GRADE 10 SCIENCE Bringing the Greenhouse Effect Down to Earth Curriculum Expectations CHV.02D CHV.03D CH2.01D CH2.06D CH2.07D CH2.13D CH3.01D CH3.02D ESV.01D ESV.02D ESV.03D ES2.01D SNC 2D Chemistry: Chemical Process Overall Expectations Design and conduct investigations of chemical reactions using standard scientific procedures, and communicate the results. Determine why knowledge of chemical reactions is important in developing consumer products and industrial processes and in addressing environmental concerns. Developing Skills of Inquiry and Communication Through investigations and applications of basic concepts, select and use appropriate apparatus, and apply WHMIS safety procedures for the handling, storage, disposal and recycling of laboratory materials (e.g., wear safety goggles and aprons; use proper techniques for the handling, disposal and recycling of acids, bases and heavy metal ions; describe procedures to be followed in an emergency). Through investigations and applications of basic concepts, describe experimental procedures in the form of a laboratory report (e.g., clearly identify the variable under investigation as well as the variables controlled; clearly describe the procedures followed and the data obtained; write an analysis of what was learned from the data). Through investigations and applications of basic concepts, select and use appropriate vocabulary, SI units and numeric, symbolic, graphic and linguistic modes of representation to communicate scientific ideas, plans, results and conclusions (e.g., descriptions of experimental procedures using the scientific method; data presented in tables). Conduct appropriate chemical tests to identify common gases (e.g., oxygen, hydrogen, carbon dioxide). Relating Science to Technology, Society and the Environment Explain how environmental challenges can be addressed through an understanding of chemical substances (e.g., challenges such as the renewal of the Great Lakes, the neutralization of acid spills, the scrubbing of waste gases in smokestacks). Describe how an understanding of chemical reactions has led to the development of new consumer products and technological processes (e.g., antacids, fireretardant materials). SNC 2D Earth and Space Science: Weather Dynamics Overall Expectations Demonstrate an understanding of the factors affecting the fundamental processes of weather systems. Investigate and analyse trends in local and global weather conditions to forecast local and global weather patterns. Evaluate how technology has contributed to our understanding of the physical factors that affect the weather. Developing Skills of Inquiry and Communication Through investigations and applications of basic concepts, formulate scientific questions about weather-related phenomena, problems and issues (e.g., What is the effect of heat energy transfer within the hydrosphere?). BRINGING THE GREENHOUSE EFFECT DOWN TO EARTH page 1 ES2.04D ES2.05D ES2.06D ES3.01D CHV.03P CH1.06P CH3.02P ES1.04P ES1.05P ES2.01P ES2.02P ES3.01P Through investigations and applications of basic concepts, analyse data and information and evaluate evidence and sources of information, identifying flaws such as errors and bias (e.g., explain possible sources of error when interpreting a satellite picture used for predicting weather). Through investigations and applications of basic concepts, select and use appropriate vocabulary and numeric, symbolic, graphic and linguistic modes of representation to communicate scientific ideas, plans, results and conclusions (e.g., use historical and current weather data to support a position on future weather patterns). Investigate factors which affect the development, severity and movement of global and local weather systems (e.g., the ozone layer, El Niño, bodies of water, glaciers, smog, rain forests). Relating Science to Technology, Society and the Environment Explain the role of weather dynamics in environmental phenomena and consider the consequences to humans of changes in weather (e.g., the role of weather in air pollution, acid rain, global warming and smog; the fact that smog aggravates asthma). SNC 2P Chemistry: Chemical Reactions and Their Practical Applications Overall Expectations Demonstrate an understanding of how chemical reactions relate to technological products and processes commonly encountered in everyday life. Understanding Basic Concepts Demonstrate an understanding of neutralization through investigation of simple acid-base reactions. Relating Science to Technology, Society and the Environment Investigate applications of acid-base reactions in common products and processes (e.g., compare the effectiveness of different brands of antacid tablets by quantitative analysis; prepare soap from lard and sodium hydroxide and compare its lather formation with that of commercial soaps). SNC 2P Earth and Space Science: Weather Systems Understanding Basic Concepts Observe, through experiment and simulation, and describe (a) the effects of atmospheric pressure, (b) the pattern of air movement in convection, (c) the phenomenon of inversion, (d) the greenhouse effect, and (e) heat transfer through