Projektinfo 05/2011 Detailed information on energy research Comparison of electricity production from fossil fuels Consistent and realistic simulation models for modern power plant processes with coal and gas If industrial production requires electricity on a windless winter morning, solar energy systems and wind turbines reach their limits. Then, power plants which can convert fossil fuels into electricity no matter what the time, provide the electricity quantities required. Power plant technologies are under development for coal and gas, which can generate electricity more efficient and with lower emissions than previously. A realistic comparison of the efficiencies of modern power plant processes helps in decisions on the role of coal and gas in the future energy mix. 60 percent of electricity worldwide is generated by burning coal, natural gas and mineral oil. Fossil power plant technology will remain extremely important for the power supply in the decades to come. Decreasing the carbon dioxide emissions to the atmosphere as a result of this process is the aim of climate protection and is intended to restrict global warming. The German research programme into CO2 reduction technologies (abbreviation: COORETEC) can contribute to effectively reducing emissions. For more efficient power plants and separation of most of the CO2 using CCS technology, a variety of development options for power plant processes are available. CCS is the abbreviation for “Carbon Capture and Storage“. This process ensures that less than 100 g/kWh of CO2 is released when converting coal into electricity. This research project is funded by the: Federal Ministry of Economics and Technology (BMWi) 2 BINE-Projektinfo 05/2011 Thus, the CO2 emissions are less than one third of those of natural gas-fired combined gas and steam turbine plants without CCS. The researchers at the Institute of Energy Systems at the Hamburg University of Technology (TUHH) have developed standards which permit an objective comparison of extremely diverse technologies. At the end of the day, when generating electricity cost effectively, efficiency and emissions are key parameters and must be determined objectively to make the right decisions. By comparing different power plant processes under uniform constraints, their efficiencies and potential CO2 avoidance can be evaluated with greater precision. Selection of the power plant processes Starting point was the current state of the art of power plants fired by fossil fuels, and the two strategic guidelines of the COORETEC concept by the German Federal Ministry of Economics and Technology. First, there are measures to increase efficiency, such as higher process temperatures and pressures when firing lignite and hard coal in steam power plants or natural gas in power plants which combine gas and steam turbines (Combined-Cyclepower plants). Second, technologies which burn coal while capturing most of the resulting CO2, to store it in subterranean repositories, where it cannot affect the climate, are currently under development. In the oxyfuel power plant version, coal is fired with pure oxygen, without the nitrogen otherwise present in combustion air, which causes high CO2 concentrations in the flue gas. Washing CO2 from the flue gases after conventional combustion is referred to as “Post Combustion Capture” (PCC or CO2 flue gas scrubbing). CO2 separation after gasification of coal traps carbon as CO2 before actual combustion, and is therefore a Pre-Combustion Capture process, which is based on the Integrated Gasification Combined Cycle (IGCC). The oxygen required for the oxyfuel technology is provided by breaking down the air via low temperature distillation in cryogenic air separation systems. Air separation processes based on high-temperature membranes were also considered as an alternative to this. More research is required into membrane oxygen separation than for the other separation processes investigated which should be available by 2020. In their project, the researchers from Harburg studied various versions of these air separation processes. The comparability problem As part of preparatory research for the comparison, which involved reviewing over 1,700 literature sources, it was found that most studies to date were performed with very different assumptions. While some studies were drawn up for Northern European ambient conditions, others assume higher ambient temperatures which are thermodynamically less favourable. Others make different assumptions on the efficiencies of comparable turbines, for example. Therefore, uniform assumptions and constraints had to be specified – in close cooperation with plant manufacturers and other research institutions. Fig. 1 provides a simplified insight into the variety of definitions used in modelling the overall process of a power plant. Using the same calculation procedurs for simulation, their selection influences the range and Constraints and balance limits Process topology Components & parameters Material values Simulation Result figures Fig. 1 Composition of the overall process model for power plants by hierarchical detail level. Source: TUHH Power plant processes and fuels studied (legend for Fig. 2 and Fig. 3) RL = raw lignite PDL = pre-dried liginite HC = Hard coal 600 = Steam power plant with 600 °C technology (state of the art) 700 = Steam power plant with 700 °C technology PCC = Post Combustion CO2 Capture (CO2 flue gas washing after combustion) OXYK = Oxyfuel power plant with cryogenic air separation system OXY4M = Oxyfuel power plant with high-temperature membrane air separation system in flue gas flushed 4-end process IGCC = Integrated Gasification Combined Cycle (coal gasification) NGCC = Combined-cycle power plant The models of all power plant processes with CO2 separation (CCS) are based on hard coal-fired steam power plants using 600° technology (except IGCC). r ealistic nature of the resulting figures. Equivalence of the assumed ambient air temperature and humidity are just as important as the fuel composition or the formula used to calculate the efficiency. For comparable studies of efficiency and specific CO2 emissions, the researchers at TUHH assumed the same gross output of 1,100 megawatts for all steam power plant processes and then defined them for uniform comparison via 72 parameters. 