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SECTION 6
THERMODYNAMIC PROPERTIES
6.1
ENTHALPIES AND GIBBS ENERGIES OF FORMATION, ENTROPIES, AND
HEAT CAPACITIES
6.1.1 Some Thermodynamic Relations
Table 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat
Capacities of Organic Compounds
Table 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at
Various Temperatures of Organic Compounds
Table 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat
Capacities of the Elements and Inorganic Compounds
Table 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at
Various Temperatures of the Elements and Inorganic Compounds
6.2 CRITICAL PHENOMENA
Table 6.5 Critical Properties
6.1
6.1
6.2
6.5
6.51
6.81
6.124
6.142
6.143
ENTHALPIES AND GIBBS ENERGIES OF
FORMATION, ENTROPIES, AND HEAT
CAPACITIES
The tables in this section contain values of the enthalpy and Gibbs energy of formation, entropy,
and heat capacity at 298.15 K (25⬚C). No values are given in these tables for metal alloys or other
solid solutions, for fused salts, or for substances of undefined chemical composition.
The physical state of each substance is indicated in the column headed “State” as crystalline solid
(c), liquid (lq), or gaseous (g). Solutions in water are listed as aqueous (aq).
The values of the thermodynamic properties of the pure substances given in these tables are, for
the substances in their standard states, defined as follows: For a pure solid or liquid, the standard
state is the substance in the condensed phase under a pressure of 1 atm (101 325 Pa). For a gas, the
standard state is the hypothetical ideal gas at unit fugacity, in which state the enthalpy is that of the
real gas at the same temperature and at zero pressure.
The values of ⌬f H⬚ and ⌬f G⬚ that are given in the tables represent the change in the appropriate
thermodynamic quantity when one mole of the substance in its standard state is formed, isothermally
at the indicated temperature, from the elements, each in its appropriate standard reference state. The
standard reference state at 25⬚C for each element has been chosen to be the standard state that is
thermodynamically stable at 25⬚C and 1 atm pressure. The standard reference states are indicated in
the tables by the fact that the values of ⌬f H⬚ and ⌬f G⬚ are exactly zero.
The values of S⬚ represent the virtual or “thermal” entropy of the substance in the standard state
at 298.15 K (25⬚C), omitting contributions from nuclear spins. Isotope mixing effects are also excluded except in the case of the 1H 9 2H system.
Solutions in water are designated as aqueous, and the concentration of the solution is expressed
in terms of the number of moles of solvent associated with 1 mol of the solute. If no concentration
is indicated, the solution is assumed to be dilute. The standard state for a solute in aqueous solution
is taken as the hypothetical ideal solution of unit molality (indicated as std. state or ss). In this state
6.1
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SECTION 6
the partial molal enthalpy and the heat capacity of the solute are the same as in the infinitely dilute
real solution.
For some tables the uncertainty of entries is indicated within parentheses immediately following
the value; viz., an entry 34.5(4) implies 34.5⫾0.4 and an entry 34.5(12) implies 34.5⫾1.2.
References: D. D. Wagman, et al., The NBS Tables of Chemical Thermodynamic Properties, in
J. Phys. Chem. Ref. Data, 11: 2, l982; M. W. Chase, et al., JANAF Thermochemical Tables, 3rd ed.,
American Chemical Society and the American Institute of Physics, 1986 (supplements to JANAF
appear in J. Phys. Chem. Ref. Data); Thermodynamic Research Center, TRC Thermodynamic Tables,
Texas A&M University, College Station, Texas; I. Barin and O. Knacke, Thermochemical Properties
of Inorganic Substances, Springer-Verlag, Berlin, 1973; J. B. Pedley, R. D. Naylor, and S. P. Kirby,
Thermochemical Data of Organic Compounds, 2nd ed., Chapman and Hall, London, 1986; V. Majer
and V. Svoboda, Enthalpies of Vaporization of Organic Compounds, International Union of Pure
and Applied Chemistry, Chemical Data Series No. 32, Blackwell, Oxford, 1985.
6.1.1
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Some Thermodynamic Relations
6.1.1.1 Enthalpy of Formation. Once standard enthalpies are assigned to the elements, it is
possible to determine standard enthalpies for compounds. For the reaction:
C(graphite) ⫹ O2(g) : CO2(g)
⌬H⬚ ⫽ ⫺393.51 kJ
(6.1)
Since the elements are in their standard states, the enthalpy change for the reaction is equal to the
standard enthalpy of CO2 less the standard enthalpies of C and O2, which are zero in each instance.
Thus,
⌬f H⬚ ⫽ ⫺393.51 ⫺ 0 ⫺ 0 ⫽ ⫺393.51 kJ
(6.2)
Tables of enthalpies, such as Tables 6.1 and 6.3, can be used to determine the enthalpy for any
reaction at 1 atm and 298.15 K involving the elements and any of the compounds appearing in the
tables.
The solution of 1 mole of HCl gas in a large amount of water (infinitely dilute real solution) is
represented by:
HCl(g) ⫹ inf H2O : H⫹(aq) ⫹ Cl⫺(aq)
(6.3)
The heat evolved in the reaction is ⌬H⬚ ⫽ ⫺74.84 kJ. With the value of ⌬f H⬚ from Table 6.3, one
has for the reaction:
⌬f H⬚ ⫽ ⌬f H⬚[H⫹(aq)] ⫹ ⌬f H⬚[Cl⫺(aq)] ⫺ ⌬f H⬚[HCl(g)]
(6.4)
for the standard enthalpy of formation of the pair of ions H⫹ and Cl⫺ in aqueous solution (standard
state, m ⫽ 1). To obtain the ⌬f H⬚ values for individual ions, the enthalpy of formation of H⫹(aq) is
arbitrarily assigned the value zero at 298.15 K. Thus, from Eq. (6.4):
⌬f H⬚[Cl⫺(aq)] ⫽ ⫺74.84 ⫹ (⫺92.31) ⫽ ⫺167.15 kJ
With similar data from Tables 6.1 and 6.3, the enthalpies of formation of other ions can be determined. Thus, from the ⌬f H⬚[KCl(aq, std. state, m ⫽ 1 or aq, ss)] of ⫺419.53 kJ and the foregoing
value for ⌬f H⬚[Cl⫺(aq, ss)]:
⌬f H⬚[K⫹(aq, ss)] ⫽ ⌬f H⬚[KCl(aq, ss)] ⫺ ⌬f H⬚[Cl⫺(aq, ss)]
⫽ ⫺419.53 ⫺(⫺167.15) ⫽ ⫺252.38 kJ
(6.5)
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THERMODYNAMIC PROPERTIES
6.1.1.2 Enthalpy of Vaporization (or Sublimation) When the pressure of the vapor in equilibrium with a liquid reaches 1 atm, the liquid boils and is completely converted to vapor on absorption
of the enthalpy of vaporization ⌬Hv at the normal boiling point Tb . A rough empirical relationship
between the normal boiling point and the enthalpy of vaporization (Trouton’s rule) is:
⌬Hv
⫽ 88 J · mol⫺1 · K⫺1
Tb
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(6.6)
It is best applied to nonpolar liquids which form unassociated vapors.
To a first approximation, the enthalpy of sublimation ⌬Hs at constant temperature is:
⌬Hs ⫽ ⌬Hm ⫹ ⌬Hv
(6.7)
where ⌬Hm is the enthalpy of melting.
The Clapeyron equation expresses the dynamic equilibrium existing between the vapor and the
condensed phase of a pure substance:
dP ⌬Hv
⫽
dT T⌬V
(6.8)
where ⌬V is the volume increment between the vapor phase and the condensed phase. If the condensed phase is solid, the enthalpy increment is that of sublimation.
Substitution of V ⫽ RT/P into the foregoing equation and rearranging gives the Clausius-Clapeyron equation,
dP
⌬Hv
⫽
P dT
RT 2
(6.9)
or
⌬Hv ⫽ ⫺R
d(ln P)
1/T
(6.10)
which may be used for calculating the enthalpy of vaporization of any compound provided its boiling
point at any pressure is known. If an Antoine equation is available (such as Eq. (5.1), page 5.30),
differentiation and insertion into the foregoing equation gives:
⌬Hv ⫽
4.5757T 2B
(T ⫹ C ⫺ 273.15)2
(6.11)
Inclusion of a compressibility factor into the foregoing equation, as suggested by the Haggenmacher equation improves the estimate of ⌬Hv:
⌬Hv ⫽
RT 2
P
冉 冊冉
dP
dT
1⫺
T c3 P
T 3Pc
冊
1/2
(6.12)
where Tc and Pc are critical constants (Table 6.5). Although critical constants may be unknown, the
compressibility factor is very nearly constant for all compounds belonging to the same family, and
an estimate can be deduced from a related compound whose critical constants are available.
6.1.1.3 Heat Capacity (or Specific Heat) The temperature dependence of the heat capacity is
complex. If the temperature range is restricted, the heat capacity of any phase may be represented
adequately by an expression such as:
Cp ⫽ a ⫹ bT ⫹ cT 2
(6.13)
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THERMODYNAMIC PROPERTIES
in which a, b, and c are empirical constants. These constants may be evaluated by taking three pieces
of data: (T1, Cp,1), (T2, Cp,2), and (T3, Cp,1), and substituting in the following expressions:
Cp,1
(T1 ⫺ T2 )(T1 ⫺ T3 )
⫹
Cp,2
(T2 ⫺ T1 )(T2 ⫺ T3 )
Cp,1 ⫺ Cp,2
T1 ⫺ T2
⫹
Cp,3
(T3 ⫺ T2 )(T3 ⫺ T1 )
⫽c
⫺ [(T1 ⫹ T2 )c] ⫽ b
(Cp,1 ⫺ bT1 ) ⫺ cT 21 ⫽ a
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(6.14)
(6.15)
(6.16)
Smoothed data presented at rounded temperatures, such as are available in Tables 6.2 and 6.4, plus
the Cp⬚ values at 298 K listed in Table 6.1 and 6.3, are especially suitable for substitution in the
foregoing parabolic equations. The use of such a parabolic fit is appropriate for interpolation, but
data extrapolated outside the original temperature range should not be sought.
6.1.1.4 Enthalpy of a System The enthalpy increment of a system over the interval of temperature
from T1 to T2 , under the constraint of constant pressure, is given by the expression:
H2 ⫺ H1 ⫽
冕
T2
T1
Cp dT
(6.17)
The enthalpy over a temperature range that includes phase transitions, melting, and vaporization, is
represented by:
H2 ⫺ H1 ⫽
冕
T2
T1
⫹
Cp(c,II) dT ⫹ ⌬Ht ⫹
冕
Tb
Tm
冕
冕
Cp(1q) dT ⫹ ⌬Hv ⫹
Tm
T1
Cp(c,I) dT ⫹ ⌬Hm
T2
Tb
Cp(g) dT
(6.18)
Integration of heat capacities, as expressed by Eq. (6.13), leads to:
⌬H ⫽ a(T2 ⫺ T1) ⫹
6.1.1.5
b(T22 ⫺ T21) c(T32 ⫺ T31)
⫹
2
3
(6.19)
Entropy In the physical change of state,
⌬Sm ⫽
⌬Hm
Tm
(6.20)
⌬Sv ⫽
⌬Hv
Tb
(6.21)
⌬Ss ⫽
⌬Hs
Ts
(6.22)
is the entropy of melting (or fusion),
is the entropy of vaporization, and
is the entropy of sublimation.
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THERMODYNAMIC PROPERTIES
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A general expression for the entropy of a system, involving any phase transitions, is
S2 ⫺ S1 ⫽
冕
Tt
Cp(c,II) dT
T
T1
⫹
冕
Tb
⫹
Cp(1q) dT
Tm
T
⌬Ht
⫹
T
⫹
冕
Tm
Cp(c,I) dT
T
Tb
⌬Hv
⫹
T
冕
Tm
⫹
⌬Hm
T
Cp(g) dT
Tb
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(6.23)
T
If Cp is independent of temperature,
⌬S ⫽ Cp(ln T2 ⫺ ln T1 ) ⫽ 2.303 Cp log
T2
T1
(6.24)
If the heat capacities change with temperature, an empirical equation like Eq. (6.13) may be inserted
in Eq. (6.23) before integration. Usually the integration is performed graphically from a plot of either
Cp /T versus T or Cp versus ln T.
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds
Substance
Acenaphthene
Acenaphthylene
Acetaldehyde
Acetaldoxime
Acetamide
Acetamidoguanidine nitrate
1-Acetamido-2-nitroguanidine
5-Acetamidotetrazole
Acetanilide
Acetic acid
ionized; std. state, m ⫽ 1
Acetic anhydride
Acetone
Acetonitrile
Acetophenone
Acetyl bromide
Acetyl chloride
Acetylene
Acetylene-d2
Acetylenedicarboxylic acid
Acetyl fluoride
1-Acetylimidazole
Acetyl iodide
Acridine
Adamantane
Physical
State
c
c
lq
g
c
lq
c
c
c
c
c
lq
g
aq
lq
lq
g
lq
g
lq
lq
lq
g
g
g
c
g
c
lq
c
c
⌬f H⬚
kJ · mol⫺1
70.34
186.7
⫺192.2
⫺166.1
⫺77.9
⫺81.6
⫺317.0
⫺494.0
⫺193.6
⫺5.0
⫺210.6
⫺484.4
⫺432.2
⫺486.34
⫺624.4
⫺248.4
⫺217.1
31.4
74.0
⫺142.5
⫺223.5
⫺272.9
⫺242.8
227.4
221.5
⫺578.2
⫺442.1
⫺574.0
⫺163.5
179.4
⫺194.1
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
188.9
Cp⬚
J · deg⫺1 · mol⫺1
160.4
263.8
190.4
166.4
89.0
55.3
115.0
91.3
⫺390.2
⫺374.2
⫺369.65
⫺489.14
⫺152.7
⫺152.7
86.5
91.9
⫺17.0
159.9
283.5
86.7
268.8
198.8
295.3
149.7
243.4
249.6
123.6
63.4
⫺6.3
168.230
126.3
74.5
91.5
52.2
204.6
⫺208.2
⫺205.8
209.0
205.9
201.0
295.1
201.0
208.9
117.0
67.8
44.1
49.3
⫺127.6
⫺133.0
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TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Adenine
(⫹)-Alanine
(⫺)-Alanine
(⫾)-Alanine
␤-Alanine
(⫾)-N-Alanylglycine
(⫺)-Alanylglycine
Allene
Alloxan monohydrate
Allylamine
Allyl tert-butyl sulfide
Allyl ethyl sulfone
Allyl methyl sulfone
Allyl trichloroacetate
Allyl (see Propene)
Aminetrimethylboron
3-Aminoacetophenone
4-Aminoacetophenone
2-Aminoacridine
9-Aminoacridine
2-Aminobenzoic acid
3-Aminobenzoic acid
4-Aminobenzoic acid
2-Aminobiphenyl
4-Aminobiphenyl
4-Aminobutanoic acid
2-Aminoethanesulfonic acid
ionized; std. state, m ⫽ 1
2-Aminoethanol
2-Aminohexanoic acid
(norleucine)
4-Aminohexanoic acid
5-Aminohexanoic acid
6-Aminohexanoic acid
(⫺)-2-Amino-3-hydroxybutanoic acid
2-Amino-2-(hydroxymethyl)1,1-propanediol
3-Aminonitroguanidine
5-Aminopentanoic acid
5-Aminotetrazole
3-Amino-1,2,4-triazole
Aniline
Anthracene
9,10-Anthraquinone
D-(⫺)-Arabinose [also (⫹)-]
(⫹)-Arginine
L-(⫹)-Ascorbic acid
L-(⫹)-Asparagine
L-(⫹)-Aspartic acid
Physical
State
⌬f H⬚
kJ · mol⫺1
c
c
c
c
c
c
c
g
c
lq
lq
lq
lq
lq
96.0
⫺561.2
⫺604.0
⫺563.6
⫺558.0
⫺777.8
⫺827.0
190.5
⫺1000.7
⫺10.0
⫺91.0
⫺406.0
⫺385.1
⫺395.3
c
c
c
c
c
c
c
c
c
c
c
c
aq
lq
c
⫺284.1
⫺173.3
⫺182.1
166.4
159.2
⫺400.9
⫺411.6
⫺412.9
112.2
81.2
⫺581.0
⫺785.9
⫺719.8
c
c
c
c
⫺646.2
⫺643.3
⫺639.1
⫺759.5
c
717.8
c
c
c
c
lq
g
c
c
c
c
c
c
c
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
299.6
⫺369.4
⫺370.5
⫺372.3
151.1
132.3
129.3
132.3
⫺489.9
⫺533.0
213.5
195.2
⫺762.3
186.7
⫺79.3
218.0
⫺562.3
⫺509.8
154.1
200.1
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Cp⬚
J · deg⫺1 · mol⫺1
147.0
140.7
195.5
⫺639.1
22.1
⫺604.1
⫺207.8
76.8
31.3
87.5
129.2
⫺207.5
⫺1057.9
⫺623.5
⫺1164.6
⫺789.4
⫺973.3
149.2
⫺7.0
286.0
191.4
317.9
207.6
191.9
107.9
210.5
