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ORGANIC COMPOUNDS
1.1 NOMENCLATURE OF ORGANIC COMPOUNDS
1.1.1 Nonfunctional Compounds
Table 1.1 Names of Straight-Chain Alkanes
Table 1.2 Fused Polycyclic Hydrocarbons
Table 1.3 Specialist Nomenclature for Heterocyclic Systems
Table 1.4 Suffixes for Specialist Nomenclature of Heterocyclic Systems
Table 1.5 Trivial Names of Heterocyclic Systems Suitable for Use in Fusion
Names
Table 1.6 Trivial Names for Heterocyclic Systems That Are Not Recommended
for Use in Fusion Names
1.1.2 Functional Compounds
Table 1.7 Characteristic Groups for Substitutive Nomenclature
Table 1.8 Characteristic Groups Cited Only as Prefixes in Substitutive
Nomenclature
Table 1.9 Functional Class Names Used in Radicofunctional Nomenclature
1.1.3 Specific Functional Groups
Table 1.10 Retained Trivial Names of Alcohols and Phenols with Structures
Table 1.11 Names of Some Carboxylic Acids
Table 1.12 Parent Structures of Phosphorus-Containing Compounds
1.1.4 Stereochemistry
1.1.5 Chemical Abstracts Indexing System
Table 1.13 Names and Formulas of Organic Radicals
1.2 PHYSICAL PROPERTIES OF PURE SUBSTANCES
Table 1.14 Empirical Formula Index of Organic Compounds
Table 1.15 Physical Constants of Organic Compounds
1.1
1.1
1.1
1.2
1.8
1.11
1.12
1.13
1.16
1.17
1.18
1.19
1.22
1.23
1.24
1.30
1.36
1.39
1.49
1.51
1.58
1.58
1.74
NOMENCLATURE OF ORGANIC COMPOUNDS
The following synopsis of rules for naming organic compounds and the examples given in explanation are not intended to cover all the possible cases. For a more comprehensive and detailed
description, see J. Rigaudy and S. P. Klesney, Nomenclature of Organic Chemistry, Sections A, B,
C, D, E, F, and H, Pergamon Press, Oxford, 1979. This publication contains the recommendations
of the Commission on Nomenclature of Organic Chemistry and was prepared under the auspices of
the International Union of Pure and Applied Chemistry (IUPAC).
1.1.1
Nonfunctional Compounds
1.1.1.1 Alkanes. The saturated open-chain (acyclic) hydrocarbons (CnH2n⫹2) have names ending
in -ane. The first four members have the trivial names methane (CH4), ethane (CH3CH3 or C2H6),
propane (C3H8), and butane (C4H10). For the remainder of the alkanes, the first portion of the name
1.1
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is derived from the Greek prefix (see Table 2.4) that cites the number of carbons in the alkane
followed by -ane with elision of the terminal -a from the prefix, as shown in Table 1.1.
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TABLE 1.1 Names of Straight-Chain Alkanes
n*
Name
n*
Name
n*
Name
1
2
3
4
5
6
7
8
9
10
Methane
Ethane
Propane
Butane
Pentane
Hexane
Heptane
Octane
Nonane†
Decane
11
12
13
14
15
16
17
18
19
20
Undecane‡
Dodecane
Tridecane
Tetradecane
Pentadecane
Hexadecane
Heptadecane
Octadecane
Nonadecane
Icosane§
21
22
23
Henicosane
Docosane
Tricosane
30
31
32
Triacontane
Hentriacontane
Dotriacontane
40
50
Tetracontane
Pentacontane
n*
Name
60
70
80
90
100
110
120
121
Hexacontane
Heptacontane
Octacontane
Nonacontane
Hectane
Decahectane
Icosahectane
Henicosahectane
* n ⫽ total number of carbon atoms.
† Formerly called enneane.
‡ Formerly called hendecane.
§ Formerly called eicosane.
For branching compounds, the parent structure is the longest continuous chain present in the
compound. Consider the compound to have been derived from this structure by replacement of
hydrogen by various alkyl groups. Arabic number prefixes indicate the carbon to which the alkyl
group is attached. Start numbering at whichever end of the parent structure that results in the lowestnumbered locants. The arabic prefixes are listed in numerical sequence, separated from each other
by commas and from the remainder of the name by a hyphen.
If the same alkyl group occurs more than once as a side chain, this is indicated by the prefixes
di-, tri-, tetra-, etc. Side chains are cited in alphabetical order (before insertion of any multiplying
prefix). The name of a complex radical (side chain) is considered to begin with the first letter of its
complete name. Where names of complex radicals are composed of identical words, priority for
citation is given to that radical which contains the lowest-numbered locant at the first cited point of
difference in the radical. If two or more side chains are in equivalent positions, the one to be assigned
the lowest-numbered locant is that cited first in the name. The complete expression for the side chain
may be enclosed in parentheses for clarity or the carbon atoms in side chains may be indicated by
primed locants.
If hydrocarbon chains of equal length are competing for selection as the parent, the choice goes
in descending order to (1) the chain that has the greatest number of side chains, (2) the chain whose
side chains have the lowest-numbered locants, (3) the chain having the greatest number of carbon
atoms in the smaller side chains, or (4) the chain having the least-branched side chains.
These trivial names may be used for the unsubstituted hydrocarbon only:
Isobutane
Isopentane
(CH3)2CHCH3
(CH3)2CHCH2CH3
Neopentane
Isohexane
(CH3)4C
(CH3)2CHCH2CH2CH3
Univalent radicals derived from saturated unbranched alkanes by removal of hydrogen from a
terminal carbon atom are named by adding -yl in place of -ane to the stem name. Thus the alkane
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ethane becomes the radical ethyl. These exceptions are permitted for unsubstituted radicals
only:
Isopropyl
Isobutyl
(CH3)2CH9
Isopentyl
(CH3)2CHCH2 9
Neopentyl
sec-Butyl
CH3CH2CH(CH3) 9
tert-Pentyl
tert-Butyl
(CH3)3C9
Isohexyl
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(CH3)2CHCH2CH2 9
(CH3)3CCH2 9
CH3CH2C(CH3)2 9
(CH3)2CHCH2CH2CH2 9
Note the usage of the prefixes iso-, neo-, sec-, and tert-, and note when italics are employed. Italicized
prefixes are never involved in alphabetization, except among themselves; thus sec-butyl would precede isobutyl, isohexyl would precede isopropyl, and sec-butyl would precede tert-butyl.
Examples of alkane nomenclature are
2-Methylbutane (or the trivial name, isopentane)
3-Methylpentane (not 2-ethylbutane)
5-Ethyl-2,2-dimethyloctane (note cited order)
3-Ethyl-6-methyloctane (note locants reversed)
4,4-Bis(1,1-dimethylethyl)-2-methyloctane
4,4-Bis-1⬘,1⬘-dimethylethyl-2-methyloctane
4,4-Bis(tert-butyl)-2-methyloctane
Bivalent radicals derived from saturated unbranched alkanes by removal of two hydrogen atoms
are named as follows: (1) If both free bonds are on the same carbon atom, the ending -ane of the
hydrocarbon is replaced with -ylidene. However, for the first member of the alkanes it is methylene
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rather than methylidene. Isopropylidene, sec-butylidene, and neopentylidene may be used for the
unsubstituted group only. (2) If the two free bonds are on different carbon atoms, the straight-chain
group terminating in these two carbon atoms is named by citing the number of methylene groups
comprising the chain. Other carbon groups are named as substituents. Ethylene is used rather than
dimethylene for the first member of the series, and propylene is retained for CH3 9 CH 9 CH2 9
(but trimethylene is 9 CH2 9 CH2 9CH2 9).
Trivalent groups derived by the removal of three hydrogen atoms from the same carbon are
named by replacing the ending -ane of the parent hydrocarbon with -ylidyne.
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1.1.1.2 Alkenes and Alkynes. Each name of the corresponding saturated hydrocarbon is converted to the corresponding alkene by changing the ending -ane to -ene. For alkynes the ending is
-yne. With more than one double (or triple) bond, the endings are -adiene, -atriene, etc. (or -adiyne,
-atriyne, etc.). The position of the double (or triple) bond in the parent chain is indicated by a locant
obtained by numbering from the end of the chain nearest the double (or triple) bond; thus
CH3CH2CH" CH2 is 1-butene and CH3C#CCH3 is 2-butyne.
For multiple unsaturated bonds, the chain is so numbered as to give the lowest possible locants
to the unsaturated bonds. When there is a choice in numbering, the double bonds are given the lowest
locants, and the alkene is cited before the alkyne where both occur in the name. Examples:
CH3CH2CH2CH2CH"CH9CH" CH2
CH2 "CHC#CCH"CH2
CH3CH"CHCH2C# CH
CH# CCH2CH"CH2
1,3-Octadiene
1,5-Hexadiene-3-yne
4-Hexen-1-yne
1-Penten-4-yne
Unsaturated branched acyclic hydrocarbons are named as derivatives of the chain that contains
the maximum number of double and/or triple bonds. When a choice exists, priority goes in sequence
to (1) the chain with the greatest number of carbon atoms and (2) the chain containing the maximum
number of double bonds.
These nonsystematic names are retained:
Ethylene
Allene
Acetylene
CH2 "CH2
CH2 "C"CH2
HC#CH
An example of nomenclature for alkenes and alkynes is
4-Propyl-3-vinyl-1,3-hexadien-5-yne
Univalent radicals have the endings -enyl, -ynyl, -dienyl, -diynyl, etc. When necessary, the positions of the double and triple bonds are indicated by locants, with the carbon atom with the free
valence numbered as 1. Examples:
CH2 "CH9CH2 9
CH3 9C#C9
2-Propenyl
1-Propynyl
CH3 9C#C9 CH2CH "CH2 9
These names are retained:
1-Hexen-4-ynyl
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Vinyl (for ethenyl)
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CH2 "CH9
Allyl (for 2-propenyl)
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CH2 "CH9 CH2 9
Isopropenyl (for 1-methylvinyl but for unsubstituted radical only)
CH2 "C(CH3) 9
Should there be a choice for the fundamental straight chain of a radical, that chain is selected
which contains (1) the maximum number of double and triple bonds, (2) the largest number of
carbon atoms, and (3) the largest number of double bonds. These are in descending priority.
Bivalent radicals derived from unbranched alkenes, alkadienes, and alkynes by removing a hydrogen atom from each of the terminal carbon atoms are named by replacing the endings -ene,
-diene, and -yne by -enylene, -dienylene, and -ynylene, respectively. Positions of double and triple
bonds are indicated by numbers when necessary. The name vinylene instead of ethenylene is retained
for 9CH "CH9 .
1.1.1.3 Monocyclic Aliphatic Hydrocarbons. Monocyclic aliphatic hydrocarbons (with no side
chains) are named by prefixing cyclo- to the name of the corresponding open-chain hydrocarbon
having the same number of carbon atoms as the ring. Radicals are formed as with the alkanes,
alkenes, and alkynes. Examples:
Cyclohexane
Cyclohexyl- (for the radical)
Cyclohexene
1-Cyclohexenyl- (for the radical with the free valence at
carbon 1)
1,3-Cyclohexandiene
Cyclohexadienyl- (the unsaturated carbons are given
numbers as low as possible, numbering from the carbon
atom with the free valence given the number 1)
For convenience, aliphatic rings are often represented by simple geometric figures: a triangle for
cyclopropane, a square for cyclobutane, a pentagon for cyclopentane, a hexagon (as illustrated) for
cyclohexane, etc. It is understood that two hydrogen atoms are located at each corner of the figure
unless some other group is indicated for one or both.
1.1.1.4 Monocyclic Aromatic Compounds. Except for six retained names, all monocyclic substituted aromatic hydrocarbons are named systematically as derivatives of benzene. Moreover, if the
substituent introduced into a compound with a retained trivial name is identical with one already
present in that compound, the compound is named as a derivative of benzene. These names are
retained:
Cumene
Cymene (all three
forms; para- shown)
Mesitylene
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Styrene
Toluene
Xylene (all three
forms; meta- shown)
The position of substituents is indicated by numbers, with the lowest locant possible given to
substituents. When a name is based on a recognized trivial name, priority for lowest-numbered
locants is given to substituents implied by the trivial name. When only two substituents are present
on a benzene ring, their position may be indicated by o- (ortho-), m- (meta-), and p- (para-) (and
alphabetized in the order given) used in place of 1,2-, 1,3-, and 1,4-, respectively.
Radicals derived from monocyclic substituted aromatic hydrocarbons and having the free valence
at a ring atom (numbered 1) are named phenyl (for benzene as parent, since benzyl is used for the
radical C6H5CH2 9 ), cumenyl, mesityl, tolyl, and xylyl. All other radicals are named as substituted
phenyl radicals. For radicals having a single free valence in the side chain, these trivial names are
retained:
Benzyl
C6H5CH2 9
Benzhydryl (alternative to
diphenylmethyl)
(C6H5)2CH9
Cinnamyl
Phenethyl
C6H5CH2CH2 9
Styryl
C6H5CH"CH9
Trityl
(C6H5)3C 9
C6H5CH" CH9CH2 9
Otherwise, radicals having the free valence(s) in the side chain are named in accordance with the
rules for alkanes, alkenes, or alkynes.
The name phenylene (o-, m-, or p-) is retained for the radical 9C6H4 9 . Bivalent radicals formed
from substituted benzene derivatives and having the free valences at ring atoms are named as substituted phenylene radicals, with the carbon atoms having the free valences being numbered 1,2-,
1,3-, or 1,4-, as appropriate.
Radicals having three or more free valences are named by adding the suffixes -triyl, -tetrayl, etc.
to the systematic name of the corresponding hydrocarbon.
1.1.1.5 Fused Polycyclic Hydrocarbons. The names of polycyclic hydrocarbons containing the
maximum number of conjugated double bonds end in -ene. Here the ending does not denote one
double bond. Names of hydrocarbons containing five or more fixed benzene rings in a linear arrangement are formed from a numerical prefix (see Table 2.4) followed by -acene. A partial list of
the names of polycyclic hydrocarbons is given in Table 1.2. Many names are trivial.
Numbering of each ring system is fixed, as shown in Table 1.2, but it follows a systematic pattern.
The individual rings of each system are oriented so that the greatest number of rings are (1) in a
horizontal row and (2) the maximum number of rings are above and to the right (upper-right quadrant) of the horizontal row. When two orientations meet these requirements, the one is chosen that
has the fewest rings in the lower-left quadrant. Numbering proceeds in a clockwise direction, commencing with the carbon atom not engaged in ring fusion that lies in the most counterclockwise
position of the uppermost ring (upper-right quadrant); omit atoms common to two or more rings.
Atoms common to two or more rings are designated by adding lowercase roman letters to the number
of the position immediately preceding. Interior atoms follow the highest number, taking a clockwise
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sequence wherever there is a choice. Anthracene and phenanthrene are two exceptions to the rule
on numbering. Two examples of numbering follow:
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When a ring system with the maximum number of conjugated double bonds can exist in two or
more forms differing only in the position of an “extra” hydrogen atom, the name can be made
specific by indicating the position of the extra hydrogen(s). The compound name is modified with
a locant followed by an italic capital H for each of these hydrogen atoms. Carbon atoms that carry
an indicated hydrogen atom are numbered as low as possible. For example, 1H-indene is illustrated
in Table 1.2; 2H-indene would be
Names of polycyclic hydrocarbons with less than the maximum number of noncumulative double
bonds are formed from a prefix dihydro-, tetrahydro-, etc., followed by the name of the corresponding
unreduced hydrocarbon. The prefix perhydro- signifies full hydrogenation. For example, 1,2-dihydronaphthalene is
Examples of retained names and their structures are as follows:
Indan
Acenaphthene
Aceanthrene
Acephenanthrene
Polycyclic compounds in which two rings have two atoms in common or in which one ring
contains two atoms in common with each of two or more rings of a contiguous series of rings and
which contain at least two rings of five or more members with the maximum number of noncumu-
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TABLE 1.2 Fused Polycyclic Hydrocarbons
Listed in order of increasing priority for selection as parent compound.
1. Pentalene
9. Acenaphthylene
2. Indene
10. Fluorene
3. Naphthalene
11. Phenalene
4. Azulene
12. Phenanthrene*
5. Heptalene
13. Anthracene*
14. Fluoranthene
6. Biphenylene
7. asym-Indacene
15. Acephenanthrylene
8. sym-Indacene
16. Aceanthrylene
* Asterisk after a compound denotes exception to systematic numbering.
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TABLE 1.2 Fused Polycyclic Hydrocarbons (Continued)
17. Triphenylene
19. Chrysene
18. Pyrene
20. Naphthacene
lative double bonds and which have no accepted trivial name (Table 1.2) are named by prefixing to
the name of the parent ring or ring system designations of the other components. The parent name
should contain as many rings as possible (provided it has a trivial name) and should occur as far as
possible from the beginning of the list in Table 1.2. Furthermore, the attached component(s) should
be as simple as possible. For example, one writes dibenzophenanthrene and not naphthophenanthrene
because the attached component benzo- is simpler than napththo-. Prefixes designating attached
components are formed by changing the ending -ene into -eno-; for example, indeno- from indene.
Multiple prefixes are arranged in alphabetical order. Several abbreviated prefixes are recognized; the
parent is given in parentheses:
Acenaphtho-
(acenaphthylene)
Naphtho-
Anthra-
(anthracene)
Perylo-
Benzo-
(benzene)
Phenanthro-
(naphthalene)
(perylene)
(phenanthrene)
For monocyclic prefixes other than benzo-, the following names are recognized, each to represent
the form with the maximum number of noncumulative double bonds: cyclopenta-, cyclohepta-,
cycloocta-, etc.
Isomers are distinguished by lettering the peripheral sides of the parent beginning with a for the
side 1,2, and so on, lettering every side around the periphery. If necessary for clarity, the numbers
of the attached position (1,2, for example) of the substituent ring are also denoted. The prefixes are
cited in alphabetical order. The numbers and letters are enclosed in square brackets and placed
immediately after the designation of the attached component. Examples are
Benz[␣]anthracene
Anthra[2,1-␣]naphthacene
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1.1.1.6 Bridged Hydrocarbons. Saturated alicyclic hydrocarbon systems consisting of two rings
that have two or more atoms in common take the name of the open-chain hydrocarbon containing
the same total number of carbon atoms and are preceded by the prefix bicyclo-. The system is
numbered commencing with one of the bridgeheads, numbering proceeding by the longest possible
path to the second bridgehead. Numbering is then continued from this atom by the longer remaining
unnumbered path back to the first bridgehead and is completed by the shortest path from the atom
next to the first bridgehead. When a choice in numbering exists, unsaturation is given the lowest
numbers. The number of carbon atoms in each of the bridges connecting the bridgeheads is indicated
in brackets in descending order. Examples are
Bicyclo[3.2.1]octane
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Bicyclo[5.2.0]nonane
1.1.1.7 Hydrocarbon Ring Assemblies. Assemblies are two or more cyclic systems, either single
rings or fused systems, that are joined directly to each other by double or single bonds. For identical
systems naming may proceed (1) by placing the prefix bi- before the name of the corresponding
radical or (2), for systems joined through a single bond, by placing the prefix bi- before the name
of the corresponding hydrocarbon. In each case, the numbering of the assembly is that of the corresponding radical or hydrocarbon, one system being assigned unprimed numbers and the other
primed numbers. The points of attachment are indicated by placing the appropriate locants before
the name; an unprimed number is considered lower than the same number primed. The name biphenyl
is used for the assembly consisting of two benzene rings. Examples are
1,1⬘-Bicyclopropyl or 1,1⬘-bicyclopropane
2-Ethyl-2⬘-propylbiphenyl
For nonidentical ring systems, one ring system is selected as the parent and the other systems
are considered as substituents and are arranged in alphabetical order. The parent ring system is
assigned unprimed numbers. The parent is chosen by considering the following characteristics in
turn until a decision is reached: (1) the system containing the larger number of rings, (2) the system
containing the larger ring, (3) the system in the lowest state of hydrogenation, and (4) the highestorder number of ring systems set forth in Table 1.2. Examples are given, with the deciding priority
given in parentheses preceding the name:
(1) 2-Phenylnaphthalene
(2) and (4) 2-(2⬘-Naphthyl)azulene
(3) Cyclohexylbenzene
1.1.1.8 Radicals from Ring Systems. Univalent substituent groups derived from polycyclic hydrocarbons are named by changing the final e of the hydrocarbon name to -yl. The carbon atoms
having free valences are given locants as low as possible consistent with the fixed numbering of the
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hydrocarbon. Exceptions are naphthyl (instead of naphthalenyl), anthryl (for anthracenyl), and phenanthryl (for phenanthrenyl). However, these abbreviated forms are used only for the simple ring
systems. Substituting groups derived from fused derivatives of these ring systems are named systematically. Substituting groups having two or more free bonds are named as described in Monocyclic Aliphatic Hydrocarbons on p. 1.5.
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1.1.1.9 Cyclic Hydrocarbons with Side Chains. Hydrocarbons composed of cyclic and aliphatic
chains are named in a manner that is the simplest permissible or the most appropriate for the chemical
intent. Hydrocarbons containing several chains attached to one cyclic nucleus are generally named
as derivatives of the cyclic compound, and compounds containing several side chains and/or cyclic
radicals attached to one chain are named as derivatives of the acyclic compound. Examples are
2-Ethyl-1-methylnaphthalene
Diphenylmethane
1,5-Diphenylpentane
2,3-Dimethyl-1-phenyl-1-hexene
Recognized trivial names for composite radicals are used if they lead to simplifications in naming.
Examples are
1-Benzylnaphthalene
1,2,4-Tris(3-p-tolylpropyl)benzene
Fulvene, for methylenecyclopentadiene, and stilbene, for 1,2-diphenylethylene, are trivial names
that are retained.
1.1.1.10 Heterocyclic Systems. Heterocyclic compounds can be named by relating them to the
corresponding carbocyclic ring systems by using replacement nomenclature. Heteroatoms are denoted by prefixes ending in a, as shown in Table 1.3. If two or more replacement prefixes are required
in a single name, they are cited in the order of their listing in the table. The lowest possible numbers consistent with the numbering of the corresponding carbocyclic system are assigned to the
heteroatoms and then to carbon atoms bearing double or triple bonds. Locants are cited immediately
preceding the prefixes or suffixes to which they refer. Multiplicity of the same heteroatom is indicated
by the appropriate prefix in the series: di-, tri-, tetra-, penta-, hexa-, etc.
TABLE 1.3 Specialist Nomenclature for Heterocyclic Systems
Heterocyclic atoms are listed in decreasing order of priority.
Element
Valence
Prefix
Element
Valence
Prefix
Oxygen
Sulfur
Selenium
Tellurium
Nitrogen
Phosphorus
Arsenic
2
2
2
2
3
3
3
OxaThiaSelenaTelluraAzaPhospha-*
Arsa-*
Antimony
Bismuth
Silicon
Germanium
Tin
Lead
Boron
Mercury
3
3
4
4
4
4
3
2
Stiba-*
BismaSilaGermaStannaPlumbaBoraMercura-
* When immediately followed by -in or -ine, phospha- should be replaced by phosphor-, arsa- by arsen-, and stibaby antimon-. The saturated six-membered rings corresponding to phosphorin and arsenin are named phosphorinane and
arsenane. A further exception is the replacement of borin by borinane.
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TABLE 1.4 Suffixes for Specialist Nomenclature of Heterocyclic Systems
Rings containing nitrogen
Rings containing no nitrogen
Number of
ring
members
Unsaturation*
Saturation
Unsaturation*
Saturation
3
4
5
6
7
8
9
10
-irine
-ete
-ole
-ine†
-epine
-ocine
-onine
-ecine
-iridine
-etidine
-olidine
‡
‡
‡
‡
‡
-irene
-ete
-ole
-in
-epin
-ocin
-onin
-ecin
-irane
-etane
-olane
-ane§
-epane
-ocane
-onane
-ecane
* Unsaturation corresponding to the maximum number of noncumulative double bonds. Heteroatoms have
the normal valences given in Table 1.3.
† For phosphorus, arsenic, antimony, and boron, see the special provisions in Table 1.3.
‡ Expressed by prefixing perhydro- to the name of the corresponding unsaturated compound.
§ Not applicable to silicon, germanium, tin, and lead; perhydro- is prefixed to the name of the corresponding
unsaturated compound.
If the corresponding carbocyclic system is partially or completely hydrogenated, the additional
hydrogen is cited using the appropriate H- or hydro- prefixes. A trivial name from Tables 1.5 and
1.6, if available, along with the state of hydrogenation may be used. In the specialist nomenclature
for heterocyclic systems, the prefix or prefixes from Table 1.3 are combined with the appropriate
stem from Table 1.4, eliding an a where necessary. Examples of acceptable usage, including (1)
replacement and (2) specialist nomenclature, are
(1) 1-Oxa-4-azacyclohexane
(2) 1,4-Oxazoline
Morpholine
(1) 1,3-Diazacyclohex-5-ene
(2) 1,2,3,4-Tetrahydro-1,3-diazine
(1) Thiacyclopropane
(2) Thiirane
Ethylene sulfide
Radicals derived from heterocyclic compounds by removal of hydrogen from a ring are named
by adding -yl to the names of the parent compounds (with elision of the final e, if present). These
exceptions are retained:
Furyl (from furan)
Furfuryl (for 2-furylmethyl)
Pyridyl (from pyridine)
Furfurylidene (for 2-furylmethylene)
Piperidyl (from piperidine)
Thienyl (from thiophene)
Quinolyl (from quinoline)
Thenylidyne (for thienylmethylidyne)
Isoquinolyl
Furfurylidyne (for 2-furylmethylidyne)
Thenylidene (for thienylmethylene)
Thenyl (for thienylmethyl)
Also, piperidino- and morpholino- are preferred to 1-piperidyl- and 4-morpholinyl-, respectively.
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TABLE 1.5 Trivial Names of Heterocyclic Systems Suitable for Use in Fusion Names
Listed in order of increasing priority as senior ring system.
Structure
Parent name
Thiophene
Radical name
Thienyl
Thianthrene
Thianthrenyl
Furan
Furyl
Pyran
(2H-shown)
Isobenzofuran
Chromene
(2H-shown)
Xanthene*
Phenoxathiin
Structure
Parent name
Radical name
2H-Pyrrole
2H-Pyrrolyl
Pyrrole
Pyrrolyl
Imidazole
Imidazolyl
Pyrazole
Pyrazolyl
Isothiazole
Isothiazolyl
Isoxazole
Isoxazolyl
Pyridine
Pyridyl
Pyrazine
Pyrazinyl
Pyrimidine
Pyrimidinyl
Pyridazine
Pyridazinyl
Pyranyl
Isobenzofuranyl
Chromenyl
Xanthenyl
Phenoxathiinyl
* Asterisk after a compound denotes exception to systematic numbering.
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TABLE 1.5 Trivial Names of Heterocyclic Systems Suitable for Use in Fusion Names (Continued)
Structure
Parent name
Radical name
Structure
Parent name
Radical name
Indolizine
Indolizinyl
Phthalazine
Phthalazinyl
Isoindole
Isoindolyl
Naphthyridine
(1,8-shown)
Naphthyridinyl
3H-Indole
3H-Indolyl
Quinoxaline
Quinoxalinyl
Quinazoline
Quinazolinyl
Cinnoline
Cinnolinyl
Pteridine
Pteridinyl
4␣HCarbazole*
4␣HCarbazolyl
Carbazole*
Carbazolyl
Indole
1H-Indazole
Purine*
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Indolyl
1H-Indazolyl
Purinyl
4H-Quinolizine
4H-Quinolizinyl
Isoquinoline
Isoquinolyl
Quinolone
Quinolyl
* Asterisk after a compound denotes exception to systematic numbering.
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TABLE 1.5 Trivial Names of Heterocyclic Systems Suitable for Use in Fusion Names (Continued)
Structure
Parent name
Radical name
Structure
Parent name
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Radical name
␤-Carboline
␤-Carbolinyl
Phenazine
Phenazinyl
Phenanthridine
Phenanthridinyl
Phenarsazine
Phenarsazinyl
Acridine*
Acridinyl
Perimidine
Perimidinyl
Phenothiazine
Phenothiazinyl
Furazan
Furazanyl
Phenoxazine
Phenoxazinyl
Phenanthroline
(1,10-shown)
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Phenanthrolinyl
* Asterisk after a compound denotes exception to systematic numbering.
If there is a choice among heterocyclic systems, the parent compound is decided in the following
order of preference:
1. A nitrogen-containing component
2. A component containing a heteroatom, in the absence of nitrogen, as high as possible in Table
1.3
3. A component containing the greater number of rings
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TABLE 1.6 Trivial Names of Heterocyclic Systems That Are Not Recommended for Use in Fusion Names
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Listed in order of increasing priority.
Structure
Parent name
Radical name
Isochroman
Isochromanyl
Chroman
Chromanyl
Pyrrolidine
Pyrrolinyl
Pyrroline
(2-shown*)
Pyrrolinyl
Imidazolidine
Imidazoline
(2-shown*)
Pyrazolidine
Structure
Parent name
Radical name
Pyrazoline
(3-shown*)
Pyrazolinyl
Piperidine
Piperidyl†
Piperazine
Piperazinyl
Indoline
Indolinyl
Isoindoline
Isoindolinyl
Quinuclidine
Quinuclidinyl
Morpholine
Morpholinyl‡
Imidazolidinyl
Imidazolinyl
Pyrazolidinyl
* Denotes position of double bond.
† For 1-piperidyl, use piperidino.
‡ For 4-morpholinyl, use morpholino.
4. A component containing the largest possible individual ring
5. A component containing the greatest number of heteroatoms of any kind
6. A component containing the greatest variety of heteroatoms
7. A component containing the greatest number of heteroatoms first listed in Table 1.3
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If there is a choice between components of the same size containing the same number and kind
of heteroatoms, choose as the base component that one with the lower numbers for the heteroatoms
before fusion. When a fusion position is occupied by a heteroatom, the names of the component
rings to be fused are selected to contain the heteroatom.
1.1.2
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Functional Compounds
There are several types of nomenclature systems that are recognized. Which type to use is sometimes
obvious from the nature of the compound. Substitutive nomenclature, in general, is preferred because
of its broad applicability, but radicofunctional, additive, and replacement nomenclature systems are
convenient in certain situations.
1.1.2.1 Substitutive Nomenclature. The first step is to determine the kind of characteristic (functional) group for use as the principal group of the parent compound. A characteristic group is a
recognized combination of atoms that confers characteristic chemical properties on the molecule in
which it occurs. Carbon-to-carbon unsaturation and heteroatoms in rings are considered nonfunctional for nomenclature purposes.
Substitution means the replacement of one or more hydrogen atoms in a given compound by
some other kind of atom or group of atoms, functional or nonfunctional. In substitutive nomenclature,
each substituent is cited as either a prefix or a suffix to the name of the parent (or substituting radical)
to which it is attached; the latter is denoted the parent compound (or parent group if a radical).
In Table 1.7 are listed the general classes of compounds in descending order of preference for
citation as suffixes, that is, as the parent or characteristic compound. When oxygen is replaced by
sulfur, selenium, or tellurium, the priority for these elements is in the descending order listed. The
higher valence states of each element are listed before considering the successive lower valence
states. Derivative groups have priority for citation as principal group after the respective parents of
their general class.
In Table 1.8 are listed characteristic groups that are cited only as prefixes (never as suffixes) in
substitutive nomenclature. The order of listing has no significance for nomenclature purposes.
Systematic names formed by applying the principles of substitutive nomenclature are single
words except for compounds named as acids. First one selects the parent compound, and thus the
suffix, from the characteristic group listed earliest in Table 1.7. All remaining functional groups are
handled as prefixes that precede, in alphabetical order, the parent name. Two examples may be
helpful:
Structure I
Structure II
Structure I contains an ester group and an ether group. Since the ester group has higher priority, the
name is ethyl 2-methoxy-6-methyl-3-cyclohexene-1-carboxylate. Structure II contains a carbonyl
group, a hydroxy group, and a bromo group. The latter is never a suffix. Between the other two, the
carbonyl group has higher priority, the parent has -one as suffix, and the name is 4-bromo-1-hydroxy2-butanone.
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Selection of the principal alicyclic chain or ring system is governed by these selection rules:
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1. For purely alicyclic compounds, the selection process proceeds successively until a decision is
reached: (a) the maximum number of substituents corresponding to the characteristic group cited
earliest in Table 1.7, (b) the maximum number of double and triple bonds considered together,
(c) the maximum length of the chain, and (d) the maximum number of double bonds. Additional
criteria, if needed for complicated compounds, are given in the IUPAC nomenclature rules.
2. If the characteristic group occurs only in a chain that carries a cyclic substituent, the compound
is named as an aliphatic compound into which the cyclic component is substituted; a radical
prefix is used to denote the cyclic component. This chain need not be the longest chain.
3. If the characteristic group occurs in more than one carbon chain and the chains are not directly
TABLE 1.7 Characteristic Groups for Substitutive Nomenclature
Listed in order of decreasing priority for citation as principal group or parent name.
Class
Formula*
1. Cations:
H4N⫹
H3O⫹
H3S⫹
H3Se⫹
H2Cl⫹
H2Br⫹
H2I⫹
2. Acids:
Carboxylic
Sulfonic
Sulfinic
Sulfenic
Salts
3. Derivatives of
acids:
Anhydrides
Esters
Acid halides
Amides
9 COOH
9 (C)OOH
9 C( " O)OOH
9 (C " O)OOH
9 SO3H
9 SO2H
9 SOH
9 COOM
9 (C)OOM
9 SO3M
9 SO2M
9 SOM
9 C( " O)OC( " O) 9
9 (C " O)O(C " O) 9
9 COOR
9 C(OOR)
9 CO 9 halogen
9 CO 9 NH2
(C)O 9 NH2
Prefix
Suffix
-onioAmmonioOxonioSulfonioSelenonioChloronioBromonioIodonio-
-onium
-ammonium
-oxonium
-sulfonium
-selenonium
-chloronium
-bromonium
-iodonium
Carboxy-
-carboxylic acid
-oic acid
-peroxy···carboxylic
acid
-peroxy···oic acid
-sulfonic acid
-sulfinic acid
-sulfenic acid
Metal···carboxylate
Metal···oate
Metal···sulfonate
Metal···sulfinate
Metal···sulfenate
SulfoSulfinoSulfeno-
R-oxycarbonylHaloformyl
Carbamoyl-
-carboxylic anhydride
-oic anhydride
R···carboxylate
R···oate
-carbonyl halide
-carboxamide
-amide
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TABLE 1.7 Characteristic Groups for Substitutive Nomenclature (Continued)
Class
Hydrazides
Imides
Amidines
4. Nitrile (cyanide)
5. Aldehydes
6. Ketones
7. Alcohols
(and phenols)
Thiols
8. Hydroperoxides
9. Amines
Imines
Hydrazines
10. Ethers
Sulfides
11. Peroxides
Formula*
Prefix
9 CO 9 NHNH2
Carbonylhydrazino-
9 (CO) 9 NHNH2
9 CO 9 NH 9 CO 9
9 C( " NH) 9 NH2
9 (C " NH) 9 NH2
9 CN
9 (C)N
9 CHO
9 (C " O)H
(then their analogs and
R-imidoAmidinoCyanoFormylOxoderivatives)
(C " O)
Oxo(then their analogs and derivatives)
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Suffix
-carbohydrazide
-ohydrazide
-carboximide
-carboxamidine
-amidine
-carbonitrile
-nitrile
-carbaldehyde
-al
-one
9 OH
Hydroxy-
-ol
9 SH
9 O 9 OH
9 NH2
NH
9 NHNH2
9 OR
9 SR
9 O 9 OR
MercaptoHydroperoxyAminoIminoHydrazinoR-oxyR-thioR-dioxy-
-thiol
-amine
-imine
-hydrazine
* Carbon atoms enclosed in parentheses are included in the name of the parent compound and not in the suffix
or prefix.
TABLE 1.8 Characteristic Groups Cited Only as Prefixes in Substitutive Nomenclature
Characteristic
group
Prefix
9 Br
Bromo-
9 Cl
9 ClO
9 ClO2
9 ClO3
9F
9I
9 IO
9 IO2
9 I(OH)2
ChloroChlorosylChlorylPerchlorylFluoroIodoIodosylIodyl*
Dihydroxyiodo-
* Formerly iodoxy.
Characteristic
group
Prefix
9 IX2
X may be halogen or a
radical; dihalogenoiodoor diacetoxyiodo-, e.g.,
9 ICl2 is dichloroido-
N2
9 N3
9 NO
9 NO2
N(" O)OH
9 OR
9 SR
9 SeR ( 9 TeR)
DiazoAzidoNitrosoNitroaci-NitroR-oxyR-thioR-seleno- (R-telluro-)
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attached to one another, then the chain chosen as parent should carry the largest number of the
characteristic group. If necessary, the selection is continued as in rule 1.
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4. If the characteristic group occurs only in one cyclic system, that system is chosen as the parent.
5. If the characteristic group occurs in more than one cyclic system, that system is chosen as parent
which (a) carries the largest number of the principal group or, failing to reach a decision, (b) is
the senior ring system.
6. If the characteristic group occurs both in a chain and in a cyclic system, the parent is that portion
in which the principal group occurs in largest number. If the numbers are the same, that portion
is chosen which is considered to be the most important or is the senior ring system.
7. When a substituent is itself substituted, all the subsidiary substituents are named as prefixes and
the entire assembly is regarded as a parent radical.
8. The seniority of ring systems is ascertained by applying the following rules successively until a
decision is reached: (a) all heterocycles are senior to all carbocycles, (b) for heterocycles, the
preference follows the decision process described under Heterocyclic Systems, p. 1.11, (c) the
largest number of rings, (d) the largest individual ring at the first point of difference, (e) the
largest number of atoms in common among rings, (f) the lowest letters in the expression for ring
functions, (g) the lowest numbers at the first point of difference in the expression for ring junctions, (h) the lowest state of hydrogenation, (i) the lowest-numbered locant for indicated hydrogen,
(j) the lowest-numbered locant for point of attachment (if a radical), (k) the lowest-numbered
locant for an attached group expressed as a suffix, (l) the maximum number of substituents cited
as prefixes, (m) the lowest-numbered locant for substituents named as prefixes, hydro prefixes,
-ene, and -yne, all considered together in one series in ascending numerical order independent of
their nature, and (n) the lowest-numbered locant for the substituent named as prefix which is cited
first in the name.
Numbering of Compounds. If the rules for aliphatic chains and ring systems leave a choice, the
starting point and direction of numbering of a compound are chosen so as to give lowest-numbered
locants to these structural factors, if present, considered successively in the order listed below until
a decision is reached. Characteristic groups take precedence over multiple bonds.
1. Indicated hydrogen, whether cited in the name or omitted as being conventional
2. Characteristic groups named as suffix following the ranking order of Table 1.7
3. Multiple bonds in acyclic compounds; in bicycloalkanes, tricycloalkanes, and polycycloalkanes,
double bonds having priority over triple bonds; and in heterocyclic systems whose names end in
-etine, -oline, or -olene
4. The lowest-numbered locant for substituents named as prefixes, hydro prefixes, -ene, and -yne,
all considered together in one series in ascending numerical order
5. The lowest locant for that substituent named as prefix which is cited first in the name
For cyclic radicals, indicated hydrogen and thereafter the point of attachment (free valency) have
priority for the lowest available number.
Prefixes and Affixes. Prefixes are arranged alphabetically and placed before the parent name;
multiplying affixes, if necessary, are inserted and do not alter the alphabetical order already attained.
The parent name includes any syllables denoting a change of ring member or relating to the structure
of a carbon chain. Nondetachable parts of parent names include
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1. Forming rings; cyclo-, bicyclo-, spiro2. Fusing two or more rings: benzo-, naphtho-, imidazo3. Substituting one ring or chain member atom for another: oxa-, aza-, thia4. Changing positions of ring or chain members: iso-, sec-, tert-, neo5. Showing indicated hydrogen
6. Forming bridges: ethano-, epoxy7. HydroPrefixes that represent complete terminal characteristic groups are preferred to those representing
only a portion of a given group. For example, for the prefix 9 C( "O)CH3 , the name (formylmethyl)
is preferred to (oxoethyl).
The multiplying affixes di-, tri-, tetra-, penta-, hexa-, hepta-, octa-, nona-, deca-, undeca-, and so
on are used to indicate a set of identical unsubstituted radicals or parent compounds. The forms
bis-, tris-, tetrakis-, pentakis-, and so on are used to indicate a set of identical radicals or parent
compounds each substituted in the same way. The affixes bi-, ter-, quater-, quinque-, sexi-, septi-,
octi-, novi-, deci-, and so on are used to indicate the number of identical rings joined together by a
single or double bond.
Although multiplying affixes may be omitted for very common compounds when no ambiguity
is caused thereby, such affixes are generally included throughout this handbook in alphabetical
listings. An example would be ethyl ether for diethyl ether.
1.1.2.2 Conjunctive Nomenclature. Conjunctive nomenclature may be applied when a principal
group is attached to an acyclic component that is directly attached by a carbon-carbon bond to a
cyclic component. The name of the cyclic component is attached directly in front of the name of
the acyclic component carrying the principal group. This nomenclature is not used when an unsaturated side chain is named systematically. When necessary, the position of the side chain is indicated
by a locant placed before the name of the cyclic component. For substituents on the acyclic chain,
carbon atoms of the side chain are indicated by Greek letters proceeding from the principal group
to the cyclic component. The terminal carbon atom of acids, aldehydes, and nitriles is omitted when
allocating Greek positional letters. Conjunctive nomenclature is not used when the side chain carries
more than one of the principal group, except in the case of malonic and succinic acids.
The side chain is considered to extend only from the principal group to the cyclic component.
Any other chain members are named as substituents, with appropriate prefixes placed before the
name of the cyclic component.
When a cyclic component carries more than one identical side chain, the name of the cyclic
component is followed by di-, tri-, etc., and then by the name of the acyclic component, and it is
preceded by the locants for the side chains. Examples are
4-Methyl-1-cyclohexaneethanol
␣-Ethyl-␤, ␤-dimethylcyclohexaneethanol
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When side chains of two or more different kinds are attached to a cyclic component, only the
senior side chain is named by the conjunctive method. The remaining side chains are named as
prefixes. Likewise, when there is a choice of cyclic component, the senior is chosen. Benzene
derivatives may be named by the conjunctive method only when two or more identical side chains
are present. Trivial names for oxo carboxylic acids may be used for the acyclic component. If the
cyclic and acyclic components are joined by a double bond, the locants of this bond are placed as
superscripts to a Greek capital delta that is inserted between the two names. The locant for the cyclic
component precedes that for the acyclic component, e.g., indene-⌬1,␣-acetic acid.
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1.1.2.3 Radicofunctional Nomenclature. The procedures of radicofunctional nomenclature are
identical with those of substitutive nomenclature except that suffixes are never used. Instead, the
functional class name (Table 1.9) of the compound is expressed as one word and the remainder of
the molecule as another that precedes the class name. When the functional class name refers to a
characteristic group that is bivalent, the two radicals attached to it are each named, and when different, they are written as separate words arranged in alphabetical order. When a compound contains
more than one kind of group listed in Table 1.9, that kind is cited as the functional group or class
name that occurs higher in the table, all others being expressed as prefixes.
Radicofunctional nomenclature finds some use in naming ethers, sulfides, sulfoxides, sulfones,
selenium analogs of the preceding three sulfur compounds, and azides.
TABLE 1.9 Functional Class Names Used in Radicofunctional Nomenclature
Groups are listed in order of decreasing priority.
Group
X in acid derivatives
9 CN, 9 NC
CO
9 OH
9 O 9 OH
O
S, SO, SO2
Se, SeO, SeO2
9 F, 9 Cl, 9 Br, 9 I
9 N3
Functional class names
Name of X (in priority order: fluoride, chloride, bromide,
iodide, cyanide, azide; then the sulfur and selenium
analogs)
Cyanide, isocyanide
Ketone; then S and Se analogs
Alcohol; then S and Se analogs
Hydroperoxide
Ether or oxide
Sulfide, sulfoxide, sulfone
Selenide, selenoxide, selenone
Fluoride, chloride, bromide, iodide
Azide
1.1.2.4 Replacement Nomenclature. Replacement nomenclature is intended for use only when
other nomenclature systems are difficult to apply in the naming of chains containing heteroatoms.
When no group is present that can be named as a principal group, the longest chain of carbon and
heteroatoms terminating with carbon is chosen and named as though the entire chain were that of
an acyclic hydrocarbon. The heteroatoms within this chain are identified by means of prefixes
aza-, oxa-, thia-, etc., in the order of priority stated in Table 1.3. Locants indicate the positions of
the heteroatoms in the chain. Lowest-numbered locants are assigned to the principal group when
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such is present. Otherwise, lowest-numbered locants are assigned to the heteroatoms considered
together and, if there is a choice, to the heteroatoms cited earliest in Table 1.3. An example is
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13-Hydroxy-9,12-dioxa-3,6-diazatridecanoic acid
1.1.3
Specific Functional Groups
Characteristic groups will now be treated briefly in order to expand the terse outline of substitutive
nomenclature presented in Table 1.7. Alternative nomenclature will be indicated whenever desirable.
1.1.3.1 Acetals and Acylals. Acetals, which contain the group ⬎C(OR)2 , where R may be different, are named (1) as dialkoxy compounds or (2) by the name of the corresponding aldehyde or
ketone followed by the name of the hydrocarbon radical(s) followed by the word acetal. For example,
CH3 9 CH(OCH3 )2 is named either (1) 1,1-dimethoxyethane or (2) acetaldehyde dimethyl acetal.
A cyclic acetal in which the two acetal oxygen atoms form part of a ring may be named
(1) as a heterocyclic compound or (2) by use of the prefix methylenedioxy for the group
9O9CH2 9 O 9 as a substituent in the remainder of the molecule. For example,
(1) 1,3-Benzo[d]dioxole-5-carboxylic acid
(2) 3,4-Methylenedioxybenzoic acid
Acylals, R1R2C(OCOR3 )2 , are named as acid esters;
Butylidene acetate
propionate
␣-Hydroxy ketones, formerly called acyloins, had been named by changing the ending -ic acid
or -oic acid of the corresponding acid to -oin. They are preferably named by substitutive nomenclature; thus
CH3 9CH(OH)9CO9 CH3
3-Hydroxy-2-butanone (formerly acetoin)
1.1.3.2 Acid Anhydrides. Symmetrical anhydrides of monocarboxylic acids, when unsubstituted,
are named by replacing the word acid by anhydride. Anhydrides of substituted monocarboxylic
acids, if symmetrically substituted, are named by prefixing bis- to the name of the acid and replacing
the word acid by anhydride. Mixed anhydrides are named by giving in alphabetical order the first
part of the names of the two acids followed by the word anhydride, e.g., acetic propionic anhydride
or acetic propanoic anhydride. Cyclic anhydrides of polycarboxylic acids, although possessing a
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heterocyclic structure, are preferably named as acid anhydrides. For example,
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1,8;4,5-Napthalenetetracarboxylic dianhydride (note the use of a
semicolon to distinguish the pairs of locants)
1.1.3.3 Acyl Halides. Acyl halides, in which the hydroxyl portion of a carboxyl group is replaced
by a halogen, are named by placing the name of the corresponding halide after that of the acyl
radical. When another group is present that has priority for citation as principal group or when the
acyl halide is attached to a side chain, the prefix haloformyl- is used as, for example, in fluoroformyl-.
1.1.3.4 Alcohols and Phenols. The hydroxyl group is indicated by a suffix -ol when it is the
principal group attached to the parent compound and by the prefix hydroxy- when another group
with higher priority for citation is present or when the hydroxy group is present in a side chain.
When confusion may arise in employing the suffix -ol, the hydroxy group is indicated as a prefix;
this terminology is also used when the hydroxyl group is attached to a heterocycle, as, for example,
in the name 3-hydroxythiophene to avoid confusion with thiophenol (C6H5SH). Designations such
as isopropanol, sec-butanol, and tert-butanol are incorrect because no hydrocarbon exists to which
the suffix can be added. Many trivial names are retained. These structures are shown in Table 1.10.
The radicals (RO9) are named by adding -oxy as a suffix to the name of the R radical, e.g.,
pentyloxy for CH3CH2CH2CH2CH2O 9. These contractions are exceptions: methoxy (CH3O 9),
ethoxy (C2H5O 9 ), propoxy (C3H7 O 9), butoxy (C4H9O 9), and phenoxy (C6H5O 9).
For unsubstituted radicals only, one may use isopropoxy [(CH3 )2CH9O 9 ], isobutoxy
[(CH3 )2CH2CH9O 9 ], sec-butoxy [CH3CH2CH(CH3 ) 9O 9], and tert-butoxy [(CH3 )3C9 O 9].
TABLE 1.10 Retained Trivial Names of Alcohols and Phenols with Structures
Ally alcohol
tert-Butyl alcohol
Benzyl alcohol
Phenethyl alcohol
Ethylene glycol
1,2-Propylene glycol
Glycerol
Pentaerythritol
Pinacol
Phenol
CH2 " CHCH2OH
(CH3)3COH
C6H5CH2OH
C6H5CH2CH2OH
HOCH2CH2OH
CH3CHOHCH2OH
HOCH2CHOHCH2OH
C(CH2OH)4
(CH3)2COHCOH(CH3)2
C6H5OH
OH
Xylitol
HOCH2CH 9 CH 9 CH 9 CH2OH
Geraniol
(CH3)2C " CHCH2CH2C " CHCH2OH
OH
OH
CH3
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TABLE 1.10 Retained Trivial Names of Alcohols and Phenols with Structures (Continued)
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Bivalent radicals of the form O9Y 9O are named by adding -dioxy to the name of the bivalent
radicals except when forming part of a ring system. Examples are 9 O 9CH2 9 O 9 (methylenedioxy), 9 O 9 CO9 O 9 (carbonyldioxy), and 9O 9 SO2 9O 9 (sulfonyldioxy). Anions derived
from alcohols or phenols are named by changing the final -ol to -olate.
Salts composed of an anion, RO9 , and a cation, usually a metal, can be named by citing first
the cation and then the RO anion (with its ending changed to -yl oxide), e.g., sodium benzyl oxide
for C6H5CH2ONa. However, when the radical has an abbreviated name, such as methoxy, the ending
-oxy is changed to -oxide. For example, CH3ONa is named sodium methoxide (not sodium methylate).
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1.1.3.5 Aldehydes. When the group 9 C( "O)H, usually written 9 CHO, is attached to carbon
at one (or both) end(s) of a linear acyclic chain the name is formed by adding the suffix -al (or
-dial) to the name of the hydrocarbon containing the same number of carbon atoms. Examples are
butanal for CH3CH2CH2CHO and propanedial for, OHCCH2CHO.
Naming an acyclic polyaldehyde can be handled in two ways. First, when more than two aldehyde
groups are attached to an unbranched chain, the proper affix is added to -carbaldehyde, which
becomes the suffix to the name of the longest chain carrying the maximum number of aldehyde
groups. The name and numbering of the main chain do not include the carbon atoms of the aldehyde
groups. Second, the name is formed by adding the prefix formyl- to the name of the -dial that
incorporates the principal chain. Any other chains carrying aldehyde groups are named by the use
of formylalkyl- prefixes. Examples are
(1) 1,2,5-Pentanetricarbaldehyde
(2) 3-Formylheptanedial
(1) 4-(2-Formylethyl)-3-(formylmethyl)-1,2,7-heptanetricarbaldehyde
(2) 3-Formyl-5-(2-formylethyl)-4-(formylmethyl)nonanedial
When the aldehyde group is directly attached to a carbon atom of a ring system, the suffix
-carbaldehyde is added to the name of the ring system, e.g., 2-naphthalenecarbaldehyde. When the
aldehyde group is separated from the ring by a chain of carbon atoms, the compound is named
(1) as a derivative of the acyclic system or (2) by conjunctive nomenclature, for example,
(1) (2-naphthyl)propionaldehyde or (2) 2-naphthalenepropionaldehyde.
An aldehyde group is denoted by the prefix formyl- when it is attached to a nitrogen atom in a
ring system or when a group having priority for citation as principal group is present and part of a
cyclic system.
When the corresponding monobasic acid has a trivial name, the name of the aldehyde may be
formed by changing the ending -ic acid or -oic acid to -aldehyde. Examples are
Formaldehyde
Acrylaldehyde (not acrolein)
Acetaldehyde
Benzaldehyde
Propionaldehyde
Cinnamaldehyde
Butyraldehyde
2-Furaldehyde (not furfural)
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The same is true for polybasic acids, with the proviso that all the carboxyl groups must be changed
to aldehyde; then it is not necessary to introduce affixes. Examples are
Glyceraldehyde
Succinaldehyde
Glycolaldehyde
Phthalaldehyde (o-, m-, p-)
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Malonaldehyde
These trivial names may be retained: citral (3,7-dimethyl-2,6-octadienal), vanillin (4-hydroxy-3methoxybenzaldehyde), and piperonal (3,4-methylenedioxybenzaldehyde).
1.1.3.6 Amides. For primary amides the suffix -amide is added to the systematic
name of the parent acid. For example, CH3 9CO9NH2 is acetamide. Oxamide is retained for
H2N 9CO9 CO9NH2 . The name -carboxylic acid is replaced by -carboxamide.
For amino acids having trivial names ending in -ine, the suffix -amide is added after the name
of the acid (with elision of e for monoamides). For example, H2N 9CH2 9CO9NH2 is glycinamide.
In naming the radical R9 CO9 NH 9, either (1) the -yl ending of RCO 9 is changed to -amido
or (2) the radicals are named as acylamino radicals. For example,
(1) 4-Acetamidobenzoic acid
(2) 4-Acetylaminobenzoic acid
The latter nomenclature is always used for amino acids with trivial names.
N-substituted primary amides are named either (1) by citing the substituents as N prefixes or (2)
by naming the acyl group as an N substituent of the parent compound. For example,
(1) N-Methylbenzamide
(2) Benzoylaminomethane
1.1.3.7 Amines. Amines are preferably named by adding the suffix -amine (and any multiplying
affix) to the name of the parent radical. Examples are
CH3CH2CH2CH2CH2NH2
H2NCH2CH2CH2CH2CH2NH2
Pentylamine
1,5-Pentyldiamine or pentamethylenediamine
Locants of substituents of symmetrically substituted derivatives of symmetrical amines are distinguished by primes or else the names of the complete substituted radicals are enclosed in parentheses. Unsymmetrically substituted derivatives are named similarly or as N-substituted products of
a primary amine (after choosing the most senior of the radicals to be the parent amine). For example,
(1) 1,3⬘-Difluorodipropylamine
(2) 1-Fluoro-N-(3-fluoropropyl)propylamine
(3) (1-Fluoropropyl)(3-fluoropropyl)amine
Complex cyclic compounds may be named by adding the suffix -amine or the prefix amino- (or
aminoalkyl-) to the name of the parent compound. Thus three names are permissible for
(1) 4-Pyridylamine
(2) 4-Pyridinamine
(3) 4-Aminopyridine
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Complex linear polyamines are best designated by replacement nomenclature. These trivial names
are retained: aniline, benzidene, phenetidine, toluidine, and xylidine.
The bivalent radical 9NH 9 linked to two identical radicals can be denoted by the prefix
imino-, as well as when it forms a bridge between two carbon ring atoms. A trivalent nitrogen atom
linked to three identical radicals is denoted by the prefix nitrilo-. Thus ethylenediaminetetraacetic
acid (an allowed exception) should be named ethylenedinitrilotetraacetic acid.
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1.1.3.8 Ammonium Compounds. Salts and hydroxides containing quadricovalent nitrogen are
named as a substituted ammonium salt or hydroxide. The names of the substituting radicals precede
the word ammonium, and then the name of the anion is added as a separate word. For example,
(CH3 )4N⫹I⫺ is tetramethylammonium iodide.
When the compound can be considered as derived from a base whose name does not end in
-amine, its quaternary nature is denoted by adding ium to the name of that base (with elision of e),
substituent groups are cited as prefixes, and the name of the anion is added separately at the end.
Examples are
C6H5NH⫹3 HSO4⫺
⫹
Anilinium hydrogen sulfate
2⫺
6
[(C6H5NH3 ) ]2 PtCl
Dianilinium hexachloroplatinate
The names choline and betaine are retained for unsubstituted compounds.
In complex cases, the prefixes amino- and imino- may be changed to ammonio- and iminio- and
are followed by the name of the molecule representing the most complex group attached to this
nitrogen atom and are preceded by the names of the other radicals attached to this nitrogen. Finally
the name of the anion is added separately. For example, the name might be 1-trimethylammonioacridine chloride or 1-acridinyltrimethylammonium chloride.
When the preceding rules lead to inconvenient names, then (1) the unaltered name of the base
may be used followed by the name of the anion or (2) for salts of hydrohalogen acids only the
unaltered name of the base is used followed by the name of the hydrohalide. An example of the
latter would be 2-ethyl-p-phenylenediamine monohydrochloride.
1.1.3.9 Azo Compounds. When the azo group (9N " N 9) connects radicals derived from
identical unsubstituted molecules, the name is formed by adding the prefix azo- to the name of the
parent unsubstituted molecules. Substituents are denoted by prefixes and suffixes. The azo group
has priority for lowest-numbered locant. Examples are azobenzene for C6H5 9N "N 9C6H5 , azobenzene-4-sulfonic acid for C6H5 9N "N 9 C6H5SO3H, and 2⬘,4-dichloroazobenzene-4⬘-sulfonic
acid for ClC6H4 9 N " N 9C6H3ClSO3H.
When the parent molecules connected by the azo group are different, azo is placed between the
complete names of the parent molecules, substituted or unsubstituted. Locants are placed between
the affix azo and the names of the molecules to which each refers. Preference is given to the more
complex parent molecule for citation as the first component, e.g., 2-aminonaphthalene-1-azo(4⬘-chloro-2⬘-methylbenzene).
In an alternative method, the senior component is regarded as substituted by RN" N 9, this
group R being named as a radical. Thus 2-(7-phenylazo-2-naphthylazo)anthracene is the name by
this alternative method for the compound named anthracene-2-azo-2⬘-naphthalene-7⬘-azobenzene.
1.1.3.10 Azoxy Compounds. Where the position of the azoxy oxygen atom is unknown or immaterial, the compound is named in accordance with azo rules, with the affix azo replaced by azoxy.
When the position of the azoxy oxygen atom in an unsymmetrical compound is designated, a prefix
NNO- or ONN- is used. When both the groups attached to the azoxy radical are cited in the name
of the compound, the prefix NNO- specifies that the second of these two groups is attached directly
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to 9N(O)9 ; the prefix ONN- specifies that the first of these two groups is attached directly to
9N(O)9. When only one parent compound is cited in the name, the prefixed ONN- and NNOspecify that the group carrying the primed and unprimed substituents is connected, respectively, to
the 9 N(O) 9 group. The prefix NON- signifies that the position of the oxygen atom is unknown;
the azoxy group is then written as 9N2O 9. For example,
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2,2⬘,4-Trichloro-NNO-azoxybenzene
1.1.3.11 Boron Compounds. Molecular hydrides of boron are called boranes. They are named
by using a multiplying affix to designate the number of boron atoms and adding an Arabic numeral
within parentheses as a suffix to denote the number of hydrogen atoms present. Examples are pentaborane(9) for B5H9 and pentaborane(11) for B5H11 .
Organic ring systems are named by replacement nomenclature. Three- to ten-membered monocyclic ring systems containing uncharged boron atoms may be named by the specialist nomenclature
for heterocyclic systems. Organic derivatives are named as outlined for substitutive nomenclature.
The complexity of boron nomenclature precludes additional details; the text by Rigaudy and Klesney
should be consulted.
1.1.3.12 Carboxylic Acids. Carboxylic acids may be named in several ways. First, 9COOH
groups replacing CH3 9 at the end of the main chain of an acyclic hydrocarbon are denoted by
adding -oic acid to the name of the hydrocarbon. Second, when the 9COOH group is the principal
group, the suffix -carboxylic acid can be added to the name of the parent chain whose name and
chain numbering does not include the carbon atom of the 9COOH group. The former nomenclature
is preferred unless use of the ending -carboxylic acid leads to citation of a larger number of carboxyl
groups as suffix. Third, carboxyl groups are designated by the prefix carboxy- when attached to a
group named as a substituent or when another group is present that has higher priority for citation
as principal group. In all cases, the principal chain should be linked to as many carboxyl groups as
possible even though it might not be the longest chain present. Examples are
CH3CH2CH2CH2CH2CH2 COOH
(1) Heptanoic acid
(2) 1-Hexanecarboxylic acid
C6H11COOH
(2) Cyclohexanecarboxylic acid
(3) 2-(Carboxymethyl)-1,4-hexanedicarboxylic acid
Removal of the OH from the 9 COOH group to form the acyl radical results in changing the
ending -oic acid to -oyl or the ending -carboxylic acid to -carbonyl. Thus the radical
CH3CH2CH2CH2CO9 is named either pentanoyl or butanecarbonyl. When the hydroxyl has not
been removed from all carboxyl groups present in an acid, the remaining carboxyl groups are denoted
by the prefix carboxy-. For example, HOOCCH2CH2CH2CH2CH2CO9 is named 6-carboxyhexanoyl.
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TABLE 1.11 Names of Some Carboxylic Acids
Systematic name
Trivial name
Methanoic
Ethanoic
Propanoic
Butanoic
2-Methylpropanoic
Pentanoic
3-Methylbutanoic
2,2-Dimethylpropanoic
Hexanoic
Heptanoic
Octanoic
Decanoic
Dodecanoic
Tetradecanoic
Hexadecanoic
Octadecanoic
Formic
Acetic
Propionic
Butyric
Isobutyric*
Valeric
Isovaleric*
Pivalic*
(Caproic)
(Enanthic)
(Caprylic)
(Capric)
Lauric*
Myristic*
Palmitic*
Stearic*
Ethanedioic
Propanedioic
Butanedioic
Pentanedioic
Hexanedioic
Heptanedioic
Octanedioic
Nonanedioic
Decanedioic
Propenoic
Propynoic
2-Methylpropenoic
trans-2-Butenoic
cis-2-Butenoic
cis-9-Octadecenoic
trans-9-Octadecenoic
cis-Butenedioic
trans-Butenedioic
cis-Methylbutenedioic
Oxalic
Malonic
Succinic
Glutaric
Adipic
Pimelic*
Suberic*
Azelaic*
Sebacic*
Acrylic
Propiolic
Methacrylic
Crotonic
Isocrotonic
Oleic
Elaidic
Maleic
Fumaric
Citraconic*
Systematic name
Trivial name
trans-Methylbutenedioic
Mesaconic*
1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid
Camphoric
Benzenecarboxylic
1,2-Benzenedicarboxylic
1,3-Benzenedicarboxylic
1,4-Benzenedicarboxylic
Naphthalenecarboxylic
Methylbenzenecarboxylic
2-Phenylpropanoic
2-Phenylpropenoic
trans-3-Phenylpropenoic
Furancarboxylic
Thiophenecarboxylic
3-Pyridinecarboxylic
4-Pyridinecarboxylic
Benzoic
Phthalic
Isophthalic
Terephthalic
Naphthoic
Toluic
Hydratropic
Atropic
Cinnamic
Furoic
Thenoic
Nicotinic
Isonicotinic
Hydroxyethanoic
2-Hydroxypropanoic
2,3-Dihydroxypropanoic
Hydroxypropanedioic
Hydroxybutanedioic
2,3-Dihydroxybutanedioic
3-Hydroxy-2-phenylpropanoic
2-Hydroxy-2,2-diphenylethanoic
2-Hydroxybenzoic
Methoxybenzoic
4-Hydroxy-3-methoxybenzoic
Glycolic
Lactic
Glyceric
Tartronic
Malic
Tartaric
Tropic
Benzilic
Salicylic
Anisic
Vanillic
3,4-Dimethoxybenzoic
3,4-Methylenedioxybenzoic
3,4-Dihydroxybenzoic
3,4,5-Trihydroxybenzoic
Veratric
Piperonylic
Protocatechuic
Gallic
* Systematic names should be used in derivatives formed by substitution on a carbon atom.
Note: The names in parentheses are abandoned but are listed for reference to older literature.
Many trivial names exist for acids; these are listed in Table 1.11. Generally, radicals are formed
by replacing -ic acid by -oyl.* When a trivial name is given to an acyclic monoacid or diacid, the
numeral 1 is always given as locant to the carbon atom of a carboxyl group in the acid or to the
carbon atom with a free valence in the radical RCO9.
* Exceptions: formyl, acetyl, propionyl, butyryl, isobutyryl, valeryl, isovaleryl, oxalyl, malonyl, succinyl, glutaryl, furoyl,
and thenoyl.
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1.1.3.13 Ethers (R1 9 O 9R2). In substitutive nomenclature, one of the possible radicals,
R9O 9, is stated as the prefix to the parent compound that is senior from among R1 or R2. Examples
are methoxyethane for CH3OCH2CH3 and butoxyethanol for C4H9OCH2CH2OH.
When another principal group has precedence and oxygen is linking two identical parent compounds, the prefix oxy- may be used, as with 2,2⬘-oxydiethanol for HOCH2CH2OCH2CH2OH.
Compounds of the type RO9 Y9 OR, where the two parent compounds are identical and contain
a group having priority over ethers for citation as suffix, are named as assemblies of identical
units. For example, HOOC9CH2 9 O 9CH2CH2 9O 9CH2 9COOH is named 2,2⬘-(ethylenedioxy)diacetic acid.
Linear polyethers derived from three or more molecules of aliphatic dihydroxy compounds,
particularly when the chain length exceeds ten units, are most conveniently named by open-chain
replacement nomenclature. For example, CH3CH2 9 O 9 CH2CH2 9O 9CH2CH3 could be 3,6dioxaoctane or (2-ethoxy)ethoxyethane.
An oxygen atom directly attached to two carbon atoms already forming part of a ring
system or to two carbon atoms of a chain may be indicated by the prefix epoxy-. For example,
CH2 9 CH 9 CH2Cl is named 1-chloro-2,3-epoxypropane.
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O
Symmetrical linear polyethers may be named (1) in terms of the central oxygen atom when there
is an odd number of ether oxygen atoms or (2) in terms of the central hydrocarbon group when there
is an even number of ether oxygen atoms. For example, C2H5 9 O 9 C4H8 9O 9C4H8 9O 9C2H5
is bis-(4-ethoxybutyl)ether, and 3,6-dioxaoctane (earlier example) could be named 1,2bis(ethoxy)ethane.
Partial ethers of polyhydroxy compounds may be named (1) by substitutive nomenclature or (2)
by stating the name of the polyhydroxy compound followed by the name of the etherifying radical(s)
followed by the word ether. For example,
(1) 3-Butoxy-1,2-propanediol
(2) Glycerol 1-butyl ether; also, 1-O-butylglycerol
Cyclic ethers are named either as heterocyclic compounds or by specialist rules of heterocyclic
nomenclature. Radicofunctional names are formed by citing the names of the radicals R1 and R2
followed by the word ether. Thus methoxyethane becomes ethyl methyl ether and ethoxyethane
becomes diethyl ether.
1.1.3.14 Halogen Derivatives. Using substitutive nomenclature, names are formed by adding
prefixes listed in Table 1.8 to the name of the parent compound. The prefix perhalo- implies the
replacement of all hydrogen atoms by the particular halogen atoms.
Cations of the type R1R2X⫹ are given names derived from the halonium ion, H2X⫹, by substitution, e.g., diethyliodonium chloride for (C2H5 )2I⫹Cl⫺.
Retained are these trivial names; bromoform (CHBr3 ), chloroform (CHCl3 ), fluoroform (CHF3 ),
iodoform (CHI3 ), phosgene (COCl2 ), thiophosgene (CSCl2 ), and dichlorocarbene radical ( CCl2).
Inorganic nomenclature leads to such names as carbonyl and thiocarbonyl halides (COX2 and CSX2 )
and carbon tetrahalides (CX4 ).
1.1.3.15 Hydroxylamines and Oximes. For RNH 9OH compounds, prefix the name of the radical R to hydroxylamine. If another substituent has priority as principal group, attach the prefix
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hydroxyamino- to the parent name. For example, C6H5NHOH would be named N-phenylhydroxylamine, but HOC6H4NHOH would be (hydroxyamino)phenol, with the point of attachment indicated by a locant preceding the parentheses.
Compounds of the type R1NH9OR2 are named (1) as alkoxyamino derivatives of compound
1
R H, (2) as N,O-substituted hydroxylamines, (3) as alkoxyamines (even if R1 is hydrogen), or
(4) by the prefix aminooxy- when another substituent has priority for parent name. Examples of
each type are
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1. 2-(Methoxyamino)-8-naphthalenecarboxylic acid for CH3ONH9C10H6COOH
2. O-Phenylhydroxylamine for H2N 9O 9 C6H5 or N-phenylhydroxylamine for C6H5NH 9OH
3. Phenoxyamine for H2N 9 O 9C6H5 (not preferred to O-phenylhydroxylamine)
4. Ethyl (aminooxy)acetate for H2N 9 O 9CH2CO9 OC2H5
Acyl derivatives, RCO9NH 9 OH and H2N 9O 9CO9 R, are named as N-hydroxy derivatives of amides and as O-acylhydroxylamines, respectively. The former may also be named as
hydroxamic acids. Examples are N-hydroxyacetamide for CH3CO9NH9OH and O-acetylhydroxylamine for H2N 9 O 9 CO9 CH3 . Further substituents are denoted by prefixes with O- and/or Nlocants. For example, C6H5NH 9 O 9C2H5 would be O-ethyl-N-phenylhydroxylamine or N-ethoxylaniline.
For oximes, the word oxime is placed after the name of the aldehyde or ketone. If the carbonyl
group is not the principal group, use the prefix hydroxyimino-. Compounds with the group N 9 OR
are named by a prefix alkyloxyimino- as oxime O-ethers or as O-substituted oximes. Compounds
with the group C " N(O)R are named by adding N-oxide after the name of the alkylideneaminc
compound. For amine oxides, add the word oxide after the name of the base, with locants. For
example, C5H5N 9 O is named pyridine N-oxide or pyridine 1-oxide.
1.1.3.16 Imines. The group ⬎C"NH is named either by the suffix -imine or by citing the
name of the bivalent radical R1R2C⬍ as a prefix to amine. For example, CH3CH2CH2CH"NH
could be named 1-butanimine or butylideneamine. When the nitrogen is substituted, as in
CH2 "N9CH2CH3 , the name is N-(methylidene)ethylamine.
Quinones are exceptions. When one or more atoms of quinonoid oxygen have been replaced by
⬎NH or ⬎NR, they are named by using the name of the quinone followed by the word imine (and
preceded by proper affixes). Substituents on the nitrogen atom are named as prefixes. Examples are
p-Benzoquinone monoimine
p-Benzoquinone diimine
1.1.3.17 Ketenes. Derivatives of the compound ketene, CH2 "C"O, are named by substitutive
nomenclature. For example, C4H9CH"C"O is butyl ketene. An acyl derivative, such as
CH3CH2 9 CO9 CH2CH" C" O, may be named as a polyketone, 1-hexene-1,4-dione. Bisketene
is used for two to avoid ambiguity with diketene (dimeric ketene).
1.1.3.18 Ketones. Acyclic ketones are named (1) by adding the suffix -one to the name of the
hydrocarbon forming the principal chain or (2) by citing the names of the radicals R1 and R2 followed
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by the word ketone. In addition to the preceding nomenclature, acyclic monoacyl derivatives of
cyclic compounds may be named (3) by prefixing the name of the acyl group to the name of the
cyclic compound. For example, the three possible names of
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(1) 1-(2-Furyl)-1-propanone
(2) Ethyl 2-furyl ketone
(3) 2-Propionylfuran
When the cyclic component is benzene or naphthalene, the -ic acid or -oic acid of the acid
corresponding to the acyl group is changed to -ophenone or -onaphthone, respectively. For example,
C6H5 9CO9CH2CH2CH3 can be named either butyrophenone (or butanophenone) or phenyl propyl
ketone.
Radicofunctional nomenclature can be used when a carbonyl group is attached directly to carbon
atoms in two ring systems and no other substituent is present having priority for citation.
When the methylene group in polycarbocyclic and heterocyclic ketones is replaced by a keto
group, the change may be denoted by attaching the suffix -one to the name of the ring system.
However, when ⱖCH in an unsaturated or aromatic system is replaced by a keto group, two alternative names become possible. First, the maximum number of noncumulative double bonds is added
after introduction of the carbonyl group(s), and any hydrogen that remains to be added is denoted
as indicated hydrogen with the carbonyl group having priority over the indicated hydrogen for lowernumbered locant. Second, the prefix oxo- is used, with the hydrogenation indicated by hydro prefixes;
hydrogenation is considered to have occurred before the introduction of the carbonyl group. For
example,
(1) 1-(2H)-Naphthalenone
(2) 1-Oxo-1,2-dihydronaphthalene
When another group having higher priority for citation as principal group is also present, the
ketonic oxygen may be expressed by the prefix oxo-, or one can use the name of the carbonylcontaining radical, as, for example, acyl radicals and oxo-substituted radicals. Examples are
4-(4⬘-Oxohexyl)-1-benzoic acid
1,2,4-Triacetylbenzene
Diketones and tetraketones derived from aromatic compounds by conversion of two or four
CH groups into keto groups, with any necessary rearrangement of double bonds to a quinonoid
structure, are named by adding the suffix -quinone and any necessary affixes.
Polyketones in which two or more contiguous carbonyl groups have rings attached at each end
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may be named (1) by the radicofunctional method or (2) by substitutive nomenclature. For example,
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(1) 2-Naphthyl 2-pyridyl diketone
(2) 1-(2-Naphthyl)-2-(2-pyridyl)ethanedione
Some trivial names are retained: acetone (2-propanone), biacetyl (2,3-butanedione), propiophenone (C6H5 9CO9 CH2CH3 ), chalcone (C6H5 9 CH"CH9CO 9C6H5 ), and deoxybenzoin
(C6H5 9 CH2 9CO 9 C6H5 ).
These contracted names of heterocyclic nitrogen compounds are retained as alternatives for systematic names, sometimes with indicated hydrogen. In addition, names of oxo derivatives of fully
saturated nitrogen heterocycles that systematically end in -idinone are often contracted to end in
-idone when no ambiguity might result. For example,
2-Pyridone
2(1H)-Pyridone
4-Pyridone
4(1H)-Pyridone
1-Isoquinolone
1(2H)-Isoquinolone
5-Pyrazolone
5(4H)-Pyrazolone
2-Quinolone
2(1H)-Quinolone
4-Oxazolone
4(5H)-Oxazolone
4-Isoxazoline
4(5H)-Isoxazolone
4-Quinolone
4(1H)-Quinolone
4-Pyrazolone
4(5H)-Pyrazolone
4-Thiazolone
4(5H)-Thiazolone
9-Acridone
9(10H)-Acridone
1.1.3.19 Lactones, Lactides, Lactams, and Lactims. When the hydroxy acid from which water
may be considered to have been eliminated has a trivial name, the lactone is designated by substituting -olactone for -ic acid. Locants for a carbonyl group are numbered as low as possible, even
before that of a hydroxyl group.
Lactones formed from aliphatic acids are named by adding -olide to the name of the nonhydroxylated hydrocarbon with the same number of carbon atoms. The suffix -olide signifies the change
of CH CH3 into C C " O.
O
Structures in which one or more (but not all) rings of an aggregate are lactone rings are named
by placing -carbolactone (denoting the 9O 9CO9 bridge) after the names of the structures that
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remain when each bridge is replaced by two hydrogen atoms. The locant for 9 CO9 is cited before
that for the ester oxygen atom. An additional carbon atom is incorporated into this structure as
compared to the -olide.
These trivial names are permitted: ␥-butyrolactone, ␥-valerolactone, and ␦-valerolactone. Names
based on heterocycles may be used for all lactones. Thus, ␥-butyrolactone is also tetrahydro-2furanone or dihydro-2(3H)-furanone.
Lactides, intermolecular cyclic esters, are named as heterocycles. Lactams and lactims, containing
a 9 CO9 NH 9 and 9 C(OH) " N 9 group, respectively, are named as heterocycles, but they may
also be named with -lactam or -lactim in place of -olide. For example,
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(1) 2-Pyrrolidinone
(2) 4-Butanelactam
1.1.3.20 Nitriles and Related Compounds. For acids whose systematic names end in -carboxylic
acid, nitriles are named by adding the suffix -carbonitrile when the 9CN group replaces the
9 COOH group. The carbon atom of the 9CN group is excluded from the numbering of a chain
to which it is attached. However, when the triple-bonded nitrogen atom is considered to replace
three hydrogen atoms at the end of the main chain of an acyclic hydrocarbon, the suffix -nitrile is
added to the name of the hydrocarbon. Numbering begins with the carbon attached to the nitrogen.
For example, CH3CH2CH2CH2CH2CN is named (1) pentanecarbonitrile or (2) hexanenitrile.
Trivial acid names are formed by changing the endings -oic acid or -ic acid to -onitrile. For
example, CH3CN is acetonitrile. When the 9 CN group is not the highest priority group, the 9 CN
group is denoted by the prefix cyano-.
In order of decreasing priority for citation of a functional class name, and the prefix for substitutive nomenclature, are the following related compounds:
Functional group
Prefix
Radicofunctional ending
9 NC
9 OCN
9 NCO
9 ONC
9 SCN
9 NCS
9 SeCN
9 NCSe
IsocyanoCyanatoIsocyanato—
ThiocyanatoIsothiocyanatoSelenocyanatoIsoselenocyanato-
Isocyanide
Cyanate
Isocyanate
Fulminate
Thiocyanate
Isothiocyanate
Selenocyanate
Isoselenocyanate
1.1.3.21 Peroxides. Compounds of the type R9 O 9OH are named (1) by placing the name of
the radical R before the word hydroperoxide or (2) by use of the prefix hydroperoxy- when another
parent name has higher priority. For example, C2H5OOH is ethyl hydroperoxide.
Compounds of the type R1O 9 OR2 are named (1) by placing the names of the radicals in alphabetical order before the word peroxide when the group 9O 9 O 9 links two chains, two rings,
or a ring and a chain, (2) by use of the affix dioxy to denote the bivalent group 9 O 9O9 for
naming assemblies of identical units or to form part of a prefix, or (3) by use of the prefix epidioxywhen the peroxide group forms a bridge between two carbon atoms, a ring, or a ring system.
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Examples are methyl propyl peroxide for CH3 9O 9O 9 C3H7 and 2,2⬘-dioxydiacetic acid for
HOOC9 CH2 9O 9O 9 CH2 9 COOH.
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1.1.3.22 Phosphorus Compounds. Acyclic phosphorus compounds containing only one phosphorus atom, as well as compounds in which only a single phosphorus atom is in each of several
functional groups, are named as derivatives of the parent structures listed in Table 1.12. Often these
TABLE 1.12 Parent Structures of Phosphorus-Containing Compounds
Formula
Parent name
H3P
H5P
Phosphine
Phosphorane
H3PO
H3PS
H3PNH
P(OH)3
HP(OH)2
H2POH
P(O)(OH)3
HP(O)(OH)2
Phosphine oxide
Phosphine sulfide
Phosphine imide
Phosphorous acid
Phosphonous acid
Phosphinous acid
Phosphoric acid
Phosphonic acid
H2P(O)OH
Phosphinic acid
Substitutive prefix
H2P 9
H4P 9
H3P
H2P
PhosphinoPhosphoranylPhosphoroanediylPhosphoranetriyl-
PhosphorylP(O)
PhosphonoylHP(O)
9 P(O)OH2 PhosphonoH2P(O) 9 PhosphinoylP(O)OH PhosphinocoPhosphinato-
Radicofunctional
ending
Phosphide
Phosphite
Phosphonite
Phosphinite
Phosphate(V)
Phosphonate
Phosphinate
are purely hypothetical parent structures. When hydrogen attached to phosphorus is replaced by a
hydrocarbon group, the derivative is named by substitution nomenclature. When hydrogen of an
9OH group is replaced, the derivative is named by radicofunctional nomenclature. For example,
C2H5PH2 is ethylphosphine; (C2H5 )2PH, diethylphosphine; CH3P(OH)2 , dihydroxy-methyl-phosphine or methylphosphonous acid; C2H5 9 PO(Cl)(OH), ethylchlorophosphonic acid or ethylphosphonochloridic acid or hydrogen chlorodioxoethylphosphate(V); CH3CH(PH2 )COOH, 2-phosphinopropionic acid; HP(CH2COOH)2 , phosphinediyldiacetic acid; (CH3 )HP(O)OH, methylphosphinic
acid or hydrogen hydridomethyldioxophosphate(V); (CH3O)3PO, trimethyl phosphate; and
(CH3O)3P, trimethyl phosphite.
1.1.3.23 Salts and Esters of Acids. Neutral salts of acids are named by citing the cation(s) and
then the anion, whose ending is changed from -oic to -oate or from -ic to -ate. When different acidic
residues are present in one structure, prefixes are formed by changing the anion ending -ate to -atoor -ide to -ido-. The prefix carboxylato- denotes the ionic group 9COO⫺. The phrase (metal) salt
of (the acid) is permissible when the carboxyl groups are not all named as affixes.
Acid salts include the word hydrogen (with affixes, if appropriate) inserted between the name of
the cation and the name of the anion (or word salt).
Esters are named similarly, with the name of the alkyl or aryl radical replacing the name of the
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cation. Acid esters of acids and their salts are named as neutral esters, but the components are cited
in the order: cation, alkyl or aryl radical, hydrogen, and anion. Locants are added if necessary. For
example,
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Potassium 1-ethyl hydrogen citrate
Ester groups in R1 9CO9OR2 compounds are named (1) by the prefix alkoxycarbonyl- or
aryloxycarbonyl- for 9 CO9OR2 when the radical R1 contains a substituent with priority for citation as principal group or (2) by the prefix acyloxy- for R1 9CO9O 9 when the radical R2
contains a substituent with priority for citation as principal group. Examples are
Methyl 3-methoxycarbonyl-2-naphthalenebutyrate
+
[CH3O9CO9CH2CH2N(CH3)3 ]Cl⫺
[(2-Methoxycarbonyl)ethyl]trimethylammonium chloride
C6H5 9 CO9 OCH2CH2COOH
3-Benzoyloxypropionic acid
The trivial name acetoxy is retained for the CH3 9CO9O 9 group. Compounds of the type
R2C(OR2)3 are named as R2 esters of the hypothetical ortho acids. For example, CH3C(OCH3 )3 is
trimethyl orthoacetate.
1.1.3.24 Silicon Compounds. SiH4 is called silane; its acyclic homologs are called disilane, trisilane, and so on, according to the number of silicon atoms present. The chain is numbered from
one end to the other so as to give the lowest-numbered locant in radicals to the free valence or to
substituents on a chain. The abbreviated form silyl is used for the radical SiH3 9. Numbering and
citation of side chains proceed according to the principles set forth for hydrocarbon chains. Cyclic
nonaromatic structures are designated by the prefix cyclo-.
When a chain or ring system is composed entirely of alternating silicon and oxygen atoms, the
parent name siloxane is used with a multiplying affix to denote the number of silicon atoms present.
The parent name silazane implies alternating silicon and nitrogen atoms; multiplying affixes denote
the number of silicon atoms present.
The prefix sila- designates replacement of carbon by silicon in replacement nomenclature. Prefix
names for radicals are formed analogously to those for the corresponding carbon-containing compounds. Thus silyl is used for SiH3 9, silyene for 9SiH2 9, silylidyne for 9SiH⬍, as well as
trily, tetrayl, and so on for free valences(s) on ring structures.
1.1.3.25 Sulfur Compounds
Bivalent Sulfur. The prefix thio, placed before an affix that denotes the oxygen-containing group
or an oxygen atom, implies the replacement of that oxygen by sulfur. Thus the suffix -thiol denotes
9SH, -thione denotes 9 (C) "S and implies the presence of an "S at a nonterminal carbon atom,
-thioic acid denotes [(C)"S]OH L [(C) " O]SH (that is, the O-substituted acid and the S-substi-
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tuted acid, respectively), -dithioc acid denotes [9 C(S)]SH, and -thial denotes 9(C)HS (or -carbothialdehyde denotes 9CHS). When -carboxylic acid has been used for acids, the sulfur analog
is named -carbothioic acid or -carbodithioic acid.
Prefixes for the groups HS9 and RS9 are mercapto- and alkylthio-, respectively; this latter
name may require parentheses for distinction from the use of thio- for replacement of oxygen in a
trivially named acid. Examples of this problem are 4-C2H5 9C6H4 9CSOH named pethyl(thio)benzoic acid and 4-C2H5 9S9 C6H4 9COOH named p-(ethylthio)benzoic acid. When
9 SH is not the principal group, the prefix mercapto- is placed before the name of the parent
compound to denote an unsubstituted 9SH group.
The prefix thioxo- is used for naming "S in a thioketone. Sulfur analogs of acetals are named
as alkylthio- or arylthio-. For example, CH3CH(SCH3 )OCH3 is 1-methoxy-1-(methylthio)ethane.
Prefix forms for -carbothioic acids are hydroxy(thiocarbonyl)- when referring to the O-substituted
acid and mercapto(carbonyl)- for the S-substituted acid.
Salts are formed as with oxygen-containing compounds. For example, C2H5 9S9 Na is named
either sodium ethanethiolate or sodium ethyl sulfide. If mercapto- has been used as a prefix, the salt
is named by use of the prefix sulfido- for 9S⫺.
Compounds of the type R1 9S9R2 are named alkylthio- (or arylthio-) as a prefix to the name
of R1 or R2, whichever is the senior.
Sulfonium Compounds. Sulfonium compounds of the type R1R2R3S⫹X⫺ are named by citing in
alphabetical order the radical names followed by -sulfonium and the name of the anion. For heterocyclic compounds, -ium is added to the name of the ring system. Replacement of ⬎CH by sulfonium
sulfur is denoted by the prefix thionia-, and the name of the anion is added at the end.
Organosulfur Halides. When sulfur is directly linked only to an organic radical and to a halogen
atom, the radical name is attached to the word sulfur and the name(s) and number of the halide(s)
are stated as a separate word. Alternatively, the name can be formed from R9SOH, a sulfenic acid
whose radical prefix is sulfenyl-. For example, CH3CH2 9 S9Br would be named either ethylsulfur
monobromide or ethanesulfenyl bromide. When another principal group is present, a composite
prefix is formed from the number and substitutive name(s) of the halogen atoms in front of the
syllable thio. For example, BrS9COOH is (bromothio)formic acid.
Sulfoxides. Sulfoxides, R1 9SO9 R2, are named by placing the names of the radicals in alphabetical order before the word sulfoxide. Alternatively, the less senior radical is
named followed by sulfinyl- and concluded by the name of the senior group. For example,
CH3CH2 9 SO9CH2CH2CH3 is named either ethyl propyl sulfoxide or 1-(ethylsulfinyl)propane.
When an ⬎SO group is incorporated in a ring, the compound is named an oxide.
Sulfones. Sulfones, R1 9SO2 9R2, are named in an analogous manner to sulfoxides, using the
word sulfone in place of sulfoxide. In prefixes, the less senior radical is followed by -sulfonyl-. When
the ⬎SO2 group is incorporated in a ring, the compound is named as a dioxide.
Sulfur Acids. Organic oxy acids of sulfur, that is, 9 SO3H, 9 SO2H, and 9SOH, are named
sulfonic acid, sulfinic acid, and sulfenic acid, respectively. In subordinate use, the respective prefixes
are sulfo-, sulfino, and sulfeno-. The grouping 9SO2 9 O 9 SO2 9 or 9SO9O 9 SO is named
sulfonic or sulfinic anhydride, respectively.
Inorganic nomenclature is employed in naming sulfur acids and their derivatives in which sulfur
is linked only through oxygen to the organic radical. For example, (C2H5O)2SO2 is diethyl sulfate
and C2H5O 9SO2 9 OH is ethyl hydrogen sulfate. Prefixes O- and S- are used where necessary to
denote attachment to oxygen and to sulfur, respectively, in sulfur replacement compounds. For
example, CH3 9S9SO2 9ONa is sodium S-methyl thiosulfate.
When sulfur is linked only through nitrogen, or through nitrogen and oxygen, to the organic
radical, naming is as follows: (1) N-substituted amides are designated as N-substituted derivatives
of the sulfur amides and (2) compounds of the type R9NH 9SO3H may be named as N-substituted
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sulfamic acids or by the prefix sulfoamino- to denote the group HO3S9NH 9. The groups
9N"SO and 9 N "SO2 are named sulfinylamines and sulfonylamines, respectively.
Sultones and Sultams. Compounds containing the group 9SO2 9 O 9 as part of the ring are
called -sultone. The 9 SO2 9 group has priority over the 9O 9 group for lowest-numbered locant.
Similarly, the 9 SO2 9 N " group as part of a ring is named by adding -sultam to the name of
the hydrocarbon with the same number of carbon atoms. The 9SO2 9 has priority over 9N " for
lowest-numbered locant.
1.1.4
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Stereochemistry
Concepts in stereochemistry, that is, chemistry in three-dimensional space, are in the process of
rapid expansion. This section will deal with only the main principles. The compounds discussed will
be those that have identical molecular formulas but differ in the arrangement of their atoms in space.
Stereoisomers is the name applied to these compounds.
Stereoisomers can be grouped into three categories: (1) Conformational isomers differ from each
other only in the way their atoms are oriented in space, but can be converted into one another by
rotation about sigma bonds. (2) Geometric isomers are compounds in which rotation about a double
bond is restricted. (3) Configurational isomers differ from one another only in configuration about
a chiral center, axis, or plane. In subsequent structural representations, a broken line denotes a bond
projecting behind the plane of the paper and a wedge denotes a bond projecting in front of the plane
of the paper. A line of normal thickness denotes a bond lying essentially in the plane of the paper.
1.1.4.1 Conformational Isomers. A molecule in a conformation into which its atoms return
spontaneously after small displacements is termed a conformer. Different arrangements of atoms
that can be converted into one another by rotation about single bonds are called conformational
isomers (see Fig. 1.1). A pair of conformational isomers can be but do not have to be mirror images
of each other. When they are not mirror images, they are called diastereomers.
FIGURE 1.1 Conformations of ethane.
(a) Eclipsed; (b) staggered.
Acyclic Compounds. Different conformations of acyclic compounds are best viewed by construction of ball-and-stick molecules or by use of Newman projections (see Fig. 1.2). Both types of
representations are shown for ethane. Atoms or groups that are attached at opposite ends of a single
bond should be viewed along the bond axis. If two atoms or groups attached at opposite ends of the
bond appear one directly behind the other, these atoms or groups are described as eclipsed. That
portion of the molecule is described as being in the eclipsed conformation. If not eclipsed, the atoms
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FIGURE 1.2 Newman projections for
ethane. (a) Staggered; (b) eclipsed.
or groups and the conformation may be described as staggered. Newman projections show these
conformations clearly.
Certain physical properties show that rotation about the single bond is not quite free. For ethane
there is an energy barrier of about 3 kcal · mol⫺1 (12 kJ · mol⫺1 ). The potential energy of the molecule
is at a minimum for the staggered conformation, increases with rotation, and reaches a maximum at
the eclipsed conformation. The energy required to rotate the atoms or groups about the carboncarbon bond is called torsional energy. Torsional strain is the cause of the relative instability of the
eclipsed conformation or any intermediate skew conformations.
In butane, with a methyl group replacing one hydrogen on each carbon of ethane, there are several
different staggered conformations (see Fig. 1.3). There is the anti-conformation in which the methyl
groups are as far apart as they can be (dihedral angle of 180⬚). There are two gauche conformations
in which the methyl groups are only 60⬚ apart; these are two nonsuperimposable mirror images of
each other. The anti-conformation is more stable than the gauche by about 0.9 kcal · mol⫺1
(4 kJ · mol⫺1 ). Both are free of torsional strain. However, in a gauche conformation the methyl
groups are closer together than the sum of their van der Waals’ radii. Under these conditions van
der Waals’ forces are repulsive and raise the energy of conformation. This strain can affect not only
the relative stabilities of various staggered conformations but also the heights of the energy barriers
FIGURE 1.3 Conformations of butane. (a) Anti-staggered; (b) eclipsed; (c) gauche-staggered; (d)
eclipsed; (e) gauche-staggered; ( f ) eclipsed. (Eclipsed conformations are slightly staggered for convenience
in drawing; actually they are superimposed.)
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between them. The energy maximum (estimated at 4.8 to 6.1 kcal · mol⫺1 or 20 to 25 kJ · mol⫺1 ) is
reached when two methyl groups swing past each other (the eclipsed conformation) rather than past
hydrogen atoms.
Cyclic Compounds. Although cyclic aliphatic compounds are often drawn as if they were planar
geometric figures (a triangle for cyclopropane, a square for cyclobutane, and so on), their structures
are not that simple. Cyclopropane does possess the maximum angle strain if one considers the
difference between a tetrahedral angle (109.5⬚) and the 60⬚ angle of the cyclopropane structure.
Nevertheless the cyclopropane structure is thermally quite stable. The highest electron density of
the carbon-carbon bonds does not lie along the lines connecting the carbon atoms. Bonding electrons
lie principally outside the triangular internuclear lines and result in what is known as bent bonds
(see Fig. 1.4).
Cyclobutane has less angle strain than cyclopropane (only 19.5⬚). It is also believed to have some
bent-bond character associated with the carbon-carbon bonds. The molecule exists in a nonplanar
conformation in order to minimize hydrogen-hydrogen eclipsing strain.
Cyclopentane is nonplanar, with a structure that resembles an envelope (see Fig. 1.5). Four of
the carbon atoms are in one plane, and the fifth is out of that plane. The molecule is in continual
motion so that the out-of-plane carbon moves rapidly around the ring.
The 12 hydrogen atoms of cyclohexane do not occupy equivalent positions. In the chair conformation six hydrogen atoms are perpendicular to the average plane of the molecule and six are directed
outward from the ring, slightly above or below the molecular plane (see Fig. 1.6). Bonds which are
perpendicular to the molecular plane are known as axial bonds, and those which extend outward
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FIGURE 1.4 The bent bonds (“tear
drops”) of cyclopropane.
FIGURE 1.5 The conformations of cyclopentane.
FIGURE 1.6 The two chair conformations of cyclohexane; a ⫽ axial hydrogen atom and e ⫽ equatorial hydrogen atom.
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from the ring are known as equatorial bonds. The three axial bonds directed upward originate from
alternate carbon atoms and are parallel with each other; a similar situation exists for the three axial
bonds directed downward. Each equatorial bond is drawn so as to be parallel with the ring carboncarbon bond once removed from the point of attachment to that equatorial bond. At room temperature, cyclohexane is interconverting rapidly between two chair conformations. As one chair form
converts to the other, all the equatorial hydrogen atoms become axial and all the axial hydrogens
become equatorial. The interconversion is so rapid that all hydrogen atoms on cyclohexane can be
considered equivalent. Interconversion is believed to take place by movement of one side of the
chair structure to produce the twist boat, and then movement of the other side of the twist boat to
give the other chair form. The chair conformation is the most favored structure for cyclohexane. No
angle strain is encountered since all bond angles remain tetrahedral. Torsional strain is minimal
because all groups are staggered.
In the boat conformation of cyclohexane (Fig. 1.7) eclipsing torsional strain is significant, although no angle strain is encountered. Nonbonded interaction between the two hydrogen atoms
across the ring from each other (the “flagpole” hydrogens) is unfavorable. The boat conformation is
about 6.5 kcal · mol⫺1 (27 kJ · mol⫺1 ) higher in energy than the chair form at 25⬚C.
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FIGURE 1.7 The boat conformation of cyclohexane. a ⫽ axial hydrogen atom and e ⫽ equatorial hydrogen
atom.
FIGURE 1.8 Twist-boat conformation of cyclohexane.
A modified boat conformation of cyclohexane, known as the twist boat (Fig. 1.8), or skew boat,
has been suggested to minimize torsional and nonbounded interactions. This particular conformation
is estimated to be about 1.5 kcal · mol⫺1 (6 kJ · mol⫺1 ) lower in energy than the boat form at room
temperature.
The medium-size rings (7 to 12 ring atoms) are relatively free of angle strain and can easily take
a variety of spatial arrangements. They are not large enough to avoid all nonbonded interactions
between atoms.
Disubstituted cyclohexanes can exist as cis-trans isomers as well as axial-equatorial conformers.
Two isomers are predicted for 1,4-dimethylcyclohexane (see Fig. 1.9). For the trans isomer the
diequatorial conformer is the energetically favorable form. Only one cis isomer is observed, since
the two conformers of the cis compound are identical. Interconversion takes place between the
conformational (equatorial-axial) isomers but not configurational (cis-trans) isomers.
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FIGURE 1.9 Two isomers of 1,4-dimethylcyclohexane. (a) Trans isomer; (b) cis
isomer.
FIGURE 1.10 Two isomers of decahydronaphthalene, or bicyclo[4.4.0]decane.
(a) Trans isomer; (b) cis isomer.
The bicyclic compound decahydronaphthalene, or bicyclo[4.4.0]decane, has two fused six-membered rings. It exists in cis and trans forms (see Fig. 1.10), as determined by the configurations at
the bridgehead carbon atoms. Both cis- and trans-decahydronaphthalene can be constructed with
two chair conformations.
1.1.4.2 Geometrical Isomerism. Rotation about a carbon-carbon double bond is restricted because of interaction between the p orbitals which make up the pi bond. Isomerism due to such
restricted rotation about a bond is known as geometric isomerism. Parallel overlap of the p orbitals
of each carbon atom of the double bond forms the molecular orbital of the pi bond. The relatively
large barrier to rotation about the pi bond is estimated to be nearly 63 kcal · mol⫺1
(263 kJ · mol⫺1 ).
When two different substituents are attached to each carbon atom of the double bond, cis-trans
isomers can exist. In the case of cis-2-butene (Fig. 1.11a), both methyl groups are on the same side
of the double bond. The other isomer has the methyl groups on opposite sides and is designated as
trans-2-butene (Fig. 1.11b). Their physical properties are quite different. Geometric isomerism can
also exist in ring systems; examples were cited in the previous discussion on conformational isomers.
For compounds containing only double-bonded atoms, the reference plane contains the doublebonded atoms and is perpendicular to the plane containing these atoms and those directly attached
to them. It is customary to draw the formulas so that the reference plane is perpendicular to that of
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FIGURE 1.11 Two isomers of 2-butene. (a) Cis isomer,
bp 3.8⬚C, mp ⫺138.9⬚C, dipole moment 0.33 D; (b) trans
isomer, bp 0.88⬚C, mp ⫺105.6⬚C, dipole moment 0 D.
the paper. For cyclic compounds the reference plane is that in which the ring skeleton lies or to
which it approximates. Cyclic structures are commonly drawn with the ring atoms in the plane of
the paper.
1.1.4.3 Sequence Rules for Geometric Isomers and Chiral Compounds. Although cis and trans
designations have been used for many years, this approach becomes useless in complex systems. To
eliminate confusion when each carbon of a double bond or a chiral center is connected to different
groups, the Cahn, Ingold, and Prelog system for designating configuration about a double bond or
a chiral center has been adopted by IUPAC. Groups on each carbon atom of the double bond are
assigned a first (1) or second (2) priority. Priority is then compared at one carbon relative to the
other. When both first priority groups are on the same side of the double bond, the configuration is
designated as Z (from the German zusammen, “together”), which was formerly cis. If the first priority
groups are on opposite sides of the double bond, the designation is E (from the German entgegen,
“in opposition to”), which was formerly trans. (See Fig. 1.12.)
FIGURE 1.12 Configurations designated by priority
groups. (a) Z (cis); (b) E (trans).
When a molecule contains more than one double bond, each E or Z prefix has associated with it the
lower-numbered locant of the double bond concerned. Thus (see also the rules that follow)
(2E,4Z)-2,4-Hexadienoic acid
When the sequence rules permit alternatives, preference for lower-numbered locants and for inclusion
in the principal chain is allotted as follows in the order stated: Z over E groups and cis over trans
cyclic groups. If a choice is still not attained, then the lower-numbered locant for such a preferred
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group at the first point of difference is the determining factor. For example,
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(2Z,5E)-2,5-Heptadienedioic acid
Rule 1. Priority is assigned to atoms on the basis of atomic number. Higher priority is assigned
to atoms of higher atomic number. If two atoms are isotopes of the same element, the atom of higher
mass number has the higher priority. For example, in 2-butene, the carbon atom of each methyl
group receives first priority over the hydrogen atom connected to the same carbon atom. Around the
asymmetric carbon atom in chloroiodomethanesulfonic acid, the priority sequence is I, Cl, S, H. In
1-bromo-1-deuteroethane, the priority sequence is Cl, C, D, H.
Rule 2. When atoms attached directly to a double-bonded carbon have the same priority, the
second atoms are considered and so on, if necessary, working outward once again from the double
bond or chiral center. For example, in 1-chloro-2-methylbutene, in CH3 the second atoms are
H, H, H and in CH2CH3 they are C, H, H. Since carbon has a higher atomic number than hydrogen,
the ethyl group has the next highest priority after the chlorine atom.
(Z)-1-Chloro-2-methylbutene
(E)-1-Chloro-2-methylbutene
Rule 3. When groups under consideration have double or triple bonds, the multiple-bonded
atom is replaced conceptually by two or three single bonds to that same kind of atom.
A
A
Thus, " A is considered to be equivalent to two A's, or
and # A equals
A . However, a
A
A
A
A
real
has priority over " A; likewise a real A has priority over # A. Actually, both atoms of
A
A
C9O
a multiple bond are duplicated, or triplicated, so that C " O is treated as
, that
O C
C9O
O9C
N
C
is
and
, and C # N is treated as
. A phenyl carbon
(C)
(C)
(N)
(N)
(O)
(C)
CH
becomes 9 C C . Only the double-bonded atoms themselves are duplicated, not the atoms or
CH
groups attached to them. The duplicated atoms (or phantom atoms) may be considered as carrying
atomic number zero. For example, among the groups OH, CHO, CH2OH, and H, the OH group has
the highest priority, and the C(O, O, H) of CHO takes priority over the C(O, H, H) of CH2OH.
1.1.4.4 Chirality and Optical Activity. A compound is chiral (the term dissymmetric was formerly
used) if it is not superimposable on its mirror image. A chiral compound does not have a plane of
symmetry. Each chiral compound possesses one (or more) of three types of chiral element, namely,
a chiral center, a chiral axis, or a chiral plane.
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Chiral Center. The chiral center, which is the chiral element most commonly met, is exemplified
by an asymmetric carbon with a tetrahedral arrangement of ligands about the carbon. The ligands
comprise four different atoms or groups. One “ligand” may be a lone pair of electrons; another, a
phantom atom of atomic number zero. This situation is encountered in sulfoxides or with a nitrogen
atom. Lactic acid is an example of a molecule with an asymmetric (chiral) carbon. (See Fig. 1.13b.)
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FIGURE 1.13 Asymmetric (chiral) carbon in the lactic acid molecule.
A simpler representation of molecules containing asymmetric carbon atoms is the Fischer projection, which is shown here for the same lactic acid configurations. A Fischer projection involves
drawing a cross and attaching to the four ends the four groups that are attached to the asymmetric
carbon atom. The asymmetric carbon atom is understood to be located where the lines cross. The
horizontal lines are understood to represent bonds coming toward the viewer out of the plane of the
paper. The vertical lines represent bonds going away from the viewer behind the plane of the paper
as if the vertical line were the side of a circle. The principal chain is depicted in the vertical direction;
the lowest-numbered (locant) chain member is placed at the top position. These formulas may be
moved sideways or rotated through 180⬚ in the plane of the paper, but they may not be removed
from the plane of the paper (i.e., rotated through 90⬚). In the latter orientation it is essential to use
thickened lines (for bonds coming toward the viewer) and dashed lines (for bonds receding from the
viewer) to avoid confusion.
Enantiomers. Two nonsuperimposable structures that are mirror images of each other are known
as enantiomers. Enantiomers are related to each other in the same way that a right hand is related
to a left hand. Except for the direction in which they rotate the plane of polarized light, enantiomers
are identical in all physical properties. Enantiomers have identical chemical properties except in
their reactivity toward optically active reagents.
Enantiomers rotate the plane of polarized light in opposite directions but with equal magnitude.
If the light is rotated in a clockwise direction, the sample is said to be dextrorotatory and is designed
as (⫹). When a sample rotates the plane of polarized light in a counterclockwise direction, it is said
to be levorotatory and is designed as (⫺). Use of the designations d and l is discouraged.
Specific Rotation. Optical rotation is caused by individual molecules of the optically active
compound. The amount of rotation depends upon how many molecules the light beam encounters
in passing through the tube. When allowances are made for the length of the tube that contains the
sample and the sample concentration, it is found that the amount of rotation, as well as its direction,
is a characteristic of each individual optically active compound.
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Specific rotation is the number of degrees of rotation observed if a 1-dm tube is used and the
compound being examined is present to the extent of 1 g per 100 mL. The density for a pure liquid
replaces the solution concentration.
Specific rotation ⫽ [␣] ⫽
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observed rotation (degrees)
length (dm) ⫻ (g/100 mL)
The temperature of the measurement is indicated by a superscript and the wavelength of the light
employed by a subscript written after the bracket; for example, [␣]20
590 implies that the measurement
was made at 20⬚C using 590-nm radiation.
Optically Inactive Chiral Compounds. Although chirality is a necessary prerequisite for optical
activity, chiral compounds are not necessarily optically active. With an equal mixture of two enantiomers, no net optical rotation is observed. Such a mixture of enantiomers is said to be racemic
and is designated as (⫾) and not as dl. Racemic mixtures usually have melting points higher than
the melting point of either pure enantiomer.
A second type of optically inactive chiral compounds, meso compounds, will be discussed in the
next section.
Multiple Chiral Centers. The number of stereoisomers increases rapidly with an increase in the
number of chiral centers in a molecule. A molecule possessing two chiral atoms should have four
optical isomers, that is, four structures consisting of two pairs of enantiomers. However, if a compound has two chiral centers but both centers have the same four substituents attached, the total
number of isomers is three rather than four. One isomer of such a compound is not chiral because
it is identical with its mirror image; it has an internal mirror plane. This is an example of a diastereomer. The achiral structure is denoted as a meso compound. Diastereomers have different physical
and chemical properties from the optically active enantiomers. Recognition of a plane of symmetry
is usually the easiest way to detect a meso compound. The stereoisomers of tartaric acid are examples
of compounds with multiple chiral centers (see Fig. 1.14), and one of its isomers is a meso compound.
FIGURE 1.14 Isomers of tartaric acid.
When the asymmetric carbon atoms in a chiral compound are part of a ring, the isomerism is
more complex than in acyclic compounds. A cyclic compound which has two different asymmetric
carbons with different sets of substituent groups attached has a total of 22 ⫽ 4 optical isomers: an
enantiometric pair of cis isomers and an enantiometric pair of trans isomers. However, when the
two asymmetric centers have the same set of substituent groups attached, the cis isomer is a meso
compound and only the trans isomer is chiral. (See Fig. 1.15.)
Torsional Asymmetry. Rotation about single bonds of most acyclic compounds is relatively free
at ordinary temperatures. There are, however, some examples of compounds in which nonbonded
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FIGURE 1.15 Isomers of cyclopropane-1,2-dicarboxylic acid. (a)
Trans isomer; (b) meso isomer.
interactions between large substituent groups inhibit free rotation about a sigma bond. In some cases
these compounds can be separated into pairs of enantiomers.
A chiral axis is present in chiral biaryl derivatives. When bulky groups are located at the ortho
positions of each aromatic ring in biphenyl, free rotation about the single bond connecting the two
rings is inhibited because of torsional strain associated with twisting rotation about the central single
bond. Interconversion of enantiomers is prevented (see Fig. 1.16).
For compounds possessing a chiral axis, the structure can be regarded as an elongated tetrahedron
to be viewed along the axis. In deciding upon the absolute configuration it does not matter from
which end it is viewed; the nearer pair of ligands receives the first two positions in the order of
precedence (see Fig. 1.17). For the meaning of (S), see the discussion under Absolute Configuration
on p. 1.49.
A chiral plane is exemplified by the plane containing the benzene ring and the bromine and
oxygen atoms in the chiral compound shown in Fig. 1.18. Rotation of the benzene ring around the
oxygen-to-ring single bonds is inhibited when x is small (although no critical size can be reasonably
established).
FIGURE 1.16 Isomers of biphenyl compounds with bulky groups attached
at the ortho positions.
FIGURE 1.17 Example of a chiral axis.
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FIGURE 1.18 Example of a chiral plane.
FIGURE 1.19 Viewing angle as a means of designating the absolute configuration of compounds with a chiral axis. (a) (R)-2-Butanol (sequence clockwise); (b) (S)-2-butanol (sequence counterclockwise).
Absolute Configuration. The terms absolute stereochemistry and absolute configuration are used
to describe the three-dimensional arrangement of substituents around a chiral element. A general
system for designating absolute configuration is based upon the priority system and sequence rules.
Each group attached to a chiral center is assigned a number, with number one the highest-priority
group. For example, the groups attached to the chiral center of 2-butanol (see Fig. 1.19) are assigned
these priorities: 1 for OH, 2 for CH2CH3 , 3 for CH3 , and 4 for H. The molecule is then viewed from
the side opposite the group of lowest priority (the hydrogen atom), and the arrangement of the
remaining groups is noted. If, in proceeding from the group of highest priority to the group of second
priority and thence to the third, the eye travels in a clockwise direction, the configuration is specified
R (from the Latin rectus, “right”); if the eye travels in a counterclockwise direction, the configuration
is specified S (from the Latin sinister, “left”). The complete name includes both configuration and
direction of optical rotation, as for example, (S)-(⫹)-2-butanol.
The relative configurations around the chiral centers of many compounds have been established.
One optically active compound is converted to another by a sequence of chemical reactions which
are stereospecific; that is, each reaction is known to proceed spatially in a specific way. The configuration of one chiral compound can then be related to the configuration of the next in sequence. In
order to establish absolute configuration, one must carry out sufficient stereospecific reactions to
relate a new compound to another of known absolute configuration. Historically the configuration
of D-(⫹)-2,3-dihydroxypropanal has served as the standard to which all configuration has been
compared. The absolute configuration assigned to this compound has been confirmed by an X-ray
crystallographic technique.
1.1.5 Chemical Abstracts Indexing System
When compounds of complex structure are considered, the number of name possibilities grows
rapidly. To avoid having index entries for all possible names, Chemical Abstracts Service has developed what might be called the principle of inversion. The indexing system employs inverted
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entries to bring together related compounds in an alphabetically arranged index. The index heading
parent from the Chemical Substance Index appears in the Formula Index in lightface before the
“comma of inversion.” The substituents follow the “comma of inversion” in alphabetical order. Any
name modification appears on a separate line. If necessary, the chemical description is completed
by citation of an associated ion, a functional derivative, a “salt with” or “compound with” term,
and/or a stereochemical descriptor.
Quite naturally there is a certain amount of arbitrariness in this system, although the IUPAC
nomenclature is followed. The preferred Chemical Abstracts index names for chemical substances
have been, with very few exceptions, continued unchanged (since 1972) as set forth in the Ninth
Collective Index Guide and in a journal article.* Any revisions appear in the updated Index Guide;
new editions appear at 18-month intervals. Appendix VI is of particular interest to chemists. Reprints
of the Appendix may be purchased from Chemical Abstracts Service, Marketing Division, P.O. Box
3012, Columbus, Ohio 43210.
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* J. Chem. Doc. 14(1):3–15 (1974).
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TABLE 1.13 Names and Formulas of Organic Radicals
For more comprehensive lists, see the various lists of radicals given in the subject indexes of the annual and
decennial indexes of Chemical Abstracts.
