Working Report 2007-96 Paleomagnetism of Diabase Dykes, Pegmatitic Granites and TGG Gneisses in the Olkiluoto Area Satu Mertanen March 2008 POSIVA OY Olkiluoto FI-27160 EURAJOKI, FINLAND Tel +358-2-8372 31 Fax +358-2-8372 3709 Working Report 2007-96 Paleomagnetism of Diabase Dykes, Pegmatitic Granites and TGG Gneisses in the Olkiluoto Area Satu Mertanen Geological Survey of Finland March 2008 Base maps: ©National Land Survey, permission 41/MYY/08 Working Reports contain information on work in progress or pending completion. The conclusions and viewpoints presented in the report are those of author(s) and do not necessarily coincide with those of Posiva. Paleomagnetism of Diabase Dykes, Pegmatitic Granites and TGG Gneisses in the Olkiluoto Area ABSTRACT Paleomagnetic studies in the Olkiluoto area were carried out on two diabase dykes, on four sites of pegmatitic granites and on three sites of TGG gneisses. Remanent magnetizations in the diabase dykes are strong, and two remanence components were isolated. The other component is regarded as primary, formed during cooling of the dykes. Based on comparison to previously known Fennoscandian paleomagnetic data, the pole position of the primary component shows that the dykes are ca. 1560 Ma in age. The pole position of the poorly defined secondary component of the diabase dyke gives an age of ca. 250 Ma. Pegmatitic granites are weakly magnetized, but one pegmatitic granite site gave a rather consistent remanence direction which points to a remagnetization at ca. 1570 Ma, probably due to emplacement of the nearby rapakivi granites. The TGG gneisses do not carry any stable remanent magnetization. Keywords: paleomagnetism, remanent magnetization, Olkiluoto, Finland Olkiluodon alueen diabaasijuonten, pegmatiittisten graniittien ja TGG gneissien paleomagnetismista TIIVISTELMÄ Olkiluodon alueella on tehty paleomagnettisia tutkimuksia kahdesta diabaasijuonesta, neljältä pegmatiittiselta graniittipaljastumalta ja kahdelta TGG-gneissipaljastumalta. Diabaasijuonten remanentti magnetoituma on vahvaa, ja näytteistä on erotettu kaksi eri komponettia. Toisen remanenssikomponentin on tulkittu edustavan primääriä magnetoitumaa, joka on syntynyt diabaasimagman jäähtyessä. Verrattaessa tämän komponentin remanenssisuunnasta laskettua napaa Fennoskandian tunnettuihin paleomagneettisiin napoihin, saadaan magnetoituman ja juonten iäksi n. 1560 Ma. Sekundäärinen komponentti on erotettu vain muutamista näytteistä, mutta paleonapa antaisi remanenssin iäksi n. 250 Ma. Pegmatiittiset graniitit ovat heikosti magnetoituneita, mutta yhdeltä paljastumalta erotettiin eri näytteistä remanenssikomponentti, joka osoittaa pegmatiittisen graniitin uudelleenmagnetoituneen n. 1570 Ma sitten. Magnetoituman on tulkittu syntyneen alueen lähellä olevien rapakivien intrudoitumisen seurauksena. TGG gneisseissä ei esiinny stabiilia remanenttia magnetoitumaa lainkaan. Asiasanat: paleomagnetismi, remanentti magnetoituma, Olkiluoto, Suomi. 1 TABLE OF CONTENTS ABSTRACT TIIVISTELMÄ 1 INTRODUCTION ................................................................................................... 2 2 STUDIED ROCKS AND SAMPLING..................................................................... 3 3 METHODS ............................................................................................................ 6 4 RESULTS ......................................................................................... .................... 7 4.1 Diabase dykes.............................................................................................. 9 4.2 Pegmatitic granites .................................................................................... 11 4.3 TGG gneisses .......................................................................... ................. 12 5 DISCUSSION ................................................................................... .................. 14 6 POSITION OF THE FENNOSCANDIAN SHIELD ....................... ....................... 18 7 CONCLUSIONS .............................................................................. ................... 19 REFERENCES ....................................................................................................... ..... 20 ACKNOWLEDGEMENTS ............................................................................................ 23 APPENDICES 1-11 ...................................................................................................... 24 2 1 INTRODUCTION Paleomagnetic investigations have been carried out on diabase dykes, TGG gneisses and pegmatitic granites in the Olkiluoto area. The study forms a continuation for a preliminary investigation (Mertanen, 2007) where the suitability of rocks of Olkiluoto for paleomagnetic studies was first tested. The preliminary results from unoriented samples showed that especially the diabase dykes carry stable remanent magnetizations. Also the pegmatitic granites and some of the TGG gneisses had strong remanent magnetizations, whereas the studied potassium feldspar porphyries and sulphidized rocks from shear zones had no signs of stable ancient remanence. In this study the new paleomagnetic results from oriented samples are shown. In paleomagnetic studies the main studied property of rocks is the remanent magnetization that can be composed of different superimposed components formed in successive geological events. By applying multicomponent analysis, those components can be separated. The Olkiluoto area is located in an interesting surroundings where several possible sources can cause magnetic