30 parameters had to be specified for gas turbines. Characteristic temperatures and pressures needed definition, as did various pressure losses and the auxiliary electricity demand of the individual components. This ranges from parameterisation of steam gen erators and turbines via pumps, blowers, compressors, electric drives and generators. For example, the specifications include details like the auxiliary power demand of the coal mills or the water content of the coal dust and included even the temperatures and pressure losses for oxygen provision via high temperature membranes. Once the researchers had specified the state of the art for coal-fired steam power plants in basic models with the corresponding parameters, they calculated the respective efficiencies and CO2 emissions through process simulation. This was followed by similar simulations for efficiency-increasing measures such as increasing the fresh steam parameters (pressure and temperature) and predrying lignite using steam fluidised bed drying which is heated by the compressed vapor originating form the coal moisture. The latest gas turbine developments for combined gas and steam turbine power plants were also simulated. Finally, the power plant processes featuring CO2 separation, subject of current debates, were investigated. For the studies the researchers modelled the power plant processes with a low degree of integration, as would likely be initially selected when imple- Stored Emitted Stored Emitted Quote of the project leader Spec. reduction Spec. reduction CO2 emissions CO2 emissions NGCC Natural gas 60 NGCC OXYK OXYK NGCC PCC PCC IGCC HC700 HC700 IGCC HC600 HC600 OXY4M OXY4M RL700 Net efficiency RL700 0 PDL600 PDL600 10 auxiliary power demand RL600 40 60 30 50 20 40 10 30 0 20 RL600 Electrical Electrical efficieny in efficieny % in % Fig. 2 Comparison of the specific CO2 quantities per kilowatt hour of CCS Natural studied. electric current generated for a selection of power plant processes gas Hard coal Source:Lignite TUHH auxiliary power demand Net efficiency 50 „In order to evaluate new power plant processes simulations must be performed due to the lack of practical experience. The results produced largely depend on the constraints and assumptions used. The main goal of the project was therefore to create the basis for a reliable and realistic comparison of various power plant processes via generally-applicable definition of identical constraints and assumptions. Starting with this basis, new power plant processes can be compared more objectively with one another in future.“ NGCC IGCC IGCC OXY4M OXY4M OXYK CCS Hard coal OXYK PCC PCC HC600 HC700 HC700 Lignite HC600 0 RL700 200 RL700 800 1.200 600 1.000 400 800 200 600 0 400 PDL600 PDL600 1.000 RL600 1.200 RL600 Specific CO Specific CO2in quantity g/kWh in g/kWh 2 quantity BINE-Projektinfo 05/2011 Fig. 3 Comparison of the heating value-specific efficiencies for a selection of the power plant processes studied. Source: TUHH menting the processes, with the result that no highly-optimised processes were examined. Moreover, when selecting the parameters for the process models, compromises had to be made between comparability and realism. Results provide an overview Figs. 2 and 3 show the results of the study for a selection of ten power plant processes. The researchers from TUHH have distinguished additional process versions. The above diagrams confirm the current knowledge on the efficiencies of the technologies studied. The electric efficiencies of natural gas-fired combined-cycle plants are approximately 15 percentage points above those of modern coal-fired power plants. If in turn the steam temperature is increased from 600 to 700 °C in a coal-fired power plant, the results of the simulations reveal with high precision that the efficiency rises up to approx. three percentage points. Fig. 2 compares the emitted CO2 mass per kilowatt hour (kWh) of net electricity generated. In processes with CO2 separation, the CO2 quantity to be stored is shown in a different colour. The difference marked as an example between the emissions of a hard-coal fired reference steam power process based on 600 °C technology and the selected CCS technology allows the specific reduction of CO2 emissions to be seen. This is equivalent to the effective decrease in atmospheric pollution if electricity is generated using CCS. In a direct comparison of electricity generation, this is approx. 670 g/kWh or roughly 88% in the example entered. At the same time, the additional CO2 quantity produced as a result of the decrease in efficiency (8% in the example) due to CO2 separation can also be seen (approx. 160 g/kWh in the example). The comparison of electric efficiencies in Fig. 3 clearly shows that all power Prof. Dr.-Ing. Alfons Kather is Head of the Institute of Energy Systems at the Hamburg University of Technology (TUHH) and spokesman for the COORETEC Initiative of the German Federal Ministry of Economics and Technology. plant processes with CO2 separation have significantly higher auxiliary electricity demands, when compared with the conventional electricity generation using fossil fuels. These and other losses of efficiency associated with CCS technology reduce the net efficiency by approx. 