Name
Acenaphthenyl
Acenaphthenylene
Acenaphthenylidene
Acetamido
Acetimidoyl
Acetoacetyl
Acetohydrazonoyl
Acetohydroximoyl
Acetonyl
Acetonylidene
Acetoxy
Acetyl (not ethanoyl)
Acetylamino
Acetylhydrazino
Acetylimino
Acridinyl (from acridine)
Acroyloyl (or propenoyl)
Adipoyl (or hexanedioyl)
Alanyl
␤-Alanyl
Allyl (or 2-propenyl)
Allylidene
Allyloxy
Amidino
Amino
Aminomethyleneamino
Aminooxy
Ammonio
Amyl, see Pentyl
Anilino
Anisidino (o-, m-, or
p-)
Anisoyl (o-, m-, or
p-; or methoxybenzoyl)
Anthraniloyl
Anthryl (from anthracene)
Anthrylene
Arginyl
Asparaginyl
Aspartoyl
␣-Aspartyl
Atropoyl (or 2-phenylpropenoyl)
Azelaoyl, see Nonanedioyl
Formula
C12H9 9
9C12H8 9
C12H8 "
CH3 9CO9NH9
CH3C("NH)9
CH3 9CO9CH2 9CO9
CH3 9C("NNH2)9
CH3 9C("NOH)9
CH3 9CO9CH2 9
CH3 9CO9CH"
CH3 9CO9O9
CH3 9CO9
CH3 9CO9NH9
CH3 9CO9NH9NH9
CH3 9CO9N"
NC13H8 9
CH2 "CH9CO9
9CO9[CH2]4 9CO9
CH3 9CH(NH2)9CO9
H2N9CH2 9CH2 9CO9
CH2 "CH9CH2 9
CH2 "CH9CH"
CH2 "CH9CH2 9O9
H2N9C("NH)9
H2N9
H2N9CH"N9
H2N9O9
⫹
H3N9
C6H5 9NH9
CH3O9C6H4 9NH9
CH3O9C6H4 9CO9
o-NH2 9C6H4 9CO9
C14H9 9
9C14H8 9
H2N9C("NH)9NH9
[CH2]3 9CH(NH)9
CO9
H2N9CO9CH2 9
CH(NH2)9CO9
9CO9CH2 9
CH(NH2)9CO9
HO2C9CH2CH(NH2)9
C6H5 9C("CH2)9CO9
Name
Azido
Azino
Azo
Azoxy
Azulenyl
Benzamido
Benzeneazo
Benzeneazoxy
1,2-Benzenedicarbonyl,
see Phthaloyl
1,3-Benzenedicarbonyl (or
isophthaloyl)
1,4-Benzenedicarbonyl (or
terephthaloyl)
Benzenesulfinyl
Benzenesulfonamido
Benzenesulfonyl
Benzenesulfonylamino
Benzenetriyl
Benzhydryl (or diphenylmethyl)
Benzidino
Benziloyl (or 2-hydroxy2,2-diphenylethanoyl)
Benzimidazolyl
Benzimidoyl
Benzofuranyl
Benzopyranyl
Benzoquinonyl (1,2- or
1,4-)
Benzo[b]thienyl
Benzoyl
Benzoylamino
Benzoylhydrazino
Benzoylimino
Benzoyloxy
Benzyl
Benzylidene
Benzylidyne
Benzyloxy
Benzyloxycarbonyl
Benzylthio
Biphenylenyl
Biphenylyl
Bornenyl
Bornyl (not camphyl or
bornylyl)
Bromo
Bromoformyl
Formula
N3 9
"N9N"
9N"N9
9N(O)9N9
C10H7 9
C6H5 9CO9NH9
C6H5 9N"N9
C6H5 9N2O9
9CO9C6H4 9CO9 (m-)
9CO9C6H4 9CO9 (p-)
C6H5 9SO9
C6H5 9SO2 9NH9
C6H5 9SO2 9
C6H5 9SO2 9NH9
C6H3 9
(C6H5)2CH9
p-H2N9C6H4 9C6H4 9
NH9
(C6H5)2C(OH)9CO9
N2C7H5 9
C6H5 9C("NH)9
OC8H5 9
OC9H7 9
(O")2C6H3 9
SC8H5 9
C6H5 9CO9
C6H5 9CO9NH9
C6H5 9CO9NH9NH9
C6H5 9CO9N"
C6H5 9CO9O9
C6H5 9CH2 9
C6H5 9CH"
C6H5 9C#
C6H5 9CH2 9O9
C6H5 9CH2 9O9CO9
C6H5 9CH2 9S9
C12H7 9
C6H5 9C6H4 9
C10H15 9
C10H17 9
Br9
Br9CO9
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TABLE 1.13 Names and Formulas of Organic Radicals (Continued)
Name
Bromonio
Butadienyl (1,3- shown)
Butanedioyl, see Succinyl
Butanediylidene
Butanediylidyne
Butanoyl, see Butyryl
cis-Butenedioyl, see Maleoyl
trans-Butenedioyl, see Fumaroyl Butenoyl, see
Crotonoyl and Isocrotonoyl
1-Butenyl
2-Butenyl (not crotyl)
2-Butenylene
Butenylidene (2- shown)
Butenylidyne (2- shown)
Butoxy
sec-Butoxy (unsubstituted
only)
tert-Butoxy (unsubstituted
only)
Butyl
sec-Butyl (unsubstituted
only)
tert-Butyl (unsubstituted
only)
Butylidene
sec-Butylidene (unsubstituted only)
Butylidyne
Butyryl (or butanoyl)
Camphoroyl
Carbamoyl
Carbazolyl
Carbazoyl
Carbonimidoyl
Carbonohydrazido (preferred to carbohydazido
or carbazido)
Carbonyl
Carbonyldioxy
Carboxy
Carboxylato
Chloro
Chlorocarbonyl, see Chloroformyl
Chloroformyl
Chlorosyl
Chlorothio
Chloryl
Formula
⫹
HBr9
CH2 "CH9CH"CH9
"CH9CH2 9CH2 9
CH"
#C9CH2 9CH2 9C#
CH3 9CH2 9CH"CH9
CH3 9CH"CH9CH2 9
9CH2 9CH"CH9
CH2 9
CH3CH"CH9CH"
CH3 9CH"CH9C#
CH3 9[CH2]3 9O9
C2H5 9CH(CH3)9O9
(CH3)3C9O9
CH3 9[CH2]3 9 or
C4H9 9
C2H5 9CH(CH3)9
(CH3)3C9
CH3 9CH2 9CH2 9CH"
C2H5C(CH3)"
Name
Cinnamoyl (or 3-phenylpropenoyl)
Cinnamyl
Cinnamylidene
Citraconoyl (unsubstituted
only)
Crotonoyl
Formula
C6H5 9CH"CH9CO
C6H5 9CH"CH9CH2 9
C6H5 9CH"CH9CH"
HC 9 CO 9
CH3 9 C9 CO 9
CH3 9CH"CH9CO9
(trans)
Crotyl, see 2-Butenyl
Cumenyl (o-, m-, or p-)
Cyanato
Cyano
Cyclobutyl
Cycloheptyl
Cyclohexadienyl (2,4shown)
(CH3)2CH9C6H4 9
NCO9
NC9
C4H7 9
C7H13 9
CH " CH 9 CH 9
Cyclohexadienylidene
(2,4- shown)
CH 9 CH2 9 C
Cyclohexanecarbonyl
Cyclohexanecarbothioyl
Cyclohexanecarboxamido
Cyclohexanecarboximidoyl
Cyclohexenyl
2-Cyclohexenylidene
CH 9 CH
CH
C6H11 9CO9
C6H11 9CS9
C6H11 9CO9NH9
C6H11 9C("NH)9
C6H9 9
CH " CH 9 C
Cyclohexyl
Cyclohexylcarbonyl
Cyclohexylene
Cyclohexylidene
CH " CH 9 CH2
CH2
H2C 9 CH2
C6H11 9
C6H11 9CO9
9C6H10 9
CH2 9 CH2 9 C
CH2 9 CH2 9 CH2
CH3 9[CH2]2 9C#
CH3 9CH2 9CH2 9CO9
C10H14O2 9
H2N9CO9
NC12H8 9
H2N9NH9CO9
9C("NH)9
H2N9NH9CO9NH9
NH9
9CO9 or "C(O)
9O9CO9O9
HO2C9
9O2C9
Cl9
Cl9C(O)9
OCl9
ClS9
O2Cl9
Cyclohexylthiocarbonyl
Cyclopentadienyl
Cyclopentadienylidene
Cyclopenta[a]phenanthryl
1,2-Cyclopentenophenanthryl
Cyclopentenyl
Cyclopentyl
Cyclopentylene
Cyclopropyl
Cysteinyl
Cystyl
Decanedioyl
Decanoyl
Decyl
Diacetoxyiodo
Diacetylamino
Diaminomethyleneamino
C6H11 9CS9
C5H5 9
CH"CH9CH"CH9C"
C17H17 9
C17H11 9
C5H7 9
C5H9 9
9C5H8 9
C3H5 9
HS9CH2 9CH(NH2)9
CO9
9CO9CH(NH2)9
CH2 9S9S9CH2 9
CH(NH2)9CO9
9CO9[CH2]8 9CO9
CH3 9[CH2]8 9CO9
CH3 9[CH2]9 9
(CH3 9CO9O)2I9
(CH3 9CO)2N9
(NH2)2C"N9
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TABLE 1.13 Names and Formulas of Organic Radicals (Continued)
Name
Diazo
Diazoamino
Dibenzoylamino
Dichloroiodo
Diethylamino
3,4-Dihydroxybenzoyl, see
Protocatechuoyl
2,3-Dihydroxybutanedioyl,
see Tartaroyl
Dihydroxyiodo
2,3-Dihydroxypropanoyl,
see Glyceroyl
3,4-Dimethoxybenzoyl,
see Veratroyl
3,4-Dimethoxyphenethyl
3,4-Dimethoxyphenylacetyl
Dimethylamino
Dimethylbenzoyl
Dioxy
Diphenylamino
Diphenylmethylene
Dithio
Diethiocarboxy
Dithiosulfo
Dodecanoyl
Dodecyl
Elaidoyl (or trans-9-octadecenoyl)
Epidioxy (as a bridge)
Epidiseleno (as bridge)
Epidithio (as a bridge)
Epimino (as a bridge)
Episeleno (as a bridge)
Epithio (as a bridge)
Epoxy (as a bridge)
Ethanesulfonamide
Ethanoyl, see Acetyl
Ethenyl, see Vinyl
Ethoxalyl
Ethoxy
Ethoxycarbonyl
Ethyl
Ethylamino
Ethylene
Ethylenedioxy
Ethylidene
Ethylidyne
Ethylsulfonylamino
Ethylthio
Ethynyl
Ethynylene
Fluoranthenyl
Formula
"N2
9N"N9NH9
(C6H5 9CO)2N9
Cl2I9
(C2H5)2N9
(HO)2I9
3,4(CH3O)2C6H3CH2CH9
3,4(CH3O)2C6H3CH2CO9
(CH3)2N9
(CH3)2C6H6H3 9CO9
9O9O9
(C6H5)2N9
(C6H5)2C"
9S9S9
HSSC9
HOS2 9
CH3[CH2]10 9CO9
CH3[CH2]11 9
CH3[CH2]7CH"CH9
[CH2]7 9CO9
9O9O9
9Se9Se9
9S9S9
9NH9
9Se9
9S9
9O9
C2H5 9SO2 9NH9
C2H5 9OOC9CO9
C2H5 9O9
C2H5 9O9CO9
C2H5 9 or CH3 9CH2 9
C2H5 9NH9
9CH2 9CH2 9
9O9CH2 9CH2 9O9
CH3 9CH"
CH3 9C#
C2H5 9SO2 9NH9
C2H5 9S9
HC#C9
9C#C9
C16H9 9
Name
Formula
Fluorenyl
Fluoro
Fluoroformyl
Formamido
Formimidoyl
Formyl (not methanoyl)
Formylamino
Formylimino
Formyloxy
Fumaroyl (or trans-butenedioyl)
Furancarbonyl, see Furoyl
C13H9 9
F9
F9CO9
OCH9NH9
CH("NH)9
OCH9 or 9C(O)H
H9CO9NH9
H9CO9N"
H9CO9O9
9CO9CH"CH9CO9
(trans)
Furfuryl (2- only; preferred to 2-furylmethyl)
HC
Furfurylidene (2- only)
HC
Furoyl (3- shown; preferred to furancarbonyl)
Furyl
3-Furylmethyl
Galloyl (or 3,4,5-trihydroxybenzoyl)
Geranyl (from geraniol)
Glutaminyl
Glutamoyl
␣-Glutamyl
␥-Glutamyl
Glutaryl (or pentanedioyl)
Glyceroyl (or 2,3- dihydroxypropanoyl)
Glycoloyl (or hydroxyethanoyl)
Glycyl
Glycylamino
Glyoxyloyl
Guanidino
Guanyl, see Amidino
Heptanamido
Heptanedioyl
Heptanoyl
Heptyl
Hexadecanoyl
Hexadecyl
Hexamethylene
Hexanamido
Hexanedioyl (or adipoyl)
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CH " C 9 CH2 9
CH 9 O
CH " C 9 CH
CH 9 O
CH " C 9 CO 9
O
CH " CH
OC4H3 9
CH " C 9 CH2 9
O
CH " CH
3,4,5-(HO)3C6H2 9 CO 9
C10H17 9
H2N9CO9CH2 9CH2 9
CH(NH2)9CO9
9CO9CH2 9CH2 9
CH(NH2)9CO9
HOOC[CH2]2CH(NH2)9
CO9
HOOC9CH(NH2)9
[CH2]2 9CO9
9CO9[CH2]3 9CO9
HO9CH2 9CH(OH)9
CO9
HO9CH2 9CO9
H2N9CH2 9CO9
H2N9CH2 9CO9NH9
OHC9CO9
H2N9C("NH)9NH9
CH3 9[CH2]5 9CO9NH9
9CO9[CH2]5 9CO9
CH3 9[CH2]5 9CO9
CH3 9[CH2]5 9CH2 9
CH3 9[CH2]14 9CO9
CH3 9[CH2]14 9CH2 9
9[CH2]6 9
CH3 9[CH2]4 9CO9NH9
9CO9[CH2]4 9CO9
short
standard
long
DEAN #37261
LEFT
(McGHP)
1.54
INTERACTIVE
top of rh
base of rh
SECTION 1
cap height
base of text
TABLE 1.13 Names and Formulas of Organic Radicals (Continued)
Name
Hexanimidoyl
Hexanoyl
Hexanoylamino
Hexyl
Hexylidene
Hexyloxy
Hippuroyl
Histidyl
Homocysteinyl
Homoseryl
Hydantoyl
Hydratropoyl (or 2-phenylpropanoyl)
Hydrazi
Hydrazino
Hydrazo
Hydrazono
Hydroperoxy
Hydroseleno
Hydroxy
Hydroxyamino
o-Hydroxybenzoyl (or salicyloyl)
m-Hydroxybenzoyl
p-Hydroxybenzoyl
Hydroxybutanedioyl, see
Maloyl
2-Hydroxy-2,2-diphenyl
ethanoyl, see Benziloyl
Hydroxyethanoyl, see Glycoloyl
Hydroxyimino
4-Hydroxy-3-methoxybenzoyl (or vanilloyl)
3-Hydroxy-2-phenylpropanoyl (or tropoyl)
Hydroxypropanedioyl (or
tartronoyl)
2-Hydroxypropanoyl (or
lactoyl)
Icosyl
Imino
Iminomethylamino
Iodo
Iodoformyl
Formula
Name
CH3 9[CH2]4 9C("NH)9
CH3 9[CH2]4 9CO9
CH3 9[CH2]4 9CO9NH9
CH3 9[CH2]4 9CH2 9
CH3 9[CH2]4 9CH"
CH3[CH2]5 9O9
C6H5 9CO9NH9CH2 9
CO9
N2C3H3 9CH2 9CH(NH2)9
CO9
HS9CH2 9CH2 9
CH(NH2)9CO9
HO9CH2 9CH2 9
CH(NH2)9CO9
H2N9CO9NH9CH2 9
CO9
C6H5 9CH(CH3)9CO9
Iodonio
Iodosyl
Iodyl
Isobutoxy (unsubstituted
only)
Isobutyl (unsubstituted
only)
Isobutylidene (unsubstituted only)
Isobutylidyne (unsubstituted only)
Isobutyryl (unsubstituted
only; or 2-methylpropanoyl)
Isocarbonohydrazido
9NH9NH9 (to single
atom)
H2N9NH9
9NH9NH9 (to different
atoms)
H2N9N"
HO9O9
HSe9
HO9
HO9NH9
o-HO9C6H4 9CO9
Isocyanato
Isocyano
Isohexyl (unsubstituted
only)
Isoleucyl
m-HO9C6H4 9CO9
p-HO9C6H4 9CO9
HO9N"
4-HO,3-CH3O9
C6H3 9CO9
C6H5 9CH(CH2OH)9CO9
Isocrotonoyl
Isonicotinoyl (or 4-pyridinecarbonyl)
Isopentyl (unsubstituted
only)
Isophthaloyl (or 1,3benzenedicarbonyl)
Isopropenyl (unsubstituted
only; or 1-methylvinyl)
Isopropoxy (unsubstituted
only)
Isopropyl (unsubstituted
only)
p-Isopropylbenzoyl
Isopropylbenzyl
Isopropylidene
Isoselenocyanato
Isosemicarbazido
Isothiocyanato
Isothioureido
9CO9CH(OH)9CO9
Isoureido
CH3 9CH(OH)9CO9
CH3 9[CH2]18 9CH2 9
9NH9, HN"
HN"CH9NH9
I9
I9CO9
Isovaleryl (unsubstituted
only; or 3-methylbutanoyl)
Lactoyl
Lauroyl (unsubstituted
only)
Formula
⫹
HI9
OI9
O2I9
(CH3)2CH9CH2 9O9
(CH3)2CH9CH2 9
(CH3)2CH9CH"
(CH3)2CH9C#
(CH3)2CH9CO9
H2N9N"C(OH)9NH9
NH9
CH3 9CH"CH9CO9
(cis)
OCN9
CN9
(CH3)2CH9[CH2]3 9
C2H5 9CH(CH3)9
CH(NH2)9CO
NC5H4 9CO9 (4-)
(CH3)2CH9CH2 9CH2 9
9CO9C6H4 9CO9
(m-)
CH2 "C(CH3)9
(CH3)2CH9O9
(CH3)2CH9
p-(CH3)2CH9C6H4 9CO9
(CH3)2CH9C6H4 9CH2 9
(CH3)2C"
SeCN9
H2N9NH9C(OH)"N9
SCN9
HN"C(SH)9NH9,
H2N9C(SH)"N9
HN"C(OH)9NH9,
H2N9C(OH)"N9
(CH3)2CH9CH2 9CO9
CH3 9CH(OH)9CO9
CH3 9[CH2]10 9CO9
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
1.55
ORGANIC COMPOUNDS
cap height
base of text
TABLE 1.13 Names and Formulas of Organic Radicals (Continued)
Name
Leucyl
Lysyl
Maleoyl
Malonyl
Maloyl
MercaptoMesaconoyl (unsubstituted
only)
Mesityl
Mesoxalo
Mesoxalyl
Mesyl
Methacryloyl (or 2-methylpropenoyl)
Methaneazo
Methaneazoxy
Methanesulfinamido
Methanesulfinyl
Methanesulfonamido
Methanesulfonyl, see
Mesyl
Methanoyl, see Formyl
Methionyl
Formula
(CH3)2CH9CH2 9
CH(NH2)9CO9
H2N9[CH2]4 9
CH(NH2)9CO9
9CO9CH"CH9CO9
9CO9CH2 9CO9
9CO9CH(OH)9CH2 9
CO9
HS9
9 CO 9 CH
CH3 9 C 9 CO 9
2,4,6-(CH3)3C6H2 9
HOOC9CO9CO9
9CO9CO9CO9
CH3 9SO2 9
CH2 "C(CH3)9CO9
CH3 9N"N9
CH3 9N2O9
CH3 9SO9NH9
CH3 9SO9
CH3 9SO2 9NH9
CH3 9S9CH2 9CH2 9
CH(NH2)9CO9
CH3OOC9CO9
CH3O9
CH3O9C6H4 9CO9
Methoxalyl
Methoxy
Methoxybenzoyl (o-, m-,
or p-)
Methoxycarbonyl
Methoxyimino
Methoxyphenyl
Methoxysulfinyl
Methoxysulfonyl
Methoxy(thiosulfonyl)
Methyl
Methylallyl
Methylamino
Methylazo
Methylazoxy
␣-Methylbenzyl
Methylbenzyl
3-Methylbutanoyl
cis-Methylbutenedioyl
CH3O9CO9
CH3O9N"
CH3O9C6H4 9
CH3O9SO9
CH3O9SO2 9
CH3O9S2O9
CH3 9
CH2 "C(CH3)9CH2 9
CH3 9NH9
CH3 9N"N9
CH3 9N2O9
C6H5 9CH(CH3)9
CH3 9C6H4 9CH2 9
(CH3)2CH9CH2 9CO9
HC 9 CO 9
trans-Methylbutenedioyl
CH3 9 C 9 CO 9
9 CO 9 CH
Methyldithio
Methylene
Methylenedioxy
3,4-Methylenedioxybenzoyl
CH3 9 C 9 CO 9
CH3 9S9S9
9CH2 9, H2C"
9O9CH2 9O9
3,4-CH2O2 : C6H3 9
CO9
Name
5-Methylhexyl
Methylidyne
Methylsulfinimidoyl
Methylsulfinohydrazonoyl
Methylsulfinohydroximoyl
Methylsulfinyl
Methylsulfinylamino
Methylsulfonohydrazonoyl
Methylsulfonimidoyl
Methylsulfonohydroxamoyl
Methylsulfonyl
Methylthio
(Methylthio)sulfonyl
1-Methylvinyl, see Isopropenyl
Morpholino (4- only)
Morpholinyl (3- shown)
top of rh
base of rh
Formula
(CH3)2CH9[CH2]4 9
HC#
CH3 9S("NH)9
CH3 9S("NNH2)9
CH3 9S("N9OH)9
CH3 9SO9
CH3 9SO9NH9
CH3 9S(O)(NNH2)9
CH3 9S(O)("NH)9
CH3 9S(O)(N9OH)9
CH3 9SO2 9
CH3S9
CH3S9SO2 9
O
O
CH29 CH2
CH29 CH2
CH29 CH2
N9
NH
CH29 CH
Myristoyl (unsubstituted
only)
Naphthalenazo
Naphthalenecarbonyl, see
Naphthoyl
Naphthoyl
Naphthoyloxy
Naphthyl
Naphthylazo
Naphthylene
Naphthylenebisazo
Naphthyloxy
Neopentyl (unsubstituted
only)
Nicotinoyl
Nitrilo
Nitro
aci-Nitro
Nitroso
Nonanedioyl
Nonanoyl
Nonyl
Norbornyl
Norbornylyl, see Norbornyl
Norcamphyl, see Norbornyl
Norleucyl
Norvalyl
Octadecanoyl
CH3 9[CH2]12 9CO9
C10H7 9N"N9
C10H7 9CO9
C10H7 9CO9O9
C10H7 9
C10H7 9N"N9
9C10H6 9
9N"N9C10H6 9
N"N9
C10H7 9O9
(CH3)3C9CH2 9
NC5H4 9CO9 (3-)
N#
O2N9
HO9(O")N"
ON9
9CO9[CH2]7 9CO9
CH3 9[CH2]7 9CO9
CH3 9[CH2]7 9CH2 9
C7H11 9
CH3 9[CH2]3 9CH(NH2)9
CO9
CH3 9CH2 9CH2 9
CH(NH2)9CO9
CH3 9[CH2]16 9CO9
short
standard
long
DEAN #37261
LEFT
(McGHP)
1.56
INTERACTIVE
top of rh
base of rh
SECTION 1
cap height
base of text
TABLE 1.13 Names and Formulas of Organic Radicals (Continued)
Name
cis-9-Octadecenoyl
Octadecyl
Octanedioyl
Octanoyl
Octyl
Oleoyl
Ornithyl
Oxalacetyl
Oxalaceto
Oxalo
Oxalyl
Oxamoyl
Oxido
Oxo
Oxonio
Oxy
Palmitoyl (unsubstituted
only)
Pentafluorothio
Pentamethylene
Pentanedioyl, see Glutaryl
Pentanoyl, see Valeryl
Pentenyl (2- shown)
Pentyl
Pentyloxy
Perchloryl
Phenacyl
Phenacylidene
Phenanthryl
Phenethyl
Phenetidino (o-, m-, or p-)
Phenoxy
Phenyl
Phenylacetyl
Phenylazo
Phenylazoxy
Phenylcarbamoyl
Phenylene
Phenylenebisazo
Phenylimino
2-Phenylpropanoyl
3-Phenylpropenoyl, see
Cinnamoyl
3-Phenylpropyl
Formula
H[CH2]8 9CH"CH9
[CH2]7 9CO9
CH3 9[CH2]16 9CH2 9
9CO9[CH2]6 9CO9
CH3 9[CH2]6 9CO9
CH3 9[CH2]6 9CH2 9
H[CH2]8 9CH"CH9
[CH2]7 9CO9
H2N9[CH2]3 9
CH(NH2)9CO9
9CO9CH2 9CO9
CO9
HOOC9CO9CH2 9
CO9
HOOC9CO9
9CO9CO9
H2N9CO9CO9
⫺
O9 (ion)
O"
⫹
H2O9
9O9
CH3 9[CH2]14 9CO9
F5S9
9CH2 9CH2 9CH2 9
CH2 9CH2 9
CH3 9CH2 9CH"CH9
CH2 9
CH3 9CH2 9CH2 9CH2 9
CH2 9
CH3 9[CH2]4 9O9
O3Cl9
C6H5 9CO9CH2 9
C6H5 9CO9CH"
C14H9 9
C6H5 9CH2 9CH2 9
C2H5O9C6H4 9NH9
C6H5 9O9
C6H5 9
C6H5 9CH2 9CO9
C6H5 9N"N9
C6H5 9N2O9
C6H5 9NH9CO
9C6H4 9
9N"N9C6H4 9
N"N9
C6H5 9N"
C6H5 9CH(CH3)9CO9
C6H5 9CH2 9CH2 9
CH2 9
Name
Formula
Phthalidyl
C6H5 9NH9SO2
C6H5 9SO9
C6H5 9SO2 9
C6H5 9SO2 9NH9
C6H5 9S9
C6H5 9NH9CO9NH9
H2N 9 CO 9 C6H4 9 CO 9
(o-)
C6H4 9 CO 9 O 9 CH 9
Phthalimido
CO 9 C6H4 9 CO 9 N 9
Phthaloyl
Picryl
Pimeloyl (unsubstituted
only)
Piperidino (1- only)
Piperidyl (2-, 3-, 4-)
Piperonyl
Pivaloyl (unsubstituted
only)
Polythio
Propanedioyl, see Malonyl
Propanoyl, see Propionyl
Propargyl, see 2-Propynyl
Propenoyl, see Acryloyl
1-Propenyl
2-Propenyl, see Allyl
Propenylene
Propioloyl
Propionamido
Propionyl
Propionylamino
Propionyloxy
Propoxy
Propyl
Propylene
Propylidene
Propylidyne
Propynoyl, see Propiolyl
1-Propynyl
2-Propynyl
Protocatechuoyl
3-Pyridinecarbonyl
4-Pyridinecarbonyl
Pyridinio
Pyridyl
2-Pyridylcarbonyl
Pyridyloxy
Pyruvoyl
Salicyl
Salicylidene
Salicyloyl
Sarcosyl
9CO9C6H4 9CO9 (o-)
2,4,6-(NO2)3C6H2 9
9CO9[CH2]5 9CO9
Phenylsulfamoyl
Phenylsulfinyl
Phenylsulfonyl
Phenylsulfonylamino
Phenylthio
3-Phenylureido
Phthalamoyl
C5H10N9
NC5H10 9
3,4-CH2O2 : C6H3 9CH2 9
(CH3)3C9CO9
9S4 9
CH3 9CH"CH9
9CH2 9CH"CH9
CH#C9CO9
CH3 9CH2 9CO9NH9
CH3 9CH2 9CO9
CH3 9CH2 9CO9NH9
CH3 9CH2 9CO9O9
CH3 9CH2 9CH2 9O
CH3 9CH2 9CH2 9
9CH(CH3)9CH2 9
CH3 9CH2 9CH"
CH3 9CH2 9C#
CH3 9C#C9
HC#C9CH2 9
3,4-(HO)2C6H3 9CO9
NC5H4 9CO9 (3-)
NC5H4 9CO9 (4-)
⫹
NC5H5 9 (ion)
NC5H4 9
NC5H4 9CO9 (2-)
NC5H4 9O9
CH3 9CO9CO9
o-HO9C6H4 9CH2 9
o-HO9C6H4 9CH"
o-HO9C6H4 9CO9
CH3 9NH9CH2 9CO9
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
1.57
ORGANIC COMPOUNDS
cap height
base of text
TABLE 1.13 Names and Formulas of Organic Radicals (Continued)
Name
Sebacoyl (unsubstituted
only)
Seleneno
Selenino
Seleninyl
Seleno
Selenocyanato
Selenoformyl
Selenonio
Selenono
Selenonyl
Selenoureido
Selenoxo
Semicarbazido
Semicarbazono
Seryl
Stearoyl (unsubstituted
only)
Styryl
Suberoyl (unsubstituted
only)
Succinamoyl
Succinimido
Succinimidoyl
Succinyl
Sulfamoyl
Sulfanilamido
Sulfanilyl
Sulfenamoyl
Sulfeno
Sulfido
Sulfinamoyl
Sulfino
Sulfinyl
Sulfo
Sulfoamino
Sulfonato
Sulfonio
Sulfonyl
Sulfonyldioxy
Tartaroyl
Tartronoyl
Tauryl
Telluro
Terephthaloyl
Terphenylyl
Formula
9CO9[CH2]8 9CO9
HOSe9
HO2Se9
OSe"
9Se9
NC9Se9
HSeC9
⫹
H2Se9 (ion)
HO3Se9
O2Se9
H2N9CSe9NH9
(C)"Se
H2N9CO9NH9NH9
H2N9CO9NH9N"
HO9CH2 9CH(NH2)9
CO9
CH3 9[CH2]16 9CO9
C6H5 9CH"CH9
9CO9[CH2]6 9CO9
H2N9CO9CH2 9CH2 9
CO9
O
CH2 9 C
N9
CH2 9 C
O
9C("NH)9CH2 9
CH2C("NH)9
9CO9CH2 9CH2 9CO9
H2N9SO2 9
p-H2N9C6H4 9SO2 9
NH9
p-H2N9C6H4 9SO2 9
H2N9S9
HO9S9
⫺
S9 (ion)
H2N9SO9
HO2S9
9SO9
HO9SO2 9
HO2S9NH9
⫺
O3S9 (ion)
⫹
H2S9 (ion)
9SO2 9
9O9SO2 9O9
9CO9CH(OH)9
CH(OH)9CO9
9CO9CH(OH)9CO9
H2N9CH2 9CH2 9SO2 9
Te replacing O
9CO9C6H4 9CO9 (p-)
C6H5 9C6H4 9C6H4 9
Name
(Terthiophen)yl
Tetradecanoyl
Tetradecyl
Tetramethylene
Thenoyl (2- shown)
Thenyl
Thienyl
Thio
Thioacetyl
Thiobenzoyl
Thiocarbamoyl
Thiocarbazono
Thiocarbodiazono
Thiocarbonohydrazido
Thiocarbonyl
Thiocarboxy
Thiocyanato
Thioformyl
Thiophenecarbonyl, see
Thenoyl
Thiosemicarbazido
Thiosulfino
Thiosulfo
Thioreido
Thioxo
Threonyl
Toluenesulfonyl (o-, m-)
Toluidino (o-, m-, or p-)
Toluoyl (o-, m-, or p-)
Tolyl (o-, m-, or p-)
Tolylsulfonyl
Tosyl (p- only)
Triazano
Triazeno
Trichlorothio
Tridecanoyl
Tridecyl
Trifluorothio
3,4,5-Trihydroxybenzoyl
Trimethylammonio
Trimethylanilino (all isomers)
Trimethylene
Trimethylenedioxy
Triphenylmethyl
Trithio
Trithiosulfo
top of rh
base of rh
Formula
SC4H3 9SC4H2 9SC4H2 9
CH3 9[CH2]12 9CO9
CH3 9[CH2]12 9CH2 9
9CH2 9CH2 9CH2 9
CH2 9
CO 9
CH " C
S
CH " CH
SC4H3 9CH2 9
SC4H3 9
9S9
CH3 9CS9
C6H5 9CS9
H2N9CS9
HN"N9CS9NH9
NH9
HN"N9CS9N"N9
H2N9NH9CS9NH9
NH9
9CS9, SC"
HSOC9, HS9CO9
NCS9
SHC9, HCS9
H2N9CS9NH9NH9
HOS2 9
HO2S2 9
H2N9CS9NH9
S"
CH3 9CH(OH)9
CH(NH2)9CO9
CH3 9C6H4 9SO2 9
CH3 9C6H4 9NH9
CH3 9C6H4 9CO9
CH3 9C6H4 9
CH3 9C6H4 9SO2 9
p-CH3 9C6H4 9SO2 9
H2N9NH9NH9
H2N9N"N9
Cl3S9
CH3 9[CH2]11 9CO9
CH3 9[CH2]12 9
F3S9
3,4,5-(HO)3C6H2 9CO9
(CH3)3N⫹ 9 (ion)
(CH3)3C6H2 9NH9
9CH2 9CH2 9CH2 9
9O9CH2 9CH2 9
CH2 9O9
(C6H5)3C9
9S3 9
HS9S3 9
short
standard
long
DEAN #37261
LEFT
(McGHP)
1.58
INTERACTIVE
top of rh
base of rh
SECTION 1
cap height
base of text
TABLE 1.13 Names and Formulas of Organic Radicals (Continued)
Name
Formula
(C6H5)3C9
C6H5 9CH(CH2OH)9
CO9
p-HO9C6H4 9CH2 9
CH(NH2)9CO9
CH3 9[CH2]9 9CO9
CH3 9[CH2]9 9CH2 9
H2N9CO9NH9
9NH9CO9NH9
CH3 9[CH2]3 9CO9
(CH3)2CH9CH(NH2)9
CO9
Trityl
Tropoyl
Tyrosyl
Undecanoyl
Undecyl
Ureido
Ureylene
Valeryl
Valyl
1.2
Name
Formula
3,4-CH3O(HO)C6H3 9
CO9
3,4-CH3O(HO)C6H3 9
CH2 9
3,4-(CH3O)2C6H3 9
CO9
3,4-(CH3O)2C6H2 9
CH2 9
CH2 "CH9
9CH"CH9
(CH3)2C6H3 9NH9
(CH3)2C6H3 9
Vanilloyl
Vanillyl
Veratroyl
Veratryl
Vinyl
Vinylene
Xylidino (all isomers)
Xylyl (all isomers)
PHYSICAL PROPERTIES OF PURE SUBSTANCES
TABLE 1.14 Empirical Formula Index of Organic Compounds
The alphanumeric designations are keyed to Table 1.15.
Br2OS: t149
ClHO3S: c248
ClH4NO: h139
Cl2OS: t150
Cl2H2Si: d270a
Cl3HSi: t249
Cl3PS: t158
H3NO3S: s23
H4N2: h85
H6Si2: d791
C1
CBr4: c13
CBrClF2: b301
CBrCl3: b432
CBrF3: b434
CBrN: c325
CBr2F2: d93
CBr4: c13
CClF3: c264
CClNO3S: c249
CCl2F2: d218
CCl3D: c146
CCl3F: t237
CCl4: c14
CCl4S: t240
CD2Cl2: d236
CD4O: m36
CD7O: m40
CFCl3: f30
CF4: c15
CHBrCl2: b316
CHBr2Cl: d88
CHBr2F: d104a
CHBr3: t204
CHClF2: c101
CHCl2F: d233
CHCl3: c145
CHF3: t307
CHF3O3S: t308
CHI3: i33
CH2BrCl: b305
CH2Br2: d110
CH2Cl2: d235
CH2F2: d409
CH2I2: d452
CH2N2: c318, d63
CH2N4: t131
CH2O: f32
(CH2O)x: p1
CH2O2: f36
CH2O3: g29
CH2S3: t451
CH3Br: b354
CH3Br3Ge: m260
CH3Cl: c157
CH3ClO2S: m36
CH3Cl3Si: m450, t242
CH3DO: m39
CH3F: f18
CH3I: i37
CH3NO: f33
CH3NO2: m325, n56
CH3NO3: m324
CH3N5: a294
CH4: m33
CH4Cl2Si: d240
CH4N2O: f38, u16
CH4N2S: t161
CH4N4O2: n54
CH4O: m38
13
CH4O: m41
CH4O2: m279
CH4O3S: m34
CH4S: m37
CH5AsO3: m137
CH5N: m127
CH5NO3S: a201
CH5N3: g30
CH5N3S: t160
CH6ClN3O: s3
CH6N2: m274
CH6N4: a180
CH6N4O: c9
CI4: c16
CN4O8: t123
CS2: c10
CO: c11
COS: c12
C2
C2Br2ClF3: d90
C2Br2Cl4: d129
C2Br2F4: d130
C2Br2O2: o54
C2ClF3: c263
C2Cl2F4: d270b, d271
C2Cl2O2: o55
C2Cl3F3: t256, t257
C2Cl3N: t222
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
1.59
ORGANIC COMPOUNDS
top of rh
base of rh
cap height
base of text
TABLE 1.14 Empirical Formula Index of Organic Compounds (Continued)
The alphanumeric designations are keyed to Table 1.15.
C2Cl4: t38
C2Cl4F2: d411, d412, t36
C2Cl4O: t224
C2Cl6: h27
C2D3N: a30
C2D4O2: a21
C2D6OS: d698
C2F4: t65
C2F6: h42
C2F6O5S2: t309
C2HBrClF3: b308
C2HBr2F3: d133
C2HBr2N: d77
C2HBr3: t203
C2HBr3O: t199
C2HBr3O2: t200
C2HClF2: c100a
C2HClF2O2: c98
C2HCl3: t235
C2HCl3O: d186, t218
C2HCl3O2: t219
C2HCl5: p7
C2HF3O2: t300
C2H2: a41
C2H2BrClO: b255
C2H2Br2: d99, d100
C2H2Br2F2: d92
C2H2Br2O: b254
C2H2Br2O2: d76
C2H2Br4: t16
C2H2ClF3: c262
C2H2ClN: c30
C2H2Cl2: d227, d228, d229
C2H2Cl2O: c34
C2H2Cl2O2: d182
C2H2Cl3NO: t217
C2H2Cl4: t36a, t37
C2H2F2: d408
C2H2F3NO: t299
C2H2F4: t64
C2H2N2S3: d488
C2H2O: k1
C2H2O2: g28
C2H2O3: g29
C2H2O4: o52, o53
C2H3Br: b336
C2H3BrO: a35
C2H3BrO2: b249
C2H3Br2Cl3Si: d101
C2H3Br3O: t202
C2H3Cl: c129
C2H3ClF2: c100
C2H3ClO: a37, c23a
C2H3ClO2: c27, m194
C2H3Cl3: t231, t232
C2H3Cl3O: t233
C2H3Cl3Si: t258
C2H3DO2: a20
C2H3FO: a43
C2H3FO2: f5
C2H3F3O: t305
C2H3F3O3S: m453
C2H3IO: a48
C2H3IO2: i21
C2H3N: a29
C2H3NO: m288
C2H3NS: m294, m440
C2H3N3: t197
C2H3N3S2: a284
C2H4: e131
C2H4BrCl: b303
C2H4BrNO: b247
C2H4Br2: d96, d97
C2H4ClNO: c24
C2H4ClO: b165a
C2H4Cl2: d225, d226
C2H4Cl2O: d237
C2H4Cl6Si2: b227
C2H4F2: d407
C2H4INO: i20
C2H4I2: d451
C2H4N2: a109
C2H4N2O2: o58
C2H4N2S2: d795
C2H4N4: a289, d281
C2H4N4O2: a314
C2H4O: e147
C2H4OS: t147
C2H4O2: a19, h87, m257
C2H4O2S: m16
C2H4O3: h88, p60
C2H4O5S: s26
C2H4S: e148
C2H5AlCl2: e61
C2H5Br: b329
C2H5BrNaO2S: b330
C2H5BrO: b331, b369
C2H5Cl: c121
C2H5ClHg: e198
C2H5ClO: c122, c156, c173
C2H5ClS: c174
C2H5Cl2OPS: e124
C2H5Cl2O2P: e123
C2H5Cl3Si: c171, e269, t236
C2H5DO: e28
C2H5F: f17
C2H5I: i31
C2H5IO: i32
C2H5N: e146
C2H5NO: a5, a6, m255, m291
C2H5NO2: e225, g26, m187,
n52
C2H5NO3: e224
C2H5NS: t138
C2H5N3O2: b238, o57
C2H6: e20
C2H6AlCl: d533
C2H6BrN: b333
C2H6Cd: d578
C2H6ClN: c126
C2H6ClNO2S: d692
C2H6ClO2PS: d582
C2H6Cl2Si: d222
C2H6Hg: d631
C2H6N2: a8
C2H6N2O: m460, n78
C2H6N2O2: m275
C2H6N2S: m444
C2H6N4O: o56
C2H6O: d603, e27
C2H6OS: d697, m20
C2H6O2: e21a, e135
C2H6O2S: d696
C2H6O3S: d695, e25, m301
C2H6O4S: d693
C2H6O5S2: m35
C2H6S: d694, e26a
C2H6S2: d600, e24
C2H6Te: d700
C2H6Zn: d709
C2H7AsO2: d560
C2H7ClSi: c111
C2H7N: d534, e63
C2H7NO: a162, a163, e29
C2H7NO3S: a160
C2H7NO4S: a169
C2H7NS: a161
C2H7N5: b137
C2H7O3P: d625
C2H8N2: d623, d624, e21, e133
C2H8N2O: h125
C2H9BD: b243
C2H10BN: b242
C3
C3Br2F5: d105
C3Cl3N3: t255
C3Cl3N3O3: t239
C3Cl6: h30
C3Cl6O: a27, h2
C3F6: h44
C3HCl5O: p5
C3H2ClN: c35
C3H2Cl2O2: m6
short
standard
long
DEAN #37261
LEFT
(McGHP)
1.60
INTERACTIVE
top of rh
base of rh
SECTION 1
cap height
base of text
TABLE 1.14 Empirical Formula Index of Organic Compounds (Continued)
The alphanumeric designations are keyed to Table 1.15.
C3H2Cl4O: t31
C3H2Cl4O2: t234
C3H2F6O: h43
C3H2N2: m5
C3H2O2: p248
C3H3Br: b415
C3H3Br2N: d126
C3H3Cl: c241
C3H3ClO: a63a
C3H3Cl3O: e18, t221
C3H3Cl3O2: m449
C3H3F3O: t302
C3H3F3O2: m452
C3H3N: a63
C3H3NOS2: r7
C3H3NO2: c320
C3H3NS: t136
C3H3N3O2S: a244
C3H3N3O3: a289, c332
C3H4: a72, p246
C3H4BrClO: b410, b411
C3H4BrN: b408
C3H4Br2: d124
C3H4Br2O: b409
C3H4Br2O2: d125
C3H4ClN: c233
C3H4Cl2: d265, d266
C3H4Cl2O: c235, c236, d183,
d184
C3H4Cl2O2: m227
C3H4F4O: t66
C3H4N2: i3, m241, p254
C3H4N2O: c287
C3H4N2O2: h84
C3H4N2S: a285
C3H4N3NaS: c326
C3H4O: p203, p249
C3H4O2: a62, o64
C3H4O3: e132, o65, p210
C3H4O4: m3
C3H5Br: b314, b404, b405
C3H5BrO: b328, b403
C3H5BrO2: b406, b407, m143
C3H5Br3: t206
C3H5Cl: c236a
C3H5ClO: c120, c232, p216
C3H5ClO2: c228, c229, e109,
m188
C3H5Cl3: t247
C3H5Cl3Si: a98
C3H5F3O3S: m453
C3H5I: a87, i50
C3H5N: p215
C3H5NO: c323, h172, h173,
v11
C3H5NO2: o59
C3H5NS: e193, m435
C3H5NS2: m26
C3H5N3O: c321
C3H5N3O9: g22
C3H5N3S: c293
C3H6: c406, p204
C3H6BrCl: b307
C3H6BrNO3: b381
C3H6Br2: d120, d121
C3H6Br2O: d122, d123
C3H6ClI: c155
C3H6ClNO: d578
C3H6Cl2: d262, d263
C3H6Cl2N2O2: d173
C3H6Cl2O: d231, d264
C3H6Cl2Si: d241
C3H6Cl4Si: t230
C3H6I2: d454
C3H6NO: a61
C3H6N2: d583
C3H6N2O: i5
C3H6N2O3: m4
C3H6N2OS: a58
C3H6N2O2: m4, m270
C3H6N2S: a286, i4
C3H6O: a26, a78, e15, m462,
p211, p232
C3H6OS: t159
C3H6O2: d734, e16, e154, h90,
m122, p213
C3H6O2S: m22, m23, m298
C3H6O3: d445, d580, L1, L2,
m43, m265, t407
C3H6O3S: p197
C3H6S: p205, p233
C3H6S3: t450
C3H7Br: b400, b401
C3H7BrO: b402
C3H7Cl: c172, c225, c226
C3H7ClO: c132, c153, c230,
c231
C3H7ClOS: c156
C3H7ClO2: c227
C3H7ClO2S: p196
C3H7Cl2OP: p241
C3H7Cl3Si: d214, p242
C3H7I: i48, i49
C3H7N: a76, p231
C3H7NO: a28, d606, m120,
p212
C3H7NO2: a68, a69, a70, e102,
i125, m264, n73, n74
C3H7NO2S: c411
C3H7NO3: i124, n75, p238, s4
C3H7NS: d704
C3H8: p188
C3H8BrClSi: b366
C3H8ClN: c225
C3H8Cl2Si: c88, d232
C3H8N2O: d708, e274
C3H8N2O2: e103
C3H8N2S: d705
C3H8O: e10, e210, p201, p202
C3H8OS2: d485, m315
C3H8O2: d507, m71, p191,
p192
C3H8O2S: m21
C3H8O3: g19
C3H8S: e221, p198, p199
C3H8S2: p195
C3H9Al: t352
C3H9BO3: t338
C3H9B3O6: t339
C3H9BrGe: b437
C3H9BrSi: b438
C3H9ClGe: c265
C3H9ClSi: c266
C3H9IOS: t400
C3H9IS: t399
C3H9ISi: i56
C3H9N: i100, p223, t354
C3H9NO: a263, a264, a265,
a266, m77, m131
C3H9NO2: a262
C3H9N3Si: a309
C3H9O3P: d635, t390
C3H9O4P: t389
C3H10N2: d54, d55, m254,
p189, p190
C3H10N2O: d56
C3H10O3Si: t343
C3H11Br2N3S: a171
C4
C4Cl6: h23
C4Cl6O3: t220
C4D6O3: a23
C4F6O3: t301
C4HBrO3: b352
C4HCl3N2: t248
C4HF7O2: h2
C4H2: b452
C4H2Br2S: d131
C4H2Cl2N2: d267
C4H2Cl2O2: f43
C4H2Cl2S: d272
C4H2F6O2: t306
C4H2O3: m2
short
standard
long
DEAN #37261
(McGHP)
RIGHT
ORGANIC COMPOUNDS
INTERACTIVE
1.61
top of rh
base of rh
cap height
base of text
TABLE 1.14 Empirical Formula Index of Organic Compounds (Continued)
The alphanumeric designations are keyed to Table 1.15.
C4H2O4: q42
C4H3IS: i52
C4H3N3O4: n88
C4H4: b489
C4H4BrNO2: b422
C4H4Br2O2: d86
C4H4Br2O4: d128
C4H4ClNO2: c247
C4H4ClO3: c28
C4H4Cl2: d213
C4H4Cl2O2: s19
C4H4Cl2O3: c25
C4H4N2: b456, p251, p256,
p277, s18
C4H4N2O2: d448, p278
C4H4N2O2S: d437
C4H4N2O3: b1
C4H4N2O5: a73
C4H4N4: d50
C4H4O: f45
C4H4O2: d483
C4H4O3: s16
C4H4O4: f42, m1
C4H4S: t151
C4H5BrO2: b283
C4H5BrO4: b421
C4H5Cl: c74, c74a, c83
C4H5ClN2O2: c184
C4H5ClO: c310, c408, m31
C4H5ClO2: a82
C4H5ClO3: c194, e232
C4H5Cl3O2: e268
C4H5N: b482, c309, c407,
m30a, p279
C4H5NO: m47, m295
C4H5NO2: m201, s17
C4H5NO2S: e39
C4H5NO3: h183
C4H5NS: a88, m432
C4H5N3: a278, i8
C4H5N3O: a194
C4H5N3OS: a187
C4H5N3O2: a152, a153, c322,
m338
C4H5N4O: d49
C4H6: b448, b449, b610a,
b610b
C4H6Br2O: b374
C4H6Br2N2O2: d95
C4H6Br2O2: d87
C4H6ClN: c86
C4H6Cl2: c89, d211, d212
C4H6Cl2O: c87
C4H6Cl2O2: m229
C4H6Cl3NSi: t250
C4H6N2: a149, m284, m285,
m286
C4H6N2O2: e121, m273
C4H6N2S: a225
C4H6N2S2: d584
C4H6N4O: d39
C4H6N4O3: a71
C4H6O: b488, c306, d421,
m27, m407
C4H6O2: b466, b483, b484,
b485, b611, b616, b617,
c307, c409, m29, m126, v5
C4H6O2S: b450
C4H6O3: a22, a24, m355, o60,
p230
C4H6O4: d652, s15
C4H6O4S: m25, t143
C4H6O5: d690, h186, h187, o67
C4H6O6: t1, t2, t3, t4
C4H7Br: b276, b277, b278
C4H7BrO2: b282, b332, b368,
b373, e83, m156
C4H7Cl: c79, c80, c81, c181,
c182, c312
C4H7ClO: b620, c78, c136, i85
C4H7ClO2: c84, c85, e105,
m196, p228
C4H7Cl3O: t241
C4H7FO2: e153
C4H7N: b618, i83
C4H7NO: h153, i115, m28,
m99a, m352, p236, p285
C4H7NO2: b467, h146, m351
C4H7NO3: a46, e233, s13
C4H7NO4: a304, i7
C4H7NS: m434
C4H7N3O: c302
C4H8: b477, b478, b479, c333,
m399
C4H8BrCl: b298, b306
C4H8Br2: d81, d82, d83, d84
C4H8Br2O: b148
C4H8Br2O2: d85
C4H8Cl2: d210
C4H8Cl2O: b163, d230
C4H8I2: d450
C4H8N2: d535
C4H8N2O: a102
C4H8N2O2: d610, s14
C4H8N2O3: a313, g27
C4H8N2S: a97, t85
C4H8O: b475, b486, b487,
b612, c311, e3, e276,
i79, m106, m389, m400,
t69
C4H8O2: b480, b481, b614,
d732, d733, e57, h107,
h108, i81. m64, m401,
p234
C4H8O2S: e196, m299, t107
C4H8O3: e24, e153, h120,
h138, m70, m296, m302
C4H8S: a90, t87
C4H8S2: d792
C4H9Br: b274, b275, b371,
b372
C4H9BrO: b337
C4H9BrO2: b319
C4H9Cl: c75, c76, c179, c180
C4H9ClO: a64, c77, c131, m74
C4H9ClO2: c105, c123, m67
C4H9ClSi: c112
C4H9Cl3Si: b604, b603, d215
C4H9Cl3Sn: b600
C4H9F: f21
C4H9I: i26, i27, i38, i39
C4H9N: e53, p280
C4H9NO: a311, b476, b613,
d526, i80, m110, m463
C4H9NO2: a133, a133a, a134,
b578, b579, h119, i73, n48
C4H9NO2S: a200
C4H9NO3: a185, a186, i72,
m341, n49
C4H9NO5: t442
C4H9NSi: c331
C4H9N3O2: c301
C4H10: b454, m390
C4H10AlCl: d320, e62
C4H10ClO2PS: d351
C4H10ClO3P: d350
C4H10Cl2Si: b165
C4H10Cl4Si2: b174
C4H10N2: p178
C4H10N2O: a227
C4H10N2O4S: a8
C4H10O: b473, b474, d365,
m397, m398, m404
C4H10OS: e180
C4H10OS2: b208
C4H10O2: b457, b457a, b457b,
b458, b563, d504, d505,
e40, e141, m105, m393
C4H10O2S: t144
C4H10O2S2: d484, h123
C4H10O3: b198, b472, d361,
o62, t378
C4H10O3S: d399
C4H10O4: e19
C4H10O4S: d397
short
standard
long
DEAN #37261
LEFT
(McGHP)
1.62
INTERACTIVE
top of rh
base of rh
SECTION 1
cap height
base of text
TABLE 1.14 Empirical Formula Index of Organic Compounds (Continued)
The alphanumeric designations are keyed to Table 1.15.
C4H10S: b470, b471, d398, i104,
m394, m395, m396, m406
C4H10S2: b468, d356
C4H10S3: b209
C4H10Zn: d405
C4H11ClSi: c183
C4H11N: b453, b509, b510,
b511, d323, d604, i66, m293
C4H11NO: a135, a164, a203,
a216, d376, d539, e44, e67,
m112
C4H11NO2: a215, d297, d506
C4H11NO3: t439
C4H11OP: d390
C4H11O2PS2: d358
C4H11O3P: d375
C4H12BrN: t93
C4H12ClN: d324, t94
C4H12Ge: t109
C4H12IN: t95
C4H12N2: b455, b560, b562,
d41, d605, m391, m392
C4H12N2O: a165
C4H12N2S4: b183
C4H12OSi: m119
C4H12O2Si: d502
C4H12O3Si: m455
C4H12Pb: t112
C4H12Si: t118
C4H12Sn: t121
C4H13N3: d362
C4H14BN: b239
C4H14OSi2: t106
C4H16O4Si4: t104
C5
C5Cl5N: p10
C5Cl6: h25
C5D5N: p258
C5H3BrS: b426, b427
C5H3Br2N: d127
C5H3ClOS: t153
C5H3ClO2: f55
C5H3ClS: c251
C5H3Cl2N: d268, d269
C5H3N3: p252
C5H4BrN: b416, b417
C5H4ClN: c242
C5H4FN: f26
C5H4F8O: o20
C5H4N2O2: p253
C5H4N2O3: n76
C5H4N4O3: u17
C5H4OS: t154
C5H4O2: f44
C5H4O2S: t155
C5H4O3: c285, f54
C5H5ClN2: a148
C5H5ClN2O2: c168
C5H5N: p257
C5H5NO: h179, h180, h181,
p271
C5H5NO2: d448, h183
C5H5N3O2: a243
C5H5N3O4: a158
C5H5N5: a61
C5H6: c395, m174
C5H6BrClN2O2: b302
C5H6Br2N2O2: d76
C5H6Cl2NO2: d220
C5H6Cl2O2: g18
C5H6N2: a275, a276, a277,
g17, m408, v12
C5H6N2O: a47, a193
C5H6N2OS: h140, h141
C5H6O: m259
C5H6OS: f48, m443
C5H6O2: f50
C5H6O3: g15, h156
C5H6O4: c284, m253
C5H6O4S3: b156
C5H6S: m441, m442
C5H7BN: b244
C5H7BrO3: e91
C5H7ClO2: c205, d581
C5H7ClO3: m189, m190, m195
C5H7N: m417, p51, p52
C5H7NO: e31, f51
C5H7NO2: c324, e115
C5H7N3: a224, d58
C5H7N3O: a188
C5H8: c401, d424, m157,
m178, p15, p16, p17, p18,
p58
C5H8Br2O2: e122
C5H8N2: d626, d684, e191,
p283
C5H8N2O2: d622
C5H8N4O12: p22
C5H8O: c399, c410, d364, e6,
m179
C5H8O2: a74, c334, d532, e60,
g16, i95, m65, m168, m169,
m170, m200, m225, m300,
p33, p34, p207, v2, v3, v10,
v14
C5H8O3: e237, h121, m123,
o63
C5H8O4: d547, g14, m278
C5H9Br: b313, b365
C5H9BrO2: b364, e93, e94,
m155
C5H9Cl: c93
C5H9ClO: c206, d681, m186,
p45, t75, t351
C5H9ClOS: c238
C5H9ClO2: b538, c237, e110,
e111, i68, i107, m193
C5H9N: d683, m185, p35
C5H9NO: b565, b566, c400,
d531, e53, e234, m419,
m461
C5H9NO2: d523, f39, m130,
p187
C5H9NO4: g12
C5H10: c396, m165a, m166,
m167, p48, p49, p50
C5H10Br2: d117, d118
C5H10ClNO: d348
C5H10Cl2: d209
C5H10Cl2: d251
C5H10I2: d453
C5H10NO3P: d293a
C5H10N2: d548
C5H10N2O: d627
C5H10N2O3: g13
C5H10N2O4S2: c412
C5H10O: a85, c398, d653,
d677, e252, m165, m171,
m172, m173, m180, m181,
m429, p28, p42, p43, t83
C5H10OS: m439
C5H10O2: b557, c398, d521,
d679, e252, h147, h164, i69,
i99, m86, m182, m183,
m184, m237, m290, m353,
p38, p222, t71, t349
C5H10O2S: e197, e222, m316,
m431
C5H10O3: d349, d520, e194,
m75, m282, m307
C5H10O4: b201, m72
C5H10O5: a300, r9, x8
C5H11Br: b362, b363, b387,
b388
C5H11BrO: b322
C5H11BrO2: b320
C5H11Br2O: b148
C5H11Br2O2: b150
C5H11Cl: c109, c150, c169a,
c170, c204a
C5H11ClO: c110
C5H11Cl2N: b164
C5H11I: i47
short
standard
long
DEAN #37261
(McGHP)
RIGHT
ORGANIC COMPOUNDS
INTERACTIVE
1.63
top of rh
base of rh
cap height
base of text
TABLE 1.14 Empirical Formula Index of Organic Compounds (Continued)
The alphanumeric designations are keyed to Table 1.15.
C5H11N: a85, c404, m418,
p180
C5H11NO: b558, d369, d678,
m317, t72
C5H11NO2: a248, a249, b133,
b532, e275, i92, m310a, v4
C5H11NO2S: m42
C5H11NO3: n58
C5H11NS2: d357
C5H11O5P: t391
C5H12: d673, m155, p29
C5H12Cl2O2Si: b162
C5H12N2: a261, m381, m382
C5H12N2O: b608, d702, t122
C5H12N2O2: b533, o46
C5H12N2S: t119
C5H12N2S2: p282
C5H12O: b572, d676, e254,
m161, m162, m163, m164,
p31, p32, p39, p40, p41
C5H12O2: b504, d307, d518,
d519, d675, i97, m64, p218
C5H12O2Si: d509, t395, v18
C5H12O3: m73, t340, t377, t440
C5H12O3S: p36
C5H12O4: p19
C5H12O5: x7
C5H12S: b577, e255, m159,
m160, p37
C5H12Si: t401
C5H13ClOSi: c125
C5H13N: a246, a247, d380,
d628, d682, m175, m176,
p54
C5H13NO: a209, a250, d546,
d547, e54, p224
C5H13NOSi: t394
C5H13NO2: a176, d508, d545,
d607, m230
C5H13N3: t110
C5H14ClN3O: g5
C5H14N2: d549, d674, p30,
t105, t113
C5H14N2O: a150, a166
C5H14O: b560, b561
C5H14OSi: e56
C5H15NSi: d707
C5H15N3: a175
C6
C6BrD5: b263
C6BrF5: b386
C6Cl4O2: t34, t35
C6Cl5NO2: p8
C6Cl6: h22
C6D6: b11
C6D12: c348
C6F6: h41
C6F14: t42
C6HBr5O: p4
C6HCl4NO2: t39
C6HCl5: p6
C6HCl5O: p9
C6H2BrFN2O4: b324
C6H2Br4: t14
C6H2Cl3NO2: t243
C6H2Cl4: t32, t33
C6H3Br2F: d103, d104
C6H3Br2NO2: d115
C6H3Br3O: t211
C6H3ClFNO2: c141
C6H3ClF2: c99
C6H3ClN2O4: c114, c115
C6H3ClN2O4S: d712
C6H3Cl2NO2: d245, d246,
d247, d248
C6H3Cl2NO3: d249
C6H3Cl3: t227, t228, t229
C6H3Cl3O: t244, t245
C6H3Cl3O2S: d201
C6H3D3: b9
C6H3FN2O4: d718
C6H3F2NO2: d410
C6H3F3: t303
C6H3N3O6: t403, t404
C6H3N3O7: p174
C6H4BrCl: b287, b288, b296
C6H4BrClO2S: b264
C6H4BrF: b340, b341, b342
C6H4BrNO2: b378
C6H4BrN3O4: b323
C6H4Br2: d79, d112
C6H4Br2N2O2: d114
C6H4Br2O: d119
C6H4Br3N: t201
C6H4ClF: c137, c138
C6H4ClFO: c142
C6H4ClI: c154
C6H4ClNO2: c192, c193, c194
C6H4ClNO3: c201
C6H4ClNO4S: n33
C6H4Cl2: d198, d199, d200
C6H4Cl2N2O2: d244
C6H4Cl2O: d252, d253, d254,
d255
C6H4Cl2O2S: c50
C6H4Cl3N: t225, t226
C6H4FNO2: f23
C6H4F2: d406
C6H4INO2: i40, i41
C6H4I2: d449
C6H4N2: a267, c328, c329,
c330
C6H4N2O2: b43
C6H4N2O4: d711
C6H4N2O5: d720
C6H4N4O6: t402
C6H4O2: b58
C6H5BO2: c22
C6H5Br: b262
C6H5BrO: b392, b393, b394
C6H5BrS: b428
C6H5Cl: c47
C6H5ClHg: p129
C6H5ClN2O2: c188, c189, c190,
c191
C6H5ClN3O4: c113
C6H5ClO: c208, c209, c210
C6H5ClO2: c102, c103, c244
C6H5ClO2S: b24
C6H5ClO3S: c49
C6H5ClS: c252
C6H5Cl2N: d187, d188, d189,
d190, d191, d192
C6H5Cl2OP: p140
C6H5Cl2O2P: p100
C6H5Cl2P: d260
C6H5Cl3Si: p159
C6H5F: f11
C6H5FN2O2: f22
C6H5FO: f28
C6H5FO2S: b25
C6H5I: b28, i23
C6H5NO: n77, p261, p262,
p263
C6H5NOS: t148
C6H5NO2: n30, n82, p265,
p266, p267
C6H5NO3: h182, n59, n60
C6H5NO4: c288
C6H5N3: b61
C6H5N3O: h104
C6H5N3O4: d710
C6H6: b8
13
C6H6: b10
C6H6AsNO6: h162
C6H6BrN: b256, b257, b258
C6H6ClN: c38, c39, c40
C6H6ClNO: a147, c162
C6H6ClNO2S: c48
C6H6Cl6: h24
C6H6FN: f7, f8
C6H6F9O3P: t447
C6H6HgO: p130
short
standard
long
DEAN #37261
LEFT
(McGHP)
1.64
INTERACTIVE
top of rh
base of rh
SECTION 1
cap height
base of text
TABLE 1.14 Empirical Formula Index of Organic Compounds (Continued)
The alphanumeric designations are keyed to Table 1.15.
C6H6IN: i22
C6H6NO6: n20
C6H6N2O: e49, p259, p260,
p264
C6H6N2O2: n23, n24, n25
C6H6N2O3: a238, a239, a240,
m94
C6H6N4O4: d721, n53
C6H6O: p65
C6H6OS: a57, m443
C6H6O2: a44, c21, d428, d429,
d430, h86, m258, r2
C6H6O2S: b21, t152
C6H6O3: b34, m259a, t317,
t318
C6H6O3S: b23
C6H6O4: d529
C6H6O6: p206
C6H6S: t156
C6H7AsO3: b12
C6H7BO2: b13
C6H7ClN2: c216, c217
C6H7N: a293, a294, m409,
m410, m411
C6H7NO: a252, a253, a254,
h155, m113, p273, p274
C6H7NO2: m414
C6H7NO2S: b22
C6H7NO3S: a115, a116, a117,
s25
C6H7NS: a287
C6H7N3O2: n65, n66, n67
C6H7O2P: p138
C6H7O3P: p139
C6H8AsNO3: a113
C6H8Br2O2: d107
C6H8Br3O: t205
C6H8ClN3O4S2: a137
C6H8Cl2O2: m228
C6H8N2: a218, a219, a220,
a221, a222, a223, d284,
m263, p104, p105, p106,
p117
C6H8N2O: a204, o69
C6H8N2O2S: b26, s24
C6H8N2O3: d561a
C6H8O: c371, d609, d620, h38
C6H8O2: b451, c360, h40,
m223
C6H8O3: a36, a311, d599, f47
C6H8O4: d598, d608, d629,
d630
C6H8O6: a302, g11, i61
C6H8O7: c289
C6H9Br: b312
C6H9BrO3: b285
C6H9ClO3: e106, e107
C6H9F3O2: b605
C6H9NO: o62, v17
C6H9NOS: m433
C6H9NO2: b540
C6H9NO3: m78, n49
C6H9N3: a156
C6H9N3O2: a157, c317, h83
C6H10: c368, d566, h39, h82,
m356
C6H10Br2: d89
C6H10N2: e211, i114, p181
C6H10N2O2: c361
C6H10N2O4: d338
C6H10N2O5: a14
C6H10N4: p27
C6H10O: c366, c370, d31,
d362, e12, h77, m224,
m368, m370, m372
C6H10O2: a91, c397, d422,
e114, e119, e142, e199, h60,
h69, h74, h75, m369
C6H10O3: d501, e58, e143,
h126, h177, m402, p214
C6H10O4: d385, d634, d691,
e22, e137, h54, m276,
m303
C6H10O4S: t146
C6H10O4S2: d794, e136
C6H10O5: d386
C6H10O6: d699, g7
C6H10S: d34
C6H11Br: b311
C6H11BrO: b424
C6H11BrO2: b279, b347, b529,
e85, e86, e89
C6H11BrO4: d346
C6H11Cl: c91
C6H11ClO: h72
C6H11ClO2: b535, c82, e98
C6H11I: i28
C6H11N: d30, h61, m361
C6H11NO: c367, e260, f40,
m388, o61, t379
C6H11NO2: e66
C6H12: c347, d572a, d573,
d574, e95a, h73, m222
C6H12Br2: d94, d106
C6H12ClNO: c133
C6H12Cl2: d217, d219, d234
C6H12Cl2O: b166
C6H12Cl2O2: b161, d169
C6H12Cl3O3P: t437
C6H12Cl3O4P: t436
C6H12F3NOSi: m457
C6H12NO3P: d294
C6H12N2: d61, d325, t279
C6H12N2S: b183, t119
C6H12N2S4: t120
C6H12N2Si: t396
C6H12N2Zn: d601
C6H12N4: h49
C6H12O: a96, b609, c365,
d572, e11, e98, h51, h70,
h71, h76, i78, m367, m430
C6H12O2: b465, b501, b502,
b503, c359, d576, d577, e99,
e100, e192, e209, e213, h64,
h150, i63, m235, m312,
m362, m363, m456, p244,
t84
C6H12O3: d525, e42, e179,
e182, i116, p2, p237, t70
C6H12O4: e149
C6H12O4Si: d27
C6H12O6: f41, g1, g8, i19, m11,
s6
C6H12O7: g6
C6H12S: c364
C6H13Br: b346
C6H13BrO2: b317
C6H13Cl: c149
C6H13ClO: c150
C6H13ClO2: c96
C6H13ClO3: c124
C6H13I: i36
C6H13N: c375, e202, h48,
m383, m384, m385, m386
C6H13NO: d314, d637, e223,
h133, h152
C6H13NO2: a182, a183, h127,
i88, L5, L6, m233
C6H13NO4: b199
C6H13NO5: t441
C6H14: d567, d568, h52, m357,
m358
C6H14ClN: d328
C6H14Cl4OSi2: b175
C6H14NO2: b213
C6H14N2: a214, c354, d43, d44,
d671, e245
C6H14N2O: a172, h129
C6H14N2O2: L13
C6H14N4O2: a301
C6H14O: b554, d476, d570,
d570a, d571, d786, e95, h66,
h67, h68, m364, m365,
m366
C6H14OSi: a93
short
standard
long
DEAN #37261
(McGHP)
RIGHT
ORGANIC COMPOUNDS
INTERACTIVE
1.65
top of rh
base of rh
cap height
base of text
TABLE 1.14 Empirical Formula Index of Organic Compounds (Continued)
The alphanumeric designations are keyed to Table 1.15.
C6H14O2: b493, d303, d304,
d569, e138, e219, h55, h56,
h57, m82, m360, p220
C6H14O2S: d789
C6H14O3: b204, b214, d305,
d779, e41, e183, h63, h176,
t321, t341
C6H14O4: t280
C6H14O4S: d788
C6H14O4S2: b459
C6H14O6: d824, m10, s5
C6H14O6S2: b210
C6H14S: b557, h62
C6H14Si: a101
C6H15Al: t273
C6H15AlI: d322
C6H15AlO: d321
C6H15As: t276
C6H15B: t277
C6H15ClGe: c260
C6H15ClO3Si: c240
C6H15ClSi: b551, c261
C6H15Ga: t286
C6H15In: t288
C6H15N: d468, d575, d777,
e97, h81, m371, t274
C6H15NO: a184, a211, a212,
b513, b553, d327, d364,
i98
C6H15NO2: d306, d540, e125
C6H15NO3: t266
C6H15N3: a174
C6H15O3B: t268
C6H15O3P: d480, t294
C6H15O3PS: t298
C6H15O4P: t292
C6H15P: t293
C6H15Sb: t275
C6H16Br2OSi2: b149
C6H16Cl2OSi2: b167
C6H16N2: d367, h53, m359,
t108
C6H16OSi: p221
C6H16O2Si: d301
C6H16O3SSi: m24
C6H16O3Si: t269, t342
C6H16Si: t297
C6H17NO3Si: a274, t344
C6H17N3: i9
C6H18ClN3Si: c268a
C6H18N2Si: b179
C6H18N3OP: h50
C6H18N4: t285, t434
C6H18OSi2: h47
C6H18O3Si3: h45
C6H19NOSi2: b233
C6H19NSi2: h46
C7
C7H3BrClF3: b297
C7H3BrF3NO: b380
C7H3ClF3NO2: c199, c200
C7H3ClN2O5: d714
C7H3Cl2F3: d206, d207
C7H3Cl2NO: d259
C7H3Cl3O: d208, d209
C7H4BrF3: b268, b269
C7H4Br4O: t15
C7H4ClFO: f14, f15
C7H4ClF3: c60, c61, c62
C7H4ClN: c54, c55
C7H4ClNO: c219, c220
C7H4ClNO3: n39, n40
C7H4ClNO4: c195, c196, c197
C7H4Cl2O: c64, c65, d194,
d195
C7H4Cl2O2: d202, d203, d204
C7H4Cl3F: t238
C7H4Cl4: c58, c59
C7H4F3NO2: n86, n87
C7H4I2O3: h113
C7H4N2O2: n38
C7H4N2O6: d713
C7H4N2O7: d722, h114
C7H4O3S: h105
C7H4O4S: s27
C7H5BrO: b65
C7H5BrO2: b266, b265
C7H5BrO3: b419
C7H5ClF3N: a142, a143
C7H5ClO: b66, c43, c44, c45
C7H5ClO2: c51, c52, c53, p99
C7H5ClO3: c207, c245, c246
C7H5Cl2F: c139
C7H5Cl2NO: d196, d197
C7H5Cl3: t251, t252, t253, t254
C7H5FO: b68, f9, f10
C7H5FO2: f12, f13
C7H5F3: t311
C7H5F3N2O2: a237
C7H5F3O: t304
C7H5F4N: a179
C7H5IO2: i25
C7H5IO3: i51
C7H5I2NO2: a154
C7H5N: b51
C7H5NO: b62, p124
C7H5NO3: n26, n27
C7H5NO3S: s1
C7H5NO4: n35, n36, n37, p268,
p269, p270
C7H5NO5: h163
C7H5NS: b59, p125
C7H5NS2: m17, m19
C7H5N3O2: a234, n34, n55
C7H5N3O2S: a236
C7H5N3O6: t405
C7H6BrClO: b300
C7H6BrNO2: n44
C7H6BrNO3: h156
C7H6Br2: b271, d132
C7H6Br2O: d111
C7H6ClF: c143, c144, f16
C7H6ClNO: c46
C7H6ClNO2: a138, a139, c202,
c203, n45
C7H6Cl2: c69, c70, d273, d274,
d275, d276
C7H6F3N: a126, a127, a128,
t310
C7H6FNO2: f24
C7H6INO2: a199
C7H6N2: a121, a122, a123, b39
C7H6N2O3: n28, n29
C7H6N2O4: a233, d723, d724
C7H6N2O5: d715, d716
C7H6N2S: a125
C7H6N4O2: t134
C7H6O: b3
C7H6OS: t139
C7H6O2: b44, h94, h95, h96,
m251
C7H6O2S: m18
C7H6O3: d427, f46, h99, h100,
h101
C7H6O4: d431, d432, d433,
d434
C7H6O5: t319
C7H6O6S: s31
C7H7Br: b85, b429, b430,
b431
C7H7BrO: b259, b260, b270,
b357, b358, b359
C7H7BrS: b425
C7H7Cl: b90, c255, c256, c257
C7H7ClNNaO2S: c258
C7H7ClN4O2: c253
C7H7ClO: c66, c160, c176,
c177
C7H7ClO2S: t177
C7H7ClO3S: m56
short
standard
long
DEAN #37261
LEFT
(McGHP)
1.66
INTERACTIVE
top of rh
base of rh
SECTION 1
cap height
base of text
TABLE 1.14 Empirical Formula Index of Organic Compounds (Continued)
The alphanumeric designations are keyed to Table 1.15.
C7H7ClS: c73
C7H7Cl3Si: b128
C7H7F: f27, f28, f29
C7H7FO: f19, f20
C7H7FO2S: t178
C7H7I: i53, i54, i55
C7H7N: v15, v16
C7H7NO: a53, a54, a55, b4,
f35
C7H7NO2: a118, a119, a120,
h97, h98, m412, m413, n83,
n84, n85
C7H7NO3: a280, a281, m92,
m339, m340, n41, n42, n43
C7H7NO4S: c17
C7H7N3: a197, a198
C7H8: b134, c344, t166
C7H8BrN: b360
C7H8ClN: c37, c67, c68, c163,
c164, c165, c166, c167
C7H8ClNO: c158, c159
C7H8ClNO2: c19
C7H8ClNO2S: c248
C7H8Cl2Si: d239
C7H8N2: h102
C7H8N2O: a112, b71, p167
C7H8N2O2: d40, h149, h170,
m326, m327, m328, m329,
m330, m415
C8H8N2O3: m89, m90, m91
C7H8N2S: p158
C7H8N4O2: t133
C7H8O: b78, c303, c304, c305,
m55
C7H8O2: d438, h106, m97,
m98, m99, m280
C7H8O2S: t172
C7H8O3: e155, f49, m314
C7H8O3S: m139, t176
C7H8S: b106, m379, t142
C7H9BrO2: e84
C7H9N: b79, d685, d686, d687,
d688, d689, e256, e257,
e258, m134, t180, t181, t182
C7H9NO: a213, b101, h132,
m48, m49, m50
C7H9NO2: d524
C7H9NO2S: t173, t174
C7H9NO3S: a205, a206, a288
C7H9NS: m436
C7H10: b135
C7H10ClN3O: g4
C7H10N2: a177, a178, d59, d60,
d287, d551, t167, t168, t169,
t170
C7H10N2O: o66
C7H10N2O2: e212, m242
C7H10N2O2S: t175
C7H10O: d294, m67, n108, t67
C7H10O2: a40, c402
C7H10O3: e17, e144, m354,
t367
C7H10O4: d29, d596, p208
C7H10O5: d528
C7H11Br: b383
C7H11BrO4: d346
C7H11ClO: c351
C7H11N: c350
C7H11NO: c381, h112
C7H11NO2: a52, b539
C7H11NO3: m83
C7H11NO5: a45
C7H11NS: c382
C7H12: c345, h20, m215, m216,
n107
C7H12N2O: m464
C7H12O: b506, c348, c352,
c369, m212, m213, m214
C7H12O2: a80, b507a, b508,
c353, d420, e126, i65
C7H12O3: e43, e201, e226,
h178, t73
C7H12O4: d378, d379, d636,
d656, h7, m76, m277,
t125
C7H12O6Si: m448
C7H13Br: b310, b367
C7H13BrO2: b390, e92
C7H13ClO: h17
C7H13N: a245
C7H13NO: a307, b507, c380
C7H13NO2: d541
C7H13NO3: d418
C7H14: c341, e118a, h18, h18a,
h18b, m202
C7H14ClN: c134
C7H14N2: d475
C7H14N2O: a272
C7H14N2O2: e246
C7H14O: c342, c384, d655,
d658, h3, h14, h15, h16,
m205, m206, m207, m208,
m209, m210, m211, m271
C7H14O2: b559, b593, b594,
d312, e128, e207, e208,
e239, h9, i74, i91, i106,
m270, p53, p228
C7H14O2S: b569
C7H14O3: b567, e130, e151
C7H14O6: m262
C7H15Br: b343, b344
C7H15Cl: c147
C7H15ClO2: c97
C7H15I: i34
C7H15N: c362, d672, e247,
e248, m218, m219, m220
C7H15NO: e186, h131, h134,
m387, p182, p183
C7H15NO2: p286
C7H15NO3: m467
C7H15O5P: t296
C7H16: d654, e238, h6, t361
C7H16BrNO2: a38
C7H16ClNO2: a39
C7H16N2: a210, a271, m308,
t392
C7H16N2S: d482
C7H16O: d657, h10, h11, h12,
t362
C7H16O2: b498, b499, d311,
d393, m405
C7H16O2Si: d310
C7H16O3: d784, t290
C7H16O4: t92, t284
C7H16S: h8
C7H17N: h19, m272
C7H17NO: b500, d332, d333
C7H17NO2: b515, d331
C7H17NO5: m261
C7H18N2: d334, d392, t116
C7H18N2O: b180
C7H18N2O2: a270
C7H18N2O4Si: t348
C7H18O2Si: b607
C7H18O3Si: b606, i77, m451
C7H19NOSi2: b232
C7H19NSi: d404
C7H19N3: d52
C7H20N2OSi2: b236
C7H22O4Si3: h5
C8
C8Br4O3: t17
C8Cl4O3: t40
C8D10: e73
C8F18O2S: p59
C8HCl4NO2: t39
C8H3NO5: n72
C8H4BrNO2: b348
C8H4Cl2O2: b15, b16, p172
C8H4Cl2O4: d261
C8H4Cl6: b225
C8H4F6: b229
C8H4N2: d282, d283
short
standard
long
DEAN #37261
(McGHP)
RIGHT
ORGANIC COMPOUNDS
INTERACTIVE
1.67
top of rh
base of rh
cap height
base of text
TABLE 1.14 Empirical Formula Index of Organic Compounds (Continued)
The alphanumeric designations are keyed to Table 1.15.
C8H4N2O2: p107
C8H4O3: p169
C8H5BrN: b272
C8H5ClO2: c224
C8H5Cl3O: t223
C8H5Cl3O3: t246
C8H5D3O: a32
C8H5F3O2S: t132
C8H5F6N: b228
C8H5NO: b67
C8H5NO2: i17, p171
C8H5NO3: h171, i60
C8H5NO6: n31, n32, n70, n71
C8H6: p84
C8H6BrClO: b286
C8H6BrN: b397
C8H6Br2O: d78
C8H6Br4: t18, t19, t20
C8H6ClN: c71, c72, c215
C8H6ClNO3: c187
C8H6Cl2O: c168, d185
C8H6Cl2O3: d256
C8H6N2: q4
C8H6N2O: q5
C8H6N2O2: n64
C8H6O: b42
C8H6O2: b14, p170, t6
C8H6O3: b69, f37, m250
C8H6O4: b17, b18, p168
C8H6S: b60
C8H7Br: b420
C8H7BrO: b251, b253
C8H7BrO2: b356, b396
C8H7BrO3: b355
C8H7ClO: c31, c32, c33, p83,
t187, t188, t189
C8H7ClOS: b92
C8H7ClO2: b91, c214, m60,
m191, m192, p69
C8H7ClO3: c161, c211
C8H7FO: f6
C8H7N: i15, p82, t183, t184,
t185
C8H7NO: m9, m147, t192
C8H7NS2: m438
C8H7NO3: n21, n22
C8H7NO3S: t179
C8H7NO4: a114, m331, m332,
m333, m334, m335, m336,
m337, n61, n62, n63
C8H7NO5: m93
C8H7NS: b126, m146
C8H7N3O2: a151
C8H8: s11
C8H8BrNO: b248
C8H8Br2: d98, d134, d135
C8H8ClNO: c25, c26, c26a
C8H8ClNO3: a146
C8H8ClNO3S: a10
C8H8Cl2: d277, d278, d279
C8H8HgO: p128
C8H8N2: a255, m140
C8H8O: a31, e9, m138, p77, s12
C8H8OS: m437
C8H8O2: b41, b99, h91, h92,
h93, m51, m52, m53, m141,
m142, m143, m144, p80,
p81
C8H8O2S: p156, t157
C8H8O3: d425, h142, h165, m8,
m57, m58, m59, m281,
m424, p68, r4, t81
C8H8O4: d25, h143
C8H8O4S: a33
C8H8O5: m454
C8H9Br: b334a, b335, b443,
b444, b445, b446
C8H9BrO: b321, b338, b361
C8H9BrO2: b318
C8H9Cl: c127, c128, c269,
c270, c271, c272, c273
C8H9ClO: c108, c218
C8H9ClO2: c104
C8H9N: b104, i18
C8H9NO: a18, a105, a106,
a107, b98, m256
C8H9NO2: a15, a16, a17, a207,
a208, b89, d638, d639,
d640, d641, e226, e259,
m54, m129, p114, t77
C8H9NO3: a202, h167, h168,
m95
C8H9NO4: d511
C8H9NO4S: m133
C8H10: e74, x4, x5, x6
C8H10ClN: c107
C8H10N2O: d642
C8H10N2O3: m85
C8H10N2O3S: m343
C8H10N4O2: c1, d286
C8H10O: b136, d659, d660,
d661, d662, d663, d664,
e36, e240, e241, e242,
m116, m117, m118, m149,
m150, p109, p110
C8H10O2: b19, d493, d494,
d495, e51, m61, m84, p72,
p108
C8H10O3: c308, c356, d512,
h118, h145, m30, m234
C8H10O3S: e75, m447
C8H10O4: d668, d669, d670
C8H10O8: b469
C8H10S: b110
C8H11N: b108, d553, d554,
d555, d556, d557, d558,
d559, e68, e69, e70, e220,
i130, m151, m152, p112,
t393
C8H11NO: a173, a251, a256,
a257, a295, d544, e32, h122,
m62, m80, m81, p101, p275,
p276
C8H11NO2: d488, d489, d490
C8H11NO2S: m446
C8H11NO3: e150
C8H12: c387, c388, v9
C8H12N2: d288, d665, t117, x9
C8H12N2O2: d461
C8H12N2O3: d339
C8H12N4: a313
C8H12O: e278
C8H12O2: d589, e262, n109
C8H12O3: e135, t74
C8H12O4: c355, d28, d370,
d377, m36
C8H12O5: d530
C8H12O6Si: t194
C8H13N: e238
C8H13NO4: m342
C8H14: c393, o19, o49, v8
C8H14N2: p185, p281
C8H14NO4: d472
C8H14O: b576, c392, d592,
d621, m217, m269, o50
C8H14O2: b464, b570, c373,
c374, c405, d620, h78, i71,
m203, n31
C8H14O3: b505, b615, e45,
e101, i64, i82
C8H14O4: b197, b460, d381,
d396, d617, e139, e177, o25
C8H14O4S: d703
C8H14O4S2: d793
C8H14O6: d400, d401
C8H15BrO2: e88
C8H15ClO: e163, o39
C8H15N: o28
C8H15NO: p243
C8H15NO2: d543, e249, e250,
p184
C8H16: c389, d585, d586, d587,
d587a, d588, e117, o40, t384
C8H16Br2: d116
C8H16N2O4S: h130
short
standard
long
DEAN #37261
LEFT
(McGHP)
1.68
INTERACTIVE
top of rh
base of rh
SECTION 1
cap height
base of text
TABLE 1.14 Empirical Formula Index of Organic Compounds (Continued)
The alphanumeric designations are keyed to Table 1.15.
C8H16O: c378, c391, d500,
d590, d591, e118, e158,
m268, o36, o37, o38, o43
C8H16O2: b531, c357, c390,
e160, e161, h79, i70, m266,
o30, p239
C8H16O3: b497, e181
C8H16O4: c313, e37, t124
C8H17Br: b385
C8H17Cl: c204
C8H17Cl3Si: o48
C8H17I: i44
C8H17N: b597, c394, d593,
d594
C8H17NO3: e173
C8H17O5P: t295
C8H18: d616a, e158a e214,
e215, o23, t100, t380, t381,
t382
C8H18AlCl: d455
C8H18ClNO2: a49
C8H18Cl2Sn: d177
C8H18F3NOSi2: b235
C8H18N2: c349
C8H18N2O4S: h130
C8H18N2O6S2: p179
C8H18O: d148, d458, e162,
m267, o32, o33, o34, o35,
o66a
C8H18OSi2: d799
C8H18OSn: d180
C8H18O2: b494, d159, d618,
e159, o26, o27, t383
C8H18O2S: d173
C8H18O3: b186, b495, t289
C8H18O3S: d172
C8H18O3Si: t272
C8H18O4: b211, t282
C8H18O4S: d169
C8H18O5: t51
C8H18S: d170, d171, o29
C8H18S2: b154, b155, d146,
d147
C8H18Si2: b231
C8H19Al: d456
C8H19N: d139, d140, d457,
d477, d619, e166, o44, t103
C8H19NO: d413
C8H19NO2: b549, d299, d300
C8H19O3P: d164
C8H20BrN: t49
C8H20ClN: t50
C8H20Ge: t58
C8H20N2: o24, t101, t102
C8H20N2O2S: t61
C8H20O3Si: e270
C8H20O4Si: t48
C8H20O4Ti: t163
C8H20Pb: t59
C8H20Si: t60
C8H20Sn: t63
C8H21NOSi2: b230
C8H21NO2Si: a269, d308
C8H22B: b241
C8H22N2O3Si: a166, t346
C8H22N4: b145
C8H22O2Si2: b234
C8H23N5: t56
C8H24Cl2O3Si4: d250
C8H24O2Si3: o22
C8H24O4Si4: o21
C8H35N: d728
C9
C9H2Cl6O3: h28
C9H3Cl3O3: b33
C9H4O5: b32
C9H5BrClNO: b304
C9H5Br2NO: d108
C9H5ClINO: c152
C9H5Cl2N: d270
C9H6BrN: b418
C9H6ClNO: c153
C9H6INO4S: h137
C9H6N2O2: t171
C9H6O2: b55, c292
C9H6O3: h111
C9H6O4: i13
C9H6O6: b29, b30, b31
C9H7BrO: b309
C9H7ClO: c280
C9H7ClO2: c90
C9H7N: i133, q3
C9H7NO: h184
C9H7NO3: h151, m289
C9H7NO4: n50
C9H7NO4S: h185
C9H7N3O4S2: a242
C9H8: i14
C9H8Cl2O3: d258
C9H8N2: m423, p120
C9H8N2O6: e129
C9H8O: c278, i12
C9H8O2: c279, d417, v6
C9H8O3: h109
C9H8O3S: p247
C9H8O4: p127
C9H9BrO: b412
C9H9BrO2: b86
C9H9Cl: v7
C9H9ClO: c234
C9H9ClO3: c213, d498
C9H9N: d564, m287
C9H9NO: m103, m104, p134
C9H9NO2: a9
C9H9NO3: a11, a12, b70
C9H9NO4: e227
C9H9N3O: a260
C9H9N3O2S2: t137
C9H9N5: d53
C9H10: a78, i10, m425, m426
C9H10Br2: d109
C9H10F3NO2: m135
C9H10N: a196, a197
C9H10N2: a296, p121
C9H10N2O: p151
C9H10N2O2: p85
C9H10N2O3: a129
C9H10O: a94, a95, c282, e14,
e72, i11, m124, p147, p148,
p149, p209, p217
C9H10O2: b63, b76, d563, e33,
e34, e76, h174, h175, m44,
m45, m46, m309, m310,
m311, m375, p103, p150,
t190
C9H10O3: d491, d492, e37, e38,
e46, e55, e178, e261, f52,
m101, m283, m297, m304,
m305, p74
C9H10O4: d496, d492, h135,
m292
C9H11Br: b350, b353, b399,
b435, b436
C9H11BrO: b413, p75
C9H11Cl: c222
C9H11ClO3S: c135
C9H11N: a77, c333, m288, t78,
t86
C9H11NO: d536, d562, m121,
m374, m445
C9H11NO2: d537, d538, e35,
e64, e65, i126, p86
C9H11NO3: t455
C9H12: e190, i103, p225, t357,
t358, t359, v13
C9H12N2O4: a241
C9H12N2O6: u18
C9H12N2S: b111
C9H12O: b98, d632, d633, i127,
i128, i129, m373, p145,
p146, p240, t385, t386, t387
C9H12O2: b115, c316, c358,
e48, p73, p148, t365, t374
short
standard
long
DEAN #37261
(McGHP)
RIGHT
ORGANIC COMPOUNDS
INTERACTIVE
1.69
top of rh
base of rh
cap height
base of text
TABLE 1.14 Empirical Formula Index of Organic Compounds (Continued)
The alphanumeric designations are keyed to Table 1.15.
C9H12O3: d499, m204, t332,
t333, t334
C9H12O3S: e263
C9H12S: p144
C9H13N: b595, d565, d706,
e80, e203, e264 e265, e266,
i101, t355
C9H13NO: b80, m96, n110
C9H13NO2: a258, b596
C9H13N5: t191
C9H14BrN: p162
C9H14Br3N: p165
C9H14ClN: p163
C9H14IN: p164
C9H14N2: n92, t388
C9H14O: d611, d613, i93, t364
C9H14O2: m350
C9H14O2Si: d510
C9H14O3: b215, t76
C9H14O3Si: p161
C9H14O5: d315, d382
C9H14O6: p200
C9H14Si: p166
C9H15N: t195
C9H15NO: c362
C9H15N3: t439
C9H16: m348
C9H16N2: d62
C9H16O: d612, n103
C9H16O2: b571, c363, h80,
n97
C9H16O3: b568, b582
C9H16O4: d368, d371, d478,
d614, n93
C9H16O6: d345
C9H17BrO2: e87
C9H17Cl: c92
C9H17ClO: n102, t372
C9H17ClO2: e167
C9H17N: a83, n95
C9H17NO2: e216, e217
C9H18: i108, p229, t363
C9H18NO: t115
C9H18N2O: d550
C9H18O: c385, d616, n99,
n100, n101, n104, t370
C9H18O2: e156, m349, n96
C9H18O3: d144
C9H18O4: d785
C9H19Br: b382
C9H19BrO2: e90
C9H19I: i42
C9H19NO: d151
C9H19NO3Si: t270
C9H19N2S: d175
C9H20: d386a, d613a, e210a,
n90, t370a
C9H20Cl2Si: d238
C9H20N2: a136, a290
C9H20N2S: d136
C9H20O: d615, n98, t371
C9H20O2: b556, n94
C9H20O2Si: c377
C9H20O3: d783, t291
C9H20O3Si: a99
C9H20O4: t430
C9H21Al: t428
C9H21BO3: t427, t326
C9H21BO6: t445
C9H21ClO3Si: c239
C9H21N: n105, t429
C9H21NO2: d470, d778
C9H21NO3: t325
C9H21N3: t287
C9H21O3P: t329
C9H22N2: d387, n91
C9H22O3: d780, d781
C9H22Si: t330
C9H23N3: p26
C9H24N4: b147
C9H24O2Si3: m153
C9H27BO3Si3: t449
C9H31ClO3Ti: c254
C10
C10H2O6: b28
C10H4Cl2O2: d243
C10H6Br2O: d113
C10H6Cl2O: d242
C10H6N2: b103
C10H6N2O4: d719
C10H6N2O4S: d64
C10H6O2: n11
C10H6O3: h161
C10H6O8: b27
C10H7Br: b376
C10H7BrO: b377, b378
C10H7Br2NO: d112
C10H7Cl: c185, c186
C10H7NO2: n57, n80, p126
C10H7NO8S2: n81
C10H8: a316, d1, n2
C10H8BrNO2: b339
C10H8N2: d790
C10H8N2O4: b205, f53
C10H8O: n9, n10
C10H8O2: d439, d440, d441,
d442, m199
C10H8O3: h148
C10H8O3S: n6, n7
C10H8O4: d443, d444
C10H9N: a228, a229, m420,
m421, m422, n17
C10H9NO: a51, a232
C10H9NO2: i16
C10H9NO3: h128
C10H9NO3S: a230
C10H9NO4S: a189, a190, a191,
a192
C10H9NO6: d643
C10H10: d423
C10H10BrClO: b299
C10H10ClFO: c121
C10H10ClNO2: c29
C10H10Cl2O3: d257
C10H10N2: a279, n4, n5
C10H10N2O: m378
C10H10N4O2S: s21
C10H10O: d363, m197, p94,
p95
C10H10O2: b63, m66, m198, s2
C10H10O3: b72, m345
C10H10O4: d590, d591, d592,
m125, p155, r3
C10H11BrO: b375
C10H11ClO3: c212
C10H11ClO4: t336
C10H11IO4: i24
C10H11N: p98
C10H11NO2: a24, d514
C10H11NO4: c8, d552a
C10H11O2S: b94
C10H12: d292, t80
C10H12N2: a170, b81
C10H12O: a89, b77a, b619, e59,
e279, i84, i102, m107,
m403, p96
C10H12O2: d419, e204, e205,
e206, e243, h154, h166,
m79, m102, m108, m109,
m111, m148, p79, p97,
p111, p226
C10H12O3: d487, e47, e195,
m306, p71, p102, p235
C10H12O4: d26a, d513, m231,
m232, t331
C10H12O5: p245, t335
C10H13Br: b280, b351
C10H13BrO: b281
C10H13BrO2: b395
C10H13Cl: b536, c178
C10H13NO: d527, p131
C10H13NO2: m380
C10H13NS2: b95
short
standard
long
DEAN #37261
LEFT
(McGHP)
1.70
INTERACTIVE
top of rh
base of rh
SECTION 1
cap height
base of text
TABLE 1.14 Empirical Formula Index of Organic Compounds (Continued)
The alphanumeric designations are keyed to Table 1.15.
C10H13N5O4: a67
C10H13O2S: b94
C10H14: b521, b522, b523,
d340a, d341, d342, i67,
i118, i119, i120, t97, t98,
t99
C10H14ClN: c130
C10H14NO5PS: p3
C10H14N2: n19, p141
C10H14N2O: d383
C10H14N2O4: b206
C10H14N4O4: d446
C10H14O: c20, i104
C10H14O: b585, b586, b587,
b588, b591, c20, i104, i121,
i122, i123, k2, m376, t162a,
t260
C10H14O2: b534, d516, p78
C10H14O3: c7
C10H14O4: b461, e23, e140,
m100, t337
C10H14O5PS: p3
C10H15BrO: b284
C10H15N: b516, b517, b518,
b519, d336, d278, e2, e277,
i105, i117, m377, p96
C10H15NO: b490, c403, d330,
e2, p219
C10H15NO2: d517
C10H15NO4: d309
C10H16: a65, c2, d595, d648,
d736, L7, L8, m467, p25,
p175, p176, t10, t11, t259,
t400a
C10H16ClN: b131
C10H16Cl2O2: d13
C10H16N2: d388
C10H16N2O4: d35
C10H16N2O8: e134
C10H16O: c3, c4, c286, d416,
d614, d645, L9, L10, p177,
p250, t376
C10H16O2: c383, m344
C10H16O4: c4, d319
C10H16O4S: c5
C10H16O5: d317, d366
C10H16Si: b132
C10H17N: a64, p284
C10H17NO: c386, m465
C10H18: d2, d3
C10H18NO2: b514
C10H18N2O7: h124
C10H18O: b245, b545, b546,
c277, d4, g2, i62, i132, L11,
m13, t12, t13, t375
C10H18O2: c379, d17, d650
C10H18O3: d680, t77, t350, v1
C10H18O4: b185, d10, d158,
d318, d394, d651, t283
C10H18O6: d481
C10H18S2: b154
C10H19ClO: d21
C10H19N: d13, d13a, t356
C10H19NO2: d329, e251
C10H20: b541, b542, c335, d22
C10H20Br2: d91
C10H20Cl2: d216
C10H20N2S4: t62
C10H20O: b543, b544, c290, d7,
d18, d19, d20, e7, e175,
m12, m313
C10H20O2: d15, e164, e231,
m177, o42
C10H20O4: b496, b530
C10H20O5: p46
C10H20O5Si: t347
C10H21Br: b315
C10H21Cl: c94
C10H21I: i29
C10H21N: d353
C10H21NO: a226
C10H21NO2: e218
C10H21NO4Si: t271
C10H22: d8
C10H22N2: d51
C10H22O: d16, d646, d647,
d738, t79
C10H22O2: d11, d12, d137
C10H22O3: d699, t433
C10H22O4: t432
C10H22O5: b212, p47, t55
C10H22O7: d735
C10H23N: d23, d649, d737
C10H23NO: d141
C10H23NO2: d313
C10H24N2: d9, t57, t111
C10H24N2O2: d731
C10H24N4: b146, t89
C10H24O3Si: i76
C10H28N6: p23
C10H30O3Si4: d6
C10H30O5Si5: d5
C11
C11H7N: c327
C11H7NO: n18
C11H8O: n1
C11H8O2: h157, m321, n3
C11H8O3: h158, h159, h160
C11H9Br: b370
C11H9Cl: c175
C11H9N: p152
C11H10: m318, m319
C11H10O: m87, m88
C11H12ClF: c140
C11H12N2O: a299
C11H12N2O2: t454
C11H12O2: b107, c281, e112,
m115
C11H12O3: b77, b200, e77,
e145, e244
C11H13ClO: b527
C11H13ClO3: c259
C11H13NO: b124, d666
C11H13NO4: b580
C11H13N3O: a110
C11H14O: p44, m114
C11H14O2: a84, b524, b526,
d522, e52, e176, p113
C11H14O3: b491, b584, b590,
e200
C11H14O4: e158
C11H15N: p142
C11H15NO: b121, d326
C11H15NO2: b512, d542, e127
C11H16: b602, p24, p55
C11H16N2: b119
C11H16O: b87, b573, b574,
b575, d667, p57
C11H16O4: d800
C11H17N: b538, d403
C11H17NO: e267
C11H17NO2: b109, m416
C11H17O3P: d344
C11H18N2O2: t366
C11H18O: d372, n106
C11H18O5: d316
C11H19ClO: u15
C11H19NO2: e168, o45
C11H20O: u12
C11H20O2: e165, i89, u13
C11H20O4: d155, d347, d354,
d373
C11H21BrO2: b442
C11H21N: u3
C11H21O2: c287
C11H22: u12a
C11H22N2: d776
C11H22O: u1, u9, u10, u11, u14
C11H22O2: e171, e228, m69,
m226, u4, u5, u6
C11H23Br: b441
C11H23I: i57
C11H24: u2
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
1.71
ORGANIC COMPOUNDS
top of rh
base of rh
cap height
base of text
TABLE 1.14 Empirical Formula Index of Organic Compounds (Continued)
The alphanumeric designations are keyed to Table 1.15.
C11H24O: u7, u8
C11H24O6Si: t444
C11H25NO2: a292
C11H26N2: b555, d166
C11H26N2O6: b237
C12
C12H4Cl6S2: b226
C12H6Br4O4S: s28
C12H6O3: n8
C12H6O12: b20
C12H7Cl6O: d296
C12H8: a3
C12H8Br2: d80
C12H8Cl2OS: b172
C12H8Cl2O2S: b171, c223
C12H8N2: p63
C12H8N2O4S: b216
C12H8O: d66
C12H8S: d67
C12H9Br: b273
C12H9BrO: b325, b398
C12H9ClO2S: c221
C12H9N: c6, d751, n16
C12H9NO: b73, b74, b75
C12H9NO2: n46, n47
C12H9NO3: n68, n69
C12H9NS: p67
C12H9N3O4: d717
C12H10: a2, b138
C12H10ClN: a145
C12H10ClO3P: c748
C12H10ClP: c118
C12H10Cl2Si: d223
C12H10Hg: d758
C12H10N2: a312
C12H10N2O: n79, p90
C12H10N2O2: n51
C12H10N3O3P: d764
C12H10O: d753, m322, m323,
p135, p136
C12H10OS: d772
C12H10O2: d436, h89, n14, n15
C12H10O2S: d771, t145
C12H10O3: n12
C12H10O3S: b142
C12H10O4: q1
C12H10O4S: s30
C12H10S: d770
C12H10S2: d750
C12H10Se2: d749
C12H11N: a130, a131, b122,
b123, d743
C12H11NO: h115, n13, p70
C12H11N3: p88
C12H11O3P: d763
C12H12N2: b140, d757, p137
C12H12N2O: o68
C12H12N2O2: b40
C12H12N2O2S: d47, d48
C12H12O: e50
C12H12O2Si: d769
C12H12O3: e78
C12H12O6: t193, t360
C12H13N: t68
C12H13N3: d34
C12H13NO3S: p272
C12H14: d467
C12H14N2: d46
C12H14N4O2S: s22
C12H14O: b525
C12H14O3: e179
C12H14O4: d391
C12H15NO: b121
C12H15N3O3: t196
C12H15N3O4S: d42
C12H16: b598, c376, m221
C12H16O2: p64
C12H16O3: d298
C12H17N: b120
C12H17NO: d402
C12H18: c338, d473, d474,
p116, t453
C12H18Cl2N4OS: t135
C12H18N2: p186
C12H18N2O2: i94
C12H18O: b552, d479, e4
C12H18O2: b550
C12H18O3: o41
C12H18O4: b463, h58
C12H19N: d471
C12H20O2: b202, b296, e112,
g3, L12
C12H20O3Si: p160
C12H20O4: d154
C12H20O4Sn: d179
C12H20O7: t278
C12H21N: t446
C12H21NO3Si: t345
C12H21N3: t429
C12H22: c339, d288
C12H22BCl: c95
C12H22N2O8: d45
C12H22O: c337, e5
C12H22O2: d811, e172, m14
C12H22O3: h65
C12H22O4: d168, d384, d597,
d787, d805
C12H22O6: d174
C12H22O11: L3, L4, m7, s20
C12H23N: d289
C12H23NO: a308, o47
C12H24: d813
C12H24Cl2: d224
C12H24O: c326, d817, e8, m459
C12H24O2: d809, e120
C12H24O6: c314
C12H25Br: b327
C12H25Cl: e119
C12H25Cl3Si: d821
C12H25I: i30
C12H25N: c340
C12H25N3: i6
C12H26: d803
C12H26O: d414, d810
C12H26O2: d806, d807
C12H26O3: b151
C12H26O4: d460, t91
C12H26O3S: d820
C12H26O5: t53
C12H26S: d808
C12H27Al: t322
C12H27B: t209
C12H27BO3: t207
C12H27ClSn: t213
C12H27N: d413, d818, t208
C12H27O3P: t212
C12H27O4P: t211
C12H28BrN: t130
C12H28N2: d804
C12H28O4Si: t129
C12H28O4Ti: t164, t165
C12H28Sn: t215
C12H29N: t323
C12H29N3: b196
C13
C13H6Cl2O2: h29
C13H8ClNO3: c198
C13H8Cl2O: d205
C13H8O: f3
C13H8OS: t162
C13H8O2: x3
C13H9BrO: b267
C13H9ClO: c56, c57
C13H9ClO2: c151
C3H9N: a60
C13H10: f2
C13H10ClNO: a140, a141, d745
C13H10Cl2: d221
C13H10Cl2O2: m243
C13H10F2: b195
C13H10N2: p91
short
standard
long
DEAN #37261
LEFT
(McGHP)
1.72
INTERACTIVE
top of rh
base of rh
SECTION 1
cap height
base of text
TABLE 1.14 Empirical Formula Index of Organic Compounds (Continued)
The alphanumeric designations are keyed to Table 1.15.
C13H10N2O3: a235
C13H10O: b53, x1
C13H10O2: b139, h103, m68,
p92
C13H10O3: d435, d747, p154,
r5
C13H10O4: t320
C13H10O5: t88
C13H11Br: b326
C13H11Cl: c116
C13H11N: b102
C13H11NO: a124, b5
C13H11NO3: p87
C13H12: d759
C13H12NO2: b112
C13H12N2: b54, d754
C13H12N2O: d775
C13H12N2S: d774, t141
C13H12N4O: d746, p89
C13H12N4S: d773
C13H12O: d760, h116, h117,
m63, p76
C13H12O2: m320
C13H12O4: d32
C13H12S: b118
C13H13ClSi: c117
C13H13N: d761, m238, p93
C13H13NO2: t187
C13H13N3: d755
C13H14N2: d35, m249
C13H14N2O3: a59
C13H14N4O: d746
C13H15NO: i96
C13H16O3: e79
C13H16O4: d389
C13H17NO2: e82
C13H18O3: b117
C13H18O5: t267
C13H20: p115
C13H20O: i58, i59
C13H22ClN: b130
C13H22N2: d290
C13H22O3Si: b129
C13H24O2: e273, i86
C13H24O4: d337
C13H26: t265
C13H26N2: m246, t369
C13H26O: t263, t264
C13H26O2: e232, t262
C13H27Br: b433
C13H28: t261
C13H28O4: t431
C13H29Cl: c250
C13H29NO4: b176
C13H30OSn: t216
C14
C14H6Cl2O2: d193
C14H7ClO2: c41, c42
C14H8O2: a298
C14H8O4: d426
C14H9Br: b391
C14H9ClO3: c63
C14H9Cl5: b173
C14H9NO2: a108, a109
C14H10: a297, d742, p62
C14H10ClNO3: a144
C14H10Cl2O4: b168
C14H10Cl4: b169
C14H10N2O2: d36, d37, d38, d39
C14H10O2: b35
C14H10O3: b45, b64, x2
C14H10O4: b141, d69, b71a
C14H10O4S2: d796
C14H11N: d741, p123
C14H11NOS: a50
C14H12: d415, s9
C14H12Cl2O: b170
C14H12N2O: b38
C14H12N2O2: b36
C14H12O: a34, d26, m145
C14H12O2: b46, b83, b84, b113,
d740
C14H12O3: b37, b100, b125,
h144
C14H13ClO: c169
C14H13N: e104, i9
C14H13NO: b82, d739
C14H13NO2: b50
C14H14: d752
C14H14N2: a168
C14H14N2O: m240
C14H14N2O3: a315
C14H14O: d73
C14H14OS: b223
C14H14O2: b114
C14H14O4: d33
C14H14S2: b222, d72
C14H15N: d71
C14H16N2O4: b207
C14H16O2Si: d503
C14H16O4: d340
C14H18N2O2: m132
C14H18O: p56
C14H18O4: d343
C14H18O7: p21
C14H19O3: d293
C14H22O: d160, d161, d162,
d163
C14H22O2: d145
C14H22O3: d153
C14H22O4: h59
C14H22O6: t281
C14H22O7: t52
C14H23N: d142
C14H23N3O10: d299
C14H26O2: i87
C14H26O3: h10
C14H26O4: d152, d395, d459
C14H27ClO: t46
C14H28: t47
C14H28O: d822
C14H28O2: d815, e272, t44
C14H29Br: b423
C14H29O4: b156
C14H30: t43
C14H30O: t45
C14H30O2Sn: d136
C14H31N: d602
C14H32N2O4: t90
C14H32OSn: t214
C15
C15H10N2O2: m247
C15H10O2: b105, m136, p122
C15H11NO: d762
C15H11NO2: m128
C15H12N2O2: d756
C15H12O: c23
C15H12O2: d68
C15H13NO: a13
C15H14O: d767
C15H14O2: b49, d768, h169
C15H14O3: b116, m239
C15H16O: c316a
C15H16O2: e189, i113
C15H17N: b96a
C15H17N3: d797
C15H20O6: e184
C15H22O3: d117, e174
C15H22O5: o46
C15H23N: b583
C15H24: t327
C15H24O: d156
C15H26O6: g20
C15H28O2: d816, i112
C15H29N: p12
C15H30N2: t368
C15H30O: p13
C15H30O2: m428
C15H32: p11
C15H32O10: t409
C15H33NO6: t443
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
1.73
ORGANIC COMPOUNDS
top of rh
base of rh
cap height
base of text
TABLE 1.14 Empirical Formula Index of Organic Compounds (Continued)
The alphanumeric designations are keyed to Table 1.15.
C16
C16H10: b52, f1, p255
C16H11NO2: p153
C16H12N4O9S2: t5
C16H13N: p132, p133
C16H14: d744, e71
C16H14O2: b93
C16H14O6S: s29
C16H16O2: b47
C16H16O3: d515
C16H18ClN3S: m248
C16H19ClSi: b537
C16H20N2: d74
C16H20N2O: b178
C16H20O2Si: d302
C16H22O4: d165, d410
C16H22O11: g9
C16H24N2: d150
C16H26O3: d814
C16H26O7: t54
C16H28O: c346
C16H30O2: d819
C16H30O4: b158, d157, d167,
d360
C16H32: h37
C16H32O: e10
C16H32O2: h34
C16H33Br: b345
C16H33Cl: c148
C16H33I: i35
C16H33NO: d359
C16H34: h4, h31, h36
C16H34O: d729, h35
C16H34O2: h32
C16H34O4: b157
C16H34S: d720, h33
C16H35N: d728, h37
C16H35O3P: b192
C16H36BF4N: t25
C16H36BrN: t21
C16H36BrP: t29
C16H36Br3N: t26
C16H36ClN: t22
C16H36IN: t24
C16H36O4Si: t28
C16H36Sn: t30
C16H37NO4S: t23
C17
C17H12O3: p118, p119
C17H13N3O5S2: p173
C17H15N2O: d355
C17H16O4: d75, p194
C17H18N2O4: p193
C17H18O2: b589
C17H18O3: b592
C17H18O4: b203
C17H20N2O: b178
C17H20N4O6: r8
C17H21NO4: b291
C17H22N2: m245
C17H23NO3: a305
C17H24O6: b492
C17H25NO2: m15
C17H27NO2: e170
C17H28NO: d149
C17H28O7: d181
C17H34O2: m269a, i131
C17H34O4: b160
C17H36: h1
C17H36O: h1a
C17H37N: m236
C18
C18H12: b6, b7
C18H12N5O6: d766
C18H14: t7, t8, t9
C18H14O8: d70
C18H15As: t412
C18H15B: t414
C18H15ClSn: c268, t425
C18H15N: t410
C18H15NO2: e116
C18H15N3Si: a310
C18H15OP: t421
C18H15O3P: t422
C18H15O4P: t419
C18H15P: t420
C18H15Sb: t411
C18H16OSn: t426
C18H16O2: b520, d280
C18H16Si: t423
C18H18O3: e81
C18H20N2O2: e152
C18H20O: b548
C18H20O2: b48
C18H22: b182
C18H26O6: e185
C18H30O: t210
C18H30O2: o7
C18H32N4O14: d364
C18H32O2: o1
C18H32O16: r1
C18H33ClO: o13
C18H34O2: o10, o11
C18H34O4: d143
C18H36: o8
C18H36O: e13, o12
C18H36O2: e157, o5
C18H37Br: b384
C18H37Cl: c203a
C18H37Cl3Si: o17
C18H37I: i43
C18H37N: o9
C18H37NO: o2
C18H38: o3
C18H38O: o6
C18H38S: o4
C18H39ClSi: t315
C18H39N: o15, t313
C18H39O7P: t435
C18H40Si: t316
C19
C19H15Br: b440, t417
C19H15Cl: c267, t418
C19H16: t415
C19H16O: t416
C19H18BrP: m458
C19H19N7O6: f31
C19H20Br4O4: i110
C19H20O4: b88
C19H22N2O: c276
C19H30O5: m252
C19H31N: d24
C19H34ClN: b127
C19H36O2: m347
C19H37NO: o16
C19H38O2: i109, m346
C19H40: n89, t114
C20
C20H10Br2O5: d105
C20H12: b56, b57, d65
C20H12O5: f4
C20H14O4: d765, p66
C20H15Br: b439
C20H18O2Sn: t424
C20H19N3: b2
C20H20BrOP: h136
C20H32O5: d782
C20H24N2O2: q2
C20H26O4: d291
C20H27O3P: i90
C20H30O2: a1
C20H30O6: b184
C20H31N: d20
C20H34O4: b159
C20H36O2: e229
short
standard
long
DEAN #37261
1.74
LEFT
(McGHP)
INTERACTIVE
top of rh
base of rh
SECTION 1
cap height
base of text
TABLE 1.14 Empirical Formula Index of Organic Compounds (Continued)
The alphanumeric designations are keyed to Table 1.15.
C20H38O2: e230
C20H38O4: b187
C20H40: i2
C20H40O: o18
C20H42: i1
C21 to C23
C21H15NO: b143
C21H21N: t198
C21H21O4P: t452
C21H22N2O2: s10
C21H24O2: b144
C21H28N2O: b177
C21H36O: p14
C21H40O2: o14
C21H45N3O12Si3: t448
C22H23N3O9: a306
C22H26O: b181
C22H30O2S: t140
C22H34O4: b547, d463
C22H42O8: b152
C22H44O2: b581, i75
C22H46: d801
C22H46O: d802
C22H48N2: t27
C23H18BrO2P: c18
C23H26N2O4: b447
C23H42O2: b581a
C24 to C29
C24H16N2O2: b218
C24H18: t413
C24H20BNa: t126
C24H20Sn: t128
C24H27NO2: e169
C24H38O4: b193, d374, d466,
d466a
C24H40O5: c275
C24H46O4: d725, d812
C24H50: t41
C24H51N: t406
C24H51O3P: t438
C24H54OSn2: b224
C25H30ClN3: c315
C25H34Cl6O4: b189
C25H48O4: d465
C26H26N2O2S: b153
C26H42O2: d138
C26H42O4: d464
C26H47O3P: d462
C26H46O8: t312
C26H50O4: b190
C27H42O: c274
C27H50ClN: b96
C28H31ClN2O3: r6
C28H32: t127
C28H50O8: t314
C28H54O6Sn: b601
C29H44O2: m244
C29H50O7: p20
C30 to C57
C30H43FO2P: e188
C30H46O2: e187
C30H50: s8
C30H58O4S: d295
C30H62: s7
C30H63O3P: t324
C32H64O4Sn: d178
C32H66: d823
C36H75O3P: d726
C39H74O6: g21
C40H82O6P2: b217
C42H82O4S: d727
C45H86O6: g25
C51H98O6: g24
C55H98O6P2: i111
C57H104O6: g23
TABLE 1.15 Physical Constants of Organic Compounds
See also the special tables of polymers, rubbers, fats, oils, and waxes.
Names of the compounds in the table starting on p. 1.76 are arranged alphabetically. Usually substitutive nomenclature is employed; exceptions generally involve ethers, sulfides, sulfones, and sulfoxides. Each compound
is given a number within its letter classification; thus compound c209 is 3-chlorophenol. Section 1.1, Nomenclature of Organic Compounds, should be consulted to familiarize oneself with present nomenclature systems.
Synonyms or Alternate Names are found at the bottom of each spread in their alphabetical listing; the number
following the same refers to the numerical place of this compound in the table. For example, epichlorohydrin,
c120, indicates that this compound is found listed under the name 1-chloro-2,3-epoxypropane.
Formulas are presented in semistructural form when no ambiguity is possible. Complicated systems are drawn
in complete structural form and located at the bottom of each page and keyed to the number of the entry.
Beilstein Reference. In this column is found the reference to the volume and page numbers of the fourth edition
of Beilstein, Handbuch der Organischen Chemie (Springer-Verlag, New York, 1918). Thus the entry 9, 202
refers to an entry in volume 9 appearing on page 202. When the volume number has a superscript attached,
reference is made to the appropriate supplementary volume. For example, 122, 404 indicates that the compound
will be found listed in the second supplement to volume 12 on page 404. The earliest Beilstein entry is listed.
Supplementary information may be found in the supplements to the basic series; such coordinating references
(series number, volume number, and page number of the main edition) along with the system number are found
at the top of each odd-numbered page. Similarly, a back reference such as H93; E II 64; E III 190 in a volume
of Supplementary Series IV means that previous items on this compound are found in the same volume of the
short
standard
long
DEAN #37261
(McGHP)
RIGHT
ORGANIC COMPOUNDS
INTERACTIVE
1.75
Basic Series on page 93, of Supplementary Series II on page 64, and of Supplementary Series III on page 190.
The absence of a back reference implies that the compound involved is described for the first time in the series
concerned.
Formula Weights are based on the International Atomic Weights of 1993 and are computed to the nearest
hundredth when justified. The actual significant figures are given in the atomic weights of the individual elements;
see Table 3.2.
Density values are given at room temperature unless otherwise indicated by the superscript figure; thus 0.9711112
indicates a density of 0.9711 for the substance at 112⬚C. A density of 0.89916
4 indicates a density of 0.899 for
the substance at 16⬚C relative to water at 4⬚C.
Refractive Index, unless otherwise specified, is given for the sodium line at 589.6 nm. The temperature at which
the measurement was made is indicated by the superscript figure; otherwise it is assumed to be room temperature.
Melting Point is recorded in certain cases as 250 d and in some other cases as d 250, the distinction being made
in this manner to indicate that the former is a melting point with decomposition at 250⬚C, while the latter
decomposition occurs only at 250⬚C and higher temperatures. Where a value such as ⫺2H2O, 120 is given, it
indicates a loss of 2 moles of water per formula weight of the compound at a temperature of 120⬚C.
Boiling Point is given at atmospheric pressure (760 mmHg) unless otherwise indicated; thus 8215mm indicates
that the boiling point is 82⬚C when the pressure is 15 mmHg. Also, subl 550 indicates that the compound sublimes
at 550⬚C.
Flash Point is given in degrees Celsius, usually using a closed cup. When the method is known, the acronym
appears in parentheses after the value: closed cup (CC), Cleveland closed cup (CCC), open cup (OC), Tag closed
cup (TCC), and Tag open cup (TOC). Because values will vary with the specific procedure employed, and many
times the method was not stated, the values listed for the flash point should be considered only as indicative.
See also Table 5.23, Properties of Combustible Mixtures in Air.
Solubility is given in parts by weight (of the formula weight) per 100 parts by weight of the solvent and at room
temperature. Other temperatures are indicated by the superscript. Another way in which solubility is explicitly
stated is in weight (in grams) per 100 mL of the solvent. In the case of gases, the solubility is often expressed
as 5 mL10, which indicates that at 10⬚C, 5 mL of the gas is soluble in 100 g (or 100 mL, if explicitly stated) of
the solvent.
top of rh
base of rh
cap height
base of text
Abbreviations Used in the Table
abs, absolute
acet, acetone
alc, alcohol (ethanol usually)
alk, alkali (aqueous NaOH or
KOH)
anhyd, anhydrous
aq, aqueous, water
as, asymmetrical
atm, atmosphere
BuOH, 1-butanol
bz, benzene
c, cold
chl, chloroform
conc, concentrated
d, decomposes or decomposed
D, dextrorotatory
deliq, deliquescent
dil, dilute
diox, 1,4-dioxane
DL, inactive (50% D and 50% L)
DMF, dimethylformamide
E, trans (German “entgegen”)
EtOAc, ethyl acetate
eth, diethyl ether
EtOH, ethanol, 95%
expl, explodes
glyc, glycerol
h, hot
HOAc, acetic acid
hyd, hydrolysis
hygr, hygroscopic
i, insoluble
ign, ignites
i-PrOH, isopropyl alcohol,
2-propanol
L, levorotatory
m, meta configuration
Me, methyl
MeOH, methanol
misc, miscible; soluble in all
proportions
NaOH, aqueous sodium hydroxide
o, ortho configuration
org, organic
p, para configuration
PE, petroleum ether
pyr, pyridine
s, soluble
sec, secondary
sl, slight, slightly
soln, solution
solv, solvent
subl, sublimes
s, symmetrical
sym, symmetrical
tert, tertiary
v, very
v s, very soluble
v sl s, very slightly soluble
vac, vacuo or vacuum
vols, volumes
Z, cis (German “zusamman”)
⬎, greater than
⬍, less than
⬃, approximately
⫾, inactive [50% (⫹) and
50% (⫺)]
␣, alpha (first) position
␤, beta (second) position
␥, gamma (third) position
␦, delta (fourth) position
␻, omega position (farthest
from parent functional
group)
short
standard
long
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Solubility in 100
parts solvent
⫺38(CC)
40
i aq; s acet, alc, bz,
chl, CS2, eth, dil alk
i aq; 3.2 alc; 20 bz; 10
chl; 1.8 MeOH; 3.2
g in 100 mL HOAc
i aq; v s alc, eth
misc aq, alc, eth
v s aq, alc, eth
1.76
a1
(⫺)-Abietic acid
302.46
92, 424
a2
Acenaphthene
154.21
5, 586
1.189
1.604895
a3
a4
a5
Acenaphthylene
Acetaldehyde
Acetaldoxime
CH3CHO
CH3CH"NOH
152.20
44.05
59.07
5, 625
1, 594
1, 608
0.89916
4
0.78816
6
0.966
1.331620
1.41520
a6
Acetamide
CH3CONH2
59.07
22, 177
0.99978
1.4158110
a7
a8
CH3C("NH)NH2 ·HCl
H2N(CO)CH2NHCH2CH2SO3H
94.54
182.20
2, 185
164–166
⬎220 dec
CH3CONHC6H4CHO
163.18
14, 38
156–158
s aq, bz; sl s alc
CH3CONHC6H4SO3Cl
233.67
14, 702
148 dec
CH3CONHC6H4CO2H
179.18
14, 337
185–187
CH3CONHC6H4CO2H
179.18
14, 432
262 dec
d aq; v s alc, bz, eth,
acet
sl s aq; v s alc, bz, eth,
acet
i aq; s alc; sl s eth
223.28
190.16
12, 1331
H2NCOCH2N(CH2CO2H)2
192–196
219 d
a15
a16
a17
a18
Acetamidine HCl
N-(2-Acetamido)-2aminoethanesulfonic
acid
4-Acetamidobenzaldehyde
4-Acetamidobenzenesulfonyl chloride
2-Acetamidobenzoic
acid
4-Acetamidobenzoic
acid
2-Acetamidofluorene
N-(2-Acetamido)iminodiacetic acid
2-Acetamidophenol
3-Acetamidophenol
4-Acetamidophenol
Acetanilide
CH3CONHC6H4OH
CH3CONHC6H4OH
CH3CONHC6H4OH
CH3CONHC6H5
151.17
151.17
151.17
135.17
13, 370
13, 415
13, 460
12, 237
1.29321
4
1.21915
4
207–210
146–149
170–172
114
a19
a20
Acetic acid
Acetic acid-d
CH3CO2H
CH3CO2D
60.05
61.06
2, 96
23, 202
1.049220
4
1.059
a9
a10
a11
a13
a14
279
88–91
⫺123
46.5(␣)
12(␤)
81
280
21
114.5
16.7
222
70 aq; 50 alc; 16 pyr; s
chl, glyc, hot bz
v s aq; s alc; i acet, eth
i aq; s alc, glycols
304–305
173
118
115.5
39 (CC)
40
INTERACTIVE
1.371820
1.271520
93.4
LEFT
a12
172–175
(McGHP)
Flash
point,⬚C
DEAN #37261
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
s alc, acet
0.56 aq25; 25 acet; 29
alc; 2 bz; 27 chl; 5
eth
misc aq, alc, eth, CCl4
misc aq, alc, eth, CCl4
top of page
short
standard
base of DF
CD3CO2D
(CH3CO)2O
64.08
102.09
23, 203
2, 166
1.137
1.08015
4
a23
a24
Acetic anhydride-d6
Acetoacetanilide
(CD3CO)2O
CH3COCH2CONHC6H5
108.14
177.20
12, 518
1.26020
a25
a26
a27
a28
a29
Acetoacetic acid
Acetone
Acetone-d6
Acetone oxime
Acetonitrile
CH3COCH2COOH
CH3COCH3
CD3COCD3
(CH3)2C"NOH
CH3CN
102.09
58.08
64.13
73.10
41.05
3, 630
1, 635
a30
a31
Acetonitrile-d3
Acetophenone
CD3CN
C6H5COCH3
a32
Acetophenonemethyl-d3
C6H5COCD3
⫺73
114.4
139
40
54 (CC)
85
6565mm
dec
54
185
d viol 100
56
55.5
135
81.6
6
80.7
202
5
77
201–202
82
1.387520
1.359120
1.355420
1, 649
2, 183
0.790820
4
0.872
0.91162
2
0.787515
4
1.346015
36–37
⫺94
⫺93.8
60
⫺44
44.08
120.15
24, 428
7, 271
0.844
1.02620
4
1.340620
1.537220
20
123.18
74, 626
1.055
1.532520
1.77
Acetamidoacetic acid, a46
2-Acetamidopentanedioic acid, a45
Acetoacetic ester, e58
Acetoin, h108
Acetonaphthones, m322, m323
ACES, a8
Acetal, d303
Acetaldehyde ammonia, a162
Acetaldehyde diethyl acetal, d303
Acetaldehyde dimethyl acetal, d504
1.368720
1.390420
⫺20
⫺17
misc aq, alc, eth, CCl4
s chl, eth; slowly s aq
forming HOAc, alc
forming EtOAc
see acetic anhydride
s alc, hot bz, acids, alkalis, chl, eth
misc aq, alc
misc aq, alc, chl, DMF
see acetone
v s aq, alc, eth
misc aq, acet, alc, chl,
eth, EtOAc
misc aq, alc, chl
0.55 aq; s alc, chl, eth,
glyc
(McGHP)
Acetic-d3 acid-d
Acetic anhydride
DEAN #37261
a21
a22
Acetonecarboxylic acid, a24
Acetone cyanohydrin, h138a
Acetone dimethyl acetal, d519
Acetone ketal of glycerin, d599
Acetonylacetone, h60
RIGHT
a2
a3
INTERACTIVE
a1
a13
top of page
short
standard
base of DF
DEAN #37261
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
a33
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
C6H5C6H4COCH3
CH3COBr
196.25
122.95
72, 337
2, 174
1.66316
4
1.448620
116–118
⫺96
325–327
76
⬎110
CH3COCl
128.13
78.50
173, 5837
2, 173
1.184620
4
1.10420
4
1.458520
1.389620
⫺113
1075mm
51
⬎110
4 (CC)
758mm
72
2-Acetylbutyrolactone
Acetyl chloride
a38
Acetylcholine bromide
(CH3)3N(Br)CH2CH2O2CCH3
226.11
41, 428
144–146
a39
Acetylcholine chloride
(CH3)3N(Cl)CH2CH2 O2CCH3
181.66
4, 281
150–152
a40
2-Acetylcyclopentanone
Acetylene
126.16
7, 558
1.043
26.04
1, 228
0.90(g)
114.06
2, 801
62.04
2, 172
a43
Acetylenedicarboxylic
acid
Acetyl fluoride
HO2CC#CCO2H
CH3OF
2-Acetylfuran
N-Acetyl-(⫺)-glutamic
acid
HO2CCH2CH2CHCO2CH3
a46
N-Acetylglycine
CH3CONHCH2CO2H
a47
1-Acetylimidazole
110.11
189.17
17, 286
42, 908
117.10
4, 354
⫺85(subl)
⫺18
180 d
⬍⫺60
1.00215
4
1.098
20
1.5065
29–30
200–201
20.8
10mm
67
1 vol in 1 vol aq, in 6
vol HOAc or alc; s
bz, eth; acet dissolves 25 vol15 but
300 vols at 12 atm
v s aq, alc, eth
5 aq(dec); sl s acet,
alc, bz, eth
71
INTERACTIVE
a44
a45
1.490520
i aq; v s alc, acet
dec viol by aq or alc;
misc bz, chl, eth
20% v/v aq
dec viol aq or alc;
misc bz, chl, eth,
HOAc, PE
v s aq (dec by hot aq
or alkalis); s alc; i
eth
v s aq, alc; dec by hot
aq or alkalis; i eth
LEFT
a36
a37
(McGHP)
1.78
112, 186
HC#CH
Solubility in 100
parts solvent
⬎300
222.20
a34
a35
a42
Flash
point,⬚C
CH3COC6H5SO3⫺ Na⫹
4-Acetylbenzenesulfonic acid, sodium
salt
Acetylbiphenyl
Acetyl bromide
a41
Boiling
point,⬚C
NHCOCH3
110.12
206–208
2.7 aq15; s alc; sl s
acet, chl, HOAc; i
bz, eth
103–105
top of page
short
standard
base of DF
a57
a58
2-Acetylthiophene
1-Acetyl-2-thiourea
a50
a51
169.95
195.69
2, 174
Merck:
12, 6003
C6H5CH(CN)COCH3
241.31
159.19
10, 699
(C5H4N)COCH3
(C5H4N)COCH3
(C5H4N)COCH3
HO2C6H4-2-O2CCH3
141.17
121.14
121.14
121.14
180.16
21,
21,
21,
10,
(C4H3S)COCH3
CH3C(O)NHC(S)NH2
126.18
118.16
17, 287
3, 191
1.79
p-Acetotoluide, m374
Acetoxime, a28
2-Acetoxybenzoic acid, a56
1-Acetoxy-1,3-butadiene, b378
(Acetoxymethyl)benzene, b76
3-Acetoxypropene, a74
Aceturic acid, a46
2.067420
4
1.549120
108
dec aq, alc; s bz, eth
v s aq, alc, chl; i eth;
dec by alkalis, eth
172–173
180–185
279
279
279
67
92–94
1.146
1.080
1.102
1.095
1.35
1.502620
1.520320
1.533620
1.535020
1.16822
4
1.556420
218
188–189
220
212
135
10–11
167
214
⬎110
73
150
⬎110
v s alc, eth
v s acids, alc, eth; s aq
v s alc, eth
0.33 aq25; 29 acet; 20
alc; 5.9 chl; 5 eth; s
bz
sl s aq; misc alc, eth
s hot aq, alc; sl s eth
(McGHP)
CH3COI
CH3CO2CH(CH3)CH2⫺
N(Br)(CH3)3
a52
a53
a54
a55
a56
Acetyl iodide
Acetyl-2-methylcholine chloride
2-Acetylphenothiazine
2-Acetylphenylacetonitrile
1-Acetyl-4-pipidone
2-Acetylpyridine
3-Acetylpyridine
4-Acetylpyridine
Acetylsalicylic acid
DEAN #37261
a48
a49
Acetylene tetrabromide, t16
Acetylene tetrachloride, t37
N-Acetylethanolamine, h119
3-Acetyl-6-methyl-2H-pyran-2,4-(3H)-dione, d25
2-(Acetyloxy)benzoic acid, a56
3-Acetyl-1-propanol, h164
N-Acetylsulfanilyl chloride, a10
Acetylacetanilid, a24
Acetyl acetate, a22
Acetylacetone, p34
N-Acetylanthranilic acid, a11
Acetylbenzene, a31
Acetylcyclopropane, c410
Acetylene dichloride, d228, d229
RIGHT
a40
a44
a47
a50
INTERACTIVE
a36
a52
top of page
short
standard
base of DF
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
a59
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
246.27
222, 469
179.22
20, 459
1.00520
4
Acrylamide
H2C"CHCONH2
71.08
2, 400
1.22230
4
a62
Acrylic acid
H2C"CHCO2H
72.06
2, 397
1.051120
a63
a63a
a64
Acrylonitrile
Acryloyl chloride
1-Adamantanamine
H2C"CHCN
H2C"CHCOCl
53.06
90.51
151.25
0.806020
4
1.114
a65
Adamantane
136.24
a66
Adenine
135.13
2, 400
2, 400
Merck:
12, 389
Merck:
12, 149
26, 420
a67
a68
(⫺)-Adenosine
(⫾)-␣-Alanine
CH3CH(NH2)CO2H
267.24
89.09
31, 27
4, 387
1.424
a69
(⫺)-␣-Alanine
CH3CH(NH2)CO2H
89.09
4, 381
1.401
a70
a71
a72
a73
␤-Alanine
Allantoin
Allene
Alloxan monohydrate
H2NCH2CH2CO2H
89.09
158.12
40.06
160.09
4, 401
25, 474
1, 248
24, 500
1.437⫺5
a74
a75
a76
Allyl acetate
Allyl alcohol
Allylamine
H2C"CHCH2OCOCH3
H2C"CHCH2OH
H2C"CHCH2NH2
100.12
58.08
57.10
2, 136
2, 436
4, 205
Flash
point,⬚C
206
s aq, alc; v s eth
106–110
subl 100
84.5
346
1.422420
12–14
141
50
1.391120
1.435020
⫺83.5
77.3
72–76
0
15
192.6
160–190
1.09
1.787
0.97720
4
0.854020
4
0.76120
4
1.568
270 (sealed
tube)
360 dec
235
264–269
(depends
on heating rate)
dec 297
1.4168
1.404020
1.413420
1.418520
197 dec
238
⫺136
anhyd: 256
dec
⫺129
⫺88.2
Solubility in 100
parts solvent
s alc, eth, CS2, PE; sl s
hot aq
at 30⬚, g/100 mL: 215
aq, 155 MeOH, 86
EtOH, 63 acet, 12.6
EtOAc, 2.7 chl, 0.3
bz
misc aq, alc, bz, eth,
chl, acet
7.3 aq; misc org solv
d aq; v s chl
sl s aq
205 subl
s acet
subl 220
0.005 aq; sl s alc; i
chl, eth
s aq; i alc
16.7 aq25; 0.009 alc25; i
eth
subl ⬎200
LEFT
H2C"C"CH2
Boiling
point,⬚C
16.7 aq25; 0.2 alc25; i
eth
v s aq; sl s alc; i eth
0.45 aq; 0.2 alc; i eth
INTERACTIVE
a61
Melting
point,⬚C
(McGHP)
1.80
a60
N-Acetyl-(⫾)-tryptophan
Acridine
Refractive
index
DEAN #37261
No.
