9/30/2012 Subatomic Particles Atomic Structure Timeline ATOM NUCLEUS NUCLEUS ELECTRONS ELECTRONS PROTONS PROTONS NEUTRONS NEUTRONS POSITIVE POSITIVE CHARGE NEUTRAL CHARGE NEGATIVE CHARGE NEGATIVE CHARGE QUARKS John Dalton (1807) John Dalton Dalton’s Four Postulates • British Schoolteacher – based his theory on others’ experimental data • Billiard Ball Model – atom is a uniform, solid sphere J. J. Thomson (1903) • Cathode Ray Tube Experiments – beam of negative particles • Discovered Electrons – negative particles within the atom • Plum-pudding Model 1. Elements are composed of small indivisible particles called atoms. 2. Atoms of the same element are identical. Atoms of different elements are different. 3. Atoms of different elements combine together in simple proportions to create a compound. 4. In a chemical reaction, atoms are rearranged, but not changed. J. J. Thomson (1903) Plum-pudding Model – positive sphere (pudding) with negative electrons (plums) dispersed throughout 1 9/30/2012 Ernest Rutherford (1911) Ernest Rutherford (1911) • Gold Foil Experiment • Discovered the nucleus – dense, positive charge in the center of the atom • Nuclear Model • Nuclear Model – dense, positive nucleus surrounded by negative electrons James Chadwick (1932) James Chadwick (1932) • Discovered neutrons – neutral particles in the nucleus of an atom Neutron Model • revision of Rutherford’s Nuclear Model Niels Bohr (1913) • Bright-Line Spectrum Electrons in Atoms – tried to explain presence of specific colors in hydrogen’s spectrum • Energy Levels – electrons can only exist in specific energy states • Planetary Model 2 9/30/2012 Niels Bohr (1913) Bright-line spectrum • Planetary Model Erwin Schrödinger (1926) • Quantum mechanics – electrons can only exist in specified energy states • Electron cloud model – orbital: region around the nucleus where e- are likely to be found – electrons move in circular orbits within specific energy levels Erwin Schrödinger (1926) Quantum Mechanics Electron Cloud Model (orbital) • dots represent probability of finding an enot actual electrons Quantum Theory Quantum Theory • Planck (1900) – Observed - emission of light from hot objects – Concluded - energy is emitted in small, specific amounts (quanta) • Einstein (1905) – Photon - particle of light that carries a quantum of energy – Quantum - minimum amount of energy change 3 9/30/2012 Bohr Model • e- exist only in orbits with specific amounts of energy called energy levels • Therefore… – e- can only gain or lose certain amounts of energy – only certain photons are produced Energy Levels • Electrons can only exist at certain energy levels. • Low energy levels are close to the nucleus. • Each energy level can hold only a certain amount of electrons. Bohr Model 65 4 • Energy of photon depends on the difference in energy levels 3 2 1 Waves • Wavelength () - length of one complete wave • Frequency () - # of waves that pass a point during a certain time period – hertz (Hz) Waves H I G H L O W crest A EM Spectrum origin A trough E N E R G Y red R O Y G. orange green yellow B blue I indigo V violet E N E R G Y 4 9/30/2012 Planck’s constant • Velocity of a Wave= frequency x wavelength • E = fh – Where, – E= energy – f= frequency – h= 6.63 x 10-34 • V= f λ • Speed of light= 3 x 108 m/s 5
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