IPS_06_TE_U5_C1.qxp 12/18/06 10:28 PM Page 101 Activity 2 What is it? CHEMICAL INTERACTIONS Activity 2: What Is It? 1. Label each of the following statements as true (T) or false (F). A. Density is the volume of equal masses of substances. B. Different substances melt and boil at the same temperature. C. You must observe or measure many properties of two unknown substances to decide whether they are really the same or different. D. Properties like electrical conductivity, density, and melting temperature are more useful for identifying unknown substances than properties like shape, mass, volume, and texture. (Questions 2-6) Use the Table of Densities and the Table of Melting and Boiling Points at the back of the book. 2. What gas is transparent, colorless and odorless; turns BTB yellow; does not burn; dissolves in water; boils and condenses at a temperature of –78ºC; and has a density of 1.84 g for each liter? 3. What gas is transparent, colorless and odorless; does not interact with BTB; does not burn; boils and condenses at a temperature of –269ºC; and has a density of 0.18 g for each liter? 5. Which has a greater mass, a liter of copper or a liter of tin? 6. Imagine that you have three unknown substances: A, B, and C. The three substances are solids consisting of small, white grains. These unknowns have two additional properties shown in the data table below. Table 2: Properties of Three Unknown Solids Unknown A Unknown B Unknown C Solid, white, small grains Solid, white, small grains Solid, white, small grains 1 L has a mass of 2650 g 1 L has a mass of 1980 g 1 L has a mass of 1680 g 1610ºC 776ºC 150ºC 2. Density 3. Melting point 1. a) False. Density is the mass of equal volumes of substances. b) True. c) False. The first property tested may indicate that the substances are different. d) True. 2. carbon dioxide 3. helium 4. Sugar (MP = 185˚C) melts at a higher temperature than ice (MP = 0˚C). 6. a) Solid A is sand (silicon dioxide) because it is the only solid listed in the Table of Melting and Boiling Points with a melting point of 1610˚C. (The density of a liter having a mass of 2650 g is not listed in the Table of Densities, so you must use the melting point to identify this solid.) Identify the three unknown solids. Justify your answers. 1. Sense properties Activity 2 Practice 5. A liter of copper (mass = 8930 g) has a higher mass than a liter of tin (mass = 5750 g). 4. Which substance melts at a higher temperature, ice (solid water) or sugar? Property 5 Unit 5 • Chapter 1 443 b) Solid B is potassium chloride because it is the only solid listed in the Table of Melting and Boiling Points with a melting point of 776˚C. (The density of a liter having a mass of 1980 g is not listed in the Table of Densities, so you must use the melting point to identify this solid.) © It’s About Time c) Solid C is Epsom Salts (magnesium sulfate) because it is the only solid listed in the Table of Melting and Boiling Points with a melting point of 150˚C. (The density of a liter having a mass of 1680 g is not listed in the Table of Densities, so you must use the melting point to identify this solid.) InterActions in Physical Science 101 PRACTICES—ANSWERS MATERIALS AND THEIR INTERACTIONS IPS_06_TE_U5_C1.qxp 12/18/06 10:28 PM Page 102 CHAPTER 1 CHEMICAL INTERACTIONS Activity 3 Practice 1. Since the initial substances were both liquid solutions, the appearance of a white solid in a different phase (at room temperature) is good evidence for a chemical reaction. Activity 3: What’s the Evidence? The White Solid (Questions 1-2) In Unit 4 Chapter 2, Activity 2 you mixed a sodium sulfate solution with a calcium chloride solution. You observed a white solid appearing in the beaker. 20 mL of calcium chloride 20 mL of sodium sulfate 2. Sodium sulfate reacts with calcium chloride to produce calcium sulfate and sodium chloride. XLT XLT RESET 3. Since the initial substance was a solid that does not dissolve in water, and the ending substances were a gas (different phase) and a white powder that dissolves in water, the differing properties of these ending substances are good evidence for a chemical reaction. START MASS RESET END MASS 1. Explain why the appearance of the white solid is good evidence for a chemical reaction. The products of this reaction are calcium sulfate and sodium chloride. Calcium sulfate does not dissolve in water, so it appears as a white solid. Sodium chloride is the chemical name for the salt you sprinkle on your food. This salt stays dissolved in the water. 