⫺34
104
97
53–55
22
21
⫺29
s aq, alc, acet, HOAc;
sl s chl, EtOAc, PE
i aq; misc alc, eth
misc aq, alc, chl, eth
misc aq, alc, chl, eth
top of page
short
standard
base of DF
N-Allylaniline
Allylbenzene
Allyl bromide
Allyl butanoate
C6H5NHCH2CH"CH2
C6H5CH2CH"CH2
H2C"CHCH2Br
CH3CH2CH2COOCH2CH"CH2
133.19
118.18
120.98
128.17
0.98225
0.89220
0
1.39820
4
0.902
12, 170
5, 484
1, 201
2, 272
1.563020
1.512220
1.465420
1.414220
⫺119
4415mm
Adipic acid, h54
Adipic acid monoethyl ester, e177
Adiponitrile, d284
Alaninol, a264, a265
1.81
a60
a59
89
33
⫺2
i aq; s alc, eth
i aq; s alc, eth
sl s aq; misc org solv
Allocimene, d669
Allylacetone, h77
4-Allylanisole, a89
Allyl butyrate, a80
a64
a65
(McGHP)
Aconitic acid, p206
Acrolein, p203
Acrolein diethyl acetal, d312
Acrolein dimethyl acetal, d521
Acrylaldehyde, p203
220
157
70
41
DEAN #37261
a77
a78
a79
a80
a66
RIGHT
a71
INTERACTIVE
a67
a73
top of page
short
standard
base of DF
DEAN #37261
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
Name
Formula
Allyl chloride
H2C"CHCH2Cl
a82
a83
a84
Allyl chloroformate
Allylcyclohexylamine
4-Allyl-1,2-dimethoxybenzene
N-Allyl-N,N-dimethylamine
Allyl ethyl ether
Allyl iodide
Allyl isothiocyanate
Allyl methacrylate
H2C"CHCH2OOCCl
(C6H11)NHCH2CH"CH2
H2C"CHCH2C6H3(OCH3)2
a85
a86
a87
a88
a89
H2C"CHCH2N(CH3)2
1.82
H2C"CHCH2OCH2CH3
H2C"CHCH2I
H2C"CHCH2NCS
H2C"C(CH3)COOCH2CH"CH2
H2C"CHCH2SCH3
H2C 9 CHCH2OCH2-
Beilstein
reference
Density,
g/mL
Refractive
index
1, 198
0.93820
4
1.415420
⫺134.5
44–46
120.54
139.24
178.23
3, 12
1.136
0.962
1.036
1.4223
1.466420
1.534420
110
27
6612mm
255
6, 963
⫺4
1.401020
85.0
86.13
167.98
99.16
126.16
1, 438
1, 202
4, 214
23, 1290
0.76520
4
1.82520
4
1.01325
4
0.938
1.388120
1,554021
1.524825
1.4360
88.17
114.14
1, 440
0.803
0.962
132.16
1, 513
Flash
point,⬚C
sl s aq; misc alc, chl,
eth, PE
⫺20
i aq; misc alc, eth
i aq; misc alc, eth
0.2 aq; misc org solv
64
46
33
1.471420
1.433220
91–93
154
18
57
1.068
1.462020
14228mm
⬎110
0.7830
1.407525
102
0
220
192
90–92
88
62
⫺5
117.5
176740mm
66–67
84–88
31
21
⫺1
7
a92
H2C"CHCH2⫺
CH2CH(OH)CH2OH
H2C"CHCH2OSi(CH3)3
130.26
a94
a95
a96
a97
3-Alloxy-1,2-propanediol
Allyloxytrimethylsilane
2-Allylphenol
Allyl phenyl ether
Allyl propyl ether
1-Allyl-2-thiourea
H2C"CHCH2C6H4OH
H2C"CHCH2OC6H5
H2C"CHCH2OC3H7
H2C"CHCH2NHC(S)NH2
134.18
134.18
100.16
116.19
6, 572
6, 144
1, 438
4, 211
1.03315
4
0.98315
4
0.76720
4
1.21920
20
1.545020
1.520020
1.399020
a98
a99
a100
a101
a102
Allyltrichlorosilane
Allyltriethoxysilane
Allyl trifluoroacetate
Allyltrimethylsilane
Allylurea
H2C"CHCH2SiCl3
H2C"CHCH2Si(OC2H5)3
CF3COOCH2CH"CH2
H2C"CHCH2Si(CH3)3
H2C"CHCH2NHCONH2
175.52
204.34
154.09
114.27
100.12
43, 1909
43, 1909
24, 464
1.201120
4
0.903020
1.183
0.719320
4
1.455020
1.406220
1.335020
1.408020
4, 209
a103
Aminoacetonitrile
H2NCH2CN
56.07
4, 344
Solubility in 100
parts solvent
⫺31
(CC)
31
53
68
103
152
6143mm
Allyl methyl sulfide
1-Alloxy-2,3-epoxypropane
a93
Boiling
point,⬚C
76.53
a90
a91
O
Melting
point,⬚C
(McGHP)
a81
Formula
weight
⫺99
⫺80
CH " CH2
70–72
5815mm d
s alc, eth
i aq; s alc, misc eth
s alc; misc eth
3.3 aq; s alc; i bz; v sl
s eth
INTERACTIVE
85
LEFT
10
v s aq, alc; i chl, CS2
eth, toluene
s acids, alc
top of page
short
standard
base of DF
a105
a106
a107
H2NCH2CN·H2SO4
154.14
4, 344
121
d 165
H2NC6H4COCH3
135.17
14, 41
H2NC6H4COCH3
135.17
14, 45
99
290
H2NC6H4COCH3
135.17
14, 46
106
293–295
223.23
14, 177
ca. 250
subl
223.23
14, 191
295 d
subl
109
128
⬎360
300 sl d
703mm
a110
a111
1-Aminoanthraquinone
2-Aminoanthraquinone
4-Aminoantipyrine
p-Aminoazobenzene
203.25
197.24
24, 273
C6H5N"NC6H4NH2
a112
2-Aminobenzamide
H2NC6H4CONH2
136.15
14, 320
110
a113
4-Aminobenzenearsonic acid
H2NC6H4AsO(OH)2
217.06
16, 878
232
a114
5-Aminobenzene-1,3dicarboxylic acid
H2NC6H3(COOH)2
181.15
141, 636
⬎300
a109
1.83
v sl s aq; s alc, eth
s hot aq, alc, eth,
HOAc; sl s bz
i aq; v s alc, bz, chl,
eth, HOAc, HCl
i aq, eth; s alc, bz
s aq, alc, bz; sl s eth
sl a aq; v s alc, bz, chl,
eth
v s hot aq, alc; i bz; sl
s eth
s hot aq; alk CO3,
conc⬘d mineral acids; i acet, bz, chl,
eth
Aminoacetaldehyde diethyl acetal, d306
Aminoacetaldehyde dimethyl acetal, d506
1-Aminoadamantane, a64
Aminoanisoles, m48 thru m50
p-Aminoazobenzene, p88
Allyl mercaptan, p205
Allyl sulfide, d34
Allyl trichloride, t247
Aluminon, a306
N-Amidinosarcosine, c301
a109
INTERACTIVE
a108
⬎110
RIGHT
Allyl carbamide, a102
Allyl chloride, c236a
Allyl cyanide, b482
Allyl glycidyl ether, a91
1-Allyl-2-hydroxybenzene, a94
Allyl iodide, i50
v s aq; sl s alc; i eth
(McGHP)
a108
Aminoacetonitrile hydrogen sulfate
2⬘-Aminoacetophenone
3⬘-Aminoacetophenone
4⬘Aminoacetophenone
DEAN #37261
a104
a110
top of page
short
standard
base of DF
DEAN #37261
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
a115
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
2 aq15; sl s alc, MeOH
d 288
1 aq20; sl s hot MeOH;
i alc, bz, eth
v s hot aq, alc, eth
v s hot aq, alc; s eth
0.59 aq; 12 alc; 2 eth;
s EtOAc, HOAc
s alc, eth
s hot aq; v s alc, eth
v s hot aq, alc, eth
sl s aq; s alc, eth
v s conc⬘d acids, alc,
chl, eth
H2NC6H4SO3H
173.19
14, 688
H2NC6H4SO3H
173.19
14, 695
a118
a119
a120
H2NC6H4COOH
H2NC6H4COOH
H2NC6H4COOH
137.14
137.14
137.14
14, 310
14, 383
14, 418
a121
a122
a123
a124
a125
2-Aminobenzonitrile
3-Aminobenzonitrile
4-Aminobenzonitrile
2-Aminobenzophenone
2-Aminobenzothiazole
H2NC6H4CN
H2NC6H4CN
H2BC6H4CN
H2NC6H4COC6H5
118.14
118.14
118.14
197.24
150.20
14, 322
14, 391
14, 425
14, 76
27, 182
a126
2-Aminobenzotrifluoride
3-Aminobenzotrifluoride
4-Aminobenzotrifluoride
N-(4-Aminobenzoyl)glycine
2-Aminobiphenyl
4-Aminobiphenyl
2-Amino-5-bromobenzoic acid
(⫾)-2-Aminobutanoic
acid
3-Aminobutanoic acid
4-Aminobutanoic acid
2-Amino-1-butanol
H2NC6H4CF3
161.13
1212, 453
1.29025
H2NC6H4CF3
161.13
12, 870
H2NC6H4CF3
161.13
123, 2151
H2NC6H4CONHCH2COOH
194.19
142, 258
198–199
H2NC6H4C6H5
H2NC6H4C6H5
Br(NH2)C6H3COOH
169.23
169.23
216.03
12, 1317
12, 1318
14, 370
50–53
52–54
218–219
299
19115mm
CH3CH2CH(NH2)COOH
103.12
4, 408
304 d
subl ⬎300
H3CCH2CH(NH2)COOH
H2NCH2CH2CH2COOH
CH2CH2CH(NH2)CH2OH
103.12
103.12
89.14
4, 412
4, 413
4, 291
193–194
195 d
⫺2
176–178
a127
a128
a129
a133
a133a
a134
a135
subl
49
53
85
108
132
268
288–290
dec
223–226
dec
⬎110
⬎110
1.478525
34
175
55
1.290
1.480020
6
187
85
1.28327
1.481525
38
8312mm
86
0.94420
20
1.452120
i aq; s alc, bz, chi
⬎110
⬎110
74 (OC)
sl s aq; s alc
s hot aq, alc, eth
s alc, bz, chl, eth,
HOAc; v s acet
21 aq25, 0.18 hot alc; i
eth
125 aq; i alc, eth
v s aq; i org solv
misc aq; s alc
INTERACTIVE
a130
a131
a132
144–146
172–174
187
1.5114
1.374
LEFT
14, 681
(McGHP)
⬎300
173.19
a117
1.84
1.5 aq15; v sl s alc, eth
H2NC6H4SO3H
1.69
Solubility in 100
parts solvent
ca. d 325
2-Aminobenzenesulfonic acid
3-Aminobenzenesulfonic acid
4-Aminobenzenesulfonic acid
2-Aminobenzoic acid
3-Aminobenzoic acid
4-Aminobenzoic acid
a116
Flash
point,⬚C
top of page
short
standard
base of DF
a137
a138
a140
a141
a142
a143
a144
1.85
a145
a146
a147
223, 3788
H2NC6H2(Cl)(SO2NH2)2
285.73
144, 2810
257–261
H2N(Cl)C6H3COOH
171.58
14, 365
231–233
H2N(Cl)C6H3COOH
171.58
14, 412
188 d
0.910
39–42
1
H2NC6H4COC6H4Cl
231.68
14 , 389
104
H2N(Cl)C6H3COC6H5
231.68
14, 79
98–100
H2N(Cl)C6H3CF3
195.57
123, 1921
H2N(Cl)C6H3CF3
195.57
H2N(Cl)C6H3COC6H4COOH
275.69
H2NC6H4⫺C6H4Cl
203.67
128–134
H2NC6H2(Cl)(OCH3)COOH
201.61
206 d
H2N(Cl)C6H3OH
143.57
13, 383
139–143
H2N(Cl)(C5H3N)
129.56
222, 332
135–138
1.386
1.506920
14810mm
⬎110
673mm
none
⬎110
36–38
14, 661
171–173
2-Aminobutane, b510
4-Aminobutyraldehyde diethyl acetal, d299
Aminobutyric acids, a133, a133a, a134
i aq; s alc, acet, bz,
chl, HOAc
12811mm
␣-Aminocaproic acid, a182
⑀-Aminocaproic acid, a183
INTERACTIVE
Aminobenzenethiol, a297
Aminobenzyl cyanide, a255
1-Aminobutane, b509
156.27
RIGHT
a148
(HNC5H9)(CH2)4NH2
(McGHP)
a139
3-(4-Aminobutyl)piperidine
4-Amino-6-chloro-1,3benzenedisulfonamide
2-Amino-4-chlorobenzoic acid
5-Amino-2-chlorobenzoic acid
2-Amino-4⬘-chlorobenzophenone
2-Amino-5-chlorobenzophenone
2-Amino-5-chlorobenzotrifluoride
5-Amino-2-chlorobenzotrifluoride
2-(3-Amino-4-chlorobenzoyl)benzoic
acid
4-Amino-4⬘-chlorobiphenyl
4-Amino-5-chloro-2methoxybenzoic
acid
2-Amino-4-chlorophenol
2-Amino-5-chloropyridine
DEAN #37261
a136
a125
top of page
short
standard
base of DF
3-Aminocrotononitrile
1-[(2-Aminoethyl)amino]-2-propanol
5-Amino-2,3-dihydro1,4-phthalazinedione
2-Amino-4,6-dihydroxypyrimidine
4-Amino-2,6-dihydroxypyrimidine
2-Amino-3,3-dimethylbutane
2-Amino-4,6-dimethylpyridine
4-Amino-2,6-dimethylpyrimidine
6-Amino-1,3-dimethyluracil
5-Amino-2,6-dioxo1,2,3,6-tetrahydro4-pyrimidinecarboxylic acid
␣-Aminodiphenylmethane
2-Aminoethanesulfonic
acid
2-Aminoethanethiol
1-Aminoethanol
2-Aminoethanol
2-(2-Aminoethoxy)ethanol
2-(2-Aminoethylamino)ethanol
1-[(2-Aminoethyl)amino]-2-propanol
a151
a152
a153
a154
a155
1.86
a156
a157
a158
a159
a160
a161
a162
a163
a164
a165
a166
CH3C(NH2)"CHCN
CH3CH(OH)CH2NHCH2CH2NH2
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
0.983725
4
1.478825
Melting
point,⬚C
82.11
118.18
3, 660
177.16
251, 698
319–320
127.10
24, 468
⬎300
127.10
24, 469
⬎300
(CH3)3CCH(NH2)CH3
101.19
4, 193
(CH3)2(NH2)(C5H2N)
122.17
Boiling
point,⬚C
102–103
22, 435
63–64
235
123.16
242, 45
184–186
155.16
24, 471
295 d
171.11
25, 264
⬎300
(C6H5)2CHNH2
183.25
12, 1323
H2NCH2CH2SO3H
125.15
4, 528
d ca. 300
HSCH2CH2NH2
CH2CH(OH)NH2
H2NCH2CH2OH
H2NCH2CH2OCH2CH2OH
77.14
61.08
61.08
105.14
4, 286
4, 274
43, 642
1.011725
4
1.048
1.453920
97–99
97
10.3
H2NCH2CH2NHCH2CH2OH
104.15
4, 286
1.030
CH3CH(OH)CH2NHCH2CH2NH2
118.18
Merck:
12, 458
0.983725
4
1.063522
4
1.413020
1.595020
Solubility in 100
parts solvent
11210mm
⫺20
0.755
Flash
point,⬚C
34
1
156 aq; 18.9 alc
304
⬎110
sl s aq; s acids
5.45 aq12; 0.004 alc17
110 d
171
218–224
93
v s aq; s alc
s aq; sl s eth
misc aq, org solv
1.486120
240753mm
⬎110
v s aq, alc; sl s eth
1.473825
11210mm
INTERACTIVE
a149
a150
Formula
LEFT
Name
(McGHP)
No.
DEAN #37261
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
s acids
top of page
short
standard
base of DF
a168
a169
a171
a172
H2NCH2CH2NHCH2CH2Si(OCH3)3
H2NCH2CH2OSO3H
1.441825
1.87
221, 642
98–100
141.15
4, 276
277 d
160.22
221, 636
118
281.01
Merck:
12, 176
194–195
130.19
273, 370
0.992
1.475520
a152
a170
1370.15mm
25.6
205
i aq, bz, chl, eth; s alc,
acet, HCl
175
s aq, alc, bz, acet,
acids
2-Aminoethanol, e29
1-(2-Aminoethyl)amino-2-[(2aminoethyl)aminoethyl]aminoethane, t56
Aminoethylbenzene, e69, e70
a157
a156
a171
INTERACTIVE
a168
a153
150
RIGHT
a151
14015mm
210.28
2-Amino-1,5-dihydro-1-methyl-4H-imidazol-4-one, c302
2-Aminodiphenylamine, p137
Aminodiphenylmethane, d761
Aminoethane, e63
4-Amino-m-cresol, a213
Aminocyclododecane, c340
Aminocyclohexane, c375
Aminodecane, d23
2-Amino-5-diethylaminopentane, d387
a158
1.0125
4
222.1
(McGHP)
a170
3-(2-Aminoethylamino)propyltrimethoxysilane
3-Amino-9-ethylcarbazole
2-Aminoethyl hydrogen sulfate
3-(2-Aminoethyl)indole
S-2-Aminoethylisothiouronium bromide HBr
N-(2-Aminoethyl)morpholine
DEAN #37261
a167
a172
top of page
short
standard
base of DF
4-(2-Aminoethyl)phenol
N-(2-Aminoethyl)piperazine
N-(2-Aminoethyl)-1,3propanediamine
2-Amino-2-ethyl-1,3propanediol
2-(2-Aminoethyl)pyridine
4-(2-Aminoethyl)pyridine
2-Amino-5-fluorobenzotrifluoride
Aminoguanidine hydrogen carbonate
N-Aminohexamethyleneimine
(⫾)-2-Aminohexanoic
acid
6-Aminohexanoic acid
6-Amino-1-hexanol
(⫺)-2-Amino-3hydroxybutanoic acid
(⫾)-4-Amino-3hydroxybutanoic acid
4-Amino-6-hydroxy-2mercaptopyrimidine
hydrate
2-Amino-4-hydroxy-6methylpyrimidine
4-Amino-3-hydroxy-1naphthalenesulfonic
acid
a174
a175
a176
a177
a178
a179
1.88
a180
a181
a182
a183
a184
a185
a186
a187
a188
a189
HOC6H4CH2CH2NH2
Formula
weight
137.18
Beilstein
reference
Density,
g/mL
Refractive
index
13, 625
Melting
point,⬚C
164–165
1662mm
⫺26
218–222
129.21
0.98520
20
1.498320
H2NCH2CH2CH2NHCH2CH2NH2
HOCH2C(NH2)(C2H5)CH2OH
H2NCH2CH2(C5H4N)
117.20
0.928
1.481520
H2NCH2CH2(C5H4N)
122.17
H2N(F)C6H3CF3
179.12
123, 1991
H2NNHC("NH)NH2 ·H2CO3
(C6H12N)NH2
136.11
3, 117
CH3(CH2)3CH(NH2)COOH
131.17
4, 433
H2N(CH2)5COOH
H2N(CH2)5CH2OH
CH3CH(OH)CH(NH2)COOH
H2NCH2CH(OH)CH2COOH
131.17
117.19
119.12
4, 434
42, 748
4, 514
204–206
56–58
d 255
119.12
42, 938
218 d
161.18
24, 476
⬎300
125.13
24, 343
⬎300
239.25
14, 846
295 d
Flash
point,⬚C
93 (OC)
96
⬎110
1.536020
9312mm
100
1.012
1.540320
1049mm
1.3781
1.460820
8120mm
4,3,850
1.09920
20
1.49020
122.17
22, 434
1.021
38
1.172
1.485020
misc aq; s alc
70
172 d
0.984
Solubility in 100
parts solvent
1 aq15; 10 boiling alc;
s HCl
15210mm
119.16
114.19
Boiling
point,⬚C
i aq; d hot aq
165
56
1.15 aq25; 0.42 alc25; s
acids
v s aq; i alc, s acids
301
13530mm
v s aq; i alc, chl, eth
s aq; sl s alc, chl, eth,
EtOAc
INTERACTIVE
a173
Formula
LEFT
Name
(McGHP)
No.
DEAN #37261
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
i aq, alc, bz, eth
top of page
short
standard
base of DF
a191
a192
a194
a195
a196
239.25
14, 835
sl s aq; i alc, eth
239.25
H2N(HO)(C5H3N)
1.89
2-(2-Aminoethyl)-2-thiopseudourea, a171
1-Aminoheptane, h19
2-Aminoheptane, m272
1-Aminohexane, h81
sl s hot aq; i eth
239.25
14, 849
⬎300
110.12
122, 408
172–174
111.10
24, 314
⬎300
133.19
133.19
12, 1191
121, 511
1.03815
4
2-Aminohexane, m371
p-Aminohippuric acid, a129
Aminohydroxybenzoic acids, a280, a281
2-Amino-2-(hydroxymethyl)-1,3-propanediol, t439
1.561320
0.77 aq; sl s alc
978mm
249745mm
1.5
36
(McGHP)
a193
4-Amino-5-hydroxy-1naphthalenesulfonic
acid
5-Amino-6-hydroxy-2naphthalenesulfonic
acid
6-Amino-7-hydroxy-2naphthalenesulfonic
acid
2-Amino-3-hydroxypyridine
4-Amino-2-hydroxypyrimidine
1-Aminoindane
5-Aminoindane
DEAN #37261
a190
94
⬎110
sl s aq
sl s aq
␣-Amino-4-imidazolepropanoic acid, h83
Aminoiminomethanesulfinic acid, f34
N-(Aminoiminomethyl)-N-methylglycine, c301
RIGHT
a174
a192
a188
a194
a189
a195
a190
INTERACTIVE
a191
a187
a196
top of page
short
standard
base of DF
5-Aminoindazole
6-Aminoindazole
2-Amino-5-iodobenzoic acid
(⫾)-2-Amino-4-mercaptobutanoic acid
Aminomethanesulfonic
acid
3-Amino-4-methoxybenzoic acid
2-Amino-1-methoxypropane
5-Amino-2-methoxypyridine
4⬘-Amino-N-methylacetanilide
4-Amino-3-methylbenzenesulfonic acid
2-Amino-5-methylbenzoic acid
3-Amino-4-methylbenzoic acid
2-Amino-3-methyl-1butanol
2-(Aminomethyl)-1ethylpyrrolidine
2-Amino-3-methyl-1pentanol
2-Amino-4-methyl-1pentanol
4-Amino-3-methylphenol
4-(Aminomethyl)piperidine
a200
a201
a202
a203
a204
1.90
a205
a206
a207
a208
a209
a210
a211
a212
a213
a214
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
H2N(I)C6H3COOH
133.15
133.15
263.03
252, 308
25, 317
14, 373
175–178
206 d
221 d
HSCH2CH2CH(NH2)COOH
135.19
43, 1647
232–233
H2NCH2SO3H
111.12
1, 583
185 d
CH3O(NH2)C6H3COOH
167.16
141, 657
210
CH3OCH2CH(CH3)NH2
84.14
44, 1615
CH3O(NH2)(C5H3N)
124.14
222, 408
CH3ON(CH3)C6H4NH2
164.21
131, 30
90–92
H2NC6H3(CH3)SO3H
187.22
14, 726
⬎300
H2N(CH3)C6H3COOH
151.17
14, 481
175 d
sl s aq; s alc, eth
H2N(CH3)C6H3COOH
151.17
14, 487
167–169
s aq
(CH3)2CHCH(NH2)CH2OH
103.17
43, 805
128.22
CH2CH2CH(CH3)CH(NH2)CH2OH
CH3CH(CH3)CH2CH(NH2)CH2OH
H2N(CH3)C3H3OH
0.845
1.574520
0.906
1.454320
0.887
1.466520
1.458920
117.19
117.19
1.406520
4, 298
0.917
35–36
30
1.449620
123.16
114.19
31
sl s aq, PE; s alc
v s aq
93
8
901mm
⬎110
808mm
90
6016mm
60
9714mm
100
200
90
200
78
INTERACTIVE
a197
a198
a199
Formula
LEFT
Name
(McGHP)
No.
DEAN #37261
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
179
1.490020
25
top of page
short
standard
base of DF
a216
a217
a218
a220
a221
a222
a223
a224
1.91
a225
HOCH2C(CH3)(NH2)CH2OH
(CH3)2C(NH2)CH2OH
89.14
43, 783
(CH3)2C(NH2)COOH
103.12
4, 414
H2NCH2(C5H4N)
108.14
1.049
1.544020
H2NCH2(C5H4N)
108.14
1.062
1.551020
H2NCH2(C5H4N)
108.14
223, 4181
1.065
H2N(CH3)(C5H3N)
108.14
222, 342
1.073
H2N(CH3)(C4H3N)
108.14
H2N(CH3)(C4H3N)
0.93420
20
1.448020
15110mm
25
165
335 (sealed
tube)
280 subl
250 aq20; s alc
67
90
⫺21
741mm
100
1.551520
⫺8
230
108
1.582320
32–34
222
111
222, 342
98–100
230
108.14
221, 633
42–45
209
109.13
24, 84
160
subl
114.17
27, 159
44–46
232
v s aq, alc, DMF
103
v s aq
s hot aq; s alc
⬎110
v s aq, alc, eth
3-Amino-␣-methylbenzyl alcohol, a256
2-Amino-3-methylpentanoic acid, i88
2-Amino-2-methylpropane, b511
a214
a224
INTERACTIVE
a210
misc aq; s alc, org solv
v s aq
8512mm
2-Amino-3-mercaptopropanoic acid, c411
1-Amino-2-methoxyethane, m77
␣-(Aminomethyl)benzyl alcohol, a257
a198
108–110
RIGHT
2-Aminoisobutanol, a216
2-Aminoisobutyric acid, a217
5-Aminoisophthalic acid, a114
a197
105.14
(McGHP)
a219
2-Amino-2-methyl-1,3propanediol
2-Amino-2-methyl-1propanol
2-Amino-2-methylpropionic acid
2-(Aminomethyl)pyridine
3-(Aminomethyl)pyridine
4-(Aminomethyl)pyridine
2-Amino-3-methylpyridine
2-Amino-4-methylpyridine
2-Amino-6-methylpyridine
2-Amino-4-methylpyrimidine
2-Amino-4-methylthiazole
DEAN #37261
a215
a225
top of page
short
standard
base of DF
2-Aminomethyl-3,5,5trimethylcyclohexanol
N-Aminomorpholine
1-Aminonaphthalene
2-Aminonaphthalene
2-Amino-1-naphthalenesulfonic acid
5-Amino-2-naphthalenesulfonic acid
8-Amino-2-naphthol
2-Amino-4-nitrobenzoic acid
2-Amino-5-nitrobenzonitrile
5-Amino-5-nitrobenzophenone
2-Amino-6-nitrobenzothiazole
4-Amino-3-nitrobenzotrifluoride
2-Amino-4-nitrophenol
2-Amino-5-nitrophenol
4-Amino-2-nitrophenol
D-(⫺)-threo-2-Amino1-(4-nitrophenyl)1,3-propanediol
2-Amino-5-(4-nitrophenylsulfonylthiazole
2-Amino-5-nitropyridine
2-Amino-5-nitrothiazole
a227
a228
a229
a230
a231
a232
a233
1.92
a234
a235
a236
a237
a238
a239
a240
a241
a242
a243
a244
Formula
weight
Beilstein
reference
171.29
Density,
g/mL
Refractive
index
0.969
1.490420
1.059
1.13
1.477220
Melting
point,⬚C
43–48
Boiling
point,⬚C
Flash
point,⬚C
265
⬎110
168
301
306
58
157
Solubility in 100
parts solvent
(C10H7)NH2
(C10H7)NH2
H2N(C10H6)SO3H
102.14
143.18
143.18
223.25
27, 8
12, 1212
12, 1212
14, 736
H2N(C10H6)SO3H
223.25
14, 758
180
0.17 aq; v s alc, eth
s hot aq, alc, eth
0.031 aq; sl s hot aq; s
dil alkali
sl s aq; s hot aq
H2NC10H6OH
H2N(NO2)C6H3COOH
159.19
182.14
13, 685
14, 374
207
270 d
i aq; v s alc, eth
H2N(NO2)C6H3CN
163.14
142, 234
200–207
C6H5COC6H4(NH2)NO2
242.23
14, 79
166–168
195.20
272, 232
247–249
H2N(NO2)C6H3CF3
206.12
O2N(NH2)C6H3OH
O2N(NH2)C6H3OH
O2N(NH2)C6H3OH
HOCH2C(NH2)C(OH)C6H4NO2
154.13
154.13
154.13
212.21
105–106
132, 192
13, 390
13, 520
285.30
H2N(C5H3N)NO2
48–50
111–113
dec
143–145
202 d
125–127
163–165
222–226
139.11
221, 631
186–188
sl s aq, bz, eth
145.14
Merck:
12, 477
d 202
s sl s aq; 0.7 alc; 0.4
ether; s dil acids
INTERACTIVE
a226
Formula
LEFT
Name
(McGHP)
No.
DEAN #37261
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
top of page
short
standard
base of DF
123, 160
0.938
1.480720
4910mm
35
H(CH2)3CH(NH2)CH3
C2H5CH(NH2)C2H5
H(CH2)3CH(NH2)COOH
87.17
87.17
117.15
4, 177
4, 179
4, 416
0.73920
0.74920
4
1.404720
1.405520
91–92
91
320 subl
1
H2N(CH2)4COOH
H2N(CH2)5OH
H2NC6H4CH2CH2OH
117.15
103.17
137.18
4, 418
41, 441
133, 1679
12216mm
1484mm
65
⬎112
H2NC6H4OH
H2NC6H4OH
109.13
109.13
13, 354
13, 401
170–174
122–123
16411mm
13, 427
190
1503mm
45–48
312
a252
a253
a254
4-Aminophenol
H2NC6H4OH
109.13
a255
4⬘-Aminophenylacetonitrile
1-(3-Aminophenyl)ethanol
2-Amino-1-phenylethanol
H2NC6H4CH2CN
132.17
H2NC6H4CH(CH3)OH
137.18
133, 1654
68–71
H2NCH2CH(C6H5)OH
137.18
132, 361
56–58
a246
a247
a248
a249
a250
a251
a256
1.93
a257
1-Aminonaphthalene, n17
1-Amino-2-naphthol-4-sulfonic acid, a189
303
0.949
1.045
1.461520
1.584920
1-Amino-2-naphthol-6-sulfonic acid, a197
1-Aminoorotic acid, a158
158–161
35–37
16017mm
⬎110
s aq, alc, eth, PE
misc aq, alc, eth
5.5 aq18; v sl s alc, chl,
eth, PE
v s aq; sl s alc; i eth
2 aq; 4.3 alc; v s eth
2.5 aq; v s hot aq, alc,
eth
0.65 aq; 4.5 alc; 9.3
EtMeKetone58; s eth
sl s hot aq; s alc
(McGHP)
111.19
exo-2-Aminonorbornane
2-Aminopentane
3-Aminopentane
DL-2-Aminopentanoic
acid
5-Aminopentanoic acid
5-Amino-1-pentanol
2-Aminophenethyl alcohol
2-Aminophenol
3-Aminophenol
DEAN #37261
a245
v s aq; s alc
1-Aminopentane, p53
RIGHT
a226
a242
a236
a244
INTERACTIVE
a227
a245
top of page
short
standard
base of DF
1S,2S-(⫹)-2-Amino-1phenyl-1,3-propanediol
L-2-Amino-3-phenyl1-propanol
3-Amino-1-phenyl-2pyrazolin-5-one
N-Aminopiperidine
3-Amino-1,2-propanediol
DL-1-Amino-2-propanol
DL-2-Amino-1-propanol
S-(⫹)-2-Amino-1-propanol
3-Amino-1-propanol
2-Amino-1-propene1,1,3-tricarbonitrile
3-Aminopropyl-(diethoxy)methylsilane
1-(3-Aminopropyl)imidazole
N-(3-Aminopropyl)iminodiethanol
N-(3-Aminopropyl)morpholine
N-(3-Aminopropyl)-2pyrolidinone
3-Aminopropyltriethoxysilane
3-Aminopropyltrimethoxysilane
2-Aminopyridine
a259
a260
a261
a262
a263
a264
1.94
a265
a266
a267
a268
a269
a270
a271
a272
a273
a274
a275
Beilstein
reference
Density,
g/mL
Refractive
index
C6H5CH(OH)CH(NH2)CH2OH
167.21
13,4, 2968
109–113
C6H5CH2(NH2)CH2OH
151.21
133, 1757
92–94
175.19
20, 89
4, 301
0.928
1.175
1.475020
1.492020
CH3CH(OH)CH2NH2
75.11
4, 289
0.973
1.448320
CH3CH(NH2)CH2OH
75.11
41, 432
0.943
CH3CH(NH2)CH2OH
75.11
43, 735
Solubility in 100
parts solvent
36
⬎110
160
76
v s aq, alc; i eth
1.449520
173–176
83
v s aq, alc, eth
0.965
1.449820
176
62
v s aq, alc, eth
4, 288
Merck:
11, 495
0.982
1.461020
188
79 (TOC)
s aq, alc
s aq
0.91620
4
1.42720
1.049
1.519020
162.23
0.1071
1.498020
144.22
0.987220
20
1.476120
142.20
1.014
1.50020
75.11
132.13
H2N(CH2)3Si(CH3)(OCH2CH3)2
191.4
125.18
H2N(CH2)3Si(OC2H5)3
221.37
H2N(CH2)3Si(OCH3)3
179.29
(C5H4N)NH2
Flash
point,⬚C
146730mm
265739mm
H2NCH2CH2CH2OH
NCC(CN)"C(NH2)CH2CN
H2N(CH3)N(CH2CH2OH)2
Boiling
point,⬚C
210 d
100.17
91.11
H2NCH2CH(OH)CH2OH
Melting
point,⬚C
94.12
233, 577
20
4
0.9506
10–12
171–173
888mm
⬎110
⫺15
20
1.4225
1.0125
4
22, 428
⫺2
1.42025
58.1
1702mm
137
224
98
1231mm
⬎110
217
104
808mm
83
210.6
92
misc aq, alc, bz
INTERACTIVE
a258
Formula
weight
Formula
LEFT
Name
(McGHP)
No.
DEAN #37261
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
s aq, alc, bz, eth
top of page
short
standard
base of DF
(C5H4N)NH2
(C5H4N)NH2
94.12
94.12
95.11
158.20
22, 431
22, 433
24, 80
22, 453
64
160–162
125–127
167–169
a280
4-Aminosalicylic acid
H2NC6H3(OH)CO2H
153.14
14, 579
150–151
a281
a282
5-Aminosalicylic acid
2-Aminoterephthalic
acid
5-Amino-1,2,3,4-tetrazole hydrate
H2NC6H3(OH)CO2H
H2NC6H3(CO2H)2
153.14
181.15
14, 579
14, 558
280 d
324 d
103.08
26, 403
204 d
a283
1-Aminopropane, p223
2-Aminopropane, i100
3-Amino-1-propene, a76
N-(3-Aminopropyl)diethanolamine, a270
6-Aminopurine, a66
4-Aminophenyl phenyl ether, p70
Aminophenyl sulfones, d47, d48
3-Aminophthalhydrazide, a151
5-Amino-m-phthalic acid, a114
Aminopicolines, a222, a223
250–252
273
subl
333
s aq, alc, bz, eth
s aq, alc; sl s bz, eth
v s aq
sl s aq; v s alc, eth,
acet; s hot bz
0.2 aq; 4.8 alc; s dil
acids, alk; sl s eth
(McGHP)
3-Aminopyridine
4-Aminopyridine
2-Aminopyrimidine
4-Aminoquinaldine
DEAN #37261
a276
a277
a278
a279
2-Amino-3-pyridinol, a193
Aminopyrimidinediols, a152, a153
2-Aminosuccinamic acid, a301
Aminosuccinic acid, a304
6-Amino-2-thiouracil, a187
1.95
RIGHT
a260
a271
a269
a278
a279
INTERACTIVE
a272
a261
a283
top of page
short
standard
base of DF
DEAN #37261
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Name
a284
2-Amino-1,3,4-thiadiazole
2-Aminothiazole
a285
a286
a287
a288
Formula
Formula
weight
100.14
27, 155
93
H2NC6H4SH
H2NC6H3(CH3)SO3H
100.14
125.19
187.22
27, 136
13, 397
14, 726
84.08
170.30
26, 137
H2N(C6H7)(CH3)3CH2NH2
129.59
a295
a296
a297
2-Anilinoethanol
3-Anilinopropionitrile
Anthracene
C6H5NHCH2CH2OH
C6H5NHCH2CH2CN
137.18
146.19
178.23
a298
9,10-Anthraquinone
1.96
Antipyrine
a300
a301
L-(⫹)-Arabinose
L-(⫹)-Arginine
H2N(CH2)10CO2H
C6H5NH2
0.922
1.488020
0.901
1.473320
201.31
93.12
208.20
H2NC("NH)NH(CH2)3CH(NH2)CO2H
1.642020
79–82
19–21
⬎300
150–153
10
Flash
point,⬚C
Solubility in 100
parts solvent
sl s aq, alc, eth; s hot
aq, HCl
s HCl
720.1mm
79
i aq12; v s hot aq
s aq, alc, chl
247
⬎110
221
97
⫺6
184–186
70
198
245
193 (CC)
15210mm
190–192
12, 59
1.02720
20
Merck:
12, 696
12, 182
1.222
1.085
1.586320
1.579320
339–342
153
⬎110
121 (CC)
185 (CC)
5, 657
1.2527
4
52–53
215-218
7, 781
1.4320
4
286
377
111–114
319
188.23
24, 27
150.13
174.20
31, 32
4, 420
113
4
1.088
157–160
d 240
3.5 aq25; s acids; misc
most org solv
100 aq; v s alc
sl s aq; v s alc, chl, eth
1.5 alc; 1.6 bz; 1.2 chl;
3.1 CS2; 0.5 eth; i
aq
0.44 alc25; 0.6 chl20;
0.2 bz20; 0.11 eth25
100 aq; 77 alc; 100
chl; 2.3 eth
100 aq; 0.4 alc
15 aq21; sl s alc
INTERACTIVE
C6H5NH2 ·HCl
156.27
1.170
Boiling
point,⬚C
LEFT
Aniline hydrochloride
a299
Melting
point,⬚C
190–192
a294
a292
Refractive
index
27, 624
a293
a291
Density,
g/mL
101.13
2-Amino-2-thiazoline
2-Aminothiophenol
2-Aminotoluene-5-sulfonic acid
3-Amino-1,2,4-triazole
5-Amino-1,3,3-trimethylcyclohexanemethylamine
5-Amino-2,2,4-trimethylcyclopentanemethylamine
11-Aminoundecanoic
acid
Aniline
a289
a290
Beilstein
reference
(McGHP)
No.
top of page
short
standard
base of DF
L-(⫹)-Ascorbic
acid
a303
L-(⫹)-Asparagine
H2NCOCH2CH(NH2)CO2H
176.12
183, 3038
132.12
4, 476
1.6525
190–192
33 aq; 3.3 alc; 1 glyc;
i bz, chl, eth, PE
3.5 aq28; s alkalis, acids; i alc, bz, eth
235
(McGHP)
Anisamide, m54
Anisic acids, m57, m58, m59
Anidisines, m48, m49, m50
Anisole, m55
p-Anisoyl chloride, m60
p-Anisyl alcohol, m61
Anthranilamide, a112
Anthranilic acid, a118
Araboascorbic acid, i61
APDC, p282
Arsanilic acids, a113
tert-Amylamine, d701
Amyl bromides, b325, b326
Amyl chloride, c204a
␣-Amylcinnamaldehyde, p56
Amyl ether, d738
Amyl iodide, i47
Amyl mercaptan, p37
Amyl methyl ketone, h14
Anethole, m107
Angelic acid, m169
Anilinesulfonic acids, a115, a116, a117
Anisaldehydes, m51, m52, m53
5-Amino-o-toluenesulfonic acid, a206
2-Amino-1,1,3-tricyanopropene, a267
1-Aminotricyclo[3.3.13,7]decane, a65
Aminouracil, a153
2-Aminovaleric acid, a248
5-Aminovaleric acid, a249
AMP, a216
Amyl compounds, see also Pentyl
Amyl alcohol, p39
act-Amyl alcohol, m161
sec-Amyl alcohol, p40
tert-Amyl alcohol, m162
DEAN #37261
a302
1.97
a285
a299
a297
a291
a300
INTERACTIVE
a298
a289
a286
RIGHT
a284
a302
top of page
short
standard
base of DF
DEAN #37261
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Name
a304
L-(⫹)-Aspartic
a305
a306
1.98
a307
a308
a309
a310
a311
a312
a313
Formula
acid
HO2CCH2CH(NH2)CO2H
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
1.66112.5
Melting
point,⬚C
Atropine
289.38
21, 27
114–116
Aurintricarboxylic
acid, triammonium
salt
2-Azacyclooctanone
2-Azacyclotridecanone
Azidotrimethylsilane
Azidotriphenylsilane
1-Aziridineethanol
Azobenzene
2,2⬘-Azobis(2-methylpropionitrile)
473.44
102, 775
225 d
127.19
197.32
115.21
301.4
87.12
182.23
164.21
21, 242
35–38
150–153
⫺95
83–84
16, 8
4, 563
116.08
258.28
3, 123
16, 637
225 d
120
128.17
128.09
337.86
106.12
121.13
197.24
228.29
228.29
52, 432
24, 467
13, 765
7, 174
9, 195
12, 262
5, 718
52, 628
1.22
1.05015
4
1.3414
1.315
99–100
252 d
250 d
⫺26
129–130
163
155–157
357 (Cu
block)
5.5
(CH3)3SiN3
(C6H5)3SiN3
(C2H4N)CH2CH2OH
C6H5N"NC6H5
(CH3)2C(CN)N"NC(CN)(CH3)2
H2NCON"NCONH2
H3OC6H4N"N( : O)C6H4OCH3
270–272
0.868
1.414020
1.088
1.20320
4
1.456020
67–68
a314
a315
Azodicarbonamide
4,4⬘-Azoxydianisole
a316
b1
b2
b3
b4
b5
b6
b7
Azulene
Barbituric acid
Basic fuchsin
Benzaldehyde
Benzamide
Benzanilide
1,2-Benzanthracene
2,3-Benzanthracene
b8
Benzene
C6H6
78.11
5, 179
0.878715
4
1.501120
b9
Benzene-1,3,5-d3
C6H3D3
81.14
53, 518
0.908
1.499020
C6H5CHO
C6H5CONH2
C6H5CONHC6H5
1.545620
1.35
0.45 aq; s alkalis,
acids; i alc, eth
0.22 aq; 50 alc; 4 eth;
100 chl; 3.9 glyc; s
bz, dil acids
v s aq
subl 110
high
vac
14810mm
⬎110
95–96
1000.01mm
168
293
107 d
23
67
4.2 alc20; s eth, HOAc
2 EtOH;20 5 MeOH;20
can explode in acetone
i aq, alc; s hot aq
242
179
288–290
11710mm
437.6
subl
63
80.0
⫺11
(CC)
⫺11
(CC)
80
Solubility in 100
parts solvent
i aq; s org solvents
s hot aq, dil acids
0.3 aq; s alc, acids
0.3 aq; misc alc, eth
1.3 aq; 17 alc; 30 pyr
i aq; 1.7 alc; sl s eth
sl s hot aq; s org solv
sl s most org solv
0.17 aq; misc most org
solv
similar to ordinary
benzene
INTERACTIVE
4, 472
Flash
point,⬚C
LEFT
133.10
Boiling
point,⬚C
(McGHP)
No.
top of page
short
standard
base of DF
Benzene-13C6
13
b11
Benzene-d6
C6D6
b12
Benzenearsonic acid
C6H5AsO(OH)2
C6H6
84.07
0.949
1.501020
5.5
80
1.498620
6.8
79.1
84.16
53, 519
0.950
202.03
16, 868
1.76025
162
Azine, p257
Aziridine, e148
Azobis(isobutyronitrile), a313
Azole, p279
4,4⬘-Azoxyanisole, a315
Barbitol, d339
similar to ordinary
benzene
similar to ordinary
benzene
2.5 aq; 2 alc; i chl
Behenyl alcohol, d817
Benzal bromide, d132
Benzal chloride, d273
Benzalphthalide, b105
Benzeneacetaldehyde, p77
(McGHP)
Aspirin, a56
Azabenzene, p257
Azacyclopentane, p280
Azacyclopropane, e146
1-Azanaphthalene, q3
Azelaic acid, n93
⫺11
(CC)
⫺11
(CC)
DEAN #37261
b10
1.99
b2
b6
a316
a308
INTERACTIVE
b1
a307
RIGHT
a306
a305
b7
top of page
short
standard
base of DF
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
b13
Benzeneboronic acid
C6H5B(OH)2
121.94
16, 920
216
b14
1,4-Benzenedicarbaldehyde
C6H4(CHO)2
134.13
7, 675
113
248
b15
1,2-Benzenedicarbonyl
dichloride
1,4-Benzenedicarbonyl
dichloride
1,3-Benzenedicarboxylic acid
1,4-Benzenedicarboxylic acid
1,4-Benzenedimethanol
Benzenehexacarboxylic acid
Benzenesulfinic acid
Benzenesulfonamide
Benzenesulfonic acid
C6H4(COCl)2
203.02
9, 834
15–16
280–282
C6H4(COCl)2
203.02
9, 844
81
266
C6H4(COOH)2
166.13
9, 832
345–348
subl
9, 841
subl 402
Benzenesulfonyl chloride
Benzenesulfonyl fluoride
Benzenesulfonyl hydrazide
1,2,4,5-Benzenetetracarboxylic acid
1,2,4,5-Benzenetetracarboxyl dianhydride
1,2,3-Benzenetricarboxylic acid dihyrate
b16
b17
b18
1.100
b19
b20
b24
b25
b27
b28
1431mm
37 bz; 9 CCl4
0.012 aq; v s alc,
HOAc; i bz, PE
sl s alc; s alkalis; v sl s
aq, chl, eth
C6H4(CH2OH)2
138.17
6, 919
C6(COOH)6
342.17
9, 1008
286 d
C6H5S("O)OH
C6H5SO2NH2
C6H5SO2OH
142.16
157.19
158.18
11, 2
11, 39
11, 26
85
150–152
50–51
100 d
C6H5SO2Cl
176.62
11, 34
1.384215
15
1.551820
14.5
12010mm
⬎110
sl s aq; s alc, bz, eth
i aq; sl s alc; s eth
v s aq, alc; sl s bz; i
CS2, eth
i aq; s alc, eth
C6H5SO2F
160.17
112, 23
1.328620
4
1.492020
⫺5
207–208
87
s alc, eth
C6H5SO2NHNH2
172.21
11, 52
d 104
flammable solid
C6H2(COOH)4
254.15
9, 997
276
1.5 aq; v s alc
218.12
19, 196
283–286
246.18
9, 976
192 d
C6H3(COOH)3 ·2H2O
117–119
180
188
v s aq, alc
397–400
sl s aq; v s eth
INTERACTIVE
b29
1.100117
2.5 aq; 1.8 bz; 30 eth;
178 MeOH
i aq; 6 bz; 17 acet; 2
eth; 14 diox; 46
MeOH
d aq, alc; s eth
ROTATED
b26
166.13
Solubility in 100
parts solvent
LEFT
b21
b22
b23
C6H4(COOH)2
1.40920
Flash
point,⬚C
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
C6H3(COOH)3
210.14
9, 997
231 d
C6H3(COOH)3
210.14
9, 978
⬎330
192.13
18, 468
161–163
24514mm
35–36
18016mm
b34
b35
1,2,4-Benzenetricarboxylic acid
1,3,5-Benzenetricarboxylic acid
1,2,4-Benzenetricarboxylic anhydride
1,3,5-Benzenetricarboxylic trichloride
1,2,4-Benzenetriol
Benzil
141
95
346–348
b36
Benzil dioxime
b37
Benzilic acid
b38
b39
b40
Benzil monohydrazone
Benzimidazole
7,8-Benzo-1,3-diazaspiro[4,5]decane2,4-dione
1,4-Benzodioxan
b31
b32
b33
1.101
b41
C6H3(COCl)3
265.48
C6H3(OH)3
C6H5CO9COC6H5
126.11
210.23
6, 1087
7, 747
C6H5C("NOH)C("NOH)C6H5
(C6H5)2C(OH)COOH
240.25
73, 3816
228.24
10, 342
C6H5C("NNH2)COC6H5
224.26
118.13
216.23
71, 394
23, 131
Merck:
12, 9372
136.15
50 acet; 22 EtOAc; 15
DMF
⬎110
v s aq, alc, eth, EtOAc
i aq; s alc, bz, chl,
EtOAc, eth
i aq, HOAc, eth; sl s
alc; s NaOH
sl s aq; v s alc, eth hot
aq
(␣) 240
(␤) 214
150
150–152
170.5
268
1.142
1.549020
⬎360
1036mm
1,4-Benzenediol, h86
Benzenemethanol, b78
1,2,3-Benzenetriol, t317
Benzenethiol, t156
Benzhydrazide, b71
Benzhydrol, d760
Benzhydrylamine, d761
sl s aq, eth; v s alc
s alc, HOAc
87
Benzhydryl bromide, b326
p-Benzidine, b140
2-Benzimidazolethiol, m17
1,3-Benzodiazole, b39
1,2,3-Benzodioxaborole, c22
1,3-Benzodioxole, m251
RIGHT
Benzeneazobenzene, a312
Benzenecarbonitrile, b51
Benzenecarbonyl chloride, b66
Benzenecarboxyaldehyde, b3
Benzenecarboxylic acid, b44
Benzene-1,2-dicarboxylic acid, p168
Benzene-1,2-dicarboxylic anhydride, p169
1.2315
4
2.1 aq; 25.3 alc; 7.9
acet; v s eth
sl s aq; v s alc; s eth
DEAN 37261 (McGHP)
b30
ROTATED
b32
b39
b40
b41
INTERACTIVE
b28
No.
Name
b42
2,3-Benzofuran
b43
b44
Benzofurazan-1-oxide
Benzoic acid
b45
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
1.566020
Flash
point,⬚C
Solubility in 100
parts solvent
1.102
i aq; misc alc, bz, eth,
PE
1.321
69–71
122.4
249
121 (CC)
9, 164
1.198915
4
42
360
110
212.25
8, 167
1.310020
4
137
19412mm
C6H5CH(C2H5)COC6H5
C6H5CH[OCH2CH(CH3)2]COC6H5
C6H5CH(OCH3)COC6H5
C6H5CH(OH)C("NOH)C6H5
C6H5CN
240.30
268.36
8, 174
1.101617
4
0.985
62
19520mm
1330.5mm
0.29 aq25; 43 alc; 10
bz; 22 chl; 33 eth;
33 acet; 30 CS2
i aq; s alc, acet, chl bz,
HOAc, EtOAc
s hot alc, acet; 20 pyr;
sl s eth
s alc, bz, eth
85
226.28
227.26
8, 174
8, 175
1.127814
4
48
152–156
18915mm
⬎110
v s alc, bz, eth
sl s aq; s alc, NH4OH
103.12
202.26
9, 275
5, 718
1.010
1.27420
4
1.528920
⫺12.7
258
191
448
71
0.2 aq; misc org solv
i aq; s alc, eth
C6H5COC6H5
C6H5C("NNH2)C6H5
182.22
196.25
7, 411
7, 417
1.110818
4
1.597545
48
95–98
305
23055mm
⬎110
13.3 alc; 17 eth; s chl
146.15
17, 327
55–60
252.32
Merck:
12, 1134
Merck:
12, 1105
7, 609
179
136.11
122.12
271, 740
9, 92
Benzoic anhydride
(C6H5CO)2O
226.22
b46
DL-Benzoin
C6H5COCH(OH)C6H5
b47
b48
Benzoin ethyl ether
Benzoin isobutyl ether
b49
b50
Benzoin methyl ether
␣-Benzoinoxime
b51
b52
b56
Benzonitrile
1,2-Benzophenanthrene
Benzophenone
Benzophenone hydrazone
1-Benzopyran-4(4H)one
1,2-Benzo[a]pyrene
b57
4,5-Benzo[e]pyrene
b58
1,4-Benzoquinone
b59
Benzothiazole
135.19
b60
Benzo[b]thiophene
134.20
252.32
C6H4("O)2
108.10
Merck:
12, 1139
17, 59
1.572717
1.548520
1.31820
4
31210mm
s bz; sl s alc
179
s bz
116
1.246020
4
1.637920
2
13134mm
⬎110
sl s aq; s alc, hot bz,
eth, hot PE; alkalis
with dec
sl s aq; v s alc, CS2
1.193740
1.630240
32
221
⬎110
s alc, bz, chl, eth
INTERACTIVE
C6H5COOH
ROTATED
56
1.072
LEFT
173–175
17, 54
b55
Boiling
point,⬚C
⬍⫺18
118.13
b53
b54
Melting
point,⬚C
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
1,2,3-Benzotriazole
b62
b63
b64
b65
b66
Benzoxazole
1-Benzoylacetone
2-Benzoylbenzoic acid
Benzoyl bromide
Benzoyl chloride
b67
b68
b69
Benzoyl cyanide
Benzoyl fluoride
Benzoylformic acid
119.13
26, 38
C6H5COCH2COCH3
C6H5COC6H4COOH
C6H5COBr
C6H5COCl
119.12
162.19
226.23
185.03
140.57
27, 42
7, 680
10, 747
9, 195
9, 182
C6H5COCN
C6H5COF
C6H5COCOOH
131.13
124.11
150.13
10, 659
9, 181
10, 654
1.238
1.642020
98.5
1.5594
30
60
129
⫺24
⫺1.0
1.09060
60
1.546720
1.21120
4
1.588320
1.553720
1.106
1.140
1.496020
32
⫺28
67–69
Benzo[def]phenanthrene, p255
Benzopyridine, q3
Benzoresorcinol, d443
2-Benzothiazolethiol, m19
Benzotrichloride, t251
Benzofuroxan, b43
Benzoglyoxaline, b39
Benzoic acid hydrazide, b71
Benzhydroxylamine, a159
o-Benzoic sulfimide, s1
204 may
explode
182
260 sl d
265
219
197.2
90
88 (CC)
206
161
48
58
sl s aq; s alc, bz, chl,
DMF
sl s aq
sl s aq; v s alc, eth
sl s aq; v s alc, eth
d aq, alc; misc eth
d aq, alc; misc bz, eth
CS2
i aq
d hot aq; v s alc, eth
DEAN 37261 (McGHP)
b61
Benzotrifluoride, t311
Benzoylamide, b4
Benzoylbenzene, b53
Benzoyl peroxide, d69
1,2-Benzophenanthrene, b6
1.103
b52
b43
b55
b56
RIGHT
b42
ROTATED
b57
b59
b61
b62
INTERACTIVE
b60
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
1.104
C6H5CONHCH2COOH
179.18
9, 225
179
b71
b71a
b72
Benzoylhydrazine
Benzoyl peroxide
3-Benzoylpropanoic
acid
2-Benzoylpyridine
3-Benzoylpyridine
4-Benzoylpyridine
Benzyl acetate
Benzyl acetoacetate
Benzylacetone
Benzyl alcohol
C6H5CONHNH2
(C6H5CO)2O2
C6H5COCH2CH2COOH
136.15
242.23
178.19
9, 319
9, 179
10, 696
117
103–106
117–119
C6H5CO(C5H4N)
C6H5CO(C5H4N)
C6H5CO(C5H4N)
CH3CO2CH2C6H5
CH3COCH2CO2CH2C6H5
C6H5CH2CH2COCH3
C6H5CH2OH
183.21
183.21
183.21
150.18
192.21
148.21
108.14
21, 330
21, 331
21, 331
6, 435
6, 438
7, 314
6, 428
44
40
71
⫺51.5
Benzylamine
N-Benzylaminoethanol
3-(Benzylamino)propanonitrile
N-Benzylbenzamide
Benzyl benzoate
2-Benzylbenzoic acid
C6H5CH2NH2
C6H5CH2NHCH2CH2OH
C6H5CH2NHCH2CH2CN
107.16
151.21
160.22
C6H5CH2NHCH2C6H5
C6H5CO2CH2C6H5
C6H5CH2C6H4COOH
Benzyl bromide
Benzyl 2-bromoacetate
Benzyl-tert-butanol
Benzyl butyl 1,2phthalate
Benzyl carbamate
Benzyl chloride
b73
b74
b75
b76
b77
b77a
b78
b79
b80
b81
b82
b83
b84
b85
b86
b87
b88
b89
b90
1.05025
4
1.112
0.989
1.045320
4
1.499825
1.512120
1.512220
1.540320
12, 1013
12, 1040
0.98319
4
1.065
1.024
1.540120
1.543520
1.530820
211.26
212.25
212.24
9, 121
92, 471
1.11825
4
1.568121
C6H5CH2Br
BrCH2CO2CH2C6H5
C6H5CH2CH2C(CH3)2OH
C6H5CH2O2C6H4CO2C4H9
171.04
229.08
164.25
312.37
5, 306
61, 220
6, 548
92, 594
1.438022
0
1.446
1.11925
25
1.575220
1.544020
1.509020
1.540020
C6H5CH2OCONH2
C6H5CH2Cl
151.17
126.59
6, 437
5, 292
1.10020
20
1.538120
⫺15.2
10
106
21
110–113
⫺3.9
31–33
87–89
⫺43 to
⫺49
Solubility in 100
parts solvent
0.4 aq; 0.1 chl; 0.25
eth; sl s alc; i bz,
PE
explodes
2.5 CS2; s bz, chl, eth
sl s aq; s alc
317
397
315
213.5
15910mm
235
205
150
150
150
102 (CC)
⬎110
98
93 (CC)
185
15612mm
60
⬎110
⬎110
323
148
199
17022mm
14485mm
86
⬎110
⬎110
199
220 d
179
67
s alc, bz, eth
s alc, bz, eth
i aq; misc alc, eth
0.08 aq; misc alc, chl,
eth
misc aq, alc, eth
misc alc, chl, eth
sl s aq; s alc, bz, chl,
eth
slowly dec aq
v s alc; sl s eth
misc alc, chl, eth
ROTATED
N-Benzoylglycine
Flash
point,⬚C
RIGHT
b70
Boiling
point,⬚C
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
INTERACTIVE
b93
b94
b95
Benzyl chloroformate
Benzyl chlorothiolformate
Benzyl cinnamate
S-Benzyl-L-cysteine
C6H5CH2OCOCl
C6H5CH2SCOCl
170.60
186.5
6, 437
C6H5CH"CHCO2CH2C6H5
C6H5CH2SCH2CH(NH2)COOH
(CH3)2NCS2CH2C6H5
238.29
211.28
9, 584
6, 465
1.195
1.23730
4
39
214 d
C6H5CH2N[(CH2)17CH3](CH3)2Cl·H2O
442.18
123, 2212
b96a
b97
Benzyl N,N-dimethyldithiocarbamate
Benzyldimethylstearylammonium chloride
hydrate
N-Butyl-N-ethylaniline
Benzyl ethyl ether
C6H5N(CH2C6H5)C2H5
C6H5CH2OC2H5
211.31
136.20
b98
b99
N-Benzylformamide
Benzyl formate
C6H5CH2NHCHO
C6H5CH2O2CH
135.17
136.15
b100
Benzyl 4-hydroxybenzoate
O-Benzylhydroxylamine hydrochloride
Benzylidineaniline
Benzylidenemalononitrile
N-Benzylidenemethylamine
HOC6H4CO2CH2C6H5
228.25
12, 1026
Merck:
12, 1168
12, 1043
Merck:
12, 1169
10,3, 311
C6H5CH2ONH2 ·HCl
159.62
6, 440
C6H5N"CHC6H5
C6H5CH"C(CN)2
181.24
154.17
12, 195
9, 895
1.04550
4
C6H5CH"NCH3
119.17
7, 213
0.967
b96
1.105
b101
b102
b103
b104
211.35
10320mm
800.13mm
91
118
dec aq; s eth
2005mm
⬎110
s alc, eth; i aq, glyc
⬎110
41
Benzyl ethanoate, b76
N-Benzylethanolamine, b80
Benzyl ether, d73
67–69
1.029
0.947820
1.595020
1.495520
1646mm
186
⬎110
misc alc, eth; i aq
61
1.08120
4
203
i aq; s alc
110–112
56
83–85
1.552020
238 subl
⬎110
300
⬎110
8018mm
⬎112
Benzylideneacetone, p94
Benzylideneacetophenone, c23
Benzylidene chloride, d273
s alc, chl, CS2
RIGHT
ROTATED
Benzylaniline, p93
Benzylbenzene, d759
Benzyl cyanide, p82
Benzyl disulfide, d72
1.519020
1.571130
DEAN 37261 (McGHP)
b91
b92
INTERACTIVE
b105
3-Benzylidenephthalide
Benzyl mercaptan
Benzyl methacrylate
N-Benzylmethylamine
3-(N-Benzyl-N-methylamino)-1,2-propanediol
Benzyl methyl sulfide
1-Benzyl-3-methyl-2thiourea
Benzyl nicotinate
4-Benzyloxybenzaldehyde
4-Benzyloxybenzyl alcohol
2-Benzyloxyethanol
4-Benzyloxy-3-methoxybenzaldehyde
4-(Benzyloxymethyl)2,2-dimethyl-1,3dioxolane
Benzyl phenyl sulfide
1-Benzylpiperazine
4-Benzylpiperidine
1-Benzyl-4-piperidone
2-Benzylpyridine
4-Benzylpyridine
1-Benzyl-2-pyrrolidinone
Benzyl salicylate
b106
b107
b108
b109
b110
b111
b112
b113
1.106
b114
b115
b116
b117
b118
b119
b120
b121
b122
b123
b124
b125
Benzyl thiocyanate
Benzyltributylammonium chloride
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
124.21
17, 376
C6H5CH2SH
H2C"C(CH3)CO2CH2C6H5
C6H5CH2NHCH3
C6H5CH2N(CH3)CH2CH(OH)CH2OH
222.24
176.22
138.23
195.26
6, 453
63, 1481
12, 1019
1.05820
1.040
0.939
1.084
1.575120
1.512020
1.523020
1.534120
C6H5CH2SCH3
C6H5CH2NHC("S)NHCH3
138.23
180.27
6, 453
12, 1052
1.015
1.562020
(C5H4N)CO2CH2C6H5
C6H5CH2OC6H4CHO
213.24
212.25
22,3, 366
8, 73
1.165
C6H5CH2OC6H4CH2OH
214.26
C6H5CH2OCH2CH2OH
C6H5CH2OC6H4(OCH3)CHO
152.20
242.29
62, 413
222.28
192, 73
200.30
176.26
175.28
189.26
169.23
169.23
175.23
6, 454
HOC6H4CO2CH2C6H5
228.25
C6H5CH2SCN
C6H5CH2N(C4H9)⫹3 Cl⫺
149.22
312.94
Merck:
12, 1181
6, 460
C6H5CH2SC6H5
C6H5CH2(C5H4N)
C6H5CH2(C5H4N)
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
99–102
20630mm
984mm
184–189
20630mm
⬎110
77
77
⬎110
195–198
73
18912mm
⬎110
265
129
910.1mm
⬎110
41–44
19727mm
6–7
279
1347mm
276
287
⬎110
⬎110
⬎110
⬎110
125
115
⬎110
74–76
1.570020
21–23
73–74
86–87
1.0720
20
1.521020
0.4 aq
63–65
20, 296
20, 425
20, 426
1.051
1.494020
1.014
0.997
1.021
1.054
1.06120
0
1.095
1.546720
1.537920
1.539920
1.579020
1.581820
1.552520
8–10
1.17520
20825mm
43
164 d
235
i aq; sl s alc; s eth
s aq, alc, eth
i aq; v s alc, eth
s alc; v s eth
sl s aq; misc alc, eth
⬎110
i aq; s alc; v s eth
INTERACTIVE
b126
b127
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
b131
b132
b133
Benzyltrichlorosilane
Benzyltriethoxysilane
Benzyltriethylammonium chloride
Benzyltrimethylammonium chloride
Benzyltrimethylsilane
Betaine
C6H5CH2SiCl3
C6H5CH2Si(OC2H5)3
C6H5CH2N(C2H5)⫹3 Cl⫺
1.28820
4
0.98620
4
1.525020
142100mm
17570mm
225.28
254.40
227.78
16, 912
12, 1021
185 d
C6H5CH2N(CH3)3 Cl
185.70
12, 1021
239 d
C6H5CH2Si(CH3)3
(CH3)3N⫹CH2COO⫺
164.32
117.15
16,1, 526
4, 347
⫹
Benzyl methyl ketone, p147
Benzyloxyamine, b101
⫺
0.893320
none
1.494120
190
dec 310
Benzylphenol, h116
o,o-Bibenzoic acid, b141
93
57
160 aq; 55 MeOH; 8.7
EtOH
DEAN 37261 (McGHP)
b128
b129
b130
Bibenzyl, d752
Bicine, b199
1.107
b117
b119
RIGHT
b105
ROTATED
b121
b124
INTERACTIVE
b120
No.
Name
b134
Bicyclo[2.2.1]hepta2,5-diene
Bicyclo[2.2.1]-2-heptene
Bicyclo[2.2.1]-2-heptene-2-carbaldehyde
Biguanide
b135
b136
b137
b138
b139
1.108
b140
b141
b142
b143
b145
b147
b148
b149
Beilstein
reference
92.14
Density,
g/mL
Refractive
index
0.90920
1.470720
94.16
122.16
1.108
Melting
point,⬚C
⫺11
i aq; s PE
44–46
96
⫺15
s eth
7012mm
51
101.11
3, 93
154.20
198.22
5, 578
9, 671
H2NC6H4 9C6H4NH2
HOOCC6H4 9C6H4COOH
184.24
242.23
13, 214
9, 922
C6H5 9C6H4SO3H
234.26
138
226.28
30–32
H2C"CHCH2OC6H4C(CH3)2C6H4 9OCH2CH"CH2
H2N(CH2)3NHCH2CH2NH(CH2)3NH2
308.42
1.022
1.563620
174.29
0.952
1.491020
200.33
232, 12
0.973
1.501520
H2N(CH2)3NHCH2CH2CH2NH(CH2)3NH2
188.32
44, 1278
0.920
1.491520
BrCH2CH2OCH2CH2Br
231.92
[BrCH2Si(CH3)2]2O
320.17
130
dec 142
69–71
226
256
subl
120
228–229
ca. 400
1.471920
s aq, alc; i bz, chl, eth
113 (CC)
s alc; 2 eth; 20 hot alc
0.06 aq; s org solvents
⬎110
15
i aq; s alc, eth
v s alc, eth; s bz; i aq
1200.1mm
1605mm
⬎110
1522mm
162
1031mm
10720mm
1.391820
4
Solubility in 100
parts solvent
89
1.488320
1.58877
Flash
point,⬚C
⫺20
H2NC("NH)NHC("NH)NH2
C6H5 9C6H5
C6H5 9C6H4COOH
0.99175
4
Boiling
point,⬚C
ROTATED
b146
Formula
weight
LEFT
b144
10415mm
INTERACTIVE
Biphenyl
4-Biphenylcarboxylic
acid
4,4⬘-Biphenyldiamine
2,2⬘-Biphenyldicarboxylic acid
4-Biphenylsulfonic
acid
2-Biphenylyl glycidyl
ether
2,2-Bis[4-(allyloxy)phenyl]-propane
N,N⬘-Bis(3-aminopropyl)ethylenediamine
N,N⬘-Bis(3-aminopropyl)piperazine
N,N⬘-Bis(3-aminopropyl)-1,3-propanediamine
Bis(2-bromoethyl)
ether
1,3-Bis(bromoethyl)tetramethyldisiloxane
Formula
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
b151
b152
b153
b154
b155
b156
2,2-Bis(bromomethyl)1,3-propanediol
Bis(2-butoxyethyl)ether
HOCH2CH(CH2Br)2CH2OH
261.95
(C4H9OCH2CH2)2O
218.34
Bis[2-(2-butoxyethoxy)ethyl] adipate
2,5-Bis(5-tert-butyl-22⬘-benzoxazolyl)thiophene
Bis(sec-butyl) disulfide
Bis(tert-butyl) disulfide
1,1-Bis(tert-butylperoxy)cyclohexane
[-CH2CH2CO2(CH2CH2O)2(CH2)3CH3]2
434.58
11, 251
23, 1718
114
0.885320
20
1.424020
⫺60.2
1.010
1.448020
⫺11
430.57
[CH3CH2CH(CH3)]2S2
(CH3)3CSSC(CH3)3
178.36
178.36
C6H10[OOC(CH3)3]2
260.38
1.109
Bicyclo[4.4.0]decane, d2, d3
Bicyclo[5.3.0]decapentane, a316
Biformyl, g28
Biphenol, d436
256
118
0.3 aq; misc alc, esters, eth, CCl4 ketones
110
201
13, 1549
1, 379
0.957
0.909
1.492020
1.493020
164739mm
204
112
79
0.970
1.457020
5415mm
90
Biphenylamines, a130, a131
2,2⬘-Bipyridine, d790
Bis(2-aminoethyl)amine, d362
Bis(4-aminophenyl)ether, o67
DEAN 37261 (McGHP)
b150
1,3-Bis(aminomethyl)cyclohexane, c349
1,2-Bis(benzylamino)ethane, d74
Bis(3-tert-butyl-4-hydroxy-5-ethylphenyl) sulfide, t140
RIGHT
b134
b135
b136
b143
ROTATED
b153
INTERACTIVE
b146
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
2,5-Bis(tert-butylperoxy)-2,5-dimethylhexane
2,5-Bis(tert-butylperoxy)-2,5-dimethyl3-hexyne
Bis[1-(tert-butylperoxy)-1-methylethylbenzene
1,1-Bis(tert-butylperoxy)-3,3,5-trimethyl-cyclohexane
1,2-Bis(2-chloroethoxy)ethane
Bis(2-chloroethoxy)methylsilane
Bis(2-chloroethyl)
ether
Bis(2-chloroethyl)-Nmethylamine
Bis(chloromethyl)dimethylsilane
Bis(chloromethyl)
ether
Bis(2-chloro-1methyl)ethyl ether
1,3-Bis(chloromethyl)tetramethyldisiloxane
Bis(4-chlorophenoxy)acetic acid
b158
b159
b160
1.110
b161
b162
b163
b164
b165
b165a
b166
b167
b168
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
0.877
1.423020
577mm
41
0.881
1.432020
672mm
85
[(CH3)3COOC(CH3)2CH2-]2
290.45
(CH3)3COOC(CH3)2C#CC(CH3)2OOC(CH3)3
286.41
C6H4[C(CH3)2OOC(CH3)3]2
338.49
[(CH3)3COO]2C6H7(CH3)3
302.46
(ClCH2CH2OCH2-)2
187.07
H(CH3)Si(OCH2CH2Cl)2
203.1
ClCH2CH2OCH2CH2Cl
143.01
CH3N(CH2CH2Cl)2
156.07
(CH3)2Si(CH2Cl)2
157.12
43, 1845
1.97520
4
1.460020
ClCH2OCH2Cl
114.96
Merck:
12, 3119
1.31520
4
1.4346
ClCH2CH(CH3)OCH(CH3)CH2Cl
[ClCH2Si(CH3)2]2O
171.07
(ClC6H4O)2CHCOOH
313.14
231.3
14, 2701
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
44–48
13, 2079
12, 335
1.441020
1.19720
4
1.461020
235
1.164320
4
1.443120
9718mm
1.222020
20
1.457520
87
⫺50 to
⫺52
⫺60
⫺41.5
1.1122
1.050
178.5
1.440520
140–142
121
55
7510mm
160
20
20
43, 1864
flammable solid oxidizer
0.906
1.11825
4
Solubility in 100
parts solvent
s most org solvents
v sl s aq; misc most
org solvents
46
106
dec aq
187.3
85
205
73
INTERACTIVE
b157
Formula
ROTATED
Name
LEFT
No.
b170
b171
b172
b173
b174
b175
b176
1.111
b177
b178
b179
b181
b182
Bis(4-chlorophenyl) sulfone, c223
320.05
53, 1830
110
similar to b168
(ClC6H4)2C(OH)CH3
267.16
63, 3396
69
s org solvents
ClC6H4SO2C6H4Cl
287.16
6, 327
145–148
ClC6H4S(O)C6H4Cl
271.17
61, 149
141–144
(ClC6H4)2CHCCl3
354.49
53, 1833
109–111
[-CH2Si(CH3)Cl2]2
256.11
44, 192
[ClCH(CH3)2Si]2O
300.16
[(C2H5O)2CHCH2]2NCH3
263.38
4, 311
[(C2H5)2NC6H4]2C"O
324.47
14, 98
95
(CH3)2NC6H4]2C"O
268.35
14, 89
172
⬎360 d
[(CH3)2N]Si(CH3)2
146.31
44, 4143
0.81022
1.417020
⫺98
128–129
[(CH3)2NCH2]2CHOH
146.23
4, 290
0.897
1.442220
[C6H5C(CH3)2]2C6H3OH
330.47
64, 5076
[(CH3)2C6H3]2CHCH3
238.38
53, 1908
0.982
[(CH3)2NC("S)S-]2
240.43
4, 76
1.29
Bis(2-cyanoethyl) ether, a62
25010mm
58 acet; 78 bz; 45 chl;
v s pyr, 1,4-dioxane
1.263
1.476020
1.221320
4
1.466020
14940mm
0.945
1.425920
222244mm
33–35
210
90
60
s alc, warm bz; v sl s
eth; i aq
⫺7
⬎110
63–65
1.564020
20615mm
1745mm
155–156
⬎110
s alc, eth; sl s bz, acet;
i aq
ROTATED
b183
(ClC6H4)2CHCHCl2
RIGHT
b180
2,2-Bis(4-chlorophenyl)-1,1-dichloroethane
1,1-Bis(4⬘-chlorophenyl)ethanol
Bis(4-chlorophenyl)
sulfone
Bis(4-chlorophenyl)
sulfoxide
1,1-Bis(4-chlorophenyl)-2,2,2-trichloroethane
1,2-Bis(dichloromethylsilyl)ethane
1,3-Bis(dichloromethyl)tetramethyldisiloxane
N,N-Bis(2,2-diethoxyethyl)methylamine
4,4⬘-Bis(diethylamino)benzophenone
4,4⬘-Bis(dimethylamino)benzophenone
Bis(dimethylamino)dimethylsilane
1,3-Bis(dimethylamino)-2-propanol
2,4-Bis(␣,␣-dimethylbenzyl)phenol
1,1-Bis(3,4-dimethylphenyl)ethane
Bis(dimethylthiocarbamyl) disulfide
DEAN 37261 (McGHP)
b169
INTERACTIVE
No.
Name
b184
Bis(3,4-epoxycyclohexylmethyl) adipate
1,4-Bis(2,3-epoxy-propoxy)butane
b185
b186
b187
b188
b189
1.112
b190
b191
b192
b194
b196
b197
b198
Refractive
index
366.46
1.149
1.4930
[H2C 9 CHCH2OCH2CH2⫽]2
202.25
1.049
1.453020
O
(C2H5OCH2CH2)2O
162.23
12, 519
0.90720
4
1.411020
370.58
23, 1715
0.990
241.46
43, 388
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
⬎110
16011mm
⬎110
188
82
1.442520
1671mm
⬎110
0.805
1.442520
1235mm
⬎110
613.28
1.240
1.50020
2330.3mm
⬎110
CH3(CH2)3CH(C2H5)CH2OOC(CH2)8COOCH2CH(C2H5)(CH2)3CH3
[CH3(CH2)3CH(C2H5)CH2O]2P(O)OH
[CH3(CH2)3CH(C2H5)CH2O]2POH
[CH3(CH2)3CH(C2H5)CH2OOC]2C6H4
[CH3(CH2)3CH(C2H5)CH2OOC]2C6H4
(FC6H4)2CH2
426.66
0.911925
25
1.449625
0.965
1.443020
20910mm
⬎110
0.916
1.442020
0.984320
1.485920
390.56
Merck:
12, 1291
9,4, 3306
0.980
204.22
53, 1789
1.145
[H2N(CH2)6]2NH
215.39
HOCH2CH2OCH2C#CCH2OCH2CH2OH
HOCH2CH2OCH2CH2OH
174.20
106.12
1, 468
(HOCH2CH2)2NCH2COOH
163.17
Merck:
12, 1248
[-CH2CH2CO2CH(C2H5)(CH2)3CH3]2
[CH3(CH2)3CH(C2H5)(CH2)3CH3]2
322.43
14, 1786
306.43
390.56
⫺45
⫺60
384
218
1.490020
400
⬎110
1.536220
29–30
260742mm
⬎110
33–36
1654mm
⬎110
1.485020
1.118420
20
1.446020
v s aq, alc, org solvents
⬎110
⫺50 to
⫺55
30–34
1.144
Solubility in 100
parts solvent
0.01 aq
⬎110
⫺10.4
193–195
246
118
misc aq, alc, acet, eth
17.9 aq0
INTERACTIVE
b199
Beilstein
reference
ROTATED
b195
Bis(2-ethylhexyl)
hydrogen phosphate
Bis(2-ethylhexyl)
hydrogen phosphite
Bis(2-ethylhexyl)
o-phthalate
Bis(2-ethylhexyl)
1,4-phthalate
Bis(4-fluorophenyl)methane
Bis(hexamethylene)triamine
1,4-Bis(2-hydroxyethoxy)-2-butyne
Bis(2-hydroxyethyl)
ether
N,N-Bis(2-hydroxyethyl)glycine
Formula
weight
LEFT
b193
Bis(2-ethoxyethyl)
ether
Bis(2-ethylhexyl)
adipate
Bis(2-ethylhexyl)amine
Bis(2-ethylhexyl)
chlorendate
Bis(2-ethylhexyl)
decanedioate
Density,
g/mL
Formula
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
b201
b202
b203
b204
b205
b206
1.113
b207
b208
b209
2,6-Bis(hydroxymethyl)-p-cresol
2,2-Bis(hydroxymethyl)propanoic
acid
4,8-Bis(hydroxymethyl)tricyclo[5.2.1.02,6]decane
4,4-Bis(4-hydroxyphenyl)pentanoic
acid
CH3C6H2(CH2OH)2OH
168.19
6, 1127
128–130
(HOCH2)2C(CH3)COOH
134.13
3, 401
181–185
196.29
64, 5538
CH3C(C6H4OH)2CH2CH2COOH
286.33
Merck:
12, 3370
Bis(2-hydroxypropyl)
ether
1,3-Bis(isocyanatomethyl)benzene
1,3-Bis(isocyanatomethyl)cyclohexane
1,3-Bis(1-isocyanato1-methylethyl)benzene
Bis(2-mercaptoethyl)
ether
Bis(2-mercaptoethyl)
sulfide
HO(CH2)3O(CH2)3OH
134.18
12, 537
1.025220
20
1.441020
C6H4(CH2NCO)2
188.19
133, 334
1.202
1.591020
C6H10(CH2NCO)2
194.24
1.101
1.485020
C6H4[C(CH3)2NCO]2
244.30
1.060
1.511020
(HSCH2CH2)2O
138.25
1.114
(HSCH2CH2)2S
154.32
1.183
1.528020
110
171–172
higher
melting
form
Bis(2-hydroxyethyl) sulfide, t144
2,2-Bis(hydroxymethyl)-1,3-propanediol, p19
⫺7
231.8
137
1302mm
⬎110
misc aq, alc
⬎110
⫺80
1.596120
s hot aq, acet, alc,
HOAc, MeEtKe
1060.9mm
153
217
98
13610mm
90
Bis(4-hydroxyphenyl) sulfide, t145
4,4-Bis(hydroxyphenyl)valeric acid, b203
RIGHT
Bis(2-ethylhexyl) sebacate, b190
1,2-Bis(2-hydroxyethoxy)ethane, t280
s aq, MeOH; sl s acet;
i bz
DEAN 37261 (McGHP)
b200
ROTATED
b184
b189
b202
INTERACTIVE
1,4-Bis(methanesulfonoxy)butane
1,2-Bis(methoxyethoxy)ethane
Bis[2-(2-methoxyethoxy)ethyl] ether
Bis(2-methoxyethyl)amine
Bis(2-methoxyethyl)
ether
2,2-Bis(4-methoxyphenyl)-1,1,1trichloroethane
Bis(2-methylallyl)
carbonate
Bis(3-nitrophenyl)
disulfide
Bis(octadecyl)pentaerythritol diphosphite
1,4-Bis(5-phenyloxazol-2-yl)benzene
N,N⬘-Bis(salicylidene)1,4-butanediamine
N,N⬘-Bis(salicylidene)ethylenediamine
N,N⬘-Bis(salicylidene)1,6-hexanediamine
Bis(p-tolyl) disulfide
Bis(p-tolyl) sulfoxide
Bis(tributyltin) oxide
1,4-Bis(trichloromethyl)benzene
b211
b212
b213
b214
b214a
1.114
b215
b216
b217
b218
b219
b220
b221
b222
b223
b224
b225
Formula
weight
(CH3SO2OCH2CH2-)2
246.30
(CH3OCH2CH2OCH2-)2
178.23
(CH3OCH2CH2OCH2CH2)2O
228.28
Beilstein
reference
Density,
g/mL
Refractive
index
Flash
point,⬚C
Solubility in 100
parts solvent
0.99020
4
1.422420
⫺45
216
110
sl hyd aq; 0.1 alc; 1.4
acet
misc aq
13, 2107
1.008720
4
1.433020
⫺27
275
140
s aq
172
58
162
67
133.19
43, 691
0.902
1.419020
(CH3OCH2CH2)2O
134.18
12, 520
0.944025
1.404325
(CH3OC6H4)2CHCCl3
345.66
6, 1007
[H2C"C(CH3)CH2O]2C"O
170.21
O2NC6H4SSC6H4NO2
308.33
[C18H37OP(OCH2)2-]2
721.01
0.943
⫺64 to
⫺68
86–88
1.437020
6, 339
0.925
1.457
misc aq
v sl s aq; s alc
202
72
83
364.40
HOC6H4CH"N(CH2)6N"CHC6H4OH
CH3C6H4SSC6H4CH3
CH3C6H4S(:O)C6H4CH3
(C4H9)3SnOSn(C4H9)3
Cl3CC6H4CCl3
Boiling
point,⬚C
115–117
(CH3OCH2CH2)2NH
HOC6H4CH"N(CH2)4N"CHC6H4OH
(-CH2N"CHC6H4OH)2
Melting
point,⬚C
i aq; s alc; v s eth
40
261
244
296.37
83, 163
88–90
268.32
8, 48
128
3
324.44
8 , 165
69
246.39
230.33
596.08
312.84
6, 425
6, 419
43–46
94–96
1.170
5, 385
1.486020
i aq; s alc; v s eth
v s alc, bz, chl, eth
1802mm
108–110
⬎110
i aq; 26 acet; 38 bz
INTERACTIVE
b210
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
b227
b228
b229
b230
b231
b232
b233
1.115
b234
b235
b236
Bis(2,4,5-trichlorophenyl) disulfide
1,2-Bis(trichlorosilyl)ethane
3,5-Bis(trifluoromethyl)aniline
1,3-Bis(trifluoromethyl)benzene
N,O-Bis(trimethylsilyl)acetamide
Cl3C6H2SSC6H2Cl3
425.01
Cl3SiCH2CH2SiCl3
296.94
Bis(trimethylsilyl)acetylene
Bis(trimethylsilyl)formamide
(CH3)3SiC#CSi(CH3)3
HC " NSi(CH3)3
N,O-Bis(trimethylsilyl)hydroxylamine
1,2-Bis(trimethylsilyloxy)ethane
N,O-Bis(trimethylsilyl)trifluoroacetamide
1,3-Bis(trimethylsilyl)urea
(F3C)2C6H3NH2
229.13
(F3C)2C6H4
214.11
140–144
44, 4266
1.48320
4
1.475020
24.5
20
202
15mm
65
1.467
1.4340
85
83
1.379025
1.391625
116
26
0.83220
4
1.417020
7335mm
11
170.41
0.77020
4
1.427020
137
2
189.41
0.885
1.438120
5513mm
(CH3)3SiONHSi(CH3)3
177.40
0.830
1.411220
80100mm
28
(CH3)3SiOCH2CH2OSi(CH3)3
206.43
0.842
1.403420
166
46
F3C["NSi(CH3)3]OSi(CH3)3
257.40
0.969
1.383920
5014mm
23
(CH3)3SiNHCONHSi(CH3)3
204.42
CH3 9 C " N 9 Si(CH3)3
53, 834
203.43
O9Si(CH3)3
DEAN 37261 (McGHP)
b226
OSi(CH3)3
232 dec
Bis-tris propane, b237
2-Bornanone, c3
RIGHT
1,2-Bis(2-methoxyethoxy)ethane, t282
Bis(phenylmethyl) disulfide, d72
⫺10
ROTATED
b218
INTERACTIVE
Beilstein
reference
Density,
g/mL
CH2[CH2NHC(CH2OH)3]2
282.34
43, 859
H2NC("O)NHC("O)NH2
(CH3)3CNH2 ·BH3
C6H5N(C2H5)2 ·BH3
103.08
86.97
163.07
3, 70
[(CH3)2CH]2C2H5 ·BH3
143.08
0.822
58.92
75.97
0.801
b244
b245
b246
b247
b248
b249
b250
b251
b253
1,3-Bis[tris(hydroxymethyl)methylamino]propane
Biuret
Borane-tert-butylamine
Borane-N,N-diethylaniline
Borane-N,N-diisopropylethylamine
Borane-dimethylamine
Borane-dimethyl
sulfide
Borane-pyridine
(1S-endo)-(⫺)-Borneol
(⫺)-1-Bornyl acetate
N-Bromoacetamide
p-Bromoacetanilide
Bromoacetic acid
Bromoacetonitrile
2-Bromoacetophenone
p-Bromoacetophenone
b254
b255
b256
b257
b258
b259
b260
b261
b262
Bromoacetyl bromide
Bromoacetyl chloride
2-Bromoaniline
3-Bromoaniline
4-Bromoaniline
2-Bromoanisole
4-Bromoanisole
3-Bromobenzaldehyde
Bromobenzene
b241
b242
b243
(CH3)2NH·BH3
(CH3)2S·BH3
1.116
C5H4N·BH3
CH3CON(Br)H
BrC6H4NHCOCH3
BrCH2COOH
BrCH2CN
C6H5COCH2Br
BrC6H4COCH3
92.93
154.25
196.29
137.96
214.06
138.95
119.95
199.05
199.05
6, 72
6, 82
2, 181
12, 642
2, 213
2, 216
7, 283
7, 283
BrCH2COBr
BrCH2COCl
BrC6H4NH2
BrC6H4NH2
BrC6H4NH2
BrC6H4OCH3
BrC6H4OCH3
BrC6H4CHO
C6H5Br
201.86
157.40
172.03
172.03
172.03
187.04
187.04
185.03
157.01
2, 215
2, 215
12, 631
12, 633
12, 636
6, 197
6, 199
7, 238
5, 206
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
170
1.4674⫺5
0.920
1.01120
4
0.982
1.717
1.93450
4
1.722
1.64720
4
1.647
2.31722
22
1.908
1.57820
4
1.58020
4
1.4970100
4
1.502
1.494
1.587
1.495220
4
anhyd 110
100 dec
⫺30
1.460020
1.532020
1.4626
1.480450
1.480020
1.574020
1.564020
1.593520
1.560220
v s alc; 2 aq25
dec 190
21
40
36
43
18
50
54
1.548020
1.496020
1.622320
1.625020
s aq
15–17
10–11
204
27
102–105
168
50
31
16.8
66.3
2
9–10
⫺30.6
Solubility in 100
parts solvent
210779mm
224
21
65
84
208
6224mm
13518mm
255
⬎110
⬎110
⬎110
⬎110
150
128
229
251
none
none
⬎110
⬎110
223
223
230
156
96
94
96
51
i aq; 176 alc; s eth
v sl s aq; s alc, eth
sl s aq; v s eth
s alc, bz, chl, EtOAc
v s aq, alc
v s alc, bz, chl, eth
s alc, bz, CS2, HOAc
PE
dec aq, alc
dec aq, alc
i aq; s alc, eth
sl s aq; s alc, eth
i aq; v s alc, eth
INTERACTIVE
i aq; v s alc, eth
0.045 aq30; 10.4 alc25;
71.6 eth25; misc bz,
chl, PE
ROTATED
b237
Refractive
index
LEFT
Name
b238
b239
b240
Formula
Formula
weight
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
b265
b266
b267
b268
b269
b270
b271
b272
1.117
b273
b274
b275
b276
b277
b278
b279
b280
Bromobenzene-d5
4-Bromobenzenesulfonyl chloride
2-Bromobenzoic acid
4-Bromobenzoic acid
4-Bromobenzophenone
2-Bromobenzotrifluoride
3-Bromobenzotrifluoride
3-Bromobenzoyl
chloride
4-Bromobenzyl
bromide
␣-Bromobenzyl cyanide
4-Bromobiphenyl
1-Bromobutane
2-Bromobutane
1-Bromo-2-butene
2-Bromo-2-butene
4-Bromo-1-butene
4-Bromobutyl acetate
1-Bromo-4-tert-butylbenzene
1.558520
5323mm
15315mm
51
82
350
1.482020
168
51
1.613
1.473020
152
43
1.662
1.596520
750.5mm
107
C6D5Br
BrC6H4SO2Cl
162.06
255.52
11, 57
BrC6H4COOH
BrC6H4COOH
BrC6H4COC6H5
201.02
201.02
261.12
9, 347
9, 351
7, 422
BrC6H4CF3
225.01
1.65220
BrC6H4CF3
225.01
BrC6H4COCl
219.47
9, 350
BrC6H4CH2Br
249.94
5, 308
C6H5CH(Br)CN
196.05
BrC6H4C6H5
CH3CH2CH2CH2Br
CH3CH2CHBrCH3
CH3CH"CHCH2Br
CH3CH"C(Br)CH3
BrCH2CH2CH"CH2
CH3CO2(CH2)4Br
(CH3)3CC6H4Br
233.11
137.02
137.02
135.01
135.01
135.01
195.06
213.12
5, 580
1, 119
1, 119
1, 205
1, 205
11, 84
23, 39
5, 416
74.5
i aq; s alc (dec); v s
eth
148–150
251–253
1.92925
4
1.619320
61
12412mm
⬎110
1.53929
4
1.569620
29
242 dec
⬎110
0.932725
4
1.268625
4
1.258520
1.312
1.328
1.323020
4
1.348
1.229
1.437425
1.436020
1.476520
1.459020
1.460820
1.460020
1.533020
90–92
⫺112.4
⫺112.7
310
101.6
91.4
99
90740mm
100
9312mm
812mm
18
21
11
1
9
109
97
p-Bromobenzenethiol, b428
4-Bromobenzyl cyanide, b397
15–16
0.18 aq25; s alc, eth
i alc; sl s bz, eth
s aq, alc, bz, eth, CS2,
HOAc
sl s aq; v s alc, acet,
eth. A war gas.
i aq; s alc, bz, eth
i aq; s alc, bz, eth
⬍0.1 aq; v s alc, eth
Mixture of cis, trans
i aq; s alc, eth
exo-2-Bromobicyclo[2.2.1]heptane, b383
Bromobutanedioic acid, b421
RIGHT
Bromal, t199
Bromoacetaldehyde diethyl acetal, b317
Bromoanisoles, b357, b358, b359
1.539
DEAN 37261 (McGHP)
b263
b264
ROTATED
b245
b246
INTERACTIVE
4-Bromobutyl phenyl
ether
2-Bromobutyric acid
␣-Bromo-␥-butyrolactone
[1R-endo]-(⫹)-3Bromocamphor
1-Bromocarbonyl-1methylethyl acetate
2-Bromo-4⬘-chloroacetophenone
2-Bromochloro-benzene
3-Bromochloro-benzene
4-Bromochlorobenzene
3-Bromo-4-chlorobenzotrifluoride
1-Bromo-4-chlorobutane
4⬘-Bromo-4-chlorobutyrophenone
4-Bromo-6-chloro-ocresol
Bromochlorodifluoromethane
3-Bromo-1-chloro-5,5dimethyl-hydantoin
1-Bromo-2-chloroethane
Bromochlorofluoromethane
b282
b283
b284
b285
b286
b287
1.118
b288
b296
b297
b298
b299
b300
b301
b302
b303
b303a
Formula
weight
Beilstein
reference
Density,
g/mL
C6H5O(CH2)4Br
229.12
62, 82
CH3CH2CH(Br)COOH
167.00
164.99
2, 281
1.566920
20
1.99020
231.14
7, 120
1.449
Refractive
index
1.472020
1.508020
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
41–43
15618mm
⬎110
⫺4
10310mm
1386mm
⬎110
⬎110
75–78
244
Solubility in 100
parts solvent
6.7 aq; s alc, eth
15 alc; 200 chl; 62 eth;
s olive oil
1.431
1.457020
7712mm
110
5, 209
1.638225
4
1.578925
204
79
i aq; v s bz
191.46
5, 209
1.630220
4
1.577020
⫺21
196
80
i aq; v s alc, bz, eth
BrC6H4Cl
191.46
5, 209
1.57671
4
1.553170
66
196
Br(Cl)C6H3CF3
259.46
53, 715
1.726
1.499020
⫺22
190
94
ClCH2CH2CH2CH2Br
171.47
53, 294
1.488
1.487520
8230mm
60
BrC6H4CO(CH2)3Cl
261.55
Br(Cl)C6H2(OH)CH3
221.49
CH3CO2C(CH3)2COBr
209.05
ClC6H4COCH2Br
233.50
BrC6H4Cl
191.46
BrC6H4Cl
Br(Cl)CF2
6, 360
165.36
241.48
ClCH2CH2Br
143.41
Br(Cl)CHF
149.37
36–38
⬎110
45–47
⬎110
⫺160
6.579
g/L
0.1 aq; misc MeOH,
eth
i aq; s alc, chl, eth
⫺3.7
160–164
1, 89
1.739220
4
1.491720
⫺18.4
106.6
1.97710
1.414455
⫺115
36
0.7 aq; misc org solv
INTERACTIVE
b281
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
b305
b306
b307
b308
b309
b310
b311
1.119
b312
b313
b314
b315
b316
b317
b318
b319
7-Bromo-5-chloro-8hydroxyquinoline
Bromochloromethane
1-Bromo-3-chloro-2methylpropane
1-Bromo-3-chloropropane
2-Bromo-2-chloro1,1,1-trifluoroethane
2-Bromocinnamaldehyde
Bromocycloheptane
Bromocyclohexane
3-Bromocyclohexene
Bromocyclopentane
Bromocyclopropane
1-Bromodecane
Bromodichloromethane
2-Bromo-1,1-diethoxyethane
4-Bromo-1,2-dimethoxybenzene
2-Bromo-1,1-dimethoxyethane
ClCH2Br
258.51
211, 222
129.38
1, 67
177–179
1.92325
4
3
1.48025
⫺88
20
ClCH2CH(CH3)CH2Br
171.47
1 , 324
1.467
1.4809
ClCH2CH2CH2Br
157.44
1, 109
1.492
1.485120
BrCH(Cl)CF3
197.39
14 156
1.863625
1.369120
C6H4CH"C(Br)CHO
211.06
7, 358
Br(C7H13)
Br(C6H11)
177.09
163.06
5, 29
5, 24
1.288722
4
1.326415
4
Br(C5H9)
Br(C3H5)
CH3(CH2)9Br
BrCHCl2
161.04
149.04
120.98
221.18
163.83
52, 40
5, 19
BrCH2CH(OC2H5)2
68
0.9 aq; misc MeOH,
eth
154
⬍⫺50
⬎110
143.5
0.1 aq; misc org solv
50.2
none
1.505220
1.495615
7210mm
165.8
68
62
12, 130
1, 67
1.389020
4
1.390020
4
1.510
1.065820
4
1.98020
1.529220
1.488120
1.460529
1.456020
1.496720
6515mm
137–139
69
238–240
87
54
35
⫺6
94
none
i aq; v s chl, eth
sl s aq; misc org solv
197.08
1, 625
1.310
1.438520
6718mm
51
s hot alc
BrC6H3(OCH3)2
217.07
6, 784
1.702
1.574320
BrCH2CH(OCH3)2
169.02
1, 624
1.430
1.445020
66–68
⫺30
⫺55
256
i aq; v s chl, eth
0.1 aq; 10 MeOH; 71
eth
109
150
53
RIGHT
␤-Bromocumene, b350
2-Bromo-p-cumene, b351
DEAN 37261 (McGHP)
b304
ROTATED
b283
b284
b302
b304
b312
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
Name
b320
1-Bromo-2,2-dimethoxypropane
4-Bromo-2,6-dimethylphenol
3-Bromo-2,2-dimethyl1-propanol
2-Bromo-4,6-dinitroaniline
1-Bromo-2,4-dinitrobenzene
4-Bromodiphenyl ether
1-Bromodiphenylmethane
1-Bromododecane
1-Bromo-2,3-epoxypropane
b321
b322
b323
b324
b325
b326
1.120
b327
b328
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
1.355
1.447520
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
8780mm
40
184–187
75
CH3C(OCH3)2CH2Br
185.05
BrC6H2(CH3)2OH
201.07
6, 485
BrCH2C(CH3)2CH2OH
167.05
11, 201
BrC6H2(NO2)2NH2
262.03
12, 761
BrC6H3(NO2)2
247.01
BrC6H4OC6H5
C6H5CH(Br)C6H5
249.11
247.14
61, 105
5, 592
1.423
1.607020
18
40–42
305
18420mm
⬎110
⬎110
CH3(CH2)11Br
H2C 9 CHCH2Br
249.24
136.98
12, 133
17, 9
1.038
1.60120
1.458020
1.482020
⫺11
⫺40
1356mm
134–136
⬎110
56
0.1 aq; s alc, eth
i aq; sl s alc; s eth
O
CH3CH2Br
108.97
1, 88
1.461220
4
1.424220
⫺119
38.2
⫺23
0.91 aq20; misc alc,
chl, eth
5720mm
⬎110
159
71
misc aq; s org solv except PE
v s aq; misc alc, eth
v s aq, alc
79–81
1.358
1.479420
154
subl
v s hot alc, hot acet
71–73
2-Bromoethanesulfonic
acid, sodium salt
2-Bromoethanol
BrCH2CH2SO2⫺ Na⫹
211.02
4, 7
BrCH2CH2OH
124.98
1, 338
1.762920
4
1.493620
2-Bromoethyl acetate
2-Bromoethylamine
HBr
(1-Bromoethyl)benzene
(2-Bromoethyl)benzene
1-Bromo-2-ethylbenzene
Bromoethylene
CH3CO2CH2CH2Br
BrCH2CH2NH2 ·HBr
167.01
204.90
21, 57
4, 134
1.51420
4
1.454720
C6H5CH(CH3)Br
185.07
5, 355
1.356
1.560020
9416mm
81
C6H5CH2CH2Br
185.07
5, 355
1.355
1.556020
221
89
BrC6H4CH2CH3
185.07
5, 355
1.338
1.549020
19416mm
71
H2C"CHBr
106.95
1, 188
1.49320
1.438020
15.8
none
b332
b333
b334
b334a
b335
b336
283 dec
⫺13.8
172–174
⫺139
i aq; misc alc, eth
INTERACTIVE
b330
ROTATED
Bromoethane
LEFT
b329
b331
Solubility in 100
parts solvent
b338
b339
b340
b341
b342
b343
b344
b345
b346
b347
1.121
b348
b350
b351
b352
4-Bromodiphenyl ether, b295
Bromoethene, b336
1.357220
4
1.445020
BrCH2CH2OCH2CH3
153.02
1, 338
BrCH2CH2OC6H5
201.07
6, 142
34
254.09
21, 461
81–84
150
21
sl s aq; misc alc, eth
14440mm
65
i sq; v s alc, eth
s hot aq; v s eth
BrC6H4F
175.01
1.601
1.533720
156
43
BrC6H4F
175.01
1.567
1.525720
150
38
BrC6H4F
175.01
5, 209
1.59315
1.531015
⫺17.4
152
60
H(CH2)7Br
H(CH2)5CH(Br)CH3
H(CH2)16Br
H(CH2)6Br
CH3(CH2)3CH(Br)COOH
179.11
179.11
305.35
165.08
195.06
1, 155
1, 155
12, 138
1, 144
2, 325
1.138420
4
1.142
0.9991
1.176320
4
1.370
1.450520
1.447020
1.461820
1.447520
1.472020
⫺58
180
6621mm
336
154–158
13818mm
60
47
177
57
⬎110
C6H5CH(CH3)CH2Br
226.03
199.10
21, 453
51, 191
1.316
1.548020
10818mm
91
CH3(Br)C6H3CH(CH3)2
213.0
1.25325
25
1.53525
1,3,5-(CH3)3C6H2Br
CH3Br
BrC6H4CH(OH)COOH
17.8
⫺85
i aq; v s alc, eth
i aq; misc org solv
i aq; misc alc, eth
s alc, eth
251–253
176.96
17, 435
1.905
1.540020
199.10
94.94
231.05
5, 408
1, 67
10, 210
1.301
1.73200
1.552020
1.423410
Bromoform, t204
⫺20
2
⫺94
117–118
120
i aq; 50 MeOH; misc
org solvents
215
⬎110
255
3.56
96
none
2-Bromomesitylene, b436
0.1 aq; s alc, chl, eth
sl s aq
RIGHT
b353
b354
b355
2-Bromoethyl ethyl
ether
2-Bromoethyl phenyl
ether
N-(2-Bromoethyl)phthalimide
1-Bromo-2-fluorobenzene
1-Bromo-3-fluorobenzene
1-Bromo-4-fluorobenzene
1-Bromoheptane
2-Bromoheptane
1-Bromohexadecane
1-Bromohexane
DL-2-Bromohexanoic
acid
5-Bromoisatin
(2-Bromoisopropyl)benzene
2-Bromo-4-isopropyl1-methylbenzene
Bromomaleic anhydride
2-Bromomesitylene
Bromomethane
4-Bromomandelic acid
DEAN 37261 (McGHP)
b337
ROTATED
b339
b348
INTERACTIVE
b352
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
5-Bromo-2-methoxybenzaldehyde
2-Bromo-1-methoxybenzene
3-Bromo-1-methoxybenzene
4-Bromo-1-methoxybenzene
4-Bromo-2-methylaniline
1-Bromo-3-methylbenzyl alcohol
1-Bromo-3-methylbutane
2-Bromo-2-methylbutane
2-Bromo-3-methylbutanoic acid
4-Bromo-2-methyl-2butene
(Bromomethyl)chlorodimethylsilane
(Bromomethyl)cyclohexane
2-Bromomethyl-1,3dioxalane
Bromomethyl methyl
ether
1-Bromo-2-methylnaphthalene
1-Bromo-2-methylpropane
b357
b358
b359
b360
b361
1.122
b362
b363
b364
b365
b366
b367
b368
b369
b370
b371
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
BrC6H3(OCH3)CHO
215.05
8, 55
116–119
BrC6H4OCH3
187.04
6, 197
1.501820
4
1.573720
2
223
BrC6H4OCH3
187.04
6, 198
1.477
1.563520
211
93
BrC6H4OCH3
187.04
6, 199
1.456420
4
1.563020
10
223
94
sl s aq; v s alc, eth
CH3(Br)C6H3NH2
186.06
12, 838
57–59
240
⬎110
sl s aq; v s alc
BrC6H4CH(CH3)OH
201.07
62, 447
1.460
36–38
1217mm
63
(CH3)2CHCH2CH2Br
151.05
1, 136
1.21015
4
1.440920
⫺112
119.7
32
C2H5C(CH3)2Br
151.05
1, 136
1.182
1.442320
107735mm
5
(CH3)2CHCH(Br)COOH
181.04
2, 317
12620mm
107
BrCH2C"C(CH3)2
149.04
12, 189
1.293
1.489820
6060mm
32
BrCH2Si(CH3)2Cl
187.5
44, 4024
1.375
1.465020
130740mm
41
(C6H11)CH2Br
177.09
52, 18
1.269
1.490720
7726mm
57
167.01
192, 8
1.613
1.481720
8227mm
62
BrCH2OCH3
124.97
1, 582
1.531
1.455020
87
26
Br(C10H6)CH3
221.10
5, 568
1.418
1.648620
296
⬎110
(CH3)2CHCH2Br
137.03
1, 126
1.264120
1.436220
91.5
18
44
⫺119
96
i aq; v s alc, eth
i aq; s alc, eth
0.02 aq; misc alc, eth
sl s aq; s alc, eth
0.06 aq; misc alc, eth
INTERACTIVE
b356
Formula
ROTATED
Name
LEFT
No.
b373
b374
b375
b376
b377
b378
b379
b380
b381
1.123
b382
b383
b384
b385
b386
(Bromomethyl)benzene, b85
4-Bromo-1-methylbenzene, b431
(CH3)3CBr
137.03
1, 127
1.212525
4
BrC(CH3)2COOH
167.01
2, 295
1.52
1.42525
⫺16.2
73.1
18
i aq; misc org solv
48–49
200
⬎110
sl s aq; s alc, eth; dec
by hot aq
24
(CH3)2C(Br)COBr
229.91
2, 297
1.860
1.5064
164
110
C6H5CO(CH3)2Br
227.11
7, 316
1.350
1.556120
14830mm
⬎112
(C10H7)Br
BrC10H6OH
BrC10H6OH
BrC6H4NO2
207.07
233.07
223.07
202.01
5, 547
6, 650
6, 650
51, 247
1.483420
4
1.658020
1.624580
4
O2N(Br)C6H3CF3
270.02
53, 755
1.799225
(HOCH2)2C(Br)NO2
199.99
1, 476
H(CH2)9Br
207.16
175.07
11, 63
1.084
1.363
1.454020
1.514820
H(CH2)18Br
H(CH2)8Br
BrC6F5
333.41
193.13
246.97
11, 69
1, 160
0.976
1.10825
4
1.94720
1.451825
1.449020
H(CH2)5Br
CH3CH2CH2CH(Br)CH3
C2H5CH(Br)C2H5
CH3CO2(CH2)5Br
151.05
151.05
151.05
209.09
1, 131
1, 131
11, 43
23, 249
1.223715
4
1.203920
4
1.216
1.255
1.444420
1.440320
1.444520
1.462020
1.518025
⫺1.8
78
78–81
43
281
130 dec
⬎110
misc alc, bz, chl, eth
i aq; s alc, bz, eth
261
110
v s alc; s bz, eth
33–35
1005mm
⬎110
120–122
2-Bromo-2-methylpropanoyl bromide, b374
s aq, alc, EtOAc; sl s
bz, acet, chl, eth
i aq; s chl, eth
201
8229mm
90
60
23
⫺55
⫺31
21612mm
201
137
⬎110
78
87
i aq; s alc, eth
i aq; misc alc, eth
⫺88
129.6
117
119
11015mm
31
20
18
⬎110
i aq; s alc; misc eth
␣-Bromo-p-nitrotoluene, n44
RIGHT
b387
b388
b389
b390
2-Bromo-2-methylpropane
2-Bromo-2-methylpropanoic acid
2-Bromo-2-methylpropionyl bromide
2-Bromo-2-methylpropiophenone
1-Bromonaphthalene
1-Bromo-1-naphthol
1-Bromo-2-naphthol
1-Bromo-2-nitrobenzene
5-Bromo-2-nitrobenzotrifluoride
2-Bromo-2-nitro-1,3propanediol
1-Bromononane
exo-2-Bromo-norbornane
1-Bromooctadecane
1-Bromooctane
Bromopentafluorobenzene
1-Bromopentane
2-Bromopentane
3-Bromopentane
5-Bromopentyl acetate
DEAN 37261 (McGHP)
b372
ROTATED
b368
b383
INTERACTIVE
b391
b392
b393
b394
b395
b400
b401
9-Bromophenanthrene
2-Bromophenol
3-Bromophenol
4-Bromophenol
1-(4-Bromophenoxy)1-ethoxyethane
4-Bromophenylacetic
acid
4-Bromophenylacetonitrile
4-Bromophenyl phenyl
ether
1-Bromo-3-phenylpropane
1-Bromopropane
2-Bromopropane
b402
b403
b404
b405
b406
b407
b408
b409
b396
b397
b398
1.124
b399
b410
b411
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
1.409101
4
1.492
1.589220
1.587580
1.348
1.522920
Melting
point,⬚C
BrC6H4OH
BrC6H4OH
BrC6H4OH
CH3CH(OC6H4Br)OC2H5
257.14
173.01
173.01
173.01
245.12
5, 671
6, 197
6, 198
6, 198
54–58
6
32
64
BrC6H4CH2COOH
215.05
9, 451
119
BrC6H4CH2CN
196.05
9, 451
47–49
BrC6H4OC6H5
249.11
61, 105
1.423
1.607020
BrC6H4CH2CH2CH2Br
199.10
5, 391
1.310
1.545020
CH3CH2CH2Br
CH3CH(Br)CH3
122.99
123.99
1, 108
1, 108
1.359715
1.322215
1.437015
1.428515
3-Bromo-1-propanol
1-Bromo-2-propanone
BrCH2CH2CH2OH
CH3OCH2Br
139.00
136.98
1.537420
4
1.63423
1.485820
1.469715
1-Bromo-1-propene
2-Bromo-2-propene
2-Bromopropionic acid
3-Bromopropionic acid
3-Bromopropionitrile
2-Bromopropionyl
bromide
2-Bromopropionyl
chloride
3-Bromopropionyl
chloride
2-Bromopropiophenone
CH3CH"CHBr
CH3C(Br)"CH2
CH3CH(Br)COOH
BrCH2CH2COOH
BrCH2CH2CN
CH3CH(Br)COBr
120.98
120.98
152.98
152.98
133.98
215.88
1, 356
Merck:
12, 1422
1, 200
1, 200
2, 254
2, 256
22, 231
2, 256
1.413320
4
1.36220
4
1.700020
1.480
1.615220
4
2.061
1.453820
1.442520
1.475020
1.480020
1.518220
CH3CH(Br)COCl
171.43
2, 256
1.70011
CH3CH(Br)COCl
171.43
22, 231
C6H5COCH(Br)CH3
213.08
7, 302
Boiling
point,⬚C
1902mm
194
236
238
1258mm
Flash
point,⬚C
⬎110
42
⬎110
14 aq; v s alc, chl
sl s aq; v s alc, eth
⬎110
⬎110
220
101
⫺110.1
⫺89.0
71.0
59.5
19
625mm
137
93
⫺36.5
70
47–49
203
7810mm
5010mm
⫺6
4
100
65
98
⬎110
1.480020
133
51
1.701
1.496820
5717mm
79
1.43020
4
1.571520
250
⬎110
⫺116
⫺125
25.7
62.5
i aq; s alc, eth
s aq; misc chl, eth
106
305
18
Solubility in 100
parts solvent
i aq; sl s alc; v s bz
0.23 aq30; misc alc
0.3 aq18; misc alc, bz,
chl, eth
s aq; misc alc, eth
v sl s aq; s alc, acet
i aq
v s aq, alc, bz, chl, eth
s aq, alc, bz, chl, eth
v s alc, eth
d aq; s chl, eth
s alc, bz, eth, acet
INTERACTIVE
b412
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
b414
b415
b416
b417
b418
b419
3-Bromopropyl phenyl
ether
3-Bromopropyltrichlorosilane
3-Bromopropyne
2-Bromopyridine
3-Bromopyridine
3-Bromoquinoline
5-Bromosalicylic acid
C6H5OCH2CH2CH2Br
215.10
Br(CH2)3SiCl3
256.44
1.365
1.546420
1.605
1.490020
1.335
1.65718
1.64504
1.533
1.4905
1.572020
1.569520
1.664020
Br(HO)C6H3COOH
1, 248
20, 233
20, 233
20, 363
10, 107
C6H5CH"CHBr
HOOCH2CH(Br)COOH
183.05
196.99
5, 477
2, 621
1.42220
4
2.073
1.606620
b422
␤-Bromostyrene
(⫾)-Bromosuccinic
acid
N-Bromosuccinimide
177.99
21, 380
2.098
b423
1-Bromotetradecane
H(CH2)14Br
277.30
12, 136
1.012425
4
1.460020
b424
3-Bromotetrahydro-2methyl-2H-pyran
3-Bromothioanisole
2-Bromothiophene
3-Bromothiophene
4-Bromothiophenol
2-Bromotoluene
179.06
173, 75
1.366
1.483020
203.11
163.04
163.04
189.08
171.04
6, 330
17, 33
1.68420
4
1.740
1.586020
1.591020
1.42225
25
1.55225
1.125
b425
b426
b427
b428
b429
BrC6H4SCH3
Br(C5H3S)
Br(C5H3S)
BrC6H4SH
BrC6H4CH3
142–143
15
166
7
161
13414mm
96
202–204
76
88–90
194
173
276
18
54
51
⬎110
11220mm
79
173 sl dec
6
17820mm
⬎110
6117mm
57
38–40
(3-Bromopropyl)benzene, b338
3-Bromopropylene, a79
151
150
239
181
76
⫺26
⬎110
60
56
78
5-Bromopseudocumene, b435
␣-Bromotoluene, b85
i aq; s org solv
s aq; v s alc, eth
s HOAc
0.3 aq80; 85 alc25; 70
eth25
i aq; misc alc, eth
18 aq; s alc, acet, eth
1.5 aq25; 14.4 acet25;
3.1 HOAc25
s alc; v s chl; misc bz,
acet
v s acet, eth
0.1 aq; misc alc, bz,
chl, eth
RIGHT
␤-Bromophenitole, b338
3-Bromopropene, a79
6, 330
5, 304
10–11
20
118.97
158.00
158.00
208.06
217.02
b420
b421
BrCH2C#CH
Br(C5H4N)
Br(C5H4N)
6, 142
DEAN 37261 (McGHP)
b413
ROTATED
b391
b418
b422
b424
INTERACTIVE
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
BrC6H4CH3
BrC6H4CH3
BrCCl3
171.04
171.04
198.28
5, 305
5, 305
1, 67
1.409920
1.395935
35
1.99725
25
1.551720
1.5490
1.506320
⫺39.8
28.5
⫺6
183.7
184.5
104–105
60
85
s alc, bz, eth
s alc, bz, eth
misc org solv
H(CH2)13Br
BrCF3
263.27
148.91
12, 134
13, 83
1.026220
4
6.087
g/L
1.459220
15010mm
⫺57.8
⬎110
v s chl
v s chl
BrC6H2(CH3)3
199.10
5, 403
7
⫺168 to
⫺172
73
BrC6H2(CH3)3
199.10
5, 408
(CH3)3GeBr
197.60
(CH3)3SiBr
(C6H5)2C"C(Br)C6H5
153.10
335.22
5, 722
115–117
(C6H5)3CBr
323.24
5, 704
152–154
23015mm
CH3(CH2)10Br
Br(CH2)10COOH
235.22
265.20
12, 132
22, 315
1.954
⫺9
51
13818mm
1742mm
⬎110
⬎110
b443
b444
b445
b446
b447
3-Bromotoluene
4-Bromotoluene
Bromotrichloromethane
1-Bromotridecane
Bromotrifluoromethane
5-Bromo-1,2,4-trimethylbenzene
2-Bromo-1,3,5-trimethylbenzene
Bromotrimethylgermane
Bromotrimethylsilane
Bromotriphenylethylene
Bromotriphenylmethane
1-Bromoundecane
11-Bromoundecanoic
acid
␣-Bromo-1,2-xylene
␣-Bromo-1,3-xylene
2-Bromo-1,4-xylene
4-Bromo-1,2-xylene
Brucine
BrCH2C6H3CH3
BrCH2C6H3CH3
BrCH2C6H3CH3
BrCH2C6H3CH3
185.07
185.07
185.07
185.07
394.45
5, 365
5, 374
5, 385
5, 365
272, 797
1.38123
1.37023
1.340
1.37015
15
21
224
185340mm
199–201
215
82
82
79
80
b448
b449
1,2-Butadiene
1,3-Butadiene
CH3CH"C"CH2
H2C"CHCH"CH2
1, 249
1, 249
0.67610
2.211
g/L
1.42051
1.4293⫺25
10.9
⫺4.4
⫺76
b450
b451
b452
Butadiene sulfone
1,3-Butadienyl acetate
1,3-Butadiyne
CH3CO2CH"CHCH"CH2
HC#CC#CH
0.945
0.736404
1.469020
1.41895
b430
b431
b432
b433
b434
b435
b436
b437
1.126
b438
b439
b440
173, 144
23, 295
13, 1056
1.551120
2
225
96
1.54418
1.470520
⫺25
113.7
37
1.160
1.414020
79
32
1.456320
1.38120
1.556020
1.550520
1.556020
9–10
178
⫺136.2
⫺108.9
66
⫺36
6040mm
10.3
i aq; s bz; v s eth
i aq; v s alc
s alc, eth
s alc, eth
v s chl, hot ether
v s alc, eth
77 alc; 1 bz; 20 chl; 4
EtOAc
misc alc, eth
misc alc, eth
⬎110
33
v s eth; s acet, bz
INTERACTIVE
118.15
112.13
50.06
1.301
ROTATED
54.09
54.09
i aq; s alc
LEFT
b441
b442
235
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
2-Butanamine
Butane
CH3CH2CH(NH2)CH3
CH3CH2CH2CH3
73.14
58.12
4, 160
1, 118
0.730815
4
0.60110
1.396315
1.3562⫺13
⫺104.5
⫺138.3
66
⫺0.50
⫺19
⫺60
b455
b456
1,4-Butanediamine
Butanedinitrile
H2NCH2CH2CH2CH2NH2
NCCH2CH2CN
88.15
80.09
4, 264
2, 615
0.87725
4
0.986760
4
1.456920
1.417360
28
54.5
158–160
266
51
132
b457
b457a
b457b
1,2-Butanediol
1,3-Butanediol
1,4-Butanediol
CH3CH2CH(OH)CH2OH
CH3CH(OH)CH2CH2OH
HOCH2CH2CH2CH2OH
90.12
90.12
90.12
1, 477
1, 477
1, 478
1.00618
0
1.005320
20
1.01625
4
1.438020
1.44120
1.445220
⬍⫺50
20
207.5
207.5
235
93
121
121
b458
b459
meso-2,3-Butanediol
1,4-Butanediol dimethanesulfonate
1,3-Butanediol diacetate
1,4-Butanediol diacrylate
CH3CH(OH)CH(OH)CH3
CH3SO2O(CH2)4OSO2CH3
90.12
246.30
1, 479
44, 19
0.993925
4
1.432435
182
85
CH3CO2CH2CH2CH(CH3)O2CCH3
(H2C"CHCO2CH2CH2-)2
174.20
2, 143
1.028
1.419920
998mm
85
198.22
24, 170
1.051
1.456020
830.3mm
⬎110
b460
1.127
b461
BTMSA, b231
Busulfan, b210
1,3-Butadiene diepoxide, d546
Butanal, b612
1-Butanamine, b509
Butanecarbaldehyde, p28
Butanedinitrile, s18
Butanedioic acid, s15
Butanedioic anhydride, s16
1,4-Butanediol diglycidyl ether, b185
b447
O
ROTATED
S
O
RIGHT
Bromo-␣,␣,␣-trifluorotoluene, b268, b269
3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptane-2-one, b284
4-Bromoveratrole, b318
4-Bromo-2,6-xylenol, b321
BSA, b230
BSTFA, b235
25
114–117
misc aq, alc
1 vol aq dissolves 0.15
vol and 1 vol alc 18
vols at 17⬚ and 770
mm; 1 vol ether or
CHCl3 dissolves 25
or 30 vols, resp.
