Material Safety Data Sheet Product No. 19545 Sodium phosphate

Material Safety Data Sheet
Product No. 19545 Sodium phosphate, dibasic heptahydrate
Issue Date (07-15-11)
Review Date (05-22-12)
Section 1: Product and Company Identification
Product Name: Sodium phosphate, dibasic heptahydrate
Synonym: Disodium phosphate heptahydrate; Phosphoric acid, Disodium salt
heptahydrate
Company Name
Ted Pella, Inc., P.O. Box 492477, Redding, CA 96049-2477
Domestic Phone (800) 237-3526 (Mon-Thu. 6:00AM to 4:30PM PST; Fri 6:00AM to
4:00PM PST)
International Phone (01) (530) 243-2200 (Mon-Thu. 6:00AM to 4:30PM PST; Fri
6:00AM to 4:00PM PST)
Chemtrec Emergency Number 1-800-424-9300 24 hrs a day.
Section 2: Composition / Information on Ingredients
Principle Hazardous
%
OSHA ACGIH
Component(s)
PEL
TLV
(chemical and common name(s))
mg/m3
(Cas. No)
Sodium phosphate, dibasic ~100
heptahydrate
ND
(7782-85-6)
NTP
IARC
OSHA
regulated
No
No
No
mg/m3
ND
Section 3: Hazard Identification
Emergency overview
Appearance: Solid white powder.
Immediate effects: Slightly hazardous in case of skin contact (irritant, permeator), of eye
contact (irritant), of ingestion, of inhalation.
Potential health effects
Primary Routes of entry: Inhalation, Ingestion.
Signs and Symptoms of Overexposure: Ingestion of large doses may affect
behavior/central nervous system (tetany). However, if a significant amount of phosphate
is absorbed, hypophosphatemia will occur. Severe hypophosphatemia may result in
hypocalcaemia and tetany. Cardiovascular, respiratory, neurological, and musculoskeletal
effects may occur secondary to hypernatremia, hypophosphatemia, and hypocalcaemia.
Eyes: Causes mild eye irritation.
Skin: Slightly hazardous in case of skin contact (irritant, permeator). May cause
dermatitis.
Inhalation: May cause respiratory tract and mucous membrane irritation. Expected to be a
low hazard for usual industrial handling.
Ingestion: May cause irritation of the digestive tract and may cause purging. It is slowly
absorbed. Expected to be a low ingestion hazard for usual industrial handling.
Chronic Exposure: Skin: High and repeated exposure may cause dermatitis.
Chemical Listed As Carcinogen Or Potential Carcinogen: No
See Toxicological Information (Section11)
Potential environmental effects
See Ecological Information (Section 12)
Section 4: First Aid Measures
If accidental overexposure is suspected
Eye(s) Contact: Check for and remove any contact lenses. In case of contact, immediately
flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get
medical attention if irritation occurs.
Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get
medical attention if irritation develops. Cold water may be used.
Ingestion: Do not induce vomiting unless directed to do so by medical personnel. Never
give anything by mouth to an unconscious person. Loosen tight clothing such as a collar,
tie, belt or waistband. Get medical attention if symptoms appear.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical attention.
Note to physician
Treatment: ND
Medical Conditions generally Aggravated by Exposure: ND
Section 5: Fire Fighting Measures
Flash Point: Non-flammable
Flammable Limits: NA
Auto-ignition point: NA
Fire Extinguishing Media: NA
Special Fire Fighting Procedures: NA
Unusual Fire and Explosion Hazards: NA
Hazardous combustion products: Under fire conditions: Oxides of phosphorus, Sodium
oxides.
DOT Class: Not regulated
Section 6: Accidental Release Measures
Steps to be Taken in Case Material is Released or Spilled: Small Spill: Use appropriate
tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and
regional authority requirements. Large Spill: Use a shovel to put the material into a
convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow evacuating through the sanitary system.
Waste Disposal Methods: Dispose of waste according to Federal, State and Local
Regulations.
Section 7: Handling and Storage
Precautions to be taken in Handling and Storage: Keep container tightly closed in wellventilated area.
Storage temperature: Keep container in a cool.
Storage Pressure: NA
Section 8: Exposure Controls / Personal Protection
Engineering Controls
Ventilation required: Use process enclosures, local exhaust ventilation, or other
engineering controls to keep airborne levels below recommended exposure limits. If user
operations generate dust, fume or mist, use ventilation to keep exposure to airborne
contaminants below the exposure limit.