2. Complete the following one-sentence description of this chemical reaction. Sodium sulfate reacts with ________ to produce ________ and ________. Heating Seashells 4. The reactant is calcium carbonate; the products are calcium oxide and carbon dioxide. (Questions 3-5) Seashells are mostly made of the substance called calcium carbonate. When seashells are heated, a gas is released leaving a white powder behind. This powder dissolves in water. 5. Calcium carbonate breaks down (decomposes) into calcium oxide and carbon dioxide. 3. What is the evidence that heating seashells results in a chemical interaction? Chemists have tested and identified the white powder and the gas. The white powder is calcium oxide and the gas is carbon dioxide. 4. What is the reactant in this chemical reaction? What are the products? 5. Complete the following one-sentence description of this chemical reaction. ________ breaks down (decomposes) into ________ and ________. InterActions in Physical Science © It’s About Time 444 102 UNIT 5: MATERIALS AND THEIR INTERACTIONS IPS_06_TE_U5_C1.qxp 12/13/06 2:45 AM Page 103 Activity 4 Acid, Base, or Neutral? CHEMICAL INTERACTIONS Activity 4: Acid, Base, or Neutral? 1. Bromothymol blue (BTB) and litmus paper are examples of a) indicators b) strong acid c) strong base d) neutral salt 2. Indicators a) are solutions with a red, blue, or yellow color. b) form a yellow solid when they react with bases. c) change color in an acide or base. d) smell unpleasant when added to an acid. 3. How can you tell whether a food might contain an acid or a base as one of its ingredients? 4. Suppose you added a nitric acid solution to a potassium hydroxide solution (a base). What are the products of this acid-base (neutralization) reaction? blue litmus paper Write a one-sentence description of this chemical reaction. (Questions 5-6) Acids turn blue litmus paper red, but they have no effect on red litmus paper. Bases turn red litmus paper blue, but they have no effect on the blue litmus paper. Neutral substances show no effect on either red litmus paper or blue litmus paper (other than making the paper wet). acid red litmus paper 6. Blue litmus paper does not change color in an unknown substance. Is the unknown substance an acid, neutral, base, or is it impossible to tell? Explain your reasoning. The pH scale of the strength of acids and bases Milk of Magnesia apples tomatoes milk ACID 0 gastric juice 1 2 lemon juice 3 4 orange juice 5 6 clean rain NEUTRAL 7 8 9 baking soda milk of magnesia 10 11 household ammonia 2. (c) Indicators change color in an acid or base. 3. If the food is a solid, you can try dissolving it in water and drop the solution into bromothymol blue and yellow, or use an electronic pH meter. If the food does not dissolve, just wet it a little with some water, and lay some litmus or Universalindicator paper on the moistened food. 6. Even though you know the substance is not an acid because it did not turn blue litmus paper red, you can’t tell if it is neutral or a base. oven cleaner 12 1. (a) Bromothynol Blue (BTB) and litmus paper are examples of indicators. 5. The substance is a base, because it turned red litmus paper blue. (Questions 7-9) Use the pH scale below to answer the questions. sea water Activity 4 Practice 4. In this neutralization reaction, nitric acid (acid) reacts with potassium hydroxide (base) to produce potassium nitrate (a neutral salt) and water (neutral). base 5. Red litmus paper turns blue in an unknown substance. Is the unknown substance an acid, neutral, base, or is it impossible to tell? Explain your reasoning. battery acid 5 BASE 13 14 drain opener ORANGE ORANGE JUICE JUICE Baking Soda 7. Bananas are acidic, because their pH number is lower than 7. 7. Bananas have a pH of about 5.1. Is a banana acidic, neutral, or basic? Explain your answer. 8. This cola is acidic, because its pH number is lower than 7. 8. A brand of cola has a pH of 2.4. Is this brand of cola acidic, neutral, or basic? Explain your answer. 