Quaternary Science Reviews 21 (2002) 1593–1609 Limited global change due to the largest known Quaternary eruption, Toba E74 kyr BP? Clive Oppenheimer* Department of Geography, Cambridge University, Downing Place, Cambridge CB2 3EN, UK Received 21 September 2001; accepted 2 December 2001 Abstract The E74 kyr BP ‘‘super-eruption’’ of Toba volcano in Sumatra is the largest known Quaternary eruption. On the basis of preserved deposits, the eruption magnitude has been estimated at E7 1015 kg (E2800 km3 of dense magma). The largest sulphate anomaly in the Greenland Ice Sheet Project 2 core has been identified as fallout from Toba’s stratospheric aerosol veil. Correlation of the sulphate and oxygen isotope stratigraphy of the ice core suggests that the Toba eruption might have played a role in triggering a millennium of cool climate prior to Dansgaard-Oeschger event 19, although a comparable stadial preceded event 20. A possible 6 yr duration ‘‘volcanic winter’’ immediately following the eruption has also been proposed as the cause of a putative bottleneck in human population supporting, in a general way, the ‘‘Garden of Eden’’ model for the origin of modern humans. However, along with counter arguments regarding the timing of any demographic crash, there remain major gaps in our understanding of the E74 kyr BP Toba eruption that hinder attempts to model its global atmospheric and climatic, and hence human consequences. The tephra record reveals basic aspects of the eruption style but calculations of the duration, and hence intensity and plume height of the event, are poorly constrained. Furthermore, estimates of the sulphur yield of the erupting magma, central to predictions of its atmospheric and climatic impacts, vary by two orders of magnitude (3.5–330 1010 kg). Previous estimates of globally averaged surface cooling of 3–51C after the eruption are probably too high; a figure closer to 11C appears more realistic. The volcanological uncertainties need to be appreciated before accepting arguments for catastrophic consequences of the Toba super-eruption. r 2002 Published by Elsevier Science Ltd. 1. Introduction The Late Pleistocene eruption of the Younger Toba Tuff (YTT) may have been the greatest single volcanic cataclysm in the Quaternary. It expelled an estimated 7 1015 kg (or 2800 km3 dense rock equivalent, DRE, at 2500 kg m3) of rhyolitic magma and made a sizeable contribution to the 100 30 km caldera complex occupied today by Lake Toba in northern Sumatra (Fig. 1; Rose and Chesner, 1987, 1990; Chesner and Rose, 1991). The size of the eruption (3500 times greater than the largest historic eruption, the 1815 outburst of Tambora volcano, Indonesia) and its approximate coincidence with global environmental and climatic change at the end of Oxygen Isotope Stage (OIS) 5a led to speculation that it accelerated the transition into the last Ice Age (Rampino and Self, 1992, 1993a). It has also been suggested that global cooling, triggered by the *Tel.: +44-1223-719-712; fax: +44-1223-333-392. E-mail address: [email protected] (C. Oppenheimer). 0277-3791/02/$ - see front matter r 2002 Published by Elsevier Science Ltd. PII: S 0 2 7 7 - 3 7 9 1 ( 0 1 ) 0 0 1 5 4 - 8 YTT eruption, precipitated an environmental catastrophe that resulted in near extinction of contemporaneous human populations (Gibbons, 1993; Rampino and Self, 1993b; Ambrose, 1998; Rampino and Ambrose, 2000; and cited in Harpending and Rogers, 2000; Hewitt, 2000). In view of the significance of these palaeodemographic implications, and a range of recently available tephrostratigraphic, ice core and petrologic evidence that bears on the possible consequences of the eruption, it is timely to re-evaluate critically the basis for the claims made for Toba. The aim of this paper is also to stimulate broad, interdisciplinary research across the Quaternary science community that will advance our understanding of the global effects of very large eruptions. 2. Age of the YTT The YTT was not the first large eruption from Toba. It was preceded by the Haranggoal dacite (1.2 Myr BP), 1594 C. Oppenheimer / Quaternary Science Reviews 21 (2002) 1593–1609 Fig. 1. The 100 30 km2 Toba caldera is situated in north-central Sumatra around 200 km north of the equator. It is comprised of four overlapping calderas aligned with the Sumatran volcanic chain. Repeated volcanic cataclysms culminated in the stupendous expulsion of the Younger Toba Tuff around 74 kyr ago. The lake area is E1100 km2. Samosir Island formed as a result of subsequent uplift above the evacuated magma reservoir. Such ‘‘resurgent domes’’ are typically seen as the concluding phase of a large eruption. Landsat Enhanced Thematic Mapper Plus (ETM+) ‘‘browse images’’ for path/row 128/58 (6 September 1999) and 129/58 (21 January 2001) from http://landsat7.usgs.gov/. Copyright USGS. the Oldest Toba Tuff (840 kyr BP) and Middle Toba Tuff (501 kyr BP) (Chesner and Rose, 1991; Chesner et al., 1991). Dates obtained for the YTT have tended to be remarkably consistent given the very different techniques that have been used to obtain them (Table 1). The best current estimate for its age is 7472 kyr. There was some controversy surrounding a more recent explosive eruption of Toba, at around 30 kyr BP. This had been suggested by fission-track measurements of a zircon crystal isolated from a 90 cm thick ash deposit at Selangor in Malaysia, 350 km from Toba, and apparently corroborated by 14C dates on wood fragments extracted from sediments directly beneath this ash. However, the lack of potential horizons on Sumatra, or in deep-sea cores, that correlate with this age, and the chemical similarity of the YTT and Selangor tephra, led Chesner et al. (1991) to doubt the interpretation. Their own subsequent fission-track analysis on a sample of the Malaysian ash yielded an age of 6877 kyr, within analytical error of other dates on known YTT material. 3. Deposits of the YTT eruption The eruption is thought to have ensued as the roof of a large magma chamber, located up to 10 km deep in the crust, began to founder (Chesner, 1998; although Beddoe-Stephens et al., 1983, estimated a shallower depth for the magma body of around 3–4 km; recent seismic tomographic investigations have suggested the presence of two principal melt regions between the lake and a depth of 10 km, Masturyono et al., 2001). This opened up ring fractures, which fed massive outpourings of pyroclastic flows. If this interpretation is correct, it implies that the caldera formed in a piecemeal fashion (e.g., Moore and Kokelaar, 1998) during the eruption, and not catastrophically, afterwards. Supporting evidence is provided by the generally symmetrical distribution of YTT around the present day lake, and the absence of plinian tephra fall deposits from an eruption above a central vent. This latter feature of the YTT is unlike most studied examples of large caldera-forming eruptions, which begin with a plinian phase. There is C. Oppenheimer / Quaternary Science Reviews 21 (2002) 1593–1609 1595 Table 1 Published age determinations for the YTT Location Material Age (kyr BP) Technique Reference Malaysia Greenland South China Sea Arabian Sea Samosir island Prapat Indian Ocean Sigurapura Prapat Ash (glass shards) Sulphate Foraminifera Foraminifera Ignimbrite (sanidine) Pumice (sanidine) Foraminifera Ignimbrite (biotite) Quartz crystals 6877 7175a 71 72.4–74.675 7374 7473 75 75712 81717 Fission-track Ice core stratigraphy 18 O/16O stratigraphy 18 O/16O stratigraphy Ar–Ar K–Ar 18 O/16O stratigraphy K–Ar ESR Chesner et al. (1991) Zielinski et al. (1996) Huang et al. (2001) Schulz et