Section 2.1 2.1 Classifying Matter 1 FOCUS Objectives 2.1.1 2.1.2 2.1.3 2.1.4 2.1.5 2.1.6 Classify pure substances as elements or compounds. Describe the characteristics of an element and the symbols used to identify elements. Describe the characteristics of a compound. Distinguish pure substances from mixtures. Classify mixtures as heterogeneous or homogeneous. Classify mixtures as solutions, suspensions, or colloids. Key Concepts Why are elements and compounds classified as pure substances? How do mixtures differ from pure substances? What is the main difference among solutions, suspensions, and colloids? Vocabulary ◆ ◆ ◆ ◆ ◆ ◆ ◆ ◆ ◆ pure substance element atom compound heterogeneous mixture homogeneous mixture solution suspension colloid Reading Strategy Summarizing Copy the diagram below. As you read, complete the classification of matter. Matter a. ? Element Mixture b. ? c. ? d. ? E ach piece of clothing sold has a care label, which lists recommended cleaning methods for the clothing. For a sweater, the instructions might say to machine wash the sweater using a gentle cycle, and then tumble dry at a low temperature. They might say to hand wash the sweater in cold water and lay the sweater flat to dry. The label might even say, “Dry clean only.” Why is it necessary to put care instructions on a label? The same cleaning method will not work for all materials. For example, a shirt made from 100 percent cotton may need to be ironed after washing. But a shirt made from a cotton and polyester blend may come out of the dryer wrinkle free. A wool jacket often needs to be dry cleaned because wool can shrink when washed in water. The tendency to wrinkle when washed is a property of cotton. The tendency not to wrinkle when washed is a property of polyester. The tendency to shrink when washed is a property of wool. Cotton, wool, and polyester have different properties because they have different compositions. The word composition comes from a Latin word meaning “a putting together,” or the combining of parts into a whole. Based on their compositions, materials can be divided into pure substances and mixtures. Reading Focus Build Vocabulary L2 Paraphrasing To help students understand the definitions of vocabulary terms, you may replace less familiar words in a definition with a more familiar word or phrase. For example, you can replace distributed in the definition of a homogeneous mixture with “spread out,” or shattering in the definition of malleability with “breaking into pieces.” Reading Strategy L2 a. Substance b. Compound c. and d. Homogeneous mixture or heterogeneous mixture 2 INSTRUCT Figure 1 You can use the care labels on clothing to sort laundry into batches for cleaning. The care label shown is for a wool sweater that needs to be dry cleaned or washed by hand. L2 Some students may associate the term material exclusively with solids because they can see and hold solid materials. They may have difficulty recognizing that liquids and gases are also matter. Challenge this misconception by pointing to the Materials list for the lab on p. 60 and asking students to identify the liquids. Verbal 38 Chapter 2 38 Chapter 2 Section Resources Print • Reading and Study Workbook With Math Support, Section 2.1 • Math Skills and Problem Solving Workbook, Section 2.1 • Transparencies, Chapter Pretest and Section 2.1 Technology • Interactive Textbook, Section 2.1 • Presentation Pro CD-ROM, Chapter Pretest and Section 2.1 • Go Online, NSTA SciLinks, Mixtures Pure Substances Pure Substances FYI Matter that always has exactly the same composition is classified as a pure substance, or simply a substance. Table salt and table sugar are two examples of pure substances. Every pinch of salt tastes equally salty. Every spoonful of sugar tastes equally sweet. Every sample of a given substance has the same properties because a substance has a fixed, uniform composition. Substances can be classified into two categories—elements and compounds. Samples of pure substances almost always contain impurities, some that are unintentional, some intentional. For example, table salt is not pure sodium chloride. It contains between 0.006% and 0.01% potassium iodide. Elements Elements Although there are millions of known substances, there are only about 100 elements. An element is a substance that cannot be broken down into simpler substances. Imagine cutting a copper wire into smaller and smaller pieces. Eventually you would end up with extremely tiny particles called copper atoms. An atom is the smallest particle of an element. An element has a fixed composition because it contains only one type of atom. No two elements contain the same type of atom. In Chapter 4, you will find out more about atoms, including how the atoms of one element differ from the atoms of every other element. Figure 2 Aluminum, carbon, and