Aerosol Ca.n Management in HHW Programs Presented at the 1993 National HHW Conference in Burlington, Vermont by Wayne Turner HHW Management Coordinator City of Greensboro Greensboro, North Carolina on Tuesday, November 9,1993 1. Introduction I It’s time to take a closer look at aerosol can management in HHW Programs. The mysterious nature of the closed, pressurized aerosol can has kept it from gerring its proper share of atrention from otherwise aggressive HHW Managers bent on squeezing the last dollar out of an already tight budget by bulking everydung possible. The liquid contents in aerosol cans have, in large part, been ignored as candidates for consolidation. Consequently, HHW Managers have accepted the idea that responsible aerosol management means simply packing the cans in a steel drum and shipping them to a hazardous waste incinerator. The moderate costs of aerosol can disposal has also contributed to this attitude of indifference. But with the increased development and use of equipment designed to safely and efficiently separate aerosol can components, it is time we reexamine aerosol can management in HHW Programs. Aerosol cans may now represent the next frontier for waste minimization and recycling efforts. By separating the individual components of aerosol cans, some important objectives of any HHW Program may be met. 1. Waste minimization 2. Beneficial reuse of products 3. Recycling of products 4. Reduced costs II. Background Aerosol products are packaged in closed steel cans that come in a variety of sizes. Product net weights usually fall in a range from 1 to 24 oz. Products including deodorants, hair sprays, automotive cleaners, household cleaners, paints and pesticides are packaged in aerosol form. Each aerosol can also includes a propellant in the form of a compressed, liquefied gas such as butane or propane. The compressed gas is responsible for creating the pressure which propels the product out of the can when the valve is pushed open. The propellant is also responsible, in part, for the convenience of traditional aerosol can management methods. Since most of the propellant gases are flammable, they are easily categorized and shipped under the flammable =mas hazard class. Most aerosol cans brought to HHW hgms are only parrially full of the ori-&al products. Because they are only partially full, the cans themsehes may represent a large share of the total weight of material destined for disposal. For example, if the net weight of the contents of a full aerosol can is 11 oz. which has only 10% left in it and the can weighs 4 oz., then the can represents 78.4%of the total weight. Of course, if aerosol cans are completely empty, they should be recycled or landfilled, whichever is appropriate in a given locale. At many HHW Collection Programs, aerosol cans are simply collected and placed directly in drums for shipment and disposal. This traditional method of aerosol can disposal packa,$ng is called ‘lab packing’ or PLC (packed lab chemicals). It is also sometimes called ‘loose packing’ since aerosols arc seldom packed with any absorbent material. The proper management of aerosol cans requires that those with any residual contents be disposed of as hazardous waste because of the presence of the flammable propellants. Aerosol cans normally are sent to hazardous waste incinerators for disposal. 218 Recently some companies have developed systems which can safely separate the liquid contents and propellants from the can. There are varying levels of sophistication to the different brands of equipment but what they all have in common is that they allow the liquid contents in the aerosol cans to be collected in a drum. This is accomplished by puncturing the can with either a hand operated or automated can punch. Some systems recover the propellant gases in a cylinder for reuse or disposal. Other systems simply use an activated charcoal filter to absorb the propellant gases. The depressurizing of aerosol containers in order to recover or filter the propellants and bulk the liquid contents prior to disposal can be a huge source of savings to HHW Programs over the traditional PLC method of disposal. This report demonstrates the cost effectiveness of such an alternative method to aerosol can disposal. 111. Discussion As stated above, there is a wide range of products that come in aerosol form. However, the most prevalent ones that are brought to HHW Collection Programs are paints and pesticides. This discussion will focus on these two categories of aerosol products. The most direct and useful method to compare costs for disposal of aerosol cans is on a per can basis. However, since no data exists showing a per can disposal cost for aerosol cans, it will have to be calculated. Although this calculation may be done on the basis of either volume or weight, data on aerosol product weights is far more plentiful. Using this data, the steps necessary to do this are as follows. 