s aq
11.5 aq; s acet, chl,
1,4-dioxane; sl s bz
s aq, alc, acet
s aq, alc, acet; 9 eth
misc aq, alc, acet; 0.3
bz; 3.1 eth; 0.9 PE
misc aq, alc
2.4 acet25; 0.1 alc25
DEAN 37261 (McGHP)
b453
b454
b450
INTERACTIVE
b482
b483
b484
1,3-Butanediol dimethacrylate
1,4-Butanediol dimethacrylate
1,4-Butanediol divinyl
ether
1,4-Butanediol vinyl
ether
2,3-Butanedione
2,3-Butanedione monoxide
1,4-Butanedithiol
Butanenitrile
1,2,3,4-Butanetetracarboxylic acid
1-Butanethiol
2-Butanethiol
1,2,4-Butanetriol
1-Butanol
2-Butanol
2-Butanone
2-Butanone oxime
1-Butene
cis-2-Butene
trans-2-Butene
cis-2-Butene-1,4-diol
trans-2-Butene-1,4diol
3-Butenenitrile
cis-2-Butenoic acid
trans-2-Butenoic acid
H2C"CHCH2CN
CH3CH"CHCOOH
CH3CH"CHCOOH
b485
b486
3-Butenoic acid
cis-2-Buten-1-ol
H2C"CHCH2COOH
CH3CH"CHCH2OH
b464
b465
b466
b467
1.128
b468
b468a
b469
b470
b471
b472
b473
b474
b475
b476
b477
b478
b479
b480
b481
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
1.010
1.452020
290
⬎110
1344mm
⬎110
6410mm
62
9520
85
86
186
7
25 aq; misc alc, eth
10630mm
117.6
70
24
i aq; v s alc
3.3 aq; misc alc, eth
2
21
167
37
24
⫺9
60
⫺80
⫺73
⫺73
128
0.06 aq; v s alc, eth
sl s aq; v s alc, eth
v s aq, alc
7.4 aq; misc alc, eth
12.5 aq; misc alc, eth
24 aq; misc alc, bz, eth
sl s aq; misc alc, eth
v s aq; s alc
55 aq; 52 EtOH; 53
acet; 37 toluene
s aq; misc alc, eth
16.6 aq; misc alc
H2C"C(CH3)CO2CH2CH2CH(CH3)O2CC(CH3)"CH2
[H2C"C(CH3)CO2CH2CH2-]2
226.28
226.28
24, 1534
1.010
1.456020
(-CH2CH2OCH"CH2)2
142.20
14, 2518
0.898
1.44420
H2C"CHO(CH2)4OH
116.16
14, 2518
0.939
1.444020
CH3C("O)C("O)CH3
CH3C("NOH)C("O)CH3
86.09
101.11
1, 769
1, 772
0.99015
15
1.395120
HSCH2CH2CH2CH2SH
CH3CH2CH2CN
[-CH(COOH)CH2COOH]2
122.25
69.11
234.16
1, 479
22, 252
2, 863
1.042
0.7936
1.529020
1.444020
CH3CH2CH2CH2SH
CH3CH2CH(SH)CH3
HOCH2CH2CH(OH)CH2OH
CH3CH2CH2CH2OH
CH3CH2CH(OH)CH3
CH3CH2COCH3
CH3CH2C("NOH)CH3
CH3CH2CH"CH2
CH3CH"CHCH3
CH3CH"CHCH3
HOCH2CH"CHCH2OH
HOCH2CH"CHCH2OH
90.19
90.19
106.12
74.12
74.12
72.11
87.12
56.11
56.11
56.11
88.11
88.11
1, 370
1, 373
1, 519
1, 367
1, 371
1, 666
1, 668
1, 203
13, 728
1, 205
12, 567
13, 2252
0.836725
4
0.824625
4
1.19020
0.809720
4
0.806920
4
0.805420
4
0.924
0.6255mp
4
0.6213
0.6041
1.070020
4
1.07020
4
1.443025
1.433825
1.474820
1.399320
1.397220
1.378820
1.442020
1.396220
1.3931⫺25
1.3848⫺25
1.478020
1.475520
⫺116
⫺165
⫺185.3
⫺139.3
⫺105.8
2
25
98.5
85.0
19118mm
117.7
99.5
79.6
6015mm
⫺6.5
3.7
0.9
234
132
67.09
86.09
86.09
2, 408
2, 412
2, 408
0.834120
4
1.026720
4
0.960480
4
1.406020
1.448314
1.424877
⫺87
14–15
72
119
168–169
185
21
86.09
72.11
2, 407
1, 442
1.009120
4
0.866220
4
1.424920
1.434220
⫺39
⫺89.4
163
123.6
65
56
⫺8
75–78
⫺112
196
⫺89.5
⫺114.7
⫺86.7
87
Solubility in 100
parts solvent
i aq; v s alc, eth
i aq; v s alc, eth
i aq; v s alc, eth
s aq; v s alc
v s aq, alc
INTERACTIVE
b462
b463
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
0.852420
4
0.863620
4
0.709514
0.992
1.100
1.490020
118.18
146.23
12, 519
13, 2085
0.901220
4
0.834
1.419820
1.401520
HOCH2CH2OCH2CH2OC4H9
162.23
12, 521
0.953620
20
1.430620
CH3CO2(CH2CH2O)2CH2CH2CH2CH3
CH3CO2CH2CH2O(CH2)3CH3
(CH3)3CO2CH2CH2OCH3
204.27
23, 308
0.978
160.22
132.20
23, 307
13, 2084
(CH3)3COCH2CH(OH)CH3
132.10
CH3(CH2)3O(CH2)3NH2
C4H9O2CH3
b502
b503
b504
b505
DL-sec-Butyl acetate
tert-Butyl acetate
tert-Butylacetic acid
tert-Butyl acetoacetate
b506
b507
b507a
b508
b509
b510
b511
2-Butylacrolein
N-tert-Butylacrylamide
Butyl acrylate
tert-Butyl acrylate
Butylamine
(⫾)-sec-Butylamine
tert-Butylamine
CH3CO2CH(CH3)C2H5
(CH3)3CO2CCH3
(CH3)CCH2COOH
(CH3)3COC("O)CH2C("O)CH3
(CH3(CH2)3C("CH2)CHO
H2C"CHCONHC(CH3)3
H2 "CHCO2(CH2)3CH3
H2C"CHCO2C(CH3)3
CH3CH2CH2CH2NH2
C2H5CH(NH2)CH3
(CH3)3CNH2
b493
b494
b495
b496
b497
b498
b499
1.129
1,4-Butanediol dimethanesulfonate, b210
Butanoic acid, b614
Butanoic anhydride, b615
trans-2-Butenal, c306
1.428920
1.408620
1.4161
1.554320
⬍⫺30
121.2
81.4
5.1
14913mm
56
⫺6
2195mm
⬎110
⫺75
168
148
69
33
5 aq; s most org solv
⫺68.1
230.4
100
misc aq, alc, bz, acet,
CCl4, PE
1.426020
245
⬎110
0.942
0.840
1.413620
1.398520
192
132
76
25
13, 2148
0.874
1.413020
143–145
44
73.14
116.16
43, 739
2, 130
0.853
0.881320
4
1.426020
1.394120
170
126
63
22
116.16
116.16
116.16
158.20
22, 131
2, 131
2, 337
0.874820
0.866520
4
0.912
0.954
1.388820
1.387020
1.411520
1.418020
112
95.1
190
31
16
112.17
127.19
128.17
128.17
73.14
73.14
73.14
14, 3482
44, 664
22, 388
23, 1228
4, 156
4, 160
4, 173
0.843
1.434820
Buten-4-carboxylic acid, p51
cis-2-Butenedioic acid, m1
2-Butene-1,1-diol diacetate, d28
trans-2-Buten-1-ol, c311
16.6 aq; misc alc
v s aq, alc, acet, eth
⬎110
150
0.894
0.875
0.732725
4
0.72420
4
0.695120
4
1.418020
1.410820
1.399225
1.392820
1.378820
⫺77/⫺78
⫺99
6–7
0.43 aq; misc alc, eth;
s most org solvents
0.62 aq; s alc, eth
i aq; misc alc, eth
60
128–129
⫺64
⫺50/⫺49
⫺104
⫺66
139
33
145
6360mm
77
63
44
39
17
⫺12
⫺9
⫺9
Butopyronoxyl, b550
Butoxybenzene, b591
1-Butoxybutane, d148
Butyl alcohols, b473, b474, m385
0.14 aq20
misc aq, alc, eth
misc aq, alc
misc aq, alc
ROTATED
1, 442
1, 728
13, 1032
132, 226
102, 93
9,3, 4187
RIGHT
72.11
70.09
52.07
165.24
194.23
336.39
DEAN 37261 (McGHP)
CH3CH"CHCH2OH
H2C"CHCOCH3
HC#CCH"CH2
CH3(CH2)3OC6H4NH2
CH3(CH2)3OC6H4COOH
2-[CH3(CH2)3O2CCH2O2C]C6H4CO2(CH2)3CH3
CH3(CH2)3OCH2CH2OH
(CH3)3COCH2CH2OC2H5
b500
b501
trans-2-Buten-1-ol
3-Buten-2-one
1-Buten-3-yne
4-Butoxyaniline
4-Butoxybenzoic acid
Butoxycarbonylmethyl
butyl phthalate
2-Butoxyethanol
1-tert-Butoxy-2-ethoxyethane
2-(2-Butoxyethoxy)ethanol
2-(2-Butoxyethoxy)ethyl acetate
2-Butoxyethyl acetate
2-tert-Butoxy-2-methoxyethane
1-tert-Butoxy-2-propanol
3-Butoxypropylamine
Butyl acetate
b487
b488
b489
b490
b491
b492
INTERACTIVE
H2NC6H4CO2(CH2)3CH3
193.25
b513
2-(tert-Butylamino)ethanol
2-(tert-Butylamino)ethyl methacrylate
3-(tert-Butylamino)1,2-propanediol
2-Butylaniline
2-sec-Butylaniline
4-Butylaniline
4-sec-Butylaniline
2-tert-Butylanthraquinone
Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Butyl benzoate
2-Butylbenzofuran
4-tert-Butylbenzoic
acid
4-tert-Butylbenzoyl
chloride
N-(tert-Butyl)benzylamine
tert-Butyl bromoacetate
Butyl 2-butoxy-2hydroxyacetate
Butyl butyrate
Butyl carbamate
Butyl carbazate
4-tert-Butylcatechol
(CH3)3CNHCH2CH2OH
117.19
H2C"C(CH3)CO2CH2CH2NC(CH3)3
(CH3)3CNHCH2CH(OH)CH2OH
CH3(CH2)3C6H4NH2
C2H5CH(CH3)C6H4NH2
CH3(CH2)3C6H4NH2
C2H5CH(CH3)C6H4NH2
185.27
b515
b516
b517
b518
b519
b520
1.130
b521
b522
b523
b524
b525
b526
b527
b528
b529
b530
b531
b532
b533
b534
142, 249
44, 1509
Melting
point,⬚C
5,
5,
5,
9,
(CH3)3CC6H4COOH
134.22
134.22
134.22
178.23
174.25
178.23
(CH3)3CC6H4COCl
196.68
C6H5CH2NHC(CH3)3
163.27
BrCH2CO2C(CH3)3
195.06
633
2721
503
635
0.953
0.957
0.945
0.977
Boiling
point,⬚C
Flash
point,⬚C
57–59
1748mm
42–45
9225mm
68
8210mm
71
1.442020
70
122,
123,
121,
122,
CH3(CH2)3OCH(OH)CO2(CH2)3CH3
CH3CH2CH2CCO2C4H9
H2NCO2(CH2)3CH3
H2NNHCO2C(CH3)3
(CH3)3C6H3-1,2-(OH)2
0.914
147.22
149.24
149.24
149.24
149.24
264.32
CH3CH2CH2CH2C6H5
C2H5CH(CH3)C6H5
(CH3)3CC6H5
C6H5CO2C4H9
Refractive
index
1.538020
1.541020
1.535020
1.537020
Solubility in 100
parts solvent
v sl s aq; s dil acids,
alc, chl, eth
921mm
12312mm
12216mm
12015mm
245727mm
108
⬎110
101
107
183
173
168.5
250
71
52
60
106
101
98–100
⫺88
⫺82.7
⫺58.1
⫺22
0.860420
4
0.860820
4
0.866920
4
1.000020
0.987
1.14220
4
1.489820
1.489020
1.492320
1.496
1.533020
1.007
1.536420
13520mm
87
12, 1022
0.881
1.496820
805mm
80
21, 96
1.321
1.445020
5010mm
49
20
40mm
90
74
166
49
108
91
151
413
414
415
112
9, 560
4
166.3
204.27
3 , 1497
0.996
1.4291
144.22
117.15
132.16
166.22
2, 271
0.869220
4
1.406420
1.04960
25
⫺91.5
53–55
39–42
52–55
misc alc, bz, eth
misc alc, bz, eth
misc alc, bz, eth
i aq; s alc, eth
i aq; v s alc, bz
650.03mm
285
i aq; misc alc, eth
0.2 aq;80 240 eth;25 s
alc; v s acet
INTERACTIVE
Butyl-4-aminobenzoate
Density,
g/mL
ROTATED
b512
Beilstein
reference
LEFT
Name
b514
Formula
Formula
weight
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
b536
b537
b538
b539
b540
b541
b542
b543
b544
b545
b546
1.131
b547
b548
tert-Butyl chloroacetate
4-tert-Butyl-1-chlorobenzene
tert-Butylchlorodiphenylsilane
Butyl chloroformate
Butyl cyanoacetate
tert-Butyl cyanoacetate
Butylcyclohexane
tert-Butylcyclohexane
2-tert-Butylcyclohexanol
4-tert-Butylcyclohexanol
2-tert-Butylcyclohexanone
4-tert-Butylcyclohexanone
Butyl decyl ophthalate
4-sec-Butyl-2,6-di-tertbutylphenol
150.61
23, 444
1.053
1.423020
(CH3)3C6H4Cl
158.67
5, 416
1.006
1.510820
1.057
20
1.5675
900.02mm
⬎110
1.07425
4
0.993
0.972
0.818
0.831
0.902
1.411420
1.425420
1.420020
1.440020
1.447020
142
11515mm
108
178–180
167
25
87
91
41
42
79
d aq, alc; misc eth
11515mm
105
i aq
634mm
72
11620mm
96
(CH3)3CSi(C6H5)2Cl
274.87
ClCO2C4H9
NCCH2CO2C4H9
NCCH2CO2C(CH3)3
(C6H11)6C4H9
(C6H11)C(CH3)3
(CH3)3C(C6H10)OH
136.58
141.17
141.17
140.27
140.27
145.27
32, 11
21, 255
(CH3)3C(C6H10)OH
156.27
61, 18
(CH3)3C(C6H9)("O)
154.25
73, 143
(CH3)3C(C6H9)("O)
154.25
71, 29
C4H9O2C6H4CO2C10H21
362.51
C2H5CH(CH3)C6H2(OH)[C(CH3)3]
262.44
51, 20
51, 20
63, 126
4911mm
23–25
⫺78
0.896
217
43–46
62–70
1.456520
47–50
0.99425
25
6,3, 2094
46
i aq
i aq
202
0.902
25
Butyl carbitol, b495
Butyl cellosolve, b493
Butyl cellosolve acetate, b497
Butyl chloride, c75
14210mm
tert-Butyl chloride, c180
2-tert-Butyl-o-cresol, b574
2-tert-Butyl-p-cresol, b573
Butyl cyanide, p35
⬎110
RIGHT
Butyl bromide, b274
sec-Butyl bromide, b275
tert-Butyl bromide, b372
N-Butyl-1-butanamine, d139
Butyl butenoate, b531
ClCH2CO2C(CH3)3
DEAN 37261 (McGHP)
b535
ROTATED
b520
b525
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Name
b549
b550
N-Butyldiethanolamine
Butyl 3,4-dihydro-2,2dimethyl-4-oxo-2Hpyran-6-carboxylate
tert-Butyldimethylchlorosilane
6-tert-Butyl-2,4-dimethylphenol
N-Butylethanolamine
Butyl ethyl ether
2-Butyl-2-ethyl-1,5pentanediamine
2-Butyl-2-ethyl-1,3propanediol
Butyl ethyl sulfide
N-tert-Butylformamide
Butyl formate
Butyl glycidyl ether
b551
b552
b553
b554
b555
1.132
b556
b557
b558
b559
b560
b561
b563
Beilstein
reference
Density,
g/mL
Refractive
index
0.98620
20
1.05425
25
1.462520
1.476720
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
⫺70
276
256–270
126
⬎110
89
124–126
22
1.517820
23
249
111
0.8920
0.749520
4
0.876
1.44420
1.381820
1.470020
⫺3.5
⫺124
192
92
269750mm
77
4
⬎110
i aq; misc alc, eth
13, 2228
0.93150
20
1.458725
41–44
17850mm
⬎110
0.8 aq
118.24
101.15
13, 1522
43, 324
0.837620
4
0.903
1.449120
1.433020
⫺95.1
16
144.2
202
95
102.13
2, 21
0.892
1.388920
⫺91.5
106
18
O
H2C 9 CHCH2OC(CH3)3
130.19
173, 988
0.917
1.416620
O
(CH3)3CNHNH2 ·HCl
124.61
43, 1734
C4H9N(CH2CH2OH)2
161.25
226.27
4, 285
(CH3)3CSi(CH3)2Cl
150.73
4,4, 4076
(CH3)3CC6H2(CH3)2OH
178.28
63, 2020
HOCH2CH2NHC4H9
C4H9OC2H5
H2N(CH2)3C[(CH2)3CH3](C2H5)CH2NH2
HOCH2C(C2H5)(C4H9)CH2OH
117.19
102.18
186.34
1, 369
160.25
C4H9SC2H5
HCONHC(CH3)3
HCO2C4H9
H2C 9 CHCH2OC4H9
(CH3)3C9O9OH
C4H9NCO
(CH3)3CNCO
CH3CH(OH)CO2C4H9
CH3COCH2CH2CO2C4H9
3
43
194
20
4
20
90.12
1 , 1579
0.896
1.4007
124.19
99.13
99.13
148.19
172.22
232, 36
0.945
0.880
0.868
0.984
0.974
1.480020
1.406120
1.386520
1.421020
1.427020
4, 175
32, 207
s chl
⫺8
⫺28
3417mm
37
11612mm
115
86
185–187
1085.5mm
⬎110
17
⫺4
69
91
s aq, alc, chl, eth
INTERACTIVE
b564
b565
b566
b567
b568
tert-Butylhydrazine
HCl
tert-Butyl hydroperoxide
1-Butylimidazole
Butyl isocyanate
tert-Butyl isocyanate
Butyl lactate
Butyl levulinate
Formula
weight
ROTATED
b562
tert-Butyl glycidyl
ether
Formula
LEFT
No.
b570
b571
b572
b573
b574
b575
b576
b577
1.133
b578
b579
Butyl 3-mercaptopropionate
Butyl methacrylate
sec-Butyl-2-methyl-2butenoate
tert-Butyl methyl ether
2-tert-Butyl-4-methylphenol
2-tert-Butyl-5-methylphenol
2-tert-Butyl-6-methylphenol
tert-Butyl-1-methyl-2propynyl ether
tert-Butyl methyl
sulfide
Butyl nitrite
tert-Butyl nitrite
HSCH2CH2CO2C4H9
162.25
H2C"C(CH3)CO2C4H9
CH3CH"C(CH3)CO2CH(CH3)C2H5
(CH3)3C9O9CH3
142.19
156.23
(CH3)3CC6H3(CH3)OH
164.25
(CH3)3CC6H3(CH3)OH
164.25
(CH3)3CC6H3(CH3)OH
164.25
(CH3)3COCH(CH3)C#CH
126.20
(CH3)3CSCH3
104.21
C4H9ONO
(CH3)3CONO
103.12
103.12
1.410020
10112mm
93
23, 1286
0.88925
15
0.889
1.423025
1.435020
170
8527mm
50
66
i aq; misc alc, eth
1, 381
0.740420
4
1.368920
⫺109
52
⫺28
0.924775
4
1.496975
51.7
237
100
4.8 aq; v s alc, eth; unstable acid solns
i aq; s org solv
0.964
1.519220
11812mm
105
230
107
4125mm
10
102
⫺3
v s alc
78
63
⫺13
⫺13
misc alc, eth
sl s aq; v s alc, chl,
eth, CS2
62, 507
1.519020
0.795
1.410020
13, 1591
0.82620
4
1.44120
1, 369
1, 382
0.911404
0.867120
4
1.3768
1.368720
1,3-Butylene glycol, b456
1,4-Butylene glycol, b457
2,3-Butylene glycol, b458
1,3-Butyleneglycol methyl ether, m64
1,2-Butylene oxide, e3
Butyl ether, d148
Butyl ethyl ketone, h15
tert-Butyl fluoride, f22
30–32
⫺97.8
Butyl glycol, b493
2,2⬘-(Butylimino)diethanol, b549
Butyl iodides, i26, i27, i38
Butyl levulinate, b582
Butyl mercaptans, b470, b471; m394, m395, m396
Butyl methanoate, b559
Butyl methyl ketone, d572
RIGHT
Butyl diglyme, b151
tert-Butyldihydroxybenzene, b534
Butyl disulfide, d146
tert-Butyl disulfide, d147
1-Butylene, b477
cis-2-Butylene, b478
trans-2-Butylene, b479
1,4-Butylene bis(2,3-epoxypropyl) ether, b185
88.15
0.795
DEAN 37261 (McGHP)
b569
ROTATED
b550
b564
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Beilstein
reference
Density,
g/mL
Refractive
index
0.855120
4
0.870415
1.442225
1.448025
0.973520
4
0.887
Name
b580
b581
b581a
Butyl 4-nitrobenzoate
Butyl octadecanoate
Butyl cis-9-octadecenoate
Butyl 4-oxopentanoate
4-(1-Butylpentyl)pyridine
O2NC6H4CO2C4H9
CH3(CH2)16CO2C4H9
CH3(CH2)8CH"CH(CH2)7CO2C4H7
CH3C("O)CH2CH2CO2C4H9
C4H9CHC(CH2)3CH3
tert-Butyl peroxobenzoate
2-sec-Butylphenol
2-tert-Butylphenol
4-sec-Butylphenol
4-tert-Butylphenol
tert-Butyl 4-phenoxyphenol ketone
tert-Butyl phenyl
carbonate
Butyl phenyl ether
4-tert-Butylphenyl
salicylate
Butyl propionate
tert-Butyl propionate
4-tert-Butyl pyridine
tert-Butyl 1-pyrrolecarboxylate
1-Butylpyrrolidine
4-tert-Butylstyrene
1-Butyl-3-sulfanilylurea
Butyltin trichloride
Butyltin tris(2-ethylhexanoate)
C6H5C("O)O9O9C(CH3)3
194.23
CH3CH2CH(CH3)C6H4OH
(CH3)3CC6H4OH
CH3CH2CH(CH3)C6H4OH
(CH3)3CC6H4OH
C6H5OC6H4C("O)C(CH3)3
150.22
150.22
150.22
150.22
254.33
C6H5OC("O)OC(CH3)3
194.23
CH3CH2CH2CH2OC6H5
HOC6H4CO2CH6H4C(CH3)3
150.22
270.31
6, 143
CH3CH2CO2C4H9
CH3CH2CO2C(CH3)3
(CH3)3C(C5H4N)
(C4H4N)CO2C(CH3)3
130.19
130.19
135.21
167.21
2, 241
23, 528
20, 252
0.881815
0.865
0.915
1.000
1.398225
1.393020
1.495220
1.468520
(C4H8N)C4H9
(CH3)3CC6H4CH"CH2
4-(H2N)C6H4SO2NHCONHC4H9
C4H9SnCl3
[CH3(CH2)3CH(C2H5)CO2]3SnC4H9
127.23
160.26
271.34
202, 4
53, 1254
14,4, 2667
0.814
0.875
1.444020
1.526020
282.17
605.43
44, 4346
1.693
1.105
1.522920
1.465020
b582
b583
b584
1.134
b585
b586
b587
b588
b589
b590
b597
b598
b599
203, 2872
Flash
point,⬚C
1608mm
343
⬎110
160
180
1.427020
1.487720
1076mm
267
91
⬎110
1.021
1.499020
760.2mm
93
0.982
0.978320
4
0.96920
4
114
0.9084
1.522220
1.522820
1.5150
1.4787114
228
221–224
13625mm
237
1753mm
112
⬎110
115
790.8mm
101
⫺19
62–64
210.3
82 (OC)
⫺89
146.8
118
197
9220mm
38
20
63
75
157
929mm
36
80
9310mm
81
⬎110
35–39
26.3
⫺26
Solubility in 100
parts solvent
s alc; v s acet
s eth
s alc, acet, eth
C5H4N
62, 489
6, 522
6, 524
83, 491
1.047
1.480520
0.935120
4
1.497020
12
⫺7
62
98
52–54
⫺37
143–145
i aq; s alc; v s eth
s hot aq, alc, eth
i aq; s alc, eth
⬎110
⬍0.1 aq; 79 alc; 153
EtOAc; 158 toluene
v s alc, eth; v sl s aq
INTERACTIVE
b600
b601
172.22
205.35
92, 259
22, 352
Boiling
point,⬚C
ROTATED
b593
b594
b595
b596
223.23
340.60
338.57
Melting
point,⬚C
LEFT
b591
b592
Formula
Formula
weight
No.
(CH3)3CC6H4CH3
C4H9SiCl3
(CH3)3CSiCl3
b608
b609
b610
b610a
4-tert-Butyltoluene
Butyltrichlorosilane
tert-Butyltrichlorosilane
Butyl trifluoroacetate
Butyltrimethoxysilane
tert-Butyl trimethylsilyl peroxide
Butylurea
Butyl vinyl ether
5-tert-Butyl-m-xylene
1-Butyne
b610b
b611
2-Butyne
2-Butyne-1,4-diol
CH3C#C9CH3
HOCH2C#CCH2OH
54.09
86.09
11, 261
b612
Butyraldehyde
CH3CH2CH2CHO
72.11
1, 662
b613
b614
b615
Butyramide
Butyric acid
Butyric anhydride
CH3CH2CH2CONH2
CH3CH2CH2COOH
[CH3CH2CH2C("O)]2O
87.12
88.11
158.20
b616
b617
␤-Butyrolactone
␥-Butyrolactone
b618
Butyronitrile
b605
b606
b607
1.135
CF3CO2C4H9
C4H9Si(OCH3)3
(CH3)3C9O9O9Si(CH3)3
170.1
178.3
162.3
C4H9NHCONH2
C4H9OCH"CH2
(CH3)3CC6H3(CH3)2
CH3CH2C#CH
116.16
100.16
162.28
54.09
CH3CH2CH2CN
5, 439
4,1, 582
43, 1905
0.861220
1.160
22
1.491820
1.437020
⫺52
97–100
190
149
132–134
dec 135
100.1
164–165
4141mm
22
1.0268
0.931220
4
0.821920
4
1.353
1.397920
1.393520
0.779220
0.867
2.211
g/L
0.688
1.400720
1.494620
41, 371
96–98
⫺92
68
45
40
⫺9
72
⫺126
94.2
205–206
8.1
1.45025
⫺32
56–58
27
238
152
0.801620
4
1.384320
⫺96/⫺99
74.8
⫺22
2, 275
2, 264
2, 274
0.958220
4
0.966820
4
1.399120
1.407020
116
⫺5.3/⫺5.7
⫺75/⫺66
216
163.5
199.5
72
54
86.09
86.09
171, 130
17, 234
1.056
1.12425
4
1.410920
1.434825
⫺43.5
⫺43.5
204
204
60
98
69.11
22, 252
0.795415
4
1.444020
⫺112
117.6
24
5, 447
Butyl propyl ketone, o38
Butyl stearate, b581
Butyl sulfate, d169
Butyl sulfide, d170
tert-Butyl sulfide, d171
Butyl sulfite, d172
Butyl sulfone, d173
␥-Butyrolactam, p285
s aq, alc, eth
0.3 aq
374 aq; 83 als; 0.04
bz; 2.6 eth; 70 acet
7.1 aq; misc alc, acet,
eth, EtOAc
16 aq; s alc
misc aq, alc, eth
s aq (dec); alc (dec),
eth
misc aq; s alc, acet, bz,
eth
3.3 aq; misc alc, eth
RIGHT
Butyl oleate, b581a
tert-Butyl perbenzoate, b584
Butyl o-phthalate, d165
Butyl 2-propenoate, b507a
148.25
191.56
191.56
DEAN 37261 (McGHP)
b602
b603
b604
ROTATED
b616
b617
INTERACTIVE
No.
Name
b619
b620
Butyrophenone
Butyryl chloride
c1
Formula
Beilstein
reference
Density,
g/mL
Refractive
index
1.519520
1.41220
1.136
1.021
1.026321
4
Caffeine
194.19
26, 461
1.2318
4
c2
c3
(⫾)-Camphene
(1R)-(⫹)-Camphor
136.24
152.24
5, 156
7, 101
0.842254
4
0.99225
4
c4
(1R,3S)-Camphoric
acid
200.23
9, 745
1.18620
4
c5
(⫾)-10-Camphorsulfonic acid
Carbazole
232.30
11, 314
167.21
20, 433
1.1018
4
182.22
10, 631
1.078
c9
4-Carbethoxy-2methyl-3-cyclohexen-1-one
Carbobenzyloxyglycine
Carbohydrazide
C6H5CH2OC("O)NHCH2COOH
H2NNHC("O)NHNH2
c10
Carbon disulfide
c11
c7
c8
1.455154
1.5462
Boiling
point,⬚C
11–13
⫺89
230
102
238
subl 178
51–52
179
159
207
Flash
point,⬚C
88
21
36
66
186–188
194 dec
245
1.488020
209.20
355
268–272
Solubility in 100
parts solvent
s aq (dec), alc (dec);
misc eth
2.1 aq; 1.5 alc; 18 chl;
0.19 eth; 1 bz; 2
acet
i aq; s alc, chl, eth
100 alc; 100 eth; 200
chl; 250 acet
at 25⬚C: 0.8 aq, 100
alc, 250 acet, 200
eth, 200 HOAc; s
chl
deliq moist air; sl s
HOAc, EtOAc; i eth
16 pyr; 11 acet; 3 eth;
0.8 bz; sl s HOAc,
PE
⬎110
122
3, 121
CS2
76.14
3, 197
1.263220
4
Carbon monoxide
CO
28.01
Merck:
12, 1861
c12
Carbon oxide sulfide
COS
60.07
c13
Carbon tetrabromide
CBr4
331.65
1.145
g/L
2.456
g/L
3.42
1, 68
157–158
1.627020
⫺111.6
46.5
⫺205
⫺191.5
⫺138.8
⫺50
90
190
⫺30
none
v s aq; i alc, bz, eth;
forms salts with
acids
0.3 aq; misc bz, chl,
eth, CCl4
2.3 aq; 16 alc; s chl,
EtOAc, HOAc
INTERACTIVE
90.08
ROTATED
7, 313
2, 274
Melting
point,⬚C
LEFT
148.21
106.55
c6
C6H5C("O)C3H7
CH3CH2CH2COCl
Formula
weight
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Carbon tetrachloride
CCl4
153.82
1, 64
1.58925
25
c15
Carbon tetrafluoride
CF4
88.01
1, 59
c16
c17
Carbon tetraiodide
4-Carboxybenzenesulfonamide
CI4
HOOCC6H4SO2NH2
1.89⫺183
liq
4.3220
4
519.63
201.20
1, 74
11, 390
1.460720
1.137
c2
⫺183.6
⫺127.8
none
0.05 aq; misc alc, bz,
chl, eth, CS2, PE
s bz, chl; dec hot alc
v s alc; s alkalis; i aq,
bz, eth
Carbazole, d751
Carbitol, e41a
Carbitol acetate, e42
Carbobenzoxy chloride, b91
Carbolic acid, p65
3-Carbomethoxypropionyl chloride, m195
Carbon bromotrichloride, b432
N-Carbonylsulfamyl chloride, c249
Carbonyl sulfide, c12
Carboxybenzaldehyde, f37
c3
c4
RIGHT
c1
76.7
171
dec 280
Capronitrile, h61
Caproyl chloride, h72
Capryl alcohol, o32
Caprylaldehyde, o43
Caprylic acid, o30
Caprylonitrile, o28
Capryloyl chloride, o39
N-(Carbamoylmethyl)iminodiacetic acid, a14
Carbamylurea, b238
Carbanilide, d775
Cadaverine, p30
2-Camphanone, c3
Capraldehyde, d7
Capric acid, d15
Capric alcohol, d16
Caproaldehyde, h51
Caproic acid, h64
Caproic anhydride, h65
6-(or ⑀)-Caprolactam, o61
⑀-Caprolactone, h69
⫺23
DEAN 37261 (McGHP)
c14
ROTATED
c5
c6
c7
INTERACTIVE
No.
c18
Name
c20
c21
(4-Carboxybutyl)triphenylphosphonium
bromide
1-(Carboxymethyl)pyridinium chloride
R-(⫺)-Carvone
Catechol
c22
c23
c19
Formula
HOOC(CH2)4(C6H5)3Br
Formula
weight
Beilstein
reference
Refractive
index
Melting
point,⬚C
443.33
205–207
173.60
189 dec
1.138
7, 157
C6H5CH"CHCOC6H5
119.92
208.26
7, 478
c23a
c24
c25
c26
c26a
c27
c28
Chloroacetaldehyde
2-Chloroacetamide
2⬘-Chloroacetanilide
3⬘-Chloroacetanilide
4⬘-Chloroacetanilide
Chloroacetic acid
Chloroacetic anhydride
ClCH2CHO
ClCH2CONH2
ClC6H4NHCOCH3
ClC6H4NHCOCH3
ClC6H4NHCOCH3
ClCH2COOH
[ClCH2C("O)]2O
78.50
93.51
169.61
169.61
169.61
94.50
170.98
1, 610
2, 199
12, 559
12, 604
12, 611
2, 194
2, 199
c29
CH3COCH2CH2CONHC6H4Cl
ClCH2CN
C6H5COCH2Cl
ClC6H4COCH3
ClC6H4COCH3
ClCH2COCl
H2C"C(Cl)CN
ClC6H3(CH3)NH2
211.65
75.50
154.60
154.60
154.60
112.94
87.51
141.60
2, 201
7, 282
71, 151
7, 281
2, 199
c38
4⬘-Chloroacetoacetanilide
Chloroacetonitrile
2-Chloroacetophenone
o-Chloroacetophenone
p-Chloroacetophenone
Chloroacetyl chloride
2-Chloroacrylonitrile
2-Chloro-4-aminotoluene
2-Chloroaniline
ClC6H4NH2
c39
3-Chloroaniline
ClC6H4NH2
0.96520
4
1.344
1.498920
⬍15
104–106
230
245
88
137
1.125
1.071262
4
1.507020
12
55–57
5050mm
20825mm
2
⬎110
⫺16
119
88–90
79–81
179
61
46
85–86
225 dec
189
203
126
134
dec
160 (CC)
47
88
90
none
6
100
1.38520
4
1.580 (c)
1.549420
4
1.429765
1.422520
12, 988
1.193
1.32415
1.188
1.19220
4
1.42020
4
1.096
1.1671
1.543820
1.55520
1.454120
1.429020
1.584020
20–21
⫺21.8
⫺65
24–25
126
245
228738mm
237
106
89
238
127.57
12, 597
1.212520
4
1.589520
⫺14
208.8
97
127.57
12, 602
1.215022
4
1.593120
⫺10.4
230.5
123
54–56
Solubility in 100
parts solvent
i aq; misc alc
43 aq; v s alkalis, pyr;
s alc, bz, chl, eth
v s bz, chl, CS2, eth; sl
s alc
s aq, alc, eth
10 aq; 10 alc; sl s eth
s alc
v s alc, bz, CS2
i aq; v s alc, eth, CS2
v s aq; s alc, bz, eth
v s chl, eth; sl s bz;
dec by aq, alc
i aq; v s alc, bz, eth
sl s aq; s eth
i aq; misc alc, eth
dec by aq, MeOH
0.88 aq; s acids, most
common org solvents
i aq; s most common
org solvents
INTERACTIVE
Catecholborane
Chalcone
Flash
point,⬚C
ROTATED
150.22
110.11
Boiling
point,⬚C
LEFT
C6H4-1,2-(OH)2
c30
c31
c32
c33
c34
c36
c37
Density,
g/mL
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
4-Chloroaniline
c41
1-Chloroanthraquinone
2-Chloroanthraquinone
2-Chlorobenzaldehyde
3-Chlorobenzaldehyde
4-Chlorobenzaldehyde
2-Chlorobenzamide
Chlorobenzene
c42
c43
c44
c45
c46
c47
c48
c49
c50
1.139
c51
4-Chlorobenzenesulfonamide
4-Chlorobenzenesulfonic acid
4-Chlorobenzenesulfonyl chloride
2-Chlorobenzoic acid
ClC6H4NH2
127.57
12, 607
242.66
1.16977
4
1.554685
72.5
232
7, 787
160
sublimes
242.66
7, 787
211
sublimes
ClC6H4CHO
ClC6H4CHO
ClC6H4CHO
ClC6H4CONH2
C6H5Cl
140.57
140.57
140.57
155.58
112.56
7, 233
7, 234
7, 235
9, 336
5, 199
11
18
47
142–144
⫺45.3
215
214
214
87
88
87
131.7
28
ClC6H4SO2NH2
191.64
11, 55
ClC6H4SO3H
192.62
11, 54
14922mm
107
ClC6H4SO2Cl
211.07
11, 55
14115mm
107
ClC6H4COOH
156.57
9, 334
1.248320
4
1.241
61
1.1964
1.5658
1.554520
1.55261
1.106320
1.524820
146
55
1.54420
4
140
sl s aq; s alc, bz, eth
s aq; v s alc, bz, eth
0.049 aq30; v s alc, bz,
chl, eth
s hot aq, hot alc, hot
eth
dec aq, alc; v s bz, eth
0.11 aq; v s alc, eth
Chloroacetaldehyde diethyl acetal, c96
Chloroacetaldehyde dimethyl acetal, c105
Chloroacetone, c229a
Chloroenthranilic acid, a138
5-Chloroanthranilonitrile, a139
Chlorobenzeneamines, c38 thru c40
p-Chlorobenzenethiol, c252
RIGHT
Cetyl alcohol, h35
Cetyl bromide, b345
Chalcone, d768
Chloral, t218
Chloramine T, c258
Chloranil, t34, t35
Chlorendic anhydride, h28
(3-Carboxy-2-hydroxypropyl)trimentylammonium hydroxide,
c19
(Carboxylmethyl)trimethylammonium hydroxide, b133
(Carbomethylimino)bis(ethylenenitrilo)-tetraacetic acid, d363
3-Carboxylpropyl disulfide, d809
Carvene, L17
Cellosolve, e40
Cellosolve acetate, e42
s hot aq; v s alc, acet,
eth, CS2
sl s alc; s hot bz; misc
eth
sl s alc, bz; i eth
DEAN 37261 (McGHP)
c40
ROTATED
c19
c20
c22
c41
c42
INTERACTIVE
No.
c52
c53
c54
c55
c56
c57
c58
c59
1.140
c60
c61
c62
c64
c65
c70
Beilstein
reference
Density,
g/mL
Refractive
index
1.49625
4
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
158
241–243
46
93
44–47
232
223
300
77
19617mm
29
264
98
245
⬎110
⫺6.4
152
58
1.443825
⫺56.7
137.7
38
1.4463
⫺36
138.7
47
Solubility in 100
parts solvent
ClC6H4COOH
ClC6H4COOH
ClC6H4CN
ClC6H4CN
ClC6H4COC6H5
156.57
156.57
137.57
137.57
216.67
9, 337
9, 340
9, 336
9, 341
7, 419
ClC6H4COC6H5
216.67
7, 419
ClC6H4CCl3
229.92
5, 302
1.508
1.581720
ClC6H4CCl3
229.92
5, 303
1.495
1.572220
ClC6H4CF3
180.56
53, 692
1.354025
1.451325
ClC6H4CF3
180.56
53, 692
1.331125
ClC6H4CF3
180.56
1.35320
ClC6H4COC6H4COOH
260.68
10, 750
ClC6H4COCl
175.01
9, 336
1.382
1.571820
⫺3
238
⬎110
dec by aq & alc
ClC6H4COCl
175.01
9, 341
1.377
1.578020
14
222
105
dec by aq & alc
ClC6H4CH2OH
ClC6H4CH2NH2
ClC6H4CH2NH2
ClC6H4CH2Cl
142.59
141.60
141.60
161.03
6, 444
12, 1073
12, 1074
5, 297
72
1.173
1.164
1.274
1.563020
1.558620
1.559120
⫺17
234
10411mm
215
214
88
90
82
ClC6H4CH2Cl
161.03
5, 308
30
222
97
ClC6H4CH2CN
151.60
9, 448
24
242
⬎110
108
⬎110
s alc, acet, bz, eth
150
1.554020
0.04 aq; v s alc, eth
0.02 aq; v s alc, eth
s alc, eth
s alc, bz, chl, eth
s alc, bz, eth
v s alc, eth
s alc, v s eth
INTERACTIVE
c71
Formula
weight
ROTATED
c66
c67
c68
c69
3-Chlorobenzoic acid
4-Chlorobenzoic acid
2-Chlorobenzonitrile
4-Chlorobenzonitrile
2-Chlorobenzophenone
4-Chlorobenzophenone
2-Chlorobenzotrichloride
4-Chlorobenzotrichloride
2-Chlorobenzotrifluoride
3-Chlorobenzotrifluoride
4-Chlorobenzotrifluoride
2-(4-Chlorobenzoyl)benzoic acid
2-Chlorobenzoyl
chloride
4-Chlorobenzoyl
chloride
4-Chlorobenzyl alcohol
2-Chlorobenzylamine
4-Chlorobenzylamine
2-Chlorobenzyl
chloride
4-Chlorobenzyl
chloride
2-Chlorobenzyl
cyanide
Formula
LEFT
c63
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
c73
c74
c74a
c75
c76
c77
c78
c79
c80
1.141
c81
c82
c83
c84
c85
c86
c87
c88
c89
c90
c96
Chlorocresol, c176, c177
151.60
9, 448
ClC6H4CH2SH
158.65
6, 466
3
1 , 949
30.3
1.589320
1.202
20
4
88.54
88.54
92.57
92.57
108.56
106.55
90.55
90.55
1.4712
1, 118
1, 119
12, 398
1, 669
12, 176
12, 176
0.9601
0.952
0.886420
4
0.873220
4
1.088320
4
1.055
0.942620
0.929
CH3CH(Cl)CH"CH2
CH3CO2CH2CH2CH2CH2Cl
CH3CH(Cl)C#CH
CH3CH(Cl)CH2COOH
ClCH2CH2CH2COOH
ClCH2CH2CH2CN
ClCH2CH2CH2COCl
90.55
150.61
88.54
122.55
122.55
103.55
141.00
12, 174
22, 141
14, 970
2, 277
2, 278
2, 278
2, 278
0.900120
4
1.072
0.961
1.18620
4
1.223620
4
1.158
1.258
1.415520
1.433820
1.428020
1.442120
1.452120
1.441320
1.460920
ClCH2Si(CH3)2Cl
143.09
1.086
1.437320
H2C"C(CH2Cl)2
125.00
12, 181
1.080
1.475320
ClC6H4CH"CHCO2H
182.61
9, 594
ClC6H11
C6H11(CH2)3Cl
118.61
160.69
5, 21
52, 23
1.00020
4
0.997
1.462020
1.466220
C5H9Cl
CH3(CH2)9Cl
(C6H11)2BCl
104.58
176.73
212.57
5, 19
1, 168
164, 1637
1.005120
4
0.868
0.970
1.451220
1.436220
ClCH2CH(OC2H5)2
152.62
1, 611
1.018
1.415720
Chlorodibromomethane, d88
20
1.402120
1.397120
1.451820
1.417220
1.439020
1.439020
⬎110
76
20
H2C"CHCH"CHCl
H2C"CHC(Cl)"CH2
CH3CH2CH2CH2Cl
CH3CH2CH(Cl)CH3
ClCH2CH2CH2CH2OH
CH3CH(Cl)C("O)CH3
CH3CH"CHCH2Cl
CH3CH"CHCH2Cl
267
⫺123.1
⫺131.3
16.3
12–16
⫺14
68
59
78.4
68.2
8920mm
117
84.1
85
⫺20
v s chl
⫺9
⫺15
32
21
⫺15
⫺5
0.11 aq; misc alc, eth
0.1 aq; misc alc, eth
s alc, eth
v s alc, eth
s alc, acet
s alc, acet
65
9222mm
68–70
10917mm
19622mm
197
174
⫺20
64
1
⬎110
⬎110
85
72
v s acet
114752mm
21
138
36
142
795mm
28
78
i aq; s alc, eth
114
223
1011mm
15
83
i aq
i aq
157
29
s alc, eth
sl s aq; v s eth
s alc, eth
dec by aq, alc; s eth
208–210
⫺44
⫺34
ROTATED
c93
c94
c95
ClC6H4CH2CN
RIGHT
c91
c92
4-Chlorobenzyl
cyanide
4-Chlorobenzyl
mercaptan
1-Chloro-1,3-butadiene
2-Chloro-1,3-butadiene
1-Chlorobutane
2-Chlorobutane
4-Chloro-1-butanol
3-Chloro-2-butanone
cis-1-Chloro-2-butene
trans-1-Chloro-2butene
3-Chloro-1-butene
4-Chlorobutyl acetate
3-Chloro-1-butyne
3-Chlorobutyric acid
4-Chlorobutyric acid
4-Chlorobutyronitrile
4-Chlorobutyryl chloride
Chloro(chloromethyl)dimethylsilane
3-Chloro-2-chloromethyl-1-propene
trans-2-Chlorocinnamic acid
Chlorocyclohexane
1-Chloro-3-cyclohexylpropane
Chlorocyclopentane
1-Chlorodecane
Chlorodicyclohexylborane
2-Chloro-1,1-diethoxyethane
DEAN 37261 (McGHP)
c72
2-Chloro-N,N-diethylethylamine, d328
INTERACTIVE
No.
c97
c98
c99
c100
c100a
c101
1.142
c102
c103
c104
c107
c108
c110
c111
c112
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
ClCH2CH2CH(OC2H5)2
166.65
1, 632
0.995
1.424020
F2C(Cl)COOH
130.48
2, 201
1.540
1.355920
ClC6H3F2
148.54
54, 653
1.353
1.475020
CH3C(Cl)F2
100.50
13, 138
4.108 g/L
⫺131
⫺10
ClCH"CF2
98.48
4.025 g/L
⫺138.5
⫺18.5
HCClF2
86.47
13, 41
1.4909⫺69
⫺157
⫺40.8
0.30 aq
ClC6H3(OH)2
144.56
62, 818
107
14718mm
v s aq, alc, chl, eth
ClC6H3(OH)2
144.56
6, 849
101–102
263
v s aq; i alc, s eth
ClC6H3(OCH3)2
172.61
63, 4432
ClCH2CH(OCH3)2
124.57
ClC6H2(CH3)2NH2
155.63
12, 1125
ClC6H2(CH3)2OH
156.61
62, 463
(CH3)3CCH2Cl
106.59
1, 141
122.60
(CH3)2Si(Cl)H
(CH3)2Si(Cl)CH"CH2
94.62
120.7
4,4, 4080
ClC6H2(NO2)2NH2
217.57
121, 367
36
122
none
127
32
0.19 aq
1.211
1.546720
234
110
1.09420
20
1.414820
130
28
1.110
0.86620
4
0.85220
4
0.88425
4
⬎110
38–40
1.404220
20
ClCH2C(CH3)2CH2OH
24–26
8425mm
Solubility in 100
parts solvent
115.5
246
⫺20
84.4
35mm
0.03 aq; 100 alc; s bz,
eth, alkalis
32
1.4504
34–36
87
71
1.382720
1.41425
⫺111
36
82.5
⫺28
⫺5
159
INTERACTIVE
c113
Formula
weight
ROTATED
c109
3-Chloro-1,1-diethoxypropane
Chlorodifluoroacetic
acid
1-Chloro-2,4-difluorobenzene
1-Chloro-1,1-difluoroethane
1-Chloro-2,2-difluoroethylene
Chlorodifluoromethane
1-Chloro-2,4-dihydroxybenzene
2-Chloro-1,4-dihydroxybenzene
2-Chloro-1,4-dimethoxybenzene
2-Chloro-1,1-dimethoxyethane
2-Chloro-4,6-dimethylaniline
4-Chloro-3,5-dimethylphenol
1-Chloro-2,2-dimethylpropane
3-Chloro-2,2dimethyl-1-propanol
Chlorodimethylsilane
Chlorodimethylvinylsilane
6-Chloro-2,4-dinitroaniline
Formula
LEFT
c105
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
c115
c116
c117
c118
c119
c120
1-Chloro-2,4-dinitrobenzene
2-Chloro-3,5-dinitrobenzoic acid
Chlorodiphenylmethane
Chlorodiphenylmethylsilane
Chlorodiphenylphosphine
1-Chlorododecane
1-Chloro-2,3-epoxypropane
1.143
c122
c123
2-Chloroethanol
2-(2-Chloroethoxy)ethanol
2-[2-(2-Chloroethoxy)ethoxy]ethanol
2-Chloroethoxytrimethylsilane
2-Chloroethylamine
hydrochloride
1-Chloro-2-ethylbenzene
(2-Chloroethyl)benzene
Chloroethylene
N-(2-Chloroethyl)-Nethylamine
2-Chloroethyl ethyl
ether
c124
c125
c126
c127
c128
c129
c130
c131
Chlorodimethyl ether, c173
5, 263
ClC6H2(NO2)2COOH
246.56
9, 415
2
1.498275
4
20
4
1.585760
20
52–54
315
186
198
241
explodes
1403mm
⬎110
C6H5CH(Cl)C6H5
202.68
5 , 500
1.140
1.5951
(C6H5)2Si(Cl)CH3
232.8
162, 606
1.127720
4
1.574220
295
⬎110
(C6H5)2PCl
220.64
16, 763
1.229
1.633820
320
⬎110
CH3(CH2)11Cl
H2C 9 CHCH2Cl
204.79
92.53
17, 6
0.867320
4
1.181220
4
1.4426
1.435820
⫺9
⫺57.2
116
116.1
93
31
v s alc; s bz
5.9 aq; misc alc, chl
64.52
1, 82
0.921404
1.374210
⫺139
12.3
⫺50
ClCH2CH2OH
ClCH2CH2OCH2CH2OH
80.52
124.57
1, 337
1, 467
1.201920
1.180
1.442220
1.452920
⫺67.5
128.6
815mm
60
90
0.45 aq0; 48 alc; misc
eth
misc aq, alc
ClCH2CH2OCH2CH2OCH2CH2OH
ClCH2CH2OSi(CH3)3
168.62
1, 468
1.160
1.458020
1205mm
107
152.70
43, 1856
0.944
1.414020
134
30
ClCH2CH2NH2 ·HCl
115.99
4, 133
ClC6H4C2H5
140.61
179.2
66
i aq; misc alc, eth
C6H5CH2CH2Cl
140.61
5, 354
1.069
1.530020
8416mm
66
s alc, bz, eth
H2C"CHCl
C6H5N(C2H5)CH2CH2Cl
62.50
183.68
1, 186
123, 263
0.97⫺14
1.075
⫺13.4
16442mm
⫺78
⬎110
sl s aq; s alc
1.558420
ClCH2CH2OCH2CH3
108.57
1, 337
0.989
1.412020
107
15
O
CH3CH2Cl
146
⫺81
1.05525
25
2-Chloroethyl alcohol, c122
17
sl s alc; s hot alc, bz,
eth
0.3 aq
⫺154
2-Chloroethyl ether, b163
ROTATED
Chloroethane
202.55
RIGHT
c121
ClC6H3(NO2)2
DEAN 37261 (McGHP)
c114
INTERACTIVE
No.
c132
Name
Formula
Chloroform-d
1-Chloroheptane
1-Chlorohexadecane
c133a
c134
c135
c136
1.144
c137
c138
c139
c141
c142
c143
c144
Refractive
index
1.035
1.409020
186.08
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
90
15
9815mm
100
1530.3mm
⬎110
Solubility in 100
parts solvent
186
156.61
63, 675
184.11
20, 17
CH3C6H4SO3CH2CH2Cl
234.70
112, 45
1.294
1.529020
H2C"CHOCH2CH2Cl
106.55
12, 473
1.052515
15
1.437020
⫺69.7
110
16
0.6 aq
ClC6H4F
130.55
51, 110
1.244
1.501020
⫺42.4
138.5
31
s alc, eth
ClC6H4F
130.55
1.219
1.494420
126
20
s alc, eth
Cl(F)C6H3CH2Cl
179.02
1.401
1.537220
93
FC6H4C("O)CH2CH2CH2Cl
200.64
1.220
1.525520
⬎110
Cl(F)C6H3NO2
175.55
51, 130
1.602817
1.567417
41.5
12717mm
Cl(F)C6H3OH
146.55
64, 880
1.344
1.5300
23
884mm
75
Cl(F)C6H3CH3
144.58
1.191
1.502620
156
46
20
C6H5OCH2CH2Cl
4
1.129
1.534020
236
743mm
Cl(F)C6H3CH3
144.58
5 , 813
1.186
1.4998
158
CHCl3
119.39
1, 61
1.483220
1.445920
⫺63.6
61.1
CDCl3
CH3(CH2)6Cl
CH3(CH2)15Cl
120.39
134.65
260.89
13, 63
1, 154
1, 172
1.500
0.88116
0
0.865
1.444520
1.425020
1.449020
⫺64
⫺69
60.9
159–161
1491mm
LEFT
c140
1, 337
Density,
g/mL
51
41
⬎110
0.50 aq25; misc alc, bz,
eth, PE, CCl4
see under chloroform
misc alc, eth
INTERACTIVE
c146
c147
c148
c133
94.54
Beilstein
reference
ROTATED
ClCH2CH2OCH3
c145
2-Chloroethyl methyl
ether
N-(2-Chloroethyl)morpholine HCl
2-Chloroethyl phenyl
ether
N-(2-Chloroethyl)piperidine HCl
2-Chloroethyl ptoluenesulfonate
2-Chloroethyl vinyl
ether
1-Chloro-2-fluorobenzene
1-Chloro-3-fluorobenzene
2-Chloro-6-fluorobenzyl chloride
4-Chloro-4⬘-fluorobutyrophenone
3-Chloro-4-fluoronitrobenzene
2-Chloro-4-fluorophenol
2-Chloro-6-fluorotoluene
4-Chloro-2-fluorotoluene
Chloroform
Formula
weight
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
c152
c153
c154
c155
c156
c157
c158
1.145
c159
c160
c161
c162
0.878020
4
1.204
1.419520
1.456020
⫺94
1-Chlorohexane
6-Chloro-1-hexanol
4-Chloro-4⬘-hydroxybenzophenone
5-Chloro-8-hydroxy7-iodoquinoline
5-Chloro-8-hydroxyquinoline
1-Chloro-4-iodobenzene
1-Chloro-3-iodopropane
1-Chloro-3-mercapto2-propanol
Chloromethane
CH3(CH2)5Cl
Cl(CH2)6OH
ClC6H4C("O)C6H4OH
120.62
136.62
232.67
1, 143
82, 187
175–178
305.50
21, 98
172
179.61
21, 95
130
ClC6H4I
238.46
5, 221
1.18657
4
Cl(CH2)3I
204.44
1, 114
1.904
HSCH2CH(OH)CH2Cl
126.61
13, 2156
1, 59
3-Chloro-4-methoxyaniline
5-Chloro-2-methoxyaniline
1-Chloro-2-methoxybenzene
5-Chloro-2-methoxybenzoic acid
2-Chloro-6-methoxypyridine
ClC6H3(OCH3)NH2
157.60
13, 511
50–55
ClC6H3(OCH3)NH2
157.60
13, 383
83–85
ClC6H4OCH3
142.59
6, 184
ClC6H3(OCH3)COOH
186.59
10, 103
CH3O(Cl)(C5H3N)
143.57
CH3Cl
50.49
26
98
i alc, eth; 0.8 chl; 0.6
HOAc
sl s aq HCl
227
108
1.546320
170–172
⬎110
1.277
1.527620
571.3mm
97
2.064 g/L
1.3712⫺24
⫺24.2
⬍0
53–54
⫺97.7
1.544520
1.123
i aq
sl s aq; v s alc, eth
s alc
0.48 aq;25 s alc,; misc
chl, eth, HOAc
110
196
76
i aq; s alc, eth
98–100
1.526320
1.207
186
1-Chloro-3-hydroxypropane, c231
5-Chloro-2-hydroxyaniline, a147
Chlorohydroxybenzoic acids, c245, c246
RIGHT
2-Chloro-6-fluorobenzal chloride, t238
␣-Chloro-4-fluorotoluene, f16
134
11014mm
25713mm
DEAN 37261 (McGHP)
c149
c150
c151
ROTATED
c133
c134
c152
c153
INTERACTIVE
2-Chloro-6-methylaniline
3-Chloro-2-methylaniline
3-Chloro-4-methylaniline
4-Chloro-2-methylaniline
5-Chloro-2-methylaniline
3-(Chloromethyl)benzoyl chloride
DL-4-Chloro-2-(␣methylbenzyl)phenol
1-Chloro-3-methylbutane
2-Chloro-2-methylbutane
Chloromethyldichloromethylsilane
Chloromethyl ethyl
ether
3-(Chloromethyl)heptane
Chloromethyl methyl
ether
Chloromethyl methyl
sulfide
1-(Chloromethyl)naphthalene
4-Chloro-2-methylphenol
c164
c165
c166
c167
c168
1.146
c169
c169a
c170
c171
c172
c172a
c173
c174
c175
c176
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
CH3O(Cl)C6H3NH2
141.60
121, 388
1.152
1.576120
2
215
98
CH3O(Cl)C6H3NH2
141.60
12, 836
1.185
1.587420
2
11710mm
⬎110
CH3O(Cl)C6H3NH2
141.60
12, 988
1.583020
25
238
100
CH3O(Cl)C6H3NH2
141.60
12, 835
1.584820
27
241
99
CH3O(Cl)C6H3NH2
141.60
12, 835
1.584020
22
237
160
ClCH2C6H4COCl
189.04
92, 325
1.330
1.574820
15020mm
⬎110
C6H5CH(CH3)C6H3(Cl)OH
232.71
64, 4710
1.238
1.599420
1552mm
⬎110
ClCH2CH2CH(CH3)CH3
106.60
0.875020
1.408420
⫺104
99
⬍21
sl s aq; misc alc, eth
CH3CH2CCl(CH3)2
106.59
1, 134
0.865020
4
1.405220
⫺73.7
85
⫺9
i aq; s alc, eth
ClCH2Si(Cl)2CH3
163.5
43, 1888
1.286
1.449420
121
110
12, 645
1.0420
4
1.404020
79–83
19
0.876920
1.431920
172
60
1.070320
4
1.396120
57–59
15
1.153
1.496320
105
17
1.180
1.638020
32
16925mm
⬎110
45–48
220–225
⬎110
ClCH2OCH2CH3
CH3CH2CH2CH2CH(CH2Cl)CH2CH3
ClCH2OCH3
94.54
148.68
80.51
1, 580
ClCH2SCH3
95.48
C10H7CH2Cl
176.65
5, 566
CH3(Cl)C6H3OH
142.59
6, 359
⫺103.5
s alc
s hot alc
s alc; v s eth
dec by aq; s acet, CS2
sl s aq
INTERACTIVE
c163
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
c178
c179
c180
c181
c182
c183
c184
1.147
c185
c186
c187
c188
c189
c190
4-Chloro-3-methylphenol
1-Chloro-2-methyl-2phenylpropane
1-Chloro-2-methylpropane
2-Chloro-2-methylpropane
1-Chloro-2-methylpropene
3-Chloro-2-methylpropene
Chloromethyltrimethylsilane
6-(Chloromethyl)uracil
1-Chloronaphthalene
2-Chloronaphthalene
4⬘-Chloro-3⬘-nitroacetophenone
2-Chloro-4-nitroaniline
2-Chloro-5-nitroaniline
4-Chloro-2-nitroaniline
CH3(Cl)C6H3OH
142.59
6, 381
C6H5C(CH3)2CH2Cl
168.67
52, 320
65–68
1.524020
1.047
235
i aq; s alc, bz, chl, eth,
acet
9610mm
92
(CH3)2CHCH2Cl
92.57
1, 124
0.8829
1.4010
⫺130.3
68.9
⬍21
0.09 aq; misc alc, eth
(CH3)3CCl
92.57
1, 125
0.842020
1.385620
⫺26
50.8
⬍0
sl s aq; misc alc, eth
(CH3)2C"CHCl
90.55
1, 209
0.918620
4
1.422520
68.1
⫺1
misc alc, eth
ClCH2C(CH3)"CH2
90.55
1, 209
0.921015
4
1.427220
72
⫺12
misc alc, eth
122.67
43, 1844
0.886120
4
1.418020
99
⫺2
160.56
231, 328
C10H7Cl
C10H7Cl
ClC6H3(NO2)C("O)CH3
162.62
162.62
199.60
5, 541
259
256
121
73, 995
⫺2.3
60
101
ClC6H3(NO2)NH2
172.57
12, 733
107–109
ClC6H3(NO2)NH2
172.57
12, 732
119–121
ClC6H3(NO2)NH2
172.57
12, 729
117–119
ClCH2Si(CH3)3
⫺80
257 dec
1.193820
4
1.137771
␣-Chloronitrotoluene, n45
15
1.632620
1.607971
s alc, bz, PE
s alc, bz, chl, eth
sl s aq; v s alc, eth
v s alc, eth
Chloronitro-␣,␣,␣-trifluorotoluenes, c199, c200
RIGHT
Chloromethylbenzenes, b90, c255, c256, c257
(Chloromethyl)oxirane, c120
15
DEAN 37261 (McGHP)
c177
ROTATED
c184
INTERACTIVE
4-Chloro-3-nitroaniline
1-Chloro-2-nitrobenzene
1-Chloro-3-nitrobenzene
1-Chloro-4-nitrobenzene
2-Chloro-4-nitrobenzoic acid
2-Chloro-5-nitrobenzoic acid
4-Chloro-3-nitrobenzoic acid
4-Chloro-3-nitrobenzophenone
2-Chloro-5-nitrobenzotrifluoride
4-Chloro-3-nitrobenzotrifluoride
4-Chloro-2-nitrophenol
2-Chloro-6-nitrotoluene
4-Chloro-2-nitrotoluene
1-Chlorooctadecane
1-Chlorooctane
1-Chloropentane
3-Chloro-2,4-pentanedione
5-Chloro-2-pentanone
3-Chloroperoxybenzoic acid
c192
c193
c194
c195
c196
1.148
c197
c198
c199
c200
c201
c202
c203
c203a
c204
c204a
c205
c206
c207
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
99–101
Solubility in 100
parts solvent
ClC6H3(NO2)NH2
172.57
12, 731
v s alc; s eth
ClC6H4NO2
157.56
5, 241
1.348
33
246
123
s alc, bz, eth
ClC6H4NO2
157.56
5, 243
1.53420
4
44
236
103
sl s alc; v s chl, eth
ClC6H4NO2
157.56
5, 243
1.520
83–84
242
⬎110
sl s alc; v s eth, CS2
ClC6H3(NO2)COOH
201.57
9, 404
ClC6H3(NO2)COOH
201.57
9, 403
ClC6H3(NO2)COOH
201.57
9, 402
ClC6H3(NO2)C("O)C6H5
261.66
71, 230
ClC6H3(NO2)CF3
225.55
1.527
1.508320
ClC6H3(NO2)CF3
225.55
1.511
1.489320
ClC6H3(NO2)OH
ClC6H3(NO2)CH3
173.56
171.58
6, 238
5, 327
1.537770
ClC6H3(NO2)CH3
171.58
5, 327
CH3(CH2)17Cl
CH3(CH2)7Cl
CH3(CH2)4Cl
CH3COCH(Cl)COCH3
288.95
148.68
106.60
134.56
13, 566
1, 159
1, 130
1, 785
0.849
0.875
0.882020
1.129
1.451620
1.429820
1.411520
1.483020
ClCH2CH2CH2COCH3
ClC6H5C(O)OOH
120.58
172.57
12, 738
94, 972
1.057118
4
1.439020
139–141
s hot aq, hot bz
1.60818
166–168
sl s aq; s alc, bz, eth
1.64518
180–183
sl s alc; s hot aq
104–106
23513mm
231
98
⫺2.5
222
101
85–87
36
238
125
i aq
39
240718mm
⬎110
i aq
⫺58
⫺99
1581.5mm
182
107–108
5218mm
⬎110
70
13
12
7220mm
35
69–71
0.02 aq; misc alc, eth
s acet, eth
INTERACTIVE
c191
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
2-Chlorophenol
ClC6H4OH
128.56
6, 183
1.257323
4
1.556520
9.8
175
63
c209
c210
3-Chlorophenol
4-Chlorophenol
ClC6H4OH
ClC6H4OH
128.56
128.56
6, 185
6, 186
1.24545
4
1.223878
4
1.556540
1.547940
33
43
214
220
⬎110
115
c211
4-Chlorophenoxyacetic
acid
2-(4-Chlorophenoxy)2-methylpropanoic
acid
(⫾)-2-(4-Chlorophenoxy)propanoic acid
4-Chlorophenylacetic
acid
(4-Chlorophenyl)acetonitrile
2-Chloro-1,4-phenylenediamine sulfate
4-Chloro-1,2-phenylenediamine
1-(4-Chlorophenyl)ethanol
3-Chlorophenyl isocyanate
4-Chlorophenyl isocyanate
4-Chlorophenyl phenyl
sulfone
ClC6H4OCH2COOH
186.59
6, 187
157–159
ClC6H4OC(CH3)2COOH
214.65
Merck:
12, 2437
118–119
ClC6H4OCH(CH3)COOH
200.62
63, 695
117
ClC6H4CH2COOH
170.60
9, 448
108
ClC6H4CH2CN
151.60
9, 448
30.5
H2NC6H3(Cl)NH2 · H2SO4
240.67
13, 117
251–253
s aq
ClC6H3(NH2)2
142.59
13, 25
70–73
s mineral acids
ClC6H4CH(CH3)OH
156.61
61, 236
1.171
1.541O20
ClC6H4NCO
153.57
12, 606
1.260
1.557620
ClC6H4NCO
153.57
12, 616
1.200
1.561820
ClC6H4SO2C6H5
252.72
61, 149
1-Chloro-3-phenylpropane
4-Chlorophenyl
sulfone
C6H5(CH2)3Cl
154.64
5, 391
(ClC6H5)2SO2
287.17
6, 327
c212
c213
c214
c215
c216
1.149
c217
c218
c219
c220
c221
c223
4-Chlorophenyl sulfone, b171
265–267
⬎110
11910mm
⬎110
⫺4.4
11443mm
86
29–31
204
⬎110
94
1.080
at 20⬚C: 74 acet; 44
bz; 5 CCl4; 65 diox;
21 i-PrOH
1.520720
219
145–148
87
25010mm
4-Chlorophenyl sulfoxide, b172
ROTATED
p-Chlorophenacyl bromide, b286
Chlorophenylamines, c38, c39, c40
v s aq, alc, eth; s bz
RIGHT
c222
sl s aq; v s alc, eth,
caustic alkali
sl s aq; s alc, eth
sl s aq; v s alc, chl,
eth, CHCl3, glyc
s aq; MeOH
DEAN 37261 (McGHP)
c208
INTERACTIVE
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
171, 162
1, 104
1, 105
0.889920
0.856320
1.388620
1.377720
3-Chloro-1,2-propanediol
2-Chloropropanoic
acid
3-Chloropropanoic
acid
1-Chloro-2-propanol
3-Chloro-1-propanol
Chloro-2-propanone
ClCH2CH(OH)CH2OH
110.54
1, 473
1.321820
4
CH3CH(Cl)COOH
108.52
2, 248
1.182
ClCH2CH2COOH
108.52
2, 249
CH3CH(OH)CH2Cl
ClCH2CH2CH2OH
ClCH2COCH3
94.54
94.54
92.53
1, 363
1, 356
1, 653
1.11520
1.130920
4
1.13515
ClCH2CH2CN
89.53
2, 250
1.144318
c241
3-Chloropropanonitrile
3⬘-Chloropropanophenone
2-Chloropropanyl
chloride
3-Chloropropanyl
chloride
3-Chloro-1-propene
3-Chloropropylacetate
3-Chloropropyl
thiolactate
(3-Chloropropyl)triethoxysilane
(3-Chloropropyl)trimethoxysilane
3-Chloropropyne
c242
2-Chloropyridine
Cl(C5H4N)
c227
c228
c229
1.150
c230
c231
c232
c233
c234
c235
c236
c239
c240
Solubility in 100
parts solvent
15010mm
46–47
35–36
⫺31
⫺35
1.480520
213
⬎110
0.27 aq; misc alc, eth
0.2 aq20; misc alc, bz,
chl, eth
s aq, alc, eth
1.434520
170–190
101
misc aq, alc, eth
41
200765mm
⬎110
v s aq, alc, chl; s eth
1.437520
4
1.445020
1.432020
51
73
27
misc aq; s alc
⫺44.5
126–127
160–162
119.7
1.434120
⫺51
9550mm
d ⬎ 130
12414mm
75
⬎110
58
⫺122.8
⫺117
10 aq; misc alc, chl,
eth
ClC6H4C("O)CH2CH3
168.62
73, 1028
CH3CH(Cl)COCl
126.97
2, 248
1.308
1.440020
109–111
31
dec aq, alc
ClCH2CH2COCl
126.97
2, 250
1.330713
1.457020
143–145
61
ClCH2CH"CH2
CH3CO2(CH3)3Cl
CH3C("O)SCH2CH2Cl
76.53
130.02
152.64
1, 198
4, 148
23, 493
0.93820
4
1.415420
45
⫺32
i aq; d hot aq, hot alc;
s alc; v s eth
0.36 aq; misc alc, PE
1.159
1.494620
45–47
20
4
⫺134.5
148–150
8410mm
20
77
10mm
Cl(CH2)3Si(OC2H5)3
240.81
1.009
1.420
102
Cl(CH2)3Si(OCH3)3
198.72
1.07725
4
1.418325
195750mm
78
57
⫺13
166714mm
65
ClCH2C#CH
74.51
1, 248
1.030625
4
1.456020
113.55
20, 230
1.20515
1.532020
ROTATED
c236a
c237
c238
Flash
point,⬚C
⫺78
misc alc, bz, eth,
EtOAc
sl s aq; s alc, eth
INTERACTIVE
168.58
78.54
78.54
3-Chlorophthalide
1-Chloropropane
2-Chloropropane
Boiling
point,⬚C
LEFT
CH3CH2CH2Cl
CH3CHClCH3
c224
c225
c226
Melting
point,⬚C
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
3-Chloropyridine
4-Chlororesorcinol
4-Chlorosalicylic acid
5-Chlorosalicylic acid
N-Chlorosuccinimide
Cl(C5H4N)
ClC6H3-1,3(OH)2
ClC6H3(2-OH)COOH
ClC6H3(2-OH)COOH
c248
Chlorosulfonic acid
c249
c250
c251
c252
c253
c254
c255
1.151
c256
c257
c258
c259
1.530020
113.55
144.56
172.57
172.57
133.53
20, 230
62, 818
10, 101
10, 102
21, 380
1.194
ClHO3S
116.52
Merck:
12, 2218
1.75320
4
1.43714
⫺80
152755mm
none
Chlorosulfonyl
isocyanate
1-Chlorotetradecane
2-Chlorothiophene
4-Chlorothiophenol
8-Chlorothiophylline
Chlorotitanium triisopropoxide
2-Chlorotoluene
ClSO2NCO
141.53
1.626
1.447020
⫺44
107
none
CH3(CH2)13Cl
Cl(C5H3S)
ClC6H4SH
12, 135
17, 32
6, 326
26, 473
0.859
1.286
1.446020
1.548320
1424mm
127–129
205–207
⬎110
22
⬎110
[(CH3)2CHO]3TiCl
232.84
118.59
144.62
214.61
260.62
ClC6H4CH3
126.59
5, 290
1.082620
4
1.526820
⫺35.6
159.0
47
3-Chlorotoluene
4-Chlorotoluene
N-Chloro-p-toluene
sulfonamide, sodium salt
4-(4-Chloro-o-tolyloxy)butyric acid
ClC6H4CH3
ClC6H4CH3
CH3C6H4SO2NCl⫺ Na⫹
126.59
126.59
227.67
5, 291
5, 292
1.076019
4
1.069720
4
1.521820
1.515020
⫺47.8
7.5
167 dec
161.8
162.4
50
49
ClC6H3(CH3)O(CH2)3COOH
228.68
1.65
⫺72
49–52
dec 290
148
14718mm
65
1.4 aq; 0.67 alc; 2 bz;
sl s chl, CCl4, eth
s pyr, dichloroethane;
aq dec with violence
i aq; misc alc, eth
s alkali
1.091
22
sl s aq; v s alc, bz, chl,
eth
s alc, bz, chl; misc eth
sl s aq; s alc, bz, eth
s aq; i bz, chl, eth
99–100
␣-Chlorotoluene, b90
Chlorotoluidines, c163 thru c167
3-Chloropropylene-1,2-oxide, c120
1-Chloro-2,5-pyrrolidinedione, c247
RIGHT
Chloroprene, c236a
␤-Chloropropionaldehyde diethyl acetal, c97
106–108
210–212
172
150–151
DEAN 37261 (McGHP)
c243
c244
c245
c246
c247
ROTATED
c224
c247
c253
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
c260
c261
c262
c269
c270
c271
c272
c273
c274
Chlorotriethylgermane
Chlorotriethylsilane
Chloro-2,2,2-trifluoroethane
Chlorotrifluoroethylene
Chlorotrifluoromethane
Chlorotrimethylgermane
Chlorotrimethylsilane
Chlorotriphenylmethane
Chlorotriphenyltin
Chloro-tris(dimethylamino)silane
␣-Chloro-o-xylene
␣-Chloro-m-xylene
␣-Chloro-p-xylene
2-Chloro-p-xylene
4-Chloro-p-xylene
Cholesterol
c275
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
1.459020
1.430020
1.30900
195.23
150.73
118.5
43, 1912
4, 624
1,3, 138
1.175
0.898
1.3890
CF2 "CFCl
116.47
13, 646
ClCF3
104.46
13, 42
(CH3)3GeCl
153.16
(CH3)3SiCl
(C6H5)3CCl
108.64
278.78
4,3, 1857
5, 700
(C6H5)3SnCl
[(CH3)2N]3SiCl
385.46
195.8
12, 914
CH3C6H4CH2Cl
CH3C6H4CH2Cl
CH3C6H4CH2Cl
ClC6H3(CH3)2
ClC6H3(CH3)2
140.61
140.61
140.61
140.61
140.61
386.66
5, 364
5, 373
5, 384
5, 384
5, 363
6,3, 2607
Cholic acid
408.58
103, 2162
c276
c277
c278
Cinchonine
1,8-Cineole
trans-Cinnamaldehyde
C6H5CH"CHCHO
194.40
154.25
132.16
232, 369
17, 23
7, 348
0.92125
25
1.05025
25
c279
trans-Cinnamic acid
C6H5CH"CHCOOH
148.16
9, 573
1.247544
c263
c264
c265
1.152
c266
c267
c268
c268a
Boiling
point,⬚C
⫺105
142–144
6.9
1.315
⫺158.2
⫺28
4.270 g/L
⫺181
⫺81
Flash
point,⬚C
⬎110
29
1.238222
1.428320
⫺13
102
1
0.858020
4
1.387020
⫺40
110–112
57
23520mm
⫺27
108 dec
24014mm
6312mm
0.97520
4
1.44220
1.063
1.06420
1.539120
1.535020
1.533020
1.524020
1.528020
1.049
1.047
1.05219
19
v s bz, chl, eth
9625mm
195–196
200
186
221–223
2030.5mm
73
75
75
57
66
ca. 260
1
⫺7.5
176.4
13620mm
48
71
133
300
4.5
2
148.5
198
1,457220
1.621920
Solubility in 100
parts solvent
i aq; misc alc, eth
i aq; misc alc, eth
misc alc, bz, eth, acet
misc alc, bz, eth, acet
1.3 alc; 35 eth; 22 chl;
s bz, PE
(15⬚): 0.03 aq; 3.1 alc;
2.8 acet; 15.2
HOAc; 0.5 chl;
0.036 bz
1.6 alc; 0.9 chl; 0.2 eth
misc alc, chl, eth
0.014 aq; misc alc, chl,
eth
0.05 aq; 16 alc; 8 chl
INTERACTIVE
(C2H5)3GeCl
(C2H5)3SiCl
CF3CH2Cl
Melting
point,⬚C
ROTATED
Name
LEFT
No.
166.61
92, 390
1.161725
4
1.61443
35–36
258
⬎110
CH3CO2CH2CH"CHC6H5
C6H5CH"CHCH2OH
176.22
134.18
62, 527
6, 570
1.0571
1.039735
35
1.542120
1.575833
33
265
250.0
⬎110
⬎110
c283
c284
Cinnamyl chloride
Citraconic acid
C6H5CH"CHCH2Cl
CH3C(COOH)"CHCOOH
159.62
130.10
5, 482
2, 768
1.096
1.62
1.584020
⫺19
92 dec
10812mm
79
c285
c286
Citraconic anhydride
Citral (geranial plus
neral, cis and trans
forms, resp.)
112.08
152.24
17, 440
1.247
0.888
1.471220
1.487620
8
(CH3)2C"CHCH2CH2C(CH3)"CHCHO
214
229
␣⬘-Chloro-␣,␣,␣-trifluoro-m-xylene, t304
Chlorotrihexylsilane, t307
Chloroxylenol, c109
Chromone, b55
2-Chlorotriethylamine, d328
2-Chloro-2-(trifluoromethyl)aniline, a141
Chloro-␣,␣,␣-trifluorotoluenes, c60, c61, c62
4-Chloro-␣,␣,␣-trifluoro-o-toluidine, a142
s hot alc, CCl4
s aq; v s common organic solvents
v s aq, alc, eth; sl s
chl; i bz, PE
101
101
DEAN 37261 (McGHP)
C6H5CH"CHCOCl
c281
c282
trans-Cinnamoyl chloride
Cinnamyl acetate
Cinnamyl alcohol
c280
Chrysene, b52
Cinchophen, p153
Citral, d644, d645
1.153
c276
c275
RIGHT
c274
ROTATED
c277
c285
INTERACTIVE
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
0.890
1.454020
Melting
point,⬚C
Boiling
point,⬚C
1.154
198.31
14, 3570
155.11
22, 254
192.12
3, 556
1.665
156.27
11, 232
0.857020
4
Cocaine
303.35
222, 150
c300
Coumarin
146.15
17, 328
c301
Creatine
131.14
4, 363
c302
c303
Creatinine
o-Cresol
CH3C6H4OH
113.12
108.14
24, 245
6, 349
1.027341
1.536141
255 dec
30
191
81
c304
m-Cresol
CH3C6H4OH
108.14
6, 373
1.03420
4
1.543820
12
202.2
86
c305
p-Cresol
CH3C6H4OH
108.14
6, 389
1.017941
1.531241
34.8
201.9
86
c306
c307
trans-Crotonaldehyde
Crotonic acid
CH3CH"CHCHO
CH3CH"CHCOOH
70.09
86.19
1, 728
2, 408
0.851620
0.96484
1.437320
1.422880
⫺76
71.6
102–104
185
13
87
c308
c309
c310
c311
c312
c313
Crotonic anhydride
Crotononitrile
Crotonyl chloride
Crotyl alcohol
Crotyl chloride
12-Crown-4
(CH3CH"CHO)2O
CH3CH"CHCN
CH3CH"CHCOCl
CH3CH"CHCH2OH
CH3CH"CHCH2Cl
154.17
67.09
104.54
72.11
90.55
176.21
2, 411
2, 412
2, 411
1, 442
12, 176
1.040
1.419020
1.091
0.845
0.929
1.089
1.474020
1.419020
1.460020
1.427020
1.436020
1.463020
248
121
120–123
122
85
700.5mm
110
20
35
37
⫺5
⬎110
c287
Citral dimethyl acetal
c288
Citrazinic acid
c289
Citric acid
c290
␤-Citronellol
c299
(CH3)2C"CHCH2CH2C(CH3)"CH(OCH3)2
HOOCCH2C(OH)(COOH)CH2COOH
(CH3)2C"CHCH2CH2CH(CH3)CH2CH2OH
HOOCCH2N(CH3)C("NH)NH2
10610mm
Flash
point,⬚C
92
carbonizes
without
melting
⬎300
154
1.456020
1.502298
0.93520
4
Solubility in 100
parts solvent
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
i aq; s alkali
59 aq
222
98
1870.1mm
68–70
298
98
v sl s aq; misc alc, eth
0.17 aq; 15 alc; 140
chl; 28 eth; s acet;
EtOAc, CS2
0.25 aq; v s alc, chl,
eth; s alkali
1.3 aq; 0.11 alc; i eth
dec 303
LEFT
ROTATED
8 aq; sl s alc; i eth
3.1 aq40; misc alc, chl,
eth; s alkali
2.5 aq40; misc alc, chl,
eth; s alkali
2.3 aq40; misc alc, chl,
eth; s alkali
18.1 aq20
54.6 aq20; 52.5
EtOH25; 53 acet;
37.5 toluene
17 aq; misc alc
INTERACTIVE
specific for Li⫹
18-Crown-6
Crystal Violet
Cumene hydroperoxide
C6H5C(CH3)2OH
264.32
407.99
152.20
13, 756
63, 1814
1.030
1.521020
1018mm
Crotononitrile, b482
trans-Crotonyl alcohol, c311
Crotyl alcohols, b486, b487
Crotyl bromide, b276
Crotyl chloride, c79
Cleland’s reagent, d484
2,4,6-Collidine, t393
p-Coumaric acid, h109
Cresylic acids, c303, c304, c305
trans-Crotonic acid, b484
⬎110
42–45
215 dec
12-Crown-4, t124
15-Crown-5, p46
Cumene, i103
Cumic alcohol, i104
56
DEAN 37261 (McGHP)
c314
c315
c316
1.155
c288
c299
c300
c302
RIGHT
ROTATED
c313
c314
c315
INTERACTIVE
No.
Name
Formula
Formula
weight
Density,
g/mL
Refractive
index
1.156
c316a
c317
c318
Cumylphenol
Cupferron
Cyanamide
C6H5C(CH3)2C6H4OH
C6H5N(NO)O⫺ NH+4
H2NCN
c319
c320
c321
2-Cyanoacetamide
Cyanoacetic acid
Cyanoacetohydrazide
NCCH2CONH2
NCCH2COOH
NCCH2C("O)NHNH2
c322
Cyanoacetylurea
127.10
c323
c324
c325
c326
2-Cyanoethanol
2-Cyanoethyl acrylate
Cyanogen bromide
1-Cyano-3-methylisothiourea, sodium
salt
1-Cyanonaphthalene
2-Cyanopyridine
3-Cyanopyridine
4-Cyanopyridine
Cyanotrimethylsilane
Cyanuric acid
NCCH2C("O)NHC("O)NH2
NCCH2CH2OH
H2C"CHCO2CH2CH2CN
BrCN
CH2NH("NCN)S⫺ Na⫹
2, 589
2, 583
Merck:
11, 2688
3, 66
71.08
125.13
105.93
137.14
32, 213
33, 543
3, 39
4, 71
1.05880
1.052
2.01520
4
1.447020
C10H7CN
NC(C5H4N)
NC(C5H4N)
NC(C5H4N)
(CH3)3SiCN
153.18
104.11
104.11
104.11
99.21
129.08
9, 649
22, 36
22, 41
22, 46
44, 3893
26, 239
1.111325
25
1.081
1.629818
1.528820
0.78320
4
1.7680
1.392420
C4H8
(C4H7)COOH
56.10
100.12
5, 17
9, 5
0.70380
1.047
1.37520
1.443320
C10H20
C12H23OH
C12H22("O)
140.27
184.32
182.31
162.28
0.871
1.470720
c335
c336
c337
c338
(C12H23)NH2
166.31
183.34
72, 48
54, 1115
74–76
163–164
46
83380mm
119.5
66
115
10815mm
dec
Flash
point,⬚C
Solubility in 100
parts solvent
335
⬎110
215
107
v s aq, alc
78 aq; 29 BuOH; 42
EtOAc; s alc, eth
25 aq; 3.1 alc
s aq, alc, eth; sl s bz
v s aq; s alc; i eth
214 dec
52
290 dec
0.90662
0.892520
4
1.507020
0.863
1.482220
38
26–28
50–52
78–80
11–12
⬎360; dec
to
HOCN
⫺91
⫺20 to
⫺7.5
10811mm
10812mm
61–62
103
5
299
215
201
89
84
118–119
1
misc aq, alc; sl s eth
v s aq, alc, eth
i aq; v s alc, eth
s aq; v s alc, bz, eth
v s aq, alc, bz, eth
s aq, alc, bz, eth
0.5 aq; s hot alc, pyr; i
acet, bz, chl, eth
13
195
83
i aq; v s alc, acet
201
65
77
59–61
⫺18
851mm
231
87
28–30
232–245
1247mm
93
121
INTERACTIVE
c339
c340
Cyclobutane
Cyclobutanecarboxylic
acid
Cyclodecane
Cyclododecanol
Cyclododecanone
trans,trans,cis-1,5,9cyclododecatriene
Cyclododecene
Cyclododecylamine
1.28220
4
Boiling
point,⬚C
ROTATED
c333
c334
84.08
85.06
99.09
161, 395
32, 63
Melting
point,⬚C
LEFT
c327
c328
c329
c330
c331
c332
212.29
155.16
42.04
Beilstein
reference
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
c345
c346
c347
c348
c349
c350
c351
c352
98.18
114.19
112.17
92.13
5, 29
6, 10
7, 13
5, 280
0.81120
4
0.94820
4
0.949020
4
0.888
1.445520
1.476020
1.461120
1.521120
C7H12
96.17
236.40
5, 65
73, 521
0.824
1.458520
1.489020
C6H12
84.16
5, 20
0.778620
4
1.426220
C6D12
C10H10(NHCH3)2
92.26
142.25
53, 36
0.893
0.945
C6H11CN
109.17
9, 9
C6H11COCl
146.62
C6H11CHO
112.17
1.157
Cycloheptane
Cycloheptanol
Cycloheptanone
1,3,5-Cycloheptatriene
Cycloheptene
8-Cyclohexadecene-1one
Cyclohexane
C7H14
C7H13OH
C7H12("O)
Cyclohexane-d12
1,3-Cyclohexanebis(methylamine)
1,3-Cyclohexanecarbonitrile
Cyclohexanecarbonyl
chloride
Cyclohexanecarboxaldehyde
118
185
179–181
115.5
6
71
55
26
v s alc, eth
sl s aq; v s alc, eth
i aq; v s alc; s eth
s alc, eth; v s bz, chl
114.7
19519mm
⫺6
⬎110
s alc, eth
80.7
⫺20
0.01 aq; misc acet, alc,
bz, CCl4, eth
1.421020
1.493020
78
⫺18
106
0.919
1.450520
7616mm
65
9, 9
1.096
1.470020
184
66
7, 19
0.926
1.450020
163
40
1-Cyanopropane, b468a
2-Cyano-1-propene, m30a
2-Cyanotoluene, t184
4-Cyanotoluene, t185
Cyanuric chloride, t255
1,5-Cyclododecadiene-9,10-epoxide, e4
⫺75.3
6.6
Cyclododecane epoxide, e5
Cycloheptanone isooxime, a307
Cycloheptyl bromide, b310
2,5-Cyclohexadien-1,4-dione, b58
2,5-Cyclohexadiene-1,4-dione with 1,4-benzenediol (1:1), q1
Cyclohexaneacetic acid, c373
RIGHT
Cupron, b50
Cyanoacetonitrile, m5
Cyanoanilines, a121, a122, a123
Cyanobenzene, b51
2-Cyanoethanol, h173
Cyanoethylene, a63
Cyanomethane, a29
⫺8.0
2
DEAN 37261 (McGHP)
c341
c342
c343
c344
ROTATED
c332
c338
c339
c344
c346
INTERACTIVE
c353
Cyclohexanecarboxylic
acid
trans-1,2-Cyclohexanediamine
1,3-Cyclohexanedicarboxylic acid
cis-1,2-Cyclohexanedicarboxyic anhydride
1,4-Cyclohexanedimethanol
1,4-Cyclohexanedivinyl ether
1,4-Cyclohexanediol
1,3-Cyclohexanedione
1,2-Cyclohexanedione
dioxime
Cyclohexanemethylamine
Cyclohexanepropionic
acid
Cyclohexanethiol
Cyclohexanol
Cyclohexanone
Cyclohexanone oxime
Cyclohexene
c354
c355
c356
c357
c358
1.158
c359
c360
c361
c362
c363
c364
c365
c366
c367
c368
c369
c370
c371
c372
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
C6H11COOH
128.17
9, 7
1.048015
4
1.453020
29
232.5
⬎110
C6H10(NH2)2
114.19
133, 8
0.951
1.488420
14–15
9218mm
68
C6H10(COOH)2
172.18
9, 732
132–141
154.17
17, 452
32–34
15817mm
⬎110
43
283
161
12614mm
⬎110
15020mm
65
C6H10(CH2OH)2
144.21
0.978100
4
1.489320
C6H10(OCH"CH2)2
196.29
0.919
1.472020
C6H10(OH)2
C6H8("O)2
C6H8("NOH)2
116.16
112.13
142.16
6, 741
7, 554
72, 526
1.086191
1.4576102
C6H11CH2NH2
113.20
12, 12
0.870
1.463020
C6H11CH2CH2COOH
156.23
9, 82
0.912
1.463620
C6H11SH
C6H11OH
C6H10("O)
C6H10("NOH)
C6H10
116.23
100.16
98.15
113.16
82.15
6, 8
6, 5
7, 8
7, 10
5, 63
0.950
0.941630
0.947820
4
1.492120
1.462930
1.451020
0.809420
4
1.446420
3
98–100
103–105
185–188
C6H9CH2OH
112.17
6 , 215
0.961
1.4853
C6H8("O)
98.15
96.13
159.23
17, 21
72, 55
203, 3239
0.970
0.993
1.021
1.452020
1.488520
1.548020
43
14–17
275.8
⬎110
25.4
⫺31
89–91
⫺103.5
158–160
161
155.7
206–210
83.0
43
68
44
CH3CO2C6H11
142.20
6, 7
0.966
1.439520
18mm
⫺53
0.21 aq; s alc, bz, eth
misc aq, alc; 2.5 eth
s aq, alc, acet, chl
s aq
145–147
20
Solubility in 100
parts solvent
⫺12
3.8 aq25; misc alc, bz
15 aq10; s alc, eth
s aq, eth; sl s alc
0.02 aq; misc alc, bz,
acet, eth
85
76
130
168
14120mm
27
56
⬎110
v s alc
173
57
sl s aq; s org solv
INTERACTIVE
c373
3-Cyclohexene-1methanol
Cyclohexene oxide
2-Cyclohexene-1-one
4-(3-Cyclohexene-1yl)pyridine
Cyclohexyl acetate
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
c378
c379
c380
c381
c382
c383
c384
c385
1.159
c386
Cyclohexylacetic acid
Cyclohexylamine
Cyclohexylbenzene
Cyclohexyldimethoxymethylsilane
2-Cyclohexylethanol
Cyclohexylethyl
acetate
N-Cyclohexylformamide
Cyclohexyl isocyanate
Cyclohexyl isothiocyanate
Cyclohexyl methacrylate
Cyclohexylmethanol
3-Cyclohexyl-1propanol
N-Cyclohexyl-2pyrrolidinone
242–244
134
240
201.2
⬎110
31
98
73
207745mm
9815mm
86
81
11310mm
⬎110
1.455120
1.535020
168–170
219
48
95
0.964
1.458020
704mm
82
6, 14
61, 15
0.921525
4
1.007
1.464025
1.497520
181
218
71
101
213, 3149
1.026
1.495
284
⬎110
C6H11CH2COOH
C6H11NH2
C6H11C6H5
C6H11Si(OCH3)2CH3
142.20
99.18
160.26
188.35
92, 9
12, 5
5, 503
1.007
0.867120
0.950220
4
0.940
1.463020
1.459320
1.525820
1.439020
C6H11CH2CH2OH
CH3CO2CH2CH2C6H11
128.22
170.25
6, 17
0.919
0.949
1.464720
1.4461
C6H11NHCHO
127.18
122, 11
C6H11NCO
C6H11NCS
125.17
141.24
122, 12
122, 12
0.980
0.996
H2C"C(CH3)CO2C6H11
168.24
63, 25
C6H11CH2OH
C6H11CH2CH2CH2OH
114.19
142.24
167.25
38–40
12
cis-4-Cyclohexene-1,2-dicarboxylic anhydride, t81
N-(1-Cyclohexen-1-yl)morpholine, m465
N-(1-Cyclohexen-1-yl)pyrrolidine, p284
Cyclohexyl alcohol, c365
Cyclohexyl bromide, b311
misc aq, alc, chl, eth
i aq; v s alc, eth
s alc, eth
Cyclohexyl chloride, c91
Cyclohexyl ketone, c366
Cyclohexyl mercaptan, c364
Cyclohexylmethane, m202
Cyclohexylmethyl bromide, b367
RIGHT
Cyclohexanecarboxylic acid chloride, c351
Cyclohexaneethanol, c378
Cyclohexaneethyl acetate, c379
Cyclohexanemethanol, c384
Cyclohexanone cyanohydrin, h112
cis-4-Cyclohexene-1,2-dicarboximide, t82
31–33
⫺18
7
DEAN 37261 (McGHP)
c374
c375
c376
c377
ROTATED
c356
c370
c386
INTERACTIVE
c372
No.
c387
c388
c389
c390
c391
c392
c393
c394
c395
1.160
c396
c397
c403
c406
c407
C8H15OH
C8H14("O)
C8H14
C8H15NH2
Beilstein
reference
Density,
g/mL
Refractive
index
Boiling
point,⬚C
Flash
point,⬚C
5534mm
24
1.490525
1.457420
1.498020
⫺53 to
⫺51
⫺69
14.8
32
149–150
151.1
940.5mm
31
30
⬎110
0.974020
4
0.958420
4
0.846
0.928
0.802120
4
1.485020
1.649420
1.469820
1.480420
1.446316
14–15
41–43
⫺16
⫺48
⫺85
10822mm
195–197
145–146
190
41–42
86
72
25
62
108.18
54, 401
0.869
1.492820
108.18
112.22
144.21
5, 116
5, 35
63, 4094
0.881825
4
0.834
1.080
128.22
126.20
110.20
127.23
66.10
62, 25
7, 21
51, 35
Merck:
12, 2807
Melting
point,⬚C
Cyclopentane
Cyclopentanecarboxylic acid
Cyclopentanol
Cyclopentanone
Cyclopentanone oxime
Cyclopentene
2-Cyclopentene-1acetic acid
N-(1-Cyclopenten-1yl)morpholine
Cyclopentylamine
3-Cyclopentylpropanoic acid
Cyclopropane
C5H10
C5H9COOH
70.13
114.14
5, 19
9, 6
0.746020
4
1.05320
4
1.406820
1.454020
⫺94
4
49.3
216
⫺37
93
C5H9OH
C5H8("O)
C5H8("NOH)
C5H8
C5H7CH2COOH
86.13
84.12
99.13
68.11
126.16
6, 5
7, 5
7, 7
5, 61
9, 42
0.948820
4
0.950918
4
1.452120
1.436620
0.772020
1.047
1.422820
1.467520
⫺19
⫺51
53–55
⫺135.1
19
140
130.6
196
44.2
942.5mm
51
26
92
⫺29
⬎110
0.957
1.510520
10612mm
60
1.448220
1.457020
106–108
13012mm
17
46
Cyclopropanecarbonitrile
Cyclopropanecarbonyl
chloride
153.23
C5H9NH2
C5H9CH2CH2COOH
85.15
142.20
12, 4
0.863
0.996
C3H6
42.08
5, 15
0.7204⫺79
C3H5CN
67.09
9, 4
0.91116
1.420720
135
32
104.54
9, 4
1.152
1.452220
119
23
C3H5COCl
⫺127
⫺32.8
Solubility in 100
parts solvent
s CCl4
misc alc, bz, CCl4, eth;
s aniline, HOAc,
CS2
i aq; misc alc, eth
sl s aq; s MeOH
sl s aq; s alc
sl s aq; misc alc, eth
s aq, alc, bz, chl, eth
37 mL/100 mL aq15; v
s alc, eth
s eth
INTERACTIVE
c408
C8H16
C8H14(OH)2
Formula
weight
ROTATED
c404
c405
cis,cis-1,3-Cyclooctadiene
1,5-Cyclooctadiene
Cyclooctane
trans-1,2-Cyclooctanediol
Cyclooctanol
Cyclooctanone
cis-Cyclooctene
Cyclooctylamine
Cyclopentadiene
Formula
LEFT
c398
c399
c400
c401
c402
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
c410
c411
c412
d1
d2
Cyclopropanecarboxylic acid
Cyclopropyl methyl
ketone
L-Cysteine
L-Cystine
d7
d8
d9
d10
1,9-Decalene
cis-Decahydronaphthalene
trans-Decahydronaphthalene
Decahydro-2-naphthol
Decamethylcyclopentasiloxane
Decamethyltetrasiloxane
Decanal
Decane
1,10-Decanediamine
Decanedioic acid
d11
d12
1,2-Decanediol
1,10-Decanediol
d3
d4
d5
d6
C3H5COOH
86.09
9, 4
1.088
1.438020
C3H5COCH3
84.12
7, 7
0.899320
4
1.424020
17–19
182–184
71
sl s hot aq; s alc, eth
114
21
s aq, alc, eth
1.161
HSCH2CH(NH2)COOH
HOOCCH(NH2)SSCH2CH(NH2)COOH
H2C"CH(CH2)6CH"CH2
C10H18
121.16
240.30
4, 506
4, 507
220 dec
dec 240
138.25
138.25
11, 123
5, 92
0.750
0.896320
4
1.432020
1.481020
⫺43
169
195.8
41
58 (CC)
C10H18
138.25
52, 56
0.870020
4
1.469020
⫺30.4
187.3
54
v s alc, chl, eth; misc
most ketones, esters
see under cis
C10H17OH
[9Si(CH3)2O9]5
154.25
370.78
6, 67
44, 4128
0.996
0.959320
4
1.50020
1.398220
⫺38
10914mm
10120mm
⬎110
72
i aq
(CH3)3SiO[Si(CH3)2O]2Si(CH3)3
H(CH2)9CHO
CH3(CH2)8CH3
H2N(CH2)10NH2
HOOC(CH2)8COOH
310.69
43, 1879
0.853620
4
1.389520
⫺68
194
62
sl s alc; s bz, PE
156.27
142.29
172.32
202.25
1, 711
1, 168
4, 273
2, 718
0.83015
4
0.730120
4
1.428020
1.411020
i aq; s alc, eth
0.07 aq
1.422134
208–209
174.1
14012mm
23210mm
85
46
1.20720
4
⫺5
⫺29.7
62–63
134.5
CH3(CH2)7CH(OH)CH2OH
HO(CH2)10OH
174.28
174.28
1, 494
12, 560
48–50
74
255
1708mm
⬎110
⬎110
0.1 aq20, eth17; v s alc,
esters, ketones
cis-Decalin, d2
trans-Decalin, d3
Decamethylene glycol, d12
Decanealdehyde, d7
1,10-Decanedicarboxylic acid, d805
sl s aq, eth; v s alc
RIGHT
Cymenes, i118 thru i120
Cysteamine, a161
Cytosine, a194
p,p⬘-DDT, b173
1,2-Decahydroacenaphthylene, a2
Cyclopentanepropanoic acid, c405
Cyclopentene oxide, e42
Cyclopentyl bromide, b313
Cyclopentyl chloride, c93
Cyclopropyl bromide, b314
Cyclopropyl cyanide, c407
v s aq, alc; i bz, eth
0.01 aq; s acid, alkali;
i alc
DEAN 37261 (McGHP)
c409
ROTATED
c387
c388
c395
c403
INTERACTIVE
1.162
1.121220
4
0.829515
4
0.841
0.875250
4
1,467820
1.429520
1.456520
1.428840
158.29
170.25
156.27
156.27
156.27
190.71
140.27
157.30
1, 425
175,9, 91
1, 711
11, 367
1, 711
2, 356
13, 858
4, 199
0.829720
4
0.954
0.825
0.825
0.82420
0
0.919
0.740820
0.787
1.435920
1.458020
1.425020
1.424120
1.423720
1.441020
1.421020
1.436020
285.48
168.15
124, 3005
17, 559
C6H5CH2COC6H5
(CH3)2Si(OOCCH3)2
196.25
176.3
72, 368
(CH3CO2)2CHCH"CHCH3
172.18
(CH3CO2)2CHCH"CH2
(H2C"CHCH2)2NH
(H2C"CHCH2)2O
H2C"CHCH2O2CCH"CHCO2CH2CH"CH2
C6H4(CO2CH2CH"CH2)2
(H2C"CHCH2)2S
[-CH(OH)CONHCH2CH"CH2]2
Decanedioyl dichloride
Decanenitrile
1-Decanethiol
Decanoic acid
ClC("O)(CH2)8COCl
CH3(CH2)8CN
CH3(CH2)9SH
CH3(CH2)8COOH
239.14
153.27
174.35
172.27
d16
d17
d18
d19
d20
d21
d22
d23
1-Decanol
␦-Decanolactone
2-Decanone
3-Decanone
4-Decanone
Decanoyl chloride
1-Decene
Decylamine
CH3(CH2)9OH
d24
d25
Dehydroabeitylamine
Dehydroacetic acid
d26
d27
Deoxybenzoin
Diacetoxydimethylsilane
trans-1,1-Diacetoxy2-butene
1,1-Diacetoxy-2propene
Diallylamine
Diallyl ether
Diallyl maleate
d28
d29
d30
d31
d32
d33
d34
d35
Diallyl 1,2-phthalate
Diallyl sulfide
(⫹)-N,N-Diallyltartardiamide
CH3(CH2)7COCH3
CH3(CH2)6COC2H5
CH3(CH2)6C("O)(CH2)2CH3
CH3(CH2)8COCl
H(CH2)8CH"CH2
H(CH2)10NH2
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
22075mm
235–237
11413mm
270
⬎110
⫺34.5
⫺66
12–14
232
1200.02mm
211
205
207
965mm
170.6
216–218
82
⬎110
71
25
71
106
47
85
111–113
270
55–56
⫺15
⫺26
32
6.9
3.5
⫺3.8
98
⬎110
Solubility in 100
parts solvent
dec aq, alc
misc alc, chl, eth
0.015 aq; s alc, bz, chl,
CS2
i aq; s alc, eth
i aq; misc alc, eth
dec aq. alc; s eth
i aq; misc alc, eth
sl s aq; misc alc, bz,
eth, acet
⬎110
1.546020
1.20104
1.05420
4
320
164–166
110
1.403020
2, 154
1.057
1.429020
10620mm
87
158.16
2, 154
1.078
1.419020
184
78
97.16
98.15
196.20
4, 208
1, 438
23, 1926
0.787
0.80518
0
1.073
1.440520
1.416020
1.470220
112
94–95
1164mm
15
⫺6 (OC)
⬎110
246.27
114.21
228.25
93, 4120
1, 440
4, 218
1.121
0.887727
4
1.518720
1.488920
1675mm
138
⬎110
46
⫺88
⫺47
⫺85
186–188
at 25⬚: 22 acet; 18 bz;
5 eth; 3 EtOH; 5
MeOH
i aq; v s alc, eth
i aq; misc alc, eth
sl s aq; misc alc, eth
INTERACTIVE
2, 719
2, 356
12, 459
22, 309
d13
d13a
d14
d15
Beilstein
reference
ROTATED
Refractive
index
Name
LEFT
Density,
g/mL
Formula
Formula
weight
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
d37
d38
d39
d40
1,2-Diaminoanthraquinone
1,4-Diaminoanthraquinone
1,5-Diaminoanthraquinone
2,6-Diaminoanthraquinone
3,5-Diaminobenzoic
acid
(H2N)2C6H3COOH
238.25
141, 459
289–291
sl s alc, eth
238.25
14, 197
265–269
sl s aq, alc; v s bz
238.25
14, 203
308 dec
238.25
14, 215
⬎325
152.15
14, 453
228
Delphinic acid, m184
Dextrose, g8
Diacetone alcohol, h150
1,2-Diacetoxyethane, e137
(Diacetoxyiodo)benzene, i24
Decyl alcohol, d16
Decyl bromide, b315
Decyl chloride, c94
Decylic acid, d15
Decyl iodide, i29
Decyl mercaptan, d14
sl s hot aq, pyr
⫺H2O,
110
sl s aq; s alc, eth
DEAN 37261 (McGHP)
d36
Diacetyl, b466
Diacetylmethane, p34
Diallyl, h39
(⫹)-N,N⬘-Diallyltartramide, d35
2,5-Diaminoanisole, m103
1.163
d24
d25
d36
RIGHT
d17
ROTATED
d37
d38
d39
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
d41
d42
d43
d44
d45
1.164
d46
d47
d49
d52
d53
Beilstein
reference
Density,
g/mL
Refractive
index
1.456920
H2N(CH2)4NH2
H2NC6H4NHC6H4NH2 · H2SO4
88.15
297.33
4, 264
13, 110
0.877
C6H10(NH2)2
114.19
133, 8
0.951
C6H10(NH2)2
114.19
C6H10[N(CH2COOH)2]2 · H2O
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
27.3
300
158–160
14–15
8115mm
68
131, 3
69–72
197
71
364.36
133, 10
213–216
H2NC6H4CH2C6H4NH2
198.27
13, 238
91–92
H2NC6H4SO2C6H4NH2
248.30
13, 426
170–173
i aq; s alc, bz
H2NC6H4SO2C6H4NH2
248.30
13, 536
175–176
126.12
24, 469
285 dec
i aq; s alc, acet, dil
HCl
s aq
108.10
170.30
42, 949
13, 4
NCC(NH2)"C(NH2)CN
CH3N[(CH2)3NH2]2
CH3CH(NH2)CH2NH2
H2N(CH2)3NH2
4
1.288620
0.914
1.480520
20
145.25
4 , 1279
0.901
187.21
261, 69
1.4025
4
74.13
74.13
4, 257
4, 261
0.878
0.888
178–179
⫺45
s aq
v s aq
398
12510mm
6mm
1.4725
51
112
221
93
102
227–228
1.446020
1.457020
⫺12
119–120
140
sl s aq; v s alc, bz, eth
33
48
0.06 aq; s alc, eth, dil
HCl; sl s DMF
v s aq
v s aq
INTERACTIVE
d54
d55
Formula
weight
ROTATED
d50
d51
1,4-Diaminobutane
4,4⬘-Diaminodiphenylamine sulfate
trans-1,2-Diaminocyclohexane
trans-1,4-Diaminocyclohexane
trans-1,2-DiaminocyclohexaneN,N,N⬘,N⬘-tetraacetic acid hydrate
4,4⬘-Diaminodiphenylmethane
3,3⬘-Diaminodiphenyl
sulfone
4,4⬘-Diaminodiphenyl
sulfone
2,4-Diamino-6hydroxypyrimidine
Diaminomaleonitrile
1,8-Diamino-p-menthane
3,3⬘-Diamino-Nmethyldipropylamine
2,4-Diamino-6-phenyl1,3,5-triazine
1,2-Diaminopropane
1,3-Diaminopropane
Formula
LEFT
d48
Name
d58
d59
d60
d61
d62
d63
d64
d65
1,3-Diamino-2propanol
2,6-Diaminopyridine
2,4-Diaminotoluene
3,4-Diaminotoluene
1,4-Diazabicyclo[2.2.2]octane
1,8-Diazabicyclo[5.4.0]undec-7-ene
Diazomethane
H2NCH2CH(OH)CH2NH2
90.13
(H2N)2C5H3N
(H2N)2C6H3CH3
(H2N)2C6H3CH3
109.13
122.17
122.17
112.18
40–45
235
221, 647
13, 124
13, 148
233, 484
120–122
97–99
91–93
158–160
283–285
15618mm
174
62
800.6mm
⬎110
152.24
CH2 "N"N
1-Diazo-2-naphthol-4sulfonic acid
1,2,5,6-Dibenzanthracene
1.018
1.521920
42.04
23, 25
⫺145
272.22
16, 595
160 dec
278.33
51, 369
266 subl
1.165
1,2-Diamino-4-nitrobenzene, n66
1,4-Diamino-2-nitrobenzene, n65
1,9-Diaminononane, n91
1,8-Diaminooctane, o24
1,5-Diaminopentane, p30
2,5-Diaminopentanoic acid, o51
1,2-Diaminopropane, p189
1,3-Diaminopropane, p190
1,4-Diaminobutane, b455
1,2-Diaminocyclohexane, c354
1,10-Diaminodecane, d9
2,2⬘-Diaminodiethylamine, d362
1,12-Diaminododecane, d804
1,2-Diaminoethane, e21
1,6-Diaminohexane, h53
1,3-Diamino-2-hydroxypropane, d56
Diaminonaphthalenes, n4, n5
⬎110
4, 290
s aq, alc
45 aq; 77 EtOH; 51
bz; 13 acet; 26
MeEtKe
⫺23
VERY EXPLOSIVE; s
eth, dioxane
524
s bz, PE; sl s alc, eth
DEAN 37261 (McGHP)
d56
4,6-Diamino-4-pyrimidinol, d49
Diaminotoluenes, t167 thru t170
1,3-Diaminourea, c9
Diamylamine, d737
Diamyl ether, d738
Diamyl ketone, u11
Diazirine, d63
1,3-Diazole, i3
RIGHT
ROTATED
d49
d51
d53
d61
d62
d64
d65
INTERACTIVE
No.
Name
d66
d67
d68
Dibenzofuran
Dibenzothiophene
Dibenzoylmethane
d69
d70
1.166
d71
d72
d73
d74
d85
d86
C6H5COCH2COC6H5
168.20
184.26
224.26
17, 70
17, 72
7, 769
Dibenzoyl peroxide
C6H5C("O)OOC("O)C6H5
242.23
(⫺)-Dibenzoyl-Ltartaric acid hydrate
Dibenzylamine
Dibenzyldisulfide
Dibenzyl ether
N,N⬘-Dibenzylethylenediamine
Dibenzyl malonate
Dibromoacetic acid
Dibromoacetonitrile
2,4⬘-Dibromoacetophenone
1,4-Dibromobenzene
4,4⬘-Dibromobiphenyl
1,2-Dibromobutane
1,3-Dibromobutane
1,4-Dibromobutane
meso-2,3-Dibromobutane
2,3-Dibromo-1,4butanediol
1,4-Dibromo-2,3butanediol
trans-2,3-Dibromo-2butene-1,4-diol
[(C6H5COOCH(COOH)-]2 · H2O
Density,
g/mL
Refractive
index
1.088699
4
1.607999
Melting
point,⬚C
Boiling
point,⬚C
81–83
97–100
78–79
285
332–333
22018mm
9, 179
103–106
may
explode
when
heated
376.34
9, 170
90–92
C6H5CH2NHCH2C6H5
C6H5CH2SSCH2C6H5
C6H5CH2OCH2C6H5
(C6H5CH2NHCH2-)2
197.28
246.39
198.27
240.35
12, 1035
6, 465
6, 434
12, 1067
CH2[CO2CH2C6H5]2
Br2CHCOOH
Br2CHCN
BrC6H4C("O)CH2Br
284.31
217.86
198.86
277.96
C6H4Br2
BrC6H4C6H4Br
CH3CH2CH(Br)CH2Br
CH3CH(Br)CH2CH2Br
BrCH2CH2CH2CH2Br
CH3CH(Br)CH(Br)CH3
⫺26
69
2
26
300
d ⬎ 270
298
1954mm
39–41
1880.2mm
13016mm
6924mm
1.026
1.573120
1.001420
4
1.02420
4
1.516820
1.562420
6, 436
2, 218
2, 219
7, 285
1.137
1.544720
235.92
312.00
215.93
215.93
215.93
215.93
5, 211
5, 580
1, 120
1, 120
1, 120
1.121
0.9641100
1.5743100
1.789
1.80020
1.808020
4
1.767
1.514120
1.508520
1.518620
1.510020
HOCH2CH(Br)CH(Br)CH2OH
BrCH2C("O)C("O)CH2Br
247.93
13, 2176
88–90
243.89
1, 774
117–119
HOCH2C(Br)"C(Br)CH2OH
245.91
11, 260
112–114
2.296
1.539320
Flash
point,⬚C
s alc, bz, eth; i aq
s aq; v s alc, bz
4.4 alc; s eth, aq
NaOH
sl s aq, alc; s bz, chl,
eth
143
135 (CC)
⬎110
⫺20
i aq; s alc, eth
s hot alc, bz, eth
misc alc, acet, chl, eth
v s alc, bz, chl, eth
⬎110
⬎110
108–110
87.3
167–170
Solubility in 100
parts solvent
v s warm alc; s eth
220
355–360
6020mm
175
198
7447mm
1501.5mm
1.4 alc; v s eth; s bz
s bz; sl s hot alc
⬎110
110
⬎110
s chl, eth
s chl
INTERACTIVE
d87
Beilstein
reference
ROTATED
d79
d80
d81
d82
d83
d84
Formula
weight
LEFT
d75
d76
d77
d78
Formula
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
d89
d90
d91
d92
d93
d94
d95
d96
d97
d98
1.167
d99
d100
d101
Dibromochloromethane
trans-1,2-Dibromocyclohexane
1,2-Dibromo-2-chloro1,1,2-trifluoroethane
1,10-Dibromodecane
1,2-Dibromo-1,1difluoroethane
Dibromodifluoromethane
1,2-Dibromo-3,3-dimethylbutane
1,3-Dibromo-5,5-dimethylhydantoin
1,1-Dibromoethane
1,2-Dibromoethane
(1,2-Dibromoethyl)benzene
cis-1,2-Dibromoethylene
trans-1,2-Dibromoethylene
1,2-Dibromoethyltrichlorosilane
208.29
1, 67
2,451
1.546520
C6H10Br2
241.96
5, 24
1.784
1.551520
FCCl(Br)C(Br)F2
276.5
Br(CH2)10Br
CH2BrC(Br)F2
300.09
223.87
Br2CF2
(CH3)3CCH(Br)CH2Br
20
⫺22
20
120748mm
none
14610mm
⬎110
93–94
none
misc alc, bz, eth
2.2478
1.4275
11, 64
1, 92
1.33530
2.223820
1.491220
1.445620
27
⫺61.3
16015mm
92.4
⬎110
none
sl s alc; s eth
i aq
209.81
11, 16
2.28815
4
1.401620
⫺110
25
none
0.1 aq; misc alc, bz,
chl, eth
243.98
1, 151
1.610
1.505320
733mm
83
10.0
70–74
113
131.7
14015mm
none
none
i aq; v s alc, eth
0.43 aq; misc alc, eth
s alc, bz, chl, eth
185.93
197 dec
CH3CHBr2
BrCH2CH2Br
C6H5CH(Br)CH2Br
187.86
187.86
263.97
1, 90
1, 90
5, 356
2.05520
4
2.180220
4
1.537920
1.538720
BrCH"CHBr
185.86
1, 190
2.2117
4
1.543118
⫺53
112.5
none
BrCH"CHBr
185.86
1, 190
2.246
1.550518
⫺6.5
108
none
BrCH2CH(Br)SiCl3
321.3
2.04620
4
1.53720
9011mm
Dibenzyl, d752
Dibenzyl ketone, d767
RIGHT
Dibenzo[b,e]pyridine, a60
Dibenzoyl, b35
HCClBr2
DEAN 37261 (McGHP)
d88
ROTATED
d66
d67
d95
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
Name
d102
4⬘5⬘-Dibromofluorescein
1,4-Dibromo-2-fluorobenzene
2,4-Dibromo-1-fluorobenzene
Dibromofluoromethane
1,2-Dibromohexafluoropropane
1,6-Dibromohexane
2,5-Dibromo-3,4hexanedione
5,7-Dibromo-8hydroxyquinoline
2,4-Dibromomesitylene
Dibromomethane
d103
d104
d104a
d105
1.168
d106
d107
d108
d109
d110
d112
d114
d115
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
490.12
19, 228
270–273
Br2C6H3F
253.91
54, 684
33–36
Br2C6H3F
253.91
Br2CHF
191.83
CF3CF(Br)C(Br)F2
309.84
14, 218
2.169
1.360520
Br(CH2)6Br
CH3CHBrC("O)C("O)CH(Br)CH3
243.98
271.95
1, 145
13, 3132
1.58618
4
1.766
1.506620
1.512020
302.96
21, 97
1,3,5-(CH3)3-C6HBr2
CH2Br2
278.00
173.85
5, 408
1, 67
Br2C6H2(CH3)OH
265.94
6, 406
49–50
316.99
213, 1240
126–130
Br2C10H5OH
301.98
6, 652
105–107
Br2C6H2(NO2)NH2
295.93
12, 743
206–208
sl s aq; s HOAc
Br2C6H3NO2
280.91
5, 250
2.374
82–84
s bz, hot alc
Br(CH2)8Br
CH3CH(Br)CH2CH2CH2Br
Br(CH2)5Br
Br2C6H3OH
272.03
229.95
229.95
251.92
1, 160
1, 131
1, 131
6, 202
1.477
1.687
1.687915
4
2.04720
2.495620
4
1.584020
1.541920
1.498120
1.508520
1.509220
s hot alc, HOAc
216
101
10522mm
92
⫺78
65
⫺95
72734mm
none
243
10310mm
⬎110
⬎110
200–201
subl
61–63
⫺52.7
278–279
96–97
15–16
⫺34
⫺34
40–42
misc eth
s alc, bz; v s eth
none
1.15 aq; misc alc, bz,
acet, chl, eth
⬎110
272
9925mm
11015mm
15411mm
⬎110
⬎110
⬎110
⬎110
INTERACTIVE
d116
d117
d118
d119
Beilstein
reference
ROTATED
d113
2,6-Dibromo-4-methylphenol
5,7-Dibromo-2-methyl8-quinolinol
1,6-Dibromo-2naphthol
2,6-Dibromo-4-nitroaniline
2,5-Dibromonitrobenzene
1,8-Dibromooctane
1,4-Dibromopentane
1,5-Dibromopentane
2,4-Dibromophenol
Formula
weight
LEFT
d111
Formula
1,2-Dibromopropane
CH3CH(Br)CH2Br
201.90
1, 109
1.93320
1.520320
⫺55.5
142
none
d121
d122
1,3-Dibromopropane
1,3-Dibromo-2propanol
2,3-Dibromo-1propanol
2,3-Dibromopropene
2,3-Dibromopropionic
acid
2,3-Dibromopropionitrile
2,6-Dibromopyridine
meso-2,3-Dibromosuccinic acid
1,2-Dibromotetrachloroethane
1,2-Dibromotetrafluoroethane
2,5-Dibromothiophene
␣,␣-Dibromotoluene
1,2-Dibromo-1,1,2trifluoroethane
␣,␣-Dibromo-o-xylene
BrCH2CH2CH2Br
BrCH2CH(OH)CH2Br
201.90
217.90
1, 110
1, 365
1.971225
4
2.136
1.523320
1.551420
⫺36
166.8
837mm
54
46
BrCH2CH(Br)CH2OH
217.90
1, 357
2.12020
4
1.559920
9710mm
⬎110
BrCH2C(Br)"CH2
BrCH2CH(Br)COOH
199.88
231.88
1, 201
2, 258
1.933620
4
1.547020
140–143
16020mm
81
BrCH2CH(Br)CN
212.88
2, 259
2.140
BrC5H3N
HOOCCH(Br)CH(Br)COOH
BrCCl2CCl2Br
236.91
275.89
202, 153
2, 625
325.65
1, 93
BrCF2CF2Br
259.83
Br2C4H2S
C6H5CHBr2
HC(Br)FC(Br)F2
241.94
249.94
241.8
C6H4(CH2Br)2
263.97
d123
d124
d125
d126
d127
d128
d129
d130
1.169
d131
d132
d133
d134
64–66
1.545020
sl s aq; misc alc, bz,
acet, eth
s aq, alc, bz
173
118–119
275 subl
2.713
0.2 aq; misc alc, bz,
chl, eth
0.17 aq; s alc, eth
255
v s aq, alc
222 dec
none
2.14925
1.36725
⫺110.5
47
none
17, 33
5, 308
1, 92
2.14723
23
1.51015
2.27427
1.628920
1.614720
1.419124
⫺6
211
15623mm
76.5
99
⬎110
5, 366
1.960
92–94
DEAN 37261 (McGHP)
d120
i aq; v s alc, eth
i aq; misc alc, eth
sl s alc, chl, eth
5,7-Dibromo-8-quinolinol, d108
RIGHT
ROTATED
d102
d108
d112
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Beilstein
reference
Refractive
index
22, 575
4, 157
1.0120
1.110
0.837420
20
0.962
0.767020
1.474020
1.413120
1.436020
1.417720
129.25
173.29
4, 162
43, 682
0.753
0.86020
20
1.410020
1.44420
C6H5N(C4H9)2
205.34
123, 95
0.90420
1.529720
C4H9O2C(CH2)8CO2C4H9
(CH3)3COC("O)OC(CH3)3
214.45
218.25
2, 719
0.936620
0.950
1.441520
1.410320
[(CH3)3C]2C6H2(OH)2
222.33
C4H9SSC4H9
(CH3)3CSSC(CH3)3
C4H9OC4H9
(CH3)2NCH2C6H2[C(CH3)3]2OH
178.36
178.36
130.22
263.43
12, 400
[CH3(CH2)3]2NCH2CH2NH2
172.32
44, 1182
HC("O)N(C4H9)2
[-CH2CH2CO2(CH2)3CH3]2
[(CH3)3C]2C6H2-1,4-(OH)2
157.26
258.36
222.33
22, 575
6, 3, 4741
C4H9O2CCH"CHCO2C4H9
CH2CO2C(CH3)3
228.29
216.27
23, 1925
23, 1621
Name
d135
d136
d137
d138
d139
␣,␣-Dibromo-p-xylene
Dibutoxydibutyltin
1,2-Dibutoxyethane
Dibutyl adipate
Dibutylamine
C6H4(CH2Br)2
[CH3(CH2)3O]2Sn[(CH2)3CH3]2
C4H9OCH2CH2OC4H9
[-CH2CH2CO2(CH2)3CH3]2
(C4H9)2NH
263.97
379.15
174.28
258.36
129.25
5, 386
d140
d141
Di-sec-butylamine
N,N-Dibutylaminoethanol
N,N-Dibutylaniline
[C2H5CH(CH3)]2NH
(C4H9)2NCH2CH2OH
d142
1.170
Density,
g/mL
d143
d144
d145
d151
d152
d153
d154
d155
Flash
point,⬚C
⫺62
261
1380.05mm
203.6
305
159.6
40
85
⬎110
47
⬍ ⫺70
135
229–230
20
91
267–275
⬎110
344–345
560.5mm
178
37
231.2
229–233
140
17230mm
93
93
25
⫺69.1
⫺10
23
Solubility in 100
parts solvent
v s alc, chl; s eth
0.2 aq; misc alc, acet
0.47 aq; s alc, acet, eth
EtOAc, PE
i aq, MeOH; s acet,
bz, EtOH, EtOAc,
eth
0.004 aq
217–219
1, 369
134, 2014
⫺71
0.938320
4
0.935
0.768920
4
1.492020
1.4920
1.399220
0.823
1.443020
11724mm
87
0.864
0.962
1.442920
1.435820
12015mm
305
100
⬎110
281
9310mm
141
88
⫺95
93–94
i aq; misc alc, eth
0.03 aq; misc alc, eth
217–219
0.995020
1.445420
1.418420
⬍ ⫺80
⫺6.0
0.05 aq
INTERACTIVE
CO2C(CH3)3
72–74
Boiling
point,⬚C
ROTATED
d150
Melting
point,⬚C
LEFT
d146
d147
d148
d149
Dibutyl decanedioate
Di-tert-butyl dicarbonate
2,5-Di-tert-butyl-1,4dihydroxybenzene
Dibutyl disulfide
Di-tert-butyl disulfide
Dibutyl ether
2,6-Di-tert-butyl-4(dimethylaminomethyl)phenol
N,N-Dibutylethylenediamine
N,N-Dibutylformamide
Dibutyl hexanedioate
2,5-Di-tert-butylhydroquinone
Dibutyl maleate
Di-tert-butyl malonate
Formula
Formula
weight
No.
