1 (a) Which ionizing radiation produces the greatest number of ion pairs per mm in air? Tick (✓) the correct answer. α particles β particles γ rays X−rays (1) (b) (i) Complete the table showing the typical maximum range in air for α and β particles. Type of radiation Typical range in air / m α β (2) (ii) γ rays have a range of at least 1 km in air. However, a γ ray detector placed 0.5 m from a γ ray source detects a noticeably smaller count-rate as it is moved a few centimetres further away from the source. Explain this observation. ............................................................................................................... ............................................................................................................... ............................................................................................................... (1) (c) Following an accident, a room is contaminated with dust containing americium which is an α−emitter. Explain the most hazardous aspect of the presence of this dust to an unprotected human entering the room. ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ (2) (Total 6 marks) Page 1 of 51 2 (a) In a radioactivity experiment, background radiation is taken into account when taking corrected count rate readings in a laboratory. One source of background radiation is the rocks on which the laboratory is built. Give two other sources of background radiation. source 1 ......................................................................................................... source 2 ......................................................................................................... (1) (b) A γ ray detector with a cross-sectional area of 1.5 × 10–3 m2 when facing the source is placed 0.18 m from the source. A corrected count rate of 0.62 counts s–1 is recorded. (i) Assume the source emits γ rays uniformly in all directions. Show that the ratio is about 4 × 10–3. (2) (ii) The γ ray detector detects 1 in 400 of the γ photons incident on the facing surface of the detector. Calculate the activity of the source. State an appropriate unit. answer = ................................... unit ........................................... (3) Page 2 of 51 (c) Calculate the corrected count rate when the detector is moved 0.10 m further from the source. answer = .......................... counts s–1 (3) (Total 9 marks) 3 (a) Bi can decay into Pb by a β– followed by an α decay, or by an α followed by a β– decay. One or more of the following elements is involved in these decays: Write out decay equations showing each stage in both of these decays. First decay path Second decay path (6) Page 3 of 51 (b) (i) Describe how you would perform an experiment that demonstrates that gamma radiation obeys an inverse square law. ............................................................................................................. ............................................................................................................. ............................................................................................................. ............................................................................................................. ............................................................................................................. ............................................................................................................. ............................................................................................................. ............................................................................................................. ............................................................................................................. ............................................................................................................. (ii) Explain why gamma radiation obeys an inverse square law but alpha and beta radiation do not. ............................................................................................................. ............................................................................................................. ............................................................................................................. ............................................................................................................. ............................................................................................................. (9) (Total 15 marks) 4 A freshly prepared radioactive source that emits negatively charged beta particles (β–) has an activity of 120 Bq and a half-life of 12 h. (a) (i) State the effect on the proton number Z and the nucleon number A when a β– particle is emitted. ............................................................................................................... ............................................................................................................... (2) Page 4 of 51 (ii) Sketch, on the axes below, a graph that shows how the activity varies during the two days after the source was prepared. (3) (b) (i) The total energy released in each decay is 5.5 × 10–13 J. Calculate the initial energy produced each second by the source. initial energy ..................................... J (1) (ii) Figure 1 shows the energy spectrum for the beta particles emitted in the decay. It shows that different energy beta particles are possible. Figure 1 Page 5 of 51 Explain why all the beta particles that are emitted do not have 5.5 × 10–13 J of energy. ............................................................................................................... ............................................................................................................... ............................................................................................................... ............................................................................................................... ............................................................................................................... (3) (c) The probability of one of the radioactive atoms decaying each second is 1.6 × 10–5. How many radioactive atoms are present when the activity is 120 Bq? number of radioactive atoms ................................... (1) (d) A scientist undertaking an investigation places the freshly prepared source close to a Geiger-Müller tube as shown in Figure 2 and records a count rate of 50 counts per second. Figure 2 State and explain two reasons why the measured count rate is lower than the activity of the source. ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ (2) (Total 12 marks) Page 6 of 51 5 An isotope of technetium is a gamma emitter used by doctors as a tracer in the human body. It is injected into the patient’s blood stream. Scanners outside the body measure the gamma activity, enabling the blood flow to be monitored. (a) The graph shows the variation of activity with time, t, for a sample of the isotope. (i) Use data from the graph to determine the half-life of the technetium isotope. (3) (ii) The decay constant of the technetium isotope is 3.2 × 10−5 s−1. Use data from the graph and the equation A = λN to calculate the number of nuclei of the radioactive technetium isotope present at time t = 0. (2) (b) (i) State why an alpha emitter would not be suitable in this application. ............................................................................................................... ............................................................................................................... (1) (ii) State why the half-life of the technetium isotope makes it suitable for this application. ............................................................................................................... ............................................................................................................... (1) Page 7 of 51 (c) State and explain how the presence of the technetium isotope may do some damage to the patient. ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ (2) (Total 9 marks) 6 The actinium series of radioactive decays starts with an isotope of uranium, nucleon (mass) number 235, proton (atomic) number 92. Which line in the table shows the nucleon number and proton number of the isotope after the emission of 5 α particles and 2 β– particles? Nucleon number proton number A 213 82 B 215 80 C 215 84 D 227 87 (Total 1 mark) 7 An alpha particle moves at one-tenth the velocity of a beta particle. They both move through the same uniform magnetic field at right angles to their motion. The magnitude of the ratio is A B C D (Total 1 mark) Page 8 of 51 8 Iodine-123 is a radioisotope used medically as a tracer to monitor thyroid and kidney functions. The decay of an iodine-123 nucleus produces a gamma ray which, when emitted from inside the body of a patient, can be detected externally. (a) Why are gamma rays the most suitable type of nuclear radiation for this application? ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ (2) (b) In a laboratory experiment on a sample of iodine-123 the following data were collected. time/h 0 4 8 12 16 20 24 28 32 count-rate /counts s–1 512 410 338 279 217 191 143 119 91 Why was it unnecessary to correct these values for background radiation? ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ (2) Page 9 of 51 (c) On the axes provided in the diagram below, complete the graph of count-rate against time. (2) (d) Use your graph to find an accurate value for the half-life of iodine-123. Show clearly the method you use. Half-life .............................. (3) Page 10 of 51 (e) Give two reasons why radioisotopes with short half-lives are particularly suitable for use as a medical tracer. ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ (2) (Total 11 marks) 9 The radioisotope iodine-131 ( ) is used in medicine to treat over-active thyroid glands. It decays into an isotope of xenon (Xe) by β– emission with a half-life of 8.1 days. The xenon subsequently emits a γ ray. (a) Explain what is meant by: (i) isotope; ............................................................................................................... ............................................................................................................... (2) (ii) half-life. ............................................................................................................... ............................................................................................................... (1) (b) Write down the equation which represents the nuclear reaction. (3) (c) Calculate the time (in days) for a sample of iodine to decay to 1% of its initial activity. (4) Page 11 of 51 (d) State and explain which decay product can be detected outside the body during treatment. ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ (2) (Total 12 marks) 10 The diagram below shows an arrangement used to maintain a constant thickness of sheet paper or steel as it is being rolled. A radioactive source and detector are used to monitor the thickness. (a) Explain briefly how this arrangement works. ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ (3) Page 12 of 51 (b) Alpha, beta or gamma sources could be selected for use in such an arrangement. State which source should be selected in each case and explain briefly why the others would not be suitable. Paper: Source selected ............................................................................................. Reasons why the others are unsuitable ........................................................ ........................................................................................................................ ........................................................................................................................ Steel: Source selected ............................................................................................. Reasons why the others are unsuitable ........................................................ ........................................................................................................................ ........................................................................................................................ (4) (c) Cobalt-60 is commonly used as a source in such applications. This has a half-life of 5.3 years. When fresh the source contains 5.0 × 1020 radioactive atoms. For it to be useful the source has to have an activity of at least 1.5 × 1012 Bq. (i) What is meant by an activity of 1 Bq? ............................................................................................................... ............................................................................................................... (1) (ii) Draw a graph showing the number of radioactive atoms in the source over a period of 3 half-lives. Include suitable scales on the axes. (2) Page 13 of 51 (iii) Determine the decay constant of cobalt-60 in s–1. (2) (iv) After what time will it be necessary to replace the source? (3) (Total 15 marks) 11 is an isotope of uranium which decays through a decay chain to the isotope of lead, which is stable. During the sequence of decays, both alpha particles and beta particles are emitted. (a) (i) , represents an alpha particle. State the values of: A .................................................................... Z .................................................................... (1) (ii) represents a beta particle. State the values of: A .................................................................... Z .................................................................... (1) (iii) State and explain how many alpha particles are emitted during the decay chain between . ............................................................................................................... ............................................................................................................... ............................................................................................................... (2) (iv) State and explain how many beta particles are emitted during the decay chain between and . ............................................................................................................... ............................................................................................................... ............................................................................................................... (2) Page 14 of 51 (b) The decay of uranium can be used to measure the age of rocks. A rock, which contained N0 atoms of (i) when it was formed, will contain NU atoms of the isotope at a later time t. The relationship between N0, NU and t is: NU = N0e–λt State the meaning of the decay