Safety Data Sheet according to Regulation (EC) No 1907/2006
PREMA GmbH
COLD VULCANISING COMPOUND A
Revision date: 03.11.2016
Product code: 00623-0006
Revision No: 1,1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
COLD VULCANISING COMPOUND A
Art.-No.
PAB-300 (SKU No. 2205705)
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Filler rubber
1.3. Details of the supplier of the safety data sheet
Company name:
Street:
Place:
Telephone:
PREMA GmbH
Aspertsham 40
D-94081 Fürstenzell
+49 (0) 8502 917 150 0
Responsible Department:
Responsible for the safety data sheet: [email protected]
1.4. Emergency telephone
number:
INTERNATIONAL: +49 - (0) 6132 - 84463, GBK GmbH (24h - 7d/w - 365d/a)
England and Wales: NHS Direct - 0845 4647; Scotland: NHS 24 - 08454 24 24
24
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture according to 1272/2008/EC
Hazard categories:
Flammable liquid: Flam. Liq. 2
Skin corrosion/irritation: Skin Irrit. 2
Specific target organ toxicity - single exposure: STOT SE 3
Hazardous to the aquatic environment: Aquatic Chronic 2
Hazard Statements:
Highly flammable liquid and vapour.
Causes skin irritation.
May cause drowsiness or dizziness.
Toxic to aquatic life with long lasting effects.
2.2. Label elements
Hazard components for labelling
Naphtha (petroleum)
Signal word:
Danger
Pictograms:
Hazard statements
H225
H315
H336
H411
Highly flammable liquid and vapour.
Causes skin irritation.
May cause drowsiness or dizziness.
Toxic to aquatic life with long lasting effects.
Precautionary statements
P210
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P304+P340
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312
Call a POISON CENTER/doctor if you feel unwell.
P273
Avoid release to the environment.
Print date: 03.11.2016
GB - EN
Page 1 of 9
Safety Data Sheet according to Regulation (EC) No 1907/2006
PREMA GmbH
COLD VULCANISING COMPOUND A
Revision date: 03.11.2016
Product code: 00623-0006
Revision No: 1,1
Special labelling of certain mixtures
EUH208
Contains N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine. May produce an allergic
reaction.
2.3. Other hazards
Vapours may form explosive mixture with air.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
Chemical characterization
Preparation in aliphatic hydrocarbons
Hazardous components
CAS No
Chemical name
EC No
Quantity
Index No
REACH No
Classification according to Regulation (EC) No. 1272/2008 [CLP]
64742-49-0
Naphtha (petroleum) (Hydrocarbons, C6-C7, n-alkanes, iso-alkanes, cyclic compounds, < 3%
n-hexane)
921-024-6
< 25 %
01-2119475514-35
Flam. Liq. 2, Skin Irrit. 2, STOT SE 3, Asp. Tox. 1, Aquatic Chronic 2; H225 H315 H336 H304
H411
64742-49-0
Naphtha (petroleum) (Hydrocarbons, C6, isoalkanes, < 3% n-hexane)
931-254-9
< 10 %
01-2119484651-34
Flam. Liq. 2, Skin Irrit. 2, STOT SE 3, Asp. Tox. 1, Aquatic Chronic 2; H225 H315 H336 H304
H411
1314-13-2
Zinc oxide
215-222-5
< 2,5 %
030-013-00-7
01-2119463881-32
Aquatic Acute 1, Aquatic Chronic 1; H400 H410
7704-34-9
sulfur
231-722-6
<5%
016-094-00-1
01-2119520616-43
Skin Irrit. 2; H315
793-24-8
N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine
212-344-0
<1%
01-2119485839-15
Acute Tox. 4, Skin Sens. 1, Aquatic Acute 1, Aquatic Chronic 1; H302 H317 H400 H410
Full text of H and EUH statements: see section 16.
Further Information
According to note P to the regulation (EC) no. 1272/2008, "Naphta (petroleum)" is not to be classified
as "carcinogenic" or "mutagen" ingredient because a benzene content (EINECS No. 200-753-7) is
below 0.1 % by weight.
SECTION 4: First aid measures
4.1. Description of first aid measures
General information
Remove contaminated soaked clothing immediately.
If you feel unwell, seek medical advice.
Take away from danger area and lay down affected person .
After inhalation
Move to fresh air in case of accidental inhalation of vapours or decomposition products.
Refer for medical treatment.
After contact with skin
Wash off with soap and plenty of water.
Consult a doctor if skin irritation persists.
After contact with eyes
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Summon a doctor immediately.
Print date: 03.11.2016
GB - EN
Page 2 of 9
Safety Data Sheet according to Regulation (EC) No 1907/2006
PREMA GmbH
COLD VULCANISING COMPOUND A
Revision date: 03.11.2016
Product code: 00623-0006
Revision No: 1,1
After ingestion
Do not induce vomiting.