al. (1998) Chesner et al. (1991) Ninkovitch et al. (1978b) Ninkovitch (1979) Ninkovitch et al. (1978b) Wild et al. (1999) a 70 kyr using the official GISP2 timescale, 68 kyr using the refined Meese et al. (1997) timescale (see Fig. 4 caption). some room for doubt with this conclusion, however. Although no pumice fallout has been found preserved beneath the base of the massive outflow sheets of ignimbrite, which cover >20,000 km2 of northern Sumatra, it is conceivable that the great erosive power of the pyroclastic flows could have scoured away any deposits from an initial plinian phase. There is no shortage of tephra fall deposit from the Toba eruption, however (Fig. 2). The pyroclastic flows generated immense co-ignimbrite (‘‘phoenix’’) clouds of fine ash and entrained (and heated) air, as the denser pyroclasts settled out. These must have risen from multiple sources across a wide area around the subsiding caldera. They are crucial for understanding the potential global atmospheric and climatic impacts of the eruption, since they would have been capable of carrying large quantities of sulphur and other volatiles into the stratosphere. The YTT ignimbrites form a well-developed outward sloping (1–41) plateau (Knight et al., 1986). Much of the Fig. 2. Distribution of recovered YTT phoenix cloud ash-fall deposits. Recent studies have fingerprinted deep-sea tephra layers south of India and in the South China Sea. Data from Ninkovitch et al. (1978a, b), Acharyya and Basu (1993), Pattan et al. (1999), Buhring . et al. (2000), Gasparotto et al. (2000), and Song et al. (2000). 1596 C. Oppenheimer / Quaternary Science Reviews 21 (2002) 1593–1609 YTT is un-welded and contains pumice blocks up to 80 cm in size. Up to 400 m thickness of YTT is exposed in the caldera walls enclosing Lake Toba. A posteruption resurgent dome occupies the central part of the caldera—the western part of the dome is the island of Samosir (Fig. 1). Knight et al. (1986) believed Samosir island to be composed of Middle Toba Tuff, challenging the YTT magnitude estimate made by Rose and Chesner (1987). Chesner et al. (1991) dated tuff from the island at 7374 kyr BP, confirming it as part of the YTT and supporting the original volume calculation, which was partly based on the thickness of tuffs on Samosir. Taking the average thickness of intracaldera deposits to be 400 m indicated a mass of 2.5 1015 kg (1000 km3, dense-rock-equivalent, DRE) of tephra within the caldera alone. The co-ignimbrite clouds drifted above both the Indian Ocean and South China Sea depositing 10 cm or more thickness of ash on at least 1% of the surface area of the planet. Toba ash has been identified in many deep-sea sediment cores (Fig. 3) and on the Indian subcontinent, up to 3100 km from the vent, providing a valuable time marker for palaeontological and palaeoanthropological studies. The minimum mass of this tephra fall deposit was estimated as 2 1015 kg (a DRE volume of 800 km3; Rose and Chesner, 1987). To estimate the volume of the YTT itself, Rose and Chesner (1987) assumed a mean thickness of 50 m outside the caldera covering an area of >20,000 km2 (>2.5 1015 kg or 1000 km3 DRE) and added this to the intracaldera fill. The total minimum mass of the entire deposit comes to 7 1015 kg, at least 30% of which is in the co-ignimbrite cloud fallout. Once more people began looking for it, the YTT turned up further afield (Fig. 2). Two independent studies, based on deep-sea cores retrieved from the South China Sea, recently extended the known distribution of the YTT, and may suggest that the Rose and Chesner (1987) calculation of the eruption magnitude is an under-estimate. The conventional interpretation of the many Quaternary tephra layers found in this region is that they derive from volcanoes in the Philippines, such as Pinatubo. Song et al. (2000) recovered volcanic glass bubble walls and mica crystals about 16 m beneath the seabed off south-eastern Vietnam, 1500 km northeast of Toba. The tephra layer was about 2 cm thick and fell within the oxygen isotope date range of 64.1– 79.3 kyr BP. Chemical fingerprinting of the >63 mmsized glass shards matched them closely with previously identified distal Toba tephra. Buhring . et al. (2000) discovered a 3 cm thick layer of rhyolitic ash in sediment cores even further away, some 1800 km northeast of Toba, retrieved from the seabed between Borneo and Indochina. The ash was dated to E74 kyr BP and is composed almost entirely of glass shards. Analyses of individual fragments indicated SiO2 Fig. 3. SEM micrographs of glass shards from the YTT layer in Bengal Fan sediment cores (Gasparotto et al., 2000): (a) assorted vesicular and bubble wall fragments (100 mm scale bar shown), (b) individual bubble wall at higher magnification (scale bar divisions are 100 mm). Photographs courtesy of Giorgio Gasparotto, University of Bologna. contents of 75–78 wt% and similar major element compositions to published analyses of YTT. These two occurrences are the first YTT deposits found substantially eastwards of the caldera. They suggest that the magnitude of the eruption might be significantly greater than previously estimated. The dispersal of the ash cloud across the South China Sea may point to eruption during the northern hemisphere summer monsoon when south-westerly winds prevail at low- to middle-tropospheric levels, transporting ash from lower parts of the co-ignimbrite clouds. Deep-sea coring in the Central Indian Basin has exhumed further suspected Toba tephra, up to 1500 km south of previous occurrences (Pattan et al., 1999), and further investigations have revealed YTT tephra on the western continental margin of India (Pattan et al., 2001) and in the Arabian Sea (Schulz et al., 1998). These new finds push dispersal of >63 mm glass shards well into the southern hemisphere to latitudes of 141S, and westwards as far as longitude 641E. Analyses of putative Toba C. Oppenheimer / Quaternary Science Reviews 21 (2002) 1593–1609 tephra from India, Sumatra, Malaysia, and, importantly, an Ocean Drilling Program sediment core located halfway between Sumatra and Sri Lanka that contains Oldest and Middle Toba tephra as well as YTT, indicate that all the Toba ash so far found on peninsular India belongs to the YTT (Shane et al., 1995, 1996; Westgate et al., 1998) and not to some of the earlier eruptions (Mishra and Rajaguru, 1996). (If correct, this clears up a palaeoanthropological controversy concerning ages of stone tools dated by their stratigraphic association with respect to Toba deposits.) Toba ash on the eastern coast of India is found in several metre-thick layers within alluvial sections and with grain sizes of a few millimetres (Acharyya and Basu, 1993). These considerable thicknesses, however, reflect post-deposition reworking. 