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HAZARD COMMUNICATION PROGRAM
TABLE OF CONTENTS
1.0
INTRODUCTION.............................................................................................................................. 2
2.0
EMPLOYER RESPONSIBILITY....................................................................................................... 2
3.0
EMPLOYEE RIGHTS & RESPONSIBILITIES ................................................................................. 3
4.0
MATERIALS, INVENTORY, AUDITS............................................................................................... 3
5.0
MATERIAL SAFETY DATA SHEETS .............................................................................................. 4
6.0
LABELS AND LABELING ................................................................................................................ 6
7.0
EMPLOYEE TRAINING ................................................................................................................... 8
8.0
PROGRAM MAINTENANCE – OTHER FUNCTIONS..................................................................... 9
9.0
PERSONAL PROTECTIVE EQUIPMENT ..................................................................................... 10
10.0
HEALTH HAZARDS OF INDUSTRIAL MATERIALS ..................................................................... 11
Metal Working Fluids and Lubricants ............................................................................................. 11
Solvents.......................................................................................................................................... 14
Adhesives/Sealers.......................................................................................................................... 15
Corrosives ...................................................................................................................................... 17
Compressed Gases........................................................................................................................ 18
Paints & Dyes................................................................................................................................. 19
Abrasives........................................................................................................................................ 21
Soaps, Cleaners, Detergents ......................................................................................................... 22
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GENERAL GUIDELINES FOR HAZARDOUS MATERIALS.......................................................... 23
Hazards .......................................................................................................................................... 23
Usage .......................................................................................................................................... 23
General Emergency Procedures .................................................................................................... 23
Forms
Employee Request For MSDS/Hazard Communication Program
Hazard Communication Program Inventory List
(Inquiry Letter)
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HAZARD COMMUNICATION PROGRAM
1.0
INTRODUCTION
Cal-OSHA has issued a Hazard Communication Standard for employers in the State of California
to comply with and enforce the Federal Hazard Communication Standard. This program complies
with this standard.
Western University notifies their employees of any hazardous materials used in the workplace and
how to safeguard themselves against any possible ill effects from exposure to these materials.
The Hazard Communication Program consists of four basic parts:
1.
The written Hazard Communication Program.
2.
Material Safety Data Sheets (MSDS) information including maintenance, distribution,
availability and locations.
3.
Labeling of hazardous chemical and material containers.
4.
Employee training and information.
The University makes this information available to employees who may be exposed to chemicals
and provides training so that employees are aware of hazardous properties and how to minimize
exposure. Further, the training provides related, detailed information regarding each of these
chemicals or group of chemicals.
This manual is designed to provide training to comply with State and Federal hazard
communication laws by providing employees that use, or may be exposed to, chemicals with the
necessary information to safely work with those materials. The manual is divided into sections
beginning with general topics and progresses into specifics related to groups of chemicals.
Other safety standards related to this topic require the disclosure of information to employees
when suspected carcinogens, lead and asbestos are present. Notices and signs may be posted
in the workplace indicating their presence. Safety information and training will be provided when
required under these safety standards. The University Chemical Hygiene Plan and Radiation
Safety Program should also be reviewed to supplement this program.
The University Safety Coordinator (USC) will administer our internal program. All levels of
management and supervision are responsible to see that the program is followed and enforced.
2.0
EMPLOYER RESPONSIBILITIES
The University has several primary responsibilities as an employer:
1.
Maintain a safe work environment.
2.
Notify employees and visitors of the hazards of materials used in the workplace.
3.
Document training of employees in the safe use of materials in the workplace.
4.
Maintain MSDS of all hazardous materials used in the workplace.
5.
Immediately provide copies of a specific MSDS and this written program to any employee
who makes such a request.
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6.
Provide and/or maintain proper container labeling.
7.
Monitor the workplace to assure safe and proper storage, use, and disposal of materials
which could be hazardous.
8.
Inform employees of their rights under this law.
EMPLOYEE RIGHTS AND RESPONSIBILITIES
Under this law, employees have specific rights and responsibilities:
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1.
Be informed of materials in the workplace which could be hazardous.
2.
Be trained in the safe use of materials which could be hazardous in the workplace.
3.
Request Material Safety Data Sheets of specific materials.
4.
Request a copy of this program.
5.
Use only known and labeled materials.
6.
Be provided with protective equipment as required by a Material Safety Data Sheet when
working with a material which could be hazardous.
7.
An employee's physician may also receive this information.
8.
Employees cannot be discharged or discriminated against for exercising their rights.
9.
Follow safety procedures and instruction.
10.
Attend training classes.
11.
Utilize safety equipment as provided.
12.
Do not alter, deface or destroy any label.
13.
Notify supervisors of unsafe conditions.
MATERIALS, INVENTORY, AUDITS
1.
An initial inventory of all hazardous substances will be made of all work areas and
facilities. An annual audit will be conducted thereafter under the direction of the Safety
Department. All hazardous substances required will be identified and listed. The
inventory list will be posted in each department.
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The listing is included with this program and will note at least the following information:
a)
b)
c)
d)
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The name of the hazardous substance.
Identify the manufacturer or supplier.
The location(s) where the hazardous substance is used.
The date the MSDS was prepared.
2.
Purchases of all materials and chemicals, whether hazardous or not, must be reviewed
and approved by the Safety Department and must include receipt of the Material Safety
Data Sheets (MSDS) for the item purchased.
3.
New purchases of all hazardous substances should be made through the Purchasing
department. If hazardous substances are purchased or otherwise obtained, it is the
responsibility of each Department Head or ASC to promptly forward the MSDS to the
Safety Department.
MATERIAL SAFETY DATA SHEETS (MSDS)
An MSDS provides all hazard and safety information relative to a product. Regardless of manufacturer or
material, the MSDS format is always the same.
MSDSs for all hazardous substances used by the University are maintained. Copies are kept at the
following locations:
WHERE CHEMICALS ARE USED / STORED
(outside)
OFFICE OF ENVIRONMENTAL HEALTH AND
SAFETY
WITHIN
OFFICE
RESPONSIBLE
DEPARTMENT
The following procedures have been implemented to assure the availability and completeness of MSDS.
1.
A MSDS will be provided for all required hazardous substances present.
2.
There will be a Master MSDS File and index of all hazardous substances which will be
located in the Safety Department.
3.
An MSDS with associated index on all hazardous substances used in a specific work area
or for a specific work assignment will be available to employees.
4.
The original inventory listing and audits will be used to ascertain that there is an MSDS
for each hazardous substance.
5.
In the event an MSDS is not available or should a new hazardous substance be
introduced for use without a required MSDS, the Department Head or ASC should
immediately contact the Safety Department.
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6.