overprinting and formation of remanence components of different ages. The basement rock is composed of Svecofennian age (ca. 1.9-1.8 Ga) rocks, but the surrounding Subjotnian rapakivi granites (ca. 1.57 Ga), Jotnian sandstones (ca. 1.4-1.3 Ga) or Postjotnian diabases (ca. 1.27 Ga) could have affected the area thermally or hydrothermally. The main aim of the study was to find out if those events have left their fingerprints in remanent magnetizations. One of the most expected result of the study was to resolve whether the diabase dykes of the Olkiluoto area are of Svecofennian or Subjotnian age. U-Pb datings of the dykes have given Svecofennian ages of ca. 1.80 – 1.86 Ga (Mänttäri et. al., 2005, 2006). Since other petrological and field evidences suggested that the dykes could be of Subjotnian age, Mänttäri et al. (2005, 2006) proposed that the zircon could have been inherited. The remanence direction of Subjotnian age rocks differs distinctly from the Svecofennian rocks (e.g. Mertanen and Pesonen, 2005). Therefore, the paleomagnetic study can give new knowledge on the age of the diabase dykes in the Olkiluoto area. 3 2 STUDIED ROCKS AND SAMPLING Oriented samples for paleomagnetic studies were taken from two diabase dykes (DB, 7 samples and DS, 11 samples), from three sites of tonalitic-granodioritic-granitic gneiss, TGG (sites GA, GB and GC, 6 samples from each site) and from four sites of pegmatitic granite (sites PE, PG, PM and PA, 6-8 samples from each site) (Figure 1). All samples were taken with a portable mini drill, the length of the cores being ca. 5-10 cm. Orientation was done with magnetic compass included in the equipment designed in GTK. At least two, but typically three standard cylindrical specimens (diameter 2.4 cm and hight 2.1 cm) were prepared from each core. In the following, the sampled rock types are described briefly. More detailed descriptions of the rock types can be found in e.g. Mänttäri et al. (2005, 2006) and Paulamäki et al. (2006 and references therein). Diabase dyke DB is a narrow, ca. 6 cm at the widest and vanishes at its edges. It can be seen in about two meters length, and in the middle it shows a stepped structure (Fig. 2a). The strike of the dyke is 66° (dip direction 346°) and probably it is quite vertical, although the dip could not be observed properly at the outcrop. The dyke is black and very fine grained. The dyke was mapped for the first time in 2002 and mentioned in Paulamäki (2007). Seven samples were taken from the dyke, two of which contained partially the host rock. For a baked contact test, two samples were taken from the host migmatitic gneiss at a distance of 0.5 cm from the dyke, and two at a distance 50 cm from the dyke. Diabase dyke DS (Fig. 2b) is about 1.5 m wide, and has a strike of 60° and dip direction/dip of ca. 340°/70°. The outcrop was recently opened, and modelled in 3D as diabase dyke DB7 in the latest geological model of the Olkiluoto site (Mattila et al., in prep.). Mänttäri et al. (2005, 2006) have studied two diabase dykes in Olkiluoto area, one from Olkiluoto 3 construction site (Mänttäri et al., 2006) and one from investigation trench OL-TK3 (Mänttäri et al., 2005), the latter one being close to dyke DS. Those dykes are not included in this study. Dyke DS cuts the host mica gneiss sharply on its northern side, but on the southern side the contact is not so clear being mostly covered. Samples from the diabase were taken mainly from the finer-grained part in the southern side of the dyke, and partly from the central and northern side of the dyke. Most samples are fine-grained black rocks without any clear visible structures. Two samples looked clearly different in that they contained visible small light-coloured amygdales. The amygdales probably represent the same type as the quartz- and calcite- filled amygdales described by e.g. Paulamäki et al. (2006) and Mänttäri et al. (2005, 2006) in other diabase dykes in the Olkiluoto area. Altogether eleven samples were taken from the diabase dyke DS. For baked contact test, samples were taken from the host mica gneiss at distances of 0.2 m, 1 m, 5 m and 8 m from the dyke. Pegmatitic granite dyke PE cuts the TGG gneisses at site GA, and the pegmatitic granite PG transects the TGG gneisses of site GB. Both sites are located quite close to each other in the nortwestern part of the Olkiluoto area (Fig. 1). 4 Figure 1. Paleomagnetic sampling sites in Olkiluoto. Lithological map compiled by Paulamäki et al., 2006. Pegmatitic granite samples of site PE (Fig. 2C) were taken mainly from a reddish coarse grained dyke with a width of about 2.5 m. In the preliminary paleomagnetic study (Mertanen, 2007) two unoriented test samples (samples OL18) were studied from this site. The dyke is described by Mänttäri (2007) who has also done the isotope age determination of the dyke. One sample was taken from a white coloured branch of the dyke. The pegmatitic granite of site PG contains a network of dykes which are partly reddish or white in colour. Both types were sampled. At site PM (Fig. 2d) the pegmatitic granite forms also a migmatizing light-coloured network structure that intersects the mica gneisses. These pegmatitic granites were studied in the preliminary paleomagnetic study (samples OL83, Mertanen, 2007) and they are described by Mänttäri (2007) who has done isotopic datings also from this site. The fourth pegmatitic granite, PA, was sampled in the northern part of Olkiluoto (north of drillhole OL-KR5, Paulamäki et al., 2006) close to diabase dyke DS. Here the pegmatitic granite is reddish, very coarse grained, and it occurs together with mica gneiss. Samples were taken in area of about 7x12 m. TGG gneisses at sites GA and GB (Fig. 2e) are quite homogeneous and even-grained greyish rocks. In some places at site GB a foliation with a SE dipping direction of 4550° is clearly visible. At site GC (Fig. 2f) the TGG gneiss contains plenty of garnet in some places. The gneiss is more foliated and includes patches and veins of granite. 