs. Site-specific cleanup goals calculated using EPA's equilibrium partitioning approach based on contaminant partitioning between sediment and sediment pore water, based on protection of aquatic life. From this evaluation, three representative sediment cleanup goals (1 mg/kg, 0.4 mg/kg and 0.05 mg/kg) were selected for further analysis. The analysis consisted of an evaluation of the long-term impacts of potential sediment cleanup goals on PCB concentrations in fish, and ultimately human health via ingestion of contaminated fish, given that the ingestion of fish is the principal exposure pathway of concern at the site. This evaluation was conducted utilizing the FGETS bioaccumulation model discussed in Section 5.4.3 of this ROD. The rationale for selecting these values is presented below. 1 mg/kg - The most frequently selected sediment cleanup goal for PCBs at NPL sites based on a review of the EPA's ROD database. A concentration of 1 mg/kg also represents a reasonable lower limit considering technical feasibility and cost. 0.4 mg/kg - The mean value for the site-specific sediment quality criteria calculated using the EPA's equilibrium partitioning approach; also equal to the Effects RangeMedian criteria based on an evaluation of published criteria associated with biological effects on aquatic life as reported by the National Oceanic and Atmospheric Administration (NOAA). 0.05 mg/kg - Equal to the Effects Range-Low from NOAA based on an evaluation of published criteria associated with biological effects on aquatic life; also representative of Final ROD-Sangamo OU2 June 1994 the more commonly reported background-based sediment criteria for PCBs. The time required for 2-8 year old largemouth bass in the Twelvemile Creek Arm of Lake Hartwell to achieve 2 mg/kg for the range of selected sediment cleanup goals are compared to the baseline condition in Figure 7-1. As shown in this figure, fish PCB concentrations decline at about the same rate regardless of the sediment cleanup goal. Therefore, a final sediment cleanup goal of 1 mg/kg was selected based on technical feasibility rather than performance or risk-based considerations. This concentration identified the entire Twelvemile Creek Arm, extending from the headwaters of the lake downstream to the confluence with the Keowee Arm, as an area to be addressed. This area covers approximately 730 acres with a total estimated volume of 4,722,000 cubic yards (yd3) of contaminated sediment. 7.2 FINAL CLEANUP GOAL FOR FISH Fish ingestion was identified as the primary exposure pathway of concern at the Sangamo OU2 Site. Potential remediation goals include the FDA tolerance level of 2 mg/kg for PCBs in the edible portions of fish, and risk-based levels that consider the fish ingestion exposure pathway. Both of these options are described below. The FDA criterion was identified as a contaminant-specific Applicable or Relevant and Appropriate Requirement (ARAR). In addition, the existing health advisory for Hartwell rake is based on the continuing presence of PCBs in fish in concentrations greater than 2 mg/kg. Selection of risk-based cleanup goals for fish were considered by determining the concentration levels in largemouth bass that would result in acceptable risk to anglers (through ingestion of the fish) based on EPA's target risk range of 1 x 10-4 to 1 x 10-6. The acceptable concentrations were estimated using the same methodology used for the baseline human health risk assessment and for determining risk levels for the sediment cleanup goals. A fish tissue concentration of 0.036 mg/kg is associated with a 10-4 risk, 0.0036 mg/kg with a 10-5 risk, and so on. Using EPA's deterministic, reasonable maximum exposure (RME) approach and site-specific exposure parameters, the 30-year carcinogenic risk associated with the FDA criterion of 2 mg/kg results in an estimated risk of 6 x 10-3. This is well above the upper end of EPA's target risk threshold of 1 x 10-4. It is important to note that EPA considers the RME assumptions to be conservative, since they represent upper confidence limits for a given range of values for a particular risk input parameter or variable. It is also important to note that consumption of fish from Lake Hartwell (or other sources) is a strictly voluntary activity. Use of the risk-based concentrations for fish remediation goals (i.e., 0.036 mg/kg) was determined to be technically impracticable at SV-107 for several reasons. Fish bioaccumulate PCBs from both the water column and food chain; thus, PCB <IMG SRC 0494178T> Final ROD-Sangamo OU2 June 1994 concentrations in sediment and surface water would likely have to be reduced to levels in the ranges of parts per billion (0.001 mg/kg) or parts per trillion (0.001 æg/L) to achieve riskbased levels in fish. Reducing surface water and sediment concentrations to these levels is beyond the capability of proven treatment technologies, particularly when the scale of the site is taken into consideration. Moreover, as shown in the FGETS modeling, PCB cycling among fish, plankton, benthos, sediment, and surface water greatly complicates the removal of PCBs from a biological system once the contaminants have been introduced. Even if concentrations in sediment and surface water could be reduced to levels commensurate with the risk-based fish concentrations, it would be many years before the fish concentrations actually declined to acceptable levels. Given the existence of an ARAR for PCB concentrations in fish, the technical impracticability of establishing risk-based cleanup goals, and the classification of fish consumption as a voluntary exposure, the FDA tolerance level of 2 mg/kg was selected as the Final Cleanup Goal for Lake Hartwell fish. 7.3 REMEDIAL ALTERNATIVES Response actions that were identified and passed the screening of technologies and process options were assembled into a range of remedial alternatives that included no action, institutional controls, containment, collection, removal/disposal, and removal/treatment/disposal. These eight remedial alternatives were evaluated in detail in the Final March 1994 Feasibility Study Report. A summary description of these alternatives follows. The reader should refer to Final FS Report for a more detailed account of this subject matter. All alternative cost estimates are expressed in 1993 dollars and are based upon conceptual engineering and design. Capital cost consists of direct (construction) and indirect (nonconstruction) costs incurred in the first year of operation. Operation and Maintenance (O&M) cost refers to long-term postconstruction items necessary to ensure continued effectiveness of a remedial action. Total present worth cost represents that sum of money, if invested in the base year and disbursed as needed, would be sufficient to cover all costs of a remedy over its planned life. ALTERNATIVE 1 - NO ACTION As required by CERCLA, a no further action alternative was evaluated to serve as the basis for comparison with other active cleanup alternatives. Under this no-action alternative, no further remedial actions for the contaminated sediments or fish at the site would be conducted. The no-action alternative would not affect the existing health advisory issued by SCDHEC, who would be expected to continue the advisory until PCB concentrations in fish tissue decline to levels below 2 mg/kg (FDA tolerance level). The advisory currently warns against the consumption of fish from the Seneca River Arm of Hartwell Lake above the Hwy 24 bridge and fish larger than 3 lb throughout the Final ROD-Sangamo OU2 June 1994 entire lake. The advisory would be modified if warranted by future trends regarding PCB levels in fish. Maintenance of the fish advisory is assumed to entail the periodic replacement of existing signs that advise against fish consumption. As discussed in Section 5.4.3 of this ROD, the mean largemouth bass PCB concentration is predicted to fall below the FDA limit by year 10. However, a longer period of time is required for concentrations in higher age classes to fall below the FDA limit. PCB concentrations in 10-year-old fish, representing the highest age class and largest fish in the model, required 12 years, or the year 2005, to fall below the 2.0 mg/kg FDA limit. For these reasons, it was assumed that the fish consumption health advisory would remain in effect for 12 years. The no-action alternative would also entail periodic reviews of site conditions to ensure that the alternative remained protective of human health and the environment. These reviews would be conducted at least every 5 years as required by CERCLA. Capital Cost = $7,000 Total O&M Cost = $123,000 Total Present Worth Cost = $130,000 ALTERNATIVE 2A - INSTITUTIONAL CONTROLS This alternative is a limited action alternative that relies on a series of institutional controls to prevent or minimize ingestion of contaminated fish tissue, which was identified as the primary exposure pathway of concern for the Site. Generally, these institutional controls consist of the following components: Continuance of the Existing Fish Advisory Public Education Program - A program would be initiated to inform the public on available methods for reducing the intake of PCBs through fish consumption. Specific preparation, handling, and cooking techniques can reduce the quantity of contamination consumed. Information of this type would be disseminated to the public through a series of local public meetings and distribution of an informational pamphlet. Fish and Sediment Monitoring - In addition to maintaining the current fish advisory, annual monitoring of PCB levels in fish and sediment of Twelvemile Creek and Lake Hartwell would be conducted. Results from this monitoring program would be utilized to support modifications to the fish advisory and to monitor concentrations of PCBs in sediment and fish over time. Results of this program would be made available to the public. Regulation of Twelvemile Creek Impoundments - A routine schedule would be developed for flushing of sediment accumulated behind the 3 small impoundments located on Twelvemile Creek. Periodic flushing (most recently in September 1993) of a large load of sediment over a short Final ROD-Sangamo OU2 June 1994 period of time has been documented to have an adverse impact on the water quality and aquatic biota of the upper portion of the Twelvemile Creek Arm. These adverse impacts are attributed to elevated levels of suspended sediment and not PCBs. A routine flushing schedule would minimize impacts to the ecosystem while enhancing burial of more contaminated sediments with cleaner sediments from the Twelvemile Creek drainage. Capital Cost = $366,000 Total O&M Cost = $2,842,000 Total Present Worth Cost = $3,208,000 ALTERNATIVE 2B - FISHERIES ISOLATION Alternative 2B is a more aggressive approach consisting of management of the fisheries resource within the lake to minimize ingestion of PCB-contaminated fish. The primary control measure includes construction of a barrier, or fish fence, to prevent the movement of migratory fish (i.e. striped bass, hybrid bass, and walleye) into or out of the most contaminated portions of the reservoir. These migratory species represent approximately 50% of the fish harvested by weight from Lake Hartwell. Placement of the barrier in the vicinity of the Hwy 37 Bridge, just south of Clemson, would result in isolation of the Twelvemile Creek, Keowee River, and upper Seneca River Arms, which represent less than 10 percent of the total area of Hartwell Lake. Isolation of these upstream areas is expected to result in an accelerated decline in migratory fish PCB concentrations in the downstream portions of the reservoir (i.e., the remaining 90+ percent of the lake). Reduction of fish PCB levels would allow for rescinding of the existing health advisories in these areas, returning the majority of lake areas to normal use. This approach is consistent with the COE's Best Management Practices for Hartwell Lake, designed to achieve the maximum beneficial uses for the reservoir, which include fish and wildlife management and recreational use. The fish isolation barrier would be designed/constructed to meet the following performance standards: Minimize safety hazards for boaters and other users of the lake (i.e. waterskiers); Maximize effectiveness to prevent passage of migratory game fish through the barrier; Allow boats to pass unimpeded to minimize disruptions of boating traffic on the lake (i.e. no gate); Construct a semi-permanent structure that could be removed once PCB levels decline to health-based levels; Incorporate value engineering principles to minimize cost for design and construction; Final ROD-Sangamo OU2 June 1994 Minimize operations and maintenance requirements and costs; Design and installation of fish fence will not impede normal lake usage. This alternative would require an approximate 6 month predesign (treatability type) phase to develop a detailed design in accordance with the above performance standards. If pre-design studies are successful, full scale