MSDS will be reviewed for completeness by Department Heads or Supervisors. If an
MSDS is missing or obviously incomplete, a new MSDS will be requested from the
manufacturer. Cal-OSHA will be notified if a complete MSDS is not received. A sample
request letter is included with this program.
7.
Whenever new or revised MSDS are received and indicate significantly increased health
risks or additional measures necessary to protect employees, this information will be
provided to employees within 30 days after receipt by the Supervisor.
8.
The procedure for any employee to request a copy of an MSDS is:
The employee should contact their Supervisor and request a photocopy of the MSDS from
the MSDS manual. If the requested MSDS is not available, the employee should fill out
the form entitled "Employee Request for Material Safety Data Sheet" and forward it to the
Safety Department. A request form is included with this program.
The following are the "information headings" found on a MSDS and a brief explanation of what is found
under each heading
MSDS SECTION
NUMBER
.
MSDS HEADING
TITLE
MSDS DESCRIPTION
I.
Product Identification
General, specific or generic identification of the
product plus its hazard classification.
II.
Hazardous Components
List all hazardous components or ingredients in
the product. Also provide the PEL (Permissible
Exposure Limit) which is the permissible
amount of exposure an employee can take in
eight hours.
III.
Physical Data
Lists a product's boiling point, vapor pressure,
vapor density, specific gravity, percent of
volatiles, evaporation rate. It also gives the
color, weight and form (liquid, solid gas).
IV.
Flammability
Provides the product's flash point, lower and
upper exposure limits (LEL, UEL) firefighting
procedures, unusual fire and explosion hazards.
V.
Health Hazard Data
Provides the permissible exposure lel (PEL)
and the physical effect on the body. Also give
first aid and medical treatment procedures.
VI.
Reactivity Data
Lists
conditions
to
avoid
hazardous
polymerization (energy release) as well as
describes the stability and any incompatibilities
of the product.
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MSDS SECTION
NUMBER
MSDS HEADING
TITLE
MSDS DESCRIPTION
VII.
Spill or Leak Procedure
Lists precautions or actions to take in case of
contamination or a spill.
VIII.
Protective Equipment to Be
Used
Lists all required personal protective equipment
to be used when handling the product.
IX.
Special
Comments
Precautions,
This section covers any relevant points not
previously mentioned.
X.
Storage,
Procedures
Handling
XI.
Transportation
Lists safe storage and handling procedures.
Provides general Department of Transportation
(DOT) requirement for shipping or transporting
the product.
MSDS are provided for the following uses:
a.
b.
c.
d.
e.
f.
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Employee training.
Product reference, application
First aid, medical information.
Protective measures to be used, taken.
Firefighting.
Storage and transportation
LABELS AND LABELING
Manufacturers and/or suppliers of materials and substances are required by law to properly and
adequately label all containers respective to the hazards and safeguards associated with their products.
1.
All hazardous substances must have a label that includes the following information:
a)
b)
c)
The name of the hazardous substance(s).
Any specific warning or other hazard information.
Identification of the manufacturer or supplier and address.
2.
A label will not be removed from its container, nor will such label be defaced.
3.
Should it become necessary for a label to either be introduced by the company or
replaced on a hazardous substance container, such label will display the information
noted in Paragraph A above.
4.
All containers of hazardous substances will be received and the label assured to be
affixed on each and all containers by the accounting department. Any hazardous
substance received directly must be checked to assure that each container is
appropriately labeled.
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5.
Where hazardous substances are stored/dispensed from a permanent fixed location, a
wall placard or sign may be used in lieu of a label. The placard or sign will be affixed to
the container or immediately adjacent to the container in clear view. Each placard or sign
will identify the hazardous substance and any hazards present, or be a duplicate of the
manufacturer's label.
6.
It will be the responsibility of each Project Manager to ensure that all containers are
labeled by periodically reviewing container labels. Secondary containers (spray bottles,
mixing jugs) must also have a proper label which identifies the hazardous substance and
any hazards present, or be a duplicate of the manufacturer's label.
The University has adopted the following system of labeling to label inadequately identified original
containers or stationary containers. As indicated on the diagrams, the labels are divided into six sections
denoted by different colors and numbers. They are as follows:
1.
Flammability is indicated as red. The degree of flammability appears in the red diamond.
The numbers correspond to a decrease in the flash point:
4- below 73 F
3- below 100 F
2- below 200 F
1- above 200 F
0- will not burn
2.
Reactivity: information is located in the yellow diamond area along with chemical names
with specific chemical information. The number indicates the degree of reactivity:
4 - may detonate
3 - shock and heat may detonate
2 - violent chemical change
1 - unstable if heated
0 - stable
3.
Health: hazards indicated in blue provide more specific health information. The number
indicates the degree of hazard:
4 - deadly
3 - extreme danger
2 - hazardous
1 - slightly hazardous
0 - normal material
4.
Specific Hazard: hazards indicated in white briefly describe the hazard associated with
each substance including:
Oxidizer
Acid
Alkali
Corrosive
Water reactive
Radiation
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EMPLOYEE TRAINING
1.
All employees will receive general training from the USC on the Hazard Communication
Program at the time of initial hire.
2.
Specific training will be provided to each employee by his or her Supervisor upon
reporting to his or her assigned work location. Training is also required whenever a new
hazardous substance is introduced into the workplace. The purpose of specific training is
to identify the particular hazardous substances that are present and explain their
associated hazards in addition to any and all necessary safety precautions which are
required.
3.
Program information and training will be accomplished by lecture, photo, slides, video,
literature or any combination thereof. Training will cover the contents of this program to
include a review of the following:
a)
b)
c)
d)
e)
f)
g)
h)
i)
j)
An overview of the requirements contained in the Hazard Communication
Regulation including each employee's rights under this law.
Location and availability of the written Hazard Communication Program, MSDS
and other supporting materials.
Procedure to request Hazard Communication Program copies or MSDS.
The specific hazardous substances in each employee's workplace including the
operations and locations where they are present.
Explanation of the physical and health hazards associated with hazardous
substances.
Description of a MSDS and an explanation on how to read the document.
Explanation of labels used by manufacturers and the University to identify
hazardous substances.
Methods and observation techniques used to determine the presence or release
of hazardous substances in the workplace (odor, appearance, irritation of eyes,
smoke, etc.).
Measures employees can take to lessen or prevent exposure to hazardous
substances (knowledge of chemicals, storage practices, personal protective
equipment, labels, emergency eye washes, etc.).
Emergency and first aid procedures to follow in the event of an employee
exposure to a hazardous substance.
4.
Employees will sign a form whenever they attend a training session indicating that they
received information on the Hazard Communication Program or received technical or
specific training relative to hazardous substances.
5.