5 a) b) c) e) d) f) Figure 2. a) Diabase dyke DB, b) Diabase dyke DS, c) Pegmatite granite of site PE,with the orientation equipments d) Pegmatite granite of site PM, diameter of the drill hole is 2.5 cm. e) TGG of site GB, with drill core GB2, f) TGG of site GC. 6 3 METHODS Density and magnetic susceptibility were first measured from each specimen before paleomagnetic measurements (Table 1). Magnetic susceptibility gives the ability of rock to magnetize and reflects the amount of ferromagnetic minerals in the samples (measured as volume susceptibility). Natural remanent magnetization (NRM) was measured for each such specimen that was also demagnetized (see below). A primary NRM of magmatic rocks is the permanent thermoremanent magnetization (TRM) that is acquired when the rock cools below the Curie temperature of its remanence carrying ferromagnetic minerals. A secondary NRM can be formed subsequently in metamorphism when the rock can be totally remagnetized, or acquire a partial thermoremanent magnetization (pTRM) when the original remanence may have preserved. Hydrothermal activity can also produce a new magnetization in the rock. It is called chemical or thermochemical remanent magnetization (CRM/TCRM), if new magnetic minerals that carry the remanence, are formed in a hydrothermal process. Unlike magnetic susceptibility, NRM exists in the absence of external magnetic field. Koenigsberger ratio (Q-value) defines the ratio between remanent magnetization (remanence intensity, J, Table 1) and the induced magnetization (magnetic susceptibility, Table 1). It was determined for each specimen that was also demagnetized. For paleomagnetic studies most of the specimens were stepwise demagnetized with increasing alternating field (AF) in 12-15 steps up to a field of 100 or 160 mT. Some of the samples were thermally demagnetized by subjecting the samples in increasing stepwise temperatures with a maximum temperature of 620°C. The remanent magnetization was measured with cryogenic three-axes Squid (RF)-magnetometer between the different steps. By stepwise demagnetization it is possible to isolate different remanence components on the basis of different coercivities of the ferromagnetic mineral grains or on the basis of different unblocking temperatures of the grains. In general, the grain size and form of ferromagnetic minerals is important for the ability of a rock to preserve an ancient remanence. Small grains occur as single domain or pseudo single domain (SD/PSD) grains which can retain the remanence much better than the larger multi domain (MD) grains which tend to easily acquire an unwanted viscous remanence in time. Even if the magnetization of rock, both induced and remanent, would be very low, the rock can still have a measurable ancient remanent magnetization, if the remanence resides in SD grains. Separation of remanent components was done with principal component analysis (Kirschvink, 1980) by using Tubefind program (Leino, 1991). Fitting of lines (Zijderveld, 1967), with the minimum of three demagnetization points, was done automatically with the maximum angular deviation of the line being 6°. In addition, the specimens were treated manually, when components with angular deviations as high as 10° were also considered. Mean values of remanence components were calculated according to Fisher (1953). GMAP program (Torsvik and Smethurst, 1999) was used for presenting the paleomagnetic poles and for calculating the position of the continent. No thin section studies were carried out for the diabases or other rock types as the petrography of the similar rock types in Olkiluoto is already reported in Mänttäri et al. (2005, 2006) and Paulamäki et al. (2006 and references therein). 7 4 RESULTS Petrophysical properties of the studied samples are shown in Table 1 and Figure 3, and the paleomagnetic results in Table 2 and Figure 4. Examples of demagnetization behaviours are shown in Appendices 1-11. In the following, the results from different rock types are described. For diabases, also the results of baked contact tests are given. Table 1. Sampling sites and petrophysical properties. Site Rock type Coordinates N/n Density 3 x, y kg/m J (NRM) mA/m Susc. x 10 Q -6 DB Diabase 6790712, 1527488 6/11 2932 502.7 14405 0.9 DS Diabase 6792902, 1525345 9/24 2964 808.0 15513 1.3 6792902, 1525345 2/5 2942 110.5 2917 0.9 DS7+8 DB, baked Gneiss 6790712, 1527488 2/6 2719 2.5 254 0.2 DB, unbaked Gneiss 6790712, 1527488 2/7 2705 5.6 229 0.6 DS, baked Gneiss 6792902, 1525345 2/6 2740 110.4 329 7.2 DS, unbaked Gneiss 6792902, 1525345 2/6 2659 0.6 155 0.5 PE Pegmatite 6792822, 1523252 6/17 2597 1.4 26 3.0 PG Pegmatite 6792830, 1523084 5/14 2613 0.8 19 2.8 PM Pegmatite 6792591, 1525874 6/14 2625 1.2 71 0.4 PA Pegmatite 6792924, 1525263 6/15 2610 0.9 38 0.8 GA TGG 6792822, 1523252 6/16 2803 12.3 398 0.8 GB TGG 6792830, 1523084 6/15 2806 2.9 397 0.2 GC TGG 6793097, 1524618 6/14 2698 0.7 207 0.1 Note: N/n denotes the number of measured samples/ specimens, the mean values calculated from samples. Susc. is the magnetic susceptibility, Q denotes Koenigsberger ratio (Q-value). Sample DB10 of dyke DB was excluded from the mean petrophysical calculations, because it contains about half of the host rock. 8 Susceptibility x10-6 SI 25000 20000 15000 Diabase 10000 DB 5000 DS 0 0 200 400 600 800 1000 1200 1400 NRM (mA/m) Susceptibility x10-6 SI 120 100 80 Pegmatite 60 PE PG 40 PM 20 PA 0 0 1 2 3 4 5 NRM (mA/m) Suskeptibilty x10-6 SI 500 450 400 350 300 250 200 TGG 150 100 GA 50 0 GC GB 0 10 20 30 NRM (mA/m) Figure 3. Petrophysical properties of the studied samples. 