construction/installation of this remedy could be accomplished in approximately 1 year. PCBs would continue to accumulate in the fish upstream of the fish fence, therefore, fish are predicted to decline to protective levels (the 2.0 mg/kg FDA tolerance level) in approximately 12 years. By isolating the impacted upstream areas, PCB concentrations in migratory fish from the remaining 90+ percent of the lake are predicted to decline to the 2 mg/kg level in approximately 3-4 years. Lake use restrictions, such as no-wake zones and warning signs would be implemented to prevent damage to the fence and for boating safety. Alternative 2B also includes the institutional controls described for Alternative 2A. Capital Cost = $1,232,000 Total O&M Cost = $3,012,000 Total Present Worth Cost = $4,244,00O ALTERNATIVE 3A - CAPPING Alternative 3A involves the isolation of PCB-contaminated sediments by placing an 18 inch clean sediment cap over the areas with the highest contamination. The cap would be constructed using fine sand (minimum particle size 0.25 mm) to eliminate the further downstream migration of contaminated sediment and the transfer of PCBs from sediment to aquatic biota. The cap would extend 7 miles from just upstream of the Maw Bridge (Rt. 337) to the confluence with the Keowee River, just upstream of Hwy 123. The cap would cover an area of 730 acres and would require approximately 1,800,000 yd3 of sand to construct the cap. Figure 7-2 provides an illustration of the area to capped under this alternative. The cap thickness was designed to minimize the impacts associated with bioturbation and sediment burrowing biota (i.e. mayfly). Based upon sediment transport modeling for a cap with a minimum particle size of 0.25 mm, no significant erosion of cap material was observed in areas below the Madden Bridge. However in areas above the Madden Bridge (i.e., the "goose-neck" bend area), the model results showed erosion for all grain sizes tested (i.e., 10, 2, and 0.25 mm). These results indicate that maintenance of the cap would be difficult in the headwaters. Placement of the cap would be accomplished using a hydraulic barge unloader equipped with a sand spreader. The barge and sand spreader would likely be supplied with sand through a slurry pipeline between the barge and the shore or by a separate hopper barge. A local sand source has been identified near the community of Liberty, South Carolina. The cost estimate assumes <IMG SRC 0494178U> Final ROD-Sangamo OU2 June 1994 that the sand would be transported by truck to the staging area, converted to a slurry using lake water, and pumped out to the sand spreader barge. Placement of the cap, including design, procurement, and construction, would require approximately 2 years. Once the contaminated sediments were isolated beneath the cap, further transfer to biota would be significantly reduced, and PCB concentrations in the fish in Twelvemile Creek Arm would decline at an accelerated rate. A period of 3 to 4 years after cap placement would be required for the mean concentration of PCBs in largemouth bass filets to fall below the FDA limit of 2.0 mg/kg. As part of cap O&M, detailed hydrographic surveys would need to be conducted periodically to assess the integrity and overall performance of the clean sediment cap. These surveys would focus on the upstream segment of the cap in the area where sediment deposition and scour processes are most active. Alternative 3A also consists of lake usage restrictions to minimize erosion of the cap once it is placed and other institutional controls described under Alternative 2A. Capital Cost = $48,296,000 Total O&M Cost = $2,843,000 Total Present Worth Cost = $51,139,000 ALTERNATIVE 3B - SEDIMENT CONTROL STRUCTURE Alternative 3B involves the construction of a 1,600 ft. fixed-crest weir near the mouth of the Twelvemile Creek Arm. The weir would maintain a constant pool elevation of 660 ft MSL in the Twelvemile Creek Arm, minimizing the scour/erosion and resuspension of contaminated sediment in the headwaters and thereby reducing the downstream migration of PCB-contaminated sediment into Hartwell Lake. The constant pool elevation may also enhance the burial of these contaminated sediments in the upstream reaches. In addition, the weir would greatly reduce the migration of fish into and out of Twelvemile Creek Arm. The location of the sediment control structure is shown on Figure 73. The weir, or sediment control structure, would be an effective barrier to the downstream movement of suspended bedload sediments, which are transported just above the sedimentwater interface. The weir would allow water to flow from the Twelvemile Creek Arm to Hartwell Lake but would otherwise be an effective physical barrier between the two water bodies. The sediment control structure would not allow the passage of boats or other watercraft, and lakeshore property owners in the Twelvemile Creek Arm would not have direct boating access to or from Hartwell Lake. Monthly pool elevation data and the reservoir operating rule curve were used to select the crest elevation for the weir. Based on the pool elevation data, it is estimated that the pool elevation for Lake Hartwell is above 660 ft MSL approximately 23 percent of the time. The sediment control structure would be constructed of concrete by utilizing proven cofferdam techniques. <IMG SRC 0494178V> Final ROD-Sangamo OU2 June 1994 Implementation of Alternative 3B, including design and construction of the weir and establishment of institutional controls, would require approximately 2 years. Within the newly impounded Twelvemile Creek Lake, contaminated sediments would not be isolated from the biota and future contaminant trends in the fish would be as described under the Alternatives 1 and 2A. The time to achieve protectiveness in the main body of Lake Hartwell (i.e., the approximate 90+ percent of the total lake area downstream of the sediment control structure) was assumed to be comparable to that predicted for Alternative 2B (fish fence), given that both the weir and fish fence would greatly limit the movement of fish into and out of the area with the most highly contaminated sediment. Using this approach, the FDA Tolerance Level in migratory fish downstream of the sediment control structure would be attained in an estimated 3 to 4 years after construction of the weir was completed. To ensure public safety, watercraft would be restricted from the immediate vicinity of the sediment control structure. Fishing restrictions in the isolated area, as well as institutional controls under Alternative 2A, would be implemented to limit consumption of contaminated fish until protective levels were achieved. Capital Cost = $51,226,000 Total O&M Cost = $2,365,000 Total Present-Worth Cost = $53,591,000 ALTERNATIVE 3C - OPTIMAL CAPPING/SEDIMENT CONTROL STRUCTURE Value engineering techniques were used to combine elements of Alternatives 3A and 3B to achieve similar results with significantly lower costs and reduced impact to lakeshore residents and property owners. Figure 7-4 provides a conceptual approach to this alternative. The sediment control structure for Alternative 3C consists of a fixed-crest weir similar in design to the structure proposed in Alternative 3B. The proposed location for the weir under Alternative 3C is approximately 1,000 ft upstream of the Hwy 133 bridge. Placement of the structure at this location would isolate the areas having the highest levels of PCB contamination in the sediment while at the same time effectively isolating a smaller portion of the Twelvemile Creek Arm from the main lake. Moving the weir upstream also allows for its placement at a relatively narrow constriction of the channel, resulting in a much smaller weir (length-wise) and construction cost. The weir would also maintain an upper pool elevation of 660 ft, minimizing scour and resuspension of contaminated sediment in the headwaters of the Twelvemile Creek Arm. This action would minimize the migration of contaminated sediment into the lower portion of the Twelvemile Creek Arm and Hartwell Lake. The weir is also expected to reduce the movement of fish into and out of the areas of highest sediment PCB contamination. The area downstream of the sediment control structure to the mouth of the Twelvemile Creek Arm would be capped under this Final ROD-Sangamo OU2 June 1994 <IMG SRC 0494178W> Final ROD-Sangamo OU2 June 1994 alternative using the same performance criteria (e.g., prevent burrowing into underlying sediment), conceptual design parameters (e.g., 18-in. thick, sand-silt mixture), and construction methods (i.e., hydraulic sand spreader barge) as described for the Alternative 3A. The area for capping consists of approximately 285 acres and would require approximately 700,000 yd3 of material to construct. Cap integrity below the weir would be maintained using riprap and other reinforcing materials to prevent scour from flow over the top of the weir. Construction of the sediment control structure and placement of the cap would require a period of 2 to 3 years. Upstream of the weir, contaminated sediments are not isolated from the biota and thus PCB concentration in fish would continue to exceed the FDA limit of 2.0 mg/kg for the an estimated 12 years. Downstream of the weir in the Twelvemile Creek Arm, cap placement would accelerate the reduction of PCB levels in fish to protective levels because contaminated sediments have been isolated, limiting further transfer of PCBs to biota. An estimated period of 3 to 4 years (after cap placement) is required for PCB concentrations to fall below the FDA limit of 2.0 mg/kg in the capped area as well as in the main body of Hartwell Lake. Institutional controls under Alternative 2A and fishing restrictions upstream of the sediment control structure would be implemented until protective levels in the fish were achieved. Capital Cost = $31,684,000 Total O&M Cost = $2,365,000 Total Present Worth Cost = $34,049,000 ALTERNATIVE 4 - CONFINED DISPOSAL FACILITY Alternative 4 involves a much more rigorous remediation approach than any of the alternatives discussed above. This alternative involves removal by hydraulic dredging of contaminated sediment from the Twelvemile Creek Arm with PCB concentrations greater than 1 mg/kg followed by disposal of the dredged material in a Confined Disposal Facility (CDF). The conceptual approach to this alternative is shown in Figure 7-5. Implementation of Alternative 4 would be a complex undertaking controlled through scheduling and rigid conformance to procedural requirements needed to minimize environmental impacts. The following discussion provides an overview of the remedial construction activities associated with Alternative 4: Excavate channel - Rerouting the Twelvemile Creek Arm would begin immediately south of the high-tension powerline crossing and would proceed due south for a distance of approximately 1,600 ft. where it would reconnect with the original lake channel. The rerouted channel would be approximately 50 ft. wide at the base with a maximum excavation depth for the channel at approximately 55 ft. Material excavated during the channeling operation would be used for construction associated with the CDF. Rerouting the channel in this area would only isolate one shoreline residence on the goose-neck bend. <IMG SRC 0494178X> Final ROD-Sangamo OU2 June 1994 Construct Confined Disposal Facility - The COE commonly uses CDFs for disposal of dredged sediments. The goose-neck bend area between Maw and Madden Bridges was selected as the optimum location for the following reasons: 1) this area has most highly contaminated sediments avoiding the need to dredge approximately 1.3 million yd3 of material; 2) approximately 113 acres is available providing sufficient capacity for disposal of 5 million yd3 of material; and 3) minimal impacts on existing residents would occur. Dredge and pump dredged sediment into CDF - Sediments from entire Twelvemile Creek Arm with PCB concentrations >1 mg/kg would be removed via hydraulic dredging and transported to CDF via pipeline. Sediment would settle out in CDF, while water was returned to the lake. Compact/grade pediment to promote runoff followed by placement of soil cap over CDF. Additional detailed information regarding dredging techniques, dredged material characteristics, and design of the CDF would be required prior to implementation of Alternative 4. Implementation of the dredging alternative is expected to require a period of 3 to 4 years (including treatability testing, design, procurement and construction). Once sediments with greater than 1 mg/kg of PCBs have been removed from the lake, the FGETS model predicts that the mean PCB concentration in largemouth bass fillets would fall below the FDA limit of 2.0 mg/kg in 5 to 6 years. Institutional controls would be used to limit consumption of contaminated fish until protective levels were achieved. Capital Cost = $43,422,000 Total O&M Cost = $3,487,000 Total Present Worth Cost = $46,9O9,000 ALTERNATIVE 5 - STABILIZATION