1. Which statement describes the particles of an ideal gas based on the kinetic molecular theory? A) The gas particles are relatively far apart and have negligible volume. B) The gas particles are in constant, nonlinear motion. C) The gas particles have attractive forces between them. D) The gas particles have collisions without transferring energy. 2. A sample of a gas is contained in a closed rigid cylinder. According to kinetic molecular theory, what occurs when the gas inside the cylinder is heated? A) The number of gas molecules increases. B) The number of collisions between gas molecules per unit time decreases. C) The average velocity of the gas molecules increases. D) The volume of the gas decreases. 3. An assumption of the kinetic theory of gases is that the particles of a gas have A) little attraction for each other and a significant volume B) little attraction for each other and an insignificant volume C) strong attraction for each other and a significant volume D) strong attraction for each other and an insignificant volume 6. A cylinder with a tightly fitted piston is shown in the diagram below. As the piston moves downward, the number of molecules of air in the cylinder A) decreases C) remains the same B) increases 7. What volume will a 300.-milliliter sample of a gas at STP occupy when the pressure is doubled at constant temperature? 8. When a base is dissolved in water it releases A) hydrogen ions C) hydroxide ions B) hydronium ions D) oxide ions 9. A base reacts with an acid to produce A) B) C) D) ammonia and methane ammonia and a salt water and methane water and a salt 10. What are the relative ion concentrations in an acid solution? A) B) C) D) more H + ions than OH – ions fewer H+ ions than OH – ions an equal number of H + ions and OH– ions H+ ions but no OH – ions 4. A cylinder with a movable piston contains a sample of 11. The OH– ion concentration is greater than the H + ion concentration in a water solution of gas having a volume of 6.0 liters at 293 K and 1.0 atmosphere. What is the volume of the sample after A) CH 3OH B) Ba(OH) 2 the gas is heated to 303 K, while the pressure is held C) HCl D) H2SO 4 at 1.0 atmosphere? 12. Which solution reacts with LiOH(aq) to produce a 5. Which two samples of gas at STP contain the same salt and water? total number of molecules? A) KCl(aq) B) CaO(aq) A) 1 L of CO(g) and 0.5 L of N2(g) C) NaOH(aq) D) H2SO 4(aq) B) 2 L of CO(g) and 0.5 L of NH 3(g) 13. The attraction between water molecules and an Na + C) 1 L of H2(g) and 2 L of Cl2(g) ion or a Cl– ion occurs because water molecules are D) 2 L of H2(g) and 2 L of Cl2(g) A) linear B) symmetrical C) polar D) nonpolar 14. Under which conditions of temperature and pressure is a gas most soluble in water? A) B) C) D) high temperature and low pressure high temperature and high pressure low temperature and low pressure low temperature and high pressure 15. At room temperature, the solubility of which solute in water would be most affected by a change in pressure? A) methanol C) carbon dioxide B) sugar D) sodium nitrate 16. The molarity of an aqueous solution of NaCl is defined as the A) B) C) D) grams of NaCl per liter of water grams of NaCl per liter of solution moles of NaCl per liter of water moles of NaCl per liter of solution 17. What is the molarity of 1.5 liters of an aqueous solution that contains 52 grams of lithium fluoride, LiF, (gram-formula mass = 26 grams/mole)? 18. Which preparation produces a 2.0 M solution of C 6H 12O 6 ? [molecular mass = 180.0] A) 90.0 g of C 6H12O6 dissolved in 500.0 mL of solution B) 90.0 g of C 6H12O6 dissolved in 1000. mL of solution C) 180.0 g of C 6H12O6 dissolved in 500.0 mL of solution D) 180.0 g of C 6H12O6 dissolved in 1000. mL of solution 19. A barium atom attains a stable electron configuration when it bonds with A) B) C) D) one chlorine atom two chlorine atoms one sodium atom two sodium atoms A) B) C) D) 22. Based on electronegativity values, which type of elements tends to have the greatest attraction for electrons in a bond? A) metals C) nonmetals B) metalloids D) noble gases 23. The bonds in BaO are best described as A) covalent, because valence electrons are shared B) covalent, because valence electrons are transferred C) ionic, because valence electrons are shared D) ionic, because valence electrons are transferred 24. What is the total number of electrons shared in a double covalent bond? A) 1 B) 2 C) 3 D) 4 25. Which two substances are covalent compounds? A) B) C) D) C6 H12 O6 (s) and KI(s) C6 H12 O6 (s) and CO 2(g) KI(s) and NaCl(s) NaCl(s) and HCl(g) 26. Covalent bonds are formed when electrons are A) B) C) D) transferred from one atom to another captured by the nucleus mobile within a metal shared between two atoms 27. Which type of bond is found between atoms of solid cobalt? 