Surfboard Project Part 2 by Marie Joo Le Guen and Roger H Newman 26 June 2008 Output 42615 2 The opinions provided in the Report have been provided in good faith and on the basis that every endeavour has been made to be accurate and not misleading and to exercise reasonable care, skill and judgment in providing such opinions. Neither Scion nor any of its employees, contractors, agents or other persons acting on its behalf or under its control accept any responsibility or liability in respect of any opinion provided in this Report By Scion. Output 42615 SURFBOARD PROJECT PART 2 ABSTRACT Two full-scale surfboards were constructed by replacing the conventional glass-fibre reinforcement by harakeke and/or ramie fibres. Both surfboards were constructed around a conventional polyurethane foam core, and the fibres were contained in a conventional unsaturated polyester resin. Surfboard 2 was reinforced with ramie plainweave fabric mats. Two mats were used, a green tie-dyed mat on the deck and a bleached mat on the keel. Surfboard 3 was also reinforced with ramie plain-weave fabric on deck and keel, and a red harakeke wet-laid mat was added on the deck for decorative purpose. For both boards, the white colour of the keel was enhanced by mixing white pigment with the resin. Both surfboards were tested in surf, without obvious damage except for a shallow dent in Surfboard 2. Fabric is better than wet-laid reinforcement, in terms of high performance surfing, but wet-laid reinforcement offers decorative effects and a combination of fabric and wet-laid fibre shows potential. 1. INTRODUCTION Background FRST contract BPLY0402 included Objective 1: “Natural Fibre Networks and their Composites”. Milestone 9 (Prototype Trials) specified: “Complete prototype trials with industry partner(s) for a concept or target product or intermediate product based on natural fibres or a natural fibre network.” Such prototypes included glass-free surfboards, fabricated and tested in a project that involved Sunshine Design and Surf, Mt Manganui. Surfboard 1 was reinforced with mats of harakeke wet-laid fibre, and described in an earlier report (Le Guen 2007). Testing in the surf showed some weaknesses, especially in impact strength, and examples of damage were recorded (Le Guen 2007). Surfboard 2 and 3 were designed to assess ideas for improving the mechanical properties. Discussions with the surfboard shaper (Mike Murden, Sunshine Design and Surf) identified two specific problems encountered in construction of Surfboard 1. (1) The harakeke reinforcing mats soaked up resin. Since the mats had a weight of just 40 g m-2, this meant that the weight of harakeke reinforcement was just one third of the weight of a conventional “4-ounce” glass fabric. Surfboard 1 was therefore fragile relative to a conventional design. (2) The harakeke reinforcing mats showed poor drapeability and permeability, so resin became trapped in an uneven manner. Subsequent shaping removed fibre from the high points, leaving resin that was poorly reinforced. The tight curves of the rails were particularly fragile. A review of fibre-network compaction has shown that woven reinforcement can be compacted to approximately three times the volume fraction of non-woven reinforcement (Toll 1998). In other words, we should be able to treble the volume of plant-fibre reinforcement simply by switching from non-woven to plain-woven reinforcement. Hemp fabric is commonly used in surfboards, e.g. by Sustainable Output 42615 4 Composites Ltd (www.suscomp.com). Our experience with plain-weave linen suggested that moisture uptake might cause problems (Burns and Newman 2006). We tried to avoid those problems by selecting a reinforcing fibre with an exceptionally low content of non-cellulosic matter, i.e., plain-weave ramie fabric (Newman and Le Guen 2008). 