Skill Practice 48 Name: ______________________________ Date: _______________ Hour: _____ 1. A certain substance in solution is known to increase the concentration of H3O+. Is this substance an acid or a base? Acid 2. Given the following reaction, identify the Arrhenius acid and describe why the substance you chose is an Arrhenius acid. H2SO4 Æ HSO4- + H+ It is an acid because it increases the concentration of H+ in solution. 3. How do the Bronsted-Lowry definitions and the Arrhenius definitions differ? Bronsted-Lowry: an acid donates a proton (H+) Arrhenius: an acid increases the concentration of H+ in solution. 4. Describe the difference between a weak and a strong acid. Strong acids dissociate completely, but weak acids only dissociate partially. 5. In each of the following reactions identify an acid (if there is one) and then specify whether it is an acid according to the Arrhenius definitions or the Bronsted-Lowry definitions or both. a) H2CO3 + CN- Æ HCN + HCO3- Bronsted-Lowry b) F- + HSO4- Æ HF + SO42- Bronsted-Lowry c) HSO4- + H2O Æ H3O+ + SO42- Both 6. What is the conjugate base of HCN? CN- © 2004 by Jason Neil. All rights reserved. Skill Practice 49 Name: ______________________________ Date: _______________ Hour: _____ 1. What is the pH of a 0.034 M solution of HNO3? 1.47 3. Calculate the pH of a 0.0105 M solution of NaOH? 12.0212 4. a) Calculate the pH of a 0.025 M solution of HNO3. 1.60 b) What is the pOH of this solution? 12.40 5. Calculate [H+], [OH-], pOH and the pH for a 0.0015 M solution of HCl. [H+] = 0.0015 M [OH-] = 6.67x10-12 M pOH = 11.18 pH = 2.82 6. Calculate [H+], [OH-], pOH and the pH for a 0.00024 M solution of sodium hydroxide, NaOH. [H+] = 4.17x10-11 M [OH-] = 0.00024 M pOH = 3.62 pH = 10.38 © 2004 by Jason Neil. All rights reserved. Skill Practice 50 Name: ______________________________ Date: _______________ Hour: _____ 1. What is the pH of a 0.34 M solution of HNO3? 0.47 2. What is the pH of a 0.34 M solution of benzoic acid (Ka=6.3x10-5) ? 2.33 3. Compare the concentrations and pH of each solution in questions 1 and 2. Why are weak acids called weak? What is the relationship between a weak acid’s Ka value and the pH? Weak acids do not dissociate completely. The larger the Ka, the lower the pH. 4. Acetic acid (HC2H3O2) has an ionization constant of 1.7x10-5. What is the Kb for C2H3O2- ? 5.88x10-10 5. What is the pH of a 0.16 M solution of acetic acid? 2.78 6. A 0.25 M solution of an unknown acid has a pH of 2.5. What is the Ka of the acid? 4.05x10-5 7. Ammonia is a weak base with Kb = 1.8x10-5. What is the pH of a 0.5 M solution of NH3? 11.48 8. A 0.045 M solution of a certain unknown base has a pH of 9.7. What is the Kb for this base? 5.58x10-8 © 2004 by Jason Neil. All rights reserved. Skill Practice 52 Name: ______________________________ Date: _______________ Hour: _____ 1. Indicate whether the following salts will result in an acidic (A), basic (B), or neutral (N) pH when dissolved in water. __A__ a) NH4Cl __N__ b) NaCl __B__ e) Na2C2H3O2 __A__ f) NH4Cl __N__ g) MgCl2 __B__ c) Mg(CN)2 __B__ d) CaF2 __N__ h) Ca(NO3)2 2. What is the pH of a solution formed by dissolving 25.8 g of ammonium chloride (NH4Cl) in 1.5 L of water? 4.87 3. A solution was made by adding acetic acid and a salt to water. The concentration of acetic acid in the solution was 0.5 M. The pH of the solution was found to be 3.3. Was the salt calcium chloride or sodium acetate? Explain. The pH of 0.5 M acetic acid is 2.5. Since the solution with the salt has a pH of 3.3, the salt must be basic. Sodium acetate if basic; calcium chloride would not affect the pH. 4. Calculate the pH of a 0.045 M solution of sodium benzoate. (Benzoate is the anion formed from benzoic acid, which has a Ka of 6.3x10-5.) 8.43 5. What effect on the pH does NH4NO3 have when it is added to a solution of ammonia in water? It lowers the pH. 6. Calculate the pH of a 0.035 M solution of sodium acetate. 5.34 7. Calculate the pH of a 0.00046 M solution of NH4Cl. 6.30 © 2004 by Jason Neil. All rights reserved.
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