NaugaNeedles NN NaugaNeedles' Ultra Sharp NanoProbe (USNP) NaugaNeedles has developed a very unique nanofabrication technology to selectively grow individual metallic Silver/Gallium (Ag2Ga) nanoneedles at the end of standard tungsten probes. The Ag2Ga nanoneedles have superior electrical, mechanical and chemical stability that significantly improve the performance of Micro-Probe-Stations and Nano-Manipulators. Figure 1 shows SEM images of an ultra sharp NanoProbe (USNP). A 5 µm long and 60 nm diameter Ag2Ga nanoneedles is grown on a standard tungsten probe, with a radius of curvature of ~ 13 nm at the tip. The nanoneedles is attached to the tungsten probe by a taper shape structure made of Ag2Ga alloy, that significantly enhances the mechanical stability of the nanoneedle. Advantages: • • • • • • • 10 µm Tungsten wire 2 µm Crystalline Ag2Ga structure Single Crystalline, cylindrical Ag2Ga Nanoneedle 60 nm R = 13 nm Figure 1: Optical (top) and SEM images of NaugaNeedles' Ultra Sharp NanoProbes (USNP) The smallest tip radius in the market The most durable NanoProbe in the market Platinum corrosion protection The best probe for multi-probing with Zero taper angle Highly conductive Excellent mechanical properties with high elasticity Cylindrical shape single metallic crystal with atomically uniform diameter www.nauganeedles.com NN Specification: Figure 2 shows schematics of different component of the USNP. The USNP are made of three parts; (1) A crystalline nanoneedle tip, (2) A polycrystalline tungsten wire, and (3) A probe shank. (1) Specification for Crystalline Nanoneedle tip: Tip radius of curvature: Nanoneedles length: Category 1: 1 to 5 µm, Contact resistance: Category 1: ≤ 30 Ohm, 25 to 50 nm Category 2 : 5 to 10 µm Category 2 : ≤ 100 Ohm (2) Specification for polycrystalline tungsten wire Diameter : ~100 µm, Length : ~5.0 mm, (3) Specification for Probe Shank: Diameter : ~ 0.25 mm, Length : ~15 mm, ~ 20 mm Total probe length : ~ 20 mm 1-5 µm or 5 - 10 µm ~ 0.5 mm ~ 4.5 mm ~5 mm Taper angle : ~ 10 o R= 15 – 50 nm Ø 100 µm Probe Shank Tungsten wire Wire and tip Ag2Ga Ø 0.25 mm Figure 2: Schematic of different components of the USNP NaugaNeedles' ultra sharp NanoProbe (USNP) 2mm Standard tungsten probes in the market 2mm (a) 2mm (a) (b) 2mm (b) Figure 3. Comparison between mechanical properties of (a) an USSP and (b) a standard tungsten probes. www.nauganeedles.com Due to crystallinity of their tip, the USNPs have excellent mechanical properties. Figure shows the SEM images of a USNP as it is pushed against a silicon surface. Despite stand tungsten probes that are plastically deformed (Figure 3b), the USSPs can be elastically deform up to 50% of their length and return to the original shape without any plastic deformation. NaugaNeedles NaugaNeedles' ultra sharp NanoProbe (USNP) Standard tungsten probes in the market 2m 2m A comparison between mechanical properties of the USSP and standard tungsten probes: (a) (b) Due to crystallinity of their tip, the USNPs have excellent mechanical properties. Figure 3 a shows Figure 3. Comparison between mechanical properties of (a) an USSP and (b) a standard tungsten the SEM images of a USNP as it is pushed against a silicon surface. Despite probes.standard tungsten probes that are plastically deformed (Figure 3b), the USSPs can be elastically deformed up to 50% of their Electrical properties of USSP: length and return to the original shape without any plastic deformation. Table 1 summarizes the resistance data taken from 9 USNPs with various Ag2Ga nanoneedles platinum coated substrate. For shorter (3 nanoneedles the resistance is as low as 40 ohm and for the longer nanoneedles (18.5 m), is as high as 2200 Ohm. as high 0.5 mA can be passed tip through Table 1 summarizes the resistance data resistance taken from 9 USNPs withCurrent various Agas2Ga nanoneedles sizethe shor USNP (1 to 5 µm) without any damage to the nanoneedle. Based on these measurements, -7 -8 when they brought in contact with a platinum coatedofsubstrate. For shorterat(31.35×10 µm) nanoneedles electrical resistivity Ag2Ga material is estimated Ωm ± 3×10 Ωm the that is can categorized as ananoneedles very good electrical conductor. resistance is as low as 40 ohm and for the longer (18.5 µm), the resistance is as high as size when they brought in with a Electrical properties ofcontact USSP: 2200 Ohm. Current as high as 0.5 mA can be passed through the shorter USNP (1 to 5 µm) withTable 1. Resistance measurement of individual USNP 3 14 9.7 27.7 39 10 25 22 18.5 out any damage to the nanoneedle. Based on L (m) these measurements, the electrical resistivity R (nm) 50 125 85 150 105 72 78 70 56 of Ag2Ga material is estimated at 1.35×10 7 R (Ohm) 40 35 52 56 272 400 1400 1500 2200 Ωm ± 3×10 8 Ωm that is can be categorized (ρ, Ωm)× -7 1.0 1.2 1.2 1.4 2.4 1.8 1.0 1.1 1.1 10 as a very good electrical conductor. Table 1. Resistance measurement of individual USNP Since the resistance of the contact point between the surface and the USNP was also a part of resistance measurement, the real value for resistivity of Ag2Ga material should be smaller th point between the surface and the USNP alsounder a part of condition. the the reported values above. All of the measurements herewas were done ambient Since the resistance of the contact resistance measurement, the real value for resistivity of Ag2Ga material should be smaller than the reported values above. All of the measurements here were done under ambient condition. Optical Evaluation of USSP, suitable for probe station probes: Due to their crystallinity, even very thin (50 to 100 nm) Ag2Ga nanoneedles are easily being seen under optical lenses. Figure 4 shows Optical image of an Ag2Ga Nanoneedle on a an optical image of a nanoneedle grown tungsten probe on a tungsten wire. As it is seen in Fig- Tungsten ure 4, the brightness of the nanoneedle Substrate is even higher than the tungsten wire 5 µm which makes it visible under relatively good optical lenses. We have been able Figure 4: Optical evaluation of USSP to detect the nanoneedles with various types of optical lenses (e.g. Keyence, Navetar). www.nauganeedles.com NN NaugaNeedles NNAUG AU www.nauganeedles.com N augaNeedles 11509 Commonwealth Dr., Suite 2 • Louisville, KY, 40299 Phone: (502) 619-5156 Email: [email protected] www.nauganeedles.com
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