20. When a sodium atom reacts with a chlorine atom to form a compound, the electron configurations of the ions forming the compound are the same as those in which noble gas atoms? A) krypton and neon C) neon and helium 21. Which is the correct electron-dot formula for a molecule of chlorine? B) krypton and argon D) neon and argon A) nonpolar covalent B) polar covalent C) metallic D) ionic 28. A solid substance is an excellent conductor of electricity. The chemical bonds in this substance are most likely A) ionic, because the valence electrons are shared between atoms B) ionic, because the valence electrons are mobile C) metallic, because the valence electrons are stationary D) metallic, because the valence electrons are mobile 29. An atom in the ground state has two electrons in its first shell and six electrons in its second shell. What is the total number of protons in the nucleus of this atom? A) 5 B) 2 C) 7 D) 8 30. An ion that consists of 7 protons, 6 neutrons, and 10 electrons has a net charge of A) 4– B) 3– C) 3+ D) 4+ 31. Every chlorine atom has A) B) C) D) 7 electrons 17 neutrons a mass number of 35 an atomic number of 17 A) total mass of all the protons and neutrons in an atom of Ti B) total mass of all the protons, neutrons, and electrons in an atom of Ti C) weighted average mass of the most abundant isotope of Ti D) weighted average mass of all the naturally occurring isotopes of Ti 33. If an element, X, can form an oxide that has the formula X2O3, then element X would most likely be located on the Periodic Table in the same group as B) Cd C) Al D) Na 34. Bronze contains 90 to 95 percent copper and 5 to 10 percent tin. Because these percentages can vary, bronze is classified as A) a compound C) a mixture A) B) C) D) homogeneous compound homogeneous mixture heterogeneous compound heterogeneous mixture 36. A 1.0-mole sample of krypton gas has a mass of A) 19 g B) 36 g C) 39 g D) 84 g 37. What is the total number of moles of oxygen atoms in 1 mole of N 2O3? A) 1 B) 2 B) an element D) a substance C) 3 D) 5 38. What is the total mass of oxygen in 1.00 mole of Al 2(CrO4) 3? A) 192 g C) 64.0 g B) 112 g D) 48.0 g 39. What is conserved in the reaction shown below? N2(g) + 3F2(g) 2NF 3(g) A) atoms only C) mass and atoms 32. The atomic mass of titanium is 47.88 atomic mass units. This atomic mass represents the A) Ba 35. A sample is prepared by completely dissolving 10.0 grams of NaCl in 1.0 liter of H 2O. Which classification best describes this sample? B) mass only D) moles only 40. How many moles of aluminum are needed to react completely with 1.2 mol of FeO? 2Al(s) + 3FeO(s) 3Fe(s) + Al2O3(s) A) 1.2 mol C) 1.6 mol B) 0.8 mol D) 2.4 mol 41. Methane and hydrogen sulfide form when hydrogen reacts with carbon disulfide. Identify the excess reagent and calculate how much remains after 36 L of H reacts with 12 L of CS. 4H2(g) + CS 2(g) CH 4(g) + 2H 2S(g) A) 3 L B) 6 L C) 9 L D) 12 L 42. Given the reaction N2(g) + 3 H2(g) ® 2 NH3(g) How many liters of ammonia, measured at STP, are produced when 28.0 grams of nitrogen is completely consumed? A) 5.60 B) 11.2 C) 22.4 D) 44.8 43. Which formula represents strontium phosphate? A) SrPO4 C) Sr 2(PO4) 3 B) Sr 3PO 8 D) Sr 3(PO4) 2 44. What is the chemical formula for iron(III) oxide? A) FeO C) Fe 3O B) Fe 2O3 D) Fe 3O2 45. The formula for nitrogen dioxide is A) N4O B) N2O2 C) N2O D) NO 2 46. Base your answer to the following question on the information below. A 1.0-gram strip of zinc is reacted with hydrochloric acid in a test tube. The unbalanced equation below represents the reaction. ____ Zn(s) + ____HCl(aq) ____H2(g) + ____ ZnCl2(aq) Balance the equation for the reaction of zinc and hydrochloric acid, using the smallest whole-number coefficients. 