Alternative 5 is a very complex and costly alternative that involves removal of contaminated sediments with PCB concentrations greater than 1 ppm via a combination of shallow water excavation and hydraulic dredging. Contaminated sediments in the middle and lower portions of Twelvemile Creek Arm would be dredged while the upper portion is dewatered and excavated. The dredged/excavated sediments would be treated by stabilization with cement and placed in a CDF as described under Alternative 4. Fish and other biota in the upstream segment would be collected and destroyed as part of the dewatering operations. This alternative was evaluated in an attempt to satisfy the preference for treatment as a principal element for selected remedial alternatives at NPL sites. Implementation of Alternative 5 would likely trigger a substantial number of ARARs, the most significant being the Clean Water Act and South Carolina Water Classification Standards. Based on a volume estimate of 4,722,000 yd3 for excavation and dredging, expected stabilization production rates, and the rate Final ROD-Sangamo OU2 June 1994 at which the confined disposal facility can be filled, implementation of Alternative 5 would entail a duration of 4 to 5 years. Once the contaminated sediment has been removed, fish PCB concentrations downstream of the Madden Bridge would decline at an accelerated rate, achieving the FDA tolerance level in approximately 5 to 6 years. The time to achieve protectiveness for this alternative therefore is 9 to 11 years. Capital Cost = $581,957,000 Total O&M Cost = $3,486,000 Total Present Worth Cost = $585,443,000 8.0 SUMMARY OF THE COMPARATIVE ANALYSIS OF ALTERNATIVES This section documents the comparative analysis conducted to evaluate the relative performance of each alternative in relation to each of the evaluation criteria. The purpose is to identify and clearly understand the advantages and disadvantages of each remedial alternative described in Section 7.0 of this ROD. As stated in NCP [40 CFR 300.430 (f)], the evaluation criterion are arranged in a hierarchial manner that is then used to select a remedy for the site based on the following categories: Threshold Criteria: Overall Protection of Human Health and the Environment Compliance with ARARs Primary Balancing Criteria: Long-term Effectiveness and Reduction of Toxicity, Mobility, or Volume Short-term Effectiveness Implementability Cost Modifying Criteria: State Acceptance Community Acceptance The Threshold criteria must be met before an alternative is eligible for selection as a preferred alternative in the Proposed Plan and ultimate selection in the ROD. The five Primary Balancing Criteria provide the basis for determining which alternative provides the best balance of trade-offs among all others considered. The State of South Carolina has reviewed this ROD and concurs with EPA's selected remedy described in Section 9.0. The State of South Carolina concurrence letter is attached as Appendix A to this ROD. Community Acceptance is addressed in the Responsiveness Summary attached as Appendix B to this ROD. The following discussion addresses the Threshold and Primary Balancing Criteria. 8.1 OVERALL PROTECTION OF HUMAN HEALTH AND THE ENVIRONMENT Overall protection of human health and the environment addresses whether each alternative provides adequate protection of human health and the environment and describes how risks posed Final ROD-Sangamo OU2 June 1994 through each exposure pathway are eliminated, reduced, or controlled, through treatment, engineering controls, and/or institutional controls. Complexities related to the cycling of PCBs in the biota of Lake Hartwell cause residual risk levels to remain above 1 x 10-4 regardless of which remedial action alternative is implemented. A reduction in sediment PCB concentrations does not result in an immediate reduction in PCB concentrations in fish. High PCB concentrations in fish during the initial years of the 30-year exposure duration result in average risk estimates exceeding acceptable levels. Therefore, all of the alternatives rely on institutional controls to minimize exposures to PCB-contaminated fish tissue (limiting these exposures was identified as one of the primary remedial action objectives). These controls include public education and continuation of the current fishing advisory. The most protective alternatives are those that rely principally on engineering rather than institutional controls to reduce or eliminate exposures, given the uncertainty regarding the performance/reliability of the institutional controls. The removal/disposal and removal/treatment/disposal actions under Alternatives 4 and 5, respectively, provide the highest level of protectiveness, as the contaminated material is removed from the lake and isolated in an engineered disposal facility. Alternative 2B entails construction of a fish fence to be designed and constructed so as to maximize effectiveness while minimizing operations and maintenance; however, additional, predesign studies would be needed to develop the actual design for the structure. Alternatives 3A and 3C involve capping actions that should permanently isolate the contaminated sediment in all or a major portion of the Twelvemile Creek Arm. The capping would be highly protective of human health and the environment; its reliance on long-term monitoring and maintenance to assure cap integrity is a disadvantage but does not compromise the overall protectiveness or long-term effectiveness of the action. 8.2 COMPLIANCE WITH APPLICABLE OR RELEVANT AND APPROPRIATE REQUIREMENTS (ARARs) Section 121 (d) of CERCLA requires that remedial actions at NPL sites at least attain legally applicable or relevant and appropriate federal and state requirements, standards, criteria and limitations which are collectively referred to as "ARARs", unless such ARARs are waived under CERCLA section 121 (d) (4). Applicable requirements are those substantive environmental protection reguirements, criteria, or limitations promulgated under federal or state law that specifically address hazardous substances found at the site ("contaminant-specific ARARs), the remedial action to be implemented at the site ("action-specific ARARs"), the location of the site ("location-specific ARARs"), or other circumstances at the site. Relevant and appropriate requirements are those substantive environmental protection requirements, criteria, or limitations promulgated under federal or state law which, while not applicable to the hazardous substances found at the site, the remedial action itself, the Final ROD-Sangamo OU2 June 1994 site location or other circumstances at the site, nevertheless address problems or situations sufficiently similar to those encountered at the site that their use is well-suited to the site. All of the alternatives rely on natural fate and transport processes to reduce PCB concentrations in Lake Hartwell fish to the FDA tolerance level of 2 mg/kg. Several alternatives include actions designed to speed up the rate at which these natural processes act (i.e. by capping or removing contaminated sediment). No contaminant-specific ARARs for PCBs in sediment were identified, which led to the identification of To-BeConsidered (TBC) criteria and the selection of a sediment cleanup goal of 1 mg/kg based on an evaluation of these criteria. Alternatives 3A (Capping), 4 (Confined Disposal Facility) and 5 (Stabilization) would best achieve the TBC criteria for sediment. The sediment control structures (Alternatives 3B and 3C) are expected to impact PCB concentrations in the sediment, but not to the same extent as capping or removal. Alternatives 4 and 5 would trigger the largest number of and most complex action- and location-specific ARARs, including the Clean Water Act dredge-and-fill requirements, South Carolina requirements for surface water discharges, and, if PCB concentrations in dredged/excavated sediments exceed 50 ppm TSCA requirements for handling/storage/treatment/disposal. The alternatives could be designed and implemented to attain compliance with these requirements. Capping activities under alternatives 3A and 3C would also trigger Clean Water Act and South Carolina requirements related to surface water discharges; compliance with these requirements would be factored into the design and implementation. Action-specific ARARs were not identified for the institutional controls under any alternative or for construction of the fish fence under Alternative 2B. 8.3 LONG-TERM EFFECTIVENESS AND PERMANENCE Long-term effectiveness and permanence refers to the expected residual risk and the ability of a remedy to maintain reliable protection of human health and the environment over time. The criterion includes the consideration of residual risk and the adequacy and reliability of controls. Contaminant transport and bioaccumulation modeling conducted during the RI showed that Lake Hartwell is a dynamic system in which PCB concentrations in sediment and biota are gradually declining in response to natural fate and transport processes such as burial by clean sediment, resuspension and desorption followed by flushing out of the reservoir, and other processes. The modeling results indicate that PCB levels in the sediment will decline below the 1 mg/kg cleanup goal in 5 to 10 years (depending on location within Twelvemile Creek Arm) and that PCB concentrations in fish will decline to the FDA tolerance level in 12 years. If the modeling predictions are accurate, even Alternative 1 (No Action) would eventually result in a permanent solution for the site in approximately 12 years, given that consumption of contaminated fish was the primary exposure pathway of concern. Final ROD-Sangamo OU2 June 1994 Alternatives 2 to 5 rely on institutional controls to prevent exposure to contaminated fish; the performance and reliability of these controls is dependent on site-specific factors and therefore difficult to predict. In the context of technology performance and reliability, the fish fence (Alternative 2B) has not been proven for the same scale of application proposed for Sangamo OU2. Capping (Alternatives 3A and 3C) is a proven technology but is dependent on an extensive program of monitoring and maintenance to ensure cap integrity and long-term effectiveness. Capping of only the downstream portion of the Twelvemile Creek Arm under Alternative 3C would result in a cap that was easier to maintain, and therefore, it should have a higher degree of long-term effectiveness. Sediment control structures (Alternatives 3B/3C) are also widely used and are less dependent on maintenance. Although dredging and confined disposal facilities are widely recognized as reliable technologies, further technology evaluation, in the form of pilot-scale treatability studies, would be needed to obtain design and operating data essential to minimize environmental impacts. Similarly, stabilization treatability studies under Alternative 5 would require further technology evaluation to determine material handling and process requirements (e.g., optimum stabilization mixture). Treatability studies are also needed to determine effluent treatment requirements for the dewatering fluids from the confined disposal facility or material handling/stockpiling areas. 