DGSM Information Paper No. 11 COMBUSTIBLE LIQUID Licensing of Flammable and Combustible Liquids Storage under the Dangerous Goods Safety Management Act 2001 CHEM services Chemical Hazards and Emergency Management services Community Safety and Sustainability Counter Disaster and Rescue Services March 2005 Emergency Services Complex, Cnr Park and Kedron Park Roads, KEDRON Qld 4031 GPO Box 1425, BRISBANE Qld 4001 Telephone: (07) 3247 8444 Facsimile: (07) 3247 8433 website: http://www.emergency.qld.gov.au/chem e-mail: [email protected] Table of Contents 1. Introduction............................................................................................................................1 2. Who needs a Licence? ...........................................................................................................2 2.1 Conditions of Licence.............................................................................................................................. 3 2.2 Administrative processes ......................................................................................................................... 4 3. Minor Storage ........................................................................................................................4 4. Classification of flammable and combustible liquids............................................................7 Appendix 1 Table 2.1 (AS1940–2004)......................................................................................9 Appendix 2: Data on some common flammable and combustible liquids ..............................14 Disclaimer Any representation, statement, opinion or advice, expressed or implied in this information paper is made in good faith but on the basis that the State of Queensland, its agent and employees are not liable (whether by reason of negligence, lack of care or otherwise) to any person for any damage or loss whatsoever which has occurred or may occur in relation to that person taking or not taking (as the case may be) action in respect of any representation, statement or advice referred to above. 1. Introduction Flammable and combustible liquids (FCL) constitute by far the largest group of hazardous materials used in Queensland. The most common FCL in the community are petrol, kerosene and diesel fuel. Because of the risk posed by their potential to cause or exacerbate a fire and their widespread presence throughout the community, a licence is required for the storage of FCL in excess of minor quantities. This information paper provides information on licensing of the storage of FCL under the Dangerous Goods Safety Management Act 2001 (DGSM). DGSM legislation The DGSM legislation establishes requirements for the safe storage and handling of dangerous goods and combustible liquids. Generally, these requirements (or obligations) are performance-based, i.e. they set goals that must be met but do not prescribe how they are to be met. Obligation holders are required to achieve an acceptable level of risk as far as reasonably practicable. Occupiers of premises have the obligation to store and handle their dangerous goods and combustible liquids at an acceptable level of risk. On the basis of the type and quantity of these materials stored, premises are classified as a Dangerous Goods Location (DGL), a Large Dangerous Goods Location (Large DGL), “other” workplace or Major Hazard Facility (MHF). The obligations of occupiers relate to the level of classification of the premises. Licensing Authority is devolved to local governments to license premises where FCL are stored, and to set and enforce conditions of licence. Australian Standard AS1940 “The storage and handling of flammable and combustible liquids” plays a key role in determining whether a FCL licence is required or not. The licensing provisions apply to premises where AS 1940 applies and where the quantity of FCL stored exceeds the minor storage exemption limits set out in that standard. For the manner in which FCL are stored, adherence to AS 1940 is not required. However, one way of achieving an acceptable level of risk is to comply with good industry practice, which may be expressed in an accepted standard such as AS19401. Hence, AS 1940 is seen as a valuable source of technical guidance. A licence holder must comply with the requirements of the DGSM Act and Regulation and with the conditions of the licence. FCL licence conditions are enforced by authorised officers from the local government that issued the licence. Thus any queries regarding licensing for the storage of FCL should be directed to the relevant local government. 