11/11/2016 Chemical Bonding Unit 5 Notes By the end of this lesson you will be able to: Name and describe the 3 types of bonds and how they are different List possible compounds in each and how elements are affected by the bonds they share Describe how we know these bonds exist. What are properties of the bonds? 1 11/11/2016 Ionic Bonds Bond most often between a metal and a nonmetal Transfer of electrons from the metal to the nonmetal Electrical attraction between large numbers of cations and anions called clusters Ion = a charged particle Ionic Bonds Cation = + charged particle – Loves to give electrons away – Low Ionization Energy, Electron Affinity & Electronegativity – Typically are metals – Most metallic element = Fr 2 11/11/2016 Ionic Bonds (cont.) Anion = - charged particle – Loves to accept electrons – High Ionization Energy, Electron Affinity & Electronegativity – Typically are nonmetals – Most nonmetallic element = F Ionic Bonds (cont.) If a bond is ionic: – The compound is solid – The compound will fall apart (dissociate) into its original ions when dissolved in water -If a conductivity test is performed, the light bulb will… light! -EN values 1.8 up to 4 3 11/11/2016 In General Ionic Bonds are the strongest bonds there are Covalent Bonds Formed when 2 nonmetal atoms share electrons Can be liquid, solid or gas 4 11/11/2016 Polar Covalent Bonds Unequal sharing of electrons Electrons attracted more to higher E.N. atom Electronegativity difference range = 0.3 – 1.7 (for polar covalent bonds) Polar Covalent Bonds dissolve in water – Why? – (Check out page 19 in your packet for EN of water) The light bulb doesn’t light up. Non-polar Covalent Bonds Equal sharing of electrons Electronegativity difference range = 0.0 – <0.3 Usually found between diatomic molecules – two of the same atoms Non-polar covalent bonds don’t dissolve in water. 5 11/11/2016 Metallic Bonds Bond formed between 2 metal atoms. Electrons are free to move within electron clouds of all metal ions = Sea of Electrons Excellent electrical conductors in solid state Metallic Bonds In metals, p-orbitals and some d-orbitals are completely vacant and overlap each atom. Electrons are delocalized – they don’t belong to any one atom anymore. 6 11/11/2016 Quick Review Ionic bonds are between – A) metals and non-metals – B) non-metals – C) metals Answer A) metals and non-metals Quick Review Covalent bonds are between – A) metals and non-metals – B) non-metals – C) metals Answer B) non-metals 7 11/11/2016 Quick Review Metallic bonds are between – A) metals and non-metals – B) non-metals – C) metals Answer C) metals Quick Review The strongest bonds are between – A) metals and non-metals – B) non-metals – C) metals Answer A) metals and non-metals (ionic) 8 11/11/2016 Quick Review Ionic bonds at room temperature are – A) solid – B) liquid – C) gas – D) any Answer A) solid Can you name some? Quick Review Covalent bonds at room temperature are – – – – A) solid B) liquid C) gas D) any Answer D) any Can you name some? HCl (aq), Bromine (aq), Fluorine (g), Diamond (s) 9 11/11/2016 Quick Review Metallic bonds at room temperature are – – – – A) solid B) liquid C) gas D) any Answer A) solid and B) liquid What metallic bonds can be liquid at room temperature? Hg Any ideas why? Bond strength not enough to make a solid yet strong enough to keep it from being a gas. Quick Review Which bonds are most likely to dissociate in water (water is polar) – A) ionic – B) polar covalent – C) nonpolar covalent – D) Metallic Answer A) ionic 10
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