SAFETY DATA SHEET
According to JIS Z 7253:2012
Revision Date 04-Sep-2014
Version 5
Section 1: PRODUCT AND COMPANY IDENTIFICATION
Product name
Product code
CAS No
Phosphoryl Chloride
165-02282,169-02285
10025-87-3
Formula
POCl3
Manufacturer
Wako Pure Chemical Industries, Ltd.
1-2 Doshomachi 3-Chome, Chuo-ku, Osaka 540-8605, Japan
Phone: +81 (0)6-6203-3741
Fax: +81 (0)6-6201-5964
Wako Pure Chemical Industries, Ltd.
1-2 Doshomachi 3-Chome, Chuo-ku, Osaka 540-8605, Japan
Phone: +81 (0)6-6203-3741
Fax: +81 (0)6-6201-5964
+81-6-6203-3741 / +81-3-3270-8571
For research purposes
Supplier
Emergency telephone number
Recommended uses and
restrictions on use
Section 2: HAZARDS IDENTIFICATION
GHS classification
Classification of the substance or mixture
Acute toxicity - Oral
Acute toxicity - Inhalation (Vapors)
Skin corrosion/irritation
Serious eye damage/eye irritation
Specific target organ toxicity (single exposure)
Category 1 central nervous system, respiratory system
Specific target organ toxicity (repeated exposure)
Category 1 central nervous system, respiratory system, kidneys
Category 4
Category 1
Category 1 A
Category 1
Category 1
Category 1
Pictograms
Signal word
Danger
Hazard statements
H314 - Causes severe skin burns and eye damage
H318 - Causes serious eye damage
H302 - Harmful if swallowed
H330 - Fatal if inhaled
H370 - Causes damage to the following organs: central nervous system, respiratory system
H372 - Causes damage to the following organs through prolonged or repeated exposure: central nervous system, respiratory
system, kidneys
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Precautionary statements-(Prevention)
Precautionary statements-(Response)
rinsing
Precautionary statements-(Storage)
Precautionary statements-(Disposal)
Others
Other hazards
Not available
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
Single Substance or Mixture
Substance
Formula
POCl3
Chemical Name
Phosphoryl chloride
Impurities and/or Additives
Weight-%
Molecular weight
153.33
99.0
ENCS
(1)-244
ISHL No.
N/A
CAS No
10025-87-3
Not applicable
Section 4: FIRST AID MEASURES
Inhalation
Remove to fresh air If symptoms persist, call a physician
Skin contact
Wash off immediately with soap and plenty of water If symptoms persist, call a physician
Eye contact
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing Immediate medical attention is required
Ingestion
Rinse mouth Never give anything by mouth to an unconscious person Call a physician or poison control center immediately Do
not induce vomiting without medical advice
Protection of first-aiders
Use personal protective equipment as required
Section 5: FIRE FIGHTING MEASURES
Suitable extinguishing media
carbon dioxide (CO2), Extinguishing powder,
Unsuitable extinguishing media
Water
Special extinguishing method
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No information available
Specific hazards arising from the chemical product
Thermal decomposition can lead to release of irritating and toxic gases and vapors.
Protection of fire-fighters
Use personal protective equipment as required Firefighters should wear self-contained breathing apparatus and full firefighting
turnout gear
Section 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
For indoor, provide adequate ventilation process until the end of working. Deny unnecessary entry other than the people
involved by, for example, using a rope. While working, wear appropriate protective equipments to avoid adhering it on skin, or
inhaling the gas. Work from windward, and retract the people downwind.
Environmental precautions
To be careful not discharged to the environment without being properly handled waste water contaminated
Methods and materials for contaminent and methods and materials for cleaning up
Absorb dry sand, earth, sawdust and the waste. Collect empty container that can be sealed. Please wash the rest with plenty of
water.