1. Determine aerosol net product weight 2. Calculate number of aerosol cans emptied in drum 3. Calculate disposal cost per aerosol can 4. Calculate savings per can 1. Determine Aemo1 Net Product Weiyht In order to determine the net weight of aerosol paints and pesticides, product weight information on as many different brands as possible was obtained from aerosol cans in local retail stores and from l2 T Distribution of Aerosol Product Weights in Retail Stores (Grouped by Product Type) Pest. Paint Hafr Deod. L9 Aut0 Fa C l n r . -.. - Product N e t W e l g h t (in 02.) Figure m-1 219 aerosol PLC packing slips from HHW collection events. The data gathered from the retail stores was analyze&and sorted by product type. When grouped by product type, as shown in figure III- 1, the aerosol product data from retail stores reveals that most paint products are packaged in the 11 - 12 oz. weight range. Of the 11 brands of aerosol paints from which information was taken, 4 brands were packaged only in the 12 oz. size, 4 brands only in the 11 oz. size, 1 brand in both the 11 and 12 oz. size, 1 brand in both a 12 oz. and 15 oz. size and 1 brand in a 3 oz. size. Eleven of the 13 cans examined, or 85.6%,fell within the 11 - 12 oz. weight range. It can also be Seen that pesticides, appear to be packaged in sizes that generally range from 14 - 17 oz. in weight. Of the 5 brands of aerosol pesticides from which information was taken, only one packaged the product in a can that had less than 14 oz. of product, Six of the 9 different cans examined, or 66.7%,fell within the 15 17 oz. weight range. From this we can conclude that most aerosol paints are packaged 11 - 12 ozJ can and most aerosol pesticides are packaged 15 - 17 oz./can. Distribution of Aerosol Product Weights from HHW Programs 2500 2000 m c a 1500 u * 0 0 a: 1000 500 0 2 3 4 5 6 7 8 9 IO 1 1 12 13 14 IS 16 17 18 19 2 0 2 2 24 3 6 40 Product N e t Weight (In 02) Figure III-2 By examining aerosol can data from HHW collection days along with the data from the retail stores, a definite pattem of can sizes and product types emerges. Packing slip data from HHW aerosol lab packs, representing over 5,400 aerosol cans, was examined. The net product weight for each aerosol can packed in the drum was recorded from the packing slips. The data was then analyzed and plotted graphically. The results, shown in figure III-2, reveal that of all aerosol cans included in the investigation, 41.2%of them contained 12 oz. and 21.1%contained 16 oz. of product when full. Since all the aerosol cans were shipped under the flammable gas hazard class, the waste description on the packing slips did not indicate what type of product was in each lab pack. However, if we apply the data from Figure III-1 to this data, we can conclude that most of the 12 oz. products were paints and most of the 16 oz. products were pesticides. We may also conclude that the choice of aerosol paints and pesticides for management review is sound since they represent a large share of the total aerosol waste stream in HHW Programs.We can now select a 12 oz. product weight for paints and a 16 OZ. product weight for pesticides to use in further calculations in this discussion. These product net weights and additional important information necessary for calculating the disposal cost/can are summarized in Table III-1 below. 220 Aerosol Can Management Assumptiom Net wt. of aerosol paint products Net wt. of aerosol pesticide products N e t w t . o f liquids in a 55 gal. steel drum (50 gals) Disposal cost f o r PLC aerosol cans Disposal cost f o r bulk liquid paints Disposal cost f o r bulk liquid pesticides 12 0 2 . 16 0 2 . 