40 50 9 4.1 Diabase dykes The magnetic susceptibilities of dykes DB (individual specimens 13 350 – 19 590 x 10-6 SI) and DS (10 619 – 21 866 x 10-6 SI) are comparable, but dyke DB has lower remanence intensities (425 – 815 mA/m) than the samples from dyke DS (425 – 1 647 mA/m). Also the Q-values are lower in dyke DB (0.7 – 1.0) compared to that of dyke DS (0.8 – 2.7) (Table 1 and Fig. 3). Due to higher remanence intensities, most specimens from dyke DS also gave stable paleomagnetic results while in dyke DB stable results were obtained only from one specimen of each core. The characteristic remanence direction (ChRM) of the diabases has a very shallow inclination that points towards north (Table 2, Fig. 4, Appendicies 1-4). The ChRM was named as DBp/DSp where p refers to a primary remanence, as will be discussed later. The component was isolated in AF fields of 30-100 mT, most typically in 30-70 mT. In higher AF fields, above 70-100 mT, the AF demagnetisation gave rise to false components (see Appendices 1 and 3), which are attributed to Gyroremanent magnetization (GRM) (Stephenson, 1980) formed in the demagnetization process. However, also in those samples carrying the GRM, the DBp/DSp component was obtained in lower fields. In thermally demagnetized samples the component was isolated in a quite narrow temperature range of 500-570°C which suggests that the remanence is carried by SD/PSD magnetite. In three samples of dyke DS and in two samples of dyke DB another component was isolated in higher AF fields and in lower temperatures than component DBp/DSp. It was named as component DBs/DSs where s denotes secondary origin for the component (Table 2, Fig. 4). It occurs only in a few samples, but as will be discussed later, it represents a remanent magnetization that has been obtained sporadically all over the Fennoscandian shield. In most specimens, a third component was typically isolated in the lowest AF fields and unblocking temperatures. This component has a steep NW pointing direction close to the Present Earth's Field (PEF) direction and it obviously represents a recent viscous remanence without any geological meaning. Appendix 4 gives an example of a case where all three components, PEF (0-20 mT), DBp/DSp (3070 mT) and DBs/DSs (70-100 mT) occur together. Samples DS7 and DS8 which contain visible amygdales show significantly lower magnetizations, both remanence and susceptibility, compared to other diabase samples (Table 1, Fig. 3). Also the Q-values are lower. Based on thermal demagnetization results (Appendix 5), their magnetic mineralogy differs from that of dyke DS. Above 500°C the remanence intensity increases and gets unstable. Also the susceptibility starts to increase hugely, suggesting that the rock contains pyrrhotite that alters to magnetite during heating. Although the remanence direction is comparable to the DBp/DSp of the other samples, the results of those two samples were not included in any mean values. 10 Table 2. NRM components of the diabases DB and DS and pegmatite PE. Site N/n AF Thermal (mT) (°C) DBp DSp DBs/DSs PE 7/7 30-100 7/17 20-100 5/7 60-100 5/6 - D (°) I (°) 400-570 4.6 -0.7 500-580 5.5 -0.1 0-560 42.0 41.5 0-520 27.9 -30.4 α95 (°) 13.9 6.4 12.2 23.9 k Plat Plong A95 (°) (°Ν) (°Ε) 19.8 28.4 196.2 90.6 28.6 195.2 40.2 43.3 144.7 11.1 8.8 175.2 K dp (°) 10.7 32.9 7.0 5.6 116.1 3.2 13.2 34.4 9.1 22.7 12.3 14.8 dm (°) 13.9 6.4 14.9 26.6 Note: N/n = number of samples/specimens, D = declination, I = inclination, AF = alternating field demagnetization, Thermal = thermal demagnetization, α95 = radius of the circle of 95% confidence, k = the Fisher's (1953) precision parameter, Plat, Plong = paleolatitude and paleolongitude of the Virtual Geomagnetic Pole (VGP), A95 = the radius of the circle of 95% confidence of the mean pole, K = the Fisher's (1953) precision parameter of the VGP, dp,dm = are the semi-axes of the oval of 95% confidence. Baked contact tests Baked contact tests are essential in defining the primary nature of the ChRM. In a baked contact test the remanence directions of the magma intrusion (dyke) and its baked and unbaked host rocks are compared. The baked zone of a dyke is defined as half of the width of the dyke. If the dyke and the baked host rock carry a similar remanence direction, but that is different from the unbaked host rock, it proves that the remanence of the dyke is primary, formed during the cooling of the rock. If both the diabase dyke and the baked and unbaked host rock carry a similar remanence direction, then the remanence of the dyke is secondary, acquired in a later metamorphic or hydrothermal event. Unfortunately, baked contact tests were not succesfull for the studied diabase dykes. Thermal demagnetizations of the baked and unbaked host gneisses showed pyrrhotite as the main magnetic mineral. However, the remanence directions of the rocks are very scattered even between the specimens of a single core. Thus, no conclusive results were obtained. Petrophysical properties can also give information about the primary/secondary nature of the remanence of the dykes. One purpose of the measurements is to see the physical effects of the dyke to the host rock