Periodically, employees may be required to perform non-routine work or tasks using
hazardous chemicals, materials or work in associated hazardous locations. Prior to
starting such projects, each affected employee will be given information about the
chemicals, materials, or exposure of such activity by the Supervisor. Such information will
include:
a)
b)
c)
Specific hazards that may be associated with the chemical or material.
Protective and other safety measures to be taken.
Measures the University is taking to lessen or prevent hazards, i.e., ventilation,
respirators, storage, safety watch personnel, postings and barriers, fire
extinguisher, other personal protective equipment, etc.
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d)
e)
6.
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Review of the hazardous substance MSDS or other technical information
applicable to the work.
Review of emergency procedures to be taken.
To ensure that employees who work with unlabeled containers have been informed as to
the hazardous substances contained within, the following procedure has been
established:
Prior to starting work with unlabeled containers, employees are to contact their supervisor
for the following information:
a)
b)
c)
d)
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The hazardous substance in the container.
The potential hazards associated with the hazardous substance.
Safety precautions which shall be taken.
Protective safety equipment which shall be used.
PROGRAM MAINTENANCE - OTHER FUNCTIONS
1.
Purchasing/MSDS Supply: A boiler plate statement will be applied to all purchase
orders on request in order to obtain applicable MSDS on all hazardous substances.
"Material Safety Data Sheets are mandatory with this order."
The MSDS must accompany the product upon delivery or a statement must be furnished
which states that the product is exempt from the regulations and does not requires a
MSDS.
2.
Other supplied hazardous substances: No hazardous substance requiring a MSDS
will be introduced or any work area by petty cash purchase, supplier samples or other
means without the knowledge of the Safety Department. Each Department Head or
Supervisor is responsible for obtaining a MSDS and supplying a copy to the Safety
Department.
3.
Contractors: Whenever contractors are engaged to perform work at company facilities,
there will be a mutual exchange of information regarding hazardous substances.
a)
A boiler plate statement will be applied to all purchase orders or bid specifications
on request in order to obtain a list of hazardous substances and any requested
MSDS used by a contractor.
"Material Safety Data Sheets are mandatory with this order."
All information provided by the contractor will be reviewed by the department
coordinating the contractor's work so that safety precautions and training (if
necessary) can be instituted to lessen or prevent possible exposure to these
hazardous substances. Copies of MSDS will be provided to the Safety
Department.
b)
It will be the responsibility of each Department Head or Supervisor to provide
contractors with the following information:
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(1)
A list of hazardous substances to which the contractor's employees may
be exposed to while on the job site. Copies of any MSDS requested
should be provided.
(2)
Precautions and controls to be taken to lessen or prevent possible
exposure by use of appropriate protective measures.
PERSONAL PROTECTIVE EQUIPMENT
The many ways a chemical can enter the body are called routes of entry. These routes of entry
are via the mouth, nose and lungs by inhalation; through the skin and eyes by absorption; through
the membranes in the eyes; and through the stomach and intestines by ingestion. Personal
protective equipment acts as a barrier to these routes of entry, blocking off access of these
chemicals to human tissues.
The specific equipment required to protect an individual varies depending on the exact nature and
type of chemical in questions, the process in which this chemical is used, the exposure to the
individual at this operation, and also the specific biological makeup of the person being exposed.
Not everybody reacts alike when it comes to chemicals. There are methods by which you can
protect yourself through the use of personal protective equipment.
Respirators are a barrier to chemicals that can be inhaled. Respirators either filter particles out of
the air, react with chemicals in the air to neutralize them or provide fresh air from a source
separate from the work area. There are two important things to remember about using
respirators. The first is that a respirator only works when you use it and that means using it
properly. They will not work if you don't use them. Second, and equally important, is that the
proper respirator and filters for a specific hazard must be used. Respirators designed for one type
of chemical will not work for another. A respirator designed for dusts will not protect against paint
vapors. If there is a question about the proper type of respirator to use, contact the Supervisor or
USC. No one is allowed to use any respirator without respirator training.
Gloves and aprons provide a barrier to skin absorption. Depending on the specific hazards in
your department, a variety of these items may be necessary to provide the proper level of
protection. Consult your Supervisor or USC for specific recommendations or if you have any
questions.
It is mandatory to use eye protection in all lab areas. Safety glasses are mandatory for personnel
working with or around liquid chemicals of any sort, splash proof chemical goggles are highly
recommended.
Always label any container to prevent accidental drinking. Always thoroughly wash your hands
with soap and water before eating, drinking or smoking. Keep any food or cigarettes away from
the work area. Breads, fruits, and cigarettes can actually absorb chemicals from the air to be
ingested later.
Anything that you can do to separate your work environment from your own personal protection,
and skin protection means good protection. Protect yourself and protect your health.
Personal protective equipment is available from your Supervisor.
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HEALTH HAZARDS OF INDUSTRIAL MATERIALS
1.
METAL WORKING FLUIDS AND LUBRICANTS
a.
Insoluble Oils and Greases
CHARACTERISTICS: Commonly known as lubricating oils or greases, generally
these oils are petroleum based hydrocarbon mixtures that contain no water.
Appearances range from clear light brown liquids to dark brown greases. Oils
can be fire hazards because they are combustible (meaning they will burn), and
should be stored/kept away from concentrated acids or other oxidizing materials.
Examples of common oils and greases are multi weight motor oil, gear lubricating
oils, and some cutting oils.
HEALTH HAZARDS: Petroleum based oils and greases are generally of low
toxicity. Inhalation of generated mists may cause mild irritation of the nose,
throat, and eyes and some difficulty in breathing, however, this is very rare.
Overexposure can cause headaches, nausea, or dizziness.
The most common exposure to petroleum based oils/fluids is skin exposure.
Excessive or prolonged exposure of the skin to the oils may cause skin conditions
such as contact dermatitis.
PPE/HANDLING: For operations where oil mists are generated, local exhaust
ventilation is preferred. If there is no local exhaust ventilation, a respirator with an
organic vapor/particulate cartridge should be utilized. Any practical way to reduce
time and frequency of skin exposure to the oils is recommended. Mild waterless
hand cleaners are especially useful for removal of oil.
Oil resistant protective gloves should be used whenever feasible. Safety glasses
or goggles should be worn at all times to prevent any oil from splattering or
splashing into the eyes. Never use solvents to clean the skin. The most common
method is the use of mild soap and lukewarm water to remove the oil.
EMERGENCY/SPECIAL: Lubricating oils and fluids like other chemicals should
be handled with care. In the event of eye contact, flush with water for 15 minutes,
then seek medical attention. In case of accidental ingestion, do not induce
vomiting, give milk or water, and seek immediate medical attention. If any
symptoms of inhalation overexposure (headaches, dizziness, nausea) should
occur, get to fresh air immediately. In the person is unconscious, remove victim
to fresh air, apply artificial respiration if necessary, and seek immediate medical
attention. Any areas of skin contact, should be washed thoroughly with mild
soap[ and lukewarm water or waterless hand cleaner, in order to reduce the risk
of skin disorders.
b.