⫺240.5
250.8
232.0
⫺530.6
⫺730.7
174.6
170.2
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THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
cis-Azobenzene
trans-Azobenzene
Azoisopropane
Azomethane
Azomethane-d6
Azopropane
Azulene
Barbituric acid
Benzaldehyde
Benzamide
Benzanilide
1,2-Benzanthracene
2,3-Benzanthracene
1,2-Benzanthracene9,10-dione
Benzene
Benzeneboronic acid
1,2-Benzenediamine
1,3-Benzenediamine
1,4-Benzenediamine
1,3-Benzenedicarboxylic acid
1,4-Benzenedicarboxylic acid
1,2,4,5-Benzenetetracarboxylic acid
Benzenethiol (thiophenol)
1,2,3-Benzenetricarboxylic acid
1,2,4-Benzenetricarboxylic acid
1,3,5-Benzenetricarboxylic acid
1,2,3-Benzenetriol
1,2,4-Benzenetriol
1,3,5-Benzenetriol
p-Benzidine
Benzil
Benzoic acid
Benzoic anhydride
Benzonitrile
Benzo[def]phenanthrene
Benzophenone
Benzo[f]quinoline
Benzo[h]quinoline
1,4-Benzoquinone
Benzo[b]thiophene
1,2,3-Benzotriazole
Benzotrifluoride
Benzoyl bromide
Benzoyl chloride
Benzoylformic acid
N-Benzoylglycine
Physical
State
⌬f H⬚
kJ · mol⫺1
c
c
g
g
g
g
g
c
lq
c
c
c
c
c
310.2
365.2
35.8
148.8
119.3
51.5
289.1
⫺637.2
⫺87.0
⫺202.6
⫺93.4
170.9
160.4
⫺231.9
lq
g
c
c
c
c
c
c
c
lq
g
c
c
c
c
c
c
c
c
c
c
lq
g
c
c
c
c
c
c
c
lq
lq
lq
c
c
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
Cp⬚
J · deg⫺1 · mol⫺1
239.7
218.3
289.9
305.7
78.0
90.6
353.4
338.1
128.5
9.4
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172.0
359.2
215.5
49.0
82.6
⫺720.1
⫺0.3
⫺7.8
3.1
803.0
816.1
1571.0
124.4
129.7
173.4
269.2
136.0
82.4
63.7
111.3
⫺1160.0
⫺1179.0
⫺1190.0
⫺551.1
⫺563.8
⫺584.6
70.7
⫺153.9
⫺385.2
⫺415.4
163.2
215.8
125.5
⫺34.5
150.6
149.7
⫺185.7
100.6
250.0
⫺636.7
⫺107.3
⫺158.0
⫺482.4
⫺609.8
134.0
147.6
222.8
336.9
173.2
104.9
⫺245.3
167.6
146.8
260.8
269.5
140.2
209.1
321.0
224.8
245.2
165.2
109.1
236.0
224.8
⫺83.6
162.8
129.0
⫺369.57
239.3
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TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Benzoyl iodide
3,4-Benzphenanthrene
Benzylamine
Benzyl alcohol
Benzyl bromide
Benzyl chloride
N-Benzyldiphenylamine
Benzyl ethyl sulfide
Benzyl iodide
Benzyl methyl ketone
Benzyl methyl sulfide
Bicyclo[1.1.0]butane
Bicyclo[2.2.1]hepta2,5-dione
Bicyclo[2.2.1]heptane
Bicyclo[4.1.0]heptane
Bicyclo[2.2.1]heptene
Bicyclo[3.1.0]hexane
Bicyclohexyl
Bicyclo[2.2.2]octane
Bicyclo[4.2.0]octane
Bicyclo[5.1.0]octane
Bicyclo[2.2.2]oct-2-ene
Bicyclopropyl
Biphenyl
2-Biphenylcarboxylic acid
(1,1⬘-Biphenyl)-4,4⬘diamine
Biphenylene
Bis(2-chloroethyl) ether
Bis(dimethylthiocarbonyl)
disulfide
Bis(2-hydroxyethyl) ether
Bromoacetone
Bromoacetylene
Bromobenzene
4-Bromobenzoic acid
1-Bromobutane
2-Bromobutane
Bromochlorodifluoromethane
1-Bromo-2-chloroethane
Bromochlorofluoromethane
Bromochloromethane
1-Bromo-2-chloro-1,1,2trifluoroethane
2-Bromo-2-chloro-1,1,1trifluoroethane
1-Bromodecane
Physical
State
⌬f H⬚
kJ · mol⫺1
lq
c
lq
lq
lq
lq
c
lq
lq
lq
lq
g
lq
⫺53.5
184.9
34.2
⫺160.7
16.0
⫺32.6
184.7
⫺4.9
57.3
⫺151.9
26.2
217.1
213.0
c
lq
lq
g
lq
c
g
g
g
g
c
c
c
⫺95.1
⫺36.7
90.0
38.6
⫺273.7
⫺146.9
⫺26.2
⫺16.6
⫺23.3
129.3
99.4
⫺349.0
70.7
c
lq
c
334.0
lq
g
g
g
lq
c
lq
lq
g
g
lq
g
lq
g
g
⫺1621.0
⫺571.1
⫺181.0
g
⫺690.4
lq
⫺344.7
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
⫺27.5
216.7
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
218.0
182.4
203.9
254.2
130.0
209.4
198.4
220.9
41.6
126.0
441.0
135.1
253.7
219.2
55.7
154.3
60.9
⫺378.3
⫺143.8
⫺154.8
⫺120.3
⫺471.5
⫺12.9
⫺19.25
⫺25.8
⫺448.4
369.8
109.3
370.3
318.5
⫺295.0
⫺278.6
304.3
110.8
74.6
130.127
63.2
52.7
⫺50.2
⫺644.8
⫺39.3
287.6
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.9
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Bromodichlorofluoromethane
Bromodichloromethane
Bromodifluoromethane
Bromoethane
Bromoethylene (vinyl bromide)
Bromofluoromethane
1-Bromoheptane
1-Bromohexane
Bromoiodomethane
Bromomethane
2-Bromo-2-methylpropane
1-Bromooctane
Bromopentafluoroethane
1-Bromopentane
1-Bromopropane
2-Bromopropane
cis-1-Bromopropene
3-Bromopropene
N-Bromosuccinimide
␣-Bromotoluene
Bromotrichloromethane
Bromotrifluoroethane
Bromotrifluoromethane
Bromotrimethylsilane
Bromotrinitromethane
Brucine
1,2-Butadiene
1,3-Butadiene
1,3-Butadiyne
Butanal
Butanamide
Butane
1,2-Butanediamine
(⫾)-1,2-Butanediol
1,3-Butanediol
1,4-Butanediol
2,3-Butanediol
Butanedinitrile
2,3-Butanedione
1,4-Butanedithiol
Physical
State
g
g
g
lq
g
lq
g
g
lq
lq
g
lq
g
lq
g
lq
g
lq
g
lq
g
lq
g
g
g
c
lq
g
g
g
lq
g
c
g
lq
g
g
lq
g
lq
lq
g
lq
lq
lq
lq
lq
c
lq
lq
lq
⌬f H⬚
kJ · mol⫺1
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
Cp⬚
J · deg⫺1 · mol⫺1
⫺269.5
⫺58.6
⫺424.9
⫺90.5
⫺61.9
⫺246.8
⫺42.5
⫺447.3
⫺25.8
⫺23.9
330.6
316.4
295.1
198.7
286.7
79.2
⫺252.7
⫺218.4
⫺194.2
50.2
81.7
⫺241.5
275.8
276.3
80.0
67.4
58.7
100.8
64.5
107.715
55.4
49.2
39.2
453.0
307.5
⫺35.4
⫺163.8
⫺132.4
⫺245.1
⫺1064.4
⫺170.2
⫺129.0
⫺121.8
⫺87.0
⫺130.5
⫺99.4
40.8
45.2
⫺335.9
23.4
⫺41.1
⫺694.5
⫺648.3
⫺325.9
80.3
⫺496.2
162.3
88.5
110.0
472.8
⫺239.2
⫺204.9
⫺346.9
⫺26.3
246.4
⫺28.2
332.0
⫺5.7
408.8
⫺22.5
330.9
⫺27.2
316.2
132.2
89.4
⫺12.4
332.8
85.3
297.8(5)
69.3
⫺125.6
⫺120.2
⫺523.6
⫺501.0
⫺503.3
⫺541.5
139.7
top of rh
base of rh
cap height
base of text
203.5
78.77
42.5
151.0
116.5
132.2
86.4
⫺622.6
199.5
150.7
444.0
293.0
199.0
278.7
250.0
⫺114.8
243.7
80.1
123.6
79.5
73.6
163.7
103.4
⫺17.2
310.1
104.5⫺0.5
97.5
223.4
227.230
200.1
213.0
160.562
⫺365.8
⫺105.7
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.10
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Butanenitrile
1-Butanethiol
2-Butanethiol
Butanoic acid
Butanoic anhydride
1-Butanol
(⫾)-2-Butanol
2-Butanone
Butanophenone
trans-2-Butenal
cis-Butenedinitrile
1-Butene
cis-2-Butene
trans-2-Butene
cis-2-Butenenitrile
trans-2-Butenenitrile
3-Butenenitrile
cis-2-Butenoic acid
trans-2-Butenoic acid
cis-2-Butenedioic acid
trans-2-Butenedioic acid
1-Buten-3-yne
2-Butoxyethanol
N-Butylacetamide
Butyl acetate
Butylamine
sec-Butylamine
tert-Butylamine
Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
sec-Butyl butanoate
Butyl chloroacetate
Butyl 2-chlorobutanoate
Butyl 3-chlorobutanoate
Butyl 4-chlorobutanoate
Butyl 2-chloropropanoate
Butyl 3-chloropropanoate
Butyl crotonate
Butylcyclohexane
Physical
State
lq
g
lq
lq
lq
lq
lq
g
lq
g
lq
g
lq
lq
c
lq
g
lq
g
g
lq
lq
g
lq
c
c
c
g
lq
lq
lq
lq
g
lq
g
g
g
lq
g
lq
lq
lq
lq
lq
lq
lq
lq
lq
lq
lq
g
⌬f H⬚
kJ · mol⫺1
⫺5.8
33.6
⫺124.7
⫺131.0
⫺533.8
⫺327.3
⫺275.0
⫺342.6
⫺292.9
⫺273.3
⫺238.5
⫺188.9
⫺138.7
268.2
⫺20.8
0.1
⫺29.8
⫺7.1
⫺11.4
95.1
95.1
159.7
⫺347.0
⫺430.5
⫺788.7
⫺811.1
304.6
⫺380.8
⫺529.2
⫺127.7
⫺92.0
⫺137.5
⫺104.6
⫺150.6
⫺121.0
63.2
⫺13.1
⫺66.4
⫺70.7
⫺492.6
⫺538.4
⫺655.2
⫺610.9
⫺618.0
⫺572.0
⫺558.2
⫺467.8
⫺263.1
⫺213.4
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
108.7
4.1
⫺0.17
⫺377.7
325.4
276.0
271.4
222.2
⫺162.5
⫺150.8
⫺177.0
⫺167.6
⫺151.4
225.8
362.8
214.9
359.5
239.1
339.9
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
15967
97.0
171.2
178.6
283.7
177.0
122.6
196.9
113.3
158.9
101.7
95.4
65.9
63.0
227.0
305.6
219.9
300.8
296.5
118.0
85.7
127.0
78.9
87.8
193.4
298.4
82.1
306.0
279.4
73.2
281.0
71.3
49.2
363.3
40.7
351.3
28.9
337.9
144.7
439.5
227.8
179.2
118.6
117.2
192.1
120.0
243.4
416.3
238.0
56.4
345.0
458.5
271.0
207.1
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.11
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Butylcyclopentane
Butyl dichloroacetate
Butyl ethyl ether
Butyl ethyl sulfide
(3-thiaheptane)
tert-Butyl ethyl sulfide
Butyl formate
tert-Butyl hydroperoxide
Butyllithium
Butyl methyl ether
tert-Butyl methyl ether
Butyl methyl sulfide
(2-thiahexane)
tert-Butyl methyl sulfide
Butyl methyl sulfone
tert-Butyl methyl sulfone
cis-Butyl 9-octadecanoate
tert-Butyl peroxide
Butyl trichloroacetate
Butylurea
Butyl vinyl ether
1-Butyne
2-Butyne
2-Butynedinitrile
2-Butynedioic acid
3-Butynoic acid
␥-Butyrolactone
(⫹)-Camphor
⑀-Caprolactam
9H-Carbazole
Carbonyl bromide
Carbonyl chloride
Carbonyl chloride fluoride
Carbonyl fluoride
Chloroacetamide
Chloroacetic acid
Chloroacetyl chloride
Chloroacetylene
2-Chlorobenzaldehyde
3-Chlorobenzaldehyde
4-Chlorobenzaldehyde
Chlorobenzene
2-Chlorobenzoic acid
3-Chlorobenzoic acid
4-Chlorobenzoic acid
Chloro-1,4-benzoquinone
1-Chlorobutane
(⫾)-2-Chlorobutane
2-Chlorobutanoic acid
Physical
State
⌬f H⬚
kJ · mol⫺1
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
g
lq
lq
g
⫺168.3
⫺550.2
61.4
456.2
177.5
⫺125.2
32.0
453.0
159.0
162.0
lq
lq
lq
lq
lq
lq
lq
⫺187.3
lq
lq
c
lq
lq
lq
c
lq
g
g
g
c
c
lq
c
c
c
g
g
g
g
c
c
lq
g
lq
lq
c
lq
c
c
c
c
lq
g
lq
g
lq
top of rh
base of rh
200.2
⫺293.6
⫺132.2
⫺290.6
⫺313.6
⫺142.8
⫺156.9
⫺535.8
⫺556.0
⫺816.9
⫺380.9
⫺545.8
⫺419.5
⫺218.8
165.2
145.7
529.2
⫺577.4
⫺241.8
⫺420.9
⫺319.4
⫺329.4
101.7
⫺96.2
⫺219.1
17.1
202.1
185.4
295.3
265.3
307.5
192.7
187.5
200.9
276.1
199.9
290.8
283.3
232.0
81.4
78.0
141.4
271.2
⫺110.9
⫺204.9
309.1
283.5
276.7
61.8
57.7
52.4
46.8
242.0
54.3
209.2
150.2
⫺639.8
⫺338.5
⫺510.5
⫺283.7
⫺118.4
⫺126.0
⫺146.4
11.0
⫺404.5
⫺423.3
⫺428.9
⫺220.6
⫺188.1
⫺154.6
⫺192.8
⫺161.2
⫺575.5
89.2
163.2
⫺38.8
358.1
175.0
107.6
⫺53.5
359.6
108.5
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.12
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
3-Chlorobutanoic acid
4-Chlorobutanoic acid
Chlorocyclohexane
1-Chloro-1,1-difluoroethane
1-Chloro-2,2-difluoroethylene
2-Chloro-1,1-difluoroethylene
Chlorodifluoromethane
2-Chloro-1,4-dihydroxybenzene
Chlorodimethylsilane
1-Chloro-2,3-epoxypropane
1-Chloroethane
2-Chloroethanol
1-Chloro-2-ethylbenzene
1-Chloro-4-ethylbenzene
Chloroethylene (vinyl chloride)
2-Chloroethyl ethyl ether
2-Chloroethyl vinyl ether
Chloroethyne
1-Chloro-1-fluoroethane
2-Chlorohexane
Chlorofluoromethane
Chlorohydroquinone
Chloroiodomethane
Chloromethane
1-Chloro-3-methylbutane
2-Chloro-2-methylbutane
2-Chloro-3-methylbutane
1-Chloro-2-methylpropane
2-Chloro-2-methylpropane
1-Chloronaphthalene
2-Chloronaphthalene
1-Chlorooctane
Chloropentafluoroacetone
Chloropentafluoroethane
1-Chloropentane
3-Chlorophenol
4-Chlorophenol
1-Chloropropane
2-Chloropropane
Physical
State
lq
lq
lq
lq
g
g
g
lq
g
c
lq
lq
lq
g
lq
lq
lq
lq
g
g
g
g
g
lq
g
c
g
lq
g
lq
g
g
g
lq
g
lq
g
lq
c
lq
g
lq
g
lq
g
c
c
lq
g
lq
g
⌬f H⬚
kJ · mol⫺1
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
⫺315.5
⫺331.4
⫺289.1
⫺305.0
307.2
303.0
302.4
⫺482.6
⫺382.81
⫺79.8
⫺148.5
⫺136.8
⫺112.1
⫺295.4
⫺54.1
⫺51.7
⫺450.0
281.0
⫺59.3
⫺60.5
190.8
275.8
125.1
104.3
62.6
53.6
263.9
89.4
53.7
197.0
241.9
54.3
⫺265.5
264.3
47.0
15.4
296.1
⫺58.5
234.6
⫺49.7
355.0
⫺64.1
322.2
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
⫺556.3
⫺566.3
⫺207.2
37.3
⫺301.3
⫺170.1
213.0
⫺313.4
⫺246.1
⫺290.8
⫺382.8
12.6
⫺81.9
⫺216.0
⫺179.7
⫺202.2
⫺185.1
⫺191.1
⫺159.4
⫺211.2
⫺182.2
54.6
55.2
⫺291.3
⫺1121.0
130.521
82.5
72.1
93.0⫺41
55.9
75.6⫺24
40.8
175.1
158.6
108.5
172.8
114.2
212.6
198.5
184.2
⫺1188.8
⫺213.2
⫺175.0
⫺206.4
⫺197.9
⫺160.6
⫺131.9
⫺172.1
⫺144.9
⫺37.4
397.0
130.5
⫺50.7
319.1
132.2
84.6
⫺62.5
304.2
87.3
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.13
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
2-Chloro-1,3-propanediol
3-Chloro-1,2-propanediol
2-Chloropropanoic acid
3-Chloropropanoic acid
2-Chloro-1-propene
3-Chloro-1-propene (allyl
chloride)
N-Chlorosuccinimide
␣-Chlorotoluene
o-Chlorotoluene
2-Chloro-1,1,1-trifluoroethane
Chlorotrifluoroethylene
Chlorotrifluoromethane
Chlorotrimethylsilane
Chlorotrinitromethane
Chrysene
(⫺)-Cinchonidine
Cinchonine
cis-Cinnamic acid
trans-Cinnamic acid
Cinnamic anhydride
Citric acid
Codeine monohydrate
Creatine
o-Cresol
m-Cresol
p-Cresol
Cuban
Cyanamide
Cyanide (CN)
Cyanogen
Cyanogen bromide
Cyanogen chloride
Cyanogen fluoride
Cyanogen iodide
Cyclobutane
Cyclobutanecarbonitrile
Cyclobutene
Cyclobutylamine
Cyclododecane
1,3-Cycloheptadiene
Cycloheptane
Physical
State
⌬f H⬚
kJ · mol⫺1
lq
lq
lq
c
g
lq
⫺517.5
⫺525.3
⫺522.5
⫺549.3
⫺21.0
g
c
lq
lq
g
⫺0.63
⫺358.1
⫺32.6
g
g
lq
lq
g
c
c
c
c
c
c
c
c
c
c
lq
g
lq
g
c
lq
g
c
c
g
g
g
g
g
c
g
g
lq
g
g
c
g
lq
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
top of rh
base of rh
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
131.6
125.1
⫺505.5
⫺707.8
⫺384.1
⫺27.1
18.4
145.3
29.7
31.0
⫺315.0
⫺338.5
⫺347.7
⫺1543.9
⫺632.6
⫺537.2
⫺204.6
⫺128.6
⫺194.0
⫺132.3
⫺199.3
⫺125.4
541.3
58.8
437.6
306.7
140.5
138.0
⫺639.8
166.2
205.5
27.7
103.0
156.7
41.2
⫺306.6
94.3
⫺156.6
43.6
306.7
75.4
326.4
166.8
154.6
⫺523.8
⫺667.4
322.1
285.4
83.9
66.9
⫺1236.4
166.2
165.4
37.1
⫺40.5
⫺30.9
407.5
297.2
165.3
131.0
357.6
212.6
356.8
167.3
347.6
154.6
233.640
130.3
224.9
122.5
150.2
221.040
124.5
29.2
56.9
46.9
45.0
41.8
185.0
196.6
110.0
202.6
241.9
248.3
236.2
224.7
96.2
256.8
265.4
174.7
263.5
67.1
54.1
242.6
123.1
48.3
72.2
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.14
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Cycloheptanone
1,3,5-Cycloheptatriene
Cycloheptene
Cyclohexane
cis-Cyclohexane-1,2dicarboxylic acid
trans-Cyclohexane-1,2dicarboxylic acid
Cyclohexanethiol
Cyclohexanol
Cyclohexanone
Cyclohexene
1-Cyclohexenylmethanol
Cyclohexylamine
Cyclohexylbenzene
Cyclohexylcyclohexane
Cyclooctane
Cyclooctanone
1,3,5,7-Cyclooctatetraene
Cyclooctene
1,3-Cyclopentadiene
Cyclopentane
cis-1,2-Cyclopentanediol
trans-1,2-Cyclopentanediol
Cyclopentanethiol
Cyclopentanol
Cyclopentanone
Cyclopentene
1-Cyclopentenylmethanol
Cyclopentylamine
Cyclopropane
Cyclopropanecarbonitrile
Cyclopropene
Cyclopropylamine
Cyclopropylbenzene
(⫺)-Cysteine
(⫺)-Cystine
Cytosine
Decafluorobutane
cis-Decahydronaphthalene
trans-Decahydronaphthalene
Decanal
Decane
Decanedioic acid
1,10-Decanediol
Physical
State
⌬f H⬚
kJ · mol⫺1
lq
lq
g
lq
g
