Meteoritics & Pinnetno Science 36, 1617-1637 (2001) Available online at http //www uark eddmeteor Space weathering on Eros: Constraints from albedo and spectral measurements of Psyche crater B. E. CLARKIt*, P. LUCEY2, P. HELFENSTEINI, J. F. BELL, 1111, C. PETERSONI, J. VEVERKAI, T. McCONNOCHIE1, M. S. ROBINSON3, B. BUSSEY3, S. L. MURCHIE4, N. I. IZENBERG4 AND c . R. CHAPMAN5 'Cornell University, Center for Radiophysics and Space Research, Ithaca, New York 14853, USA 2University of Hawai'i, HIGP, 2525 Correa Road, Honolulu, Hawai'i 96822, USA 3Northwestern University, Geological Sciences, 1847 Sheridan Road, Evanston, Illinois 60208, USA 4Johns Hopkins University, John Hopkins Road, Laurel, Maryland 20723, USA 5Southwest Research, 1050 Walnut Street, Suite 426, Boulder, Colorado 80302, USA ?Present address: Ithaca College, Physics Department, Ithaca, New York 14850, USA *Correspondence author's e-mail address: [email protected] (Received 2001 June 28; accepted in revised form 2001 September 26) (Part of a series ofpapers on the NEAR-Shoemaker mission to 433 Eros) Abstract-We present combined multi-spectral imager (MSI) (0.95 pm) and near-infrared spectrometer (NIS) (0.8-2.4pm) observations of Psyche crater on S-type asteroid 433 Eros obtained by the NearEarth Asteroid Rendezvous (NEAR)-Shoemaker spacecraft. At 5.3 km in diameter, Psyche is one of the largest craters on Eros which exhibit distinctive brightness patterns consistent with downslope motion of dark regolith material overlying a substrate of brighter material. At spatial scales of620 m/ spectrum, Psyche crater wall materials exhibit albedo contrasts of 3 2 4 0 % at 0.946 pm. Associated spectral variations occur at a much lower level of 4-8% (+2-4%). We report results of scattering model and lunar analogy investigations into several possible causes for these albedo and spectral trends: grain size differences, olivine, pyroxene, and troilite variations, and optical surface maturation. We find that the albedo contrasts in Psyche crater are not consistent with a cause due solely to variations in grain size, olivine, pyroxene or lunar-like optical maturation. A grain size change sufficient to explain the observed albedo contrasts would result in strong color variations that are not observed. Olivine and pyroxene variations would produce strong band-correlated variations that are not observed. A simple lunar-like optical maturation effect would produce strong reddening that is not observed. The contrasts and associated spectral variation trends are most consistent with a combination of enhanced troilite (a dark spectrally neutral component simulating optical effects of shock) and lunar-like optical maturation. These results suggest that space weathering processes may affect the spectral properties of Eros materials, causing surface exposures to differ optically from subsurface bedrock. However, there are significant spectral differences between Eros' proposed analog meteorites (ordinary chondrites and/or primitive achondrites), and Eros' freshest exposures of subsurface bright materials. After accounting for all differences in the measurement units of our reflectance comparisons, we have found that the bright materials on Eros have reflectance values at 0.946pm consistent with meteorites, but spectral continua that are much redder than meteorites from 1.5 to 2.4 pm. Most importantly, we calculate that average Eros surface materials are 3040% darker than meteorites. INTRODUCTION The near-Earth asteroid rendezvous (NEAR)-Shoemaker observations of asteroid 433 Eros reveal a large crater, called Psyche, centered at 25" north latitude and 88" west longitude (Fig. 1). At 5.3 km in diameter, Psyche is the largest example of the craters on Eros which exhibit brightness contrasts on their walls (Murchie et af.,2002; Thomas et al., 2002). Murchie et al. (2002) PvelLcde preprint MS#4579 show a correlation between gravitational slope on Eros and the brightness of the surface. Steep slopes tend to have higher albedo materials than exist on the surrounding plains. Murchie et al. (2002) suggest that downslope movement has exposed subsurface material which is both brighter and somewhat less red than average Eros surface material, characteristics consistent with a space weathering process on Eros which has not had sufficient time to weather the bright, presumably subsurface material. 1617 0 Meteoritical Society, 2001. Printed in USA. 1618 Clark et al. FIG. 1. Centrally located on asteroid 433 Eros, Psyche crater is -5.3 km in diameter. This image mosaic was obtained by the NEARShoemaker multi-spectral imager (MSI) shortly after orbital insertion of the spacecraft in February 2000. At spatial scales of up to 180 mipixel from NEAR'S multispectral imager (MSI) data, the subsurface materials exposed on Psyche's steep slopes have albedo contrasts with the surroundings of 83% at 0.95 p m (Murchie et al., 2002). In color ratio images (0.76/0.95 pm) these albedo contrasts are associated with minor color variations (10%). In near-infrared spectrometer (NIS) global maps, the albedo contrasts are also detectable (Bell et al., 2002). For the purposes of this investigation, we assume that the suggestions of Thomas et al. (2002) are correct: the regolith of Eros has experienced downslope motions on steep slopes. This mass wasting mechanism has caused the dark surface materials to slide down steep crater walls, exposing brighter subsurface materials below (Fig. 2). The brighter substrate is probably also particulate material. Thus, although the albedo markings have been linked with macroscopic processes, the microscopic causes of the contrasts (light scattering behavior) have yet to be identified. While the spectral relationships among bright and dark terrains on Eros, and the spectral relationship between Eros and proposed analogs are qualitatively consistent with operation of a space weathering process, these relationships have not been examined quantitatively. That is the subject of this paper. We present a study of Psyche crater which integrates images and spectroscopic observations. We present measurements of the albedo contrasts and their associated spectral variations. Using mixing models, meteorite spectra, and lunar analogies we discuss three possible explanations of Psyche's albedo contrasts: (1) grain size differences, (2) olivine, pyroxene, and troilite compositional variations, and (3) maturation of the optical surface by space weathering processes. We will show that the spectral relationships among terrains of different albedos on Eros are quantitatively consistent with FIG. 2. A glimpse inside of Psyche by the MSI reveals a boulder strewn field at the bottom of the crater and evidence of downslope processes on the gravitationallysteep crater walls. This image was obtained at a spatial resolution of up to 3.5 dpixel, at mission elapsed time I40150800 s, after the spectrometer failed. The image is looking south-southeast centered at 3" north latitude and 87" west longitude, and is 1.4 km wide. It was obtained from a range of 36 km. the operation of a space weathering process which must include both the accumulation of submicroscopic iron and some dark, spectrally neutral weathering product. The latter product is represented in the meteorite collection in the form of black chondrites. We will also show that the brightest terrain on Eros, consistent with the least weathered material, is not consistent with the presence of ordinary chondrite material. The Psyche bright material shares a similar albedo to that of ordinary chondrites, but is much redder and exhibits less contrast. In other words, even the bright material appears quite weathered and requires a precursor material which is brighter than ordinary chondrites. PREVIOUS WORK There is a variety of evidence that asteroids in general possess regoliths (of unknown depth). Asteroid regoliths are thought to be dominated by grains of a different average size than lunar regolith due to the fact that asteroids have different Space weathering on Eros gravitational fields, different agglutination rates, and probably retain less impact ejecta (Housen and Wilkening, 1982; Dollfus et al.,1989). Polarization studies indicate a surface grain size range on S-type asteroids of 30-300pm (Dollfus et al., 1989). For Eros at least, Veverka et al. (2001) show convincing evidence that the regolith could be quite deep. In addition, observations of 951 Gaspra and 243 Ida by the Galileo spacecraft revealed surfaces with degraded crater morphology and evidence of retained crater ejecta, suggesting that regolith formation and evolution processes were