1 UNIT 3 NOTES: PHASE CHANGES Essential Question Explain how matter changes phase and what causes it. 2 The State of Matter of a substance depends on several things • Attraction between particles called IMF or InterMolecular Forces • Solids have very high IMF • Gases have no attraction between molecules • Liquids have IMF a bit lower than solids • Energy of the particles • Space between particles 3 PHASE CHANGES Energy added Melting: Solid to Liquid Vaporizing: Liquid to Gas Sublimation: Solid to Gas Energy removed Freezing: Liquid to Solid Condensing: Gas to Liquid Deposition: Gas to Solid 4 HEATING CURVE Temperature Vaporizing Gas Liquid Melting Solid Energy 5 COOLING CURVE Temperature Gas Condensing Liquid Freezing Solid Energy 6 Energy – causes changes in matter weightless, odorless, tasteless All chemical reactions and changes in state involve either: a) release of energy, called Exothermic or b) absorption of energy called Endothermic 7 The Law of Conservation of Energy states that in any chemical or physical process, energy is neither created nor destroyed. All the energy is accounted for as Eth Eph or Ech 8 UNIT 3: HEAT CAPACITY NOTES Essential Question: Which substance will heat up quicker and explain why? Ethanol 2.44J/g̊C or Graphite 0.709J/g̊C 9 Heat Capacity - the amount of heat needed to increase the temperature of an object exactly 1 oC Depends on both the object’s mass and its chemical composition Specific Heat Capacity (abbreviated “C”) - the amount of heat it takes to raise the temperature of 1 gram of the substance by 1 oC 10 The higher a material’s specific heat the LONGER it take to heat up and the LONGER it takes to cool down. ex. metals have low specific heat which means they heat up and cool down quickly. 11 UNITS OF ENERGY (HEAT) 1) A calorie is defined as the quantity of heat needed to raise the temperature of 1 g of pure water 1 oC. 1 Food Calorie = 1 kilocalorie = 1000 cal. 2) The Joule, the SI unit of heat and energy 4.184 J = 1 cal 12 HOW TO SOLVE HEAT CAPACITY PROBLEMS: Q = mc∆T Q = mHv Q = mc∆T Q = mHf Q = mc∆T 13 MEANING OF FORMULA SYMBOLS Q = heat or energy unit calories or joules (1 cal = 4.18 joules) m = mass in grams c = specific heat –it is different for each substance and phase of matter. J/g°C or cal/g°C ∆T = Change in temperature (Tempfinal – Tempinitial) Hf = Heat of fusion or melting. Energy needed for a phase change. Hv = Heat of vaporization or condensation. Energy needed for a phase change. 14 Energy Constants For water c solid = 2.1 J/g°C or 0.5 cal/g°C 1 kcal = 1000 cal c liquid = 4.18 J/g°C or 1 cal/g°C 1 kJ = 1000 J c vapor = 1.8 J/g°C or 0.44 cal/g°C Hf = 334 J/g or 80 cal/g Hv = 2260J/g or 540 cal/g 15 UNIT 3 NOTES: ENDOTHERMIC AND EXOTHERMIC REACTIONS Essential Question: Explain the difference between endothermic and exothermic reactions 16 Endothermic Reactions Eth flowing into a system from it’s surroundings: Q has a positive value system gains heat (gets warmer) as the surroundings cool down 17 Exothermic reactions Eth flowing out of a system into it’s surroundings: Q has a negative value system loses heat (gets cooler) as the surroundings heat up 18 IN YOUR NOTEBOOK CREATE THE ENERGY BAR CHART FOR THIS SITUATION Hot steam from your shower cools and condenses on the bathroom mirror 19
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