c
⫺299.4
142.2
⫺9.2
⫺156.4
⫺123.4
⫺961.1
c
⫺970.7
lq
g
lq
lq
g
lq
lq
lq
lq
lq
lq
lq
lq
lq
g
lq
g
c
c
lq
lq
lq
lq
g
lq
lq
g
g
g
lq
g
lq
c
c
c
lq
lq
lq
g
lq
c
c
⫺140.7
⫺96.1
⫺348.1
⫺271.2
⫺226.1
⫺38.5
⫺382.4
⫺147.7
⫺76.6
⫺329.3
⫺167.7
⫺326.0
254.5
⫺74.0
134.3
⫺105.1
⫺76.4
⫺484.9
⫺489.9
⫺89.5
⫺300.1
⫺235.7
4.4
34.0
34.3
⫺95.1
53.3
182.8
277.1
45.8
77.0
100.3
⫺534.1
⫺1032.7
⫺221.3
⫺219.4
⫺230.6
⫺330.9
⫺300.9
⫺1082.8
⫺693.5
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
Cp⬚
J · deg⫺1 · mol⫺1
243.1
214.6
162.8
26.7
31.8
204.4
298.3
154.9
106.3
255.6
192.6
199.6
255.6
322.2
214.6
208.2
182.2
109.7
148.3
⫺133.3
⫺90.8
101.6
cap height
base of text
261.3
358.6
220.3
184.0
179.3
36.4
38.6
267.8
204.3
292.9
128.9
83.0
46.8
⫺127.8
256.9
206.3
108.5
110.8
201.3
291.8
165.2
184.1
154.5
122.4
75.1
104.4
241.0
237.4
181.2
55.6
223.3
187.7
147.1
286.3
132.6
68.9
57.7
⫺66.5
17.5
265.0
265.0
578.6
425.5
127.220
232.0
228.5
239.7
314.4
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.15
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
1-Decanenitrile
1-Decanethiol
Decanoic acid
1-Decanol
1-Decene
1-Decyne
Deoxybenzoin
Diacetamide
Diacetyl peroxide
1,2-Diallyl phthalate
2,2⬘-Diaminodiethylamine
2,6-Diaminopyridine
Diazomethane
Dibenz[de,kl]anthracene
1,2-Dibenzoylethane
trans-1,2-Dibenzoylethylene
Dibenzoylmethane
Dibenzoyl peroxide
Dibenzyl
Dibenzyl sulfide
Dibenzyl sulfone
1,2-Dibromobutane
1,3-Dibromobutane
1,4-Dibromobutane
2,3-Dibromobutane
Dibromochlorofluoromethane
Dibromochloromethane
1,2-Dibromo-1-chloro-1,2,2trifluoroethane
1,2-Dibromocycloheptane
1,2-Dibromocyclohexane
1,2-Dibromocyclooctane
Dibromodifluoroethane
Dibromodichloromethane
Dibromodifluoromethane
1,1-Dibromoethane
1,2-Dibromoethane
cis-1,2-Dibromoethylene
trans-1,2-Dibromoethylene
Dibromofluoromethane
Dibromomethane
1,3-Dibromo-2-methylpropane
1,3-Dibromotetrafluoroethane
1,2-Dibromopropane
1,2-Dibromotetrafluoroethane
Physical
State
lq
lq
g
c
lq
lq
g
c
c
lq
lq
lq
c
g
c
c
c
c
c
c
c
c
g
lq
g
g
g
g
lq
g
lq
lq
lq
g
g
g
lq
lq
g
g
g
g
lq
g
g
lq
g
lq
g
lq
⌬f H⬚
kJ · mol⫺1
⫺158.4
⫺276.5
⫺211.5
⫺713.7
⫺478.1
⫺173.8
41.2
⫺71.0
⫺489.0
⫺535.3
⫺550.6
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
top of rh
base of rh
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
61.4
476.1
610.1
350.4
255.6
⫺132.2
105.0
252.2
430.5
425.0
524.5
370.6
300.8
219.7
25440
⫺6.5
192.5
182.8
⫺255.6
⫺114.7
⫺223.5
⫺369.6
44.1
99.0
⫺282.6
⫺91.5
⫺148.0
⫺87.8
⫺102.0
⫺231.8
⫺20.9
⫺691.7
217.8
242.8
109.8
319.2
260.0
269.4
255.2
⫺13.1
408.8
127.1
⫺223.4
⫺18.8
342.8
327.7
82.4
69.2
⫺19.5
⫺419.1
327.7
347.8
325.3
80.8
87.1
77.0
⫺20.9
223.3
136.0
⫺223.4
⫺221.1
313.3
313.5
316.8
⫺14.8
⫺137.6
⫺817.7
⫺789.1
⫺16.2
293.2
68.8
70.3
65.1
105.3
54.7
⫺71.5
⫺17.7
376.1
⫺656.6
⫺157.6
⫺162.8
⫺173.3
⫺36.9
⫺29.3
⫺429.7
⫺66.2
⫺79.2
⫺37.5
52.5
160.0
102.8
180.3
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.16
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Dibutoxymethane
Dibutylamine
Dibutyl disulfide
Di-tert-butyl disulfide
Dibutyl ether
Di-sec-butyl ether
Di-tert-butyl ether
Dibutylmercury
Dibutyl peroxide
Dibutyl 1,2-phthalate
Dibutyl sulfate
Dibutyl sulfide
Di-tert-butyl sulfide
Dibutyl sulfite
Dibutyl sulfone
Dichloroacetic acid
ionized
Dichloroacetyl chloride
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,3-Dichlorobutane
1,4-Dichlorobutane
Dichlorodimethylsilane
Dichlorodiphenylsilane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethylene
cis-1,2-Dichloroethylene
trans-1,2-Dichloroethylene
Dichlorofluoromethane
1,1-Dichloro-1-fluoroethane
1,1-Dichlorofluoroethylene
1,1-Dichlorofluoromethane
Dichloromethane
Dichloropentadienyliron
1,2-Dichloropropane
Physical
State
lq
lq
g
lq
lq
g
lq
g
lq
g
lq
lq
c
lq
lq
lq
lq
c
lq
aq
lq
lq
g
lq
g
c
lq
g
lq
g
g
g
g
lq
lq
g
lq
g
lq
g
g
lq
g
g
g
g
lq
lq
g
c
lq
⌬f H⬚
kJ · mol⫺1
⫺549.4
⫺206.0
⫺160.6
⫺255.2
⫺377.9
⫺332.8
⫺401.5
⫺360.9
⫺399.6
⫺362.0
⫺97.9
⫺380.7
⫺842.6
⫺904.6
⫺220.7
⫺232.4
⫺693.1
⫺610.2
⫺496.3
⫺507.1
⫺280.4
⫺17.5
30.2
⫺20.7
25.7
⫺42.3
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
Cp⬚
J · deg⫺1 · mol⫺1
53.9
572.8
292.9
231.1
⫺88.5
500.4
278.2
204.0
276.1
498.0
32.2
405.1
82.7
341.5
78.6
343.5
22.5
77.2
175.4
336.7
⫺477.4
⫺195.0
⫺183.4
⫺461.1
⫺278.2
⫺158.4
⫺127.7
⫺167.4
⫺126.4
⫺23.9
2.8
4.6
⫺23.1
5.0
⫺283.0
⫺439.4
300.8
147.8
113.9
117.2
72.3
335.4
101.1
⫺124.2
⫺95.4
141.0
⫺198.8
cap height
base of text
⫺73.8
305.1
⫺73.9
308.4
25.4
24.4
289.1
289.5
28.6
⫺253.0
289.9
293.1
320.2
313.9
⫺68.9
177.8
270.3
284.3
162.4
113.5
171
113.8
126.3
76.2
128.4
78.7
111.3
67.0
65.1
116.8
66.7
6l.0
88.7
76.5
112.6
101.2
51.0
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.17
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
1,3-Dichloropropane
2,2-Dichloropropane
1,3-Dichloro-2-propanol
2,3-Dichloro-1-propanol
2,3-Dichloropropene
1,2-Dichlorotetrafluoromethane
2,2-Dichlorotetrafluoroethane
2,2-Dichloro-1,1,1-trifluoroethane
Dicyanoacetylene
Dicyanobenzene
1,4-Dicyanobutane
1,4-Dicyano-2-butyne
Dicyanodiamide
Dicyclopentadiene
Diethanolamine
1,1-Diethoxyethane
1,2-Diethoxyethane
Diethoxymethane
1,3-Diethoxypropane
2,2-Diethoxypropane
Diethylamine
Diethylamine hydrochloride
Diethylbarbituric acid
(veronal)
1,2-Diethylbenzene
1,3-Diethylbenzene
1,4-Diethylbenzene
Diethyl carbonate
cis-1,2-Diethylcyclopropane
trans-1,2-Diethylcyclopropane
Diethyl disulfide
Diethylenediamine
Diethylene glycol
Diethylene glycol dibutyl ether
Diethylene glycol diethyl
ether
Diethylene glycol dimethyl
ether
Diethylene glycol monoethyl
ether
Diethylene glycol monomethyl
ether
Diethyl ether
Physical
State
⌬f H⬚
kJ · mol⫺1
g
g
g
lq
lq
lq
lq
g
lq
g
⫺162.8
⫺159.2
⫺173.2
⫺385.4
⫺381.3
⫺73.3
lq
c
lq
c
c
c
c
lq
lq
lq
lq
lq
lq
lq
g
c
c
500.4
275.4
85.1
366.5
22.6
116.7
⫺493.8
g
g
g
lq
lq
lq
lq
g
c
lq
g
lq
lq
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
⫺83.1
⫺82.6
⫺84.6
354.8
367.2
326.0
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
98.2
99.6
105.9
164.2
⫺916.3
⫺960.2
352.8
⫺491.4
⫺451.4
⫺450.4
⫺482.1
⫺538.5
⫺103.7
⫺72.2
⫺358.6
⫺747.7
⫺19.0
⫺21.8
⫺22.3
⫺681.5
⫺79.9
83.3
⫺120.0
⫺79.4
⫺13.4
⫺628.5
⫺571.1
111.7
102.5
128.7
179.5
129.3
118.8
233.530
238.0
259.4
169.2
115.7
72.1
352.2
141.1
136.7
137.9
434.3
439.3
434.0
182.6
176.9
176.2
212.4
9.5
22.3
240.2
269.3
414.5
85.8
171.4
141.3
441.0
244.8
135.1
45220
341.415
lq
274.1
lq
301.0
lq
271.1
lq
g
top of rh
base of rh
⫺279.5
⫺252.1
⫺116.7
⫺122.3
172.4
342.7
172.6
119.5
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.18
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Di-2-ethylhexyl phthalate
Diethyl malonate
Diethylmercury
Diethyl oxalate
3,3-Diethylpentane
Diethyl peroxide
Diethyl 1,2-phthalate
Diethyl selenide
Diethyl sulfate
Diethyl sulfide
Diethyl sulfite
Diethyl sulfone
Diethyl sulfoxide
N,N-Diethylurea
Diethylzinc
1,2-Difluorobenzene
1,3-Difluorobenzene
1,4-Difluorobenzene
2,2⬘-Difluorobiphenyl
4,4⬘-Difluorobiphenyl
1,1-Difluoroethane
1,1-Difluoroethylene
Difluoromethane
9,10-Dihydroanthracene
1,2-Dihydronaphthalene
1,4-Dihydronaphthalene
Dihydro-2H-pyran
5,12-Dihydrotetracene
2,3-Dihydrothiophene
2,5-Dihydrothiophene
2,5-Dihydrothiophene-1,1dioxide
2⬘,4-Dihydroxyacetophenone
1,2-Dihydroxybenzene
(pyrocatechol)
1,3-Dihydroxybenzene
1,4-Dihydroxybenzene
(p-hydroquinone)
Dihydroxymalonic acid
2,4-Dihydroxy-5-methylpyrimidine
2,4-Dihydroxy-6-methylpyrimidine
Diiodoacetylene
1,2-Diiodobenzene
Physical
State
lq
lq
lq
lq
lq
lq
lq
lq
lq
lq
g
lq
c
lq
c
lq
lq
g
lq
g
lq
g
c
c
lq
g
g
g
c
lq
lq
lq
c
lq
g
g
c
⌬f H⬚
kJ · mol⫺1
⫺805.5
30.1
⫺805.5
⫺275.4
⫺223.3
⫺776.6
⫺96.2
⫺813.2
⫺119.4
⫺83.6
⫺600.7
⫺515.5
⫺268.0
⫺372.2
16.7
⫺330.0
⫺293.8
⫺343.9
⫺309.2
⫺342.3
⫺306.7
⫺295.9
⫺296.5
⫺497.0
⫺335.0
⫺452.2
66.4
71.5
84.2
⫺157.4
106.4
52.9
90.7
86.9
318.9
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
704.7
260.7
182.8
278.2
425.1
366.1
269.3
368.0
171.4
117.0
⫺257.0
222.6
321.9
223.8
320.4
⫺252.8
315.6
159.0
106.5
159.1
106.3
157.5
106.9
⫺443.0
⫺321.5
⫺425.4
282.4
266.2
246.6
118.4
67.8
60.1
42.9
133.5
131.6
303.5
297.1
79.8
83.3
17.8
⫺242.0
c
c
⫺573.6
⫺354.1
⫺210.0
150.2
132.2
c
c
⫺368.0
⫺364.5
⫺209.2
⫺207.0
147.7
140.2
131.0
136.0
c
c
⫺1216.3
⫺468.2
c
⫺456.9
g
c
313.1
70.3
172.4
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.19
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
1,3-Diiodobenzene
1,4-Diiodobenzene
1,2-Diiodoethane
Diiodomethane
1,2-Diiodopropane
1,3-Diiodopropane
Diisobutylamine
Diisopentyl ether
Diisopropylamine
Diisopropyl ether
Diisopropylmercury
Diisopropyl sulfide
Diketene
1,2-Dimethoxybenzene
1,1-Dimethoxybutane
2,2-Dimethoxybutane
1,1-Dimethoxyethane
1,2-Dimethoxyethane
Dimethoxymethane
1,1-Dimethoxypentane
2,2-Dimethoxypentane
1,1-Dimethoxypropane
2,2-Dimethoxypropane
1,1-Dimethoxy-2-methylpropane
N,N-Dimethylacetamide
Dimethylamine
4-(Dimethylamino)benzaldehyde
Dimethylaminomethanol
N,N-Dimethylaminotrimethylsilane
N,N-Dimethylaniline
2,6-Dimethylaniline
2,3-Dimethylbenzoic acid
2,4-Dimethylbenzoic acid
2,5-Dimethylbenzoic acid
2,6-Dimethylbenzoic acid
3,4-Dimethylbenzoic acid
3,5-Dimethylbenzoic acid
3,3⬘-Dimethylbiphenyl
2,2-Dimethylbutane
2,3-Dimethylbutane
3,3-Dimethyl-2-butanone
Physical
State
⌬f H⬚
kJ · mol⫺1
c
lq
c
g
lq
g
g
lq
lq
lq
lq
lq
g
lq
lq
g
lq
lq
lq
lq
lq
lq
lq
lq
lq
lq
lq
lq
187.0
⫺30.0
160.7
75.0
66.9
119.5
35.6
⫺9.0
⫺218.5
⫺178.5
⫺351.5
⫺319.2
⫺13.0
⫺181.6
⫺142.1
⫺233.1
⫺290.4
⫺468.1
⫺485.1
⫺420.2
⫺376.7
⫺377.8
⫺494.6
⫺509.2
⫺443.3
⫺459.0
⫺476.2
lq
lq
g
c
⫺278.3
⫺43.9
⫺18.5
⫺137.6
lq
lq
⫺253.6
⫺279.5
lq
lq
c
c
c
c
c
c
lq
lq
g
lq
g
lq
47.7
⌬f G⬚
kJ · mol⫺1
78.5
90.4
95.8
S⬚
J · deg⫺1 · mol⫺1
348.5
174.1
309.7
top of rh
base of rh
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
82.3
134.0
57.7
379100
⫺450.4
⫺458.5
⫺456.1
⫺440.7
⫺468.8
⫺466.4
20.0
⫺213.8
⫺186.1
⫺207.4
⫺178.3
⫺328.6
⫺121.9
390.2
216.8
158.3
27.1
313.0
415.5
232.0
169.2
244.0
193.3
161.3
182.3
273.0
175.6
137.7
70.7
70.0
68.5
214.629
238.9
⫺9.2
⫺4.1
272.5
358.2
287.8
365.8
191.9
141.9
189.7
140.5
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.20
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
2,3-Dimethyl-1-butene
2,3-Dimethyl-2-butene
3,3-Dimethyl-1-butene
2,3-Dimethyl-2-butenoic acid
Dimethylcadmium
1,1-Dimethylcyclohexane
cis-1,2-Dimethylcyclohexane
trans-1,2-Dimethylcyclohexane
cis-1,3-Dimethylcyclohexane
trans-1,3-Dimethylcyclohexane
cis-1,4-Dimethylcyclohexane
trans-1,4-Dimethylcyclohexane
1,1-Dimethylcyclopentane
cis-1,2-Dimethylcyclopentane
trans-1,2-Dimethylcyclopentane
cis-1,3-Dimethylcyclopentane
trans-1,3-Dimethylcyclopentane
1,1-Dimethylcyclopropane
cis-1,2-Dimethylcyclopropane
trans-1,2-Dimethylcyclopropane
cis-2,4-Dimethyl-1,3-dioxane
4,5-Dimethyl-1,3-dioxane
5,5-Dimethyl-1,3-dioxane
4,4⬘-Dimethyldiphenylamine
Dimethyl disulfide
Dimethyl ether
N,N-Dimethylformamide
Dimethyl fumarate
Dimethylglyoxime
2,2-Dimethylheptane
2,6-Dimethyl-4-heptanone
2,2-Dimethylhexane
2,3-Dimethylhexane
2,4-Dimethylhexane
2,5-Dimethylhexane
3,3-Dimethylhexane
3,4-Dimethylhexane
Dimethyl hexanedioate
cis-2,2-Dimethyl-3-hexene
trans-2,2-Dimethyl-3-hexene
cis-2,5-Dimethyl-3-hexene
trans-2,5-Dimethyl-3-hexene
Physical
State
⌬f H⬚
kJ · mol⫺1
⌬f G⬚
kJ · mol⫺1
⫺62.6
⫺101.4
⫺68.2
⫺60.5
⫺455.6
63.6
⫺218.7
⫺180.9
⫺211.8
⫺172.1
⫺218.2
⫺180.0
⫺222.9
⫺184.6
⫺215.7
⫺176.5
⫺215.6
⫺176.6
⫺222.4
⫺184.5
⫺138.2
⫺165.3
⫺129.5
⫺136.6
⫺135.9
⫺133.6
⫺33.3
⫺26.3
⫺30.7
⫺465.2
⫺451.6
⫺461.3
⫺11.72
⫺62.6
⫺184.1
⫺239.3
⫺729.3
⫺199.7
⫺288.2
⫺408.5
⫺261.9
⫺252.6
⫺257.0
⫺260.4
⫺257.5
⫺251.8
⫺886.6
⫺126.4
⫺144.9
⫺151.0
⫺159.2
79.0
lq
g
g
c
lq
lq
g
lq
g
lq
g
lq
g
lq
g
lq
g
lq
g
g
lq
g
g
g
g
lq
lq
lq
lq
lq
lq
c
lq
g
lq
lq
c
lq
lq
lq
lq
lq
lq
lq
lq
lq
lq
lq
lq
lq
S⬚
J · deg⫺1 · mol⫺1
Cp⬚
J · deg⫺1 · mol⫺1
365.6
270.2
364.6
343.8
143.5
174.7
123.6
126.5
132.0
209.2
154.4
210.2
165.5
209.4
159.0
209.4
157.3
212.8
157.3
212.1
157.3
210.2
157.7
133.3
45.7
38.4
39.2
41.5
201.9
267.2
365.0
274.1
374.5
273.2
370.9
272.6
370.5
276.3
376.2
271.1
370.5
268.0
364.8
359.3
269.2
366.1
366.8
366.8
366.8
7.0
⫺112.6
235.4
266.4
146.1
64.4
150.6
3.0
9.1
3.7
2.5
5.2
8.5
331.9
342.7
345.7
338.7
339.4
347.2
76.1
98.2
139.3
26.5
35.2
41.2
34.5
29.8
36.3
38.0
31.7
39.0
cap height
base of text
134.14
134.5
134.5
134.5
297.3
249.2
246.6
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.21
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
5,5-Dimethylhydantoin
1,1-Dimethylhydrazine
1,2-Dimethylhydrazine
3,5-Dimethylisoxazole
Dimethyl maleate
Dimethylmaleic anhydride
Dimethyl malonate
Dimethylmercury
6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptane
Dimethyl oxalate
2,2-Dimethylpentane
2,3-Dimethylpentane
2,4-Dimethylpentane
3,3-Dimethylpentane
Dimethyl pentanedioate
2,4-Dimethyl-3-pentanone
2,4-Dimethyl-1-pentene
4,4-Dimethyl-1-pentene
2,4-Dimethyl-2-pentene
cis-4,4-Dimethyl-2-pentene
trans-4,4-Dimethyl-2-pentene
2,7-Dimethylphenanthrene
4,5-Dimethylphenanthrene
9,10-Dimethylphenanthrene
2,3-Dimethylphenol
2,4-Dimethylphenol
2,5-Dimethylphenol
2,6-Dimethylphenol
3,4-Dimethylphenol
3,5-Dimethylphenol
Dimethyl 1,2-phthalate
Dimethyl 1,3-phthalate
Dimethyl 1,4-phthalate
2,2-Dimethylpropane
2,2-Dimethylpropanenitrile
2,2-Dimethyl-1,3-propanediol
2,2-Dimethylpropanoic acid
2,2-Dimethylpropanoic
anhydride
2,2-Dimethyl-1-propanol
2,3-Dimethylpyridine
2,4-Dimethylpyridine
2,5-Dimethylpyridine
Physical
State
⌬f H⬚
kJ · mol⫺1
c
lq
lq
lq
lq
c
lq
lq
g
lq
⫺533.3
48.9
52.7
⫺63.2
⫺703.8
⫺581.6
⫺795.8
59.8
94.4
⫺7.7
lq
lq
g
lq
g
lq
g
lq
g
lq
lq
g
g
g
g
g
g
c
c
c
c
lq
c
c
c
c
lq
c
c
lq
g
lq
c
lq
lq
⫺756.3
⫺238.3
⫺205.9
⫺233.1
⫺198.9
⫺234.6
⫺201.7
⫺234.2
⫺201.2