1 Other suitable standards may be used; e.g. for laboratories, AS 2243 “Safety in laboratories”, especially Part 10. DGSM Information Paper No. 11 Licensing of Flammable and Combustible Liquids Storage (March 2005) CHEM services, Department of Emergency Services Page 1 2. Who needs a Licence? The occupier of premises intending to store FCL above minor storage quantities as specified in AS1940 and not exempted by the Act or Regulation must apply for a licence. The application on the approved form must be made to the local government where the premises are situated. In order for the local government to determine if a license should be granted to the occupier, sufficient information must be provided about the storage facility as well as the occupier, in order to determine their suitability. A licence is required if the quantity of FCL exceeds the minor storage limits stated in Table 2.1 of AS1940. This quantity can be in underground tanks, aboveground tanks, packaged goods stores or a combination of these. The information in Table 2.1of AS 1940 is given in a rearranged format as a reference in Appendix 1 of this information paper. AS 1940 sets out requirements for the design, construction and operation of installations for the storage and handling of FCL in locations that are generally industrial, commercial or rural in nature. It includes matters relating to operations and management of emergencies. It identifies issues to be considered in any risk management of facilities handling FCL. ℡ To purchase a copy of AS1940 or any other Australian Standard, contact Standards Australia on 1300 654 646. -- Note that a new version of AS1940 was released October 2004 -Note that licensing provisions also apply to the following liquids: • • Class 3 liquids that have a subsidiary risk assigned (e.g. methanol Class 3 sub risk 6.1); Dangerous goods of other classes that possess a subsidiary flammable liquid risk (e.g. glacial acetic acid Class 8 sub risk 3, or selected pesticide products of class 6.1, sub risk 3). An occupier must include the quantities of materials that have a flammable subsidiary risk when determining obligations under DGSM Act and whether licensing is required. The factors determining whether a site requires a licence include: • • the flashpoint and classification of the material (i.e. Packing Groups I, II and III, and combustible liquid types C1 and C2); and the maximum quantities stored at any one location, either as a total or as the amount per unit floor area. The quantity thresholds above which a licence is required depend on the type of premises, the floor area of the premises and in some cases whether the storage is inside or outside. The types of premises are as follows: • • • • commercial building hospital educational establishment laboratory DGSM Information Paper No. 11 Licensing of Flammable and Combustible Liquids Storage (March 2005) CHEM services, Department of Emergency Services Page 2 • • • • • factory or workshop shop warehouse service station or open land. Under the DGSM legislation, a FCL licence is not required in the following situations: • • for coal mines, mines, petroleum leases and gas pipelines (Act, s. 3); and for rural places (land exceeding 5 ha in area used exclusively for agricultural, horticultural, floricultural or pastoral purposes, unless the FCL is stored for resale) (Regulation, s.78). Because the AS 1940 minor storage exemption limits are different from the quantity thresholds for DGLs, it is possible that premises may be regarded as a minor storage workplace for the purposes of Part 3 of the DGSM Regulation but still require an FCL licence. An example would be a warehouse storing 8,000 litres of C1 combustible liquids in packages inside the building. Under Table 2.1 of AS 1940, this quantity exceeds the minor storage exemption limit of 2,000 litres; the premises would require an FCL licence. However, the quantity does not exceed the relevant DGL threshold (50,000 litres - Item 7 of the Table in Schedule 1 of the DGSM Regulation), and so is a minor storage workplace. Conversely, premises classed as a DGL because of the quantity of FCL stored would not need a licence if the quantity of FCL did not exceed the AS 1940 minor storage exemption limits. An example would be open land with a 2,000 litre tank containing PG III flammable liquid. This premises exceeds the DGL threshold of 1,000 litres but not the AS 1940 exemption limit of 5,000 litres. As the licensable quantities of FCL vary for different types of premises, as shown in Table 2.1 of AS 1940, any person who is proposing to store FCL is advised to contact their local government to determine if they require a licence. 