gold are elements that you can see in common objects, such as cans, pencils, and rings. Mixtures containing iodine are used to prevent and treat infections. Analyzing Data Which of these elements has a symbol that is not related to its name in English? FYI Sometimes an atom is defined as “the smallest particle of an element that has the properties of the element.” However, an atom of copper has none of the properties associated with bulk copper, such as malleability, ductility, or density. Build Science Skills Examples of Elements At room temperature (20°C, or 68°F), most elements are solids, including the elements aluminum and carbon. You have seen aluminum foil used to wrap food. Most soft drink cans are made from aluminum. Carbon is the main element in the marks you make with a pencil on a piece of paper. Some elements are gases at room temperature. The elements oxygen and nitrogen are the main gases in the air you breathe. Only two elements are liquids at room temperature, bromine and mercury, both of which are extremely poisonous. Figure 2 shows four elements and their symbols. Iodine (I) L2 Observing Have students look at the elements in Figure 2. Ask, What are some characteristics of the elements in Figure 2? (Gold is yellow and shiny. Aluminum is gray and shiny. Carbon is dull and black. Iodine is a dark purple solid.) Follow up on their observations by asking students to hypothesize about why the iodine sample is in a closed container. (At room temperature, iodine evaporates and forms a purple gas, which is visible in the container. The gas is poisonous.) Visual Aluminum (Al) Gold (Au) Carbon (C) Properties of Matter 39 Customize for English Language Learners Sharing Experiences Encourage multilingual students to describe what a particular element is called in their native language. This exercise will be most useful for those elements that have been known for centuries or millennia. (Examples include carbon, mercury, sulfur, iron, copper, tin, zinc, silver, gold, and lead.) Use this information as a springboard for discussing the element names given in the text. Answer to . . . Figure 2 Gold Properties of Matter 39 Section 2.1 (continued) Integrate Language Arts Symbols for Elements In 1813, Jöns Berzelius, a Swedish L2 Silicon Have students research and explain the origin of element symbols (other than Au) that are not abbreviations for element names in English. Examples include silver (Ag), lead (Pb), tin (Sn), antimony (Sb), and mercury (Hg). Verbal, Portfolio Compounds FYI When the terms element, atom, compound, and molecule are defined in an introductory section, the definition of a molecule is often both too broad and too narrow. Molecules are not the smallest particle of all compounds, and many elements exist in nature as molecules. For this reason, in this text, the formal definition of molecule does not appear until Chapter 6, the chapter on bonding, where it can be defined accurately. (The term molecule is introduced informally in Section 3.3 when water molecules are described.) chemist, suggested that chemists use symbols to represent elements. Many of the symbols he assigned to elements are still used. Each symbol has either one or two letters. The first letter is always capitalized. If there is a second letter, it is not capitalized. It is easy to see why C and Al are used to represent carbon and aluminum. But why does gold have the symbol Au? The symbols that Berzelius chose were based on the Latin names of the elements. The Latin name for gold is aurum. The symbols allow scientists who speak different languages to communicate without confusion. For example, nitrogen is known as azote in France, as stickstoff in Germany, and as nitrógeno in Mexico. But scientists who speak English, French, German, and Spanish all agree that the symbol for the element nitrogen is N. Sometimes an element’s name contains a clue to its properties. For example, the name hydrogen comes from the Greek words hydro and genes, meaning “water” and “forming.” Compounds Oxygen Figure 3 Elements have different properties than their compounds. Silicon is a gray solid and oxygen is a colorless gas, which can be stored in a metal tank. Silicon and oxygen combine to form silicon dioxide—a colorless, transparent solid found in most grains of sand. Silicon dioxide Water is composed of the elements hydrogen and oxygen. When electricity passes through water, bubbles of oxygen and hydrogen gas form and rise to the surface of the water. If the gases are collected in a container and a flame is brought near the mixture, the hydrogen and oxygen react and form water. Water is classified as a compound. A compound is a substance that is made from two or more simpler substances and can be broken down into those simpler substances. The simpler substances are either elements or other compounds. The