Maximum Energy Products (kJ/m ) 3 60 400 50 320 40 240 30 160 20 80 10 0 0 Maximum Energy Products (MGOe) 480 Guiding principles which led to the new magnets: Transition Guiding principle Old New Alnico SmCo5 Getting high coercivity by using high anisotropy fields originated from 4f electrons SmCo5 Sm2Co17 Getting high remanence by using high saturation magnetization of Sm2Co17 Sm2Co17 Nd2Fe14B Getting an Fe-base magnet by extending the search for R-Fe-X ternary systems with various R (R=Rare Earth) At MMM Conference, November 10, 1983 Map of the magnetic properties of the NdFeB sintered magnets and corresponding applications MRI, Speaker 50 HDD, CD, DVD, MD, VTR, Digital camera, Head phone -50 BH)max MGOe 45 -48 -46BH ABS sensor -49H 40 OA FA motor -40BH 35 X NEOMAX N NEOREC 30 10 -39SH -38AH Servo motor Compressor motor -35SH -35EH Motor for robotics Generator HEV driving motor -32EH 20 HcJ kOe 30 Map of the magnetic properties of the NdFeB sintered magnets and corresponding applications MRI, Speaker 50 HDD, CD, DVD, MD, VTR, Digital camera, Head phone -50 -48BH -46BH BH)max MGOe 45 -44H 40 OA FA motor -42VH -39SH -38VH 35 30 2000 ABS sensor Servo motor Compressor motor -35SH -35EH 1987 Motor for robotics Generator HEV driving motor -32EH 10 20 HcJ kOe 30 Process for the NdFeB sintered magnets Raw Materials Nd, Dy, Fe, B Melting Course Grinding Jet Milling Compaction Sintering Annealing Process for the NdFeB sintered magnets Raw Materials Melting Course Grinding Strip Casting Hydrogen Decrepitation Jet Milling Compaction Nd, Dy, Fe, B Improvements: Lubricant Low pressure pressing Binder High magnetic field Low oxygen process Sintering Annealing Amount of Production(t/year) NdFeB Sintered Magnets Amount of Production(t/year) NdFeB Bonded Magnets Map of the magnetic properties of the NdFeB sintered magnets and corresponding applications MRI, Speaker 50 HDD, CD, DVD, MD, VTR, Digital camera, Head phone -50 BH)max MGOe 45 -48BH -46BH ABS sensor -44H 40 OA FA motor -42VH 35 X NEOMAX N NEOREC 30 10 -39SH -38VH Servo motor Compressor motor -35SH -35EH Motor for robotics Generator HEV driving motor -32EH 20 HcJ kOe 30 VCM Application of NdFeB sintered magnets (Pick-up for CD-ROM) Tracking coil Focus coil NdFeB magnet Optical pick-up Lense Application of NdFeB sintered magnet (IPM compressor motor for air conditioner) Outside the house Compressor Inside the house NdFeB magnet DC motor IPM rotor Air Conditioner Induction motor IPM synchronous motor Efficiency isimproved by 20% statistically ! 35km/liter! Map of the magnetic properties of the NdFeB sintered magnets and corresponding applications MRI, Speaker 50 HDD, CD, DVD, MD, VTR, Digital camera, Head phone -50 BH)max MGOe 45 -48BH -46BH ABS sensor -44H 40 Strong needs OA FA motor -42VH 35 X NEOMAX N NEOREC 30 10 -39SH -38VH Servo motor Compressor motor -35SH -35EH Motor for robotics Generator HEV driving motor -32EH 20 HcJ kOe 30 Composition of the NdFeB sintered magnets 31Nd-68Fe-1B 50 BH)max MGOe 45 26Nd-5Dy-68Fe-1B 40 Nature Dy 35 Nd 21Nd-10Dy-68Fe-1B 0.1 30 10 20 HcJ kOe 30 Map of the magnetic properties of the NdFeB sintered magnets and corresponding applications MRI, Speaker 50 HDD, CD, DVD, MD, VTR, Digital camera, Head phone -50 BH)max MGOe 45 -48BH -46BH Hybrid car application requires this range ! ABS sensor -44H 40 OA FA motor -42VH 35 X NEOMAX N NEOREC 30 10 -39SH -38VH Servo motor Compressor motor -35SH -35EH Motor for robotics Generator HEV driving motor -32EH 20 HcJ kOe 30 Direction of our development 50 BH)max MGOe 45 0% Dy Incr eas ing 40 35 ani sot rop y 30 10 20 HcJ kOe 30 Sintering Pressless Process (PLP) PLP Coercivity of NdFeB sintered magnets (PLP Experimental data) 25 2.7μm 17kOe 20 HcJ kOe 2.9μm 16.5kOe 5μm 13.5kOe 15 10 1 1.5 2 3 3 4 5 6 7 8 9 10 4.5 6.0 7.5 9.0 12.0 15.0 D 1.5d Particle size d μm Grain size D μm PLP Record 50 BH)max MGOe 45 0% Dy (Particle size=2.7μm 40 35 30 10 20 HcJ kOe 30 Prices of Rare Earths /kg Nd price also soars ! 2005 2006 2007 /kg Prices of Rare Earths Our goal for PLP Net Shape Production Yield 90 New National Project in Japan Subject:“Development of Alternative Materials for Rare Metals” Rare Metals: W for toolings Dy for NdFeB magnets In for LCD Term: 2007 2011 Budget: 5.5BJPY ( 34M€ Members for Dy: Intermetallics Co., Ltd. Tohoku University NationalInstitute for Material Science etc. Coercivity of NdFeB sintered magnets (PLP Experimental data) 25 2.7μm 17kOe 20 HcJ kOe 2.9μm 16.5kOe 5μm 13.5kOe 15 10 1 1.5 2 3 3 4 5 6 7 8 9 10 4.5 6.0 7.5 9.0 12.0 15.0 D 1.5d Particle size d μm Grain size D μm Object of the National Project 50 BH)max MGOe 45 0% Dy Present level 40 35 30 10 20 HcJ kOe 30 How to reach the object ? Athorough investigation about the relation between microstructure and coercivityin NdFeB magnets. Athorough investigation about the mechanism of the magnetization reversal,including calculations based on the first principle. Determination of the ideal structure for the NdFeB magnet. Determination of the process for the NdFeB magnet with the ideal structure. “NdFeB Magnets rescue the Earth.” To rescue the Earth,let’s act: All motors in allfactories →NdFeB PM motors All motors for elevators → NdFeB PM motors All motors for air conditioners →NdFeB PM motors All motors for refrigerators → NdFeB PM motors All motors for trains →NdFeB PM motors Allcars →HEV or EV Problems ? Let’s overcome ! e. g. Shortage of Nd, Dy ? → Find new mines ! Cost of NdFeB magnets ? → Find a way for cost reduction ! Cost of HEV → Develop HEV with acceptable cost ! (Toyota is doing.) Isitimpossible to find a new magnet after the NdFeB magnet ? To find a new magnet after the NdFeB magnet, a new guiding principle must be found: The guiding principle for the NdFeB magnet is useless any more. We have allsorts of mystery in the coercivity of the NdFeB magnets. Profound and thorough researches on the coercivity of the NdFeB magnets willgive us a new guiding principle for a new magnet!
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