SEMINCK GAS Gas distributie en Service Diebeke 12 • B-9500 Geraardsbergen tel 054/41.41.11 • fax 054/41.40.28 [email protected] • www.seminck.be Safety Data Sheet for propane, butane and LPG 1 & 2 Chemical product and company identification Supplier Product Formula CAS-nr EINECS-nr EG-nr Product use Main substances 3 Seminck Gas Commercial propane C3H8 74-98-6 200-827-9 601-003-00-5 Fuel Propane Seminck Gas Commercial butane C4H10 0106-97-8 203-448-7 601-004-00-0 Fuel Butane Seminck Gas LPG C3H8 + C4H10 Fuel for automobiles Mix of propane and butane Hazards Flammable products. Heavier than air. Inhalation of vapors causes: dizziness, headache and nausea. When inhaling a high concentration this may result in onconsciousness due to lack of oxygen. Can cause severe frostbite when the liquid comes into contact with skin or eyes. Frostbite and burn wounds are similar in appearance and severity. 4 First Aid measures Inhalation: bring the victim into fresh air. Contact with liquid: bring the victim into a heated room. Remove clothing slowly Contact with bare skin and/or eyes: rinse with plenty of water. 5 Fire-fighting measures Close the gas supply before extinguishing the flame. Apply water from a safe distance to cool storage tanks & cylinders. 6 Accidental release measures Close the gas supply. Provide natural ventilation, if possible prevent the gas from spreading by spraying with water. Remove any source of ignition. 7 Handling and storage These products are liquid under pressure and will be stored in special containers in a well ventilated area. Storage tanks must always be grounded. Use only costum accessories (valves, hoses, pressure regulators, ...) 8 Exposure controls & personal protection If contact with the liquid is possible, use suitable protection such as insulating gloves and face protection, ... 9 Physical and chemical properties Commercial propane Liquid under pressure Evaporates immediately Belgian norm T52-706 Odor Typical unpleasant odor Density at 15°C 0,510 kg/l Density relative to air 1,54 (heavier than air) Boiling point -42°C Vapour pressure at +5°C 5,2 bar Vapour pressure at + 15°C 7,5 bar Ignition temperature 450°C Explosion limits LEL: 2,4 volume % with air Max. Ratio UEL: 9,3 volume % with air Flame temperature w/ air 1920°C Calorific value 13,8 kWh MAK (mg/m3) 1800 mg/m3 10 Commercial butane Liquid under pressure Evaporates immediately T52-706 Typical unpleasant odor 0,570 kg/l 2,07 (heavier than air) + 1°C 0,8 bar 1,7 bar 405°C LEL: 1,8 volume % with air UEL: 8,8 volume % with air 1915°C 13,7 kWh 1800 mg/m3 LPG fuel Liquid under pressure Evaporates immediately EN 589 Typical unpleasant odor 0,540 kg/l 1,81 (heavier than air) - 20°C 3,0 bar 4,6 bar 430°C LEL: 1,8 volume % UEL: 9,3 volume % 1920°C 13,8 kWh 1800 mg/m3 Stability and reactivity After combustion with air: CO, CO2 and water are left Avoid contact with strong oxidizers. 11 Toxicological information Toxicological effects of these products are unknown. 12 Ecological information These products will not cause any pollution to the soil, water or air. 13 Disposal considerations According to local, national regulations. Preferably by controlled combustion 14 Transport information ADR: Class 2, 2F 15 UN nr: 1965 GI nr: 23 Label: figure 3 Regulatory information - Symbol F + R12: lightly flammable product - The EG-nr - S9: Keep in a well ventilated area - S16: Keep away from sources of ignition. No smoking - S33: Take precautionary measures against static electricity. 16 Other information To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. SEMINCK GAS Gas distributie en Service Diebeke 12 • B-9500 Geraardsbergen tel 054/41.41.11 • fax 054/41.40.28 • [email protected] • www.seminck.be
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