[(CH3)3C]2C6H2(CH3)OH
220.36
63, 2073
1.04820
4
1.485975
[-(CH2)3CO2(CH2)3CH3]2
C4H9O2CCO2C4H9
(CH3)3CO9OC(CH3)3
[(CH3)3C]2C6H3OH
[CH3CH2CH(CH3)]2C6H3OH
[(CH3)3C]2C6H3OH
[(CH3)3C]2C6H3OH
(C4H9O)2P(O)H
C6H4 1,2-[CO2C4H9]2
286.41
202.25
146.23
206.33
206.23
206.23
206.23
194.21
278.35
23, 1767
2, 540
13, 1580
0.948
0.98620
20
0.79420
1.439020
1.423220
1.389020
0.918
1.510020
C4H9NH(CH2)3NHC4H9
186.34
d167
N,N-Dibutyl-1,3propanediamine
Dibutyl suberate
286.41
d168
d169
d170
d171
d172
d173
d174
d175
d176
d177
d178
Dibutyl succinate
Dibutyl sulfate
Dibutyl sulfide
Di-tert-butyl sulfide
Dibutyl sulfite
Dibutyl sulfone
Dibutyl L-tartrate
N,N-Dibutyl-2-thiourea
Dibutyltin diacetate
Dibutyltin dichloride
Dibutyltin dilaurate
CH3(CH2)3O2C(CH2)6CO2(CH2)3CH3
[C4H9O2CCH2⫺]2
C4H9OSO2OC4H9
C4H9SC4H9
(CH3)3CSC(CH3)3
(C4H9O)2S("O)
(C4H9)2SO2
[-CH(OH)CO2(CH2)3CH3]2
C4H9NC("S)NHC4H9
(CH3CO2)2Sn(C4H9)2
(C4H9)SnCl2
[CH3(CH2)10CO2]2Sn(C4H9)2
230.30
210.29
146.30
146.30
194.29
178.29
262.31
188.34
351.01
303.83
631.56
d157
d158
d159
d160
d161
d162
d163
d164
d165
d166
1.171
11, 187
92, 586
⫺30.0
⫺40
56.5
⫺42
35–38
87–89
265
127
1764.5mm
239–240
110
263.5
255–260
253
⬎110
108
1
115
127
118
11911mm
340
121
157
0.995
1.046520
4
1.423920
1.491120
0.827
1.446320
205
103
23, 1767
0.948
1.439020
175.54.5mm
⬎110
22, 551
0.976820
4
1.05925
4
0.838620
0.815
0.994422
4
1.429920
1.421320
1.453020
1.450620
1.431020
1.091
1.446520
1.320
1.470020
1.066
1.468320
1, 370
12, 397
1, 371
3, 518
Merck:
12, 3089
⫺29.0
⫺80
46
22
63–65
39–41
22–24
274.5
13211mm
185
151
10815mm
295
1755mm
misc alc, ketones, PE
misc acet, octane
s hot alc; i alk
s hot alc; i alk
0.01 aq; v s alc, bz,
acet, eth
i aq; s alc, eth
76
48
i aq; v s alc, eth
143
⬎110
i aq; s alc, eth
i aq; s alc; sl s eth
14510mm
13510mm
⬎110
⬎110
⬎110
2,5-Di-tert-butylhydroquinone, d145
Dibutyl ketone, n101
Dibutyl sebacate, d143
s PE, bz, acet, eth, org
esters
ROTATED
Dibutyl carbitol, b151
Dibutyl cellosolve, d137
Di-tert-butylcresol, d156
⫺35
s alc, bz, acet, PE
RIGHT
Dibutyl adipate, d152
Dibutyl 1,2-benzenedicarboxylate, d165
Dibutyl butanedioate, d168
N,N-Dibutyl-1-butanamine, t208
63, 2061
70
DEAN 37261 (McGHP)
2,6-Di-tert-butyl-4methylphenol
Dibutyl octanedioate
Dibutyl oxalate
Di-tert-butyl peroxide
2,4-Di-tert-butylphenol
2,6-Di-sec-butylphenol
2,6-Di-tert-butylphenol
3,5-Di-tert-butylphenol
Dibutyl phosphite
Dibutyl 1,2-phthalate
d156
INTERACTIVE
Dibutyltin maleate
Dibutyltin oxide
Dicaprolactone 2(acryloxy)ethyl
ester
Dichloroacetic acid
1,1-Dichloroacetone
1,3-Dichloroacetone
2⬘,4⬘-Dichloroacetophenone
Dichloroacetyl
chloride
2,3-Dichloroaniline
2,4-Dichloroaniline
2,5-Dichloroaniline
2,6-Dichloroaniline
3,4-Dichloroaniline
3,5-Dichloroaniline
1,5-Dichloroanthraquinone
2,3-Dichlorobenzaldehyde
2,4-Dichlorobenzaldehyde
2,4-Dichlorobenzamide
2,6-Dichlorobenzamide
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
2,5-Dichlorobenzenesulfonyl chloride
2,4-Dichlorobenzoic
acid
d182
d183
d184
d185
d186
1.172
d187
d188
d189
d190
d191
d192
d193
d194
d195
d196
d197
d198
d199
d200
d201
d202
Formula
weight
Beilstein
reference
346.98
248.92
344.41
41, 588
Cl2CHCOOH
CH3C("O)CHCl2
ClCH2C("O)CH2Cl
Cl2C6H3C("O)CH3
128.94
126.97
126.97
189.04
Cl2CHC("O)Cl
(C4H9)2SnO
HO(CH2)5CO2(CH2)5CO2CH2CH2O2CCH"CH2
Density,
g/mL
Refractive
index
Melting
point,⬚C
135–140
⬎ 300
1.100
1.466020
2, 202
1, 654
1, 655
7, 282
1.56320
4
1.30518
15
1.383
1.446220
1.445520
147.39
2, 204
1.531516
4
Cl2C6H3NH2
Cl2C6H3NH2
Cl2C6H3NH2
Cl2C6H3NH2
Cl2C6H3NH2
Cl2C6H3NH2
162.02
162.02
162.02
162.02
162.02
162.02
277.11
12, 621
12, 621
12, 625
12, 626
12, 626
12, 626
7, 787
Cl2C6H3CHO
175.01
73, 878
64–67
Cl2C6H3CHO
175.01
7, 236
69–73
Cl2C6H3CONH2
Cl2C6H3CONH2
C6H4Cl2
C6H4Cl2
C6H4Cl2
Cl2C6H3SO2Cl
190.03
190.03
147.00
147.00
147.00
245.51
93, 1376
91, 149
5, 201
5, 202
5, 203
111, 15
Cl2C6H3COOH
191.01
9, 342
Boiling
point,⬚C
1.563520
1.596920
1.3059
1.2884
1.2417
39–41
33–34
1.460320
1.56720
20
4
20
4
6
9–11
20
1.5510
1.546020
1.528520
23–24
59–62
49–51
38–41
70–72
51–53
245–247
191–194
196–199
⫺17.0
⫺24.8
53
36–37
157–160
Flash
point,⬚C
Solubility in 100
parts solvent
⬎110
193–194
120
173
14515mm
⬎110
24
89
⬎110
misc aq, alc, eth
s sl aq; s alc, eth
107–108
none
dec aq, alc; misc eth
252
245
251
⬎110
s alc; v s eth
sl s aq; s alc, eth
s alc, bz, eth
272
259741mm
⬎110
⬎110
⬎110
233
180.4
173.1
174.1
i aq
s alc, eth; sl s bz
i aq; s alc, eth
sl s alc, bz, acet
i aq; s alc
66
72
66
⬎110
misc alc, bz, eth
0.01 aq; s alc, eth
s alc, bz, chl, eth
d hot alc, hot aq
s hot aq, alc, bz, chl
INTERACTIVE
d179
d180
d181
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
d204
d205
d206
d207
d208
d209
d210
d211
1.173
d212
d213
d214
d215
d216
d217
2,5-Dichlorobenzoic
acid
3,4-Dichlorobenzoic
acid
4,4⬘-Dichlorobenzophenone
2,4-Dichlorobenzotrifluoride
3,4-Dichlorobenzotrifluoride
2,4-Dichlorobenzoyl
chloride
3,4-Dichlorobenzoyl
chloride
1,4-Dichlorobutane
cis-1,4-Dichloro-2butene
3,4-Dichloro-1-butene
1,4-Dichloro-2-butyne
Dichloro(2-chloroethyl)methylsilane
Dichloro(3-chloropropyl)methylsilane
1,10-Dichlorodecane
1,1-Dichloro-2,2-diethoxyethane
Cl2C6H3COOH
191.01
9, 342
154–157
Cl2C6H3COOH
191.01
9, 343
207–209
(ClC6H4)2C"O
251.11
7, 420
144–146
Cl2C6H3CF3
215.00
53, 698
1.484
1.481020
Cl2C6H3CF3
215.00
53, 698
1.478
1.475020
Cl2C6H3C("O)Cl
209.46
9, 342
1.494
1.529720
Cl2C6H3C("O)Cl
209.46
9, 344
ClCH2CH2CH2CH2Cl
ClCH2CH"CHCH2Cl
127.01
125.00
1, 119
13, 743
1.159820
4
1.18825
4
ClCH2CH(Cl)CH"CH2
ClCH2C#CCH2Cl
ClCH2CH2SiCl2(CH3)
125.00
122.98
177.53
13, 725
13, 927
43, 1892
Cl(CH2)3Si(CH3)Cl2
191.56
Cl(CH2)10Cl
Cl2CHCH(OC2H5)2
211.18
187.07
sl s aq; s alc, eth
s hot aq, eth; v s alc
353
s hot alc, v s chl, eth
117–118
72
⫺12
173–174
65
16–18
15034mm
137
dec aq, alc
30–33
242
142
dec aq, alc
1.456620
1.488725
⫺38
⫺48
161–163
152
40
55
i aq; s chl
i aq; s org solvents
1.150
1.25820
4
1.261
1.465820
1.504820
1.458020
⫺61
123
165–168
157744mm
28
160
32
44, 4170
1.227
1.462020
8018mm
59
13, 522
1, 614
0.999
1.138
1.460520
1.436020
16828mm
183–184
⬎110
60
2,6-Dichlorobenzyl chloride, t253
15.6
2,2⬘-Dichlorodiethyl ether, b163
RIGHT
Dichloroacetaldehyde diethyl acetal, d217
301
DEAN 37261 (McGHP)
d203
ROTATED
d179
d193
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Beilstein
reference
Density,
g/mL
Refractive
index
Name
d218
Cl2CF2
120.91
1, 61
1.486⫺30
(CH3)3CCH2CHCl2
155.07
13, 409
1.027
197.02
242, 158
(C6H5)2CCl2
237.13
5, 590
1.235
1.604020
d222
d223
Dichlorodifluoromethane
1,1-Dichloro-3,3dimethylbutane
1,3-Dichloro-3,5dimethylhydantoin
Dichlorodiphenylmethane
Dichlorodimethylsilane
Dichlorodiphenylsilane
(CH3)2SiCl2
(C6H5)2SiCl2
129.06
253.20
1.06420
4
1.22220
1.403820
16, 910
d224
d225
d226
1,12-Dichlorododecane
1,1-Dichloroethane
1,2-Dichloroethane
Cl(CH2)12Cl
CH3CHCl2
ClCH2CH2Cl
239.23
98.96
98.96
11, 67
1, 83
1, 84
1.175720
4
1.235120
4
d227
1,1-Dichloroethylene
H2C"CCl2
96.94
1, 186
d228
cis-1,2-Dichloroethylene
trans-1,2-Dichloroethylene
2,2⬘-Dichloroethyl
ether
2,2-Dichloroethyl
methyl ether
Dichloroethylmethylsilane
Dichlorofluoromethane
1,6-Dichlorohexane
Dichloromethane
Dichloromethane-d2
ClCH"CHCl
96.94
ClCH"CHCl
d219
d220
d221
1.174
d230
d232
d233
Flash
point,⬚C
Solubility in 100
parts solvent
⫺158
⫺29.8
⫺56
148
36
305
⬎110
⫺16
308–309
70
157
1.416420
1.444820
28–30
⫺97
⫺35.7
17210mm
57.3
83.5
⫺16
dec aq,
alc
⬎110
⫺17
13
1.212920
4
1.424720
⫺122.6
31.6
⫺28
1, 188
1.283820
4
1.449020
⫺80.1
60
2
0.51 aq; misc alc
0.8 aq; misc alc, chl,
eth
0.01 aq; s alc, bz, chl,
eth
0.7 aq; s alc, eth
96.94
1, 188
1.256520
1.445220
⫺49.8
48.7
2
0.6 aq; s alc, eth
ClCH2CH2OCH2CH2Cl
143.01
12, 335
1.222020
20
1.45720
178.5
55
1.1 aq; s alc, bz, eth
Cl2CHCH2OCH3
128.99
1.226
1.437520
1.063
20
1.4190
1.438820
0.01 aq; 9 bz; 5.5 chl;
6 diox; s alc, eth
134–136
33
(C2H5)Si(CH3)Cl2
143.09
100
FCHCl2
102.92
1, 61
1.4059
1.37249
⫺135
8.9
Cl(CH2)6Cl
CH2Cl2
CD2Cl2
155.07
84.93
86.95
1, 144
1, 60
14, 39
1.068
1.326520
1.3621
1.456820
1.424620
1.421820
⫺95
8715mm
40
40
43
73
none
none
69 HOAc; 108 diox; s
alc, eth; i aq
s chl
1.3 aq; misc alc, eth
INTERACTIVE
d234
d235
d236
Boiling
point,⬚C
ROTATED
d231
Melting
point,⬚C
LEFT
d229
Formula
Formula
weight
No.
d238
d239
d240
d241
d242
d243
d244
d245
d246
1.175
d247
d248
d249
␣,␣-Dichloromethyl
methyl ether
Dichloro(methyl)octylsilane
Dichloro(methyl)phenylsilane
Dichloro(methyl)silane
Dichloro(methyl)vinylsilane
2,4-Dichloro-1naphthol
2,3-Dichloro-1,4naphthoquinone
2,6-Dichloro-4-nitroaniline
2,3-Dichloronitrobenzene
2,4-Dichloronitrobenzene
2,5-Dichloronitrobenzene
3,4-Dichloronitrobenzene
2,4-Dichloro-6nitrophenol
Cl2CHOCH3
114.96
CH3(CH2)7Si(CH3)Cl2
227.25
4, 4, 4182
1.271
1.430020
85
42
0.973
1.444020
946mm
98
1.176
20
1.5190
205
82
1.105
1.08720
4
1.39820
1.430020
41
92
⫺32
4
C6H5Si(CH3)Cl2
191.13
HSi(CH3)Cl2
H2C"CHSi(CH3)Cl2
115.04
141.07
41, 581
Cl2C10H5OH
213.06
6, 612
108
227.05
7, 729
190–192
Cl2C6H2(NO2)NH2
207.02
12, 735
190–192
Cl2C6H3NO2
192.00
5, 245
1.72114
61–62
257–258
123
s PE
Cl2C6H3NO2
192.00
5, 245
1.43980
29–32
258
⬎110
s hot alc; misc eth
Cl2C6H3NO2
192.00
5, 245
54–57
266–269
⬎110
Cl2C6H3NO2
192.00
5, 246
41–44
256
123
Cl2C6H2(NO2)OH
208.00
6, 241
sl s alc, bz, eth
118–120
4,4⬘-Dichloro-␣-methylbenzhydrol, b169
sym-Dichloromethyl ether, t165a
Dichloroisopropyl alcohol, d264
2,4-Dichloro-1-methylbenzene, d274
(Dichloromethyl)benzene, d273
RIGHT
5,5⬘-Dichloro-2,2⬘-dihydroxydiphenylmethane, m243
1,1-Dichlorodimethyl ether, d237
Dichlorohydrin, d264
1.45675
⫺93
DEAN 37261 (McGHP)
d237
ROTATED
d220
d243
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Refractive
index
43, 1884
1.01120
4
1.40320
⫺62
222
141.04
163.00
163.00
163.00
163.00
221.04
1, 131
61, 102
6, 189
6, 189
6, 190
1.105820
4
1.455320
⫺72
58–60
42–43
56–58
65–68
136–140
6610mm
206
210
211
218–220
1600.4mm
Cl2C6H3O(CH2)3CO2H
249.10
63, 708
117–119
Cl2C6H3OCH(CH3)CO2H
235.07
6, 189
110–112
Cl2C6H3NCO
188.01
123, 1405
42–44
12018mm
⬎110
C6H5PCl2
178.99
16, 763
⫺51
222
⬎112
Cl2C6H2(CO2H)2
235.02
91, 366
CH3CH(Cl)CH2Cl
112.99
1, 105
1.155820
1.439020
⫺100
96
4
ClCH2CH2CH2Cl
ClCH2CH(OH)CH2Cl
112.99
128.99
1, 105
1, 364
1.187820
4
1.198
1.448720
1.483520
⫺99.5
⫺4
120–122
174.3
32
85
0.26 aq; misc alc, bz,
chl, eth
v s alc, eth
9.1 aq; misc alc, eth
ClCH2CH"CHCl
ClCH2C(Cl)"CH2
110.97
110.97
1, 199
1, 199
1.21720
4
1.20425
25
1.47020
1.461120
97–112
94
25
10
i aq; s chl, eth
misc alc; s eth
148.98
147.99
147.99
198.05
101.01
20, 231
20, 231
203, 3384
[Cl(CH3)2SiOSi(CH3)2-]2
351.53
Cl(CH2)5Cl
Cl2C6H3OH
Cl2C6H3OH
Cl2C6H3OH
Cl2C6H3OH
Cl2C6H3OCH2COOH
1,3-Dichloropropane
1,3-Dichloro-2propanol
1,3-Dichloropropene
2,3-Dichloro-1propene
3,6-Dichloropyridazine
2,6-Dichloropyridine
3,5-Dichloropyridine
4,7-Dichloroquinoline
Dichlorosilane
d257
d258
d259
d260
d261
d262
d263
d264
d265
d266
d267
d268
d269
d270
d270a
Cl2C5H3N
Cl2C5H3N
Cl2SiH2
1.319
1.598020
Boiling
point,⬚C
Flash
point,⬚C
26
113
i aq; s alc, eth
s alc, eth
v s alc, bz, chl, eth
v s alc, bz, eth
v s alc, eth
s alc, bz, chl, eth
46 ppm aq25; s acet,
alc, eth; sl s bz
350 ppm aq20; v s org
solvents
201–203
66–69
86–88
65–67
84–86
⫺122
Solubility in 100
parts solvent
s aq; v s eth
14810mm
8.3
INTERACTIVE
1,7-Dichlorooctamethyltetrasiloxane
1,5-Dichloropentane
2,3-Dichlorophenol
2,4-Dichlorophenol
2,5-Dichlorophenol
2,6-Dichlorophenol
2,4-Dichlorophenoxyacetic acid
4-(2,4-Dichlorophenoxy)butanoic acid
2-(2,4-Dichlorophenoxy)propanoic acid
3,4-Dichlorophenyl
isocyanate
Dichlorophenylphosphine
4,5-Dichloro-ophthalic acid
1,2-Dichloropropane
Melting
point,⬚C
ROTATED
d250
Beilstein
reference
LEFT
Name
d251
d252
d253
d254
d255
d256
1.176
Density,
g/mL
Formula
Formula
weight
No.
F3CCFCl2
170.92
d271
1,2-Dichloro-1,1,2,2tetrafluoroethane
ClCF2CF2Cl
170.93
13, 152
d272
d273
d274
d275
d276
d277
d278
2,5-Dichlorothiophene
␣,␣-Dichlorotoluene
2,4-Dichlorotoluene
2,6-Dichlorotoluene
3,4-Dichlorotoluene
␣,␣-Dichloro-o-xylene
␣,␣-Dichloro-p-xylene
Cl2(C4H2S)
C6H5CHCl2
Cl2C6H3CH3
Cl2C6H3CH3
Cl2C6H3CH3
C6H4(CH2Cl)2
C6H4(CH2Cl)2
153.03
161.03
161.03
161.03
161.03
175.06
175.06
17, 33
5, 297
5, 295
5, 296
5, 296
5, 364
5, 384
d279
2,5-Dichloro-p-xylene
Cl2C6H2(CH3)2
175.06
5, 384
d280
d281
d282
d283
d284
d285
d286
Dicumyl peroxide
Dicyandiamide
1,2-Dicyanobenzene
1,3-Dicyanobenzene
1,4-Dicyanobutane
1,6-Dicyanohexane
2,4-Dicyano-3-methylglutaramide
1,5-Dicyanopentane
[C6H5C(CH3)2]2O2
H2NC("NH)NHCN
C6H4(CN)2
C6H4(CN)2
NC(CH2)4CN
NC(CH2)6CN
CH3CH[CH(CN)CONH2]2
270.37
84.08
128.13
128.13
108.14
136.20
194.19
3, 91
9, 815
9, 836
2, 653
2, 694
22, 704
NC(CH2)5CN
122.17
2, 671
d287
1,1-Dichloro-2-propanone, d184
␣,o-Dichlorotoluene, c56
1.45525
satd
pressure
1.47020
4
satd
pressure
1.442
1.254
1.246020
20
1.254
25
1.25125
1.30920
⫺57
4
1.309220
⫺94
3.6
1.562120
1.550020
1.551120
1.550720
1.547220
⫺40.5
⫺16/⫺17
⫺13
⫺15
55–57
99–101
162
205
200.5
196–203
209
239–241
254
71
222
1.40025
4
0.951
0.954
1.438020
1.443620
0.951
1.441020
␣,p-Dichlorotoluene, c70
39–41
208–211
139–141
158–160
1–3
⫺3.5
159–160
s alc, eth
59
92
79
82
85
107
i aq; misc alc, eth
v s alc, eth
i aq
i aq; s chl
i aq
22.5 acet; 20 bz; 4.5
CCl4; 11 eth; 18
EtOAc
27 acet; 44 bz; 39 eth;
32 EtOAc; 5 MeOH
⬎110
2.3 aq; 1.3 alc; i bz
v s bz, alc; s hot eth
s alc, bz, chl, eth
295
18515mm
93
⬎110
17614mm
⬎110
1,2-Dicyanoethane, b456
RIGHT
1,1-Dichlorotetrafluoroethane
DEAN 37261 (McGHP)
1.177
d270b
ROTATED
d267
d270
INTERACTIVE
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
d288
Dicyclohexyl
C6H11C6H11
166.31
5, 108
0.864
1.478220
3–4
227
92
d289
d290
(C6H11)2NH
C6H11N"C"NC6H11
181.32
206.33
0.910
1.484220
⫺2
35–36
255.8
1246mm
96
110
C6H4-1,2-(CO2C6H11)2
330.43
12, 6
Merck:
12, 3146
9, 799
132.21
218.30
5, 495
63, 1942
0.93025
4
1.050
1.505025
1.508020
170
13713mm
26
⬎110
110.16
514.86
0.977
0.915
1.467020
160–162
33, 556
39
⬎110
d296
Dicyclohexylamine
N,N⬘-Dicyclohexylcarbodiimide
Dicyclohexyl ophthalate
Dicyclopentadiene
Dicyclopentenyl
methacrylate
Dicyclopropyl ketone
Didodecyl 3,3⬘-thiodipropionate
Dieldrin
380.92
173, 526
d297
Diethanolamine
HOCH2CH2NHCH2CH2OH
105.14
4, 283
1.088130
4
1.474730
d298
2,2-Diethoxyacetophenone
4,4-Diethoxybutylamine
2,2-Diethoxy-N,N-dimethylethylamine
Diethoxydimethylsilane
Diethoxydiphenylsilane
1,1-Diethoxyethane
1,2-Diethoxyethane
2,2-Diethoxyethanol
2,2-Diethoxyethylamine
Diethoxymethane
C6H5C("O)CH(OC2H5)2
208.26
71, 361
1.034
H2N(CH2)3CH(OC2H5)2
161.25
4, 319
(C2H5O)2CHCH2N(CH3)2
161.25
4, 308
(C2H5O)2Si(CH3)2
148.28
(C2H5O)2Si(C6H5)2
272.42
CH3CH(OC2H5)2
C2H5OCH2CH2OC2H5
(C2H5O)2CHCH2OH
(C2H5O)2CHCH2NH2
118.18
118.18
134.18
133.19
(C2H5O)2CH2
104.15
d291
d292
d293
d294
d295
1.178
d300
d302
d303
d304
d305
d306
⫺1
40–42
176–177
28.0
269
172
1.499520
13410mm
⬎110
0.933
1.427520
196
62
0.883
1.412920
170
45
0.84020
4
1.381120
114
11
162, 608
1.032920
4
1.526920
1392mm
⬎110
1, 603
1, 468
1, 818
4, 308
0.825420
4
0.842
24
0.8884
0.916
1.381920
1.392220
1.416020
1.4170
102.2
121.4
167
162–163
⫺21
27
67
45
0.839
1.373220
87–88
⫺5
⫺87
⫺100
⫺74
s alc, eth
i aq; s common org
solvents except PE
96 aq; 4 bz; 0.8 eth;
misc MeOH, acet
5 aq; misc alc, eth
21 aq
s alc, eth
INTERACTIVE
d307
64–66
ROTATED
d301
7 MeOH; misc bz,
acet, eth
misc alc, bz, chl, eth
LEFT
d299
(C3H5)2C"O
S[CH2CH2CO2(CH2)11CH3]2
Solubility in 100
parts solvent
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
d317
3-(Diethoxymethylsilyl)propylamine
2,5-Diethoxynitrobenzene
Diethoxymethylvinylsilane
1,1-Diethoxypropane
3,3-Diethoxy-1propene
2,2-Diethoxytriethylamine
N,N-Diethylacetamide
Diethyl 1,3-acetonedicarboxylate
Diethyl 2-acetylglutarate
Diethyl acetylsuccinate
d318
d319
Diethyl adipate
Diethyl allylmalonate
d320
Diethylaluminum
chloride
Diethylaluminum
ethoxide
Diethylaluminum
iodide
d309
d310
d311
d312
d313
d314
d315
d316
1.179
d321
d322
CH3Si(OC2H5)2(CH2)3NH2
191.35
4, 4, 4201
(C2H5O)2C6H5NO2
211.22
6, 857
4
0.916
1.426020
48–51
20
4
20
888mm
75
16913mm
⬎110
(C2H5O)2Si(CH3)CH"CH2
160.29
4 , 4183
0.858
1.400
133–134
17
CH3CH2CH(OC2H5)2
(C2H5O)2CHCH"CH2
132.20
130.19
1, 630
1, 727
0.823220
4
0.854
1.388420
1.400020
122.8
125
7
4
(C2H5O)2CHCH2N(C2H5)2
189.30
4, 309
0.850
1.418920
194–195
65
CH3C("O)N(C2H5)2
C2H5OOCCH2C("O)CH2CO2C2H5
C2H5O2CCH2CH2CH[C("O)CH3]CO2C2H5
C2H5O2CCH2CH[C("O)CH3]CO2C2H5
C2H5O2C(CH2)4CO2C2H5
C2H5O2CCH(CH2CH"CH2)CO2C2H5
(C2H5)2AlCl
115.18
202.21
4, 110
3, 791
0.925
1.113
1.440120
1.438520
182–186
250
70
86
230.26
3, 809
1.071
1.438620
15411mm
⬎110
216.23
3, 801
1.081
1.434620
18350mm
⬎110
202.25
200.23
2, 652
2, 776
1.009
1.015
1.427020
1.430420
⫺18
251
222–223
110
71
120.56
43, 1972
0.961
⫺50
12650mm
⫺18
(C2H5)2AlOC2H5
130.17
43, 1972
0.850
2.5–4.5
10910mm
⫺18
(C2H5)2AlI
212.01
42, 1024
1.609
1204mm
⫺18
Diethylacetic acid, e100
Diethyl 2-acetylpentanedioate, d316
RIGHT
Diethyl acetal, d303
v s alc, eth
DEAN 37261 (McGHP)
d308
ROTATED
d292
d293
d296
INTERACTIVE
d323
d324
d325
Diethylamine
Diethylamine HCl
2-(Diethylamino)acetonitrile
4-(Diethylamino)benzaldehyde
2-Diethylaminoethanol
2-Diethylaminoethylchloride HCl
2-(Diethylamino)ethyl
methacrylate
3-(Diethylamino)phenol
3-Diethylamino-1,2propanediol
1-Diethylamino-2propanol
3-Diethylamino-1propanol
3-Diethylaminopropylamine
N,N-Diethylaniline
2,6-Diethylaniline
Diethyl azelate
Diethyl azodicarboxylate
5,5-Diethylbarbituric
acid
d326
d327
d328
d329
d330
1.180
d331
d332
d333
d334
d335
d336
d337
d338
d339
Diethyl benzalmalonate
1,2-Diethylbenzene
1,3-Diethylbenzene
1,4-Diethylbenzene
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
0.707420
4
1.04821
4
0.866
1.386410
(C2H5)2NH
(C2H5)2NH · HCl
(C2H5)2NCH2CN
73.14
109.60
112.18
4, 95
4, 95
4, 350
(C2H5)2NC6H4CHO
177.25
142, 25
(C2H5)2NCH2CH2OH
ClCH2CH2N(C2H5)2 · HCl
117.19
172.10
4, 282
42, 618
0.880025
1.438920
H2C"C(CH3)CO2CH2CH2N(C2H5)2
(C2H5)2NC6H4OH
185.27
43, 676
0.922
1.444020
165.24
13, 408
(C2H5)2NCH2CH(OH)CH2OH
(C2H5)2NCH2CH(OH)CH3
147.22
4, 302
0.97320
20
1.460220
131.22
42, 737
0.889
1.425520
(C2H5)2NCH2CH2CH2OH
131.22
4, 288
0.884
(C2H5)2NCH2CH2CH2NH2
130.24
C6H5N(C2H5)2
(C2H5)2C6H3NH2
C2H5O2C(CH2)7CO2C2H5
C2H5O2CN"NCO2C2H5
149.24
149.24
244.33
174.16
12, 164
C6H5CH"C(CO2C2H5)2
C6H4(C2H5)2
C6H4(C2H5)2
C6H4(C2H5)2
Melting
point,⬚C
Boiling
point,⬚C
⫺50.0
227–230
55.5
320–330
170
⫺23
39–41
1747mm
⬎110
⫺70
108–210
163
48
8010mm
76
1.426020
65–69
Flash
point,⬚C
Solubility in 100
parts solvent
misc aq, alc
s aq, alc, chl; i eth
53
17015mm
s aq, alc, bz, eth
s aq, alc, eth
233–235
107
s aq, alc, chl, eth
5913mm
33
s alc
1.4435
8315mm
65
0.826
1.441620
159
58
2, 709
3, 123
0.930225
4
0.906
0.973
1.106
1.539425
1.545220
1.435020
1.428020
216
243
17218mm
10613mm
97
123
⬎110
⬎110
184.19
242, 279
1.220
248.28
134.22
134.22
134.22
9,
5,
5,
5,
1.107
0.880
0.864020
4
0.862020
4
892
426
426
426
13.5
⫺38
3
⫺16
188–192
1.536520
1.502020
1.495020
1.494020
⫺31
⫺83.9
⫺42.8
1 aq; sl s alc, eth
0.7 aq; 7 alc; 1.3 chl;
3.2 eth; s acet,
HOAc
21530mm
184
181.1
183.8
⬎110
49
50
56
s alc, eth
s alc, eth
INTERACTIVE
d340
d340a
d341
d342
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
d344
d345
d346
d347
d348
d349
d350
d351
d352
1.181
d353
d354
d355
d356
Diethyl benzylmalonate
Diethyl benzophosphonate
Diethyl bis(hydroxymethyl)malonate
Diethyl
bromomalonate
Diethyl butylmalonate
Diethylcarbamoyl
chloride
Diethyl carbonate
C6H5CH2CH(CO2C2H5)2
250.29
9, 869
1.064
1.486820
16210mm
⬎110
C6H5CH2P(O)(OC2H5)2
228.23
12, 164
1.095
1.497020
1081mm
⬎110
(HOCH2)2C(CO2C2H5)2
220.22
BrCH(CO2C2H5)2
239.07
2, 594
1.402225
4
1.455020
⫺54
235 dec
⬎110
i aq; misc alc, eth
C4H9CH(CO2C2H5)2
(C2H5)2N(O)Cl
216.28
135.59
21, 282
4, 120
0.983
1.070
1.4220
1.451520
⫺32
235–240
187–190
93
75
v s alc, eth
d hot aq, hot alc
(C2H5O)2C"O
118.13
3, 5
0.976420
4
1.384320
⫺43.0
126
25
69 aq; misc alc, bz,
eth, esters
Diethyl chlorophosphate
Diethyl chlorothiophosphate
Diethyl cyanophosphate
N,N-Diethylcyclohexylamine
Diethyl diethylmalonate
1,3-Diethyl-1,3diphenylurea
Diethyl disulfide
(C2H5O)2P(O)Cl
172.55
1, 332
1.194
1.416520
602mm
61
(C2H5O)2P(S)Cl
188.61
13, 1332
1.200
1.471520
453mm
⬎110
(C2H5O)2P(O)CN
163.11
1.075
1.401220
10519mm
80
C6H11N(C2H5)2
155.29
12, 6
0.850
1.456220
194–195
57
(C2H5)2C(CO2C2H5)2
216.28
2, 686
0.990
1.423020
228–230
94
[C6H5N(C2H5)]2C"O
268.36
12, 422
C2H5SSC2H5
122.25
1, 347
154.0
40
73–75
0.99820
4
Diethyl cis-2-butanedioate, d377
1.506320
⫺101.5
Diethyl carbitol, b186
sl s aq; misc alc, eth
RIGHT
Diethylaminoacetaldehyde diethyl acetal, d313
3-Diethylaminopropylamine, d400
⬎110
49–51
DEAN 37261 (McGHP)
d343
ROTATED
d339
INTERACTIVE
Name
d357
Diethyldithiocarbamic
acid, sodium salt
Diethyl dithiophosphate
N,N-Diethyldodecanamide
Diethyl dodecanedioate
Diethylene glycol
Diethylenetriamine
Diethylenetriaminepentaacetic acid
N,N-Diethylethanolamine
Diethyl ether
Diethyl ethoxymethylenemalonate
N,N-Diethylethylenediamine
Diethyl ethylmalonate
N,N-Diethylformamide
Diethyl fumarate
Diethyl glutarate
d358
d359
d360
d361
d362
d363
d364
1.182
d365
d366
d367
d368
d369
d370
d371
d373
d374
d375
d376
Beilstein
reference
(C2H5)2NC("S)S⫺ Na⫹ · 3H2O
225.31
42, 613
(C2H5O)2P(S)SH
186.23
1, 333
CH3(CH2)10C("O)N(C2H5)2
255.45
C2H5O2C(CH2)10CO2C2H5
186.41
(HOCH2CH2)2O
(H2NCH2CH2)NH
[(HO2CCH2)2NCH2CH2]2N(CH2CO2H)N(CH2CO2H)2
HOCH2CH2N(C2H5)2
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
95–99
1.111
1.512020
601mm
82
0.847
1.454520
1662mm
⬎110
22, 616
0.951
1.440220
15
19314mm
⬎110
106.12
103.17
393.35
1, 468
4, 255
44, 2454
1.119715
0.954220
20
1.446020
1.482620
⫺10
⫺35/⫺39
219–220
246
207
124
98
117.19
4, 282
0.884
1.441020
161
48
C2H5OC2H5
(C2H5O2C)2C"CHOC2H5
74.12
216.23
1, 314
3, 469
0.713420
4
1.070
1.352720
1.462020
34.6
279–281
⫺45
155
(C2H5)2NCH2CH2NH2
116.21
4, 251
0.827
1.436020
145–147
30
C2H5CH(CO2C2H5)2
(C2H5)2NCHO
C2H5O2CCH"CHCO2C2H5
C2H5O2CCH2CH2CH2CO2C2H5
H2C"CHCH2CH(C2H5)CH"C(C2H5)CHO
C2H5O2C(CH2)5CO2C2H5
C6H4[CO2CH2CH(C2H5)C4H9]2
(C2H5O)2P(O)H
188.22
101.15
172.18
188.22
2, 644
4, 109
2, 742
2, 633
1.00420
20
0.908
1.05220
4
1.022
1.415820
1.434020
1.440620
1.424020
775mm
176–177
218–219
237
88
60
91
96
0.862
1.467620
9112mm
86
192100mm
384
⬎110
207
i aq; s alc, eth
512mm
90
hyd aq; s alc, eth
(C2H5)2NOH
C2H5O2CCH"CHCO2C2H5
166.27
⫺116.3
1–2
⫺23.8
⫺24
⫺50
216.28
390.56
2, 671
10, 1248
0.994520
0.98125
25
1.428020
1.485320
138.10
1, 330
1.07920
4
1.407620
89.14
4, 536
1.867
1.419520
⫺25
125–130
45
172.18
2, 751
1.068720
1.440020
⫺8.8
225.3
93
misc aq, alc, bz, eth
6 aq; misc alc, bz, chl
sl s aq; v s alc, eth
misc aq; v s alc, eth
0.9 aq; v s alc; s eth
1.4 aq; s alc, eth
INTERACTIVE
d377
2,4-Diethyl-2,6heptadienal
Diethyl heptanedioate
Di-(2-ethylhexyl)-ophthalate
Diethyl hydrogen
phosphonate
N,N-Diethylhydroxylamine
Diethyl maleate
Formula
weight
ROTATED
d372
Formula
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
C2H5O2CCH2CO2C2H5
HO2CC(C2H5)2CO2H
(C2H5)2NH3
d384
d385
Diethyl malonate
Diethylmalonic acid
N,N-Diethylmethylamine
Diethyl methylmalonate
Diethyl 2-methyl-2⬘oxosuccinate
N,N-Diethyl-4-nitrosoaniline
Diethyl octanedioate
Diethyl oxalate
d386
d386a
d387
d381
d382
d383
1.183
d388
d389
d390
d391
d392
d393
160.17
160.17
87.17
2, 573
2, 686
4, 99
1.0550
1.413620
0.720
1.388720
20
4
⫺49.9
127
20
199.3
170–180
63–65
93
⫺23
2.7 aq; misc alc, eth
v s aq, alc, eth
C2H5O2CCH(CH3)CO2C2H5
174.20
2, 629
1.018
1.4130
198
76
C2H5O2CCH(CH3)C("O)CO2C2H5
C6H4(NO)N(C2H5)2
202.21
3, 794
1.073
1.431320
13823mm
⬎110
178.24
12, 684
C2H5O2C(CH2)6CO2C2H5
C2H5O2CCO2C2H5
230.30
146.14
2, 693
2, 535
0.982220
4
1.078520
4
1.432320
1.410220
282
185.4
⬎112
76
Diethyl oxydiformate
[C2H5OC("O)]2O
162.14
Merck:
12, 8182
1.1220
4
1.398020
9318mm
69
3,3-diethylpentane
N1,N1-Diethyl-1,4pentanediamine
N1,N1-Diethyl-1,4phenylenediamine
Diethyl phenylmalonate
Diethyl phosphite
Diethyl o-phthalate
N,N-Diethyl-1,3propanediamine
2,2-Diethyl-1,3propanediol
C(C2H5)4
CH3CH(NH2)(CH2)3N(C2H5)2
128.26
158.29
0.753620
0.817
1.420620
1.442920
146
200
68
(C2H5)2NC6H4NH2
164.25
Merck:
12, 6819
13, 75
0.988
1.571020
1165mm
⬎110
C6H5CH(CO2C2H5)2
236.27
9, 854
1.095020
4
1.491320
16
17014mm
⬎110
i aq; s alc
(C2H5)2P(O)H
C6H4(CO2C2H5)2
(C2H5)2NCH2CH2CH2NH2
138.10
222.24
130.24
1, 330
9, 798
1.07920
4
1.23214
4
0.826
1.407920
1.504914
1.441620
⫺40
512mm
295
159
90
160
58
hyd aq; s alc, eth
i aq; misc alc, eth
(C2H5)2C(CH2OH)2
132.20
1.05220
1.457425
61.3
12510mm
⫺33
i aq; s alc, eth
3.6 aq (gradual dec);
misc alc, eth
50 alc; s esters, ketones; s aq
s aq, alc, eth
25 aq; v s alc, eth
O,O-Diethyl O-p-nitrophenyl phosphorothioate, p3
Diethyl 3-oxoglutarate, d315
2,3-Diethylpentane, e210a
Diethyl 2-pentenedioate, d371
Diethyl phosphorochloridate, d350
Diethyl phosphorochloridothionate, d351
Diethyl pimelate, d373
Diethyl propanedioate, d378
ROTATED
Diethylene glycol monomethyl ether, m73
Diethyleneimide oxide, m463
N,N-Diethylethanamine, t274
Diethyl ethanedioate, d385
N,N-Diethylethanolamine, d327
Diethyl ethoxycarbonylmethylphosphonate, t287
Di-2-ethylhexyl phthalate, b193
Diethyl ketone, p43
5.9
⫺40.6
RIGHT
Diethylene dioxide, d733
Diethylene glycol, b198
Diethylene glycolamine, a164
Diethylene glycol dibutyl ether, b151
Diethylene glycol diethyl ether, b186
Diethylene glycol dimethyl ether, b214
Diethylene glycol monobutyl ether, b495
Diethylene glycol monoethyl ether, e41
Diethylene glycol monoethyl ether acetate, e41a
82–84
DEAN 37261 (McGHP)
d378
d379
d380
INTERACTIVE
Diethyl propylmalonate
Diethyl sebacate
Diethyl succinate
Diethyl sulfate
Diethyl sulfide
Diethyl sulfite
(⫹)-Diethyl-L-tartrate
(⫺)-Diethyl-D-tartrate
N,N-Diethyl-mtoluamide
N,N-Diethyl-mtoluidine
N,N-Diethyl-1,1,1-trimethylsilylamine
Diethylzinc
1,2-Difluorobenzene
1,4-Difluorobenzene
1,1-Difluoroethane
1,1-Difluoroethylene
Difluoromethane
2,4-Difluoronitrobenzene
1,1-Difluorotetrachloroethane
1,2-Difluorotetrachloroethane
Dihexylamine
Dihexyl ether
9,10-Dihydroanthracene
(⫹)-Dihydrocarvone
Dihydrocoumarin
d395
d396
d397
d398
d399
d400
d401
d402
d403
1.184
d404
d405
d406
d406a
d407
d408
d409
d410
d411
d412
d413
d414
d415
d416
d417
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
C2H5O2CCH(C3H7)CO2C2H5
202.25
2, 657
0.987
1.418520
C2H5O2C(CH2)8CO2C2H5
C2H5O2C(CH2)2CO2C2H5
(C2H5O)2SO2
(C2H5)2S
(C2H5O)2SO
[-CH(OH)CO2C2H5]2
[-CH(OH)CO2C2H5]2
CH3C6H4C("O)N(C2H5)2
258.36
174.20
154.18
90.19
138.19
206.19
206.19
191.27
2, 717
2, 609
1, 327
1, 344
1, 325
3, 512
31, 181
92, 325
0.963
1.04020
4
1.17225
4
0.836720
4
1.883
1.20520
4
1.205
0.99620
4
1.436020
1.420020
1.400420
1.443020
1.45020
1.446020
1.446020
1.521220
CH3C6H4CN(C2H5)2
163.26
12, 857
0.922
(C2H5)2NSi(CH3)3
145.32
43, 1861
(C2H5)2Zn
C6H4F2
C6H4F2
CH3CHF2
CH2 "CF2
CH2F2
F2C6H3NO2
123.49
114.09
114.09
66.05
64.04
52.02
159.09
ClF2CCCl3
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
221–222
91
312
217.7
208
92.1
158
280
16219mm
1111mm
⬎110
100
78
⫺9
53
93
93
⬎110
1.536020
231–232
100
0.767
1.411020
125–126
10
6, 672
52, 147
5, 199
13, 130
1, 186
1, 59
51, 129
1.206520
4
1.158
1.170120
0.90921
1.498320
1.443020
1.441020
1.3011⫺72
1.511020
118
92
89
⫺24.7
⫺86
⫺51.6
203–204
⫺23
2
2
2.126 g/L
1.451
⫺28
⫺34
⫺13
⫺117
⫺144
⫺136
9–10
203.83
1, 86
1.649
1.413
41
91
none
FCl2CCCl2F
203.83
13, 365
1.644725
4
1.41325
23.8
203.8
(C6H13)2NH
(C6H13)2O
185.36
186.34
180.25
41, 384
13, 1656
5, 641
0.795
0.793620
4
0.880
1.432020
1.420420
95
77
108–110
192–195
226.2
312
152.24
148.16
73, 337
17, 315
0.92919
1.16918
1.471820
1.556320
25
221–222
272
81
⬎110
1–2
⫺21
⫺25
⫺103.9
17
Solubility in 100
parts solvent
0.14 aq; misc alc, eth
i aq; misc alc, eth
i aq; misc alc, eth
i aq; misc alc, eth
s aq(dec), alc
sl s aq; misc alc, eth
sl s aq; misc alc, eth
i aq; v s alc, bz, eth
0.32 aq
FLAMMABLE GAS
90
sl s alc; v s eth
i aq; s alc, eth
s alc, eth
i aq; s ethers
i aq; s alc, bz, eth
sl s alc, eth; s chl
INTERACTIVE
d394
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
d419
d420
d421
d422
d423
d424
d425
2,5-Dihydro-2,5-dimethoxyfurfurylamine
2,3-Dihydro-2,2-dimethyl-7-benzofuranol
3,4-Dihydro-2-ethoxy2H-pyran
2,3-Dihydrofuran
3,4-Dihydro-2methoxy-2H-pyran
3,4-Dihydro-1(2H)naphthalenone
3,4-Dihydro-2H-pyran
2⬘,4⬘-Dihydroacetophenone
159.19
183, 7426
1.102
1.460020
164.21
175, 4, 47
1.101
1.541020
0.957
1.439420
4216mm
24
54–55
⫺24
16
128.17
(HO)2C6H3C("O)CH3
1.185
Diethyl pyrocarbonate, d386
Diethyl suberate, d384
Diglycine, i7
9612mm
96
110
70.09
114.14
173, 141
0.927
1.423920
1.442520
146.19
7, 370
1.099
1.568520
5–6
1166mm
⬎110
84.12
152.15
0.92219
15
1.180
1.441020
⫺70
145–147
86
⫺15
8, 266
Diglycol, b198
Diglycolic acid, o67
Diglyme, b214
DEAN 37261 (McGHP)
d418
s aq, alc
s warm alc, HOAc,
pyr; i bz, eth
Dihexyl ketone, t264
1,2-Dihydroacenaphthylene, a2
2,5-Dihydroanisole, m67
RIGHT
d415
d416
d417
d418
ROTATED
d419
d420
d421
d422
d424
INTERACTIVE
d423
No.
Name
d426
d428
1,8-Dihydroxyanthraquinone
2,4-Dihydroxybenzaldehyde
1,2-Dihydroxybenzene
d429
d430
d431
d427
d432
1.186
d433
d434
d435
d439
d440
d441
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
240.21
8, 458
193–197
subl
(HO)2C6H3CHO
138.12
8, 241
135–136
22622mm
C6H4(OH)2
110.11
6, 759
1.3444
104–106
245.5
137
1,3-Dihydroxybenzene
C6H4(OH)2
110.11
62, 802
1.27215
109–110
276
171
1,4-Dihydroxybenzene
2,4-Dihydroxybenzoic
acid
2,5-Dihydroxybenzoic
acid
3,4-Dihydroxybenzoic
acid
3,5-Dihydroxybenzoic
acid
2,4-Dihydroxybenzophenone
2,2⬘-Dihydroxybiphenyl
4,6-Dihydroxy-2mercaptopyrimidine
C6H4(OH)2
(HO)2C6H3CO2H
110.11
154.12
6, 836
10, 377
1.33215
285–287
(HO)2C6H3CO2H
154.12
10, 384
170–171
213 rapid
heating
199–200
(HO)2C6H3CO2H
154.12
10, 389
(HO)2C6H3CO2H
154.12
(HO)2C6H3C("O)C6H5
1,2-Dihydroxy-4methylbenzene
1,5-Dihydroxynaphthalene
1,6-Dihydroxynaphthalene
2,3-Dihydroxynaphthalene
2,7-Dihydroxynaphthalene
1.54
Solubility in 100
parts solvent
0.005 alc; 0.2 eth; s
chl
v s aq, alc, chl, eth
43 aq; s alc, bz, chl,
eth; v s pyr, alkalis
110 aq; 110 alc; v s
eth, glyc; sl s chl
7 aq; v s alc, eth
s hot aq, alc, eth
0.5 aq; s alc, eth
200–202
2 aq; s alc, eth
10, 404
236 dec
sl s aq; s alc, eth
214.22
8, 312
144–145
v s alc, eth, HOAc
HOC6H4C6H4OH
186.21
144.15
6, 989
24, 476
110
236
315
s alc, bz, eth; sl s aq
(HO)2C6H3CH3
124.14
6, 878
67–69
251
v s aq, alc, eth
C10H6(OH)2
160.17
6, 980
259 dec
sl s aq; s alc; v s eth
C10H6(OH)2
160.17
6, 981
138–140
v s alc, eth
C10H6(OH)2
160.17
6, 982
162–164
v s alc, eth
C10H6(OH)2
160.17
6, 985
187 dec
sl s aq; v s alc, eth
1.12974
4
1.542574
INTERACTIVE
d442
Beilstein
reference
ROTATED
d438
Formula
weight
LEFT
d436
d437
Formula
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
(HO)2C10H5CO2H
204.19
10, 442
220 dec
(HO)2C10H5CO2H
204.19
10, 444
277 dec
90.08
1, 846
65–71
v s aq, alc, acet, eth
158
33 aq; 2 alc; 1 chl
sl s ahot alc; s hot aq
d448
d449
d450
d451
d452
1,4-Dihydroxy-2naphthoic acid
3,5-Dihydroxy-2naphthoic acid
1,3-Dihydroxy-2propanone
7-(2,3-Dihydroxypropyl)theophylline
3,6-Dihydroxypyridazine
2,3-Dihydroxypyridine
1,4-Diiodobenzene
1,4-Diiodobutane
1,2-Diiodoethane
Diiodomethane
d453
d454
1,5-Diiodopentane
1,3-Diiodopropane
d444
d445
d446
d447
HOCH2C("O)CH2OH
254.25
112.09
24, 312
306–308
(HO)2C5H3N
C6H4I2
I(CH2)4I
ICH2CH2I
CH2I2
111.10
329.91
309.92
281.86
267.84
212, 107
5, 227
1, 123
1, 99
1, 71
2.350
2.13210
3.32520
4
1.742520
245 dec
131–133
6
81–84
6
285
15226mm
200
181
I(CH2)5I
I(CH2)3I
323.94
295.88
1, 133
1, 115
2.177
2.575520
4
1.600220
1.642320
⫺13
1023mm
222
1.187
10,11-Dihydro-5H-dibenz[b,f]azepine, i9
2,5-Dihydro-2,5-dimethoxyfuran, d501
3,7-Dihydro-3,7-dimethyl-1H-pyridine-2,6-dione, t134
Dihydro-2(3H)-furanone, b617
2,3-Dihydroindene, i10
Dihydromyrcenol, m313
Dihydroresorcinol, c323
1.621220
3,7-Dihydro-1,3,7-trimethyl-1H-purine-2,6-dione, c1
1,3-Dihydroxyacetone, d445
1,4-Dihydroxybenzene, h86
1,4-Dihydroxycyclohexane, c359
2,2⬘-Dihydroxydiethylamine, d297
N,N-Di(hydroxyethyl)aminoacetic acid, b199
sl s alc; v s eth
DEAN 37261 (McGHP)
d443
none
⬎110
⬎110
⬎110
sl s aq; s alc, eth
0.12 aq; misc alc, bz,
eth, PE
i aq; s chl, eth
2,2-Dihydroxy-1,3-indandione, i13
2,2-Dihydroxymethyl-1-butanol, e183
1,1-Di(hydroxymethyl)ethylamine, a215
Dihydroxypropane, p191, p192
3,5-Diiodosalicylic acid, h113
Diisobutyl adipate, d459
RIGHT
ROTATED
d426
d437
d446
d447
INTERACTIVE
Diisobutylaluminum
chloride
Diisobutylaluminum
hydride
Diisobutylamine
Diisobutyl ether
Diisobutyl hexanedioate
Diisobutyl o-phthalate
1,6-Diisocyanatohexane
Diisodecyl phenyl
phosphite
Diisoheptyl o-phthalate
Diisononyl o-phthalate
Diisooctyl nonanedioate
Diisooctyl o-phthalate
Diisopentyl ether
1,3-Diisopropenylbenzene
Diisopropylamine
2-(Diisopropylamino)ethanol
3-Diisopropylamino1,2-propanediol
2,6-Diisopropylaniline
Diisopropyl azodicarboxylate
1,3-Diisopropylbenzene
1,4-Diisopropylbenzene
Diisopropylcyanamide
d456
d457
d458
d459
d460
d461
d462
1.188
d463
d464
d465
d466
d466a
d467
d468
d469
d470
d471
d472
d473
d474
d475
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
1.450620
Melting
point,⬚C
⫺40
Boiling
point,⬚C
Flash
point,⬚C
15210mm
⫺18
1181mm
⫺18
137–139
122–124
29
8
160
Solubility in 100
parts solvent
[(CH3)2CHCH2]2AlCl
176.67
44, 4403
0.905
[(CH3)2CHCH2]2AlH
142.22
44, 4400
0.798
[(CH3)2CHCH2]2NH
[(CH3)2CHCH2]2O
[(CH3)2CHCH2O2CCH2CH2⫺]2
129.25
130.22
258.36
4, 166
0.740
0.76115
0.95025
25
1.408120
C6H4[CO2CH2CH(CH3)2]2
OCN(CH2)6NCO
278.35
168.20
92, 587
42, 711
1.03825
25
1.040
1.490020
1.452520
255
(C10H21O)2P(O)C6H5
438.64
0.940
1.480020
1765mm
C6H4(CO2C7H15)2
C6H4(CO2C9H19)2
C8H17O2C(CH2)7CO2C8H17
412.66
0.990
0.972
0.905
1.486020
1.485020
1.451010
2102mm
C6H4(CO2C8H17)2
[(CH3)2CHCH2CH2]2O
C6H4[C(CH3)"CH2]2
390.56
158.28
158.25
0.983
0.777720
0.925
1.486020
1.408520
1.557120
172.5
231
91
[(CH3)2CH]2NH
[(CH3)2CH]2NCH2CH2OH
101.19
145.25
0.715320
0.826
1.392420
1.441720
83.5
187–192
⫺1
57
[(CH3)2CH]2NCH2CH(OH)CH2OH
[(CH3)2CH]2C6H3NH2
(CH3)2CHO2CNCO2CH(CH3)2
C6H4[CH(CH3)2]2
175.27
0.962
1.458320
13110mm
⬎110
177.29
202.21
12, 168
0.940
1.027
1.533220
1.420020
⫺45
257
750.25mm
123
106
162.28
5, 447
0.85620
4
1.489020
⫺63
203
76
misc alc, bz, eth, acet
C6H4[CH(CH3)2]2
162.28
52, 339
0.85720
4
1.488920
⫺17
204
76
misc alc, bz, acet, eth
[(CH3)2CH]2NCN
126.20
43, 279
0.839
1.427020
9325mm
78
4, 154
41, 430
⫺77
s alc, acet, eth, chl
i aq; misc alc, eth
174
140
⬎110
⬎110
⬎110
⬎110
⫺61
11 aq; s alc
INTERACTIVE
d455
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Diisopropyl ether
[(CH3)2CH]2O
102.17
1, 362
0.725820
4
1.367920
⫺86.9
68.4
⫺28
d477
N,N-Diisopropylethylamine
Diisopropyl malonate
[(CH3)2CH]2NC2H5
129.25
4, 4, 511
0.742
1.413320
⬍ ⫺50
127
10
20
d478
d479
d480
d481
d482
d483
d484
d485
d486
1.189
d487
d488
d489
d490
d491
d492
188.22
2 , 1620
0.991
1.4120
178.28
166.16
234.25
61, 272
1, 363
3, 517
0.962
0.997
1.114
1.514020
1.407020
1.438720
(CH3)2CHNHCSNHCH(CH3)2
160.28
4, 155
84.07
154.25
173, 4297
HSCH2CH(OH)CH(OH)CH2SH
HSCH2CH(SH)CH2OH
18
95
88
256
72–7520
15212mm
110
⬎110
109
127
34
143–145
1.090
1.433020
42.43
1.238525
4
124.22
1.527025
v s aq, alc, chl, eth
12015mm
⬎110
8 aq(dec); s alc, eth
⬎110
sl s aq, alc, eth
⬎110
s alc, bz, eth
s aq, alc
s hot eth
150.24
27, 677
162 dec
(CH3O)2C6H3COCH3
180.20
82, 298
49–51
286–288
(CH3O)2C6H3NH2
(CH3O)2C6H3NH2
(CH3O)2C6H3NH2
(CH3O)2C6H3CHO
153.18
153.18
153.18
166.18
13, 784
13, 788
13, 780
8, 245
34–37
80–82
88
49–52
270
17622mm
14610mm
⬎110
(CH3O)2C6H3CHO
166.18
8, 255
42–43
281
⬎110
v s alc, eth
C6H4(OCH3)2
138.17
6, 771
22.5
206.3
87
sl s aq; s alc, eth
1.075
1.081925
1.523225
Diisopropyl ketone, d658
Dimedone, d596
ROTATED
Diisobutylene, t384
Diisobutyl ketone, d616
(CH3)2CHO2CCH2CO2CH(CH3)2
[(CH3)2CH]2C6H3OH
[(CH3)2CHO]2P(O)H
[-CH(OH)CO2CH(CH3)2]2
12mm
RIGHT
d493
2,6-Diisopropylphenol
Diisopropyl phosphite
(⫹)-Diisopropyl
L-tartrate
1,3-Diisopropyl-2thiourea
Diketene
threo-1,4-Dimercapto2,3-butanediol
2,3-Dimercapto-1propanol
2,5-Dimercapto-1,3,4thiadiazole
3⬘4⬘-Dimethoxyacetophenone
2,4-Dimethoxyaniline
2,5-Dimethoxyaniline
3,4-Dimethoxyaniline
2,5-Dimethoxybenzaldehyde
3,4-Dimethoxybenzaldehyde
1,2-Dimethoxybenzene
3
1.2 aq; misc alc, bz,
chl, eth
DEAN 37261 (McGHP)
d476
d483
d486
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
1,3-Dimethoxybenzene
1,4-Dimethoxybenzene
3,4-Dimethoxybenzoic
acid
3,5-Dimethoxybenzoic
acid
2,6-Dimethoxybenzoyl
chloride
3,4-Dimethoxybenzyl
alcohol
2,2-Dimethoxycyclohexanol
2,5-Dimethoxy-2,5dihydrofuran
Dimethoxydimethylsilane
Dimethoxydiphenylsilane
1,1-Dimethoxyethane
1,2-Dimethoxyethane
(2,2⬘-Dimethoxy)ethylamine
Dimethoxymethane
1,1-Dimethoxy-2methylaminoethane
Dimethoxymethylvinylsilane
Dimethoxymethylphenylsilane
1,2-Dimethoxy-4nitrobenzene
2,6-Dimethoxyphenol
d497
d498
d499
d500
1.190
d501
d502
d503
d504
d505
d506
d507
d508
d509
d510
d511
d512
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
1.055
1.03665
8
1.5240
Melting
point,⬚C
⫺55
55–60
180–181
C6H4(OCH3)2
C6H4(OCH3)2
(CH3O)2C6H3CO2H
138.17
138.17
182.18
6, 813
6, 843
101, 188
(CH3O)2C6H3CO2H
182.18
10, 405
182–184
(CH3O)2C6H3COCl
200.62
103, 1402
64–66
(CH3O)2C6H3CH2OH
168.19
5, 1113
(CH3O)2C6H9OH
Boiling
point,⬚C
Flash
point,⬚C
877mm
213
87
Solubility in 100
parts solvent
s alc, bz, eth
s alc; v s bz, eth
0.05 aq; v s alc, eth
1.157
1.552020
297732mm
⬎110
160.22
1.072
1.462020
909mm
40
130.14
1.073
1.433920
160–162
47
(CH3O)2Si(CH3)2
120.23
0.880
1.369020
81.4
10
(C6H5)2Si(OCH3)2
244.4
1.077120
4
1.544720
16115mm
CH2CH(OCH3)2
CH3OCH2CH2OCH3
H2NCH2CH(OCH3)2
90.12
90.12
105.14
1, 603
1, 467
42, 758
0.850220
0.862020
4
0.965
1.366820
1.379620
1.417020
⫺113
⫺68
64.5
85.2
13595mm
⫺17
1
53
s aq, alc, chl, eth
misc aq, alc; s PE
CH2(OCH3)2
CH3NHCH2CH(OCH3)2
76.10
119.16
1, 574
42, 759
0.860120
20
0.928
1.351420
1.411520
⫺104.8
42.3
140
⫺32
29
32 aq
CH3Si(OCH3)2CH"CH2
132.24
0.884
1.395020
106
3
(CH3O)2Si(CH3)C6H5
182.3
0.99320
4
1.46920
199–200
(CH3O)2C6H3NO2
183.16
6, 789
(CH3O)2C6H3OH
154.17
6, 1081
1.1888133
4
95–98
23017mm
53–56
261
v s alc, eth; s chl
⬎110
s alc, alk; v s eth
INTERACTIVE
d494
d495
d496
Formula
ROTATED
Name
LEFT
No.
d514
d515
d516
d517
d518
d519
d520
d521
d522
1.191
d523
d524
d525
d526
d527
196.20
10, 409
96–98
(CH3O)2C6H3CN
177.20
101, 198
62–63
C6H5C(O)C(OCH3)2C6H5
256.30
C6H5CH2CH(OCH3)2
166.22
7, 293
1.004
1.495020
221
83
(CH3O)2C6H3CH2CH2NH2
181.24
13, 800
1.074
1.546420
18815mm
⬎110
CH3CH(OCH3)CH2OCH3
(CH3)2C(OCH3)2
CH3C(O)CH(OCH3)2
104.15
104.15
118.13
14, 2471
1, 648
11, 395
0.855
0.847
0.976
1.383520
1.378020
1.397820
96
83
143–147
0
⫺11
37
(CH3O)2CHCH"CH2
102.13
11, 378
0.862
1.395420
89–90
⫺2
CH3CH"CHC6H5(OCH3)2
178.23
6, 956
1.055
1.568020
262–264
⬎110
(CH3O)2CHCH2CN
115.13
34, 521
1.026
1.413020
9230mm
86
(CH3O)2C5H3N
(CH3O)2C4H6O
139.15
132.16
1.053
1.020
1.512920
1.418020
178–180
145–147
61
35
0.936625
1.437620
165.5
70
15025mm
⬎110
CH3C(O)N(CH3)2
87.12
s aq; v s alc, eth
17810mm
67–70
4, 59
CH3C(O)NHC6H3(CH3)2
163.22
12, 1109
[CH3O2CCH2]2C"O
174.15
3, 790
misc aq, alc, bz, eth
182–184
1.185
Dimethyl acetal, d504
⫺20
1.443420
Dimethylacetic acid, i81
ROTATED
3,4-Dimethoxyphenethylamine, d517
1,1-Dimethyoxytrimethylamine, d614
(CH3O)2C6H3CO2H
RIGHT
d528
3,4-Dimethoxyphenylacetic acid
3,4-Dimethoxyphenylacetonitrile
2,2-Dimethoxy-2phenylacetophenone
1,1-Dimethoxy-2phenylethane
2-(3,4-Dimethoxyphenyl)ethylamine
1,2-Dimethoxypropane
2,2-Dimethoxypropane
1,1-Dimethoxy-2propanone
3,3-Dimethoxy-1propene
1,2-Dimethoxy-4propenylbenzene
3,3-Dimethoxypropionitrile
2,6-Dimethoxypyridine
2,5-Dimethoxytetrahydrofuran
N,N-Dimethylacetamide
2⬘,6⬘-Dimethylacetanilide
Dimethyl 1,3-acetonedicarboxylate
DEAN 37261 (McGHP)
d513
d501
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Dimethyl acetylenedicarboxylate
Dimethyl acetylsuccinate
N,N-Dimethylacrylamide
3,3-Dimethylacrylic
acid
Dimethylaluminum
chloride
Dimethylamine
Dimethylaminoacetonitrile
4-(Dimethylamino)benzaldehyde
3-Dimethylaminobenzoic acid
4-Dimethylaminobenzoic acid
2-(Dimethylamino)ethanol
2-[2-(Dimethylamino)ethoxy]ethanol
2-(Dimethylamino)ethyl acrylate
2-(Dimethylamino)ethyl benzoate
2-(Dimethylamino)ethyl methacrylate
d530
d531
d532
1.192
d533
d534
d535
d536
d537
d538
d539
d540
d541
d542
d543
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
1.447020
CH3O2CC#CCO2CH3
142.11
2, 803
1.156
CH3O2CC2CH(COCH3)CO2CH3
H2C"CHC(O)N(CH3)2
188.18
34, 1825
1.160
99.13
43, 130
0.962
(CH3)2C"CHCO2H
100.12
2, 432
Melting
point,⬚C
33
1.473020
Boiling
point,⬚C
Flash
point,⬚C
9819mm
86
13412mm
⬎110
8120mm
71
69
195
⫺21
126–127
⫺18
⫺92.2
6.9
138
20
36
17617mm
(CH3)2AlCl
92.51
43, 1971
0.996
(CH3)2NH2
(CH3)2NCH2CN
45.08
84.12
4, 39
4, 346
0.68004
0.863
(CH3)2NC6H4CHO
149.19
14, 31
74
(CH3)2NC6H4CO2H
165.19
14, 392
148–152
(CH3)2NC6H4CO2H
165.19
14, 426
241 dec
(CH3)2NCH2CH2OH
89.14
4, 276
0.887620
4
1.429420
135
40
133.19
42, 719
0.954
1.442020
9515mm
92
143.19
43, 649
0.943
1.428020
6412mm
58
1.014
1.507720
15920mm
⬎110
0.933
1.440020
182–192
70
(CH3)2NCH2CH2OCH2CH2OH
H2C"CHCO2CH2CH2N(CH3)2
C6H5CO2CH2CH2N(CH3)2
H2C"C(CH3)CO2CH2CH2N(CH3)2
193.26
157.22
43, 649
1.35017
1.410120
Solubility in 100
parts solvent
v s aq; s alc, eth
s alc, chl, eth, HOAc
s alc; sl s eth
misc aq, alc, eth
INTERACTIVE
d529
Formula
ROTATED
Name
LEFT
No.
d545
d546
d547
d548
d549
d550
d551
d552
1.193
d553
d554
d555
d556
d557
d558
d559
d560
3-Dimethylaminophenol
3-Dimethylamino-1,2propanediol
1-Dimethylamino-2propanol
3-Dimethylamino-1propanol
3-(Dimethylamino)propionitrile
3-Dimethylaminopropylamine
N-[3-(Dimethylamino)propyl]methacrylamide
4-(Dimethylamino)pyridine
Dimethyl 2-amino-1,4phthalate
N,N-Dimethylaniline
2,3-Dimethylaniline
2,4-Dimethylaniline
2,5-Dimethylaniline
2,6-Dimethylaniline
3,4-Dimethylaniline
3,5-Dimethylaniline
Dimethylarsinic acid
137.18
13, 405
1.589525
(CH3)2NCH2CH(OH)CH2OH
119.16
4, 302
1.004
1.460920
216–217
105
0.837
20
1.4193
121–127
35
163–164
36
171750mm
62
82–84
265–268
v s alc, bz, eth, acet
CH3CH(OH)CH2N(CH3)2
103.17
(CH3)2NCH2CH2OH
103.17
41, 433
0.872
1.436020
(CH3)2NCH2CH2CN
98.15
43, 1265
0.870
1.425820
(CH3)2N(CH2)3NH2
102.18
43, 554
0.812
1.4350
133
15
H2C"C(CH3)CONH(CH2)3N(CH3)2
170.26
0.940
1.479020
1342mm
⬎110
(CH3)2N(C5H4N)
122.17
222, 341
112–114
H2NC6H3(CO2CH3)2
209.20
14, 559
127–130
C6H5N(CH3)2
(CH3)2C6H3NH2
(CH3)2C6H3NH2
(CH3)2C6H3NH2
(CH3)2C6H3NH2
(CH3)2C6H3NH2
(CH3)2C6H3NH2
(CH3)2As(O)OH
121.18
121.18
121.18
121.18
121.18
121.18
121.18
138.00
12, 141
12, 1101
12, 1111
12, 1135
12, 1107
12, 1103
12, 1131
4, 610
0.955920
4
0.993320
0.972320
0.979021
4
0.984220
18
1.076
0.970620
1.558420
1.568520
1.5568620
1.559220
1.560120
1.557820
Dimethylaminoacetaldehyde diethyl acetal, d300
Dimethyl 2-amino-1,4-benzenedicarboxylate, d552
Dimethyl 2-aminoterephthalate, d552
⫺43
2.5
⬍ ⫺15
⫺14.3
15.5
11.2
51
9.8
195–196
s aq, alc, chl, eth
v s aq, alc, bz, chl
194.2
221–222
214
214
215
228
220.5
63
97
90
93
96
98
93
v s alc, chl, eth
sl s aq; s alc, eth
s alc, bz, eth
sl s aq; s alc, eth
sl s aq; s alc, eth
sl s aq; s alc
sl s aq; s alc
v s alc; 200 aq; i eth
N,N-Dimethylaminotrimethylsilane, d707
Dimethylanisole, d631, d632
2,4-Dimethyl-3-azapentane, d468
RIGHT
ROTATED
cis-2,3-Dimethylacrylic acid, m168
trans-2,3-Dimethylacrylic acid, m169
3,3-Dimethylacrylic acid, m170
Dimethyl adipate, d617
(CH3)2NC6H4OH
DEAN 37261 (McGHP)
d544
INTERACTIVE
d561
1,3-Dimethylbarbituric
acid
N,N-Dimethylbenzamide
3,4-Dimethylbenzoic
acid
2,5-Dimethylbenzonitrile
N,N-Dimethylbenzylamine
2,3-Dimethyl-1,3butadiene
2,2-Dimethylbutane
2,3-Dimethylbutane
2,3-Dimethyl-2,3butanediol
2,3-Dimethyl-2-butanol
3,3-Dimethyl-1-butanol
3,3-Dimethyl-2-butanol
3,3-Dimethyl-2butanone
2,3-Dimethyl-1-butene
2,3-Dimethyl-2-butene
3,3-Dimethyl-1-butene
N,N-Dimethylbutylamine
2,2-Dimethylbutyric
acid
3,3-Dimethylbutyric
acid
Dimethylcadmium
d562
d563
d564
d565
d566
1.194
d567
d568
d569
d570
d570a
d571
d572
d572a
d573
d574
d575
d576
d577
d578
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
156.14
24, 471
124–126
C6H5CON(CH3)2
149.19
9, 201
43–45
13315mm
(CH3)2C6H3CO2H
150.18
92, 353
165–167
subl
(CH3)2C6H3CN
131.18
9, 535
0.957
1.528420
13–14
223730mm
92
C6H5CH2N(CH3)2
135.21
12, 1019
0.900
1.501120
⫺75
183
54
Solubility in 100
parts solvent
⬎110
s alc, bz
H2C"C(CH3)C(CH3)"CH2
82.15
13, 991
0.722225
4
1.436225
⫺76.0
69.2
⫺22
CH3CH2C(CH3)3
(CH3)2CHCH(CH3)2
(CH3)2C(OH)C(OH)(CH3)2
86.18
86.18
86.18
1, 150
1, 151
1, 487
0.649220
0.661620
1.368820
1.375020
⫺99.9
⫺128.5
41.1
49.7
58.0
174.4
⫺48
⫺29
77
v s hot aq, alc, eth
(CH3)2CHC(CH3)2OH
(CH3)3CCH2CH2OH
(CH3)3CCH(OH)CH3
(CH3)3CCOCH3
102.18
102.18
102.18
100.16
1, 413
13, 1677
1, 412
1, 694
0.823620
4
0.82420
0.818520
4
0.725025
25
1.417620
1.417620
1.415120
1.393925
⫺14
⫺60
5.6
⫺52.5
118
143
120
106
29
47
28
23
(CH3)2CHC(CH3)"CH2
(CH3)2C"C(CH3)2
(CH3)3CCH"CH2
CH3(CH2)3N(CH3)2
84.16
84.16
84.16
101.19
13, 816
1, 218
1.217
4, 1, 371
0.680
0.708120
4
0.653120
4
0.721
1.389020
1.412420
1.376220
1.398020
⫺157
⫺75
⫺115
55.6
73
41
93750mm
⫺18
⫺16
⫺28
⫺3
C2H5C(CH3)2CO2H
116.16
2, 335
0.928
1.415420
965mm
79
(CH3)3CCH2CO2H
116.16
2, 337
0.912420
4
1.410020
6–7
190
88
s alc, eth
(CH3)2Cd
142.48
1.984617
4
1.5488
⫺4.5
105.5
⬎150
explodes
dec aq; s PE
s aq; misc alc, eth
s alc; misc eth
2.5 aq; s alc, eth
s alc, eth
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
INTERACTIVE
d580
d581
d582
d583
d584
d584a
d585
d586
d587
1.195
d587a
d588
d589
Dimethylcarbamyl
chloride
Dimethyl carbonate
Dimethyl chloromalonate
Dimethyl chlorothiophosphate
Dimethylcyanamide
Dimethyl N-cyanothioiminocarbonate
1,1-Dimethylcyclohexane
cis-1,2-Dimethylcyclohexane
trans-1,2-Dimethylcyclohexane
cis-1,3-Dimethylcyclohexane
trans-1,3-Dimethylcyclohexane
cis-1,4-Dimethylcyclohexane
5,5-Dimethyl-1,3cyclohexanedione
(CH3)2NCOCl
107.54
4, 73
1.168
1.454020
⫺33
168
68
(CH3O)2C"O
ClCH(CO2CH3)2
90.08
166.56
3, 4
2, 592
1.06517
4
1.305
1.368220
1.437020
0.5
90–91
10619mm
18
106
(CH3O)2P(S)Cl
160.56
11, 143
1.322
1.481920
6716mm
105
(CH3)2NCN
(CH3S)2C"NCN
70.09
146.23
4, 74
3, 220
0.867
1.410020
161–163
58
110
(CH3)2C6H10
112.22
5, 35
0.777
1.428020
⫺33
120
7
(CH3)2C6H10
112.22
5, 36
0.796320
1.433520
⫺49.9
129.7
16
i aq; s alc, bz
(CH3)2C6H10
112.22
5, 36
0.776020
1.427320
⫺90
123.4
11
i aq; s alc, bz
(CH3)2C6H10
112.22
5, 36
0.784
1.423020
⫺76
120
5
(CH3)2C6H10
112.22
52, 21
0.780
1.430520
⫺90
124.5
7
(CH3)2C6H10
112.22
52, 22
0.783
1.429720
⫺88
125
6
140.18
7, 559
dec 149
Dimethyl 1-butynedioate, d529
Dimethyl cellosolve, d505
Dimethylchlorosilane, c93
cis-2-Dimethylcrotonic acid, m168
trans-2-Dimethylcrotonic acid, m169
0.4 aq; s alc, bz
RIGHT
Dimethylbenzenes, x4, x5, x6
6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol, n106
Dimethyl cis-butenedioate, d628
46–50
i aq; misc alc, eth
DEAN 37261 (McGHP)
d579
ROTATED
d561
d589
INTERACTIVE
d590
2,3-Dimethylcyclohexanol
3,5-Dimethylcyclohexanol
2,6-Dimethylcyclohexanone
N,N-Dimethylcyclohexylamine
2,3-Dimethylcyclohexylamine
1,5-Dimethyl-1,5cyclooctadiene
Dimethyl 1,1-cyclopropanedicarboxylate
Dimethyl decanedioate
2,2-Dimethyl-1,3dioxane-4,6-dione
2,2-Dimethyl-1,3dioxolane-4-methanol
Dimethyl disulfide
Dimethyldithiocarbamic acid, Zn
salt
N,N-Dimethyldodecylamine
Dimethyl ether
d591
d592
d593
d594
d595
1.196
d596
d597
d598
d599
d600
d601
d602
d603
d604
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
0.934
1.465320
(CH3)2C6H9OH
128.22
(CH3)2C6H9OH
128.22
6, 18
0.892
1.4552
(CH3)2C6H8("O)
126.20
7, 23
0.925
C6H11N(CH3)2
127.23
(CH3)2C6H9NH2
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
65
11–12
186
73
1.446020
175
51
0.849
1.453520
159
42
127.23
0.835
1.459520
160
51
136.24
0.867
1.489620
7416mm
55
196–198
95
1445mm
145
i aq; s alc, eth
s aq, acet
188–189
80
misc aq, alc, bz, esters,
eth, PE, acetals
i aq; misc alc, eth
⬍ 0.2 alc, eth; ⬍ 0.5
acet, bz; 0.5
naphtha
C3H4(CO2CH3)2
158.16
91, 314
1.147
1.441020
CH3O2C(CH2)8CO2CH3
230.30
144.13
2, 719
0.98330
20
1.433528
132.16
19, 65
1.063
1.434020
CH3SSCH3
[(CH3)2NCS2]2Zn
94.20
305.80
1, 291
43, 149
1.062520
1.66
1.528920
⫺84.7
250–252
109.8
24
CH3(CH2)11N(CH3)2
213.41
43, 409
0.775
1.437520
⫺20
1123mm
⬎110
(CH3)2O
46.07
1, 281
0.66120
⫺141.5
⫺24.9
⫺41
C2H5N(CH3)2
73.14
4, 94
0.675
1.372020
⫺140
36–38
⫺36
C2H5NCH2CH2NH2
88.15
42, 690
0.803
1.426020
106
23
23
94–96
i aq; s alc, eth
35 aq(5 atm); 15 bz;
11.8 acet
INTERACTIVE
d605
N,N-Dimethylethylamine
N,N-Dimethylethylenediamine
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
d607
d608
d609
d610
d611
d612
d613
d613a
d614
1.197
d615
d616
d616a
d617
d618
N,N-Dimethylformamide
N,N-Dimethylformamide dimethyl
acetal
Dimethyl fumarate
2,5-Dimethylfuran
Dimethylglyoxime
2,4-Dimethyl-1,6heptadienal
2,4-Dimethyl-2,6heptadien-1-ol
2,6-Dimethyl-2,5heptadien-4-one
2,2-Dimethylheptane
Dimethyl heptanedioate
2,6-Dimethyl-4heptanol
2,6-Dimethyl-4heptanone
2,4-Dimethylhexane
Dimethyl hexanedioate
2,5-Dimethyl-2,5hexanediol
(CH3)2NCHO
0.944525
4
1.430520
0.897
1.397220
1.045106
0.900020
4
1.441420
138.21
0.870
140.23
73.10
(CH3)2NCH(OCH3)2
119.16
CH3O2CCH"CHCO2CH3
(CH3)2(C4H2O)
CH3C("NOH)C("NOH)CH3
H2C"CHCH2CH(CH3)CH"C(CH3)CHO
H2C"CHCH2CH(CH3)CH"C(CH3)CH2OH
(CH3)2C"CHC("O)CH"(CH3)2
(CH3)3C(CH2)4CH3
CH3O2C(CH2)5CO2CH3
144.13
96.13
116.12
4, 58
2, 741
17, 41
1, 772
153.0
57
103720mm
7
193
93
⫺1
1.466420
472mm
64
1.351
1.464020
8610mm
78
105
⫺62
240
misc aq, alc, bz, eth
sl s alc, eth
i aq; misc alc, eth
s alc, acet, eth, pyr
138.21
1, 751
0.88520
4
1.496821
28
198–199
79
sl s aq; s alc, eth
128.26
188.22
21, 281
0.710520
1.062520
4
1.401620
1.431420
⫺113
⫺21
132.7
12211mm
⬎110
s alc
178
66
⫺41.5
169.4
49
8
86–90
109.5
11210mm
214–215
10
107
126
(CH3)2CHCH2CH(OH)CH2CH(CH3)2
[(CH3)2CHCH2]2C"O
144.26
1, 425
0.809
1.423620
142.24
1, 710
0.80620
20
1.411420
C2H5CH(CH3)CH2CH(CH3)2
CH3O2C(CH2)4CO2CH3
[(CH3)2C(OH)CH2⫺]2
114.23
174.20
146.23
1, 162
1, 652
1, 492
0.696225
1.060020
4
1.392925
1.428520
N,N-Dimethylethanolamine, d539
(1,1-Dimethylethyl)benzene, b523
4-(1,1-Dimethylethyl)-4-methylbenzene, b602
4-(1,1-Dimethylethyl)phenol, b588
Dimethyl glutarate, d656
0.06 aq; misc alc, bz,
chl, eth
i aq; s alc, eth
RIGHT
Dimethyl diphenyl sulfone 4,4⬘-dicarboxylate, s29
Dimethyleneimine, e148
Dimethylene oxide, e146
⫺60.4
DEAN 37261 (McGHP)
d606
ROTATED
d595
d598
d599
INTERACTIVE
1.420920
126.20
12, 507
0.859
128.13
24, 289
(CH3)2NNH2
CH3NHNHCH3
60.10
60.10
4, 547
4, 547
0.79122
4
0.827420
4
1.407520
1.420920
(CH3O)2P(O)H
110.05
1, 285
1.20020
4
1.400920
96.13
114.15
23, 66
1.084
1.044
87.17
42, 630
CH3O2CCH"CHCO2CH3
CH3O2CCH2CO2CH3
(CH3)2Hg
(CH3)2C6H3OCH3
144.13
132.12
230.66
136.19
(CH3)2C6H3OCH3
(CH3)2CH(CH2)3CH(NH2)CH3
(CH3)2C(OH)C#CC(OH)(CH3)2
(CH3)2CHCH2C(CH3)(OH)C#CH
d622
1,5-Dimethylhexylamine
2,5-Dimethyl-3hexyne-2,5-diol
3,5-Dimethyl-1hexyn-3-ol
5,5-Dimethylhydantoin
d623
d624
1,1-Dimethylhydrazine
1,2-Dimethylhydrazine
d625
Dimethyl hydrogen
phosphonate
1,2-Dimethylimidazole
1,3-Dimethyl-2imidazolidinone
N,N-Dimethylisopropylamine
Dimethyl maleate
Dimethyl malonate
Dimethylmercury
3,4-Dimethyl-1methoxybenzene
3,5-Dimethyl-1methoxybenzene
Dimethyl methylmalonate
Dimethyl methylphosphonate
Dimethyl methylsuccinate
2,6-Dimethylmorpholine
d621
d626
d627
d628
d629
d630
d631
d632
d633
d634
d635
d636
d637
Beilstein
reference
129.25
Melting
point,⬚C
Boiling
point,⬚C
154–156
94–95
1.433520
Flash
point,⬚C
48
205–206
151
44
176–178
⫺58
Solubility in 100
parts solvent
170–171
1
flammable
29
1.472020
204
10817mm
92
80
0.715
1.390520
66
⫺9
2, 751
2, 572
4, 678
6, 481
1.160620
1.15420
4
3.187420
0.974414
4
1.442220
1.413520
1.545220
1.519814
202
180–181
92–94
200
113
90
5
8.7 aq
sl s aq; misc alc, eth
i aq; s alc, eth
i aq; s alc, bz, eth
136.19
6, 493
0.962715
4
1.510715
193
65
i aq; s alc, bz, eth
CH3CH(CO2CH3)2
146.14
2, 628
1.098
1.414020
176–177
76
(CH3O)2P(O)CH3
124.08
41, 572
1.145
1.413020
181
68
CH3O2CCH2CH(CH3)CO2CH3
160.17
23, 1696
1.076
1.420020
196
83
0.934620
1.447020
147
48
(CH3)2CHN(CH3)2
115.18
29–30
⫺19
⫺62
⫺43
⫺85
63.9
81
v s aq, alc, bz, chl, eth,
acet
misc aq, alc, eth, PE
misc aq, alc, eth, PE
s aq(hyd); misc alc,
acet, eth
misc aq, alc, bz
INTERACTIVE
d619
Formula
weight
ROTATED
0.767
142.20
Merck:
11, 6678
1, 501
Formula
LEFT
Refractive
index
Name
d620
1.198
Density,
g/mL
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
d646
1,2-Dimethylnaphthalene
1,2-Dimethyl-3-nitrobenzene
1,2-Dimethyl-4-nitrobenzene
1,3-Dimethyl-2-nitrobenzene
1,3-Dimethyl-4-nitrobenzene
N,N-Dimethyl-4nitrosoaniline
Dimethyl 2-nitro-1,4phthalate
cis-3,7-Dimethyl-2,6octadienal
trans-3,7-Dimethyl2,6-octadienal
3,7-Dimethyl-1-octanol
d647
3,7-Dimethyl-3-octanol
d638
d639
d640
d641
d642
d643
d644
d645
C10H6(CH3)2
156.23
51, 267
1.017920
1.616620
0.8
266.5
⬎110
(CH3)2C6H3NO2
151.17
5, 367
1.129
1.543420
7–9
245
107
i aq; s alc
29–31
143
⬎110
i aq; s alc
1.522020
14–16
225744mm
87
i aq; s alc
1.549720
2
237–239
107
s alc, bz, chl, eth
12, 677
86
flammable
solid
9, 826
72–75
(CH3)2C6H3NO2
151.17
5, 368
1.139
(CH3)2C6H3NO2
151.17
5, 378
1.112
(CH3)2C6H3NO2
151.17
5, 378
1.117
(CH3)2NC6H4NO
150.18
O2NC6H3⫺1,4-(CO2CH3)2
239.18
1.199
(CH3)2CH(CH2)3CH(CH3)CH2CH2OH
(CH3)2CH(CH2)3C(OH)(CH3)C2H5
Dimethyl isophthalate, d669
1,4a-Dimethyl-7-isopropyl-1,2,3,4,4a,9,10,10a-octahydro-1phenanthrenemethylamine, d24
20mm
i aq; s alc, eth
152.24
0.888820
4
1.489820
229
101
misc alc, eth, glyc
152.24
0.886920
4
1.486920
229
101
misc alc, eth, glyc
158.29
1, 426
0.840
1.435520
969mm
95
158.29
1, 426
0.826
1.433620
736mm
76
Dimethyl ketone, a26
2,2-Dimethyl-3-methoxyoxirane, m86
6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptane, p176
DEAN 37261 (McGHP)
d637a
2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane, c2
2,2-Dimethyl-3-methylenenorbornane, c2
6,6-Dimethyl-2-methylenenorpinene, p176
RIGHT
ROTATED
d622
d626
d627
d637
d644
d645
INTERACTIVE
0.811
1.542920
157.30
41, 386
0.765
1.424320
170.35
11, 263
C2H5CH(CH3)CH(CH3)2
(CH3)2CHCH2CH(CH3)2
CH3O2C(CH2)3CO2CH3
202.25
118.09
86.13
100.21
100.21
160.17
2, 693
2, 534
172, 21
12, 120
1, 158
2, 633
1.021020
4
1.14854
0.835
0.695120
4
0.672720
1.087620
1.432520
1.37980
1.3990
1.392020
1,381520
1.424420
(CH3)2CHCH(OH)CH(CH3)2
116.20
1, 417
0.82920
4
1.425420
(CH3)2CHC(O)CH(CH3)2
114.19
1, 703
0.806220
4
1.398620
(CH3)2C6H3OH
(CH3)2C6H3OH
(CH3)2C6H3OH
(CH3)2C6H3OH
(CH3)2C6H3OH
(CH3)2C6H3OH
(CH3)2NC6H4NH2
122.17
122.17
122.17
122.17
122.17
122.17
136.20
6, 480
6, 486
6, 494
6, 485
6, 480
6, 492
13, 72
1.542020
1.542014
175.23
274, 1114
136.24
C2H5C(CH3)(OH)C#CC(CH3)(OH)C2H5
CH3O2C(CH2)6CO2CH3
CH3O2CCO2CH3
d669
d670
Dimethyl 1,3-phthalate
Dimethyl 1,4-phthalate
d650
d651
d652
d653
d654
d655
d656
d657
d658
d659
d660
d661
d662
d663
d664
d665
d666
d667
1.027614
4
0.96580
0.983020
0.968020
1.025
C6H5CH2C(CH3)2CH2OH
164.25
C6H4(CO2CH3)2
194.19
9, 797
1.190520
C6H4(CO2CH3)2
C6H4(CO2CH3)2
194.19
194.19
9, 834
9, 843
1.19420
4
1.532220
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
7514mm
68
⫺57
195
65
53–55
214680mm
⬎110
⫺4.8
50–54
268
163.5
81
89.8
80.4
214
75
⫺9
⬍⫺7
⫺12
102
i aq; s alc, eth
140
37
sl s aq; s alc, eth
⫺69
125
15
72.8
24.5
74.5
45.7
60.8
64
36
217
211
211.5
201
227
222
262
20–24
12420mm
102
15mm
⫺120
⫺42.5
⬎110
73
90
35
126
109
1.513820
5.5
283.7
146
1.516820
67–68
140–142
282
288
i aq; s alc
6 aq; s alc, eth
v s alc, eth
v s alc, bz, chl, eth
v s alc, bz, chl, eth
v s alc, bz, chl, eth
v s alc, bz, chl, eth
v s alc, bz, chl, eth
v s alc, bz, chl, eth
v s aq; s alc
0.4 aq; misc alc, chl,
eth; i PE
i aq
0.3 hot aq; s hot alc; s
eth
INTERACTIVE
CH3CH"C(CH3)CH"CHCH"C(CH3)2
CH3(CH2)7N(CH3)2
d668
2,6-Dimethyl-2,4,6octatriene
N,N-Dimethyloctylamine
3,6-Dimethyl-4octyne-3,6-diol
Dimethyl octanedioate
Dimethyl oxalate
3,3-Dimethyloxetane
2,3-Dimethylpentane
2,4-Dimethylpentane
Dimethyl pentanedioate
2,4-Dimethyl-3pentanol
2,4-Dimethyl-3pentanone
2,3-Dimethylphenol
2,4-Dimethylphenol
2,5-Dimethylphenol
2,6-Dimethylphenol
3,4-Dimethylphenol
3,5-Dimethylphenol
N,N-Dimethyl-1,4phenylenediamine
4,4-Dimethyl-2phenyl-2-oxazoline
2,2-Dimethyl-3phenyl-1-propanol
Dimethyl 1,2-phthalate
Melting
point,⬚C
ROTATED
13, 1050
d648
Beilstein
reference
LEFT
Refractive
index
Name
d649
1.200
Density,
g/mL
Formula
Formula
weight
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
d672
d673
d674
d675
d676
d677
d678
d679
1.201
d680
d681
d682
1,4-Dimethylpiperazine
cis-2,6-Dimethylpiperidine
2,2-Dimethylpropane
2,2-Dimethyl-1,3propanediamine
2,2-Dimethyl-1,3propanediol
2,2-Dimethyl-1propanol
2,2-Dimethylpropionaldehyde
N,N-Dimethylpropionamide
2,2-Dimethylpropionic
acid
2,2-Dimethylpropionic
anhydride
2,2-Dimethylpropionyl
chloride
1,1-Dimethylpropylamine
(CH3)4C
114.19
23, 7
0.844
1.446320
132750mm
18
113.20
20, 108
0.840
1.439420
127
11
72.15
0.613
1.3476
⫺16.6
9.5
⫺65
0.851
1.456620
31
154
47
0
6
H2NCH2C(CH3)2CH2NH2
102.18
Merck:
12, 6545
43, 595
(CH3)2C(CH2OH)2
104.15
1, 483
1.1125
127–128
208–210
107
88.15
1, 406
0.81220
4
52.5
113.1
36
(CH3)3CCH2OH
180 aq; 12 bz; 60 acet;
v s alc, eth
3.6 aq; misc alc, eth
0.793
1.379420
6
74730mm
⬍1
43, 126
0.920
1.440020
⫺45
175
62
102.13
2, 319
0.90550
1.393137
35.5
163.8
63
[(CH3)3DD(O)]2O
186.25
2, 320
0.918
1.409220
193
57
(CH3)3CC(O)Cl
120.58
2, 320
0.979
1.412020
105–106
⬍1
dec aq, alc; v s eth
87.17
4, 179
0.73125
4
1.399620
77
65
misc aq, alc, eth
(CH3)3CCHO
186.25
C2H5C(O)N(CH3)2
101.15
(CH3)3CCO2H
CH3CH2C(CH3)2NH2
1,5-Dimethyl-2-phenyl-4-aminopyrazolone, a110
2,3-Dimethyl-1-phenyl-3-pyrazolin-5-one, a299
Dimethyl phosphite, d625
Dimethyl pimelate, d617
Dimethyl propanedioate, d630
1,1-Dimethylpropargylamine, d683
2.5 aq; v s alc, eth
RIGHT
3,7-Dimethyl-6-octen-1-ol, c275
Dimethylolpropionic acid, b201
Dimethyl 3-oxoglutarate, d325
⫺105
DEAN 37261 (McGHP)
d671
ROTATED
d653
d666
d671
d672
INTERACTIVE
No.
d683
d684
d685
d686
d687
d688
d689
d690
d691
d692
1.202
d693
d702
d703
d704
HC#CC(CH3)2NH2
Dimethyl sulfide
Dimethyl sulfite
Dimethyl sulfone
Dimethyl sulfoxide
Dimethyl-d6 sulfoxide
(⫹)-Dimethyl Ltartrate
Dimethyltelluride
2,5-Dimethyltetrahydrofuran
1,3-Dimethyl-3,4,5,6tetrahydro-2(1H)pyrimidinone
Dimethyl 3,3⬘-dithiopropionate
N,N-Dimethylthioformamide
N,N⬘-Dimethylthiourea
Beilstein
reference
83.13
Density,
g/mL
Refractive
index
0.790
1.423520
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
79–80
2
108
⫺15
⬍ ⫺64
⫺6.0
⫺12
⫺9
218
163
158.3
144
164
170
465mm
50
37
33
53
53
80
Solubility in 100
parts solvent
(CH3)2(C5H3N)
(CH3)2(C5H3N)
(CH3)2(C5H3N)
(CH3)2(C5H3N)
(CH3)2(C5H3N)
O(CO2CH3)2
96.13
107.16
107.16
107.16
107.16
107.16
134.09
23, 74
20, 243
20, 244
20, 244
20, 246
20, 246
34, 17
0.945
0.930920
0.922620
0.95425
4
0.93925
4
1.250
1.5080
1.501020
1.495620
1.510025
1.503325
1.393320
CH3O2CCH2CH2CO2CH3
(CH3)2NSO2Cl
146.14
143.59
2, 609
4, 84
1.119820
1.337
1.419020
1.451820
19
196.4
11475mm
85
94
0.83 aq; 2.9 alc
(CH3O)2SO2
126.13
1, 283
1.332220
4
1.387420
⫺31.8
188 dec
83
(CH3)2S
(CH3O)2SO
(CH3)2SO2
(CH3)2SO
(CD3)2SO
CH3O2CH(OH)CH(OH)CO2CH3
(CH3)2Te
(CH3)2(C4H2O)
62.13
110.13
94.13
78.13
84.18
178.14
1, 288
1, 282
1, 289
1, 289
14, 1279
3, 510
0.848320
1.294
1.443820
1.408320
⫺98.3
1.10120
4
1.190
1.32820
4
1.417020
1.475820
37.3
126–127
238
189.0
555mm
16323mm
⫺36
30
143
95
95
⬎110
2.8 aq(hyd); s acet, bz,
dioxane, eth
2 aq; s alc, eth
157.68
100.16
1, 291
17, 14
0.833
1.4041
91–92
90–92
26
128.18
243, 32
1.060
1.488020
14644mm
⬎110
1.198
1.474020
14818mm
⬎110
1.047
1.575720
581mm
99
(CH3O2CCH2CH2)2S
206.26
(CH3)2NC(S)H
89.16
4, 70
(CH3NH)2C"S
104.18
4, 70
109
18.5
48–50
⫺10
60–62
s aq; v s bz, eth
17 aq; v s alc, bz, eth
43 aq45; s alc, eth
sl s aq; s alc, eth
s aq, alc, eth
v s aq, alc, acet
s alc, acet, bz, chl
s aq; 200 alc15; v s bz
dec aq; v s alc; i eth
v s aq, alc, acet
INTERACTIVE
d705
1,1-Dimethyl-2propynylamine
3,5-Dimethylpyrazole
2,3-Dimethylpyridine
2,4-Dimethylpyridine
2,6-Dimethylpyridine
3,4-Dimethylpyridine
3,5-Dimethylpyridine
Dimethyl pyrocarbonate
Dimethyl succinate
Dimethylsulfamoyl
chloride
Dimethyl sulfate
Formula
weight
ROTATED
d700
d701
Formula
LEFT
d694
d695
d696
d697
d698
d699
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
1.545820
211
83
0.732
1.397020
84
⫺19
⫺1
CH3C6H4N(CH3)2
135.21
(CH3)3SiN(CH3)2
117.27
d708
d709
(CH3NH)2C"O
(CH3)2Zn
88.11
95.45
d710
d711
2,4-Dinitroaniline
1,3-Dinitrobenzene
(O2N)2C6H3NH2
C6H4(NO2)2
183.12
168.11
4, 65
Merck:
12, 3312
12, 747
5, 258
d712
2,4-Dinitrobenzenesulfenyl chloride
3,5-Dinitrobenzoic
acid
3,5-Dinitrobenzoyl
chloride
2,6-Dinitro-p-cresol
4,6-Dinitro-o-cresol
2,4-Dinitrodiphenylamine
2,4-Dinitro-1-fluorobenzene
1,5-Dinitronaphthalene
(O2N)2C6H3SCl
234.62
62, 316
96
(O2N)2C6H3CO2H
212.12
9, 413
205–207
(O2N)2C6H3COCl
230.56
9, 414
69–71
(O2N)2C6H2(OH)CH3
(O2N)2C6H2(OH)CH3
(O2N)2C6H3NHC6H5
198.13
198.13
259.22
6, 414
6, 368
12, 751
77–79
83–87
159–161
FC6H3(NO2)2
186.10
5, 262
C10H6(NO2)2
218.17
5, 558
d707
d713
d714
1.203
d715
d716
d717
d718
d719
0.724
101–104
⫺40
268–270
46
1.61514
1.368
176–178
89–90
297
1.569020
1.482
Dimethyl suberate, d651
Dimethyl terephthalate, d670
v s aq, alc; i eth
misc bz, PE; s eth
i aq; 0.75 alc
0.05 aq; 2.7 alc; v s
bz, chl, EtOAc
s bz, HOAc; dec alc
1.9 hot aq; v s alc; sl s
bz, eth
dec aq, alc; s eth
19611mm
v s alc, acet, eth, alk
27–30
17825mm
216–217
subl
⬎110
s bz, eth, glyc
s bz; v s eth; sl s alc
2,4-Dinitrochlorobenzene, c114
3,4-Dinitrochlorobenzene, c115
RIGHT
1,3-Dimethyl-2,4,6(1H,3H,5H)pyrimidinetriol, d561
N⬘-(4,6-Dimethyl-2-pyrimidinyl)sulfanilamide, s22
Dimethyl sebacate, d597
12, 902
0.937
N,N-Dimethyl-ptoluidine
N,N-Dimethyltrimethylsilylamine
1,3-Dimethylurea
Dimethylzinc
DEAN 37261 (McGHP)
d706
ROTATED
d684
d702
INTERACTIVE
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Boiling
point,⬚C
Flash
point,⬚C
2,4-Dinitrophenol
(O2N)2C6H3OH
184.11
6, 251
d721
(O2N)2C6H3NHNH2
198.14
15, 489
ca. 200
(O2N)2C6H2(OH)CO2H
228.12
10, 122
169–172
s aq; v s alc, eth
CH3C6H3(NO2)2
CH3C6H3(NO2)2
C9H19O2C(CH2)4CO2C9H19
(C18H37O)2P(O)H
S[CH2CH2CO2(CH2)17CH3]2
182.14
182.14
398.63
586.97
683.18
5, 339
5, 341
(C8H17)2NH
(C8H17)2O
(C8H17)2S
H2N(CH2)3O(CH2)4O(CH2)3NH2
241.46
242.45
258.51
204.32
4, 196
1, 419
1, 419
0.799
0.806
0.842
0.962
1.443220
1.431820
1.461020
1.460920
14–16
⫺7.6
298
287
18010mm
1364mm
⬎110
⬎110
⬎110
⬎110
d732
d733
2,4-Dinitrophenylhydrazine
3,5-Dinitrosalicylic
acid
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Dinonyl hexanedioate
Dioctadecyl phosphite
Dioctadecyl 3,3⬘thiopropionate
Dioctylamine
Dioctyl ether
Dioctyl sulfide
4,9-Dioxa-1,12dodecanediamine
1,3-Dioxane
1,4-Dioxane
s alc, bz; 16 EtOAc;
36 acet; 5 chl; 20
pyr
sl s aq, alc; s acid
88.11
88.11
19, 2
19, 3
1.032
1.032920
4
1.418020
1.422420
⫺45
11.8
106
101.2
15
12
d734
d735
1,3-Dioxolane
Dipentaerythritol
74.08
254.28
192, 2
1.06020
4
1.400020
⫺95
215–218
78
2
d736
d737
d738
d739
Dipentene
Dipentylamine
Dipentyl ether
N,N-Diphenylacetamide
Diphenylacetic acid
Diphenylacetonitrile
Diphenylacetylene
Diphenylamine
136.24
157.29
158.29
211.26
5, 137
41, 378
11, 193
12, 247
0.840221
4
0.777
0.783320
4
1.473920
1.4272
1.412020
⫺95.5
(C5H11)2NH
(C5H11)2O
CH3CON(C6H5)2
⫺69.4
103
178
195–202
190
1300.02mm
45
52
57
(C6H5)2CHCO2H
(C6H5)2CHCN
C6H5C#CC6H5
(C6H5)2NH
212.25
193.25
178.23
169.23
9, 673
9, 674
5, 656
12, 174
1.25815
15
148
71–73
62.5
53
1955mm
18112mm
300
302
d723
d724
d725
d726
d727
1.204
d728
d729
d730
d731
1.442
1.479
67–70
64–66
300 sl d
1.2 alc; 9 eth
s alc
218
57–59
65–67
misc aq, alc, bz, chl,
eth, PE
misc aq; s alc, eth
i aq; misc alc
v s alc, eth
misc alc, eth; s acet
sl s aq; s alc, eth
ROTATED
s hot aq, alc, chl, eth
152
v s eth, hot alc
45 alc; v s bz, eth
INTERACTIVE
0.990
1.160
i aq; v s alc, eth
LEFT
d740
d741
d742
d743
(HOCH2)3CCH2OCH2C(CH2OH)3
1.32171
1.2833111
0.91725
25
106–108
Solubility in 100
parts solvent
d720
d722
1.683
Melting
point,⬚C
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
d745
d746
d747
d748
d749
d750
d751
d752
d753
d754
d755
5, 676
0.997422
4
cis,trans-1,4-Diphenyl1,3-butadiene
Diphenylcarbamoyl
chloride
1,5-Diphenylcarbohydrazide
Diphenyl carbonate
Diphenyl chlorophosphate
Diphenyl diselenide
Diphenyl disulfide
Diphenylenimine
C6H5CH"CHCH"CHC6H5
206.29
(C6H5)2NC(O)Cl
231.68
(C6H5NHNH)2C"O
242.28
15, 292
(C6H5O)2C"O
(C6H5O)2P(O)Cl
214.22
268.64
6, 158
6, 179
1.296
C6H5SeSeC6H5
C6H5SSC6H5
312.13
218.34
167.21
6, 346
6, 323
20, 433
1.55780
4
1.35320
4
18
1.104
1,2-Diphenylethane
Diphenyl ether
N,N⬘-Diphenylformamidine
1,3-Diphenylguanidine
C6H5CH2CH2C6H5
C6H5OC6H5
C6H5N"CHNHC6H5
182.27
170.21
196.25
5, 598
6, 146
12, 236
0.99520
4
1.066130
4
C6H5NHC("NH)NHC6H5
211.27
12, 369
1.13
149.7
350720mm
s alc; sl s eth
82–84
168–171
80–81
1.205
Diphenic acid, b141
Diphenolic acid, b205
Diphenyl, b138
Diphenylacetone, d767
Diphenylbenzenes, t7 thru t9
sym-Diphenylcarbazide, d746
Diphenyldiazene, a312
1,3-Dioxacyclohexane, d732
1,4-Dioxacyclohexane, d733
1,3-Dioxacyclopentane, d734
3,6-Dioxa-1,11-undecanediol, t430
(2,5-Dioxo-4-imidazolidinyl)urea, a71
1,3-Dioxolane-2-one, e132
Dipentyl ketone, u11
1.065322
1.550020
61–63
58–60
246
1.5338
1.576330
s hot alc, acet, HOAc
301–302
316272mm
s hot alc, bz, eth
⬎110
310
355
52.5
26.9
138–141
284
258
148–150
dec 170
⬎110
112
s hot alc
s alc, bz, eth; i aq
0.8 bz; 3 eth; 16 pyr;
11 acet; i aq
s alc; v s chl, eth
s alc, bz, eth, HOAc
s eth; v s chl
DEAN 37261 (McGHP)
d744
s alc, hot bz, chl
Diphenylenemethane, f2
Diphenylethanedione, b35
Diphenylethanedione dioxime, b36
1,2-Diphenylethene, s9
Diphenylethyne, d742
Diphenylglycolic acid, b37
Diphenylglyoxime, b36
RIGHT
ROTATED
d732
d733
d734
d736
d751
INTERACTIVE
5,5-Diphenylhydantoin
1,2-Diphenylhydrazine
Diphenylmercury
Diphenylmethane
Diphenylmethanol
d761
1,1-Diphenylmethylamine
2,5-Diphenyloxazole
Diphenyl phosphite
Diphenylphosphoryl
azide
Diphenyl o-phthalate
2,2-Diphenyl-1-picrylhydrazyl
1,3-Diphenyl-2propanone
2,2-Diphenylpropionic
acid
Diphenylsilanediol
Diphenyl sulfide
Diphenyl sulfone
Diphenyl sulfoxide
Diphenylthiocarbazone
1,3-Diphenyl-2-thiourea
1,3-Diphenylurea
Dipiperidinomethane
Dipropylamine
3-Dipropylamino-1,2propanediol
Dipropylene glycol
Dipropylene glycol
butyl ether
d762
d763
d764
1.206
d765
d766
d767
d768
d769
d770
d771
d772
d773
d774
d775
d776
d777
d778
d779
d780
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
C6H5NHNHC6H5
(C6H5)2Hg
C6H5CH2C6H5
C6H5CH(OH)C6H5
252.27
184.24
354.81
168.24
184.24
24, 410
15, 123
16, 946
52, 498
6, 678
1.15816
4
2.3184
1.006
1.576820
C6H5CH(NH2)C6H5
183.25
12, 1323
1.063522
4
1.595699
(C6H5O)2P(O)H
(C6H5O)2P(O)N3
221.26
234.19
275.20
27, 78
61, 94
1.223
1.277
1.557520
1.551820
C6H4(CO2C6H5)2
318.33
394.32
9, 801
162, 363
C6H5CH2(C"O)CH2C6H5
210.28
7, 445
CH3C(C6H5)2CO2H
226.28
92, 474
(C6H5)2Si(OH)2
(C6H5)2S
(C6H5)2SO2
(C6H5)2SO
C6H5N"NC(S)NHNHC6H5
C6H5NHC(S)NHC6H5
216.31
186.28
218.27
202.28
256.33
228.32
16, 909
6, 299
6, 300
6, 300
16, 26
12, 394
C6H5NHC(O)NHC6H5
212.35
182.31
101.19
175.27
12, 352
134.18
190.29
(C3H7)2NH
(C3H7)2NCH2CH(OH)CH2OH
HO(CH2)3O(CH2)3OH
CH3CH(OH)CH2OCH2CH(OC4H9)CH3
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
294–297
123–126
128–129
25
66.7
dec ⬎306
265
298
⬎110
34
295
⬎112
72–74
12
360
21926mm
1570.17mm
176
⬎110
Solubility in 100
parts solvent
i aq; 1.7 alc; 3.3 acet
v s alc; sl s bz
s chl; sl s hot alc
v s alc, bz, chl, eth
0.05 aq; v s alc, chl,
eth
sl s aq
74–76
127 dec
1.2
1.11815
15
1.632720
1.32
4, 138
43, 841
1.239
0.915
0.737520
4
0.949
1.482020
1.404320
1.455420
12, 537
1, 4, 2474
1.023
0.91725
25
1.441020
1.42525
32–34
330
i aq; v s alc, eth
175–177
300
s alc; v s bz, eth
140 dec
⫺40
128–129
69–71
168 dec
154
238
⫺63
296
379
20713mm
53
⬎110
misc bz, eth, CS2
i aq; s hot alc, bz
i aq; v s chl, CCl4
i aq; v s alc, eth
260 dec
12315mm
109.2
1439mm
91
17
⬎110
0.015 aq; s eth, HOAc
229
137
96
4 aq; v s alc, eth, PE
INTERACTIVE
d756
d757
d758
d759
d760
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
(CH3)3CO(CH2)3O(CH2)3OH
190.29
[C6H5CO2(CH2)3]2O
342.40
d786
d787
d788
d789
d790
Dipropylene glycol
tert-butyl ether
Dipropylene glycol
dibenzoate
Dipropylene glycol
isopropyl ether
Dipropylene glycol
methyl ether
Dipropylene glycol
acetate
Dipropyl ether
Dipropyl hexanedioate
Dipropyl sulfate
Dipropyl sulfone
2,2⬘-Dipyridyl
d791
Disilane
H3SiSiH3
d782
d783
d784
d785
CH3CH(OH)CH2OCH2CH[OCH(CH3)2]CH3
CH3CH(OH)CH2OCH2CH(OCH3)CH3
CH3CO2(CH2)3O(CH2)3OCH3
(C3H7)2O
C3H7O2C(CH2)4CO2C3H7
(C3H7O)2SO2
(C3H7)2SO2
1.424020
220–222
87
1.120
1.528020
2325mm
⬎110
80.1
90
188.3
74
200
85
⫺126.2
⫺20
dec 140
28–30
70–73
89.6
14410mm
12020mm
270
273
21
⫺132
⫺14.3
ignites in
air
25
25
25
176.2
0.878
1.421
148.2
0.95120
20
1.41920
190.24
0.970
1.418020
1, 354
22, 574
1, 354
1, 359
23, 199
0.746620
0.979020
4
1.10620
4
1.02850
4
1.380320
1.431420
Merck:
12, 3419
0.686⫺425
102.18
230.30
182.24
150.24
156.19
62.22
1.207
5,5-Diphenyl-2,4-imidazolidinedione, d756
Diphenyl ketone, b53
Diphenylmethanone, b53
1,1-Diphenylmethylamine, a159
Diphenyl oxide, d753
92, 108
0.900
Diphenylphosphorochloridate, d748
1,3-Diphenyl-1,3-propanedione, d68
sym-Diphenylthiourea, t141
Dipicolinic acid, p270
Di-2-propenylamine, d30
⫺117
0.4 aq
i aq; s alc, eth
v s PE
DEAN 37261 (McGHP)
d781
126
0.5 aq; v s alc, bz, chl,
eth, PE
s alc, bz, CS2
Dipropyl adipate, d787
Dipropylene glycol, b204
Dipropyl ketone, h16
Distearylpentaerythritol diphosphite, b217
Disulfram, t62
RIGHT
ROTATED
d756
d762
d766
d776
d790
INTERACTIVE
No.
Name
d792
d793
d794
1,3-Dithiane
4,4⬘-Dithiobutyric acid
3,3⬘-Dithiodipropionic
acid
Dithiooxamide
2,2⬘-Dithiosalicylic
acid
1,3-Di-o-tolylguanidine
Divinyl ether
d795
d796
d797
d798
d799
1.208
d800
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
HO2C(CH2)3SS(CH2)3CO2H
HO2C(CH2)2SS(CH2)2CO2H
120.24
238.32
210.27
3, 312
53–55
110
157–159
H2NC(S)C(S)NH2
S2(C6H4CO2H)2
120.20
306.36
2, 565
10, 129
245
287–290
(CH3C6H4NH)2C"NH
H2C"CHOCH"CH2
239.32
70.09
1.1020
4
0.77320
4
1.398920
176–178
⫺101
28.3
⬍ ⫺30
1,3-Divinyltetramethyldisiloxane
3,9-Divinyl-2,4,8,10tetraoxaspiro[5.5]undecane
Docasane
1-Docosanol
Dodecane
1,12-Dodecanediamine
Dodecanedioic acid
1,2-Dodecanediol
1,12-Dodecanediol
1-Dodecanethiol
Dodecanoic acid
[CH2 "CHSi(CH3)2]2O
186.39
12, 803
Merck: 12,
10133
4,4,4080
0.81120
4
1.411020
⫺99
139
24
212.25
193, 5679
1.251
43–46
1102mm
110
CH3(CH2)20CH3
CH3(CH2)21OH
CH3(CH2)10CH3
H2N(CH2)12NH2
HO2C(CH2)10CO2H
CH3(CH2)9CH(OH)CH2OH
HOCH2(CH2)10CH2OH
CH3(CH2)11SH
CH3(CH2)10CO2H
310.61
326.61
170.34
200.37
230.30
202.34
202.34
202.40
200.32
1, 174
1, 431
1, 171
4, 273
2, 729
13, 2237
12, 562
0.778245
1.435845
1.421620
369
18022mm
216.2
⬎110
0.749020
4
43–45
65–72
⫺10
71
128–130
58–60
81–84
1-Dodecanol
␦-Dodecanolactone
Dodecanoyl peroxide
1-Dodecene
2-Dodecen-1-ylsuccinic
anhydride
Dodecyl acetate
Dodecyl acrylate
CH3(CH2)11OH
186.34
198.31
398.63
168.32
266.38
228.38
240.39
[CH3(CH2)10CO]2O2
CH3(CH2)9CH"CH2
CH3CO2(CH2)11CH3
H2C"CHCO2(CH2)11CH3
0.84520
20
0.86914
1.458720
1.418382
1, 428
175,9,100
23, 893
1, 225
0.830825
4
0.942
1.441325
1.460220
0.758420
4
1.429420
2, 136
23, 1230
0.865
0.884
1.431820
1.445020
2, 359
43
24
⫺12
55–57
⫺35.2
41–43
Solubility in 100
parts solvent
90
sl s aq; s alc; i eth
s hot alc, eth
0.53 aq; misc alc, eth
i aq; sl s alc; v s eth
sl s eth; s alc, chl
74
155
24510mm
18912mm
266–283
225100mm
87
⬎110
259
1261mm
⬎110
⬎110
213.4
1805mm
79
177
15015mm
⬎110
⬎110
i aq; s alc, eth
i aq; 100 alc; v s bz,
eth; 40 PrOH
i aq; s alc, eth
s alc, eth, PE
INTERACTIVE
d815
d816
Beilstein
reference
ROTATED
d810
d811
d812
d813
d814
Formula
weight
LEFT
d801
d802
d803
d804
d805
d806
d807
d808
d809
Formula
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
CH3(CH2)10CHO
CH3(CH2)11NH2
H2C"C(CH3)CO2(CH2)11CH3
CH3(CH2)11SO3⫺ Na⫹
184.32
185.36
254.42
288.38
1, 714
4, 200
23, 1290
13, 1786
0.835
0.808
0.868
d821
d822
d823
d824
e1
Dodecyl aldehyde
Dodecylamine
Dodecyl methacrylate
Dodecyl sulfate,
sodium salt
Dodecyltrichlorosilane
Dodecyl vinyl ether
Dotriacontane
Dulcitol
Eicosane
CH3(CH2)11SiCl3
CH3(CH2)11OCH"CH2
CH3(CH2)30CH3
43, 1907
CH3(CH2)18CH3
303.8
212.38
450.88
182.17
282.56
e2
e3
1R,2S-(⫺)-Ephedrine
1,2-Epoxybutane
CH3NHCH(CH3)CH(OH)C6H5
H2C 9 CHCH2CH3
165.24
72.11
13, 636
172, 17
1.020
0.817
0.812420
4
1.4720
0.7823
(s)
1.124
0.829720
1,177
1, 544
1, 174
1.434420
1.446020
1.45820
1.438220
1.436470
1.385020
30–32
⫺7
204–207
185100mm
247–249
1424mm
1.209
DMSO, d697
Dodecyl alcohol, d810
Dodecyl iodide, i30
DPPH, d766
Durene, t99
EDTA, e134
Eicosane, i1
⬎110
⬎110
68–70
188–191
37
294
117–120
467
2801mm
343
39
⫺150
255
63
85
⫺22
sl s alc, bz, eth
3.3 aq; sl s alc
⬎110
s aq, alc, chl, eth
6 aq; misc alc, bz, chl,
eth
1-Eicosene, i2
Elaidic acid, o11
Enanthic alcohol, h11
Enanthylic acid, h9
Epibromohydrin, b328
Epichlorohydrine, c120
1,4-Epoxybutane, t69
d811
RIGHT
d800
d792
misc alc, bz, chl, eth
10 aq
O
2,3-Dithiabutane, d607
5,6-Dithiadecane, d146
3,4-Dithiahexane, d356
2,2⬘-Dithiodibenzoic acid, d796
2,2⬘-Dithiodiethanol, h123
Dithizone, d773
Divinylene oxide, f45
101
⬎110
⬎110
DEAN 37261 (McGHP)
d817
d818
d819
d820
ROTATED
d814
d824
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
e4
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
178.28
0.980
1.504520
182.31
0.939
1.477320
Melting
point,⬚C
Boiling
point,⬚C
831mm
Flash
point,⬚C
Solubility in 100
parts solvent
⬎110
e6
e7
1,2-Epoxy-5,9-cyclododecadiene
1,2-Epoxycyclododecane
1,2-Epoxycyclopentane
1,2-Epoxydecane
H2C 9 CHCH2(CH2)6CH3
84.12
156.27
17, 21
17, 18
0.964
0.840
1.433620
1.429020
102
9415mm
10
78
e8
1,2-Epoxydodecane
O
H2C 9 CHCH2(CH2)8CH3
184.32
173, 136
0.844
1.435520
12515mm
105
1,2-Epoxyethylbenzene
O
H2C 9 CHC6H5
120.15
17, 49
1.052316
4
1.533820
⫺37
194
79
1,2-Epoxyhexadecane
O
H2C 9 CHCH2(CH2)12CH3
240.43
17, 20
0.846
1.445220
21–22
18012mm
93
1,2-Epoxyhexane
O
H2C 9 CHCH2CH2CH2CH3
100.16
174, 86
0.831
1.405620
118–120
15
1,2-Epoxy-5-hexene
O
H2C 9 CHCH2CH2CH " CH2
98.15
173, 163
0.870
1.425220
121
15
1,2-Epoxyoctadecane
O
H2C 9 CHCH2(CH2)14CH3
268.49
173, 140
33–35
1370.5mm
⬎110
O
H2C 9 CHCH2OC6H5
150.18
17, 105
1.109
1.53020
3.5
245
⬎110
⫺112
35
⫺37
41 aq; misc alc, eth
misc aq
e5
e9
1.210
e10
e11
e13
e15
e16
1,2-Epoxypropane
O
H2C 9 CHCH3
58.08
17, 6
0.85904
1.366020
2,3-Epoxy-1-propanol
O
H2C 9 CHCH2OH
74.08
17, 104
1.114325
4
1.431520
662.5mm
81
2,3-Epoxypropylmethacrylate
O
H2C 9 CHCH2O2C(CH3)CH " CH2
O
1.042
1.449420
189
76
142.16
INTERACTIVE
e17
1,2-Epoxy-3-phenoxypropane
ROTATED
e14
i aq; s alc, eth
LEFT
e12
⬎110
1,2-Epoxy-3,3,3-trichloropropane
H2C 9 CHCCl3
161.42
172, 14
O
HOCH2[CH(OH)]2CH2OH
CH3CH3
122.12
30.07
1, 525
1, 80
e19
e20
meso-Erythritol
Ethane
e21
e21a
e22
H2NCH2CH2NH2
HOCH2CH2OH
CH3CO2CH2CH2O2CCH3
60.10
62.07
146.14
[H2C"C(CH3)CO2CH⫺2 ]2
HSCH2CH2SH
C2H5SO3H
CH3CH2SO2Cl
e26a
e27
e28
e29
1,2-Ethanediamine
1,2-Ethanediol
1,2-Ethanediol
diacetate
1,2-Ethanediol
dimethacrylate
1,2-Ethanedithiol
Ethanesulfonic acid
Ethanesulfonyl
chloride
Ethanethiol
Ethanol
Ethanol-d
Ethanolamine
e30
Ethoxyacetic acid
CH3CH2OCH2CO2H
e23
e24
e25
e26
1.211
CH3CH2SH
CH3CH2OH
CH3CH2OD
H2NCH2CH2OH
1.477820
4, 230
1, 465
2, 142
1.3560
g/L
0.897720
4
1.113520
4
1.104320
1.456820
1.431820
1.415020
198.22
23, 1292
1.051
1.454920
94.20
110.13
128.57
1, 471
4, 5
4, 6
1.12324
1.350
1.35722
1.558020
1.434020
1.433020
1, 340
1, 292
13, 1287
Merck:
12, 3712
3, 233
0.831525
0.789420
4
0.801
1.018020
1.42025
1.361120
1.359520
1.453920
1.102120
4
1.419020
62.13
46.07
47.08
61.08
104.11
Ethanedial, g28
1,2-Ethanediol, e135
Ethanediamide, o58
Ethanenitrile, a29
Ethanoic acid, a19
Ethanoic anhydride, a22
Ethanolamine, a164
151745mm
66
120–123
⫺182.8
329–331
⫺88
⫺135
4.7 mL aq; 46 mL alc4
11
⫺12.6
⫺31
117.3
197.3
190.2
33
110
82
misc aq, alc; i bz
misc aq, alc, glyc, pyr
misc alc, eth
1005mm
⬎110
146
1230.01mm
177
50
⬎110
83
v s alc, alk
35.0
78.3
78.8
170.8
⫺17
13
12
86
0.7 aq; s alc, eth
misc aq, alc, chl, eth
misc aq, alc, eth
misc aq, alc, acet
9711mm
97
s aq, alc, eth
⫺17
⫺147.9
⫺114
10.5
Ethanoyl bromide, a35
Ethanoyl chloride, a37
Ethene, e131
Ethenone, k1
Ethenyl acetate, v2
Ethenylbenzene, s11
dec aq, alc; v s eth
RIGHT
Epoxyethane, e147
1,2-Epoxy-1-methoxy-2-methylpropane, m86
1,2-Epoxypropane, p232
Estragole, a89
Ethanal, a4
Ethanamide, a6
Ethanamidine HCl, a7
1.495
DEAN 37261 (McGHP)
e18
ROTATED
e4
e5
e6
INTERACTIVE
No.
e31
e32
e33
e34
e35
e36
e37
e38
e39
e40
e41
1.212
e41a
e46
e47
e49
e50
e51
e52
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
C2H5OCH"CHCN
CH3CH2OC6H5NH2
CH3CH2OC6H4CHO
CH3CH2OC6H4CHO
CH3CH2OC6H4CONH2
CH3CH2OC6H5
CH3CH2OC6H4CO2H
CH3CH2OC6H4CO2H
CH3CH2OC("O)NCS
97.12
137.18
150.18
150.18
165.19
122.17
166.18
166.18
131.15
33, 681
13, 436
8, 43
8, 73
10, 93
6, 140
10, 64
10, 156
33, 279
0.944
1.065216
4
1.074
1.08025
25
1.454520
1.560920
1.5422
1.558420
0.96720
4
1.105
1.507420
1.540020
1.112
1.500020
CH3CH2OCH2CH2OH
C2H5OCH2CH2OCH2CH2OH
90.12
134.18
1, 467
12, 520
0.929520
0.984125
4
1.407520
1.425425
CH3CO2CH2CH2OCH2CH2OCH2CH3
CH3CO2CH2CH2OCH2CH3
H2C"CHCO2CH2CH2OC2H5
CH3CH2OCH2CH2NH2
H2C"C(CH3)CO2CH2CH2OC2H5
176.21
1.009620
132.16
144.17
89.14
158.20
22,
23,
42,
23,
0.974920
4
0.982
0.851220
4
0.964
C2H5OC6H3(OH)CHO
166.18
8, 256
76–78
C2H5OC6H3(OCH3)CHO
180.2
8, 256
51–53
C2H5OC6H4OCH3
152.19
6, 771
155
1232
718
1291
1.044
Flash
point,⬚C
9119mm
250
13624mm
255
81
115
107
⬎110
169.8
17415mm
63
⬎110
5618mm
50
⫺70
⫺76
134.8
196
43
96
1.421320
⫺25
218.5
110
1.402320
1.427020
1.410120
1.428520
⫺61.7
156.3
7823mm
107
9335mm
57
65
21
71
4
20
13–14
132–134
⫺29.5
19.4
197–199
1.524020
1
CH3CH2OCH"C(CN)2
122.13
3 , 162
C10H7OCH2CH3
C2H5OC6H4OH
C2H5OC6H3(CH"CHCH3)OH
172.23
138.17
178.23
6, 606
6, 771
62, 918
1.06020
4
1.090
1.604020
1.528820
99.14
3, 298
0.911
1.406520
C2H5OCH2CH2CN
Boiling
point,⬚C
Solubility in 100
parts solvent
i aq; s alc
misc alc, eth
v s alc, bz, eth
sl s aq; s alc, eth
v s alc, eth
sl s aq
sl s hot aq
misc aq, alc, acet, eth
misc aq, alc, bz, chl,
acet, pyr
29 aq; misc alc, eth
misc aq, alc, eth
s eth, glycols; 50 alc
⬎110
217–218
s alc, bz, chl, eth
90
12mm
64–66
160
5.5
29
86–88
280
217
⬎110
91
171–172
63
i aq; v s alc, eth
INTERACTIVE
e53
Formula
weight
ROTATED
e48
3-Ethoxyacrylonitrile
4-Ethoxyaniline
2-Ethoxybenzaldehyde
4-Ethoxybenzaldehyde
2-Ethoxybenzamide
Ethoxybenzene
2-Ethoxybenzoic acid
4-Ethoxybenzoic acid
Ethoxycarbonyl
isothiocyanate
2-Ethoxyethanol
2-(2-Ethoxyethoxy)ethanol
2-(2-Ethoxyethoxy)ethanol acetate
2-Ethoxyethyl acetate
2-Ethoxyethyl acrylate
2-Ethoxyethylamine
2-Ethoxyethyl
methacrylate
3-Ethoxy-4-hydroxybenzaldehyde
3-Ethoxy-4-methoxybenzaldehyde
1-Ethoxy-2-methoxybenzene
Ethoxymethylenemalononitrile
1-Ethoxynaphthalene
2-Ethoxyphenol
trans-2-Ethoxy-5-(1propenyl)phenyl
3-Ethoxypropionitrile
Formula
LEFT
e42
e43
e44
e45
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
e56
e57
e58
e59
e60
e61
e62
e63
e64
e65
e66
1.213
e67
e68
e69
e70
e71
e72
e73
3-Ethoxypropylamine
3-Ethoxysalicylaldehyde
Ethoxytrimethylsilane
Ethyl acetate
C2H5OCH2CH2CH2NH2
C2H5OC6H3(OH)CHO
103.17
166.18
43, 739
82, 267
0.861
(CH3)3SiOC2H5
CH3CO2C2H5
118.3
88.11
43, 1856
2, 125
0.757320
4
0.900620
4
1.374220
1.372420
Ethyl acetoacetate
p-Ethylacetophenone
Ethyl acrylate
Ethylaluminum
dichloride
Ethylaluminum
sesquichloride
Ethylamine
Ethyl 2-aminobenzoate
Ethyl 4-aminobenzoate
CH3COCH2CO2C2H5
C2H5C6H4COCH3
H2C"CHCO2C2H5
C2H5AlCl2
130.15
148.21
100.12
126.95
3, 632
74, 1101
2, 399
43, 1973
1.021325
4
0.993
0.923420
1.20750
1.417420
1.529320
1.406020
C2H5AlCl2 · ClAl(C2H5)2
247.51
C2H5NH2
H2NC6H4CO2C2H5
H2NC6H4CO2C2H5
45.09
165.19
165.19
4, 87
14, 319
14, 422
0.68915
15
1.08815
Ethyl 3-aminocrotonate
2-(Ethylamino)ethanol
N-Ethylaniline
2-Ethylaniline
4-Ethylaniline
2-Ethylanthraquinone
4-Ethylbenzaldehyde
Ethylbenzene-d10
CH3C(NH2)"CHCO2C2H5
129.16
3, 654
1.02120
4
CH3CH2NHCH2CH2OH
C6H5NHC2H5
CH3CH2C6H4NH2
CH3CH2C6H4NH2
89.14
121.18
121.18
121.18
236.27
134.18
116.25
4, 282
12, 159
122, 584
12, 1090
71, 425
7, 307
0.91420
4
0.95825
25
0.983
0.975
1.440220
1.555920
1.559020
1.554220
0.979
0.949
1.539020
1.492020
1.092
(Ethoxymethyl)benzene, b97
␣-Ethoxy-␣-phenylacetophenone, b47
3-Ethoxy-1-propene, a86
Ethylacetylene, b160a
1.366320
1.564020
136–138
264
32
66–68
⫺84
75–76
77
⫺18
⫺4
⫺45
⫺20.6
⫺71
32
180.8
11411mm
99
11350mm
57
90
10
⫺18
⫺50
204
⫺18
⫺81
13–15
88–90
16.6
266–268
310
⬍ ⫺18
⬎110
33–35
210–215
97
misc aq, alc, eth
i aq; s alc, eth
0.04 aq; 20 alc; 50 chl,
25 eth; s dil acid
i aq; s alc, bz, eth
⫺90
⫺63.5
⫺44
⫺5
108–111
170
203
210
216
71
85
91
85
v s aq, alc, eth
i aq; misc alc, eth
sl s aq; v s alc, eth
sl s aq; v s alc, eth
221
134.6
92
31
Ethyl alcohol, e27, e28
Ethylaldehyde, a4
Ethyl anthranilate, e64
Ethyl benzencarboxylate, e76
9.7 aq; misc alc, acet,
chl, eth
2.9 aq; misc alc, chl
1.5 aq; s alc, eth
RIGHT
ROTATED
4-Ethoxy-m-anisaldehyde, e48
1-Ethoxybutane, b554
Ethoxyethane, d365
2-Ethoxyethyl ether, b186
Ethoxyformic anhydride, d386
C2H5C6H4CHO
C6D5CD2CD3
1.417820
DEAN 37261 (McGHP)
e54
e55
e71
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
106.17
52, 274
0.867020
4
1.495920
e75
4-Ethylbenzenesulfonic acid
Ethyl benzoate
C2H5C6H4SO3H
186.23
11, 120
1.229
1.5331
C6H5CO2C2H5
150.18
9, 110
1.05115
1.500020
Ethyl benzoylacetate
Ethyl 3-benzoylacrylate
Ethyl 2-benzylacetoacetate
N-Ethylbenzylamine
Ethyl (2-benzyl)benzoylacetate
Ethyl N-benzyl-Ncyclopropylcarbamate
Ethyl bromoacetate
Ethyl 4-bromobenzoate
Ethyl 2-bromobutyrate
Ethyl 4-bromobutyrate
Ethyl 2-bromoheptanoate
Ethyl 6-bromohexanoate
Ethyl 2-bromoisobutyrate
Ethyl 2-bromooctanoate
Ethyl 3-bromo-2-oxopropionate
C6H5(C"O)CH2CO2C2H5
C6H5(C"O)CH"CHCO2C2H5
192.21
204.23
10, 674
102, 501
1.110
1.112
CH3C("O)CH(CH2C6H5)CO2C2H5
220.27
10, 710
C6H5CH2NHC2H5
C6H5C("O)CH(CH2C6H5)CO2C2H5
C6H5CH2N(C3H5)CO2C2H5
135.21
282.34
12, 1020
10, 764
BrCH2CO2CH2CH3
BrC6H4CO2C2H5
167.01
229.08
CH3CH2CH(Br)CO2C2H5
BrCH2CH2CH2CO2C2H5
CH3(CH2)3CH(Br)CO2C2H5
e76
e77
e78
e79
1.214
e80
e81
e82
e83
e84
e85
e86
e87
e88
e89
e90
e91
⫺95.0
136.2
22
0.01 aq; misc alc, bz,
chl, eth
⬎110
⫺34.7
212.4
84
1.533820
1.543520
265–270
18525mm
63
⬎110
1.036
1.499620
276
⬎110
0.909
1.110
1.511720
1.556720
194
27080mm
66
⬎110
0.997
1.510420
2, 214
9, 352
1.50620
20
1.403
1.451020
1.544020
195.06
195.06
237.14
22, 255
2, 283
2, 341
1.32920
20
1.363
1.211
Br(CH2)5CO2C2H5
223.12
23, 737
(CH3)2C(Br)CO2C2H5
195.06
CH3(CH2)5CH(Br)CO2C2H5
BrCH2C("O)CO2C2H5
219.28
Solubility in 100
parts solvent
0.05 aq; misc alc, chl,
bz, eth, PE
i aq; misc alc, eth
⬎110
⬍ ⫺20
159
13114mm
47
⬎110
i aq; misc alc, eth
1.447020
1.455920
1.452420
177 dec
8210mm
10910mm
58
90
104
i aq; misc alc, eth
1.254
1.459020
13016mm
⬎110
2, 296
1.32920
4
1.444620
6711mm
60
251.17
2, 349
1.167
1.452020
195.02
32, 409
1.554
1.469520
i aq; misc alc, eth
106
10010mm
98
INTERACTIVE
C6H5CH2CH3
Flash
point,⬚C
ROTATED
Ethylbenzene
Boiling
point,⬚C
LEFT
e74
Melting
point,⬚C
e95
e95a
e96
e97
e98
e99
e100
e101
Ethyl 2-bromopentanoate
Ethyl 2-bromopropionate
Ethyl 3-bromopropionate
2-Ethyl-1-butanol
2-Ethyl-1-butene
2-Ethylbutyl acetate
N-Ethylbutylamine
2-Ethylbutyraldehyde
Ethyl butyrate
2-Ethylbutyric acid
Ethyl butyrylacetate
e102
Ethyl carbamate
e103
e104
e105
e106
Ethyl carbazate
N-Ethylcarbazole
Ethyl chloroacetate
Ethyl 2-chloroacetoacetate
Ethyl 4-chloroacetoacetate
e93
e94
1.215
e107
CH3(CH2)2CH(Br)CO2C2H5
209.09
2, 302
1.116
1.448620
190–192
77
i aq; misc alc, eth
CH3CH(Br)CO2C2H5
181.03
2, 255
1.394
1.446020
156–160
51
i aq; misc alc, eth
136
79
i aq; misc alc, eth
146
65
160740mm
108
116.7
121
194
10422mm
58
⫺26
52
18
21
24
87
78
0.63 aq
49–50
182–184
92
200 aq; 125 alc; 111
chl; 67 eth
44–47
68–70
⫺21
11022mm
86
144
10714mm
65
50
i aq; misc alc, eth
i aq; s alc, eth
11514mm
96
i aq; misc alc, eth
18
4
18
BrCH2CH2CO2C2H5
181.03
2, 256
1.4123
1.4569
(C2H5)2CHCH2OH
(C2H5)2C"CH2
CH3CO2CH2CH(C2H5)2
CH3(CH2)3NHC2H5
(C2H5)2CHCHO
CH3CH2CH2CO2C2H5
(C2H5)2CHCO2H
CH3(CH2)2C("O)CH2CO2C2H5
H2NCO2C2H5
102.18
84.16
144.21
101.19
100.16
116.16
116.16
158.20
1, 412
12, 95
23, 257
4, 157
1, 693
2, 270
2, 333
3, 684
0.833020
0.689
0.876
0.74020
4
0.816220
20
0.87920
4
0.922520
20
1.001
1.422420
1.396020
1.410020
1.405020
1.401820
1.399820
1.413320
1.427020
3, 22
1.056
H2NNHCO2C2H5
ClCH2CO2C2H5
CH3C("O)CH(Cl)CO2C2H5
104.11
195.27
122.55
164.59
3, 98
20, 436
2, 197
3, 662
1.149820
4
1.190
1.422720
1.443020
ClCH2C("O)CH2CO2C2H5
164.59
3, 663
1.21817
4
1.452020
Ethyl bromopyruvate, e91
Ethyl bromovalerate, e92
Ethyl butanoate, e99
2-Ethylbutyl alcohol, e95
Ethyl butyl ether, b554
⬍ ⫺15
⫺131
⫺89
⫺98
⫺14
Ethyl butyl ketone, h15
Ethyl caprate, e120
Ethyl caproate, e160
Ethyl caprylate, e231
Ethyl chloride, c121
0.31 aq
0.49 aq; misc alc, eth
RIGHT
Ethyl 3-benzenepropenoate, e113
␣-Ethylbenzyl alcohol, p145
Ethyl benzyl ether, b97
Ethyl bromide, b329
Ethyl 2-bromo-2-methylpropanoate, e89
89.09
50mm
DEAN 37261 (McGHP)
e92
ROTATED
e104
INTERACTIVE
Ethyl 4-chlorobutyrate
Ethyl chloroformate
Ethyl 2-chloropropionate
Ethyl 3-chloropropionate
Ethyl
chrysanthemumate
Ethyl trans-cinnamate
Ethyl crotonate
Ethyl cyanoacetate
Ethyl 2-cyano-3,3diphenylacrylate
Ethylcyclohexane
4-Ethylcyclohexanol
Ethylcyclopentane
Ethyl cyclopropanecarboxylate
Ethyl decanoate
Ethyl diazoacetate
Ethyl 2,3-dibromopropionate
Ethyl dichlorophosphate
Ethyl dichlorothiophosphate
N-Ethyldiethanolamine
Ethyl 3,3-dimethylacrylate
Ethyl 4-dimethylaminobenzoate
Ethyl 2,2-dimethylpropionate
e111
e112
e113
e114
e115
e116
1.216
e117
e118
e118a
e119
e120
e121
e122
e123
e124
e125
e126
e127
e128
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
ClCH2CH2CH2CO2C2H5
ClCO2C2H5
CH3CH(Cl)CO2C2H5
150.61
108.52
136.58
2, 278
3, 10
2, 248
1.075420
4
1.140320
4
1.08720
4
1.430620
1.394120
1.418520
ClCH2CH2CO2C2H5
136.58
2, 250
1.108620
4
196.29
92, 45
C6H5CH"CHCO2C2H5
CH3CH"CHCO2C2H5
NCCH2CO2C2H5
(C6H5)2C"C(CN)CO2C2H5
176.22
114.14
113.12
277.33
C6H11CH2CH3
CH3CH2C6H10OH
C2H5(C5H9)
C3H5CO2CH2CH3
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
186
93
38
51
13
s alc, acet, eth
misc alc, bz, chl, eth
1.424920
162–163
54
misc alc, eth
0.906
1.460020
11210mm
84
92, 385
2, 411
2, 585
93, 4601
1.049520
4
0.917520
4
1.056425
4
1.559820
1.424020
1.417620
10
271
138
206
1740.2mm
⬎110
28
110
112.22
128.22
98.19
114.14
5, 35
62, 26
52, 19
9, 4
0.787920
0.889
0.763
0.960
1.433020
1.462520
1.419020
1.419720
⫺111
131.8
8410mm
103
129–133
35
77
15
18
CH3(CH2)8CO2C2H5
N2CH2CO2C2H5
BrCH2CH(Br)CO2C2H5
200.32
114.10
259.94
2, 356
31, 211
2, 259
0.86220
1.085218
4
1.78816
4
1.424820
1.458818
1.498620
245
141710mm
214
102
26
91
CH3CH2OP(O)Cl2
162.94
1, 332
1.373
1.433820
6510mm
⬎110
CH3CH2OP(S)Cl2
179.01
1, 353
1.353
1.504020
6810mm
⬎110
246–252
155
123
33
118.2
16
CH3CH2N(CH2CH2OH)2
(CH3)2C"CHCO2C2H5
133.19
128.17
4, 284
2, 433
(CH3)2NC6H4CO2C2H5
193.25
141, 571
(CH3)3CCO2C2H5
130.19
2, 320
1.014
0.924720
4
20
1.4665
1.435020
⫺81
146–149
⫺22
97–99
⫺138
⫺22
⫺50
misc alc, eth; i aq
i aq; s alc, eth
i aq; misc alc, eth
misc alc, chl, eth
misc alc, bz, eth
s alc, eth
64–66
0.858418
4
1.392218
s alc, eth
INTERACTIVE
e108
e109
e110
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
e130
e131
e132
e133
e134
e135
e136
e137
e138
1.217
e139
e140
Ethyl 3,5-dinitrobenzoate
5-Ethyl-1,3-dioxane5-methanol
Ethylene
Ethylene carbonate
Ethylenediamine
EthylenediamineN,N,N⬘,N⬘-tetraacetic acid
Ethylene glycol
Ethylene glycol bis(mercaptoacetate)
Ethylene glycol
diacetate
Ethylene glycol
diethyl ether
Ethylene glycol
diglycidyl ether
Ethylene glycol
dimethacrylate
240.17
9, 414
146.19
195,2,382
1.090
1, 180
1.147 g/L
88.06
60.10
292.24
19, 100
4, 230
43, 1187
1.321439
0.87920
HOCH2CH2OH
(HSCH2CO2CH2 9)2
62.07
210.27
1, 465
1.113
1.313
1.431020
1.521120
CH3CO2CH2CH2O2CCH3
146.14
2, 142
1.104320
1.415920
C2H5OCH2CH2OC2H5
118.18
1, 468
0.848420
(H2C 9 CHCH2OCH2⫺)2
174.20
1, 468
O
[H2C"C(CH3)CO2CH2⫺]2
198.22
23, 1292
H2C"CH2
28.05
H2NCH2CH2NH2
(HO2CCH2)2NCH2CH2N(CH2CO2H)2
94–95
1.463020
1.419940
1.456620
1055mm
⫺169.4
⫺104
36.4
11
250 dec
248
117
⬎110
143
40
0.05 aq
196–198
1392mm
⬎110
⬎110
⫺31
190
88
1.386020
⫺74
119
35
0.842
1.392320
⫺74
121
20
1.051
1.454920
1005mm
⬎110
Ethylene cyanohydrin, h173
Ethylene diacetate, e22
Ethylenediamine, e21
Ethylene dibromide, d97
Ethylene dichloride, d226
Ethylene diglyme, b186
(Ethylenedinitril)tetraacetic acid, e134
2,2⬘-Ethylenedioxybis(ethanol), t280
11 mL aq25; 200 alc25;
v s eth; s acet, bz
misc aq
Ethylene glycol, e21a
Ethylene glycol bis(thioglycolate), e136
Ethylene glycol tert-butyl ether, b494
Ethylene glycol tert-butyl methyl ether, b498
Ethylene glycol p-butylphenyl ether, b590
Ethylene glycol diacetate, e22
Ethylene glycol diethyl ether, d304
Ethylene glycol dimethacrylate, e23
RIGHT
Ethyl chloroglyoxylate, e232
Ethyl citrate, t278
Ethyl cyanide, p215
Ethyl 2-cyano-3-ethoxyacrylate, e150
N-Ethyldiisopropylamine, d477
Ethylene bromohydrin, b331
Ethylene chlorobromide, b303
Ethylene chlorohydrin, c122
(O2N)2C6H3CO2C2H5
DEAN 37261 (McGHP)
e129
ROTATED
e112
e130
e132
INTERACTIVE
No.