Personal Protection Equipment
Respiratory protection: Where protection from nuisance levels of dusts are desired, use
type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested
and approved under appropriate government standards such as NIOSH (US) or CEN
(EU).
Protective gloves: Wear Gloves.
Skin protection: Lab coat and gloves.
Eye protection: Safety glasses, goggles or face shield.
Additional clothing and/or equipment: Lab coat.
Exposure Guidelines
See Composition/Information on Ingredients (Section2)
Section 9 Physical and Chemical Properties
Appearance and Physical State: Solid white powder.
Odor (threshold): Odorless
Specific Gravity (H2O=1): 1.7
Vapor Pressure (mm Hg): NA
Vapor Density (air=1): 4.9 (Lit.)
Percent Volatile by volume: NA
Evaporation Rate (butyl acetate=1): NA
Boiling Point: ND
Freezing point / melting point: 48 °C (Lit.)
pH: ND
Solubility in Water: Easily soluble in cold water, hot water. 104 g/100 ml @ 40ºC
Molecular Weight: 268.07 (Lit.)
Section 10: Stability and Reactivity
Stability: Stable.
Conditions to Avoid: Keep away from incompatibles.
Materials to Avoid (Incompatibility): Reactive with oxidizing agents, acids, alkalis.
Special Remarks on Reactivity: Loses 5 H2O @48ºC. Incompatible with magnesium,
alkaloids, antipyrine, chloral hydrate, lead acetate, pyrogalloi, resorcinol, strong mineral
acids, strong organic acids.
Hazardous Decomposition Products: Under fire conditions: Oxides of phosphorus,
Sodium oxides.
Hazardous Polymerization: Will not occur.
Section 11: Toxicological Information
Results of component toxicity test performed: Acute oral toxicity (LD50): 12930 mg/kg
[Rat].
Human experience: ND
This product does not contain any compounds listed by NTP or IARC or regulated by
OSHA as a carcinogen.
Section 12: Ecological Information
Ecological Information: Toxicity of the Products of Biodegradation: The product itself
and its products of degradation are not toxic.
Chemical Fate Information: ND
Section 13 Disposal Considerations
RCRA 40 CFR 261 Classification: ND
Federal, State and local laws governing disposal of materials can differ. Ensure proper
disposal compliance with proper authorities before disposal.
Section 14: Transportation Information
US DOT Information: Proper shipping name: Not regulated
Poison Inhalation Hazard: No
IATA: Proper shipping name: Not regulated.
IMO: Proper shipping name: Not regulated.
Marine Pollutant: No
Canadian TDG: Not regulated.
Section 15: Regulatory Information
United States Federal Regulations
MSDS complies with OSHA’s Hazard Communication Rule 29, CFR 1910.1200.
SARA: No
SARA Title III: No
RCRA: No
TSCA: NIF or not listed.
CERCLA: Sodium phosphate, dibasic heptahydrate (7782-85-6): No (Note: The
anhydrous form: Disodium hydrogen phosphate, (7558-79-4) has RQ =5000 lbs)
State Regulations
California Proposition 65: No
International Regulations
Canada WHMIS: Not regulated
Europe EINECS Numbers: ND
RTECS: WC4600000
Section 16: Other Information
Label Information: Irritant.
European Risk and Safety Phrases: R36/37/38. S26-36
European symbols needed: Xi
Canadian WHMIS Symbols: ND
HMIS® Hazard Rating: Health: 1; Flammability: 0; Physical Hazard: 0; Personal
Protection: E
NFPA Hazard Rating: Health: 1; Flammability: 0; Instability: 0; Special Hazards ND
(0=least, 1=Slight, 2=Moderate, 3=High, 4=Extreme)
Abbreviations used in this document
NE= Not established
NA= Not applicable
NIF= No Information Found
ND= No Data
Disclaimer
Ted Pella, Inc. makes no warranty of any kind regarding the information furnished
herein. Users should independently determine the suitability and completeness of
information from all sources. While this data is presented in good faith and believed to be
accurate, it should be considered only as a supplement to other information gathered by
the user. It is the User's responsibility to assure the proper use and disposal of these
materials as well as the safety and health of all personnel who may work with or
otherwise come in contact with these materials.
MSDS Form 0013F1 V2