Soluble Oils
CHARACTERISTICS: soluble oils, generally referred to as soluble cutting fluids,
are emulsified oils, which means that they can be mixed with water. They can be
derived from animal, vegetable, or petroleum sources. soluble oils come in a
variety of colors ranging from brown to blue depending upon whether or not they
contain dyes or additives, and usually have a mild fragrant odor. Most oils are
combustible (meaning they will burn) and should be stored away from
concentrated acids or other oxidizing agents. Examples of soluble oils are Van
Stratten cutting oil, Trim-Sol and Pems oil.
HEALTH HAZARDS: Oil mists (particulates) and vapors can be generated and
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may cause mild irritation of the nose, throat and eyes when inhaled. some
difficulty in breathing can result. Overexposure can cause headaches, nausea, or
dizziness.
The most common exposure to the soluble cutting oils is via the skin. Exposure
to used, dirty, or contaminated oils, may cause mild irritation, chronic skin
conditions or contact dermatitis. Ingestion may be harmful, depending on the
amount ingested and the concentration of the cutting fluid.
PPE/HANDLING: For operations where oil mists are generated, local exhaust
ventilation is preferred. If there is no local exhaust ventilation, a respirator with an
organic vapor/particulate cartridge should be utilized. There is no substitute for
good personal hygiene and safe work practices. Any practical way to reduce time
and frequency of skin exposure to the soluble oils is recommended. Mild soap
and lukewarm water is generally a good source for removing the oil from the skin.
For excessive exposure, oil impervious gloves should be worn and skin cream
applied to prevent drying. Safety glasses or goggles should always be worn to
prevent the oil from splashing into the eyes. Never use solvents to clean the skin.
This will only increase the risk of unusual skin disorders.
EMERGENCY/SPECIAL: In the event of eye contact, flush with water for 15
minutes, if the irritation persists seek medical attention.
If inhalation
overexposure occurs, get to fresh air immediately. In the case of an unconscious
person, remove victim to fresh air, apply artificial respiration if necessary, and
seek medical attention. If accidental ingestion occurs, do not induce vomiting,
and seek immediate medical attention. Any skin contact, should be washed
thoroughly with mild soap and lukewarm water, in order to reduce the risk of skin
disorders.
c.
Aerosol Spray Lubricants
CHARACTERISTICS: Aerosol spray lubricants, unlike other oil based lubricants,
generally contain a high percentage of halogenated solvents, (methylene chloride,
etc.). Most of the 12 oz. aerosol sprays are usually flammable or extremely
flammable because of the propellant (propane, butane, etc.) within them.
Therefore, these products should never be exposed to open flames or high
temperatures. Examples of spray lubricants include Zip Aerosol products and
#711 Lubricant.
HEALTH HAZARDS: As indicated above, many of these aerosols contain
methylene chloride either as a propellant or a carrier solvent. Methylene chloride
is a suspected carcinogen, therefore, exposure to the aerosol vapors should be
minimized as much as possible. Some of the aerosol spray lubricants may also
contain small percentages of metals, which are used as pigments.
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ADDITIONAL INFORMATION: Phosgene gas, an extremely toxic gas, may be
generated as a decomposition product of combustion if the spray lubricants come
in contact with a flame (e.g., a lighted cigarette, or welding operations, etc.) or a
very hot metal. Phosgene gas when inhaled is a severe respiratory irritant that
causes irritation of the eyes, nose, and throat at extremely low concentrations.
Exposure to moderate concentrations can cause a delayed onset or pulmonary
edema (fluid in the lungs) which may progress to pneumonia.
A brief
overexposure to high concentrations of phosgene gas may cause death.
PPE/HANDLING: All solvents should be handled with respect and used in well
ventilated areas. If spraying in moderate concentrations, avoid overexposure by
wearing a respirator with organic vapor cartridges. If spraying occurs in high
concentrations an airline respirator should be worn. Avoid excessive contact with
the skin in order to reduce the risk of skin irritation and/or dermatitis. Use
chemically resistant (neoprene) gloves for prolonged or repeated contact. Always
wear safety glasses or goggles to prevent eye contact with the aerosol spray or
mist.
EMERGENCY/SPECIAL: In the event of excessive skin or eye contact, flush
eyes with water for 15 minutes. Wash skin with soap and water. If swallowed do
not induce vomiting, and seek medical attention immediately. In case of
excessive overexposure by inhalation, remove person to fresh air, and seek
immediate medial attention, apply artificial respiration if necessary. Containers
should be stored in a clean, dry area avoiding storage above 80ΝF to avoid the
risk of the aerosol containers bursting or exploding.
d.
Solvent Based Fluids and Films
CHARACTERISTICS: Solvent based fluids and films are commonly known as
dry film or solid film lubricants. They vary in appearance from watery, clear
liquids to grayish, black viscous fluids. Examples include high speed drilling
compounds and fluids, Stoddard solvent as a rust preventative, Lubri-Bond 220
(bulk) and Lubrifilm LF-22.
HEALTH HAZARDS: Consult the specific MSDS to determine which health
hazard category to consult for further information. Generally, the primary routes
of exposure to solvents are via inhalation and skin contact. Acute inhalation
exposure may cause moderate anesthetic and narcotic effects, headache,
dizziness, and nausea.
Chronic exposure to some solvents may cause
permanent damage to the central nervous system. Prolonged or repeated skin
exposure may cause dermatitis.
PPE/HANDLING: Always handle hazardous materials with care. Safety glasses,
goggles, plastic face shield, etc., should be worn if material is handled in such a
way that could be splashed into the eyes. Solvent resistant (neoprene) gloves
and clothing, boots, aprons, etc. should be worn over parts of the body that may
be exposed. If low concentration of oil mists occurs, a respirator with an organic
vapor/mist cartridge should be worn. If high concentration occurs, an airline
respirator should be worn. All solvent based lubricants should be utilized in well
ventilated areas. General ventilation should be adequate. Always remember to
wash hands and face with mild soap and lukewarm water before smoking or
eating.
EMERGENCY/SPECIAL: If eye contact occurs, flush eyes with large amounts of
water for 15 minutes, obtain immediate medical attention. For skin contact,
remove all contaminated clothing. Wash exposed areas of the skin with mild
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soap and lukewarm water. Contaminated clothing must be washed before worn.