at work (Sullivan et al., 1996; Lee et al.,1996; Carr et al., 1994; Geissler et al., 1996). Since the Galileo results at Ida and Gaspra, it has been suspected that a surface modification process (or processes) occurs on asteroids which changes the brightness and color of the surface with time. It has not been determined whether that process is simply comminution (reduction of grain size) or chemical alteration due to exposure of the surface to the space environment (i.e.,space weathering). In this paper, we use the term "space weathering" to mean micrometeorite impact, solar wind particle implantation, and any other processes (known and unknown) that may tend to change-over time-the apparent traits (optical properties, physical structure, chemical or mineralogical properties) of the immediate, remotely-sensed surface of an airless body from analogous traits of the body's inherent bulk material as analysed in the laboratory. On Ida in particular, regolith processes such as crater formation have been linked with albedo and color variations by Sullivan et al. (1996). These color variations were attributed to the exposure (by impact cratering) of fresh subsurface materials which contrasted with the surrounding surface (Chapman, 1996). The nature of color contrast exposures in and around craters on Gaspra and Ida argues that the albedo and color contrasts are caused by macroscopic ejecta emplacement. On the Moon, albedo and color contrasts are commonly observed around fresh craters and are due to differences between the optically mature surface and the optically less mature subsurface. Some information on the spectral effects of space weathering on asteroids has been inferred from measurements and experiments with meteorites and minerals in the laboratory (Moroz et al., 1996; Clark et al.,1992; Britt and Pieters, 1989; etc.), and by analogy with the Moon (Pieters et al., 2000). Recently, several studies have shown that energetic heating of a regolith to simulate micrometeorite bombardment on asteroids can cause optical alteration patterns similar to those observed on Ida (Sasaki et al.,2001; Hiroi and Sasaki, 2001). These optical alteration patterns are also similar to those required to explain the discrepancies between certain meteorite classes and their proposed asteroid parent bodies (Hapke, 2001). In addition, progress in understanding space weathering on the Moon has made it feasible to extrapolate studies to asteroids (Pieters et al.,2000; Hapke, 2001). Currently the model for space weathering on the Moon which is most consistent with 1619 all of the data is that micrometeorite bombardment, perhaps aided by solar wind sputtering, produces a vapor from particulate target materials which, upon redeposition at the surface, is chemically reduced such that iron previously existing in silicates condenses out as a coating of submicroscopic particles on individual grains (Hapke, 2001). Because we do not have samples of an asteroid surface for analysis in the laboratory, we do not know to what extent the lunar weathering process(es) operates on asteroids (McKay et al., 1989). However, meteorite evidence and lunar soil studies indicate that asteroid surfaces are probably characterized by complex particle size distributions (Horz and Cintala, 1996), impact shock effects (Keil et al., 1992), and mineral specific responses to impacts, solar wind, and cosmic-ray bombardment (Sasaki et al.,2001; Moroz et al., 1996; Clark and Johnson, 1996; Hapke, 2001). The arguments presented by Pieters et al.(2000) show that many aspects of lunar-type space weathering must occur on asteroids; however, the rates and relative importance of different effects (vapor deposition, comminution, glass production, etc.) may be quite different yielding cumulative optical effects which may differ in detail fiomthe lunar example. The main components detectable in 0.8-2.4 p m spectra of Eros and other S-type asteroids are the minerals olivine and pyroxene, common constituents of ordinary chondrite and primitive achondrite meteorites (Sears and Dodd, 1988; McCoy et al.,2000). These minerals and meteorites exhibit absorption features in reflectance spectra centered near 1.O and 2.0 pm, the precise central wavelength depends on mineral chemistry (Cloutis and Gaffey, 1991). Albedo and color variations in imaging data of Eros are compared with similar measurements of asteroids 243 Ida and 95 1 Gaspra by Murchie et al. (2002). Preliminary reports on the geology of Eros have been presented by Veverka et al. (2000, 2001), Thomas et al. (2002) and Murchie et al. (2002). In their paper, Thomas et al. (2002) compare Psyche crater with other craters on Eros. Psyche is found to have a rim consistent with impact crater morphology in gravitational profiles, although it is somewhat degraded. It is not known to what extent the formation of Psyche may have affected the rest of Eros, although areas to the southwest show possible infilling of craters. Psyche has a deptwdiameter ratio of -0.21, a high value compared with typical craters on Gaspra and Ida (-0.15) (Thomas et al., 2002). OBSERVATIONS Images and spectra obtained by the NEAR-Shoemaker spacecraft are identified by mission elapsed time (MET) (measured in seconds since launch on the spacecraft clock). Imaging observations were conducted throughout the mission by the MSI; however, the NIS only obtained data until MET 133588706, whereupon the instrument ceased to function due to a failure in the electronics (Bell et al.,2002). Although the coverage of asteroid terrain by both instruments is quite good 1620 Clark et a1 (100% in the case of MSI, and 90% in the case of NIS; Veverka et al., 2000; Bell et al., 2002), there are comparatively few occurrences of simultaneous MSI-NIS observations of Psyche crater. Listed in Table 1 are all MSI observations used in figures for this paper. Corresponding NIS measurements are listed for individual spectra. However it would not be feasible to list each of the 250 spectra used in the global mapping. Instead, selection criteria for NIS spectra are given below. TABLE1. MSI-NIS Observations of Psyche crater. Figure 1 2 4 8 13a 13b MSI MET* NIS MET* 125956839, 125957025, 125957087, 125957273 140150800 132393412 Basemap (mosaic)+ 133148793 133147433 - - - 133148862-133148874 133147380-133147392 Images Figure 3 is an oblique view across the top of Psyche crater. This image indicates the steepness of the sides of the crater walls, which have slope angles up to 35" (Thomas et al., 2002). The contact between bright crater wall materials and the surrounding terrain does not support the existence of bright ejecta deposits around the rim, nor do the bright markings tend to emerge from specific source ridges, blocks, or crater rims. Downslope, the bright material margins commonly have very sharp transitions to darker material, a characteristic very different from the diffusive boundaries observed on Phobos, Deimos, and Gaspra. The bright markings terminate against the bottoms of craters, suggesting that whatever they are, they do not run out over flat areas, and thus are not high velocity failures (Thomas et al., 2001). As concluded by Thomas et al. (200 l ) , downslope processes can apparently continue to function long after crater formation on Eros. Figure 3 suggests that since Psyche formed, the optical surface has equilibrated to match the mean surface surrounding the crater (hereafter called the plains). Any bright crater rays or ejecta deposits that might have formed with the Psyche impact have since faded or been covered with dark material. Apparently, bright materials FIG. 3. This oblique view across the top of Psyche shows the steep northern slopes of the crater. Steep slopes allow gravitational processes to compete successfully with surface darkening processes. *MET is mission elapsed time, in seconds since launch. +SeeBussey et al. (2001) for basemap details. are exposed on the crater walls because the slopes are (or have been) locally unstable for the upper layers containing the dark materials. These general relationships have also been described by Murchie et al. (2002). The association between dark and bright materials on Eros is entirely different from associations observed on Gaspra and Ida (Sullivan et al., 1996). On Eros, bright materials are correlated with steep crater walls (Thomas et al., 2002; Murchie et al., 2002), whereas on Gaspra and Ida we see only color contrasts associated with craters and ejecta emplacement (Geissler etal., 1996; Lee etal., 1996; Chapman, 1996). These geomorphologic associations are important constraints on models of the causes of the microscopic