8.4 REDUCTION OF TOXICITY, MOBILITY, OR VOLUME Reduction of toxicity, mobility, or volume through treatment refers to the anticipated performance of the treatment technologies for the remedy. None of the alternatives has an effect on the toxicity of the contaminants, expect Alternative 5 which involves treatment by stabilization. Alternative 5 would accomplish the most significant reduction in the mobility of PCBs through a stabilization treatment process, followed by disposal in a confined disposal facility. Contaminant mobility would also be reduced through disposal in a CDF, with no treatment, in Alternative 4. The capping alternatives (Alternatives 3A and 3C) also accomplish a reduction in contaminant mobility, but the effect is contingent upon proper maintenance of the cap. Reductions in contaminant mobility are expected with the sediment control structures (Alternatives 3B and 3C), primarily through maintaining pool elevation, thereby decreasing scour/erosion in the headwaters. The capping, sediment control structures and fish fence alternatives also reduce PCB transfer to migratory fish by isolating the contaminated sediment (through capping) or restricting the migration of fish into and out of the areas with the highest sediment contamination (through the fence or weirs). The net result is a reduction in the level of PCB contamination in lake-wide migratory fish. Final ROD-Sangamo OU2 June 1994 8.5 SHORT-TERM EFFECTIVENESS Short-term effectiveness refers to the period of time needed to complete the remedy and any adverse impacts on human health and the environment that may be posed during the construction and implementation of the remedy. Implementation of Alternatives 1 (No-Action) and 2A (Institutional Controls) would have the least impact on the community, workers, and the environment; Alternative 2B has only a slightly greater impact. Alternatives 3A/3B/3C have greater impacts on the local community due to construction of sediment control structures and excessive truck traffic associated with the transportation of capping material. The greatest impacts (and least short-term effectiveness) are associated with the more aggressive alternatives that entail dredging, re-channeling, and construction of the CDF (Alternatives 4/5). Table 8-1 summarizes the estimated schedule for each alternative, presenting the time required to implement, time required for fish PCB concentrations to decline to protective levels (FDA tolerance level), and total time for alternative to achieve protectiveness. Because the most highly contaminated sediment is concentrated in a relatively small, upstream portion of the lake that represents less than 10 percent of the reservoir area, separate estimates are shown for the time to attain FDA levels and time to achieve protectiveness in both this upstream portion (i.e., the Twelvemile Creek/Seneca River Arm) and in the main body of Hartwell Lake. The impact on a given alternative with regard to protective levels throughout the lake is an important consideration given the significant resource potential of the reservoir. It is important to note that the time required for implementation includes design, procurement, and construction but does not consider the time between issuance of the Proposed Plan/signing of the ROD and initiation of the Remedial Design. The table shows that isolation or removal of the most highly contaminated sediment, through fisheries isolation, capping, sediment control structures, or dredging often has a much greater effect on PCB levels in downstream areas than within the Twelvemile Creek Arm. This response is mostly due to the impact of limiting or preventing the movement of migratory fish into and out of the areas with the more highly contaminated sediment (lake-wide, non-migratory fish have exceeded the FDA levels on an infrequent and isolated basis while migratory fish have typically had PCB levels higher than 2 mg/kg). Accelerated declines in PCB levels would be expected for alternatives involving capping or removal; otherwise, PCB reductions would be accomplished only through natural fate and transport processes conditions. The most favorable alternatives with regard to the estimated time to achieve protectiveness would be Alternatives 2B and 3A; fisheries isolation (Alternative 2B) is more quickly implemented and therefore leads to a slightly faster reduction in PCB levels in the main body of Hartwell Lake but the capping alternative would have a much greater effect in the Twelvemile Creek/Seneca River Arm. If more than 1 to 2 years elapse between the signing Final ROD-Sangamo OU2 June 1994 Table 8-1 Estimated Time to Achieve Protectiveness TIME FOR FISH TO ATTAIN FDA LEVEL TIME TO A PROTECTIVENESS(4) (yrs) ALT. BODY OF NO. DESCRIPTION HARTWELL LAKE 2 No action 2A Institutional TIME TO IMPLEMENT(1) (yrs) TWELEMILE CREEK/SENECA RIVER(2) ARM 0 0.5 12 12 MAIN BODY OF HARTWELL LAKE(3) 12 12 R 2B 3A 3B 3C 4 5 Fisher Isolation Capping Sediment Control Structure Optimal Capping/Sediment Control Structure Confined Disposal Facility Stabilization 1 2 2 2-3 3-4 4-5 12 3-4 12 3-4 (downstream) 12 (upstream 5-6 5-6 3-4 3-4 12 3-4 5-6 5-6 NOTE: (1) Includes time needed for pre-design studies, procurement, and constr between Proposed Plan/Record of Decision and initiation of Remedial Design. (2) Twelvemile Creek Arm only; FGETS modeling results indicate that fish mg/kg) in approximately 12 years under baseline conditions; none of the alternatives will extend the period required for this to period to achieve protectiveness of greater than 12 yrs). (3) Downgradient of the Twelvemile Creek Arm (i.e., main body of Hartwel decline more rapidly for actions involving isolating, capping or removal of contaminated sediment (Alternatives 2B, 3A-C, 4 and 5). It was a comparable to that observed in the Twelvemile Creek Arm for Alternatives involving capping (3-4 yrs) or removal of the sediment verify this estimated. (4) Duration only; based on estimated time to implement remedy and durat to decline to FDA level, based on the FGETS modeling results presented in Section 3.3 and assumptions regarding migratory Final ROD-Sangamo OU2 June 1994 of the ROD and the initiation of the Remedial Design, the dredging alternatives (Alternatives 4/5) will not achieve protectiveness appreciably faster than that obtained under baseline (no-action) conditions. 8.6 IMPLEMENTABILITY Alternatives 1 and 2A would be the most readily implementable; the main activity associated with the institutional controls under Alternative 2A (and other alternatives) involves planning and coordination with COE, SCDHEC, and other agencies. Alternative 2B (Fish Fence) would be somewhat more complex to implement, primarily due to the predesign testing to assess the suitability of various designs. Alternatives 3A, 3B, and 3C represent an intermediate range of implementability. Capping and weirs have been successfully constructed at a wide variety of sites and conditions at Hartwell Lake and should not present any unusual difficulties. The reduced scale of the area to be capped and size of weir for Alternative 3C would simplify both design and construction activities associated with these individual components. A limitation to Alternative 3A and, to a lesser extent, 3C, concerns the availability and transportation logistics of as much as 1.8 million yd3 of capping material. From a technical and engineering perspective, construction of the fixed crest weirs for Alternatives 3B and 3C should be much more implementable than capping due to the likelihood of encountering problems with the capping materials. The most difficult alternatives to implement, in terms of both technical and administrative feasibility, would be Alternatives 4 and 5; both involve dredging, which is a widely used technology, but they would still require considerable predesign testing and evaluation to optimize operations and minimize environmental impacts. Construction of the confined disposal facility in what is currently a large body of open water and rechanneling the Twelvemile Creek Arm through a forested ridge would also present a number of technical challenges, while not insurmountable, the challenges do make implementation of Alternatives 4 and 5 considerably more complex than the other remedial alternatives. These alternatives would also have the greatest administrative requirements due to the need to fulfill permit-related requirements related to Clean Water Act dredgeand-fill permits, South Carolina NPDES permits, and possibly other permitted activities. 8.7 COST Costs for each alternative were provided under Section 7.3 of this ROD. Alternative 5 is the most expensive alternative to implement, and is considered cost prohibitive. The more aggressive alternatives (Alternatives 3A/3B/3C/4) that involve engineering controls to satisfy the remedial action objectives have total present worth costs that generally range from $30-50 million. Alternative 2B achieves protectiveness in the main body of Lake Hartwell in a shorter amount of time than the other more Final ROD-Sangamo OU2 June 1994 aggressive and passive (Alternatives 1/2A) alternatives for only an additional $1 million over the cost of Alternative 2A (estimated present worth cost of $3,208,000). The No-Action alternative is the least expensive. 9.0 THE SELECTED REMEDY This section of the ROD discusses EPA's selected remedy in detail for the Sangamo OU2 Site. EPA has selected Alternative 2A - Institutional Controls to address the contaminated sediments and fish at the Site. The selected remedial alternative for the Sangamo OU2 Site consists of the following components: 1) continuation of existing fish advisory; 2) public education program; 3) future sediment and aquatic biota monitoring; and 4) regulation of the Twelvemile Creek Impoundments. These primary components are discussed below. 9.1 CONTINUATION OF EXISTING FISH ADVISORY The existing fish advisory on Lake Hartwell shall remain in effect. Signs warning against consuming fish have been posted at the majority of the public boat launch and recreation areas since 1987. Figure 9-1 provides an illustration of the posted advisory. The advisory is currently maintained by SCDHEC, and SCDHEC will remain responsible for management, supervision, and administration of the fish consumption advisory in the future. The advisory will be modified if warranted by future trends regarding PCB concentrations in fish. Modifications shall be fully supported and justified by the annual monitoring program discussed in Section 9.3 of this ROD. Maintaining the fish advisory will likely entail the posting and replacement of signs describing the advisory at access points along the shoreline. For purposes of enhancing the effectiveness of the advisory, additional signs may be posted. Additional activities designed to increase public awareness of the existing fish consumption advisory are discussed in Section 9.2 of this ROD. As discussed in the Section 5.4.3, FGETS bioaccumulation food-chain modeling, the mean PCB concentration in 2-8 year old largemouth bass is predicted to fall below the FDA limit by year 10. However, a longer period of time is required for concentrations in higher age classes to fall below the FDA limit. PCB concentrations in 10-year-old fish, representing the highest age class and largest fish in the model, required 12 years to fall below the 2.0 mg/kg FDA limit. For these reasons, it was assumed that the fish consumption health advisory would remain in effect for a minimum of 12 years, or the year 2005. 9.2 PUBLIC EDUCATION PROGRAM Proper preparation of contaminated fish can reduce the quantity of contamination consumed. Contaminants (PCBs) are generally stored in fatty tissue (i.e., belly flap, strip along the backbone and lateral line, and skin). By removing these Final ROD-Sangamo OU2 June 1994 ATTENTION FISH CONSUMPTION ADVISORY-LAKE HARTWELL S.C. DEPARTMENT OF HEALTH AND ENVIRONMENTAL CONTROL (SCDHEC) ALL FISH TAKEN FROM THE SENECA RIVER ARM OF LAKE HARTWELL NORTH OF SC HIGHWAY 24 AND 12 MILE CREEK SHOULD BE RELEASED AND NOT EATEN. ALL FISH LARGER THAN THREE (3) POUNDS TAKEN FROM THE REMAINDER OF LAKE HARTWELL SHOULD BE RELEASED AND NOT EATEN. FISHING IS NOT PROHIBITED BUT SCDHEC ADVISES THAT THESE FISH NOT BE EATEN DUE TO THE PRESENCE OF ELEVATED LEVELS OF POLYCHLORINATED BIPHENYLS (PCBs). SWIMMING, BOATING, AND OTHER WATER RELATED ACTIVITIES ARE NOT RESTRICTED BY THIS ADVISORY. FOR ADDITIONAL INFORMATION, CONTACT SCDHEC AT: COLUMBIA 734-5300 GREENVILLE 242-9850 ANDERSON 225-3731 Figure 9-1 Current Lake Hartwell Fsh Advisory Final ROD-Sangamo OU2 June 1994 areas when cleaning the fish, individuals can substantially reduce their intake of PCBs. Broiling, baking, and grilling fish also provides additional risk reduction. Many states, including Georgia, provide fish preparation suggestions to the public in pamphlets and other publications on state fishing regulations; South Carolina currently does not. EPA shall develop a pamphlet that outlines methods, including those described above, for reducing the intake of contaminants through fish consumption. This pamphlet will be distributed to the general public and to frequent Lake Hartwell resource users. The most effective method of distribution to the general public is to provide the pamphlet to everyone who purchases a fishing license. Thus, all establishments that sell fishing licenses in the Hartwell Lake area will be supplied with the pamphlets, as will marinas and selected retail establishments (i.e., convenience stores) in the area. In addition to the pamphlets, advertisements will be placed periodically in newspapers from all of the counties surrounding the lake. The advertisements will reiterate the potential risks associated with consumption of PCB-contaminated fish from Lake Hartwell. Printed information regarding the fish advisory will also be supplemented with periodic public meetings hosted by EPA, SCDHEC, and the COE. Public meetings will begin the first year following signing of the ROD and will be held at a minimum of 5-year intervals. The public meetings will serve to update the general population on PCB concentration trends in sediment and fish as well as the latest estimates of PCB-related risks resulting from consumption of contaminated fish. Analytical results from the annual monitoring program described in Section 9.3 and the fiveyear reviews, as required by CERCLA, will be disseminated to those attending these meetings, local citizens, and frequent lake users. The meetings would also provide a forum for public input into the decision-making process regarding continued institutional controls for the lake. The proposed locations for these meetings include: Anderson, S.C. Cateechee/Norris S.C. Clemson, S.C. Hartwell, Ga. Seneca, S.C. The above public education program represents a baseline approach. EPA, COE, and SCDHEC will periodically evaluate the overall approach and effectiveness of this program by soliciting public comment and input from Lake Hartwell resource users. Creel surveys, similar to those conducted as part of the Biological Investigation, may also be utilized as a mechanism to obtain information from anglers on Lake Hartwell. The public education program is expected to evolve while attempting to identify the most productive method(s) for reaching the targeted audience. EPA, in close consultation with SCDHEC and the COE shall modify the public education program as required. Final ROD-Sangamo OU2 June 1994 9.3 AQUATIC BIOTA AND SEDIMENT MONITORING This section describes the program of annual monitoring of PCB levels in the fish, corbicula, and sediment of Lake Hartwell and the Twelvemile Creek watershed. 