2.1 Conditions of Licence A licence may be issued only if the following criteria are met: • • the premises are suitable for the proposed storage of FCL; and the applicant is a suitable person to hold a licence. The local government may approve the application provided the site achieves an acceptable level of risk. This may be demonstrated by complying with accepted standards or by the applicant carrying out a suitable risk study. The licence may be issued subject to conditions stated in the licence which must be complied with at all times while the license is valid. The occupier of the site may then store FCL at the site in compliance with the licence conditions set for the site. DGSM Information Paper No. 11 Licensing of Flammable and Combustible Liquids Storage (March 2005) CHEM services, Department of Emergency Services Page 3 Under the DGSM Regulation (s.92), it is a condition of licence that the licensee must comply with the DGSM Act. The quantity of FCL stored must not exceed the quantities stated in the licence. The local government may set appropriate conditions on the licence to give effect to the DGSM Act. 2.2 Administrative processes The Regulation makes provisions for the renewal, amendment and transfer of licences as well as their suspension or cancellation. 3. Minor Storage Any storage of FCL in quantities not exceeding those listed in Table 2.1 (Section 2) of AS1940 is classified as minor storage. The underlying concept of minor storage for the purposes of AS1940 is that quantities below a certain level are so small, or so scattered and separated, that they present little risk, add little to a building’s fire load, and are generally unlikely to play a significant part in spreading a fire from place to place. The fire-fighting facilities required under normal building regulations are expected to cope adequately. Minor storage may exist at a site at which no other FCL are present. It may also exist at a site where major quantities of FCL are present but the minor storage is separated from those quantities. There may also be more than one minor storage at the one site. Section 2 of AS1940 (Minor Storage) provides guidance on multiple minor storages in the same building and/or same site, including proximity to other stores. This guidance indicates the degree to which FCL may be accumulated in a small area within minor storage limits. The requirements also apply to minor storage on construction sites. Under the DGSM Regulation (Part 4), storage of quantities below the limits in the Minor Storage Table does not require the site to be licensed provided the following precautionary measures as stated in AS1940 Section 2 (Minor Storage) are complied with. The following information is taken from Section 2.3 Precautions applying to minor storage. Location of minor storage The following requirements and recommendations apply to the location of an indoor minor storage: (a) If the storage is located on a floor that is above the building’s lowest floor (i.e. on a floor that is above the ground floor or basement), its location shall not jeopardize the safety of any areas on lower levels of the building or impede firefighting operations. (b) Flammable vapours and spilt liquids shall be prevented from escaping to any lower levels of the building. (c) Concentrated storage of liquids in any one area shall be avoided, so as to reduce the fire load and the potential rate of fire spread. (d) The storage area shall be adequately ventilated. (e) The build-up of flammable vapours should be avoided (see Control of ignition sources). DGSM Information Paper No. 11 Licensing of Flammable and Combustible Liquids Storage (March 2005) CHEM services, Department of Emergency Services Page 4 Operations The following handling requirements and precautions apply: (a) Persons who handle the liquids shall be fully aware of the hazards involved. (b) All