Higher Performance Capacity Through the Use of Coatings Coated rolling bearings and precision components Contents Coating systems and their areas of application Coatings · Overview 1 Main function Anti-corrosion protection and fretting corrosion 2 Main function Anti-wear protection / friction reduction 3 Main function Current insulation 4 Main function Surfaces subjected to high tribomechanical stresses 1 Main function – Anti-corrosion protection and fretting corrosion Corrotect ® coating systems: Corrotect ® thin layer coating (zinc-iron alloy) Corrotect ® ZI (zinc-iron alloy) Corrotect ® ZN (zinc-nickel alloy) Corrotect ® ZK (zinc, electroplated) Corrotect ® ZF (zinc, lamellar coating) 2 3 3 4 5 5 6 7 8 8 9 2 Main function – Anti-wear protection / friction reduction Durotect ® coating systems: Durotect ® B (mixed iron oxide) 10 Durotect ® Z (zinc phosphate) 11 Durotect ® M (manganese phosphate) 12 Durotect ® CK (columnar hard chromium coating) 13 Durotect ® CK + (columnar hard chromium coating + anti-friction coating) 14 Durotect ® CM (microcracked hard chromium coating) 15 Durotect ® NP (nickel-phosphorus coating) 16 Durotect ® C (copper) and Durotect ® S (silver) 17 Durotect ® HA (hard anodising) 17 Durotect ® polymer-based coating systems: Durotect ® P (polymer-based coating) 18 3 Main function – Current insulation Insutect ® coating system: Insutect ® A (aluminium oxide) 19 4 Main function – Surfaces subjected to high tribomechanical stresses Triondur ® coating systems: Triondur ® C (metal-doped carbon coating) 20 Triondur ® C + / CX + (amorphous carbon coating) 21 Triondur ® CH (hydrogen-free amorphous carbon coating) 21 Triondur ® CN (chromium nitride) 22 Triondur ® CNN (chromium carbonitride) 22 Triondur ® TN (titanium nitride) 23 Coating systems and their areas of application Anti-corrosion protection Corrotect® HA (AI) Corrotect® A*, C, F Corrotect® N*, P, T Durotect® ZK Corrotect® ZI Corrotect® ZN Durotect® ZF Anti-wear protection Durotect® NP Insutect® A Durotect® CK Durotect® CM Triondur® TN Durotect® P Durotect® CK* Triondur® CX+ Triondur® C, C+ Triondur® CN, CH Insulation Insutect® A Durotect® B Durotect® M Durotect® Z Durotect® C Durotect® S Durotect® P Friction reduction 2 Coatings · Overview Bearings and precision components from the Schaeffler Group offer high performance capacity and a long operating life. They provide the user with thoroughly developed and economical solutions for the large majority of requirements. The characteristics of the components can be expanded by the use of suitable coating systems, thus offering the customer advantages in the application. The Schaeffler modular coating concept allows a dedicated solution for the customer with the coating as a design element. Through the prevention of corrosion and wear, Schaeffler coating systems contribute to the conservation of resources, since the operating life of the components is extended significantly. By reducing friction, the coatings contribute to energy efficiency in the form of reduced energy consumption. The coating systems are applied to the surface by a wide variety of methods. They should always be individually matched to the mounting situation. In many cases it is sufficient to coat only one of the components in rolling contact or only a part thereof. This Technical Information gives an overview of the coatings used at Schaeffler, arranged according to the main areas of application. The features, advantages and benefits are given for each type of coating. Specific examples and references are shown. Further information: [email protected] 1 Main function: Anti-corrosion protection – Corrotect ® coating systems Designation Coating system Comment Suffix Main functions Anti-corrosion Anti-wear protection protection Corrotect® A* Zinc alloy CT001 X – Corrotect® N* CT004 X – Corrotect® ZK Zinc CT010 – CT013 Zinc-iron CT020 – CT023 Zinc-nickel CT030 – CT033 Zinc lamellae CT100 X Corrotect® ZI Corrotect® ZN Corrotect® ZF Friction reduction Additional Main area of application