9.3.1 AGUATIC BIOTA MONITORING In the interest of consistency and to support trend analysis, fish samples will be collected from the same 6 Lake Hartwell stations that have been utilized historically by SCDHEC and also during the Biological Investigation. These stations are shown on Figure 9-2 and are generally described as follows: SV-107 Twelvemile Creek Arm of Lake Hartwell in the vicinity of County Road 37; Pickens County, SC. SV-106 Seneca River Arm of Lake Hartwell in the vicinity of Martin Creek; Anderson County, SC. SV-532 Seneca River Arm of Lake Hartwell in the vicinity of Eighteen Mile Creek; Anderson County, SC. SV-535 Andersonville Island area of Lake Hartwell near the confluence of the Tugaloo and Seneca Rivers; Anderson County, SC. SV-641 Tugaloo River Arm of Lake Hartwell in the vicinity of Interstate I-85; Oconee County, SC. SV-642 Open water area of Lake Hartwell in the vicinity of Hartwell Dam; Anderson County, SC. Fish samples shall be collected annually in the spring using gill nets and/or electrofishing techniques. Hybrid bass (weight class 3.0-5.0 lbs.), largemouth bass (weight class 1.5-3.0 lbs.) and channel catfish (weight class 2.0-4.0 lbs.) will be collected from the above 6 stations in Lake Hartwell. In past sampling events, 10 hybrid bass, 10 largemouth bass, and 4 catfish were collected at each station to calculate a representative mean. The adequacy of these respective numbers in determining a representative mean concentration in fish tissue is currently under review by SCDHEC. In any event, sampling conducted pursuant to this ROD will at a minimum include 10 hybrid bass, 10 largemouth bass, and 4 catfish. Game fish shall be prepared in accordance with the standard US FDA fillet method ti.e., fillet including rib cage and belly flap with skin on and scales off except for catfish where skin is removed.). All fish shall be analyzed for the PCB component of EPA,s Target Compound List (TCL). Forage fish, consisting of gizzard shad/blueback herring, threadfin shad and bluegill, shall be collected at stations SV107, SV-532, and SV-641. Forage fish will be collected concurrently with game fish sampling discussed above using electrofishing techniques. Samples will consist of whole body composite samples for each species. All forage fish samples <IMG SRC 0494178Y> Final ROD-Sangamo OU2 June 1994 shall be analyzed for PCBs. Data generated from the forage fish collection and analyses shall be utilized to support future foodchain modeling activities. In addition to fish sampling in Lake Hartwell, corbicula (fresh water clams) baskets will be placed at 6 locations in Twelvemile Creek for 28 days each in the spring of each year to determine current PCB loading into the Twelvemile Creek system. The sampling locations for corbicula baskets are shown on Figure 9-3. Corbicula baskets will be deployed concurrent with the fish sampling activities described above. After 28 days, baskets shall be recovered and analyzed for PCBs. 9.3.2 SEDIMENT MONITORING Sediment monitoring locations are shown in Figures 9-4 and 9-5. Sediment samples shall be collected annually from 15 locations in Hartwell Lake and 5 locations in the watershed. Sediments will be collected using a ponar dredge. Stations SD001 through SD-005 in the Twelvemile Creek watershed will be discrete samples. For the remaining 15 locations in Lake Hartwell, a transect shall be established at each station and 5 grab samples will be collected along the transect. These 5 samples shall be composited to provide a mean concentration of PCBs in surface sediments from a given transect. Sample and transect locations shall be established with sufficient accuracy to enable collection of future samples from same locations. Details of the sediment sample locations in Twelvemile Creek and Lake Hartwell are presented in Table 9-1. All sediment and aquatic biota monitoring shall continue under the direction of EPA. Data from the annual monitoring will allow EPA, SCDHEC and COE to continue ongoing efforts to evaluate contamination trends in the sediment and biota. These trends will be used to support decisions to modify the advisory, in response to PCB concentration trends in the fish. Annual monitoring results shall be summarized and disseminated to the public in support of the public education program described under Section 9.2. For purposes of the cost estimate described in Section 9.6, it was assumed that this annual monitoring program will continue for a minimum of 15 years from signature of the ROD. 9.4 REGULATION OF TWELVEMILE CREEK IMPOUNDMENTS The Federal Energy Regulatory Commission (FERC) regulates hydroelectric facilities in the U.S. Currently, the middle and lower impoundments on Twelvemile Creek, Woodside I and II, respectively, are non-licensed hydroelectric impoundments based on the date of construction and navigability of Twelvemile Creek. These impoundments effectively trap a large portion of the sediment load from Twelvemile Creek, and as a result, are flushed periodically to remove sediment and to restore storage capacity within the impoundments. Historically, these trapped sediments have contained high levels of PCBs. However, the RI and subsequent sampling in response to a recent flushing event (September 1993) have shown that more recent sediment <IMG SRC 0494178Z> <IMG SRC 04941781> <IMG SRC 04941782> Final ROD-Sangamo OU2 June 1994 TABLE 9-1 Sediment Sample Locations in Twelvemile Creek Watershed and Arm of Lake Hartwell Station ID Location SD-001 Town Creek downstream of Sangamo Weston outfall - same location as corbicula basket 2 SD-002 Twelvemile Creek upstream of Wolf Creek confluence - same location as corbicula basket 3 SD-003 Wolf Creek downstream of Breazeale site - same location as corbicula basket 4 SD-004 Twelvemile Creek at Easley-Central impoundment same location as corbicula basket 5 SD-005 Twelvemile Creek at Lay Bridge SD 006 Maw Bridge SD-007 - 009 Between Maw and Madden Bridges SD 010 Madden Bridge SD-011 Between Madden and Hwy 133 Bridges SD-012 Hwy 133 Bridge SD-013 Mouth of Twelvemile Creek Arm SD-014 Between US 123 and Hwy 93 Bridges SD-015 Hwy 37 Bridge SD-106 SV-106 fish sampling station SD-532 SV-532 fish sampling station SD-535 SV-535 fish sampling station SD-641 SV-641 fish sampling station SD-642 SV-642 fish sampling station accumulating behind the small dams has relatively low levels of PCB contamination (1 to 3 mg/kg). These low concentrations confirm that PCB-contaminated sediments continue to flow down Twelvemile Creek into Hartwell Lake, but the magnitude of this contaminant flux is small. Although flushing of these impoundments is not currently contributing appreciable quantities of PCB contamination to the Twelvemile Creek Arm of the lake, the release of the equivalent of a half-year's sediment load (or more) during a short time period (typically less than 1 week) has been documented to have potentially significant adverse effects on water quality in the upper portion of the Twelvemile Creek Arm. The influx of sediment in the most recent flushing event (September 1993) was observed to result in a notable fish kill in Twelvemile Creek below the impoundments and in the upper portion of the Twelvemile Final ROD-Sangamo OU2 June 1994 Creek Arm. This was attributed to elevated levels of suspended sediments and not PCBs. Similar and possibly more damaging effects to benthic organisms within the upper portion of the reservoir are also likely to occur. The frequency at which these impoundments are flushed is based primarily on an operations schedule established by the owner/operator rather than hydraulic or other technical constraints. To minimize the negative impacts on water quality, and to facilitate burial of relatively more contaminated sediments downstream, EPA's selected remedy shall include the development of a routine schedule for sluicing of all three impoundments (i.e., Woodside I and II, and Easley-Central Water District). Quarterly flushing of these impoundments is thought to be adequate to minimize the negative impacts. Preliminary discussions with Consolidated Hydro, Inc., owners/operators of Woodside I and II, have indicated a willingness to comply with this requirement. It is estimated that approximately $200,000 in capital improvements to the gating mechanisms are necessary to fulfill the objectives of this component of EPA's selected remedy. Compliance with the routine schedule shall be monitored by SCDHEC. In addition, water quality and sediment monitoring will be conducted on downstream areas during the sluicing events to facilitate modification of the schedule as needed. 9.5 FIVE YEAR REVIEWS As required by CERCLA, 5-year reviews will be conducted to ensure that the alternative remains protective of human health and the environment. The results of the annual monitoring studies shall be incorporated into the 5-year reviews. The 5year reviews shall continue at intervals no less often than 5 years following signature of this ROD until protectiveness has been achieved. 9.6 COST ESTIMATE Table 9-2 provides a cost breakdown, by component, of Alternative 2A - Institutional Controls. The estimated total present worth cost for EPA's selected remedy is $3,208,000, which includes $366,000 of capital costs. Final ROD-Sangamo OU2 June 1994 TABLE 9-2 Cost Estimate for EPA's Selected Remedy, Alternative 2AInstitutional Controls Remedy Component/ Cost Item Fish Advisory Public Education Capital Cost ($) $4,000 O&M Cost ($/yr.) $1,000 $33,000 O&M Cost ($5/yrs.) $25,000 Present Worth Cost ($) $12,000 $314,000 Biota & Sediment Monitoring Twelvemile Creek Impoundments 5-Year Reviews Subtotal $132,000 $1,202,000 $200, 000 $200,000 $204,000 $166,000 $28,000 $53,000 $60,000 $1,788,000 10% 5% $20,000 $10,000 $17,000 $8,000 $5,000 $3,000 $179,000 $89,000 15% $31,000 $265,000 $25,000 $216,000 $8,000 $69,000 $268,000 $2,324,000 Indirects/Profit Subtotal Contingency 20% TOTAL $40,000 $305,000 $61,000 $366,000 $32,000 $248,000 $50,000 $298,000 $10,000 $79,000 $16,000 $95,000 $349, 000 $2,673,000 $535,000 $3,208,000 Engineering Procurement Construction Management Subtotal 10.0 STATUTORY DETERMINATIONS This section of the ROD describes how EPA's selected remedy, Alternative 2A - Institutional Controls, meets the statutory requirements as delineated in Section 121 of CERCLA. 10.1 PROTECTION OF HUMAN HEALTH AND THE ENVIRONMENT The extent to which EPA' selected remedy is protective of human health and the environment is directly dependent upon the effectiveness of the institutional controls that are the principal components of this response action. The reliability of the institutional controls in limiting exposure is difficult to predict due to the significance of site-specific demographic factors governing the likely response of the public to the advisory and other component of this remedy that are designed to limit exposures. Risks posed by the primary exposure pathway, ingestion of PCB contaminated fish, are declining due to natural fate and transport processes, primarily the burial of contaminated sediment. Baseline modeling activities predict that PCB concentrations in largemouth bass fillets would decline to the FDA tolerance limit in approximately 12 years (year 2005). Final ROD-Sangamo OU2 June 1994 Effective implementation of the institutional controls described in Section 9.0 of this ROD would limit exposures until PCB contamination dropped to these protective levels. Therefore, this alternative is considered to be adequately protective of human health and the environment. 10.2 COMPLIANCE WITH APPLICABLE OR RELEVANT AND APPROPRIATE REQUIREMENTS The only applicable requirement identified for the selected remedy is the contaminant-specific ARAR governing PCB concentrations is fish. Continuation of the existing fish advisory in conjunction with the aggressive public education program addresses the FDA requirement governing consumption of PCB contaminated fish. No sediment-related, contaminant-specific ARARs were identified. TBC and health-based criteria for sediment were identified in the discussions of ARARs and sediment cleanup goals. Alternative 2A does not attain the TBC or health-based levels directly, but these levels would be attained through natural sedimentation processes in the reservoir. Depending on the area of the Twelvemile Creek Arm, the selected TBC sediment cleanup goal of 1 mg/kg will be attained in a period of 5-10 years. 