/100 Assignment # 6 Lab (/25) 1. Titration Lab: Write the following: Purpose: 2-3 sentences stating why we performed this lab Observations: hand in completed lab data sheet Sample calculations: for calculations done, do 1 sample calculation to show how values were determined Conclusion: In a paragraph, discuss the following: o Lab A-1: % purity you found of the KOH and discuss why the purity of a “tech grade” substance may not be 100% o Lab A-2: compare mass content you found in tablets with the value identified on the label o Lab A-3: state molar mass and identity of salt you used. Compare with real molar mass & identity. o Lab A-4: Compare your 2 answers. Which do you think is more accurate? Why? o Lab A-5: state molar mass and identity of the carbonate you used. Compare with real molar mass & identity. o Lab A-6: State % ammonia found in commercial cleaner. Compare with value found on container. o State any errors or improvements to future labs! 2. Assign Oxidation numbers to the elements in bold print. Answer on this page! (/25) a) Mg b) P4 c) Cl f) Na2O g) Fe2O3 k) SO2 l) PCl5 p) CO3 – d) HCl e) CaO h) N2O3 i) P2O3 j) PF3 m) ThO2 n) CO2 o) CO – 2– q) Ca(VO3)2 r) ClO u) K2CrO4 v) Na2Cr2O7 w) SO3 s) NaClO2 t) KClO3 2– x) NO y) NO2 3. Balance the following eq'ns taking place using oxidation #'s. Put final answer on this page! Attach work on a separate page. (3 marks each = /30) a) MnO4 – 2– b) Cr2O7 c) SO4 2– 2+ + 2+ + H Mn Fe + H + Cr Cu + H + Cu Fe + Fe + + 2+ 3+ d) H2SO3 + Fe + H2O e) KMnO4 + HCl KCl 3+ 2+ 2+ + 3+ + Fe + Fe + H2O + SO2 + H2O + SO4 + H Cl2 + MnCl2 3+ + 2– + H2O + H2O f) CaC2O4 + g) I2 + KMnO4 + H2SO4 HIO3 HNO3 h) K2Cr2O7 + i) Sb2 (SO4) 3 j) KIO3 HCl + KMnO4 + KI + + NO2 KCl + H2 O + HCl CaSO4 + + CrCl3 + MnSO4 + H2O + H2O + H3SbO4 + KCl K2SO4 + Cl2 K2SO4 + I2 + + H2O MnSO4 + H2SO4 H2O 4. Balance the following eq'ns taking place using half-reaction method. Put final answer on this page! Attach work on a separate page. (5 marks 3ach = /20) a) O3 + I- b) Pt + NO3- c) CN – d) MnO4- – + ClO2 + I- + Cl IO3- + – – CNO I2 + + O2 PtCl6 Cl 2– – Mn+2+ + NO2 CO2
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