Rinse out mouth and give plenty of water to drink.
Never give anything by mouth to an unconscious person.
Summon a doctor immediately.
4.2. Most important symptoms and effects, both acute and delayed
Causes skin irritation.
May cause drowsiness or dizziness.
Attention. Beware, danger of aspiration.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptoms.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
Foam, carbon dioxide (CO2), dry chemical, water-spray.
Unsuitable extinguishing media
Full water jet.
5.2. Special hazards arising from the substance or mixture
Fire may produce:
Carbon monoxide, carbon dioxide, sulphur oxides and nitrogen oxides (NOx).
5.3. Advice for firefighters
Use breathing apparatus with independent air supply.
Protective suit.
Additional information
Cool containers at risk with water spray jet.
The vapour/air mixture is explosive, even in empty, uncleaned receptacles.
Vapours are heavier than air and spread along ground .
Fire residues and contaminated firefighting water must be disposed of in accordance with the local
regulations.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
In case of vapour formation use respirator.
Use only explosion-proof equipment.
Ensure adequate ventilation.
Use personal protective clothing.
Keep away sources of ignition.
6.2. Environmental precautions
Do not discharge into the drains/surface waters/ground water.
6.3. Methods and material for containment and cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder).
Shovel into suitable container for disposal.
6.4. Reference to other sections
Observe protective instructions (see Sections 7 and 8).
Information for disposal see section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Advice on safe handling
Keep container tightly closed.
Keep a good ventilation and air-exhaust at the place of work.
Vapours are heavier than air and spread along ground .
Advice on protection against fire and explosion
Keep away from heat and sources of ignition.
Print date: 03.11.2016
GB - EN
Page 3 of 9
Safety Data Sheet according to Regulation (EC) No 1907/2006
PREMA GmbH
COLD VULCANISING COMPOUND A
Revision date: 03.11.2016
Product code: 00623-0006
Revision No: 1,1
Do not smoke.
Take precautionary measures against static discharges .
Use only explosion-proof equipment.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep container tightly closed in a dry, cool and well-ventilated place.
Pay attention to anti-explosion protection rules.
Advice on storage compatibility
Incompatible with oxidizing agents.
Further information on storage conditions
Keep away from food, drink and animal feeding stuffs.
7.3. Specific end use(s)
Filler rubber
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Exposure limits (EH40)
CAS No
Substance
1333-86-4
Carbon black
1332-58-7
Kaolin respirable dust
ppm
mg/m³
-
3.5
-
fibres/ml
Category
Origin
TWA (8 h)
WEL
7
STEL (15 min)
WEL
-
2
TWA (8 h)
WEL
-
-
STEL (15 min)
WEL
8.2. Exposure controls
Appropriate engineering controls
Ensure adequate ventilation, especially in confined areas.
Protective and hygiene measures
Wash hands before breaks and immediately after handling the product .
When using do not eat, drink or smoke.
Treat subsequently with skin cream.
Remove and wash contaminated clothing before re-use.
Eye/face protection
Tightly fitting goggles (EN 166).
Eye wash bottle with pure water (EN 15154).
Hand protection
Protective gloves resistant to chemicals made of nitrile, minimum coat thickness 0.4 mm, permeation
resistance (wear duration) approx. 480 minutes, i.e. protective glove < Camatril Velours 730> made by
www.kcl.de.
This recommendation refers exclusively to the chemical compatibility and the lab test conforming to EN
374 carried out under lab conditions.
Requirements can vary as a function of the use. Therefore it is necessary to adhere additionally to the
recommendations given by the manufacturer of protective gloves.
Skin protection
Long sleeved clothing (EN 368).
Respiratory protection
In case of insufficient ventilation wear suitable respiratory equipment (gas filter type A) (EN 14387).
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state:
Colour:
pasty
Black
Odour:
Like petrol (gasoline )
Print date: 03.11.2016
GB - EN
Page 4 of 9
Safety Data Sheet according to Regulation (EC) No 1907/2006
PREMA GmbH
COLD VULCANISING COMPOUND A
Revision date: 03.11.2016
Product code: 00623-0006
Revision No: 1,1
Changes in the physical state
Melting point:
< - 20 °C
*)
Initial boiling point and boiling range:
60 - 95 °C
*)
Flash point:
Lower explosion limits:
Upper explosion limits:
Ignition temperature:
Vapour pressure:
(at 20 °C)
Density (at 20 °C):
Water solubility:
(at 20 °C)
Viscosity / kinematic:
(at 40 °C)
Flow time:
- 25 °C
1,0 vol. %
7,3 vol. %
413 °C
*)
*)
*)
*)
150 hPa
*)
1,01 g/cm³
Immiscible
approx.