400 l b s 6,400 0 2 . $475/drum $ 200 / d r u m $588 / d r u m Table III-1 The figure for the net weight of liquids in a 55 gallon drum was computed by assuming the liquids would have an estimated weight of 8 pounds per gallon. The drums are assumed to be filled to 50 gallons, thus allowing enough freeboard (headspace) for expansion. The disposal costs for lab packed aerosol cans and bulked liquids for each of the two categories were obtained from two nationally known commercial hazardous waste companies. One company provided mainly a hazardous waste collection and transportation service while the other was a full service company providing collection, transportation and ultimate disposal of materials at their own permitted facilities. The cost figures, two each for paints and pesticides, were very close, so the average used in table ID-1should be very consistent industry-wide. The substantially lower cost to dispose of a drum of buked paints over a drum of PLC aerosol paints is due to the fact that the bulked paints can be beneficially reused through a fuels blending program, whereas the lab packed cans would have to be incinerated. Disposal of high-btu paints through a fuels program is typically much less expensive than incineration. On the other hand, note that the cost to dispose of a drum of bulk pesticides is somewhat higher than the cost to dispose of a drum of PLC aerosol pesticides. However, since a greater number of aerosol cans can be decanted into a drum than can be lab packed into one, the higher drum cost should be offset by the greater consolidation of material. . 1.nto Drum 2. C a l c W the Number 0f Cans Emptled To calculate the number of aerosol cans that can be emptiedkto a 55 gallon drum, we need to know the weight of the product remaining in the cans, Since there are no data available on the amount of aerosol products remaining in cans in HHW Programs, another equally useful approach would be to calculate a range of values that represents the number of cans that can be emptied into a drum depending on how much product remains in the cans. To do this, we simply apply a remaining product factor (0%- 100%in 10%increments) to the original product net weight to calculate a range of remaining product weights per can. Table III-2 shows the results of this calculation for both the paint and pesticide products. The number of cans/drum was computed by dividing the 6,400 02. drum capacity by each remaining product weight value. The two waste streams must be shown separately because, 1) once decanted they have significantly different disposal costs, and 2) their product net weights are different, both of which will affect the disposal cost per can. Using the values for the number of cans that can be emptied into a 55 gallon drum,we can now calculate disposal costs/cm. 221 I Number of Cans Emptied into a 55 gallon Drum % Product Remaining 10 20 30 40 50 60 70 80 90 100 Paints Rem. Prod. Number Cans/Drum W t . i n Oz. 1.20 2.40 3.60 4.80 6.00 7.20 8.40 9.60 10.80 12.00 5,333 2,667 1,778 1,333 1,067 889 762 667 593 533 Pesticides Number Rem. Prod. W t . i n 02. CandDrum 1.60 3.20 4.80 6.40 8.00 9.60 1 1.20 12.80 14.40 16.00 4,000 2,000 1,333 1,000 800 667 57 1 500 444 400 Table lII-2 3. #calculateDisppsal Costs Per Aerosol Can With the infoxmation we now have, we can calculate the disposal cost per can for both lab packed and bulked aerosol cans. The lab pack calculation is very straightforward yet requires one additional piece of data. To calculate the cost/can for lab packed aerosols, we need to know how many cans will fit into a 55 gallon drum. This has been a most Micult piece of data to obtain. Although tens of thousands of drums of lab packed aerosols have been shipped from HHW Programs, very few people have found it necessary to know how many cans are in them. Moreover, since the number of cans that will fit inside a drum is more a function of their volume than weight, it is unreasonable to assume that it can be computed by dividing the weight of a can into the weight of a drum full of cans. It is important to note that products having the same net weight may be packaged aerosol cans of different physical size. However, some HHW programs now bulking aerosol products have conducted some can counts during the initial collection and sorting of the aerosols. Information from these programs indicates that approximately 234 aerosol cans will fit inside a 55 gallon drum. This information is used to compute the cost/can for lab packed aerosol cans shown below in Figure III-3. The $2.03 figure is calculated by dividing the $475/drum lab pack cost by the 234 caddrum capacity of the lab pack. Disposal Cost/Can for Lab Packed Aerosol Cans Disposal cosUdrum for aerosol lab packs = Number of aerosol cans/drum = Disposal costkan for aerosol lab packs = Figure III-3 222 $475/drum 234/drum $2.03/can Following the same format for the calculation of the number of cans that can be emptied into a drum for bulked aerosol products, a range of values are shown for the bulk disposal costs depending on how much product remains in the can. Table a - 3 illustrates these costs for the two aerosol products being discussed, paints and pesticides. The disposal cost/can is computed by dividing the $2OO/drum cost for bulk paint and the $588/drum cost for bulk pesticides