9. Which is the strongest base: baking soda, drain cleaner, household ammonia, or milk of magnesia? Explain your answer. 445 9. Drain cleaner (pH of about 13.5) is the strongest base among household ammonia (pH of 11), milk of magnesia (pH of 10.5), and baking soda (pH of 8.5). © It’s About Time Unit 5 • Chapter 1 InterActions in Physical Science 103 PRACTICES—ANSWERS MATERIALS AND THEIR INTERACTIONS IPS_06_TE_U5_C1.qxp 12/18/06 10:31 PM Page 104 CHAPTER 1 CHEMICAL INTERACTIONS Activity 5 Practice 1. a) Activity 5: The Burning Reaction 2. d) 3. The reactants are glucose and oxygen; the products are carbon dioxide and water. Multiple Choice 1. Which of the following is always a reactant in a burning reaction? a) oxygen b) soot 4. Glucose + oxygen ➞ carbon dioxide + water c) carbon dioxide d) water 5. Both burning methane and cellular respiration (involving glucose) have oxygen as a reactant and form the products carbon dioxide and water. 2. Which of the following is always a product in a burning reaction? 6. The reactants are lemon juice and amines; the products are a salt and water. The rapid burning of fuel helps you survive cold weather, provides you with electricity, and helps you move rapidly from place to place. But there is a slow interaction involving oxygen that is even more important to your life. Your body is made up of several hundred million cells. Where does the energy come from to make each of your cells work? The energy comes from a chemical reaction involving oxygen. In each of your cells, the sugar glucose combines with oxygen to produce carbon dioxide and water, and releases energy for the cell. This process is called cellular respiration. a) carbon monoxide b) oxygen c) fuel d) water Cellular Respiration 7. Lemon juice + amines ➞ salt + water 3. What are the reactants of this chemical reaction? What are the products? 4. Write a word chemical equation for this reaction. 5. What is similar about burning methane and cellular respiration? A Fishy Story You know that citric fruit juices, including lemon juice, are acidic. Fish oils contain dissolved bases called amines (uh-MEENS]. Amines do not smell good, but most people think lemon juice smells good. Here is a practical example of an acid-base interaction. lemon juice amines no fishy odor 6. What are the reactants? What are the products? (Hint: In Activity 4, you learned the products of all acid-base reactions.) 7. Write a word chemical equation for this chemical interaction. InterActions in Physical Science © It’s About Time 446 104 UNIT 5: MATERIALS AND THEIR INTERACTIONS IPS_06_TE_U5_C1.qxp 12/18/06 10:31 PM Page 105 Activity 6 Chemical Reactions and Mass CHEMICAL INTERACTIONS Activity 6: Chemical Reactions and Mass Food for Plants Where do you and other animals get the food you need to live and grow? From plants! Green plants, algae, and some bacteria are the only organisms that make their own food. The series of chemical reactions that makes food in plant leaves is called photosynthesis (foht-OH-sinh-thuh-sihs). Plants use water from the roots and carbon dioxide from the air to make a sugar called glucose. This reaction also produces oxygen, which is released into the air. Basic Photosynthesis 1. Write a word chemical equation for the photosynthesis reaction. light energy oxygen 2. How does the mass of the reactants compare to the mass of the products? Justify your answer. sugar carbon dioxide Many people add liquid or solid “plant food” to their garden and houseplants. But plant food is not really food for plants. Plants make their own food — the sugar, glucose. Plant foods contain substances such as nitrogen, potassium, phosphorus, and sulfur, that plants need for healthy growth. water Instant Hot Packs wrapper and pad Chemical Interaction XLT RESET START MASS XLT rusting RESET Activity 6 Practice 1. Water + carbon dioxide ➞ glucose + oxygen 2. If you consider the system to be the plant, this is an open system for mass, with both mass inputs (water and carbon dioxide) and a mass output (oxygen). So, we cannot compare the mass of the reactants with the mass of the products without knowing the actual values of the mass inputs and outputs. 3. The rusting of iron reaction requires oxygen as a reactant, so the pad with iron must be removed from the sealed wrapper and exposed to the oxygen in air for the reaction to occur. 