at various distances from the dyke. It is supposed that if the remanence intensity and susceptibility are clearly increased at the baked contact zone of the host rock, closest to the dyke, it may give support that the dykes carry a primary remanent magnetization. If the whole area has been in increased temperatures, it is possible that the petrophysical values are smoothened and no clear difference is seen between the baked and unbaked host rock. 11 DSP PE PEF DBS/DSS Figure 4. Sample mean remanence directions DBP (circles) and DSP (squares) denoting the possible primary remanence of the diabase dykes, DBS/DSS (hexagons) the secondary remanence of the diabase dykes and PE (triangels) the remanence component of pegmatite granite PE. The cones of 95% confidence are shown. PEF indicates the Present Earth's Field magnetization direction of the sampling area. Closed symbols denote positive inclination and open symbols negative inclination. At the baked contact zone of dyke DB there is no significant change in magnetic properties between the baked and unbaked host rock (Table 1). At dyke DS the magnetic susceptibility values of the baked and unbaked samples do not differ significantly, although the values are slightly higher in the baked rocks (Table 1). The main difference is seen in the remanence intensity values and Q-values which are clearly higher in the baked rocks than in the unbaked rocks. This gives the signature that the dykes have baked the host rocks and both the dyke and the baked host rock have acquired their remanent magnetization simultaneously during cooling of the rocks. The lower values of the unbaked host rock would indicate that they are unaffected by the dykes and carry their original magnetizations. 4.2 Pegmatitic granites Magnetizations of the pegmatitic granites are very weak. The magnetic susceptibilites of distinct specimens are within range 0-340 x 10-6 SI, remanence intensities 0.1-12.8 mA/m and Q- values between 0.03 and 12.2. Mean values of samples are shown in Table 1 and Figure 2. 12 Pegmatitic granite from site PE shows stable paleomagnetic results in part of the samples although the remanence intensities are weak. One remanence component was isolated. The component has a NE pointing moderate negative inclination (see Appendix 6). Although the remanence directions between samples are scattered, the mean direction (Fig. 4) has a clearly higher negative inclination than the diabases. The component occurs typically only in one thermally demagnetized specimen of each core as thermal demagnetization proved to be the more effective method than AF demagnetization in isolating the remanence component. In some specimens AF demagnetization showed high coercivities which suggests the existence of pyrrhotite. In three of the samples the NE pointing component was isolated in a temperature range of about 200-400°C, also suggesting pyrrhotite as the remanence carrier. However, in two samples the remanence was unblocked below 500-520°C (Appendix 7) implying that the remanence resides in titanomagnetite. Since the remanence seems to reside in both pyrrhotite and titanomagnetite, the mechanism of magnetization is not clear. It has probably chemical or thermochemical secondary origin. The remanence direction is clearly different from the known direction of Svecofennian age rocks (Pesonen et al., 2003) which supports its secondary origin. It is implied that the pegmatite is totally remagnetized, or that at least those samples with stable remanences are remagnetized although the unstable samples may have been already originally weak and have not retained any primary remanence at all. The pegmatitic granites of sites PG, PM and PA are very weakly magnetized. No stable results were obtained due to scatter of data in successive demagnetization steps. However, although principal component analyses could not isolate any stable component, many specimens do show a negative NE pointing remanence direction corresponding to that of the DBp/DSp component or the characteristic component of the PE pegmatite (Appendix 8). The remanence unblocks at 300-400°C, again suggesting pyrrhotite as the main magnetic mineral (Appendix 9). 4.3 TGG-gneisses Samples from TGG gneisses were taken from three sites (Fig. 1). Preliminary studies of the TGG gneisses (Mertanen, 2007) already showed that this rock type did not give stable paleomagnetic results. However, new studies were carried out because the remanence intensities and Koenigsberger Q values were high, which in general suggest prevalence of an ancient remanence. With new sampling it wanted to be tested whether the TGG could still carry stable remanent magnetizations. New TGG gneiss samples are from different locations than the test samples. Unlike the test samples, the new samples have low remanence intensities and Q values in most cases (Table 1, Fig. 2). The Q-values are typically below 0.5 and the remanence intensities below 10 mA/m, usually around or below 1 mA/m. As expected, they do not carry stable consistent remanent magnetizations. This is seen as scattered remanence directions of different samples. Thermal demagnetizations show that most of the studied rocks loose their magnetization below 400°C which implies that the ferromagnetic mineral is pyrrhotite. In few samples there seems to be also magnetite (Appendix 10). In two samples from site GA (samples GA2 and GA6, Table 1, Figure 3) the remanence intensity values and Q- ratios are higher compared to other samples. In these samples an 13 equivalent remanence component was isolated in low AF fields of 0-30 mT and temperatures of 0-350°C. The remanence has a very steep negative inclination which is reversed to the Present Earth's Field magnetization direction. The direction is not known from previous paleomagnetic studies. The latest reversal of the Earth's magnetic field took place about 750 000 – 780 000 years ago (Butler, 1980) so that it cannot be connected to any Holocene time event, like glaciation that might have affected the remanent magnetization. In this study the origin of the steep negative inclination component remains unresolved. It must be related to some unknown secondary mechanism, even to a drilling induced magnetization at worst. 