function Special feature Automotive, belt drives, selector shafts, bearings, bearing components, Cr(VI)-free Automotive, belt drives, detents, Cr(VI)-free Simple anti-corrosion applications X – Industrial, Automotive, belt drives, bearing components, screws X – X – Industrial, Automotive, belt drives, bearing components, screws Industrial, Automotive, chassis engineering, components, screws 3 Coatings ∙ Overview 2 Main function: Anti-wear protection and friction reduction – Durotect ® coating systems Comment Suffix Durotect® B Mixed iron oxide CT240 X Durotect® Z Zinc phosphate CT250 – CT251 X Durotect® M Manganese phosphate CT260 – CT261 X Durotect® CK Columnar hard chromium coating CT230 Durotect® CK+ Columnar hard chromium coating plus mixed chromium oxide CT231 Durotect® CM Microcracked hard chromium coating CT220 – CT224 Durotect® NP Chemical nickel CT200 – CT205 Durotect® C Copper CT270 Silver CT271 Durotect® S Durotect® HA Durotect® P 4 Main functions Anti-corrosion Anti-wear Friction protection reduction protection Designation Coating system Hard anodising (Al) Polymer-based coating CT700 – CT702 X X X X Additional function Main area of application Special feature Improved running-in behaviour, reduced slippage damage, slight anti-corrosion protection Temporary anti- Industrial, Automotive, bearing components, wind energy, full complement roller bearings corrosion protection, protection against fretting corrosion, suitable for sliding seats Improved runningin behaviour, slight anti-corrosion protection, emergency running lubrication Anti-corrosion protection, slight reduction in friction, reduced fretting corrosion Industrial, Aerospace, linear guidance systems, bearings, bearing components Industrial, Automotive, Aerospace, bearing components Industrial, Linear Technology, Aerospace, vibratory screen bearings, helicopter bearings, spindle bearings Additionally good anti-corrosion protection Industrial, bearing components, linear technology X Slight anticorrosion protection, slight reduction in friction Industrial, needle roller bearings X – Industrial, drawn cups, guide ring segments Industrial, cages X X X Emergency running lubrication X Emergency running lubrication X X Current insulation Protection against fretting corrosion Reduction in friction Industrial, Aerospace, linear guidance systems, bearing components, cages Automotive, sliding sleeves Industrial, bearing rings Coatings ∙ Overview 3 Main function: Current insulation – Insutect ® coating systems Designation Coating system Comment Suffix Insutect® A Aluminium oxide Main functions Anti-corrosion Anti-wear protection protection Main area of application Special feature Friction reduction Main function Current insulation Industrial, rail vehicles, electric motors, generators 4 Main function: Surfaces subjected to high tribomechanical stresses – Triondur ® coating systems Additional function Main area of application Special feature X – Automotive, valve train components X X – X X Reduced slippage damage Automotive, valve train components Industrial, Automotive, bearing components, engine components a-C:H CT450 –CT479 X X – Triondur® CX+ a-C:H:X CT480 – CT509 X X Minimal friction in valve train Triondur® TN TiN CT415 – CT419 X Triondur® CH ta-C CT520 – CT529 X Main functions Anti-corrosion Anti-wear protection protection Designation Coating system Comment Suffix Triondur® CN CrxN CT400 – CT404 CrN/CrC CT405 – CT409 a-C:H:Me CT420 X Triondur® C+ Triondur® CNN Triondur® C Friction reduction – Industrial, Automotive, engine components, bearing components Automotive, valve train components, bearing components Aerospace, bearing components, rib surfaces Automotive 5 1 Main function: – Anti-corrosion protection Corrotect ® thin layer coating (zinc-iron alloy) Features Colour: dependent on post-treatment A*: iridescent silver - Cr(VI)-free N*: silver, slightly iridescent - Cr(VI)-free Coating structure Zinc-iron coating with passivation A*/N* Layer thickness 0,5 – 3 μm or 2 – 5 μm. A* = thick layer passivation