constant, λ. ............................................................................................................... ............................................................................................................... (1) (ii) Because the half-life of is much longer than that of any other member of the decay chain, it may be assumed that the number of atoms of present at time t is equal to the number of atoms which have decayed. Show that the ratio of the number of lead atoms (NP) to the number of uranium atoms at time t is given by: = eλt – 1 (2) (iii) The half-life of is 4.5 × 109 year. Calculate the age of a rock sample which contains 4.2 parts per million of and 0.62 parts per million of . (4) (iv) The above analysis assumes that the rock contained no lead when it was formed. State and explain the effect on the estimated age if the rock had contained lead when it was formed. ............................................................................................................... ............................................................................................................... ............................................................................................................... ............................................................................................................... (2) Page 15 of 51 (v) State reasons why the measurement of the amount of uranium in a rock sample would be inaccurate when performed by a radiation counting technique. ............................................................................................................... ............................................................................................................... ............................................................................................................... ............................................................................................................... (2) (Total 17 marks) 12 Potassium-42 decays with a half-life of 12 hours. When potassium-42 decays it emits β– particles and gamma rays. One freshly prepared source has an activity of 3.0 × 107 Bq. (a) To determine the dose received by a scientist working with the source the number of gamma ray photons incident on each cm2 of the body has to be known. One in every five of the decaying nuclei produces a gamma ray photon. A scientist is initially working 1.50 m from the fresh source with no shielding. Show that at this time approximately 21 gamma ray photons per second are incident on each cm2 of the scientist's body. (2) (b) The scientist returns 6 hours later and works at the same distance from the source. (i) Calculate the new number of gamma ray photons incident per second on each cm2 of the scientist's body. (3) (ii) At what distance from the source could the scientist now work and receive the original dose of 21 photons per second per cm2 . (2) (c) Explain why it is not necessary to consider the beta particle emission when determining the dose of radiation the scientist receives. ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ (2) (Total 9 marks) Page 16 of 51 13 The graph below shows how the nucleon number A changes with proton number Z for the decay series that starts with uranium-238. The half-lives of each decay are also shown. (a) How many alpha particles and beta particles are emitted when a uranium-238 nucleus decays to radon-222 (222Rn)? Number of alpha particles .............................................................................. Number of beta particles................................................................................. (2) Page 17 of 51 (b) How many neutrons are there in a nucleus of polonium-210 (210Po)? ........................................................................................................................ (1) (c) Identify the stable isotope that results from this decay chain. ........................................................................................................................ (1) (d) 214 g of bismuth-214 (214 Bi) contains 6.0 × 1023 atoms. A sample containing only bismuth-214 has an initial mass of 0.60 g. (i) After what period of time will the mass of bismuth-214 present in the sample be 0.15 g? (2) (ii) Determine the number of bismuth-214 atoms present after this time. (1) (iii) Calculate the activity of the bismuth-214 in the sample after this time. (4) (iv) Explain how the total activity of the sample will be different from the value calculated in (iii). ............................................................................................................... ............................................................................................................... ............................................................................................................... ............................................................................................................... (2) (v) The bismuth-214 decays into polonium-214. Explain why you would find very little polonium-214 if you were to analyse the sample. ............................................................................................................... ............................................................................................................... (2) (Total 15 marks) 14 (a) (i) Explain what is meant by background radiation. ............................................................................................................... ............................................................................................................... ............................................................................................................... (2) Page 18 of 51 (ii) Name a source of background radiation. ............................................................................................................... (1) (b) State the meaning of each of the terms in the equation A = λN A ..................................................................................................................... ........................................................................................................................ λ ...................................................................................................................... ........................................................................................................................ N ..................................................................................................................... ........................................................................................................................ (3) (Total 6 marks) 15 A radium-288 nuclide ( ) is radioactive and decays by the emission of a β– particle to form an isotope of actinium (Ac). (a) Complete the equation for this decay. (3) (b) β– decay is the result of a neutron within a nucleus decaying into a proton. Describe the change in the quark sub-structure that occurs during the decay. ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ (1) (Total 4 marks) 16 A student has access to a radioactive source that decays by emitting alpha, beta and gamma radiation. The student wishes to investigate whether the count rate due to the gamma radiation varies with distance from the source according to an inverse square law and sets up the source and detector as shown in Figure 1. Page 19 of 51 (a) State and explain how the student can ensure that only gamma radiation is detected during the investigation. ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ (2) (b) The corrected count rate due to gamma radiation is 64 counts per second at a distance of 50 mm from the source. Assuming that an inverse square law is obeyed calculate the expected corrected count rate at a distance of 80 mm from the source. Count rate at 80 mm .............................................. (2) Page 20 of 51 (c) Using the data from part (b) sketch, on the axes in Figure 2, the graph the student would expect if an inverse square law were obeyed. The corrected count rate at 50 mm has been plotted already. Figure 2 (2) (Total 6 marks) 17 Thallium (Tl) decays to a stable form of lead (Pb) with the emission of a β– particle. Complete the equation below for this decay. (Total 3 marks) Page 21 of 51 18 (a) Calculate the radius of the U nucleus. r0 = 1.3 × 10–15 m ...................................................................................................................... ...................................................................................................................... ...................................................................................................................... ...................................................................................................................... (2) (b) At a distance of 30 mm from a point source of rays the corrected count rate is C. Calculate the distance from the source at which the corrected count rate is 0.10 C, assuming that there is no absorption. ...................................................................................................................... ...................................................................................................................... ...................................................................................................................... ...................................................................................................................... (2) (c) The activity of a source of b particles falls to 85% of its initial value in 52 s. Calculate the decay constant of the source. ...................................................................................................................... ...................................................................................................................... ...................................................................................................................... ...................................................................................................................... ...................................................................................................................... (3) Page 22 of 51 (d) Explain why the isotope of technetium, 99Tc m, is often chosen as a suitable source of radiation for use in medical diagnosis. You may be awarded additional marks to those shown in brackets for the quality of written communication in your answer. ...................................................................................................................... ...................................................................................................................... ...................................................................................................................... ...................................................................................................................... ...................................................................................................................... ...................................................................................................................... ...................................................................................................................... (3) (Total 10 marks) 19 (a) State which type of radiation, α, β or γ, (i) produces the greatest number of ion pairs per mm in air, ............................................................................................................... (ii) could be used to test for cracks in metal pipes. ............................................................................................................... ............................................................................................................... (2) (b) Specific radioisotope sources are chosen for tracing the passage of particular substances through the human body. (i) Why is a γ emitting source commonly used? ............................................................................................................... ............................................................................................................... (ii) State why the source should not have a very short half-life. ............................................................................................................... ............................................................................................................... Page 23 of 51 (iii) State why the source should not have a very long half-life. ............................................................................................................... ............................................................................................................... (3) (c) A detector, placed 0.20 m from a sealed γ ray source, receives a mean count rate of 2550 counts per minute. The experimental arrangement is shown in the diagram below. The mean background radiation is measured as 50 counts per minute. Calculate the least distance between the source and the detector if the count rate is not to exceed 6000 counts per minute. ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ (5) (Total 10 marks) 20 (a) (i) Alpha and beta emissions are known as ionising radiations. State and explain why such radiations can be described as ionising. ............................................................................................................... ............................................................................................................... ............................................................................................................... ............................................................................................................... (2) Page 24 of 51 (ii) Explain why beta particles have a greater range in air than alpha particles. ............................................................................................................... ............................................................................................................... ............................................................................................................... (2) (b) The figure below shows the variation with time of the number of Radon (220Ra) atoms in a radioactive sample. (i) Use the graph to show that the half-life of the decay is approximately 53 s. Show your reasoning clearly. (3) (ii) The probability of decay (decay constant) for 220Ra is 1.3 × 10–2 s–1. Use data from the graph to find the activity of the sample at a time t = 72 s. activity ..................................................... (3) (Total 10 marks) Page 25 of 51 21 A radioactive nucleus decays with the emission of an alpha particle and a gamma-ray photon. (a) Describe the changes that occur in the proton