differences controlling the albedo contrasts in Psyche crater. Near-Infrared Spectroscopy Spectroscopic data used for this analysis have been calibrated (Izenberg et al., 2000) and photometrically corrected (Clark et al., 2002). Calibration procedures correct instrumental fluxes for the effects of dark current, detector crosstalk, and bias. Photometric correction procedures correct each spectrum for variations due to illumination and viewing geometry (Clark et al., 2002). These corrections are further discussed in the section "Models" where we review the importance of viewing geometry to spectrum characterization. Figure 4 shows the observation phase angle and spatial resolution of the data. The spectra we used were constrained to phase angles <IOO", incidence and emission angles <75", spatial resolution 400800 &spectrum, and areal distribution centered on Psyche (-30 to 70" north latitude, and 35 to 175" west longitude). For the purposes of comparing NEAR spectra with laboratory spectra of analogue materials, we have photometrically corrected all of the data to both 0 and 30" phase angle. In reflectance spectrum analysis, it is customary to normalize spectra at 0.55 pm, the wavelength where most asteroid brightness and albedo information is measured. In this paper, we are restricted to wavelengths obtained by the NIS spectrometer (0.8-2.4 pm) and therefore we will normalize all spectra to a wavelength near the continuum at 1.3 pm. When Space weathering on Eros 1 - Average Spectral Properties Psyche High Resolution NIS Data 0 $ 500 p: L 400 50 1621 60 70 80 90 Phase angle (degrees) 100 110 FIG. 4. This figure shows the phase angle and spatial resolution coverage of the NIS spectra we used in our analysis of Psyche crater. Data were constrained to latitudes -30 to 70" , and longitudes 35 to 175". A tiny spot is plotted for each of the 1246 spectra in this Psyche crater subset of the NIS dataset. spectra are normalized at 0.55 pm, any differences in the visible wavelengths are minimized and differences in the infrared are enhanced. When spectra are normalized at 1.3 prq the similarities at wavelengths from 0.8 to 1.4 p m are enhanced and the differences in both the short wavelength visible (0.3-0.8 pm) and in the infrared (1.4-2.5 pm) are emphasized. To study the spectral effects of the albedo contrasts observed in Psyche crater, we defined a study area which spatially encloses Psyche and which also captures the surrounding plains. Figure 5 is a simple cylindrical map showing the areal coverage of the Psyche study area. Each spectrum covers an area associated with a triangular plate number in the shape model (for details on the shape model see Thomas et al., 2002). In Fig. 5 the plate model is shaded according to the photometrically corrected normal albedo values at 0.946pm and reprojected to a simple cylindrical map. Thus, although the spectrometer footprint is rectangular in shape (Izenberg et al., 2000), resolution elements in our coverage maps are triangular in shape because we use a plate model of Eros. Each plate is covered at least 80% by the specified spectrum. The highest spatial resolution of the NIS spectra is 0.55 km across (see Fig. 4). This map can be compared with Fig. 6, which shows imaging at the same scale, but at much higher spatial resolution (for details on the basemap see Bussey et al., 2002). Figure 7 shows a histogram of the normal albedo values at 0.946 p m mapped in Fig. 5. The mean normal albedo value is 0.22 ? 0.04 and the values are weakly enhanced in the bright tail of the distribution. Figure 8 shows a histogram of the reflectance values at 0.946pm for data photometrically corrected to 30" phase angle. To compare the spectral properties of the darker ambient materials with the brighter crater wall materials in Psyche, we iteratively mapped the locations of bright and dark spectra until the spatial locations of each concurred with the imaging data FIG. 5. A simple cylindrical map representing the NIS observations of Psyche crater on Eros. Mapped are the photometrically corrected normal albedo values at 0.946pm. The highest spatial resolution element is 550 m across. This can be compared with Fig. 6, which shows imaging at the same scale, but at much higher spatial resolution ( 1 80 dpixel). 1622 Clark et al. FIG.6. A simple cylindrical represention of a MSI basemap mosaic. For details on basemap construction, see Bussey et al. (2001). The area around Psyche crater (centered at +20" latitude and 90" longitude) can be compared with Fig. 5 , which shows the NIS coverage at much lower spatial resolution (550-800 dspectrum). Histograms u) Q) 8 0 100 GI0 k sE k iz 2 0 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 u) $ 60 50 8 0 30 8 20 i$ 10 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 u) - - - - - Bri ht Materials -Dar! Materials P z o . . . . ., . . . 8 El Q) 58 40 % 100 0 - 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 Normal Albedo (0.946p.m) FIG.7. The distribution of reflectance values at 0.946 p m for data photometrically corrected to 0" phase angle. The top panel shows a histogram for all spectra used to make the map of Psyche crater in Fig. 5 . The bottom panel shows histograms for the spectra used to make the maps of Psiche bright and da;k materials in Figs. 9 and 10. 60 50 40 % 30 8 20 P Bright Materials - - - - Dark Materials - i$ 10 z o 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 Reflectance (0.946p.m) FIG.8. The distribution ofnormal albedo values at 0.946pm for data photometrically corrected to 30" phase angle. The top panel shows a histogram for all spectra used to make the map of Psyche crater in Fig. 5 . The bottom panel shows histograms for the spectra of Psyche bright and dark materials. Space weathering on Eros shown in Fig. 6. The MSI basemap image in Fig. 6 was used only to aid in defining contacts between bright and dark units. It is possible that a given location on Eros was classified in both bright and dark bins because spectrum footprints may overlap. In addition, uncertainties in normal albedo values due to unresolved topographic slopes may be folded into the bright/dark contact zones. These uncertainties could not be avoided, and it is our hope that on average we have succeeded in binning the bright and dark units sufficiently. We found a total of 2 17 spectra in the dark areas and 76 spectra in the bright areas, the remaining -1000 spectra in the Psyche NIS dataset are probably mixtures of the two terrains. Results are shown in Figs. 7, 9, and 10, and listed in Table 2. The resulting bright and dark unit distribution maps nicely match the gravitational slope map reproduced here from Thomas et al. (200 1) in Fig. 11. 1623 Note that the materials we call the "dark unit" are actually average Eros surface materials, represented in both the plains and in crater floors. Figure 9 shows the spatial location of the 217 spectra we have binned to represent the spectral properties of average dark materials and Fig. 10 shows the spatial location of the 76 spectra we have binned to represent the spectral properties of average bright materials in Psyche. The mean dark value is 0.19 (0.08 at 30") and the mean bright value is 0.26 (0.11 at 30"), thus there is not quite the 83% contrast in the NIS observations as in the MSI observations (Murche et al., 2001). This is probably due to the differing spatial resolutions of the two datasets. The MSI data were obtained at 180 &pixel, whereas the NIS data were obtained at 620 dspectrum. One would expect higher resolution data to resolve more detail and contrasting surface FIG. 9. The spatial locations of the 217 spectra binned for the average spectral properties of dark materials in and around Psyche crater. TABLE2. Psyche NIS Spectra.