N* = nanoparticle-based passivation Advantages/benefits • Anti-corrosion protection, 48 – 360 hours against red rust formation (depending on design type) in accordance with salt spray test to DIN EN ISO 9227. • Economical cathodic anti-corrosion protection. • Thin layer coating technology allows complete bearing coating without taking account of tolerances. Applications • Various bearings, bearing components and bearing adjacent parts with requirement for increased corrosion resistance, e. g. bearing inner rings / outer rings / rolling elements; drawn cup needle roller bearings and thin-walled components in large quantities, e.g. detent sleeves. 6 1 Main function: – Anti-corrosion protection Corrotect ® ZI (zinc-iron alloy) Features Colour: dependent on post-treatment A*: iridescent silver - Cr(VI)-free N*: silver, slightly iridescent - Cr(VI)-free Coating structure Zinc-iron coating with passivation A*/N* Layer thickness Dependent on requirement, 5 μm or more. A* = thick layer passivation N* = nanoparticle-based passivation Advantages/benefits • Anti-corrosion protection, 120 – 600 hours against red rust formation (depending on design type) in accordance with salt spray test to DIN EN ISO 9227. • Economical cathodic anti-corrosion protection. Applications • Automotive and industrial components with requirement for increased anti-corrosion protection • Large size bearings in rolling mill sector. 7 1 Main function: – Anti-corrosion protection Corrotect ® ZN (zinc-nickel alloy) Features Colour: dependent on post-treatment, preferably with thick layer passivation A* silver, at some points slightly iridescent yellow; Cr(VI)-free Coating structure Zinc-nickel coating with thick layer passivation A*. Layer thickness Dependent on requirement, 2 μm or more. Advantages/benefits • Anti-corrosion protection, 360 – 720 hours against red rust formation (depending on design type) in accordance with salt spray test to DIN EN ISO 9227. • High quality cathodic anti-corrosion protection. Applications • Automotive and industrial components with requirement for very high anti-corrosion protection, such as joint and detent bushes, bearing pins, mechanical levers, etc. Corrotect ® ZK (zinc, electroplated) Features Colour: dependent on post-treatment, preferably with thick layer passivation A* silver, at some points slightly iridescent yellow; Cr(VI)-free Layer thickness Dependent on requirement, 5 μm or more. Advantages/benefits • Anti-corrosion protection, 24 – 360 hours against red rust formation (depending on design type) in accordance with salt spray test to DIN EN ISO 9227. Applications • Simple adjacent parts. 8 1 Main function: – Anti-corrosion protection Corrotect ® ZF (zinc lamellar coating) Features Colour: silver-grey Coating structure Soft zinc lamellar coating, partially cathodic, paint-type anti-corrosion protection. Layer thickness 8 – 15 μm Advantages/benefits • Anti-corrosion protection, up to 720 hours against red rust formation (salt spray test to DIN EN ISO 9227). Applications • Principally automotive sector: wheel bearings, sensor and intermediate rings, screws. 9 2 Main function – Anti-wear protection / friction reduction Durotect ® B (mixed iron oxide) Features (dependent on material) Colour: dark brown to deep black Coating structure Coating comprising mixed iron oxides. Layer thickness 0,5 – 2 μm. Advantages/benefits • Improvement in running-in behaviour of bearings • Favourable under low risk of slippage. Applications • Rolling elements and rings for bearings in wind turbines and railway drive bearings • Full complement cylindrical roller bearings • Ball bearings under poor lubrication conditions. 