number and the nucleon number of the nucleus. proton number ............................................................................................... nucleon number ............................................................................................. (2) (b) Comment on the relative penetrating powers of the two types of ionizing radiation. ........................................................................................................................ ........................................................................................................................ (1) (c) Gamma rays from a point source are travelling towards a detector. The distance from the source to the detector is changed from 1.0 m to 3.0 m. Calculate intensity of radiation at 3.0 m intensity of radiation at 1.0 m answer ....................................... (2) (Total 5 marks) Page 26 of 51 Mark schemes 1 (a) A α particles [auto mark question] 1 (b) (i) type of radiation Typical range in air / m α 0.04 β 0.40 Allow students to use their own distance units in the table α allow 0.03 0.07 m β allow 0.20 3.0 m. If a range is given in the table use the larger value. A specific number is required e.g. not just a few cm. 2 (ii) reference to the inverse square law of (γ radiation) or reference to lowering of the solid angle (subtended by the detector as it moves away) or radiation is spread out (over a larger surface area as the detector is moved away) (owtte) Ignore any references to other types of radiation. Any contradiction loses the mark. For example, follows inverse square law so intensity falls exponentially. 1 (c) dust may be ingested / taken into the body / breathed in First mark for ingestion not just on the body causing (molecules in human tissue / cells) to be made cancerous / killed / damaged by ionisation Second mark for idea of damage from ionisation 2 [6] 2 (a) any 2 from: the sun, cosmic rays, radon (in atmosphere), nuclear fallout (from previous weapon testing), any radioactive leak (may be given by name of incident) nuclear waste, carbon-14 1 Page 27 of 51 (b) (i) (ratio of area of detector to surface area of sphere) ratio = (0.00368) 0.0037 2 (ii) activity = 0.62/(0.00368 × 1/400) give first mark if either factor is used. Bq accept s-1 or decay/photons/disintegrations s-1 but not 67000 counts s-1 (67400 Bq) 3 (c) (use of the inverse square law) or calculating k = 0.020 from I = k/x2 0.26 counts s-1 (allow 0.24-0.26) 3 [9] 3 (a) number correct for alpha (1) number correct for beta (1) alpha decay first goes via Tl (1) numbers correct for Tl (208, 81) (1) beta decay first goes via Po (1) numbers correct for Po (212, 84) (1) 6 (b) (i) use of GM tube + counter/rate-meter (1) measurement of count rate (1) at range of distances + suitable ruler or tape measure (1) specifies suitable range (1) determines background & corrects (1) safety precaution given (1) graph of count rate or corrected count rate against 1/d2 (1) max 6 Page 28 of 51 (ii) gamma not absorbed (1) spreads uniformly from a point source/spherically symmetrically (1) area over which it spreads is proportional to radius squared (1) alpha and beta are absorbed in addition to spreading out (1) max 3 [15] 4 (a) (i) Z increases by 1 B1 A remains the same B1 2 (ii) Correct curvature starting at 120 Bq B1 60 (or 0.5 × their start value) at 12 h days later B1 30 (or half their value at 12 h) and continuing to fall thereafter approximately exponentially B1 3 Page 29 of 51 (b) (i) 6.6 × 10–11 J (s–1) (120 × 5.5 × 10–13) B1 1 (ii) another particle is emitted in each decay (not gamma radiation) or the nucleus recoils B1 anti-neutrino emitted (this would get first and second mark 2 marks) B1 the other particle/neutrino/antineutrino/nucleus takes some/varying amounts of the energy B1 3 (c) 7.5 × 106 B1 1 (d) Particles are emitted in all directions/particles do not all go to detector B1 Detector only detects some of the particles that enter it/mention of dead time or recovery time (not detector does not detect all the particles - this adds nothing) B1 Some particles are absorbed by the window B1 max 2 [12] Page 30 of 51 5 (a) (i) correct construction method seen on graph or quotes appropriate values from the graph C1 2.0 × 104 s to 2.4 × 104 s allow 1 or2 s.f. A1 repeats and averages B1 (3) (ii) A = 3.7 or 3.8 × 1016 (Bq) at t = 0 C1 1.2 × 1021 A1 (2) (b) (i) alpha will not penetrate the body or risk to patient from ionisations B1 (1) (ii) long enough half life to make measurements / short enough half life so does not remain long in body B1 (1) (c) causes ionisations / damage B1 to cell / cell nucleus / body tissue / DNA B1 (2) [9] 6 7 C [1] B [1] Page 31 of 51 8 (a) Gamma rays are very penetrating/alpha/beta rays would not be detected B1 (outside body) Gamma rays are less ionising/less hazardous (to patients)/ alpha/beta are more ionising/more hazardous B1 2 (b) Background radiation/count is much smaller/negligible B1 Random fluctuations in the readings greater than background B1 2 (c) Accurate plotting check all four points ( ½ square) M1 reasonably smooth curve with even point scatter A1 2 (d) two or more half-lives averaged B1 Half-life calculated from best fit line C1 Half-life = 13 1 hour A1 3 allow ecf from inaccurate plotting, but straight line = P.E. Page 32 of 51 (e) High activity (so only a small sample needed) B1 Decays quickly B1 Less risk to patient/other people B1 (Short half-life ok because) medical test doesn‘t last long B1 Any two from four 2 [11] 9 (a) (i) nuclides or atoms of same element or same proton / atomic number not just ‘same element’ different mass / nucleon number or numbers of neutrons B1 B1 (2) (ii) time taken for half the sample or half the number of nuclei (not just ‘atoms’) to decay or activity to fall to half initial value B1 (1) (b) B1 B1 B1 (3) Page 33 of 51 (c) A / A0 = 0.01 or A = 1 and A0 = 100 C1 λ = 0.69 / 8.1 or or 0.086 (0.0856) attempt to take logs C1 54 days (53.8) A1 (for between 6 and 7 half-lives, 50% → 25% → 12.5%) C1 (4) (d) γ radiation detected M1 β cannot penetrate tissue or γ can penetrate tissue – A1 (2) [12] 10 (a) thicker material absorbs more particles B1 count rate (number detected) falls if material is thicker B1 fall in count rate produces change to adjust process to produce thinner material / restore to original thickness allow 1 mark for ‘change in thickness changes count rate and rollers adjust to compensate’ B1 (3) (b) use a beta source M0 alphas would be absorbed by paper A1 gammas would not be affected A1 use a gamma source M0 beta would be absorbed completely A1 alphas would be absorbed completely allow beta if candidate includes statement about the steel sheet being thin A1 (4) Page 34 of 51 (c) (i) 1 disintegration / decay / particle emitted per second (per unit time) not one count per second B1 (1) (ii) correct curvature starting at 5 × 1020; time scale inserted up to 15 (unit not necessary) or labelled T1/2, 2T1/2, 3T1/2 M1 sensible scales (not multiples of 3); correct number of atoms at each half-life; reasonable curve and unit for time A1 (2) (iii) half-life = 0.69 / decay constant C1 4.1 – 4.2 × 10–9 (s–1) A1 (2) (iv) A = (–)λN C1 number of R / A atoms when activity is 1.5 × 1012 Bq = 3.6 × 1020 C1 correct time read from graph A1 (2.5 y / 920 days / 8.0 × 107s) or determines original activity or final number of atoms 2.1 × 1012 Bq or 3.6 × 1020 allow ecf from (iii) C1 N = N0e–λt or A = A0e–λt C1 940 d or 2.6 y (answer depends on where rounding off has been done) A1 (3) [15] 11 (a) (i) A = 4; Z = 2 B1 (1) (ii) A = 0; Z = –1 B1 (1) Page 35 of 51 (iii) 8 alphas c.a.o. B1 explanation consistent with their (i) / correct equations including values of A and Z B1 (2) (iv) 6 betas e.c.f. B1 explanation consistent with their (i) and (ii) / correct equations including values of A and Z B1 (2) (b) (i) probability of a nucleus decaying per unit time or ratio of activity to number of nuclei (of that type) present or with terms defined or with terms defined B1 (1) (ii) NP = N0 – N0e–λt / Nu = (Nu + Np) e–λt / Np = No – Nu B1 correct manipulation B1 (2) (iii) NP / NU = 0.62 / 4.2 C1 λ = (ln2) / 4.5 × or 109 0.69 / 4.5 × 109 C1 correct manipulation of logs C1 9.0 × 108 y / 8.96 × 108 y A1 look for alternative approach based on No = 4.82 and then use of N = Noe–λt (4) (iv) age will be overestimated B1 not all of the Pb is the result of uranium decay or words to that effect B1 (2) Page 36 of 51 (v) change of count rate for U will be small as half life is large B1 comment about background count (rate) or background radiation B1 absorption in sample B1 presence of other radioactive nuclides / daughter nuclei B1 max 2 [17] 12 (a) number of gamma ray photons per sec = (= 6.0 × 106) B1 correct use of 4πr2; substitution of data = 21.2 NB they may determine number per m2 and divide by 10 000 B1 (b) (i) decay constant = 0.69 / 12 = 0.0575 h–1 or 1.6 × 10–5 (or time =.5 half life) Cl dose = 21e–(6×0.0575) dose = 21 / 20.5 Cl or new (gamma) activity = 6 × 106 e–(6×0.0575) or new (total) activity = 3 × 107 e–(6×0.0575) Cl 15 (gamma rays per cm2 per second) Condone 14.8 – 14.9 (no up) Al (ii) clear attempt to apply inverse square law Cl 1.3 (1.26) m Al Page 37 of 51 (c) beta particles are more heavily ionising than gamma radiation or loses energy rapidly by ionising the air / matter Bl beta particle range / penetration (in air) is low or beta particle range is about 30 cm or is less than 1.5 m or is much lower than gamma radiation NB: mention of not able to penetrate skin or clothing is talk out Bl [9] 13 (a) number of alpha particles = 4 B1 number of beta particles = 2 B1 (2) (b) 126 B1 (1) (c) Pb-206 B1 (1) (d) (i) number of half lives = 2 or half life = 20 minutes C1 40 minutes A1 (2) (ii) 4.2 × 1020 B1 (1) Page 38 of 51 (iii) decay constant = 0.69 / half life (allow e.c.f. from (i)) or = N0e–λt1 / 2 C1 5.75 × 10–4 s–1 or 5.78 × 10–4 s–1 or 0.0345 min–1 (allow if calculation is done in (ii)) C1 A = λN C1 2.4 (2.42) × 1017 Bq (or decays per s) or 1.5 (1.45) × 1019 decays per minute A1 (4) (iv) the (daughter) products are also decaying [or are radioactive] M1 activity will be greater A1 (2) (v) any 2 of: polonium-214 has a half life of 1.6 × 10–4 s B1 decays almost as soon as it is formed or decays very quickly B1 only some of the bismuth-214 decays via polonium-214 B1 max 2 [15] 14 (a) (i) mention of radioactivity / decay / nuclear radiation B1 ever present / independent of source being in proximity / always there / cannot be eliminated B1 (2) (ii) radon / rocks / cosmic rays / nuclear fallout / medicine / space / sun B1 (1) Page 39 of 51 (b) A – activity / rate of decay B1 λ – decay constant / probability of decay B1 N – number of nuclei (radioactive atoms) present not number of isotopes / atoms / particles B1 [6] 15 (a) Ac B1 β B1 suitable anti - neutrino indication (anti - neutrino not required) B1 (b) Down quark changes to up quark B1 [4] 16 (a) place a sheet of aluminium/metal between source and detector Sheet thickness stated 2 to 10 mm thick or several/a few mm thick plus M1 only gamma radiation can pass through such a sheet or alpha and beta will be absorbed/stopped by the sheet A1 2 (b) count rate 1/r2 or evidence of C1/C2 = r22/r12 C1 25 counts per second (allow cps or s–1) (Bq is a up) A1 2 Page 40 of 51 (c) their value calculated in (b) plotted correctly and reasonable attempt to draw correct curvature C1 Correct point (25 cps) plotted with correct curvature (mark quality: must not flatten out or rise at end of their line for large distances) A1 2 [6] 17 Anti-neutrino indicated appropriately B1 Beta 0, and –1 B1 Tl 81 Pb 208 B1 [3] 18 (a) R (= r0A1/3) = 1.3 × 10–5 × (238)1/3 (1) = 8.0(6) × 10–15m (1) 2 (b) (use of inverse square law e.g. 10 = gives) (1) x = 0.095 m (1) (0.0949 m) 2 Page 41 of 51 (c) (use of A = Aoexp(–λt gives) 0.85 = 1.0 exp (–λ52) (1) (1) = 3.1(3) × 10–3s–1 (1) 3 (d) it only emits γ rays (1) relevant properties of γ radiation e.g. may be detected outside the body/weak ioniser and causes little damage (1) it has a short enough half-life and will not remain active in the body after use (1) it has a long enough half-life to remain active during diagnosis (1) the substance has a toxicity that can be tolerated by the body (1) it may be prepared on site (1) any three (1)(1)(1) 3 [10] 19 (a) (i) α (radiation) (1) (ii) γ (radiation) (1) 2 (b) (i) the radiation needs to pass through the body (to be detected) (1) (ii) (otherwise) the activity of the source becomes too weak (during measurements) (1) (iii) the decaying source may remain in the body for a long time and could cause damage (1) [or the activity of the source will be low unless a large quantity is used (T1 / 2 ∝ 1 / λ)] 3 Page 42 of 51 (c) corrected count rate at 0.2 m (= 2550 - 50) = 2500 (c min-1) (1) corrected count rate at least distance (= 6000 - 50) = 5950 (c min-1) (1) use of I = (or in the form ) (1) (allow C.E. for using uncorrected count rate) gives least distance = 0.20 × (1) least distance = 0.13 m (1) 5 [10] 20 (a) (i) remove electrons from atoms B1 by colliding with them/knocking into them B1 2 (ii) fewer collisions per metre B1 because beta particles are smaller/less ionising (accept smaller charge) not less mass B1 so lose energy over a larger distance B1 max 2 (b) (i) one correct construction shown on graph (52 s – 53 s) M1 at least one other determination visible on graph M1 averaging process shown A1 3 Page 43 of 51 (ii) N = 1.08 to 1.1 × 1021 (condone errors in powers of 10) B1 A = λN C1 1.4(3) × 1019 Bq (allow decays/second) allow ecf for minor error in N A1 or attempt to find gradient at 72 s correct extraction from a tangent of graph 1.3 to 1.5 × 1019 Bq (allow decays / second) 3 [10] 21 (a) (proton) down 2/–2 B1 (nucleon) down 4/–4 B1 2 (b) gamma greater, must express comparison, don’t allow simple list B1 1 Page 44 of 51 (c) use of inverse-square law C1 A1 2 [5] Page 45 of 51 Examiner reports 1 2 4 Most students understood the questions about the range and dangers of ionising radiations but many failed to gain marks over the details. Part (a) was done well by a majority of students but in part (b)(i) there was a great deal of uncertainty about the range of alpha and beta particles. It was common to see alpha particles having ranges over 10 cm. However, almost all students did put the range of beta particles larger than alpha particles. Part (b)(ii) was done very well with a majority of students referring to the inverse square relationship between intensity and distance. A few did contradict themselves by quoting the inverse square relationship but then they talked about the intensity falling off exponentially. The other successful students discussed the spreading of the rays. Part (c) was again done well. Most realised that the dust had the potential to be ingested usually by breathing it in. Some students did struggle with the mark on the dangers of the ionising radiation. Some gave details of the damage that may be caused but failed to say that the damage is caused by the