For inhalation overexposure, remove exposed person to fresh air immediately,
apply artificial respiration if necessary, and obtain immediate medical care. In
case of accidental ingestion, DO NOT induce vomiting. Get medical attention
right away. In the case of a spill, remove all sources of ignition, ventilate the
area, evacuate the area, and call the Fire Department to clean up the spill.
2.
SOLVENTS
a.
Halogenated Solvents
CHARACTERISTICS: These products are usually clear, rapidly evaporating
solvents containing chlorinates. They generally exhibit low flammability and have
the consistency of water. They have a mild odor and are used in degreasing,
painting, stripping and other operations. Examples of chlorinated solvents are
1,1,1-Trichloroethane, methylene chloride and Freon-type products.
HEALTH HAZARDS: Most solvents are irritating to the eyes and upper
respiratory tract. Excessive, repeated exposure to the skin may produce
dermatitis and drying of the skin due to the defatting properties of solvents. Most
are toxic and may be harmful or fatal if swallowed. Inhalation of excessive vapors
may produce narcotic effects by depression of the central nervous system. Such
exposure is evident by dizziness, nausea, and light-headedness in some
individuals. Chronic health effects include affects to organs such as lungs, liver,
kidney, and nervous system. Some solvents have been shown to produce cancer
in laboratory animals. Compressed Freon products may produce "Freeze burns"
on the skin and eyes when released. Very high concentration of vapors may be
dangerous to life and health.
PPE/HANDLING:
Solvents should be handled with respect.
Avoid any
unnecessary exposure. Never wash hands in solvents, use soap and water after
using solvents. Avoid excessive skin contact, use chemically resistant (neoprene
gloves if necessary. Avoid inhalation of vapors when possible. Use airline
respirators in areas of high concentration and confined spaces. Avoid contact
with eyes, use chemical goggles for protection. Provide ventilation where
possible. Boots, aprons and chemical suits are recommended for heavy potential
exposures. Avoid contact with strong oxidizers and reactive metals (magnesium,
aluminum powders).
EMERGENCY/SPECIAL: In the event of eye contact, flush eyes for 15 minutes
with water. Wash skin with soap and water and remove soaked clothing. Do not
allow wet clothing to remain in prolonged contact with skin. If ingested, do not
induce vomiting, and seek medical attention immediately. If inhaled remove to
fresh air, apply artificial respiration if necessary. In the event of a major spill,
evacuate area and call the Fire Department. Avoid drainage into the public water
sewage system.
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b.
IIPP SUB-PROGRAM
Organic Solvents
CHARACTERISTICS: Usually clear, rapidly evaporating solvents of a petroleum
or alcohol base. These solvents usually are very flammable and may or may not
mix with water. They usually have an oil odor or alcohol like odor and are used in
a variety of degreasing, painting and stripping type operations. Examples of
organic solvents are toluene, methyl ethyl ketone, acetone and alcohol.
HEALTH HAZARDS: Organic solvents evaporate very quickly and pose a great
fire hazard. Because of this rapid evaporation, and the natural penetrating nature
of solvents, these materials can enter the body very rapidly through inhalation into
the respiratory tract, through the skin and the eyes. Exposures of these type, in
some instances, may lead to skin irritation, eye irritation, and respiratory irritation.
These products may be harmful or fatal if swallowed. Some solvents may
produce allergic reactions in sensitive people.
PPE/HANDLING: It is important to minimize your exposure to solvents. For
example, avoid skin contact by wearing heavy, non-porous gloves (neoprene).
cotton or leather gloves should never be worn when working with a solvent. Use
tongs or a basket to handle or hold parts in a solvent bath. Never wash your
hands in a solvent, use soap or waterless hand cleaner. Barrier creams may
provide additional protection. Use ventilation system and avoid inhaling vapors.
If your job requires it, wear a respirator. Use of airline respirators in areas of high
concentration or confined spaces. Protect eyes with safety glasses or goggles.
Boots, aprons, and chemical suits are available for heavy exposures. Electrically
ground all containers when pouring or transferring solvents.
EMERGENCY/SPECIAL: Danger, these products are flammable! In the event of
a spill, eliminate ignition sources, evacuate the area, and contact the Fire
Department. In the event of eye contact, flush eyes for 15 minutes with water.
For skin contact, wash skin with soap and water. Remove soaked clothing and
wash before reusing. Avoid prolonged skin contact with any solvent. If ingested,
do not induce vomiting, seek medical help immediately. If inhaled, move victim to
fresh air, give artificial respiration if necessary. Avoid spillage into the public
water sewage systems.
3.
ADHESIVES/SEALERS
a.
Adhesives
CHARACTERISTICS: Adhesives are made-up of resins composed of two
reaction components 1) the curing agent (hardener, catalyst, accelerator,
activator or setting agent) and 2) the resin. The cured resins are generally found
in a paste form, and the uncured resins are viscous liquids or solids.
HEALTH HAZARDS: Some of the cured resins contain amine curing agents. All
amines are caustic and can cause dermatitis, severe burns and sometimes
sensitization. Inhalation of amine vapors may cause irritation of the mucous
membranes and asthmatic conditions. Amines in direct contact with the eyes can
cause severe damage. Some of the liquid uncured resins are skin irritants,
sensitizers of both. Typical lesions resemble contact dermatitis with reddening
and weeping. Epoxy resins may be modified with fillers such as silicone and
asbestos. Asbestos is identified as a known carcinogen, and excessive exposure
to silica can result in the condition known as silicosis. These health hazards are
usually limited to inhalation of fine dust containing asbestos or silica. Because
the fibers are locked into a solid or semi solid form the associated health hazards
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are greatly reduced or nonexistent. Solvents are often the major component of
the uncured resins. They are primary skin irritants as a result of their ability to
dehydrate and remove natural oils of the skin. Although they in themselves are
not sensitizers they can enhance the sensitizing effects of the strong dermatitis
through inhalation may result in such symptoms as headaches, dizziness,
nausea, impairment of reaction time and incoordination. A few adhesives are
composed of polyurethanes, which are strong sensitizers. Overexposure may
produce mucous membrane irritation, chest tightness, irritation of the respiratory
tract, coughing, headache, and shortness of breath. The irritation may be severe
enough to produce bronchitis and pulmonary edema, but this is extremely rare.
PPE/HANDLING: Safety glasses should be worn at all times. Impervious gloves
and protective clothing should be worn. Remove and wash soaked clothing
before reuse. If inhalation overexposure results, remove the subject to fresh air.
These adhesives should only be used in well ventilated areas. Use of organic
vapor respirators may be necessary if ventilation seems inadequate.
EMERGENCY/SPECIAL: Keep all stored material away from heat and flames.
Adequate ventilation should be provided if any of the liquid components spill. In
the event of eye contact, flush with water for 15 minutes, and if the skin is
exposed, wash the effected area with soap and water. In the event of ingestion,
do not induce vomiting. Seek medical help immediately.
b.
