Revising the Precambrian Timescale: a new look at an old story Martin J. Van Kranendonk Such changes are exemplified across the period of Earth’s School of Biological, Earth and Environmental Sciences, University of New South Wales Kensington, NSW 2052 Australia adolescence, from 2.8–2.0 Ga (Fig. 3), during which time the E: [email protected] Ga) and then by cooling of the atmosphere, rise of atmospheric Earth system was flung out of equilibrium by the largest crustal growth episode in history (2.78–2.63 Ga), followed by unprecedented deposition of banded iron-formation (2.63–2.42 oxygen, and global deposition of glacial rocks (2.42–2.22 Ga) A) represented by the Precambrian is currently divided by chronometric boundaries derived from a 1980’s review of data compiled at the very start of the zircon geochronological revolution (Fig. 1a: Plumb, 1991). This scheme is unsatisfactory primarily because: • Eon and era boundaries are defined as whole numbers that are disassociated from the actual rock record (Fig. 1b); • B) Archean-Proterozoic boundary during global shutdown of the magmatic system (Condie et al., The nearly 4 billion year period of Earth history 2009). These changes were accompanied by chaos in the biosphere, reflected in the largest anomalies of stable isotopes in Earth history (Fig. 4). Subsequent restart of the global mantle engine at 2.2–2.06 Ga was accompanied by deposition of the first widespread Ca-sulfate deposits (Fig. 5) and redbeds, rise of eukaryotes, and by the Lomagundi–Jatuli isotopic excursion of carbon isotopes, followed by reappearance of iron-formations and worldwide deposition of organic-rich black shales (Shungites: Melezhik et al., 2005). No formal definition of early Earth history, despite This linear succession of events, exquisitely preserved in the widespread use of “Hadean” for rocks >c. 4 Ga. rock record (Fig. 6), forms the basis of a revised Precambrian timescale across this period. Since the current timescale was devised, knowledge of the Precambrian Earth system has exploded, with precise UPb zircon ages and new isotopic geochemical techniques Figure 1: A) Current Precambrian timescale; B) Stratigraphic column of the Hamersley Basin, Western Australia, showing ages and position of current ArcheanProterozoic boundary (2500 Ma). revealing a rich history that can be used to better constrain the evolution of our planet and the biosphere through deep time (Van Kranendonk, 2012). Figure 5: Polished rock slab showing gypsum crystals in carbonate from the c. 2.2 Ga Yerrida Basin, Western Australia. The Precambrian Subcommission of the International Commission on Stratigraphy is currently reviewing the Figure 3: A causative, linked series of events across the Archean-Proterozoic boundary transition: 1) radiogenic heat flow decreases to below the rate of oceanic heat flow, resulting in cooling of oceanic lithosphere and onset of modern-style plate tectonics; 2) major peak in juvenile crustal growth, releasing huge volumes of CO2 into the atmosphere and causing a highly anoxic atmosphererise and intense chemical weathering of continents, resulting in; 3) precipitation of huge volumes of banded ironformations (BIFs); 4) mantle cooling due to widespread subduction, a decrease in volcanic CO2 emmissions, and a bloom of cyanobacteria results in atmospheric oxidation; 5) microbial bloom resulting from delivery of increased nutrients to the oceans following deglaciation, combined with increased atmospheric pCO2 from renewed volcanism, results in disequilibrium in the biosphere – the Lomagundi-Jatuli isotopic excursion. Figure 6: Field photograph of the conformable depositional contact between banded ironformation (BIF) and the transitional chert unit (TC) of the Hamersley Group and overlying glacial mudstones and sandstones of the Turee Creek Group; author’s finger points to the site of a possible GSSP for a revised Archean-Proterozoic boundary at the first appearance of glaciogenic rocks. Figure 4: Temporal variations through the Precambrian: a) Δ33S of sedimentary sulphides (orange bar, MDF = range of mass-dependent fractionation); PAL = % of present atmospheric level of oxygen (logarithmic scale; b) δ34S of sedimentary sulphides (red circles) and of seawater sulphate (blue lines); c) δ13C of kerogens; d) δ13C of carbonates (black triangles denote time of Paleoproterozoic glaciations); e) δ56Fe of diagenetic sediments; f) relative abundance of banded iron-formation. Grey shade indicates time of instability in the biosphere. Indeed, analysis of global datasets shows that Precambrian Earth Precambrian timescale with the aim of establishing evolved through five main cycles (3.2–2.8 Ga; 2.8-2.22 Ga; chronostratigraphic divisions of the Precambrian, with 2.22-1.7 Ga; 1.7-0.9 Ga; 0.9 Ga-542 Ma), driven by changes in Global Stratotype Section and Points (GSSPs, or “Golden mantle temperature and rate of convection, and reflected in the Spikes”) in rock successions, wherever possible (Fig. 2). geological record by pulses of crustal growth tied to the supercontinent cycle, and by changes in atmospheric The proposed scheme follows the rationale of Cloud conditions and biological activity (Fig. 7: Van Kranendonk, (1972): 2012). These cycles, and the major atmospheric and biological “…we seek trend-related events that have affected the changes that accompanied them, form the basis for a revised entire Earth over relatively short intervals of time and left Precambrian timescale changes. recognizable signatures in the rock sequences of the A working group is currently investigating available data globe. Such attributes are more likely to result from towards formally establishing a Hadean Eon, to reflect the events in atmospheric, climatic, or biologic evolution period of early planetary formation, the Moon-forming Giant than plutonic evolution and hence should be more Impact, crystallisation of the magma ocean, and solidification characteristic of the sedimentary record than of the of the first differentiated continental crust. The next step will be igneous or metamorphic record, although the latter must Figure 7: Major cycles of crustal growth and biospheric response through the middle part of the Precambrian, showing relative peaks of activity, whose sharp boundaries may be used as GSSPs (spikes at top of diagram). Vertical dotted line represents the position of a potentially revised Archean-Proterozoic boundary. to erect a candidate GSSP section for a revised Archean- be included in any meaningful global assessment.” Proterozoic boundary at, or near, the transition to a cooler, more oxidized atmosphere, at roughly 2420 Ma (revised from the current 2500 Ma). Conformable successions are being Figure 2: A prototype for a revised Precambrian timescale, based on the data presented in Van Kranendonk (2012). Clocks represent chronometric boundaries ; Spikes represent potential GSSPs. Australian Centre for Astrobiology investigated in South Africa and Australia. Following that, era boundaries for the Proterozoic and Archean will be reexamined. References cited Cloud, P., 1972. A working model of the primitive earth. American Journal of Science, 272: 537–548. Condie, K.C., O’Neill, C., and Aster, R.C., 2009. Evidence and implications for a widespread magmatic shutdown for 250 My on Earth. Earth and Planetary Science Letters, 282: 294–298. Melezhik, V.A., Fallick, A.E., et al., 2005. Emergence of the aerobic biosphere during the ArcheanProterozoic transition: Challenges of future research. GSA Today, 15: 4–11. Plumb, K.A., 1991. New Precambrian time scale. Episodes, 14: 139–140. Van Kranendonk, M.J. (2012): A chronostratigraphic division of the Precambrian: possibilities and challenges. In: Gradstein, F.M, Ogg, J.G., Schmitz, M.D., Ogg, G.J. (eds.), The Geologic Time Scale 2012; Elsevier, USA, pp. 313–406.
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