⫺205.9
⫺352.9
⫺311.5
⫺83.8
⫺81.6
⫺88.7
⫺72.6
⫺88.8
36.4
89.0
47.7
⫺241.2
⫺228.7
⫺246.6
⫺237.4
⫺242.3
⫺244.4
⫺678
⫺730.0
⫺732.6
⫺168.0
⫺39.8
⫺551.2
⫺564.4
⫺779.9
lq
lq
lq
lq
⫺399.4
19.4
16.2
18.7
⌬f G⬚
kJ · mol⫺1
206.7
212.6
S⬚
J · deg⫺1 · mol⫺1
198.0
199.2
top of rh
base of rh
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
164.1
171.0
263.2
140.3
146.1
209.0
306.0
0.1
300.3
392.9
83.3
3.1
414.0
303.2
396.6
221.1
166.0
218.3
166.0
224.2
166.0
2.6
399.7
166.0
318.0
233.7
0.7
206.9
303.1
⫺1.5
306.4
232.0
261.1
163.96
121.6
179.4
243.7
248.5
248.8
189.5
184.8
184.7
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.22
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
2,6-Dimethylpyridine
3,4-Dimethylpyridine
3,5-Dimethylpyridine
Dimethyl succinate
2,2-Dimethylsuccinic acid
meso-2,3-Dimethylsuccinic
acid
Dimethyl sulfate
Dimethyl sulfide
Dimethyl sulfite
Dimethyl sulfone
Dimethyl sulfoxide
1,5-Dimethyltetrazole
2,2-Dimethylthiacyclopropane
5,5-Dimethyl-4-thia-1-hexene
N,N-Dimethylurea
N,N’-Dimethylurea
Dimethylzinc
2,3-Dinitroaniline
2,4-Dinitroaniline
2,5-Dinitroaniline
2,6-Dinitroaniline
3,4-Dinitroaniline
3,5-Dinitroaniline
2,4-Dinitroanisole
2,6-Dinitroanisole
1,2-Dinitrobenzene
1,3-Dinitrobenzene
1,4-Dinitrobenzene
1,1-Dinitroethane
1,2-Dinitroethane
Dinitromethane
1,5-Dinitronaphthalene
2,4-Dinitro-1-naphthol
2,4-Dinitrophenol
2,6-Dinitrophenol
1,1-Dinitropropane
1,3-Dinitropropane
2,2-Dinitropropane
2,4-Dinitroresorcinol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
1,3-Dioxane
1,4-Dioxane
1,3-Dioxolane
Physical
State
⌬f H⬚
kJ · mol⫺1
lq
lq
lq
lq
c
c
12.7
18.3
22.5
⫺835.1
⫺987.8
⫺977.5
lq
lq
g
lq
c
lq
g
lq
c
lq
lq
c
c
lq
c
c
c
c
c
c
c
c
c
c
c
lq
lq
lq
g
c
c
c
c
lq
lq
lq
c
c
c
lq
lq
g
lq
g
⫺735.5
⫺65.4
⫺37.5
⫺523.6
⫺450.1
⫺373.1
⫺204.2
188.7
⫺24.2
⫺90.7
⫺319.1
⫺312.1
23.4
⫺11.7
⫺67.8
⫺44.4
⫺50.6
⫺32.6
⫺38.9
⫺186.6
⫺189.1
⫺1.8
⫺27.4
⫺38.7
⫺148.2
⫺165.2
⫺104.9
⫺58.9
30.5
⫺181.4
⫺232.6
⫺210.0
⫺163.2
⫺207.1
⫺181.2
⫺415.5
⫺71.6
⫺51.0
⫺379.7
⫺353.9
⫺315.8
⫺333.5
⫺298.0
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
Cp⬚
J · deg⫺1 · mol⫺1
249.2
240.7
241.7
185.2
191.8
184.5
7.0
285.9
118.1
74.1
⫺302.5
⫺272
142.0
⫺99.2
310.6
188.3
100.0
153.0
201.6
129.2
211.5
184.6
216.3
220.9
⫺188.1
⫺180.8
270.2
299.8
cap height
base of text
143.9
153.6
94.1
118.0
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.23
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
1,3-Dioxolan-2-one
1,3-Dioxol-2-one
Dipentene
Dipentyl ether
N,N-Diphenylacetamide
Diphenylacetylene
Diphenylamine
Diphenylboron bromide
cis,cis-1,4-Diphenylbutadiene
trans,trans-1,4-Diphenylbutadiene
Diphenylbutadiyne
1,4-Diphenylbutane
1,4-Diphenyl-1,4-butanedione
1,4-Diphenyl-2-butene-1,4-dione
Diphenyl carbonate
Diphenyl disulfide
Diphenyl disulfone
Diphenyleneimine
1,1-Diphenylethane
1,2-Diphenylethane
Diphenylethanedione
Diphenyl ether
1,1-Diphenylethylene
Diphenylethyne
6,6-Diphenylfulvene
1,2-Diphenylhydrazine
Diphenylmercury
Diphenylmethane
1,3-Diphenyl-2-propanone
Diphenyl sulfide
Diphenyl sulfone
Diphenyl sulfoxide
1,3-Diphenylurea
Dipropylamine
Dipropyl disulfide
Dipropyl ether
Dipropylmercury
Dipropyl sulfate
Dipropyl sulfide
Dipropyl sulfite
Dipropyl sulfone
Dipropyl sulfoxide
2,2’-Dipyridyl ketone
1,3-Dithiane
1,2-Dithiolane
1,3-Dithiolane
Physical
State
⌬f H⬚
kJ · mol⫺1
c
lq
lq
lq
c
c
c
lq
c
c
⫺581.6
⫺459.9
⫺50.8
c
c
c
c
c
c
c
c
lq
lq
c
c
lq
lq
c
c
c
c
c
lq
c
lq
c
c
c
lq
lq
lq
g
lq
lq
lq
g
lq
lq
lq
c
g
g
g
518.4
⫺9.9
⫺256.2
⫺114.7
⫺401.2
⫺148.5
⫺643.2
126.8
48.7
51.5
⫺154.0
⫺32.1
⫺14.9
172.4
312.4
197.4
221.3
279.5
71.7
89.7
⫺84.0
163.4
⫺225.0
9.7
⫺122.6
⫺156.1
⫺171.3
⫺328.8
⫺292.9
⫺20.9
⫺859.0
⫺171.5
⫺125.3
⫺646.8
⫺548.2
⫺329.4
⫺19.7
⫺10.0
0.0
10.0
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
top of rh
base of rh
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
133.950
249.4
250
⫺43.1
312.4
130.6
⫺16.1
198.8
178.8
225.9
7.8
111.5
⫺175.9
324.7
319.2
278.4
245.1
67.2
335.9
270.3
144.2
233.9
291.3
216.6
268.6
239.3
276.9
233.1
253.075
19.1
⫺105.6
373.6
323.9
422.5
221.6
158.3
33.2
448.4
161.2
72.4
47.7
54.7
333.5
313.5
323.3
110.4
86.5
84.7
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.24
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Divinyl ether
Divinyl sulfone
Docosanoic acid
cis-13-Docosenic acid
trans-13-Docosenic acid
Dodecane
Dodecanedioic acid
Dodecanoic acid
1-Dodecanol
1-Dodecene
1-Dodecyne
Dulcitol
1,2-Epoxybutane
Ergosterol
Ethane
Ethane-d6
1,2-Ethanediamine
1,2-Ethanediol
Ethanedithioamide
Ethanedioyl dichloride
1,2-Ethanedithiol
Ethanethiol
Ethanol
Ethene (see Ethylene)
Ethoxybenzene
2-Ethoxyethyl acetate
2-Ethoxyethanol
Ethyl acetate
Ethylamine
Ethyl 4-aminobenzoate
N-Ethylaniline
Ethylbenzene
Ethyl benzoate
2-Ethylbenzoic acid
3-Ethylbenzoic acid
4-Ethylbenzoic acid
2-Ethyl-1-butene
Ethyl trans-2-butenoate
(ethyl crotonate)
Ethyl carbamate
Ethyl 4-chlorobutanoate
Physical
State
⌬f H⬚
kJ · mol⫺1
lq
g
lq
c
c
c
lq
g
c
c
lq
lq
lq
g
g
c
lq
c
g
g
lq
lq
g
c
lq
lq
lq
g
lq
g
⫺39.8
⫺13.6
⫺207.4
⫺983.0
⫺866.0
⫺960.7
⫺350.9
⫺289.7
⫺1130.0
⫺774.6
⫺737.9
⫺528.5
⫺226.2
⫺165.4
⫺0.04
⫺1346.8
⫺168.9
⫺789.9
⫺84.0
⫺107.4
⫺63.0
⫺455.3
⫺392.2
⫺20.8
⫺367.6
⫺54.4
⫺73.6
⫺46.1
⫺277.6
⫺234.8
lq
lq
lq
lq
g
lq
g
c
lq
lq
g
lq
c
c
c
g
lq
⫺152.6
c
lq
⫺520.5
⫺566.5
⌬f G⬚
kJ · mol⫺1
28.1
50.0
S⬚
J · deg⫺1 · mol⫺1
Cp⬚
J · deg⫺1 · mol⫺1
490.6
622.5
376.0
280.3
484.8
618.3
602.4
404.3
438.1
360.7
269.6
265.4
230.9
147.0
⫺323.2
⫺304.5
229.1
244.5
209.2
163.2
303.8
52.5
64.6
172.6
149.3
82.7
⫺5.5
⫺4.8
⫺174.8
⫺167.9
207.0
296.1
161.0
281.6
117.9
72.7
112.3
65.6
137.9
268.6
⫺32.0
⫺47.3
⫺479.3
⫺443.6
⫺332.7
⫺327.4
257.7
362.8
⫺47.4
⫺418.0
4.0
⫺12.3
29.9
36.3
283.8
188.7
239.3
130.6
360.5
cap height
base of text
228.5
376.0
210.8
170.7
113.6
130.0
71.5
183.2
246.0
⫺441.3
⫺445.8
⫺460.7
⫺56.0
⫺420.1
80.0
376.6
133.6
228.0
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.25
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Ethyl chloroformate
Ethylcyclobutane
Ethylcyclohexane
1-Ethylcyclohexene
Ethylcyclopentane
1-Ethylcyclopentene
Ethylcyclopropane
Ethyl diethylcarbamate
Ethyl 2,2-dimethylpropanoate
Ethylene
Ethylene-d4
Ethylene carbonate
Ethylenediaminetetraacetic acid
Ethylenediammonium chloride
2,2⬘-(Ethylenedioxy)bisethanol
Ethylene glycol dibutyl ether
Ethylene glycol diethyl ether
Ethylene glycol dimethyl ether
Ethyleneimine
Ethylene oxide
Ethyl formate
2-Ethylhexanal
3-Ethylhexane
2-Ethyl-1-hexanol
Ethyl hydroperoxide
Ethylidenecyclohexane
Ethylidenecyclopentane
Ethyl isocyanide
Ethyl isopropyl sulfide
Ethyl lactate
Ethyllithium
Ethylmercury bromide
Ethylmercury chloride
Ethylmercury iodide
1-Ethyl-2-methylbenzene
2-Ethyl-3-methyl-1-butene
Ethyl 2-methylbutanoate
Ethyl 3-methylbutanoate
Ethyl methyl ether
3-Ethyl-2-methylpentane
3-Ethyl-3-methylpentane
3-Ethyl-2-methyl-1-pentene
Physical
State
⌬f H⬚
kJ · mol⫺1
lq
g
lq
g
lq
lq
g
lq
lq
lq
g
g
g
c
c
⫺505.1
⫺27.5
⫺211.9
⫺171.7
⫺106.7
⫺163.4
⫺19.7
⫺24.8
⫺592.3
⫺577.2
⫺536.0
52.5
38.2
⫺581.5
⫺1759.4
c
lq
⫺513.4
⫺804.2
lq
lq
lq
lq
g
lq
g
lq
lq
lq
g
lq
g
lq
lq
lq
lq
lq
c
c
c
c
g
g
lq
lq
g
lq
g
lq
g
g
⫺451.4
⫺376.6
91.9
126.5(9)
⫺78.0
⫺52.6(6)
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
top of rh
base of rh
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
29.1
39.3
280.9
382.6
211.8
158.8
37.3
279.9
185.8
68.4
59.2
219.3
230.5
42.9
51.9
133.9
35020
259.4
193.3
178.0
⫺11.8
⫺13.1
⫺342.5
⫺250.4
⫺210.7
⫺432.8
198.9
⫺103.5
⫺56.7
108.4
⫺156.1
250.6
153.9
242.4
52.6
88.0
47.9
149.3
347.0
317.5
254
⫺58.6
⫺107.5
⫺141.1
⫺65.7
1.3
⫺79.5
⫺566.8
⫺570.9
⫺216.4
⫺249.6
⫺211.0
⫺252.8
⫺214.8
⫺100.3
131.1
399.2
157.9
⫺117.7
309.2
93.3
21.3
19.9
441.1
433.0
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.26
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Ethyl methyl sulfide
Ethyl nitrate
Ethyl nitrite
1-Ethyl-2-nitrobenzene
1-Ethyl-4-nitrobenzene
Ethyl 3-oxobutanoate
3-Ethylpentane
Ethyl pentanoate
2-Ethylphenol
3-Ethylphenol
4-Ethylphenol
Ethylphosphonic acid
Ethylphosphonic dichloride
Ethyl propanoate
Ethyl propyl ether
Ethyl propyl sulfide
2-Ethylpyridine
S-Ethyl thioacetate
2-Ethyltoluene
3-Ethyltoluene
4-Ethyltoluene
N-Ethylurea
Ethyl ␤-vinylacrylate
Ethyl vinyl ether
Ethynylbenzene
Ethynylsilane
Fluoranthene
Fluoroacetamide
Fluoroacetic acid
Fluoroacetylene
Fluorobenzene
2-Fluorobenzoic acid
3-Fluorobenzoic acid
4-Fluorobenzoic acid
Fluoroethane
2-Fluoroethanol
Fluoroethylene
Fluoromethane
1-Fluoropropane
2-Fluoropropane
Fluorosyltrifluoromethane
4-Fluorotoluene
Fluorotribromomethane
Fluorotrinitromethane
Formaldehyde
Physical
State
lq
g
g
g
lq
lq
lq
lq
g
lq
lq
lq
c
c
lq
lq
g
g
lq
g
lq
lq
g
g
g
c
lq
lq
g
g
g
c
c
c
g
lq
g
c
c
c
g
lq
g
g
g
g
g
lq
g
lq
g
⌬f H⬚
kJ · mol⫺1
⫺91.6
⫺59.6
⫺154.1
⫺104.2
⫺48.7
⫺55.4
⫺224.9
⫺189.6
⫺553.0
⫺214.3
⫺224.4
⫺1051.4
⫺613.4
⫺502.7
⫺463.3
⫺272.2
⫺144.8
⫺104.7
7.4
⫺268.2
1.3
⫺1.8
⫺3.2
⫺357.8
⫺338.1
⫺167.4
⫺140.8
327.3
189.9
⫺496.6
⫺688.3
⫺150.6
⫺116.0
⫺567.6
⫺582.0
⫺585.7
⫺263.2
⫺465.7
⫺138.8
⫺237.8
⫺285.9
⫺293.5
⫺766.0
⫺186.9
⫺190.4
⫺220.9
⫺108.6
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
11.4
⫺36.9
239.1
333.1
348.3
103.5
144.6
95.1
97.4
99.2
314.5
411.5
248.0
219.6
166.0
11.0
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
⫺208.8
206.9
196.1
⫺323.7
23.6
295.0
309.5
414.1
197.2
198.4
139.3
131.1
126.4
85.3
399.2
404.2
398.9
157.9
152.2
151.5
361.8
345.6
321.7
269.4
230.5
114.9
72.6
230.2
⫺69.0
269.4
205.9
302.6
72.6
146.4
94.4
⫺211.0
264.5
58.6
⫺213.8
⫺200.3
⫺204.2
⫺707.0
⫺79.8
⫺193.1
222.8
304.2
292.1
322.4
237.1
345.8
37.5
82.6
82.0
79.4
171.2
⫺102.5
218.8
35.4
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.27
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Formamide
Formanilide
Formic acid
Formyl fluoride
D-(⫺)-Fructose
D-(⫹)-Fucose
Fullerene-C60
Fumaric acid
Fumaronitrile
Furan
2-Furancarboxaldehyde
2-Furancarboxylic acid
2-Furanmethanol
Furfuryl alcohol
Furylacrylic acid
Furylethylene
D-(⫹)-Galactose
D-Gluconic acid
D-(⫹)-Glucose
D-(⫺)-Glutamic acid
L-(⫹)-Glutamic acid
L-Glutamine
Glutaric acid
Glyceraldehyde
Glycerol
Glyceryl 1-acetate
Glyceryl 1-benzoate
Glyceryl 2-benzoate
Glyceryl 1,3-diacetate
Glyceryl 1-dodecanoate
Glyceryl 2-dodecanoate
Glyceryl 1-hexadecanoate
Glyceryl 1-hexanoate
Glyceryl 2-hexanoate
Glyceryl 1-octadecanoate
Glyceryl 1-tetradecanoate
Glyceryl triacetate
Glyceryl trinitrate
Glyceryl tris(dodecanoate)
Glyceryl tris(tetradecanoate)
Glycine
ionized; std. state
⫹
H3NCH2COOH; std. state
Glycylglycine
Glyoxal
Glyoxime
Glyoxylic acid
Guanidine
Physical
State
lq
g
c
lq
g
g
c
c
c
c
c
lq
g
lq
c
lq
lq
c
lq
c
c
c
c
c
c
c
lq
lq
lq
c
c
lq
c
c
c
c
c
c
c
lq
lq
c
c
c
aq
aq
c
g
c
c
c
⌬f H⬚
kJ · mol⫺1
⫺254.0
⫺193.9
⫺151.5
⫺424.7
⫺378.7
⫺376.6
⫺1265.6
⫺1099.1
2327.0
⫺811.7
268.2
⫺62.3
⫺34.9
⫺201.6
⫺498.4
⫺276.2
⫺276.2
⫺459.0
⫺10.5
⫺1286.3
⫺1587.0
⫺1273.3
⫺1009.7
⫺1005.2
⫺826.4
⫺960.0
⫺598.0
⫺668.5
⫺909.1
⫺777.3
⫺772.8
⫺1120.7
⫺1160.9
⫺1152.6
⫺1281.5
⫺1109.0
⫺1095.8
⫺1324.8
⫺1222.6
⫺1330.8
⫺370.9
⫺2046.0
⫺2176.0
⫺528.5
⫺469.8
⫺517.9
⫺747.7
⫺212.0
⫺90.5
⫺835.5
⫺56.0
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
⫺141.0
248.6
⫺361.4
⫺351.0
⫺368.1
129.0
248.7
246.5(8)
2302.0
⫺655.6
426.0
168.0
520.0
142.0
0.88
177.0
267.2
114.8
65.4
163.2
⫺154.2
215.5
204.0
204.0
⫺918.8
205.4
⫺910.4
⫺727.5
⫺731.3
212.1
191.2
188.2
⫺477.0
206.3
218.9
⫺368.6
⫺315.0
⫺384.2
⫺490.6
103.5
111.0
190.2
190.0
99.2
top of rh
base of rh
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
107.6
45.4
99.5
45.2
40.0
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.28
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Guanidine carbonate
Guanidine nitrate
Guanidine sulfate
Guanine
Guanylurea nitrate
L-Gulonic acid-␥-lactone
Heptadecane
Heptadecanoic acid
1-Heptadecene
Heptanal
Heptane
Heptanedioic acid
Heptanenitrile
1-Heptanethiol
Heptanoic acid
1-Heptanol
2-Heptanone
1-Heptene
cis-2-Heptene
trans-2-Heptene
cis-3-Heptene
trans-3-Heptene
1-Heptyne
Hexabromoethane
Hexachlorobenzene
Hexachloroethane
Hexadecafluoroethylcyclohexane
Hexadecafluoroheptane
Hexadecane
Hexadecanoic acid
1-Hexadecanol
1-Hexadecene
1,5-Hexadiene
2,4-Hexadienoic acid
1,5-Hexadiyne
Hexafluoroacetone
Hexafluoroacetylacetone
Hexafluorobenzene
Hexafluoroethane
cis-Hexahydroindane
Physical
State
⌬f H⬚
kJ · mol⫺1
⫺971.9
⫺387.0
⫺1205.0
⫺183.9
⫺427.2
⫺1219.6
⫺393.9
⫺924.4
⫺268.4
⫺311.5
⫺264.0
⫺224.2
⫺187.7
⫺1009.4
⫺82.8
⫺150.0
⫺610.2
⫺403.3
⫺336.4
c
c
c
c
c
c
g
c
g
lq
g
lq
g
c
lq
g
lq
lq
g
lq
lq
g
lq
lq
lq
lq
g
g
c
g
c
g
lq
⫺127.6
⫺35.5
⫺202.8
⫺143.6
⫺3420.0
lq
lq
g
c
c
lq
lq
g
lq
c
lq
g
c
lq
g
g
g
⫺3420.8
⫺456.1
⫺374.8
⫺891.5
⫺686.7
⫺635.4
⫺328.7
⫺248.5
54.1
⫺390.8
384.2
⫺1249.3
⫺2286.7
⫺991.3
⫺955.4
⫺1344.2
⫺127.2
⫺97.9
⫺62.3
⫺105.1
⫺109.5
⫺104.3
⫺109.3
103.0
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
⫺557.4
295.4
47.4
160.3
82.1
817.3
179.9
⫺100.6
⫺86.7
813.1
335.4
461.7
8.0
427.9
36.2
493.3
⫺142.3
⫺120.9
320.1
480.3
95.8
327.6
423.6
186.9
265.4
272.1
178.7
232.6
211.8
155.2
⫺54.9
407.7
441.9
260.2
441.2
237.3
398.7
151.1
139.3
201.3
173.2
198.2
136.7
⫺3093.0
561.8
83.7
⫺316.1
⫺98.7
⫺96.6
171.5
778.3
452.4
451.9
606.7
587.9
774.1
419.0
501.6
371.8
460.7
422.0
⫺79.4
⫺1255.8
280.8
383.2
332.3
226.7
1.1
44.2
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
258.9
394.7
475.7
383.9
230.1
224.9
166.0
488.9
361.0
156.6
106.7
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.29
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
trans-Hexahydroindane
Hexamethylbenzene
1,1,1,3,3,3-Hexamethyldisilazane
Hexamethyldisiloxane
Hexamethylenetetramine
Hexamethylphosphoric triamide
Hexanal