14 5 DISCUSSION Two remanence components, DBp/DSp and DBs/DSs were obtained from the diabase dykes DB and DS, and one remanence component from the pegmatitic granite PE. The other studied formations did not give stable results, except some hints of a NE pointing remanence direction. In order to define the ages of the magnetizations, virtual geomagnetic poles (VGP's) were calculated from the remanence directions. The ages are obtained by comparing the VGP's with known Fennoscandian paleomagnetic 'key' poles that are statistically well defined and have precisely dated isotopic ages (Buchan et al., 2000). The VGP's are shown in Table 2 and Figure 5. Poles DBp and DSp plot close to the 1560 Ma key pole obtained from the Föglö (Neuvonen and Grundström, 1969) and Föglö-Sottunga diabase dykes (Pesonen and Neuvonen, 1981, Pesonen et al., 1987) in Åland archipelago. The dykes have U-Pb ages (zircon and baddeleyite) of 1577±12 Ma and 1540±12 Ma (Suominen, 1991). The DBp and DSp poles differ clearly from the Svecofennian 1880 Ma and 1840 Ma key poles and therefore they cannot be of Svecofennian age, unless the dykes were totally remagnetized at ca. 1560 Ma (see below). Another source for a remagnetization in the Olkiluoto area could be the emplacement of Postjotnian 1270 Ma (Suominen, 1991) Satakunta olivine diabases. However, the DBP and DSP poles differ also clearly from the 1270 Ma key pole (Buchan et al., 2000, Pesonen et al., 2003). Therefore, since no remanence direction corresponding to the remanence of the Postjotnian magmatism was obtained in the dykes, the dykes have not been either partially or totally remagnetized due to the Satakunta diabase. Figure 5 shows also the 1630 Ma key pole obtained from quartz porphyry dykes in southern Finland (Neuvonen, 1963, Mertanen and Pesonen, 1995). The DBP and DSP poles are also different to that pole, so that the dykes cannot be of the age of 1630 Ma. One more key paleomagnetic pole with an age of 1570 is also obtained from Åland, from the Kumlinge-Brändö diabase and quartz porphyry dykes (Pesonen and Neuvonen, 1981) the latter with U-Pb (zircon) ages between 1571±9 Ma and 1576±13 Ma (Suominen, 1991). Thus, the ages of the Åland diabase and quartz porphyry dykes are equivalent within dating limits and therefore, the age difference between the 1560 Ma and 1570 Ma key poles is not strictly defined. However, based on paleomagnetic studies, the Föglö dykes have normal polarity and the Kumlinge dykes reversed or mixed polarity, and the cross cutting relationships suggest that the normal polarity dykes are slightly younger than the reversed polarity dykes (Bylund and Pesonen, 1987). Based on the similarity of poles DBP and DSP with the poles from the FöglöSottunga dykes and with the occurrence of normal polarity, it is suggested that the dykes of the Olkiluoto area are of the age of ca. 1560 Ma. It is implied that the remanent magnetization is of primary origin and the dykes represent Subjotnian magmatism. Baked contact tests could not properly confirm the primary or secondary origin for the magnetization as the host rocks at the diabase dykes did not give stable remanence directions. However, as discussed before, the remanence intensities have increased at the baked contact zone of dyke DS which is so wide that it have had a more thorough effect on the host rock compared to the very thin dyke DB. Based on this evidence it is suggested that the remanent magnetization of the diabase dykes is primary. 15 a) 1840 DBS /DSS 1630 1560 DS P 1880 DBP PE 30 N 1570 1270 Equator 180 240 b) 580 600 60 560 500 30 700 480 470 Equator DBS /DSS 210 750 440 380 -30 460 410 425 320 280 770 250 -60 240 270 300 330 0 30 60 90 120 150 Figure 5. a) Precambrian key poles of the Fennoscandian Shield (Buchan et al., 2000) are shown as squares with dashed A95 confidence cones and ages (Ma). The shaded A95 confidence cones are shown for the mean VGP poles of components DBP and DSP (regarded as primary), DBS/DSS (regarded as secondary) of the diabase dykes and for the component obtained from pegmatite granite PE. b) Paleozoic APW path of the Fennoscandian shield (Torsvik et al., 1996) where the pole DBS/DSS is reversed. 