VER# LILYTAB VER 1.01 MATERIAL SAFETY DATA SHEET Date prepared: January 2012 Cooper's Own Self Dissolving Lily Tabs (All Sizes) SECTION I. IDENTIFICATION OF THE PREPARATION AND COMPANY PRODUCT NAME Cooper's Own Self Dissolving Lily Tabs USE OF SUBSTANCE DEODORIZING WASTE TREATMENT TABLETS PolyJohn Enterprisese 2500 Gaspar Ave. COMPANY Whiting, IN USA TELEPHONE EMERGENCY TELEPHONE FAX E-MAIL 219-659-1152 1-800-535-5053 219-659-0625 SECTION II. HAZARDS IDENTIFICATION CLASSIFICATION The product is classified as IRRITANT Irritating to skin Risk of serious damage to eyes In concentrated form, may be harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment SECTION III. COMPOSITION/INFORMATION ON INGREDIENTS CAS # EINECS # CONCENTRATION % W/W CLASSIFICATION AND RISK PHRASES Xn; R21/22 Xi; R37/38-41 N; R50 Xn; R22-41 Octylphenol ethoxylate 9002-93-1 Polymer N; R51/53 Other classified trade secret and non classified components are also present in the product. Their cautions and risks are included in the classification of this product. Bronopol 52-51-7 200-143-0 SECTION IV. FIRST AID MEASURES IN EYES: ON SKIN: SWALLOWED: INHALED: Immediately flush eyes with water for 15 minutes. Remove contact lenses and continue flushing. If irritation persists, seek medical attention. Wash skin after contact. Do not wear contaminated clothing. If redness, itching, or a burning sensation develops, get medical attention. Rinse mouth. Do not induce vomiting. Seek medical attention immediately. Move to fresh air. If cough or irritation develops, seek medical attention. SECTION V. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: SPECIAL FIRE FIGHTING PROCEDURES: UNUSUAL FIRE AND EXPLOSION HAZARDS: COMBUSTION PRODUCTS: Page 1 of 3 Water, carbon dioxide, dry chemical, foam Wear self-contained breathing apparatus to fight fires. Not considered to be a fire or explosion hazard. Bromine; oxides of carbon, nitrogen, and sulfur VER# LILYTAB VER 1.01 SECTION VI. ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE OF RELEASE OR SPILL: General procedures are to sweep up and recover. Dispose of waste in accordance with local regulations. See section VII below for handling precautions. Wear appropriate personal protective equipment. Residues may be washed down drain to municipal waste water. SECTION VII. HANDLING AND STORAGE The tablets have individual water soluble wrapping. Under normal use, the product ingredients should not come into contact with an operator. HANDLING In case of accidental contact, avoid ingestion. Harmful if swallowed. Wash hands well before eating or smoking. Avoid skin contact. Do not get into eyes, on skin, or on clothing. Irritant to eyes and may cause skin irritation. May cause eye damage if not removed promptly. Avoid breathing dust. STORING Keep away from water. Store in a cool, dry environment 0°C minimum to 25°C maximum. Keep away from heat source. KEEP OUT OF REACH OF CHILDREN. USE FOR INDUSTRIAL USE ONLY. To provide cleaning and deodorizing for portable toilets. To use, dissolve tablet in water (typically 20 L) in toilet holding tank. SECTION VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION VENTILATION: Normal room ventilation is adequate. RESPIRATORY PROTECTION: Not necessary under conditions of normal use. HANDS: Gloves recommended. EYES: Tablets are wrapped, not necessary under conditions of normal use. OTHER: Eye wash station HYGENIC PRACTICES: Wash hands thoroughly after handling. EXPOSURE LIMIT VALUES: None of the ingredients have exposure limit values. SECTION IX. PHYSICAL/CHEMICAL CHARACTERISTICS INITIAL BOILING POINT: N/A VAPOR PRESSURE: N/A VAPOR DENSITY (air=1): N/A SOLUBILITY IN WATER: 100% FLAMMABILITY: Not classified VISCOSITY: N/A APPEARANCE AND ODOR: Blue tablet with pleasant fragrance SPECIFIC GRAVITY (water=1): NE MELTING POINT: N/A EVAPORATION RATE (butyl acetate=1): N/A OXIDISING PROPERTIES: Not classified SECTION X. STABILITY AND REACTIVITY DATA STABILITY: INCOMPATIBILITY (materials to avoid): HAZARDOUS DECOMPOSITION PRODUCTS: HAZARDOUS POLYMERIZATION: CONDITIONS TO AVOID: Stable Water will cause effervescence. Avoid alkalis and amines Bromine; oxides of carbon, nitrogen, and sulfur Will not occur Temperatures above 140°C SECTION XI. TOXICOLOGICAL INFORMATION CARCINOGENICITY: No NTP: No RC MONOGRAPHS: NE OSHA REGULATED: NE EFFECTS OF OVEREXPOSURE: Irritation to eyes, skin, respiratory and digestive systems. MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE: NE No data are available on the formulated product. The product has been classified in accordance with the conventional methods. It is incumbent upon the user to exercise precautions to ensure that persons using this product are not dangerously exposed to eye contact and that skin exposure is properly washed to remove material. SECTION XII. ECOLOGICAL INFORMATION Product has been classified as Water Hazard Class category 1 (Slightly hazardous to water) Most sensitive end-point: Algal EC50 for the product determined to be 11.9mg product/L. SECTION XIII. DISPOSAL CONSIDERATIONS Dispose of in accordance with all appropriate governmental regulations. Wastes resulting from use of this product may be disposed of on-site or at an approved waste disposal facility. Keep container closed when not in use. The tablets have individual water soluble wrapping and are contained in a HDPE zip-lock bag, which, as it does not come into contact with the tablet ingredients, can be disposed of as normal non-hazardous waste. SECTION XIV. TRANSPORT INFORMATION Product is not classified for any mode of transportation. Not considered a Haz-Mat. Page 2 of 3 VER# LILYTAB VER 1.01 SECTION XV. REGULATORY INFORMATION Hazard Symbols Xi-Irritants Risk Phrases Irritating to skin Risk of serious damage to eyes Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Safety phrases In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection This material and its container must be disposed of in a safe way SECTION XVI. OTHER INFORMATION Risk Phrases in section III but not included in Section XV. R21- Harmful in contact with skin; R22-harmful if swallowed; R36-Irritating to eyes; R37-Irritating to respiratory system; R60-May impair fertility; R61- May cause harm to the unborn child; R50-Very toxic to aquatic organisms Version number: LILYTAB VER 1.01 Reason for revision: Major revision The information accumulated herein is believed to be accurate but is not warranted. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. NE: not established N/A: not applicable Page 3 of 3
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