properties of a compound differ from those of the substances from which it is made. For example, oxygen and hydrogen are gases at room temperature, but water is a liquid. Hydrogen can fuel a fire, and oxygen can keep a fire burning, but water does not burn or help other substances to burn. In fact, water is one of the substances commonly used to put out fires. Figure 3 shows another example of how properties change when elements join and form compounds. Silicon dioxide is a compound found in most light-colored grains of sand. It is a colorless, transparent solid. Yet, silicon dioxide is made from a colorless gas (oxygen) and a gray solid (silicon). Silicon is used to make chips for computers. A compound always contains two or more elements joined in a fixed proportion. For example, in silicon dioxide, there are always two oxygen atoms for each silicon atom. (Di- means “two.”) In water, there are always two hydrogen atoms for each oxygen atom. What happens if electricity passes through water? 40 Chapter 2 Facts and Figures Electrolysis of Water Early chemists were able to use heat to break down many compounds into their constituent elements. Because water cannot be decomposed by this method, water was classified as an element until chemists were able to use electric current 40 Chapter 2 to break down water into hydrogen and oxygen. (The decomposition of water into hydrogen and oxygen will not occur unless ions are added to the water because there are not enough ions in pure water to conduct an electric current.) Mixtures Figure 4 The ingredients shown are used to make one kind of salsa, which is an example of a heterogeneous mixture. Salsa oes um tomat • 4 or 5 pl Serrano sh fre 5 • 3– s chili pepper of cilantro s rig sp 12 • c clove • large garli ite onion • small wh 1 teaspoons •1 2 juice fresh lime • teaspoon salt 3 4 Figure 5 Sand is a heterogeneous mixture. The spoon is stainless steel, which is a homogeneous mixture. Interpreting Photographs Explain how viewing sand through a hand lens helps show that sand is a heterogeneous mixture. L1 Compare and Contrast Refer to page 226D in Chapter 8, which provides the guidelines for comparing and contrasting. Have students read pp. 41–44 and gather information on different classifications of mixtures. Then, have students create a chart that compares and contrasts each type of mixture. Visual Integrating Language Arts Mixtures Suppose you are making salsa using the ingredients shown in Figure 4. You have a choice. You can use exactly the amounts listed in the recipe, or you can adjust the ingredients according to your own taste. You might have to prepare the recipe a few times before deciding if you have just the right amount of each ingredient. Mixtures tend to retain some of the properties of their individual substances. But the properties of a mixture are less constant than the properties of a substance. The properties of a mixture can vary because the composition of a mixture is not fixed. The type of pepper and the quantity of pepper used in a salsa recipe determine the “hotness” of a batch of salsa. Chili peppers contain a compound called capsaicin (kap SAY uh sin) that can cause a burning sensation in your mouth. The amount of capsaicin varies among types of peppers. Cayenne peppers, for example, contain more capsaicin than do jalapeño peppers. No matter how well you stir a batch of salsa, the ingredients will not be evenly distributed. There may, for example, be more onion in one portion of the salsa than another. Mixtures can be classified by how well the parts of the mixture are distributed throughout the mixture. Build Reading Literacy L2 Have students consider the difference between hot food (as in warm versus cold) and hot food (as in spicy versus mild). Encourage students to suggest examples of dishes other than salsa that are hot in the second, spicy sense. Some students may want to record a family recipe for a “hot” dish. Have them identify the ingredient(s) that can be varied to control the “hotness” of the mixture. Logical Build Science Skills L2 Observing Have students look at samples of sand with a hand lens. Explain that the composition of sand can vary from beach to beach because the rocks and shells from which sand forms have different compositions. Ask, How can you tell that sand is a heterogeneous mixture? (The grains of sand vary in color and size.) (A sample of sand that contains only ground-up shells would probably be classified as homogeneous.) Visual Heterogeneous Mixtures If you look at a handful of sand from a beach, the sand appears to be all the same material. However, if you use a hand lens, you will notice that the sample of sand is not the same throughout. Figure 5 shows that grains of sand vary in size. Also, some grains are light in color and some are dark. Sand is an example of a heterogeneous