Period: Name: Date: Unit 13 HW Packet: Acids, Bases, and Neutralization Part 1: Naming Binary Acids (hydro- prefix a. b. c. d. e. root –ic suffix) HCl HBr HF H2S H3P Part 2: Naming Acids with Polyatomic Ions (Oxyacids) If the polyatomic ion ends in –ate, the acid ends in –ic. If the polyatomic ion ends in –ite, the acid ends in –ous. a. b. c. d. e. f. g. h. H2SO4 HNO2 HClO3 H3PO4 H2CO3 HC2H3O2 HClO2 HNO3 Part 3: Naming Bases a. b. c. d. e. f. g. h. KOH Al(OH)3 Mg(OH)2 LiOH Fe(OH)3 Zn(OH)2 NaOH CsOH Part 4: Writing Formulas for Acids and Bases Remember the rules you just practiced and work backwards. Acids always begin with “H” and Bases always end with “OH”. You will also need to criss-cross the charges to determine subscripts. a. Hydrosulfuric Acid i. Chloric Acid b. Sulfuric Acid j. Chlorous Acid c. Sulfurous Acid k. Ammonium Hydroxide d. Nitric Acid l. e. Nitrous Acid m. Hydrophosphoric Acid f. Silver Hydroxide n. Phosphoric Acid g. Iron (II) Hydroxide o. Acetic Acid h. Hydrochloric Acid p. Magnesium Hydroxide Aluminum Hydroxide Part 5: Use these formulas to complete the chart below. pH = - log [H3O+] pH =================== [H3O+] = antilog(-pH) Acid/Base HCl NaOH HBr KOH HI LiOH HC2H3O2 CsOH HNO3 Mg(OH)2 H2SO4 Ca(OH)2 [H3O+] 1.0 x 10-4 - 2.6 x 10 3 9.5 x 10-11 [H3O+][OH-] = 1 x 10-14 [H3O ] ==================== [OH-] + [OH-] pH 1.0 x 10-4 1.0 x 10 -3 1.00 5.8 x 10-4 3.6 x 10-10 4.70 11.90 0.20 2.89 Acid or Base? Part 6: More pH Calculations 1. If the hydronium ion concentration is 3.4x10 -3M, calculate the pH. 2. If the hydroxide ion concentration is 3.4x10 -3 M, calculate the pH. 3. If the hydroxide ion concentration is 3.4x10 -3 M, calculate the hydronium ion concentration. 4. If the pH = 5.47, calculate the hydronium ion concentration. 5. If the pH = 5.47, calculate the hydroxide ion concentration. Part 7: Bronsted-Lowry Acids and Bases Label the Bronsted-Lowry acid, Bronsted-Lowry base, conjugate acid, and conjugate base. 1. HCO3- + H2O → OH- + H2CO3 2. HPO42- + H2O → H2PO4- + OH- 3. CH3NH3+ + H2O → CH3NH2 + H3O+ 4. HClO4 + H2O → H3O+ + ClO4- 5. HSO4- + H3O+ → H2O + H2SO4 6. NH3 + HSO3- → NH4+ + SO32- Part 8: Neutralization Reactions Predict the correct formula for the salt formed in the following equations. Write the name of each acid under the formula for the acid. ACID + BASE SALT + WATER HCl + NaOH NaCl + H2O H2SO4 + Ca(OH)2 + H2O HNO3 + KOH + H2O H2CO3 + NaOH + H2O H3PO4 + Ca(OH)2 + H2O HC2H3O2 + KOH + H2O HCl + NH4OH + H2O H2SO4 + Mg(OH)2 + H2O Hydrochloric acid Part 9: Titration Calculations Balance the equation. Substitute into the formula with units. Show your answer with units. Use the following formula: MAVA = MBVB CB CA MA and MB: Molarity of the acid/base VA and VB: Volume of the acid/base CA and CB: Coefficient of the acid/base from the balanced equation. 1. If it takes 25.0mL of HCl to neutralize 50.0 mL of 3.0M NaOH, what is the molarity of the acid? HCl + NaOH NaCl + H2O 2. If it takes 25.0mL of H2S to neutralize 50.0mL of 3.0M NaOH, what is the molarity of the acid? H2S + NaOH Na2S + H2O 3. If you start with 75.0mL of Ca(OH)2 and titrate it with 125mL of 1.5M hydrobromic acid, what is the molarity of the base? HBr + Ca(OH)2 CaBr2 + H2O 4. Given 80.0mL of 0.50M sulfuric acid, what vo lume of 0.75M potassium hydroxide is needed to neutralize the acid? H2SO4 + KOH K2SO4 + H2O 5. Given 80.0mL of 0.50M nitric acid, what volume of 0.75M lithium hydroxide is needed to neutralize the acid? HNO3 + 6. H2O Mg(OH)2 Mg3(PO4)2 + H2O If you react 25.7mL of 0.0550M HCl with 38.0mL of NaOH, calculate the molarity of the base. HCl + 8. LiNO3 + If you titrate with 0.0075M phosphoric acid, what volume of this acid is needed to neutralize 285mL of 0.025M magnesium hydroxide? H3PO4 + 7. LiOH NaOH NaCl + H2O If you react 25.7mL of 0.0550M H2SO4 with 38.0mL of NaOH, calculate the molarity of the base. H2SO4 + NaOH Na2SO4 + H2O 9. If you react 25.7mL of 0.0550M HCl with 38.0mL of Ca(OH) 2, calculate the molarity of the base. HCl + Ca(OH)2 CaCl2 + H2O 10. If you react 25.7mL of 0.0550M H3PO4 with 38.0mL of Mg(OH)2, calculate the molarity of the base. H3PO4 + Mg(OH)2 Mg3(PO4)2 + H2O
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