* Rim Plains Bright Dark Bright average Dark average Phase angle average Incidence angle average Emission angle average Average resolution (dspectrum) Reflectance (0.946 pm) 68 68 66 67 72 24 38 37 41 62 60 46 30 41 591 600 600 60 1 624 616 0.10 0.08 0.12 0.08 0.11 0.08 80 40 96 100 *Note that all angles are given in degrees, and all reflectances are given at phase angle 30". Reflectance Reflectance (0.946pm) (0.946pm) (minimum) (maximum) 0.10 0.06 - 0.13 0.10 1624 Clark et al. FIG.10. The spatial locations of the 76 spectra binned for the average spectral properties of bright materials in the walls of Psyche crater. FIG.1 1. This simple cylindrical map shows gravitational slopes on Eros, reproduced from Thomas et al. (2001). Note the high correlation between gravitational slope and albedo around Psyche crater (shown in Fig. 5 ) . areas than lower resolution data because there is less averaging within the field-of-view of the detector. If we use the equation percentage contrast = ((rhigh - rlow)/ravg) x 100 (l) to describe the contrast, where rhigh is the average bright reflectance value at 0.946 p m , 'low is the average dark value and ravg is the average of the two, then we find a 32% albedo contrast between bright and dark materials at spatial scales of 620 dspectrum. The maximum contrast level is difficult to gauge with certainty; however, at 30" phase angle there are some Space weathering on Eros spectra with values higher than 0.13 and some with values as low as 0.06, more than a factor of 2 difference, or 74%contrast. This compares well with the Murchie et al. (2002) study in which they find albedo contrasts of 83% at spatial scales of 180 d p i x e l . Figure 12 compares the average dark materials spectrum with the average bright materials spectrum. This figure shows that darker materials on Eros have slightly broader 1 p m bands and slightly redder spectral slopes than brighter materials. The total variation is ~ 4 (%2 2 % ) . This analysis indicates that on average the albedo contrasts in Psyche crater are 32%. However, because we have binned and averaged many spectra there is a chance that we are including shadows or topographic facets not captured by the shape model (Clark et al., 2002). On average, these problems occur in both senses (there are just as many dark shadows as there are bright facets) such that binning of a statistically significant number of spectra will even things out. However, for confirmation, in the following section we examine the level of contrast observable at close range (i.e., with individual spectra rather than with large areal averages). Local Spectral Properties We have searched through the imaging and spectroscopy datasets for examples of both dark and bright material exposures 1.o 0.251 Q) 0 9 c, . . ' - 1.5 within Psyche crater. A constraint we imposed was that the images and the spectra must have been obtained within 1 min of each other, otherwise the motion of the spacecraft makes it difficult to superpose the data such that the NIS field-of-view is exactly placed on the MSI image. Figure 13 shows two examples of local occurrences fitting our search criteria (spectra are listed in Table 2). This figulle shows exposures of both bright and dark materials close to each other, with minimal shadows and minimal differences in viewing angles. Minimal differences in viewing geometry helps to assure that uncertainties in the photometric correction (Clark et al., 2001) are not important to the spectral comparison. Shown in Fig. 14a is a comparison of spectra of materials on the rim of Psyche crater with materials in the plains surrounding Psyche. Shown in Fig. 14b is a comparison of spectra of the brightest and darkest materials. The top panels show each spectrum in normal albedo units, the middle panels show each spectrum in reflectance at 30" phase angle, and the bottom panels show a ratio of the normalized spectra. This ratio brings out the subtle spectral differences between bright and dark materials. At 0.946pm, the bright crater wall materials have a reflectance at 30" phase angle of 0.12 and the dark crater wall materials have a reflectance of 0.08. Similarly, the bright rim materials have a reflectance of 0.10 and the dark plains materials have a reflectance of 0.08. Using Eq. (1) again, we calculate an albedo contrast between these two areas to be 40 and 2.0 1.0 . 0.20: 1625 '*04 1 0.96 1 1.5 2.0 DarklBright Ratio 0.15 4 0.10 i 0 0.05; 0.00 l 1.o 1.5 2.0 Wavelength (microns) 1.0 1.5 2.0 Wavelength (microns) FIG. 12. Average spectra for Psyche crater dark materials and bright materials. Error bars are the standard deviations of the mean. Panel (a) IS i n units of reflectance at 0" phase angle, and panel (b) is a ratio of dark materials over bright materials and normalized to 1.3 ,urn to bring out the subtle differences between the two avcrage spectra. A straight dotted line is plotted to aid in comparison. Points along the line are wavelengths for which the normalized spectra show no spectral differences. Panel (c) shows the same spectra in units of reflectance at 30" phase angle, and panel (d) shows their normalized ratio. This figure shows that the phase angle ofphotometric correction has no effect on the trends observed in the spectrum ratios. 1626 Clark et al. FIG.13. The spatial relationships of spectra obtained of Psyche bright and dark materials deposits. (left) A spectrum of bright rim materials is outlined in red and a spectrum of dark plains materials is outlined in blue. (right) A spectrum of bright crater wall materials is outlined in red, and a spectrum of dark crater wall materials is outlined in blue. Image and spectrum MET numbers are given in Table 1. Associated viewing and illumination angles are given in Table 2. 1.06 - 1.04 : - PlaindRim 0 - B 1.02- l.OO 3 # --B 0.98 0.96 0.94 - - ...% 0.0 0 0.. ..oo0 a Dark/Bright - 1.04 -:.23 1.02 -: - - 1.06 *, **+ ++++ - + j - 4*++++ b 0.96 0.94 + - - FIG. 14. These figures compare the spectra of local dark material deposits with local bright material deposits. (a) A region on the bright rim of Psyche crater is compared with a region in the darker surrounding plains. (b) A dark region on the wall of Psyche crater is compared with a spectrum of a nearby area of bright materials (see Fig. 13). Spectra were obtained within 12 s of each other, minimizing instrumental drift and viewing angle differences. In addition, as shown in Fig. 13, there are no large shadows in either spectrum footprint. The top panels show each spectrum in normal albedo, the middle panels show each spectrum in reflectance at 30" phase, and the bottom panels show a ratio of dark (plains) materials to bright (rim) materials. Viewing angles for all spectra are listed in Table 2. Space weathering on Eros 22%, respectively. In total, the peak-to-peak spectral variations are 8% (?4%) and are most significant in the shape of the 1 p m band from 0.8 to 1.0 pm, and in the slope of the continuum from 1.5 to 2.4 pm. Similar to Fig. 12, Fig. 14 shows that individual spectra of dark materials on Eros have slightly broader 1 p m bands and slightly redder spectral slopes than brighter materials. In sum, the global averages show contrasts of 32% and spectral variations of 4%, and the local spectra show contrasts of up to 40% with attendant spectral variations of up to 8%. We do not distinguish which measure of the contrasts and variations is most representative of the surface of Eros, but instead use the range of values as a general guide. 1627 . ' l . " . ' Spectral Photometric Model In this section we begin by briefly explaining the photometric model. Although the photometric correction procedure is described in detail in Clark et al. (2001), we touch on some aspects here in order to illustrate how photometric effects are important to the comparison of asteroid and meteorite data. The main sources of variation in the NIS spectral dataset are photometric effects: variations in reflectance level due to changes in illumination and viewing geometry (Veverka et al., 2000; Clark et al., 2001; Bell et al., 2001). Because photometric effects can cause large differences in spectral reflectance (Fig. 1 3 , it is necessary to analyze spectra of Eros at viewing angles similar to those of analog minerals and meteorites measured in the laboratory. For this study we use the model of Clark et al. (2001) to photometrically correct our measured spectra of Eros to the viewing geometry of common laboratory measurements. The model consists of a set of Hapke parameter values for each of 52 wavelengths. The parameters modeled are average single scatter albedo (w),a single particle phase function HenyeyGreenstein asymmetry parameter (g),macroscopic roughness mean slope angle (@,opposition surge amplitude (Bo),and the . " l . l " l a 0.40 i c, $ 0.30; p: 3 0.20 1 M z 0.10 MODELS In this section we use scattering models and lunar analogies to explore three plausible explanations for the albedo and color contrasts in Psyche: grain size, mineral chemistry and modal abundance, and optical maturation processes. We then compare predicted spectra1 variation trends with the measured variations presented in the previous section. We begin with a brief explanation of the photometric correction procedure, used to correct all NIS spectra to a viewing geometry comparable to laboratory viewing angles (Clark et al., 2002). We then use mineral mixture models to simulate the photometrically corrected spectra. Finally, we modify our mineral mixtures to simulate the spectral consequences of variations in grain size, composition, and optical maturity. We constrain our model mixture variations to be consistent with the observed albedo contrasts of 32-40%. . Eros Model Spectra , . - . " ' , . ' ' . , l o Model Spectrum 37,29 29 m Measured Spectrum 33,29,29 0.05/..1 . . . . 