Sealants
CHARACTERISTICS: Sealants are found in paste form and are generally
composed of polysulfides or polysiloxznes. These compounds offer great
resistance to oils and solvents and are impermeable to gases. As with adhesives
the sealants are furnished in two parts which cure at room temperature when
blended.
HEALTH HAZARDS: The catalyst for the polysulfide based sealants can contain
lead peroxide (lead dioxide). This form of lead has not been documented to
cause any adverse health effects upon exposure as do other forms of lead.
Some sealants contain calcium dichromate as a catalyst agent. As with lead, the
hazardous effects associated with the chromate are noted if inhaled n the form of
mists and dusts. A few sealants may be composed of polyureathanes. These
compounds act as sensitizers. All of the sealants contain small amounts of
solvent. The presence of solvents may give some grades a fairly strong odor.
The primary exposure in handling sealants is skin contact, especially broken
areas, resulting in contact dermatitis if excessive.
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PPE/HANDLING: As noted above, the primary result of exposure for sealants is
via the skin. It is necessary to avoid excessive exposure to the hands by using
gloves and/or protective hand creams. Should exposure occur, wash affected
areas thoroughly with water. Safety goggles should be worn to protect the eyes.
Again, if contact is made with the eyes, flush with water for 15 minutes. Adequate
general ventilation is sufficient to reduce solvent vapor exposure.
EMERGENCY/SPECIAL: Store sealants in closed containers in sheltered area.
Keep away from heat, sparks and open flame. Upon burning toxic vapors may be
emitted.
4.
CORROSIVES
a.
Acids, liquid, Water Soluble
CHARACTERISTICS: Acids are usually clear or slightly tinted solutions of
dissolved salts. They are usually nonflammable, but are very reactive and
corrosive. They tend to have a very strong, pungent odor, and their dangerous
properties are greatly magnified when the solutions are heated. They are used in
treating, plating, etching, batteries, and other processes. Examples of acids are
nitric acid, hydrofluoric acid, hydrochloric acid, phosphoric acid, sulfuric acid, and
chromic acid.
HEALTH HAZARDS: Acids are very powerful corrosives. They will react quickly
with human tissues causing severe burns that are painful and slow healing. Acid
mists can cause severe eye irritation and respiratory irritation including coughing
and burning sensations. The liquid can cause severe eye burns and may result in
blindness. Most acids will cause immediate pain, but some acids are slow, and
will cause great damage before sensations of pain are evident. Acids will react
with bare metals and produce hydrogen gas, a fire/explosion hazard.
PPE/HANDLING: For working with acids, eye safety glasses or goggles and
neoprene/acid resistant gloves are mandatory. For very concentrated acids, face
shields, aprons, boots are necessary. Avoid vapors and any contact with skin.
Always add concentrated acids to water (do not add water to acids) using full
protective equipment. Use local ventilation, and the use of a full organic
vapor/acid gas respirator or airline respirator may be necessary. Store in cool,
dry, well ventilated areas, away from alkaline type materials. Avoid contact with
reactive materials (aluminum and/or magnesium). Avoid storing in direct sunlight.
EMERGENCY/SPECIAL: In the event of eye or skin contact, flush with water for
15 minutes. If acids are swallowed DO NOT INDUCE VOMITING. Give plenty of
water, seek immediate medical attention. Do not give liquids to unconscious
victims, remove contaminated clothing, wash before reuse. If inhalation has
occurred and breathing stops, give artificial respiration. In the event of a large
spill, evacuate area, and contact the Fire Department.
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b.
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Bases, Caustics, Water Soluble.
CHARACTERISTICS: Bases are usually clear or slightly tinted solutions of
various dissolved salts. They are not flammable, but highly reactive and very
corrosive. They tend to have a very strong, biting odor, and are used in cleaning
solutions, neutralizers, drain openers and chemical processes. Their dangerous
properties tend to increase at higher temperatures. Examples of basic solutions
include sodium hydroxide, potassium hydroxide, Kolene, and "Draino" type drain
opening solutions.
HEALTH HAZARDS: Bases are powerful corrosives. They will react quickly with
human tissue causing severe burns that are painful and slow healing. The mists
and vapors can cause eye irritation and respiratory irritation including coughing
and burning sensations. The liquid can cause severe eye burns and may result in
blindness. If swallowed bases may produce severe burns of the mouth, throat,
and intestinal tract; stomach pains and diarrhea may also be evident. Most bases
will cause immediate pain, but some react slowly, causing great damage before
sensations of pain are evident.
PPE/HANDLING: For working with bases, eye safety glasses or goggles and
neoprene/acid resistant gloves are mandatory. For very concentrated bases, face
shields, aprons, and boots are necessary. Avoid breathing vapors and contact
with skin. Bases will destroy most clothing materials. Always add concentrated
bases to water (DO NOT ADD WATER TO BASES) using full protective
equipment. Use local ventilation, and the use of a full face acid gas or vapor
respirator or airline respirators may be necessary in areas of high concentration.
Store in cool, dry, well ventilated areas, away from acid materials. Avoid contact
with aluminum, zinc, tin, and like alloys with concentrated product. Do not mix
with strong acids without dilution first.
EMERGENCY/SPECIAL: In the event of eye or skin contact, flush with water;
this must- be started within 1 minute of exposure to minimize damage, and must
be continued for 15 minutes. Some bases will cause great damage before pain,
so washing off exposed tissue is very important. If bases are swallowed, DO
NOT INDUCE VOMITING, give plenty of water, seek immediate medical
attention, give artificial respiration if necessary. In the event of a large spill,
evacuate area, call Fire Department.
5.
COMPRESSED GASES
a.
General
Store cylinders in well ventilated areas. Keep cylinders away from sources of
heat. Storage should not be in heavy traffic areas so as to prevent accidental
knocking over or damage from passing or falling objects. Valve caps should
remain on cylinders not connected for use. Segregate full and empty cylinders.
Storage areas should be free of combustible material. Avoid exposure to areas
where salt or corrosive chemicals are present. Secure cylinders when not in use.
Avoid dragging, rolling or sliding cylinders even for a short distance. Do not use
compressed air to blow off clothing or to perform any operations in which the gas
stream is directed against the body. Always point to the cylinder valve opening
away from yourself and
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other personnel while "cracking" the valve to clear the opening of dirt, dust or
moisture. Do not "crack" the cylinder valve of highly toxic or flammable gases in
confined, non-ventilated areas.
b.
Flammable Gases
CHARACTERISTICS: Acetylene gas used in the gas welding process is a
flammable gas. Acetylene is colorless at normal temperatures and pressure, but
has a garlic-like odor. This gas is a simple asphyxiant which in increased
concentrations can reduce the oxygen levels in air (normally about 21%) to
dangerous levels (18% or lower) which can cause asphyxiation.