4. The system of the wrapper and pad is an open system for mass because the reactant oxygen has to come in from outside the system. Since the product rust remains in the system, this system only has a mass input. Thus, the mass of the wrapper and pad after several hours will be greater than the mass before opening. Have you ever used an instant “hot pack” to reduce muscle pain or to keep your hands warm in the winter? One type of hand warmer comes in a sealed wrapper. Inside the wrapper is a soft mesh, cloth pad, which contains fine iron powder. The iron rusting reaction lets the hand warmer stay at temperatures above 60ºC for several hours. unopened 5 PRACTICES—ANSWERS MATERIALS AND THEIR INTERACTIONS END MASS 3. Why do you have to open the sealed wrapper and take out the pad to start the rusting reaction and the transfer of energy? (Hint: What is the other reactant in the rusting reaction?) 4. Is the mass of the wrapper and pad after the pad has been removed for several hours greater than, less than, or equal to the mass of the wrapper and pad before it was opened? Justify your answer. 447 © It’s About Time Unit 5 • Chapter 1 InterActions in Physical Science 105 IPS_06_TE_U5_C1.qxp 12/18/06 10:31 PM Page 106 CHAPTER 1 CHEMICAL INTERACTIONS Activity 7 Practice 1. The heating of seashells (calcium carbonate) to produce carbon dioxide gas and calcium oxide is an endothermic reaction because the calcium carbonate needs to absorb (receive from surroundings) energy for the reaction to occur. Activity 7: Energy and Reactions Heating Seashells In the Practice for Activity 3, you learned that when seashells (calcium carbonate) are heated, carbon dioxide gas is released, leaving solid calcium oxide. If you stop heating the seashells, then the reaction stops. 1. Is this an exothermic reaction (that produces energy) or an endothermic reaction (that absorbs energy)? Justify your answer. 2. Draw an energy diagram for this reaction. 2. Source Photosynthesis Receiver Surrounding Objects Energy transfer Have you ever tried to grow a plant in a dark room or closet? The plant shrivels up and dies. Without sunlight, the plant cannot make its own food (the sugar glucose) in the photosynthesis reaction (see the Practice for Activity 6). System Reactant (calcium carbonate) and products (carbon dioxide and calcium oxide) 3. Is photosynthesis an exothermic reaction or an endothermic reaction? Justify your answer. increases in stored chemical energy 4. Draw an energy diagram of the photosynthesis reaction. 3. The photosynthesis reaction is endothermic because it requires light energy from the sun to produce its food, glucose. 4. Inside a Car Engine Source Surrounding Objects Four-fifths of the air is nitrogen, which usually does not take part in chemical reactions. But at the very high temperatures inside a car engine, the nitrogen reacts with oxygen to produce the poisonous gas, nitrogen oxide. The stored chemical energy of the reactants (nitrogen and oxygen) is greater than the stored chemical energy of the product (nitrogen oxide). Receiver Energy transfer Nitrogen reacts with oxygen to produce nitrogen monoxide System Reactants (water and carbon dioxide) and products (glucose and oxygen) increases in stored chemical energy 5. Is this an exothermic reaction or an endothermic reaction? Justify your answer. (Hint: Use the reactant-product diagrams in the activity.) 6. Draw an energy diagram of the photosynthesis reaction. 5. The reaction inside the car engine is exothermic. My reason is that the stored chemical energy of the reactants is greater than that of the products, so energy must have been transferred (output) from the system to the surroundings. 