2. EXPERIMENTAL 2.1 Surfboard 2 The ramie fabric was imported from China under the name Dazhu Golden Bridge ramie fabric. More details are provided elsewhere (Newman and Le Guen 2008). The grammage was approximately 125 g m-2. Four mats were cut into rectangles approximately 2 m by 1 m. One was tie-dyed for the deck. 2.1.1 Tie-dyeing process Two small samples were dyed in preliminary experiments, in to get the concentration of the dye and the design right. The dye used was a commercial cloth dye; Dylon 59 Green verdure, purchased in Spotlight. Sample 1: 7 g of fabric was tied with 6 knots and immersed in 300 ml of warm water with 7 g of salt and 2.8 g of dye (Figure 1). Sample 2: 7 g of fabric was tied with 4 knots and immersed in 300 ml of warm water with 7 g of salt and 1.4 g of dye (Figure 2). Figure 1: Sample 1 Figure 2: Sample 2 From a design point of view, the conditions for preparing Sample 1 seemed preferable, so they were selected for the full-size mat. Eight rubber bands were attached to the full size mat (2 m by 1 m) representing 191 g of fabric. The mat was immersed for 2 h in 4.5 L of warm water in a bucket with 76.4 g of dye and 191 g of table salt. It was then rinsed with water until there was no dye bleeding out the fabric. The mat was then ironed (Figure 3). Output 42615 5 Figure 3: Tie-dyed ramie fabric mat 2.1.2 Bleaching process To accentuate the white colour of the other three mats, they were bleached with commercial bleach powder. The bleach used was NapiSan® OxyAction® made and distributed by Reckitt Benckiser and purchased in Countdown Rotorua. The three mats were bleached at the same time in a 10 L solution at 200 g L-1 of bleach. They were left 48h then rinsed and ironed. The four mats were then sent by courier to Mike Murden (Mount Maunganui) to be used in shaping Surfboard 2. 2.1.3 Characteristics of Surfboard 2 The shaper used 2 plies, one tie-dyed mat on the deck and one white mat on the keel. The bleaching process of the mat was not enough to get a pure white colour, so white pigment was added to the resin on the bottom part. The shaper experienced difficulty in wrapping the fabric around the tight curvature of the rails, and used grey tape to hide the defects. The mass of Surfboard 2 was 3305 g without fins. This surfboard was sufficiently light to be recognised as a high-performance board. Surfboard 2 was tested for a first immersion in the Blue Lake over a period of less than one hour, and in the waves in Mount Maunganui as a kite-surf board (Figure 4). No obvious damage was recorded, apart from a shallow dent attributed to pressure applied by a heel on the deck. It was used again in confused surf after a storm at Riversdale Output 42615 6 Beach, with no further visible damage. Although the initial intention was to test this board to destruction, the weather patterns over the summer of 2007-2008 meant that most of the scheduled tests were cancelled. Figure 4: Damien Even kite surfing on surfboard 2 2.2 Surfboard 3 Surfboard 3 was built with a hybrid reinforcement combining the decorative design of a harakeke reinforcing mat and the strong mechanical properties of plain-weave ramie fabric. Harakeke line fibre was obtained from the Templeton Flax Mill via AgResearch. One kilogram of raw fibres was chopped in 2.5 cm in length with scissors and then soaked in water one overnight. The pulp used in Surfboard 1 showed an abundance of coarse fibres which were partly removed by hand. To avoid this work, the fibres for Surfboard 3 were pulped at the same temperature but at higher sodium hydroxide concentration (45 g L-1) and over a longer time. The raw fibres were drained but the water uptake was measured and allowed for in making up the pulping liquor. The liquor-to-fibre ratio was 16:1, with a NaOH charge of 36% of the oven-dried weight of harakeke fibres. Anthroquinone was added at 0.18% of the weight of harakeke fibres. The temperature was raised to 140 ºC over 90 minutes and held for a cooking time of 180 minutes. The pulp was cooled and washed with water, then kept wet at 4 °C in plastic bags into the PAPRO fridge to avoid fungal growth. To obtain a good quality pulp, the pulped fibres were beaten in the 3 L egg beater by 100 g portion into 500 mL of water for a period of 10 min at high speed (speed 10). As expected, the proportion of coarse fibres was smaller than in the case of Surfboard 1. . Output 42615 7 Production of each mat used 540 g of wet fibres which corresponded to a grammage of the air-dry mats of approximately 65 g m-2. Two bags of pulp, each containing 540 g, were dyed with a cloth dye “DYLON 36 Cherry Red”. Each bag of fibre was dissolved in 10 L of warm water (50 °C) with 500 g of table salt and 100 g of dye. During the first 15 minutes, the fibres were stirred and then left during 45 additional minutes. The pulp was washed with cold water until the water flowed colourless. 