Advanced Materials Research ISSN: 1662-8985, Vol. 331, pp 310-313 doi:10.4028/www.scientific.net/AMR.331.310 © 2011 Trans Tech Publications, Switzerland Online: 2011-09-02 Research of wool-like modification of polyester with Sodium alginate Min Liu1,a, Junying Tian2,Meiyan Liu2 1 Chifeng Institute of Industry Technology , Chifeng, 024000,China 2 Textile institute, Tianjin Polytechnic University, Tianjin, 300160, China a [email protected] Key Words: Sodium alginate, Alkali deweighting, Polyester, Wool-like Abstract. This paper mainly discusses the influence of sodium alginate to polyester fabric in the process of wool-like. Polyester is pre-treated by sodium alginate solution firstly, and then modified by caustic soda, at last, the sample is steamed in the saturated vapor. Wool-like effect changes along with the concentration of sodium alginate and caustic soda, steaming time are analyzed. The results show that wettability, warmth retention and fullness of wool-like fabric are improved obviously. So treated with sodium alginate and then caustic soda can give polyester fabric ideal wool-like effect. Introduction Wool fabric has been favored by people because of it’s comfortable handle and excellent elasticity. But wool raw materials can not meet the demand of textile industry, wool fiber production is influenced by many factors such as geographic conditions. However, development of synthetic fiber industry provides opportunities for wool-like products. Polyester is impregnated into sodium alginate paste, slapped with glass rod to make sodium alginate paste distribute unevenly,and then treated with caustic soda solution, steamed with saturated steam. The purpose is to form uneven groove on the surface of polyester fiber, to imitate scale structure of wool fiber. On the other hand, sodium alginate is a polymer with high hydrophilic, polyester fabric can feel smooth, soft, warmth to achieve wool-like effect when treated by sodium alginate。 Materials and test Polyester plain fabric. Sodium alginate produced by Shanghai cognis chemical Co., LTD Warmth retention test Warmth retention is tested according to GB/T11048-89《Testing method for warmth retention property》with ASTM plate-type fabric warm apparatus. Fabric style test KES-FB is used to test wool-like and common polyester fabric. Fabric size is 150mm×150mm,the same specimen test 3 times the average check, to achieve WOMEN’S THIN KN-201-MDY fullness. All rights reserved. No part of contents of this paper may be reproduced or transmitted in any form or by any means without the written permission of Trans Tech Publications, www.ttp.net. (ID: 130.203.136.75, Pennsylvania State University, University Park, USA-12/05/16,18:05:40) Advanced Materials Research Vol. 331 311 Results and Discussion The relation of warmth retention, full sensitivity of wool-like fabric to the concentration of Sodium alginate Fig.1 The relation of warmth retention of fabric to the concentration of sadium alginate Fig.2 The relation of fullness to the concentration of sadium alginate The warmth retention of fabric related to air content in fabric, the looser the fabric is, the better the warmth retention is. The fiber surface became more coarser after treated with sodium alginate and caustic soda,the compactness of yarns reduced, air content in fabric increased,so the warmth retention increased also. The fullness sensitivity of fabric improved when the concentration of sodium alginate increases. The results show that sodium alginate pretreatment can influence fabric surface coarse and fullness. Fabric fullness gets maximum value when the concentration of sodium alginate is 2g/L. The relation of warmth retention, full sensitivity of wool-like fabric to the concentration of caustic soda Fig.3 The relation of warmth retention to the concentration of caustic soda Fig.4The relation of fullness to the concentration of caustic soda Fig.3 and Fig.4 show that warmth and full sensitivity of wool-like fabric improved as the concentration of caustic soda go up, because there are more groove on the surface of fiber, fabric