Name
e141
Ethylene glycol
dimethyl ether
Ethylene glycol
divinyl ether
Ethylene glycol methyl
ether acrylate
Ethylene glycol methyl
ether methacrylate
Ethylene glycol phenyl
ether acrylate
Ethyleneimine
e142
e143
e144
e145
e146
Formula
CH3OCH2CH2OCH3
1.379620
⫺58
Flash
point,⬚C
85
⫺2
Solubility in 100
parts solvent
1.218
125–127
27
H2C"CHCO2CH2CH2OCH3
130.14
23, 1232
1.012
1.427020
5612mm
60
H2C"C(CH3)CO2CH2CH2OCH3
144.17
23, 1291
0.993
1.431020
6512mm
60
H2C"CHCO2CH2CH2OC6H5
192.21
63, 572
1.104
1.518020
840.2mm
⬎110
0.832125
4
1.412325
⫺78
56
⫺11
misc aq; s alc
⫺111
10.6
⫺18
misc aq; s alc, eth
sl s alc, eth
17, 4
0.89104
1.35977
60.12
172, 12
1.010
1.493520
55–56
10
S
HOCH(OC2H5)CO2C2H5
148.16
3, 601
1.079
1.420020
137
49
C2H5OCH"C(CN)CO2C2H5
169.18
3, 470
19030mm
⬎110
C2H5OCH2CH2CO2C2H5
146.19
3, 298
166
52
C6H5N(C2H5)CH"N9C6H4CO2C2H5
296.37
FCH2CO2C2H5
HCO2C2H5
106.10
74.08
140.14
158.24
CH3(CH2)5CO2C2H5
2, 193
2, 19
18, 275
22, 295
51–53
0.949
1.092621
0.91720
4
1.11720
4
0.868520
4
1.405020
1.375520
1.359020
1.414415
62–65
2152mm
⫺80
35–37
⫺66
119
54
196
189
30
⫺20
70
66
s aq
10 aq; misc alc, eth
i aq; s alc, eth
s alc, eth
INTERACTIVE
44.05
ROTATED
43.07
LEFT
H2C 9 CH2
O
H2C 9 CH2
e153
e154
e155
e156
0.869120
Boiling
point,⬚C
1.435020
Ethylene sulfide
e152
1, 467
Melting
point,⬚C
0.914
e148
e151
Refractive
index
13, 2807
Ethylene oxide
e150
Density,
g/mL
114.14
e147
Ethyl 2-ethoxy-2hydroxyacetate
Ethyl (ethoxymethylene)cyanoacetate
Ethyl 3-ethoxypropionate
Ethyl 4-{[(ethylphenylamino)methylene]amino}benzoate
Ethyl fluoroacetate
Ethyl formate
Ethyl 2-furoate
Ethyl heptanoate
90.12
Beilstein
reference
H2C"CHOCH2CH2OCH"CH2
N
H
H2C 9 CH2
e149
Formula
weight
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Ethyl hexadecanoate
2-Ethylhexanaldehyde
3-Ethylhexane
2-Ethyl-1,3-hexanediol
e160
e161
e162
Ethyl hexanoate
2-Ethylhexanoic acid
2-Ethyl-1-hexanol
e163
2-Ethylhexanoyl
chloride
2-Ethylhexyl acetate
e164
e165
e166
e167
e168
1.219
e169
2-Ethylhexyl acrylate
2-Ethylhexylamine
2-Ethylhexyl chloroformate
2-Ethylhexyl cyanoacetate
2-Ethylhexyl 2-cyano3,3-diphenylacrylate
22, 336
1, 707
14, 431
Merck: 12,
3790
2, 323
2, 349
Merck: 12,
3854
22, 304
0.857725
4
0.822
0.713620
0.932522
4
1.434734
1.4155
1.401820
1.453022
22
⫺40
19110mm
5513.5mm
118.6
244
0.87120
4
0.9077
0.831925
1.407520
1.424120
1.430020
⫺67
⫺118.4
⫺70
166–168
228
184.6
49
127
73
0.939
1.433520
6811mm
69
Merck: 12,
6860
23, 1229
43, 388
34, 28
0.8718
1.420420
⫺80
199
71
0.885
0.789
0.981
1.4358
1.430020
1.431220
⫺76
214–219
169
10730mm
79
60
81
197.28
0.975
1.438020
15011mm
⬎110
361.49
1.051
1.567020
2181.5mm
⬎110
CH3(CH2)14CO2C2H5
CH3(CH2)3CH(C2H5)CHO
(C2H5)CHCH2CH2CH3
CH3(CH2)2CH(OH)CH(C2H5)CH2OH
CH3(CH2)4CO2C2H5
CH3(CH2)3CH(C2H5)CO2H
CH3(CH2)3CH(C2H5)CH2OH
144.21
144.21
130.23
CH3(CH2)3CH(C2H5)COCl
162.66
CH3(CH2)3CH(C2H5)CH2O2CCH3
H2C"CCO2CH(C2H5)(CH2)3CH3
CH3(CH2)3CH(C2H5)CH2NH2
CH3(CH2)3CH(C2H5)CH2O2CCl
172.27
NCCH2CO2CH2CH(C2H5)(CH2)3CH3
(C6H5)2C"C(CN)CO2CH2CH(C2H5)(CH2)3CH3
184.28
129.31
192.69
Ethylene glycol monomethyl ether acetate, m75
Ethylene iodide, d451
Ethylene iodohydrin, i32
1,8-Ethylenenaphthalene, a2
Ethylenethiourea, i4
Ethylene trichloride, t232
Ethyleneurea, i5
⫺10
s alc, eth
42
127
N-Ethylethanamine, d323
Ethyl 2-ethoxyglycolate, e149
Ethyl N-ethylcarbamate, e275
Ethyl fluoride, f17
2-Ethyl-1-hexanamine, e166
2-Ethylhexyl alcohol, e162
s alc, eth
0.6% (w/w) aq; s alc,
propylene glycol
i aq; misc alc, eth
0.25 aq
0.07 aq; s alc, bz, chl
0.03 aq; misc alc, oils,
org liquids
i aq; s alc, acet, eth
RIGHT
Ethylene glycol dimethyl ether, d505
Ethylene glycol ethyl ether acetate, e42
Ethylene glycol monoacetate, h120
Ethylene glycol monobutyl ether, b493
Ethylene glycol monobutyl ether acetate, b497
Ethylene glycol monoethyl ether, e40
Ethylene glycol monomethyl ether, m71
284.48
128.22
114.23
146.23
DEAN 37261 (McGHP)
e157
e158
e158a
e159
ROTATED
e155
INTERACTIVE
No.
e170
e171
e172
e173
e174
e175
1.220
e176
e177
e178
e180
e181
e183
e184
2-Ethylhexyl
methacrylate
2-Ethylhexyl nitrate
2-Ethylhexyl salicylate
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
(CH3)2NC6H4CO2CH2CH(C2H5)(CH2)3CH3
277.41
0.995
1.542020
325
⬎110
CH3(CH2)3CH(C2H5)CH2OCH2CH 9CH2
186.30
0.891
1.434020
610.3mm
96
O
H2C"C(CH3)CO2CH2CH(C2H5)(CH2)3CH3
CH3(CH2)3CH(C2H5)CH2ONO2
2-(HO)C6H4CO2CH2CH(C2H5)(CH2)3CH3
CH3(CH2)3CH(C2H5)CH2OCH"CH2
C6H5CH2CH2CO2C2H5
HO2C(CH2)4CO2C2H5
Solubility in 100
parts solvent
198.31
23, 1289
0.885
1.438120
12018mm
92
175.23
250.34
0.963
1.014
1.432020
1.502020
19021mm
75
⬎110
explodes when heated
103, 124
0.8102
1.427320
⫺85
177–178
52
0.01 aq
1.010
1.494020
1.438720
28–29
247–248
18018mm
107
⬎110
116–118
297–298
156.26
178.23
174.20
9, 511
21, 277
HOC6H4CO2C2H5
166.18
10, 159
CH3CH(OH)CH2CO2C2H5
132.16
3, 309
1.01720
4
1.420520
170
64
s aq, alc
HOCH2CH2SCH2CH3
106.19
12, 525
1.020
1.486920
180–184
⬎110
s eth
HO(CH2)5CO2C2H5
160.22
3,3,628
0.985
1.437020
12812mm
⬎110
(CH3)2C(OH)CO2C2H5
132.16
3, 315
0.965
1.407820
150
44
C2H5C(CH2OH)3
134.18
(H2C"CHCO2CH2)3CC2H5
296.32
3
1 , 2349
60–62
1.100
1.473620
0.07 aq; v s alc, eth
2mm
161
157
⬎110
dec by hot aq
INTERACTIVE
2-Ethylhexyl vinyl
ether
Ethyl hydrocinnamate
Ethyl hydrogen
hexanedioate
Ethyl 4-hydroxybenzoate
Ethyl 3-hydroxybutyrate
Ethyl 2-hydroxyethyl
sulfide
Ethyl 6-hydroxyhexanoate
Ethyl 2-hydroxyisobutyrate
2-Ethyl-2-(hydroxymethyl)-1,3propanediol
2-Ethyl-2-(hydroxymethyl)-1,3propanedioltriacrylate
Formula
weight
ROTATED
e182
2-Ethylhexyl 4-(dimethylamino)benzoate
2-Ethylhexyl glycidyl
ether
Formula
LEFT
e179
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
e186
e187
e188
e189
e190
1.221
e191
e192
e193
2-Ethyl-2-(hydroxymethyl)-1,3propanedioltrimethacrylate
N-Ethyl-3-hydroxypiperidine
2,2⬘-Ethylidenebis(4,6-di-tert-butylphenol)
2,2⬘-Ethylidenebis(4,6-di-tert-butylphenyl) fluorophosphite
4,4⬘-Ethylidenebisphenol
5-Ethylidene-2norborene
2-Ethylimidazole
Ethyl isobutyrate
Ethyl isothiocyanate
[H2C"C(CH3)CO2CH2]3CC2H5
338.40
129.20
CH3CH{C6H2[C(CH3)3]2OH}2
CH3CH2CH(C6H4OH)2
Merck: 12,
3890
0.970
1.475420
⬎110
9515mm
162–164
486.66
201–203
214.26
6, 1006
96.13
116.16
87.14
23, 78
2, 291
4, 123
47
123–127
0.893
1.4895
0.87020
1.00318
4
1.390320
1.514218
Ethylidene chloride, d225
Ethylidene dimethyl ether, d504
Ethylidene fluoride, d407
2,2⬘-Ethyliminodiethanol, e125
Ethyl iodide, i31
38
86
⫺88
⫺6
268
110
130–132
13
32
misc alc, eth; sl s aq
i aq; misc alc, eth
Ethyl isopentanoate, e208
Ethyl isonipicotate, e250
Ethyl isopropylactate, e208
Ethyl isothiocyanatoformate, e39
Ethyl isovalerate, e208
RIGHT
Ethyl hexyl ketone, n100
Ethyl hydrogen adipate, e177
N-Ethyl-N-(2-hydroxyethyl)-3-toluidine, e267
Ethyl 2-hydroxy-2-methylpropanoate, e182
Ethyl 2-hydroxypropionate, e194
Ethylidene bromide, d96
1.472420
438.70
120.20
(CH3)2CHCO2C2H5
CH3CH2NCS
1.060
DEAN 37261 (McGHP)
e185
ROTATED
e186
e188
e190
e191
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
118.13
3, 264
1.032820
1.412420
⫺26
154–155
46
e195
e196
Ethyl (⫾)-mandelate
Ethyl 2-mercaptoacetate
Ethyl 3-mercaptopropionate
Ethylmercury chloride
Ethyl methacrylate
Ethyl 4-methoxyphenylacetate
Ethyl 2-methylacetoacetate
N-Ethyl-2-methylallylamine
N-Ethyl-N-methylaniline
Ethyl 2-methylbenzoate
Ethyl 3-methylbenzoate
Ethyl 4-methylbenzoate
Ethyl 2-methylbutyrate
Ethyl 3-methylbutyrate
2-Ethyl-2-methyl-1,3dioxolane
Ethyl methyl ether
C6H5CH(OH)CO2C2H5
HSCH2CO2C2H5
180.21
120.17
10, 202
3, 255
1.115
1.0964
1.512020
1.457120
33–34
253–255
5412mm
⬎110
47
HSCH2CH2CO2C2H5
134.20
33, 555
1.039
1.457020
7610mm
72
CH3CH2HgCl
H2C"C(CH3)CO2C2H5
CH3OC6H4CO2C2H5
165.13
114.14
194.23
2, 423
101, 83
3.5
0.917
1.097
1.411625
1.507520
sublimes
118
1387mm
15
46
CH3C("O)CH(CH3)CO2C2H5
144.17
3, 679
1.019
1.428020
187
62
99.18
44, 1104
0.753
1.422120
105
7
C6H5N(CH3)C2H5
135.21
12, 162
0.947
1.547020
203–205
74
CH3C6H4CO2C2H5
164.21
9, 463
1.032
1.507020
221731mm
91
CH3C6H4CO2C2H5
164.21
9, 476
1.030
1.505420
11020mm
101
20
235
99
⫺99
133
135
116–117
26
26
12
⫺113
7.4
e197
1.222
e198
e199
e200
e201
e202
e203
e204
e205
e206
e207
e208
e209
e210
H2C"C(CH3)CH2NHC2H5
192
CH3C6H4CO2C2H5
164.21
9, 484
1.025
1.5085
CH3CH2CH(CH3)CO2C2H5
(CH3)2CHCH2CO2C2H5
130.19
130.19
116.16
2, 305
22, 275
192, 11
0.869
0.865620
0.929
1.396920
1.396220
1.409020
60.10
1, 314
2.456 g/L
C2H5OCH3
misc aq, alc, eth, esters, PE
s alc, eth
0.78 eth; 2.6 chl
i aq; s alc, eth
i aq; s alc, eth
i aq; misc alc, eth
0.2 aq; misc alc, bz
s aq; misc alc, eth
INTERACTIVE
CH3CH(OH)CO2C2H5
ROTATED
Ethyl (⫺)-lactate
LEFT
e194
Solubility in 100
parts solvent
e211
e212
e213
e214
e215
e216
e217
1.223
3-Ethyl-4-methylhexane
2-Ethyl-4-methylimidazole
Ethyl 4-methyl-5imidazolecarboxylate
4-Ethyl-2-methyl-2(3-methylbutyl)oxazolidine
3-Ethyl-2-methylpentane
3-Ethyl-3-methylpentane
Ethyl 1-methyl-2piperidinecarboxylate
Ethyl 1-methyl-3piperidinecarboxylate
(C2H5)2CHCH(CH3)C2H5
128.26
110.16
154.17
232, 72
114.24
(C2H5)3CCH3
114.24
171.24
0.975
1.500020
25 , 534
13, 489
221, 485
171.24
Ethyl levulinate, e236
Ethyl linoleate, e229
Ethyl mercaptan, e26a
1.413420
1
185.3
(C2H5)2CHCH(CH3)2
0.742020
47–54
140
24
292–295
137
194
82
⬍21
204–206
0.877
1.442020
0.719320
4
1.404020
⫺115.0
115.7
0.727420
1.407820
⫺90.9
118.3
0.975
1.451920
9611mm
73
0.954
1.451020
8911mm
68
Ethyl 3-methylcrotonate, e126
Ethyl methyl ketone, b475
Ethyl 1-methylnipecotate, e216
i aq; sl s alc; s eth
DEAN 37261 (McGHP)
e210a
i aq; s eth
Ethyl 2-methyl-4-oxo-2-cyclohexene-1-carboxylate, c7
Ethyl N-methyl-N-phenylcarbamate, m379
Ethyl 2-methylpipicolinate, e217
RIGHT
ROTATED
e209
e211
e212
e213
e216
e217
INTERACTIVE
Ethyl 3-methyl-1piperidine propionate
2-Ethyl-2-methyl-1,3propanediol
5-Ethyl-2-methylpyridine
Ethyl methyl sulfide
Ethyl (methylthio)acetate
N-Ethylmorpholine
Ethyl nitrate
Ethyl nitrite
4-Ethylnitrobenzene
Ethyl 4-nitrobenzoate
Ethyl nonanoate
Ethyl cis,cis-9,12-octadecadienoic acid
Ethyl cis-9-octadecenoate
Ethyl octanoate
Ethyl oxalyl chloride
Ethyl oxamate
2-Ethyl-2-oxazoline
Ethyl 2-oxocyclopentanecarboxylate
Ethyl 4-oxopentanoate
Ethyl 2-oxopropionate
3-Ethylpentane
Ethyl pentanoate
2-Ethylphenol
3-Ethylphenol
4-Ethylphenol
Ethyl phenylacetate
e219
e220
e221
e222
1.224
e223
e224
e225
e226
e227
e228
e229
e230
e231
e232
e233
e234
e235
e236
e237
e238
e239
e240
e241
e242
e243
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
0.945
1.453020
199.30
22, 59
HOCH2C(C2H5)(CH3)CH2OH
118.18
1, 487
C2H5(CH3)C5H3N
121.18
20, 248
0.919
1.497020
CH3CH2SCH3
CH3SCH2CO2C2H5
76.15
134.20
1, 343
0.842
1.043
1.439220
1.458720
115.18
91.13
75.07
151.17
195.17
186.30
308.51
271, 203
1, 329
1, 329
5, 358
9, 390
2, 353
22, 461
0.905
1.10025
4
0.9015
15
1.118
0.866
0.8846
1.421920
1.467520
310.53
2, 467
0.869
1.450020
2, 348
2, 541
2, 544
0.878
1.2223
1.4166
1.416420
(O")(C5H7)CO2C2H5
172.27
136.53
117.10
99.13
156.18
10, 597
0.982
1.054
1.437020
1.448520
CH3C("O)CH2CH2CO2C2H5
CH3C("O)CO2C2H5
(C2H5)3CH
CH3(CH2)3CO2C2H5
C2H5C6H4OH
C2H5C6H4OH
C2H5C6H4OH
C6H5CH2CO2C2H5
144.17
116.12
100.20
130.19
122.17
122.17
122.17
164.20
3, 675
3, 616
13, 441
2, 301
5, 470
6, 471
6, 472
9, 434
1.012
1.06016
4
0.698220
4
0.87720
4
1.037
1.001
1.011
1.031
1.422220
1.40816
1.393420
1.373220
1.537220
1.533020
1.5239
1.498020
CH3CH2ONO2
CH3CH2ONO
C2H5C6H4NO2
O2NC6H4CO2C2H5
CH3(CH2)7CO2C2H5
H(CH2)5CH"CHCH2CH"CH(CH2)7CO2C2H5
CH3(CH2)7CH"CH(CH2)7CO2C2H5
CH3(CH2)7CO2C2H5
CH3CH2OC("O)C("O)Cl
CH3CH2OC("O)C("O)NH2
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
11213mm
99
226
⬎110
178
66
s alc, bz, eth, acid
⫺106
66.7
7225mm
⫺15
59
i aq; misc alc, eth
1.441020
1.384922
⫺63
⫺94.6
1.544520
⫺32
55–59
⫺37
139
87.7
17
245–246
27
10 (CC)
⫺35
⬎110
misc aq, alc, eth
1 aq; misc alc, eth
misc alc, eth
v s alc, eth
227
1936mm
94
⬎110
i aq; misc alc, eth
misc DMF, oils
⫺32
21615mm
⬎110
i aq; misc alc, eth
⫺43
208
135
75
41
i aq; misc alc, eth
d aq, alc; s bz, eth
s aq, eth; i bz
128
10211mm
29
77
41–44
114–116
⫺62
⫺118.6
⫺91.3
⫺18
⫺4
45
205–206
144
93.5
145.5
204
11015mm
218
229
45
78
94
100
77
v s aq; misc alc
sl s aq; misc alc, eth
i aq; s alc, eth
0.2 aq; misc alc, eth
i aq; misc alc, eth
i aq; misc alc, eth
INTERACTIVE
e218
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
e245
e246
e247
e248
e249
e250
e251
Ethyl 3-phenylglycidate
1-Ethylpiperazine
Ethyl N-piperazinocarboxylate
1-Ethylpiperidine
2-Ethylpiperidine
Ethyl 3-piperidinecarboxylate
Ethyl 4-piperidinecarboxylate
Ethyl N-piperidinepropionate
192.21
1.518020
960.5mm
⬎110
114.19
158.20
232, 5
232, 9
0.899
1.080
1.469020
1.476520
157
273
43
⬎110
113.20
113.20
157.21
20, 17
20, 104
0.834
0.858
1.012
1.444020
1.451020
1.460120
131
143
1047mm
18
31
90
s aq
1.010
1.459120
204
80
s aq, alc, bz, eth
0.927
1.454520
217–219
87
157.21
185.27
Ethyl nipecotate, e249
Ethyl oleate, e230
Ethyl oxirane, e3
1.102
20, 62
Ethyl pelargonate, e228
Ethyl pentyl ketone, o37
Ethyl phenyl ether, e36
DEAN 37261 (McGHP)
e244
Ethyl picolinate, e259
Ethylpiperidinol, e186
Ethyl pivalate, e128
1.225
e223
e234
e244
e245
RIGHT
e218
ROTATED
e246
e247
e248
e249
e250
e251
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Ethyl 1-propenyl ether
Ethyl propionate
Ethyl propyl ether
Ethyl propyl sulfide
2-Ethylpyridine
3-Ethylpyridine
4-Ethylpyridine
Ethyl 2-pyridinecarboxylate
1-Ethyl-2pyrrolidinone
Ethyl salicylate
Ethyl sorbate
2-Ethyltoluene
3-Ethyltoluene
4-Ethyltoluene
Ethyl 4-toluenesulfonate
N-Ethyl-m-toluidine
N-Ethyl-o-toluidine
6-Ethyl-o-toluidine
2-(N-Ethyl-mtoluidino)ethanol
Ethyl trichloroacetate
Ethyltrichlorosilane
Ethyltriethoxysilane
Ethyltriphenylphosphonium iodide
Ethyl undecanoate
Ethyl 10-undecenoate
Ethylurea
N-Ethylurethane
e260
1.226
e261
e262
e262a
e262b
e262c
e263
e264
e265
e266
e267
e268
e269
e270
e271
e272
e273
e274
e275
CH3CH"CHOC2H5
CH3CH2CO2C2H5
CH3CH2OCH2CH2CH3
CH3CH2SCH2CH2CH3
CH3CH2(C5H4N)
CH3CH2(C5H4N)
CH3CH2(C5H4N)
Formula
weight
86.13
102.13
88.15
104.21
107.16
107.16
107.16
151.17
Beilstein
reference
1, 435
2, 240
1, 354
13, 1432
20, 241
20, 242
20, 243
22, 35
113.16
Density,
g/mL
Refractive
index
0.778
0.891720
0.739
0.8270
0.937
0.954
0.942
1.1194
1.398020
1.383920
1.369520
1.446220
1.496420
1.501520
1.500920
1.508820
0.992
1.465220
C6H4(OH)CO2C2H5
CH3CH"CHCH"CHCO2C2H5
CH3C6H4C2H5
CH3C6H4C2H5
CH3C6H4C2H5
CH3C6H4SO2OC2H5
166.18
140.18
120.19
120.19
120.19
200.26
10, 73
2, 484
51, 192
5, 398
5, 397
11, 99
1.131
0.956
0.865
0.865
0.861
1.16645
4
1.521920
1.494220
1.504020
1.496020
1.495020
1.511020
CH3C6H4NHC2H5
CH3C6H4NHC2H5
C2H5C6H3(CH3)NH2
CH3C6H4N(C2H5)CH2CH2OH
135.21
135.21
135.21
179.26
12, 857
0.957
0.938
0.968
1.019
1.545120
1.547020
1.552520
1.554020
Cl3CCO2C2H5
C2H5SiCl3
C2H5Si(OC2H5)3
C2H5P(C6H5)3I
191.44
163.51
192.33
418.26
2, 209
4, 630
44, 4223
16, 760
1.38320
4
1.238
0.895
1.444720
1.425220
1.392020
CH3(CH2)10CO2C2H5
H2C"CH(CH2)8CO2C2H5
CH3CH2NHC("O)NH2
CH3CH2NHCO2C2H5
214.35
212.34
88.11
117.15
2, 358
2, 459
4, 115
4, 114
0.859
0.879
1.21318
0.98120
4
Melting
point,⬚C
⫺73.9
⫺79
⫺117.0
2
2–3
⫺81
⫺95
⫺62
33
⫺33
⫺106
Boiling
point,⬚C
Flash
point,⬚C
⫺18
12
32
Solubility in 100
parts solvent
67–76
99
62–63
118.5
149
162–165
168
240–241
29
48
47
107
9720mm
76
232–234
195.5
165
161
162
17315mm
107
69
39
38
36
157
221
218
231
1151mm
89
88
89
⬎110
168
99
158–166
65
13
38
i aq; s alc, eth
1054mm
258–259
⬎110
⬎110
i aq; s org solvents
8520mm
75
1.7 aq; misc alc, eth
sl s aq; misc alc, eth
s alc
sl s aq; s alc, eth
v s alc, eth; sl s aq
sl s aq; s alc, eth
misc aq, alc, eth
misc alc, eth; sl s aq
i aq; s alc, eth
169–171
1.428020
1.439020
93–96
1.421120
v s aq; 80 alc; i eth
63 aq
INTERACTIVE
e252
e253
e254
e255
e256
e257
e258
e259
Formula
ROTATED
Name
LEFT
No.
1.227
e279
Ethyl vinyl ether
N-Ethyl-2,3-xylidine
1-Ethynyl-1cyclohexanol
Eugenol
f1
f2
f3
f4
f5
f6
f7
f8
f9
f10
f11
f12
f13
Fluoranthene
Fluorene
Fluorenone
Fluorescein
Fluoroacetic acid
4-Fluoroacetophenone
2-Fluoroaniline
4-Fluoroaniline
2-Fluorobenzaldehyde
4-Fluorobenzaldehyde
Fluorobenzene
2-Fluorobenzoic acid
4-Fluorobenzoic acid
CH3CH2OCH"CH2
(CH3)2C6H3NHC2H5
HOC6H10C#CH
72.11
149.24
124.18
4-(H2C"CHCH2)C6H32-(OCH3)OH
FCH2CO2H
FC6H4COCH3
FC6H4NH2
FC6H4NH2
FC6H4CHO
FC6H4CHO
C6H5F
FC6H5CO2H
FC6H5CO2H
1, 433
12, 1101
62, 100
0.758920
0.917
0.967
164.20
6, 961
1.066
202.26
166.22
180.21
332.31
78.04
138.14
111.12
111.12
124.11
124.11
96.11
140.11
140.11
5, 685
5, 625
7, 465
19, 222
2, 193
1.25204
1.20304
1.130099
4
121, 296
12, 597
71, 132
71, 132
5, 198
9, 333
9, 333
1.138
1.151
1.1725
1.178
1.157
1.024020
4
1.46025
4
1.47925
4
Ethyl toluates, e204, e205, e206
Ethyl p-tolyl ether, m373
Ethyl trimethylacetate, e128
Ethyl vanillin, e46
Ethyne, a41
Ethynylbenzene, p84
1-Ethyl-1-propanol, p41
Ethyl propenoate, e60
1-Ethylpropylamine, a247a
Ethyl pyruvate, e237
2-(Ethylthio)ethanol, e180
Ethyl thioglycolate, e196
31–33
35
228
180
⬍ ⫺45
71
62
1.5410
⫺12/⫺10
254
⬎110
1.636999
108
115
82–85
320
33
384
295
342
1.376720
1.546820
20
1.511020
1.542020
1.539520
1.522020
1.520020
1.465720
⫺116
⫺29
⫺2
⫺44.5
⫺10
⫺42.2
123–125
184–187
165
196
183
187
9146mm
181
84.7
0.9 aq; s alc, eth
2.4 aq; misc alc, bz,
acet, ketones, PE
sl s alc; s bz, eth
v s HOAc; s bz, eth
s alc, bz; v s eth
s hot alc, hot HOAc
sl s aq, alc
71
60
73
55
56
⫺15
DEAN 37261 (McGHP)
e276
e277
e278
sl s aq; s alc, eth
0.15 aq; misc alc
sl s aq; s alc, eth
0.1 aq; s alc, eth
Eugenol, m108
Eugenol methyl ether, a84
Fenchone, t376
Fenchyl alcohol, t375
N-9H-(2-Fluorenyl)acetamide, a13
RIGHT
ROTATED
e259
e260
f1
f2
f3
f4
INTERACTIVE
No.
f14
f15
f16
f17
f18
f19
f20
f21
1.228
f22
f23
f24
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
FC6H5COCl
158.56
91, 136
1.328
1.536520
4
9215mm
82
FC6H5COCl
158.56
91, 137
1.342
1.529620
9
8220mm
82
FC6H5CH2Cl
144.58
1.207
1.513020
8226mm
60
CH3CH2F
CH3F
FC6H4OCH3
48.06
34.04
126.13
1, 82
1, 59
FC6H4OCH3
126.13
61, 98
76.11
14, 286
FC6H3(NO2)NH2
FC6H4NO2
156.12
141.10
12, 729
5, 241
CH3C6H3(NO2)F
155.13
FC6H4OH
F(C5H4N)
FC6H4CH3
FC6H4CH3
FC6H4CH3
FCCl3
112.10
97.09
110.13
110.13
110.13
137.37
H2C"O
HC("O)NH2
HC("NH)NH2 · HO2CCH3
H2NC("NH)S(O)OH
C6H5NHCHO
HCO2H
HO2CC6H4HCO
(CH3)3CF
⫺143.2
⫺141.8
1.195 g/L
1.104
1.488020
1.114
1.487720
⫺37.7
⫺78.4
158743mm
43
⫺45
157
43
⫺77
12
⫺12
Solubility in 100
parts solvent
198 mL aq; v s alc, eth
166 mL aq; v s alc, eth
s eth
1.330020
4
1.531220
96–98
21
205
91
83
1.262
1.524020
28–30
241
⬎110
6, 183
201, 80
5, 290
5, 290
5, 290
1, 64
46–48
1.128
1.001417
0.997420
0.997520
1.494
1.468020
1.471617
1.469120
1.469820
1.382120
185
126
115
115
117
24
68
28
12
9
17
none
30.03
45.04
104.11
108.12
1, 558
2, 26
0.815⫺420
1.133420
4
0.8153⫺20
1.447520
⫺92
2.6
158 dec
126 dec
⫺19.5
220
56
154
122 aq; s alc, eth
misc aq, alc, acet
121.14
46.03
150.13
12, 230
2, 8
10, 666
1.144
1.22020
4
1.404
1.370420
47
8.3
96–98
271
100.8
⬎110
68
2.5 aq
misc aq, alc, eth
s aq; v s alc, eth
31, 36
⫺62
⫺87
⫺56
⫺110
i aq; s alc, eth
v s alc, eth
s alc, eth
s alc, eth
INTERACTIVE
f35
f36
f37
Formula
weight
ROTATED
f31
f32
f33
f34
2-Fluorobenzoyl
chloride
4-Fluorobenzoyl
chloride
4-Fluorobenzyl
chloride
Fluoroethane
Fluoromethane
3-Fluoro-1-methoxybenzene
4-Fluoro-1-methoxybenzene
2-Fluoro-2-methylpropane
4-Fluoro-3-nitroaniline
1-Fluoro-4-nitrobenzene
4-Fluoro-3-nitrotoluene
4-Fluorophenol
2-Fluoropyridine
2-Fluorotoluene
3-Fluorotoluene
4-Fluorotoluene
Fluorotrichloromethane
Formaldehyde
Formamide
Formamidine acetate
Formamidinesulfinic
acid
Formanilide
Formic acid
2-Formylbenzoic acid
Formula
LEFT
f25
f26
f27
f28
f29
f30
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Formylhydrazine
4-Formylmorpholine
N-Formylpiperidine
D-(⫺)-Fructose
Fumaric acid
Fumaroyl dichloride
2-Furaldehyde
Furan
2-Furanacrylic acid
f47
f48
2,5-Furandimethanol
2-Furanmethanethiol
HC("O)NHNH2
HO2CCH"CHCO2H
ClC("O)CH"CHC("O)Cl
60.06
115.13
113.16
180.16
116.07
152.96
96.09
68.07
138.12
2, 93
273, 274
20, 45
31, 321
2, 737
2, 743
172, 305
17, 27
18, 300
128.13
114.17
171, 90
172, 116
54–56
1.484820
1.478020
1.145
1.019
1.63520
4
1.40820
1.159820
4
0.951420
1.498820
1.526220
1.421420
1.132
1.530420
287
⬎110
⬎110
91
73
60
⫺35
74–76
1.229
Formylphenols, h94, h95, h96
Formylpyridines, p261, p262, p263
Freon-11, t237
Freon-12, d218
Freon-12B2, d93
Freon-21, d233
Fluorothane, b308
Fluorotrichloromethane, t237
2-Fluoro-5-(trifluoromethyl)aniline, a179
Formal, d507
Formaldehyde diethyl acetal, d307
Formic acid hydrazide, f38
Formylamide, f33
⫺36.5
⫺85.6
142–144
236–237
222
122 dec
subl 300
161–164
161.8
31.4
286
155
45
v s alc, chl, eth; s bz
v s aq; 6.7 alc; s pyr
0.6 aq; 9 alc; 0.7 eth
dec aq, alc
8 aq; misc alc, eth
1 aq; misc alc, eth
0.2 aq; 1.1 bz; s alc,
eth, HOAc
DEAN 37261 (McGHP)
f38
f39
f40
f41
f42
f43
f44
f45
f46
Freon-22, c101
Freon-114, d271
2,5-Furandione, m2
2-Furanmethanol, f50
Furfural, f44
2-Furfuraldehyde, f44
RIGHT
f45
f40
f41
f46
f44
f47
ROTATED
f39
f48
INTERACTIVE
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
1.230
f49
f50
Furfuryl acetate
Furfuryl alcohol
140.14
98.10
172, 115
17, 112
1.117520
4
1.129520
4
1.461820
1.486820
f51
f52
f53
f54
f55
g1
g2
Furfurylamine
Furfuryl methacrylate
␣-Furildioxime
2-Furoic acid
2-Furoyl chloride
D-(⫹)-Galactose
Geraniol
18, 584
173, 1248
19, 166
18, 272
18, 276
31, 295
1, 457
1.099520
4
1.078
1.490020
1.482020
g3
Geranyl acetate
196.29
2, 140
g4
Gerard reagent P
(CH3)2C"CHCH2CH2C(CH3)"CHCH2OH
(CH3)2C"CHCH2CH2C(CH3)"CHCH2O2CCH3
[(C5H5N)CH2C("O)NHNH2]⫹ Cl⫺
97.12
166.18
220.18
112.08
130.53
180.16
154.25
187.63
g5
Gerard reagent T
[(CH3)3NCH2C("O)NHNH2]⫹ Cl⫺
g6
g7
g8
D-Gluconic
acid
␦-Gluconolactone
␣-D-(⫹)-Glucose
196.16
178.14
180.16
Merck:
12, 4436
Merck:
12, 4436
3, 542
181, 405
31, 83
g9
390.34
31, 119
109–111
176.12
176–178
27 aq; 2.8 MeOH
g12
g13
␣-D-Glucose pentaacetate
D-Glucurono-3,6lactone
(S)-(⫹)-Glutamic acid
(S)-(⫹)-Glutamine
less soluble in polar
solvents than T
v s aq, HOAc, glyc,
ethylene glycol
v s aq; sl s alc; i eth
50 aq; 1 alc; i eth
91 aq; 0.83 MeOH; s
pyr
0.15 aq; 1.3 alc; 3 eth
g14
g15
g16
g17
2, 631
Glutaric anhydride
Glutaric dialdehyde
Glutaronitrile
OCHCH2CH2CH2CHO
NCCH2CH2CH2CN
114.10
100.12
94.12
17, 411
1, 776
2, 635
145–146
825mm
46
90
i aq; s alc, eth
misc aq(dec); v s alc,
eth
misc aq; s alc, eth
1.324
1.531020
0.889420
4
1.476620
230
76
v s alc, eth; sl s bz
4 aq; s alc; v s eth
dec aq, alc; s eth
200 aq; s pyr; sl s alc
i aq; misc alc, eth
0.917415
15
1.462815
13825mm
104
v s alc; misc eth
230–232
170
85
dec 200
192
131
153
153–156
1.562018
4
1.53820
4
1.42920
4
1.4188106
0.988823
1.433825
1.434520
d 247
185 dec
subl 200
98
303
55–57
15010mm
187–189
286
⫺29
0.8 aq; i alc, eth
5 aq; 0.0035 MeOH; i
bz, chl, eth, acet
43 aq20; v s alc, eth; s
bz, chl; sl s PE
⬎110
none
⬎110
s aq, alc
s aq, alc, chl; i eth
INTERACTIVE
132.12
166–168
133–134
⫺2
167
65
75
ROTATED
147.13
146.15
Glutaric acid
HO2CCH2CH2CH(NH2)CO2H
H2NC("O)CH2CH2CH(NH2)CO2H
HO2CCH2CH2CH2CO2H
Merck:
11, 4362
4, 488
4, 491
⫺70
175–177
171
LEFT
g11
167.64
⫺31
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Glutaryl dichloride
Glycerol
Glyceryl tris(butyrate)
ClC("O)(CH2)3C("O)Cl
HOCH2CH(OH)CH2OH
(CH3CH2CH2CO2CH2)2CHO2CCH2CH2CH3
Furfuryl mercaptan, f48
Furylacrylic acid, d46
2-Furyl methyl ketone, a44
Galactitol, d824
169.01
92.09
302.37
2, 634
1, 502
2, 273
1.324
1.261320
1.03220
4
1.472020
1.474620
1.435920
18
⫺75
Gallic acid, t319
Gentisic acid, d432
Geranial, d665
D-Glucitol, s5
1.231
f49
f50
dec aq, alc; s eth
misc aq, alc; 0.2 eth
i aq; v s alc, eth
Glutaraldehyde, g16
Glycerol dichlorohydrin, d264
Glycerol ␣-monochlorohydrin, c227
Glyceryl triacetate, p200
f51
f55
106
199
173
f52
g1
f53
g6
RIGHT
f54
216–218
290
287–288
DEAN 37261 (McGHP)
g18
g19
g20
g7
ROTATED
g8
g9
g11
g12
g13
g15
INTERACTIVE
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
[CH3(CH2)10CO2CH2]2CHO2C(CH2)10CH3
O2NOCH2CH(ONO2)CH2ONO2
639.02
2, 362
0.89460
4
1.440460
46
g22
Glyceryl tris(dodecanoate)
Glyceryl tris(nitrate)
227.09
1, 516
1.59420
4
1.478612
13.3
1605mm
g23
Glyceryl tris(oleate)
885.46
4, 468
0.91515
4
1.462140
⫺4/⫺5
23515mm
g24
Glyceryl tris(palmitate)
807.35
2, 373
0.866380
4
1.438180
65–66
310–320
v s bz, chl, eth
g25
723.18
2, 367
0.88560
4
1.442860
57
v s alc, bz, chl
g26
g27
g28
Glyceryl tris(tridecanoate)
Glycine
N-Glycylglycine
Glyoxal
[CH3(CH2)7CH"CH(CH2)7CO2CH2]2CHO2C(CH2)7CH"CH(CH2)7CH3
[CH3(CH2)14CO2CH2]2CHO2C(CH2)14CH3
[CH3(CH2)11CO2CH2]2CHO2C(CH2)11CH3
H2NCH2CO2H
H2NCH2C("O)NHCH2CO2H
HC("O)CHO
0.18 aq; 54 alc; misc
eth
s chl, eth, CCl4
75.07
132.12
58.04
4, 333
4, 371
1, 759
1.1607
1.382620
dec 240
260 dec
15
g29
g30
g31
Glyoxylic acid
Guanidine
Guanine
HC("O)CO2H
H2NC("NH)NH2
74.04
59.07
151.13
3, 594
3, 82
26, 449
h1
h1a
h2
Heptadecane
1-Heptadecanol
Heptafluorobutyric
acid
Heptaldehyde
2,2,4,4,6,8,8-Heptamethylnonane
1,1,1,3,5,5,5-Heptamethyltrisiloxane
Heptane
Heptanedioic acid
1-Heptanethiol
CH3(CH2)15CH3
CH3(CH2)16OH
CF3CF2CF2CO2H
140.41
256.48
214.04
1, 173
11, 220
25 aq; 0.6 pyr; i eth
s hot aq; sl s alc
viol rxn aq; s anhyd
solvents; mixtures
with air may explode
v s aq; sl s alc, eth
v s aq, alc
s alk soln, dil acids; sl
s alc, eth
s eth; sl s alc
CH3(CH2)5CHO
(CH3)3CCH2C(CH3)2CH2CH(CH3)CH2C(CH3)3
[(CH3)3SiO]2SiHCH3
114.19
226.45
CH3(CH2)5CH3
HO2C(CH2)5CO2H
CH3(CH2)6SH
g21
1.232
1.436025
1.625
⬍1.30020
12, 750
0.821615
4
0.793
1.428520
1.439120
222.51
43, 1874
0.819
1.382020
100.21
160.17
132.27
1, 154
2, 670
1, 415
0.683820
4
1.32915
1.387720
50.4
dec 160
22.0
53.8
302.2
333
120
148
⬎110
none
⫺43
153
240
35
95
142
27
98.4
21210mm
176.9
⫺4 (CC)
⫺90.6
105.8
⫺43.2
46
misc alc, eth; sl s aq
s alc, chl, eth
5 aq; v s alc, eth
i aq
INTERACTIVE
h6
h7
h8
0.776722
explodes
270
ROTATED
h5
98
ca. 50
⬎300
v s bz, eth; sl s alc
LEFT
h3
h4
1.14
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
1.233
h24
Heptanoic acid
Heptanoic anhydride
1-Heptanol
2-Heptanol
3-Heptanol
2-Heptanone
3-Heptanone
4-Heptanone
Heptanoyl chloride
1-Heptene
cis-2-Heptene
trans-2-Heptene
1-Heptylamine
1-Heptyne
Hexachloroacetone
Hexachlorobenzene
Hexachloro-1,3butadiene
1,2,3,4,5,6-Hexachlorocyclohexane, ␥isomer
130.19
242.36
116.20
116.20
116.20
114.19
114.19
114.19
148.63
98.90
98.19
98.19
115.22
96.17
264.75
284.78
260.76
2, 338
2, 340
1, 414
1, 415
11, 205
1, 699
1, 699
1, 699
2, 340
1, 219
13, 825
1, 219
4, 193
1, 256
1, 657
5, 205
1, 250
0.918120
4
0.923
0.821920
4
0.816720
0.822720
0.819715
4
0.819720
20
0.817
0.960
0.697020
0.70820
0.701220
0.777
0.733
1.743
2.04424
1.655
C6H6Cl6
290.83
51, 8
1.8720
Glycolaldehyde, h87
Glycolaldehyde diethyl acetal, d305
Glycolic acid, h88
Glycol methacrylate, h126
Glyoxaline, i3
Guaiacol, m97
Heliotropin, m250
Hemimellitene, t357
1.422120
1.433220
1.424220
1.421010
1.421420
1.411615
1.405520
1.406820
1.430020
1.399920
1.40620
1.404520
1.424320
1.407520
1.511220
1.555020
⫺8
⫺12.4
⫺34
⫺70
⫺35
⫺39
⫺32.1
⫺120
⫺109.5
⫺23
⫺81
⫺30
232
⫺21
222
268
176.4
159
157
151
147
143.7
173
93.6
98.4
98
154–56
99–100
666mm
325
215
113–115
Hemimellitic acid, b29
Heptaldehyde, h3
sec-Heptyl alcohol, h12
Heptyl bromide, b343
Heptyl chloride c147
Heptyl iodide, i34
Heptyl mercaptan, h8
Heptyl methyl ketone, n99
⬎110
⬎110
73
71
60
39
46
48 (CC)
58
⫺8
⫺6
⫺1
35
⫺2
none
242
none
0.25 aq; s alc, eth
i aq; s alc, eth
misc alc, eth
0.35 aq; s alc, bz, eth
sl s aq
s alc, eth
0.43 aq; s alc, eth
0.53 aq; misc alc, eth
dec aq, alc; s eth
0.1 aq; s alc, eth
s alc, acet, eth, PE
sl s aq; s acet
s bz, chl, eth
s alc, eth
s bz, chl
RIGHT
Glyceryl tris(laurate), g21
Glyceryl tris(myristate), g25
Glycidic acid, h88
Glycidol, e16
Glycidyl methacrylate, e17
Glycidyl phenyl ether, e14
Glycinol, e29
Glycinonitrile, a103
CH3(CH2)5CO2H
[CH3(CH2)5CO]2O
CH3(CH2)6OH
CH3(CH2)5CH(OH)CH3
CH3(CH2)3CH(OH)CH2CH3
HC3(CH2)4C("O)CH3
CH3(CH2)3C("O)CH2CH3
CH3(CH2)2C("O)(CH2)2CH3
CH3(CH2)5C("O)Cl
CH3(CH2)4CH"CH2
CH3(CH2)3CH"CHCH3
CH3(CH2)3CH"CHCH3
CH3(CH2)6NH2
CH3(CH2)4C#CH
Cl3CC("O)CCl3
CCl6
CL2C"CClCCl"CCl2
DEAN 37261 (McGHP)
h9
h10
h11
h12
h13
h14
h15
h16
h17
h18
h18a
h18b
h19
h20
h21
h22
h23
ROTATED
g31
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
h25
h27
h28
1.234
h44
h45
h46
Beilstein
reference
272.77
Density,
g/mL
Refractive
index
1.70125
4
1.564420
Cl3CCCl3
236.74
370.83
1, 87
93, 4049
2.091
CH3[C6H(Cl)3OH]2
Cl3CC(Cl)"CCl2
CH3(CH2)14CH3
CH3(CH2)13CH(OH)CH2OH
CH3(CH2)15SH
CH3(CH2)14CO2H
CH3(CH2)15OH
CH3(CH2)14CH"CH2
CH3(CH2)15NH2
CH3CH"CHCH"CHCHO
H2C"CHCH2CH2CH"CH2
CH3CH"CHCH"CO2H
406.91
248.75
226.45
258.45
258.51
256.43
242.45
224.43
241.46
96.13
82.15
112.13
63, 5407
1, 200
1, 172
13, 2244
1, 430
2, 370
1, 429
1, 226
4, 202
12, 809
1, 253
2, 483
C6F6
F3CCF3
(CF3)2CHOH
186.05
138.01
168.04
53, 523
13, 132
CF3CF"CF2
[-Si(CH3)2O-]3
150.02
222.48
13, 697
43, 1884
(CH3)3SiNHSi(CH3)3
161.40
4,3, 1861
0.77420
4
1.407120
(CH3)3SiOSi(CH3)3
162.38
99.18
43, 1859
20, 94
0.76420
4
0.880
1.377520
1.463120
Melting
point,⬚C
Boiling
point,⬚C
1.548020
1.434520
0.840
0.85262
4
0.811660
0.78320
4
1.472020
1.427380
1.435560
1.4401
0.871
0.692320
4
1.538620
1.404220
1.618220
1.590⫺78
1.59625
1.378120
1.275020
Solubility in 100
parts solvent
⫺10
239
none
187
239–242
sublimes
none
s alc, bz, chl, eth
210
286.8
none
none
135
misc eth
163–165
1.765
0.773320
4
Flash
point,⬚C
18.2
72–74
18–20
62
49.3
4.1
45–48
101
⫺140.7
134.5
1847mm
351
334
284
330
7630mm
59.5
11910mm
5.1
⫺100.7
⫺3
80.3
⫺78.3
58.2
10
none
⫺153
64–66
⫺28
133–135
35
126
8
101
138749mm
⫺2
18
⫺67
135
132
140
67
⫺27
127
sl s alc, s eth
s hot: chl, eth
s alc, chl, eth
s alc, eth, PE
v s alc, eth; s bz, chl
s alc, eth
0.2 aq; 13 alc; 9 acet;
2.3 bz; 11 diox; 1
CCl4
sl s alc, eth
s aq, bz, CCl4
INTERACTIVE
h47
h48
Hexafluorobenzene
Hexafluoroethane
1,1,1,3,3,3-Hexafluoro2-propanol
Hexafluoropropene
Hexamethylcyclotrisiloxane
1,1,1,3,3,3-Hexamethyldisilazane
Hexamethyldisiloxane
Hexamethyleneimine
Formula
weight
ROTATED
h41
h42
h43
Hexachlorocyclo-1,3pentadiene
Hexachloroethane
1,4,5,6,7,7-Hexachloro5-norbornene-2,3-dicarboxylic anhydride
Hexachlorophene
Hexachloropropene
Hexadecane
1,2-Hexadecanediol
1-Hexadecanethiol
Hexadecanoic acid
1-Hexadecanol
1-Hexadecene
1-Hexadecylamine
2,4-Hexadienal
1,5-Hexadiene
2,4-Hexadienoic acid
Formula
LEFT
h29
h30
h31
h32
h33
h34
h35
h36
h37
h38
h39
h40
Name
h50
h51
h52
h53
h54
h55
h56
h57
h58
h59
1.235
h60
h61
h62
h63
Hexamethylenetetramine
Hexamethylphosphoramide
Hexanaldehyde
Hexane
1,6-Hexanediamine
1,6-Hexanedioic acid
DL-1,2-Hexanediol
1,6-Hexanediol
2,5-Hexanediol
1,6-Hexanediol
diacrylate
1,6-Hexanediol
dimethacrylate
2,5-Hexanedione
Hexanenitrile
1-Hexanethiol
1,2,6-Hexanetriol
140.19
[(CH3)2N]3P("O)
1, 583
1.02720
179.20
CH3(CH2)4CHO
CH3(CH2)4CH3
H2N(CH2)6NH2
HO2C(CH2)4CO2H
CH3(CH2)3CH(OH)CH2OH
HO(CH2)6OH
CH3CH(OH)CH2CH2CH(OH)CH3
[H2C"CHCO2(CH2)3⫺]2
100.16
86.18
116.21
146.14
118.18
118.18
118.18
226.28
[H2C"C(CH3)CO2(CH2)3⫺]2
254.33
CH3C("O)CH2CH2C("O)CH3
CH3(CH2)4CN
CH3(CH2)5SH
HOCH2CH(OH)(CH2)3CH2OH
114.14
97.16
118.24
134.17
1.331⫺5
2
1 , 745
1, 142
4, 269
2, 649
11, 251
1, 484
1, 485
1, 788
2, 324
13, 1659
14, 2784
280 subl
1.458820
20
4
20
4
20
0.8335
0.6594
1.4035
1.374920
1.36025
4
0.951
0.958
0.961745
16
1.010
1.442520
1.457925
1.446520
1.456220
0.995
1.458020
0.97320
4
0.805220
0.842420
4
1.106320
20
1.426020
1.406920
1.449620
1.5820
Hexahydrobenzene, c347
Hexahydrobenzoic acid, c353
Hexahydrobenzylamine, c362
Hexahydrophthalic acid, c356
Hexahydropyridine, p180
Hexamethylenediamine, h53
Hexamethylene diisocyanate, d461
67 aq; 8 alc; 10 chl
7
232740mm
105
misc aq
⫺56
⫺95.4
42
152–154
131
68.7
205
337.5
223–224
208
220.8
32
⫺22
81
196
⬎110
101
101
⬎110
v s alc, eth; sl s aq
misc alc, chl, eth
v s aq; sl s alc, bz
1.4 aq; v s alc; s acet
⬎ 350
⬎110
188
163.6
152.7
1785mm
78
43
20
191
42.8
⫺50
⫺9
⫺80.3
⫺80.5
⫺32.8
v s aq, alc
s aq, alc, eth
misc aq, alc, eth
i aq; s alc, eth
i aq; v s alc, eth
misc alc, acet; i bz
Hexamethylene glycol, h56
Hexamethylethane, t100
2,6,10,15,19,23-Hexamethyl-2,6,10,14,18,22-tetracosene, s8
1,6,10,15,19,23-Hexamethyltetracosane, s7
1,6-Hexanedinitrile, d284
6-Hexanelactam, o61
RIGHT
Hexachloro-2-propanone, h21
␣,␣,␣,␣⬘,␣⬘,␣⬘-Hexachloro-p-xylene, b225
Hexadecyl mercaptan, h33
␣,␣,␣,␣⬘,␣⬘,␣⬘-Hexafluoro-3,5-xylidine, h229
Hexahydroaniline, c375
Hexahydro-2H-azepin-2-one, o61
Hexahydrobenzaldehyde, c352
250
DEAN 37261 (McGHP)
h49
ROTATED
h25
h28
h48
h49
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
1.236
116.16
214.31
102.18
2, 321
2, 324
1, 407
0.926520
4
0.926
0.813620
1.416820
1.428020
1.418220
⫺3
⫺41
⫺44.6
205
246–248
157.5
102
⬎110
63
h67
h68
h69
h70
h71
h72
h73
h74
h75
h76
h77
h78
2-Hexanol
3-Hexanol
6-Hexanolactone
2-Hexanone
3-Hexanone
Hexanoyl chloride
1-Hexene
trans-2-Hexenoic acid
trans-3-Hexenoic acid
trans-2-Hexen-1-ol
5-Hexen-2-one
trans-2-Hexenyl
acetate
Hexyl acetate
Hexyl acrylate
Hexylamine
1-Hexyne
L-Histidine
Hydantoin
Hydrazine
CH3(CH2)3CH(OH)CH3
CH3CH2CH2CH(OH)CH2CH3
102.18
102.18
114.14
100.16
100.16
134.61
84.16
114.14
114.14
100.16
98.15
142.20
1, 408
1, 408
172, 290
1, 689
1, 690
2, 324
1, 215
24, 1563
2, 435
12, 486
1, 734
22, 151
0.810825
4
0.819320
4
1.030
0.811320
0.815
0.975420
4
0.673220
0.965
0.963
0.849
0.847
0.898
1.412825
1.416020
1.463020
1.400720
1.400220
1.426320
1.387920
1.488520
1.439820
1.434320
1.419720
1.427520
⫺47
139.9
135
215
127.6
123
153
63.5
217
11922mm
158–160
128–129
166
41
41
109
25
35
50
⫺9
⬎110
⬎110
54
23
58
144.21
156.23
101.19
82.14
155.16
100.08
32.05
0.86020
20
0.888
0.76325
4
0.715220
4
1.409020
1.428020
1.418020
1.398920
⫺81
45
68
8
⫺21
1.003625
4
1.470020
⫺23
⫺131.9
282 dec
221–223
1.4
171
9024mm
133
71.3
113.5
52
1.332
172
286
93–94
80
98–100
11012mm
100
325 sl d
⫺17
146
h79
h80
h81
h82
h83
h84
h85
CH3(CH2)3C("O)CH3
CH3CH2CH2C("O)CH2CH3
CH3(CH2)4C("O)Cl
CH3(CH2)3CH"CH2
CH3(CH2)2CH"CHCO2H
CH3CH2CH"CHCH2CO2H
CH3CH2CH2CH"CHCH2OH
H2C"CHCH2CH2C("O)CH3
CH3C("O)CH2CH"CHCH2CH2CH3
CH3(CH2)5O2CCH3
H2C"CHCO2(CH2)5CH3
CH3(CH2)5NH2
CH3(CH2)3C#CH
h86
1,4-Hydroquinone
C6H4-1,4-(OH)2
110.11
2, 132
23, 1228
4, 188
1, 253
25, 513
24, 242
Merck:
12, 4809
6, 836
h87
h88
h89
Hydroxyacetaldehyde
Hydroxyacetic acid
1⬘-Hydroxy-2⬘-acetonaphthone
Hydroxyacetone
HOCH2CHO
HOCH2CO2H
C10H6(OH)C("O)CH3
60.05
76.05
186.21
1, 817
3, 228
8, 149
1.366100
74.08
11, 84
1.082
h90
H2NNH2
HOCH2C("O)CH3
15
1.431520
⫺18
⫺55.5
⫺87
⫺139.8
33–35
11–12
1.1 aq; v s alc, eth
s alc
8 aq; misc bz, eth; s
alc
sl s aq; s alc, eth
v s alc, eth
dec aq, alc; s eth
0.005 aq
0.13 aq; v s alc, eth
sl s aq; misc alc, eth
i aq; s alc, eth
41 aq; v sl s alc
s alc, alk; sl s eth
misc aq, alc
7 aq; v s alc, eth; sl s
bz
v s aq, alc; sl s eth
s aq, alc, acet, eth
i aq; v s bz; s HOAc
56
misc aq, alc, eth
INTERACTIVE
CH3(CH2)4CO2H
[CH3(CH2)4C("O)]2O
CH3(CH2)5OH
ROTATED
Hexanoic acid
Hexanoic anhydride
1-Hexanol
LEFT
h64
h65
h66
Solubility in 100
parts solvent
h92
h93
h94
h95
h96
h97
h98
h99
2⬘-Hydroxyacetophenone
3⬘-Hydroxyacetophenone
4⬘-Hydroxyacetophenone
2-Hydroxybenzaldehyde
3-Hydroxybenzaldehyde
4-Hydroxybenzaldehyde
2-Hydroxybenzaldehyde oxime
2-Hydroxybenzamide
2-Hydroxybenzoic
acid
HOC6H4C("O)CH3
136.15
8, 85
1.13121
4
1.558420
4–6
213717mm
HOC6H4C("O)CH3
136.15
8, 86
1.100100
1.535100
87–89
296
100
HOC6H4C("O)CH3
136.15
8, 87
1.109
C6H4(OH)CHO
122.12
8, 31
1.167420
C6H4(OH)CHO
122.12
8, 58
C6H4(OH)CHO
122.12
8, 64
C6H4(OH)CH"NOH
137.14
8, 49
C6H4(OH)C("O)NH2
C6H4(OH)CO2H
137.14
138.12
10, 87
10, 43
1.237
1.129130
4
s aq; v s alc, bz, eth
3mm
109–111
148
v s alc, eth; sl s aq
⫺7
196.7
103–105
19150mm
s alc, bz, eth; sl s aq
57
dec
1 aq; 70 acet; 4 bz65; v
s alc, eth
v s alc, bz, eth, acids
140
157–159
dec 270
21120mm
78
117–119
1.44320
4
Hexyl methyl ketone, o36
Hexyl propyl ketone, d20
Hippuric acid, b70
Homocysteine, a200
Homopiperidine, h48
Homoveratric acid, d513
Homoveratrylamine, d517
Hydroacrylonitrile, h173
2-Hydrazinoethanol, h125
misc alc, eth; sl s aq
Hydrazobenzene, d757
Hydrindene, i10
Hydrocinnamic acid, p150
Hydroquinone, d430
Hydroquinone dimethyl ether, d495
Hydroxyacetanilides, a15 thru a17
Hydroxybenzene, p65
2-Hydroxybenzenemethanol, h107
1.7 aq86; s alc, eth
0.2 aq; s alc, chl, eth
0.2 aq; 37 alc; 33 eth;
33 acet; 2 chl; 0.7
bz
RIGHT
D-erythro-Hex-2-enonic acid ␥-lactone, i69
Hexyl alcohol, h66
sec-Hexyl alcohol, e95
sec-Hexylamine, m371
Hexylbenzene, p116
Hexyl bromide, b346
Hexyl chloride, c149
Hexylene glycol, m360
Hexyl iodide, i36
1.574020
⬎110
DEAN 37261 (McGHP)
h91
ROTATED
h69
h83
h84
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
3-Hydroxybenzoic
acid
4-Hydroxybenzoic
acid
4-Hydroxybenzoic
hydrazide
4-Hydroxybenzophenone
1-Hydroxybenzotriazole
6-Hydroxy-1,3-benzoxathiol-2-one
2-Hydroxybenzyl
alcohol
1-Hydroxy-2-butanone
3-Hydroxy-2-butanone
4-Hydroxycinnamic
acid
7-Hydroxycoumarin
1-Hydroxy-1-cyclohexanecarbonitrile
2-Hydroxy-3,5-diiodobenzoic acid
4-Hydroxy-3,5-dinitrobenzoic acid
3-Hydroxydiphenylamine
(2-Hydroxydiphenyl)methane
(4-Hydroxydiphenyl)methane
h101
h102
h103
h104
1.238
h105
h106
h107
h108
h109
h111
h112
h113
h114
h115
h116
h117
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
C6H4(OH)CO2H
138.12
10, 134
1.473
201–203
0.8 aq; 10 eth
C6H4(OH)CO2H
138.12
10, 149
1.4684
215–217
0.2 aq; v s alc; 23 eth
HOC6H4C("O)NHNH2
152.15
10, 174
266 dec
HOC6H4C("O)C6H5
198.22
82, 184
132–135
135.13
26, 41
155–158
168.17
194, 2508
158–160
HOC6H4CH2OH
124.13
6, 891
1.16125
CH3CH2C("O)CH2OH
CH3C("O)CH(OH)CH3
HOC6H4CH"CHCO2H
88.11
88.11
164.16
1, 826
1, 827
10, 297
1.026
0.997217
4
1.428220
1.417120
C6H10(OH)CN
162.14
125.17
18, 27
10, 5
1.031
1.457620
I2C6H2(OH)CO2H
389.91
10, 113
232–235
HOC6H2(NO2)CO2H
228.12
1, 183
245 dec
HOC6H4NHC6H5
185.23
13, 410
80–82
340
HOC6H4CH2C6H5
184.24
6, 675
54
312
HOC6H4CH2C6H5
184.24
6, 675
84
322
83–85
1.599420
15
210–213
v s alc, eth; sl s aq
subl 100
7860mm
148
226–228
29
6.6 aq; v s alc, chl,
eth; s bz
60
50
misc aq, alc; sl s eth
s alc, eth; sl s aq
v s alc, chl, alk, HOAc
60
v s alc, eth; i bz, chl
⬎110
s organic solvents, alk
s hot aq, org solvents,
HOAc, alkalis
INTERACTIVE
h100
Formula
ROTATED
Name
LEFT
No.
h119
h120
h121
h122
h123
h124
h125
h126
1.239
h127
h128
h129
2-(2-Hydroxyethoxy)phenol
N-(2-Hydroxyethyl)acetamide
2-Hydroxyethyl acetate
2-Hydroxyethyl
acrylate
3-(1-Hydroxyethyl)aniline
2-Hydroxyethyl
disulfide
N-(2-Hydroxyethyl)ethylenediamineN,N,N⬘-triacetic
acid
2-Hydroxyethylhydrazine
2-Hydroxyethyl
methacrylate
N-(2-Hydroxyethyl)morpholine
N-(2-Hydroxyethyl)phthalimide
1-(2-Hydroxyethyl)piperazine
HOCH2CH2C6H4OH
154.17
62, 782
HOCH2CH2NHC("O)CH3
103.12
41, 430
CH3CO2CH2CH2OH
H2C"CHCO2CH2CH2OH
104.11
116.12
2, 141
24, 1469
CH3CH(OH)C6H4NH2
137.18
133, 1654
HOCH2CH2SSCH2CH2OH
154.25
1, 471
HO2CCH2N(CH2CH2OH)CH2CH2N(CH2CO2H)2
278.26
HOCH2CH2NHNH2
76.10
HOCH2CH2O2CC(CH3)"CH2
15
1.108
1.011
1.457520
1280.7mm
63–65
1555mm
176
misc aq; sl s bz
188
9212mm
88
98
misc aq, alc, chl, eth
1583.5mm
⬎110
220
73
20
1.4201
1.450020
66–69
1.261
1.565520
25–27
212 dec
41, 562
130.14
131.18
27, 7
191.19
21, 469
130.19
232, 6
⫺70
1.123
1.496120
1.073
1.452020
673.5mm
97
1.083
1.476020
227
99
246
⬎110
misc aq; s alc
misc aq
126–128
1.061
Hydroxyethanal, h87
3-(␣-Hydroxyethyl)aniline, a256
N-(2-Hydroxyethyl)-3-aza-1,5-pentanediol, t266
1.506520
N-(2-Hydroxyethyl)ethyleneimine, a311
N-(2-Hydroxyethyl)piperidine, p182
2-(2-Hydroxyethyl)piperidine, p183
RIGHT
m-Hydroxybenzotrifluoride, t304
Hydroxybutanedioic acids, h186, h187
5-Hydroxydecanoic acid, ␦-lactone, d17
1.123320
20
99–100
DEAN 37261 (McGHP)
h118
ROTATED
h104
h105
h111
h127
h128
h129
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
N-(2-Hydroxyethyl)piperazine-N⬘ethane-sulfonic acid
N-(2-Hydroxyethyl)piperidine
N-(2-Hydroxyethyl)pyridine
N-(2-Hydroxyethyl)pyrrolidine
N-(2-Hydroxyethyl)2-pyrrolidinone
2-Hydroxyethyl
salicylate
(2-Hydroxyethyl)triphenylphosphonium
bromide
8-Hydroxy-7-iodo-5quinolinesulfonic
acid
2-Hydroxyisobutyric
acid
2-Hydroxyisobutyronitrile
Hydroxylamine HCl
4-Hydroxy-2-mercapto6-methylpyrimidine
4-Hydroxy-2-mercapto6-propylpyrimidine
4-Hydroxy-3-methoxybenzaldehyde
4-Hydroxy-3-methoxybenzoic acid
h131
h132
h133
h134
1.240
h135
h136
h137
h138
h138a
h139
h140
h141
h142
h143
Beilstein
reference
238.31
Merck:
12, 4687
129.20
20, 25
1.005915
4
1.480420
199–202
68
HOCH2CH2NC5H4
123.16
21, 50
1.093
1.536820
1169mm
92
HOCH2CH2NC4H8
115.8
202, 5
0.985
1.471320
8113mm
56
129.16
214, 3142
1.143
1.496020
1422mm
⬎110
(HO)C6H4CO2CH2CH2OH
182.18
10, 81
1.224
1.548020
16613mm
⬎110
HOCH2CH2P(C6H5)3Br
387.26
16, 761
217–219
351.12
22, 408
269–270
dec
104.11
3, 313
82
841.5mm
85.11
3, 316
⫺19
8223mm
69.49
142.18
24, 351
(CH3)2C(OH)CO2H
(CH3)2C(OH)CN
H2NOH · HCl
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
0.932
170.23
1.399020
159 dec
330 dec
219–221
152.15
8, 247
CH3OC6H3(OH)CO2H
168.15
10, 392
1.056
80–81
210–213
Solubility in 100
parts solvent
sat’d aq: 2.25M 0
234 dec
1.670
CH3OC6H3(OH)CHO
Flash
point,⬚C
285
v s aq, alc, chl
v s aq, alc, eth
63
v s aq NH3, alkalis; sl
s alc, acet
0.1 aq; 1.7 alc; 1.7
acet; v s alkalis
1 aq; s alc, chl, pyr
0.12 aq; v s alc
INTERACTIVE
h130
Formula
weight
Formula
ROTATED
Name
LEFT
No.
h145
h146
h147
h148
h149
h150
h151
2-Hydroxy-4-methoxybenzophenone
4-Hydroxy-3-methoxybenzyl alcohol
N-(Hydroxymethyl)acrylamide
4-Hydroxy-3-methyl2-butanone
7-Hydroxy-4-methylcoumarin
N-(Hydroxymethyl)nicotinamide
4-Hydroxy-4-methyl2-pentanone
N-(Hydroxymethyl)phthalimide
CH3OC6H3(OH)C("O)C6H5
228.25
8, 312
63–66
CH3OC6H3(OH)CH2OH
154.17
6, 1113
4
101.11
2 , 1472
1.074
1.430
HOCH2CH(CH3)C("O)CH3
102.13
11, 422
0.993
1.434020
176.17
18, 31
190–192
(C5H4N)C("O)NHCH2OH
152.15
10, 4750
152–154
(CH3)2C(OH)CH2C("O)CH3
116.16
Merck:
12, 3008
21, 475
1.241
Hydroxyhydroquinone, b34
2-Hydroxyisobutyronitrile, h153
0.930625
4
1.423520
none
9215mm
⫺44
h134
167.91
58
misc aq
sl s aq, alc, bz
1,3-Hydroxy-2-methyl-2-propylamine, a226
h137
h140
RIGHT
h131
81
s alc, HOAc; sl s eth
147–149
2-Hydroxy-3-methyl-2-cyclopenten-1-one, m223
(2-Hydroxymethyl)-2-nitro-1,3-propanediol, t442
h130
v s alc, chl, eth
113–115
20
H2C"CHC("O)NHCH2OH
177.16
1605mm
DEAN 37261 (McGHP)
h144
ROTATED
h141
h148
h151
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
4-Hydroxy-N-methylpiperidine
2-Hydroxy-2-methylpropionitrile
2-Hydroxy-2-methylpropiophenone
5-Hydroxy-2-methylpyridine
3-Hydroxy-2-methyl4-pyrone
2-Hydroxy-1-naphthaldehyde
1-Hydroxy-2-naphthoic
acid
2-Hydroxy-1-naphthoic
acid
3-Hydroxy-2-naphthoic
acid
2-Hydroxy-1,4naphthoquinone
4-Hydroxy-3-nitrobenzenearsonic acid
4-Hydroxy-3-nitrobenzoic acid
5-Hydroxy-2pentanone
4-Hydroxyphenylacetic
acid
4-(4-Hydroxyphenyl)2-butanone
4-Hydroxyphenylglycine
h153
h154
h155
h156
h157
1.242
h158
h159
h160
h161
h162
h163
h164
h165
h166
h167
Formula
weight
115.18
Beilstein
reference
Density,
g/mL
211, 188
Refractive
index
Boiling
point,⬚C
Flash
point,⬚C
1.477520
29–31
200
⫺19
95
63
1034mm
⬎110
85.10
3, 316
0.926725
4
1.399220
C6H5C("O)C(CH3)2OH
164.20
81, 553
1.077
1.533020
HO(C5H2N)CH3
109.13
213, 480
(CH3)2C(OH)CN
Melting
point,⬚C
Solubility in 100
parts solvent
s aq, alc, chl, eth
168–170
126.11
161–162
1.2 aq; v s hot aq; s
alc, alk; sl s bz, eth
19227mm
C10H6(OH)CHO
172.18
8, 143
82–85
C10H6(OH)CO2H
188.18
10, 331
191–192
C10H6(OH)CO2H
188.18
10, 328
167 dec
C10H6(OH)CO2H
188.18
10, 333
222–223
v s alc, eth; s bz, chl
174.16
8, 300
dec ⬎191
s HOAc
HOC6H3(NO2)AsO(OH)2
263.04
161, 456
⬎300
v s alc, acet, HOAc,
alk; sl s aq; i eth
HOC6H3(NO2)CO2H
183.12
10, 181
184–185
CH3C("O)CH2CH2CH2OH
102.13
1, 831
HOC6H4CH2CO2H
152.15
10, 190
149–151
HOC6H4CH2CH2C("O)CH3
164.20
82, 117
82–83
HOC6H4CH(NH2)CO2H
167.16
141, 659
240 dec
1.00720
4
1.437220
v s alc, bz, eth, alk
144100mm
93
misc aq; s alc, eth
v s alc, eth; sl s aq
sl s aq, alc, bz, acet
INTERACTIVE
h152
Formula
ROTATED
Name
LEFT
No.
h169
h170
h171
h172
h173
h174
h175
h176
1.243
h177
h178
h179
h180
h181
N-(4-Hydroxyphenyl)glycine
2⬘-Hydroxy-3-phenylpropiophenone
1-(3-Hydroxyphenyl)urea
N-Hydroxyphthalimide
2-Hydroxypropionitrile
3-Hydroxypropionitrile
HOC6H4NHCH2CO2H
167.16
13, 488
HOC6H4C("O)CH2CH2C6H5
226.28
82, 202
HOC6H4NHC("O)NH2
152.15
13, 417
CH3CH(OH)CN
HOCH2CH2CN
163.13
71.08
71.08
21, 500
32, 209
3, 298
0.983425
1.040425
4
1.402725
1.424820
2⬘-Hydroxypropiophenone
4⬘-Hydroxypropiophenone
1-(2-Hydroxy-1propoxy)-2-propanol
Hydroxypropyl acrylate
Hydroxypropyl
methacrylate
2-Hydroxypyridine
3-Hydroxypyridine
4-Hydroxypyridine
HOC6H4C("O)CH2CH3
150.18
8, 102
1.094
1.548020
HOC6H4C("O)CH2CH3
150.18
8, 102
CH3CH(OH)CH2OCH2CH(OH)CH3
134.18
H2C"CHCO2(CH2)3OH
H2C"C(CH3)CO2(CH2)3OH
130.14
144.17
HOC5H4N
HOC5H4N
HOC5H4N
95.10
95.10
95.18
24, 1469
24, 1532
244 dec
1.596820
⬎110
36–37
182–184
233 dec
⫺40
⫺46
10350mm
221
76
129
11515mm
⬎110
148
1.444020
231.8
138
1.044
1.066
1.445020
1.447020
775mm
570.5mm
89
96
21, 43
misc aq, alc; s eth
misc aq, alc, acet; 2,3
eth; i bz, PE
v s alc, eth; sl s aq
v s alc, eth; sl s aq
1.025220
20
105–107
126–129
280–281
1513mm
23012mm
misc aq, alc
aq, alc, bz, sl s eth
v s aq, alc; sl s eth
v s aq; i alc, bz, eth
1-Hydroxy-2-propanone, h90
3-Hydroxypropionitrile, c323
1-(2-Hydroxy-1-propoxy)-2-propanol, b204
3-Hydroxy-1-propyne, p249
RIGHT
␣-Hydroxy-␣-phenylacetophenone, b46
3-(p-Hydroxyphenyl)alanine, t455
2-Hydroxy-2-phenylbenzeneacetic acid, b37
3-Hydroxy-1-propanesulfonic acid ␥-sultone, p197
2-Hydroxypropanoic acid, L1, L2
1-Hydroxy-2-naphthalenecarboxylic acid, h158
2-Hydroxy-1-naphthalenecarboxylic acid, h159
3-Hydroxy-2-naphthalenecarboxylic acid, h160
6-Hydroxynicotinic acid, h182
Hydroxynitroanilines, a238, a239, a240
s alk, acid; v sl s aq,
alc, acet, bz, eth
DEAN 37261 (McGHP)
h168
ROTATED
h152
h156
h161
h171
INTERACTIVE
No.
Name
h182
2-Hydroxypyridine-5carboxylic acid
3-Hydroxypyridine-Noxide
8-Hydroxyquinoline
8-Hydroxyquinoline-5sulfonic acid
DL-Hydroxysuccinic
acid
h183
h184
h185
h186
1.244
h188
i1
i2
i3
i4
N-Hydroxysuccinimide
Icosane
1-Icosene
1H-Imidazole
2-Imidazolidinethione
i5
i6
2-Imidazolidone
3,3⬘-Iminobis(N,N-dimethyl)propylamine
Iminodiacetic acid
Iminodiacetonitrile
Iminodibenzyl
Indane
i7
i8
i9
i10
i11
i12
i13
139.11
(HO)C5H4N"O
111.10
Density,
g/mL
Refractive
index
Melting
point,⬚C
72–74
⬎300
HO2CCH(OH)CH2CO2H
134.09
3, 435
131–133
HO2CCH(OH)CH2CO2H
134.09
3, 419
100
115.09
282.56
280.54
68.08
102.16
21, 380
1, 174
13, 881
23, 45
24,4
86.09
187.33
24, 16
43, 565
133.10
95.11
195.27
118.18
4, 365
4, 367
HO2CCH2NHCH2CO2H
NCCH2NHCH2CN
134.18
132.16
178.14
116.16
117.15
175.19
Solubility in 100
parts solvent
sl s aq, alc, eth
190–192
21, 91
22, 407
HN[(CH2)3N(CH3)2]2
Flash
point,⬚C
⬎300
22, 215
145.16
225.22
CH3(CH2)18CH3
CH3(CH2)17CH"CH2
Boiling
point,⬚C
Merck:
12, 4966
6, 575
7, 360
Merck:
12, 6645
5, 515
20, 304
22, 66
0.777737
1.434640
95–98
36.4
28.7
90–91
203–204
1.449020
133–135
⫺78
0.963920
4
1.538320
243 dec
77
105–108
⫺51.4
1.109045
4
1.56145
0.996820
4
1.0643
1.576220
1.60960
0.841
267742mm
v s alc, acet, bz, chl
v s aq; sl s alc, eth
56 aq; 45 EtOH; 18
acet; 0.8 eth; 23
diox
36 aq; 87 EtOH; 61
acet; 2.7 eth; 75
diox
v s aq
343.8
342.4
257
⬎112
13120mm
98
145
v s aq, alc, chl, eth
2 aq; s alc, pyr; i bz,
acet, chl, eth
v s aq, hot alc
2 aq; v sl s bz, eth
s aq, alc; sl s eth
178
50
s alc, chl, eth; i aq
51–53
40–42
dec 241
255
243–245
⬎110
111
v s alc, eth; sl s aq
s alc, eth; sl s aq
v s aq; s alc
⫺1.8
52.54
168–170
181.6
253–254
58
⬎110
misc alc, bz, chl, eth
s hot aq, bz, eth
v s alc; s acet, eth
INTERACTIVE
i14
i15
i16
5-Indanol
1-Indanone
1,2,3-Indantrione
hydrate
Indene
Indole
Indole-3-acetic acid
HO(C5H3N)CO2H
Beilstein
reference
ROTATED
(⫺)-Hydroxysuccinic
acid
Formula
weight
LEFT
h187
Formula
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Indole-2,3-dione
Indoline
Inositol
Iodoacetamide
Iodoacetic acid
147.13
119.17
180.16
184.96
185.95
ICH2CONH2
ICH2CO2H
Icosane, e1
Imidodicarbonic diamide, b238
Imidole, p279
21, 432
20, 257
62, 1157
2, 223
2, 222
203.5 dec
1.063
1.752
1.590620
221
225
93–96
79–82
Indalone, b450
Indanamine, a195, a196
1.245
h184
h185
i11
Indonaphthene, i14
5-Iodoanthranilic acid, a199
i3
i4
i12
i5
i13
i9
RIGHT
i10
h188
s hot aq, hot alc, alk
sl s aq
14 aq; sl s alc; i eth
s hot aq
s aq, alc; v sl s eth
92
DEAN 37261 (McGHP)
i17
i18
i19
i20
i21
i14
ROTATED
i15
i16
i17
i18
i19
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
1.246
219.03
204.01
322.10
248.02
184.02
184.02
210.06
268.19
296.24
155.97
12, 670
5, 215
5, 218
9, 363
1, 123
1, 123
52, 13
1, 168
11, 67
1, 96
1.821
1.830820
1.682020
1.620020
2.24925
4
1.615420
1.592020
1.62615
15
1.25720
4
1.201
1.935820
1.499920
1.499120
1.547220
1.485020
1.4844
1.513020
i32
i33
2-Iodoethanol
Iodoform
ICH2CH2OH
CHI3
171.97
393.73
1, 339
1, 73
2.219720
4
4.008
1.569420
i34
i35
i36
i37
i38
1-Iodoheptane
1-Iodohexadecane
1-Iodohexane
1-Iodomethane
1-Iodo-2-methylpropane
2-Iodo-2-methylpropane
1-Iodo-3-nitrobenzene
1-Iodo-4-nitrobenzene
1-Iodononane
1-Iodooctadecane
1-Iodooctane
1-Iodopentane
1-Iodopropane
2-Iodopropane
3-Iodo-1-propene
5-Iodosalicylic acid
CH3(CH2)6I
CH3(CH2)15I
CH3(CH2)5I
CH3I
(CH3)2CHCH2I
226.10
352.35
212.08
141.94
184.02
1, 155
1, 172
1, 146
1, 69
1, 128
1.37320
4
1.121
1.43720
4
2.278920
4
1.603520
1.490020
1.480620
1.492020
1.530820
1.496020
⫺48
23
(CH3)3CI
184.02
13, 326
1.57100
1.491820
IC6H4NO2
IC6H4NO2
CH3(CH2)8I
CH3(CH2)17I
CH3(CH2)7I
CH3(CH2)4I
CH3CH2CH2I
(CH3)2CHI
ICH2CH"CH2
IC6H3(OH)CO2H
249.01
249.01
254.18
380.40
240.13
198.06
169.99
169.99
167.97
264.02
5, 253
5, 252
1, 166
1, 173
1, 160
1, 133
1, 113
1, 114
1, 202
10, 112
1.947750
4
i39
i40
i41
i42
i43
i44
i47
i48
i49
i50
i51
25
⫺31
163–165
162–164
⫺103.5
⫺104.0
⫺3
⫺111
14615mm
188
⬎110
74
130–131
120
180
13215mm
16015mm
72.4
33
23
1.487020
1.33020
4
1.51220
4
1.748920
1.704220
1.84522
4
1.488920
1.495420
1.505820
1.499220
1.554021
s alc, eth; sl s aq
i aq; s alc, eth
i aq; s alc, eth
i aq; s eth
i aq; s alc, eth
0.4 aq; misc alc, bz,
chl, eth
s aq; v s alc, eth
1.4 alc; 10 chl; 13 eth;
v s bz, acet
i aq; s alc, eth
755mm
65
none
⫺66.5
⫺93.5
204
20710mm
179–180
42.5
121
78
⬎110
61
none
12
⫺38
100
7
dec aq; misc alc, eth
36–38
175–177
280
289772mm
1088mm
1972mm
226
155
102
89.5
103
71
⬎110
85
⬎110
95
51
44
42
18
i aq; s alc, eth
120–123
1.288
⬎110
⬎110
none
i aq; s alc, eth
misc alc, chl, eth
33–35
⫺46
⫺85
⫺101
⫺90
⫺99
189–191
i aq
1.4 aq; misc alc, eth
i aq; misc alc, eth
s alc, eth
sl s aq; s alc, eth
0.1 aq; misc alc, eth
0.14 aq; misc alc, eth
misc alc, chl, eth
v s alc; i bz, chl
INTERACTIVE
IC6H4NH2
C6H5I
C6H5I(O2CCH3)2
IC6H4CO2H
HC3CH2CH2CH2I
CH3CH2CH(I)CH3
C6H11I
CH3(CH2)9I
CH3(CH2)11I
CH3CH2I
Solubility in 100
parts solvent
ROTATED
3-Iodoaniline
Iodobenzene
Iodobenzene diacetate
2-Iodobenzoic acid
1-Iodobutane
2-Iodobutane
Iodocyclohexane
1-Iododecane
2-Iodododecane
Iodoethane
Flash
point,⬚C
LEFT
i22
i23
i24
i25
i26
i27
i28
i29
i30
i31
Boiling
point,⬚C
2-Iodothiophene
2-Iodotoluene
3-Iodotoluene
4-Iodotoluene
Iodotrimethylsilane
1-Iodoundecane
␣-Ionone
␤-Ionone
Isatoic anhydride
D-(⫺)-Isoascorbic acid
DL-Isoborneol
Isobutyl acetate
Isobutyl acetoacetate
Isobutyl acrylate
Isobutylamine
Isobutylbenzene
Isobutyl chloroformate
Isobutyl formate
Isobutyl isobutyrate
Isobutyl methacrylate
IC6H4CH3
IC6H4CH3
IC6H4CH3
(CH3)3SiI
CH3(CH2)10I
(CH3)2CHCH2O2CCH3
CH3COCH2CO2CH2CH(CH3)2
H2C"CHCO2CH2CH(CH3)2
(CH3)2CHCH2NH2
C6H5CH2CH(CH3)2
ClCO2CH2CH(CH3)2
HCO2CH2CH(CH3)2
(CH3)2CHCH2O2CH(CH3)2
H2C"C(CH3)CO2CH2CH(CH3)2
210.04
218.04
218.04
218.04
200.10
282.21
192.30
192.30
163.13
176.12
154.25
116.16
158.20
128.19
73.14
134.22
136.58
102.13
144.22
142.19
17, 34
5, 310
5, 311
5, 312
11, 66
7, 168
7, 167
27, 264
62, 80
2, 131
23, 1227
4, 163
5, 414
3, 12
2, 21
2, 291
23, 1287
1.902
1.713
1.698
1.652020
1.607920
1.604020
1.40620
4
1.220
0.93220
0.94617
1.471020
1.484920
1.498020
1.52117
34–36
0.871220
0.980
0.890
0.72420
4
0.853220
1.053
0.877620
0.854220
0.88225
15
1.390220
1.424020
1.4140
1.397220
1.486620
1.407020
1.385520
1.399920
1.417025
1,3-Isobenzofurandione, p169
Isobutane, m390
Isobutene, m399
␣-Isobutoxy-␣-phenylacetophenone, b48
Isobutylacetylene, m372
Isobutyl alcohol, m397
233 dec
169 dec
214 subl
⫺99
⫺86.6
⫺51.5
⫺95.5
⫺80.7
7315mm
211
8210mm
211
106
1305mm
12411mm
12812mm
71
90
82
90
⫺31
⬎110
104
⬎110
116.5
10022mm
132
68
172.8
128.8
98.4
148.5
155
18
78
32
⫺9
55
27
10
38
41
v s eth
i aq; s alc, eth
i aq; misc alc, eth
s alc, bz, chl, eth
s alc, bz, chl, eth
sl s aq, hot alc, acet
s aq, alc, acet, pyr
v s alc, chl, eth
0.7 aq; v s alc
misc aq, alc, acet, eth
misc alc, eth
misc bz, chl, eth
1 aq; misc alc, eth
0.5 aq; misc alc
misc alc, eth
Isobutyl bromide, b371
Isobutyl chloride, c179
Isobutyl chlorocarbonate, i68
Isobutyl ether, d458
Isobutyl mercaptan, m395
Isobutyl methyl ketone, m370
RIGHT
Isatin, i17
Isoamyl acetate, i91
Isoamyl alcohol, m163
sec-Isoamyl alcohol, m164
Isoamyl bromide, b362
Isoamyl chloride, c169a
Isoamyl nitrite, i92
⫺40
DEAN 37261 (McGHP)
1.247
i52
i53
i54
i55
i56
i57
i58
i59
i60
i61
i62
i63
i64
i65
i66
i67
i68
i69
i70
i71
ROTATED
i52
i58
i59
i60
i61
i62
INTERACTIVE
No.
i72
i73
i74
i75
i76
Name
Formula
Formula
weight
178.30
(CH3)2CHCH2OCH"CH2
(CH3)2CHCHO
100.16
72.11
i80
i81
Isobutyramide
Isobutyric acid
(CH3)2CHCONH2
(CH3)2CHCO2H
i82
i83
i84
i85
i86
i87
i88
i89
i90
Isobutyric anhydride
Isobutyronitrile
Isobutyrophenone
Isobutyryl chloride
Isodecyl acrylate
Isodecyl methacrylate
L-Isoleucine
Isooctyl acrylate
Isooctyl diphenyl
phosphite
Isopentyl acetate
Isopentyl nitrite
Isophorone
Isophorone diisocyanate
Isopropenyl acetate
3-Isopropenyl-␣,␣-dimethylbenzyl isocyanate
2-Isopropoxyethanol
1.248
i91
i92
i93
i94
i95
i96
i97
1.01520
4
0.87022
4
0.88804
1.402820
1.371522
1.397420
0.880
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
123
67
137
21
⫺21
26
1.40020
190–191
60
0.930
1.396020
137
39
13, 1862
1, 671
0.770220
20
0.798820
4
1.395020
1.372320
⫺112
⫺65.9
83.4
64.5
⫺13
⫺18
(CC)
0.2 aq
11 aq; misc alc, bz,
acet, chl, eth
87.12
88.11
2, 293
2, 288
1.013
0.968120
1.392520
127–129
⫺46
216–220
154
56
17 aq; misc alc, chl,
eth
[(CH3)2CHCO]2O
(CH3)2CHCN
C6H5COCH(CH3)2
(CH3)2CHCOCl
H2C"CHCO2C10H21
H2C"C(CH3)CO2C10H21
C2H5CH(CH3)CH(NH2)CO2H
H2C"CHCO2C8H17
(C6H5O)2POC8H17
158.20
69.11
148.21
106.55
212.34
226.36
131.18
184.25
346.41
2, 292
2, 294
7, 316
2, 293
0.954
0.770420
0.98820
1.017
0.875
0.878
1.406220
1.372020
1.5172
1.407320
1.442020
1.443020
⫺56
⫺71.5
59
8
84
1
106
⬎110
0.880
1.045
1.437020
1.522020
182
104
217
91–93
12110mm
12610mm
subl 168
12520mm
188
CH3CO2CH2CH2CH(CH3)2
ONOCH2CH2CH(CH3)2
130.19
117.15
138.21
222.29
2, 132
1, 402
7, 65
0.87615
4
0.872
0.95520
1.049
1.400720
1.386020
1.475920
1.484120
142
99
215.2
15915mm
25
10
84
⬎110
CH3CO2C(CH3)"CH2
H2C"C(CH3)C6H4C(CH3)2NCO
100.12
201.27
22, 278
0.909
1.108
1.400520
1.530020
94
268–271
18
⬎110
(CH3)2CHOCH2CH2OH
104.15
12, 519
0.903
1.410420
4413mm
45
4, 454
⫺71
ca. 20
⫺90
288 dec
⫺78.5
⫺8.1
i aq; misc alc, eth
misc alc; sl s aq (dec)
i aq; misc alc
v s alc, eth; sl s aq
dec aq, dec alc; s eth
4 aq; sl s hot alc
80
0.25 aq; misc alc, eth
misc alc, eth; sl s aq
1.2 aq
INTERACTIVE
(CH3)2CHCH2Si(OCH3)3
i77
1, 377
1, 377
2, 241
Refractive
index
ROTATED
119.12
103.12
130.19
340.57
220.39
Density,
g/mL
LEFT
(CH3)2CHCH2ONO2
(CH3)2CHCH2ONO
C2H5CO2CH2CH(CH3)2
CH3(CH2)16CO2CH2CH(CH3)2
(CH3)2CHCH2Si(OC2H5)3
i78
i79
Isobutyl nitrate
Isobutyl nitrite
Isobutyl propionate
Isobutyl stearate
Isobutyltriethoxysilane
Isobutyltrimethoxysilane
Isobutyl vinyl ether
Isobutyraldehyde
Beilstein
reference
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
i99
i100
i101
i102
i103
i104
i105
i106
i107
i108
3-Isopropoxypropylamine
Isopropyl acetate
Isopropylamine
2-Isopropylaniline
4-Isopropylbenzaldehyde
Isopropylbenzene
4-Isopropylbenzyl
alcohol
N-Isopropylbenzylamine
Isopropyl butyrate
Isopropyl chloroacetate
Isopropylcyclohexane
(CH3)2CHO(CH2)3NH2
117.19
43, 739
0.845
1.419520
(CH3)2CHO2CCH3
(CH3)2CHNH2
(CH3)2CHC6H4NH2
(CH3)2CHC6H4CHO
102.13
59.11
135.2
148.21
2, 130
4, 152
12, 1147
7, 318
0.871820
0.68625
4
0.955
0.977
1.377020
1.371125
1.547720
1.529820
(CH3)2CHC6H5
(CH3)2CHC6H4CH2OH
120.20
150.22
5, 393
6, 543
0.86420
4
0.98215
1.491520
1.520620
C6H5CH2NHCH(CH3)2
149.24
0.892
CH3CH2CH2CO2CH(CH3)2
ClCH2CO2CH(CH3)2
130.19
136.58
2, 271
2, 198
C6H11CH(CH3)2
126.24
5, 41
1.249
39
⫺73
⫺95
89
31.7
222
236
2
⫺37
95
93
3 aq; misc alc, eth
misc aq, alc, eth
⫺96
28
152–154
248.4
36
⬎110
s alc, bz, eth
misc alc, eth; i aq
1.502520
200
87
0.859
1.096
1.393220
1.419020
131
149–150
30
70
0.802320
4
1.439920
155
35
Isonicotinaldehyde, p263
Isonicotinic acid, p267
Isonicotinonitrile, c330
Isooctane, t381
Isopentane, m158
Isopentyl alcohol, m163
Isopentyl isopentanoate, m177
Isopentyl isovalerate, m177
Isophorone, t364
Isophthalic acid, b17
Isophthalonitrile, d283
Isophthaloyl dichloride, b15
Isoprene, m157
⫺90
Isopropanolamine, a263
Isopropenyl acetate, p207
Isopropenylacetylene, m174
Isopropenyl methyl ether, m106
Isopropylacetylene, m178
Isopropylacrylic acid, m369
Isopropyl alcohol, p202
Isopropyl bromide, b401
Isopropyl chloride, c226
Isopropyl cyanide, i83
Isopropylethanol, m164
Isopropyl ether, d476
Isopropylethylene, m167
v s alc, eth
RIGHT
Isobutyl octadecanoate, i75
Isobutyraldehyde, m389
Isobutyric acid, m402
Isocapronitrile, m361
Isocinchomeronic acid, p269
Isocrotonic acid, b483
Isocumene, p225
5-Isocyanato-1-(isocyanatomethyl)-1,3,3-trimethylcyclohexane,
i94
Isodurene, t98
Isoeugenol, m108
Isohexane, m357
Isoleucinol, a211
Isomesityl oxide, m370
7985mm
DEAN 37261 (McGHP)
i98
ROTATED
i93
i94
INTERACTIVE
No.
i109
i110
i111
i112
i113
1.250
i114
i115
i116
i117
i118
i120
i121
i123
i124
i125
1-Isopropyl-4-nitrobenzene
Beilstein
reference
22, 336
CH3(CH2)14CO2CH(CH3)2
298.51
(CH3)2C[C6H2(Br)2OCH2CH2OH]2
632.01
[(C10H21O)2POC6H4]2C(CH3)2
917.34
(CH3)2C(C6H10OH)2
240.39
62, 761
(CH3)2C(C6H4OH)2
228.29
6, 1011
(CH3)2CHCNO
(CH3)2CHO2CCH(OH)CH3
(CH3)2CHC6H3(CH3)NH2
110.16
85.11
132.16
149.24
23, 83
4, 155
3, 282
(CH3)2CHC6H4CH3
134.21
(CH3)2CHC6H4CH3
Density,
g/mL
Refractive
index
0.862
1.438520
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
⬎110
107
0.964
1.498020
336
⬎110
23414mm
⬎110
137–140
2204mm
129–131
256–260
74–75
166–168
⫺2
57
41
0.866
0.99820
20
0.957
1.382520
1.408225
1.544020
5, 419
0.876620
4
1.500620
⫺71.5
178.2
misc alc, eth
134.21
5, 419
0.861020
4
1.493020
⫺63.8
175.1
misc alc, eth
(CH3)2CHC6H4CH3
134.21
5, 420
0.857320
4
1.490920
⫺68.9
177.1
(CH3)2CHC6H3(CH3)OH
150.22
6, 532
0.92580
4
51.5
232.5
(CH3)2CHC6H3(CH3)OH
150.22
62, 491
111–114
(CH3)2CHC6H3(CH3)OH
150.22
6, 526
51
(CH3)2CHONO2
(CH3)2CHONO
105.09
89.09
(CH3)2CHC6H4NO2
165.19
1, 363
Merck:
12, 5235
52, 308
47
s aq, alc, eth
misc alc, eth
i aq; v s alc, chl, eth
⬎110
1.03619
19
0.84425
4
1.39120
1.352020
102
39752mm
12
1.090
1.538020
10711mm
⬎110
INTERACTIVE
i126
Formula
weight
ROTATED
i122
Isopropyl
hexadecanoate
4,4⬘-Isopropylidenebis(2,6-dibromophenoxy)ethanol
4,4⬘-Isopropylidenebis(diisodecyl
phenyl phosphite)
4,4⬘-Isopropylidenedicyclohexanol
4,4⬘-Isopropylidenediphenol
2-Isopropylimidazole
Isopropyl isocyanate
Isopropyl S-(⫺)-lactate
2-Isopropyl-6-methylaniline
2-Isopropyl-1-methylbenzene
3-Isopropyl-1-methylbenzene
4-Isopropyl-1-methylbenzene
2-Isopropyl-5-methylphenol
4-Isopropyl-3-methylphenol
5-Isopropyl-3-methylphenol
Isopropyl nitrate
Isopropyl nitrite
Formula
LEFT
i119
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
2-Isopropylphenol
3-Isopropylphenol
4-Isopropylphenol
4-Isopropylpyridine
Isopropyl tetradecanoate
i132
i133
k1
k2
Isopulegol
Isoquinoline
Ketene
8-Ketotricyclo[5.2.1.02,6]decane
DL-Lactic acid
L-(⫹)-Lactic acid
␣-Lactose
L1
L2
L3
(CH3)2CHC6H4OH
(CH3)2CHC6H4OH
(CH3)2CHC6H4OH
(CH3)2CH(C5H4N)
(CH3)2CHO2C(CH2)12CH3
H2C"C"O
CH3CH(OH)CO2H
CH3CH(OH)CO2H
136.19
136.19
136.19
121.18
270.46
6, 504
6, 505
6, 505
20, 248
23, 923
1.01220
0.994
0.99020
0.938
0.850
1.525920
1.525020
154.25
129.16
42.04
150.22
6, 65
20, 380
1, 724
72, 133
0.912
1.091030
4
1.472520
1.620830
1.063
1.502020
90.08
90.08
342.32
3, 268
3, 261
31, 408
1.24915
4
1.206025
4
1.427020
1.498020
1.435020
1.251
Isopropyl myristate, i131
Isopropyl palmitate, i109
Isopropyltoluenes, i118, i119, i120
Isopseudocumenol, t385
Isovaleraldehyde, m181
Isovaleric acid, m184
Isovaleronitrile, m185
Isopropylidone acetone, m370
Isopropyl iodide, i49
Isopropyl mercaptan, p199
1-Isopropyl-4-methyl-1,3-cyclohexadiene, t10
2-Isopropyl-5-methylcyclohexanol, m12
1-Isopropyl-4-methyl-1,4-cyclohexadiene, t11
Isopropyl methyl ketone, m165
15–16
25
59–61
ca. 3
26.5
⫺151
16.8
53
202
212–213
228
212
173
19320mm
88
104
misc alc, eth
316 alc; 350 eth
66
⬎110
9112mm
243.5
⫺49.8
13230mm
78
107
12214mm
11912mm
⬎110
⬎110
s caster oil, cottonseed
oil, acet, EtOAc,
EtOH, toluene, mineral oil
v sl s aq
sl s aq; s acid
s acet, eth; dec aq
101
DEAN 37261 (McGHP)
i127
i128
i129
i130
i131
s aq, alc; i chl, PE
v s aq, alc, eth
20 aq; v sl s alc
Isovaleryl chloride, m186
Itaconic acid, m253
Keto-, see oxo2-Ketobutyric acid, o60
5-Keto-1,7,7-trimethylnorcamphane, c3
4-Ketovaleric acid, o63
Lactonitrile, h172
RIGHT
ROTATED
i114
i132
i133
k2
L3
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
Name
1.252
R-(⫹)-Limonene
S-(⫺)-Limonene
(⫹)-Limonene oxide
Linalool
Linalyl acetate
S-(⫹)-Lysine
Maleic acid
m2
Maleic anhydride
m3
Malonic acid
m4
m5
m6
m7
m8
m9
m10
m11
m12
m13
m14
Malonodiamide
Malononitrile
Malonyl dichloride
D-(⫹)-Maltose hydrate
DL-Mandelic acid
Mandelonitrile
Mannitol
D-(⫹)-Mannose
(⫺)-Menthol
(⫺)-Menthone
S-(⫹)-Menthyl acetate
Density,
g/mL
Refractive
index
1.52520
Melting
point,⬚C
(CH3)2CHCH2CH(NH2)CO2H
(CH3)2CHCH2CH(NH2)CO2H
342.32
131.18
131.18
31, 408
4, 447
4, 437
H2N(CH2)4CH(NH2)CO2H
HO2CH"CHCO2H
136.24
136.24
152.24
154.25
196.29
146.19
116.07
5, 133
5, 136
17, 44
1, 462
2, 141
4, 435
2, 748
1.590
212 dec
130.5
98.06
17, 432
1.48
52.8
HO2CCH2CO2H
104.06
2, 566
1.63
135–137
H2NCOCH2CONH2
NCCH2CN
ClCOCH2COCl
102.09
66.06
140.95
360.32
152.15
133.15
182.17
180.16
156.27
154.25
198.31
2, 582
2, 589
21, 252
31, 386
10, 192
10, 193
1, 534
31, 284
6, 28
7, 38
6, 32
1.191020
4
1.448619
4
17
1.540
20
1.3004
1.117
1.5220
1.5420
0.89015
15
0.89520
4
1.448020
C6H5CH(OH)CO2H
C6H5CH(OH)CN
202
dec 332
293 dec
1.29318
0.841120
4
0.84120
4
0.929
0.86515
0.89520
4
1.4730
1.474620
1.466120
1.461520
1.446020
1.414634
1.462020
1.531520
1.45825
1.451020
⫺96.5
⫺96.5
172–175
32–34
119–121
120–122
⫺10
166–168
128–130
41–43
⫺6
Boiling
point,⬚C
Flash
point,⬚C
subl 293
subl 145
178
178
11450mm
197720mm
220
49
48
65
76
90
202
103
220
5519mm
dec 130
112
47
170
2903.5mm
97
212
207
229–230
93
72
77
Solubility in 100
parts solvent
45 aq; i alc, eth
1 aq; 0.13 alc; i eth
2.4 aq25; 0.07 alc; 1
HOAc; i eth
misc alc, eth
misc alc, eth
misc alc, eth
misc alc, eth
v s aq; sl s alc; i eth
70 aq; 70 alc; s acet,
HOAc; sl s eth
s aq (to acid), alc (to
ester); 227 acet; 53
chl; 50 bz; 112
EtOAc
154 aq; 42 alc; 8 eth;
14 pyr
9 aq; i alc, eth
13 aq, 40 alc; 20 eth
dec hot aq; s eth
v s aq; sl s alc; i eth
16 aq; 100 alc; s eth
v s alc, cho, eth; i aq
18 aq; 1.2 alc; i eth
250 aq; 28 pyr; 0.8 alc
v s alc, chl, eth, PE
misc alc, eth; sl s aq
INTERACTIVE
L7
L8
L9
L10
L11
L12
m1
Beilstein
reference
ROTATED
␤-Lactose
DL-Leucine
L-Leucine
Formula
weight
LEFT
L4
L5
L6
Formula
DEAN 37261 (McGHP)
Limonene, m313a
Linoleic acid, o1
Linolenic acid, o7
Luminol, a151
2,6-Lupetidine, d672
␤-Lutidine, e257
Lutidines, d685 thru d689
Maleic hydrazide, d447
Malic acid, h186, h187
Malonaldehyde bis(dimethyl acetal), t92
Malonamide nitrile, c319
Lauraldehyde, d817
Lauric acid, d809
Lauryl alcohol, d810
Laurylamine, d818
Lauryl bromide, b327
Lauryl mercaptan, d808
Lauryl methacrylate, d819
Lauryl sulfate, d820
Lepidine, m421
Leucinol, a212
Levulinic acid, o63
Malonic acid diamide, m4
Malonylurea, b1
Margaryl alcohol, h1a
Mellitic acid, b20
MEM chloride, m74
Menadione, m321
1,8-Mentanediamine, d51
p-Mentha-1,8-diene, L17, L18
p-Mentha-6,8-dien-2-one, c20
Mercaptobenzene, t156
1.253
L4
L9
m10
m11
L10
L11
m2
RIGHT
L7, L8
ROTATED
m7
m12
m13
m14
INTERACTIVE
No.
m15
m16
m17
m18
m19
m20
m21
m22
m23
1.254
m24
m34
m35
Beilstein
reference
Density,
g/mL
Refractive
index
1.040
1.325
1.542020
1.503020
HSCH2CO2H
275.40
92.12
150.20
143, 885
3, 245
24, 119
HSC6H4CO2H
154.19
10, 125
167.25
27, 185
1.4220
4
HSCH2CH2OH
HSCH2CH(OH)CH2OH
78.13
108.16
1, 470
1, 519
1.114320
4
1.29514
14
1.500620
1.524320
CH3CH(SH)CO2H
106.14
3, 289
1.22015
4
1.480920
HSCH2CH2CO2H
106.14
3, 299
1.218
1.491120
HS(CH2)3Si(OCH3)3
196.34
1.03920
4
1.444020
HO2CCH2CH(SH)CO2H
150.15
119.21
70.09
85.11
86.09
154.17
67.91
104.54
172.18
H2C"C(CH3)CHO
H2C"C(CH3)CONH2
H2C"C(CH3)CO2H
[H2C"C(CH3)CO]2O
H2C"C(CH3)CN
H2C"C(CH3)COCl
(CH3CO2)2CHC(CH3)"CH2
CH4
3, 439
27, 140
1, 731
22, 399
2, 421
23, 1293
2, 423
22, 394
24, 292
16.04
1, 56
CH3SO3H
(CH3SO2)2O
96.10
174.19
4, 4
4, 5
CH3SO2Cl
114.55
4, 5
Melting
point,⬚C
⫺16.5
301–305
Boiling
point,⬚C
1793mm
965mm
Flash
point,⬚C
⬎110
⬎110
165–168
180–181
0.847
1.416020
1.015320
4
1.035
0.800120
4
1.070
1.039
1.431420
1.453020
1.400720
1.442020
1.424520
Solubility in 100
parts solvent
misc aq, alc, bz, eth
sl s aq; s alc
v s alc, HOAc
156.9
1185mm
73
⬎110
2 alc; 1 eth; 10 acet; 1
bz; s alk; i aq
misc aq, alc, bz, eth
misc alc; v s acet
10–14
10216mm
87
misc aq, alc, eth, acet
17–19
11115mm
93
198
48
5–7
105–107
⫺81
109–111
16
dec
50 aq; 50 alc; s eth
69
⫺15
⫺15
163
8713mm
90.3
95–96
191
77
84
1.1
2
83
⫺182.5
⫺161.5
⫺35.8
6 aq; misc alc, eth
s alc; sl s eth
9 aq; misc alc, eth
2.6 aq; misc acet, bz
0.7168
g/L
0.4240bp
1.481218
4
3.3 mL aq; 47 mL alc
1.430320
20
71
16710mm
13810mm
⬎110
1.5 bz; misc aq
v s aq (dec)
1.480518
4
1.451820
⫺32
161
⬎110
s alc, eth
INTERACTIVE
m36
Methanesulfonic acid
Methanesulfonic
anhydride
Methanesulfonyl
chloride
Formula
weight
ROTATED
m33
Menthyl anthranilate
Mercaptoacetic acid
2-Mercaptobenzimidazole
2-Mercaptobenzoic
acid
2-Mercaptobenzothiazole
2-Mercaptoethanol
3-Mercapto-1,2propanediol
2-Mercaptopropionic
acid
3-Mercaptopropionic
acid
(3-Mercaptopropyl)trimethoxysilane
Mercaptosuccinic acid
2-Mercaptothiazoline
Methacrylaldehyde
Methacrylamide
Methacrylic acid
Methacrylic anhydride
Methacrylonitrile
Methacryloyl chloride
Methallylidene
diacetate
Methane
Formula
LEFT
m25
m26
m27
m28
m29
m30
m30a
m31
m32
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Methanethiol
CH3SH
48.11
1, 288
m38
Methanol
CH3OH
32.04
1, 273
m39
m40
m41
m42
m43
m44
m45
m46
1.255
m47
m48
m49
m50
Methanol-d
Methanol-d4
Methanol-13C
DL-Methionine
Methoxyacetic acid
2⬘-Methoxyacetophenone
3⬘-Methoxyacetophenone
4⬘-Methoxyacetophenone
3-Methoxyacrylonitrile
2-Methoxyaniline
3-Methoxyaniline
4-Methoxyaniline
3
1.966
g/L
0.791320
4
20
4
1.328420
20
⫺123
6.0
⫺97.7
64.7
11
⫺110
65.5
65.4
64
11
11
12
2.3 aq; v s alc, eth
misc aq, alc, bz, chl,
eth
misc aq, alc, eth
misc aq, alc, eth
CH3OD
CD3OD1
13CH OH
3
CH3SCH2CH2CH(NH2)CO2H
CH3OCH2CO2H
CH3OC6H4COCH3
33.05
36.07
33.03
149.21
90.08
150.18
1 , 1186
13, 1187
13, 1187
42, 938
3, 232
8, 85
0.8127
0.888
0.815
1.340
1.174
1.09020
4
1.3270
1.325620
1.329020
1.415820
1.539320
202–204
13118mm
⬎110
108
CH3OC6H4COCH3
150.18
8, 86
1.094
1.541020
239–241
⬎110
s aq
CH3OC6H4COCH3
150.18
8, 87
1.08241
4
1.5335
36–38
15426mm
⬎110
v s alc, eth
CH3OCH"CHCN
CH3OC6H4NH2
CH3OC6H4NH2
CH3OC6H4NH2
83.09
123.16
123.16
123.16
13, 358
13, 404
13, 435
0.990
1.09815
15
1.096
1.087
1.455020
1.573020
1.579420
5–6
⫺10
57–60
225
251
240–243
Metanilic acid, a116
Methacholine chloride, a49
Methacrolein, m27
Methacrolein diacetate, m32
Methallyl alcohol, m400
Methallyl chloride, c182
Mesidine, t335
Mesitol, t387
Mesitylene, t359
Mesityl oxide, m370
Mesoxylurea, a73
Mesyl chloride, m36
⫺97.8
281 dec
76
98
⬎110
3 aq; i eth; v sl s alc
misc aq, alc, eth
DEAN 37261 (McGHP)
m37
i aq; misc alc, eth
s alc, acid; sl s aq
v s alc; sl s aq
Methanal, f31
Methanoic acid, f36
Methenamine, h49
Malononitrile dimer, a267
Methone, d596
Methoxyacetaldehyde dimethyl acetal, t340
RIGHT
ROTATED
m15
m17
m19
m26
INTERACTIVE
No.