4. Eruption parameters: intensity, duration The granulometry of feldspar crystals in Indian Ocean YTT tephra horizons was investigated by Ledbetter and Sparks (1979) to estimate the eruption duration. By computing settling velocities for the crystals in water, and from an estimate of the contemporary water depth, they concluded that the eruption lasted between 9 and 14 days. Combined with the eruption magnitude estimate, this suggests a mean eruption intensity of around 7 109 kg s1 of magma, 1–3 orders of magnitude greater than the magma discharge rates calculated by Carey and Sigurdsson (1989) for a number of historic and prehistoric plinian eruptions. Woods and Wohletz (1991) developed a model for the dynamics of co-ignimbrite clouds and concluded that their rise height is less sensitive to intensity than for plinian plumes. Consequently, an eruption like Tambora 1815, which was characterised by fountain collapse, propelled its co-ignimbrite clouds to only about the same height (around 23 km) as the lower ! in 1982. Taking intensity plinian column of El Chichon the intensity of the Toba eruption as 7.1 109 kg s1, they estimated the plume height for the YTT cloud as 3275 km. Rampino and Self (1993a) considered this to be an under-estimate, suggesting that for peak intensities approaching 1010 kg s1, column heights may have reached 40 km. In any case, these calculations of plume height cannot be reliable when it is considered that neither the magnitude nor duration of the eruption are well constrained. In particular, the estimate of eruption duration may need to be reconsidered. Since the model based on the vertical size grading in deep-sea tephra layers, elaborated by Ledbetter and Sparks (1979), there has been increasing recognition of the importance of ash aggregation during airborne transport. There have also been observations and models of the surprisingly fast sedimentation of ash clumps through the water column 1597 (Weisner et al., 1995; Carey, 1997). These effects probably have significant consequences for grain size profiles in tephra layers settling on the seabed. Unfortunately, all these uncertainties necessarily propagate into any modelling of the chemical and radiative impacts of Toba’s stratospheric aerosol veil. Gasparotto et al. (2000) studied thirteen piston cores containing YTT tephra, retrieved from the Bengal deep sea fan off the coast of Bangladesh and India (Fig. 3). Detailed granulometry of sub samples within the layer revealed two grain size populations. This had been observed previously by Ninkovitch et al. (1978a) who considered the possibility that these reflected different transport dynamics of a plinian plume and phoenix cloud. However, as there is no evidence for plinian style activity, an alternative explanation is that aggregation of particles in a co-ignimbrite cloud caused them to fall out of the plume at the same distance as larger, individual particles. As they dropped through the water, these aggregates could have broken up so that the final deposit includes two grain size populations. The different wind dispersal patterns suggested by the widespread tephra distribution (Fig. 2) add further complexity to understanding and modelling observed grain size spectra. 5. Impacts on the atmosphere and climate Assessing the impacts of Toba on the Earth system is highly challenging given the uncertainties in the key parameters for the eruption (intensity, height, magnitude), and amounts of gaseous sulphur species released. Initial interest focused on the apparent coincidence of the eruption with the onset of the Last Glaciation. Rampino and Self (1992) dwelled on the coincidence of the YTT eruption with the transition to glacial climate at the OIS 5a-4 boundary at 67.5 kyr BP. They argued that Toba caused a ‘‘volcanic winter’’—a global mean surface temperature drop of 3–51C—which accelerated the glacial transition from warm to cold temperatures of the last glacial cycle. They also hinted that falling sealevel accompanying the incipient glaciation may have even played a role in triggering the eruption by reducing the load on Toba’s magma reservoir promoting overpressure within it. However, given the relatively shallow depth of the Toba magma chamber, Toba’s distance from the sea (>100 km), and the low strength of the crust, a more likely mechanism whereby climate change could have triggered the eruption may be via the impact of sea-level change on seismicity along the Great Sumatra Fault that runs the length of the island, accommodating oblique convergence between the Eurasian and Australasian plates. Major earthquakes have been implicated as eruption triggers (e.g., Linde and Sacks, 1998), and the location of Toba itself may be 1598 C. Oppenheimer / Quaternary Science Reviews 21 (2002) 1593–1609 related to an apparent restraining bend in the Great Sumatra Fault which could have promoted the development of large, long-lived magma reservoirs there in the first place (Wark and McCaffrey, 2001). Rampino and Self (1992) argued that although global cooling was already underway at the time of the YTT, it had been sluggish up to that point. North Atlantic ocean surface temperatures did not cool significantly, retarding ice sheet growth. But the aerosol veil from Toba, they believed, was sufficient to overcome this slow start and push climate into fully glacial conditions. They suggested that the regional climatic response of Canada to the volcanic forcing played a particularly important role, reporting climate model results that indicated around a 121C reduction in summer temperatures in Canada. This would have favoured the growth of the Laurentide ice sheet, providing a strong positive feedback to the combined Milankovitch and volcanic forcing at an especially sensitive time. Since publication of this work, improved evidence for the timing of the eruption in relation to regional-tohemispheric scale climate changes has emerged from the Greenland ice core record and high-resolution marine cores. In addition, understanding of the atmospheric and climatic impacts of volcanic eruptions has advanced considerably, largely through investigations of the effects of the Mt. Pinatubo eruption (e.g., Minnis et al., 1993; McCormick et al., 1995). In particular, these have highlighted the importance of eruptive volatile budgets. 5.1. Volatile yields There is no doubt from the size of the Toba caldera and extent of ignimbrite and co-ignimbrite fall deposits that the YTT was the result of a monumentally large eruption. Critical for evaluation of its potential climatic impacts, however, are estimation of the gaseous sulphur yield (Table 2) and resulting sulphate aerosol loading of the stratosphere (Robock, 2000). Rose and Chesner (1990) estimated gas contents of the YTT magma to have been about 0.05 wt% H2S and 3 wt% H2O. It is significant that the primary sulphur species released would have been H2S because of the reducing conditions of the magma. Once in the atmosphere, though, oxidation to SO2 would presumably have been rapid. Scaling the H2S content by the estimated total eruption magnitude (7 1015 kg), they determined an eruptive emission of 3.5 1012 kg of H2S (adding that this could be a minimum figure if the magma contained a free vapour phase containing sulphur prior to the eruption). This is equivalent to >1013 kg of sulphate/water aerosol. However, it should not be assumed that all of this sulphur would have reached the stratosphere, since the co-ignimbrite clouds only account for an estimated 800 km3 of the deposit. Scaling the sulphur content by this value suggests a sulphate aerosol loading of Table 2 Estimates of sulphur yields for the YTT eruption Method Sulphur yield (kg of S) Reference Mineral chemistry of YTT 3.3 1012 Ice core sulphate deposition Experimental petrology 0.57–1.1 1012 3.5 1010 Rose and Chesner (1990) Zielinski et al. (1996) Scaillet et al. (1998) o4 1012 kg. Scavenging of SO2 or H2S by ice or ash particles or aggregates or by liquid droplets in the plume, and subsequent deposition, would have reduced the stratospheric loading further still (Rose and Chesner, 1990; Oppenheimer et al., 1998; Textor, 1999). A relationship between a volcano’s sulphur yield (MS ) and the ensuing maximum surface temperature anomaly, DT; for the northern hemisphere was proposed by Sigurdsson (1990) based on historical climate observations DT¼ 5:9 105 MS0:31 : ð1Þ Eq. (1) yields a DT of 3.2 to 4.51C for this range of sulphur