10 2 Main function – Anti-wear protection / friction reduction Durotect ® Z (zinc phosphate) Features Colour: grey/black Coating structure Zinc phosphate Layer thickness 1 – 10 μm Advantages/benefits • Anti-corrosion protection in oiled condition, up to 48 hours against red rust formation (salt spray test to DIN EN ISO 9227). • Prevention of fretting corrosion in the bearing seat • Friction reduction promotes displacement effect. Applications • Tapered roller bearings in rail vehicles • Large bearings – paper industry • Expander roller eccentric bearings • Rolling bearing cages and drawn cups. 11 2 Main function – Anti-wear protection / friction reduction Durotect ® M (manganese phosphate) Features Colour: matt dark grey Coating structure Manganese phosphate Layer thickness 1 – 10 μm Advantages/benefits • Improvement in sliding and running-in behaviour. Applications • Roller coating in bearings in mixer gearboxes • Sheet steel cages • Adapter and withdrawal sleeves • Inner ring bores in crankshaft bearings • Primary layer for anti-friction paints. 12 2 Main function – Anti-wear protection / friction reduction Durotect ® CK (columnar hard chromium coating) Features Colour: matt grey Coating structure Chromium coating with columnar surface surface. Layer thickness Functional surfaces: Secondary surfaces: 1 – 3 μm 1 – 6 μm. Hardness: approx. 1 000 HV. Advantages/benefits • High wear resistance (high hardness) especially at the axial contact running points or on fit surfaces where fretting corrosion is expected • Effective anti-wear protection under mixed friction for small ball or roller bearings • Low friction factors under mixed friction due to smoothing of the pearly structure after the running-in process • Reduced friction factors allow unconstrained displacements in non-locating bearings • Corrosion resistance approx. 5 times higher compared with rolling bearing steel (salt spray test to DIN EN ISO 9227). Applications • Raceways in high precision bearings • Outside diameter of spindle bearings • Complete coating of spherical roller bearings (rings, rolling elements) running in corrosive environments • Bore of vibratory screen bearings against fretting corrosion / vibratory wear • Ball bearing rings for swash plates in helicopters • Linear components. 13 2 Main function – Anti-wear protection / friction reduction Durotect ® CK + (columnar hard chromium coating + + anti-friction coating) Features Colour: black Coating structure Smooth upper layer comprising mixed chromium oxide on columnar chromium layer. Layer thickness As Durotect ® CK plus 0,5 – 3 μm Hardness: approx. 1 000 HV; the covering layer is soft and malleable under load. Advantages/benefits • Improved running-in behaviour • Improved friction and wear behaviour under lubricant starvation (the depressions between the chromium pearls act as a “lubricant reservoir“ for the chromium oxide). • Extension of maintenance intervals in rail transport When the bearings are used in aggressive atmospheres and at high temperatures, the thick layer acts in a supporting role to the lubricant compared with pure thin layer chromium plating and increases the corrosion resistance. Due to mechanical load, the soft thick layer is compacted into the pearly structure. The resulting grey functional layer reveals the base layer Durotect ® CK. Applications • Traction motor bearings in rail vehicles • Back-up rollers for multi-roll cold rolling mills • Linear components. 14 2 Main function – Anti-wear protection / friction reduction Durotect ® CM (microcracked hard chromium coating) Features Colour: lustrous silver, replicates subsurface structure Coating structure Smooth, microcracked hard chromium coating. Layer thicknesses 0,1 – 500 μm, depending on the application (suitable for mechanical processing). Hardness: approx. 850 – 1 100 HV. Advantages/benefits • Improved friction and wear behaviour under lubricant starvation • Increased life due to hard surfaces as anti-wear protection • Good anti-corrosion protection and high resistance to many chemicals with coating thicknesses over 30 μm • Temperature resistance up to +300 °C • Protection against tribocorrosion • Low friction coefficient / good sliding characteristics • Anti-adhesive characteristics. Applications • Spherical plain bearing applications • Automotive and industrial products subjected to wear loads. 