mixture. Heterogeneous (het uh roh GEE nee us) comes from the Greek words hetero and genus, meaning “different” and “kind.” In a heterogeneous mixture, the parts of the mixture are noticeably different from one another. Properties of Matter 41 Facts and Figures Capsaicinoid Content Capsaicin (8-methylN-vanillyl-6-nonenamide) is the most abundant of a group of compounds called capsaicinoids. These compounds are found in the seeds and membranes of chili peppers. When they are ingested, they affect pain receptors in the mouth and throat. Because capsaicin is an oil, and oil and water do not mix, drinking water spreads the oil to more parts of the mouth and increases the burning sensation. The capsaicinoid content of a pepper is measured in Scoville units. Wilbur Scoville developed the method for measuring the “hotness” of chili peppers in 1912. He mixed ground chilies with a sugar and water solution and diluted the mixture until tasters no longer reported a burning sensation. The greater the dilution needed, the higher the assigned number of Scoville units. Fifteen Scoville units is equivalent to one part per million. Answer to . . . Figure 5 More details are visible in the magnified sand, making it easier to observe the different parts of the mixture. Bubbles of oxygen and hydrogen form and rise to the surface of the water. Properties of Matter 41 Section 2.1 (continued) Do the Contents of Two Cans of Mixed Nuts Meet FDA Regulations? Contents of Two Cans of Mixed Nuts Do the Contents of Two Cans of Mixed Nuts Meet FDA Regulations? L2 Answers 1. Both brands contain the same six types of nuts, but the amount of each type of nut varies. 2. There are 344.79 g in Brand A and 350.32 g in Brand B. The percents by mass in Brand A are: 44.2% peanuts, 13.64% almonds, 16.79% Brazil nuts, 13.4% cashews, 5.77% hazelnuts, and 6.21% pecans. The percents by mass in Brand B are: 54.8% peanuts, 8.90% almonds, 5.59% Brazil nuts, 21.06% cashews, 4.82% hazelnuts, and 4.82% pecans. 3. Yes. Both brands contain more than four types of nuts other than peanuts. The percent of each nut by mass is within the 2% to 80% range. 4. The ingredients are listed in order by total mass. The ingredient with the largest total mass is listed first. For Extra Help The Food and Drug Administration (FDA) has two main areas of concern about food. First, and most important, the FDA ensures that food sold in the United States is safe to eat. Second, the FDA ensures that the information on a food label accurately describes a food product. What can you assume when you see the label “mixed nuts” on a can of nuts? According to the FDA regulations, a can labeled mixed nuts must contain at least four types of shelled nuts other than peanuts. The mass of each type of nut must be not less than 2 percent of the total mass and not more than 80 percent of the total mass. Mass in Brand A Mass in Brand B Peanut 152.39 g 191.96 g Almond 47.02 g 31.18 g Brazil nut 57.88 g 19.60 g Cashew 46.20 g 73.78 g Hazelnut 19.90 g 16.90 g Pecan 21.40 g 16.90 g 1. Comparing and Contrasting How are the two brands of mixed nuts alike? How are they different? 2. Calculating What is the percent by mass of each type of nut in each can? 3. Drawing Conclusions Do the contents of each can meet the FDA regulations? Explain. 4. Inferring On the Brand A label, the nuts are listed in this order: peanuts, Brazil nuts, almonds, cashews, pecans, and hazelnuts. What do you think determines the order? Homogeneous Mixtures If you collect water from both the shallow end and the deep end of a swimming pool, the water samples will appear the same. The water in a swimming pool is a homogeneous (hoh moh GEE nee us) mixture of water and substances that dissolve in water. In a homogeneous mixture, the substances are so evenly distributed that it is difficult to distinguish one substance in the mixture from another. A homogeneous mixture appears to contain only one substance. The serving spoon in Figure 5 is made of stainless steel—a homogeneous mixture of iron, chromium, and nickel. L1 Have students answer Question 3 by calculating 2% and 80% of each total mass and checking to see if any of the masses fall outside that range. Logical Solutions, Suspensions, and Colloids It isn’t always easy to tell a homogeneous mixture from a heterogeneous mixture. You may need to observe the properties of a mixture before you decide. The size of the particles in a mixture has an effect on the properties of the mixture. Based on the size of its largest particles, a mixture can be classified as a solution, a suspension, or a colloid. Solutions, Suspensions, and Colloids Solutions If you place a spoonful of sugar in a glass of hot water FYI Many alloys are not true solutions. Sterling silver, a mixture of silver and copper, is an example. Silver and copper are completely soluble in all proportions when molten. However, solid sterling silver is a two-phase alloy with pockets of silver and pockets of a 71.9% silver and 28.1% copper mixture. Type of Nut For: Links on mixtures Visit: www.SciLinks.org Web Code: ccn-1021 and stir, the sugar dissolves in the water. The result is a homogeneous mixture of sugar and water. When substances dissolve and form a homogeneous mixture, the mixture that forms is called a solution. The windshield wiper fluid in Figure 6 is a solution. So is tap water. 