yield. Rampino and Self (1992, 1993a, b) essentially used this equation, as well as linear scaling from the observed temperature drop following the 1815 Tambora eruption, to arrive at an estimated 3–51C hemispheric surface temperature fall (they assumed an aerosol loading of around 1012 kg). Such relationships should be used cautiously, however. Not only are they based on sometimes poorly constrained estimates of temperature anomalies and sulphur yields, they may also fail to represent adequately several factors that influence the climate changing potential of an eruption (e.g., plume and upper atmospheric dynamics). Physical and chemical processes in stratospheric volcanic clouds may act in a ‘‘self-limiting’’ way. Pinto et al. (1989) applied simplified aerosol photochemical and microphysical models to show that, for a 1011 kg injection of SO2, condensation and coagulation produce larger aerosol particles, which are less effective at scattering incoming sunlight, and also sediment more rapidly. Combined, these effects lessen the expected magnitude and duration of climate forcing expected from supereruptions, certainly if based on linear extrapolations of observations of cooling from eruptions like Pinatubo. An independent estimate of the sulphur yield from the YTT eruption was obtained from the Greenland ice core record (Fig. 4). Zielinski et al. (1996) observed sulphate spikes at 69.4, 71, 72, and 73.6 kyr BP in the Greenland Ice Sheet Project 2 (GISP2) core. At this depth, the error in ages is E75 kyr. The 71 kyr BP anomaly (70 kyr BP using the latest GISP2 chronology, Fig. 4) was by far the strongest, with concentrations of volcanic sulphate 3–5 times the other nearby peaks. In fact, it is the largest C. Oppenheimer / Quaternary Science Reviews 21 (2002) 1593–1609 1599 Fig. 4. Oxygen isotope and total sulphate measurements for the GISP2 core between 60 and 80 kyr. The sulphate measurements (lower curve, in ppb by mass) are un-corrected for non-volcanic contributions but the putative Toba spike is very clear. The upper curves indicate oxygen isotopic measurements (more negative values indicate lower temperatures), which were made at much coarser temporal resolution (2 m sections of core). The thick and thin lines indicate ages for the top and bottom of the measured layers, respectively. Dansgaard-Oeschger events 19 and 20 are labelled. Note that the cold spell between them is not that different in magnitude and duration from the one immediately prior to event 20. Ages correspond to the official GISP2 ‘‘Meese/Sowers’’ timescale which dates the YTT eruption to 70 kyr BP. The refined timescale elaborated by Meese et al. (1997) which is arguably more accurate, places the eruption date a little later at 68 kyr BP. These differ slightly from the original sulphate record published by Zielinski et al. (1996), which dated the YTT eruption at 71 kyr BP. Data from Stuiver et al. (1995, 1997) and Mayewski et al. (1997) and provided by the National Snow and Ice Data Center, University of Colorado at Boulder, and the World Data Center-A for Paleoclimatology, National Geophysical Data Center, Boulder, Colorado. For a review of ice core and other records of volcanism, see Zielinski (2000). sulphate anomaly reported in the entire 110 kyr record, and this was considered befitting for the largest known Late Quaternary eruption. The spike was also close to the beginning of the last glacial period, consistent with the timing identified by other records. It was accordingly designated as the YTT layer. They estimated the sulphate/water aerosol loading from the volcanic sulphate concentrations (given by the difference of total and background sulphate concentrations, {½SO2 4 total and ½SO2 ; respectively) in each of five con4 background secutive 1.5 yr samples of the core containing the identified YTT layer Maerosol ¼ 3:2 109 f½SO2 4 total ½SO2 4 background g L rice k; ð2Þ where L is the length of the ice layer, rice its density, and k is a thinning factor (approximately 16 for this depth of ice) to account for compaction of the annual layers. The constant multiplier converts the flux of volcanic sulphate (in kg km2 per 1.5 yr) for each sample into an aerosol loading, using a calibration based on nuclear bomb fallout, and taking into account the mass difference between H2SO4 and sulphate/water aerosol. Summing the five samples yielded an estimate of 2.3–4.7 1012 kg of aerosol, in reasonable agreement with the earlier calculations based on mineral chemistry of the YTT. However, more recent work based on experimental petrology presents an intriguing challenge to these estimates. In general, silicic magmas degas less sulphur than mafic magmas. What made the silicic magmas ! (1982) and Pinatubo (1991) erupted by El Chichon atypical was their highly oxidising conditions. Recalling that H2S rather than SO2 was stable in the YTT magma implies a very different environment for evolution of magmatic volatiles. The reducing conditions and the relatively low temperature of the YTT magma could indicate that Toba’s sulphur yield was actually remarkably low. Based on an extrapolation of experimental data, Scaillet et al. (1998) estimated that only around 3.5 1010 kg of sulphur would have been liberated by the YTT magma on eruption, 2–3 orders of magnitude lower than the previous estimates. A 3.5 1010 kg sulphur yield is only three times that measured for Pinatubo’s eruption, which was probably o0.2% of the size of the YTT event in terms of tephra production. C. Oppenheimer / Quaternary Science Reviews 21 (2002) 1593–1609 This leaves a problem of reconciling the massive ice core sulphate anomaly with such a modest sulphur emission. Firstly, there is potentially a circular argument in the identification of the YTT ice core horizon. One of the main reasons for its designation was that the largest sulphate anomaly in the GISP2 core (five times bigger in terms of concentration than the Tambora 1815 horizon) was considered ‘‘appropriate for the great size of the [YTT] eruption and the estimated large amount of atmospheric loading associated with it’’. If the YTT was only Tambora-sized in terms of sulphur output then it would not have left so impressive a mark in the Greenland core. Scaillet et al. (1998) point out that the dating accuracy at this depth of the ice core is only about 75 kyr and suggested therefore that the 71 kyr BP ice core signal might be the cumulative imprint of several eruptions with sulphur yields comparable to Krakatau or Pinatubo. Ten Krakatau-sized aerosol events occurring at the rate of one per century, they claimed, could leave a 460 ppb signal similar to that identified as Toba’s. But this explanation does not work because the ‘‘YTT’’ sulphate anomaly spans only 6 yr, not 1 kyr, and so is consistent with fallout from a single event. Another possibility is that the 71 kyr BP anomaly records a very large Icelandic or other high northern latitude, sulphur-rich eruption. The problem with this argument is that such an event should have deposited identifiable glass shards in the horizon—none has been found. This is even hard to explain if the layer is genuinely that of the YTT. Even shards from much smaller eruptions, further south than Toba, have been identified in the Greenland ice core, for example, those belonging to the 1600 eruption of Huyanaputina volcano, Peru, at 161S (de Silva and Zielinski, 1998). This could reflect several factors including the different dynamics of co-ignimbrite plumes, lower altitudes of injection into the stratosphere, or retarded poleward circulation of the cloud, allowing ash to fall out before the