HEALTH HAZARDS: Acetylene exposure under moderate concentrations may
cause headaches, drowsiness, dizziness and unconsciousness.
PPE/HANDLING: Impervious gloves and safety glasses should be worn when
handling cylinders. Both gases are extremely flammable and form explosive
mixtures with air and oxidizing agents.
EMERGENCY/SPECIAL: Evacuate all personnel from danger area.
c.
Oxygen Gas Cylinders.
CHARACTERISTICS: Accelerates the combustion of flammable materials.
HEALTH HAZARDS: Breathing high concentrations causes symptoms of
hyperopia including cramps, nausea, dizziness, hypothermia, respiratory
difficulties, fainting, and convulsions capable of leading to death.
PPE/HANDLING: Protective loose-fitting gloves of impermeable material such as
leather and safety glasses should be used when handling gas cylinders.
Prevent liquid oxygen from contacting grease, oil, asphalt or combustibles.
Ventilate area to evaporate and disperse oxygen. Avoid smoking and contact
with Sources of ignition after exposure to concentrations of oxygen. Materials
which burn in air will burn violently in an atmosphere of oxygen. Some materials
will burn in pure oxygen which are nonflammable in air. Oxygen is not to be used
as a substitute for compressed air.
EMERGENCY/SPECIAL: Attempt to stop the source of release. Evacuate all
personnel from effected area. Use appropriate protective equipment. Remove all
sources of heat or ignition and ventilate area.
6.
PAINTS & DYES
a.
Water Based Acrylics, Latex Paints
CHARACTERISTICS: These products are available in a variety of colors for
many uses including interior and exterior painting of equipment, vehicles, aircraft,
and facilities. They are usually nonflammable, but some may burn under extreme
situations. They are pigmented with a variety of compounds, and usually have a
thick, soupy consistency with a mild ammonia odor.
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HEALTH HAZARDS:
Water based paints are generally considered
nonhazardous. Some may contain solvents that may produce mild eye and/or
nose irritation. Some of these products may produce limited skin conditions in
extremely sensitive people. These products may be harmful if swallowed. In
general, under normal working conditions, these products are generally
considered safe for use.
PPE/HANDLING:
General ventilation should be sufficient, with exhaust
ventilation for very confined spaces. Goggles or eye protection should always be
used in any painting process. Gloves and aprons are recommended for
extremely sensitive individuals. Avoid any unnecessary exposures. Do not
freeze this product. Store in stainless steel or baked phenolic coated drums.
Wash hands/skin with soap and water after use. Store in a cool, dry place.
EMERGENCY/SPECIAL: In the event of eye contact, flush, with water for 15
minutes, consult physician if irritation persists. If excessive inhalation occurs,
remove victim to fresh air, and call physician. In the event of ingestion give water
and contact physician immediately. Wash soaked clothes before reuse. Use
soap and water to wash skin.
b.
Inks, Stains, Dyes
CHARACTERISTICS: Inks, stains, and dyes usually consist of a small amount of
pigment dissolved in a large quantity of various solvents. This means that the
hazards associated with inks are very much like those associated with organic
solvents. They are usually thin, water-like solutions with intense colors. Most are
highly flammable and non-reactive. Solvents contained in these products include
methyl ethyl ketone, isopropyl alcohol, methanol, toluene, xylene, and butyl
alcohol.
HEALTH HAZARDS: When used in small quantities, these dyes should pose no
real health hazards. When used excessively, over long periods of time, some of
the solvents may cause problems in the organ systems of the human body. The
vapors from these products may cause respiratory and eye irritation. Direct
contact of the liquid in the eyes might result in redness, blurred vision, or tearing.
These products may be mildly irritating to the skin, causing dermatitis in some
cases. Some of the solvents may enter the bloodstream through the skin.
Absorption through the skin, and inhalation of excessively high concentrations of
vapors may produce central nervous system depressive symptoms such as
nausea, headache, and dizziness. Ingestion of any amount may result in nausea,
vomiting, and irritation of the mucous lining. Also possible is blindness and death.
These products are harmful and can be fatal if swallowed.
PPE/HANDLING: Do not use these products in enclosed areas. If necessary,
use organic vapor respirators or airline respirators in emergency situations. Avoid
inhaling any unnecessary vapors. For people whose skin is irritated, nitrile rubber
gloves are recommended. Always wear eye protection when using these
products. Stains can be removed from hands using pumice type soap. Use hand
lotions to prevent drying of hands.
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EMERGENCY/SPECIAL: Caution: flammable products, avoid heat; flames and
sparks. In the event of eye exposure, flush with water for 15 minutes. Wash skin
with soap and water, remove soaked clothing and wash before reuse. In the
unlikely event of swallowing, give plenty of water and immediately seek medical
attention. Do not delay in seeking help. If excessive inhalation has taken place,
remove to fresh air, apply artificial respiration if necessary. Seek medical help. In
the event of a large spill, eliminate ignition sources, evacuate area and call the
Fire Department. Avoid spillage into public drainage system.
7.
ABRASIVES
a.
Polishing Compounds
CHARACTERISTICS: Polishing/rubbing compounds are in the form of astes or
thick viscous liquids which are then applied to metal surfaces for finishing. They
contain for the most part petroleum derivatives (i.e. solvents) which exhibit the
characteristic odors of petroleum by-products.
HEALTH HAZARDS: As with solvent inhalation, over exposure may result in
such symptoms as headaches, nausea, impairment of reaction time and
coordination. In the case of inhalation, move the affected individual to fresh air.
Prolonged exposure to the skin can result in skin dermatitis. Any direct skin
contact with these compounds should be avoided. Eyes exposed through
splattering should be flushed with water for at least 15 minutes. Seek medical
attention if the irritation persists.
Dusts are generated with the use of the power buffers. Use of respirators should
be evaluated.
PPE/HANDLING: Eye protection in the form of goggles or safety glasses should
always be worn when working with these materials. General ventilation should be
adequate, however, if working in an area where air contaminant control is not
feasible, respirators with organic vapor cartridges should be used. If the dusts
generated present a problem dust mask may be worn. Protective cloth gloves
should be worn if repeated and prolonged exposure to hands is expected. These
compounds should be kept away from heat, sparks, and open flames.
EMERGENCY/SPECIAL: In case of accidental contact with eyes or skin, flush
with water. Remove sources of ignition if compounds are accidentally spilled.
b.
Abrasive Papers
CHARACTERISTICS: Generally referred to as "sand paper", these products
come in a variety of shapes and sizes. Generally they consist of a granular
abrasive agent (aluminum oxide, titanium oxide) adhered to a paper, cloth, or belt.