448 InterActions in Physical Science 6. Source System Reactants (nitrogen and oxygen) and product (nitrogen oxide) Receiver Energy transfer Surrounding Objects © It’s About Time decreases in stored chemical energy 106 UNIT 5: MATERIALS AND THEIR INTERACTIONS IPS_06_TE_U5_C1.qxp 12/18/06 10:31 PM Page 107 Activity 8 Describing Substances and Chemical Interactions 5 CHEMICAL INTERACTIONS Activity 8: Describing Substances and Chemical Interactions Multiple Choice 1. Which of the following is a chemical property of a substance? a) It is a gas at room temperature. b) It is flammable (it burns). c) It has a density of 1.33 g/L of the gas. d) It melts at a temperature of 218°C. 2. When a fuel (e.g., a candle, wood, or gasoline) reacts with the oxygen in the air, the products are a) a neutral salt and water. b) the sugar, glucose and water. c) calcium carbonate and water. d) carbon dioxide and water. PRACTICES—ANSWERS MATERIALS AND THEIR INTERACTIONS Activity 8 Practice 1. b) 2. d) 3. a) 4. c) 5. d) 6. d) 3. When an acid reacts with a base, one of the products is a) a salt. b) an indicator. c) oxygen. d) carbon dioxide. 4. In an exothermic reaction, the stored chemical energy of the reactants is a) lower than the stored chemical energy of the products. b) the same as the stored chemical energy of the products. c) greater than the stored chemical energy of the products. d) There is not enough information to tell. 5. When you mix hydrochloric acid with sodium hydroxide, two new substances are produced: water and sodium chloride. Which of the following is the word chemical equation for this reaction. a) sodium chloride hydrochloric acid → water sodium hydroxide b) sodium hydroxide → hydrochloric acid sodium chloride water c) sodium chloride hydrochloric acid → water sodium hydroxide d) sodium hydroxide hydrochloric acid → sodium chloride water 6. The pH scale indicates a) the color an indicator changes in acids or bases. b) the strength of an indicator. c) whether the acid or base is a solid, liquid, or gas. d) the strength of an acid or base. 449 © It’s About Time Unit 5 • Chapter 1 InterActions in Physical Science 107 IPS_06_TE_U5_C1.qxp 12/18/06 10:31 PM Page 108 CHAPTER 1 CHEMICAL INTERACTIONS Activity 9 Practice First Chemical Reaction: 1. Coke + oxygen ➞ carbon dioxide Activity 9: Analyze and Explain 2. iron ore and coke Source Receiver System Reactants (coke and oxygen) and product (carbon dioxide) Blast Furnace exhaust gases Surrounding Objects Energy transfer One source of iron metal is the ore called hematite (iron oxide). To obtain the iron from the hematite (iron oxide), the hematite is heated with coke (a form of carbon) in a blast furnace. The furnace is a large steel structure about 30 m high. It is lined with firebricks. A mixture of the iron ore and coke is poured into the top of the furnace. You will analyze the series of chemical reactions for obtaining iron from hematite. First Chemical Reaction: The coke (carbon) falls to the bottom of the furnace to the level where the hot air blast (about 850ºC) enters the furnace. The coke reacts with the oxygen in the air to make carbon dioxide. decreases in stored chemical energy hot air blast molten slag Second Chemical Reaction: hot air blast molten iron 1. Write a word chemical equation for this reaction. 2. This reaction is exothermic. It raises the temperature of the blast furnace to about 2000ºC. Draw an energy diagram for this reaction. Second Chemical Reaction: As the carbon dioxide rises in the furnace, it reacts with more coke (carbon) to produce the poisonous gas, carbon monoxide. 3. Coke + carbon dioxide ➞ carbon monoxide 3. Write a word chemical equation for this reaction. 4. 4. This reaction is endothermic. Draw an energy diagram for this reaction. Source Surrounding Objects Third Chemical Reaction: Finally, the iron oxide reacts with the carbon monoxide gas to produce the metal iron and carbon dioxide gas. Receiver Energy transfer 5. Write a word chemical equation for this reaction. System Reactants (coke and carbon dioxide) and products (carbon monoxide) 6. The stored chemical energy of the products is greater than the stored chemical energy of the reactants. Is this reaction exothermic or endothermic? Justify your answer. The iron, which is molten at the high blast furnace temperature, trickles down to the base of the blast furnace, where it is removed. The iron is cooled and solidifies into pig iron or is transferred directly to a steel-producing furnace. The waste impurities form a molten liquid is called slag. When the slag is removed and cooled, it solidifies and can be used in road building. increases in stored chemical energy Third Chemical Reaction: 5. iron oxide + carbon monoxide ➞ iron + carbon dioxide Three forms of iron ore (hematite). 