radiation (e.g., (a) the reduction of the boiling point of water with reduced pressure or altitude; (c) the formation of dew or frost early in the morning following a clear calm night; (e) the use of dark solar panels for effective heat transfer). Describe the factors relating to the rotation of the Earth that cause the movement of air masses and variations in the Earth’s temperature. Developing Skills of Inquiry and Communication Through investigations and applications of basic concepts, identify factors that affect the development, severity and movement of local weather systems (e.g., microclimates in rural and urban areas, El Nino, bodies of water, frontal systems, smog). Through investigations and applications of basic concepts, formulate scientific questions about these factors and outline experimental procedures for finding answers. Relating Science to Technology, Society and the Environment Identify the impact of climate change on economic, social and environmental conditions. BRINGING THE GREENHOUSE EFFECT DOWN TO EARTH page 2 Teacher's Lab Notes This lab compares the amount of carbon dioxide found in four different sources. To compare the amount of carbon dioxide among the sources you may use either bromothymol blue to determine the amount of carbon dioxide followed by a titration or the CO2 probe may be used. The first method will provide an indirect quantitative analysis of carbon dioxide while the second method will provide actual carbon dioxide concentrations in the four sources. The students will be filling balloons with pure carbon dioxide, exhaled air, and ambient air. The teacher should fill the balloons with automobile exhaust. For safety reasons, you should wear thick gloves to protect your hands from being burned. Fill the balloons in an open area and when a slight breeze is blowing to keep the exhaust gases away from your face. Place a balloon over the narrow end of a metal funnel and place the wide end of the funnel over the exhaust pipe of a running car. When inflated, the balloons should each be about 7.5 cm in diameter. It may be easier to over inflate the balloon and then let a little gas escape. Twist and tie the balloon. Repeat the procedure with the same coloured balloon until you have one for each lab group. For the Bromothymol Blue method the ambient air solution in vial A will not turn yellow. The level of CO2 in ambient air is too low to be detected by bromothymol blue. Students will need around 60 drops of the diluted ammonia to neutralize the solution in vial D (vinegar-baking soda reaction). The other two vials should require between 7 and 40 drops. Caution students to add the drops slowly and shake solutions between drops so they can get a careful record of when the colour changes back to the same colour blue as the control. Since the students will have to add a relatively large amount of ammonia to the solution in vial D, the colour of this sample may be affected by dilution. To equalize this effect, you can have students add some water to the other samples to make the volume in each sample equal. This is easiest to do if sample D is titrated last. Purpose To compare the amount of carbon dioxide (CO2) in four different sources of gases (ambient air, exhaled air, car exhaust, pure CO2). Hypothesis Rank the sources of carbon dioxide from highest concentration to lowest concentration. BRINGING THE GREENHOUSE EFFECT DOWN TO EARTH page 3 Method A: Bromothymol Blue Method Materials (enough for each team of two or four students) • • • • • • • • • • • • 4 different coloured balloons (or 4 labeled balloons) 4 twist-ties 100 mL vinegar 5 mL baking soda Safety goggles for wear at all times 5 vials or test tubes 1 funnel 1 graduated cylinder a marble-size piece of modeling clay a narrow-necked bottle (the neck should be narrow enough for a balloon to fit over it) a dropper bottle of bromothymol blue indicator solution a dropper bottle of dilute household ammonia (1 part ammonia to 50 parts distilled water) Procedure 1. Add 15 mL of water and 10 drops of bromothymol blue indicator solution to each vial or test tube. Label the vials A, B, C, D, and Control. 2. Fill each balloon until it has a 7.5 cm diameter. Sample A (Ambient Air) - Use a tire pump to inflate the balloon to the required diameter. Twist the rubber neck of the balloon and fasten it shut with a twist tie. The tie should be at least 1 cm from the opening of the balloon. Record the colour of the balloon used for this sample. Sample B (Human Exhalation) - Have one team member blow up a balloon to the required diameter. Twist and tie the balloon, and record balloon colour. Sample C (Automobile Exhaust) - Your teacher will supply you with this balloon. Record the colour. Sample D (Nearly pure CO2) - Put 100 mL of vinegar in the narrow-necked bottle. Using a funnel, add 5 mL of baking soda. Let the mixture bubble for 3 seconds to drive the air out, then slip the balloon over the neck of the bottle. Inflate the balloon to the proper diameter. Twist, tie, and record the colour. BRINGING THE GREENHOUSE EFFECT DOWN TO EARTH page 4 3. Soften the clay and wrap it around one end of the straw to make a small airtight collar that will fit into the neck of a balloon. The collar should look like a cone with the straw in its middle, and should be large enough to plug the neck of the balloon. 