They are used in sanding, deburring, polishing, and various other common
operations.
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HEALTH HAZARDS: The primary health hazards associated with abrasive
papers is that of nuisance dust from the mechanical action associated with these
types of operations. The dust, if kept below the OSHA limits is not considered to
be hazardous to your health. During sanding operations, the object being sanded
may also release free dust, which may pose a hazard. Generally, wood sanding,
aluminum, titanium, and steel sanding pose no excessive dangers.
PPE/HANDLING: The largest concern in using abrasive papers is the inhalation
of dusts. This exposure can be limited by wearing a NIOSH approved dust/mist
respirator for nuisance dusts. Eye protection should always be worn, and gloves
may be necessary for skin sensitive people. Avoid any unnecessary inhalation of
dusts while sanding. Some operations may require wet sanding to limit
generation of dust.
EMERGENCY/SPECIAL: Use care in cleaning up dust. Do not use compressed
air to clean up sand paper dust. Sweep in controlled fashion or use a vacuum. In
the event of eye exposure, flush eyes for 15 minutes, and seek medical help if
irritation persists.
8.
SOAPS, CLEANERS, DETERGENTS
a.
Soaps, Detergents
CHARACTERISTICS: Soap and detergent products come in a variety of
compositions including powders, liquids, and creams in a variety of colors. Most
are slightly alkaline, and some may be strongly alkaline. They range in use from
mild hand soaps to strong detergents. They are usually completely water soluble,
and non flammable. Some have fragrances added.
HEALTH HAZARDS: Soaps and detergents generally present mild health
hazards. Some may be irritants to the eyes, but these effects are acute and tend
to be short-lived. Ingestion of extremely large amounts of very powerful
detergents might produce strong gastrointestinal reactions such as vomiting, pain,
cramps, and irregularity. Inhalation of these compounds is not likely to occur, but
may produce some upper respiratory irritation. Excessive exposure to soap
compounds may have a drying effect on the skin, and may produce mild skin
irritation. Strong laundry detergents may be corrosive and harmful or fatal if
swallowed.
PPE/HANDLING: Soaps and detergents are mild in nature, but should still be
handled with respect. Avoid splashing into eyes. Always use eye protection.
Avoid unnecessary skin exposure, especially to concentrated products. Use
rubber gloves if skin becomes very dry or irritated. Hand lotion is recommended
to moisturize dry skin. Do not expose soaps to powerful acids or oxidizers.
EMERGENCY/SPECIAL: In the event of eye exposure, flush with large amounts
of water. If irritation persists, seek medical attention. In the case of ingestion,
give water and seek medical attention immediately. Flush skin with water. Avoid
pouring or spilling concentrated products into sewage systems. In the event of a
spill, wash with plenty of water. In a major spill, call the Fire Department.
Evacuate immediate area.
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b.
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Waterless Hand Cleaners
CHARACTERISTICS: These products usually come in a gel or cream and are
usually tinted and mildly fragranced. They are used to wash oils, some paints,
inks, and other grease products from the skin. They are water soluble, and
usually come in small containers designed for personal use. They are generally
made from light mineral oil compounds and may contain a variety of other
compounds in limited quantities.
HEALTH HAZARDS: The health hazards associated with these products are
minimal. Ingestion and inhalation of any significant amount is very unlikely.
These products may produce some eye irritation and mild skin irritation.
PPE/HANDLING: Under normal use, this product poses no real threat. Avoid
strong oxidizing agents and acids. Avoid ingestion and eye contact. Rinse
thoroughly after use. Hand lotion may be used to prevent drying.
EMERGENCY/SPECIAL: In the event of eye contact, flush with water, seek
medical help if irritation persists. In the event of excessive ingestion, give water,
and seek medical help. Wipe up any spill using towels or rags, rinse.
11.0
FOR HAZARDOUS MATERIALS
1.
HAZARDS
a.
b.
c.
d.
e.
2.
USAGE
a.
b.
3.
Avoid using any chemical until you have been instructed in its potential hazards
and safe use.
Make certain all substances are clearly labeled.
Notify your supervisor in the event of a chemical spill. He/she will determine what
kind of emergency response is required.
Try to stay upwind from any chemical spill.
Refer to, and be familiar with, applicable Material Safety Data Sheets (MSDS) for
all chemicals involved in your work.
Store all chemicals in approved, safety-type containers.
Use personal protective equipment which is appropriate for the chemicals you are
using. If in doubt, consult the Safety Coordinator.
GENERAL EMERGENCY PROCEDURES
Briefly, general first aid practices should be followed in the event of exposure to
hazardous materials.
EYES: Flush eyes for at least 15 minutes at an eye wash station. It is important to note
these stations in your work area before an accident occurs.
SKIN: Wash affected area with soap and water. If clothing is involved, remove and
launder before putting back on. If very caustic acids and bases are spilled, remove
soaked clothing immediately and use the safety shower.
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INGESTION: DO NOT INDUCE VOMITING - transport the affected persons to the
dispensary immediately for treatment. They will take the appropriate action.
INHALATION: Generally, removing the person to fresh air is adequate after short term
exposure to most vapors.
In the event of an emergency, call emergency 911, and contact the Project Manager.
FORMS
WESTERN UNIVERSITY OF HEALTH SCIENCES
EMPLOYEE REQUEST FOR MSDS/HAZARD COMMUNICATION PROGRAM
Dept:
Employee Name:
Request Date:
I request a copy of the Material Data Safety Sheet (MSDS) for the following materials used in the
department: (Please use the trade name of the material.)
1.
2.
3.
I request a copy of the Hazard Communication Program.
Yes
Employee Signature
No
Date
For Safety Department Use
Date Received:
MSDS Provided On:
Received By:
Request File On:
Comments:
Note:
If MSDS is not available, management will contact the appropriate supplier to request a
MSDS.
HAZARD COMMUNICATION PROGRAM INVENTORY LIST
Location/Facility
Prepared By
HAZARDOUS
SUBSTANCE
MANUFACTURER
Date Prepared
OPERATION/AREA
WHERE USED
MSDS
AVAILABLE
DATE MSDS
PREPARED
(INQUIRY LETTER)
Gentlemen:
RE: Material Safety Data Sheets (MSDS)
The California Hazard Communication Regulation or "Right to Know" Law requires employers to advise
employees of hazardous materials used in the workplace on a regular or routine basis.
In accordance with the Law, manufacturers and vendors of toxic materials must provide material safety
information for employer/purchasers. We would like material safety data sheets (MSDS) and any other
related information on the following items:
MSDS information will be used to develop and conduct employee safety training. We would appreciate
your expeditious handling of this request.
Sincerely,
Western University of Health Sciences
University Safety Coordinator