storage areas shall be secured against access by unauthorized persons at all times. (c) Packages shall not be placed where they could hinder escape from a building in an emergency. (d) Care should be taken when decanting or transferring flammable liquids. Dispensing pumps or self-closing metal taps should be used, in order to reduce the hazards of splash filling, spillage and vapour escape. (e) Packages shall be kept closed when not in use. Packages containing flammable liquids should only be opened or decanted in well-ventilated areas and away from any potential ignition source. (f) The area in or around the minor storage shall be kept free of combustible materials and residues. (g) Any materials that might react dangerously if mixed shall be kept apart so that the possibility of reaction is minimized, e.g. fuel and pool chorine. (h) Liquids should not be stored near any hot surfaces, e.g. steam pipes, furnace walls or engines, or where they might be accidentally exposed to heat, e.g. from escaping steam. (i) Liquids should be transferred and moved in manner that reduces the likelihood of spillage, vapour escape or fire. Control of ignition sources (flammable liquids only) Except for domestic premises, AS/NZS 2430.3.3 shall be consulted for hazardous atmosphere zoning if the volume of flammable liquids exceeds— (a) 100 L in closed containers; (b) 25 L for decanting purposes, e.g. petrol transfer to a motor vehicle or lawn mower; (c) 5 L in open containers for occasional use; or (d) 1 L in open containers for continuous use. There shall be no ignition sources in any space in which a flammable mixture of vapour and air could be present. WARNING: EVEN SMALL QUANTITIES OF FLAMMABLE LIQUID CAN CREATE A VAPOUR CLOUD THAT CAN TRAVEL CONSIDERABLE DISTANCES AND FLASHBACK TO ITS POINT OF GENERATION IF IT MEETS A SOURCE OF IGNITION. THIS IS PARTICULARLY THE CASE WHEN DECANTING OR IF THE LIQUID IS SPILT. Spillage Control All spills and leaks shall be cleaned up immediately. Any waste shall be disposed of safely and in accordance with the local regulations. Liquids should not be allowed to reach ignition sources, stores of other chemicals, or combustible materials (e.g. timber and paper), or flow into drains or onto neighbouring land, or enter any creek, pond or waterway. Precautions should be based at least on the loss of contents of the largest container kept. A simple spillage kit may consist of— (a) a metal bin with a tightly-fitting lid (plastics can be attacked by the liquid), partially filled with non-combustible absorbent such as vermiculite; (b) broom, shovel, face shield, chemically-resistant boots and gloves; and (c) a suitable respirator. Oils of animal or vegetable origin can oxidize, with the generation of heat and the possibility of spontaneous ignition if they are absorbed onto combustible absorbents. DGSM Information Paper No. 11 Licensing of Flammable and Combustible Liquids Storage (March 2005) CHEM services, Department of Emergency Services Page 5 Fire protection and warning signs At premises other than residences or farms, in locations where more than 100 L of flammable liquids, or more than 1000 L of combustible liquids are stored, or where flammable liquids are decanted, the following requirements apply: (a) At least one portable fire extinguisher, having a suitable rating for use with the range of materials being kept, shall be readily accessible and adjacent to the minor storage area. Where liquids are stored on open land, a fire extinguisher shall be provided if the liquids are decanted or transferred within 5 m of the storage. (b) In areas where flammable liquids are decanted, a sign bearing the words DANGER - FLAMMABLE LIQUID - NO SMOKING - KEEP FIRE AWAY shall be displayed. NOTE: Signs should comply with AS 1319. For retail areas with customer access, this requirement shall apply if the liquids are decanted or transferred, or are in packages having capacities of more than 25 L. A flammable liquid storage cabinet is designed for storage of small quantities of flammable liquids. AS1940 provides requirements for these. Figure 1 is an example of a flammable liquid storage cabinet. AS1940 Section 2 also states conditions for minor storage on open land and storage in tanks. DGSM Information Paper No. 11 Licensing of Flammable and Combustible Liquids Storage (March 2005) CHEM services, Department of Emergency Services