Hexanamide
Hexane
1,6-Hexanedioic acid
1,2-Hexandediol
1,6-Hexanediol
Hexanedinitrile
1-Hexanethiol
Hexanoic acid
1-Hexanol
2-Hexanol
3-Hexanol
2-Hexanone
3-Hexanone
1-Hexene
cis-2-Hexene
trans-2-Hexene
cis-3-Hexene
trans-3-Hexene
Hexyl acetate
1-Hexyne
(⫺)-Histidine
Hydantoin
Hydrazine
Hydrazinecarbothioamide
Hydrazobenzene
Hydroxyacetic acid
2⬘-Hydroxyacetophenone
3⬘-Hydroxyacetophenone
4⬘-Hydroxyacetophenone
2-Hydroxybenzaldehyde
2-Hydroxybenzaldoxime
2-Hydroxybenzoic acid
3-Hydroxybenzoic acid
4-Hydroxybenzoic acid
Physical
State
⌬f H⬚
kJ · mol⫺1
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
g
c
lq
⫺131.4
⫺162.4
⫺518.0
117.4
306.3
245.6
lq
g
c
lq
g
c
lq
lq
g
lq
lq
c
lq
g
lq
lq
g
lq
lq
lq
lq
lq
g
lq
g
lq
g
lq
g
lq
lq
g
g
c
c
lq
c
c
c
c
c
c
lq
c
c
c
c
⫺814.6
⫺777.7
125.5
⫺541.8
⫺534.5
434.8
433.8
535.0
163.4
311.4
238.5
⫺248.4
⫺423.0
⫺397.0
⫺198.8
⫺167.1(8)
⫺985.4
⫺577.1
⫺569.9
85.1
⫺129.9
⫺583.9
⫺377.5
⫺317.6
⫺392.9
⫺392.4
⫺322.0
⫺320.2
⫺74.1
⫺43.5
⫺83.9
⫺52.3
⫺85.5
⫺53.9
⫺79.0
⫺47.6
⫺86.1
⫺100.1
422.9
⫺3.8
⫺0.25
⫺207.3
296.1
388.4
⫺54.4
123.6
⫺466.7
⫺448.5
50.6
24.7
221.3
⫺663.6
⫺357.7
370.7
⫺364.4
⫺279.9
⫺183.7
⫺589.9
⫺584.9
⫺584.5
top of rh
base of rh
321
148.2
195.6
143.1
232.2
27.8
454.3
⫺152.3
⫺135.6
287.4
441.4
128.7
164.1
225.0
240.4
155.6
83.6
84.45
305.3
295.1
384.6
286.2
213.3
216.9
183.3
132.3
76.2
386.5
125.7
76.4
380.6
132.4
83.0
379.6
123.6
77.6
218.6
374.8
368.7
282.8
132.8
128.2
149.2
121.2
98.9
⫺421.3
⫺417.3
⫺416.5
178.2
177.0
175.7
159.1
157.3
155.1
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.30
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
(⫾)-2-Hydroxybutanoic acid
2-Hydroxy-2,4,6-cycloheptatrienone
2-Hydroxyisobutanoic acid
2-Hydroxy-1-isopropyl-4methylbenzene
3-Hydroxy-4-methoxybenzaldehyde
4-Hydroxy-4-methyl-2pentanone
2-Hydroxymethyl-1,3-propanediol
3-Hydroxy-2-naphthalenecarboxylic acid
5-Hydroxy-1-pentanal
trans-(⫺)-4-Hydroxyproline
(S)-2-Hydroxypropanoic acid
2-Hydroxypropanonitrile
2-Hydroxypyridine
3-Hydroxypyridine
4-Hydroxypyridine
8-Hydroxyquinoline
(⫺)-2-Hydroxysuccinic acid
(⫾)-2-Hydroxysuccinic acid
Hypoxanthene
Icosane
Icosanoic acid
Icosene
Imidazole
Iminodiacetic acid
Indane
1H-Indazole
Indene
1H-Indole
Indole-2,3-dione
Iodoacetone
Iodobenzene
2-Iodobenzoic acid
3-Iodobenzoic acid
4-Iodobenzoic acid
Iodocyclohexane
Iodoethane
Iodoethylene
Iodomethane
2-Iodo-2-methylpropane
1-Iodonaphthalene
2-Iodonaphthalene
2-Iodophenol
3-Iodophenol
Physical
State
⌬f H⬚
kJ · mol⫺1
lq
c
⫺679.1
⫺239.2
c
c
⫺744.3
⫺309.6
c
⫺453.6
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
lq
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
221.3
c
⫺744.6
c
⫺547.7
lq
c
c
lq
c
c
c
c
c
c
c
g
c
g
c
c
lq
c
lq
c
c
g
lq
g
c
c
c
lq
lq
g
g
g
lq
g
lq
c
c
c
⫺479.9
⫺661.1
⫺694.0
⫺138.9
⫺166.3
⫺132.0
⫺144.6
⫺81.2
⫺1103.7
⫺1105.7
⫺110.8
⫺455.8
⫺1011.9
⫺330.2
49.8
⫺932.6
11.5
151.9
110.6
86.7
⫺268.2
⫺130.5
117.1
164.9
⫺302.3
⫺316.9
⫺316.1
⫺97.2
⫺40.0
⫺8.1
14.4
⫺107.5
⫺72.0
161.5
144.3
⫺95.8
⫺94.5
34.3
⫺884.7
76.9
117.3
145.6
934.1
205.1
929.9
134.5
463.3
545.1
452.5
150.8
56.0
190.3
217.6
215.3
186.9
187.8
205.4
334.1
158.7
100.8
15.6
211.7
306.0
285.0
254.1
23.6
342.2
115.1
66.9
57.9
44.1
162.3
118.3
14.7
l9.2
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.31
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
4-Iodophenol
1-Iodopropane
2-Iodopropane
3-Iodopropanoic acid
3-Iodo-1-propene
␣-Iodotoluene
3-Iodotoluene
4-Iodotoluene
Isobutanenitrile
Isobutylamine
Isobutylbenzene
Isobutyl trichloroacetate
Isocyanomethane
(⫺)-Isoleucine
(⫾)-Isoleucine
Isoxazole
Isopropenyl acetate
Isopropyl acetate
Isopropylamine
Isopropylbenzene
1-Isopropyl-2-methylbenzene
1-Isopropyl-3-methylbenzene
1-Isopropyl-4-methylbenzene
Isopropyl methyl ether
2-Isopropyl-5-methylphenol
Isopropyl methyl sulfide
Isopropyl nitrate
2-Isopropylphenol
3-Isopropylphenol
4-Isopropylphenol
Isopropyl thioacetate
Isopropyl trichloroacetate
Isoquinoline
Ketene
(⫹)-Lactic acid
(⫾)-Lactic acid
␤-Lactose
(⫹)-Leucine
(⫺)-Leucine
(⫹)-Limonene
(⫾)-Lysine
Malic acid
Maleic anhydride
(R)-Malic acid
(S)-Malic acid
Physical
State
c
lq
g
lq
g
c
g
lq
lq
lq
g
lq
lq
lq
g
c
c
g
lq
lq
lq
g
lq
g
lq
lq
lq
lq
g
c
lq
g
g
lq
lq
lq
lq
lq
c
lq
g
c
lq
c
c
c
lq
c
c
c
c
c
⌬f H⬚
kJ · mol⫺1
⫺95.4
⫺66.0
⫺30.0
⫺74.8
⫺40.3
⫺460.0
91.5
57.7
79.1
67.4
25.4
⫺132.6
⫺69.8
⫺553.4
163.5
⫺637.9
⫺635.3
78.6
⫺386.4
⫺518.9
⫺112.3
⫺83.7
⫺41.1
4.0
⫺73.3
⫺78.6
⫺78.0
⫺278.8
⫺252.0
⫺309.7
⫺105.7
⫺90.5
⫺191.0
⫺233.7
⫺252.5
⫺265.9
⫺298.2
⫺536.0
144.5
⫺47.5
⫺694.1
⫺674.5
⫺2236.7
⫺637.3
⫺637.4
⫺54.5
⫺678.6
⫺789.4
⫺469.8
⫺1105.7
⫺1103.6
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
top of rh
base of rh
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
126.8
91.0
90.1
20.1
324.5
103.6
313.3
96.4
183.2
165.7
⫺347.2
246.9
208.0
52.9
188.3
32.2
124.3
137.0
218.3
312.2
279.8
388.6
199.4
163.8
97.5
210.7
151.7
⫺120.9
306.6
253.8
332.3
161.9
111.1
13.4
⫺40.7
263.1
359.3
373.2
172.4
117.2
120.7
⫺48.3
⫺522.9
⫺518.2
⫺1567.0
⫺347.2
⫺346.3
247.6
142.3
192.1
386.2
208.0
211.8
⫺625.1
160.8
119.1
196.8
51.8
201.0
249.0
137.0
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.32
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Malonamide
Malonic acid
Malonodiamide
Malononitrile
D-(⫹)-Maltose
(⫾)-Mandelic acid
(⫹)-Mannitol
D-(⫹)-Mannose
2-Mercaptopropanoic acid
Methane
Methane-d4
Methanethiol
Methanol
(⫺)-Methionine
2-Methoxybenzaldehyde
3-Methoxybenzaldehyde
4-Methoxybenzaldehyde
Methoxybenzene
2-Methoxybenzoic acid
3-Methoxybenzoic acid
4-Methoxybenzoic acid
2-Methoxyethanol
2-Methyoxyethyl acetate
2-Methoxytetrahydropyran
5-Methoxytetrazole
1-Methoxy-2,4,6-trinitrobenzene
Methyl (CH3)
Methyl acetate
Methyl acrylate
Methylamine
N-Methylaniline
o-Methylaniline
m-Methylaniline
p-Methylaniline
Methyl benzoate
2-Methylbenzoic acid
3-Methylbenzoic acid
4-Methylbenzoic acid
Physical
State
⌬f H⬚
kJ · mol⫺1
c
c
c
c
c
c
c
c
lq
g
g
lq
g
lq
g
c
c
lq
lq
lq
g
c
c
c
lq
lq
lq
c
c
⫺546.0
⫺891.0
⫺546.1
186.6
⫺2220.9
⫺579.4
⫺1337.1
⫺1263.0
⫺468.2
⫺74.6
⫺88.2
⫺46.7
⫺22.9
⫺239.1
⫺201.0
⫺577.5
⫺266.5
⫺276.1
⫺267.2
⫺114.8
⫺67.9
⫺538.5
⫺553.5
⫺561.7
g
lq
g
lq
g
lq
g
lq
lq
g
lq
g
lq
g
lq
c
lq
c
lq
c
lq
145.7
⫺445.8
⫺413.3
⫺362.2
⫺333.0
⫺47.2
⫺22.5
32.2
⫺6.3
56.4
⫺8.1
54.6
⫺23.5
55.3
⫺343.5
⫺416.5
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
⫺1726.3
⫺942.2
238.5
⫺343.9
⫺50.5
⫺59.5
⫺7.7
⫺9.9
⫺166.6
⫺162.3
⫺505.8
228.9
186.3
198.9
169.2
255.1
126.8
239.9
231.5
35.7
40.3
90.5
50.3
81.2
44.1
199.0
171.1
310.0
⫺442.3
69.1
⫺157.5
147.9
⫺243.2
⫺237.6
35.7
32.7
194.2
324.4
239.5
150.2
242.9
167.6
351.0
165.4
352.5
167.7
347.0
38.7
141.9
86.0
158.8
102.1
50.1
207.1
209.6
130.2
227.0
125.5
126.2
221.3
174.9
⫺426.1
163.6
⫺429.2
169.0
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.33
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
2-Methylbenzoic anhydride
4-Methylbenzoic anhydride
1-Methylbicyclo[4.1.0]heptane
1-Methylbicyclo[3.1.0]hexane
2-Methylbiphenyl
3-Methylbiphenyl
4-Methylbiphenyl
2-Methyl-1,3-butadiene
3-Methyl-1,2-butadiene
2-Methylbutane
2-Methyl-2-butanethiol
3-Methyl-1-butanethiol
3-Methyl-2-butanethiol
2-Methylbutanoic acid
3-Methylbutanoic acid
2-Methyl-1-butanol
3-Methyl-1-butanol
2-Methyl-2-butanol
(⫾)-3-Methyl-2-butanol
3-Methyl-2-butanone
2-Methyl-1-butene
3-Methyl-1-butene
2-Methyl-2-butene
trans-2-Methyl-2-butenedioic
acid [also cis]
cis-2-Methyl-2-butenoic acid
trans-2-Methyl-2-butenoic acid
3-Methylbutyl acetate
3-Methyl-1-butyne
Methyl trans-2-butenoate
Methylcyclobutane
Methylcyclobutanecarboxylic
acid
Methylcyclohexane
cis-2-Methylcyclohexanol
trans-2-Methylcyclohexanol
cis-3-Methylcyclohexanol
trans-3-Methylcyclohexanol
cis-4-Methylcyclohexanol
trans-4-Methylcyclohexanol
2-Methylcyclohexene
Methylcyclopentane
Physical
State
⌬f H⬚
kJ · mol⫺1
c
c
lq
lq
lq
lq
c
lq
g
g
lq
g
lq
g
g
lq
lq
lq
lq
lq
lq
lq
lq
g
lq
g
lq
g
lq
g
c
⫺533.5
⫺520.9
⫺59.9
⫺33.2
108.0
85.4
55.2
48.2
75.5
129.7
⫺178.4
⫺154.0
⫺162.8
⫺127.1
⫺114.9
⫺158.8
⫺554.4
⫺561.6
⫺356.6
⫺356.4
⫺379.5
⫺366.6
⫺299.5
⫺262.5
⫺61.1
⫺35.3
⫺51.5
⫺27.6
⫺68.6
⫺41.8
⫺824.4
c
c
lq
g
lq
lq
lq
⫺455.6
⫺490.8
lq
g
lq
lq
lq
lq
lq
lq
lq
lq
g
⌬f G⬚
kJ · mol⫺1
145.9
198.6
⫺14.8
9.2
S⬚
J · deg⫺1 · mol⫺1
229.3
315.6
319.7
260.4
343.6
290.1
386.9
152.6
104.6
105.4
164.8
118.8
198.1
143.5
268.5
59.7
254.0
339.5
253.3
333.5
251.0
338.6
157.2
110.0
156.1
118.6
152.8
105.0
136.4
⫺382.8
⫺44.5
⫺395.0
205.5
319.0
248.5
104.7
⫺190.1
⫺154.7
⫺390.2
⫺415.8
⫺416.1
⫺394.4
⫺413.2
⫺433.3
⫺81.2
⫺138.0
⫺106.2
20.3
27.3
247.9
343.3
184.9
135.0
20017
20017
29217
20217
20217
20217
31.5
35.8
247.9
339.9
158.7
109.8
65.6
74.8
229.3
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
197.1
220.1
210.0
247.1
232.2
179.9
⫺175.3
top of rh
base of rh
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.34
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
1-Methylcyclopentanol
2-Methylcyclopentanone
1-Methylcyclopentene
3-Methylcyclopentene
4-Methylcyclopentene
1-Methylcyclopropene
Methylenecyclobutane
Methylenebutanedioic acid
Methylenecyclohexane
Methylenecyclohexene
Methylenecyclopropane
Methyl decanoate
Methyl 2,2-dimethylpropanoate
2-Methyl-1,3-dioxane
4-Methyl-1,3-dioxane
N-Methyldiphenylamine
4-Methyldiphenylamine
Methyl dodecanoate
Methylene (CH2)
Methylenebutanedioic acid
Methylenecyclohexane
2-Methylenecyclohexanol
3-Methylenecyclohexene
2-Methylenecyclopentanol
Methylenecyclopropane
Methylenesuccinic acid
Methylene sulfate
N-Methylformamide
Methyl formate
Methyl 2-furancarboxylate
2-Methyl-2,5-furandione
␣-Methyl-(⫹)-glucoside
N-Methylglycine
Methylglyoxal
Methylglyoxime
2-Methylheptane
3-Methylheptane
4-Methylheptane
Methyl heptanoate
2-Methylhexane
3-Methylhexane
Methyl hexanoate
5-Methyl-1-hexene
cis-3-Methyl-3-hexene
Physical
State
lq
lq
g
g
g
lq
g
g
c
lq
lq
g
lq
lq
lq
c
lq
c
lq
g
c
lq
lq
lq
lq
g
c
c
lq
lq
g
lq
lq
c
c
g
c
lq
g
lq
g
lq
g
lq
lq
g
lq
g
lq
g
g
⌬f H⬚
kJ · mol⫺1
⫺343.3
⫺265.3
⫺3.8
7.4
14.6
1.7
243.6
121.6
⫺841.1
⫺61.3
⫺12.7
200.5
⫺640.4
⫺530.0
⫺436.4
416.1
120.5
49.0
⫺693.0
390.4
⫺841.1
⫺61.3
⫺277.6
⫺12.7
46.9
200.5
⫺841.2
⫺688.7
⫺386.1
⫺357.4
⫺450.0
⫺504.5
⫺1233.4
⫺513.3
⫺27.1
⫺126.8
⫺255.0
⫺215.4
⫺252.3
⫺212.5
⫺251.6
⫺212.0
⫺567.1
⫺229.5
⫺194.6
⫺226.4
⫺192.3
⫺540.2
⫺65.7
⫺79.4
⌬f G⬚
kJ · mol⫺1
102.1
115.0
121.6
S⬚
J · deg⫺1 · mol⫺1
326.4
330.5
328.9
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
100.8
100.0
100.0
257.9
372.9
⫺297.2
194.9
33.8
285.3
123.8
119.1
64.4
13.7
356.4
452.5
362.6
461.6
16.7
453.3
3.2
323.3
420.0
4.6
424.1
12.8
252.0
250.2
251.1
285.1
222.9
166.0
214.2
166.0
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.35
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
trans-3-Methyl-3-hexene
Methylhydrazine
2-Methyl-1H-indole
3-Methyl-1H-indole
Methyl isocyanate
Methyl isocyanide
1-Methyl-4-isopropylbenzene
Methyl isopropyl sulfide
Methyl isothiocyanate
5-Methylisoxazole
Methylmercury bromide
Methylmercury chloride
Methylmercury iodide
Methyl 2-methylbutanoate
Methyl 3-methylbutanoate
7-Methyl-3-methylene-1,6octadiene
(R)-1-Methyl-4-(1-methylethenyl)cyclohexene
1-Methylnaphthalene
2-Methylnaphthalene
Methyl nitrate
Methyl nitrite
Methyl nitroacetate
2-Methyl-5-nitroaniline
4-Methyl-3-nitroaniline
1-Methyl-2-nitrobenzene
1-Methyl-3-nitrobenzene
1-Methyl-4-nitrobenzene
2-Methyl-2-nitropropane
2-Methyl-2-nitro-1,3propanediol
2-Methyl-2-nitro-1-propanol
2-Methylnonane
5-Methylnonane
Methyl phenylcarbamate
Methyl cis-9-octadecanoate
Methyl octanoate
2-Methyl-2-oxazoline
2-Methylpentane
3-Methylpentane
2-Methyl-2,4-pentanediol
Methyl pentanoate
2-Methyl-1-pentanol
2-Methyl-3-pentanol
Physical
State
⌬f H⬚
kJ · mol⫺1
g
lq
g
c
c
lq
g
lq
g
c
g
lq
c
c
c
lq
lq
lq
⫺76.8
54.2
94.7
60.7
68.2
⫺92.0
163.5
⫺78.0
⫺90.4
79.4
131.0
⫺5.6
⫺86.2
⫺116.3
⫺43.5
⫺534.3
⫺538.9
14.5
lq
⫺54.5
lq
c
g
lq
g
g
lq
c
c
lq
lq
c
c
c
56.3
44.9
106.7
⫺156.3
⫺124.4
⫺66.1
⫺464.0
⫺91.3
⫺71.7
⫺9.7
⫺31.5
⫺48.1
⫺229.8
⫺575.3
c
lq
lq
c
lq
lq
g
lq
g
lq
g
lq
lq
lq
lq
⫺410.0
⫺309.8
⫺307.9
⫺186.7
⫺734.5
⫺590.3
⫺130.5
⫺204.6
⫺174.8
⫺202.4
⫺172.1
⫺514.2
⫺396.4
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
top of rh
base of rh
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
179.9
186.9
165.9
278.7
134.9
71.1
165.7
246.8
13.4
359.3
52.9
236.4
117.2
144.4
252.3
65.5
24920
189.4
192.6
216.2
⫺43.5
⫺39.3
1.0
⫺5.0
2.1
254.8
220.0
380.0
217.2
318.5
284.3
224.4
196.0
159.8
157.3
76.5
63.2
420.1
423.8
313.3
314.4
290.6
380.5
292.5
379.8
193.7
144.2
190.7
143.1
236.0
229.3
248.0
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.36
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
3-Methyl-2-pentanol
3-Methyl-3-pentanol
4-Methyl-2-pentanol
2-Methyl-3-pentanone
4-Methyl-2-pentanone
2-Methyl-1-pentene
2-Methyl-2-pentene
3-Methyl-1-pentene
cis-3-Methyl-2-pentene
trans-3-Methyl-2-pentene
4-Methyl-1-pentene
cis-4-Methyl-2-pentene
trans-4-Methyl-2-pentene
Methyl 2-methylpropenoate
4-Methyl-3-penten-2-one
Methyl pentyl sulfide
3-Methyl-1-phenyl-1-butanone
Methyl phenyl sulfide
Methyl phenyl sulfone
Methylphosphonic acid
(⫾)-2-Methylpiperidine
2-Methylpropanal
N-Methylpropanamide
2-Methylpropanamine
2-Methylpropane
2-Methyl-1,2-propanediamine
2-Methyl-1,2-propanediol
2-Methylpropanenitrile
2-Methyl-1-propanethiol
2-Methyl-2-propanethiol
2-Methylpropanoic acid
2-Methyl-1-propanol
2-Methyl-2-propanol
2-Methylpropene
2-Methylpropenoic acid
1-Methyl-2-propylbenzene
1-Methyl-3-propylbenzene
1-Methyl-4-propylbenzene
(2-Methylpropyl)benzene
Methyl propyl ether
Methyl propyl sulfide
2-Methylpyridine
3-Methylpyridine
4-Methylpyridine
1-Methyl-1H-pyrrole
Physical
State
lq
lq
lq
lq
lq
g
g
