Date of Issue: 03/2015
Page 1 of 2
Vinylmagnesium Chloride, typ. 16.5 % solution in
THF (typ. 1.9 M)
PRODUCT
Vinylmagnesium Chloride, typ. 16.5 % solution in THF (typ. 1.9 M)
Product No. 408464
CAS-No. 3536-96-7
EINECS-No. 222-575-9
FURTHER
INGREDIENTS
THF
CAS-No. 109-99-9 EINECS-No. 203-726-8
APPLICATION
Grignard-reactions: reagent for the introduction of the vinyl group.
APPEARANCE
Yellowish to dark brown liquid
FORMULA
C 2 H 3 ClMg
PHYSICAL
PROPERTIES
Molecular weight:
86.80 g/mol
Density:
0.98 g/ccm (at 20°C)
Boiling Point:
66 °C for THF
Flash Point:
-21.5 °C for THF
Thermal Stability:
Crystallization below around 5 °C
SPECIFICATION
Vinylmagnesium Chloride: 15.5 – 17.5 %
METHOD OF
ANALYSIS
Acidimetric titration of the hydrolized product for the determination of assay as total base.
Detailed description available on request.
HANDLING
Vinylmagnesium Chloride should only be handled under inert gas atmosphere. Avoid contact
with eyes, skin and clothes as well as inhalation. Never add water, acids or oxidizing
materials. In case of fire use dry extinguishers based on sodium chloride or limestone
powder, never use water or CO2 . Pay attention to the Safety Data Sheet.
STORAGE
Vinylmagnesium Chloride should be stored in tightly closed containers under exclusion of air
and humidity. As material tends to crystallize at lower temperatures, it should be stored
above 15 °C. Storage temperatures above 25 °C should be avoided due to slow irreversible
oligomerization of the product.
The abov e details hav e been compiled to the best of our knowledge
on the basis of thorough tests and with regard to the current state
of our long practical experience. No liabilities or guarantees deriv ing
f rom or in connection with this leaf let can be imputed to us.
Reproduction, in whole or in part, only with our express permission.
® registrated trademark
www.rockwoodlithium.com
Europe:
Rockwood Lithium GmbH
Fax: +49 69 40126-72000
Americas:
Rockwood Lithium Inc.
Fax: +1 704 734-2718
Asia:
Rockwood Lithium Japan K.K.
Fax: +81-3-6434-5623
Product No. 408464
Date of Issue: 03/2015
Page 2 of 2
Recommended retest date: three months after date of delivery.
TRANSPORT
REGULATIONS
UN-No.:
3399
Rail/Road (RID/ADR):
Class 4.3, I
Label 4.3 and 3
Sea (IMDG-Code):
Class 4.3, I
Label 4.3 and 3
Air (IATA-DGR):
Class 4.3, I
CAO 494
GHS HAZARD
PICTOGRAMS
H&P Phrases: See Safety Data Sheet
SIGNAL WORD
Danger
PACKING
Glass bottles of 100, 250, 500 and 1,000 ml. Steel bottles with volumes of 7.4, 27, 127 or 450
l. For safety reasons these are filled to a maximum of 90 %. Steel drums up to 200 l.
TIME OF DELIVERY
To be agreed upon.
FURTHER RELATED
DOCUMENTS
Brochure ''Organomagnesium Compounds''
Trifold 'C-C Coupling Reactions in Organic Synthesis'
Safety Data Sheet.
The abov e details hav e been compiled to the best of our knowledge
on the basis of thorough tests and with regard to the current state
of our long practical experience. No liabilities or guarantees deriv ing
f rom or in connection with this leaf let can be imputed to us.
Reproduction, in whole or in part, only with our express permission.
® registrated trademark
www.rockwoodlithium.com
Europe:
Rockwood Lithium GmbH
Fax: +49 69 40126-72000
Americas:
Rockwood Lithium Inc.
Fax: +1 704 734-2718
Asia:
Rockwood Lithium Japan K.K.
Fax: +81-3-6434-5623