volcanic cloud reached high latitudes, but is surprising nevertheless. The low yield calculated by Scaillet et al. (1998), though, is sensitive to the assumed depth of the magma reservoir (they used the 10 km estimate of Chesner, 1998). Such a large chamber as must have been involved in the YTT eruption may have had considerable vertical extent (as the present magmatic system appears to have according to Masturyono et al., 2001) with the possibility that sulphur was considerably more abundant at greater depth in the more mafic roots of the system. Another potential source of sulphur in eruption columns is from hydrothermal fluids and minerals incorporated into the erupting fluid as the conduit and vent widens (Oppenheimer, 1996). Any contribution from this source would be neglected by the approach taken by Scaillet et al. (1998), which considers only pre-eruptive sulphur co-existing as a fluid phase in the magma, or dissolved in the melt. As it stands, we can only conclude that we need better petrologic understanding of the YTT eruption, improved estimates of the magnitude of the co-ignimbrite fall deposits, the ‘‘smoking gun’’ of YTT glass in the ice core, and especially more reliable figures for the sulphur yield, before being able to verify the correspondence between the YTT eruption and atmospheric and climatic change. This uncertainty should be kept in mind while reading the following sections on the YTT eruption’s atmospheric and climatic impacts. 5.2. Modelling the impacts on the atmosphere of a super-eruption The only atmospheric model to date for the YTT eruption was presented by Bekki et al. (1996). They used a global-scale, two-dimensional model that had been developed initially for studies of aircraft emissions, and simulated the eruption by a 6 1012 kg SO2 injection into the tropical stratosphere at altitudes between 25 and 35 km. The model indicated considerably enhanced residence times of SO2 in the stratosphere compared with Pinatubo (Fig. 5). Only after 5–6 yr in the model did SO2 concentrations return to background levels in the stratosphere. The reason for this is that the volcanic SO2 mops up all the available OH radicals in oxidising to sulphate aerosol, long before all the SO2 has been consumed. The remaining gaseous SO2 effectively has to wait until more OH is produced photochemically. 12 10 11 10 Mass of sulfur (kg) 1600 Toba 10 10 9 10 Pinatubo 8 10 10 Aerosol background 7 SO 2 background 0 1 2 3 4 5 6 7 8 9 10 Time after eruption (yr) Fig. 5. Total mass of SO2 and sulphate aerosol in the stratosphere (heavy solid and dotted lines, respectively) modelled for a 6 1012 kg stratospheric injection of SO2. Observed SO2 and aerosol mass for the 1991 Pinatubo eruption are shown for comparison. The much larger amount of SO2 in the Toba simulation soaks up all available oxidants in the stratosphere leading to a much longer lifetime of SO2 and, in turn, prolonging the manufacture of sulphate aerosol. Data from Read et al. (1993) and Bekki et al. (1996). C. Oppenheimer / Quaternary Science Reviews 21 (2002) 1593–1609 However, production of OH is also retarded because the aerosol already formed backscatters solar ultraviolet radiation. In the case of a much smaller input of sulphur, such as Pinatubo’s, the oxidation rate of SO2 to SO2 4 is proportional to the product of the concentrations of SO2 and OH. For the Toba model, in the first 2 years after the eruption when SO2 concentrations are very high, the OH concentration is itself inversely proportional to the SO2 concentration. As a consequence, the oxidation rate is slow and roughly constant, and the SO2 cloud long-lived. As sulphate forms in the gas phase, it condenses to form sulphate aerosol. The aerosol is believed to form by spontaneous nucleation of new particles condensing from the gas phase rather than by condensation on to existing aerosol. This ensures that the aerosol maintains small (sub-micron) sizes resulting in a longer residence time in the stratosphere, and stronger backscattering of solar short-wave radiation. The combination of slow oxidation of a long-lived SO2 gas cloud, and gas-phase nucleation of aerosol results in a longer-lived layer of finer sized, radiatively effective aerosol. In fact, the model predicts that the peak aerosol loading due to the YTT eruption did not occur until 3 yr after the eruption, and that the volcanically-enhanced stratospheric aerosol persisted for almost a decade. The radiative effects of this longer-lasting aerosol may have been sufficient to overcome the thermal inertia of the oceans, triggering a longer-term climatic cooling. 5.3. Ice cores The GISP2 record also pointed to a longer-lived aerosol layer. The high-resolution sampling of the putative YTT layer led Zielinski et al. (1996) to conclude that sulphate deposition lasted about 6 yr (Fig. 6). Possible effects of shearing of the ice layer or diffusion of the acid were discounted because there were neither symmetry nor repeat signals in this part of the core. Initially, they attributed this extended fallout to the possibility of multiple eruptions from Toba but the observation is consistent with the model prediction from Bekki et al. (1996) of sustained replenishment of sulphate aerosol due to the slow oxidation of a single massive SO2 cloud. Taking the intermediate values for sulphate loading from Zielinski et al. (1996), indicates annual sulphate/ water aerosol loadings of 1.8–6.5 1011 kg. Inserting the equivalent sulphur amounts into Eq. (1) suggests mean surface temperature anomalies of between 0.91C and 1.31C, much less than the values computed from an instantaneous release of >1012 kg of aerosol. These values coincide with results of oxygen isotopic analyses of the sediment immediately above the YTT layer in a South China Sea core, which suggest that sea-surface temperatures dropped by E11C (Song et al., 2000), 1601 although these could reflect conditions 10s or 100s yr after the event. This finding has been reinforced more recently by Huang et al. (2001) who used the unsaturation index of long-chain ketones (produced by various single-celled algae) to estimate sea-surface temperatures in the South China Sea following the YTT eruption. The high sedimentation rates in this region (E20 cm kyr1) permit 100 yr resolution. Their analyses indicate a 11C sea-surface temperature anomaly that lasted for about 1 kyr immediately following the eruption. This seasurface temperature change appears consistent with conclusions reached by Rousseau and Kukla (2000). They suggested that a possible explanation for a rapid monsoon retreat, documented by a rapid switch from soil complexes to loess deposition in the Chinese Loess Plateau, is the sudden rearrangement of the oceanic conveyor belt triggered by the YTT eruption. Huang et al. (2001) also note the coincidence of increased East Asia winter monsoon intensity, increased ice-rafted debris in North Pacific sediments (Kotilaninen and Shackleton, 1995), and decreased d18O in the Greenland ice core (Zielinski et al., 1996), implicating the following chain of events: polar cooling, expansion of northern hemisphere ice sheets, increasing intensity of the East Asian monsoon, cooling of China and the tropical Pacific, and reduction of atmospheric water concentration. They concluded that such processes could have acted to prolong the short term cooling initiated by the Toba event. de Garidel-Thoron et al. (2001) have also noted a teleconnection between the East Asian winter monsoon and Greenland climate. The high temporal resolution, multi-parameter measurements of the GISP2 core enable a detailed inspection of the