became more loose and contain more air. Warmth retention achieves the maximum value when the concentration of caustic soda get 15g/L. 312 Advances in Textile Engineering The relation of warmth retention, full sensitivity of wool-like fabric to the steaming time Fig5. The relation of warmth to steaming time Fig5. The relation of warmth to steaming time Fig5. The relation of warmth to steaming time Fig6. The relation of fullness to steaming time Fig5 shows that warmth retention of wool-like fabric increased as the steaming time prolong,if steaming time exceeds 3min, warmth retention will remain constant. Fig6 shows that the influence of steaming time on fullness sensitivity of wool-like fabric is insignificant. Steaming time can determined as 3min. Wrinkle recovery angle, stiffness, drape and smooth sensitivity of wool-like polyester fabric Tab.1 compared wrinkle recovery angle, stiffness, drape and smooth sensitivity of treated polyester with common polyester fabric. Data in tab.1 show that wool-like process make wrinkle recovery angle, drape and smooth degree of polyester fabric increase, and stiffness decrease, so wrinkle resistance, drape improved and fabric feels soft and smooth. Tab.1 Performance of wool-like and common polyester fabric Wrinkle recovery angle(°) Stiffness Smooth Fabric Drape warp filling Polyester fabric 144 140.2 5.89 3.62 4.05 Wool-like fabric 153.7 144.5 5.31 5.43 4.18 Advanced Materials Research Vol. 331 313 Color fastness and K/S Fabric Polyester fabric Wool-like fabric Tab.2 Color fastness and K/S Crocking color fastness Water washing Staining Dry Wet Fade cotton Polyester 4~5 4~5 4~5 4~5 4~5 5 5 4~5 4~5 4~5 K/S 20.81 17.78 Compare to common polyester fabric, K/S of wool-like fabric decreased obviously dyeing under the same conditions. The reason of apparent color of wool-like fabric being pale is larger surface area of wool-like fabric, when incident light irradiates wool-like fabric, diffuse reflection light escalates and K/S reduces. Color fastness in tab.2 shows that color fastness to crocking of wool-like fabric is superior to common polyester fabric, because fiber surface of wool-like fabric are found to exist many small grooves, fabric surface area is increased. it is beneficial for dyes adsorbing onto fibers and diffusing into fibers,so color fastness to crocking of wool-like fabric improved. Conclusions By a series of experiments, optimal process conditions are sodium alginate concentration 12g/L, NaOH concentration 15g/L,steaming time7min. Common polyester fabric treated under above conditions can achieves superior performance include hydrophilic, warmth retention, full sensitivity and so on. Dyeing properties of wool-like fabric improved also. References [1] Lawrence E.Blackmon,Foley,Ala,John R.Dee,Wayne T.METHOD FOR PRODUCING [2] Xianghong Zhou. Production technology of polyester wool-like fabric[J].Shanghai textile science and technology,1993 (2 :50—53. [3] HOWARD L, NEEDLES, DAVID B. BROOK, JOHN H, KEIGHLEY. How Alkali Treatments Affect Selected Properties Of Polyester, Cotton and Polyester/Cotton Fabrics. Treated vs. Nontreated,1985,17(9):23~26 [4] Zhiping Shen,Liangxia He. alkali reduction processing of polyester woven. China Textile Leader.2009,(1):77~80 [5] Matsudaira Mitsuo,Matsui Masao,Changes in the Mechanical Properties and Fabric Handle of Polyester-fibre Fabrics Through the Finishing Stages[J],Journal of the Textile Institute,1992,83(1):144-155 [6] Sheth Geeta N., Musale Aparna A.,Changes in Characteristics of Polyester and Polyester/Cotton Blended Fabrics during Weight Reduction[J], AATCC Review, 2005,5(10):39-43 Advances in Textile Engineering 10.4028/www.scientific.net/AMR.331 Research of Wool-Like Modification of Polyester with Sodium Alginate 10.4028/www.scientific.net/AMR.331.310 DOI References [5] Matsudaira Mitsuo, Matsui Masao, Changes in the Mechanical Properties and Fabric Handle of Polyesterfibre Fabrics Through the Finishing Stages[J], Journal of the Textile Institute, 1992, 83(1): 144-155. 10.1080/00405009208631184
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