47. Which compound can be classified as an electrolyte? A) B) C) D) carbon tetrachloride sugar hydrochloric acid distilled water A) 3.0 M C) 0.75 M 49. A gas occupies a volume of 444 mL at 273 K and 79.0 kPa. What is the final kelvin temperature when the volume of the gas is changed to 1880 mL and the pressure is changed to 38.7 kPa? 50. Given the equation: OH–(aq) NH 3(g) + H 2O( ) --> + + The reactant that donates a H ion in the reaction is 51. What are the products of a reaction between KOH(aq) and HCl(aq)? A) H2O and KCl C) KH and HClO B) 0.33 M D) 6.0 M 53. A solution at 25°C with a pH of 7 contains 48. A cylinder with a movable piston contains a sample of gas having a volume of 6.0 liters at 293 K and 1.0 atmosphere. What is the volume of the sample after the gas is heated to 303 K, while the pressure is held at 1.0 atmosphere? NH 4+ (aq) 52. What is the molarity of an H 2SO 4 solution if 0.25 liter of the solution contains 0.75 mole of H 2SO 4? B) H2 and KClO D) KOH and HCl A) B) C) D) more H 3O+ ions than OH – ions fewer H3O+ ions than OH – ions an equal number of H 3O+ ions and OH– ions no H3O+ ions or OH – ions 54. What is the correct formula for nitrous acid? A) H3N C) HNO2 B) HNO3 D) H2NO 2 55. The products of a neutralization reaction between a base and an acid are A) B) C) D) ammonia and methane ammonia and a salt water and methane water and a salt 56. The attraction between water molecules and a K + ion or a Br – ion occurs because water molecules are A) linear C) polar B) symmetrical D) nonpolar 57. The bonds in CaO are best described as A) covalent, because valence electrons are shared B) covalent, because valence electrons are transferred C) ionic, because valence electrons are shared D) ionic, because valence electrons are transferred 58. Which formula represents iron(III) phosphate? A) FePO 4 C) Fe 2(PO4) 3 B) Fe 3PO 8 D) Fe 3(PO4) 2 59. What is the chemical formula for dinitrogen trioxide? A) NO B) N2O3 C) N3O D) N3O2 60. A student tested a 0.1 M aqueous solution and made the following observations: • conducts electricity • turns blue litmus to red • reacts with Zn(s) to produce gas bubbles 66. An atom of argon rarely bonds to an atom of another element because an argon atom has A) B) C) D) 2 electrons in the first shell 8 valence electrons 3 electron shells 22 neutrons 67. The bonds in P 2O5 are best described as A) covalent, because valence electrons are shared B) covalent, because valence electrons are transferred C) ionic, because valence electrons are shared D) ionic, because valence electrons are transferred 68. When ionic bonds are formed, metallic atoms tend to A) B) C) D) lose electrons and form anions lose electrons and form cations gain electrons and form anions gain electrons and form cations 69. Which substance is not an electrolyte? Which compound could be the solute in this solution? A) NH 3 C) HBr B) LiBr D) LiOH 61. Which compounds can be classified as electrolytes? A) B) C) D) Carbon tetrachloride sugar hydrochloric acid distilled water A) True B) False 63. What property of water enables a water strider to walk on water? B) High heat capacity D) Universal solvent 64. Which property of water allows nutrients from food to be carried by the blood to all of the body's cells? A) High heat capacity B) Universal solvent C) Cohesion D) Adhesion 65. Which formula represent hydroiodic acid? A) HBr B) HCl C) HF 70. What is the correct name for NH 4Cl A) B) C) D) nitrogen hydrochloric (IV) acid nitrogen hydrogen choride ammonium chloride nitrogen tetrahydrochloride 71. ________ gain electrons and _________ lose electrons when forming ionic bonds. 62. Always add acid to water when diluting acids. A) Transparency C) Cohesion A) K2O B) CO 2 C) NaCl D) KOH D) HI A) B) C) D) cations; anions metals; non-metals anions; cations none of the above 72. What is the mass in grams of 5.90 mol C 8H18? A) 0.0512 g C) 389 g B) 19.4 g D) 673 g 73. Which equation represents a decomposition reaction? A) CaCO 3(s) CaO(s) + CO 2(g) B) Cu(s) + 2AgNO 3(aq) 2Ag(s) + Cu(NO3) 2(aq) C) 2H2(g) + O 2(g) 2H2O(l) D) KOH(aq) + HCl(aq) KCl(aq) + H 2O(l) 74. The total number of molecules in 34.0 grams of NH 3 is equal to A) B) C) D) 22.4 molecules of NH 3 44.8 molecules of NH 3 6.02 × 10 23 molecules of NH 3 1.20 × 10 24 molecules of NH 3 75. What is the total mass in grams of 0.75 mole of sulfur dioxide? A) 16 g B) 24 g C) 32 g D) 48 g 76. A covalent bond is formed when a chemical reaction occurs between atoms of A) B) C) D) chlorine and potassium chlorine and zinc oxygen and fluorine oxygen and magnesium 77. Given the Lewis structure for nitrogen: What is the total number of electrons shared between the atoms represented in this diagram? A) 1 B) 2 C) 4 D) 6 78. Which element consists of positive ions immersed