450 InterActions in Physical Science © It’s About Time 6. The reaction is endothermic. My evidence is the stored chemical energy of the products is greater than the stored chemical energy of the reactants, so energy must have been transferred (input) from the surroundings to the system. 108 UNIT 5: MATERIALS AND THEIR INTERACTIONS IPS_06_TE_U5_C1.qxp 12/13/06 2:45 AM Page 109 SCIENTISTS’ CONSENSUS IDEAS—ANSWERS Scientists’ Consensus Ideas UNIT 5 CHAPTER 1 Answer Keys Idea 1. Materials and Properties 1. a. Chemists describe materials by their properties. A property of a material is a description of how the material interacts with other things, like our senses or instruments that extend our senses.) b. Different materials are identified by a unique set of properties. c. Characteristic properties are more useful for identifying unknown substances than properties like shape, mass, volume, or texture. Examples of Characteristic Properties: Density, melting and boiling points, electrical conductivity Idea 2. Chemical Properties 2. Chemical properties of a substance are descriptions or measurements of how a material interacts chemically with other materials. Examples of Chemical Properties: • Whether or not the substance supports burning • whether or not the substance itself burns (flammability, interaction with a flame) • interaction that makes the substance (what reactants are involved) • interaction with indicators (e.g., BTB, litmus paper) • measurement of pH number • reaction with some chemicals (e.g., water, acids, oxygen) Idea 3. Classifications of Materials Chemists find it useful to identify classes of substances with common properties 3. a. Acids taste sour, react with certain indicators to produce a new substance with a different color, react with certain metals to produce hydrogen gas, and react with a base to produce a neutral salt and water. (Act 4) © It’s About Time Examples of Some Acids: apple juice (malic acid), lemon juice (citric acid), orange juice (ascorbic acid or vitamin C), vinegar (acetic acid), battery (sulfuric) acid, gastric juice (hydrochloric acid) Examples of Some Indicators for Acids: BTB (turns yellow when reacted with an acid) blue litmus paper (turns red when reacted with an acid) universal-indicator paper or pH meter Examples of Some Metals That React With Acids: magnesium, aluminum, iron, zinc InterActions in Physical Science 109 IPS_06_TE_U5_C1.qxp 12/13/06 2:45 AM Page 110 b. Bases taste bitter, feel slippery, react with certain indicators to produce a new substance with a different color, do not react with metals, and react with acids to produce a neutral salt and water (U5C1 Act 4) Examples of Some Bases: baking soda (sodium bicarbonate), window cleaner (ammonia), tonic water (quinine), drain opener (sodium hydroxide), milk of magnesia (magnesium hydroxide), calcium oxide (lime), calcium hydroxide (slaked lime) Examples of Some Indicators for Bases: bromothymol yellow (turns blue when reacted with a base) red litmus paper (turns blue when reacted with a base) universal-indicator paper or pH meter (indicates a pH number) c. Neutral substances are neither acids nor bases. They usually do not change the color of acid-base indicators. (U5C1 Act 4) Examples of Some Neutral Substances: Distilled water, sugar, salt, milk, alcohols, many fuels d. Salts are neutral substances that are one of the products of an acid-base (neutralization) chemical reaction. (U5C1 Act 4) Examples of Some Salts: Sodium acetate, potassium chloride, sodium chloride (table salt), Epsom salt (magnesium sulfate) e. Fuels are substances that release large amounts of heat energy when they burn (react with oxygen). (U5C1 Act 4) Examples of Some Fuels: © It’s About Time Kerosene, gasoline, jet fuel, methanol 110 UNIT 5: MATERIALS AND THEIR INTERACTIONS IPS_06_TE_U5_C1.qxp 12/13/06 2:45 AM Page 111 DEFINING CHARACTERISTICS OF SCIENTISTS’ CONSENSUS IDEAS—ANSWERS Scientists’ Consensus Ideas UNIT 5 CHAPTER 1 Answer Keys CHEMICAL INTERACTIONS Idea 1. A chemical interaction is any type of interaction (such as mechanical, heat conduction, or electric current) that results in at least one new material. (Act. 3) Names of Common Chemical Interactions: baking, roasting, broiling, rotting, rusting, burning, exploding, digesting food, breaking-down, composting. Idea 