ionisation. Others did not explicitly say humans might be harmed or damaged, they simply said ionisation could occur in the body. A majority of students could not give two clear specific sources of background radiation. The answers given in response to question part (a) were all too often of a general nature and too vague to be worthy of a mark. For example, ‘power stations’ or ‘the air’. The answers needed to be clearer statements like, ‘radioactive material leaked from a power station, or radon gas in the atmosphere. As only one mark was being awarded only one detailed source gained the mark provided the second point was in some way appropriate even if poorly stated. Part (b)(i) was a very good discriminator. More able students realised that a comparison of areas was required to answer the question. Part (b)(ii) was also a good discriminator. Only the top 20% of students used the detection efficiency factor as well as the fraction of gamma rays hitting the detector to obtain the correct answer. Most used only the 1/400 detection efficiency. Students were more successful in choosing the correct unit. Part (c) was interesting in that students either attempted the question successfully or they left this section blank. (a) (b) (c) (i) In this straight-forward question it was surprising how many candidates thought that the proton number would decrease. Most appreciated that the nucleon number remained the same. (ii) This was usually done well. Common errors were to show the starting activity of 120 Bq at 12 h or to show an activity of 140 Bq at time = 0. Failure to complete the graph for the 48 h period and very poor line drawing also cost some the third mark. (i) That the energy per second would be the activity x the energy per decay was understood by relatively few candidates. The number of seconds in an hour or a day appeared in the working of many candidates. (ii) Although there were many excellent answers the fact that another particle (antineutrino) was the reason for the different energies was not as well known as one would have hoped. Many concentrated only on the recoil of the nucleus. Others wrote about the energy of emission becoming weaker as the source decayed, the randomness of radioactive decay or the source becoming charged. This was usually completed successfully. Page 46 of 51 (d) 8 There were many good answers. Many candidates appreciated that particles were emitted in all directions so that only a proportion of those emitted would reach the detector. A misconception in some answers was that if the source had been shielded then all the particles would have gone in the same direction (being reflected by the shielding). Other points about the effect of absorption by the window to the tube and the limitations of the tube in detecting particles that arrive at the same time, or within a certain time, were also appreciated by many. This question gave nearly every candidate the opportunity to gain some marks and a pleasing number scored very well indeed. Part (a) returned at least one mark to most candidates, but part (b) was answered poorly. The examiners were hoping to be told that a typical background count-rate was much smaller than the figures given in the table and negligible compared to the random fluctuations apparent in these data. A surprising number of candidates were unable to plot all four points accurately in part (c), and some did not even attempt to do so. The better candidates averaged two or more half-life readings taken from their line of best fit in part (d), although some then lost a mark for an incorrect unit. Most candidates provided at least one appropriate reason in answer to part (e). 9 (a) This was rather disappointingly answered with a number of inconsistencies. Isotope was rarely used as a comparative term and candidates frequently referred to an isotope as being ‘an element with the same proton number but different neutron numbers’. Half-life was often referred to as being ‘the time for the number of atoms / nuclides / molecules to be reduced to half’. None of these responses was given credit. Candidates should be encouraged to talk in terms of decay of nuclei or the activity of a sample of material. (b) This part was done relatively well, although a minority of candidates was very confused by the nomenclature used in the equation representing this nuclear reaction. (c) This part was well answered with the majority of candidates being able to calculate a value for the decay constant and the majority of those candidates being able to use their value in order to calculate a sensible time for the reduction of the activity. Weaker candidates were awarded a compensation mark for estimating that the time would be between six and seven half-lives. (d) Although the majority of candidates recognised that the γ radiation would be detected outside the body, few supported their assertion in an unambiguous manner. Weaker candidates suggested numerous different ‘decay products’ ranging from α and β particles to iodine and xenon. Page 47 of 51 10 (a) There were many well explained answers to this part. However, the question exposed many misunderstandings. Many candidates wrote that either the source or radioactive particles passed through the material. Some thought that the material itself was radioactive. Although many referred to less radiation reaching the detector, it was disappointing how few referred to the radiation being ‘absorbed’. (Did they think it was reflected?) Many candidates referred to radiation being detected or not detected as thickness changed rather than that there being a variation in count rate. (b) (i) To gain credit in either part the correct source first had to be identified. There were many who stated that alpha sources should be used for paper although the fact that alpha particles are absorbed by paper and travel only a short distance in air should be well-known. (ii) A beta source was stated by many to be suitable. This was allowed only if they also stated that the steel would be thin. Many stated or implied in one or other of the two parts that gamma radiation could pass through anything without any change in intensity. (i) There was a surprising number of incorrect answers to this. Statements such as ’1 Bq means that one radioactive atom is radiated from the source per second’ or simply that ‘it is the activity of a source’ were not uncommon. Many associate the value with the count rate of a detector rather than a property of the source. (ii) Poor graph drawing skills cost many candidates a mark here. To gain the first mark the correct value at t = 0 had to be plotted and indicated at 5 × 1020 and the curvature had to be correct though not accurate. For the second mark the scale should have been sensible (e.g. not 5.3, 10.6 etc at the 2 cm grid markings), and the values were expected to be reasonably accurate at times equal to 1, 2 and 3 half lives. (iii) Most candidates did this correctly. Common faults were giving the answer as 0.13 year−1 or as 0.13 s−1. (iv) Whilst there were many correct answers, many were confused. A common response was 1.5 × 10−2 = 5 × 1020 e−λt. These candidates did not appreciate that they needed to find either the original activity or the final number of radioactive atoms. There were also many instances where units were mixed. Calculation of the number of atoms remaining when the activity is 1.2 × 1012 Bq and reading the time from the graph was an expected, easy route to the answer but this approach was