16 Petrographic and mineralogical evidences (e.g. Mänttäri et al., 2005, Paulamäki et al., 2006 and references therein) show that the diabase dykes are highly altered, the original minerals having been replaced by hydrothermal minerals (e.g. epidote, calcite, sericite). Strong alteration of the dykes could support a secondary origin for the magnetization which would then have been formed in a later low temperature hyrothermal event, an event that has affected the whole Olkiluoto area (Paulamäki et al., 2006). The remanence would thus represent a total remagnetization and could be of thermal, chemical or thermochemical remanence type. However, the magnetization is carried by SD/PSD magnetite which is the typical primary Fe-oxide mineral of diabase dykes. Therefore, although hydrothemally altered, the primary magnetite seems to have preserved. Hydrothermal alteration of the dykes may have also taken place in the late stages of crystallization of the dykes, simultaneously with fluid activity from the nearby rapakivi granites. Field evidences also support the primary Subjotnian origin for the dykes. In Olkiluoto area the studied dykes strike ca. N60°E, although more E-W striking also occur (e.g. Paulamäki et al., 2006 and references therein). In Föglö the strike is more NE, striking ca. N20-40E° (Suominen, 1987). In the Rauma and Uusikaupunki map sheet explanations Suominen et al. (1997, 2006, respectively) have described several mainly NE-SW (Uusikaupunki) or E-W (Rauma) striking thin diabase dykes. The dykes in Rauma area also contain amygdales of carbonate and quartz, as described also in the Olkiluoto diabase dykes (Mänttäri et al., 2005, Paulamäki et al., 2006,). Suominen et al. (2006) correlate the hornblende diabase dykes in Uusikaupunki area with the Subjotnian diabase dykes in the Åland archipelago. Further north from the Olkiluoto and Rauma map sheet area, in the Pori region, Pihlaja (1987) has described diabase dykes with a similar strike of ca. N60°E as in Olkiluoto area. Those dykes have corresponding narrow width (0.1-3 m) as in Olkiluoto, they are slightly altered and also contain quartz and carbonate filled amygdales. Ehlers and Ehlers (1977) have described corresponding amygdales also in the diabases of Åland archipelago. To sum up, based on geological evidences from the western coast of SW Finland, from the Åland archipelago through Rauma up to Pori region, there exists several NE/NNESW/SSW trending diabase dyke swarms. Although not isotopically dated, on the basis of their petrology, crosscutting relationships and mode of occurrence, they all belong to the Subjotnian magmatism that is related to the rapakivi granites. Paleomagnetic results alone from the Olkiluoto area cannot define the extent of ca. 1560 Ma Subjotnian dykes in other areas, but anyway based on field evidences reported before (Pihlaja, 1987, Suominen et al., 1997, 2006, Mänttäri et al., 2005, 2006, Paulamäki et al., 2006 and references teherin), it is probable that there exists ca. 1560 Ma old NE/NNE-SW/SSW rapakivi granite related dykes or dyke swarms along the rapakivi granite hosted southwestern coast of Finland. Virtual geomagnetic pole calculated from the remanence direction of pegmatitic granite PE is close to the pole with an age of 1570 Ma (Pesonen and Neuvonen, 1981), although the polarity of the pegmatite is normal (Fig. 5). The main differerence in 1560 Ma and 1570 Ma remanence directions was the higher inclination of the 1570 Ma component. The data of PE are scattered, obtained only in five samples. Furthermore, the A95 confidence cone of the pole intersects with the 1630 Ma and 1560 Ma confidence cones. Therefore, any interpretations about the age of pole PE are quite uncertain. However, it is suggested that the pegmatitic granites may record a reheating 17 of the Laitila rapakivi batholith and the satellite Eurajoki rapakivi granite stock with UPb ages of 1573±5 - 1548±3 Ma (Vaasjoki, 1977, Vaasjoki and Rämö, in Suominen, et al., 2006). The diabases did not yield this steeper inclination remanence component which implies that the remanence component in pegmatitic granites is older than the remanence in the diabases. This also supports the primary origin for the remanence in the diabases. If the remanence of the diabases were formed in the same hydrothermal/ thermal event as the one affecting the pegmatitic granites, the dykes would have acquired the same remanence. The secondary pole DBS/DSS (Fig. 5) of the diabases was obtained only in five samples and therefore its importance is doubtful. Anyway, it represents a remanent magnetization that has been sporadically obtained all over in the Fennoscandian shield (e.g. Mertanen et al., 2004). When plotted among Precambrian key poles, it doesn't correspond to any known poles (Fig. 5a). However, when the polarity is reversed and the pole is plotted along the Paleozoic Apparent Polar Wander Path (APWP) of the Fennoscandian shield (Torsvik et al., 1996), it gives an age of about 250 Ma. The age corresponds to a Permian time that was geologically manifested by the occurrence of supercontinent Pangea. It is possible that the magnetization was formed in the regional events related to the formation of the supercontinent. However, based on these few data, no further interpretations are attempted. 18 6 POSITION OF THE FENNOSCANDIAN SHIELD Figure 6 shows the latitudinal position and orientation of the Fennoscandian shield at 1560 Ma, based on the mean pole position (Plat=28.5°N, Plong=195.7°E) obtained from the diabase dykes DB and DS. The position is in agreement with previous studies (Mertanen and Pesonen, 2005, Pesonen et al., 2003). For comparison, the figure also shows the positions of the Fennoscandian shield at 1830 Ma (Neuvonen et al., 1981), 1570 Ma (Pesonen and Neuvonen, 1981) and 1270 Ma (Neuvonen, 1965, 1966, Neuvonen and Grundström, 1969). During the emplacement of the 1570-1560 Ma rapakivi granites and associated dykes, there was some latitudinal movement and rotation of the shield. At 1560 Ma the Fennoscandian shield was located at the equator. This could be considered in the interpretations of the alteration processes observed in the Olkiluoto area (e.g. Paulamäki et al., 2006). Likewise, when taking into account the occurrence of amygdales in the diabase dykes, which may indicate their emplacement at shallow depths (Suominen et al., 1997) or even onto the surface (Ehlers and Ehlers, 1977), the equatorial position of the shield may be partly responsible for the high alteration seen in the dykes. Mänttäri et al. (2005) have described occurrence of hematite in one of the Olkiluoto diabase dyke, which could possibly be related to weathering at the equator. 