1.0 I 1.5 . . . . t . . . . 2.0 2.5 Wavelength (microns) FIG. 15. This figure shows models and measurements of Eros' spectrum. The top panel shows model spectra calculated at various viewing geometries using the Hapke parameters provided in Clark et al. (2002). To the right side of each spectrum are the viewing angles listed in order of incidence, emission,and phase angles, respectively. The brightest spectrum is calculated at normal viewing geometry, where incidence, emission, and phase angle are all exactly 0". Most laboratory spectra of analog materials used to study Eros' composition are measured at the 30,0,30 viewing geometry (last spectrum). The bottom panel compares an average of 56 NIS spectra measured at incidence = 37", emission = 29", and phase = 29" with a model spectrum calculated at the same viewing geometry. The model agrees quite well with the measurement, lending a degree of confidence in the photometric model of Eros. Error bars have been supressed for this comparison-for more detail on uncertainties see Clark et al. (2002). opposition surge angular width parameter (A). Parameter values are provided in Clark et al. (2001) in the form of spectra of Hapke parameters. The model predicts the spectral reflectance of Eros as a function of viewing geometry, and is accurate to within 2 2 % on average. In Fig. 15 we use the spectral photometric model of Eros to show some effects of viewing geometry on Eros spectra. The top panel shows how changing incidence, emission, and phase angles affect the overall brightness of the Eros spectrum. For 1628 Clark et al. example, the model spectrum calculated at normal reflectance (incidence = emission = phase = 0) is 2 . 5 brighter ~ than any of the spectra calculated for moderate laboratory-like reflectance geometries (generally constrained to phase angles from 15 to 30"). As a check on the accuracy of the photometric model, the bottom panel of Fig. 15 compares a measured spectrum with a model spectrum. The measured spectrum is an average of 56 NIS spectra obtained at phase angles between 28 and 32". For this average spectrum, the average incidence and emission angles were 37 and 29", respectively. The model spectrum was calculated at the same viewing geometry. There is good agreement between the model and the measurement, lending a high degree of confidence in the photometric model. We can now compare Eros to laboratory spectra of analog materials. Our suite of analog mineral samples were measured at the Reflectance Laboratory Facility at Brown University (RELAB) (Pieters, 1983; Sunshine et al., 1990; Britt et al., 1992). At RELAB the standard viewing geometry is incidence = 30", emission = 0", and phase = 30". ' 1.0 1 ' ' ' ' ' ' 1 . Olivine 0.0'. I . . . . I , . ' 1 ' ' . , .-./--- , , I , .--, 0.8-, ' //-\//\TL \-I . .,' ' 1 ' 1.0 ' ' ' ' ' ' ' " " ' ' , Orthopyroxene ' 0.8 . 0.0 . # . . . . # . . . . I . . . . _ Neutral Dark \ 0) $ 0.6 - Y 0 Modeling the Spectral Relationship Between Psyche Bright and Dark Material While the differences between Psyche bright and dark material are qualitatively consistent with a space weathering relationship, it is plausible that grain size, mineral composition or other reasonable mechanisms can account for these differences. We will use an intimate mixing model based on the work of Hapke to quantitatively explore the effects of several parameters. We will present spectral effects of variations in grain size, mineral chemistry, relative abundance of olivine and pyroxene, abundance of a spectrally neutral dark component, and submicroscopic iron. We will show that a model which includes processes consistent with current understanding of space weathering (Pieters et al., 2000; Hapke, 2001) can account for the differences between Psyche bright and dark material, though grain size differences are also at least spectrally plausible. Our model relies largely upon the work of Hapke (1993, 2001). Hapke (1993) presented a compilation and extension of his work on radiative transfer in powders. Hapke (2001) presents the methods necessary to compute the optical effects of submicroscopic iron which serves an important role in lunar space weathering optical effects (see also Hapke, 2000). Our model allows the computation of the reflectance spectrum of a meteorite-like assemblage consisting of intimately mixed olivine, ortho- and clinopyroxene, plagioclase feldspar, troilite, Fe-Ni metal, iron-bearing glass, and submicroscopic Fe metal. Figure 16 shows the major mineral endmembers included in our model. We can compute the spectrum of an arbitrary mixture of these components at any grain size and, within limits, mineral chemistry. The model begins with a definition of the relative abundances of the components and the mineral chemistries of the components for which this is an important variable. For Q, 9 w Coarse 0.4 0.4. --- 0.2 . : 0.0 Plagioclase w 1.5 2.0 2.5 Wavelength (pm) 1.0 0.0 1.0 1.5 2.0 2.5 Wavelength (pn) FIG. 16. Shown here are RELAB measurements of the reflectance spectra of our four mineral endmembers used in the mixing model of Eros' spectrum. Grain size separates are labeled in the legend at the right. the transparent minerals (olivine, pyroxene, plagioclase and glass) we compute the optical constants from defined chemistries. Chemistry-dependent optical constant coeficients for olivine and pyroxene are from Lucey (1998). The chemistries of olivine and orthopyroxene were linked to conform to the relationship between olivine and pyroxene Mgnumber in ordinary chondrites from Keil and Fredrikkson (1964). Optical constants for glass as a function of iron content were computed by Lucey (1998). We used the Hapke-based methods presented in Lucey (1998) to compute the irondependent optical constants of plagioclase from reflectance spectra ofplagioclase in the U.S.G.S. Denver spectrum library. Next, using the methods outlined in Hapke (1981, 1984, 1986, 1993) modified to include the effects of submicroscopic iron presented by Hapke (2001) we compute the single scattering albedos of the transparent components from the optical constants, grain sizes and the defined abundance of submicroscopic iron, assuming a coating of metal for the minerals, and a uniform distribution of metal throughout the grain for glass. We note that lunar and asteroidal submicroscopic iron deposition may be quantitatively different Space weathering on Eros because the asteroidal submicroscopic iron may also contain nickel. Our models assume that the submicroscopic coatings are pure iron, which appears to be a good assumption on the Moon (Hapke, 2001). The extent to which Ni will alter the optical constants of iron is not clear. For troilite, the single scattering albedo at a given grain size is computed from a fit to derived single scattering albedos for three different sizes of troilite. For metal, the single scattering albedo at a given grain size is computed from Mie theory. In this implementation all components share the same particle size (except for submicroscopic iron). The single scattering albedos are combined using Eq. (1 7) of Hapke (1981). The single particle phase functions are combined using the methods of Helfenstein et al. (1994, 1996). The mixture single scattering albedo is converted to reflectance using Eq. (37) of Hapke (1981). Shown in Fig. 17 are our mixing model spectra of Eros compared with the measured spectra for the bright and dark materials in Psyche crater. Mixing ratios for each endmember are listed in Table 3. The best model fits are achieved with a grain size of 63 pm. Note that because we do not have constraints on the actual composition of the minerals present at the surface of Eros, these mixing models are not meant to be construed as unique determinations of the composition of Eros, but should instead be taken as reasonable interpretations of the reflectance spectra. In reality, the surface is likely to be an extremely complex mixture of particles of different sizes (Horz and Cintala, 1996), different shock histories (Keil et al., 1992), and mineral specific responses to impacts, solar wind, and cosmic-ray bombardment (Sasaki et al., 2001; Moroz et al., 1996). In this effort we were unable to mimic any spectra of Eros without including the reddening effect of submicroscopic iron. However, our approach to modeling the effect