42 Chapter 2 Facts and Figures Download a worksheet on mixtures for students to complete, and find additional teacher support from NSTA SciLinks. 42 Chapter 2 Regulatory Agencies Responsibility for protecting the food supply is shared among the FDA, the Department of Agriculture, and the EPA, which regulates pesticides. Food that is adulterated or mislabeled may be voluntarily destroyed or recalled, or seized by court order. The FDA is responsible for establishing standards for identity, quality, and fill of container. If standards have been set for a product, such as mixed nuts, the product must comply with those standards. Food labels must include a statement of identity (usual or common name), the net quantity of the contents, the name and place of business of the supplier, and a list of ingredients in descending order by mass. The goal is to have honest and informative labels. A Figure 6 The liquids shown represent three categories of mixtures. A Windshield wiper fluid is a solution. B Muddy water collected from a swamp is a suspension. C Milk is a colloid. Comparing and Contrasting Based on appearance, how are a solution and a colloid similar? Transmission Versus Scattering L2 Purpose Students observe light pass through different mixtures. B C Materials 2 beakers, water, iodine solution, table salt, stirring rods, milk, fish tank, flashlight, white paper Procedure Demonstrate that a solution can have color and still transmit light. Fill two beakers halfway with water. Add a small amount of iodine solution to one beaker and stir. Add table salt to the second beaker. Ask students to describe the color of each mixture and state whether it is clear. Demonstrate transmission of light versus scattering. Fill the tank with water. Turn off the lights. Shine a flashlight through the tank so that it lights up the white paper placed behind the tank. Add some milk to the water and stir. Shine the light through the tank again. (These behaviors of light are discussed in detail in Section 18.3.) Liquid solutions are easy to recognize. They do not separate into distinct layers over time. If you pour a liquid solution through a filter, none of the substances in the solution are trapped in the filter. You can see through solutions that are liquids because light passes through them without being scattered in all directions. These three properties of liquid solutions can be traced to the size of the particles in a solution. The particles in a solution are too small to settle out of the solution, be trapped by a filter, or scatter light. Suspensions Have you ever seen the instruction “Shake well before using” on a bottle? This instruction is a clue that the material in the bottle is a suspension. A suspension is a heterogeneous mixture that separates into layers over time. For example, if you shake up a container of sand and water, the sand mixes with the water and forms a suspension. Over time, the suspended particles of sand settle to the bottom of the container. You could use a filter to separate the sand from the water. The water would pass through the filter, but the sand would remain in the filter paper. Suspended particles settle out of a mixture or are trapped by a filter because they are larger than the particles in a solution. The worker in Figure 7 is using a mask to filter out particles of plastic foam that are suspended in air. Because larger particles can scatter light in all directions, suspensions are cloudy. Expected Outcome Although the salt solution is colorless and the iodine solution is colored, both transmit light. Light passes through the water in the tank and makes a bright spot on the paper. With milk added, the light is scattered so that the spot is much less distinct. Visual What happens to suspended particles over time? Figure 7 When a surfboard is sanded, particles of plastic become suspended in air. The worker wears a mask to keep from breathing in the particles. Properties of Matter 43 L1 Use Visuals Figure 7 To emphasize that suspended particles settle out over time, ask, What will happen to the particles of plastic suspended in the air? (The particles will eventually settle out.) Discuss with students the dangers of inhaling suspended particles. Ask, How does a mask prevent the worker from inhaling particles of plastic? (The particles in suspensions can be