10 percentage points depending on the contrasted coalfired technologies. Comparison basis for future use The results of this project by TUHH can be used as a basis for the implementation of other simulation-based process studies in research projects pertaining to power plant technology. This would improve the comparability of the various power plant processes in future. The approach developed by the Harburg research team allows other key technologies to be studied in a similar way and objectively compared with known technologies. But first, the proposed parameters and simulation processes must prove themselves in a practical environment. If the new comparison method is revealed to be useful in general, it could form the basis for a directive, which simplifies the documentation of constraints, further input parameters and mathematical/physical partial models required for comprehension. The method can be transferred to any future energy comparison of power plant technologies based on the familiar basic processes. 3 BINE Projektinfo 01/2010 BINE-Projektinfo 05/2011 Structural change in the electricity market The market share of electricity generated from renewable energy sources is growing in Germany. By 2030 more than every third kilowatt hour is to be derived from renewable energy sources such as wind, biomass and hydroelectricity. Even if this percentage is twice that of today, the question remains: Where will the remaining electricity come from? Another objective further complicates this answer: Within the next 10 years, Germany also intends to reduce emissions of carbon dioxide, the „climate gas“ by 40% compared with 1990. High-efficiency, low CO2 power plants for fossil fuels such as coal and gas could be a solution for this. They are a flexible replacement for renewable energy sources when yield is low due to natural fluctuations. Fossil-fired power plants are often described as bridge technologies, which can replace old plants and compensate green electricity supplies. If we succeed in increasing the average efficiency of German power plants by just 2 percent with constant electricity generation, this is mathematically equivalent to one tenth of the CO2 emissions caused by road traffic. Since 1985 research has managed to increase the efficiency of the latest power plant technologies by over 20%. With the cooperation of industry and science the COORETEC support initiative of the German Federal Ministry of Economics and Technology has developed a whole range of technologies since 2004 to further increase the efficiency of power plants or to capture CO2 in the power plant process and store it geologically. The new power plant technologies are not only intended for German power supply. In the long term, Germany will fall below 1% of the electricity generated globally. Developing innovative power plant technologies for the global market not only contributes to the competitiveness of the export-oriented German economy but also offers a way to reach the ambitious global climate targets. In order to limit global warming to 2 °C, the CO2 emissions around the world must be reduced rapidly and significantly. The global population is growing and will probably reach 9 billion people by 2050. This will increase the demand for energy, in particular for electricity. As long as the reserves of coal and natural gas are available around the world at low prices, the percentage of electricity produced by fossil-fired power plants will increase rather than decrease. Comparative research allows us to make the best choice between energyefficient, economic and flexible technologies. Project participants >> Hamburg University of Technology (TUHH), Institute of Energy Systems (M-5), Prof. Dr.-Ing. Alfons Kather, Imo Pfaff, Hamburg (Germany), Phone +49 40 42878-3243 Links and literature (in German) >> www.tu-harburg.de/iet | www.kraftwerkforschung.info | www.cooretec.de >> Kather, A.; Pfaff, I.: Vergleich der in COORETEC verfolgten Kraftwerksprozesse unter einheitlichen realitätsnahen Randbedingungen. Abschlussbericht. Technische Universität Hamburg-Harburg (Hrsg.). März 2011. 170 S., FKZ 0327742. Download at TIB Hannover , Germany: www.getinfo.de | Bundesministerium für Wirtschaft und Technologie, Berlin (Hrsg.): E mpfehlungen des COORETEC-Beirats zur Förderung von Forschung und Entwicklung CO2-emissionsarmer Kraftwerkstechnologien und CO2-Abscheide- und Speichertechnologien, April 2009. Download at: www.kraftwerkforschung.info | Bundesministerium für Wirtschaft und Technologie, Berlin (Hrsg.): Leuchtturm COORETEC – Der Weg zum zukunftsfähigen Kraftwerk mit fossilen Brennstoffen, Juni 2007. Forschungsbericht Nr. 566. Download at: www.kraftwerkforschung.info More from BINE Information Service b This Projektinfo brochure is available as an online document at www.bine.info under ublications/Projektinfos. Additional information in German, such as other project addresses P and links, can be found under “Service”. BINE Information Service reports about energy research projects in its brochure series and newsletter. You can subscribe to these free of charge at www.bine.info/abo. b Project organisation Federal Ministry of Economics and Technology (BMWi) 11019 Berlin Germany Project Management Organisation Jülich Research Centre Jülich Dr.-Ing. Jochen Seier 52425 Jülich Germany Project number 0327742 Imprint ISSN 0937 - 8367 Publisher FIZ Karlsruhe · Leibniz Institute for Information Infrastructure Hermann-von-Helmholtz-Platz 1 76344 Eggenstein-Leopoldshafen Germany Author Peter Horenburg Cover image Installation by Vattenfall Europe AG of the Jänschwalde power plant site with the planned CCS demonstration power plant Copyright Text and illustrations from this publication can only be used if permission has been granted by the BINE editorial team. We would be delighted to hear from you. Contact · Info Questions regarding this Projektinfo brochure? 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