of macroscopic Fe-Ni metal grains may not be an accurate representation of the true effect. Note that between these two fits there have been only minor changes in composition and grain size, but large increases in the amount of troilite (which in our case we use to represent both the effects of the mineral, and any other dark neutral component), and submicroscopic iron. Our approach to using this model to explore the parameter space is to begin with the inputs resulting in the fit to the Psyche bright material, then modify these by varying individual parameters to illustrate these parameters' effects on the bright Psyche material. Our goal in each case is to attempt to transform 0.20 1629 1 1.0 1.5 2.0 Wavelength (microns) FIG.17. Intimate mixture models for the spectra of Eros bright and dark materials. The Eros spectra are shown in symbols and the models are shown in solid lines. the bright material spectrum into the spectrum of the dark material using model variations. Grain Size The first plausible explanation for the albedo contrasts observed in Psyche crater is grain size. As shown by A d a m and Filice (1976), Johnson and Fanale (1973), Clark et al. (1992) and Clark (1999, the reflectance ofmeteorite and mineral samples increases with decrease in the average grain size. We began with our nominal Eros bright material mixture model spectrum (grain size 63 p m ) and produced three comparison spectra at 88,107, and 126pmgrain size. Figure 18 shows the spectral consequences of this variation. For the purposes of comparing grain size variations to our observed variations in Psyche crater, we ratio the dark spectra (coarser grain sizes) to the nominal bright materials mixture model spectrum. In the normalized spectral ratios, the amplitude of expected spectral variation is as high as 18% (+5-13%), and there are minor variations correlated with the absorption band centers near 1 and 2 pm. In contrast, the observed spectral ratio variation amplitude on Eros is at the level of 4-8%, and there are no variations correlated with band centers. TABLE3. Mixing model parameters.* Olivine Bright Dark 54 49 Orthopyroxene Plagioclase Neutral dark 17 16 15 14 2.5 Grain size SMFe Mg-number (01) 14 63 0.03 22 77 0.07 70 70 *Note that all endmembers are given in weight percentages, and grain sizes are given in microns. Abbreviations: SMFe = submicroscopic iron. 1630 Clark et al. I . . . . I ' . . . I . . . 1.20 i . j - Variations GrainSize 0-20; 88 microns - - - - 107 microns - - 126 microns -.---.-. 0.05 . .... I 1.0 I . . . . # . . . 0.80 . 1.5 2.0 Wavelength (pm) 2.5 1.0 1.5 2.0 Wavelength (pm) 2.5 FIG. 18. Variations in grain size of our mineral mixture are shown: the left panel shows the nominal mixture model (grain size 63 pm) compared with mixture models made with grain sizes of 88, 107, and 126pm. Also plotted are the dark material mixture model (solid line), and the observed darkhright material spectrum ratio (solid dots) to aid in comparison. The right panel shows the coarser grain size mixtures ratioed to the nominal grain size. 0.20 . Forsterite 0 .H 4 d 1.10 i 0.15 0.10 0.05 Mg58 - - - - - I . 1.0 . . . I . . . . I . . 1.5 2.0 Wavelength (pm) . . > 2.5 0.80 1.0 1.5 2.0 Wavelength (pm) 2.5 FIG. 19. Variations in forsterite composition (as measured by the irodmagnesium ratio-Mg number) of our mineral mixture. (left) The nominal bright material model is compared with mixture models made using increasing proportions of the magnesium content of the olivine and pyroxene endmembers. (right) The enhanced magnesium models ratioed to the nominal model spectrum. This figure shows that the trends in spectral ratios associated with olivine magnesium content have amplitudes of -lo%, and result in wave-like spectral ratios. Also plotted are the dark material mixture model (solid line), and the observed dark/bright material spectrum ratio (solid dots) to aid in comparison. Composition The second plausible explanation for the albedo contrasts observed in Psyche is a compositional heterogeneity. We consider variations in either the relative abundance of components, or the chemistry of the components to be compositional variations, and we simulate both effects in thls section. We begin four comparison variations: one with a steadily decreasing forsterite number (increasing proportions of iron in the olivine and pyroxene), one with increasing olivine weight percent in the mixture, one with increasing orthopyroxene weight percent in the mixture, and finally one with increasing troilite. Figure 19 shows the spectral consequences of variations in forsterite composition (as measured by the irodmagnesium content). In this case, the total amplitude of expected spectral variations is -10%. Note that forsterite (Mg number) variations change the shape of the reflectance spectrum as band centers shift in wavelength, causing the spectral ratios to exhibit a distinct wave-like appearance. These trends are not observed Space weathering on Eros 1631 not result in albedo contrasts at 0.946 p m comparable to the observed albedo contrasts in Psyche. Figure 2 1 shows the spectral consequences of the increase in orthopyroxene proportion of the mixture composition. In this case, the total amplitude of expected spectral variations is 13%. Again, however, increasing the pyroxene proportions did not result in albedo contrasts comparable to the observed contrasts in Psyche. In addition, pyroxene variations cause in spectral ratios of Eros' materials. Also, the magnitude of the change in forsterite content necessary to account for the albedo contrast is extremely large, and probably unreasonable for a single object. Figure 20 shows the spectral consequences of the increase in olivine proportion of the mixture composition. In this case, the total amplitude of expected spectral variations is -15%. Note, however, that increasing the proportion of olivine did - 0 . 3 c, a p: '.' .- - 1.5 2.0 4 0.8 1.o 2.0 1.5 1.o 2.5 Wavelength (urn) 2.5 Wavelength (urn) FIG.20. Variations in olivine proportions of our mineral mixture. (left) The nominal bright material model is compared with models made with increasing weight percentages of the olivine endmember. (right) The enhanced olivine models are ratioed to the nominal model spectrum. Also plotted are the dark material mixture model (solid line), and the observed darklbright material spectrum ratio (solid dots) to aid in comparison. This figure illustrates that the trends in spectral ratios associated with olivine variations have amplitudes of-I 5%; however the 40% albedo contrasts observed in Psyche cannot be simulated with these increases in olivine. 1 . 2 q q 30%-. -. -. -. 0.05.1 . . . . 1.o # 1.5 . . . . . . . 2.0 2.5 . I Wavelength (urn) 0.8 j dark Model 1.o 1.5 2.0 Wavelength (urn) , 2.5 FIG. 21. Variations in pyroxene proportions of our mineral mixture. (left) The nominal bright material model is compared with models made by increasing the proportions ofthe pyroxene endmember. (right) The enhanced pyroxene models are ratioed to the nominal model spectrum. Also plotted are the dark material mixture model (solid line), and the observed darwbright material spectrum ratio (solid dots) to aid in comparison. This figure illustrates that the trends in spectral ratios associated with pyroxene compositional variations have amplitudes of - 1 3%; however, the albedo contrasts O f 40% observed in Psyche crater cannot be simulated with increases in pyroxene proportions. Clark et al. 1632 distinct band-correlated variations which are not observed in spectral ratios of Eros' materials. Figure 22 shows the spectral consequences of.