separated by filtration. The mask is a filter.) Visual Answer to . . . Figure 6 The solution and the colloid both appear homogeneous. Suspended particles settle out of a mixture. Properties of Matter 43 Section 2.1 (continued) Build Science Skills L3 High beam Classifying Have interested students research categories of colloids such as gels, foams, aerosols, and emulsions. Have students find out how scientists distinguish different types of colloids. Have them identify household examples of each type. Visual, Portfolio 3 ASSESS Evaluate Understanding L2 Have students make a game of concentration using the terms in the chapter and their definitions. Have groups of students write each term on separate index cards and the definition of each term on a second set of index cards. To play the game, students should shuffle all the cards together and then lay them face down in a grid. Each student takes turns flipping over two index cards. If the cards match, the student can remove the cards from the grid. If the cards do not match, the student places the cards face down. After all of the cards are gone, the student who has removed the most cards wins the match. Reteach L1 Use Figure 6 as a visual aid to summarize the key differences among different types of mixtures. Students should specify which ingredients are required for the cereal to qualify for a particular label and suggest a range for ingredients such as dried fruit or nuts. (Students could choose another edible mixture, such as canned vegetable soup.) Low beam Figure 8 The photograph shows how water droplets in fog scatter the light from high beams. The drawing compares the areas lit by high beams and low beams. Interpreting Diagrams Which beams normally make a larger area of a road visible? Colloids Milk is a mixture of substances including water, sugar, proteins, and fats. When fresh cow’s milk is allowed to stand, a layer of cream rises to the top. This layer contains much of the fat in the milk. In the milk you buy at the store, the cream does not form a separate layer. The milk has been processed so that the fat remains dispersed throughout the milk. The result is homogenized milk, which is a colloid. A colloid contains some particles that are intermediate in size between the small particles in a solution and the larger particles in a suspension. Like solutions, colloids do not separate into layers. You cannot use a filter to separate the parts of a colloid. Fog is a colloid of water droplets in air. Figure 8 shows how fog affects which headlights a driver uses. Automobiles have headlights with low beams for normal driving conditions and high beams for roads that are poorly lit. With the high beams, a driver can see a bend in the road or an obstacle sooner. But the high beams are not useful on a foggy night because the water droplets scatter light back toward the driver and reduce visibility. With the low beams, much less light is scattered. The scattering of light is a property that can be used to distinguish colloids and suspensions from solutions. Section 2.1 Assessment Reviewing Concepts 1. Why does every sample of a given substance have the same properties? 2. Explain why the composition of an element is fixed. 3. 4. 5. Describe the composition of a compound. Why can the properties of a mixture vary? On what basis can mixtures be classified as solutions, suspensions, or colloids? Critical Thinking 6. Predicting If you added salt instead of sugar to a pitcher of lemonade, how would this change the properties of the lemonade? 7. Interpreting Visuals Explain why silicon dioxide cannot be the only compound in the sample of sand shown in Figure 5. 8. Inferring Fresh milk is a suspension. After fresh milk is homogenized, it is a colloid. What happens to the size of the drops of fat in milk when milk is homogenized? Writing Instructions Pick a cereal that is an obvious mixture. Write rules that could be used to control the cereal’s composition. Use the FDA rules for mixed nuts as a model. 44 Chapter 2 If your class subscribes to the Interactive Textbook, use it to review key concepts in Section 2.1. Section 2.1 Answer to . . . Figure 8 High beams 44 Chapter 2 Assessment 1. A pure substance has a fixed composition. 2. An element contains only one kind of atom. 3. Compounds contain two or more elements joined in a fixed proportion. 4. Because the composition of a mixture is not fixed 5. Mixtures can be classified as solutions, suspensions, or colloids based on the size of their largest particles. 6. The lemonade would taste salty instead of sweet. 7. Silicon dioxide is colorless. There must be at least one other compound in the sample to account for the dark-colored grains. 8. Large drops are broken down into smaller drops, which can remain dispersed throughout the milk.
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