g
g
g
g
g
g
lq
lq
g
lq
lq
c
c
lq
lq
g
lq
lq
g
lq
lq
lq
g
g
lq
lq
g
lq
g
g
lq
lq
lq
lq
lq
lq
g
g
lq
g
lq
g
lq
lq
⌬f H⬚
kJ · mol⫺1
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
Cp⬚
J · deg⫺1 · mol⫺1
275.9
293.4
273.0
⫺394.7
⫺325.9
⫺59.4
⫺66.9
⫺49.5
⫺62.3
⫺63.1
⫺51.3
⫺57.5
⫺61.5
77.6
71.2
86.4
73.2
71.3
90.0
82.1
79.6
382.2
378.4
376.8
378.4
381.8
367.7
373.3
368.3
122.9
⫺220.2
43.0
⫺345.4
⫺1054
⫺124.9
⫺247.4
⫺215.8
35.1
450.7
213.3
135.6
126.6
142.4
126.6
126.6
126.5
133.6
141.4
191.2
212.5
163.7
⫺20.9
294.6
179
183.2
130.5⫺12
5.6
0.7
362.9
338.0
⫺132.6
⫺134.2
⫺133.9
⫺539.7
⫺13.8
⫺97.3
⫺109.6
⫺334.7
⫺283.9
⫺359.2
⫺312.5
⫺16.9
⫺72.5
⫺76.2
⫺75.1
⫺69.8
⫺266.0
⫺238.2
⫺82.3
56.7
99.2
61.9
106.4
59.2
62.4
cap height
base of text
⫺167.35
⫺177.7
58.1
⫺109.9
18.4
166.5
177.1
214.0
184.3
214.7
359.0
193.3
326.7
293.6
262.9
349.5
371.7
217.9
325.0
216.3
325.0
209.1
118.3
121.0
173
181.2
111.3
219.8
113.6
89.1
161.1
240.6
165.4
112.5
117.4
158.4
100.0
158.7
99.6
159.0
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.37
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
2-Methyl-1H-pyrrole
3-Methyl-1H-pyrrole
N-Methylpyrrolidone
2-Methylquinoline
Methyl salicylate
Methylsilane
␣-Methylstyrene
cis-(␤)-Methylstyrene
trans-(␤)-Methylstyrene
Methylsuccinic acid
Methylsuccinic anhydride
Methyl tetradecanoate
2-Methylthiacyclopentane
4-Methylthiazole
Methylthiirane
2-Methylthiophene
3-Methylthiophene
Methyl p-tolyl sulfone
5-Methyluracil
Methylurea
Morphine monohydrate
Morpholine
Murexide
Naphthalene
1-Naphthaleneacetic acid
2-Naphthaleneacetic acid
1-Naphthoic acid
2-Naphthoic acid
1-Naphthol
2-Naphthol
1,4-Naphthoquinone
1-Naphthyl acetate
2-Naphthyl acetate
1-Naphthylamine
2-Naphthylamine
Nicotine
Nitrilotriacetic acid
Nitroacetone
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrobenzoic acid
3-Nitrobenzoic acid
4-Nitrobenzoic acid
3-Nitrobiphenyl
4-Nitrobiphenyl
1-Nitrobutane
Physical
State
lq
lq
lq
c
lq
g
g
g
g
c
lq
lq
g
lq
g
lq
g
lq
g
c
c
c
c
lq
c
c
g
c
c
c
c
c
lq
c
c
c
c
c
lq
c
lq
c
c
c
lq
c
c
c
c
c
g
⌬f H⬚
kJ · mol⫺1
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
23.3
20.5
⫺262.2
164.4
⫺531.8
113.0
121.3
117.2
⫺958.2
⫺617.6
⫺743.9
⫺63.3
68.0
45.8
44.6
83.5
43.1
82.6
⫺372.8
⫺462.8
⫺332.8
⫺711.7
top of rh
base of rh
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
307.8
208.5
216.9
213.7
256.5
383.7
383.7
380.3
249.0
65.9
145.2
145.2
146.0
122.9
320.6
149.8
95.4
121.8
321.3
94.9
164.8
⫺1212.1
77.9
150.6
⫺359.2
⫺371.9
333.5
⫺346.1
⫺121.0
⫺124.2
⫺183.4
⫺288.2
⫺304.3
67.8
59.7
39.3
⫺1311.9
⫺278.6
⫺26.1
⫺38.3
⫺42.0
12.5
⫺378.5
⫺394.7
⫺392.2
65.1
40.5
⫺143.9
201.6
224.1
167.4
333.1
165.7
131.9
166.9
⫺1307.5
178.2
174.1
151.0
146.2
⫺196.4
⫺220.5
⫺222.0
176.2
176.2
176.2
224.3
208.4
205.0
210.0
166.0
158.8
167.0
185.8
10.1
394.5
124.9
181.2
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.38
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
2-Nitrobutane
3-Nitro-2-butanol
N-Nitrodiethylamine
2-Nitrodiphenylamine
Nitroethane
2-Nitroethanol
2-Nitrofuran
5-Nitrofurancarboxylic acid
1-Nitroguanidine
Nitromethane
(Nitromethyl)benzene
1-Nitronaphthalene
1-Nitroso-2-naphthol
2-Nitroso-1-naphthol
4-Nitroso-1-naphthol
1-Nitropropane
2-Nitropropane
1-Nitro-2-propanone
4-Nitrosodiphenylamine
␤-Nitrostyrene
4-Nitrotoluene
Nonadecane
1-Nonadecene
1-Nonanal
Nonane
1-Nonanethiol
Nonanoic acid
1-Nonanol
2-Nonanone
5-Nonanone
1-Nonene
Norleucine
Octadecane
Octadecanoic acid
1,8-Octadecanoic acid
1-Octadecene
cis-9-Octadecenoic acid
trans-9-Octadecenoic acid
1,7-Octadiyne
Octafluorocyclobutane
Octafluoropropane
Octafluorotoluene
1-Octanal
Octanamide
Physical
State
g
lq
lq
c
lq
g
lq
c
c
c
lq
g
lq
c
c
c
c
lq
g
lq
g
c
c
c
c
g
g
g
lq
g
g
lq
g
lq
lq
g
c
c
g
c
c
g
lq
c
lq
lq
g
g
lq
g
c
⌬f H⬚
kJ · mol⫺1
⫺163.6
⫺390.0
⫺106.2
64.4
⫺143.9
⫺102.3
⫺350.7
⫺104.1
⫺516.8
⫺92.4
⫺113.1
⫺74.3
⫺22.8
42.6
⫺50.5
⫺61.8
⫺107.8
⫺167.2
⫺123.8
⫺180.3
⫺139.0
⫺294.7
213.0
30.5
⫺48.1
⫺435.1
⫺309.6
⫺310.3
⫺274.7
⫺228.2
⫺190.8
⫺659.7
⫺376.3
⫺397.2
⫺398.2
⫺103.5
⫺639.1
⫺567.4
⫺414.6
⫺947.7
⫺1038.1
⫺289.0
⫺743.5
⫺910.9
334.4
⫺1542.6
⫺1783.1
⫺1311.1
⫺289.6
⫺473.2
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
⫺6.2
383.3
123.5
⫺4.9
315.4
134.4
78.2
⫺14.4
⫺6.8
171.8
275.0
106.6
57.3
175.3
170.3
108.9
196.7
⫺74.9
895.2
891.0
539.6
24.8
53.0
505.7
571.2
⫺110.5
558.6
172.3
440.4
429.7
216.8
284.4
211.7
232.7
362.4
224.3
112.7
401.4
501.5
303.6
201.0
100.5
480.2
856.2
485.6
417.6
501.5
188.3
852.0
406.8
577.050
⫺1398.8
400.4
209.8⫺6
156.2
⫺83.3
355.5
500.7
262.3
194.0
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.39
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Octane
1-Octanenitrile
1-Octanethiol
Octanoic acid
1-Octanol
2-Octanol
2-Octanone
1-Octene
cis-2-Octene
trans-2-Octene
1-Octyne
(⫾)-Ornithine
Oxalic acid
Oxalic acid dihydrate
Oxaloyl dichloride
Oxaloyl dihydrazide
Oxamic acid
Oxamide
Oxazole
2-Oxetanone
Oxindole
2-Oxohexamethyleneimine
Oxomethyl (HCO)
2-Oxo-1,5-pentanedioic acid
4-Oxopentanoic acid
2-Oxopropanoic acid
8-Oxypurine
Papaverine
Paraformaldehyde
Paraldehyde
Pentachloroethane
Pentachlorofluoroethane
Pentachlorophenol
Pentacyclo[4.2.0.02,5.03,8.04,7]octane
Pentadecane
Pentadecanoic acid
1-Pentadecene
1-Pentadecyne
1,2-Pentadiene
cis-1,3-Pentadiene
trans-1,3-Pentadiene
1,4-Pentadiene
2,3-Pentadiene
Pentaerythritol
Pentaerythritol tetranitrate
Pentafluorobenzoic acid
Pentafluoroethane
Physical
State
⌬f H⬚
kJ · mol⫺1
⫺250.1
⫺208.6
⫺107.3
⫺44.9
⫺636.0
⫺426.5
lq
g
lq
g
lq
lq
lq
lq
lq
g
lq
lq
g
c
c
c
lq
c
c
c
g
lq
c
c
g
c
c
lq
c
c
c
lq
lq
g
g
c
c
⫺384.5
⫺121.8
⫺81.4
⫺135.7
⫺135.7
82.4
⫺652.7
⫺821.7
⫺1492.0
⫺367.6
⫺295.2
⫺661.2
⫺504.4
⫺5.5
⫺329.9
⫺172.4
⫺329.4
43.1
⫺1026.2
⫺697.1
⫺584.5
⫺64.4
⫺502.3
⫺177.6
⫺687.0
⫺187.6
⫺142.0
⫺317.2
⫺292.4
541.8
g
c
g
g
g
g
g
g
g
c
c
c
g
⫺352.8
⫺861.7
⫺227.2
⫺61.8
140.7
81.5
76.5
105.7
133.1
⫺920.6
⫺538.6
⫺1239.6
⫺1104.6
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
254.6
188.9
466.7
44.6
582.2
⫺143.1
377.4
⫺140.3
373.8
104.2
462.5
235.4
496.6
209.8
297.9
305.1
330.1
273.3
241.0
178.1
239.0
239.0
174.0
⫺697.9
109.8
91.0
⫺342.7
118.0
175.3
122.1
⫺95.1
28.0
168.6
224.7
156.8
34.6
⫺463.4
179.5
⫺70.3
⫺234.0
⫺144.1
381.5
391.8
251.9
75.2
739.4
⫺1029.3
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
16.4
163.1
293.9
210.4
145.8
146.73
170.3
205.9
⫺613.8
top of rh
base of rh
173.8
118.1
202.0
735.2
719.3
333.5
324.3
319.7
333.5
324.7
198.1
349.0
443.3
338.2
33.41
105.4
94.6
103.3
105.0
101.3
190.4
333.7
95.7
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.40
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Pentafluorophenol
2,3,4,5,6-Pentafluorotoluene
Pentamethylbenzene
Pentamethylbenzoic acid
Pentanal
Pentanamide
1-Pentanamine
Pentane
1,5-Pentanediol
2,4-Pentanedione
1,5-Pentanedithiol
Pentanenitrile
1-Pentanethiol
Pentanoic acid
1-Pentanol
2-Pentanol
3-Pentanol
2-Pentanone
3-Pentanone
1-Pentene
cis-2-Pentene
trans-2-Pentene
cis-2-Pentenenitrile
trans-2-Pentenenitrile
trans-3-Pentenenitrile
2-Pentenoic acid
3-Pentenoic acid
4-Pentenoic acid
cis-3-Penten-1-yne
trans-3-Penten-1-yne
Pentyl acetate
1-Pentyne
2-Pentyne
Perfluoropiperidine
Perylene
␣-Phellandrene
Phenanthrene
9,10-Phenanthrenedione
Phenazine
Phenol
Physical
State
c
lq
c
g
c
g
c
lq
lq
g
lq
lq
g
g
lq
lq
lq
g
lq
g
lq
g
lq
g
lq
g
lq
lq
g
lq
g
lq
g
lq
lq
lq
lq
lq
lq
lq
lq
lq
g
g
lq
c
lq
c
c
c
c
⌬f H⬚
kJ · mol⫺1
⫺1024.1
⫺883.8
⫺133.6
⫺74.5
⫺536.1
⫺228.5
⫺379.5
⫺173.5
⫺146.9
⫺531.5
⫺423.8
⫺380.6
⫺71.0
⫺33.1
⫺151.3
⫺559.4
⫺491.9
⫺351.6
⫺294.7
⫺365.2
⫺311.0
⫺368.9
⫺311.4
⫺297.3
⫺259.0
⫺296.5
⫺46.0
⫺21.2
⫺53.7
⫺27.6
⫺58.2
⫺31.9
71.8
74.9
80.9
⫺446.4
⫺434.8
⫺430.6
226.5
228.2
144.4
128.9
⫺2020.5
182.8
41.3
116.2
⫺154.7
237.0
⫺165.1
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
Cp⬚
J · deg⫺1 · mol⫺1
306.4
225.8
123.3
443.9
216.5
⫺108.3
383.0
125.4
⫺9.3
⫺8.4
262.7
349.0
397.9
cap height
base of text
218.0
167.2
120.2
321.3
208.2
120.1
180
⫺357.2
259.8
439.8
210.3
⫺146.0
402.5
⫺158.2
382.0
⫺137.1
69.9
376.2
266.0
262.6
345.8
258.6
346.3
256.5
340.4
184.1
121.0
190.9
154.0
109.6
151.7
101.8
157.0
108.5
210.3
194.2
⫺1768.5
329.8
331.8
393.4
261.0
106.7
98.7
296.8
268.3
215.1
220.6
⫺50.4
144.0
127.4
208.1
133.1
239.7
79.1
71.8
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.41
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Phenoxyacetic acid
Phenyl acetate
Phenylacetic acid
Phenylacetylene
(⫾)-3-Phenyl-2-alanine
Phenyl benzoate
Phenylboron dichloride
1-Phenylcyclohexene
Phenylcyclopropane
N-Phenyldiacetimide
1,3-Phenylenediamine
Phenyl formate
N-Phenylglycine
(⫾)-2-Phenylglycine
Phenylhydrazine
Phenyl 2-hydroxybenzoate
Phenylmethanethiol
Phenylmethyl acetate
N-Phenyl-2-naphthylamine
1-Phenyl-1-propanone
1-Phenyl-2-propanone
1-Phenylpyrrole
2-Phenylpyrrole
Phenylsuccinic acid
S-Phenyl thioacetate
Phenyl vinyl ether
Phosgene
Phthalamide
l,2-Phthalic acid
l,3-Phthalic acid
1,4-Phthalic acid
Phthalic anhydride
Phthalonitrile
Picric acid
␣-Pinene
␤-Pinene
Piperazine
2,5-Piperazinedione
Piperidine
2-Piperidone
L-Proline
Propadiene
Propanal
Propanamide
Propane
Propanediamide
(⫾)-1,2-Propanediamine
Physical
State
lq
g
c
lq
c
g
c
c
lq
lq
lq
c
c
lq
c
c
lq
c
lq
lq
c
lq
lq
c
c
c
lq
lq
g
c
c
c
c
c
c
c
lq
lq
c
c
lq
c
c
g
lq
g
c
lq
g
c
lq
⌬f H⬚
kJ · mol⫺1
⫺96.4
⫺513.8
⫺334.9
⫺398.7
327.3
⫺466.9
⫺241.0
⫺299.4
⫺16.8
100.3
⫺362.5
⫺7.8
⫺268.7
⫺402.5
⫺431.8
141.0
⫺436.6
43.5
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
Cp⬚
J · deg⫺1 · mol⫺1
⫺32.9
315.6
199.841
103.6
363.5
⫺211.7
321.7
213.6
114.9
203.0
154.5
159.6
top of rh
base of rh
cap height
base of text
217.0
148.5
159.8
⫺167.2
⫺151.9
154.3
139.2
⫺841.0
⫺122.0
⫺26.2
⫺220.9
⫺433.1
⫺782.0
⫺803.0
⫺816.1
⫺460.1
280.6
⫺214.4
⫺16.4
⫺7.7
⫺45.6
⫺446.5
⫺86.4
⫺306.6
515.2
190.5
⫺215.3
⫺185.6
⫺338.2
⫺103.8
⫺546.1
⫺97.8
⫺206.8
283.8
57.7
⫺591.6
207.9
188.3
⫺331.0
180.0
160.0
240.2
85.8
⫺112.1
210.0
164.9
202.4
243.9
⫺130.5
304.5
⫺23.4
270.2
179.9
(lq 307.8)
59.0
137.2
80.7
98.3⫺43
73.6
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.42
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
1,2-Propanediol
1,3-Propanediol
1,2-Propanedione
Propanedinitrile
1,2-Propanedithiol
1,3-Propanedithiol
Propanenitrile
1-Propanethiol
2-Propanethiol
1,2,3-Propanetriol tris(acetate)
Propanoic acid
Propanoic anhydride
1-Propanol
2-Propanol
2-Propenal
Propene
trans-1-Propene-1,2dicarboxylic acid
2-Propenenitrile
cis-1,2,3-Propenetricarboxylic acid
trans-1,2,3-Propenetricarboxylic acid
2-Propenoic acid
2-Propen-1-ol
2-Propenyl acetate
cis-1-Propenylbenzene
trans-1-Propenylbenzene
2-Propenylbenzene
Propyl acetate
Propylamine
Propylbenzene
Propylcarbamate
Propylchloroacetate
Propylchlorocarbonate
Propylcyclohexane
Propylcyclopentane
Propylene carbonate
Propylene oxide
Physical
State
⌬f H⬚
kJ · mol⫺1
lq
lq
lq
lq
lq
lq
lq
lq
g
lq
g
lq
lq
lq
lq
g
lq
g
g
g
c
⫺485.7
⫺464.9
⫺309.1
186.4
⫺79.4
⫺79.4
15.5
⫺99.9
⫺67.9
⫺105.0
⫺76.2
⫺1330.8
⫺510.7
⫺679.1
⫺302.6
⫺255.1
⫺318.1
⫺272.6
⫺85.8
20.0
⫺824.4
lq
g
c
147.1
180.6
⫺1224.7
c
⫺1233.0
lq
g
lq
g
lq
g
g
lq
lq
lq
g
lq
g
c
lq
g
lq
g
lq
g
lq
lq
g
⫺383.8
⫺336.5
⫺171.8
⫺124.5
⫺386.2
121.3
117.2
88.0
⫺101.5
⫺70.2
⫺38.3
7.9
⫺552.6
⫺515.6
⫺492.7
⫺237.4
⫺192.5
⫺188.8
⫺147.1
⫺613.2
⫺123.0
⫺94.7
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
190.8
89.2
193.6
322.7
181.1
309.2
119.3
144.6
94.8
145.3
96.0
384.7
152.8
235.0
143.7
85.6
155.0
89.3
266.6
64.3
195.4
274.1
108.8
63.8
⫺286.3
315.2
⫺71.3
307.6
216.9
213.7
383.7
380.3
145.7
77.8
138.9
76.0
184.1
145.2
146.0
325.1
287.8
400.7
196.2
162.5
91.2
214.7
152.3
2.2
⫺2.6
⫺383.5
⫺475.6
⫺170.6
⫺161.8
⫺180.3
⫺173.4
⫺64.6
62.8
39.8
137.2
189.3
242.5
336.4
233.5
324.3
458.3
191.0
52.6
311.9
419.5
310.8
417.3
⫺25.8
196.5
286.9
47.3
242.0
184.2
216.8
154.6
218.6
120.4
72.6
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.43
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Propyl formate
Propyl nitrate
S-Propyl thioacetate
Propyl trichloroacetate
Propyl vinyl ether
2-Propynyl-1-amine
Propyne
2-Propynoic acid
1H-Purine
Pyrazine
1H-Pyrazole
Pyrene
Pyridazine
Pyridine
3-Pyridinecarbonitrile
3-Pyridinecarboxylic acid
Pyrimidine
1H-Pyrrole
Pyrrole-2-carboxaldehyde
Pyrrole-2-carboldoxime
Pyrrolidine
(⫾)-2-Pyrrolidinecarboxylic
acid
2-Pyrrolidone
Quinhydrone
Quinidine
Quinine
Quinoline
Raffinose
L-(⫹)-Rhamnose
D-(⫺)-Ribose
Salicylaldehyde
Salicylaldoxime
Salicylic acid
Semicarbazide std. state
(⫺)-Serine
(⫾)-Serine
L-(⫺)-Sorbose
5,5⬘-Spirobis(1,3-dioxane)
Spiro[2.2]pentane
cis-Stilbene
trans-Stilbene
(⫺)-Strychnine
Styrene
Succinic acid
Succinic acid monoamide
Physical
State
⌬f H⬚
kJ · mol⫺1
lq
g
lq
lq
lq
lq
g
lq
c
c
c
lq
c
lq
lq
g
c
c
lq
lq
c
c
lq
g
c
⫺500.3
⫺173.9
⫺294.1
⫺513.0
⫺190.9
205.7
184.9
⫺193.2
169.4
139.8
116.0
105.4
125.5
224.8
100.2
140.4
193.4
⫺344.9
145.9
63.1
⫺106.4
12.1
⫺41.0
⫺3.6
⫺524.2
c
c
c
c
lq
c
c
c
lq
c
c
aq
c
c
c
c
lq
g
lq
c
c
lq
g
c
c
⫺286.2
⫺82.8
⫺160.3
⫺155.2
141.2
⫺3184
⫺1073.2
⫺1047.2
⫺279.9
⫺183.7
⫺589.5
⫺166.9
⫺732.7
⫺739.0
⫺1271.5
⫺702.1
157.5
185.2
183.3
136.9
⫺171.5
103.8
147.9
⫺940.5
⫺581.2
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
⫺27.3
385.4
171.4
121.3
194.4
248.1
60.7
224.9
229.7
177.9
282.8
132.7
78.1
156.4
127.7
114.7
204.1
309.5
156.6
81.1
⫺323.0
325.9
164.4
277.0
275.7
217.2
194.9
181.3
190.2
top of rh
base of rh
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
22218
⫺418.1
⫺40.6
178.2
297.9
⫺908.4
220.9
265.3
193.7
282.2
317.6
251.0
202.4
213.8
⫺747.4
237.6
345.1
167.3
134.5
88.1
182.0
122.1
153.1
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.44
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Succinic anhydride