& increase in dark component (troilite) proportions of the' mixture . . .T.' composition. .... Addition of troilite (a dark spectrally neutral component) can match the albedo contrast observed within Psyche, but model spectra with albedos similar to Psyche dark material are much less red than observed within Psyche (and otherwise on Eros). "! , Optical Maturity The only surface for which optical maturation is understood is the Moon. There is no proof that optical maturation occurs on asteroids, however it is reasonable to suppose that it might. Pieters et al. (2000) showed that aspects of lunar-type space weathering should occur on asteroids, including the accumulation of submicroscopic iron (SMFe) from micrometeorite impact vaporization. Our model allows variations in the amount of lunar-like optical maturation. We find that increasing the amount of SMFe with the Eros bright material model as a starting point substantially darkens the spectrum. However, the spectra redden too rapidly to match Eros dark material (see Fig. 23). Model spectra with the same composition as the Eros bright material fits, but with sufficient SMFe to match the albedo of Eros dark material, are substantially redder than Eros dark material. Pieters et al. (2000) and Hapke (2001) noted that increases both in SMFe and dark material were necessary to match the spectra of lunar soil using a powder lunar rock starting material. On the Moon, space weathering includes the effects of impact- 0.201 8El 2 + shocked Fe-Ni and troilite components that have been dispersed into grains larger than the observation wavelength. Indeed, in meteorite regolith breccias shock-darkened materials (e.g., black chondrites) are common (Britt and Pieters, 1989). A dark neutral component is thus a reasonable addition to an asteroidal weathering model. We find that making the abundance of our dark component (represented by troilite) directly proportional to the abundance of SMFe gives rise to a good match to Eros dark using the Eros bright model as a starting composition. The excessive redness of the SMFe is counteracted by the spectrally neutral effect of the dark component (see Fig. 24). DISCUSSION Albedos of Eros and Meteorites In our study we have taken pains to exploit the measurements obtained by the NEAR NIS at many viewing geometries to ensure that we can directly compare reflectances of Eros to the reflectance of meteorites measured in the laboratory. After accounting for all differences in brightness units of our reflectance comparisons, we have found that the bright materials on Eros have reflectance values at 0.946pm consistent with meteorites (see Fig. 25), and that average Eros surface materials are 3 0 4 0 % darker than meteorites. Fanale et al. (1992) compared S-type asteroid albedos and ordinary chondrite (OC) meteorite reflectances and showed that there was significant overlap in values, indicating a possible genetic relationship between the two populations. However, in that study Fanale et al. did not take into account the fact that OCs are measured in the laboratory at bidirectional viewing Neutral Dark Variations / 0.15 0 EG 0.10 0.05 0.801. I . . . . . . . .: 1.0 1.5 2.0 2.5 Wavelength (pm) I 1.0 1.5 2.0 Wavelength (pn) 2.5 . . FIG.22. Variations in the dark (troilite) proportions of our mineral mixture models. (left) The nominal bright materials model spectrum is compared with spectra made by increasing the proportions of the dark component. (right) The dark component enhanced spectra are each ratioed to the nominal bright spectrum and normalized at 1.3 pm. Also plotted are the dark material mixture model (solid line), and the observed darkhright material spectrum ratio (solid dots) to aid in comparison. This figure illustrates that the trends in spectral ratios associated with troilite variations consist of decrease in spectral contrast in the 1 p m band and flattening (or blueing) of the spectral continuum. 1633 Space weathering on Eros I 0.20 I: . . . . . l ' . . ' I ' . . ' SMFe Variations 0 .w Y 4 Q) 0 9 9) 0.15 Y 0 9 0 4E Y 0 4 0.10 0.05 E I . 1.0 . . . I . . . 1.5 . I . . . . 2.0 2.5 1.0 Wavelength (pm) 1.5 2.0 2.5 Wavelength (pm) FIG.23. The left panel shows our nominal bright material spectrum together with three different models of silicates and submicroscopic iron metal (SMFe). The right panel shows the three SMFe-enhanced spectra ratioed to the nominal Eros spectrum. Also plotted are the dark material mixture model (solid line), and the observed dark/bright material spectrum ratio (solid dots) to aid in comparison. This figure illustrates that the trends in spectral ratios associated with SMFe variations consist of broadening of the 1 pm band and reddening of the spectral continuum from 1.5 to 2.4 pm. These trends match the trends observed in Psyche crater; however, their amplitude is too high. I 1.10 0.05.1 . . . . 1 .o 1.5 I . . . . I . . . . 2.0 Wavelength (urn) 2.5 0.8d. 5%S 18%D----6%S 21% D- - 8%S 25% Dark Model -I I I . . . . I . . . . I . . 1.o 1.5 2.0 Wavelength (urn) . .1 2.5 FIG. 24. (left) The nominal mixture model spectrum of bright materials in Psyche is compared with mixture models made by increasing the proportions of both the neutral dark and the SMFe endmembers. (right) Each comparison spectrum is ratioed to the nominal spectrum and normalized to 1 .O at 1.3 p m . Also plotted are the dark material mixture model (solid line), and the observed darmright material spectrum ratio (solid dots) to aid in comparison. This figure shows that the albedo contrasts and overall amplitude ofspectral variation trends observed in Psyche crater can be simulated with a mixture model incorporating enhanced neutral dark and SMFe endmember components. and illumination geometry which differs from that used for the calculation of asteroid albedos. In fact, it is actually very dificult to compare the two quantities. Asteroid albedo values are measurements of the geometric albedc-defined as the ratio of the brightness of a body at 0" phase angle to the brightness of a perfect Lambert disk of the same radius and at the same distance as the body, b u t illuminated and observed perpendicularly (Hapke, 1993). Geometric albedo can thus be thought of as the weighted average of the normal albedo over the illuminated area of the body. The largest database of geometric albedos of asteroids is from the infrared astronomical satellite (IRAS) survey published by Tedesco (1992). Laboratory reflectance quantities at RELAB a r e bidirectional reflectance factors, defined as the ratio of the brightness of a sample at 30" incidence and 0" emission, to the brightness of halon (an almost perfect Lambertian surface) illuminated identically (Pieters, 1983). At any given wavelength, the value of the geometric albedo (0" phase) is Clark et al. 1634 Eros Compared with Meteorites Eros and Meteorite Analogs CI 8 9 8 Y BE 0.20 O0 3 0.15 0.10 1.0 1.5 I - . 2.0 2.5 Wavelength (microns) . - - - - . - - - - b 8' 433ErosNEAFt o 433 Eros Telescopic Aca ulcoite LL Ordinary C%ondrite . -- FIG. 26. This figure compares spectra of Eros obtained by NEAR 0.6t . . . . . . . . . . . . . . . . 1.0 1.5 2.0 1 2.5 Wavelength (microns) FIG. 25. Both Psyche crater units, bright and dark materials, are (global average) and by telescope (disk-integrated)(Murchie and Pieters, 1996)with spectra of Eros' potential meteorite analog types, the LL ordinary chondrites and the Acapulcoite primitive achondrites. Note the considerable spectral differences between Eros and its proposed meteorites beyond 0.8 pm. Meteorite spectra are from T. Hiroi (pers. comm.), measured at the Brown University Reflectance Laboratory (RELAB). ratio vs. band center position analysis in the manner of Cloutis et al. (1986) to estimate a relative abundance of olivine to pyroxene of -2: 1, which is similar to LL ordinary chondrites. Another class of viable analogs, the Acapulcoite and Lodranite meteorites, known as primitive achondrites, have not been completely ruled out (McCoy et al., 2000; Burbine et al., 200 1). However, as shown in Fig. 26 neither proposed meteorite analog therefore systematically higher than the value of the type for asteroid Eros is a match to the spectrum of Eros. Eros bidirectional reflectance of a lab sample (30" phase). Using is both redder and exhibits less contrast. Meteorite spectra are the photometric model of Clark et al. (2001), we estimate that from T. Hiroi, and were measured at the Brown University the difference can be up to a factor of 2.5 (this is also shown in Reflectance Laboratory Facility (T. Hiroi, pers. comm.). Both Fig. 15). Taking this photometric factor into consideration, the meteorite types appear to have reflectance spectra which are results of Fanale et al. (1992) indicate that meteorites are 2 . 5 ~ too flat in the infrared, and which have absorption features too brighter than asteroids on average. In other words, S-type deep to match the asteroid. The spectral differences observed asteroids are generally much darker than OC meteorites. It is between Eros and its proposed meteorite analogs are typical of the differences between S-type asteroids and meteorites (Fanale therefore not surprising that Eros is darker than its proposed et al., 1992; Pieters and McFadden, 1994; Meibom and Clark, meteorite analogs. 