4. Pick up Balloon A. Keeping the tie on it, slip the balloon's neck over the clay collar and hold it against the collar to make an airtight seal. Place the other end of the straw into the vial of water and bromothymol blue labeled A. Have another partner remove the tie on the balloon and slowly untwist the balloon. Keeping the neck of the balloon pinched to control the flow of gas, gently squeeze the balloon so the gas slowly bubbles through the solution. 5. Repeat the same procedure with the other balloons and their respective vials. In some cases, the bromothymol blue solution will change colour, from blue to yellow, indicating the presence of carbonic acid formed from CO2. 6. Analyze each of the samples by titrating them with drops of dilute ammonia. Ammonia neutralizes the carbonic acid. The bromothymol blue will return to a blue colour when all the acid has reacted. Add drops of ammonia to each of the samples that turned yellow, carefully counting the number of drops needed until they are about the same colour as your control. Record the results. Observations Air Source Colour of Bromothymol Blue after bubbling Number of drops of ammonia Ambient Air Exhaled Human Air Car Exhaust (nearly) Pure CO2 BRINGING THE GREENHOUSE EFFECT DOWN TO EARTH page 5 Method B: CO2 Probe Method Materials (enough for each team of two or four students) • • • • • • • • 4 different coloured balloons (or 4 labeled balloons) 4 twist-ties 100 mL vinegar 5 mL baking soda Safety goggles for wear at all times LabPro interface Data Pro program Vernier CO2 sensor Procedure Figure 1 1. Plug the CO2 Gas Sensor into Channel 1 of the LabPro interface. Connect the handheld to the LabPro using the interface cable. Firmly press in the cable ends. 2. Press the power button on the handheld to turn it on. To start Data Pro, tap the Data Pro icon on the Applications screen. Choose New from the Data Pro menu or tap to reset the program. BRINGING THE GREENHOUSE EFFECT DOWN TO EARTH page 6 3. Set up the handheld and interface for a CO2 Gas Sensor. a) b) c) d) e) f) If the handheld displays CO2 GAS (ppm) in CH 1, proceed directly to Step 4. If it does not, continue with this step to set up your sensor manually. On the Main screen, tap. Tap to select Channel 1. Press the Scroll buttons on the handheld to scroll through the list of sensors. Choose CO2 GAS (ppm) from the sensor menu. Tap to return to the Main screen. 4. Place the shaft of the CO2 Gas Sensor in the opening of the balloon (CO2 container). See figure 1. Gently twist the stopper on the shaft of the CO2 Gas Sensor into the container opening. Do not twist the shaft of the CO2 Gas Sensor or you may damage it. 5. Wait one minute, then tap to begin data collection. Data will be collected for 2†minutes (or until there is no change in the data registered). 6. Record the concentration of CO2. 7. Remove the CO2 Gas Sensor from the respiration container. 8. Use a notebook or notepad to fan air across the openings in the probe shaft of the CO2 Gas Sensor for 1 minute. 9. Repeat the same procedure (steps 7 - 11) with the other balloons to determine the concentration of CO2 in each sample. Observations Air Source Carbon Dioxide Concentration Ambient Air Exhaled Human Air Car Exhaust (nearly) Pure CO2 BRINGING THE GREENHOUSE EFFECT DOWN TO EARTH page 7 Analysis Questions 1. 2. 3. 4. Identify the control. What is the purpose of the control? Identify the dependent and independent variable. For procedure A, explain why the ambient air sample did not turn yellow. How did your results compare to your hypothesis? Explain any differences. Making Connections 5. 6. 7. 8. 9. Why is automobile exhaust a concern? What ways could you reduce the amount of CO2 you create? How could a city reduce the amount of CO2 they emit? What's more important, to develop and adapt cars with a new fuel that's safe for the environment or to improve public transportation systems? Why might it be difficult for the public to start using an alternative source? What alternative power sources could be used with cars? Conclusion References This activity is used with the permission of Climate Protection Institute. CTI publishes "Greenhouse Gazette" and other programs. To receive more information about CTI and other activities, write and tell them what grade you teach at 5833 Balmoral Dr., Oakland, CA 94619. This activity appeared in The Science Teacher, May 1989. Vernier Software and Technology. 2002. Science with Handhelds. Suggested Website for Support New Scientist Special Report on Climate Change. November, 2005. http://www.newscientist.com/channel/earth/climate-change/ CSIRO Atmospheric Research. May 2002. The Greenhouse Effect Information Sheet. http://www.dar.csiro.au/publications/holper_2001b.html One-tonne Challenge. Last updated 2005-11-04. http://www.climatechange.gc.ca/onetonne/english/index.asp?pid=170 BRINGING THE GREENHOUSE EFFECT DOWN TO EARTH page 8
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