Succinimide
Succinonitrile
(⫹)-Sucrose
(⫾)-Tartaric acid
(⫺)-Tartaric acid
meso-Tartaric acid
␣-Terpinene
1,1,2,2,-Tetrabromoethane
Tetrabromoethylene
Tetrabromomethane
Tetrabutyltin
Tetracene
Tetrachloro-1,4-benzoquinone
1,1,2,2,-Tetrachloro-1,2difluoroethane
1,1,1,2-Tetrachloroethane
1,1,2,2,-Tetrachloroethane
Tetrachloroethylene
Tetrachloromethane
1,1,1,3-Tetrachloropropane
1,2,2,3-Tetrachloropropane
1,1,2,2-Tetracyanocyclopropane
Tetracyanoethylene
Tetracyanomethane
Tetradecane
Tetradecanoic acid
1-Tetradecanol
1-Tetradecene
Tetraethylene glycol
Tetraethylgermanium
Tetraethyllead
Tetraethylsilane
Tetraethyltin
1,1,1,2-Tetrafluoroethane
Tetrafluoroethylene
Tetrafluoromethane
2,2,3,3-Tetrafluoro-1-propanol
Tetrahydrofuran
Tetrahydro-2-furanmethanol
1,2,3,4-Tetrahydronaphthalene
5,6,7,8-Tetrahydro-1-naphthol
Physical
State
c
c
lq
c
c
c
c
g
lq
g
c
g
lq
c
c
⌬f H⬚
kJ · mol⫺1
⫺608.6
⫺459.0
139.7
⫺2226.1
⫺1290.8
⫺1282.4
⫺1279.9
⫺20.5
29.4
83.9
⫺304.6
158.8
⫺288.7
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
⫺1544.7
191.6
360.2
47.7
67.0
387.1
212.5
358.1
lq
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
145.6
165.7
102.7
144.3
91.2
178.6
g
lq
g
lq
g
lq
g
lq
g
lq
lq
c
⫺489.9
⫺407.1
382.8
⫺149.4
⫺195.0
⫺149.2
⫺50.6
⫺10.9
⫺128.2
⫺95.7
⫺207.8
⫺251.8
590
⫺80.3
⫺95.0
⫺85.6
355.9
246.9
362.7
3.0
⫺62.6
⫺53.6
266.9
216.2
309.9
c
c
g
c
c
g
lq
lq
lq
lq
lq
g
g
g
g
lq
g
lq
lq
c
623.8
611.6
⫺332.1
⫺833.5
⫺629.6
⫺206.5
⫺981.6
⫺210.5
52.7
66.9
700.4
154.8
696.2
336.4
464.6
307.4
298.1
⫺826.2
⫺623.7
⫺888.3
316.2
300.0
261.6
86.3
80.5
61.0
204.3
302.4
124.0
76.3
181.2
217
⫺95.8
⫺895.8
⫺658.9
⫺933.6
⫺1061.3
⫺216.2
⫺184.2
⫺435.6
⫺29.2
⫺285.3
123.4
153.8
102.7
162.3
100.8
143.4
130.7
83.4
326.1
432.0
388.0
315.3
428.8
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.45
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Tetrahydro-2H-pyran
Tetrahydro-2H-pyran-2-one
1,2,3,6-Tetrahydropyridine
Tetrahydrothiophene
Tetrahydrothiophene-1,1dioxide
Tetraiodoethylene
Tetraiodomethane
Tetramethylammonium bromide
Tetramethylammonium chloride
Tetramethylammonium iodide
1,2,3,4-Tetramethylbenzene
1,2,3,5-Tetramethylbenzene
1,2,4,5-Tetramethylbenzene
2,3,5,6-Tetramethylbenzoic acid
2,2,3,3-Tetramethylbutane
1,1,2,2-Tetramethylcyclopropane
Tetramethyllead
2,2,3,3-Tetramethylpentane
2,2,3,4-Tetramethylpentane
2,2,4,4-Tetramethylpentane
2,3,3,4-Tetramethylpentane
Tetramethylsilane
Tetramethylsuccinic acid
Tetramethylthiacyclopropane
Tetramethyltin
Tetranitromethane
1,1,1,2-Tetraphenylethane
1,1,2,2-Tetraphenylethane
Tetraphenylethylene
Tetraphenylhydrazine
Tetraphenylmethane
Tetraphenyltin
Tetrapropylgermanium
Tetrapropyltin
1,2,3,4-(1H)-Tetrazole
Theobromine
2-Thiaadamantane
Thiacyclobutane
Thiacycloheptane
Thiacyclohexane
Thiacyclopentane
Thiacyclopropane
Thianthrene
Thiirane
Physical
State
⌬f H⬚
kJ · mol⫺1
lq
lq
lq
lq
g
lq
⫺258.3
⫺436.7
33.5
⫺72.9
⫺34.1
c
g
c
c
c
lq
lq
c
c
c
g
lq
305.0
474.0
⫺251.0
⫺276.4
⫺203.4
⫺90.2
⫺96.4
⫺119.9
⫺506.1
⫺269.0
⫺225.6
⫺119.7
lq
g
lq
lq
lq
lq
lq
g
c
c
g
lq
c
c
c
c
c
c
g
lq
c
c
c
g
g
lq
g
g
g
c
g
97.9
135.9
⫺278.3
⫺277.7
⫺280.0
⫺277.9
⫺264.0
⫺239.1
⫺1012.5
⫺83.0
⫺18.8
38.4
223.0
216.0
311.5
457.9
247.1
412.1
⫺229.7
⫺211.3
237.0
⫺361.5
⫺143.5
60.6
⫺61.3
⫺106.3
⫺63.5
⫺33.8
82.2
⫺182.5
82.0
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
top of rh
base of rh
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
156.5
⫺45.8
309.6
92.5
18020
217.1
391.9
95.9
106.7
98.7
101.3
290.6
416.5
245.6
240.7
215.1
22.0
273.7
389.4
239.2
192.5
262.8
270.7
320.1
420.5
144.0
271.5
266.3
359.1
204.1
143.9
53.1
46.0
96.9
285.0
361.9
218.2
323.0
309.4
255.3
68.3
124.6
163.3
109.7
90.9
53.7
96.8
255.2
53.3
⫺100.0
574.0
107.1
84.1
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.46
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Thiirene
Thioacetamide
Thioacetic acid
1,2-Thiocresol
Thiohydantoic acid
Thiohydantoin
2-Thiolactic acid
Thiophene
Thiophenol
Thiosemicarbazide
Thiourea
(⫺)-Threonine
(⫾)-Threonine
Thymine
Thymol
Toluene
1H-1,2,4-Triazol-3-amine
2,4,6-Triamino-1,3,5-triazine
2-Triazoethanol
Tribenzylamine
Tribromoacetaldehyde
Tribromochloromethane
Tribromofluoromethane
Tribromomethane
Tributoxyborane
Tributylamine
Tributyl phosphate
Tributylphosphine oxide
Trichloroacetaldehyde
2,2,2-Trichloroacetamide
Trichloroacetic acid
ionized
Trichloroacetonitrile
Trichloroacetyl chloride
Trichlorobenzoquinone
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethylene
Trichlorofluoromethane
Trichloromethane
Physical
State
g
c
lq
g
lq
c
c
lq
lq
g
lq
g
c
c
g
c
c
c
c
lq
g
c
c
lq
c
lq
g
g
lq
g
lq
lq
lq
c
lq
c
c
aq
g
lq
c
lq
g
lq
g
lq
g
lq
g
lq
g
⌬f H⬚
kJ · mol⫺1
300.0
⫺71.7
⫺216.9
⫺175.1
44.2
⫺554.8
⫺249.0
⫺468.4
80.2
115.0
64.1
111.6
25.1
⫺89.1
22.9
⫺807.2
⫺758.8
⫺462.8
⫺309.7
12.4
50.4
76.8
⫺72.4
94.6
140.6
⫺130.3
12.6
⫺190.0
⫺28.5
23.8
⫺1199.6
⫺281.6
⫺1456
⫺460
⫺234.5
⫺358.2
⫺503.3
⫺517.6
⫺280.8
⫺269.9
⫺177.4
⫺144.6
⫺191.5
⫺151.2
⫺43.6
⫺9.0
⫺301.3
⫺268.3
⫺134.5
⫺102.7
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
Cp⬚
J · deg⫺1 · mol⫺1
255.3
54.7
313.2
80.9
121.2
126.8
134.0
147.6
181.2
278.9
222.8
336.9
123.8
72.9
173.2
104.9
21.8
115.9
275.8
⫺154.0
cap height
base of text
150.8
113.8
122.0
221.0
320.7
184.5
149.1
9.1
⫺193.1
8.0
⫺5.0
357.8
345.9
220.9
330.9
157.0
103.6
89.4
84.4
130.7
71.2
151.0
336.6
96.1
⫺77.5
227.4
323.1
232.6
337.1
19.9
⫺236.8
⫺249.3
73.7
⫺76.0
324.8
255.4
309.7
201.7
295.7
144.3
93.3
150.9
89.0
124.4
80.3
121.6
78.0
114.2
65.7
⫺76.2
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.47
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
1,2,2-Trichloropropane
1,2,3-Trichloropropane
1,2,3-Trichloropropene
1,1,2-Trichlorotrifluoroethane
1,1,1-Tricyanoethane
Tricyanoethylene
Tridecane
Tridecanoic acid
1-Tridecene
Triethanolamine
Triethoxyborane
Triethoxymethane
Triethylaluminum
Triethylamine
Triethylaminoborane
Triethyl arsenite
Triethylarsine
Triethylbismuthine
Triethylborane
Triethylenediamine
Triethylene glycol
Triethyl phosphate
Triethylphosphine
Triethyl phosphite
Triethylstibine
Triethylsuccinic acid
Triethyl thiophosphate
Trifluoroacetic acid
Trifluoroacetonitrile
1,1,1-Trifluoroethane
1,1,2-Trifluoroethane
2,2,2-Trifluoroethanol
Trifluoroethylene
Trifluoroiodoethane
Trifluoroiodomethane
Trifluoromethane
(Trifluoromethyl)benzene
1,1,1-Trifluoro-2,4-pentanedione
3,3,3-Trifluoropropene
Trihexylamine
(⫾)-Trihydroxyglutaric acid
2,4,6-Trihydroxypryimidine
Triiodomethane
Triisopropyl phosphite
Trimethoxyborane
Trimethoxyethane
Trimethoxymethane
Physical
State
⌬f H⬚
kJ · mol⫺1
g
lq
g
lq
lq
c
c
g
c
g
c
lq
lq
lq
lq
g
lq
lq
lq
lq
lq
g
c
lq
lq
lq
lq
lq
c
lq
lq
g
g
g
lq
g
g
g
g
g
lq
⫺185.8
⫺230.6
⫺182.9
⫺101.8
⫺805.8
351.0
439.3
⫺311.5
⫺806.6
⫺186.0
⫺664.2
⫺1047.4
⫺687.3
⫺236.8
⫺127.7
⫺92.8
⫺198.6
⫺706.7
13.0
169.9
⫺194.6
⫺157.7
⫺14.2
⫺804.2
⫺1243
⫺89.1
⫺861.5
5.0
⫺1066.5
⫺972.8
⫺1069.9
⫺497.9
⫺744.6
⫺730.7
⫺932.4
⫺490.4
⫺644.5
⫺587.8
⫺695.4
⫺599.1
⫺1040.2
g
lq
c
c
g
lq
g
lq
lq
⫺614.2
⫺433.0
⫺1490
⫺634.7
251.0
⫺980.3
⫺899.1
⫺612.0
⫺570.0
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
⫺97.8
382.9
top of rh
base of rh
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
112.2
183.6
170.1
58.5
661.5
303.2
146.3
657.3
292.4
389.0
110.3
405.4
9.4
16.1
239.7
336.7
437.8
157.6
241.2
⫺461.9
⫺678.3
298.1
279.9
77.9
78.2
⫺469.5
292.6
69.2
⫺572.0
⫺658.9
⫺511.3
307.5
259.6
372.6
70.9
51.1
130.4
178.0
356.2
75.1
219.9
160.9
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.48
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Trimethylacetic acid
Trimethylacetic anhydride
2⬘,4⬘,5⬘-Trimethylacetophenone
2⬘,4⬘,6⬘-Trimethylacetophenone
Trimethylaluminum
Trimethylamine
std. state
Trimethylamine-aluminum
chloride adduct
Trimethylamine-borane
Trimethylammonium ion,
std. state
Trimethyl arsenite
Trimethylarsine
1,2,3-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
2,3,4-Trimethylbenzoic acid
2,3,5-Trimethylbenzoic acid
2,3,6-Trimethylbenzoic acid
2,4,5-Trimethylbenzoic acid
2,4,6-Trimethylbenzoic acid
3,4,5-Trimethylbenzoic acid
2,6,6-Trimethylbicyclo-[3.1.1]2-heptene
Trimethylbismuthine
Trimethylborane
2,2,3-Trimethylbutane
2,2,3-Trimethylbutane
2,3,3-Trimethyl-1-butene
Trimethylchlorosilane
cis,cis-1,3,5-Trimethylcyclohexane
1,1,2-Trimethylcyclopropane
Trimethylene oxide (Oxetane)
Trimethylgallium
2,3,5-Trimethylhexane
Trimethylindium
2,2,3-Trimethylpentane
2,2,4-Trimethylpentane
2,3,3-Trimethylpentane
2,3,4-Trimethylpentane
2,2,4-Trimethyl-3-pentanone
2,4,4-Trimethyl-1-pentene
Physical
State
⌬f H⬚
kJ · mol⫺1
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
lq
lq
lq
lq
⫺564.4
⫺779.9
⫺252.3
⫺267.4
lq
lq
g
aq
c
⫺136.4
⫺45.7
⫺23.7
⫺76.0
⫺879.1
⫺9.9
98.9
93.0
209.4
208.5
287.1
133.5
c
⫺142.5
70.7
187.0
aq
lq
g
lq
lq
lq
c
c
c
c
c
c
lq
⫺112.9
⫺590.8
11.7
⫺58.5
⫺61.8
⫺63.4
⫺486.6
⫺488.7
⫺475.7
⫺495.7
⫺477.9
⫺500.9
16.4
37.2
196.7
107.5
102.3
103.9
267.8
284.2
273.6
216.4
215.0
209.3
g
g
g
lq
lq
lq
g
g
192.9
⫺124.3
⫺204.5
⫺236.5
⫺117.7
⫺382.8
⫺352.8
⫺215.4
⫺35.9
4.3
314.7
383.3
292.2
88.5
164.6
213.5
⫺246.4
⫺243.5
33.9
278.2
369.1
390.4
179.6
lq
lq
g
g
lq
g
lq
g
lq
g
lq
g
lq
lq
lq
⫺96.2
⫺110.8
⫺80.5
⫺46.9
⫺284.0
170.7
⫺256.9
⫺220.0
⫺259.2
⫺224.0
⫺253.5
⫺216.3
⫺255.0
⫺381.6
⫺145.9
⫺9.8
273.9
9.3
17.1
6.9
13.7
10.6
18.9
10.7
327.6
425.2
328.0
423.2
334.4
431.5
329.3
86.4
306.3
155.6
137.9
91.8
188.9
239.1
245.6
247.3
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.49
THERMODYNAMIC PROPERTIES
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
2,4,4-Trimethyl-2-pentene
Trimethylphosphine
Trimethylphosphine oxide
Trimethyl phosphite
Trimethylsilane
Trimethylsilanol
Trimethylstibine
Trimethylsuccinic acid
Trimethylsuccinic anhydride
Trimethylthiacyclopropane
Trimethyltin bromide
Trimethyltin chloride
Trimethylurea
Trinitroacetonitrile
2,4,6-Trinitroanisole
1,3,5-Trinitrobenzene
1,1,1-Trinitroethane
Trinitroglycerol
Trinitromethane
2,4,6-Trinitrophenetole
2,4,6-Trinitrophenol
2,4,6-Trinitrophenylhydrazine
2,4,6-Trinitrotoluene
2,4,6-Trinitro-1,3-xylene
Trioctylamine
1,3,6-Trioxacyclooctane
1,3,5-Trioxane
Triphenylamine
Triphenylarsine
Triphenylbismuthine
Triphenylborane
Triphenylene
1,1,1-Triphenylethane
1,1,2-Triphenylethane
Triphenylethylene
2,4,6-Triphenylimidazole
Triphenylmethane
Triphenylmethanol
Triphenyl phosphate
Triphenylphosphine
Triphenylphosphine oxide
Triphenylstibine
Tripropoxyborane
Tripropylamine
Tripropynylamine
Tris(acetylacetonato)chromium
Tris(diethylamino)phosphine
1,1,1-Tris(hydroxymethyl)ethane
Physical
State
⌬f H⬚
kJ · mol⫺1
⫺142.4
⫺122.2
⫺477.8
⫺741.0
lq
lq
c
lq
g
lq
g
c
c
lq
lq
lq
c
lq
c
c
lq
lq
lq
g
c
c
c
c
c
lq
lq
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
lq
lq
lq
c
⫺545.0
32.2
⫺1000.8
⫺688.3
⫺60.5
⫺185.4
⫺213.0
⫺330.5
183.7
⫺157.3
⫺37.2
⫺96.9
⫺370.9
⫺32.8
⫺0.2
⫺204.6
⫺214.3
36.8
⫺65.5
⫺102.5
⫺584.9
⫺515.9
⫺522.5
234.7
310.0
469.0
48.5
151.8
157.2
130.2
233.5
272
171.2
⫺3.4
⫺757
232.2
⫺60.3
329.3
⫺1127.2
⫺207.2
814.2
⫺1533.0
lq
c
⫺289.5
⫺744.6
⌬f G⬚
kJ · mol⫺1
88.0
S⬚
J · deg⫺1 · mol⫺1
top of rh
base of rh
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
311.7
331.0
117.9
133.0
114.4
504.2
329.2
254.7
514.6
412.5
272.8
312.1
329.3
295.0
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.50
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.1 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of Organic
Compounds (Continued)
Substance
Tris(hydroxymethyl)nitromethane
Tris(isopropoxy)borane
Tris(trimethylsilyl)amine
(⫺)-Tryptophane
(⫺)-Tyrosine
Undecane
Undecanoic acid
1-Undecanol
1-Undecene
10-Undecenoic acid
Uracil
Urea
Urea nitrate
Urea oxalate
5-Ureidohydantoin
Uric acid
(⫾)-Valine
Valylphenylalanine
Vinyl acetate
Vinylbenzene
Vinylcyclohexane
4-Vinylcyclohexene
Vinylcyclopentane
Vinylcyclopropane
2-Vinylpyridine
Xanthine
Xanthone
1,2-Xylene
1,3-Xylene
1,4-Xylene
Xylitol
D-(⫹)-Xylose
Physical
State
⌬f H⬚
kJ · mol⫺1
c
⫺735.6
lq
c
c
c
lq
c
lq
g
c
c
c
g
c
c
c
c
c
c
g
lq
lq
lq
lq
lq
lq
c
c
lq
g
lq
g
lq
g
c
c
⫺293.3
⫺725.1
⫺415.3
⫺685.1
⫺327.2
⫺735.9
⫺504.8
⫺144.8
⫺577
⫺429.4
⫺333.1
⫺245.8
⫺564.0
⫺1528.4
⫺718.0
⫺618.8
⫺628.9
⫺767.8
⫺314.4
103.8
⫺88.7
26.8
⫺34.8
122.5
157.1
⫺379.6
⫺191.5
⫺24.4
19.1
⫺25.4
17.3
⫺24.4
18.0
⫺1118.5
⫺1057.8
⌬f G⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
⫺119.4
⫺385.7
22.8
251.0
214.0
458.1
238.2
216.4
344.9
129.5
579.4
246.7
⫺196.8
104.6
120.5
93.1
⫺434.0
⫺358.8
⫺359.0
195.1
173.2
178.9
166.1
168.8
⫺165.9
161.1
151.3
110.3
122.1
107.7
118.9
110.1
121.1
246.5
352.8
252.2
357.7
247.4
352.4
186.1
133.3
183.3
127.6
181.5
126.9
cap height
base of text
Cp⬚
J · deg⫺1 · mol⫺1
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.51
THERMODYNAMIC PROPERTIES
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds
top of rh
base of rh
cap height
base of text
Abbreviations Used in the Table
⌬Hm, enthalpy of melting (at the melting point) in kJ · mol⫺1
⌬Hv, enthalpy of vaporization (at the boiling point) in kJ · mol⫺1
⌬Hs, enthalpy of sublimation (or vaporization at 298 K) in kJ · mol⫺1
Cp, specific heat (at temperature specified on the Kelvin scale) for the physical state in existence (or specified:
c, lq, g) at that temperature in J · K⫺1 · mol⫺1
⌬Ht, enthalpy of transition (at temperature specified, superscript, measured in degrees Celsius) in kJ · mol⫺1
Cp
Substance
Acenaphthene
Acenaphthylene
Acetaldehyde
Acetamide
Acetanilide
Acetic acid
Acetic anhydride
Acetone
Acetonitrile, ⌬Ht ⫽ 0.22⫺56
Acetophenone
Acetyl bromide
Acetyl chloride
Acetylene
Acetylene-d2
Acetylenedicarbonitrile
Acetyl fluoride
Acetyl iodide