1999). An important question which must be answered is "Do the Eros Materials Compared to Meteorites Psyche crater bright wall materials spectrally resemble Detailed analysis of the absorption features present in the meteorites more closely than does average Eros?" Shown in spectrum of Eros suggest a surface composition similar to OC Fig. 25 is a comparison of Psyche crater materials with both meteorites ( e . g . , Murchie and Pieters, 1996, and references proposed meteorite analogs for Eros. In this figure we compare therein) (see Fig. 26). Preliminary NEAR results from the the local individual spectra (not the global averages) of both of x-ray spectrometer (Trombka et al., 2000) and from the NIS the Psyche crater wall units, bright and dark materials, with the (Veverka et al., 2000; Bell et al., 2001) corroborate this proposed Eros meteorite analog types. The top panel shows compositional similarity. Bell et al. (2001) use a band-area- all spectra in reflectance at RELAB geometry (incidence = 30, compared with proposed Eros meteorite analog types. The top panel shows all spectra in reflectanceat RELAB geometry(incidence= 30, emission = 0, and phase = 30"). The bottom panel shows all spectra normalized to 1.0 at 1.4 pm. The bright materials are similar to meteorites in brightness and spectral properties from 0.8 to 1.5 pm, however neither analog spectrally matches either unit of Psyche crater at wavelengths beyond 1.5 pm. Space weathering on Eros 1635 models predict that grain size differences should result in band correlated variations that are not observed. It is interesting that the NEAR x-ray spectrometer team reports marked depletions in sulfur elemental abundances at Eros relative to ordinary chondrites. Other elements, Mg, Al, Ca, and Fe, all seem to be consistent with OCs, suggesting that if indeed Eros is similar to OCs then partial melting or impact volatilization processes may have been active, resulting in fractionation of sulfur at the surface (Trombka et al., 2000). This evidence, together with our current understanding that the lunar space weathering mechanism is partly a process involving volatilization of target materials, implies that surface alteration processes may be required to explain the optical differences between bright and dark areas on Eros. However, while the elementalresults allow (but do not require) an OC composition (excepting sulfur) and mineralogical analysis suggests that Eros bears an o1ivine:pyroxene ratio consistent with LL chondrites, our results are difficult to reconcile with an OC composition in detail. The brightest material on Eros does not look like a powdered meteorite: it is red and exhibits lower contrast. But the brightest material on Eros has a similar albedo to that of analog meteorites. Our work suggests that if space weathering is operating on Eros, unaltered Eros material must be inherently brighter than previously proposed analogs. For example, it is possible that Eros bright materials are of much finer grain sizes than previously supposed. Shown in Fig. 27a is a comparison between lunar rocks and soils. When the spectra are normalized and ratioed in the manner we have been utilizing in this paper, it is evident that soils are redder than rocks. Similarly, if we use an asteroid emission = 0, and phase = 30"). The bottom panel shows all spectra normalized to 1.O at 1.4 pm. Neither analog is a good spectral match to either unit of Psyche crater. The bright materials are similar to the Acapulcoite meteorite in terms of reflectance at 0.946 pm, however the spectra diverge beyond 1.5pm. The dark materials, which probably represent exposures of Eros' average surface, are darker and redder than either meteorite. The shapes of the absorption features at 1.0 p m also differ, with the Eros units being broader and smoother than the meteorites (which have well-defined minima and U-shaped profiles). The meteorites shown here are typical and representative of their classes, however this comparison is not exhaustive. It is possible that better matches to Eros could be found among the meteorite spectrum collection, however we were not able to find them. We conclude that bright materials in Psyche are optically fresher than dark materials, but do not spectrally match meteorites. Space Weathering on Eros Our modeling suggests that the albedo and color contrasts in Psyche crater are best explained by a space weathering process which includes accumulation of both SMFe and a dark neutral component. Geologic relationships suggest that the bright material is being exposed from the subsurface and is therefore younger. Both this study and that of Murchie et al. (2001) suggest that materials that are consistent with recent exposure are brighter and less red than material consistent with longer exposure to space. A combination of effects which includes a grain size difference is also possible; however, our --___---- Optical Maturity Variations 1.0 1.5 2.0 2.5 1.0 1.5 2.5 2.0 1.2 1.0 a a Y 0.5 ! 0.51 0.01 0.0 - - Highland 7 1.0 4 L . 1.5 -___ 2.0 Wavelength (microns) 2.5 c, 0 o-."[ 0.6 B 0.4 & b 433-s ACS ul o!b LL ordinary CfonLte I 1.0 1.5 2.0 --I 0 2.5 Wavelength (microns) FIG.27. In this figure, (a) lunar surface soils are compared with lunar basalt rocks (reproduced from Pieters et al., 2000 by permission) and (b) the photometric model spectrum of average Eros is compared with both of its meteorite analog types. If Eros' subsurface is similar to ordinary chondrite or Acapulcoite meteorites, then the differences between Eros' surface soils (shown in diamonds) and the subsurface (represented by meteorites shown in solid and dashed lines) are similar to the differences between lunar surface soils and subsurface rocks. Clark et al. 1636 spectrum to represent asteroid soils, and meteorite spectra to represent asteroid rocks, a spectral ratio shows that asteroids are redder than meteorites in a sense that is very similar to the lunar comparison (Fig. 27b). If, as we favor, space weathering has been an important process on Eros, then it must be pervasive because all portions of Eros, even the brightest, appear weathered. It is possible that Eros does not have color contrasts around the rims of craters as Gaspra and Ida have because it is in a different weathering environment in the solar system. Eros is in near-Earth space, whereas Gaspra and Ida are in the main belt. This argues for different rates of the competing processes of surface maturation and impact cratering between near-Earth orbits and the asteroid main belt. indicating that since the formation of the crater the surface of Eros has been weathered. (9) These findings suggest that Eros's surface may be completely weathered due to its exposure to the space environment. Our results suggest that space weathering processes affect Eros' spectral properties, but do not fully explain the differences between Eros and its proposed analog meteorites, the ordinary chondrites and/or the primitive achondrites. (10) Differences in optical maturation trends between Eros and other S-type asteroids studied by spacecraft may indicate different rates of the competing processes of surface maturation and impact cratering between objects in near-Earth orbits and objects in the main asteroid belt. SUMMARY Acknowledgnzents-We gratefully acknowledge the help of J. Joseph, B. Carcich, A. Harch, M. Ockert-Bell, and B. Owen. Helpful reviews were provided by B. Hapke and A. W. Harris (DLR). B. E. C. especially thanks the NEAR project and the NEAR Science teams for a wonderful mission. This research is supported by the NEAR In summary, we find: (1) The background surface of Eros in and around Psyche crater is 3 2 4 0 % darker than the bright materials exposed on steep slopes in the crater walls at spatial scales of -620 m/ spectrum. (2) The dark material is 2 4 % redder than the bright material at 1.5-2.4 pm, and has a 1 p m band which is 2 4 % broader at 0.8-1 .Opm. The total spectral variation is 4-8% peak-to-peak from the normalized mean at 1.3 pm. (3) The albedo and contrasts in Psyche crater are not consistent with a cause due solely to either grain size or compositional variations. (4) The contrasts and associated spectral variation trends observed in Psyche are consistent with a lunar-like optical maturation which combines accumulation of SMFe with an enhancement of the dark spectrally neutral component of Eros' surface materials (presumably shocked silicates). (5) Bright materials in Psyche appear optically less mature than dark materials, but do not spectrally match meteorites. The bright materials are approximately the same brightness as meteorites, however their spectra are 33% too red from 1.5 to 2.4 pm. ( 6 ) We calculate that average Eros surface materials are 30-40% darker than meteorites. We also find that when differences in reflectance measurement units and photometric geometry are accounted for, most meteorites are 2-3x brighter than asteroids. 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