UW CHEM 120 Ch. 8-‐10 Study Guide Tips for Success on Exams: • • • Show ALL YOUR WORK when solving numerical problems. ALWAYS express any numerical value with units and significant figures. This includes intermediate values in calculations! Be able to discriminate between necessary and extraneous information in a word problem. Chapter 8 – Solutions • • • • • • • • • • • • • • • • Understand what solutions are and how they are formed Know how to distinguish the solute from the solvent when a solution is described Understand the influence of polarity on solubility (like dissolves like!) Understand why electrolytes conduct electricity and the difference between strong electrolytes, weak electrolytes, and nonelectrolytes Understand saturation and the properties of a saturated solution Know the influence of temperature and pressure on the solubility of solids, liquids, and gases in liquid solvents Be able to predict whether a chemical reaction will happen or not (you will be provided with charts of soluble/insoluble ions, the activity series, or other important data, but you must know how to use them) Be able to write ionic and net ionic equations for chemical reactions Know how to calculate the concentration of a solution (4 ways, see pp. 312-316 for more info) Use the concentration of a solution to calculate the amount of solute, or the volume of a solution Understand the concept of dilution Calculate the concentration or volume of a solution being diluted (C1V1 = C2V2, p.319-321) Use the concentration of a solution to determine the limiting reactant in a chemical reaction Know the similarities and differences in general properties of solutions, colloids, and suspensions Understand the influence of concentration on the boiling point and melting point of a solution (and the different effects of electrolyte versus nonelectrolyte solutes) Use the concept of osmotic pressure to determine which direction solvent will flow when two solutions are separated by a semipermeable membrane Chapter 9 – Reaction Rates & Chemical Equilibrium • • • • • • • Understand the concept of reaction rate Know how to describe chemical reactions using potential energy diagrams, including drawing the curves for reactions with and without catalysts Be able to draw the following terms in the correct place on a potential energy diagram: reactants, products, activation energy, energy difference between reactants and products Use collision theory to predict how changes in temperature, pressure, or concentration will affect the reaction rate Know the difference between reversible and irreversible reactions Understand the concept of chemical equilibrium Know how the concentrations of reactants and products as well as the forward and reverse reaction rates change as a system approaches equilibrium 1 of 2 UW • • • • • • CHEM 120 Use equilibrium constants to describe reversible reactions Be able to write equilibrium expressions for homogeneous and heterogeneous systems Calculate the equilibrium constant for a reaction, when given the concentration of reactants & products, and be able to calculate the concentration of a reactant or product when given the concentrations of other reactants/products and the equilibrium constant Know the qualitative difference between small and large equilibrium constants Use Le Chatelier’s principle to predict the changes in reaction rate when a system at equilibrium is subjected to stress, including changes in temperature, pressure, or concentrations of reactants/products Understand the influence of a catalyst on chemical equilibrium Chapter 10 – Acids & Bases • • • • • • • • • • • • • • • Know the Arrhenius and Bronsted-Lowry definitions of acids and bases Be able to recognize acids and bases in a completed chemical reaction Know the name and formula of the strong acids HCl, HNO3, and H2SO4 Understand the concept of conjugate acid-base pairs and be able to recognize conjugate acidbase pairs in chemical reactions When given an acid or base, be able to write the conjugate base or conjugate acid, respectively Know how to write the acid dissociation expression for weak acids (this is almost exactly the same as the equilibrium constants that we learned about in chapter 9) Know the strong bases LiOH, NaOH, and KOH Understand the relationship between acid strength and acid dissociation constant + Know the relationship between [H3O ] and [OH ] Understand the pH scale + Know how to calculate pH from [H3O ] and vice versa Remember, sig figs are treated a little differently in pH calculations! Be able to write neutralization reactions for acids or bases Understand how buffers regulate pH Understand the carbonic acid/bicarbonate buffer that is present in human blood. Know where these chemicals come from… 2 of 2
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