30 N 1830 1560 Equator 1270 1570 30 S This study Figure 6. Drift history of the Fennoscandian shield at certain times (see Mertanen and Pesonen, 2005, Pesonen et al., 2003.) 19 7 CONCLUSIONS The two studied diabase dykes in the Olkiluoto area yield a consistent remanent magnetization component that is suggested to be primary. Based on similarity of the pole positions with the known Fnnoscandian paleomagnetic poles, the age of the diabase dykes is ca. 1560 Ma. In addition to the primary component the diabases carry another, secondary remanence component that may be related to the formation of supercontinent Pangea during Permian time at ca. 250 Ma. Pegmatitic granite at one site shows a remanence direction that based on its pole position is ca. 1570 Ma, and may have been acquired due to hydrorthermal events related to the intrusion of the nearby rapakivi granites. The other studied pegmatitic granites also gave some hints of a corresponding remanence, but they could not be properly isolated. No remanence component that would point to a reactivation of the Olkiluoto area due to Postjotnian magmatism at ca. 1270 Ma was observed. The studied TGG gneisses did not give any stable paleomagnetic results. Based on thermal demagnetizations the remanence carrying magnetic mineral of the diabases is magnetite. In the two samples from dyke DS that show high concentrations of amygdales, the main Fe-oxide mineral is probably pyrrhotite. In pegmatitic granites both magnetite and pyrrhotite occur. It is suggested that magnetite can be the original primary mineral in the pegmatitic granites, but the occurrence of pyrrhotite is related to the hydrothermal alteration when the pegmatitic granites were remagnetized. Also in TGG gneisses the main magnetic mineral is pyrrhotite. The amount of samples that gave reliable paleomagnetic results was statististically very limited. Therefore, in order to confirm the now obtained results and to assess whether the whole Olkiluoto area was partially remagnetized due to the rapakivi granites, more data are required. 20 REFERENCES Buchan, K.L., Mertanen, S., Park, R.G., Pesonen, L.J., Elming, S.-A., Abrahamsen, N. & Bylund, G. 2000. The drift of Laurentia and Baltica in the Proterozoic: a comparison based on key paleomagnetic poles. Tectonophysics 319: 167-198. Butler, R.F., 1980. Paleomagnetism. Blackwell Scientific Publications, 319 pp. Bylund, G. and Pesonen, L.J., 1987. 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Mertanen, S. and Pesonen, L.J., 1995. Palaeomagnetic and rock magnetic investigations of the Sipoo Subjotnian quartz porphyry and diabase dykes, southern Fennoscandia. Physics of the Earth and Planetary Interiors 88, 145-175. Mertanen, S., Pajunen, M. and Elminen, T., 2004. Multiple remagnetization events of shear zones in southern Finland. In: S. Mertanen (ed.), Supercontinents, remagnetization and geomagnetic modelling. 5th Nordic Paleomagnetic Workshop, Suitia-Helsinki, Finland, September 25-30, 2004. Report Q29.1/2004/1, Espoo 2004, 39-44. Mertanen, S. and Pesonen, L.J., 2005. Drift history of the shield. In: M. Lehtinen, P. Nurmi and O.T. Rämö (eds.), Precambrian Geology of Finland - Key to the Evolution of the Fennoscandian Shield. Elsevier Science B.V., 645-668. Mänttäri, I., Paulamäki, S. and Suominen, V., 2005. U-Pb age constraints for the diabase dyke from investigation trench OL-TK3 at the Olkiluoto study site, Eurajoki, SW Finland. Posiva. Working report 2004-67. 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Elsevier, New York, 254-286. 23 ACKNOWLEDGEMENTS Ismo Aaltonen and Jussi Mattila pointed the sampling sites, Fredrik Karell drilled the samples and helped with the orientations in the field. Matti Kauranne made the sample preparations, Tuula Laine carried out the paleomagnetic measurements and Matti Leino took care of the equipments and software. Seppo Paulamäki provided the lithological map of the Olkiluoto area and made improving comments on the manuscript. All these people are greatly acknowledged. 24 APPENDICES 1-11 a) Stereoplot shows the movement of NRM vectors during progressive demagnetization. Declination (0-360°) is read from the stereoplot circle and inclination (0-90°) from the axis of the stereoplot. Closed circle indicates that the inclination is pointing downwards (positive inclination), open circle that the inclination is pointing upwards (negative inclination). b) Intensity decay curve of AF demagnetization (e.g. Appendix 1) shows the decline of relative remanence intensity when the specimen is subjected to stepwisely increasing AF fields. The AF fields (H) are in oerstedts (Oe). Intensity decay curve of thermal demagnetization (e.g. Appendix 2) shows the decline of remanence intensity when the specimen is gradually heated in higher temperatures. Temperatures are in °C. c) Zijderveld plot shows the vector end points after demagnetization steps, projected on two perpendicular planes. Horizontal projection on the left, and vertical projection on the right. In AF demagnetized specimens the large numbers refer to AF fields (in milliteslas, 1 mT = 10 Oe), in thermally demagnetized specimens to temperatures (°C). The small numbers show the order of used steps. 25 26 27 28 29 30 31 32 33 34 35
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