relative timings of the sulphate impulses and climatic changes, that is much more difficult with even the highest-resolution oxygen isotope records from the deep-sea sediment cores containing YTT glass. The first observation is that while the Toba spike coincides with a 1 kyr cool period between interstadials 19 and 20, it is separated by the 2 kyr long, and dramatic warming event (Lang et al., 1999) of interstadial 19, from the prolonged (9 kyr) major glacial which began around 67.5 kyr BP. This undermines the early argument that the YTT eruption played a role in initiating the Last Glaciation, though leaves open the possibility that it is implicated in the E1 kyr cold period prior to interstadial 19. It remains difficult to ascertain, for certain, the YTT eruption’s climatic consequences. To begin with, it is clear from the glaciochemical record that climate was already unstable prior to the eruption and the main glacial period. For example, interstadial 20 is preceded by an 800 yr period of cold climate, apparent from low d18O, high Ca2+, and very low ECM signals (Fig. 1 in Zielinski et al., 1996). Also apparent from the GISP2 records, Ca2+ levels began increasing, and ECM drops, C. Oppenheimer / Quaternary Science Reviews 21 (2002) 1593–1609 1602 Years 15 12 9 6 3 0 500 2000 SO42- 400 300 1000 200 Ca2+ [Ca2+] (ppb) [SO42-] (ppb) 1500 500 100 0 0 2590.95 2591.05 2591.15 2591.25 Depth (m) Fig. 6. High temporal resolution sulphate (corrected for sea-salt contributions) and calcium ion concentrations spanning the Toba horizon in the GISP2 ice core. The sampling was carried out for 1.5 cm thick slices of core which are equivalent to E1.5 yr each. From Zielinski et al. (1996). just before the YTT spike. This suggests that the 71 kyr BP stadial might have happened even without Toba. On the other hand, the timing of the eruption during a phase of high climate sensitivity may have been sufficient to amplify the initial cooling impulse. Ca2+ fluctuations at the very start of the 71 kyr BP stadial provide some evidence for this hypothesis. No other stadials reveal a pulse of Ca2+ deposition prior to the main peak of the cooling event as the 71 kyr BP episode does. Zielinski et al. (1996) concluded that ‘‘eruptions of [Toba’s] magnitude can significantly modify atmospheric conditions to the point of playing a role in forcing climatic cooling on century timescalesyAn eruption of Toba’s magnitude occurring today would have devastating repercussions (i.e., a true volcanic winter)’’. 5.4. Other atmospheric impacts Evidence for other atmospheric perturbations arising from the Toba eruption has come to light from further ice core analysis. Yang et al. (1996) recorded timeresolved concentrations of chloride, nitrate, and the ratio of Cl to Na+, in the GISP2 YTT layer, and compared them with the sulphate spike (Fig. 7). The pulse of aerosol fallout was found to coincide with a low concentration of nitrate (about 5 ppb, the lowest in the entire GISP2 record, and compared with a mean of about 83 ppb prior to the eruption), and low concentrations of Cl (25 ppb, compared with a pre-eruption mean of 66 ppb). These depletions of chloride and nitrate, and an accompanying low ratio of Cl to Na+ (0.75, compared with a pre-eruptive value of 1.9) indicate strong impacts on tropospheric chemistry. The primary source of Cl to the ice caps is from deposition of sea salt (NaCl). Reaction between sea salt aerosol and H2SO4 in the atmosphere is thought to yield most of the atmosphere’s complement of HCl 2NaCl þ H2 SO4 ¼ 2HClðgÞ þ Na2 SO4 : ð3Þ This reaction is sometimes responsible for lowering the Cl/Na+ ratio in the sea salt transported to the ice caps relative to the mean value for seawater of about 1.8. The additional H2SO4 produced by Toba may have abstracted even more Cl from sea salt, further reducing the Cl and Cl/Na+ ratio in the ice core. Chloride concentrations reach a peak following the sulphate spike (Fig. 7), possibly as a result of build-up of atmospheric chlorine due to the limited solar ultraviolet radiation passing through the aerosol veil. Usually, C. Oppenheimer / Quaternary Science Reviews 21 (2002) 1593–1609 1603 Years 15 12 9 6 3 0 2000 120 SO42Cl- 100 80 1000 60 [Cl-] (ppb) [SO42-] (ppb) 1500 40 500 20 0 0 3 2000 SO42Cl-/Na+ 2 1000 1 Cl-/Na+ [SO42-] (ppb) 1500 500 0 0 2000 200 1500 150 1000 100 500 50 0 2590.95 [NO3-] (ppb) [SO42-] (ppb) SO42NO3- 0 2591.05 2591.15 2591.25 Depth (m) Fig. 7. High temporal resolution sulphate (as in Fig. 6), chloride, and nitrate concentrations, and the chloride/sodium ionic ratio for the Toba horizon in the GISP2 ice core. The timescale is the same as for Fig. 6. From Yang et al. (1996). 1604 C. Oppenheimer / Quaternary Science Reviews 21 (2002) 1593–1609 chlorine formed by reaction between sea salt and ozone undergoes rapid photochemical conversion to HCl. As the volcanic aerosol veil dissipated and solar short-wave radiation again penetrated into the troposphere, the reservoir of accumulated chlorine would have been rapidly photochemically converted to HCl, resulting in a pulse of Cl deposition seen in the ice core record. The low nitrate levels can be explained by Toba’s cooling effect on the lower atmosphere. Reduced heating would lessen thermal convection, decreasing the frequency of electrical storms that are a key source of NOx. The combination of less NOx with reduced production of OH radicals (which oxidise NO and NO2 to NO 3 ) would result in low atmospheric nitrate. This result is at odds with earlier modelling efforts, which suggested that significant denitrification of the polar lower stratosphere would occur after the Toba eruption. The lost nitrogen should end up being scavenged by the polar snow leaving a peak of NO 3 in the ice core, contrary to observations. There are some significant caveats to this work however. It is possible that the apparent perturbations to ice core chemistry do not reflect contemporary atmospheric chemistry but rather post-deposition reactions occurring in the highly acidic YTT ice horizon, and, to an extent, the conclusions hinge on the assumption that, given the size of the YTT eruption, there must have been an atmospheric chemistry perturbation. ! and Pinatubo eruptions resulted in The El Chichon global reductions of stratospheric ozone of up to 10% (McCormick et al., 1995), and it is important to consider whether the more prolonged and concentrated YTT aerosol veil might have had major impacts on upper atmospheric ozone (Tie and Brasseur, 1995). However, the chlorine activated by the stratospheric aerosol veils of these recent eruptions would have been primarily anthropogenic (i.e., not a factor in the Middle Palaeolithic). There is likely to have been an impact on stratospheric ozone chemistry, however, due to the levels of solar radiation intercepted by SO2. This would have reduced the photochemical production of ozone, and Bekki et al. (1996) have modelled localised 30–60% reductions in stratospheric ozone within 3 yr of the eruption. What this might have meant in terms of biologically significant levels of ultraviolet-B penetrating to the surface is difficult to assess, however, since the gaseous SO2 and the aerosol veil in the stratosphere would have counteracted the effect of ozone loss by absorbing and scattering ultraviolet radiation. 