10.3 COST EFFECTIVENSS EPA believes this remedy will minimize risks posed to human health and the environment at an estimated cost of $3,208,000. Complexities related to the cycling of PCBs in the aquatic biota of Lake Hartwell cause residual risk levels to remain above acceptable levels regardless of which remedial alternative is implemented. The most effective means to limit exposure to PCBcontaminated fish is by the effective implementation of the primary components of EPA's selected remedy, Alternative 2A Institutional Controls. Therefore, in terms of risk-reduction for money spent, Alternative 2A is the most cost-effective remedial alternative that was evaluated in detail by EPA. 10.4 UTILIZATION OF PERMANENT SOLUTIONS AND ALTERNATIVE TREATMENT TECHNOLOGIES TO THE MAXIMUM EXTENT PARTICABLE EPA has determined and the State of South Carolina has concurred with EPA's determination that the selected remedy represents the maximum extent to which permanent solutions can be utilized in a practicable manner for Operable Unit Two of the Sangamo Site. Engineering controls and treatment technologies did not offer a significant advantage in terms of overall risk reduction for the cost. EPA and the State have determined that the selection of Alternative 2A - Institutional Controls, provides the best balance of trade-offs in terms of the five balancing criteria, while also considering the statutory preference for treatment as a principal element and community acceptance. The selected remedy addresses the primary risk associated with Sangamo OU2, the ingestion of PCB contaminated fish, by the most effective means practicable. Final ROD-Sangamo OU2 June 1994 10.5 PREFERENCE FOR TREATMENT AS A PRINCIPAL ELEMENT EPA's selected remedy does not satisfy the preference for treatment as a principal element due to the excessive costs (> $500 million) associated with removal, treatment and disposal of approximately 4.7 million cubic yards of PCB contaminated sediment spread out over approximately 730 acres. Moreover, alternatives that involved aggressive engineering controls to contain, remove, and dispose of PCB contaminated sediment ranged from $30-$50 million without offering a significant advantage in terms of overall risk reduction. 11.0 DOCMENTATION OF SIGNIFICANT CHANGES Pursuant to the requirements of Section 117(b) of CERCLA, this section of the ROD documents and discusses the reasons for significant changes made to the selected remedy from the time the Proposed Plan was released to the public to the final selection of the remedy in this ROD. For reference, the Proposed Plan is attached to this ROD as Appendix C. Specific written and/or oral comments received during the formal 60-day public comment period held from April 11 through June 10, 1994 are discussed in the Responsiveness Summary (Appendix B). EPA's preferred alternative, as delineated in the Proposed Plan, was Alternative 2B - Fisheries Isolation. In addition to the Institutional Controls under Alternative 2A, Alternative 2B also involved the construction of a fishery isolation barrier ("fish fencer") to prohibit the movement of migratory fish into or out of the area of Lake Hartwell with the highest PCB concentrations in sediment. Placement of the fish fence near the Hwy 37 Bridge, just south of Clemson on the Seneca River Arm, would result in isolation of less than 10 percent of the total area of Lake Hartwell. Isolation of these upstream areas was expected to result in accelerated declines in PCB concentrations in migratory fish in the downstream portions of Lake Hartwell (i.e. the remaining 90+ percent of the lake). The reasons supporting EPA's preference for Alternative 2B were simply: 1) Migratory species represent approximately 50% of the fish harvested by weight from Lake Hartwell. Accelerated reductions of PCB concentrations in these fish, for the majority of Lake Hartwell, would achieve a higher degree of protection by eliminating, or at the very least, minimizing exposures to this group of migratory fish; 2) Reduction in fish PCB levels would allow for rescinding of the existing fish advisories in the areas downstream of the fish fence, in an accelerated time frame, thus returning the majority of Lake Hartwell to its highest beneficial use; 3) The incremental cost to implement Alternative 2B was only approximately $1 million over that of Alternative 2A. Moderate, yet unwavering public opposition was expressed to EPA's preferred alternative at the Proposed Plan public meeting held in Clemson, SC on April 19, 1994. This and subsequent comments received during the public comment period suggest that the general consensus supports Alternative 2A and/or no-further Final ROD-Sangamo OU2 June 1994 action. In summary, the reasons supporting public opposition to Alternative 2B were essentially two-fold. First, the public does not believe EPA is capable of designing, constructing and installing a safe fishery isolation barrier that would meet the specified performance standards (See Section 7.3) at the estimated cost. Secondly, given the fact that Institutional Controls provide the most reliable mechanism for reducing exposures to PCB contaminated fish, the incremental cost for constructing a fish fence is not justified. EPA has given serious consideration to the concerns that were voiced by the public. In response to these concerns, EPA, in close consultation with SCDHEC and the Savannah District Corps of Engineers, has selected Alternative 2A - Institutional Controls as the Final remedial alternative for the Sangamo OU2 Site. Appendix Proposed Plan Fact Sheet UNITED STATES ENVIROMENTAL PROTECTION AGENCY SUPERFUND PROPOSED PLAN FACT SHEET SANGAMO WESTON/TWELVE MILE CREEK/LAKE HARTWELL PCB CONTAMINATION SUPERFUND SITEOPERABLE UNIT TWO Pickens County, South Carolina A number of terms specific to the Superfund process (printed in bold print end of this publication. INTRODUCTION The Region IV office of the United States Environmental Protection Agency has developed this Proposed Plan Fact Sheet for the Sangamo Weston/Twelvemile Creek/Lake Hartwell Polychlorinated Biphenyl (PCB) Contamination Superfund Site - Operable Unit Two ("Sangamo OU2 Site") in Pickens County, South Carolina. This Proposed Plan is issued to present the altenatives that EPA has considered to address PCB contamination in the sedinment and aquatic biota of the Sangamo OU2 Site. More specifically, the purpose of this Proposed Plan is to: Identify the preferred alternative for remedial action at the Site and explain the rationale for that preference; Describe the other remedial options considered in detail in the Final Feasibility Study Report; Solicit public review of and comment on all of the alternatives described; and Provide information on how the public can be involved in the remedy selection process at the Sangamo OU2 Site. PROPOSED P MEE for SANGAMOSUPERFUND Tuesday, 7: RAMAD U.S. 76 Clemson, EPA, in consulta Distact of the U Engineers (COE) Department of He Control (SCDHEC) ramedy for the S public comment p information subm been reviewed an encouraged to su alternatives, an supports these a Remedial Project of this publicat presented in a R could differ fro depending upon n EPA receives dur comment period. EPA is issuing this Proposed Plan as part of its public participation responsibilities under Section 117(a) of the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA, more commonly known as Superfund). This fact sheet summrizes information that can be found in greater detail in the Remedial Investigation/Feasibility Study (RI/FS) Reports and other site-related documents contained in the Administrative Record, located at the established information repositories. The reader is referred to the information repositories listed at the end of this publication for a more detailed account of this subject matter. SITE BACKGROUND From l955 to 1987, Sangamo Weston, Inc. owned and operated a capacitor eaten. manufacturing plant in Pickens, South Carolina, near the headwaters of Lake Hartwell. In its manufacturing processes, Sangamo used several varieties of dielectric fluids which contained PCBs. Waste disposal practices from the Sangamo Plant included land burial of off-specification capacitors and wastewater treatment sludges on the plant site and at six satellite disposal areas. PCBs were discharged with untreated effluent directly into Town Creek, which is a tributary of Twelvemile Creek. Twelvemile Creek is a major tributary of Lake Hartwell. It is estimated that over 400,000 lbs. of PCBs were released into the Twelvemile Creek system until the use of PCBs were discontinued prior to an EPA ban in January 1978. Schlumberger Industries, Inc. (SII) is the current owner of the plant site, as a result of a merger with Sangamo Weston in December 1989. Historical sampling events conducted by SCDHEC, COE, and EPA documented the presence of widespread PCB contamnation Field sampling and analysis for the sediment of the sediments, biota from the San Town Creek through well into the Twel Hartwell. During was discovered tha of Late Hartwell c exceeded the recom by the U.S. Food a (U.S. FDA). Subse a fish consumption issued in 1976 and SCDHEC in 1985 as to reduce human ex states: 1) All fi River Arm of Lake Highway 24 and Twe be released and no larger than 3 lbs. Lake Hartwell shou eaten. This advis warning signs agai posted at the majo launch and recreat In 1987, based upo Ranking System, SC programs and accom citizens in the ar proposed for inclu Priorities List (N was finalized on t A Remedial Investi separate sediment components, was th nature and extent the Sangamo OU2 st study area extends Weston Plant's dis Creek, through the watershed, and fin of Lake Hartwell. this publication p illustration of La surrounding area. focused descriptio Arm and decrea component of the OU2 RI was performed in July and August 1991 (Phase I) and April and May 1992 (Phase II). The sediment investigation included the collection and analysis of over 1,100 sediment cores and grab samples to adequately characterize the horizontal and vertical distribution of PCB contamination in the sediments of the study area. The sediment investigation determined that most of the PCB-contaminated sediment lies within the upper portion of Lake Hartwell, specifically the Twelvemile Creek Arm. PCB concentrations of surficial sediments (i.e. grab samples) were typically less than 5 parts per million (ppm), but higher concentrations up to 61 ppm were detected in the deeper sediments (i.e. core samples). Figure 3 illustrates average sediment PCB concentrations for an approximate 10 mile reach extending from Maw Bridge(Rt. 337)to the Rt 37 Bridge at the southernmost boundary of the focused OU2 study area. Field sampling and analysis for the biological component of the OU2 RI was conducted in the Spring of 1991 and 1992. Largemouth bass, catfish, and hybrid bass were collected and analyzed from 6 stations in Lake Hartwell. These stations are illustrated on Figure 4. The biological investigation determined that fish in the Twelvemile Creek drainage and Lake Hartwell are contaminated with PCBs, often at levels that exceed FDA's safe tolerance level of 2 ppm. Furthermore, caged fresh water clams and forage fish (small, young fish) accmulated PCBs over a relatively short period of time which confirmed the presence of food chain and respiratory transport mechanisms. PCB concentrations in sedentary fish (i.e. largemouth bass, catfish) are highest in the Twelvemile Creek downstream, si sediment conta species (i.e. concentrations entire reservo frequently exc level. PCB co bass and hybri stations, year Figures 5 and SCOPE OF THE P The Sangamo Si Units. Operab the land-based the Sangamo We satellite disp mile radius of Industries, un initiated clea November 1993. consist of exc contannnated s disposal areas excavated mate facilities at The excavated storage facili treatment syst site, at which materials will temperature th This publicati to present the for Operable U addresses the migration rout land-based sou final response implement as p remediating th SUMMARY OF SITE RISKS Human Risk CERCLA directs EPA to protect human health and the environment from current and potential exposure to hazardous substances at the Site. A Baseline Risk Assessment was The risks associated fish were calculated stations in Twelvemil Hartwell (Figure 4). conducted to evaluate the potential current and future human health and ecological impacts associated with exposure to PCBs in sediment and fish. The human exposure pathways which were quantitatively evaluated under current and future land-use conditions included: 1) Ingestion and dermal absorption of PCBs in the shallow sediment by a child and an adult; and 2) Ingestion of PCB-contaminated fish by a recreational fisherman. PCBs were not