Page 6 4. Classification of flammable and combustible liquids The words “flammable” and “combustible” have a very specific meaning within the context of fire prevention and suppression. In general, a flammable liquid burns more easily than a combustible liquid. More specifically, the Australian Dangerous Goods (ADG) Code makes the distinction between a flammable liquid and a combustible liquid based on the liquid’s flash point and boiling point. The division between flammable and combustible occurs at a flashpoint of 60.5oC. That temperature represents the upper limit of ambient temperature one might expect to encounter in all but the hottest climates. Liquids with a flash point below 60.5oC are flammable. Hazard grouping based on flammability for Class 3 materials Packing Group2 I II III Flash point (closed cup) <23 oC >23oC - 60.5oC Initial boiling point < 35 oC > 35 oC > 35 oC The ADG Code states that flammable liquids are liquids, or mixtures of liquids, or liquids containing solids in solution or suspension (e.g., paints, varnishes, lacquers) that give off a flammable vapour at temperatures of not more than 60.5oC (closed cup test), referred to as the flash point. Liquids meeting this criterion but with a flash point of more than 35oC that do not sustain combustion are not flammable liquids for the purposes of the ADG Code. Flammable liquids also include: • liquids offered for transport at temperatures at or above their flash point; and, • substances that are transported at elevated temperatures in a liquid state and that give off a flammable vapour at a temperature at or below the maximum transport temperature. Note: The flash point of flammable and combustible liquids may be altered by the presence of an impurity. Generally the flash point is quoted for a chemically pure substance. However, hydrocarbon liquids such as fuels and oils are composed of more than one type of hydrocarbon and hence the value quoted may vary depending on the relative composition. Commercial products may contain added substances or impurities, and hence flash points may vary. It is for reasons such as these that a range may be quoted for a flash point rather than a single value. This may have an effect on classification or determination of the Packing Group for the material. If there is doubt as to the flash point and thus the materials classification (details should be found on the product’s MSDS3), then check with the supplier, otherwise a flash point test should be performed by a reputable laboratory. 2 The Packing Group indicates the degree of danger presented by the substance when it is in its correct packaging during the course of transport. The packing groups are: PG I - items presenting great danger PG II - items presenting medium danger PG III - items presenting minor danger 3 MSDS means Material Safety Data Sheet, used to provide health and safety information about a product . DGSM Information Paper No. 11 Licensing of Flammable and Combustible Liquids Storage (March 2005) CHEM services, Department of Emergency Services Page 7 Viscous flammable liquids As stated in the ADG Code4, viscous flammable liquids such as paints, enamels, lacquers, varnishes, adhesives and polishers with a flash point of less than 23oC are included in Packing Group III provided that: a) b) c) less than 3% of the clear solvent layer separates in the solvent separation test; and the mixture does not contain any substance with a primary or a subsidiary risk5 of Class 6.1 or Class 8; and The viscosity and flash point are in accordance with Table 2 shown below. Table 2: Criteria for Flammable Viscous Substances Flow time (t seconds) 4 mm cup 6 mm cup 20 < t < 60 60 < t < 100 20 < t < 32 32 < t < 44 44 < t < 100 100 < t Flash point (°C) >17 >10 >5 >-1 >-5 -5 and below For further information on classification of flammable liquids, refer to the ADG Code, Addendum to Appendix 2, Assignment of Packing Groups Class 3, Vol 2 pp 21-24. Manufactured product is a Class 3 dangerous good of Packaging Group II or III, being a suspension or solution of a least 10% nonvolatile materials as determined by AS 1580, Method 301.1, of which less than 3% of the mobile solvent layer separates in the solvent separation test specified in Clause A6.2(a) of AS 1940 and the following viscosity criteria: a) a viscosity of at least 250 centistokes at 23°C; or b) requires stirring before use and has