Recoverly, neutralization
No information available
Secondary disaster prevention measures
Clean contaminated objects and areas thoroughly observing environmental regulations
Section 7: HANDLING AND STORAGE
Handling
Technical measures
Possibility of hydrogen chloride generated by hydrolysis occurs. May be internal pressure of the container is increased. Wear
safety glasses, protective gloves, etc. when you opening Avoid contact with water and moisture. Use with local exhaust
ventilation.
Precautions
Do not rough handling containers, such as upsetting, falling, giving a shock, and dragging. Prevent leakage, overflow, and
scattering. Not to generate steam and dust in vain. Seal the container after use. After handling, wash hands and face, and then
gargle. In places other than those specified, should not be smoking or eating and drinking. Should not be brought contaminated
protective equipment and gloves to rest stops. Deny unnecessary entry of non-emergency personnel to the handling area.
Safety handling precautions
Avoid contact with skin, eyes or clothing Use personal protective equipment as required
Storage
Safe storage conditions
Storage conditions
Safe packaging material
Incompatible substances
container tightly closed. Packed with an inert gas. Store locked up
Glass
Water, Alkali, Alcohols, Amines
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering controls
For indoor, provide adequate ventilation process until the end of working. Deny unnecessary entry other than the people
involved by, for example, using a rope. While working, wear appropriate protective equipments to avoid adhering it on skin, or
inhaling the gas. Work from windward, and retract the people downwind.
Exposure limits
Chemical Name
Japan
ISHL Working Environmental
ACGIH
Evaluation Standards Administrative Control Levels
Phosphoryl chloride
N/A
N/A
TWA: 0.1 ppm
10025-87-3
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Personal protective equipment
Respiratory protection
Hand protection
Eye protection
Gas mask for acidic gas
Protection gloves
protective eyeglasses or chemical safety goggles
Long-sleeved work clothes
General hygiene considerations
Handle in accordance with good industrial hygiene and safety practice
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Form
Odor
pH
Melting point/freezing point
Boiling point, initial boiling point and boiling range
Flash point
Evaporation rate:
Flammability (solid, gas):
Upper/lower flammability or
explosive limits
Upper
Lower
Vapour pressure
Vapour density
Specific Gravity (relatinve density)
Solubilities
n-Octanol/water partition coefficient: log Pow)
Auto-ignition temperature:
Decomposition temperature:
Viscosity (coefficient of viscosity)
Dynamic viscosity
colorless clear liquid
characteristic odor
No data available
105 °C
No data available
No data available
No data available
No data available
No data available
No data available
No data available
1.692 (15°C/15°C)
water , Ethanol : decomposes. benzene : freely soluble .
No data available
No data available
No data available
No data available
No data available
Section 10: STABILITY AND REACTIVITY
Stability
Stability
Reactivity
Hazardous reactions
altered by moisture.
No data available
Conditions to avoid
Extremes of temperature and direct sunlight, Moisture
Incompatible materials
Water, Alkali, Alcohols, Amines
Hazardous decomposition products
Hydrogen, Hydrogen chloride, Phosphoric acid, Phosphorus oxide
Section 11: TOXICOLOGICAL INFORMATION
Acute toxicity
Chemical Name
Phosphoryl chloride
Component
Phosphoryl chloride
10025-87-3 ( 99.0 )
Oral LD50
380 mg/kg ( Rat )
Dermal LD50
N/A
Acute toxicity -oral- source
information
LD50(orl,rat):380mg/kg RTECS
(2005), IUCLID (2000) .
Based on the NITE GHS
classification results.
Based on the NITE GHS
classification results.
Inhalation LC50
31.4 ppm ( Rat ) 4 h
Acute toxicity -inhalation gassource information
Based on the NITE GHS
classification results.
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Component
Phosphoryl chloride
10025-87-3 ( 99.0 )
Acute toxicity -inhalation vaporsource information
Based on the NITE GHS
classification results.
Acute toxicity -inhalation dustsource information
Based on the NITE GHS
classification results.