2. The evidence of a chemical interaction is that the materials at the end of the interaction have a different set of properties than the original materials (before the interaction). Observations that can provide evidence of a chemical interaction include: A. The disappearance of one of the original materials. (Act. 2) Examples: crushed chalk and vinegar (some of the chalk dust disappears) baking soda and vinegar (some of the baking soda disappears) rusting (some of the oxygen in the air disappears) burning (some of the oxygen in the air disappears) compost (some of the decaying material disappears) B. The appearance of a material in a different phase (at room temperature). (Act. 3) Examples: crushed chalk and vinegar (a gas appears from a solid and a liquid) baking soda and vinegar (a gas appears from a solid and a liquid) milk and lemon juice (a white solid appears from two liquids) burning candle in a closed jar (water and black soot appears on the inside of the jar) C. Changes in other properties (e.g., color, odor, texture, density, hardness, size or shape, interaction with water (dissolves, does not dissolve) flammability (burns or does not burn in air), reaction with acid-base indicators, and so on). (Act. 3, Act. 5, Act. 6) Examples: © It’s About Time bubbling carbon dioxide through BTB solution changes its color to yellow crushed chalk and vinegar (an odorless, colorless gas appears from a odorless white solid and a smelly colorless liquid) match and air (a black solid appears from match’s red tip and light brown stem) bread dough and baked bread (The outside crust of the bread is harder and a darker brown color than the original bread dough. The baked bread is larger than the dough (change in size). The dough feels wet and sticky, is kind of elastic (you can stretch it), and is thick. The inside of baked bread is dry and not sticky, tears apart when you pull it, and has lots of holes (is not thick.) InterActions in Physical Science 111 IPS_06_TE_U5_C1.qxp 12/13/06 2:45 AM Page 112 Examples: Mixing vinegar and baking soda in a closed baggie: acetic acid mass + sodium bicarbonate mass ➝ carbon dioxide mass + sodium acetate mass + water mass Rusting iron in a sealed flask: iron mass + oxygen mass ➝ rust mass Idea 5. Chemical Reactions and the Conservation of Energy A. Once started, all chemical reactions either produce energy–continually transfer energy out of the system of interacting substances to the surrounding objects or absorb energy–require a continual transfer of energy into the system of interacting substances. Chemists call reactions that produce (release) energy exothermic. All reactions that absorb energy Exothermic (require continual energy input) are called endothermic. chemical energy of the reactants is greater than the stored chemical energy of the products. So for energy to be conserved, energy is transferred out of the system and the stored chemical energy of the system decreases Reactants decrease stored chemical energy B. A chemical reaction is exothermic (produces energy) when the stored Products Examples of Exothermic Reactions: • burning methane gas System Reactant and Product Substances Energy transfer Energy Output Surrounding Objects • rusting iron • reaction of nitrogen and oxygen in hot car engine decrease in stored chemical energy chemical energy of the products is greater than the stored chemical energy of the reactants. So for energy to be conserved, energy is transferred into the system and the stored chemical energy of the system increases. Surrounding Objects Energy transfer Products Energy Output increase C. A chemical reaction is endothermic (absorbs energy) when the stored stored chemical energy Endothermic Reactants System Reactant and Product Substances Examples of Endothermic Reactions: • baking soda (sodium bicarbonate) and vinegar (acetic acid) • (video of reacting) barium hydroxide and ammonium thiocyanate • photosynthesis • heating sea shells (calcium carbonate) 112 UNIT 5: MATERIALS AND THEIR INTERACTIONS © It’s About Time increase in stored chemical energy IPS_06_TE_U5_C1.qxp 12/13/06 2:45 AM Page 113 SCIENTISTS’ CONSENSUS IDEAS—ANSWERS © It’s About Time NOTES InterActions in Physical Science 113
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