6. Impacts on the terrestrial environment Rose and Chesner (1990) likened the aftermath of the eruption to an ‘‘enormous fire’’, covering up to 30,000 km2, arising from the widespread ignition of vegetation. They judged that the outflow sheets of the YTT would have had temperatures up to 5501C when they came to rest, compared with an initial temperature of 710–7701C. From observations following Pinatubo’s 1991 eruption (e.g., Torres et al., 1996), we can imagine that these deposits remained at high temperatures for years given their great thicknesses (up to several 100 m), and that their lack of welding would have resulted in frequent remobilisation and generation of secondary pyroclastic flows. There must have also been many months of explosions due to the interaction between the hot deposits and rain or surface water. Rampino and Ambrose (2000) suggested that soot from the burnt vegetation, as well as very fine ash and sulphate particles, would have contributed to the aerosol veil spreading across the globe in the weeks after the eruption. They likened the environmental consequences to those predicted from studies of nuclear winter, and asteroid impacts on the Earth. The low light levels reaching the Earth’s surface due to the turbid aerosol veil would have reduced photosynthesis, which, coupled with low surface temperatures, would have killed off much vegetation. They suggested that tropical forests would have been most vulnerable to chilling, with potentially severe and lasting damage resulting from temperature drops of up to 101C. Temperate forests may have fared little better with both coniferous and deciduous trees suffering, especially during cold springs and summers when new shoots are less resistant to chilling. In the oceans, Rampino and Ambrose (2000) argued that the tephra sedimenting through the water column would have scavenged out nutrients. This effect combined with reduced sunlight reaching sea-level, and changes in atmospheric circulation, could have limited surface productivity in the oceans. They considered that ‘‘given the magnitude of the effects of volcanic winter on global climate and primary productivity it would be remarkable if this cataclysmic event did not affect tropical humans and other species’’. However, recent analyses of leachates of fresh ash fall from the modest 2000 eruption of Hekla in Iceland suggest that ash fallout can actually fertilise the oceans by supplying macronutrients and ‘‘bioactive’’ trace metals (Frogner et al., 2001). 7. Human impacts Investigation of the palaeodemography of Homo through the Pleistocene has been tackled from many perspectives, including palaeoanthropology, archaeology, numerical modelling, and, most recently, a range of genetic studies. Around the time of the eruption, Neanderthals inhabited Eurasia and the Levant, modern C. Oppenheimer / Quaternary Science Reviews 21 (2002) 1593–1609 humans occupied Africa, the Arabian peninsula and parts of central Asia, ‘‘Homo heidelbergensis’’ was in China, and Homo erectus in southeast Asia. Some authors contend that modern humans are the ancestors of a small founder population (several thousand individuals) surviving one or more population ‘‘bottlenecks’’ at some point in the Pleistocene (for a review, see Harpending and Rogers, 2000). The timing and duration of this event are controversial, not least because of large confidence limits in the application of the ‘‘molecular clocks’’ behind many of the estimates— and there are arguments that refute the evidence for any significant bottlenecks occurring after the beginning of the Homo lineage (e.g., Hawks et al., 2000; Hawks and Wolpoff, 2001; Wolpoff et al., 2001). Elaborating on arguments for the origins of modern humans (e.g., Harpending et al., 1993; Rogers and Jorde, 1995), Ambrose (1998) and Rampino and Ambrose (2000) have argued that 6 years of volcanic winter caused by the YTT eruption, and a consequent millennium of cold climate and its global environmental consequences, precipitated a severe bottleneck, implying an abrupt and recent differentiation of human populations. Ambrose (1998) suggested that Neanderthals might have faired better in these climatic conditions due to their more cold-tolerant anatomy (Stringer and Gamble, 1993; note that Neanderthals survived up to around 30 kyr BP, e.g., Bolus and Conard, 2001). Release from the bottleneck would have been facilitated by invention of improved Later Stone Age technology, and increasing access to food supplies around 50 kyr BP (Harpending et al., 1993; Ambrose, 1998), though McBrearty and Brooks (2000) have argued for a far earlier and more gradual development of tool technology, long distance trade, and other putative aspects of behavioural modernity. The equatorial region of Africa would have offered the most extensive refugia for survival of humans during this period, and therefore have sustained the highest populations through the bottleneck. There are a number of difficulties with this hypothesis. Population bottlenecks at various times are turning up in the lineages of all kinds of creatures including elephant seals, pin-worms, koalas, fruit flies and anchovies. What would lend weight to the ‘‘volcanic winter-Garden of Eden’’ scenario (Ambrose, 1998) would be contemporaneous bottlenecks in the ancestry of great apes. However, the genetic variation in humans reveals a very different pattern to the African great apes, apparently undermining suggestions of parallel demographic histories (Gagneux et al., 1999). The possible exception to this is the eastern chimpanzee clade. Harpending and Rogers (2000) point out that a species could survive an environmental catastrophe like the YTT eruption in two or more refugia, resulting in far more genetic variance than a species that survived in 1605 only one, ‘‘thus, a few species that showed a different pattern would not refute the hypothesis of a Pleistocene bottleneck, but a few showing the same pattern would greatly strengthen it’’. Perhaps a more substantive problem is that on the basis of the well-constrained date for the YTT, 74 kyr BP, and the broader age range proposed for the bottleneck, one cannot even conclude with any confidence that the eruption actually preceded the bottleneck. In fact, the widely accepted median estimate for the bottleneck age based on mitochondrial DNA studies is about 200 kyr (Harpending and Rogers, 2000; Hawks et al., 2000; Hawks and Wolpoff, 2001). There is no firm evidence, therefore, linking the YTT eruption to a human demographic crash. Nor is the climate around 74 kyr BP uniquely cold by Quaternary standards. The GISP2 oxygen isotope record reveals comparably low temperatures to 70 kyr BP at 36 and 33 kyr BP. The direct impacts of the eruption (inundation by ash, etc.) would surely have been devastating, but at a regional rather than global scale. If Toba is to be held responsible for a more global impact on human demography, however, one would have to argue that the eruption occurred at a particularly sensitive time for other reasons, or the suddenness of the impacts played a role. Interestingly, if Swisher et al. (1996) have correctly identified and dated the Ngandong fossils from Java, the eruption does not appear even to have extinguished the last vestiges of Homo erectus populations, which they claim survived up to 30–50 kyr BP, although both the interpretation of these fossils as Homo erectus, and the young dates have been challenged (e.g., Grun . and Thorne, 1997; Wolpoff et al., 2001, respectively). It is also relevant to consider that there are approximately 10 super-eruptions (involving eruption of 300–3000 km3 DRE magma) per 106 yr (Pyle, 2000; Simkin and Siebert, 2000), i.e., there have been more than 20 such events during the Homo lineage. Especially in view of its potentially low sulphur yield (Scaillet et al., 1998), the eruption of the YTT may not have been the most climatically significant volcanic event of the Quaternary. Without a clear picture even of the relative timing of events, we cannot at present establish a causal chain. Just because the YTT event is the largest known Late Quaternary eruption does not by itself implicate it in a global human population crash. There are often many contending explanations for demographic demise. With the repeated, profound and prolonged global climatic change and environmental stress associated with interglacial–glacial transitions, we may not have to look too hard for an underlying cause for any putative near extinction of Homo and for proposed expansions and contractions of human populations throughout the Quaternary (e.g., Lahr and Foley, 1998, who associate the bottleneck with OIS 6; Hewitt, 2000). 