Acute toxicity -inhalation mistsource information
Based on the NITE GHS
classification results.
Skin irritation/corrosion
Component
Phosphoryl chloride
10025-87-3 ( 99.0 )
Skin corrosion irritation source information
Based on the NITE GHS classification results.
Serious eye damage/ irritation
Component
Phosphoryl chloride
10025-87-3 ( 99.0 )
Serious eye damage source information
Based on the NITE GHS classification results.
Respiratory or skin sensitization
Component
Phosphoryl chloride
10025-87-3 ( 99.0 )
Respiratory, Skin sensitization source information
Based on the NITE GHS classification results.
Reproductive cell mutagenicity
Component
Phosphoryl chloride
10025-87-3 ( 99.0 )
Mutagenic source information
Based on the NITE GHS classification results.
Carcinogenicity
Component
Phosphoryl chloride
10025-87-3 ( 99.0 )
Carcinogenicity source infotmation
Based on the NITE GHS classification results.
Reproductive toxicity
Component
Phosphoryl chloride
10025-87-3 ( 99.0 )
Reproductive toxicity source information
Based on the NITE GHS classification results.
STOT-single exposure
Component
Phosphoryl chloride
10025-87-3 ( 99.0 )
STOT -single exporsure- source information
Based on the NITE GHS classification results.
STOT-repeated exposure
Component
Phosphoryl chloride
10025-87-3 ( 99.0 )
STOT -repeated exposure- source information
Based on the NITE GHS classification results.
Aspiration hazard
Component
Phosphoryl chloride
10025-87-3 ( 99.0 )
Aspiration Hazard source information
Based on the NITE GHS classification results.
Section 12: ECOLOGICAL INFORMATION
Ecotoxicity
Other data
Component
Phosphoryl chloride
10025-87-3 ( 99.0 )
Persistence and degradability
Bioaccumulative potential
Mobility in soil
Hazard to the ozone layer
Aquatic toxicity -Acute- source information
Based on the NITE GHS classification
results.
Aquatic toxicity -Chronic- source information
Based on the NITE GHS classification
results.
No information available
No information available
No information available
No information available
Section 13: DISPOSAL CONSIDERATIONS
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Waste from residues
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated container and contaminated packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Section 14: TRANSPORT INFORMATION
ADR/RID
UN number
Proper shipping name:
UN classfication
Subsidiary hazard class
Packing group
Marine pollutant
IMDG
UN number
Proper shipping name:
UN classfication
Subsidiary hazard class
Packing group
EmS-No
Marine pollutant (Sea)
IATA
UN number
Proper shipping name:
UN classfication
Subsidiary hazard class
Packing group
Enviromenntally Hazardous
Substance
UN1810
6.1
8
I
Not applicable
UN1810
6.1
8
I
F-A, S-B
Not applicable
Forbidden
UN1810
I
Not applicable
Section 15: REGULATORY INFORMATION
International Inventories
EINECS/ELINCS
TSCA
Listed
Listed
Japanese regulations
Firefighting Inhibitor
Fire Service Act
Poisonous Substances 2nd. Grade
Poisonous and Deleterious
Substances Control Law
Industrial Safety and Health Act Notifiable Substances (Law Art.57-2, Enforcement Oder Art.18-2 Attached Table No.9, and
Law Art.56-1)
Not applicable
Act on the Evaluation of
Chemical Substances and
Regulation of Their Manufacture,
etc
Regulations for the carriage and Corrosive Substances (Ordinance Art.3, Ministry of Transportation Ordinance Regarding
storage of dangerous goods in Transport by Ship and Storage, Attached Table 1)
ship
Corrosive Substances (Ordinance Art.194, MITL Nortification for Air Transportation of
Civil Aeronautics Law
Explosives etc., Attached Table 1)
Marine Pollution Prevention Law
Pollutant Release and Transfer Not applicable
Register Law
Water Pollution Control Act
Not applicable
Export Trade Control Order
Appendix 1
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