rarely used. (c) Page 48 of 51 12 14 15 Only the better candidates scored well on this and many of these obtained full or near full marks. However, it was disappointing that this was generally a low scoring question. (a) The need to identify the approach and then to extract the appropriate data from both the stem and the question proved to be too demanding for most. Candidates needed to appreciate that the gamma activity is 1 / 5 of the total activity and that the gamma ray photons pass through an area of 4πr2. Many tried using the decay formula in this part. (b) (i) Candidates are required to be able to use the decay equations and here the decay formula could be applied here using the total activity or the gamma activity or the value 21 given in (a), the last being the easiest approach. Many thought that if the activity halves in 12 hours it will be reduced by a quarter in 6 hours. Errors made by those who used the correct approach usually involved an incorrect decay constant or inability to do the arithmetic. (ii) Candidates could gain credit if it was clear that they were applying the inverse square law but this was far from evident in many scripts. (c) The majority of candidates stated that beta particles have a short range but few stated why this was the case. A significant proportion demonstrated unclear thinking by saying that the beta particles would not pass through clothes or skin hence talking themselves out of the mark. A worrying number thought that beta particles were harmless since the skin prevents them entering the body. Of those who mentioned ionisation a number thought that the beta particles themselves are ionised. (a) (i) Although many candidates were able to suggest a sensible source for background radiation few gave a full enough explanation, of what it is, to gain full credit (ii) It was unclear in many cases whether or not candidates understood that the source of background radiation was radioactive decay. (b) Most candidates were able to define the symbols in the equation but too often, having given a correct quantity, the candidate would then give an alternative meaning for the symbol that was contradictory – inevitably this was penalised. Unsurprisingly, many weak candidates took λ to mean wavelength. (a) The equation was completed well by a large proportion of the candidates but there was a significant number who could make no valid attempt. The β– was usually correct, but common errors were to quote together with an ambiguous symbol for the antineutrino. Examiners required candidates to make it clear that the third particle was an anti-neutrino. 16 (b) This was well answered by the majority who knew that a down quark changes to an up quark when the neutron decays to a proton. (a) Most realised that a metal sheet between the source and detector was needed. However, many did not give a satisfactory thickness for the metal and others did not say clearly where it would be placed. Weaker candidates thought that taking a background count rate and subtracting it was what was expected. Page 49 of 51 17 19 (b) Relatively few candidates were able to do this successfully and most showed no appreciation of the application of the inverse square law to gamma radiation. Many worked with differences or assumed inverse proportionality. Some of those who obtained the correct value failed to include the unit. (c) It was essential for candidates to show the correct general curvature in this part. For full credit they needed to have applied the inverse square law successfully in (b) and to have plotted the correct value on the graph. Many of those who understood the inverse square law went on to calculate other points correctly when drawing their graph. There remains a widespread inability to balance this beta-emission equation correctly. Candidates do not know the correct values of proton and nucleon number for the beta particle, they could not subsequently balance the equation correctly, and very few indicated the neutrino fully, often omitting to indicate that it is an anti-neutrino in this case. Few candidates scored three marks on this comparatively simple question. The question on nuclear instability performed well on the whole and many candidates gained high marks. Most of the answers to part (a) had the á radiation correct, but the answer to part (ii) seemed to be guesswork between β radiation and γ radiation. In part (b) most candidates scored at least one mark and the majority, two marks, but very few were awarded all three. The main problem seemed to be part (i) which asked why a ã source was used. A large number of answers to this were disregarded when candidates referred to the source and not to the radiation being able to pass through the body. In general the answers to parts (ii) and (iii) were sensible and overall the majority of candidates seemed to have good understanding of this part of the course. The calculation in part (c) provided an accessible five marks, but many candidates forfeited two marks by not taking into account the mean background radiation. A surprising number corrected one count only, usually the 2550 count, but failed to apply a correction to the other count rate. The majority of candidates applied the inverse square law correctly, even if sometimes the calculation became long winded, but it usually ended with the correct answer. The examiners were concerned for those candidates who thought that the constant k in the equation was the Boltzmann constant, and also for those candidates who used the corrected count rate as I and the uncorrected count rate as Io. Both these fundamental errors indicated complete misunderstanding of the equation. 20 (a) (i) This part was done reasonably well. Some candidates distracted themselves with ideas about positive and negative ions or with the idea that the alpha particles were themselves ions. (ii) Most of the candidates knew that beta particles were less ionising or that they suffered fewer collisions. They found it more difficult to express ideas relating to the number of collisions per millimetre of travel or the consequent notion that alpha particles lost all of their kinetic energy over a smaller distance than beta particles Page 50 of 51 (b) 21 (i) Many candidates could use the graph to find the half life. Some made mistakes over the interpretation of the scales and others did not show their constructions clearly enough for credit. Fewer candidates thought it worth finding more than one determination from the graph and then averaging their answers. (ii) This was done quite well but significant figure errors and unit penalties were common and a surprising number of candidates made powers often mistakes. (a) Another simple question for which many gained full marks. (b) Candidates were asked for the relative penetrating powers of alpha and gamma radiation. Far too many produced standard lists of materials that alpha and gamma can penetrate without giving a summary statement. A significant minority interpreted the question as requiring a comparison between alpha-particle and beta-particle penetration. (c) Roughly 50% of the candidates scored full marks on this question where the normal rules of significant penalty errors were eased (allowing an answer of -). However, answers of 9 were common even from those acknowledging the correct use of the inverse-square law. They did not appear to be able to cope with the arithmetic manipulations required. Page 51 of 51
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