m51
m52
m53
m54
m55
m56
m57
m58
1.256
m59
m60
m61
m67
m68
m69
Beilstein
reference
Density,
g/mL
Refractive
index
CH3OC6H4CHO
136.15
8, 43
1.127
1.56020
CH3OC6H4CHO
136.15
8, 59
1.119
1.553320
CH3OC6H4CHO
136.15
8, 67
1.119
1.571320
CH3OC6H4CONH2
CH3OC6H5
CH3OC6H4SO2Cl
151.17
108.14
206.65
102, 100
6, 138
11, 243
0.994220
1.517020
CH3OC6H4CO2H
152.15
10, 64
1.180
CH3OC6H4CO2H
152.15
10, 137
CH3OC6H4CO2H
152.15
10, 154
CH3OC6H4COCl
170.60
10, 163
CH3OC6H4CH2OH
138.17
6, 897
CH3OC6H4CH2NH2
CH3OC6H4C6H5
CH3OCH(CH3)CH2CH2OH
CH3OCH"CHCOCH3
137.18
184.24
104.15
100.12
13, 606
6, 672
CH3OC6H4CH"CHCHO
162.19
(CH3)2C(OCH3)(CH2)3CH(CH3)CH2CHO
110.16
63, 367
198.22
173, 1590
186.30
104.11
194, 617
Melting
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
238
117
14350mm
⬎110
⫺1
248
108
misc alc
164–167
⫺37.5
40–43
295
153.8
108
51
⬎110
s aq; v s alc; sl s eth
1 aq; misc alc, eth
dec aq; s alc, eth
100
200
0.5 aq; v s alc, eth
104
17210mm
s hot aq, alc, eth
185
275–280
0.04 aq; v s alc, chl
1.581020
22
14514mm
87
1.10925
4
1.544220
23–25
259
⬎110
1.05015
1.023
0.922920
20
0.982
1.546220
1.610520
1.414520
1.468020
30–33
⫺85
236–237
274
161.1
200
⬎110
⬎110
46
63
44–48
1300.6mm
⬎110
148–150
36
1.3854
0.940
37–39
Boiling
point,⬚C
1.481920
⬎110
42–45
0.877
1.437420
600.45mm
98
1.092
1.409120
129–130
31
sl s alc, bz; i eth
i aq (dec); s alc (dec);
s acet, bz
i aq; s alc, eth
v s aq, alc, eth
misc aq
INTERACTIVE
m70
Formula
weight
ROTATED
m66
2-Methoxybenzaldehyde
3-Methoxybenzaldehyde
4-Methoxybenzaldehyde
4-Methoxybenzamide
Methoxybenzene
4-Methoxybenzenesulfonyl chloride
2-Methoxybenzoic
acid
3-Methoxybenzoic
acid
4-Methoxybenzoic
acid
4-Methoxybenzoyl
chloride
4-Methoxybenzyl
alcohol
4-Methoxybenzylamine
2-Methoxybiphenyl
3-Methoxy-1-butanol
4-Methoxy-3-buten-2one
2-Methoxycinnamaldehyde
1-Methoxy-1,4-cyclohexadiene
2-Methoxydibenzofuran
7-Methoxy-3,7dimethyloctanal
2-Methoxy-1,3dioxolane
Formula
LEFT
m62
m63
m64
m65
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
m73
m74
m75
m76
m77
m78
m79
m80
m81
1.257
m82
m83
m84
m85
m86
1-Methoxynaphthalene
0.964620
1.180
1.402120
1.438020
⫺85.1
124
245–250
39
⬎110
misc aq
120.15
1.03520
4
1.426420
⫺50
194
96
misc aq, alc, bz, eth,
ketones
CH3OCH2CH2OCH2Cl
124.57
1.091
1.427020
5013mm
⬎110
CH3CO2CH2CH2OCH3
CH3COCH2CO2CH2CH2OCH3
118.13
160.17
2, 141
1.004920
1.090
1.400220
1.433920
144
12020mm
49
103
misc aq
CH3OCH2CH2NH2
CH3OCH2CH2O2CCH2CN
75.11
143.14
42, 718
24, 1891
0.864
1.127
1.405420
1.434020
95
1001mm
9
⬎110
v s aq, alc
164.20
137.18
6, 970
132, 388
1.128
1.548220
CH3OC6H3(CH3)NH2
52–54
14611mm
235
⬎110
⬎110
s aq; v s alc, bz, eth
CH3OC6H3(CH3)NH2
137.18
132, 330
1.065
1.564720
13–14
248–249
⬎110
s alc
CH3OC(CH3)2CH2CH2OH
118.18
13, 2198
0.926
1.428020
173–175
71
NCCH2CO2CH(CH3)CH2OCH3
157.17
1.030
1.431020
1052mm
62
CH3OC6H3(CH3)OH
138.17
6, 878
1.092
1.537220
222
99
CH3OC6H3(CH3)(NO2)NH2
182.18
133, 1575
(CH3)2C 9 CH(OCH3)
102.13
173, 1035
0.904
1.392920
94
6
O
C10H7OCH3
158.20
6, 606
1.090
1.622020
13512mm
⬎110
CH3OCH2CH2OH
CH3OCH2CH2OCH2CO2H
76.10
134.13
CH3OCH2CH2OCH2CH2OH
Methoxyethane, e210
1, 467
33, 374
⫺70
5
168–170
RIGHT
m87
2-Methoxyethanol
2-(2-Methoxyethoxy)acetic acid
2-(2-Methoxyethoxy)ethanol
2-Methoxyethoxymethyl chloride
2-Methoxyethyl acetate
2-Methoxyethyl
acetoacetate
2-Methoxyethylamine
2-Methoxyethyl
cyanoacetate
1-Methoxy-2-indanol
2-Methoxy-5-methylaniline
4-Methoxy-2-methylaniline
3-Methoxy-3-methyl1-butanol
2-Methoxy-1-methylethyl cyanoacetate
2-Methoxy-4-methylphenol
5-Methoxy-2-methyl4-nitroaniline
1-Methoxy-2-methylpropylene oxide
DEAN 37261 (McGHP)
m71
m72
2-Methoxyethoxychloromethane, m74
ROTATED
m67
m68
m70
m79
INTERACTIVE
No.
m88
m89
m90
m91
m92
m93
m94
1.258
m95
m96
m102
m103
m104
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
C10H7OCH3
CH3OC6H3(NO2)NH2
158.20
168.15
6, 640
13, 390
73–75
140–142
CH3OC6H3(NO2)NH2
168.15
13, 389
117–119
s alc, hot bz, HOAc
CH3OC6H3(NO2)NH2
168.15
13, 521
123–126
sl s aq; s alc, eth
CH3OC6H4NO2
153.14
6, 217
CH3OC6H3(NO2)CO2H
197.15
10, 181
192–194
CH3O(C5H3N)NO2
154.13
213, 33
108–109
CH3OC6H3(NO2)CH3
167.16
6, 411
1.207
1.552520
CH3OC6H3CH2CH2NH2
151.21
13, 626
1.033
1.537920
CH3OC6H4OH
CH3OC6H4OH
CH3OC6H4OH
CH3OC6H4OCH2CH(OH)CH2OH
124.14
124.14
124.14
198.22
6, 768
6, 813
6, 843
63, 4411
1.112(lg)
1.131
1.5429
1.551020
CH3OC6H4CH2CO2H
166.18
10, 190
CH3OC6H4CH2OCH3
164.20
83, 397
CH3OC6H4CH2CN
147.18
10, 188
CH3OC6H4CH2CN
147.18
10, 191
1.085
1.530020
90.12
72.11
12, 536
1, 435
0.91920
20
0.735
1.402121
1.382020
CH3OCH2CH(OH)CH3
CH3C(OCH3)"CH2
1.252720
4
1.054
1.516120
274
Solubility in 100
parts solvent
s bz, eth, CS2
277
⬎110
267
⬎110
14020mm
⬎110
28
⬍ ⫺17.5
55–57
76–80
205
1155mm
243
82
⬎110
⬎110
86–88
1403mm
10.5
17
1.525020
13010mm
65–68
⫺97
0.17 aq; s alc, eth
1.5 aq; misc alc, eth
misc alc, eth; sl s aq
v s bz; s alk
1 aq; v s alc; s eth
⬎110
14315mm
s alc, eth
s hot bz
286–287
⬎110
120.1
34–36
33
⫺29
misc aq, acet, bz, eth
INTERACTIVE
m105
m106
Formula
weight
ROTATED
m101
2-Methoxynaphthalene
2-Methoxy-4-nitroaniline
2-Methoxy-5-nitroaniline
4-Methoxy-2-nitroaniline
2-Methoxynitrobenzene
4-Methoxy-3-nitrobenzoic acid
2-Methoxy-5-nitropyridine
4-Methoxy-2-nitrotoluene
4-Methoxyphenethylamine
2-Methoxyphenol
3-Methoxyphenol
4-Methoxyphenol
3-(4-Methoxyphenoxy)-1,2propanediol
4-Methoxyphenylacetic acid
2-Methoxyphenylacetone
2-(Methoxyphenyl)acetonitrile
4-(Methoxyphenyl)acetonitrile
1-Methoxy-2-propanol
2-Methoxypropene
Formula
LEFT
m97
m98
m99
m100
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
m108
m109
m110
m111
m112
m113
m114
1.259
m115
m116
m117
m118
m119
m120
m121
m122
m123
m124
trans-1-Methoxy-4(1-propenyl)benzene
2-Methoxy-4-propenylphenol
2-Methoxy-4-(2propenyl)phenol
3-Methoxypropionitrile
4-Methoxypropiophenone
3-Methoxypropylamine
2-Methoxypyridine
6-Methoxy-1,2,3,4tetrahydronaphthalene
6-Methoxy-1-tetralone
2-Methoxytoluene
3-Methoxytoluene
4-Methoxytoluene
Methoxytrimethylsilane
N-Methylacetamide
4⬘-Methylacetanilide
Methyl acetate
CH3OC6H4CH"CHCH3
148.21
6, 566
0.988320
4
1.561520
21.4
237
90
CH3OC6H3(OH)CH"CHCH3
164.20
6, 955
1.08720
4
1.574820
⫺10
266
⬎112
Methyl acetoacetate
4⬘-Methylacetophenone
misc chl, eth; 50 alc; s
bz, EtOAc
misc alc, eth; sl s aq
CH3OC6H3(OH)CH2CH"CH2
164.20
6, 961
1.0664
1.5408
⫺9.2
255
⬎112
CH3OCH2CH2CN
CH3OC6H4COCH2CH3
85.11
164.20
31, 113
8, 103
0.937
1.071
1.403020
1.546520
27–29
165
274
61
61
CH3O(CH2)3NH2
CH3O(C5H4N)
89.14
109.13
162.23
43, 739
21, 44
62, 537
0.874
1.038
1.033
1.417520
1.502929
1.540220
118733mm
142
901mm
22
32
⬎110
CH3OC6H4CH3
CH3OC6H4CH3
CH3OC6H4CH3
CH3OSi(CH3)3
176.22
122.17
122.17
122.17
104.23
92, 889
6, 352
6, 376
6, 392
43, 1856
0.985115
15
0.969725
25
0.96925
25
0.756020
4
1.516120
1.513120
1.511220
1.367820
17111mm
170–172
175–176
174
57–58
51
54
53
⫺30
i aq; v s alc, eth
s alc, bz, eth; i aq
s alc, eth; i aq
CH3CONHCH3
CH3OCONHC6H4CH3
CH3CO2CH3
73.10
149.19
74.08
4, 58
12, 920
2, 224
0.946035
1.425335
108
s aq
0.934220
4
24 aq; misc alc, eth
CH3COCH2CO2CH3
CH3C6H4COCH3
116.12
134.18
3, 632
7, 307
1.075720
1.0051
⫺10
(CC)
77
92
20
77–79
1.361920
30.6
150
⫺98
206
307
57
1.418620
1.532820
27.5
22–24
171.7
226
3-Methoxypropionaldehyde dimethyl acetal, t341
6-Methoxytetralin, m114
misc alc, chl, eth; s
HOAc, alk; i aq
misc aq
50 aq; misc alc
i aq; v s alc, eth
RIGHT
␣-Methoxy-␣-phenylacetophenone, b49
20
4
DEAN 37261 (McGHP)
m107
ROTATED
m114
m115
INTERACTIVE
Methyl 4-acetoxybenzoate
Methyl acrylate
Methylamine
1-(Methylamino)anthraquinone
Methyl 2-aminobenzoate
Methyl 3-aminocrotonate
2-(Methylamino)ethanol
4-Methylaminophenol
sulfate
Methyl 2-(aminosulfonyl)benzoate
N-Methylaniline
N-Methylanilinium
trifluoroacetate
2-Methylanthraquinone
Methylarsonic acid
4-Methylbenzaldehyde
Methyl benzenesulfonate
2-Methylbenzimidazole
Methyl benzoate
2-Methylbenzoic acid
3-Methylbenzoic acid
4-Methylbenzoic acid
4-Methylbenzophenone
2-Methylbenzothiazole
m126
m127
m128
m129
m130
m131
m132
1.260
m133
m134
m135
m136
m137
m138
m139
m140
m141
m142
m143
m144
m145
m146
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
CH3CO2C6H4CO2CH3
194.19
10, 159
H2C"CHCO2CH3
CH3NH2
86.09
31.06
237.26
2, 399
4, 32
14, 179
0.954120
4
0.6994⫺11
1.404020
⫺76.5
⫺93.5
170–172
80.2
⫺6.3
⫺3 (CC)
0
6 aq; s alc, eth
959 mL aq; 10.5 bz
H2NC6H4CO2CH3
151.17
14, 317
1.16819
4
1.582020
24
256
104
sl s aq; v s alc, eth
CH3C(NH2)"CHCO2CH3
115.13
3, 632
75.11
4, 276
159
72
misc aq, alc, eth
(CH3NC6H4OH)2 · H2SO4
344.39
13, 441
260 dec
H2HSO2C6H4CO2CH3
215.23
11, 377
126–128
C6H5NHCH3
C6H5NHCH3 · HO2CCF3
107.16
221.18
12, 135
222.24
7, 809
139.96
120.15
172.20
4, 613
7, 297
112, 20
132.17
23, 145
CH3NHCH2CH2OH
CH3AsO(OH)2
CH3C6H4CHO
C6H5SO2OCH3
C6H5CO2CH3
CH3C6H4CO2H
CH3C6H4CO2H
CH3C6H4CO2H
CH3C6H4COC6H5
82–84
81–83
0.93720
0.98920
4
1.438720
1.568420
⫺57
65–66
4 aq; sl s alc; i eth
196
78
170–173
v s bz; s alc, eth
161
1.019417
4
1.288904
1.544720
1.515120
15
4
15
⫺4
sl s aq; s alc, eth
205
15420mm
80
176–177
v s aq; s alc
misc alc, eth; sl s aq
v s alc, chl, eth
s alk, hot aq; sl s alc
136.15
136.15
136.15
136.15
196.25
9, 109
9, 462
9, 475
9, 483
7, 440
1.0933
1.062
1.054
1.5205
⫺15
103.7
111–113
180
57
199.5
258–259
263
274–275
326
83
0.2 aq; misc alc, eth
sl s aq; v s alc
0.09 aq; v s alc
v s alc, eth
v s bz, eth
149.22
27, 46
1.173
1.617020
12–14
238
102
s alc, HOAc; i aq
INTERACTIVE
m125
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
m149
m150
m151
m152
m153
m154
m155
m156
m157
1.261
2-Methylbenzoxazole
␣-Methylbenzyl
acetate
␣-Methylbenzyl
alcohol
2-Methylbenzyl
alcohol
(⫾)-␣-Methylbenzylamine
4-Methylbenzylamine
Methylbis(trimethylsilyloxy)vinyl ether
Methyl bromoacetate
(⫾)-Methyl 2-bromobutyrate
Methyl 2-bromopropionate
2-Methyl-1,3butadiene
133.15
164.20
27, 46
6, 476
1.121
1.028
1.549720
1.494520
8–10
CH3CO2CH(CH3)C6H5
178
9512mm
75
91
C6H5CH(CH3)OH
122.17
6, 475
1.019113
4
1.526520
20
204745mm
85
v s alc; s bz, chl
CH3C6H4CH2OH
122.17
6, 484
1.540820
33–36
11014mm
104
5 aq; 5 alc; s eth
C6H5CH(CH3)NH2
121.18
12, 1094
0.940
1.526020
185
79
4.2 aq; misc alc, eth
CH3C6H4CH2NH2
CH3Si[OSi(CH3)2]CH"CH2
121.18
148.55
12, 1141
44, 4184
0.952
0.864
1.534020
1.397020
195
488.8mm
75
51
BrCH2CO2CH3
CH3CH2CH(Br)CO2CH3
152.98
181.04
2, 213
2, 282
1.616
1.573
1.458620
1.45220
5215mm
13850mm
62
68
s alc
CH3CH(Br)CO2CH3
167.01
2, 253
1.497
1.542020
5119mm
51
s alc
68.12
1, 252
0.68120
4
1.421620
34.1
⫺53
misc alc, eth
H2C"C(CH3)CH"CH2
5-Methyl-o-anisidine, m81
Methylanisoles, m116 thru m118
Methyl anthranilate, m129
Methylanthranilic acid, a207, a208
Methylbenzene, t166
4-Methylbenzenesulfonic acid, t176
Methyl benzilate, m239
2-Methylbenzonitrile, t184
⫺146.0
4-Methylbenzonitrile, t185
o-Methylbenzyl alcohol, p109
N-Methylbenzylamine, b108
Methylbenzyl bromide, b343, b344
Methylbenzyl chlorides, c269 thru c271
Methylbis(2-chloroethoxy)silane, b162
N-Methylbis(2-chloroethyl)amine, b164
Methyl bromide, b225
RIGHT
Methylal, d507
Methyl alcohol, m38
Methylallene, b448
Methylaminoacetaldehyde dimethyl acetal, d508
␣-(1-Methylaminoethyl)benzyl alcohol, e2
Methylanilines, t180 thru t182
Methyl o-anisate, m304
Methyl p-anisate, m305
2-Methyl-p-anisidine, m80
12–13
DEAN 37261 (McGHP)
m147
m148
ROTATED
m128
m136
m140
m146
m147
INTERACTIVE
1.262
m158
m159
m160
m161
m162
2-Methylbutane
2-Methyl-1-butenethiol
2-Methyl-2-butanethiol
2-Methyl-1-butanol
2-Methyl-2-butanol
CH3CH2CH(CH3)2
CH3CH2CH(CH3)CH2SH
CH3CH2C(CH3)2SH
CH3CH2CH(CH3)CH2OH
CH3CH2C(CH3)2OH
m163
3-Methyl-1-butanol
(CH3)2CHCH2CH2OH
m164
m165
m165a
m166
m167
m168
3-Methyl-2-butanol
3-Methyl-2-butanone
2-Methyl-1-butene
2-Methyl-2-butene
3-Methyl-1-butene
cis-2-Methyl-2butenoic acid
trans-2-Methyl-2butenoic acid
3-Methyl-2-butenoic
acid
2-Methyl-3-buten-2-ol
3-Methyl-2-buten-1-ol
3-Methyl-3-buten-1-ol
2-Methyl-1-buten-3yne
N-Methylbutylamine
1-Methylbutylamine
3-Methylbutyl 3methylbutyrate
3-Methyl-1-butyne
2-Methyl-3-butyne-2-ol
2-Methylbutyraldehyde
3-Methylbutyraldehyde
Methyl butyrate
2-Methylbutyric acid
m169
m170
m175
m176
m177
m178
m179
m180
m181
m182
m183
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
72.15
104.22
104.22
88.15
88.15
1, 134
12, 421
11, 196
1, 388
1, 388
0.619720
0.848
0.842
0.81620
4
0.809620
1.353720
1.446520
1.438520
1.410020
1.405020
⫺159.9
88.15
1, 392
0.812915
4
(CH3)2CHCH(OH)CH3
(CH3)2CHCOCH3
C2H5C(CH3)"CH2
CH3CH"C(CH3)2
(CH3)2CHCH"CH2
CH3CH"C(CH3)CO2H
88.15
86.13
70.14
70.14
70.14
100.12
1, 391
1, 682
1, 211
1, 211
1, 213
2, 428
CH3CH"C(CH3)CO2H
100.12
(CH3)2C"CHCO2H
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
⫺103.9
⬍⫺70
⫺9.0
27.8
117
99.1
128
102.0
⫺56
19
⫺1
43
21
1.408515
⫺117
131
45
0.817920
0.80220
4
0.650
0.662020
4
0.627220
4
0.98347
4
1.409120
1.388020
1.378020
1.387820
1.363820
1.443747
⫺92
⫺137.6
⫺133.8
⫺168
45
112.9
94.3
31
38.6
20
185
38
6
⬍ ⫺34
⫺45
⫺56
2, 430
0.969
1.434281
64
198
s alc, eth; v s hot aq
100.12
2, 432
1.00624
69
194–195
s aq, alc, eth
(CH3)2C(OH)CH"CH2
(CH3)2C"CHCH2OH
H2C"C(CH3)CH2CH2OH
H2C"C(CH3)C#CH
86.13
86.13
86.13
66.10
1, 444
1, 444
1.417020
1.444020
1.433720
1.414020
2.6
98–99
140
11, 126
0.824
0.848
0.853
0.695
⫺113
32
13
43
36
⫺6
CH3CH2CH2CH2NCH3
CH3CH2CH2CH(CH3)NH2
(CH3)2CHCH2CH2O2CCH2CH(CH3)2
(CH3)2CHC#CH
(CH3)2C(OH)C#CH
CH3CH2CH(CH3)CHO
(CH3)2CHCH2CHO
CH3CH2CH2CO2CH3
CH3CH2CH(CH3)CO2H
87.17
87.17
172.27
4, 157
4, 177
2, 312
0.736
0.738420
4
0.854125
1.399520
1.402920
1.410025
⫺75
91
91
190.4
1
35
84
68.12
84.12
86.13
86.13
102.13
102.13
1, 251
11, 235
11, 352
1, 684
2, 270
2, 305
0.66620
4
0.867220
20
0.804
20
0.78520
0.89820
4
1.405520
1.374020
1.420920
1.391920
1.388220
1.386020
⫺89.8
2.6
26.4
104
90–92
92–93
103
176.5
25
4
19
11
73
⫺51
⫺85.8
0.005 aq; misc alc
s alc, eth; i aq
s alc, eth; i aq
3 aq; misc alc, eth
11 aq; misc alc, bz,
chl, eth
2 aq; misc alc, bz, chl,
eth, PE, HOAc
2.8 aq; misc alc, eth
misc alc, eth
misc alc, eth; i aq
misc alc, eth
s alc, eth; v s hot aq
LEFT
m171
m172
m173
m174
Formula
misc aq, alc, eth
misc alc, eth
misc alc, eth
misc aq, acet, bz
misc alc, eth; sl s aq
1.4 aq; misc alc, eth
INTERACTIVE
Name
ROTATED
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
m187
m188
m189
m190
m191
m192
m193
m194
m195
1.263
m196
m197
m198
m199
3-Methylbutyric acid
3-Methylbutyronitrile
3-Methylbutyryl
chloride
Methyl carbamate
Methyl chloroacetate
Methyl 2-chloroacetoacetate
Methyl 4-chloroacetoacetate
Methyl 3-chlorobenzoate
Methyl-4-chlorobenzoate
Methyl 4-chlorobutyrate
Methyl chloroformate
Methyl 3-(chloroformyl)propionate
Methyl 2-chloropropionate
2-Methylcinnamaldehyde
Methyl transcinnamate
6-Methylcoumarin
(CH3)2CHCH2CO2H
(CH3)2CHCH2CN
(CH3)2CHCH2COCl
102.13
83.13
120.58
0.930820
4
0.792519
4
0.98520
4
2, 309
22, 278
2, 315
56
4
20
20
1.403320
1.392720
1.416120
H2NCO2CH3
ClCH2CO2CH3
CH3COCH(Cl)CO2CH3
75.07
108.52
150.56
3, 21
2, 197
1.136
1.238
1.236
1.422020
1.446520
ClCH2COCH2CO2CH3
150.56
32, 426
1.305
1.456420
ClC6H4CO2CH3
170.60
9, 338
1.227
1.492320
ClC6H4CO2CH3
170.60
9, 340
1.38220
ClCH2CH2CH2CO2CH3
136.58
2, 278
1.126814
1.432120
ClCO2CH3
CH3O2CCH2CH2COCl
94.50
150.56
3, 9
22, 553
1.22320
4
1.223
CH3CH(Cl)CO2CH3
122.55
2, 248
C6H5CH"C(CH3)CHO
146.19
7, 369
C6H5CH"CHCO2CH3
162.19
9, 581
160.17
17, 337
18
177
130
137
51
71
854mm
102
10112mm
104
42–44
4 aq; s alc, chl, eth
misc alc, eth
dec aq, alc; s eth
220 aq; 73 alc; s eth
i aq; misc alc, eth
106
s alc
175–176
59
v s eth; s alc, acet
1.386520
1.440220
70–72
653mm
17
73
misc alc, bz, chl, eth
1.075
1.419320
132–133
38
s alc
1.040717
4
1.604520
14927mm
79
36–38
262
⬎110
75–76
303725mm
Methyl carbitol, m73
4-Methylcatechol, d438
Methyl cellosolve, m71
Methyl cellosolve acetate, m75
Methyl chlorocarbonate, m194
Methyl chloroform, t231
INTERACTIVE
m199
21
70
ROTATED
2-Methylbutyl isovalerate, m177
Methyl tert-butyl ketone, h70
Methyl caprate, m226
Methyl caproate, m270
Methyl caprylate, m349
Methyl carbazate, m275
56–58
⫺32
⫺32.7
176.5
129
115–117
RIGHT
3-Methyl-1-butencarboxylic acid, m369
cis-2-Methyl-2-butenedioic acid, c284
Methyl 2-buten-1-oate, m200
3-Methylbutyl acetate, i91
2-Methylbutylamine, a246
Methyl tert-butyl ether, b572
⫺29.3
⫺101
DEAN 37261 (McGHP)
m184
m185
m186
Methyl crotonate
Methyl cyanoacetate
Methylcyclohexane
Methyl cyclohexanecarboxylate
4-Methyl-1,2-cyclohexanedicarboxylic
anhydride
1-Methylcyclohexanol
cis-2-Methylcyclohexanol
trans-2-Methylcyclohexanol
cis-3-Methylcyclohexanol
trans-3-Methylcyclohexanol
cis-4-Methylcyclohexanol
trans-4-Methylcyclohexanol
2-Methylcyclohexanone
3-Methylcyclohexanone
4-Methylcyclohexanone
1-Methyl-1-cyclohexene
4-Methyl-1-cyclohexene
6-Methyl-3-cyclohexene-1-methanol
m204
m205
m206
m207
1.264
m208
m209
m210
m211
m212
m213
m214
m215
m216
m217
CH3CH"CHCO2CH3
NCCH2CO2CH3
C6H11CH3
C6H11CO2CH3
Formula
weight
100.12
99.09
98.19
142.20
Beilstein
reference
2, 410
2, 584
5, 29
9, 8
168.19
Density,
g/mL
Refractive
index
0.944420
4
1.122525
0.769420
0.995416
4
1.424220
1.416625
1.422120
1.443020
1.162
1.477420
Melting
point,⬚C
⫺22.5
⫺126.6
Boiling
point,⬚C
121
201
100.9
183
Flash
point,⬚C
4
⬎110
⫺4
60
Solubility in 100
parts solvent
v s alc, eth; i aq
misc alc, eth
i aq; s alc, eth
⬎110
CH3C6H10OH
CH3C6H10OH
114.19
114.19
6, 11
62, 17
0.925125
0.936020
4
1.458725
1.464030
25
7
155
165
67
58
i aq; b bz, chl
misc alc, eth
CH3C6H10OH
114.19
6, 11
0.924720
4
1.461620
⫺2
167.5
65
misc alc; s eth
CH3C6H10OH
114.19
6, 12
0.915520
1.457220
⫺6
168
62
misc alc, eth
CH3C6H10OH
114.19
6, 12
0.921420
1.458020
⫺0.5
167
62
CH3C6H10OH
114.19
6, 14
0.917020
1.461420
⫺9.2
173
70
misc alc, eth
CH3C6H10OH
114.19
6, 14
0.911821
4
1.455920
174
70
misc alc; s eth
CH3C6H9("O)
112.17
7, 14
0.92520
4
1.447820
162
46 (CC)
i aq; s alc, eth
CH3C6H9("O)
112.17
7, 15
0.915520
4
1.446020
169
51
i aq; s alc, eth
CH3C6H9("O)
112.17
7, 18
0.91620
4
1.445520
171
40
i aq; s alc, eth
96.17
5, 66
0.80920
4
1.450220
⫺121
111
⫺3
i aq; s alc, eth
96.17
5, 67
0.799
1.441220
⫺115.5
102
⫺1
i aq; s alc, eth
0.954
1.483020
126.20
INTERACTIVE
m200
m201
m202
m203
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
m219
m220
m221
m222
m223
m224
m225
m226
m227
m228
1.265
m229
m230
m231
m232
C6H11NHCH3
113.20
12, 6
0.868
1.456020
149
29
CH3C6H10NH2
113.20
12, 10
0.855
1.452520
150730mm
22
20
151–154
26
CH3C6H10NH2
113.20
12, 12
0.955
1.4531
160.26
54, 1435
0.941
1.497620
⫺51
200
26
84.16
112.13
5, 27
71, 310
0.748720
1.409720
⫺142.4
105–107
71.8
⫺23
0.013 aq
98.15
72, 13
0.920020
4
1.434720
⫺76
139
26
s aq; v s alc, eth
C3H5CO2CH3
100.12
91, 3
0.985
1.418120
119
17
CH3(CH2)8CO2CH3
Cl2CHCO2CH3
186.30
142.97
183.03
2, 356
2, 203
0.873
1.380819
1.245
1.425520
1.442120
1.463920
223
143
748mm
94
80
74
i aq; misc alc, eth
i aq; s alc
ClCH2CH(Cl)CO2CH3
157.00
21, 111
1.328220
4
1.444720
9250mm
42
s alc
CH3N(CH2CH2OH)2
119.16
4, 284
1.037720
1.468520
248
126
misc aq, alc
(CH3O)2C6H3CO2CH3
196.20
10, 396
59–62
283
(CH3O)2C6H3CO2CH3
196.20
10, 405
43
298
C5H9CH3
trans-2-Methylcrotonic acid, m169
Methyl cyanide, a29
⫺18
⫺52
⬎110
Methyl 4,6-dimethyl-2-oxo-2H-pyran-5-carboxylate, m292
ROTATED
CH2OH
H3C
m204
m215
m216
m217
RIGHT
N-Methylcyclohexylamine
3-Methylcyclohexylamine
4-Methylcyclohexylamine
Methylcyclopentadiene
dimer
Methylcyclopentane
3-Methyl-1,2-cyclopentanedione
2-Methylcyclopentanone
Methyl cyclopropanecarboxylate
Methyl decanoate
Methyl dichloroacetate
Methyl 2,2-dichloro-1methylcyclopropanecarboxylate
Methyl 2,3-dichloropropionate
N-Methyldiethanolamine
Methyl 3,4-dimethoxybenzoate
Methyl 3,5-dimethoxybenzoate
DEAN 37261 (McGHP)
m218
m221
m223
m224
m225
m228
INTERACTIVE
Methyl 3-(dimethylamino)propionate
Methyl 2,5-dimethyl3-furoate
Methyl 2,2-dimethylpropionate
N-Methyldioctylamine
4-Methyl-1,3-dioxane
N-Methyldiphenylamine
Methyl diphenylglycolate
3-Methyl-1,1-diphenylurea
Methyleneaminoacetonitrile
N,N⬘-Methylenebisacrylamide
2,2⬘-Methylenebis(4-chlorophenol)
4,4⬘-Methylenebis(2,6-di-tert-butylphenol
4,4⬘-Methylenebis(N,N-dimethylaniline)
1,1⬘-Methylenebis(3methylpiperidine)
4,4⬘-Methylenebis(phenylisocyanate)
Methylene blue
4,4⬘-Methylenedianiline
m234
m235
m236
m237
m238
m239
1.266
m240
m241
m242
m243
m244
m245
m246
m247
m248
m249
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
131.18
4, 403
0.917
1.418420
154
51
154.17
18, 398
1.037
1.475020
198
80
(CH3)3CCO2CH3
116.16
21, 139
0.873
1.388020
101–103
⫺1
(C8H17)2NCH3
43, 381
194, 49
12, 180
1.066
0.976
1.04820
4
1.442420
1.415020
1.619320
⫺30.1
⫺45
⫺7.6
16515mm
114
1356mm
⬎110
22
(C6H5)2NCH3
255.49
102.13
183.26
(C6H5)2C(OH)CO2CH3
242.27
10, 344
74–76
18713mm
(C6H5)2NCONHCH3
226.28
12,2, 852
172–174
Merck:
11, 5976
129
(CH3)2NCH2CH2CO2CH3
CH2 "NCH2CN
68.08
Solubility in 100
parts solvent
misc alc, eth; sl s aq
i aq; s alc, eth
s hot aq, alc; sl s bz
⬎300
H2C"CHC("O)NHCH2NHC("O)CH"CH2
CH2[C6H3(Cl)OH]2
154.17
269.13
6,3, 5408
168–172
CH2{C6H2[C(CH3)3]2OH}2
424.67
64, 6811
156–158
CH2[C6H4N(CH3)2]2
254.38
13, 239
88–89
CH2[CH3C5H9N]2
210.37
CH2(C6H4NCO)2
250.26
13,3, 461
CH2(C6H4NH2)2
373.90
198.26
27, 393
13, 238
0.887
1.180
100 EtOH; 100 eth; s
PE
28940mm
16050mm
⬎110
42–44
2005mm
⬎110
190 dec
89–91
399
221
1.473420
4 aq; 1.3 alc; s chl
v s alc, bz, eth; sl s aq
INTERACTIVE
m233
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
m251
m252
m253
3,4-Methylenedioxybenzaldehyde
1,2-Methylenedioxybenzene
3,4-Methylenedioxy-6propylbenzyldiethyleneglycol butyl
ether
Methylenesuccinic
acid
H2C"C(CO2H)CH2CO2H
150.13
19, 115
37
122.12
19, 20
338.45
3
19 , 779
1.059
130.10
2, 760
1.573
1.064
1.5398
⬎110
173
55
1mm
1.498
180
171
167
4,4⬘-Methylenedianiline, d46
Methylene dimethyl ether, d507
1,1⬘-Methylenedipiperidine, d776
Methylene fluoride, d409
Methyldinitrophenol, d715, d716
Methyl enanthate, m266
Methylene bromide, d110
Methylene bromochloride, b305
Methylene chloride, d235
264
0.2 aq; v s alc, eth
misc alc, bz, geons
8.2 aq; 20 alc; v sl s
bz, chl, eth, PE
DEAN 37261 (McGHP)
m250
Methylene iodide, d452
␤-Methylene-␤-propiolactone, d483
(1-Methylethyl)benzene, i103
Methyl ethyl ketone, b475
1.267
m237
m248
RIGHT
m234
ROTATED
m250
m251
m252
INTERACTIVE
No.
m254
m255
m256
m257
m258
m259
m259a
m260
m261
1.268
m262
m263
Beilstein
reference
Density,
g/mL
Refractive
index
74.13
41, 415
0.841
1.439520
59.07
135.17
60.05
110.11
82.10
126.11
327.35
4, 58
12, 234
2, 18
17, 289
17, 36
18, 274
0.998825
1.095
0.981515
1.107218
4
0.91520
4
1.17920
2.633720
4
1.430025
1.561020
1.346515
1.526320
1.433220
1.487920
1.577020
195.22
194.18
Merck:
12, 6154
31, 179
1.4630
4
NCCH2CH2CH(CH3)CN
108.14
2, 656
0.950
1.434020
CH3NHCH2CO2H
HOCH2CO2CH3
CH3(CH2)5CO2CH3
(CH3)2CH(CH2)3CH(OH)CH3
C2H5CH(CH3)CH2COC2H5
(CH3)2C"CHCH2CH2COCH3
89.09
90.08
144.22
130.23
128.22
126.20
4, 345
3, 236
2, 339
1, 421
11, 363
13, 3010
1.16818
4
0.881520
4
0.803
0.823
0.85516
4
1.417020
1.411520
1.424020
1.414220
1.439220
CH3(CH2)14CO2CH3
CH3(CH2)4CO2CH3
(CH3)2CHCH2CH2COCH3
CH3(CH2)4CH(NH2)CH3
2, 372
2, 323
12, 756
4, 194
24, 244
42, 957
31, 46
0.852
0.903804
0.88820
4
0.766518
1.451220
1.403823
1.406220
1.417520
CH3NHNH2
H2NNHCO2CH3
270.46
130.19
114.19
115.22
114.10
46.07
90.08
0.866
1.422520
HO2CCH2CH2CH2CO2CH3
146.14
22, 565
1.169
1.438120
CH3NHCH2CH2NH2
HC("O)NHCH3
C6H5N(CH3)CHO
HCO2CH3
CH3GeBr3
Melting
point,⬚C
⫺4
8–13
⫺99
⫺88
Boiling
point,⬚C
Flash
point,⬚C
114–116
42
199.5
244
31.7
187
63–66
181
168
98
126
⫺19
72
⫺22
73
168
2000.2mm
⫺45
269–271
126
151
173.5
172
157–162
7318mm
67
52
67
43
50
19615mm
151
144
144
subl
87.5
10812mm
⬎110
45
3641
54
⫺67
32–34
⫺71
⫺73.9
157
⫺52.4
70–73
misc aq
30 aq; misc alc
s aq; v s alc; misc eth
0.3 aq
s alc, eth; sl s aq
100 aq25; 1.2 alc70
128–129
208 dec
74
⫺55.8
Solubility in 100
parts solvent
15110mm
63 aq; 1.6 alc; i eth
21
⬎110
42 aq; sl s alc
s aq; misc alc, eth
s alc, eth; sl s aq
misc alc, eth
s alc, chl, eth
v s alc, eth
0.5 aq; misc alc, eth
sl s aq; s alc, eth
s aq, alc; 3 eth
misc aq, alc; s PE
INTERACTIVE
m276
Methyl-␣-D-glucopyranoside
(⫾)-2-Methylglutaronitrile
N-Methylglycine
Methyl glycolate
Methyl heptanoate
5-Methyl-2-heptanol
5-Methyl-3-heptanone
6-Methyl-5-hepten-2one
Methyl hexadecanoate
Methyl hexanoate
5-Methyl-2-hexanone
1-Methylhexylamine
1-Methylhydantoin
Methylhydrazine
Methyl hydrazinocarboxylate
Methyl hydrogen
glutarate
Formula
weight
ROTATED
m269a
m270
m271
m272
m273
m274
m275
N-Methylethylenediamine
N-Methylformamide
N-Methylformanilide
Methyl formate
5-Methylfuraldehyde
2-Methylfuran
Methyl 2-furoate
Methylgermanium
tribromide
N-Methylglucamine
Formula
LEFT
m264
m265
m266
m267
m268
m269
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
m278
m279
m280
m281
m282
m283
m284
m285
Methyl hydrogen
hexanedioate
Methyl hydrogen
succinate
Methyl hydroperoxide
Methylhydroquinone
Methyl 4-hydroxybenzoate
Methyl 2-hydroxyisobutyrate
Methyl 4-hydroxyphenylacetate
2-Methylimidazole
2-Methylimidazole
HO2C(CH2)4CO2H
160.17
2, 652
HO2CCH2CH2CO2H
132.12
2, 608
1.081
2
15
4
CH3OOH
CH3C6H3 91,4-(OH)2
HOC6H4CO2CH3
48.04
124.14
152.15
1 , 270
6, 874
10, 158
1.997
(CH3)2C(OH)CO2CH3
118.13
32, 223
1.023
HOC6H4CH2CO2CH3
166.18
10, 191
82.11
82.11
23, 46
23, 65
1.440120
8–9
16210mm
56–59
15120mm
15
1.3642
1.411220
1.496020
1.269
m259
misc aq, alc, eth; s bz
270 dec
42
v s alc, eth, acet; 0.25
aq
v s aq, alc
92
misc aq
57–60
1635mm
⫺60
142–143
198
268
Methyl isobutenyl ketone, m370
Methyl isobutyl ketone, m367
Methyl isonicotinate, m413
Methyl isopentyl ketone, m271
2-Methyllactic acid, h138
m259a
RIGHT
m258
38
127
Methyl hydroxyacetate, m265
Methyl 2-hydroxypropionate, m296
2,2⬘-Methyliminodiethanol, m230
2,2⬘-Methyliminobis(acetaldehyde diethyl acetal), b176
Methyl iodide, i37
Methyl isoamyl ketone, m271
Methyl 2-furancarboxylate, m259a
5-Methylfurfural, m258
Methyl gallate, m454
␣-Methyl-D-glucopyranoside, m262
N-Methylguanidine acetic acid, c301
4-Methylhexahydrophthalic anhydride, m204
s alc
v s aq, alc, eth
65mm
128–130
126–128
1.030
⬎110
DEAN 37261 (McGHP)
m277
m261
ROTATED
m262
m273
m280
m284
m285
INTERACTIVE
Name
m286
m287
m288
m289
4-Methylimidazole
2-Methyl-1H-indole
2-Methylindoline
N-Methylisatoic
anhydride
Methyl isobutyrate
Methyl isocyanate
Methyl isodehydracetate
N-Methylisopropylamine
Methyl isothiocyanate
5-Methylisoxazole
Methyl lactate
Methyl mandelate
Methyl mercaptoacetate
Methyl 3-mercaptopropionate
Methyl methacrylate
m290
m291
m292
m293
1.270
m294
m295
m296
m297
m298
m299
m300
m301
m304
m305
m306
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
82.11
131.18
133.19
177.16
23, 69
20, 311
20, 279
27, 265
(CH3)2CHCO2CH3
CH3NCO
102.13
57.05
182.18
2, 290
4, 77
18, 410
0.89120
0.967
1.384020
1.369520
⫺84.7
⫺45
68–70
(CH3)2CHNHCH3
73.14
41, 153
0.702
1.384020
50–53
4, 77
27, 16
3, 280
10, 202
1.069
1.018
1.08820
4
1.175620
1.187
1.525837
1.438620
1.413120
35
CH3CH(OH)CO2CH3
C6H5CH(OH)CO2CH3
HSCH2CO2CH3
73.12
83.09
104.10
166.18
106.14
HSCH2CH2CO2CH3
120.17
32, 214
H2C"C(CH3)CO2CH3
100.12
CH3SO2OCH3
CH3NCS
1.0720
4
1.023
53–56
58–60
1.568120
Boiling
point,⬚C
263
273
229
Flash
point,⬚C
Solubility in 100
parts solvent
⬎110
v s alc, eth; s hot aq
93
165 dec
92.5
39
16714mm
3
⫺6
⫺31
1.465720
118
122
144–145
13512mm
4310mm
32
30
49
⬎110
30
1.085
1.466020
5514mm
60
22, 398
0.943320
1.414020
100
10
110.13
4, 4
1.294320
4
1.413820
202–203
104
CH3OCH2CO2CH3
CH3OCH2COCH2CO2CH3
104.11
146.14
3, 236
34, 1939
1.051120
4
1.129
1.396420
1.431620
130
898.5mm
35
89
CH3OC6H4CO2CH3
166.18
10, 71
1.157
1.533520
248
⬎110
CH3OC6H4CO2CH3
166.18
10, 159
245
⬎110
CH3OC6H4CH2CO2CH3
180.20
10, 191
1.135
1.516520
15819mm
36
CH3OCH2CH2CO2CH3
118.13
3, 297
1.009
1.4020
142–143
47
54–56
⫺48
51
misc alc, eth; sl s aq
s aq
v s alc, eth; sl s aq
s aq (dec), alc, eth
s aq, alc, bz, chl
s alc, eth
1,6 aq; s ketones,
esters, CCl4
20 aq; 100 DMF
v s alc, eth; sl s aq
INTERACTIVE
m307
Formula
weight
ROTATED
m302
m303
Methyl methanesulfonate
Methyl methoxyacetate
Methyl 4-methoxyacetoacetate
Methyl 2-methoxybenzoate
Methyl 4-methoxybenzoate
Methyl 4-methoxyphenylacetate
Methyl 4-methoxypropionate
Formula
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
m309
m310
m311
m312
m313
m314
1-Methyl-4-(methylamino)piperidine
Methyl 2-methylbenzoate
Methyl 3-methylbenzoate
Methyl 4-methylbenzoate
Methyl 2-methylbutyrate
2-Methyl-6-methylene2-octanol
128.22
CH3C6H4CO2CH3
150.18
9, 463
CH3C6H4CO2CH3
150.18
9, 475
CH3C6H4CO2CH3
150.18
9, 484
C2H5CH(CH3)CO2CH3
116.16
2, 304
C2H5C("CH2)(CH2)3C(CH3)2OH
Methyl 2-methyl-3furancarboxylate
1.271
Methyl mercaptan, m37
Methylmercaptoanilines, m436
4-Methylmercaptobenzaldehyde, m437
0.882
1.467220
1.073
1.519020
1.063
20
207–208
1.5160
33–36
82
27mm
113
95
10415mm
90
0.885
1.393120
115
32
156.27
0.784
1.443120
8410mm
76
140.14
1.116
1.473020
7520mm
63
2-Methyl-2-methoxypropane, b572
7-Methyl-3-methylene-1,6-octadiene, m467
1-Methyl-4-(1-methylethenyl)cyclohexane, d736
m287
m288
sl s aq; misc alc, eth
5-Methyl-2-(1-methylethyl)cyclohexanol, m12
5-Methyl-2-(1-methylethyl)cyclohexanone, m13
m289
RIGHT
m286
55
DEAN 37261 (McGHP)
m308
ROTATED
m292
m295
m308
m314
INTERACTIVE
Methyl S-methylthiomethyl sulfoxide
Methyl 3-(methylthio)propionate
4-Methylmorpholine
1-Methylnaphthalene
2-Methylnaphthalene
Methyl 1-naphthaleneacetate
2-Methyl-1,4-naphthoquinone
Methyl 1-naphthyl
ketone
Methyl 2-naphthyl
ketone
Methyl nitrate
Methyl nitrite
N-Methyl-4-nitroaniline
2-Methyl-3-nitroaniline
2-Methyl-4-nitroaniline
2-Methyl-5-nitroaniline
4-Methyl-2-nitroaniline
Methyl 2-nitrobenzoate
Methyl 3-nitrobenzoate
Methyl 4-nitrobenzoate
m316
m317
m318
m319
m320
m321
m322
1.272
m323
m324
m325
m326
m327
m328
m329
m330
m331
m332
m333
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
CH3S("O)CH2SCH3
124.22
1.191
1.548720
952.5mm
⬎110
CH3SCH2CH2CO2CH3
134.20
1.077
1.465020
7513mm
72
C10H7CH3
C10H7CH3
C10H7CH2CO2CH3
101.15
142.20
142.20
200.24
27, 6
5, 566
5, 567
93, 3206
0.920
1.020220
1.02920
4
1.142
1.434920
1.617020
1.602640
1.596120
116
245
241
1625mm
23
82
97
⬎110
172.18
72, 656
C10H7COCH3
170.21
7, 401
C10H7COCH3
170.21
7, 402
CH3ONO2
CH3ONO
O2NC6H4NHCH3
77.04
61.04
152.15
1, 284
1, 284
12, 714
CH3C6H3(NO2)NH2
152.15
12, 848
CH3C6H3(NO2)NH2
152.15
12, 846
CH3C6H3(NO2)NH2
152.15
CH3C6H3(NO2)NH2
⫺66
⫺30.4
34.4
105–107
1.133604
1.207520
4
0.991(lq)
1.628420
1.374820
Solubility in 100
parts solvent
s aq, alc, eth
v s alc, eth
v s alc, eth
1.4 alc; 10 bz; s chl
11
302
⬎110
s alc, eth; i aq
53–55
301
⬎110
sl s alc; s CS2
⫺83
64 expl
⫺17.3
sl s aq; s alc, eth
s alc, eth
152–154
88–90
1.1586140
4
305
131–133
v s alc; s bz
12, 844
104–107
s alc, acet, eth
152.15
12, 1000
115–116
v s alc; s eth
O2NC6H4CO2CH3
181.15
9, 372
O2NC6H4CO2CH3
181.15
O2NC6H4CO2CH3
181.15
⫺13
1060.1mm
9, 378
78–80
279
9, 390
94–96
1.280
1.534020
⬎110
s alc, eth
INTERACTIVE
m315
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
m335
m336
m337
m338
m339
m340
m341
m342
1.273
m343
m344
m345
m346
2-Methyl-3-nitrobenzoic acid
3-Methyl-4-nitrobenzoic acid
4-Methyl-3-nitrobenzoic acid
5-Methyl-2-nitrobenzoic acid
2-Methyl-5-nitroimidazole
3-Methyl-4-nitrophenol
4-Methyl-2-nitrophenol
2-Methyl-2-nitro-1propanol
2-Methyl-2-nitropropyl
methacrylate
N-Methyl-N-nitroso-4toluenesulfonamide
Methyl 2-nonynoate
Methyl-5-norbornene2,3-dicarboxylic
anhydride
Methyl octadecanoate
CH3C6H3(NO2)CO2H
181.15
9, 471
182–184
CH3C6H3(NO2)CO2H
181.15
9, 481
216–218
CH3C6H3(NO2)CO2H
181.15
9, 502
187–190
CH3C6H3(NO2)CO2H
181.15
9, 482
134–136
127.10
231, 23
252–254
CH3C6H3(NO2)OH
153.14
6, 386
127–129
CH3C6H3(NO2)OH
153.14
6, 412
O2NC(CH3)2CH2OH
119.12
1, 378
H2C"C(CH3)CO2CH2C(CH3)2NO2
CH3C6H4SO2N(CH3)NO
187.20
23, 1288
214.24
111, 29
CH3(CH2)5C#CCO2CH3
168.24
178.19
2, 490
172, 461
CH3(CH2)16CO2CH3
298.51
2, 379
1.087
1.57440
32–35
12522mm
86–89
9510mm
1.450020
108
v s alc, eth
350 aq
1024mm
⬎110
12120mm
100
⬎110
21515mm
⬎110
62
0.915
1.232
1.448420
1.506020
38
Methyl myristate, m428
Methyl nicotinate, m412
4-Methyl-3-nitroanisol, m95
Methyl nonyl ketone, u9
s alc, eth
RIGHT
Methyl 2-methyllactate, m282
Methyl methyl-2-propenoate, m290
Methyl methylsulfinylmethyl sulfide, m315
1.24040
4
DEAN 37261 (McGHP)
m334
ROTATED
m321
m338
m345
INTERACTIVE
m317
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
CH3(CH2)7CH"CH(CH2)7CO2CH3
(CH3)2C"CH(CH2)3CH"CH2
CH3(CH2)6CO2CH3
CH3(CH2)4C#CCO2CH3
m364
m365
m366
m367
Methyl cis-9-octadecenoate
7-Methyl-1,6-octadiene
Methyl octanoate
Methyl 2-octynoate
3-Methyl-2oxazolidinone
2-Methyl-2-oxazoline
3-Methyl-3-oxetanemethanol
Methyl 2-oxocyclopentanecarboxylate
Methyl 2-oxopropionate
trans-2-Methyl-1,3pentadiene
2-Methylpentane
3-Methylpentane
2-Methyl-1,5-pentanediamine
2-Methyl-2,4pentanediol
4-Methylpentanenitrile
Methyl pentanoate
2-Methylpentanoic
acid
2-Methyl-1-pentanol
3-Methyl-3-pentanol
4-Methyl-2-pentanol
4-Methyl-2-pentanone
m368
2-Methyl-2-pentenal
CH3CH2CH"C(CH3)CHO
m352
m353
m354
1.274
m355
m356
m357
m358
m359
m360
m361
m362
m363
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
1682mm
⬎110
143–144
192.9
217–220
901mm
26
72
88
⬎110
1.434020
1.446020
110
8040mm
20
98
1.145
1.456020
10519mm
⬎110
3, 616
1.130
1.406520
134–137
39
82.15
1, 255
0.718
1.446920
75–76
⫺12
CH3CH2CH2CH(CH3)2
(CH3CH2)2CHCH3
H2N(CH2)3CH(CH3)CH2NH2
86.18
86.18
116.21
1, 148
1, 149
4, 270
0.653220
0.664320
0.860
1.372520
1.376520
1.459020
⫺154
⫺163
80
60.3
63
⬍⫺29
⬍⫺7
(CH3)2C(OH)CH2CH(OH)CH3
118.18
1, 486
0.921620
4
1.427020
⫺50
198
102
misc aq
(CH3)2CHCH2CH2CN
CH3(CH2)3CO2CH3
CH3CH2CH2CH(CH3)CO2H
97.16
116.16
116.16
2, 329
2, 301
22, 288
0.803520
4
0.875
0.924220
20
1.406120
1.396220
1.413520
⫺51.1
⫺85
156.5
128
196.4
45
22
107
s alc; misc eth
sl s aq; misc alc, eth
1.3 aq
CH3CH2CH2CH(CH3)CH2OH
(CH3CH2)2C(CH3)OH
(CH3)2CHCH2CH(OH)CH3
(CH3)2CHCH2COCH3
102.18
102.18
102.18
100.16
1, 409
1, 411
1, 410
1, 691
0.826220
0.828120
0.808020
0.797820
1.418020
1.418620
1.411220
1.395820
⫺23.6
⫺90
⫺84
148
123
132
116.5
54
46
41
18
14, 3471
0.861
1.450320
138
31
s alc, eth
misc alc, eth; sl s aq
1.6 aq
1.7 aq; misc alc, bz,
eth
s alc
296.50
2, 467
0.83920
1.452120
124.23
158.24
154.21
101.11
14, 1049
2, 348
2, 487
0.753
0.877520
4
0.920
1.170
1.436020
1.416025
1.446020
1.454120
85.11
102.13
27, 13
173, 1128
1.005
1.024
(O")C5H7CO2CH3
142.16
10, 597
CH3C("O)CO2CH3
102.09
CH3CH"CHC(CH3)"CH2
98.15
⫺19.9
Boiling
point,⬚C
⫺40
15
misc abs alc, eth
v s alc, eth; i aq
misc alc, eth; sl s aq
INTERACTIVE
m347
m348
m349
m350
m351
Formula
ROTATED
Name
LEFT
No.
m370
m370a
m371
m372
m373
m374
m375
m376
m377
m378
1.275
m379
4-Methyl-2-pentenoic
acid
4-Methyl-3-penten-2one
4-Methyl-2-pentyl
acetate
1-Methylpentylamine
3-Methyl-1-pentyn-3-ol
(CH3)2CHCH"CHCO2H
4-Methylphenetole
N-(4-Methylphenyl)acetamide
Methyl phenylacetate
2-Methyl-1-phenyl-2propanol
1-Methyl-3-phenylpropylamine
3-Methyl-1-phenyl-2pyrazolin-5-one
Methyl phenyl sulfide
(CH3)2C"CHCOCH3
114.14
22, 406
0.9529
1.4489
35
11520mm
46
i aq; v s alc
98.15
1, 736
0.865320
1.444020
⫺59
129.5
31
3.1 aq
25
20
147.5
45
⫺19
⫺30.6
116–118
122
13
26
189–191
307
70
150–153
25–26
218
9618mm
90
81
222
97
(CH3)2CHCH2CH(CH3)O2CCH3
144.21
0.8805
1.3980
CH3(CH2)3CH(NH2)CH3
CH3CH2C(CH3)(OH)C#CH
101.19
98.15
4, 190
12, 506
0.76720
4
0.868820
4
1.431820
CH3C6H4OCH2CH3
CH3C6H4NHCOCH3
136.19
149.19
6, 393
12, 920
0.945
1.21215
1.504420
C6H5CH2CO2CH3
CH6H5CH2C(CH3)2OH
150.18
150.22
9, 434
6, 523
1.044
0.974
1.507520
1.514020
C6H5CH2CH2CH(CH3)NH2
149.24
12, 1165
0.922
1.512320
174.20
24, 20
124.21
6, 297
C6H5SCH3
Methyl octyl ketone, d19
Methyl oleate, m347
o-Methylolphenol, h106
2-Methyloxacyclopropane, p232
Methyl oxirane, p232
1.058
Methyl palmitate, m269a
Methyl pentyl ketone, h14
Methylphenols, c303 thru c305
Methyl-m-phenylene diisocyanate, t171
1.588220
129–130
287265mm
⫺15
188
s aq, alc, PE
13 aq, misc bz, acet
PE, EtOAc; s eth
s alc, EtOAc, HOAc
57
DEAN 37261 (McGHP)
m369
i aq; misc alc, eth
i aq; s alc
Methyl phenyl ether, m55
Methyl phenyl ketone, a31
2-Methyl-2-phenylpropane, b523
Methyl ␥-picolinate, m413
RIGHT
ROTATED
m351
m352
m353
m378
INTERACTIVE
Beilstein
reference
Density,
g/mL
Refractive
index
1.074
1.514920
0.903
1.465520
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
Name
m380
N-Methyl-N-phenylurethane
N-Methylpiperazine
2-Methylpiperazine
N-Methylpiperidine
2-Methylpiperidine
3-Methylpiperidine
4-Methylpiperidine
1-Methyl-3-piperdinemethanol
1-Methyl-4-piperidone
2-Methylpropanaldehyde
2-Methylpropane
C6H5N(CH3)CO2CH2CH3
(CH3)3CH
58.12
1, 124
N-Methyl-1,3-propanediamine
2-Methyl-1,2-propanediamine
2-Methyl-1,3-propanediol
1-Methyl-1-propanethiol
2-Methyl-1-propanethiol
2-Methyl-2-propanethiol
2-Methyl-1-propanol
2-Methyl-2-propanol
2-Methylpropene
2-Methyl-2-propen1-ol
Methyl propionate
H2NCH2CH2CH2NHCH3
88.15
41, 419
0.844
1.446820
(CH3)2C(NH2)CH2NH2
88.15
4, 266
0.841
1.441020
HOCH2CH(CH3)CH2OH
90.12
1, 480
1.015
1.445020
⫺91
12520mm
⬎110
CH3CH2CH(SH)CH3
90.19
1, 373
0.824625
4
1.433825
⫺165
84–85
21
sl s aq; v s alc, eth
(CH3)2CHCH2SH
90.19
1, 378
0.835720
1.439620
⫺79
88.5
⫺9
v s alc, eth
(CH3)3CSH
90.19
1, 383
0.794325
4
1.419825
1.1
64.1
⫺4
i aq
(CH3)2CHCH2OH
(CH3)3COH
(CH3)2C"CH2
H2C"C(CH3)CH2OH
74.12
74.12
56.11
72.11
1, 373
1, 379
1, 207
1, 443
0.801620
0.788820
0.6266mp
4
0.857
1.395820
1.387720
⫺108
25.8
⫺140
108
82.4
⫺6.9
113–115
28
11
10 aq; misc alc, eth
misc aq, alc, eth
v s alc, eth
CH3CH2CO2CH3
85.11
2, 239
0.91520
4
1.377020
79.7
6
m381
m382
m383
m384
m385
m386
m387
m388
m389
1.276
m390
m391
m392
m394
m396
m397
m398
m399
m400
⫺5
138
155.6
106–107
119
126
124
140–145
42
65
3
8
17
7
94
1.461420
1.372720
⫺65
64.1
60
⫺40
1.3810⫺25
⫺138
⫺11.7
⫺87
139–141
35
100.17
100.17
99.19
99.19
99.19
99.19
129.20
23, 17
20, 19
20, 95
20, 100
20, 101
212, 8
0.816
0.844
0.845
0.838
1.013
1.437820
1.445920
1.447020
1.445820
1.477220
113.16
72.11
212, 215
1, 671
0.920
0.789120
65–67
v s aq, alc, eth
78 aq; 37 acet; 32 bz
v s aq; misc alc, eth
v s aq; misc alc, eth
v s aq
v s aq
9 aq; misc alc, bz, chl,
eth
13 mL aq; 1320 mL
alc; 2890 mL eth
23
1.426020
⫺88
33
6 aq; misc alc, eth
INTERACTIVE
m401
(CH3)2CHCHO
⬎110
12, 417
ROTATED
m395
C5H10NCH3
CH3C5H9N
CH3C5H9N
CH3C5H9N
243–244
179.22
LEFT
m393
Formula
Formula
weight
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
m403
m404
m405
m406
m407
m408
m409
m410
m411
m412
m413
1.277
m414
Methyl propionylacetate
4⬘-Methylpropiophenone
Methyl propyl ether
2-Methyl-2-propyl1,3-propanediol
Methyl propyl sulfide
Methyl 2-propynyl
ether
2-Methylpyrazine
2-Methylpyridine
3-Methylpyridine
4-Methylpyridine
Methyl 3-pyridinecarboxylate
Methyl 4-pyridinecarboxylate
1-Methyl-2-pyridone
C2H5COCH2CO2CH3
130.15
33, 1212
1.037
1.422020
CH3C6H4COCH2CH3
148.21
7, 317
0.993
1.528020
CH3CH2CH2OCH3
CH3CH2CH2C(CH3)(CH2OH)2
745mm
71
7.2
238–239
96
58–60
232
39.1
⬎110
20
74.12
132.20
1, 354
11, 254
0.738
CH3SCH2CH2CH3
CH3OCH2C#CH
90.18
70.09
13, 1432
1, 4541
0.842420
0.830
1.444220
1.396120
⫺113.0
95.5
62
CH3C5H4N
CH3C5H4N
CH3C5H4N
(C5H4N)CO2CH3
94.12
93.13
93.13
93.13
137.14
23, 94
20, 234
20, 239
20, 240
22, 39
1.030
0.944320
0.956620
0.954820
1.504220
1.495720
1.504020
1.503720
⫺29
⫺66.7
⫺18.3
3.8
39
135
129
144
145
209
50
39
36
57
(C5H4N)CO2CH3
137.14
22, 46
1.001
1.512220
8.5
207–209
82
109.13
21, 268
1.112
1.569020
30–32
250740mm
⬎110
s aq
⫺18
2-Methyl-2-propylamine, b511
2-Methylpropylamine, i66
(1-Methylpropyl)benzene, b522
(2-Methylpropyl)benzene, i67
2-Methylpropyl formate, i69
Methyl propyl ketone, p42
2-Methylpropyl-2-methylpropanoate, i70
Methyl pyridyl ketones, a53, a54, a55
v s aq, alc, eth
misc aq; s alc, eth
misc aq, alc, eth
misc aq, alc, eth
s aq, alc, bz
RIGHT
2-Methylpropenoic acid, m29
2-Methylpropionaldehyde, i79
2-Methylpropionamide, i70
2-Methylpropionic acid, i81
2-Methylpropionic anhydride, i82
2-Methylpropionitrile, i83
1-Methylpropyl acetate, b502
2-Methylpropyl acetate, i63
Methylpiperidinol, h152
Methyl pivalate, m235
2-Methyl-1-propanamine, i66
2-Methyl-2-propanamine, b511
1-Methyl-1-propanethiol, b471
Methyl propargyl ether, m407
2-Methyl-2-propenenitrile, m30a
Methyl propenoate, m126
sl s aq; misc alc, eth
DEAN 37261 (McGHP)
m402
ROTATED
m381
m382
m387
m388
m408
m414
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
m415
m416
m417
m418
m419
1.278
m420
m421
m422
m423
m424
m430
m432
m433
m434
m435
152.15
Beilstein
reference
C6H5C(CH3)"CH2
CH3C6H4CH"CH2
HO2CCH2CH162CO2CH3
CH3(CH2)12CO2CH3
Refractive
index
223, 4076
195.26
HOC6H4CO2CH3
Density,
g/mL
Melting
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
121–123
1.052
1.515020
⬎110
81.12
85.15
99.13
20, 163
20, 4
21, 237
0.914
0.81920
4
1.027925
1.487520
1.424720
1.468025
⫺57
143.19
143.19
143.19
144.18
152.15
20, 387
20, 395
20, 397
231, 44
10, 70
1.058
1.082620
4
1.063
1.118
1.183120
1.610820
1.620020
1.614020
1.615620
1.536020
⫺2
9–10
118.18
118.18
132.12
242.40
86.13
5, 484
5, 485
2, 608
22, 326
17, 12
0.909
0.897
1.537520
1.541220
⫺24
0.855
0.855220
1.436220
1.405620
100.16
173, 77
0.863
134.20
Boiling
point,⬚C
112–113
80–81
202
15
⫺21
96
i aq; misc alc, eth
misc aq, eth
misc aq, alc, bz, eth
248
263
259
245–247
223
79
⬎110
⬎110
107
96
i aq; s chl, eth
misc alc, bz, eth
165.5
170–175
15120mm
323
78
45
45
⬎110
⫺11
1.420420
109733mm
6
1.191
1.477220
276
⬎110
20
134
1357mm
32
⬎110
145
6315mm
37
67
16516mm
⬎110
99.16
143.21
27.16
27,3, 1754
1.090
1.196
1.5257
1.550820
101.17
87.14
27, 13
CH3SCH2CN
1.067
1.039
1.520020
1.482620
CH3SC6H4NH2
139.22
131, 141
1.130
1.642320
⫺24.4
180
⫺8
56–59
18.4
⫺101
misc aq
0.7 aq; misc alc,
HOAc; s chl, eth
misc alc, bz, eth
INTERACTIVE
m436
␣-Methylstyrene
4-Methylstyrene
mono-Methyl succinate
Methyl tetradecanoate
2-Methyltetrahydrofuran
3-Methyltetrahydropyran
3-Methyltetrahydrothiophene-1,1-dioxide
4-Methylthiazole
4-Methyl-5-thiazoleethanol
2-Methyl-2-thiazoline
(Methylthio)acetonitrile
3-(Methylthio)aniline
Formula
weight
ROTATED
m431
Methyl 3-pyridylcarbamate
2-[3-(6-Methyl-2pyridyl)propoxy]ethanol
N-Methylpyrrole
N-Methylpyrrolidine
N-Methyl-2pyrrolidinone
2-Methylquinoline
4-Methylquinoline
6-Methylquinoline
2-Methylquinozaline
Methyl salicylate
Formula
LEFT
m425
m426
m427
m428
m429
Name
m438
m439
m440
m441
m442
4-(Methylthio)benzaldehyde
2-(Methylthio)benzothiazole
3-(Methylthio)-2butanone
Methyl thiocyanate
2-Methylthiophene
3-Methylthiophene
CH3SC6H4CHO
CH3CH(SCH3)COCH3
152.22
81, 533
181.28
27, 109
118.20
CH3SCN
73.12
98.17
98.17
1-Methyl-2-(3-pyridyl)pyrrolidine, n19
Methyl pyruvate, m355
Methyl stearate, m346
1.144
1.645220
1 , 3993
0.975
20
1.4710
3, 175
17, 37
17, 38
1.06820
1.019320
1.021820
1.468020
1.519920
1.518020
4
⬎110
901mm
⬎110
43–46
Methyl succinyl chloride, m195
Methylsulfonic acid, m34
Methyl theobromine, c1
20mm
⫺5
⫺63
⫺69
50–54
44
133
113
115.4
38
7
11
i aq; misc alc, eth
i aq; misc alc, eth
Methyl thienyl ketone, a57
Methyl thioglycolate, m298
DEAN 37261 (McGHP)
m437
1.279
m415
m416
m417
m418
m419
m420
RIGHT
m421
m422
m423
m429
m430
m431
ROTATED
m432
m433
m434
m438
m441
m442
INTERACTIVE
5-Methyl-2-thiophenecarboxaldehyde
N-Methyl-2-thiourea
N-Methyl-o-toluamide
N-Methyl-p-toluenesulfonamide
Methyl p-toluenesulfonate
Methyltriacetoxysilane
Methyl trichloroacetate
Methyltrichlorosilane
Methyltriethoxysilane
Methyl trifluoroacetate
Methyl trifluoromethanesulfonate
Methyl 3,4,5-trihydroxybenzoate
Methyltrimethoxysilane
Methyl trimethylacetate
N-Methyl-N-(trimethylsilyl)trifluoroacetamide
(Methyl)triphenylphosphonium
bromide
2-Methylundecanal
Methyl urea
N-Methyl–N-vinylacetamide
m444
m445
m446
m447
m448
m449
1.280
m450
m451
m452
m453
m454
m455
m456
m457
m458
m459
m460
m461
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
1.586020
Melting
point,⬚C
Boiling
point,⬚C
11425mm
Flash
point,⬚C
126.18
171, 151
1.170
CH3NHC("S)NH2
CH3C6H4CONHCH3
CH3C6H4SO2NHCH3
90.15
149.19
185.25
4, 70
9, 465
11, 105
1.15815
119–121
69–71
76–79
CH3C6H4SO2OCH3
186.23
11, 99
1.234
27.5
1455mm
⬎110
CH3Si(O2CCH3)3
Cl3CCO2CH3
220.26
177.42
43, 1896
2, 208
1.17520
4
1.488
1.40820
1.455820
40–45
883mm
153
85
72
CH3SiCl3
CH3Si(OCH3)3
F3CCO2CH3
149.48
178.30
128.05
43, 1896
4, 629
23, 427
1.273
0.895
1.273
1.411020
1.384020
1.290720
66
141–143
43
⫺15
23
⫺7
F3CSO2OCH3
164.10
34, 34
1.450
1.324420
94–99
38
(HO)3C6H2CO2CH3
184.15
10, 483
CH3Si(OCH3)3
136.22
44, 4203
0.955
1.370320
102
11
(CH3)3CCO2CH3
116.16
2, 320
0.873
1.390020
101
6
F3CC("O)N(CH3)Si(CH3)3
199.25
1.075
1.380220
132
25
[CH3P(C6H5)3]⫹ Br⫺
357.24
16, 760
CH3(CH2)8CH(CH3)CHO
CH3NHCONH2
CH3CON(CH3)CH"CH2
184.32
74.08
99.13
171
93
4, 64
43, 442
7025mm
58
Solubility in 100
parts solvent
82
v s aq, alc
201–203
230–234
0.83015
4
1.204
0.959
1.432120
101–102
1.482920
s alc, eth
v s aq, alc; i eth
INTERACTIVE
m443
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
m467
Methyl vinyl ether
Morpholine
4-Morpholinepropionitrile
N-Morpholino-1-cyclohexene
3-(N-Morpholino)-1,2propanediol
Myrcene
n1
n2
1-Naphthaldehyde
Naphthalene
n3
1-Naphthalenecarboxylic acid
1,5-Naphthalenediamine
1,8-Naphthalenediamine
m465
m466
n4
n5
CH3OCH"CH2
0.751120
4
1.000520
1.037
1.3947
1.454820
1.471520
167.25
0.995
1.512820
161.20
1.157
58.08
87.12
140.19
13, 1857
27, 5
273, 337
⫺123
⫺4.9
21
5.5
128
1212mm
⫺56
375
12010mm
68
19130mm
⬎110
167
39
s alc, chl, eth, HOAc
1–2
80
16115mm
217.7
⬎110
79
300
s alc, eth
0.3 aq; 7 alc; 33 bz; 50
chl
sl s aq; v s hot alc, eth
37–38
(CH3)2C"CHCH2CH2C("CH2)CH"CH2
C10H7CHO
C10H8
136.24
1, 264
0.801320
1.470920
156.18
128.17
7, 400
5, 531
1.15020
4
1.16220
4
1.652020
1.5821100
C10H7CO2H
172.18
9, 647
160–162
C10H6(NH2)2
158.20
13, 203
185–187
C10H6(NH2)2
158.20
13, 204
1.126599
4
1.281
66.5
s hot aq, hot alc
20512mm
MSTFA, m457
Myristic acid, t44
Myristolyl chloride, t46
Myristyl alcohol, t45
Myristyl bromide, b36
Naphthacene, b7
1-Naphthaleneacetamide, n13
1-Naphthaleneacetonitrile, n16
1,2-(1,8-Naphthalene)benzene, f1
Naphthalenediols, d439 thru d442
sl s aq; s alc, eth
RIGHT
Methyl veratrate, m231
Michler⬘s ketone, b178
Monoethyl adipate, e177
Monoglyme, d505
Monomethyl adipate, m277
Monomethyl glutarate, m276
Monomethyl succinate, m278
4-Morpholinocarboxyaldehyde, f39
1-Morpholinocyclopentene, c403
4-Morpholinoethanol, h127
4-Methyl-2-thiouracil, h125
Methyl o-toluate, m309
Methyl m-toluate, m311
Methyltrichlorosilane, t242
Methyl trimethylacetate, m235
␤-Methylumbelliferone, h148
Methyl undecyl ketone, t263
Methyl urethane, m187
Methyl valerate, m362
4-Methylvaleronitrile, m361
1.682899
0.8 aq; v s alc
misc aq, alc, bz, eth
DEAN 37261 (McGHP)
m462
m463
m464
ROTATED
m443
m463
m464
m465
m466
INTERACTIVE
No.
n6
n7
n8
n9
n10
n11
n12
Name
1-Naphthalenesulfonic
acid
2-Naphthalenesulfonic
acid
1,8-Naphthalic
anhydride
1-Naphthol
2-Naphthol
1.282
Density,
g/mL
Refractive
index
Melting
point,⬚C
C10H7SO3H
208.24
11, 155
C10H7SO3H
208.24
11, 171
198.18
17, 521
C10H7OH
C10H7OH
144.17
144.17
6, 596
6, 627
1.095499
4
1.2174
158.16
202.21
7, 724
6, 645
1.422
C10H7OCH2CO2H
C10H7CH2ONH2
185.23
9, 666
182
C10H7O2CCH3
C10H7CH2CO2H
C10H7CH2CN
C10H7NH2
C10H7NCO
186.21
186.21
167.21
143.18
169.19
162.24
6, 608
9, 666
9, 667
12, 1212
12, 1244
23, 117
1.619220
1.6703
1.634420
1.588220
43–46
135
33–35
50
4
⫺79
191.14
165.15
165.15
138.13
138.13
138.13
151.12
151.12
166.12
166.12
123.11
4, 369
7, 288
7, 288
12, 687
12, 698
12, 711
7, 250
7, 256
9, 373
9, 381
5, 233
1.554615
242 dec
76–78
78–80
71
114
147
58
106–107
174–178
140–143
5.8
N(CH2CO2H)3
O2NC6H4COCH3
O2NC6H4COCH3
O2NC6H4CH2
O2NC6H4CH2
O2NC6H4CH2
O2NC6H4CHO
O2NC6H4CHO
O2NC6H4CONH2
O2NC6H4CONH2
C6H5NO2
1.12325
25
1.177
1.009720
4
1.620699
Flash
point,⬚C
Solubility in 100
parts solvent
90 dehydrates
124 dehydrates
v s aq, alc; sl s eth
268
sl s HOAc
96
123
v s aq, alc
288
285
161
126
155–157
1.44215
1.43
1.43714
1.279220
4
1.496
32
1.462
1.20515
4
Boiling
point,⬚C
v s alc, bz, chl, eth
0.1 aq; 125 alc; 6 chl;
77 eth; s alk
s bz, chl, eth, hot alc
i aq; s bz, CS2
⬎110
dec
19418mm
301
267
12317mm
202
202
284
306
332
16423mm
⬎110
157
⬎110
101
165
317
210.8
88
s alc, eth
3.3 alc; v s chl, eth
s alc
0.2 aq; v s alc, eth
misc aq; v s alc, eth,
PE
0.1 aq; s hot alc
s alc, eth
s alc
s hot aq, alc, chl
0.1 aq; 5 alc; 6 eth
4 alc; 3.3 eth; s bz
s alc, chl, eth
s alc, bz, HOAc
s hot aq, hot alc, eth
v s alc, bz, eth
INTERACTIVE
Nitrilotriacetic acid
3⬘-Nitroacetophenone
4⬘-Nitroacetophenone
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
3-Nitrobenzaldehyde
4-Nitrobenzaldehyde
2-Nitrobenzamide
3-Nitrobenzamide
Nitrobenzene
Beilstein
reference
ROTATED
n20
n21
n22
n23
n24
n25
n26
n27
n28
n29
n30
n13
Formula
weight
LEFT
n14
n15
n16
n17
n18
n19
1,4-Naphthoquinone
(2-Naphthoxy)acetic
acid
2-(1-Naphthyl)acetamide
1-Naphthyl acetate
1-Naphthylacetic acid
1-Naphthylacetonitrile
1-Naphthylamine
1-Naphthyl isocyanate
Nicotine
Formula
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
n32
n33
n34
n35
n36
n37
n38
n39
n40
1.283
n41
n42
n43
n44
3-Nitrobenzene-1,2dicarboxylic acid
5-Nitrobenzene-1,3dicarboxylic acid
2-Nitrobenzenesulfonyl
chloride
5-Nitrobenzimidazole
2-Nitrobenzoic acid
3-Nitrobenzoic acid
4-Nitrobenzoic acid
4-Nitrobenzonitrile
3-Nitrobenzoyl
chloride
4-Nitrobenzoyl
chloride
2-Nitrobenzyl alcohol
3-Nitrobenzyl alcohol
4-Nitrobenzyl alcohol
4-Nitrobenzyl bromide
O2NC6H3(CO2H)2
211.13
9, 823
216 dec
2 aq; v s hot alc
O2NC6H3(CO2H)2
211.13
9, 840
260
0.15 aq; v s alc, eth
O2NC6H4SO2Cl
221.62
11, 67
65–67
s eth; d hot aq, alc
O2NC6H4CO2H
O2NC6H4CO2H
O2NC6H4CO2H
O2NC6H4CN
O2NC6H4COCl
163.14
167.12
167.12
167.12
148.12
185.57
23, 135
9, 370
9, 376
9, 389
9, 397
9, 381
207–209
146–148
140–142
242.8
146–149
32–35
275–278
s alc, acid
0.7 aq; 33 alc; 22 eth
0.3 aq; 33 alc; 40 acet
9 alc; 2 eth; 5 acet
s HOAC; sl s aq, alc
dec aq, alc; v s eth
O2NC6H4COCl
185.57
9, 394
75
205105mm
O2NC6H4CH2OH
O2NC6H4CH2OH
O2NC6H4CH2OH
O2NC6H4CH2Br
153.14
153.14
153.14
216.04
6, 447
6, 449
6, 450
5, 334
70–72
30–32
92–94
98–100
270
1803mm
18512mm
1.58
1.494
1.58
dec aq, alc; s eth
⬎110
Nicotinic acid, p266
Nicotinonitrile, c329
Ninhydrin, i13
Nioxime, c361
2,2⬘,2⬙-Nitrilotriethanol, t266
1,1⬘,1⬙-Nitrilotris(2-propanol), t325
2-Nitro-p-anisidine, m89
5-Nitro-o-anisidine, m90
Nitroanisoles, m81, m92
s aq, alc, eth
v s alc, eth; sl s aq
2 alc; v s eth
RIGHT
NBS, b422
Neohexane, d567
Neohexene, d574
Neopentane, d673
Neopentyl alcohol, d676
Neopentyl glycol, d594
Neophyl chloride, c178
Neral, d666
Nicotinaldehyde, p262
1-Naphthol-2-carboxylic acid, h158
3-Naphthol-2-carboxylic acid, h160
1-Naphthonitrile, c327
1-Naphthylamine, a228
N-1-Naphthylaniline, p132
1-Naphthyl bromide, b376
1-Naphthyl chloride, c185
Natural orange 6, h161
NBA, b247
⬎110
DEAN 37261 (McGHP)
n31
ROTATED
n8
n11
n19
n34
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
1.4425
4
1.61325
0.97520
20
1.129625
4
1.4112
1.441420
Melting
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
1.284
n45
n46
n47
n48
n49
n50
4-Nitrobenzyl chloride
2-Nitrobiphenyl
4-Nitrobiphenyl
1-Nitrobutane
3-Nitro-2-butanol
3-Nitrocinnamic acid
O2NC6H4CH2Cl
O2NC6H4C6H5
O2NC6H4C6H5
CH3CH2CH2CH2NO2
CH3CH(NO2)CH(OH)CH3
O2NC6H4CH"CHCO2H
171.58
199.21
199.21
103.18
119.12
193.16
n51
n52
2-Nitrodiphenylamine
Nitroethane
O2NC6H4NHC6H5
CH3CH2NO2
214.22
75.07
5, 329
5, 582
5, 583
1, 123
1, 373
Merck:
12, 6692
12, 690
1, 99
n53
5-Nitro-2-furaldehyde
semicarbazone
1-nitroguanidine
5-Nitro-1H-indazole
Nitromethane
1-Nitronaphthalene
3-Nitro-2-pentanol
2-Nitrophenol
4-Nitrophenol
4-Nitrophenyl acetate
2-Nitrophenylacetic
acid
4-Nitrophenylacetic
acid
4-Nitrophenylacetonitrile
2-Nitro-1,4-phenylenediamine
4-Nitro-1,2-phenylenediamine
4-Nitrophenylhydrazine
198.14
173, 4467
242–244
i aq; s alc
4.5 aq; misc alc, eth; s
alk, chl
s alk, chl, alk; 0.2 alc
CH3NO2
C10H7NO2
CH3CH2CH(NO2)CH(OH)CH3
O2NC6H4OH
O2NC6H4OH
O2NC6H4O2CCH3
O2NC6H4CH2CO2H
104.07
163.14
61.04
173.17
133.15
139.11
139.11
181.15
181.15
3, 126
23, 129
1, 74
5, 553
1, 385
6, 213
6, 226
6, 233
9, 454
dec ⬎225
207–209
⫺28.4
59–60
0.4 aq; sl s MeOH
s alc, bz, eth, acet
11 aq; s alc, eth
s alc; v s chl, eth
O2NC6H4CH2CO2H
181.15
9, 455
153–155
s alc, bz, eth; sl s aq
O2NC6H4CH2CN
162.15
9, 456
115–117
s alc, eth; i aq
O2NC6H3(NH2)2
153.14
13, 120
137–140
O2NC6H3(NH2)2
153.14
13, 29
199–201
sl s aq; s HCl
O2NC6H4NHNH2
153.14
15, 468
156 dec
s alc, chl, eth, hot bz
n64
n65
n66
47
91
200–201
1.052820
20
1.132225
4
1.223
1.081825
4
1.495
1.270120
4
1.392020
1.379525
76
⫺90
1.443020
45
113–114
77–79
139–142
8 alc; s eth
s alc, acet, CCl4
sl s alc; s chl, eth
sl s aq; misc alc, eth
1 alc
114
101.2
304
10010mm
216
279
28
35
90
s alc, bz, eth, alk
s aq; v s alc, chl, eth
s aq; v s alc, bz, eth
s hot aq, alc
INTERACTIVE
n67
179
ROTATED
n63
O2NNHC("NH)NH2
325
340
152.8
9210mm
LEFT
n54
n55
n56
n57
n58
n59
n60
n61
n62
70–73
36.7
112–114
⫺81.3
Boiling
point,⬚C
n69
n70
n71
n72
n73
n74
n75
n76
n77
n78
1.285
n79
n80
n81
2-Nitrophenyl phenyl
ether
4-Nitrophenyl phenyl
ether
3-Nitro-1,2-phthalic
acid
4-Nitro-1,2-phthalic
acid
3-Nitrophthalic
anhydride
1-Nitropropane
2-Nitropropane
2-Nitro-1-propanol
4-Nitropyridine-Noxide
Nitrosobenzene
N-Nitrosodimethylamine
4-Nitrosodiphenylamine
1-Nitroso-2-naphthol
⬍ ⫺20
1848mm
6, 232
53–56
320
211.13
9, 823
211.13
9, 828
213–216
dec
170–172
193.11
17, 486
163–165
CH3CH2CH2NO2
(CH3)2CHNO2
CH3CH(NO2)CH2OH
O2NC5H4N(:O)
89.09
89.09
105.09
140.10
1, 115
1, 116
1, 358
203, 2528
C6H5NO
(CH3)2NNO
107.11
74.08
6, 230
8, 84
C6H5NC6H4NO
198.22
144–145
v s alc, bz, chl, eth
C10H6(NO)OH
173.16
Merck:
12, 6737
7, 712
109–110
377.26
112, 190
⬎300
3 alc; s bz, eth, alk;
0.1 aq
2.5 aq; sl s alc
O2NC6H4OC6H5
215.21
62, 222
O2NC6H4OC6H5
215.21
O2NC6H3(CO2H)2
O2NC6H3(CO2H)2
1-Nitroso-2-naphthol3,6-disulfonic acid
disodium salt
hydrate
1.000920
0.982120
1.184125
4
1.57520
1.401620
1.394920
1,437920
⫺108
⫺91.3
s alc, eth
⬎110
s bz, eth
sl s aq, bz
131.1
120.3
9910mm
36
24
100
1.4 aq; misc org solv
1.7 aq; misc org solv
s aq, alc, eth
5918mm
151
61
v s aq, alc, eth
159–162
67–69
1.004820
4
Nitroglycerine, g22
5-Nitroisophthalic acid, n32
1.436820
3-Nitrophenyl disulfide, b216
3-Nitro-o-phthalic acid, n31
RIGHT
4-Nitrobenzyl cyanide, n64
Nitrocresols, m339, m340
1.253920
DEAN 37261 (McGHP)
n68
ROTATED
n53
n55
n72
n81
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
123.11
7, 622
n83
n84
n85
n86
2-Nitrotoluene
3-Nitrotoluene
4-Nitrotoluene
2-Nitro-␣,␣,␣-trifluorotoluene
3-Nitro-␣,␣,␣-trifluorotoluene
5-Nitrouracil
Nonadecane
Nonane
1,9-Nonanediamine
Nonanedinitrile
1,9-Nonanedioic acid
1,9-Nonanediol
Nonanenitrile
Nonanoic acid
␥-Nonanoic lactone
1-Nonanol
2-Nonanone
3-Nonanone
5-Nonanone
Nonanoyl chloride
3-Nonen-2-one
Nonyl aldehyde
Nonylamine
Nopol
Norbornane
2-Norbornanone
CH3C6H4NO2
CH3C6H4NO2
CH3C6H4NO2
CF3C6H4NO2
137.14
137.14
137.14
191.11
5, 318
5, 321
5, 323
52, 251
1.162219
15
1.158120
4
1.392
CF3C6H4NO2
191.11
5, 327
157.09
268.51
128.26
158.29
150.23
188.22
160.26
139.24
158.24
156.23
144.26
142.24
142.24
142.24
176.69
140.23
142.24
143.27
166.26
96.17
110.16
24, 320
1, 174
1, 165
4, 272
2, 709
2, 707
1, 493
2, 354
2, 352
17, 245
1, 423
1, 709
1, 709
1, 710
2, 353
13, 3017
1, 708
4, 198
63, 396
51, 45
7, 57
n87
1.286
n88
n89
n90
n91
n92
n93
n94
n95
n96
n97
n98
n99
n100
n101
n102
n103
n104
n105
n106
n107
n108
CH3(CH2)17CH3
CH3(CH2)7CH3
H2N(CH2)9NH2
NC(CH2)7CN
HO2C(CH2)7CO2H
HO(CH2)7OH
CH3(CH2)7CN
CH3(CH2)7CO2H
CH3(CH2)8OH
CH3(CH2)6COCH3
CH3(CH2)5COCH2CH3
(CH3CH2CH2CH2)2CO
CH3(CH2)7COCl
CH3(CH2)4CH"CHCOCH3
CH3(CH2)7CHO
CH3(CH2)8NH2
Flash
point,⬚C
Solubility in 100
parts solvent
126
dec 144
1.547220
1.545920
⫺10
15.5
52
31–32
222
231.9
238
10520mm
106
101
106
95
s aq; v s alc, eth; explodes on contact
with conc acid, alk,
or fire
s alc, bz
misc alc, eth; s bz
s alc, bz, chl, eth
v s alc, bz
1.43616
4
1.471520
⫺2.4
200–205
87
s alc, eth
0.777632
4
0.717620
4
1.433538
1.405420
⬎300
32
⫺53.5
37–38
1.446020
168
31
⬎110
⬎110
s eth; sl s alc
s abs alc, eth
0.929
1.02920
4
0.85115
4
0.90620
4
0.976
0.827920
4
0.832
0.821
0.80620
4
0.94615
4
0.848
0.82719
19
0.782
0.973
1.426020
1.433020
1.447520
1.433820
1.421020
1.420420
1.419020
1.437720
1.448420
1.424020
1.433020
1.493020
330
150.8
258
17611mm
286100mm
17715mm
224.0
254.5
1226mm
215
192743mm
187–188
186–187
215.4
8512mm
185
201
230–240
168–172
33
106.5
47–49
⫺34.2
12.5
⫺5.5
⫺21
⫺50
⫺60.5
82–84
94–96
⬎110
81
100
⬎110
75
64
67
60
95
81
63
62
98
v s alc, bz, eth
0.24 aq; v s alc; 3 eth
s alc, eth
s alc, chl, eth
0.6 aq; misc alc, eth
misc alc, eth
dec aq, alc; s eth
sl s aq; s alc, eth
s alc
INTERACTIVE
HOC6H4NO
Boiling
point,⬚C
ROTATED
4-Nitrosophenol
Melting
point,⬚C
LEFT
n82
Refractive
index
n110
o1
o2
o3
o4
o5
o6
o7
o8
o9
o10
exo-2-Norbornyl
formate
(⫹)-Norephedrine
cis,cis-9,12-Octadecadienoic acid
Octadecanamide
Octadecane
1-Octadecanethiol
Octadecanoic acid
1.287
1-Octadecanol
9,12,15-Octadecatrienoic acid
1-Octadecene
9-Octadecen-1-amine
cis-9-Octadecenoic
acid
140.18
6,3, 219
1.048
1.462220
C6H5CH(OH)CH(CH3)NH2
CH3(CH2)4CH"CHCH2CH"CH(CH2)7CO2H
CH3(CH2)16CONH2
CH3(CH2)16CH3
CH3(CH2)17SH
CH3(CH2)16CO2H
151.21
280.44
132, 371
2, 496
0.902520
4
1.469920
51–54
⫺5
23016mm
283.50
254.50
286.57
284.48
2, 383
1, 173
1,3, 1838
2, 377
0.776728
4
0.84770
1.436728
1.4648
1.429980
102–104
28.2
31–35
69
25112mm
316.3
360
383
CH3(CH2)17OH
CH3(CH2CH"CH2)3CH2(CH2)6CO2H
CH3(CH2)15CH"CH2
CH3(CH2)7CH"CH(CH2)8NH2
CH3(CH2)7CH"CH(CH2)7CO2H
270.50
278.44
1, 431
2, 499
0.812358
4
0.91418
4
1.438820
1.480020
59.6
20310mm
23017mm
252.49
267.50
282.47
1, 226
0.79118
4
0.813
0.893620
4
1.443920
1.459620
1.458120
17.7
314.9
13.4
360
2, 463
53
⬎110
v s eth; 10 PE; s abs
alc
s hot alc, hot eth
s acet, eth; sl s alc
s eth; sl s alc
4.9 alc; 20 bz; 50 chl;
3.9 acet; 16.6 CCl4;
s toluene, pentyl
acetate
s alc, eth
s alc, bz, eth
165
185
⬎110
148
154
189
s hot acet
s alc, bz, chl, eth
5-Norbornen-2-carbaldehyde, b136
Norbornene, b135
Norbornylene, b135
Norcamphor, a104
Norleucine, a182
Norvaline, a248
NTA, n20
RIGHT
5-Nitro-o-toluidine, m329
4-Nitroveratrole, d511
Nitroxylenes, d638 thru d641
Nonyl alcohol, n98
Nonyl iodide, i42
2,5-Norbornadiene, b134
exo-2-Norbornanamine, a245
N-Nitrosophenylhydroxylamine, c317
Nitroso-R-salt, n81
3-Nitro-o-toluic acid, m334
3-Nitro-p-toluic acid, m336
4-Nitro-m-toluic acid, m331
6-Nitro-m-toluic acid, m337
2-Nitro-p-toluidine, m330
4-Nitro-o-toluidine, m328
6716mm
DEAN 37261 (McGHP)
n109
ROTATED
n88
n97
n106
n107
n108
n109
INTERACTIVE
No.
o11
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
1.288
22, 441
0.85179
1.430899
44-45
288100mm
CH3(CH2)7CH"CH(CH2)8OH
CH3(CH2)7CH"CH9(CH2)7COCl
268.49
300.92
1, 453
2, 469
0.85020
4
0.912
1.461020
1.463020
13–19
1958mm
1803mm
⬎110
⬎110
H2C"CHCO2(CH2)17CH3
CH3(CH2)17NH2
CH3(CH2)17NCO
CH3(CH2)17SiCl3
324.55
269.52
299.51
387.94
24, 1468
4, 196
43, 439
0.800
0.77727
0.847
0.984
1.450120
1.460220
23232mm
1735mm
22310mm
⬎110
⬎110
148
89
CH3(CH2)17OCH"CH2
H2C"CH(CH2)4CH"CH2
HCF2CF2CF2CF2CH2OH
296.54
110.20
232.07
1.444030
1.422020
1.317820
28
14, 1648
0.82130
4
0.746
1.664720
1875mm
114–121
140–141
177
9
75
[-(CH3)2SiO-]4
296.62
43, 1885
0.956
1.395820
17–18
176
60
[(CH3)3SiO]2Si(CH3)2
CH3(CH2)6CH3
H2N(CH2)8NH2
HO2C(CH2)6CO2H
CH3(CH2)5CH(OH)CH2OH
HO(CH2)8OH
CH3(CH2)6CN
CH3(CH2)7SH
CH3(CH2)6CO2H
236.54
114.23
144.26
174.20
146.23
146.23
125.22
146.30
144.21
43, 1879
1, 159
4, 271
2, 691
13, 2217
1, 490
2, 349
13, 1710
2, 347
0.820020
0.702820
4
1.384820
1.397420
⬎110
1.420220
1.452520
1.427920
153
125.7
225–226
23015mm
13210mm
17220mm
198
199.0
239
29
22
165
0.813520
0.843
0.908820
4
ca. ⫺80
⫺56.8
50–52
140–144
36–38
59–61
⫺45.6
⫺49.2
16.6
⫺15.5
234
195
⬎110
81
175
174–176
176.6
173
71
65
71
52
142.20
130.23
17, 244
1, 418
0.981
0.825820
4
1.444020
1.429020
o33
o34
o35
o36
(⫾)-2-Octanol
3-Octanol
4-Octanol
2-Octanone
CH3(CH2)5CH(OH)CH3
CH3(CH2)4CH(OH)CH2CH3
CH3(CH2)3CH(OH)CH2CH2CH3
CH3(CH2)5COCH3
130.23
130.23
130.23
128.22
1, 419
11, 208
0.819320
4
0.819
0.819220
0.81920
4
1.420220
1.426020
1.42520
1.415020
1, 704
⫺31.6
⫺16
s alc, eth; i aq
s alc, bz, eth
s bz, PE; sl s alc
s eth; sl s alc
0.16 aq; 0.6 eth; s alc
73
68
⬎110
v s alc; sl s aq, eth
s eth; sl s alc
s alc
0.07 aq; v s alc, chl,
eth, PE
0.06 aq; misc alc, chl,
eth
0.1 aq; misc, alc, eth
i aq; misc alc, eth
INTERACTIVE
CH3(CH2)7OH
s bz, chl, eth
ROTATED
␥-Octanoic lactone
1-Octanol
o21
32–34
55–57
15–16
Solubility in 100
parts solvent
LEFT
o31
o32
o18
o19
o20
Flash
point,⬚C
282.47
o22
o23
o24
o25
o26
o27
o28
o29
o30
o14
o15
o16
o17
Boiling
point,⬚C
CH3(CH2)7CH"CH(CH2)7CO2H
trans-9-Octadecenoic
acid
cis-9-Octadecen-1-ol
9-Octadecenoyl
chloride
Octadecyl acrylate
Octadecylamine
Octadecyl isocyanate
Octadecyltrichlorosilane
Octadecyl vinyl ether
1,7-Octadiene
1H,1H,5H-Octafluoro1-pentanol
Octamethylcyclotetrasiloxane
Octamethyltrisiloxane
Octane
1,8-Octanediamine
1,8-Octanedioic acid
1,2-Octanediol
1,8-Octanediol
Octanenitrile
1-Octanethiol
Octanoic acid
o12
o13
Melting
point,⬚C
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
1.289
o42
o43
o44
o45
o46
o47
o48
o49
o50
o51
o52
o53
3-Octanone
4-Octanone
Octanoyl chloride
1-Octene
2-Octen-1-ylsuccinic
anhydride
Octyl acetate
Octyl aldehyde
Octylamine
Octyl cyanoacetate
Octyl gallate
1-Octyl-2-pyrrolidine
Octyltrichlorosilane
1-Octyne
1-Octyn-3-ol
L-(⫹)-Ornithine
Oxalic acid
Oxalic acid dihydrate
o54
o55
Oxalyl bromide
Oxalyl chloride
CH3(CH2)4COCH2CH3
CH3(CH2)3COCH2CH2CH3
CH3(CH2)6COCl
CH3(CH2)5CH"CH2
128.22
128.22
162.66
112.22
210.27
1, 706
1, 706
2, 348
1, 221
0.822020
4
0.809
0.955
0.714920
4
1.000
1.415020
1.413920
1.435020
1.408720
1.469420
CH3CO2(CH2)7CH3
CH3(CH2)6CHO
CH3(CH2)7NH2
NCCH2CO2(CH2)7CH3
3,4,5-(HO)3C6H2CO2(CH2)7CH3
2, 134
1, 704
4, 196
0.868
0.82120
4
0.782
0.934
1.418520
1.418320
1.429020
1.449020
CH3(CH2)7SiCl3
CH3(CH2)5C#CH
CH3(CH2)4CH(OH)C#CH
H2N(CH2)3CH(NH2)CO2H
HO2CCO2H
HO2CCO2H · 2H2O
172.27
128.22
129.25
197.28
282.34
197.32
247.67
110.19
126.20
132.16
90.04
126.07
43, 1907
1, 258
13, 1996
4, 420
2, 502
2, 502
0.920
1.07020
0.745720
0.864
1.465020
1.447320
1.415920
1.441020
BrC("O)C("O)Br
ClC("O)C("O)Cl
215.84
126.93
21, 236
2, 542
1.9017
4
1.65319
4
1.455
Octyl bromide, b385
Octyl chloride, c204
Octyl cyanide, n95
Octyldimethylamine, d649
Octyl ether, d729
Octyl iodide, i44
Octyl sulfide, d730
Oleic acid, o11
1.522020
1.429020
12–15
⫺5/⫺1
101–104
⫺25
⫺79.3
140
190 dec
⫺2H2O,
102
⫺19
⫺10
46
45
80
21
⬎110
211
171
175–177
950.11mm
88
51
62
⬎110
17215mm
226730mm
126.2
8319mm
⬎110
96
17
63
i aq; misc alc, eth
dec aq, alc; s eth
i aq; misc alc, eth
sl s aq; misc alc
sl s aq; misc alc
i aq; s alc, eth
i aq; s alc, eth
v s aq, alc; sl s eth
14 aq20; 40 alc; 1.3 eth
14 aq; 40 alc; 1 eth
103720mm
64
none
none
Oleoxyl chloride, o13
Oleyl alcohol, o12
Oleylamine, o9
o-Orthanilic acid, a115
7-Oxabicyclo[2.2.1]heptane, c331b, e7
7-Oxabicyclo[4.1.0]heptane, e6
6-Oxabicyclo[3.1.0]hexane, e10
Oxacyclopentane, t69
s eth; viol dec aq, alc
RIGHT
Octadecyl bromide, b384
Octadecyl iodide, i43
Octadecyl mercaptan, o4
2,3,4,6,7,8,9,10-Octahydropyrimidol[1,2-a]azepine, d62
Octaldehyde, o43
Octamethylene glycol, o27
Octanal, o43
1,8-Octanedicarboxylic acid, d10
tert-Octylamine, t103
103, 2079
⬍ ⫺70
⫺102
8–12
167–168
164
195
121
16810mm
DEAN 37261 (McGHP)
o37
o38
o39
o40
o41
ROTATED
o31
o41
o47
INTERACTIVE
No.
o56
o57
o58
o59
o60
o61
o62
o63
o64
o65
o66
1.290
o66a
o67
o68
o69
Beilstein
reference
118.10
103.08
88.07
87.08
102.09
113.16
2, 559
2, 559
2, 545
27, 135
3, 629
212, 216
CH3CO(CH2)3CN
CH3COCH2CH2CO2H
CH3C("O)CHO
CH3C("O)CO2H
111.14
116.12
72.06
88.06
138.17
33, 1234
3, 671
1, 762
3, 608
(CH3)3COC(CH3)3
130.23
HO2CCH2OCH2CO2H
H2NC6H4OC6H4NH2
NCCH2CH2OCH2CH2CN
134.09
200.24
124.14
CH3CH2C("O)CO2H
(CH2O)x
Density,
g/mL
Refractive
index
1.66720
4
1.20017
4
1.0275
4
1.397220
0.975
1.144725
4
1.045524
15
1.2674
1.120
1.432820
1.439620
1.420920
1.431520
1.488020
0.7658
1.394920
3, 234
13, 441
19, 385
6, 206
1, 690
5, 205
1, 87
5, 247
C6Cl5OH
C5Cl5N
CH3(CH2)13CH3
CH3(CH2)13CN
[CH3(CH2)7]2C"O
266.34
251.33
212.42
223.40
226.40
6, 194
20, 232
1, 172
21, 163
1, 717
33–35
11.8
Boiling
point,⬚C
1.404920
1.537025
1, 656
1.834216
1.671225
4
1.71825
4
1.496720
1.503020
1.97822
4
0.768420
4
0.825
1.431920
1.442020
Solubility in 100
parts solvent
s hot aq; sl s alc, eth
s alk; sl s aq; i eth
sl s hot aq, alc
22048mm
8216mm
270
81
125
240
246
72
165 dec
1400.3mm
107
137
none
82
⬎110
1120.5mm
124
375
190–191
124–126
9.9
20–23
41–43
310
192
275–277
160
270
322
178
v s aq, alc, bz, eth
s aq, alc
misc aq, alc, eth
v s aq, alc; sl s eth
218
⬎110
71
12.6
6
223–226
21 (anhyd)
82–85
⫺29.0
140–143
v s aq, alc; v sl s eth
84 aq; v s alc, eth,
chlorinated HC’s
dec acids
dec
165 dec
0.998415
1.2625
4
Flash
point,⬚C
107
1.440520
1, 566
132.16
291.27
488.62
230.31
250.34
202.30
295.34
240 dec
218 dec
dec 350
86–89
32–34
69.2
142–145
190–192
1.043
[-HC(CH3)O-]3
(C2H5O)2P("S)C6H4NO2
C6Br5OH
Cl2CHC("O)CCl3
C6HCl5
Cl2CHCCl3
C6Cl5(NO2)
Melting
point,⬚C
none
none
none
s(slow) aq; s alk; i alc,
eth
11 aq; misc alc, chl
v s alc, bz, eth
sl s alc, eth
i aq; v s acet
v s bz, chl, eth
0.05 aq; misc alc, eth
s bz, chl
v s alc; s bz; 148 eth
132
⬎110
⬎110
v s alc, eth
s alc
INTERACTIVE
p9
p10
p11
p12
p13
Paraldehyde
Parathion
Pentabromophenol
Pentachloroacetone
Pentachlorobenzene
Pentachloroethane
Pentachloronitrobenzene
Pentachlorophenol
Pentachloropyridine
Pentadecane
Pentadecanenitrile
8-Pentadecanone
H2NNHC("O)C("O)NHNH2
H2NC("O)C("O)NHNH2
H2NC("O)C("O)NH2
Formula
weight
ROTATED
p2
p3
p4
p5
p6
p7
p8
Oxalyl dihydrazide
Oxamic hydrazide
Oxamide
2-Oxazolidone
2-Oxobutyric acid
2-Oxohexamethyleneimine
5-Oxohexanonitrile
4-Oxopentanoic acid
2-Oxopropionaldehyde
2-Oxopropionic acid
2-Oxo-1-pyrrolidinepropionitrile
2,2⬘-Oxybis[2-methyl]propane
2,2⬘-Oxydiacetic acid
4,4⬘-Oxydianiline
3,3⬘-Oxydipropionitrile
Paraformaldehyde
Formula
LEFT
p1
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
p21
p22
p23
p24
p25
1.291
3-Pentadecylphenol
1,2-Pentadiene
cis-1,3-Pentadiene
trans-1,3-Pentadiene
1,4-Pentadiene
Pentaerythritol
Pentaerythritol
diacrylate
monostrearate
Pentaerythritol
triacrylate
Pentaerythrityl
tetranitrate
CH3(CH2)14C6H4OH
CH3CH2CH"C"CH2
CH3CH"CHCH"CH2
CH3CH"CHCH"CH2
H2C"CHCH2CH"CH2
C(CH2OH)4
CH3(CH2)16CO2CH2C(CH2O2CCH"CH2)2CH2OH
(H2C"CHCO2CH2)3CCH2OH
304.52
68.12
68.12
68.12
68.12
136.15
510.72
C(CH2ONO2)4
316.15
12, 602
1.177320
4
Pentaethylenehexamine
Pentamethylbenzene
1,2,3,4,5-Pentamethylcyclopentadiene
H2N(CH2CH2NH)4CH2CH2NH2
232.38
44, 1245
0.950
1.509620
C6H(CH3)5
148.25
136.24
5, 443
0.91720
4
0.870
1.52720
1.473320
1, 251
1, 251
1, 251
1, 251
1, 528
298.30
0.692620
4
0.691010
0.676020
0.660822
4
1.3825
4
1.018
1.420920
1.436320
1.430120
1.388820
1.548
1.180
1.486420
50–53
⫺137.3
⫺140.8
⫺87.5
⫺148.3
260
29–31
⬎110
⫺28
⫺28
4
6 aq; v sl s alc; i eth
⬎110
⬎110
140
explodes
on
shock
s acet; sl s eth, alc
⬎110
54.4
231
5813mm
91
44
Palmitic acid, h34
Pelargonaldehyde, n104
Pelargonic acid, n96
Pelargononitrile, n95
Pelargonoyl chloride, n102
Pentaerythritol diformal, t125
Pentalin, p7
Pentamethylene glycol, p32
Pentamethylene oxide, t83
v s alc, bz
RIGHT
1,1⬘-Oxybis(2-ethoxyethane), b186
1,1⬘-Oxybis(2-methoxyethane), b214
1,1⬘-Oxybis(3-methylbutane), d466a
1,1⬘-Oxybis(2-methylpropane), d458
1,1⬘-Oxybis(pentane), d738
2,2⬘-Oxybis(propane), d476
3,3⬘-Oxybis(1-propene), d31
2,2⬘-Oxydiethanethiol, b208
2,2⬘-Oxydiethanol, b198
Oxapentadiene, f45
Oxetanone, p210
Oxirane, e147
2-Oxo-10-bornanesulfonic acid, c5
3-Oxobutanoic acid, a25
Oxolan-2-one, b617
3-Oxo-N-phenylbutanamide, a24
2,2⬘-Oxybis(chloroethane), b163
1,1⬘-Oxybis(chloromethane), b165a
1951mm
44.9
44.1
42.0
26.0
DEAN 37261 (McGHP)
p14
p15
p16
p17
p18
p19
p20
ROTATED
o59
o61
o66
p25
INTERACTIVE
No.
p26
p27
1.292
p28
p29
p30
p31
p32
p33
p34
p35
p36
Beilstein
reference
Density,
g/mL
Refractive
index
0.830
1.442020
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
⫺20
198
59–61
19412mm
1.394220
1.357520
1.459120
1.439720
1.449420
1.406820
1.451020
1.399115
⫺92
⫺129.7
⫺129.7
103
36.0
178–180
206
239
110–112
138
141.3
12
⫺49
62
104
129
19
34
40
1.4 aq; misc alc, eth
misc alc, eth
s aq, alc; sl s eth
0.840
0.939020
4
0.814620
4
0.809820
4
0.815025
4
0.809520
0.814320
0.988
1.016
1.109
1.446020
1.408020
1.410020
1.405420
1.407725
1.390020
1.392020
1.514320
1.421620
1.465020
⫺75.7
⫺33.7
⫺79
⫺73
⫺69
⫺76.8
⫺39.0
126.6
186
137.5
119.3
116
102
102.0
1075mm
125–127
1350.2mm
18
96
33
34
41
7
13
102
32
⬎110
i aq; misc alc, eth
2.4 aq; v s alc, eth
2.7 aq22; misc alc, eth
16.6 aq20; misc alc, eth
5.5 aq20; s alc, eth
misc acet, bz, eth, PE
3.4 aq
s alc, eth
13, 2107
1.008720
4
1.433020
⫺27
275–276
140
1, 210
1, 210
1, 210
22, 400
2, 427
0.642920
4
0.650320
4
0.648220
4
0.820
0.837
1.371420
1.381320
1.379220
1.426920
1.422120
⫺165
⫺151
⫺140
30.1
37.0
36.3
128
144–147
⫺18
⫺20
⫺45
23
40
s aq; misc hydrocarbon
solvents
misc alc, bz, eth
misc alc, eth
misc alc, eth
173.30
4,4, 1245
138.17
262, 213
CH3CH2CH2CH2CHO
CH3CH2CH2CH2CH3
H2N(CH2)5NH2
CH3CH2CH2CH(OH)CH2OH
HO(CH2)5OH
CH3CH2C("O)C("O)CH3
CH3COCH2COCH3
CH3CH2CH2CH2CN
CH3(CH2)4SO3⫺ Na⫹
86.13
72.15
102.18
104.15
104.15
100.11
100.11
83.13
174.19
1, 676
1, 130
4, 266
12, 548
1, 481
1, 776
1, 777
2, 301
43, 23
0.809520
4
0.626220
4
0.87325
4
0.971
0.994120
0.957
0.972125
0.803515
4
CH3(CH2)4SH
CH3(CH2)3CO2H
CH3(CH2)4OH
CH3CH2CH2CH(OH)CH3
CH3CH2CH(OH)CH2CH3
CH3CH2CH2COCH3
CH3CH2COCH2CH3
C6H5CO(CH2)3CH3
CH3(CH2)3COCl
[-CH2CH2O-]5
104.22
102.13
88.15
88.15
88.15
86.13
86.13
162.23
120.58
220.27
1, 384
2, 299
1, 383
1, 384
1, 385
1, 676
1, 679
7, 327
2, 301
CH3(OCH2CH3)4OCH3
222.28
CH3CH2CH2CH"CH2
CH3CH2CH"CHCH3
CH3CH2CH"CHCH3
CH3CH2CH"CHCN
CH3CH"CHCH2CN
70.14
70.14
70.14
81.12
81.12
⫺18
⫺52
⫺23.1
⫺92
⬎300
53
s aq, alc; sl s eth
17 aq; misc alc, eth
i aq; s alc, eth
4 aq
INTERACTIVE
p48
p49
p50
p51
p52
[(CH3)2NCH2CH2]2NCH3
Formula
weight
ROTATED
p47
N,N,N⬘,N⬘,N⬙-Pentamethyldiethylenetriamine
1,5-Pentamethylenetetrazole
Pentanal
Pentane
1,5-Pentanediamine
1,2-Pentanediol
1,5-Pentanediol
2,3-Pentanedione
2,4-Pentanedione
Pentanenitrile
1-Pentanesulfonic acid,
sodium salt
1-Pentanethiol
Pentanoic acid
1-Pentanol
2-Pentanol
3-Pentanol
2-Pentanone
3-Pentanone
Pentanophenone
Pentanoyl chloride
1,4,7,10,13-Pentaoxacyclopentadecane
2,5,8,11,14-Pentaoxapentadecane
1-Pentene
cis-2-Pentene
trans-2-Pentene
cis-2-Pentenenitrile
trans-3-Pentenenitrile
Formula
LEFT
p37
p38
p39
p40
p41
p42
p43
p44
p45
p46
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
p60
p61
Pentyl acetate
Pentylamine
Pentylbenzene
2-Pentylcinnamaldehyde
4-tert-Pentylphenol
1-Pentyne
Perfluoro-1-octanesulfonyl fluoride
Peroxyacetic acid
Petroleum ether
p62
p63
Phenanthrene
1,10-Phenanthroline
p64
Phenethylisobutyrate
p57
p58
p59
CH3(CH2)4O2CCH3
CH3(CH2)4NH2
CH3(CH2)4C6H5
C6H5CH"C[(CH2)4CH3]CHO
130.19
87.16
148.25
202.30
2, 131
4, 175
5, 434
72, 310
0.875320
0.754420
0.859420
4
0.970
1.402020
1.44820
1.488520
1.557120
CH3CH2C(CH3)2C6H4OH
CH3CH2CH2C#CH
CF3(CF2)7SO2F
164.25
68.11
502.12
6, 548
1, 250
24, 996
0.96220
4
0.690120
4
1.824
1.385220
1.301020
1.22615
4
0.640
1.387620
1.363020
178.23
180.21
2, 169
Merck:
12, 7329
5, 667
23, 227
192.26
62, 451
0.988
CH3C("O)CO2H
Principally pentanes and hexanes
(CH3)2CHCO2CH2CH2C6H5
1.293
1.063
1.488020
tert-Pentylamine, d682
Pentyl bromide, b387
Pentyl chloride, c204a
Pentyl cyanide, h61
Pentyl mercaptan, p37
Peracetic acid, p60
Perdeuterocyclohexane, c348
Perfluoropropane, h44
Perylene, d65
Phenacetin, e51
Phenacyl bromide, b251
149.2
104
202.2
290
16
⫺1
65
⬎110
93
⫺106
262
40.2
154–155
⫺34
none
⫺0.2
110
35–60
41
⫺49
100
114–117
340
250
0.17 aq; misc alc, eth
v s aq; misc eth; s alc
s alc, misc bz, eth
s alc, eth
v s alc; misc eth
v s aq, alc, eth
misc bz, chl, eth, CCl4;
s glacial HOAc
1.6 alc; 50 bz; 30 eth
0.3 aq; 1.4 bz; s alc,
acet
108
Phenacyl chloride, c31
Phenazone, a299
1,2,4-Phenenyl triacetate, t193
Phenethyl acetate, p111
Phenethyl alcohol, p110
sec-Phenethyl alcohol, m149
Phenethylamine, p112
Phenethyl bromide, b334
Phenethyl chloride, c128
Phenetole, e36
RIGHT
Pentamethylethyl alcohol, t362
1,5-Pentanedicarboxylic acid, h7
Pentanedinitrile, g17
Pentanedioic acid, g14
3,6,9,12,15-Pentaoxaheptadecane, t53
2,5,8,11,14-Pentaoxapentadecane, b212
Pentetic acid, d363
Pentyl alcohol, p39
sec-Pentyl alcohol, p40
tert-Pentyl alcohol, m162
sec-Pentylamine, a246
76.05
⫺70.8
⫺55
⫺78.3
DEAN 37261 (McGHP)
p53
p54
p55
p56
ROTATED
p27
p62
p63
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
Name
1.294
Phenoxyacetyl chloride
4-Phenoxyaniline
2-Phenoxybutyric acid
2-Phenoxyethanol
1-Phenoxy-2-propanol
2-Phenoxypropionic
acid
3-Phenoxypropyl
bromide
3-Phenoxytoluene
Phenylacetaldehyde
Phenylacetaldehyde
dimethyl acetal
Phenylacetaldehyde
ethylene acetal
Phenyl acetate
Phenylacetic acid
Phenylacetonitrile
Phenylacetyl chloride
Phenylacetylene
Phenylacetylurea
C6H5OCH2COCl
C6H5OC6H4NH2
CH3CH2CH(OC6H5)CO2H
C6H5OCH2CH2OH
C6H5OCH2CH(OH)CH3
CH3CH(OC6H5)CO2H
170.60
185.23
180.20
138.17
152.19
166.18
6, 162
13, 438
6, 163
6, 146
61, 85
6, 163
1.235
C6H5O(CH2)3Br
215.10
6, 142
1.365
1.546020
C6H5OC6H4CH3
C6H5CH2CHO
C6H5CH2CH(OCH3)2
184.24
120.15
166.22
6, 377
7, 292
7, 293
1.051
1.02725
25
1.004
1.572720
1.529020
1.493020
164.21
194, 220
1.100
1.522020
C6H5O2CCH3
C6H5CH2CO2H
C6H5CH2CN
C6H5CH2COCl
C6H5C#CH
C6H5CH2CONHCONH2
136.15
136.15
117.15
154.60
102.14
178.19
1.073
1.09177
4
1.0214
1.169
0.9300
1.503020
(⫾)-3-Phenylalanine
Phenyl 4-aminosalicylate
4-Phenylazoaniline
C6H5CH2CH(NH2)CO2H
H2NC6H3-2-(OH)CO2C6H5
165.19
229.24
C6H5N"NC6H4NH2
197.24
6, 152
9, 431
9, 441
9, 436
5, 511
Merck:
12, 7343
14, 495
Merck;
12, 7426
161, 310
1.10222
4
1.06325
4
41
182
261–263
185.1
98–100
371
285 sl dec
84
79–83
14
13–18
116–119
225–226
18914mm
258
245.2
240
265
1.534020
1.537020
1.52320
1.523320
1.532520
1.547020
33–34
76.5
⫺23.8
⫺44.9
212–216
79
108
⬎110
135
Solubility in 100
parts solvent
6.7 aq; 8.2 bz; v s alc,
chl, eth, alk
8.2 alc; 1 eth
v s bz; s eth; sl s alc
1.3 aq; v s alc, bz,
HOAc, CS2, eth
dec aq, alc; s eth
s hot aq; v s alc, eth
sl s aq
s aq; v s alc, eth
s alc; sl s aq
13414mm
96
271–273
195
221
⬎110
86
83
12012mm
107
196
265.5
233.5
9512mm
142.4
76
271–273
153
123–126
Flash
point,⬚C
101
102
31
sl s aq; s alc, eth
misc alc, eth, chl
s hot aq, alc, eth
i aq; misc alc, eth
dec aq, alc
misc alc, eth
sl s alc, bz, chl, eth
1.4 aq
0.7 mg aq
⬎360
v s alc, bz, chl, eth
INTERACTIVE
C6H5OCH2CO2H
Boiling
point,⬚C
ROTATED
1.299
C6H5OH
Melting
point,⬚C
LEFT
p88
1.541841
18, 143
27, 63
6, 161
p69
p70
p71
p72
p73
p74
p86
p87
Refractive
index
318.33
199.28
152.15
Phenolphthalein
Phenothiazine
Phenoxyacetic acid
p80
p81
p82
p83
p84
p85
Density,
g/mL
1.057641
4
p66
p67
p68
p79
Beilstein
reference
6, 110
Phenol
p76
p77
p78
Formula
weight
94.11
p65
p75
Formula
p90
p91
p92
p93
p94
p95
p96
p97
p98
p99
p100
Phenylazoformic acid
2-phenylhydrazide
4-Phenylazophenol
2-Phenylbenzimidazole
Phenyl benzoate
N-Phenylbenzylamine
trans-4-Phenyl-3buten-2-one
2-Phenyl-3-butyn-2-ol
3-Phenylbutyraldehyde
2-Phenylbutyric acid
2-Phenylbutyronitrile
Phenyl chloroformate
Phenyl dichlorophosphate
C6H5N"NCONHNHC6H5
240.27
16, 24
C6H5N"NC6H4OH
C6H5CO2C6H5
C6H5CH2NHC6H5
C6H5CH"CHCOCH3
198.23
194.24
198.22
183.25
146.19
16, 96
23, 230
9, 116
12, 1023
7, 364
1.235
1.061
1.009745
4
1.583645
CH3C(OH)(C6H5)C#CH
CH3CH(C6H5)CH2CHO
CH3CH2CH(C6H5)CO2H
CH3CH2CH(C6H5)CN
C6H5O2CCl
C6H5OP(O)Cl2
146.19
148.21
164.20
145.21
156.57
210.98
62, 559
71, 168
92, 356
9, 541
6, 159
6, 179
0.997
1.055
0.974
1.248
1.412
1.517920
1.516020
1.508620
1.510720
1.523020
1.295
4-Phenoxybutyl bromide, b281
Phenylacetaldehyde dimethyl acetal, d516
N-Phenylacetamide, a18
2-Phenylacetoacetonitrile, a51
Phenylacetone, p147
␣-Phenylacetophenone, d26
␤-Phenylacrylic acid, c279
␥-Phenylallyl alcohol, c282
Phenylamine, a293
␤(Phenylamino)phenol, h115
156–159
dec
150–152
293–296
69–72
35–38
41.5
47–49
42–44
23020mm
298–299
306–307
260–262
⬎110
65
217–218
9416mm
270–2
11415mm
719mm
241–243
96
96
⬎110
105
75
⬎110
v s alc, eth
s abs alc; sl s bz, chl
v s hot alc; sl s eth
s alc, chl, eth
v s alc, bz, chl, eth
0.8 aq; s alc, bz, acet
s bz, eth
DEAN 37261 (McGHP)
p89
1-Phenylbutane, b521
2-Phenylbutane, b522
1-Phenyl-1,3-butanedione, b63
4-Phenyl-2-butanone, b77a
Phenyl cellosolve, p72
Phenyl chloride, c47
Phenylcyclohexane, c376
2-Phenylcinchoninic acid, p153
␣-Phenyl-o-cresol, h116
N-Phenylaniline, d760
o-Phenylanisole, m63
Phenylarsonic acid, b12
Phenylazoformic acid 2-phenylhydrazide, d746
N-Phenylbenzamide, b5
Phenylbenzene, b138
␣-Phenylbenzenemethanamine, a159
Phenylbenzoic acid, b139
Phenylboric acid, b13
Phenyl bromide, b262
RIGHT
ROTATED
p66
p67
p79
p91
INTERACTIVE
N-Phenyldiethanolamine
4-Phenyl-1,3-dioxane
2-Phenyl-1,3-dioxolane
1,2-Phenylenediamine
1,3-Phenylenediamine
1,4-Phenylenediamine
1,4-Phenylene diisocyanate
1-Phenyl-1,2ethanediol
1-Phenylethanol
2-Phenylethanol
2-Phenylethyl acetate
2-Phenylethylamine
1-Phenylethyl
propionate
(⫾)-2-Phenylglycine
1-Phenylheptane
1-Phenylhexane
Phenylhydrazine
Phenyl 1-hydroxy-2naphthoate
Phenyl 3-hydroxy-2naphthoate
2-Phenylimidazole
2-Phenyl-2-imidazoline
2-Phenyl-1,3indandione
2-Phenylindole
Phenyl isocyanate
Phenyl isothiocyanate
N-Phenylmaleimide
Phenylmalonic acid
p102
p103
p104
p105
p106
p107
p108
1.296
p109
p110
p111
p112
p113
p114
p115
p116
p117
p118
p119
p120
p121
p122
p123
p124
p125
p126
p127
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
C6H5N(CH2CH2OH)2
181.24
12, 183
1.12060
20
191, 616
1.111
1.106
C6H4-1,2-(NH2)2
C6H4-1,3-(NH2)2
C6H4-1,4-(NH2)2
C6H4-1,4-(NCO)2
164.21
150.18
108.14
108.14
108.14
160.13
13,
13,
13,
13,
C6H5CH(OH)CH2OH
138.17
6, 907
CH3CH(OH)(C6H5)
C6H5CH2CH2OH
CH3CO2CH2CH2C6H5
C6H5CH2CH2NH2
C2H5CO2CH(CH3)C6H5
122.17
122.17
164.20
212.18
178.23
6, 475
6, 478
9, 510
12, 1096
53, 1680
1.013020
1.02325
25
0.984
0.964025
4
1.007
1.527020
1.531720
1.498520
1.529025
1.489520
C6H5CH(NH2)CO2H
C6H5(CH2)6CH3
C6H5(CH2)5CH3
C6H5NHNH2
HOC10H6CO2C6H5
151.17
176.30
162.28
108.14
264.28
14, 460
5, 451
52, 337
152, 44
10, 332
0.860
0.861
1.097820
4
1.485020
1.486020
1.608020
C10H6(OH)CO2C6H5
264.28
10, 335
129–132
144.18
146.19
222.28
23, 182
23, 154
7, 808
144–147
94–99
148–150
193.25
119.12
135.19
173.17
180.16
20, 467
12, 437
12, 453
21, 400
C6H5NCO
C6H5NCS
C6H5CH(CO2H)2
6
33
61
105
Flash
point,⬚C
56–80
350 sl dec
103
63.5
146
97–98
250–251
800.3mm
257
285
267
260
66–68
272–274
20
⫺27
204
221
238–239
197.5
925mm
85
102
101
90
94
233
226
243
95
83
88
1.530020
1.526020
1.13915
Boiling
point,⬚C
⬍0
5 aq; v s alc; 29 eth;
25 bz
⬎110
98
156
⬎110
subl 255
1.095620
4
1.128825
4
1.535020
1.649720
⫺61
19.5
94–96
188–190
⫺30
⫺21
85–87
153 dec
Solubility in 100
parts solvent
v s alc, chl, eth; sl s aq
s aq, alc, acet, chl
1 aq; s alc, chl, eth
v s aq, alc, bz, eth, chl,
HOAc
2.3 aq
2 aq; misc alc, eth
2 aq; misc alc, eth
80 aq15; s alc; i eth
s org solvents, alk
misc eth
misc alc, bz, chl, eth
261160mm
25010mm
162–163
221
16312mm
55
87
dec aq, alc; s eth
i aq; s alc, eth
s alc, chl, eth
INTERACTIVE
p101
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
p129
p130
p131
p132
p133
Phenylmercury(II)
acetate
Phenylmercury(II)
chloride
Phenylmercury(II)
hydroxide
N-Phenylmorpholine
N-Phenyl-1naphthylamine
N-Phenyl-2naphthylamine
C6H5HgO2CCH3
336.74
C6H5HgCl
313.15
C6H5HgOH
294.70
Merck:
12, 7453
Merck:
12, 7454
16, 952
C10H7NHC6H5
163.22
219.29
27, 6
12, 1224
C10H7NHC6H5
219.29
12, 1275
150–152
0.17 aq; s alc, bz, acet
250–252
s bz, eth, pyr
190 dec
1.058270
51–54
60–62
268
22615mm
107–109
395
1-Phenylethanone, a31
Phenylethene, s11
N-Phenylformamide, f35
Phenylglyoxylic acid, b69
Phenylglyoxylonitrile, b67
Phenylethane, e74
Phenylethanenitrile, p82
1-Phenylethanol, m149
Phenylethanolamine, a257
N-Phenylethanolamine, a295
⬎110
1.0 aq; v s hot alc
s alc, bz, chl, eth
DEAN 37261 (McGHP)
p128
2,2⬘-(Phenylimino)diethanol, p101
p-(2-Phenylisopropyl)phenol, m316a
Phenyl mercaptan, t156
Phenylmethanol, b78
1.297
p103
p120
p121
p122
RIGHT
p102
ROTATED
p123
p126
p131
INTERACTIVE
Name
p134
p135
p136
p137
2-Phenyl-2-oxazoline
2-Phenylphenol
4-Phenylphenol
N-Phenyl-1,4phenylenediamine
Phenylphosphinic acid
Phenylphosphonic acid
Phenylphosphonic
dichloride
N-Phenylpiperazine
1-Phenylpiperidine
2-Phenyl-1,2propanediol
3-Phenyl-1propanethiol
1-Phenyl-1-propanol
3-Phenyl-1-propanol
1-Phenyl-2-propanone
2-Phenylpropionaldehyde
3-Phenylpropionaldehyde
3-Phenylpropionic acid
p138
p139
p140
p141
p142
p143
1.298
p144
p145
p146
p147
p148
p149
p150
p155
Phenylsuccinic acid
p152
p153
Beilstein
reference
C6H5C6H4OH
C6H5C6H4OH
C6H5NHC6H4NH2
147.18
170.21
170.21
184.24
27, 47
62, 623
6, 674
13, 76
C6H5PH(O)OH
C6H5P(O)(OH)2
C6H5P(O)Cl2
142.09
158.09
194.99
16, 791
16, 803
16, 804
CH3C(C6H5)(OH)CH2OH
162.24
161.25
152.19
C6H5CH2CH2CH2SH
Density,
g/mL
Refractive
index
1.118
1.213
1.567020
1.375
1.560020
233, 49
20, 22
6, 930
1.062120
4
1.001
1.587520
1.562020
152.26
61, 253
1.010
1.549420
C6H5CH(OH)CH2CH3
C6H5CH2CH2CH2OH
C6H5CH2COCH3
CH3CH(C6H5)CHO
136.19
136.19
134.18
134.18
6, 502
6, 503
72, 233
7, 305
0.991525
4
1.008
1.015720
4
1.00920
4
1.520020
1.525720
1.516020
1.517520
C6H5CH2CH2CHO
134.18
7, 304
1.019
1.523020
C6H5CH2CH2CO2H
150.18
9, 508
1.047100
4
162.19
24, 2
C6H5C5H4N
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
750.3mm
282
321
123
165
85–87
163–166
3
258
⬎110
3–4
44–45
286
257–258
16226mm
⬎110
106
⬎110
10910mm
90
219
235
10013mm
202–205
90
109
84
76
9812mm
95
280
⬎110
268–270
⬎110
44–46
17312mm
⬎110
167–169
⫺H2O,
⬎168
12
57–59
165–167
73–75
⫺18
27
47–49
121–123
155.20
249.27
20, 424
22, 103
1.086
C6H5(OH)CO2C6H5
214.22
10, 76
1.25
HO2CCH2CH(C6H5)CO2H
194.19
9, 865
20
1.6332
214–215
Solubility in 100
parts solvent
s alc, chl, eth, alk
s alc, chl, eth, alk
i aq; misc alc
misc alc, bz
s aq; misc alc, eth
v s alc, eth; misc bz
i aq; s alc
0.6 aq; s bz, alc, chl,
eth, HOAc, PE
10 hot aq; s hot alc,
alk, acid
s alc, eth
0.8 alc; 1 eth; 0.3 chl
17 alc; 66 bz; s acet,
chl, eth; 0.015 aq
s hot aq, alc, eth
INTERACTIVE
p154
1-Phenyl-3pyrazolidinone
2-Phenylpyridine
2-Phenyl-4-quinolinecarboxylic acid
Phenyl salicylate
Formula
weight
ROTATED
p151
Formula
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
p158
p159
p160
p161
p162
p163
p164
p165
1.299
p166
p167
(Phenylthio)acetic acid
S-Phenyl thioisobutyrate
1-Phenyl-2-thiourea
Phenyltrichlorosilane
Phenyltriethoxysilane
Phenyltrimethoxysilane
Phenyltrimethylammonium bromide
Phenyltrimethylammonium chloride
Phenyltrimethylammonium iodide
Phenyltrimethylammonium tribromide
Phenyltrimethylsilane
Phenylurea
C6H5SCH2CO2H
(CH3)2CHC("O)SC6H5
168.21
152.22
6, 313
6,4, 1524
1.056
1.546020
64–66
C6H5NHC(S)NH2
C6H5SiCl3
C6H5Si(OC2H5)3
C6H5Si(OCH3)3
152.22
211.55
240.38
198.30
12, 388
16, 911
16, 911
164, 1556
1.3
1.32920
0.996
1.062
1.523020
1.460420
1.468020
[C6H5N(CH3)3]⫹ Br⫺
216.13
12, 158
215 dec
v s aq; s hot alc
[C6H5N(CH3)3]⫹ Cl⫺
171.67
12, 158
237 subl
s aq; v s alc; sl s eth
[C6H5N(CH3)3]⫹ I⫺
263.12
12, 159
227 subl
s aq, alc; sl s acet
[C6H5N(CH3)3]⫹ Br⫺3
375.95
12, 159
114–116
C6H5Si(CH3)3
C6H5NHCONH2
150.30
136.15
161, 525
12, 346
0.873
1.302
⬎110
201
11310mm
233
91
42
99
154
1.490720
145–147
3-Phenylpropyl mercaptan, p144
Phenyl sulfide, d770
Phenyl sulfone, d771
Phenylsulfonic acid, b23
Phenyl sulfoxide, d772
(Phenylthio)acetic acid, t157
0.25 aq; s alc, alk
168–170
238
44
s hot aq, hot alc, eth
Phenyl thiocarbamide, p158
␣-Phenyl-o-toluic acid, b84
Phenyl m-tolyl ether, p76
Phloroglucinol, t318
Phorone, d613
Phthalaldehydic acid, f37
RIGHT
1-Phenylpentane, p55
2-Phenylpropane, i103
3-Phenyl-2-propenoic acid, e279
3-Phenyl-2-propen-1-ol, c282
3-Phenyl-2-propenoyl chloride, c280
3-Phenylpropyl alcohol, p146
Phenyl propyl ketone, b619
12910mm
DEAN 37261 (McGHP)
p156
p157
ROTATED
N
p134
p141
p142
p151
p153
INTERACTIVE
No.