a viscosity of at least 20 centistokes. The term “manufactured product” essentially refers to paint products. These classifications help define the basis required under AS 1940 required for storage of flammable and combustible liquids to meet requirements of the legislation. Combustible Liquids A Combustible liquid is defined as any liquid other than a flammable liquid that has a flashpoint, and that has a firepoint less than its boiling point. For the purposes of AS1940, combustible liquids are divided into two classes as follows: Class C1 - a combustible liquid that has a flashpoint of 150°C or less, i.e. >60.5°C, <150°C. Class C2 - a combustible liquid that has a flashpoint exceeding 150°C. C1 and C2 are not to be confused with Class 1 or Class 2 dangerous goods. Combustible liquids are not considered to be dangerous goods whereas Class 3 flammable liquids are. 4 5 Australian Dangerous Goods Code 6th Edition, Volumes 1 & 2 Note: The container of the mixture is not necessarily required to bear a Class 6.1 or Class 8 subsidiary risk label. Refer to the MSDS. DGSM Information Paper No. 11 Licensing of Flammable and Combustible Liquids Storage (March 2005) CHEM services, Department of Emergency Services Page 8 Appendix 1 Table 2.1 (AS1940–2004) FACTORIES & WORKSHOPS Inside Outside and either; Class of liquid Manufactured products Flammable Combustible C1, C2 PGI, PGII 250L or 1L per 2 m2 floor space with no more than 250 L in any 500 m2 area PGIII 500L or 1L per 1 m2 of floor space with no more than 500L in any 500 m2 area 2,000L or 4L per 1 m2 floor space with no more than 2000L in any 500 m2 area (need > 500 m2 for additional storage) (need > 500 m2 for additional storage) (need > 500 m2 for additional storage) 250L As above (but generally up to 500L) 2,500L 250L 1,400L in tanks not over 700L each, or in packages 5,000L 2,000L in packages only, not tanks (a) in attached outhouse/ shed if separated by a partition having an FRL of 60/60/60; OR (b) outside or in a detached outhouse/shed separated from the factory or workshop by at least 1 m FACTORIES & WORKSHOPS STORING FCL ABOVE THESE QUANTITIES REQUIRE A LICENCE DGSM Information Paper No. 11 Licensing of Flammable and Combustible Liquids Storage (March 2005) CHEM services, Department of Emergency Services Page 9 Class of liquid SHOPS & WAREHOUSES Manufactured products Flammable PGI, PGII Inside 250L shop: no package >20L or 1L per 2 m2 floor space with no more than 250 L in any 2 500 m area (need > 500 m2 for additional storage) Combustible PGIII 500L or 2 1L per 1 m of floor space with no more than 500L in any 500 m2 area (need > 500 m2 for additional storage) C1, C2 2,000L or 2 4L per 1 m floor space with no more than 2000L 2 in any 500 m area (need > 500 m2 for additional storage) Flammable Products: 10,000L • • Outside plus either: (a) in attached outhouse/ shed if separated by a partition having an FRL of 60/60/60; 250L As above (but generally up to 500L) 2,500L 250L 1,400L in tanks not over 700L each or in packages 5,000L OR (b) outside or in a detached outhouse/shed separated from the factory or workshop by at least 1 m SHOPS & WAREHOUSES STORING FCL ABOVE THESE QUANTITIES REQUIRE A LICENCE DGSM Information Paper No. 11 Licensing of Flammable and Combustible Liquids Storage (March 2005) CHEM services, Department of Emergency Services Page 10 of which no more than 2,000L are PGII and provided that storage is in closed containers, not to be opened except for tinting paint for immediate sale Class of liquid OTHER BUILDINGS Manufactured products Flammable PGI, PGII Combustible PGIII C1, C2 Inside Commercial Buildings & Hospitals 10L per 50 m2 of floor space, but 5 L for any tenancy less than 50 m2 25L per 50 m2 of floor space, but 25 L for any tenancy less than 50 m2 500 L in total of C1 and C2 per 50 m2 of floor space, but 500 L for any tenancy less than 50 m2 Outside Commercial Buildings & Hospitals plus either: (a) in attached outhouse/ shed if separated by a partition having an FRL of 60/60/60; OR (b) outside or in a detached outhouse/shed separated from the factory or workshop by at least 1 m 250L As above (but generally up to 500L) 2,500L 250L 1,400L in tanks not over 700L each or in packages 5,000L Inside Educational Establishments 5L per 50 m2 of floor space 10L per 50 m2 of floor space 500 L in total of C1 and C2 per 50 m2 of floor space Inside Laboratories 50L per 50 m2 