15 2 Main function – Anti-wear protection / friction reduction Durotect ® NP (nickel-phosphorus coating) Features Colour: metallic silver, slight yellow tinge Coating structure Chemically deposited nickel coating, with 8 – 15 % phosphorus in the alloy. Layer thickness Dependent on requirement For anti-corrosion protection 8 – 15 μm, 25 – 300 μm. Hardness 500 – 600 HV (increasable by heat treatment to 750 – 1 000 HV). Advantages/benefits • Coating true to contours of component, in some cases also in depressions • Combined characteristics of anti-wear protection and anti-corrosion protection allow a wide range of applications • High coating thicknesses give very good anti-corrosion protection characteristics • Suitable for mechanical processing in certain cases. Applications • Guide rings, spherical roller bearings • Spherical plain bearings • Housings for the food industry • Usage in fresh water/salt water applications. Special features Durotect ® NP can be dispersed by means of PTFE or hard material particles (diamond, SiC) in order to optimise the sliding characteristics or improve the wear resistance. 16 2 Main function – Anti-wear protection / friction reduction Durotect ® C (copper) and Durotect ® S (silver) Features Colour: copper-coloured or silver-coloured Coating structure Durotect ® C copper Durotect ® S silver with copper intermediate layer. Layer thickness Dependent on requirement, 2 – 50 μm. Advantages/benefits • Improvement in emergency running behaviour Applications • Sheet steel cages in two-stroke and four-stroke engines • Cages for aerospace applications. • Large size bearing cages Durotect ® HA (hard anodising) Features Colour: silver to mouse grey Coating structure Durotect ® HA, aluminium oxide layer. Layer thickness Dependent on requirement, 2 – 25 μm. Advantages/benefits • Increase in wear resistance of aluminium • Current insulation. Applications • Aluminium sliding sleeves in clutch bearings • Aluminium cages for aerospace applications. 17 2 Main function – Anti-wear protection / friction reduction Durotect ® P (polymer-based coating) Features Colour: dependent on coating system Coating structure Polymer-based coating Layer thickness 10 – 20 μm. Advantages/benefits • Improvement in sliding capacity on the bearing outer ring, reduction in the friction factor to < 0,1 under axial displacement of bearing rings. Applications • Quadropol mills for cement production (outer ring outside surface of spherical roller bearings) • Suction box rolls and thermo rolls in paper machinery (outer ring outside surface of spherical roller bearings) • Main rotor bearing arrangements – wind power. 18 3 Main function – Current insulation Insutect ® A (aluminium oxide) Features Colour: light grey to matt beige Coating structure Ceramic coating comprising aluminium oxide Al 2 O 3 with sealant. Layer thickness 100 – 200 μm, higher upon customer request. Advantages/benefits • Current insulation according to coating type – resistance to current puncture up to 3 000 V. • Anti-corrosion protection. Applications • Bearings in threephase motors • Traction motor bearings • Wheelset bearing arrangements • Bearings in generators. Details: see TPI 206, Current-Insulating Bearings. 19 4 Main function – Surfaces subjected to high tribomechanical stresses Triondur ® C (metal-doped carbon coating) Features: see TPI 115 Colour: matt greyish black Coating structure Hard amorphous hydrocarbon coating of lamellar type structure with content of tungsten and tungsten carbides. The surface structure is smooth. Layer thickness 0,5 – 4 μm. Friction reduction in DLC/steel compared with steel/steel (dry in each case) 80 percent. Hardness: 1 100 – 1 500 HV Advantages/benefits • Effective anti-wear protection under mixed friction • Higher wear resistance due to high hardness • Favourable under adhesive wear due to the low friction factor • Highly suitable under slippage risk. Applications • Barrel rollers in spherical roller bearings for paper calenders • Barrel rollers in axial spherical roller bearings for hydraulic motors • Track rollers with coated outside diameter for the printing industry. 