by each cans/drum value. Empty aerosol cans should represent no cost to HHW Programs (i.e. recycled or landfiied. In fact, evtry HKW Program should have as one of its key educational components, information encouraging consumers to use up products when appropriate and to toss the empty containers in either the recycling bin or the garbage.) On the other hand, disposal costs for full aerosol cans that are bulked would cost no more than $0.38/can for paint products and $1.47/can for pesticide products. Obviously, most aerosol cans brought to HHW Programs would most likely fall somewhere between these two extremes of being completely full or empty. And although it becomes readily apparent that a sigrufcant cost savings can result from bulking aerosol products, let's continue and calculate the savings for the entire range of product remaining values. Disposal Costs/Can for Bulked Aerosol Products Paints % Product Disposal Remaining Cans/Drum Cost/Can 10 20 30 40 50 60 70 80 90 100 5,333 2,667 1,778 1,333 1,067 889 762 667 593 533 0.04 0.08 0.1 1 0.15 0.19 0.23 0.26 0.30 0.34 0.38 P e s t ic i d e s Disposal C a n s I D r u m CostICan 4,000 2,000 1,333 1,000 800 667 57 1 500 444 400 0.15 0.29 0-44 0.59 0.73 0.88 1.03 1.18 1.32 1.47 Table III-3 4. s v'n3 A e r o s o1 P rodm As shown in Table ID-4, the savings that can be realized by bulking aerosol products are substantial. The savingskan figures are computed by subtracting each bulk disposal cost/can from the $2.03 PLC cost/can. A minimum of 81.53% of the disposal costs for aerosol paints using PLC packing methods can be saved by using the bulk packing method. A minimurn of 27.64%of the disposal costs for aerosol pesticides using PLC packing methods can be saved by using the bulk packing method. Using infomation from paint products remaining in gallon cans and data froman HHW Program that is bulking aerosol paints, it is safe to assume that the average amount of product remaining in aerosol cans will fall within the 25% - 45% range. This means that savings should fall within the range of 90% - 96% for paints and 63% - 85% for pesticides. It should be noted that the savings for bulking pesticides may be somewhat offset by higher labor costs due to the possible necessity of using a higher level of PPE during the processing of the waste. 223 SavingdCan for Bulked Aerosol Products W Product Remaining 10 20 30 40 50 60 70 80 90 100 Paints Savings W Savings per Can per Can 1.99 1.95 1.92 1.88 1.84 1.80 1.77 1.73 1.69 1.65 98.15 96.31 9 4.46 92.6 1 90.76 88.92 87.07 85.22 83.37 8 1.53 Pesticides Savings X Savings p e r Can p e r Can 1.88 1.74 1.59 1.44 1.30 1.15 1 .oo 0.85 0.71 0.56 92.76 85.53 78.29 7 1.06 63.82 56.59 49.35 42.12 34.88 27.64 Table m-4 IV. Conclusion At the outset of this report, some important potential benefits of separating the components of aerosol cans were enumerated. This report has demonstrated how each of these benefits can be achieved. Waste can be minimized by separating the hazardous liquid from the cans, aerosol paints which are bulked can be reused beneficially in a fuels blending program, the empty steel cans can be recycled and reduced disposal costs can result in substantial savings. Every HHW Program Manager in the United States has probably been, at one time or another, in a position of trying to explain why their program costs so much. Over the 10 to 13 years that HHW Programs have been in existence a great deal of progress has been made toward minimizing wastes and reducing disposal costs. Lets not let the mysterious nature of the aerosol can waste stream lessen our diligence. With the advent of improved aerosol can evacuation techniques and equipment, it is now time to take a look at how its use can save your program money. The cost savings that can be realized by utilizing this method of waste processing makes it worth investigating. Appendix A contains the names of companies that manufacture and sell aerosol can evacuation equipment. Note: If you have any questions about aerosol can management in HHW Programs, I will be happy to try and answer them. My phone number and address is shown below. B. Wayne Turner HHW Management Coordinator City of Greensboro P. 0. Box 3 136 Greensboro, NC 27402 (919) 373-2167 224 Appendix A Aerosol Can Evacuation Equipment Manufacturers Katec (Aerosolv) P. 0. Box 3399 Virginia Beach, VA 23454 Mike Campbell (804) 428-8822 Aervoe-Pacific Company 1198 Sawmill Road Gardnerville, NV 89410 Mark Williams 1-800-548-4656 American Gas Products 7200 Greenleaf Avenue, Suite 250 Whittier, CA 90602 Robert J. Hohne (3 10) 693-2431
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