CHEM 1301 FALL 2004 TEST 2 VERSION 1 NO CHEATING! BUBBLE IN “1” IN THE P COLUMN TO GET YOUR GRADE POSTED!!!!! [the only way you’ll find out how you did!] 1. How many valence electrons does an arsenic atom have? (A) 33 2. An atom has the valence electron configuration, ns2np5. What group is it in? (A) noble gas 3. Which ions should be formed by magnesium, nitrogen, and chlorine, respectively? (A) Mg2+, N3-, Cl- 4. Which element, isotope, or ion listed below contains 40 protons, 56 neutrons, and 36 electrons? (A) 96 5. Consider the ion formed by an atom of selenium-80. How many protons, electrons and neutrons does it contain? (A) 34, 34, 46 6. How many valence electrons should be drawn in the Lewis dot structure of the polyatomic anion GaCl4 ? (A) 99 7. What is the formula of aluminum sulfide? (A) AlS Zr4+ (B) (B) (B) (B) (B) 15 alkali metal Mn7+, N3-, C4+ 96 Zr4- 34, 36, 46 (C) (C) (C) (C) (C) 8 alkaline earth metal Mg2+, N5+, Cl- 84 Kr 34, 36, 80 (D) 5 (E) 3 (D) chalcogen (E) halogen Mg+, N5+, C4+ (E) Mg+, N3-, Cl- (E) 96 (D) (D) (D) 91 Zr4+ 36, 36, 44 Kr (E) 34, 34, 80 - (B) (B) 100 AlSO3 (C) 42 (D) 31 (E) 32 (C) Al3S2 (D) Al2(SO3)3 (E) Al2S3 1 8. Which of the following molecules can be correctly described by a Lewis structure that contains only single bonds? (A) C2F4 9. Which molecule contains two unshared pairs of valence electrons? (A) H2Te 10. Within the context of this course, which of the following statements is false? (A) (B) (C) (D) (E) Hydrogen will never make more than one bond Carbon will never make more than four bonds Compounds are known that contain noble gas atoms Nitrogen will never make more than 3 bonds Sulfur can form more than 4 bonds 11. Which of the following molecules has an ideal Lewis structure (that is, all atoms happy)? (A) BH3 12. What is the name given to the compound whose formula is S3F6? (A) (D) sulfur fluorine sulfur fluoride 13. Which of the following has a charge of –1? (A) ammonium 14. Which of the following compounds contains both ionic and covalent bonds? (A) HCl (B) (B) (B) C2F2 (C) AsF3 (C) NO2 (C) (B) (E) (B) (B) carbonate NaCl CO2 SF4 BH4- trisodium hexafluoride trisulfur hexafluoride (C) (C) phosphate H2O 2 (D) N2F2 (E) N2F4 (D) Cl2 (E) SiSe2 (D) XeF2 (E) SiF6 (C) trisulfur sexafluoride (D) sulfate (E) acetate (D) NaOH (E) CO2 15. Bearing in mind the relationship between sulfate and sulfite or nitrate and nitrite, what is the formula of phosphite? (A) PO43- 16. What is the formula of aluminum sulfite? (A) AlS 17. Which one of the following will contain at least one angle of 90º? (A) BCl3 18. Which of the following species would have a bent shape? (A) BCl3 19. In reality, one finds that lone pairs are more repulsive than bonding groups. With this in mind, what would be the observed angle in nitrite? (A) 109.5° 20. Which atom in each of the following pairs is more electronegative? (A) (D) (B) (B) (B) (B) (B) I. O or S I. O I. S II. N II. C II. III. O III. Cl HPO43- AlSO3 SF6 (C) PO42- (D) PO33- (E) PO32- (C) Al2(SO4)3 (D) Al2(SO3)3 (E) Al2S3 SO2 (D) CH4 (E) CS2 SeO2 (D) CO32- (E) PBr3 (C) CO2 (C) 120° (C) C or N (B) (E) <109.5° III. O or Cl I. O I. S II. C II. N III. Cl III. O 3 (D) >120° (C) I. O (E) II. N III. Cl <120°
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