2.2.1 Wet laying The two harakeke reinforcing mats were made with the same equipment and the same procedure as the mats for Surfboard 1, except for weather conditions. Surfboard 1 was made in summer time, allowing the mat to dry quickly unlike Surfboard 3 which was made at the beginning of winter in cold conditions (Figure 5). Once made, the mats were air dried and ironed flat. The best-looking one was cut to a rectangle 2 m by 0.65 m and hot pressed at 50 °C under 450 KN pressure (Figure 6). The grammage of the mat was 60 g m-2. The hot pressed mat was sent to the shaper. The second one kept for display. Figure 5: Wet mat Figure 6: Dry mat after ironing. 2.2.2 Bleaching process Three ramie mats were bleached in the same conditions as Surfboard 2, then treated with laundry detergent , and finally fabric conditioner to increase their permeability. The laundry detergent was Coldpower washing liquid and the commercial fabric conditioner was Cuddly, both manufactured by Colgate Palmolive Ltd, Petone, New Zealand. The mats were washed with 20 g L-1 of cold power in 10L then rinse and let to soak overnight in 6 L of conditioner at 33 g L-1. Output 42615 8 2.1.3 Characteristics of Surfboard 3 The shaper used 3 plies, two on the deck (ramie and Cherry red Harakeke mats) and one ramie mat on the keel. The bleaching process of the mat was not enough to get a pure white colour, so white pigment was added to the resin on the keel as for Surfboard 2. The ramie mats were difficult to shape around the rails, and perhaps even more difficult than the untreated mats used on Surfboard 2. The detergent/conditioner treatment did not work as well as expected. The shaper hid defects by adding black tape around the rails. The mass of the surfboard was 4155 g without fins. This was a little too heavy for the board to be regarded as “high performance.” Surfboard 3 was tested for three times in surf conditions: twice in photographic sessions aimed at the Scion 2007 Christmas card and once for TV1 news item. No damage was observed during these tests, but there was minor damage to nose and rails during storage at Scion and in moving the surfboard between rooms for display purposes. 3. RESULTS AND DISCUSSION Construction of Surfboards 2 and 3 completed a colour-coded series that allowed comparison between three types of construction: (a) Blue (Surfboard 1): all harakeke wet-laid fibre. (b) Red (Surfboard 3): a combination of plain-weave ramie fabric and harakeke wetlaid fibre. (c) Green (Surfboard 2): all ramie plain-weave fabric. The weight decreased as the proportion of ramie fabric increased (Fig. 7). In comparing these weights, it is important to consider the contributions from the foam blank with stringer (2.21 kg) and fins (0.23). These contributions are represented by the white bars in Fig. 7. The known weights of the surfboards, along with known area densities (grammages) of reinforcement provided the information required for estimation of fibre fractions and skin thicknesses (Table 1). A surface area of 0.60 m2 was assumed for each of the decks and keels, based on interpretation of a photograph of Surfboard 1. The area of the rails was neglected in these calculations. It was assumed that the weight of the foam blank was the same as that of a shaped blank provided by Mike Murden, i.e., 2.208 kg including stringer. It was assumed that the shaper achieved the same fibre fraction in the ramie-reinforced layers of Surfboard 3 as in Surfboard 2. According to the estimated values in Table 1, the harakeke-reinforced surface layer on deck of Surfboard 3 contained a slightly higher fibre fraction than the deck of Surfboard 1. The difference