1606 C. Oppenheimer / Quaternary Science Reviews 21 (2002) 1593–1609 8. Discussion and conclusions Probing the published investigations of the YTT eruption reveals that a number of conclusions have been based on unreliable assumptions and inferences. In particular, model outputs are sensitive to poorly constrained inputs. For example, the model elaborated by Bekki et al. (1996) assumed a stratospheric injection of 6 1012 kg of SO2 but the total aerosol loading computed by Zielinski et al. (1996) is 0.7–3.5 1012 kg, corresponding to 0.46–2.3 1012 kg of SO2, up to an order of magnitude less. Scaillet et al. (1998) suggest an even lower sulphur yield. A smaller SO2 pulse can be expected to produce a shorter-lived SO2 cloud and hence less radiatively active aerosol. The eruption intensity estimate was based partly on size grading of tephra in deep-sea cores (Ledbetter and Sparks, 1979). But the observed grading could reflect variable column dynamics and wind dispersal patterns, clumping of the ash as it settled through the water column, or possibly even bioturbation of sediment after deposition. If the derived eruption duration is unreliable, then the intensity is unreliable. If the intensity is uncertain then the column heights estimated for the YTT are hard to evaluate. In other words, there remain major unresolved issues that limit current attempts to model the atmospheric and climatic effects of the eruption. Advances in modelling will require new approaches to documenting the eruption style, and the temporally and spatially (vertically) resolved sulphur yield. Assuming that the YTT fallout has been correctly identified in the GISP2 sulphate stratigraphy, we can discount earlier suggestions that the eruption triggered the last Ice Age, but still have the possibility that it was responsible for the onset of a millennium of cool climate prior to Dansgaard-Oeschger event 19. On the other hand, a comparable stadial preceded event 20. What kinds of impact might the eruption have had on contemporary human populations? Can any credence be given to suggestions that the eruption precipitated a crash in human population numbers? While the arguments proposed by Rampino and Ambrose (2000) and Ambrose (1998) are plausible, they are not yet compelling because, in addition to the problems in estimating the global and regional climatic impacts of the eruption, it is hard to compare a fairly robust date for the YTT eruption itself, with controversial and uncertain dates for the putative demographic bottleneck. Furthermore, the timing of the YTT is at the limit of radiocarbon dating, perhaps holding out limited hope of advances coming from archaeology. Resolving the sequences of events and the relationships between cause and effect is difficult enough for the Late Bronze Age ‘‘Minoan’’ eruption of Santorini, a mere 3.5 kyr ago. So what can realistically be achieved in the next years? There is an increasingly clear indication of the rich tephra record of the YTT eruption in the oceans, and to a lesser extent, on land. The deep-sea sediment stratigraphy often appears disturbed and the ash horizons are thin but given refined models for ash deposition in deep water, new studies of YTT occurrences, their thickness, componentry and granulometry could provide a strong basis for re-evaluating the total mass of tephra, atmospheric transport, plume rise heights, and eruption intensity vs. time. It could shed light on the fractions of sulphur entrained into the stratosphere and troposphere, the time of year of the eruption, and suggest analogies with modern equatorial explosive eruptions (e.g., the 1994 eruption of Rabaul, Papua New Guinea). The ice cores provide a further repository of information on the eruption. Conclusive identification of YTT-like glass shards would corroborate designation of the YTT sulphate spike. More high temporal resolution analyses might also yield additional information on atmospheric dynamics and climate response. Perhaps some new information might come from the Antarctic ice core records. The experimental work of Scaillet et al. (1998) may point the way to new petrological methods that will ultimately yield more reliable estimates of the sulphur (and halogen) yield of the eruption. New melt inclusion analyses of volatiles would also help to corroborate or refute the conclusions reached by Scaillet et al. (1998), at least concerning the availability of volatiles from syneruptive degassing. Hard data on all these aspects of the YTT eruption, along with advances in understanding the contemporary climate and atmospheric dynamics, and their response to the eruption, based on a wide range of high-temporal resolution palaeoclimate records, will be essential to parameterise any models for the eruption’s potential global consequences. Development of such models will open up many avenues of research into volcano-atmosphere-climate interactions. For example, currently we have only a limited understanding of the implications of atmospheric injection of sulphur gases by phoenix clouds rather than a central eruption column, or of the primary release of H2S rather than SO2. Other fruitful research directions include modelling the atmospheric environments that could permit large amounts of volcanic chlorine or bromine to reach the stratosphere, and quantifying the oceanatmosphere-cryosphere interactions and system thresholds whereby short-term (a few years) volcanic cooling can trigger millennial scale cold periods (e.g., Pollack et al., 1976). In addition to the approaches described above, we should also be open to broad, integrated multi- and inter-disciplinary investigations of the YTT eruption involving both novel and conventional approaches (high resolution palaeoclimate records, sedimentology, palynology, archaeology, geochemistry, climate modelling, C. Oppenheimer / Quaternary Science Reviews 21 (2002) 1593–1609 terrestrial ecology, etc.). While there is clearly much work still to do, the rewards of an improved understanding of the YTT eruption and its aftermath will be highly significant, not least for the insights to be gained into the potential effects of the next ‘‘supereruption’’. Acknowledgements I am grateful to Rob Foley, Marta Lahr, David Pyle, Bruno Scaillet and Milford Wolpoff for discussions and comments; to Bill Rose and John Westgate for beneficial reviews of the manuscript; to Giorgio Gasparotto for the SEM images; and Owen Tucker for assistance with the illustrations; and Jim Rose for overall editorial input. References Acharyya, S.K., Basu, P.K., 1993. Toba ash on the Indian subcontinent and its implications for correlation of Late Pleistocene alluvium. Quaternary Research 40, 10–19. Ambrose, S.H., 1998. Late Pleistocene human population bottlenecks, volcanic winter, and differentiation of modern humans. 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