of floor space 100 L per 50 m2 of floor space 200 L in total of C1 & C2 The limit for any manufactured product is the same as for a liquid of the same packing group COMMERCIAL BUILDINGS, HOSPITALS, EDUCATIONAL ESTABLISHMENTS & LABORATORIES THAT STORE FCL ABOVE THESE QUANTITIES REQUIRE A LICENCE DGSM Information Paper No. 11 Licensing of Flammable and Combustible Liquids Storage (March 2005) CHEM services, Department of Emergency Services Page 11 Class of liquid SERVICE STATIONS Manufactured products Flammable PGI, PGII Inside Outdoors 500L total in packages • Packages in sales area shall be unopened. • not > 20L capacity Combustible PGIII 1,250L total in tanks or packages C1, C2 3,000L total C1 & C2 2000L (in packages only not tanks) An additional 1,000L in packages only SERVICE STATIONS MAY STORE THE ABOVE QUANTITIES OF FCL AS MINOR STORAGE DGSM Information Paper No. 11 Licensing of Flammable and Combustible Liquids Storage (March 2005) CHEM services, Department of Emergency Services Page 12 RESIDENTIAL BUILDING OF ANY TYPE Class of liquid Flammable Manufactured products Combustible PGI, PGII PGIII C1, C2 Within a dwelling 5L 25 L 50 L 50 L In a garage attached to a dwelling with a 60/60/60 FRL rating separation wall 25 L 50 L 100 L 250 L Outdoors, or in a shed or garage, separated from the dwelling or any other building by 1 m space 100 L 250 L 500 L Outdoors, uncovered, or in a shed or garage, separated from the dwelling or any structure or boundary by either 3m of space or a wall having an FRL of 180/180/180 250 L 250 L 250 L 500 L 250 L A supply tank for domestic oil-fired appliances installed in accordance with AS 1691 is excluded from any calculation of the quantity stored on the premises. STORAGE IN OR AROUND RESIDENTIAL BUILDINGS SHOULD NOT EXCEED ABOVE QUANTITIES WITHOUT A LICENCE (Note - there may be Town Planning restrictions on the storage of dangerous goods in residential areas) NOTES: • In the case of laboratories, commercial buildings and the like, this Table is intended to cater for the day-to-day working stock in the laboratory or workroom. If these quantities are to be exceeded, it will be necessary to install a cabinet or major store facility according to the scale needed. • It is permissible to store at the same time on the same area, the maximum permissible allowance for each or all of the other classes of liquids. • Where the maximum allowance is specified in terms of quantity per unit area, any arrangement which results in concentration at one point should be avoided. Such aggregation contravenes the intent of minor storage, which is dispersal, and additional storage provisions may be required. DGSM Information Paper No. 11 Licensing of Flammable and Combustible Liquids Storage (March 2005) CHEM services, Department of Emergency Services Page 13 Appendix 2: Data on some common flammable and combustible liquids Note: values shown are indicative only. Flash Point and Boiling Point may vary considerably for a particular product such as crude oil, petrol, and oils depending on the source/supplier. Always check the chemical property information with the supplier and in the MSDS for the product. Product UN Number Flash point oC Flammable Liquids Carbon Disulphide 1131 -30 Crude Oil 1267 <20 Diethyl ether 1155 -4 Isopropylamine 1221 -32 Acetal 1088 -14 Acetone 1090 -17 Acetonitrile 1648 5 Adhesives 1133 -1 Benzene 1114 -11 Cyclohexane 1145 -20 Ethanol 1170 13 Isopropyl alcohol 1219 12 Lacquer thinner 1263 -1 Methanol 1230 12 Methyl ethyl ketone (MEK) 1193 -4 Methyl isobutyl ketone (MIBK) 1245 14 Methyl methacrylate 1247 11 Petrol 1203 <-30 Tetrahydrofuran (THF) 2056 -14 Toluene 1294 5 Vinyl acetate 1301 -7 Jet Fuel (Aviation Turbine Fuel/JetA1) 1863 38-57 Kerosene 1223 40 Mineral Turpentine/ White Spirit 1300 33-36 Xylene 1307 24-26 Combustible Liquids Diesel fuel >61 Fuel Oil >61 Heating Oil >61 Lube Oil >150 Waste Oil variable Boiling Point oC Packing Group 46 0-540 35 33-34 102 56 81 Not avail. 80 81 78 82 78-134 63-65 79 114 101 30-228 66 110 72-73 150-280 160-250 145-200 138-140 I I I I II II II II II II II II II II II II II II II II II III III III III 200-400 >200 150-285 >280 variable C1 C1 C1 C2 variable DGSM Information Paper No. 11 Licensing of Flammable and Combustible Liquids Storage (March 2005) CHEM services, Department of Emergency Services Page 14
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