was attributed to use of mats with different grammage: 60 g m-2 for Surfboard 3, compared with two layers of 40 g m-2 for Surfboard 1. The lesson learnt here was that it is better to use one high-grammage mat than two low-grammage mats. Even higher grammages were not considered desirable, because of problems with drapability and permeability. High-grammage mats trap pockets of resin. In future work, it might be helpful to punch holes in the mats to allow resin to escape. Similar problems were encountered with the ramie fabric. The shaper pointed out that the weave was Output 42615 9 closer than desirable. If production was shifted to a commercial basis, it would be desirable to specify a looser weave, i.e., similar yarn linear density but a lower thread count in both warp and weft directions. The problem of permeability is illustrated in Fig. 8, which shows holes approximately 0.5 mm square in a typical glass “four-ounce cloth” designed for surfboards, and holes approximately 0.2 mm square in plain-weave ramie cloth. Figure 7: Weights of three surfboards, showing the advantages of using woven fabric (ramie) rather than random mats (harakeke). Each surfboard was weighed with fins but without leash. The white portion of each bar indicates the contribution from the foam, the stringer and the fins. The coloured portion indicates the contribution from the fibrereinforced shell. Table 1. Surfboard data. Brackets indicate assumed values. Surfboard and part Fibre Fibre weight fraction Fibre volume fraction Composite Thickness of this density -3 layer (kg m ) (mm) Surfboard 1 (blue) Deck Harakeke 0.032 0.027 1182 2.1 Keel Harakeke 0.032 0.027 1182 1.1 Ramie 0.137 0.111 1212 0.75 Deck (surface) Harakeke 0.042 0.036 1183 1.2 Deck (base) Ramie (0.137) (0.111) (1212) (0.75) Keel Ramie (0.137 (0.111) (1212) (0.75) Surfboard 2 (green) Deck & keel Surfboard 3 (red) Output 42615 10 Figure 8. Scanned images of (left) plain-weave glass “four-ounce cloth”, (right) plainweave ramie fabric. Each square shows a portion 25 mm by 25 mm. Low weight and high strength are just two of many requirements for surfboards. Visual appearance is another requirement, and the red surfboard was selected for publicity purposes because of a combination of attractive appearance and adequate strength/weight ratio. Figures 9 to 11 show additional photos of the full set of three surfboards. While the bold patterns of the tie-dyed ramie in Surfboard 2 are clearly visible at a distance, the choice of a green colour was criticised by a user. The surfboard was not clearly visible in surf, and the surfer sometimes felt he was “walking on water”, lacking visual input to judge his stance on the board. Figure 9. Surfboard 2. The tie-dyed ramie deck is so thin that the wooden stringer is visible, running through the centre line from nose to tail. Output 42615 11 Figure 10. Surfboard 3. The random pattern of coarse and fine fibres is not obvious in this oblique view. Figure 10: Surfboards with shells reinforced by harakeke reinforcing mat (left), and ramie plain-weave fabric (right). 4. CONCLUSIONS Plain-weave fabric is better than wet-laid reinforcement, in terms of high performance surfing, but wet-laid reinforcement offers decorative effects. A combination of fabric and wet-laid fibre shows potential. Output 42615 12 5. ACKNOWLEDGEMENTS The authors thank the Biopolymer Network Limited for funding under New Zealand Foundation for Research Science and Technology contract BPLY0402, Mike Murden for shaping the surfboards, and Damien Even and Kent Newman for their assistance in testing Surfboard 2. 6. REFERENCES Burns J, Newman RH (2006) Epoxy-biofibre composites containing epoxidised vegetable oil. Scion Report 11533, Output 39251. Le Guen MJ (2007) Harakeke surfboard project. Scion Report 12282, Output 41075. Newman RH and Le Guen MJ (2008) Ramie plain-weave fabric as reinforcement for unsaturated polyester resin. Scion Report 12813, Output 42532. Toll S. (1998) Packing mechanics of fiber reinforcements. Polymer Engineering and Science, 38, 1337-1350. Output 42615
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