in a "sea" of mobile electrons? A) oxygen C) gold B) nitrogen D) chlorine 79. Chlorine gas is bubbled through a solution of sodium bromide to form bromine gas and sodium chloride. Which equation represents this reaction? A) B) C) D) Cl 2 + 2NaBr --> 2NaCl + Br 2 Cl 2 + 2NaBr --> 2NaCl + 2Br 2Cl + 2NaBr --> 2NaCl + Br 2 Cl + Na2Br --> Na 2Cl + Br 80. The sum of the atomic masses of the atoms in one molecule of C3H6Br 2 is called the A) B) C) D) molar mass isotopic mass percent abundance percent composition 81. Given the unbalanced equation: When the equation is balanced using the smallest whole-number coefficients, what is the mole ratio of aluminum to copper? A) B) C) D) 1 mole of aluminum : 1 mole of copper 2 moles of aluminum : 3 moles of copper 3 moles of aluminum : 2 moles of copper 2 moles of aluminum : 1 mole of copper 82. Given the balanced equation: 86. Given the unbalanced equation: F2(g) + H 2(g) 2HF(g) How many grams of HF would be produced if 4 moles of H 2 reacted with excess F 2? A) 80g HF C) 40g HF B) 160g HF D) 20g HF 83. Based on the equation: 2 Al + 3 Ni(NO 3) 2 A) 6 2 Al(NO 3) 3 + 3 Ni If 50 grams of Al react with 100 grams of Ni(NO 3) 2, what is the limiting reactant? 84. Given the unbalanced chemical equation: K + Br2 KBr If 100 grams of K react with 100 grams of Br 2, how many grams of KBr will be formed? A) 200 grams C) 149 grams B) 100 grams D) 74 grams 85. Given the unbalanced chemical equation: ____ Zn(s) + ____HCl(aq) ZnCl2(aq) ____H2(g) + ____ If a student began an experiment with 9.74 grams of zinc and produced an experimental (actual) yield of 0.227 grams of H2, what is the percent yield of H 2? A) 73.5% C) 61.3% When this equation is correctly balanced using smallest whole numbers, what is the coefficient of O 2 (g)? B) 2.2% D) 33.9% B) 2 C) 3 D) 4 87. Given the balanced reaction: 2 C2H2(g) + 5 O 2(g) 4 CO 2(g) + 2 H 2O(g) What is the total number of grams of O 2(g) needed to react completely with 0.50 mole of C 2H2(g)? A) 10. g C) 80. g B) 40. g D) 160 g 88. Given the balanced reaction: C6H6 + Br 2 C6H5Br + HBr If 2 moles of benzene (C 6H6) are combined with 3 moles of bromine, what is the theoretical yield of HBr? A) 81 grams C) 243 grams B) 162 grams D) 405 grams 89. Which of the following pH values indicates the highest concentration of hydrogen ions in a solution? A) pH = 1 C) pH = 9 B) pH = 5 D) pH = 14 90. When a base is dissolved in water it yields A) hydrogen ions C) hydroxide ions B) hydronium ions D) oxide ions 91. Base your answer to the following question on the following balanced equation representing a reaction: Show your work!!! 2H2 + O2 2H2O What is the Limiting Reactant/ Reagent if 20 grams of oxygen with 7 grams of hydrogen to produce water? 92. According to solubility graph, which compound is least soluble in water at 60. °C? A) KClO 3 C) NaCl B) KNO3 D) NH 4Cl 93. According to the solubility graph, which substance forms an unsaturated solution when 80 grams of the substance is dissolved in 100 grams of H2O at 10°C? A) KI C) NaNO3 B) KNO3 D) NaCl 94. Which equation represents a single replacement reaction? A) B) C) D) 95. Given the balanced equations representing two chemical reactions: Cl 2 + 2NaBr 2NaCl + Br2 2NaCl 2Na + Cl2 Which type of chemical reactions are represented by these equations? A) B) C) D) single replacement and decomposition single replacement and double replacement synthesis and decomposition synthesis and double replacement 96. The volume of a sample of a gas at 273°C is 200. liters. If the volume is decreased to 100. liters at constant pressure, what will be the new temperature of the gas? A) 0 K C) 273 K B) 137. K D) 546 K 97. Which set of values represents standard pressure and standard temperature? A) B) C) D) 1 atm and 101.3 K 1 kPa and 273 K 101.3 kPa and 0°C 101.3 atm and 273°C 98. At 25ºC, gas in a rigid cylinder with a movable piston has a volume of 145 mL and a pressure of 125 kPa. Then the gas is compressed to a volume of 80. mL. What is the new pressure of the gas if the temperature is held at 25ºC? A) 69 kPa C) 160 kPa B) 93 kPa D) 230 kPa 99. A rigid cylinder contains a sample of gas at STP. What is the pressure of this gas after the sample is heated to 410 K? A) 1.0 atm C) 0.67 atm B) 0.50 atm D) 1.5 atm 100. Which graph represents the relationship between pressure and volume for a sample of an ideal gas at constant temperature? A) B) C) D)
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