detected in the surface water during the RI and therefore this medium was not evaluated in the risk assessment. EPA evaluated PCBs according to their potential to produce either cancer and/or noncancer health effects. The carcinogenic risk range EPA has set for Superfund cleanups to be protective of human health is 1 X 10-4 to 1 X 10-6. For example, a cancer risk of 1 X 10-6 indicates that an individual has a 1 in 1,000,000 (or 1 in 10,000 for 1 X 10-4) incremental chance of developing cancer as a result of site-related exposure to a carcinogen over a 70 year lifetime under the specific exposure conditions at the Site. EPA generally uses the cumulative benchmark risk level of 1 X 10-4 for all exposures relating to a particular medium to trigger action for that medium. Noncancer exposure estimates were developed using EPA reference doses to calculate a Hazard Quotient (HQ). A HQ greater than 1 indicates that PCBs are present at concentrations that could produce harmful effects. at the population level for fish that have PCB concentrations around 5 ppm. However, there is evidence that as concentrations increase to greater than 20 ppm, fish health can be effected. Based upon the results of the Baseline Risk Assessment, it was concluded that actual or threatened releases of hazardous substances from this Site, if not addressed by the preferred alternative or one of the other separately by fish sp species combined to a individuals who may e exclusively and indiv types of fish. Expos ingestion of fish cau stations resulted in ranging from 10-2 to than 1. The highest was calculated for an consuming largemouth Twelvemile Creek wate cancer risk for inges combined, 1 X 10-2, w Twelvemile Creek Arm. associated with inges combined was 5 X 10-3 health risks resultin incidental ingestion unlikely to occur, ho continuing source of aquatic biota of the Ecological Risk An ecological risk as to evaluate the impac on the aquatic recept The biological invest document PCB contamin the aquatic food web. PCBs appear to be imp macroinvertebrate com Twelvemile Creek, hab man's influence is li adverse impacts at th community levels. Th Lake Hartwell does no Final Fish Cleanup Go safe tolerance level based upon technical carcinogenic risk-bas evaluated by determin levels in largemouth in acceptable risk to ingestion of fish. U assessment methods, a concentration of 0.03 with a 10-4 risk. Th active measures considered, may present a current or potential imminent and/or substantial endangerment to public health, welfare, or the environment. SUMMARY OF ALTERNATIVES Thorough development and evaluation of feasible remedial alternatives for the Sangamo OU2 Site required the derivation of cleanup goals for the media of concern: sediment and fish. Cleanup goals were not developed for surface water since PCBs were not detected in any sample collected during the RI above the detection limits of 1.2 to 1.3 ppb. Cleanup goals were also necessary to identify areas to be addressed by EPA's preferred alternative. The final cleanup goals are discussed below. Final Sediment Cleanup Goal Concentration of 1 ppm was selected based upon technical feasibility. Remediation goal of 1 ppm identified the entire Twelvemile Creek Arm, extending from the headwaters of the lake downstream to the confluence with the Keowee Arm, as an area to be remediated. This area covers approximately 730 acres with a total estimated volume of 4,722,000 cubic yards of contaminated sediment. would be conducted. The existing fishing advisory would continue and 5-year reviews would be conducted to assess sediment/fish PCB concentrations and associated risks to human health and the environment. goal of 0.036 ppm was technically impractab In a similar fact she and in the Final FS R the range of remedial under consideration f alternatives are brie All alternative cost in 1993 dollars and a conceptual engineerin cost consists of dire indirect (non-constru the first year of ope maintenance (O&M) cos postconstruction item continued effectivene Total present worth c of money, if invested disbursed as needed, cover all costs of a life. Alternative 1: No Ac As required by CERCLA alternative was evalu basis for comparison cleanup alternatives. no further remedial a contaminated sediment Sediment Quality Tre The objective of sed was to predict the f in the surface and b Twelvemile Creek/Lake Ha Due to the complex, dynamic nature of the over the next 30 yea Lake Hartwell system, significant changes in sediments upstream o the nature and extent of contamination are are predicted to dec expected over time even under the no-action within 5 years. Sed scenario. A comprehensive modeling effort 133 Bridge and the H consisting of sediment transport, water predicted to fall be quality and contaminant transport, and foodgoal in approximatel chain bioaccumulation was conducted during bottom sediments lyi the RI to predict the future fate and transport Bridge and the Hwy 3 of PCBs in sediments and aquatic biota of to increase and rema the study area. The predicted results of this cleanup goal after 3 modeling exercise are important increase is attribut considerations when evaluating the no-action alternative. For this reason, the predicted results of the baseline modeling activities are summarized below. finer, clay sized pa constriction of the embankment. Future Sedimentation Bioaccumulation and Fish Concentrations The objective of sediment modeling was to determine the rates at which presently contaminated sediments would be buried by relatively clean sodiments from tributary drainages over the next 30 years. Average sediment burial rates for the 30 year simulation are presented in Figure 7. Substantial rates of sediment deposition are predicted from Maw Bridge (Rt. 337) to just above the Hwy 133 Bridge. All of the sand and most of the silt coming into the reservoir from the Twelvanile Creek drainage are deposited in this reach with a predicted 30-year accumulation of nearly 10 feet of sedimet in some areas. This deposition pattern is favorable since PCB concentrations have historically been higher in sediments from this portion of the study area. Aquatic bioaccumulat conducted to assess fish would change over t the contaminated sedimen unmanaged, and 2) H for levels to drop be goal. A representa developed to evalua into fish via respi contaminated food. Larg selected as the top p shad/bluegill sunfish plankton and bentho levels of the food PCB concentrations for t web are presented in bioaccumulation mod concentrations to d food web during thc 30-y PCB concentrations in older largemouth bass are predicted to fall below the 2 ppm cleanup goal by 2005. Capital Cost = $7,000 Total O&M Cost = $123,000 Total Present Worth Cost = $130.000 Alternative 2A: Institutional Controls This alternative is a limited action alternative that relies on a series of institutional controls to prevent or minimize ingestion of contaminated fish tissue, which was identified as the primary exposure pathway of concern for the Site. GeneraUy, these institutional controls consist of the following: Public Education Program - A program would be initiated to inform thc public on available methods for reducing the intake of PCBs through fish consumption. Regulation of Impoundments be developed f accumlated beh impoundments l Creek. Period September 1993 sediment over been documente impact on the biota of thc u Twelvemile Cre impacts are at suspended sedi routine flushi impacts to the burial of more with cleaner s Twelvemile Cre Capital Cost = $ Total O&M Cost = Total Present Wo Specific preparation, handling, and cooking techniques can reduce the quantity of contamination consumed. Information of this type would be disseminated to the public through a series of local public meetings and distribution of an informational pamphlet. Fish and Sediment Monitoring - In addition to maintaining the current fish advisory, annual monitoring of PCB levels in fish and sediment of Twelvemile Creek and Lake Hartwell would be conducted. Results from this monitoring program would be utilized to support modifications to the fish advisary and to monitor concentrations of PCBs in sediment and fish over time. Results of this program would be made available to the public. Minimize safety hazards for boaters and other users of the lake (ie. waterskiers); Maximize effectiveness to prevent passage of migratory game fish through the barrier; Allow boats to pass unimpeded to minimize disruptions of boating traffic on the lake (i.e. no gate); Construct a semi-permanent structure that could be removed once PCB levels decline to health-based levels; Incorporate value engineering principles to minimize cost for design and construction; and Minimize operations and maintenance requirements and costs. Lake use restrictions, such as no-wake zones and warning signs would be implemented to prevent damage to the fence and for boating safety. Alternative 2B also includes the institutional controls described for Alternative 2A. Capital Cost = $1,232,000 Alternative 2B: Alternative 2B i approach consist fisheries resour minimize ingesti fish. The prima construction of prevent the move striped bass, hy or out of the m the reservoir. represent approx harvested by wei The fish isolati the vicinity of designed/constru perfonrmance sta 123. The cap would acres and would req 1,800,000 yd3 of sa Alternative 3A also restrictions to min once it is placed a controls described Capital Cost = $48, Total O&M Cost = $2 Total Present Worth Alternative 3B: Structure Se Alternative 3B woul a 1,600 ft. long fi of the Twelvemile C the confluence with Construction of the structure would phy Twelvemile Creek Ar of Lake Hartwell re downstream migratio sediment and moveme areas with highest Fishing restriction well as institution Altarnative 2A, wou limit consumption o Total O&M Cost = $3,012,000 Total Present Worth Cost = $4,244,000 Altenative 3A: Capping Under this alternative, an 18 inch clean sediment cap would be placed over the entire Twelvemile Creek Arm to eliminate thc further downstream migration of contaminated sediment and the transfer of PCBs from sediment to aquatic biota. The cap would extend from just upstream of the Maw Bridge (Rt. 337) to the confluence with the Keowee River, just upstream of Hwy resulting in the physical isolation of a much smaller area than Alternative 3B. A similar clean sediment cap as described under Alternative 3A would be placed below the weir and extend downstream to the mouth of the Twelvemile Creek Arm. The area to be capped under this alternative is approximately 285 acres. Institutional controls under Alternative 2A and fishing restrictions for the isolated area would be implemented until protective levels in the fish were achieved. Capital Cost = $31,684,000 Total O&M Cost = $2,365,000 Total Present Worth Cost = $34,049,000 Alternative 4: Confined Disposal Facility Alternative 4 involves a much more rigorous remediation approach than any of the alternatives discussed above. Under this alternative, contaminated sediments from the Twelvemile Creek Arm with PCB concentrations greater than 1 ppm would be removed by hydraulic dredging. All dredged sediments would be placed in a near-shore confined disposal facility (CDF) located in the "goose neck" bend area between the Maw (Rt. 337) and Madden (Rt. 15) Bridges. Twelvemile Creek would then be diverted around the CDF via a physically rerouted channel. lnstitutional contro would be used to limit comumption of contaminated fish until protective levels protective levels w Capital Cost = $51, Total O&M Cost = $2 Total Prment Worth Alternative 3C: Op Sediment Control St Alternative 3C util techniques to optim capped and location The weir would be c upstream location n concentrations gr combination of sh hydraulic dredgin in the middle and Twelvemile Creek while the upper p excavated. The d would be treated cement and placed under Alternative the upstream segm and destroyed as operations. Inst used to limit con fish until protec Capital Cost = $5 Total O&M Cost = Total Present Wor EVALUATION OF ALT EPA has estlished comparing the adv eath alternative alternatives disc against one anoth specified in the 40 CFR 300.430(e) evaluation criter 1) 2) Overall Prote and the Envir Compliance wi Relevant and were achieved. 