20 4 Main function – Surfaces subjected to high tribomechanical stresses Triondur ® C + / CX + (amorphous carbon coating) Features: see TPI 115 Colour: black Coating structure Hard lamellar type amorphous non-metallic hydrocarbon coating. Triondur ® CX + is doped with non-metals. The surface structure is smooth. Layer thickness 2 – 4 μm. Friction reduction in DLC/steel compared with steel/steel (dry in each case) 85 percent. Hardness: > 2 000 HV. Advantages/benefits • Very high anti-wear protection under mixed friction • Higher wear resistance due to high hardness • Friction reduction under mixed friction • Highly suitable for components subjected to high tribological stresses with lubricant starvation. Applications • Reduction in wear and friction in valve train components (e. g. tappets) • Anti-wear protection in diesel injection components • Bearing components (e. g. cages) for increased life. Triondur ® CH (hydrogen-free amorphous carbon coating) Features: see TPI 115 Colour: iridiescent anthracite Layer thickness 0,5 – 1 μm Friction reduction in DLC/steel compared with steel/steel (dry in each case) 85 percent. Hardness: > 4 000 HV. Advantages/benefits • Highest wear resistance of all Triondur ® coatings • Maximum friction reduction Applications • Engine components 21 4 Main function – Surfaces subjected to high tribomechanical stresses Triondur ® CN (chromium nitride) Features Colour: lustrous silver-grey Coating structure Hard nitridic chromium coating with nanocrystalline structure. The surface structure is smooth. Layer thickness 1 – 4 μm. Friction reduction in Triondur CN/steel compared with steel/steel (dry in each case) 20 percent. Hardness: > 2 200 HV. Advantages/benefits • Very high protection against abrasive wear due to high hardness • Friction reduction under adequate lubrication. Applications • Reduction in wear and friction in valve train components (e. g. tappets). Triondur ® CNN (chromium carbonitride) Features Colour: matt silver Coating structure Multi-layer, nanodispersive, chromium-based hard material coating. Coating thickness: 5 – 15 μm. Friction reduction in Triondur CNN/steel compared with steel/steel (dry in each case) 15 percent. Hardness: 1 200 – 1 800 HV. Advantages/benefits • High abrasive wear resistance due to high hardness • Good anti-wear protection under lubricant starvation or oil contamination. Applications • Reduction in wear and friction in valve train components (e. g. hydraulic insert elements). 22 4 Main function – Surfaces subjected to high tribomechanical stresses Triondur ® TN (titanium nitride) Features Colour: lustrous gold Coating structure Titanium nitride Layer thickness 2 – 5 μm. Hardness: > 2 000 HV. Advantages/benefits • High anti-wear protection Applications • On the rib surfaces of aircraft engine bearings. Attention! The coating cannot be used on the bearing raceway. 23 Notes 24 MATNR 036805394-0000 / TPI 186 / GB-D / 2013031 / Printed in Germany by bresler Schaeffler Technologies Schaeffler Technologies AG & Co. KG AG & Co. KG Center of Competence Center of Competence for Surface Technology for Surface Technology Industriestraße 1–3 Georg-Schäfer-Straße 30 91074 Herzogenaurach 97421 Schweinfurt Germany Germany Internet www.ina.com Internet www.fag.com E-Mail E-Mail [email protected] Every care has been taken to ensure the correctness of the information contained [email protected] in this publication but no liability can be accepted for any errors or omissions. We reserve the right to make technical In Germany: In Germany: changes. Phone 0180 5003872 Phone 0180 5003872 © Schaeffler Technologies AG & Co. KG Fax 0180 5003873 Fax 0180 5003873 Issued: 2013, March From other countries: From other countries: This publication or parts thereof may not Phone +49 9132 82-0 Phone +49 9721 91-0 be reproduced without our permission. Fax +49 9132 82-4950 Fax +49 9721 91-3435 TPI 186 GB-D
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