Solvent separation test:
Solvent content:
<3%
30 - 35 %
> 20,5 mm²/s
> 100 s
3 mm DIN/ISO 2431
9.2. Other information
*) Naphtha (petroleum)
SECTION 10: Stability and reactivity
10.1. Reactivity
No decomposition if stored and applied as directed.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
Reactions with oxidizing agents.
10.4. Conditions to avoid
To avoid thermal decomposition, do not overheat.
Heating can release vapours which can be ignited.
Vapour/air-mixtures are explosive at intense warming.
10.5. Incompatible materials
oxidizing agents
10.6. Hazardous decomposition products
Carbon monoxide, carbon dioxide, sulphur oxides, and nitrogen oxides (NOx).
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity
Based on available data, the classification criteria are not met.
No toxicological data available.
Naphtha (petroleum)
LD50/oral/rat: > 2000 mg/kg (Estimated)
LD50/dermal/rabbit: > 2000 mg/kg (Estimated)
LC50/inhalation/rat: > 20 mg/l (Estimated)
Irritation and corrosivity
Causes skin irritation.
Serious eye damage/eye irritation: Based on available data, the classification criteria are not met.
Eye irritation: Not classified.
Sensitising effects
Based on available data, the classification criteria are not met.
STOT-single exposure
Print date: 03.11.2016
GB - EN
Page 5 of 9
Safety Data Sheet according to Regulation (EC) No 1907/2006
PREMA GmbH
COLD VULCANISING COMPOUND A
Revision date: 03.11.2016
Product code: 00623-0006
Revision No: 1,1
May cause drowsiness or dizziness. (Naphtha (petroleum) (Hydrocarbons, C6-C7, n-alkanes,
iso-alkanes, cyclic compounds, < 3% n-hexane))
Severe effects after repeated or prolonged exposure
Based on available data, the classification criteria are not met.
Carcinogenic/mutagenic/toxic effects for reproduction
Based on available data, the classification criteria are not met.
Aspiration hazard
Based on available data, the classification criteria are not met.
Additional information on tests
Classification in compliance with the assessment procedure specified in the Regulation (EC) no
1272/2008.
Practical experience
Other observations
Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness,
nausea and vomiting.
A longer or repeated contact my lead to irritation of eyes and mucous membranes .
Repeated or prolonged skin contact may cause skin irritation and/or dermatitis and sensitization of
susceptible persons.
Attention. Beware, danger of aspiration!
SECTION 12: Ecological information
12.1. Toxicity
Ecological data are not available.
Naphtha (petroleum)
LC50/EC50/EC50 : 1 - 10 mg/l (Estimated)
Toxic to aquatic life with long lasting effects.
CAS No
Chemical name
7704-34-9
sulfur
Aquatic toxicity
Acute fish toxicity
793-24-8
Method
LC50
Dose
866 mg/l
[h] | [d] Species
Source
96 h Danio rerio
N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine
Acute fish toxicity
LC50
0,028 mg/l
Acute algae toxicity
ErC50
2,6 mg/l
Acute crustacea toxicity
EC50
0,23 mg/l
96 h Oryzias latipes
Desmodesmus subspicatus
48 h Daphnia magna
OECD 203
OECD 201
OECD 202
No data available.
12.3. Bioaccumulative potential
No data available.
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
According to Regulation (EC) No 1907/2006 (REACH) none of the substances, contained in this
product are a PBT / vPvB substance.
12.6. Other adverse effects
Low hazard to waters.
Further information
Do not flush into surface water or sanitary sewer system.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Advice on disposal
Can be incinerated, when in compliance with local regulations.
Where possible recycling is preferred to disposal.
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GB - EN
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Safety Data Sheet according to Regulation (EC) No 1907/2006
PREMA GmbH
COLD VULCANISING COMPOUND A
Revision date: 03.11.2016
Product code: 00623-0006
Revision No: 1,1
Waste disposal number of waste from residues/unused products
WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS
080409
(PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS;
wastes from MFSU of adhesives and sealants (including waterproofing products); waste adhesives and
sealants containing organic solvents or other hazardous substances
Classified as hazardous waste.
Contaminated packaging
Empty containers should be taken for local recycling, recovery or waste disposal.
Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be
taken for reuse.
Packaging that cannot be cleaned should be disposed of like the product.