3) Capital Cost = $43,422,000 Total O&M Cost = $3,487,000 Total Present Worth Cost = $46,909,000 Alternative 5: Stabilization Altarnative 5 is a very complex and costly alternative that involves removal of contaminated sediments with PCB The first two criteria are referred to as threshold criteria and must be met for an alternative to be eligible for selection. The next five criteria are referred to as balancing criteria and are used to weigh major tradeoffs among alternatives. The final two criteria, state and community acceptance, are referred to as modifying criteria and are addressed during the proposed Plan comment period. The following discussion briefly evaluates the relative performance of each alternative to the evaluation criteria. Overall Protection of Human Health and the Environment - It is important to note that complexities related to cycling of PCBs in the biota of Lake Hartwell cause the residual risk levels to remain above EPA's threshold of 1 X 10-4 regardless of which remedial alternative is implemented. A reduction in sediment PCB concentrations does not result in an immediate reduction in PCB concentrations in fish. High PCB concentrations in fish during the initial years of the 30-year exposure duration result in average risk estimates exceeding acceptable levels. Therefore, the most effective measures to minimize exposures to PCBcontaminated fish tissue are institutional controls (i.e. public education, continuation of fish advisory). However, the most protective alternatives rely principally on engineering rather than institutional controls to reduce or eliminate exposures, gives the uncertainty regarding the performance/reliability of institutional controls. Alternatives 3A and 3C involve capping actions that would permanently 4) 5) 6) 7) 8) 9) (ARARs) Long-term Eff Premanence Reduction of Volume Short-term Ef Implementabil Cost State Accepta Community Acc protectiveness, a is removed from t engineered dispos Compliance with A assesses the over Federal/State req alternatives rely processes to redu Lake Hartwell fis level of 2 ppm. capping and isola 2B/3A/3B/3C) achi quicker in the ma Alternatives 3A, the cleanup goal However, Alternat trigger a large n requirements asso dredging, and dis Long-term Effecti With the exceptio Alternative, all institutional con contaminated fish reliability of th site-specific fac predict. The fis would require pre to demonstrate ef application at Sa (Alternatives 3A/ but is dependent monitoring and ma integrity and lon Sediment control widely used and a maintenance. Fur isolate the contaminated sediment in all or a major portion of the Twelvemile Creek Arm. The more aggressive alternatives 4 and 5 provide an even higher level of Reduction of Toxciity. Mobility, or Volume - Alternative 5 would accomplish the most significant reduction in the mobility of PCBs through a stabilization treatment process followed by disposal in CDF. The capping alternatives (Alternatives 3A/3C) also accomplish a reduction in contaminant mobility, but the effect is contingent upon proper maintenance of the cap. The sediment control structures (Alternatives 3B/3C) and fish fence (Alternative 2B) would be the most effective in limiting contaminant mobility related to the migration of fish into and out of the areas with the highest sediment contamination. Short-term Effectiveness - Implementation of Alternatives 1 (No-Action) and 2A (Institutiona1 Controls) would have the least impact on the community, workers, and the enironment; Alternative 2B has only a slighly greater impact. Alternatives 3A/3B/3C have greater impacts on the local community due to construction of sediment control structures and excessive truck traffic associated with transportation of capping material. The greatest impacts (and least short-term effectiveness) are the more aggressive alternatives that entail dredging, re-channeling and construction of the CDF (Alternatives 4/5). Table 1 at the end of this publication summarizes the estimated schedule for each alternative, presenting the time required to implement, time required for fish PCB concentrations to decline to the FDA safe tolerance level, and total time to achieve protectiveness. This information is presented for the focused Sangamo OU2 study area (Twelvemile Creek/Seneca River Arm) as well as the main portion of Lake Hartwell The table shows that most of the alternatives rely on natural fate and transport processes and treatability prior to implamen and 5 to obtain d the dredging, CDF within the r protective l Twelvemile C alternatives control stru protectivene years. Alte achieves pro Lake Hartwel lake area) i 5 years) tha costly alter Implementabi would be the Alternatives close coordi and other ag administrati with these a manageable. to implement and technica Alternatives Cost - Costs provided und section of t State Accept Carolina is Plan. The S Alternative should be se final select the public c State will r selection of Community Ac this Propose is to encour the remedy s acceptance o be evaluated after the public comment period and will be described in the Record of Decision for the Site. EPA'S PREFERRED ALTERNATIVE maximum exten remedy does n treatment as a princ excessive costs. Ba received from the pu comment In summary, based upon the information available at this time, EPA is proposing Alternative 2B - Fisheries Isolation, which also includes those activities described under Alternative 2A. Placement of the fish fence in the vicinity of the Hwy 37 Bridge would result in isolation of the Twelvemile Creeks Keowee River and upper Seneca River Arms, which represent less than 10 pacent of the total area of Lake Hartwell Isolation of these upstream areas is expectd to result in an accelerated decline in migratory fish PCB concentrations in the downstream portions of the reservoir (i.e. the remaining 90+ percent of the lake). Migratory species represent approximate 50% of the fish harvested by weight from Lake Hartwell Reduction of fish PCB levels would allow for rescinding of the existing fish advisories in these areas, returning the majority of lake areas to normal use. This approach is consistent in the COE's Best Management Practices for Lake Hartwell, designed to achieve the maximum beneficial uses for the reservoir, which include fish and wildlife management and recreational use. period, EPA, in clos COE and SCDHEC, may preferred alt remedial alte Proposed Plan Alternative 2B - Fisheries Isolation represents the best balance among the criteria used to evaluate the other alternatives. Alternative 2B is believed to be protective of human health and the environment, would attain ARARs, would be cost effective and would utilize permanent solutions and resource technologies to the COMMUNITY PAR Concurrent wi Plan, EPA has comment perio through May 1 written and o Plan and all located in th below. All c should be dir Remedial Proj OU2 Site, at number listed EPA will exte by 30 additio public meetin 1994 to prese the RI/FS Rep rationale beh Altanative 2B meeting will located at th Hwy 123 in Cl Representativ Corps of Engi Department of Control will questions the future activi GLOSSARY Administrative Record - A file which contains all information used by the EPA to make its decision on the selection of a response action under CERCLA. Parts Per B Units of contamin This file is required to be available for public review million oun in 1 and a copy is to be established at or near the site, PCB's are m usually at the information repository. A duplicate file pool, the w is maintained in a central location such as a regional EPA and/or state office. Polychlorinated Biphenyls family of organic compounds used since 1926 in electric Baseline Risk Assessment - An assessment which transformer lubricants, provides an evaluation of the potential risk to human carbo health and the environment in the absence of remedial compo action. proce environment because they do no break down. Comprehensive Environmental Response, PCBs are st Compensation and Liability Act (CERCLA)animals through the biaccumulation process. EPA A federal law passed in 1980 and modified in 1986 banne by the Superfund Amendments and Reauthorization are not although Act (SARA). The Act created a trust fund, known as acute Superfund to investigate and clean up abandoned or PCBs uncontrolled hazardous waste sites. Remed Hazard Ranking System - A scoring system used by Two d EPA to evaluate relative risks to public health and the toget environment. A score is calculated based on actual or conta potential release of hazardous substances through all sitemedia present (i.e. the air, soils, surface water, sediments, groundwater). If a site scores above 28.5, Recor the site is proposed for inclusion of the National expla Priorities List. Natio choos Information Repository - Materials on Superfund possi and a specific site located conveniently for local residents. Super (SARA Macroinvertebrates - Small animals lacking Octob backbones found in sediments of water bodies. National Contingency Plan - The Federal regulation that guides the Superfund program. National Priorities List (NPL) - EPA's list of uncontrolled or abandoned hazardous wastes sites eligible for long-term cleanup under the Superfund Remedial Program. FOR MORE INFORMATION CONTACT: Remedial Project Managers Operable Unit Two - Craig Zeller Operable Unit One - Bernie Hayes Community Relations Coordinator Cynthia Peurifoy AT U S. Environmental Protection Agency - Region IV North Superfund Ramedial Branch 345 Courtland Street, N.E., Atlanta, GA 30365 1-(800) 435-9233, or (404) 347-7791 ************************** C. Michael Alexander Savannah District Fishies Biologist U.S. Army Corps of Engineers Richard B. Russell Lake 4144 Russell Dam Drive Elberton, GA 30635 (706) 283-8731 ********************** Richard Haynes, District Engineer South Carolina Department of Health & Enviromental Control 2600 Bull Street, Columbia, South Carolina 29201 (803) 734-5487 INFORMATION REPOSITORIES The Administrative Record for the Sangamo Site is available for review a The Village Library Main Street Pickens, SC 29671 (803) 859-9679 Pickens Coun Easley Branc 110 West Fir Easley, SC 2 (803) 859-96 R. M. Cooper Library Clemson University Clemson, SC 29634-3001 (803) 656-5174 Hart County Benson Stree Hartwell, GA (706) 376-46 Lake <IMG SRC 04941783> <IMG SRC 04941784> U S. Army Corps of Engineers Hartwell Natural Resources Management Center Hartwell, Georgia (706)376-4788 <IMG SRC 04941785> <IMG SRC 04941786> <IMG SRC 04941787> <IMG SRC 04941788> <IMG SRC 04941789> Table 1 Estimated Time Required to Achieve Protectiveness Sangamo OU-2 FS TIME FOR FISH TO ATTAIN FDA LFVEL PROTECTIVENESS(4) (yrs) TIME TO IMPLEMENT(1) ALT. TWELVEMILE CREEK/SENECA MAIN BODY OF BODY OF NO. HARTWELL LAKE 1 2A 2B 3A 3B 3C 4 5 DESCRIPTION (yrs) No action 0 Institutional Control 0.5 Fisheries Isolation 1 Capping 2 Sediment Control Structure 2 Optimal Capping/Sediment 2-3 Control Structure Confined Disposal Facility 3-4 Stabilization 4-5 RIVER(2) ARM HARTWELL LAKE(3 12 12 12 3-4 12 3-4 (downstream) 12 (upstream) 5-6 5-6 12 12 3-4 3-4 3-4 3-4 5-6 5-6 NOTE: (1) Includes time needed for pre-design studies, design, procure include time between Proposed Plan/Record of Decision Initiation of Remedial Design. (2) Twelvemile Creek Arm only; FGETS modeling results indicate t level (2 mg/kg) in approximately 12 years under baseline conditions; none of the alternatives will extend the period required for this period to achieve protectiveness of greater than 12 yrs). (3) Downgradient of the Twelvemile Creek Arm (i.e., main body of decline more rapidly for actions involving isolation, capping or removal of contamainted sediment (Alternatives 2B, 3A-C, 4 and 5). It comparable to that observed in the Twelvemile Creek Arm for Alternatives involving capping (3-4 yrs) or removal of the sediment (5-6 estimate. (4) Duration only; based on estimated time to implement remedy a levels to decline to FDA level, based on the FGETS modeling results presented in Section 3.3 and assumptions regarding migratory USE THIS SPACE TO WRITE YOUR COMMENTS Your input on the Proposed Plan for the Sangamo Superfund Site - OU2 i helping EPA select a final remedy for the site. You may use the spac your comment, then fold and mail. A response to your comment will be ________________________________________________________________________________ ______________________________________________________________________ ______________________________________________________________________ ______________________________________________________________________ ______________________________________________________________________ ______________________________________________________________________ ______________________________________________________________________ ______________________________________________________________________ ______________________________________________________________________ ______________________________________________________________________ REQUEST TO BE PLACED ON THE SANGAMO WESTON, INC./TWELVE MILE CREEK/LAKE HARTWELL SITE MAILING LIST If you would like to be placed on the mailing list for the Sangamo Sit this form and return to: Cynthia Peurifoy, Community Relations Coordi IV, North Superfund Remedial Branch, 345 Courtland Street, Atlanta, Ge call 1-800-435-9233. NAME:___________________________________________________________________________ ADDRESS:________________________________________________________________________ ______________________________________________________________________ TELEPHONE:______________________________________________________________________ AFFILIATION:____________________________________________________________________
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