Name
1.300
p169
p170
p171
p172
p173
Phthalic anhydride
Phthalide
Phthalimide
1,2-Phthaloyl
dichloride
Phthalylsulfathioazole
p174
Picric acid
p175
p176
p177
p178
p179
(⫹)-␣-Pinene
(⫺)-␤-Pinene
␣-Pinene oxide
Piperazine
1,4-Piperazinebis(ethanesulfonic
acid)
Piperidine
1-Piperidinecarbonitrile
N-Piperidineethanol
2-Piperidineethanol
1-Piperidinepropionic
acid
Piperidinepropionitrile
2-(2-Piperidineethyl)pyridine
L-Proline
p180
p181
p182
p183
p184
p185
p186
p187
Density,
g/mL
C6H4-1,2-(CO2H)2
166.13
9, 791
1.59320
4
17, 469
17, 310
21, 458
9, 805
1.53
1.16499
4
C6H5-1,2-(COCl)2
148.12
134.13
147.13
203.02
403.44
Merck:
12, 7533
6, 265
2,4,6-(O2N)3C6H2OH
229.11
1.40920
1.76320
4
0.862220
4
0.951
1.452520
1.470520
⫺13
0.873225
25
1.01017
1.480420
0.933
0.985
1.469520
1.526020
85.15
110.16
20, 6
20, 56
129.20
129.20
157.21
20, 25
21, 2
203, 1049
Pimelic ketone, c366
Pinacolone, d572
Pinacolyl alcohol, d571
122–123
⫺62
⫺61
0.859120
4
0.859020
0.964
22, 2
230 rapid
heating
131–134
72–74
234–236
15–16
1.465020
1.478020
1.469020
1.446113
5, 146
5, 154
5, 152
23, 4
Merck:
12, 7633
115.13
1.568420
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
295
290
151
280–282
⬎110
272–277
136.24
136.24
152.24
86.14
302.37
138.21
190.29
Refractive
index
108–110
⬎300
38–40
105–110
Solubility in 100
parts solvent
0.6 aq; ;10 alc; 0.5 eth;
v sl s chl
0.6 aq(dec); s alc
s alc
v s alk; v sl s bz, PE
dec by aq, alc; s eth
s alk; sl s alc; i chl
explodes
⬎300
156
166
10350mm
145–146
35
38
65
109
106
10210mm
4
97
misc aq; s alc, bz, chl
199–202
234
1080.5mm
68
102
misc aq; s alc
v s aq, alc, eth
11116mm
15017mm
102
⬎110
228 dec
Pivalic acid, d679
Pivalic anhydride, d680
Pivaloyl chloride, d681
1.3 aq; 8.2 alc; 10 bz;
2.9 chl; 1.6 eth
misc alc, eth
v s aq; 50 alc; i eth
INTERACTIVE
m-Phthalic acid, b17
p-Phthalic acid, b18
Phthalonitrile, d282
Beilstein
reference
ROTATED
1,2-Phthalic acid
Formula
weight
LEFT
p168
Formula
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
1.301
p169
p171
p178
Pivaloyloxymethyl chloride, c172
POPOP, b218
PPO, d779
Prehnitene, t97
Propadiene, a72
1-Propanal, p211
p173
p179
p180
p175
p181
p182
p176
p183
RIGHT
p177
p170
DEAN 37261 (McGHP)
Pipecolines, m381 thru m383
1-Piperazinoethanol, h129
1-Piperidinecarboxyaldehyde, f40
Piperonal, m250
Piperonyl butoxide, m252
cis-Piperylene, p16
Pivaldehyde, d677
Picolinaldehyde, p261
Picolines, m409 thru m411
Picolinic acids, p265, p267
Picolinonitrile, c328
Picolylamines, a218 thru a220
Picramide, t402
Pimelic acid, h7
ROTATED
p185
p186
p187
INTERACTIVE
p184
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
1.302
p188
Propane
CH3CH2CH3
44.10
1, 103
0.584⫺42
1.340⫺42
⫺188
⫺42.1
⫺104
p189
p190
p191
1,2-Propanediamine
1,3-Propanediamine
1,2-Propanediol
CH3CH(NH2)CH2NH2
H2NCH2CH2CH2NH2
CH3CH(OH)CH2OH
74.13
74.13
76.10
4, 257
4, 261
1, 472
0.87815
0.88425
4
1.036420
4
1.446020
1.457520
1.433120
⫺12
⫺60
119–120
140
188
33
48
107
p192
1,3-Propanediol
HOCH2CH2CH2OH
76.10
1, 475
1.053820
1.439620
⫺27
214
79
p193
1,3-Propanediol bis(4-aminobenzoate)
1,2-Propanediol
dibenzoate
1,3-Propanedithiol
1-Propanesulfonyl
chloride
1,3-Propane sultone
1-Propanethiol
2-Propanethiol
1,2,3-Propanetriol
tris(acetate)
1-Propanol
2-Propanol
2-Propenal
Propene
CH2(CH2CO2CC6H4NH2)2
314.34
143, 1034
1.140
C6H5CO2CH2CH(CH3)O2CC6H5
HSCH2CH2CH2SH
CH3CH2CH2SO2Cl
284.31
9, 129
1.160
1.545020
⫺3
23212mm
⬎110
108.23
142.60
1, 476
4, 8
1.077220
4
1.286415
4
1.540520
1.454220
⫺79
172.9
668mm
58
80
122.14
76.16
76.16
218.21
193, 4
1, 359
1, 367
2, 147
1.392
0.83625
4
0.80925
4
1.158020
1.438020
1.425520
1.430220
31–33
⫺113
⫺131
⫺78
18030mm
67–68
52.6
259
⬎110
⫺20
⫺34
138
60.10
60.10
56.07
42.08
1, 350
1, 360
1, 725
1, 196
0.803720
0.785520
4
0.84120
4
⫺48
0.610 4
1.384020
1.377220
1.401720
1.3567⫺40
⫺127
⫺89.5
⫺88
⫺185.2
97.2
82.4
52.6
⫺47.7
23
12
⫺18
⫺108
2-Propene-1-thiol
trans-1,2,3-Propenetricarboxylic acid
1-Propen-2-yl acetate
H2C"CHCH2SH
74.15
174.11
1, 440
2, 849
0.92523
4
1.476520
67–68
21
97
18
p194
p195
p196
p205
p206
H2C"C(O2CCH3)CH3
100.12
190 dec
0.909
1.400020
misc alc, bz, eth, chl
dec hot aq, hot alc
s alc, eth
misc alc, eth; sl s aq
7.2 aq; misc alc, bz,
chl, eth
misc aq, alc, eth
misc aq, alc, chl, eth
21 aq; s alc, eth
vols in 100 vols
solvent: 45 aq; 1200
alc; 500 acet
misc alc, eth
50 aq25; 50 88% alc12;
sl s eth
INTERACTIVE
p207
CH3CH2CH2OH
(CH3)2CHOH
H2C"CHCHO
H2C"CHCH3
124–127
ROTATED
p201
p202
p203
p204
CH3CH2CH2SH
CH3CH(SH)CH3
H3CCO2CH(CH2O2CCH3)3
volumes per 100 vols
solvent: 6.5 aq; 790
alc; 926 eth; 1300
chl; 1450 bz
misc aq, bz; s alc, eth
misc alc, eth; s aq
misc aq, acet, chl; s
alc, eth
misc aq, alc
LEFT
p197
p198
p199
p200
Solubility in 100
parts solvent
p209
p210
p211
p212
p213
p214
p215
p216
p217
p218
p219
1.303
p220
p221
p222
p223
4-(1-Propenyloxymethyl)-1,3-dioxolan-2-one
2-Propenylphenol
␤-Propiolactone
Propionaldehyde
Propionamide
Propionic acid
Propionic anhydride
Propionitrile
Propionyl chloride
Propiophenone
2-Propoxyethanol
2-(2-Propoxyethyl)pyridine
1-Propoxy-2-propanol
Propoxytrimethylsilane
Propyl acetate
Propylamine
158.16
1.100
1.461020
134.18
72.06
61, 279
171, 130
1.044
1.146020
4
1.578020
1.413120
CH3CH2CHO
CH3CH2CONH2
CH3CH2CO2H
[CH3CH2C("O)]2O
CH3CH2CN
CH3CH2COCl
C6H5COCH2CH3
CH3CH2CH2OCH2CH2OH
C5H4NCH2CH2OCH2CH2CH3
58.08
73.10
74.09
130.14
55.08
92.53
134.18
104.15
165.24
1, 629
2, 243
2, 234
2, 242
2, 245
2, 243
72, 231
1, 468
0.807120
4
0.959780
4
0.993420
4
1.011020
0.781820
4
1.06520
4
1.010520
4
0.913
0.954
1.363620
1.4160110
1.380920
1.403720
1.365820
1.405120
1.525820
1.413020
1.488020
C5H4NCH2CH2OCH2CH(OH)CH3
CH3CH2CH2OSi(CH3)3
CH3CH2CH2O2CCH3
CH3CH2CH2NH2
118.18
132.28
102.13
59.11
12, 536
4,4, 3994
2, 129
4, 136
0.885
0.76820
4
0.8878
0.717320
1.411020
1.384020
1.384420
1.387220
CH3CH"CHC6H4OH
⬎110
⫺33.4
230–231
162
90
70
⫺81
79
⫺20.5
⫺45
⫺92.8
⫺94
21
⫺75
48
222.2
141.1
170
97.2
80
218.0
150–153
⫺30
⫺93
⫺83
140–160
100735mm
101.6
42.2
52
63
2
11
87
48
95
48
⫺2
13
⫺37
2-Propenyl acetate, a74
2-Propenylamine, a74
Propenylanisole, m107
N-2-Propenyl-2-propen-1-amine, d30
(2-Propenyl)thiourea, a97
Propiolic acid, p248
Propyl alcohol, p201
37 aq(hyd); misc alc
(reacts); bz, eth,
acet
30 aq; misc alc, eth
v s aq, alc, chl, eth
misc aq; s alc, chl, eth
dec aq; s alc, chl, eth
10 aq; misc alc, eth
dec by aq, alc
misc bz, eth, abs alc
2.3 aq; misc alc, eth
misc aq, alc, eth
RIGHT
Propargyl alcohol, p249
Propargyl chloride, c241
Propenamide, a61
2-Propen-1-amine, a76
2-Propenenitrile, a63
3-Propenoic acid, a62
2-Propen-1-ol, a75
1,3-Propanedicarboxylic acid, g14
Propanedioic acid, m3
1,2-Propanediol cyclic carbonate, p230
Propanenitrile, p215
1,2,3-Propanetriol, g19
Propanoic acid, p213
2-Propanone, a26
251–252
DEAN 37261 (McGHP)
p208
ROTATED
p197
p206
p208
p210
INTERACTIVE
No.
p224
Name
1.304
Melting
point,⬚C
0.900
1.441520
CH3CH2CH2C6H5
C6H5CO2CH2CH2CH3
CH3CH2CH2CO2CH2CH2CH3
ClCO2CH2CH2CH3
CH3CH2CH2C6H11
5, 390
9, 112
2, 271
3, 11
52, 23
193, 1564
20, 3
0.862120
4
1.03220
0.87915
4
1.090
0.792920
4
1.204120
0.801725
1.491220
1.501020
1.400020
1.403420
1.437020
1.421020
1.408425
⫺99.2
⫺51.6
⫺95
CH3CH 9 CH2
120.20
164.20
130.19
122.55
126.24
102.09
57.09
1,2-Propylene oxide
NH
CH3CH 9 CH2
58.08
17, 6
0.828720
1.366020
⫺112
Propylene sulfide
O
CH3CH 9 CH2
Propyl formate
Propyl 4-hydroxybenzoate
Propyl isocyanate
Propyl lactate
Propyl nitrate
Flash
point,⬚C
182746mm
78
159.2
230
143
105–106
156.7
242
66.0
47
98
38
28
35
135
⫺15
s alc, eth
i aq; s alc, eth
sl s aq; misc alc, eth
misc bz, chl, eth
s bz, eth
v s aq, alc, bz, eth
misc aq, alc, PE
34
⫺35
(CC)
41 aq; misc alc, eth
72–75
10
80.9
⫺3
83–84
8640mm
110.1
0
74.15
172, 15
0.946
1.476020
S
CH3CH2CH2O2CH
HOC6H4CO2CH2CH2CH3
88.10
180.20
2, 21
10, 160
0.905820
1.377920
CH3CH2CH2NCO
CH3CH(OH)CO2CH2CH2CH3
CH3CH2CH2ONO2
85.11
132.16
105.09
41, 366
3, 265
1, 355
0.908
0.99620
1.053820
4
1.394020
1.416725
1.397620
(CH3CH2CH2)2CHCO2H
CH3CH2CH2C6H4OH
CH3CH2CH2P(O)Cl2
144.21
136.19
160.97
2, 350
6, 499
4, 596
0.921
1.01520
1.290
1.425020
1.527920
1.464320
220
224–226
9050mm
23 (may
explode
on
heating)
111
93
⬎110
CH3CH2CH2SiCl3
177.53
141.22
116.16
4, 630
1.185120
4
0.936
0.88320
1.42920
1.460020
1.393520
123–124
561mm
122.5
2
75
19
CH3CH2CO2CH2CH2CH3
2, 240
⫺92.9
95–98
⫺100
⫺76
Solubility in 100
parts solvent
2 aq; misc alc, eth
0.05 aq; v s alc, eth
s aq, alc, eth
s alc, eth
s alc, eth
0.5 aq; 103 alc; 83 eth
INTERACTIVE
2-Propylpentanoic acid
2-Propylphenol
Propylphosphonic
dichloride
Propyltrichlorosilane
1-Propyl-4-piperidone
Propyl propionate
⫺94.9
⫺48.8
Boiling
point,⬚C
ROTATED
p242
p243
p244
Refractive
index
LEFT
p239
p240
p241
Density,
g/mL
4, 282
p232
p236
p237
p238
Beilstein
reference
103.17
p225
p226
p227
p228
p229
p230
p231
p234
p235
Formula
weight
C3H7NHCH2CH2OH
2-(Propylamino)ethanol
Propylbenzene
Propyl benzoate
Propyl butyrate
Propyl chloroformate
Propylcyclohexane
Propylene carbonate
Propyleneimine
p233
Formula
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
(HO)3C6H2CO2CH2CH2CH3
212.20
CH3C#CH
C6H5SO3CH2C#CH
40.06
196.23
Merck:
12, 8044
1, 246
113, 37
HC#CCO2H
HC#CH2OH
70.05
56.06
152.24
80.09
105.10
124.10
2, 477
1, 454
7, 87
23, 91
253, 777
25, 125
p254
p255
p256
Propyl 3,4,5-trihydroxybenzoate
Propyne
2-Propynyl benzenesulfonate
2-Propynoic acid
2-Propyn-1-ol
(⫹)-Pulegone
Pyrazine
Pyrazinecarbonitrile
Pyrazinecarboxylic
acid
Pyrazole
Pyrene
Pyridazine
68.08
202.26
80.09
23, 39
5, 693
23, 89
p257
p258
p259
Pyridine
Pyridine-d5
2-Pyridinealdoxime
C5H5N
C5D5N
(C5H4N)-2-CH"NOH
79.10
84.14
122.13
20, 181
203, 2305
211, 288
p246
p247
p248
p249
p250
p251
p252
p253
150
0.691⫺420
1.243
1.3725⫺20
1.525020
⫺102.8
⫺30
⫺23.2
1422mm
100
1.13820
4
0.947820
0.934615
4
1.03161
4
1.174
1.432020
1.432020
1.487020
1.495361
1.534020
9
⫺51.8
102200mm
114
224
115
876mm
58
36
85
55
96
55
v s alc; 3000 mL eth
s aq, alc, eth
misc aq, alc, bz, chl
misc alc, chl, eth
v s aq, alc, eth
225 dec
1.4203
1.27123
1.103525
4
1.523023
0.982725
4
1.050
1.506725
1.509220
68
151
⫺8
187
404
208
85
⫺41.6
115.2
114.4
20
20
sl s hot aq; 0.008 abs
alc; i bz, chl, eth
s aq, alc, bz, eth
s org solvents
misc aq, bz; v s alc,
eth
misc aq, alc, eth
1.305
110–112
Propylenediamine, p189
Propylene glycol, p191
Propylene glycol dimethyl ether, d518
Propylene glycol monomethyl ether, m105
Propylene glycol monophenyl ether, p73
Propylene oxide, e15
Propyl gallate, p245
Propyl iodide, i48
Propyl mercaptan, p198
6-Propyl-2-thiouracil, h140
Pseudocumene, t358
Pyrene, b52
3,6-Pyridazinediol, d447
RIGHT
Propyl bromide, b400
Propyl butanoate, p227
Propyl cyanide, b468a
Propyl chloride, c225
Propylene, p204
sec-Propylene chlorohydrin, c230
Propylene dibromide, d120
0.35 aq; 1 alc; 83 eth
DEAN 37261 (McGHP)
p245
ROTATED
p230
p243
p250
p251
p252
p253
p254
p255
p256
INTERACTIVE
4-Pyridinealdoxime
2-Pyridinecarboxaldehyde
3-Pyridinecarboxaldehyde
4-Pyridinecarboxaldehyde
3-Pyridinecarboxamide
2-Pyridinecarboxylic
acid
3-Pyridinecarboxylic
acid
4-Pyridinecarboxylic
acid
2,3-Pyridinedicarboxylic acid
2,5-Pyridinedicarboxylic acid
2,6-Pyridinedicarboxylic acid
Pyridine-N-oxide
Pyridinium p-toluenesulfonate
2-Pyridylcarbinol
3-Pyridylcarbinol
3-(3-Pyridyl)-1propanol
3-(4-Pyridyl)-1propanol
Pyrimidine
2,4(1H,3H)Pyrimidinedione
Pyrrole
Pyrrolidine
p262
p263
p264
p265
p266
p267
1.306
p268
p269
p270
p271
p272
p273
p274
p275
p276
p277
p278
p279
p280
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
(C5H4N)-4-CH"NOH
(C5H4N)-2-CHO
122.13
107.11
211, 287
1.126
1.537020
181
54
(C5H4N)-3-CHO
107.11
211, 288
1.135
1.549320
9715mm
60
(C5H4N)-4-CHO
107.11
21, 287
1.122
1.544020
7812mm
54
(C5H4N)-3-CONH2
(C5H4N)-2-CO2H
122.13
123.11
22, 40
22, 33
1.400
1.466
(C5H4N)-3-CO2H
123.11
22, 38
1.473
(C5H4N)-4-CO2H
123.11
(C5H4N)-2,3-(CO2H)2
Solubility in 100
parts solvent
130–133
s aq, eth
130–133
134–136
sublimes
100 aq; 66 alc
s aq, alc, bz; v s
HOAc
1.4 aq; s alk; v s hot
aq, hot alc
0.52 aq; i alc, bz, eth
236.6
sublimes
22, 45
319
26015mm
167.12
22, 150
0.56 aq; s alk
(C5H4N)-2,5-(CO2H)2
167.12
22, 153
188–190
dec
256 dec
(C5H4N)-2,6-(CO2H)2
167.12
22, 154
sl s aq; v sl s alc
C5H5NO
C5H5NH⫹ ⫺O3SC6H4CH3
95.10
251.31
202, 131
202, 129
248–250
dec
61–65
117–119
(C5H4N)-2-CH2OH
(C5H4N)-3-CH2OH
(C5H4N)-3-CH2CH2CH2OH
109.13
109.13
137.18
211, 203
21, 50
213, 549
1.131
1.124
1.063
(C5H4N)-4-CH2CH2CH2OH
137.18
214, 550
1.061
80.09
112.09
23, 89
24, 312
1.016
67.09
71.12
20, 159
20, 4
0.969120
4
0.858620
s hot acid
270
11316mm
15428mm
1333mm
⬎110
⬎110
⬎110
35–39
289
⬎110
1.504020
22
335
124
31
misc aq; s alc, eth
0.3 aq; s alk
1.508520
1.443120
⫺23.4
⫺58
130
86.5
39
3
4.5 aq; v s alc, eth
misc aq; s alc, chl, eth
1.542020
1.544520
1.530020
v s aq, alc, eth
v s aq, eth
INTERACTIVE
p260
p261
Formula
ROTATED
Name
LEFT
No.
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
p282
p283
p284
p285
p286
1-Pyrrolidinebutyronitrile
1-Pyrrolidinecarbodithioic acid, ammonium salt
1-Pyrrolidinecarbonitrile
1-Pyrrolidino-1cyclohexene
2-Pyrrolidinone
138.21
3-(N-Pyrrolidino)1,2-propanediol
145.20
0.926
1.460520
164.29
153–155
0.954
1.469020
771.8mm
107
151.25
0.940
1.522520
11515mm
39
1.11625
4
1.480625
25
251
129
46–48
15830mm
⬎110
21, 236
201, 4
1.307
Pyrocatechol, d428
Pyrogallol, t317
Pyromellitic acid, b27
Pyromellitic dianhydride, b28
Pyromucic aldehyde, f44
Pyrrolidinedithiocarbamate, p282
p278
p279
p280
misc aq, alc, bz, chl,
eth, EtOAc
1-Pyrrolidineethanol, h133
4-(N-Pyrrolidino)butyronitrile, p281
Pyruvic acid, o65
Pyruvic aldehyde, o64
Pyruvic aldehyde dimethyl acetal, d520
p281
p282
RIGHT
p277
99
96.13
85.11
2,3-Pyridinediol, d448
2-Pyridineethanol, h132
3-Pyridinol N-oxide, h183
Pyridinols, h179 thru h181
2(1H)-Pyridone, h179
2-(2-Pyridyl)pyridine, d790
11518mm
DEAN 37261 (McGHP)
p281
ROTATED
p283
p284
p285
p286
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
q1
q2
q3
q4
q5
r1
r2
1.308
r3
Name
Quinhydrone
Quinine
Quinoline
Quinoxaline
2-Quinoxalinol
D-Raffinose pentahydrate
Resorcinol
r7
r4
r5
Formula
weight
Beilstein
reference
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
7, 617
23, 511
20, 339
23, 176
24, 147
31, 462
1.40120
4
C6H4-1,3-(OH)2
110.11
6, 796
1.272
C6H4-1,3-(O2CCH3)2
194.19
6, 816
1.178
1.503020
14612mm
⬎110
CH3CO2C6H4-3-(OH)
152.15
6, 816
1.223
1.537020
ca 283
⬎110
C6H5CO2C6H4-3-(OH)
214.20
171–173
173–175
⫺15
29–32
271–272
80–82
237
220–223
dec 118
14 aq; 10 MeOH
110–112
280
111 aq; 111 alc; v s
eth
101
98
s hot aq, alc, eth
125 alc; 1.2 bz; 83 chl
0.6 aq; misc alc, eth
v s aq, alc, bz, eth
i aq; misc alc, bz, chl,
acet; s alk OH’s
133.19
27, 242
r8
Riboflavin
376.37
Merck:
12, 8367
r9
s1
D-Ribose
150.13
183.19
1, 859
27, 168
0.868
0.828
210–211
dec
167–170
may explode
on rapid
heating
dec 278–
282
88–92
228–230
v s aq, alc
v s hot aq, alc, eth
v s alk(dec); i acet, bz,
eth; sl s pentyl acetate, cyclohexanol
s aq; sl s alc
0.34 aq; 3 alc; 8 acet
ROTATED
Rhodanine
INTERACTIVE
p-Quinone, b58
1.09520
4
1.33448
4
1.625
1.627320
1.623148
Solubility in 100
parts solvent
133–135
19, 345
Quinaldine, m420
Refractive
index
218.20
324.44
129.16
130.15
146.15
594.52
479.02
Saccharin
Density,
g/mL
LEFT
r6
Resorcinol 1,3diacetate
Resorcinol
monoacetate
Resorcinol
monobenzoate
Rhodamine B
Formula
RIGHT
ROTATED
INTERACTIVE
q1
r1
q2
r9
r6
q3
s1
r7
q4
q5
r8
DEAN 37261 (McGHP)
1.309
No.
s2
s3
s4
s5
Name
Safrole
Semicarbazide
hydrochloride
L-Serine
D-Sorbitol
Formula
H2NNHCONH2 · HCl
HOCH2CH(NH2)CO2H
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
1.09520
1.537020
1.310
Melting
point,⬚C
Boiling
point,⬚C
232–234
350
218
55 aq; v sl s alc
s bz, chl, eth, PE
200
v s eth, acet, PE
v s bz, eth
0.66 alc; 20 chl; 0.55
bz; 0.15 mg aq
s alc, acet, eth, CS2
162.19
111.53
19, 39
3, 98
105.09
182.17
4, 505
1, 533
1.472⫺5
180.16
422.83
1, 927
11, 72
1.6515
0.811515
1.453015
11.2
175–177
dec
222 dec
98–100 if
hydrated;
111 anhyd
163–165
⫺38
470.73
11, 130
0.858420
4
1.496520
⫺75
28525mm
180.25
334.42
5, 630
272, 723
0.970
1.3620
4
122–124
284–286
307
2705mm
Flash
point,⬚C
97
s9
s10
trans-Stilbene
(⫺)-Strychnine
s11
Styrene
C6H5CH"CH2
104.15
5, 474
0.906020
1.546320
⫺31
145
31
s12
Styrene oxide
H2C 9 CHC6H5
120.15
17, 49
1.054
1.533820
⫺37
194
79
s13
s14
s15
Succinamic acid
Succinamide
Succinic acid
O
H2NCOCH2CH2CO2H
H2NCOCH2CH2CONH2
HO2CCH2CH2CO2H
117.10
116.12
118.09
2, 614
2, 614
2, 601
s16
s17
s18
s19
s20
s21
Succinic anhydride
Succinimide
Succinonitrile
Succinyl chloride
Sucrose
Sulfadiazine
100.07
99.09
80.09
154.98
342.30
250.28
s22
Sulfamethazine
17, 407
21, 369
2, 615
2, 613
31, 424
Merck:
12, 9071
Merck:
12, 9083
NCCH2CH2CN
ClCOCH2CH2COCl
278.34
153–156
265 dec
188
1.552
1.41
0.986460
1.39515
4
1.58725
4
60
1.4173
1.47315
119.6
123–125
54.5
16–17
185–187
252–256
198–201
235 dec
261
285–290
266
190
132
76
s aq; sl s alc; i eth
0.45 aq; i alc, eth
7.7 aq; 5.4 alc; 2.8
acet; 0.88 eth; i bz
s alc, chl; v sl s eth
33 aq; 4 alc; i eth
see b456
dec by aq, alc; s bz
200 aq; 0.59 alc
sl s aq, alc, acet; v s dil
mineral acids, alk
0.15 aq; s alk
INTERACTIVE
Squalene
ROTATED
s8
LEFT
L-Sorbose
[(CH3)2CH(CH3)2CH(CH3)(CH2)3CH(CH3)CH2CH2-]2
CH3[C(CH3)"CHCH2CH2]5C(CH3)"C(CH3)2
C6H5CH"CHC6H5
v s alc; misc chl, eth
v s aq, alc; i eth
s aq; v sl s alc, eth
83 aq; s hot alc, acet
s6
s7
Squalane
Solubility in 100
parts solvent
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Sulfamic acid
HSO3NH2
97.09
s24
Sulfanilamide
H2NC6H4SO2NH2
172.21
Merck:
12, 9090
14, 698
2.15
205 dec
s25
Sulfanic acid
4-(H2N)-C6H4SO3H
173.19
14, 695
d 288
s26
s27
Sulfoacetic acid
2-Sulfobenzoic acid
cyclic anhydride
HCO2CH2SO3H
140.11
184.17
4, 21
19, 110
84–86
164–166
Stryene dibromide, d98
Stryene glycol, p108
Stryene oxide, e9
Suberic acid, o25
Suberonitrile, d285
Salicylaldehyde, h94
Solketal, d599
Stearamide, o2
Stearic acid, o5
Stearyl bromide, b385
15 aq; sl s alc, acet; s
bases
0.76 aq; 2.7 alc; 20
acet; s acid, alk
1.45 aq; sl s hot
MeOH
s aq, alc; i eth, chl
s bz, chl, eth; i aq
245 dec
18618mm
Succinic acid monoamide, s13
Succinonitrile, b456
Sulfanilic acid, a117
Sulfolane, t107
DEAN 37261 (McGHP)
s23
1.311
s5
s6
s10
s16
RIGHT
s2
s17
ROTATED
s20
s21
s22
s27
INTERACTIVE
No.
s28
Name
Formula
Formula
weight
Beilstein
reference
1.312
6, 865
303–306
(CH3O2CC6H4)2SO2
334.35
102, 109
195–196
(HOC6H4)2SO2
HO3SC6H3(OH)CO2H
250.27
254.21
150.09
6, 861
11, 411
3, 520
1.366315
1.759820
4
245–247
120 anhyd
172–174
150.09
3, 481
1.759820
4
168–170
1.66620
4 ;
1.737
also
1.69720
4
140; also
159–160
meso-Tartaric acid
monohydrate
HO2CCH(OH)CH(OH)CO2H · H2O
168.11
3, 528
t4
DL-Tartaric
HO2CCH(OH)CH(OH)CO2H · H2O
168.11
3, 522
534.37
134.13
25, 252
7, 675
C6H2Br4
230.31
230.31
230.31
136.24
136.24
154.25
154.25
393.72
5, 695
52, 611
5, 695
5, 126
5, 128
6, 55
6, 57
5, 214
CH3C6Br4(OH)
423.75
6, 362
Br2CHCHBr2
345.67
1, 94
t7
t8
t9
t10
t11
t12
t13
t14
t15
t16
C6H4-1,4-(CHO)2
C6H5 9C6H4 9C6H5
C6H5 9C6H4 9C6H5
C6H5 9C6H4 9C6H5
Solubility in 100
parts solvent
s alc, eth, acet; i aq
v s aq, alc; s eth
139 aq20; 59 MeOH;
33 EtOH; s glyc;
0.4 eth
139 aq20; 59 MeOH;
33 EtOH; s glyc;
0.4 eth
125 aq20
20.6 aq20; 5 alc25; 1 eth
210–212
v s aq
1.195
1.16
1.213
0.837520
4
0.85315
4
0.933820
4
0.933720
1.477520
1.475416
1.482020
1.481320
115–116
245–248
87
56.2
210
363
332
376
174
183
906mm
220
36.4
40.5
180–182
⬎110
⬎110
46
51
79
90
205–208
2.965520
1.635820
0
misc alc, eth
v s alc, eth
s alc, eth, alk
243.5
none
misc alc, chl, eth,
HOAc
INTERACTIVE
t3
acid
Flash
point,⬚C
ROTATED
L-(⫹)-Tartaric
Boiling
point,⬚C
LEFT
t2
t5
t6
Melting
point,⬚C
565.88
s30
s31
t1
acid
monohydrate
Tartrazine
Terephthaldicarboxaldehyde
m-Terphenyl
o-Terphenyl
p-Terphenyl
␣-Terpinene
␥-Terpinene
Terpinen-4-ol
␣-Terpineol
1,2,4,5-Tetrabromobenzene
3,4,5,6-Tetrabromocresol
1,1,2,2,-Tetrabromoethane
Refractive
index
[2,6-(Br)2 9C6H2OH]2SO2
4,4⬘-Sulfonylbis(2,6dibromophenol)
4,4⬘-Sulfonylbis(methyl
benzoate)
4,4⬘-Sulfonyldiphenol
5-Sulfosalicylic acid
D-(⫺)-Tartaric acid
s29
Density,
g/mL
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Tetrabromophthalic
anhydride
␣,␣,␣⬘,␣⬘-Tetrabromoo-xylene
␣,␣,␣⬘,␣⬘-Tetrabromom-xylene
␣,␣,␣⬘,␣⬘-Tetrabromop-xylene
Tetrabutylammonium
bromide
Tetrabutylammonium
chloride
Tetrabutylammonium
hydrogen sulfate
Tetrabutylammonium
iodide
Tetrabutylammonium
tetrafluoroborate
Tetrabutylammonium
tribromide
t18
t19
t20
t21
t22
t23
t24
t25
1.313
t26
463.72
17, 485
274–276
sl s bz; i aq, alc
C6H4-1,2-(CHBr2)2
421.77
5, 367
114–116
v s chl
C6H4-1,3-(CHBr2)2
421.77
5, 375
105–108
C6H4-1,4-(CHBr2)2
421.77
5, 386
254–256
(C4H9)4N⫹ Br⫺
322.38
42, 634
102–104
(C4H9)4N⫹ Cl⫺
277.92
43, 292
73–75
(C4H9)4N⫹ HSO⫺4
339.54
(C4H9)4N⫹ I⫺
369.38
4, 157
145–147
(C4H9)4N⫹ BF⫺4
329.28
43, 293
160–162
(C4H9)4N⫹ Br⫺3
482.20
44, 557
74–76
Sulfonyldianiline, d47, d48
Sylvan, m259
Sylvic acid, a1
2,4,5-T, t246
DEAN 37261 (McGHP)
t17
171–173
Taurine, a160
Terephthalaldehyde, b14
Terephthaldicarboxaldehyde, b14
Terephthalic acid, b18
sl s aq; s alc, eth
Terephthaloyl chloride, b16
Tetrabromomethane, c13
Tetrabutoxysilane, t28
RIGHT
ROTATED
t1
t2
t5
t10
t11
t12
t13
t17
INTERACTIVE
No.
t27
t28
t29
t30
t31
t32
t33
1.314
t34
t35
t36
t37
t40
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
0.820
1.451020
832mm
57
0.89920
4
1.413120
275
78
14510mm
182745mm
107
none
v s acet, chl
46–47
254
⬎110
v s eth; sl s alc
139–142
240–246
⬎110
s bz, chl, eth
{-(CH2)3N[(CH2)3]2}2
340.64
Si[O(CH2)3CH3]4
320.55
[CH3(CH2)3]4PBr
339.35
(C4H9)4Sn
Cl2CHC("O)CHCl2
347.15
195.86
1, 656
C6H2Cl4
215.89
5, 204
C6H2Cl4
215.89
5, 205
C6Cl4-1,2-("O)2
245.88
7, 602
127–129
C6Cl4-1,4-("O)2
245.88
7, 636
290 dec
Cl2CFCFCl2
203.83
ClCH2CCl3
167.85
Cl2CHCHCl2
Cl2C"CCl2
HC6Cl4NO2
CH3(CH2)22CH3
CF3(CF2)4CF3
CH3(CH2)12CH3
CH3(CH2)12CO2H
CH3(CH2)13OH
CH3(CH2)12COCl
12, 398
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
100–103
1.057
1.62415
4
1.474220
1.49718
1.85822
⫺97
s eth; sl s chl; i aq
1.644725
1.413025
26.0
92.8
1, 86
1.540620
1.482120
⫺70.2
130.5
47
167.85
1, 86
1.586625
4
1.491025
⫺44
147
62
165.83
260.89
1, 187
5, 247
1.623020
4
1.74425
4
1.505720
⫺22
98–101
121
304
45
285.90
17, 484
254–258
371
338.66
338.05
198.40
228.38
214.39
246.82
1, 175
13, 388
1, 171
2, 365
1, 428
2, 368
51
⫺4
5.5
54
39.5
⫺1
391
58–60
253.6
250100mm
289
16815mm
0.778651
1.669
0.762720
4
0.852570
4
0.815150
0.908
1.428370
1.251520
1.429020
1.427370
1.435850
1.449020
0.012 aq
0.3 aq; misc alc, chl,
eth, PE
misc alc, chl, eth
s alc, bz, chl
dec hot aq; sl s eth
⬎110
none
99
⬎110
⬎110
9.4 chl; s eth
v s alc, eth
v s bz, chl, eth; s alc
s eth; sl s alc
dec aq, alc; s eth
INTERACTIVE
t41
t42
t43
t44
t45
t46
Formula
weight
ROTATED
t38
t39
N,N,N⬘,N⬘-Tetrabutyl1,6-hexanediamine
Tetrabutyl orthosilicate
Tetrabutyl phosphonium bromide
Tetrabutyltin
1,1,3,3,-Tetrachloroacetone
1,2,3,4-Tetrachlorobenzene
1,2,4,5-Tetrachlorobenzene
Tetrachloro-1,2benzoquinone
Tetrachloro-1,4-benzoquinone
Tetrachloro-1,2difluoroethane
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
2,3,5,6-Tetrachloronitrobenzene
Tetrachlorophthalic
anhydride
Tetracosane
Tetradecafluorohexane
Tetradecane
Tetradecanoic acid
1-Tetradecanol
Tetradecanoyl chloride
Formula
LEFT
t36a
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
t50
t51
t52
t53
t54
t55
t56
t57
1.315
t58
t59
t60
t61
1-Tetradecene
Tetraethoxysilane
Tetraethylammonium
bromide
Tetraethylammonium
chloride
Tetra(ethylene glycol)
Tetra(ethylene glycol)
diacrylate
Tetra(ethylene glycol)
diethyl ether
Tetra(ethylene glycol)
dimethacrylate
Tetra(ethylene glycol)
dimethyl ether
Tetraethylenepentamine
N,N,N⬘,N⬘-Tetraethylethylenediamine
Tetraethylgermanium
Tetraethyllead
Tetraethylsilane
N,N,N⬘,N⬘-Tetraethylsulfamide
196.38
208.33
210.16
1, 226
1, 334
4, 104
0.77515
4
0.93420
4
1.39720
4
1.436020
1.38320
(CH3CH2)4N⫹ Cl⫺
165.71
4, 104
1.080121
4
(HOCH2CH2OCH2CH2)2O
(H2C"CHCO2CH2CH2OCH2CH2)2O
C2H5(OCH2CH2)4OC2H5
194.23
302.33
1, 468
1.12520
20
1.110
1.457720
1.465020
250.34
13, 2107
0.970
[H2C"C(CH3)CO2CH2CH2OCH2CH2]2O
CH3(OCH2CH2)4OCH3
330.37
24, 1531
222.28
(H2NCH2CH2NHCH2CH2)2NH
⫺12.9
⫺77
285 dec
251.2
168
115
46
v s alc, eth
dec aq; s alc
v s aq, alc, acet, chl
141 aq; s alc; 8.2 chl
⫺6
328
182
⬎110
misc aq, alc, bz, eth
1.432420
15911mm
⬎110
s aq
1.080
1.463020
220
⬎110
13, 2107
1.008720
4
1.433020
⫺30
275–276
140
s aq
189.31
4,3, 543
0.99920
20
1.505520
⫺40
340
185
misc aq, alc, eth
(C2H5)2NCH2CH2N(C2H5)2
172.32
4, 251
0.808
1.434320
189–192
58
(C2H5)4Ge
(C2H5)4Pb
(C2H5)4Si
(C2H5)2NSO2N(C2H5)2
188.84
323.45
144.34
208.33
4, 631
4, 639
4, 625
4, 129
0.998
1.65320
4
0.765820
1.030
1.442020
1.519020
1.426820
1.448020
165.5
8515mm
154.7
249–251
35
72
26
⬎110
␣,␣,␣,4-Tetrachlorotoluene, c59
Tetradecyl alcohol, t45
⫺90
⫺136
⫺82
Tetraethylmethane, d386a
Tetraethyl orthosilicate, t48
s alc, eth; i aq
s bz; misc eth
i aq
RIGHT
Tetracene, b7
Tetrachloromethane, c14
␣,␣,␣,2-Tetrachlorotoluene, c58
CH3(CH2)11CH"CH2
(CH3CH2O)4Si
(CH3CH2)4N⫹ Br⫺
DEAN 37261 (McGHP)
t47
t48
t49
ROTATED
t40
INTERACTIVE
No.
t62
t63
t64
t65
t66
t67
t68
1.316
t69
t70
t71
t72
t74
t76
t77
t78
Beilstein
reference
Density,
g/mL
Refractive
index
[(C2H5)2NC("S)S⫺]2
296.54
4, 122
1.30
(C2H5)4Sn
FCH2CF3
234.94
102.03
4, 632
1,4, 123
1.19920
1.473020
F2C"CF2
HCF2CF2CH2OH
100.02
132.06
13, 638
14, 1438
1.151⫺40
1.485320
4
1.319720
C6H9CHO
110.16
71, 48
0.940
1.474520
171.24
20, 416
72.11
132.16
17, 10
0.889220
4
1.154225
4
102.13
172, 106
101.15
Boiling
point,⬚C
Flash
point,⬚C
71–72
⫺112
⫺26.5
181
53
⫺142.5
⫺15
⫺76
109–110
43
163–164
57
Solubility in 100
parts solvent
3.8 alc; 7.1 eth; s bz,
acet, chl; 0.02 aq
i aq; s eth
i aq
118–120
325–330
1.405220
1.476625
⫺108.5
⬍⫺50
65
265
⫺14
1.052420
1.452020
⬍⫺80
178
75
182, 415
0.980
1.456020
154744mm
45
144.17
172, 107
1.061
1.437020
196
84
156.18
173, 1104
1.064
1.460020
879mm
⬎110
120.58
173, 61
1.110
1.455020
150–151
47
170.21
173, 1105
1.044
1.458020
520.4mm
90
1.030
1.461020
186.25
(CH3)2CHCH2CH2CH2C(CH3)(OH)CH2CH3
Melting
point,⬚C
97
133.19
20, 275
1.064
1.566820
⫺30
232–233
98
158.29
1, 426
0.826
1.434020
76
736mm
76
misc aq, alc, eth, PE
misc aq, alc, bz, chl; s
eth
misc aq, alc, bz, chl,
eth, acet
INTERACTIVE
t79
Formula
weight
ROTATED
t75
Tetraethylthiuram
disulfide
Tetraethyltin
1,1,1,2-Tetrafluoroethane
Tetrafluoroethylene
2,2,3,3-Tetrafluoro-1propanol
1,2,3,6-Tetrahydrobenzaldehyde
1,2,3,4-Tetrahydrocarbazole
Tetrahydrofuran
2,5-Tetrahydrofurandimethanol
Tetrahydro-2-furanmethanol
Tetrahydro-2-furanmethylamine
Tetrahydrofurfuryl
acetate
Tetrahydrofurfuryl
acrylate
Tetrahydrofurfuryl
chloride
Tetrahydrofurfuryl
methacrylate
2(3)-(Tetrahydrofuryloxy)tetrahydropyran
1,2,3,4-Tetrahydroisoquinoline
Tetrahydrolinalool
Formula
LEFT
t73
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
t81
t82
t83
1,2,3,4-Tetrahydronaphthalene
cis-1,2,3,6-Tetrahydrophthalic anhydride
cis-1,2,3,6-Tetrahydrophthalimide
Tetrahydropyran
C10H12
132.21
5, 491
152.15
17, 462
0.970220
4
1.541420
Tetraethyl titanate(IV), t163
Tetrafluoromethane, c15
Tetraglyme, b212
1,2,3,4-Tetrahydrobenzene, c368
207.6
77
97–103
151.17
86.14
⫺35.8
misc alc, bz, chl, eth,
acet, PE
157
129–133
17, 12
0.881420
4
1.420020
⫺45
Tetrahydrodicyclopentadiene, t259
Tetrahydro-2,5-dimethoxyfuran, d525
Tetrahydrofurfuryl alcohol, t70
⫺155
88
Tetrahydrofurfuralamine, t72
Tetrahydrolinalool, d668
Tetrahydro-2-methylfuran, m429
misc aq, alc, eth
DEAN 37261 (McGHP)
t80
1.317
t68
t69
t71
t74
t72
t75
t76
RIGHT
t73
t70
ROTATED
t77
t78
t81
t82
t83
INTERACTIVE
No.
t84
t85
t86
t87
t88
t89
t90
1.318
t91
t92
t93
t95
t97
t98
t99
Beilstein
reference
116.16
Density,
g/mL
Refractive
index
1.025420
1.458020
Melting
point,⬚C
⫺70
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
187
93
misc aq, alc, bz, eth
116.19
24, 5
210–212
133.19
20, 262
1.061
1.594020
15–16
249
100
s aq; misc alc, eth
88.17
246.22
171, 5
8, 496
0.998720
1.504020
⫺96
200–203
121
12
misc alc, eth; i aq
[(HO)2C6H3]2C"O
[(CH3)2N]2C"C[N(CH3)2]2
200.23
44, 167
0.861
1.480020
590.9mm
53
[CH3CH(OH)CH2]2NCH2CH2N[CH2CH(OH)CH3]2
292.40
44, 1685
1.013
1.481220
1810.8mm
⬎110
(CH3O)2CH(CH2)6CH(OCH3)2
234.34
0.949
1.430020
1305mm
52
[(CH3O)2CH]2CH2
164.20
0.997
1.408120
183
54
(CH3)4N⫹ Br⫺
154.06
4, 51
1.56
⬎300
55 aq
(CH3)4N⫹ Cl⫺
109.60
4, 51
1.16920
4
⬎300
s aq, hot alc
(CH3)4N⫹ I⫺
201.06
4, 51
1.829
⬎300
sl s aq; v s abs alc
(CH3)2C6H3N(CH3)2
149.24
12, 1131
0.913
1.544320
C6H2-1,2,3,4-(CH3)4
134.22
5, 430
0.90520
4
1.518720
C6H2-1,2,3,5-(CH3)4
134.22
5, 430
0.890620
4
1.513420
C6H2-1,2,4,5-(CH3)4
134.22
5, 431
(CH3)3CC(CH3)3
114.23
1, 165
226–228
90
⫺6.2
205.0
68
misc alc, eth
⫺23.7
198.0
63
s alc; v s eth
0.83881
4
79.3
196.8
73
v s alc, bz, eth
0.824220
⫺100.7
106.5
4
INTERACTIVE
t100
Formula
weight
ROTATED
t96
Tetrahydropyran-2methanol
3,4,5,6-Tetrahydropyrimidinethiol
1,2,3,4-Tetrahydroquinoline
Tetrahydrothiophene
2,2⬘,4,4⬘-Tetrahydroxybenzophenone
Tetrakis(dimethylamino)ethylene
N,N,N⬘,N⬘-Tetrakis(2hydroxypropyl)ethylenediamine
1,1,8,8-Tetramethoxyoctane
1,1,3,3-Tetramethoxypropane
Tetramethylammonium bromide
Tetramethylammonium chloride
Tetramethylammonium iodide
N,N-3,5-Tetramethylaniline
1,2,3,4-Tetramethylbenzene
1,2,3,5-Tetramethylbenzene
1,2,4,5-Tetramethylbenzene
2,2,3,3-Tetramethylbutane
Formula
LEFT
t94
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
t102
t103
t104
t105
t106
t107
1.319
t108
t109
t110
N,N,N⬘,N⬘-Tetramethyl-1,3-butanediamine
N,N,N⬘,N⬘-Tetramethyl-1,4-butanediamine
1,1,3,3-Tetramethylbutylamine
1,3,5,7-Tetramethylcyclotetrasiloxane
N,N,N⬘,N⬘-Tetramethyldiaminomethane
1,1,3,3-Tetramethyldisiloxane
Tetramethylene
sulfone
(CH3)2NCH(CH3)CH2CH2N(CH3)2
144.26
43, 570
0.787
1.431820
165
40
(CH3)2N(CH2)4N(CH3)2
144.26
4, 265
0.78620
1.428020
169
46
s aq, alc, eth
(CH3)3CCH2C(CH3)2NH2
129.25
4, 198
0.805
1.424020
137–143
32
s alc, eth, PE; i aq
[-SiH(CH3)O-]4
240.51
44, 4099
0.991220
4
1.387020
(CH3)2NCH2N(CH3)2
102.18
4, 54
0.749
1.400520
85
⫺12
[(CH3)2CH]2O
134.33
44, 3991
0.75720
4
1.370020
70–71
⫺10
120.17
171, 5
1.260630
4
1.482030
27.6
285
177
N,N,N⬘,N⬘-Tetramethylethylenediamine
Tetramethylgermanium
1,1,3,3-Tetramethylguanadine
(CH3)2NCH2CH2N(CH3)2
116.21
4, 250
0.770
1.417920
⫺55
120–122
10
(CH3)4Ge
132.73
4,2, 1008
0.978
1.389020
⫺88
43.4
⫺37
[(CH3)2N]2C"NH
115.18
41, 335
0.918
1.469220
163
60
⫺69
Tetramethyl glycol, b457
Tetramethylene oxide, t69
Tetramethylene sulfide, t87
Tetramethylethylene glycol, d569
misc aq, acet, toluene;
s octanes, olifines,
naphthenes
RIGHT
␤-Tetralonehydantoin, b40
N,N,N⬘,N⬘-Tetramethyldiaminomethane, t113
N,N,N⬘,N⬘-Tetramethyl-1,3-diamino-2-propanol, b180
2,2,5,5-Tetramethyl-3,4-dithiahexane, d171
Tetramethylene, c333
Tetrahydropyrrole, p280
6,7,8,9-Tetrahydro-5H-tetrazolazepine, p27
Tetrahydrothiophene 1,1-dioxide, t107
Tetraiodomethane, c16
Tetralin, t80
134–135
DEAN 37261 (McGHP)
t101
ROTATED
t84
t85
t86
t87
t107
INTERACTIVE
No.
t111
t112
t113
t114
t115
1.320
t116
t117
t118
t119
t123
t124
t125
Beilstein
reference
Density,
g/mL
Refractive
index
N,N,N⬘,N⬘-Tetramethyl-1,6-hexanediamine
Tetramethyl lead
N,N,N⬘,N⬘-Tetramethylmethanediamine
2,6,10,14-Tetramethylpentadecane
2,2,6,6-Tetramethylpiperidinyl-1-oxy
(free radical)
N,N,N⬘,N⬘-Tetramethyl-1,3-propanediamine
Tetramethylpyrazine
Tetramethylsilane
1,1,3,3-Tetramethyl2-thiourea
[(CH3)2N(CH2)3-]2
172.32
41, 423
0.806
1.435920
(CH3)4Pb
(CH3)2NCH2N(CH3)2
267.33
102.18
4, 639
4, 54
1.99520
4
0.749
1.400520
[(CH3)2CH(CH3)3CH(CH3)CH2]2CH2
268.53
Merck:
12, 7932
0.782720
4
1.438520
Tetramethylthiuram
disulfide
Tetramethyltin
1,1,3,3-Tetramethylurea
Tetranitromethane
1,4,7,10-Tetraoxacyclododecane
(12-Crown-4)
2,4,8,10-Tetraoxaspiro[5.5]undecane
Tetraphenylboron
sodium
156.25
Boiling
point,⬚C
130.24
4, 262
0.779
1.423420
(CH3)4Si
(CH3)2NC("S)N(CH3)2
136.20
88.23
132.23
23, 99
4, 625
41, 336
0.641120
4
1.358020
[(CH3)2NCS2-]2
240.43
4, 76
1.29
(CH3)4Sn
(CH3)2NC("O)N(CH3)2
178.83
116.16
4, 631
4, 74
1.314925
0.968720
4
1.5201
1.449325
C(NO2)4
196.03
176.21
1, 80
1.622925
4
1.089
1.435825
1.463020
160.17
342.23
Flash
point,⬚C
Solubility in 100
parts solvent
209–210
73
⫺27.5
110
85
38
⫺12
misc alc, eth
⫺100
296
⬎110
s bz, chl, eth, PE
36–40
(CH3)2N(CH2)3N(CH3)2
(C6H5)4B⫺ Na⫹
Melting
point,⬚C
67
145–146
31
190
26.5
245
⫺27
⫺54
⫺0.6
74–75
176–177
⫺12
77
13.8
16
126
700.5mm
⬎110
⬎110
19, 436
52–55
831.5mm
108
Merck:
12, 8839
⬎300
84–86
⫺99.5
75–77
v s alc, eth
0.002 alc, 0.002 eth;
0.012 acet; 0.025
bz; s chl
155–156
misc aq, common org
solvents
v s alc, eth, alk
v s aq, acet; s chl
INTERACTIVE
t126
Formula
weight
ROTATED
t121
t122
Formula
LEFT
t120
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
t128
t129
t130
t131
t132
t133
1,1,4,4-Tetraphenyl1,3-butadiene
Tetraphenyltin
Tetrapropoxysilane
Tetrapropylammonium
bromide
1H-Tetrazole
2-Thenoyltrifluoroacetone
Theobromine
(C6H5)2C"CHCH"C(C6H5)2
358.49
5, 750
(C6H5)4Sn
(C3H7O)4Si
(CH3CH2CH2)4N⫹ Br⫺
427.11
264.4
266.27
1, 355
41, 364
Tetramethylolmethane, p19
2,2,4,4-Tetramethyl-3-thiapentane, d147
Tetramethylthiuram disulfide, b183
70.06
222.18
26, 346
180.17
26, 457
207–209
1.4900
0.91624
224–227
1.40120
⬎420
945mm
110
95
270 dec
157–158
40–44
357
Tetrantoin, b40
2,5,8,13-Tetraoxododecane, b211
Tetraphene, b6
s aq
s aq, alc, acet
988mm
sublimes
290–
295
100 aq; 0.045 alc; s
alk; i bz, chl, eth
DEAN 37261 (McGHP)
t127
Tetrapropoxytitanate(IV), t163
2-Thenoic acid, t155
1.321
t117
t124
t125
t131
RIGHT
t115
ROTATED
t132
t133
INTERACTIVE
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
Melting
point,⬚C
1.322
26, 455
274–275
t135
Thiamine HCl
337.27
dec 260
t136
t137
Thiazole
N2-(2-Thiazolyl)sulfanilamide
85.13
255.32
Merck:
12, 9430
27, 15
273, 4623
t138
t139
t140
CH3C("S)NH2
C6H5C("O)SH
75.13
138.19
358.54
2, 232
9, 419
64, 6043
C6H5NHC("S)NHC6H5
HSC6H4CH3
(HO2CCH2)2S
(HOCH2CH2)2S
(HOC6H4)2S
(HO2CCH2CH2)2S
228.32
124.21
150.15
122.19
218.27
178.21
12, 394
6, 416
3, 253
1, 470
6, 860
t147
t148
t149
Thioacetamide
Thiobenzoic acid
4,4⬘-Thiobis(2-tertbutyl-6-methylphenol)
Thiocarbanilide
p-Thiocresol
2,2⬘-Thiodiacetic acid
2,2⬘-Thiodiethanol
4,4⬘-Thiodiphenol
3,3⬘-Thiodipropionic
acid
Thiolacetic acid
N-Thionylaniline
Thionyl bromide
CH3C("O)SH
C6H5N"SO
SOBr2
76.12
139.18
207.88
1.065
1.236
2.683
1.4630
1.627020
1.675020
t150
Thionyl chloride
SOCl2
118.97
1.635
t151
t152
t153
Thiophene
2-Thiopheneacetic acid
2-Thiophenecarbonyl
chloride
2-Thiophenecarboxaldehyde
C4H4S
(C4H3S)CH2CO2H
(C4H3S)COCl
84.14
142.18
146.60
2, 230
12, 578
Merck:
12, 9484
Merck:
12, 9485
17, 29
18, 293
18, 290
(C4H3S)CHO
112.15
17, 285
t141
t142
t143
t144
t145
t146
t154
1.200
1.539020
0.83 aq; 1.25 alc; 0.9
chl; s hot aq, alk,
dil acids
100 aq; 1 alc; 5.5 glyc
117–118
22
12230mm
31640mm
⬎110
240
195
68
282
160
202
1.174
1.605020
1.3224
1.182420
4
1.520320
112–114
15–18
163–165
152–155
42–44
128–131
⫺10.2
154–156
131–134
⬍ ⫺17
11
84
⫺52
88–91
200
138
1.51720
⫺101
76
none
1.057325
4
1.525725
⫺39.4
63–67
⫺1
1.371
1.590020
84
16022mm
206–208
1.200
1.590020
198
77
s alc, eth; sl s aq
0.06 aq; 0.52 alc; s
acet, dil mineral
acids, alkalis
16 aq; 16 alc; sl s eth
misc eth; v s alc; i aq
v s alc, eth
s alc, eth; i aq
s aq, alc
misc aq, alc; sl s eth
3.7 aq; v s hot aq, alc,
acet
s aq; v s alc
misc bz, chl, CCl4; hyd
by aq
misc bz, chl, CCl4; hyd
by aq
misc alc, eth; i aq
90
s eth
INTERACTIVE
180.17
Solubility in 100
parts solvent
ROTATED
Theophylline
Flash
point,⬚C
LEFT
t134
Boiling
point,⬚C
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
t156
t157
t158
2-Thiophenecarboxylic
acid
Thiophenol
Thiophenoxyacetic
acid
Thiophosphoryl
chloride
(C4H3S)CO2H
128.15
18, 289
C6H5SH
C6H5SCH2CO2H
110.18
168.21
6, 294
6, 313
PSCl3
169.40
260
s aq, chl; v s alc, eth
1.073
1.588020
⫺14.9
64–66
169
50
v s alc; misc bz, eth
1.668
1.555020
⫺36 (␤)
⫺40 (␣)
125
none
s bz, chl, CCl4, CS2
2-Thiapentane, m406
3-Thiapentane, d398
Thioanisole, m379
2-Thiobarbituric acid, d437
1,1⬘-Thiobis(butane), d170
Thiocarbanilide, d791
2,2⬘-Thiodiethanethiol, b209
2-Thiabutane, e221
Thiacyclopentane, t87
1,3,4-Thiadiazole-2,5-dithiol, d486
3-Thiaheptane, b557
2-Thiahexane, b577
3-Thiahexane, e255
Thianaphthene, b60
5-Thianonane, d170
127–130
Thiodiethylene glycol, t144
Thiodiglycol, t144
Thiodiglycolic acid, t143
Thioethanol, e26a
Thioethanolamine, a161
1-Thioglycerol, m21
Thioglycolic acid, m16
DEAN 37261 (McGHP)
t155
1.323
t135
t136
RIGHT
t134
ROTATED
t137
t140
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
Name
Formula
Formula
weight
Beilstein
reference
1.324
t163
t164
Titanium(IV) ethoxide
Titanium(IV) isopropoxide
Titanium(IV) propoxide
Toluene
2,4-Toluenediamine
2,5-Toluenediamine
2,6-Toluenediamine
3,4-Toluenediamine
Toluene-2,4-diisocyanate
p-Toluenesulfinic acid
o-Toluenesulfonamide
p-Toluenesulfonamide
p-Toluenesulfonylhydrazide
p-Toluenesulfonic acid
p-Toluenesulfonyl
chloride
p-Toluenesulfonyl
fluoride
CH3C6H3-2,4-(NH2)2
CH3C6H3-2,5-(NH2)2
CH3C6H3-2,6-(NH2)2
CH3C6H3-3,4-(NH2)2
CH3C6H3-2,4-(NCO)2
122.17
122.17
122.17
122.17
174.16
13,
13,
13,
13,
13,
CH3C6H4SO2H
CH3C6H4SO2NH2
CH3C6H4SO2NH2
156.21
171.22
171.22
11, 9
11, 86
11, 104
t165
t166
t167
t168
t169
t170
t171
t172
t173
t174
t175
t176
t177
t178
1.014
1.464020
90.14
91.14
76.12
212.27
150.22
2, 264
3, 195
3, 180
17, 357
6, 532
1.405
0.969925
4
Ti(OC2H5)4
Ti[OCH(CH3)2]4
228.15
284.26
1, 335
12, 382
Ti(OCH2CH2CH3)4
284.26
C6H5CH3
92.14
Boiling
point,⬚C
108–110
Flash
point,⬚C
11
1.522720
182–184
176–178
212–213
51.5
373715mm
233
102
1.088
0.963
1.504320
1.466020
18–20
15210mm
220
28
22
13, 1423
1.033
1.498620
1703mm
42
5, 280
0.866020
4
1.496020
⫺94.9
110.6
4
292
273–274
1.568920
99
64
104–106
91–93
20–21
124
144
148
148
138
2
1.224420
4
15618mm
251
Solubility in 100
parts solvent
132
85
156–158
138–140
s aq, alc
9 aq; s alc; sl s eth
v s bz, chl, hot HOAc
0.1 aq; 100 alc; 140
eth; s HOAc, alk
OH
s bz, chl, eth
misc alc, chl, eth, acet,
HOAc; 0.067 aq
s hot aq, alc, eth
v s aq, alc, eth
s aq, alc
v s aq
dec aq, alc; misc acet,
bz, eth
v s alc, eth; sl s aq
0.2 aq; 3.6 alc
CH3C6H4SO2NHNH2
186.23
11 , 66
110 dec
CH3C6H4SO3H
CH3C6H4SO2Cl
172.20
190.65
11, 97
11, 103
107 anhyd
67–69
14020mm
13410mm
CH3C6H4SO2F
174.19
112, 54
41–42
11216mm
67 aq; s alc, eth
v s alc, bz, eth; i aq
105
INTERACTIVE
CH3CH2C("O)SH
H2NC("S)NHNH2
H2NC("S)NH2
Melting
point,⬚C
ROTATED
Thiopropionic acid
3-Thiosemicarbazide
Thiourea
Thioxanthen-9-one
Thymol
Refractive
index
LEFT
t159
t160
t161
t162
t162a
Density,
g/mL
t180
t181
t182
t183
t184
t185
t186
t187
t188
t189
t190
t191
t192
t193
1.325
t194
t195
p-Toluenesulfonyl
isocyanate
m-Toluidine
o-Toluidine
p-Toluidine
m-Tolunitrile
o-Tolunitrile
p-Tolunitrile
2-(p-Toluoyl)benzoic
acid
m-Toluoyl chloride
o-Toluoyl chloride
p-Toluoyl chloride
p-Tolyl acetate
1-(o-Tolyl)biguanide
m-Tolyl isocyanate
1,2,4-Triacetoxybenzene
Triacetoxyvinylsilane
Triallylamine
197.21
CH3C6H4NH2
CH3C6H4NH2
CH3C6H4NH2
CH3C6H4CN
CH3C6H4CN
CH3C6H4CN
CH3C6H4COC6H4CO2H
107.16
107.16
107.16
117.15
117.15
117.15
240.26
12, 853
12, 772
12, 880
9, 477
9, 466
9, 489
10, 759
0.98920
4
0.99820
0.961920
0.97615
0.989
0.978530
4
1.568020
1.572020
1.553259
1.525620
1.527920
CH3C6H4COCl
CH3C6H4COCl
CH3C6H4COCl
CH3CO2C6H4CH3
CH3C6H4NHC("NH)NHC("NH)NH2
CH3C6H4NCO
C6H3(O2CCH3)3
154.60
154.60
154.60
150.18
191.24
9, 477
9, 464
9, 484
6, 397
123, 1873
1.173
1.185
1.169
1.048
1.548520
1.554920
1.553020
1.501020
133.15
252.22
12, 864
6, 1089
1.033
(CH3CO2)3SiCH"CH2
(H2C"CHCH2)3N
232.26
137.23
4, 208
⫺2
⬎110
203
200
200
210
205
217
85 (CC)
85
87
86
84
85
865mm
9012mm
225–227
210–211
76
76
82
90
⬎110
7612mm
65
12825mm
76
30
143–145
1.530520
misc alc, eth
1.7 aq; s alc, eth
7.4 aq; v s alc, eth
0.09 aq; v s alc, eth
i aq; misc alc, eth
i aq; v s alc, eth
v s alc, bz, eth, acet
s alc, eth; i aq
98–100
1.167
0.790
1.422020
1.451020
Tioxolone, h105
TMS, t118
TMSi, t396
Tolan, d742
p-Tolualdehyde, m138
Toluenethiol, t142
150–151
Toluic acids, m142 thru 144
␣-Tolunitrile, p82
p-Tolylacetamide, m374
Tolyl bromide, b431
␣-Tolyl chloride, b90
Tolyl chlorides, c255 thru c257
OH
H3C
CH3
ROTATED
CH3
t162
⫺31
⫺16.3
43.8
⫺23
⫺13
29.5
137–139
14410mm
RIGHT
Thiolactic acid, m22
Thiomalic acid, m25
Thiosalicylic acid, m18
Thiosinamine, a97
2-Thioxo-4-thiazolidinone, r7
Threonine, a185
Tiglic acid, m169
1.435520
CH3C6H4SO2NCO
DEAN 37261 (McGHP)
t179
t162a
INTERACTIVE
No.
t196
t197
t198
t199
t200
t201
t202
t203
t204
1.326
t205
t206
t207
t208
t209
t210
Beilstein
reference
249.27
Density,
g/mL
Refractive
index
1.159
1.512920
(C6H5CH2)3N
Br3CCHO
Br3CCO2H
Br3C6H2NH2
Br3CCH2OH
BrCH"CBr2
69.07
287.41
280.76
296.76
329.83
282.77
264.74
26, 13
12, 1038
1, 626
2, 220
12, 663
12, 338
1, 191
1.70821
1.624725
CHBr3
252.77
1, 68
2.900015
2,4,6-Tribromophenol
1,2,3-Tribromopropane
Tributoxyborane
Tributylamine
Tributylborane
2,4,6-Tri-tert-butylphenol
Tributyl phosphate
Tributyl phosphite
Tributyltin chloride
Tributyltin ethoxide
Tributyltin hydride
Tributyltin methoxide
Trichloroacetamide
Trichloroacetaldehyde
Br3C6H2OH
BrCH2CH(Br)CH2Br
(C4H9O)3B
(C4H9)3N
(C4H9)3B
[(CH3)3C]3C6H2OH
330.82
280.78
230.16
185.36
182.16
262.44
6, 203
1, 112
12, 398
4, 157
42, 1022
2.55
2.390
0.856720
0.7784
0.747
0.86427
4
(C4H9O)3P(O)
(C4H9O)3P
(C4H9)3SnCl
(C4H9)3SnOC2H5
(C4H9)3SnH
(C4H9)3SnOCH3
Cl3CCONH2
Cl3CCHO
266.32
250.32
325.49
335.10
291.05
321.07
162.40
147.40
12, 397
11, 187
43, 1926
Trichloroacetic acid
Trichloroacetic
anhydride
1,1,3-Trichloroacetone
Trichloroacetonitrile
Cl3CCO2H
(Cl3CCO)2O
163.39
308.75
44, 4312
44, 4331
2, 211
Merck:
12, 9755
2, 206
2, 210
ClCH2COCHCl2
Cl3CCN
161.42
144.39
1, 655
2, 212
0.99195
4
2.665
Melting
point,⬚C
Boiling
point,⬚C
1524mm
119–121
91–94
1.585020
Flash
point,⬚C
⬎110
260
65
65
130–133
120–122
73–79
174
245
300
9310mm
162.5
1.600515
8.1
149.6
83
1.58418
1.409220
1.428020
87–89
16.5
⬍⫺70
⫺70
290746mm
220
234
216
10920mm
277
93
93
86
⫺36
2.35
129–132
0.972725
0.92520
4
1.200
1.098
1.082
1.115
1.422625
1.432620
1.490520
1.467220
1.473020
1.472020
1.51020
4
1.455720
1.62961
4
1.690
1.620020
1.483820
1.508
1.440325
4
1.489220
1.440920
⫺79
289
1257mm
17325mm
920.1mm
800.4mm
970.06mm
238–240
97.8
146
91
⬎110
40
40
98
57.5
196.5
14160mm
⬎110
none
13–15
⫺42
172
86
79
none
141–143
⫺57.5
Solubility in 100
parts solvent
s aq, alc
s hot alc, eth
s aq, alc, chl, eth
s aq, alc, eth
s hot alc, chl, eth
2 aq; s alc, bz, eth
0.3 aq; misc eth,
MeOH
s alc, chl, eth; i aq
s alc, eth
hyd aq
v s alc, eth; s acet
i aq; s most org solv
0.04 aq; misc org solv
misc alc, bz, eth, PE
dec aq, alc; s eth
120 aq; v s alc, eth
INTERACTIVE
t221
t222
Formula
weight
ROTATED
t219
t220
Triallyl-1,3,5-triazine2,4,6(1H,3H,5H)trione
1H-1,2,4-Triazole
Tribenzylamine
Tribromoacetaldehyde
Tribromoacetic acid
2,4,6-Tribromoaniline
2,2,2-Tribromoethanol
1,1,2-Tribromoethylene
Tribromomethane
Formula
LEFT
t211
t212
t213
t214
t215
t216
t217
t218
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
t224
t225
t226
t227
t228
t229
t230
t231
t232
t233
t234
t235
1.327
t236
t237
t238
t239
2,2⬘,4⬘-Trichloroacetophenone
Trichloroacetyl
chloride
2,4,5-Trichloroaniline
2,4,6-Trichloroaniline
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,3,5-Trichlorobenzene
Trichloro-3-chloropropylsilane
1,1,1-Trichloroethane
1,1,2-Trichloroethane
2,2,2-Trichloroethanol
2,2,2-Trichloroethyl
chloroformate
Trichloroethylene
Cl2C6H3COCH2Cl
223.49
7, 283
Cl3CCOCl
181.83
2, 210
Cl3C6H2NH2
Cl3C6H2NH2
C6H3Cl3
C6H3Cl3
C6H3Cl3
Cl(CH2)3SiCl3
196.46
196.46
181.45
181.45
181.45
211.98
12, 627
12, 627
5, 203
5, 204
5, 204
CH3CCl3
ClCH2CHCl2
Cl3CCH2OH
ClCO2CH2CCl3
133.41
133.41
149.40
211.86
ClCH"CCl2
Trichloroethylsilane
Trichlorofluoromethane
␣,␣,2-Trichloro-6fluorotoluene
Trichloroisocyanuric
acid
1354mm
⫺146
118
93–95
73–75
53–55
17
63.5
270
262
218–220
213–214
208
181–183
⬎110
s alc
s alc, eth
v s bz, CS2; sl s alc
misc bz, eth, PE
v s bz, eth, PE
1.69
1.45420
1.66
1.350
1.577620
1.570720
1.566219
1.466620
1, 85
1, 85
1, 338
1.339020
1.439720
1.557
1.539
1.437920
1.471420
1.490020
1.470320
⫺30.4
⫺37
18
74
114
151–153
171–172
⫺1
32
s acet, bz, eth
misc alc, eth
8 aq; misc alc, eth
131.39
1, 187
1.464220
1.477320
⫺84.8
87
32
0.1 aq; misc alc, chl,
eth
C2H5SiCl3
Cl3CF
163.51
137.37
1.237320
1.48521
1.425620
1.38420
⫺105.6
⫺111
100.5
23.8
22
ClC6H3(F)CHCl2
213.47
4, 630
Merck:
12, 9770
53, 701
1.446
1.550620
228–230
⬎110
232.41
25, 256
126
110
107
0.14 aq; s alc, eth
249–251
Tributyl borate, t207
Tributyrin, g20
Trichloroethanal, t218
␤,␤,␤-Trichloroethoxycarbonyl chloride, t234
RIGHT
Triacetin, p200
1,3,5-Triazine-2,4,6-triol, c332
1.468920
1.629
52–55
DEAN 37261 (McGHP)
t223
ROTATED
t196
t197
t239
INTERACTIVE
No.
t240
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
1.70020
4
1.543620
(CH3)2C(OH)CCl3
177.46
1, 382
CH3SiCl3
Cl3C6H2NO2
149.48
226.45
43, 1896
5, 246
Cl3C6H2OH
197.45
62, 180
t245
2,4,6-Trichlorophenol
Cl3C6H2OH
197.45
6, 190
t246
(2,4,5-Trichlorophenoxy)acetic acid
1,2,3-Trichloropropane
2,4,6-Trichloropyrimidine
Trichlorosilane
Cl3C6H2OCH2CO2H
255.49
63, 702
ClCH2CH(Cl)CH2Cl
147.43
183.43
1, 106
23, 90
1.388920
1.485420
1.570020
HSiCl3
135.45
1.342
1.400020
4-(Trichlorosilyl)butyronitrile
␣,␣,␣-Trichlorotoluene
␣,2,4-Trichlorotoluene
␣,2,6-Trichlorotoluene
␣,3,4-Trichlorotoluene
2,4,6-Trichloro-1,3,5triazine
1,1,1-Trichlorotrifluoroethane
1,1,2-Trichlorotrifluoroethane
Trichlorovinylsilane
Cl3Si(CH2)3CN
202.54
Merck:
12, 9776
4,4, 4272
1.300
1.463020
C6H5CCl3
Cl2C6H3CH2Cl
Cl2C6H3CH2Cl
Cl2C6H3CH2Cl
195.48
195.48
195.48
195.48
184.41
5, 300
54, 819
1.372320
1.407
5, 300
26, 35
1.411
1.558020
1.576020
1.576120
1.576620
t241
t242
t243
1.328
t247
t248
t249
t250
t251
t252
t253
t254
t255
t256
t257
t258
Cl3CCF3
187.38
Cl2CFCClF2
187.38
H2C"CHSiCl3
161.49
13, 157
1.27320
4
1.79020
1.410820
1.490175
4
Solubility in 100
parts solvent
146–148
99 anhyd
167
s alc, bz, chl, eth
⫺90
49–55
66
288
67–69
253
69
246
none
615 acet; 163 bz; 525
eth; 615 MeOH; i
aq
525 acet; 113 bz; 354
eth; 525 MeOH; i
aq
s alc; v sl s aq
⫺14.7
23–25
157
⬎110
71
misc alc, eth; i aq
⫺127
31–32
⫺13
dec aq; s bz, chl
237–238
92
127
⬎110
⬎110
⬎110
146–148
219–223
248
11914mm
12414mm
190
⫺9
⬎110
154–158
⫺5
⫺2.6
36–39
1.579
1.369920
13–14
46
1.563525
1.355725
⫺35
47.7
1.270
1.436020
⫺95
90
v s bz, eth
s alc, bz, eth
v s alc, eth
i aq; s alc
0.017 aq
10
INTERACTIVE
3, 135
Flash
point,⬚C
ROTATED
185.89
Boiling
point,⬚C
LEFT
Cl3CSCl
t244
Trichloromethanesulfenyl chloride
1,1,1-Trichloro-2methyl-2-propanol
Trichloromethylsilane
1,2,4-Trichloro-5nitrobenzene
2,4,5-Trichlorophenol
Melting
point,⬚C
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
Tricyclo[5.2.1.02,6]decane
Tricyclo[5.2.1.02,6]decan-8-one
Tridecane
Tridecanoic acid
2-Tridecanone
7-Tridecanone
1-Tridecene
Triethanolamine
136.24
5, 164
150.22
72, 133
1.063
1.502520
CH3(CH2)11CH3
CH3(CH2)11CO2H
CH3(CH2)10COCH3
[CH3(CH2)5]2CO
CH3(CH2)10CH"CH2
(HOCH2CH2)3N
184.37
214.35
198.35
198.35
182.35
149.19
1, 171
2, 364
1, 715
1, 715
1, 225
4, 285
0.756320
4
1.425620
0.822
0.825
0.765820
1.124220
4
1.435020
(C2H5O)3C6H2CO2H
254.29
10, 481
(C2H5O)3B
(C2H5O)3SiH
(C2H5O)3SiCH2CH2CN
145.99
164.28
217.34
1, 335
1, 334
44, 4271
(C2H5O)3Si(CH2)3NCO
247.37
t272
t273
t274
3,4,5-Triethoxybenzoic
acid
Triethoxyborane
Triethoxysilane
3-(Triethoxysilyl)propionitrile
3-(Triethoxysilyl)propyl isocyanate
Triethoxyvinylsilane
Triethylaluminum
Triethylamine
(C2H5O)3SiCH"CH2
(C2H5)3Al
(C2H5)3N
190.32
114.17
101.19
t275
t276
t277
Triethylantimony
Triethylarsine
Triethylborane
(C2H5)3Sb
(C2H5)3As
(C2H5)3B
208.94
162.11
98.00
t260
t261
t262
t263
t264
t265
t266
t267
t268
t269
t270
t271
1.329
1.434020
1.485320
193
40
13230mm
⫺5 to ⫺4
41–42
29–31
30–32
⫺13
20.5
235
236100mm
13410mm
264
232.8
335.4
70
⬎110
⬎110
⬎110
79
179
v s alc, eth
v s alc, eth; i aq
dec aq
s alc; v s eth
misc aq, alc, acet; 4.5
bz; 1.6 eth; s chl
110–112
0.864
0.890
0.979
1.374020
1.377020
1.414020
117–118
134–135
224
11
26
100
0.999
1.420020
283
77
0.90320
4
0.83225
0.727520
1.397820
4, 643
4, 99
1.401020
⫺50
⫺114.7
160–161
194
88.8
34
⫺18
⫺7
4, 618
4, 602
4, 641
1.32416
1.15020
4
0.696123
1.42
⫺29
1.397020
⫺02.9
159.5
140736mm
95
dec aq, air
5.5 aq; misc alc, eth; s
acet, EtOAc
i aq; misc alc, eth
i aq; dec by air
Tricyclo[5.2.1.02,6]decane-4,8-dimethanol, b202
3-Triethoxysilylpropylamine, a273
Triethyl borate, t268
Tricine, t441
Tri-o-cresyl phosphate, t452
Tricyclene, t400a
Tricyclo[3.3.1.13,7]decane, a65
RIGHT
Trichloromethane, c145
(Trichloromethyl)benzene, t251
Tricyclophenylsilane, p159
3,3,3-Trichloropropylene oxide, e18
77–79
DEAN 37261 (McGHP)
t259
ROTATED
t248
t255
t259
t260
INTERACTIVE
No.
Name
Formula
HOC(CO2C2H5)(CH2CO2C2H5)2
t280
t281
t292
t293
Tri(ethylene glycol)
Tri(ethylene glycol)
dimethacrylate
Tri(ethylene glycol)
dimethyl ether
Tri(ethylene glycol)
divinyl ether
Tri(ethylene glycol)
monomethyl ether
Triethylenetetramine
Triethylgallium
1,3,5-Triethylhexahydro-1,3,5-triazine
Triethylindium
Triethyl orthoacetate
Triethyl orthoformate
Triethyl orthopropionate
Triethyl phosphate
Triethylphosphine
t294
t295
t282
t283
t284
1.330
t285
t286
t287
t288
t289
t290
t291
t296
Refractive
index
1.442020
Melting
point,⬚C
Boiling
point,⬚C
1271mm
Flash
point,⬚C
⬎110
62
Solubility in 100
parts solvent
276.29
112.18
3, 568
233, 484
1.137
(HOCH2CH2OCH2-)2
[H2C"C(CH3)CO2CH2CH2OCH2-]2
(CH3OCH2CH2OCH2-)2
150.17
286.33
1, 468
24, 1531
1.127415
1.092
1.455020
1.460520
⫺7
285
1725mm
177
⬎110
178.23
0.99020
4
1.422420
⫺45
216
111
H2C"CH(OCH2H2)3OCH"CH2
202.25
Merck:
12, 9820
13, 2106
0.990
1.453020
12618mm
⬎110
CH3(OCH2CH2)3OH
164.20
13, 2105
1.026
1.439920
12210mm
⬎110
(H2NCH2CH2NHCH2-)2
(C2H5)3Ga
146.24
156.91
171.20
4, 255
1.4971
266
142.6
207–208
143
26, 2
0.982
1.057630
0.894
80
144
142
146
155–160
36
30
60
misc alc, chl, eth
dec aq; s alc, eth
v s alc, eth
215
128–129
115
⫺17
s aq(dec), alc, eth
i aq; misc alc, eth; pyrophoric
i aq(hyd); misc alc,
acet, bz, eth, PE
158–160
12
⫺82.3
1.459520
(C2H5)3In
CH3C(OC2H5)3
HC(OC2H5)3
CH3CH2C(OC2H5)3
202.01
162.23
148.20
176.26
1.26020
0.884725
4
0.89120
4
0.876
1.53820
1.395025
1.391020
1.399520
⫺32
2, 129
2, 20
2, 240
(C2H5O)3P(O)
(C2H5)3P
182.16
118.16
1, 332
4, 582
1.069520
0.80015
4
1.405820
1.456320
⫺56
⫺88
Triethyl phosphite
(C2H5O)3P
166.16
1, 330
0.96920
4
1.413020
156
54
Triethyl phosphonoacetate
Triethyl phosphonoformate
Triethylsilane
Triethyl thiophosphate
2,2,2-Trifluoroacetamide
(CH3CH2O)2P(O)CH2CO2C2H5
224.19
41, 573
1.130
1.431020
1459mm
⬎110
(CH3CH2O)2P(O)CO2C2H5
212.17
32, 103
1.110
1.432020
13512mm
⬎110
(C2H5)3SiH
(C2H5O)3P(S)
CF3CONH2
116.28
198.22
113.04
4, 625
1, 333
22, 186
0.73120
4
1.082
1.41220
1.448020
107–108
10016mm
162.5
⫺3
107
⫺76
70–75
45 aq; 13 acet; 77 alc;
51 bz
misc aq, alc, bz
misc aq, hydrocarbon
solvents
i aq; misc alc, eth
INTERACTIVE
t297
t298
t299
Density,
g/mL
ROTATED
Triethyl citrate
Triethylenediamine
Beilstein
reference
LEFT
t278
t279
Formula
weight
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
t302
t303
t304
t305
t306
t307
t308
t309
t310
1.331
t311
t312
t313
t314
t315
Trifluoroacetic acid
Trifluoroacetic
anhydride
1,1,1-Trifluoroacetone
1,3,5-Trifluorobenzene
␣,␣,␣-Trifluoro-mcresol
2,2,2-Trifluoroethanol
2,2,2-Trifluoroethyl
trifluoroacetate
Trifluoromethane
Trifluoromethanesulfonic acid
Trifluoromethanesulfonic anhydride
3-(Trifluoromethyl)aniline
␣,␣,␣-Trifluorotoluene
Trihexyl O-acetylcitrate
Trihexylamine
Trihexyl O-butylcitrate
Trihexylchlorosilane
CF3CO2H
[CF3C(O)]2O
114.02
210.03
22, 186
22, 186
1.489020
1.487
1.285020
⬍1.300
⫺15.3
⫺65
73
39–40
CF3C(O)CH3
C6H3F3
CF3C6H4OH
112.05
132.09
162.11
12, 717
61, 187
1.252
1.277
1.333
⬍1.30
1.415020
1.458820
⫺5.5
⫺1.8
22
75–76
178–179
⫺30
⫺7
73
CF3CH2OH
CF3CH2O2CCF3
100.04
196.05
13, 1342
23, 427
1.384220
4
1.472518
4
1.290720
1.281218
⫺43.5
⫺65.5
74
55
29
0
HCF3
CF3SO3H
70.01
150.07
1, 59
34, 34
1.52⫺100
1.69525
1.325025
⫺160
34
⫺84
162
none
75 mL aq; 500 mL alc
v s aq; misc eth
(CF3SO2)2O
282.13
34, 35
1.677
1.321220
84
none
dec aq, alc
CF3C6H4NH2
161.13
12, 870
1.290
1.480020
5–6
187
85
C6H5CF3
CH3CO2C[CO2(CH2)5CH3][CH2CO2(CH2)5CH3]2
[CH3(CH2)5]3N
C3H7CO2C[CO2(CH2)5CH3][CH2CO2(CH2)5CH3]2
[CH3(CH2)5]3SiCl
146.11
486.65
5, 290
1.188620
1.005
1.414520
1.447020
⫺29
102
12
⬎110
269.52
514.71
4, 188
0.794
0.993
1.441520
1.448020
163–265
⬎110
⬎110
0.87120
4
1.45620
2,2,2-Trifluoroethyl mesylate, m453
2-(Trifluoromethyl)aniline, a126
3-(Trifluoromethyl)aniline, a127
Trifluoromethylbenzene, t311
v s alc, eth; i aq
1555mm
m-Trifluoromethylphenol, t304
4,4,4-Trifluoro-1-(2-thienyl)-1,3-butanedione, t132
␣,␣,␣-Trifluorotoluidines, a126 thru a128
Triglyme, b211
RIGHT
Triethylenediamine, d61
Triethylene glycol, e139
Triethylene glycol dimethyl ether, b211
O,O,O-Triethyl phosphorothioate, t298
319.12
⫺55
misc aq
DEAN 37261 (McGHP)
t300
t301
ROTATED
t279
t287
INTERACTIVE
No.
t316
t317
t318
t319
t320
t321
1.332
t322
t323
t324
t325
t326
t327
t332
t333
t334
Beilstein
reference
Density,
g/mL
Refractive
index
0.799
1.45
1.44820
Melting
point,⬚C
Boiling
point,⬚C
Flash
point,⬚C
Solubility in 100
parts solvent
⬎110
Trihexylsilane
1,2,3-Trihydroxybenzene
1,3,5-Trihydroxybenzene
3,4,5-Trihydroxybenzoic acid
[CH3(CH2)5]3SiH
C6H3(OH)3
284.60
126.11
44, 3915
6, 1071
C6H3(OH)3
126.11
6, 1092
218–221
1 aq; 10 alc; s eth
(HO)3C6H2CO2H
170.12
10, 470
258–265
1.1 aq; 17 alc; 1 eth;
20 acet; i bz, chl,
PE
2,3,4-Trihydroxybenzophenone
1,2,6-Trihydroxyhexane
Triisobutylaluminum
Triisobutylamine
Triisodecyl phosphite
Triisopropanolamine
Triisopropoxyborane
1,3,5-Triisopropylbenzene
Triisopropyl orthoformate
Triisopropyl phosphite
Triisopropylsilane
3,4,5-Trimethoxybenzaldehyde
1,2,3-Trimethoxybenzene
1,2,4-Trimethoxybenzene
1,3,5-Trimethoxybenzene
3,4,5-Trimethoxybenzoic acid
(HO)3C6H2COC6H5
230.22
8, 417
140–142
HO(CH2)4CH(OH)CH2OH
134.18
133
1,4, 2784
1.109
1.476020
4, 643
4, 166
1.449420
1.423020
1.460020
161
309
59 aq; 77 alc; 62 eth
1785mm
79
1.376420
1.488020
8610mm
192–193
166
305.4
139–141
232–236
⫺18
57
235
152
10
86
[(CH3)2CHCH2]3Al
[(CH3)2CHCH2]3N
[(CH3)2CH(CH2)7O]3P
[CH3CH(OH)CH2]3N
[(CH3)2CHO]3B
C6H3[CH(CH3)2]3
198.33
185.36
502.80
191.27
188.08
204.36
43, 762
1, 363
5, 458
0.786
0.766
0.884
0.999650
20
0.815
0.845
4–6
CH[OCH(CH3)2]3
190.29
23, 39
0.854
1.397020
6618mm
42
[(CH3)2CHO]3P
[(CH3)2CH]3SiH
(CH3O)3C6H2CHO
208.24
158.36
196.20
1, 363
43, 1851
8, 391
0.91420
4
0.773
1.411020
1.434420
67
37
73–75
6411mm
8635mm
16510mm
C6H3(OCH3)3
168.19
6, 1081
1.112
43–45
241
⬎110
C6H3(OCH3)3
168.19
6, 1088
1.126
247
⬎110
C6H3(OCH3)3
168.19
6, 1101
51–53
255
85
(CH3O)3C6H2CO2H
212.20
10, 481
168–171
22710mm
⬍0
48–52
1.533020
pyrophoric
v s aq
i aq(sl hyd)
v s alc, eth; s chl
INTERACTIVE
t335
Formula
weight
ROTATED
t329
t330
t331
Formula
LEFT
t328
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
t337
t338
t339
t340
t341
t342
t343
t344
t345
t346
1.333
t347
t348
t349
t350
t352
230.65
10, 487
(CH3O)3C6H2CH2OH
198.22
6, 1159
(CH3O)3B
[-OB(OCH3)-]3
CH3OCH2CH(OCH3)2
103.91
173.53
120.15
CH3OCH2CH2CH(OCH3)2
134.18
CH3OCH2CH2CH2Si(OCH3)3
164.28
(CH3O)3SiH
H2N(CH2)3Si(OCH3)3
122.20
179.29
C6H5NH(CH2)3Si(OCH3)3
1.233
23
4
1.543920
20
⫺34
10
18518mm
22825mm
⬎110
67–68
130
5956mm
⫺13
10
23
13, 3183
0.920
1.195
0.932
1.3568
1.399620
1.392120
1, 820
0.942
1.400420
4617mm
40
0.932
1.390020
142
40
0.960
1.027
1.357920
1.424020
81
9215mm
⫺4
83
255.39
1.070
1.555020
310
⬎110
(CH3O)3Si(CH2)3NHCH2CH2NH2
224.36
1.019
1.445020
14615mm
⬎110
(CH3O)3Si(CH2)3O2CC(CH3)"CH2
248.35
1.04520
4
1.431020
190
92
(CH3O)3Si(CH2)3NHCONH2
222.32
1.150
1.460020
217–250
98
(CH3)3CCO2H
[(CH3)3CCO]2O
102.13
186.25
2, 319
2, 320
0.889
0.918
1.409020
163–164
193
63
57
(CH3)3CCOCl
120.58
2, 320
0.979
1.412020
105–106
8
72.09
4, 643
0.75220
1.43212
125–126
⫺18
(CH3)3Al
1, 287
81–84
12, 274
Trimellitic anhydride, b32
Trimesic acid, b31
Trimesoyl chloride, b33
Trimethoxymethylsilane, m455
Trimethylacetaldehyde, d677
⫺115
33–35
15
Trimethylacetamide, d678
Trimethylacetic acid, d679
Trimethylacetic anhydride, d680
Trimethylacetyl chloride, d681
hyd aq; misc alc, eth
s alk; v sl s alc
ROTATED
Tri-(2-hydroxyethyl)amine, t266
1,2,6-Trihydroxyhexane, h63
1,2,3-Trihydroxypropane, g19
Triiodomethane, i33
Trimellitic acid, b30
(CH3O)3C6H2COCl
RIGHT
t351
3,4,5-Trimethoxybenzoyl chloride
3,4,5-Trimethoxybenzyl alcohol
Trimethoxyborane
Trimethoxyboroxine
1,1,2-Trimethoxyethane
1,1,3-Trimethoxypropane
1,1,3-Trimethoxypropylsilane
Trimethoxysilane
3-(Trimethoxysilyl)propylamine
N-[3-(Trimethylsilyl)propyl]aniline
N1-[3-(Trimethoxysilyl)propyl]ethylenediamine
3-(Trimethoxysilyl)propyl methacrylate
[3-(Trimethoxysilyl)propyl]urea
Trimethylacetic acid
Trimethylaceticanhydride
Trimethylacetyl
chloride
Trimethylaluminum
DEAN 37261 (McGHP)
t336
INTERACTIVE
No.
Name
Formula
Formula
weight
Beilstein
reference
Density,
g/mL
Refractive
index
4, 43
0.656
1.36310
⫺25.4
176.1
48
i aq; s alc, eth
1.504820
⫺43.9
169
48
s alc, bz, eth
0.863720
4
1.499420
⫺44.7
165
44
misc alc, bz, eth
91, 429
1.261
1.521420
38–40
19412mm
⬎110
100.20
116.20
12, 121
12, 447
0.690120
4
0.838025
4
1.389020
1.423322
⫺24.9
15–17
80.9
130.5
⫺6
126.24
5, 42
0.786
1.433020
141–143
18
138.2
7, 65
0.918
1.472020
⫺8.1
215
80
152.19
74, 2032
1.491020
26–28
9411mm
96
149
⬎110
135.21
153.27
12, 1160
0.963
0.902
1.551020
1.471620
C6H3(CH3)3
120.20
5, 399
0.894420
4
1.513920
C6H3(CH3)3
120.20
5, 400
0.875620
4
C6H3(CH3)3
120.20
5, 406
C6H3(CO2CH3)3
252.22
(CH3)2CHC(CH3)3
(CH3)3CC(CH3)2OH
C6H9(CH3)3
t363
t364
t365
t366
t367
t368
t369
210.28
142.16
3
19 , 1604
238.42
1.012
1.462020
1.088
20
1.4620
12–13
67
86
0.896
1.482020
13
21550mm
⬎110
682.4mm
46
210.37
(CH3)3CCH2CH(CH3)CH2CHO
142.24
2mm
s alc, eth
misc alc, eth
1.2 aq
65–58
13, 2894
0.817
1.421520
INTERACTIVE
t370
OCNCH2CH2C(CH3)CH2C(CH3)CH2CNO
41 aq; misc alc; s bz,
chl, eth
ROTATED
(CH3)3C6H2NH2
t361
t362
59.11
LEFT
2,4,6-Trimethylaniline
1,3,3-Trimethyl-6-azabicyclo[3.2.1]octane
1,2,3-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Trimethyl 1,2,4benzenetri-carboxylate
2,2,3-Trimethylbutane
2,3,3-Trimethyl-2butanol
1,2,4-Trimethylcyclohexane
3,5,5-Trimethylcyclohex-2-ene-1-one
2,6,6-Trimethyl-2cyclohexene-1,4dione
Trimethyl-1,6-diisocyanatohexane
2,2,6-Trimethyl-4H1,3-dioxin-4-one
4,4⬘-Trimethylenebis(1-methylpiperidine)
4,4⬘-Trimethylenedipiperidine
3,5,5-Trimethylhexanal
t360
1.334
96
75
t355
t356
t359
Solubility in 100
parts solvent
233
194
(CH3)3N
t358
Flash
point,⬚C
⫺7
Trimethylamine
⫺117
Boiling
point,⬚C
2.9
t354
t357
Melting
point,⬚C
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
t372
t374
t375
3,5,5-Trimethylhexane
3,5,5-Trimethyl-1hexanol
3,5,5-Trimethylhexanoyl chloride
(CH3)2CHCH2CH(CH3)CH(CH3)2
(CH3)3CCH2CH(CH3)CH2CH2OH
(CH3)3CCH2CH(CH3)CH2COCl
Trimethylhydroquinone
1,3,3-Trimethyl-2norbornanol
(CH3)3C6H(OH)2
128.26
144.25
13, 1755
0.721820
0.823620
4
1.405120
1.430025
176.89
23, 834
0.930
1.436020
152.19
6, 931
154.25
6, 70
131
193–194
80
188–190
140
172–174
0.964120
4
3,5,5-Trimethylcyclohex-2-en-1-one, i93
1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid, c4
Trimethylene chlorobromine, b307
Trimethylene chlorohydrin, c231
Trimethylenediamine, p190
endo-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol, b245
2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene, p175
1,7,7-Trimethylbicyclo[2.2.1]hepten-2-one, c3
Trimethyl borate, t338
Trimethylchlorosilane, c266
␣,␣,4-Trimethyl-3-cyclohexene-1-methanol, t13
⫺128
⬍ ⫺70
s alc, eth
s aq; v s alc, bz, eth
39–45
201
73
s alc, eth
DEAN 37261 (McGHP)
t370a
t371
Trimethylene dibromide, d121
Trimethylene dimercaptan, p195
Trimethylene glycol, p192
Trimethylethylene, m166
Trimethylgermanium bromide, b437
1.335
t364
t365
t367
RIGHT
t356
ROTATED
t368
t369
t375
INTERACTIVE
No.
t376
t377
t378
t379
t380
t381
t382
t383
1.336
t384
t385
t386
t387
t388
t391
t393
t394
Beilstein
reference
Density,
g/mL
Refractive
index
152.24
7, 96
0.94818
1.463518
120.15
106.12
22, 128
2, 19
0.942825
4
0.967620
4
113.16
(CH3)3CCH(CH3)CH2CH3
(CH3)2CHCH2C(CH3)3
(CH3)2CH[CH(CH3)]2CHCH3
(CH3)2CHCH(OH)C(CH3)2CH2OH
114.23
114.23
114.23
146.22
11,
12,
13,
13,
(CH3)3CCH2C(CH3)"CH2
112.22
13, 849
(CH3)3C6H2OH
(CH3)3C6H2OH
(CH3)3C6H2OH
(CH3)3C6H(NH2)2
136.19
136.19
136.19
152.23
6, 518
6, 518
131, 190
(CH3O)3P(O)
(CH3O)3P
140.08
124.08
1, 286
1, 285
Trimethyl phosphonoacetate
1,2,4-Trimethylpiperazine
2,4,6-Trimethylpyridine
(CH3O)2P(O)CH2CO2CH3
C5H2N(CH3)3
121.18
N-(Trimethylsilyl)acetamide
Trimethylsilyl acetate
N-(Trimethylsilyl)imidazole
CH3CONHSi(CH3)3
131.25
CH3CO2Si(CH3)3
132.24
140.26
62
127
500
2225
Melting
point,⬚C
5
Boiling
point,⬚C
Flash
point,⬚C
192–194
52
v s alc, eth
1.385925
1.379020
107–109
100.6
16
15
v s alc, eth
0.887
1.421320
112–113
12
0.716020
4
0.691920
4
0.719020
4
0.92855
15
1.403020
1.391520
1.404220
1.451315
⫺112.3
⫺107.4
⫺109.2
52–56
110
99.2
113–114
232
⬍21
⫺12
5
113
0.715020
4
1.411220
⫺93
101–102
⫺6
92–95
62–64
71–74
88–91
230–231
⫺46
⫺78
197
111–112
107
27
1180.85mm
⬎110
1.396720
1.408020
182.11
1.125
1.437020
128.22
0.85125
25
1.448025
⫺50
151746mm
25
⫺46
171
57
46–49
186
57
⫺32
108
9414mm
4
5
43, 1857
22
4
0.9166
0.882
0.956
1.4959
1.388020
1.475120
s eth; sl s alc
s bz, chl, eth
s alc, org solv
1.8 aq; 75 alc; 22 bz;
25 acet
220
1.19720
1.04620
4
20, 250
Solubility in 100
parts solvent
100 aq; s alc
dec aq; misc alc, acet,
bz, PE
s aq, alc, acet, bz
3.5 aq; misc eth; s alc,
bz, chl
INTERACTIVE
t395
t396
CH3C(OCH3)3
HC(OCH3)3
Formula
weight
ROTATED
t392
1,3,3-Trimethyl-2norbornanone
Trimethyl orthoacetate
Trimethyl
orthoformate
2,4,4-Trimethyl-2oxazoline
2,2,3-Trimethylpentane
2,2,4-Trimethylpentane
2,3,4-Trimethylpentane
2,2,4-Trimethyl-1,3pentanediol
2,4,4-Trimethyl-1pentene
2,3,5-Trimethylphenol
2,3,6-Trimethylphenol
2,4,6-Trimethylphenol
2,4,6-Trimethyl-1,3phenylenediamine
Trimethyl phosphate
Trimethyl phosphite
Formula
LEFT
t389
t390
Name
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
158.28
0.890
1.415020
5120mm
32
CF3SO3Si(CH3)3
222.26
1.228
1.360020
7780mm
25
[(CH3)3S]I
204.07
[(CH3)3S(O)]I
220.07
t405
t406
t407
t398
t399
t400
t400a
215–220
sublime
169 dec
1.337
136.24
5, 164
0.866880
1.429680
(CH3)3SiCH"CH2
(O2N)3C6H2NH2
C6H3(NO2)3
C6H3(NO2)3
100.24
228.12
213.11
213.11
0.649
1.76214
1.7316
1.68820
4
1.392020
12, 763
5, 271
5, 271
2,4,6-Trinitrotoluene
(O2N)3C6H2CH3
227.13
5, 347
1.65420
4
Trioctylamine
1,3,5-Trioxane
[(CH3(CH2)7]3N
353.68
90.08
4, 196
19, 381
0.809
1.17065
67.5
152.5
188–190
61–62
122.5
55
explodes
explodes
explodes
80.1
explodes
60.2
365–367
115
1.448520
Trimethylsilyl cyanide, c331
(N-Trimethyl)silyldiethylamine, d404
(N-Trimethyl)silyldimethylamine, d726
Trimethylsilyl iodide, i56
⬍ ⫺34
s hot acet; sl s alc
5.5 alc; 7.1 eth; i aq
0.035 aq; 1.9 alc; 1.5
eth; 6.2 bz
1.5 alc; 4 eth; s bz,
acet; 0.01 aq
⬎110
45
17.2 aq18; v s alc, bz,
eth, EtOAc
Trimethylsilylnitrile, c331
2,4,6-Trinitrophenol, p174
Triolein, g23
RIGHT
Trimethylolpropane, e183
Trimethylolpropane triacrylate, e114
Trimethylolpropane trimethacrylate, e185
1,3,3-Trimethyl-2-oxabicyclo[2.2.2]octane, c277
DEAN 37261 (McGHP)
H2C"C(CH3)CO2Si(CH3)3
t401
t402
t403
t404
Trimethylsilyl
methacrylate
Trimethylsilyl trifluoromethane sulfonate
Trimethylsulfonium
iodide
Trimethylsulfoxonium
iodide
1,7,7-Trimethyltricyclo[2.2.1.O2,6]heptane
Trimethylvinylsilane
2,4,6-Trinitroaniline
1,2,4-Trinitrobenzene
1,3,5-Trinitrobenzene
t397
ROTATED
t376
t379
t392
t396
t400a
t407
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
t408
Name
Formula
Formula
weight
Beilstein
reference
1.338
t409
4,7,10-Trioxa-1,13tridecanediamine
Tripentaerythritol
t410
t411
t412
t413
t414
t415
Triphenylamine
Triphenylantimony
Triphenylarsine
1,3,5-Triphenylbenzene
Triphenylborane
Triphenylmethane
t416
t417
(C6H5)3COH
(C6H5)3CBr
260.34
323.24
6, 713
5, 704
(C6H5)3CCl
278.78
t419
Triphenylmethanol
Triphenylmethyl
bromide
Triphenylmethyl
chloride
Triphenyl phosphate
(C6H5O)3P(O)
t420
Triphenylphosphine
t421
Triphenylphosphine
oxide
Triphenyl phosphite
Triphenylsilane
Triphenyltin acetate
Triphenyltin chloride
Triphenyltin hydroxide
Tripropoxyborane
Tripropylaluminum
Tripropylamine
Tripropylene glycol
t418
Refractive
index
1.005
1.464020
O[CH2CH2O(CH2)3NH2]2
220.31
(HOCH2)3CCH2OCH2C(CH2OH)2CH2OCH2C(CH2OH)3
(C6H5)3N
(C6H5)3Sb
(C6H5)3As
(C6H5)3C6H3
(C6H5)3B
(C6H5)3CH
372.41
245.33
353.07
306.24
306.41
242.13
244.34
12, 181
16, 891
16, 828
5, 737
162, 636
5, 698
0.77400
1.434325
1.222548
1.205
1.19904
Melting
point,⬚C
Boiling
point,⬚C
1484mm
Flash
point,⬚C
Solubility in 100
parts solvent
⬎110
225 dec
125–127
52–54
60–62
172–174
145
92–94
347–348
377
23314mm
460
20315mm
360
160–163
152–154
360
23015mm
5, 700
110–112
23520mm
326.29
6, 179
50–52
24410mm
223
(C6H5)3P
262.29
16, 759
79–81
377
181
(C6H5)3P(O)
278.29
16, 783
(C6H5O)3P
(C6H5)3SiH
CH3CO2Sn(C6H5)3
(C6H5)3SnCl
(C6H5)3SnOH
(CH3CH2CH2O)3B
(CH3CH2CH2)3Al
(CH3CH2CH2)3N
H(OCH2CH2CH2)3OH
310.29
260.41
409.06
385.46
367.02
188.08
156.25
143.27
192.26
6, 177
162, 605
164, 1606
16, 914
16, 914
12, 369
4, 643
4, 139
360
1522mm
218
76
1.613948
1.013499
4
1.07581
4
⬎110
v s bz, eth; sl s alc
v s bz, eth; s alc
v s bz; s abs alc, eth
v s hot alc, eth; 49 chl;
7 bz; s PE
v s alc, bz, eth; i aq
misc alc; s bz, acet,
chl, eth; i aq
v s eth; s bz, chl,
HOAc; sl s alc; i aq
LEFT
156–158
1.184
22–24
42–44
124–126
108 dec
124–126
1.394820
1.416020
1.44225
⫺107
⫺93.5
s alc, bz, chl, eth
s eth; sl s alc, bz
24013.5mm
175–177
842mm
155–158
273
32
⫺18
36
141
v s alc; misc eth
s aq, alc, eth
s aq
INTERACTIVE
0.857620
4
0.823
0.753
1.021
1.590320
ROTATED
t422
t423
t424
t425
t426
t427
t428
t429
t430
4,4, 1625
Density,
g/mL
t432
t433
t434
t435
t436
t437
t438
t439
t440
1.339
t441
t442
t443
t444
t446
248.4
HO(CH2CH2CH2O)3CH3
206.29
14, 2475
2, 21
4, 256
0.932
1.43020
0.967
1.42825
20
4
⫺42
20
276
135
242.4
127
40mm
misc aq, alc, eth
HC(OCH2CH2CH3)3
(H2NCH2CH2)3N
190.28
146.24
(C4H9OCH2CH2O)3P(O)
398.48
(ClCH2CH2O)3P(O)
285.49
(ClCH2CH2O)3P
269.49
[C4H9CH(C2H5)CH2O]3P(O)
434.65
13, 1734
(HOCH2)3CNH2
121.14
4, 303
171–172
CH3C(CH2OH)3
120.15
1, 520
200–203
(HOCH2)3CNHCH2CO2H
179.17
Merck:
12, 9783
187
satd aq0 is 0.8M
(HOCH2)3CNO2
151.12
1, 520
214 pure
175 tech
220 aq; v s alc; sl s bz
(CH3OCH2CH2OCH2CH2)3N
323.43
H2C"CHSi(OCH2CH2 9OCH3)3
280.39
(CH3OCH2CH2O)3B
[H2C"C(CH3)CH2]3N
12, 337
0.8805
0.977
1.4072
1.497020
108
11415mm
72
⬎110
1.006
1.435920
2284mm
110
1.390
1.472120
330
232
1.35320
4
1.486320
1152mm
190
misc alc, bz, eth
0.924
1.443720
2154mm
⬎110
i aq
22010mm
⬎110
1.011
1.448620
44, 4257
1.03425
4
1.42725
284–286
⬎110
236.08
13, 2118
1.010
1.415020
13515mm
87
179.31
43, 462
0.794
1.457520
8515mm
53
Triphenyltin chloride, c267
Tripropyl borate, t427
TRIS, t439
Tris(dimethylamino)phosphine oxide, h50
Tris(dimethylamino)silyl chloride, c268a
Tris(3,5-dioxaheptyl)amine, t443
Tris(7-methylnonyl) phosphite, t324
Tris(2-methylphenyl) phosphate, t452
ROTATED
Trioxymethylene, t407
Tripalmitin, g24
Triphenylmethyl bromide, b440
Triphenyl azide, a310
HO(CH2CH2CH2O)3(CH2)3CH3
RIGHT
t445
Tripropylene glycol
butyl ether
Tripropylene glycol
monomethyl ether
Tripropyl orthoformate
Tris(2-aminoethyl)amine
Tris(2-butoxyethyl)
phosphate
Tris(2-chloroethyl)
phosphate
Tris(2-chloroethyl)
phosphite
Tris(2-ethylhexyl)
phosphate
Tris(hydroxymethyl)aminomethane
1,1,1-Tris(hydroxymethyl)ethane
N-[Tris(hydroxymethyl)methyl]glycine
Tris(hydroxymethyl)nitromethane
Tris[2-(2-methoxyethoxy)ethyl]amine
Tris(2-methoxyethoxy)vinylsilane
Tris(2-methoxyethyl)
borate
Tris(2-methylallyl)amine
DEAN 37261 (McGHP)
t431
INTERACTIVE
No.
t447
t448
Name
Formula
Tris(2,2,2-trifluoroethyl) phosphite
Tris[3-(trimethoxysilyl)propyl]
isocyanurate
Tris(trimethylsilyl)
borate
1,3,5-Trithiane
Trithiocarbonic acid
Tri-o-tolyl phosphate
(CF3CH2O)3P
Formula
weight
328.07
Beilstein
reference
14, 1371
615.86
Density,
g/mL
Refractive
index
1.487
1.324520
131743mm
⬎110
1.170
1.461020
250
102
186
42
0.831
1.386120
(HS)2CS
(CH3C6H4O)3P(O)
138.27
110.21
368.37
19, 382
3, 221
Merck:
12, 9893
1.48320
4
1.195520
1.822520
1.557520
(H2C"CH)3C6H9
162.28
0.836
1.478020
t454
1,2,4-Trivinylcyclohexane
L-(⫺)-Tryptophan
t455
L-Tyrosine
u1
u2
u3
u4
u5
u6
u7
u8
u9
u10
u11
u12
u12a
u13
u14
t450
t451
t452
t453
216–218
⫺26.9
11
1.340
204.23
22, 546
(HO)C6H4CH2CH(NH2)CO2H
181.19
14, 605
1.456
Undecanal
Undecane
Undecanenitrile
Undecanoic acid
Undecanoic ␥-lactone
Undecanoic ␦-lactone
1-Undecanol
2-Undecanol
2-Undecanone
CH3(CH2)9CHO
CH3(CH2)9CH3
CH3(CH2)9CN
CH3(CH2)9CO2H
1, 712
1, 170
2, 358
2, 358
17, 247
173, 4257
1, 427
1, 427
1, 173
0.825
0.740220
4
0.823
0.8907
0.949
0.969
0.8324
0.828
0.829
1.432220
1.417320
1.433020
1.429445
1.450020
1.459020
1.440220
1.437020
1.430020
⫺4
⫺25.6
CH3(CH2)10OH
CH3(CH2)8CH(OH)CH3
CH3(CH2)8COCH3
170.30
156.31
167.30
186.30
184.28
184.28
172.31
172.31
170.30
3-Undecanone
6-Undecanone
10-Undecenal
1-Undecene
10-Undecenoic acid
10-Undecen-1-ol
CH3(CH2)7COCH2CH3
CH3(CH2)4CO(CH2)4CH3
H2C"CH(CH2)8CHO
H2C"CH(CH2)8CH3
H2C"CH(CH2)8CO2H
H2C"CH(CH2)9OH
170.30
170.30
168.28
154.30
184.28
170.30
1, 713
1, 174
1,3, 3029
1, 225
2, 458
1, 452
0.827
0.831
0.810
0.750320
0.90724
4
0.85015
1.429120
1.428020
1.442720
1.426120
1.449320
1.450020
57.8
410
225
8820mm
68
280–285
dec
342–344
11
2–3
11–13
1155mm
196
253
228160mm
16613mm
15510.5mm
242.8
13128mm
231–232
96
60
⬎110
⬎110
⬎110
⬎110
⬎110
88
88 (CC)
12–13
14.6
225–229
228
⫺49
24.5
⫺2
193
1372mm
245
89
88
92
71
148
93
28.5
Solubility in 100
parts solvent
s bz; sl s alc, eth
dec aq, alc; sl s eth
sl s aq, alc; s eth
1.14 aq25; s hot alc,
alk; i eth, chl
0.045 aq; 0.01 alc; s
alk; i eth
i aq; s alc, eth
i aq; misc alc, eth
s alc, chl, eth; i aq
s alc, bz, chl, eth, acet;
i aq
i aq; v s alc, eth
s alc, chl, eth; i aq
INTERACTIVE
43, 1861
Flash
point,⬚C
ROTATED
278.38
Boiling
point,⬚C
LEFT
[(CH3)3SiO]3B
t449
Melting
point,⬚C
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
u16
u17
u18
10-Undecenoyl
chloride
Urea
Uric acid
Uridine
H2C"CH(CH2)8COCl
202.73
2, 459
0.944
(H2N)2CO
60.06
168.11
244.20
3, 42
26, 513
31, 23
1.335
1.89320
Trityl alcohol, t416
Triptamine, a170
Tyramine, a173
Umbelliferone, h111
1.454020
12210mm
133–135
⬎300 dec
166–167
Undecyl alcohol, u7
Undecylenic aldehyde, u12
Undecyl-10-en-1-oic acid, u13
Undecylic aldehyde, u1
dec ⬎mp
93
100 aq; 20 alc
s alk; i aq, alc, eth
s aq; hot alc, pyr
Undecyl iodide, i57
Uracil, p278
4-Ureidohydantoin, a71
Urethane, e102
DEAN 37261 (McGHP)
u15
1.341
CH3(CH2)3CH2
t448
t450
t454
O
O
u5
RIGHT
ROTATED
CH3(CH2)4CH3
u6
O
O
u17
u18
INTERACTIVE
DEAN 37261 (McGHP)
TABLE 1.15 Physical Constants of Organic Compounds (Continued)
No.
1.342
D-(⫹)-Xylose
m-Xylylenediamine
(CH3)2CHCH(NH)CO2H
H2C"CHO2CCH3
C6H5CO2CH"CH2
H2C"CHC6H4CH2Cl
C6H11CH"CH2
HCONHCH"CH2
CH3CH2CO2CH"CH2
(C5H4N)CH"CH2
(C5H4N)CH"CH2
H2C"CHSi(OCH3)3
186.25
100.12
100.12
117.15
86.09
148.16
152.62
110.20
108.18
100.12
71.08
94.12
120.20
100.12
105.14
105.14
111.14
Beilstein
reference
2, 301
17, 235
17, 235
4, 427
21, 63
91, 65
51, 35
51, 63
234, 569
23, 532
20, 256
202, 170
Density,
g/mL
Refractive
index
0.942
1.057
1.079
1.230
0.93220
4
1.070
1.083
0.805
0.80320
4
1.001
1.014
1.039
0.841
0.919
0.975
0.975
1.040
1.421020
1.433020
1.458020
1.395420
1.529020
1.574020
1.446320
1.464020
1.430020
1.494020
1.530820
1.480220
1.403020
1.549020
1.550020
1.512020
0.968
1.392020
148.24
182.22
226.23
17, 73
182, 279
C6H4(CH3)2
C6H4(CH3)2
C6H4(CH3)2
HOCH2(CHOH)3CH2OH
196.21
106.17
106.17
106.17
152.15
17, 354
5, 370
5, 362
5, 382
1, 531
0.864220
0.880820
4
0.861120
4
1.52
C6H4(CH2NH2)2
150.13
136.20
31, 47
13, 186
1.5350
1.032
Melting
point,⬚C
⫺57
⫺31
⬎315 subl
⫺93
⫺101
⫺16
⫺80
⫺80
101
217 dec
1.497220
1.505420
1.495820
1.570920
174–176
⫺47.9
⫺25.2
13
95–97
156–158
⬎110
Boiling
point,⬚C
Flash
point,⬚C
11216mm
207–208
600.5mm
101
81
100
72–73
9620mm
229
126–127
127
115–116
210
7913mm
141
94–95
158–159
6515mm
9313mm
⫺8
82
104
20
20
14
102
81
27
6
46
51
93
123
310–312
22
350730mm
139
144–145
138
Solubility in 100
parts solvent
8.8 aq; v sl s alc, eth
2 aq; misc alc, eth
v s alc, chl, eth
sl s hot aq, hot alc
s bz, eth; sl s alc, aq
s hot alc, eth
27
32
27
0.5 alc; v s chl
misc alc, eth; 0.02 aq
misc alc, eth; 0.017 aq
v s eth; s alc; 0.02 aq
64 aq; 1.2 EtOH; 6.0
MeOH
117 aq; s hot alc, pyr
INTERACTIVE
x8
x9
v18
x1
x2
[CH3(CH2)3CO]2O
Formula
weight
ROTATED
x3
x4
x5
x6
x7
Valeric anhydride
␥-Valerolactone
␦-Valerolactone
L-Valine
Vinyl acetate
Vinyl benzoate
4-Vinylbenzyl chloride
Vinylcyclohexane
4-Vinyl-1-cyclohexene
2-Vinyl-1,3-dioxolane
N-Vinylformamide
1-Vinylimidazole
5-Vinyl-2-norbornene
Vinyl propionate
2-Vinylpyridine
4-Vinylpyridine
N-Vinyl-2pyrrolidinone
Vinyltrimethoxysilane
Xanthene
Xanthen-9-carboxylic
acid
9-Xanthenone
m-Xylene
o-Xylene
p-Xylene
Xylitol
Formula
LEFT
v1
v2
v3
v4
v5
v6
v7
v8
v9
v10
v11
v12
v13
v14
v15
v16
v17
Name
1.343
v2
v9
x1
v10
x2
v12
x3
v13
x8
RIGHT
v17
v3
Vitamin B1, t135
Vitamin B2, r8
Vitamin C, a302
Xanthone, x3
Xylene-␣,␣⬘-diol, b18
Xylenols, d659 thru d664
Xylidenes, d554 thru d559
o-Xylyl bromide, b443
Xylyl chlorides, c271 thru c273
p-Xylylene glycol, b19
DEAN 37261 (McGHP)
Vinylacetic acid, b485
Vinylbenzene, s11
Vinyl bromide, b336
Vinyl butyl ether, b609
Vinyl chloride, c129
Vinyl cyanide, a63
Vinylethylene, b449
Vinylidene chloride, d227
Vinyltrimethylsilane, t401
Vinyltris(2-methoxyethoxy)silane, t444
Valeraldehyde, p28
Valeric acid, p38
Valeronitrile, p35
Valeryl chloride, p45
Vanillic acid, h143
Vanillin, h142
Vanillyl alcohol, h145
Veratraldehyde, d492
Veratric acid, d496
Veratrole, d493
Veronal, d330
ROTATED
INTERACTIVE
DEAN #37261
(McGHP)
LEFT
BLANK