SECTION 14: Transport information
Land transport (ADR/RID)
14.1. UN number:
UN 1133
14.2. UN proper shipping name:
Adhesives
14.3. Transport hazard class(es):
3
14.4. Packing group:
III
Hazard label:
3
Classification code:
Limited quantity:
Excepted quantity:
Transport category:
Tunnel restriction code:
F1
5 L / 30 kg
E1
3
D/E
Inland waterways transport (ADN)
14.1. UN number:
UN 1133
14.2. UN proper shipping name:
Adhesives
14.3. Transport hazard class(es):
14.4. Packing group:
3
III
Hazard label:
3
Classification code:
Limited quantity:
Excepted quantity:
F1
5 L / 30 kg
E1
Marine transport (IMDG)
14.1. UN number:
UN 1133
14.2. UN proper shipping name:
Adhesives (Naphtha (petroleum))
14.3. Transport hazard class(es):
3
14.4. Packing group:
III
Hazard label:
3
Marine pollutant:
Limited quantity:
Excepted quantity:
EmS:
Yes
5 L / 30 kg
E1
F-E, S-D
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GB - EN
Page 7 of 9
Safety Data Sheet according to Regulation (EC) No 1907/2006
PREMA GmbH
COLD VULCANISING COMPOUND A
Revision date: 03.11.2016
Product code: 00623-0006
Revision No: 1,1
Other applicable information (marine transport)
Receptacle max. 30 L, IMDG Code subsection 2.3.2.3
Air transport (ICAO-TI/IATA-DGR)
14.1. UN number:
UN 1133
14.2. UN proper shipping name:
Adhesives
14.3. Transport hazard class(es):
3
14.4. Packing group:
III
Hazard label:
3
Limited quantity Passenger:
Passenger LQ:
Excepted quantity:
10 L
Y344
E1
IATA-packing instructions - Passenger:
IATA-max. quantity - Passenger:
IATA-packing instructions - Cargo:
IATA-max. quantity - Cargo:
355
30 L (*)
366
30 L (*
Other applicable information (air transport)
*) [3.3.3.1 IATA DGR]
14.5. Environmental hazards
ENVIRONMENTALLY HAZARDOUS:
yes
14.6. Special precautions for user
Handle in accordance with good industrial hygiene and safety practice.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
The transport takes place only in approved and appropriate packaging.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
2004/42/EC (VOC):
30 - 35 %
National regulatory information
Employment restrictions:
Water contaminating class (D):
Observe restrictions to employment for juvenils according to the 'juvenile
work protection guideline' (94/33/EC). Observe employment restrictions
under the Maternity Protection Directive (92/85/EEC) for expectant or
nursing mothers.
1 - slightly water contaminating
15.2. Chemical safety assessment
For this substance a chemical safety assessment has not been carried out.
SECTION 16: Other information
Abbreviations and acronyms
ADR = Accord européen relatif au transport international des marchandises Dangereuses par Route
RID = Règlement concernant le transport international ferroviaire de marchandises dangereuses
ADN = Accord européen relatif au transport international des marchandises dangereuses par voie de navigation intérieure
IMDG = International Maritime Code for Dangerous Goods
IATA/ICAO = International Air Transport Association / International Civil Aviation Organization
MARPOL = International Convention for the Prevention of Pollution from Ships
IBC-Code = International Code for the Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk
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GB - EN
Page 8 of 9
Safety Data Sheet according to Regulation (EC) No 1907/2006
PREMA GmbH
COLD VULCANISING COMPOUND A
Revision date: 03.11.2016
Product code: 00623-0006
Revision No: 1,1
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
REACH = Registration, Evaluation, Authorization and Restriction of Chemicals
CAS = Chemical Abstract Service
EN = European norm
ISO = International Organization for Standardization
DIN = Deutsche Industrie Norm
PBT = Persistent Bioaccumulative and Toxic
vPvB = Very Persistent and very Bio-accumulative
LD = Lethal dose
LC = Lethal concentration
EC = Effect concentration
IC = Median immobilisation concentration or median inhibitory concentration
Relevant H and EUH statements (number and full text)
H225
Highly flammable liquid and vapour.
H302
Harmful if swallowed.
H304
May be fatal if swallowed and enters airways.
H315
Causes skin irritation.
H317
May cause an allergic skin reaction.
H336
May cause drowsiness or dizziness.
H400
Very toxic to aquatic life.
H410
Very toxic to aquatic life with long lasting effects.
H411
Toxic to aquatic life with long lasting effects.
EUH208
Contains N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine. May produce an allergic
reaction.
Further Information
Data of items 4 to 8, as well as 10 to 12, do partly not refer to the use and the regular employing of the
product (in this sense consult information on use and on product), but to liberation of major amounts in
case of accidents and irregularities.
The information describes exclusively the safety requirements for the product(s) and is based on the
present level of our knowledge.
The delivery specifications are contained in the corresponding product sheet.
This data does not constitute a guarantee for the characteristics of the product(s) as defined by the
legal warranty regulations.
(n.a. = not applicable; n.d. = not determined)
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)
Print date: 03.11.2016
GB - EN
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