Acrylic acid
Acrylonitrile
Adamantane
Adenine
␣-Alanine
Allyl tert-butyl sulfide
Allyl ethyl sulfone
Allyl ethyl sulfoxide
Allyl methyl sulfone
Allyl trichloroacetate
3-Aminoacetophenone
4-Aminoacetophenone
2-Aminobenzoic acid
3-Aminobenzoic acid
4-Aminobenzoic acid
2-Aminoethanol
Aniline
Anthracene
9,10-Anthraquinone
cis-Azobenzene
trans-Azobenzene
Azobutane
Azomethane
Azomethane-d6
⌬Hm
⌬Hv
⌬Hs
21.54
54.73
3.24
15.71
25.8
56.1
64.7
23.7
38.2
29.1
29.8
38.8
86.2
73.0
25.5
78.7
80.8
23.4
48.3
31.0
32.9
55.9
33.1
30.1
21.3
11.54
10.5
5.69
8.17
3.8
11.16
6.23
12.1
15.9
20.5
21.8
20.9
20.5
10.56
28.83
22.04
22.6
17.0
44.1
32.6
28.8
25.1
38.5
54.3
33.5
59.7
108.8
138.1
44.4
83.7
71.6
79.5
52.3
400 K
600 K
800 K
1000 K
66.3(g)
85.9
101.3
112.5
79.7
129.1
92.1
61.2
106.2
174.1
122.8
76.8
125.5
204.6
144.9
89.0
139.3
226.4
162.0
98.3
78.9
50.1
54.8
94.8
97.0
58.1
61.9
106.2
110.0
63.5
67.4
114.1
119.7
68.0
71.8
119.8
96.0
76.8
123.4
96.7
142.0
110.6
155.3
120.8
143.0
192.8
225.1
230.9
93.9
110.7
123.1
142.8
145.7
165.2
162.6
180.6
104.9
128.0
116.1
50.9
42.4
56.5
88.5
55.8
101.5
112.1
92.9
93.8
49.3
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.52
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
cap height
base of text
Cp
Substance
Azoisopropane
Azopropane
trans-Azoxybenzene
Azulene
Benzaldehyde
Benzamide
1,2-Benzanthracene
2,3-Benzanthracene
1,2-Benzanthracene-9,10-dione
Benzene
Benzeneacetic acid
1,3-Benzenedicarboxylic acid
1,4-Benzenedicarboxylic acid
Benzenethiol
Benzil
Benzoic acid
Benzoic anhydride
Benzonitrile
Benzo[def]phenanthrene
Benzophenone
1,4-Benzoquinone
Benzo[f]quinoline
Benzo[h]quinoline
Benzo[b]thiophene, ⌬Ht ⫽ 3.0⫺11.6
Benzotrifluoride
Benzoyl bromide
Benzoyl chloride
Benzoyl iodide
4-Benzphenanthrene
Benzyl acetate
Benzyl alcohol
Benzylamine
Benzyl benzoate
Benzyl bromide
Benzyl chloride
Benzyl ethyl sulfide
Benzyl iodide
Benzyl mercaptan
Benzyl methyl ketone
Benzyl methyl sulfide
Bicyclo[1.1.0]butane
Bicyclo[2.2.1]hepta-2,5-dione
Bicyclo[2.2.1]heptane
Bicyclo[4.1.0]heptane
Bicyclo[2.2.1]-2-heptene
Bicyclo[3.1.0]hexane
Bicyclohexyl
Bicyclo[2.2.2]octane
Bicyclo[4.2.0]octane
Bicyclo[5.1.0]octane
⌬Hm
⌬Hv
⌬Hs
400 K
600 K
800 K
1000 K
176.4
248.2
295.4
327.4
113.5(g)
160.1
190.5
211.4
138.4
196.7
234.9
260.7
140.8
187.4
217.9
238.8
36.0
39.9
17.93
12.1
9.32
18.49
9.95
14.49
11.48
23.54
18.06
17.2
10.88
17.1
18.19
18.53
55.5
42.5
76.8
49.8
30.7
123.0
126
82.8
33.8
39.9
106.7
98.3
47.6
50.6
45.9
91.1
96.4
52.5
100.2
94.1
62.8
83.1
80.8
11.8
37.6
58.6
54.8
61.9
106.3
8.97
49.4
50.5
53.6
60.3
60.2
77.8
47.3
51.5
56.9
47.3
56.6
49.0
53.6
23.4
32.9
40.2
38.0
38.8
32.8
58.0
48.0
42.0
43.5
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.53
THERMODYNAMIC PROPERTIES
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
Bicyclo[2.2.2]-2-octene
Bicyclopropyl
Biphenyl
Biphenylene
Bis(2-butoxyethyl) ether
Bis(2-chloroethyl) ether
Bis(2-ethoxyethyl) ether
Bis(2-ethoxymethyl) ether
Bis(2-hydroxyethyl) ether
Bis(2-methoxyethyl) ether
Bromobenzene
4-Bromobenzoic acid
1-Bromobutane
(⫾)-2-Bromobutane
1-Bromo-2-chloroethane
Bromochloromethane
1-Bromo-3-chloropropane
1-Bromo-2-chloro-1,1,2-trifluoroethane
Bromochloro-2,2,2-trifluoroethane
1-Bromododecane
Bromoethane
Bromoethylene
1-Bromoheptane
1-Bromohexadecane
1-Bromohexane
Bromomethane, ⌬Ht ⫽ 0.47⫺99.4
1-Bromo-2-methylpropane
2-Bromo-2-methylpropane
⌬Ht ⫽ 5.7⫺64.5
⌬Ht ⫽ 1.0⫺41.6
1-Bromonaphthalene
1-Bromooctane
1-Bromopentane
1-Bromopropane
2-Bromopropane
3-Bromopropene
Bromotrichloromethane
Bromotrifluoromethane
Bromotrimethylsilane
1,2-Butadiene
1,3-Butadiene
1,3-Butadiyne
Butanal
Butanamide
Butane, ⌬Ht ⫽ 2.1⫺165.6
1,2-Butanediamine
Butanedinitrile
1,3-Butanediol
1,4-Butanediol
2,3-Butanediol
⌬Hm
18.6
8.66
10.62
6.69
6.89
5.86
5.12
5.98
⌬Hv
45.6
55.9
45.2
49.0
36.2
52.3
43.1
37.9
32.5
30.8
33.7
30.0
37.6
28.3
28.1
74.8
27.0
23.4
⌬Hs
43.8
33.5
81.8
84.3
400 K
600 K
800 K
1000 K
221.0
307.7
363.7
401.7
127.4
171.5
199.9
219.2
136.6
138.1
180.0
214.7
211.2
238.2
234.4
79.2
66.6
102.8
83.0
119.6
94.1
74.8
132.2
102.3
50.0
62.7
72.2
79.5
146.1
190.7
220.3
241.6
165.6
107.5
110.2
219.0
140.8
144.0
257.5
164.9
167.7
286.0
182.8
185.2
79.3
91.3
97.5
100.9
98.4
101.2
84.4
126.4
128.5
154.1
96.8
165.7
150.7
169.5
105.1
195.0
167.4
123.9
168.6
201.8
226.9
44.7
57.3
44.5
87.9
36.7
34.4
38.2
32.8
44.1
30.1
29.8
28.0
18.2
50.6
94.4
45.9
22.8
34.8
31.8
1.97
23.9
31.3
29.2
15.16
39.3
11.46
6.53
35.0
29.8
28.3
30.2
52.5
55.8
41.3
32.0
30.2
32.7
7.0
7.98
24.0
22.5
32.6
23.2
20.9
11.09
17.6
4.66
31.5
3.7
48.5
58.5
2.54
22.4
34.5
85.9
21.0
46.3
70.0
67.8
76.6
59.2
111.3
216.3
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.54
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
cap height
base of text
Cp
Substance
2,3-Butanedione
1,4-Butanedithiol
Butanenitrile
meso-1,2,3,4-Butanetetrol
1,4-Butanedithiol
1-Butanethiol
2-Butanethiol
1,2,4-Butanetriol
Butanoic acid
Butanoic anhydride
1-Butanol
2-Butanol
2-Butanone
trans-2-Butenal
1-Butene
cis-2-Butene
trans-2-Butene
cis-2-Butenedinitrile
cis-2-Butenedioic acid
trans-2-Butenedioic acid
cis-2-Butene-1,4-diol
trans-2-Butene-1,4-diol
cis-2-Butenenitrile
trans-2-Butenenitrile
3-Butenenitrile
cis-2-Butenoic acid
trans-2-Butenoic acid
cis-2-Buten-1-ol
1-Buten-3-yne
2-Butoxyethanol
1-tert-Butoxy-2-ethoxyethane
2-(2-Butoxyethoxy)ethanol
2-Butoxyethyl acetate
1-tert-Butoxy-2-methoxyethane
N-Butylacetamide
Butyl acetate
tert-Butyl acetate
Butylamine
sec-Butylamine
tert-Butylamine
Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
sec-Butyl butanoate
Butyl chloroacetate
Butyl 2-chlorobutanoate
Butyl 3-chlorobutanoate
Butyl 4-chlorobutanoate
Butyl 2-chloropropanoate
Butyl 3-chlorobutanoate
⌬Hm
⌬Hv
5.02
33.7
10.46
6.5
8.44
32.2
30.6
58.6
41.8
50.0
43.3
40.8
31.3
3.9
7.58
9.8
22.1
23.3
22.7
11.08
9.28
⌬Hs
38.7
55.1
39.3
135.1
49.7
36.6
34.0
400 K
600 K
800 K
1000 K
118.8
155.1
181.9
201.8
146.2
148.0
194.7
194.2
233.0
227.2
263.4
251.1
137.2
141.0
124.7
183.7
187.1
163.6
218.0
220.4
192.8
243.8
245.3
214.8
109.0
101.8
108.9
147.1
141.4
145.6
174.9
171.0
184.9
195.9
193.1
194.9
89.0
111.6
127.2
138.7
148.3
148.1
152.6
229.1
197.9
199.0
204.5
314.6
234.4
236.1
240.5
373.9
261.7
261.7
266.9
416.3
40.5
52.3
49.7
34.8
34.5
20.2
22.2
21.4
72.0
110.0
136.3
66.1
69.0
38.9
40.0
40.0
12.57
12.98
46.4
56.6
50.9
28.0
38.5
0.88
11.22
9.83
8.39
36.3
33.1
31.8
29.9
28.3
38.9
38.0
37.6
59.5
47.8
76.1
43.9
38.0
35.7
32.8
29.6
51.4
48.0
47.7
47.3
51.0
52.7
53.1
54.4
54.4
55.4
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.55
THERMODYNAMIC PROPERTIES
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
Butyl crotonate
sec-Butyl crotonate
Butylcyclohexane
Butylcyclopentane
N-Butyldiacetimide
Butyl dichloroacetate
Butylethylamine
Butyl ethyl ether
Butyl ethyl sulfide
tert-Butyl ethyl sulfide
Butyl formate
tert-Butyl hydroperoxide
Butylisopropylamine
Butyllithium
Butyl methyl ether
sec-Butyl methyl ether
tert-Butyl methyl ether
Butyl methyl sulfide
tert-Butyl methyl sulfide
Butyl methyl sulfone
tert-Butyl methyl sulfone
Butyl octadecanoate
tert-Butyl peroxide
Butyl propyl ether
Butyl thiolacetate
Butyl trichloroacetate
Butyl vinyl ether
1-Butyne
2-Butyne
2-Butynedinitrile
4-Butyrolactone
Butyrophenone
(⫹)-Camphor
9H-Carbazole
Chloroacetic acid
Chloroacetyl chloride
2-Chloroaniline
2-Chlorobenzaldehyde
Chlorobenzene
2-Chlorobenzoic acid
3-Chlorobenzoic acid
4-Chlorobenzoic acid
Chloro-1,4-benzoquinone
1-Chlorobutane
2-Chlorobutane
Chlorocyclohexane
1-Chloro-1,1-difluoroethane
Chlorodifluoromethane
2-Chloro-1,4-dihydroxybenzene
Chlorodimethylsilane
⌬Hm
14.16
11.3
12.4
7.1
⌬Hv
38.5
36.2
34.0
31.6
37.0
33.5
36.6
34.5
12.5
8.4
29.6
28.1
27.9
34.5
31.5
⌬Hs
51.9
49.4
49.4
45.9
64.4
52.3
40.2
36.3
44.5
39.3
41.1
47.7
42.1
107.1
32.4
30.2
29.8
40.5
35.8
76.2
82.4
400 K
600 K
800 K
1000 K
276.1
241.7
289.5
336.3
469.9
407.3
525.9
480.3
202.4
271.8
325.3
367.2
174.6
233.0
278.4
314.1
99.9
94.6
129.0
124.2
150.4
147.0
166.7
164.4
128.1
172.2
200.4
219.6
135.1
136.1
179.0
180.7
210.5
212.7
234.0
236.8
65.4
78.9
87.2
92.4
56.90
33.7
6.0
9.23
31.6
24.5
26.5
9.57
52.2
6.84
26.9
12.28
59.5
11.88
44.4
9.61
25.73
35.2
31.8
40.2
48.1
53.6
36.2
23.3
26.6
28.8
60.7
30.4
29.2
2.69
4.12
84.5
75.3
38.9
56.8
53.1
41.0
79.5
82.0
87.9
69.0
33.5
31.5
43.5
22.4
20.2
69.0
26.2
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.56
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
cap height
base of text
Cp
Substance
Chlorodiphenylsilane
1-Chloro-2,3-epoxypropane
Chloroethane
2-Chloroethanol
1-Chloro-2-ethylbenzene
1-Chloro-4-ethylbenzene
Chloroethylene
2-Chloroethyl vinyl ether
Chloroethyne
1-Chloroheptane
1-Chlorohexane
Chlorohydroquinone
Chloromethane
1-Chloro-2-methylbenzene
1-Chloro-3-methylbenzene
1-Chloro-4-methylbenzene
1-Chloro-3-methylbutane
1-Chloro-2-methylpropane
2-Chloro-2-methylpropane
⌬Ht ⫽ 1.7⫺90.1
⌬Ht ⫽ 5.8⫺53.6
1-Chloronaphthalene
2-Chloronaphthalene
1-Chloro-3-nitrobenzene
1-Chloro-4-nitrobenzene
1-Chlorooctane
Chloropentafluoroacetone
Chloropentafluorobenzene
Chloropentafluoroethane
1-Chloropentane
2-Chloropentane
2-Chlorophenol
3-Chlorophenol
4-Chlorophenol
1-Chloropropane
2-Chloropropane
3-Chloro-1-propene
Chlorotrifluoroethylene
Chlorotrifluoromethane
Chlorotrimethylsilane
Chlorotrinitromethane
Chrysene
Coronene
1,2-Cresol
1,3-Cresol
1,4-Cresol
Cubane
Cyanamide
Cyanogen
Cyclobutane, ⌬Ht ⫽ 5.8⫺126.8
⌬Hm
⌬Hv
4.45
33.1
24.7
41.4
⌬Hs
400 K
600 K
800 K
1000 K
77.6
101.6
118.8
131.7
65.0
82.1
93.5
101.9
69.5
40.6
47.3
48.1
4.75
20.8
38.2
35.7
6.43
8.37
10.46
21.4
37.5
2.09
38.7
32.0
29.2
27.6
12.90
52.1
60.2
66.8
71.0
74.3
47.7
42.8
69.0
18.9
48.2
61.3
71.3
78.9
36.2
31.7
29.0
136.1
142.3
180.7
184.9
212.7
215.5
236.8
238.5
164.2
218.0
256.8
285.6
106.1
108.7
92.6
139.9
143.1
111.0
164.2
167.1
137.8
182.4
184.8
151.9
77.5
90.3
96.9
100.5
76.0
61.7
73.9
80.3
166.3
162.1
161.7
220.8
218.7
218.0
257.5
256.4
255.7
287.9
286.6
286.5
19.7
23.5
61.9(g)
100.0
68.2
145.4
72.9
177.5
76.4
200.7
65.3
82.0
19.37
20.77
1.88
12.52
14.91
14.07
5.54
7.39
5.6
34.8
19.4
33.2
31.8
27.2
26.3
29.0
20.8
15.8
27.6
26.15
19.2
13.94
9.41
11.89
45.2
47.4
47.5
8.76
8.1
1.1
68.6
23.3
24.2
52.4
25.3
41.1
38.2
36.0
53.1
51.9
28.4
26.9
28.2
30.1
45.4
124.5
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.57
THERMODYNAMIC PROPERTIES
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
Cyclobutanecarbonitrile
Cyclobutanenitrile
Cyclobutene
Cyclobutylamine
Cyclododecane
Cycloheptane
⌬Ht ⫽ 5.0⫺138.4
⌬Ht ⫽ 0.3⫺75.0
⌬Ht ⫽ 0.5⫺60.8
Cycloheptanone
1,3,5-Cycloheptatriene
⌬Ht ⫽ 2.4⫺119.2
Cyclohexane
⌬Ht ⫽ 6.7⫺87
Cyclohexanecarbonitrile
Cyclohexanethiol
Cyclohexanol
⌬Ht ⫽ 8.2⫺9.7
Cyclohexanone
Cyclohexene
⌬Ht ⫽ 4.3⫺134.4
1-Cyclohexenecarbonitrile
Cyclohexylamine
Cyclohexylbenzene
Cyclohexylcyclohexane
cis, cis-1,5-Cyclooctadiene
Cyclooctane
⌬Ht ⫽ 6.3⫺106.7
⌬Ht ⫽ 0.5⫺89.4
Cyclooctanone
1,3,5,7-Cyclooctatetraene
Cyclooctene
Cyclopentadiene
Cyclopentane
⌬Ht ⫽ 4.8⫺150.8
⌬Ht ⫽ 0.3⫺135.1
Cyclopentanecarbonitrile
1-Cyclopentenecarbonitrile
Cyclopentanethiol
Cyclopentanol
Cyclopentanone
Cyclopentene
⌬Ht ⫽ 0.5⫺186.1
Cyclopentylamine
Cyclopropane
Cyclopropanecarbonitrile
Cyclopropylamine
Cyclopropylbenzene
Cyclopropyl methyl ketone
Decafluorobutane
⌬Hm
⌬Hv
⌬Hs
36.9
44.3
40.0
35.6
76.4
38.5
400 K
600 K
800 K
1000 K
90.3
126.8
151.7
169.6
175.0
261.2
322.3
365.7
155.4
209.5
245.1
270.2
1.88
33.2
1.2
38.7
2.63
30.0
33.0
149.9
225.2
279.3
317.2
1.76
37.1
45.5
51.9
44.6
62.0
172.1
248.1
302.0
339.5
3.29
40.3
30.5
45.1
33.5
150.6
144.9
221.3
206.9
272.0
248.9
305.4
278.7
53.5
43.7
59.9
58.0
43.4
43.3
200.1
297.1
365.3
414.3
160.9
220.8
260.4
288.2
118.7
178.1
220.1
250.4
144.5
203.6
245.2
275.5
104.9
155.6
191.5
217.3
76.6
109.4
140.5
148.1
51.9
36.1
15.30
51.9
2.41
11.3
0.61
7.8
35.9
36.4
27.3
35.3
36.4
3.36
8.31
5.44
20.1
35.6
13.18
34.1
22.9
54.4
43.1
47.0
28.4
28.5
43.4
45.0
41.4
57.6
42.7
28.1
40.2
16.9
41.9
31.3
50.2
38.4
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.58
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
cap height
base of text
Cp
Substance
⌬Hm
⌬Hv
⌬Hs
cis-Decahydronaphthalene
⌬Ht ⫽ 2.1⫺57.1
trans-Decahydronaphthalene
Decanal
Decane
Decanedioic acid
Decanenitrile
1-Decanethiol
Decanoic acid
1-Decanol
1-Decene
⌬Ht ⫽ 8.0⫺74.8
1-Decyne
Deoxybenzoin
Dibenz[de,kl]anthracene
Dibenzoyl peroxide
Dibenzyl ether
Dibenzyl sulfide
Dibenzyl sulfone
1,2-Dibromobutane
1,4-Dibromobutane
2,3-Dibromobutane
1,2-Dibromo-1-chloro-1,1,2-trifluoroethane
1,2-Dibromocycloheptane
1,2-Dibromocyclohexane
1,2-Dibromocyclooctane
1,2-Dibromoethane
1,2-Dibromoheptane
Dibromomethane
1,2-Dibromopropane
1,3-Dibromopropane
1,2-Dibromotetrafluoroethane
1,2-Dibutoxyethane
Dibutoxymethane
Dibutylamine
N,N-Dibutyl-1-butanamine
Dibutyl decanedioate
Dibutyl disulfide
Di-tert-butyl disulfide
Dibutyl ether
Di-sec-butyl ether
Di-tert-butyl ether
Dibutylmercury
Di-tert-butyl peroxide
Dibutyl 1,2-phthalate
Dibutyl sulfate
Dibutyl sulfide
Di-tert-butyl sulfide
Dibutyl sulfite
Dibutyl sulfone
9.49
41.0
50.2
14.41
40.2
43.5
28.78
40.8
38.8
31.0
28.02
37.7
21.10
46.4
51.4
160.7
66.8
65.5
118.8
81.5
50.4
49.8
38.7
400 K
600 K
800 K
1000 K
237.0
352.0
432.5
489.5
237.6
300.4
298.1
352.3
400.4
403.2
432.6
472.8
480.8
489.2
525.9
536.4
320.6
429.4
510.9
573.1
187.2
283.6
418.2
381.9
495.9
453.0
553.3
505.9
274.6
363.8
428.5
476.6
153.9
195.4
224.3
244.8
99.7
122.3
137.8
149.8
63.0
124.4
74.8
157.4
82.5
179.5
88.0
195.6
286.1
376.5
442.8
493.1
254.3
340.1
403.8
451.3
259.8
348.6
420.8
475.8
93.3
125.5
102.5
31.4
20.2
31.2
10.84
8.94
13.6
7.04
34.8
32.9
35.6
27.0
47.8
38.4
46.9
92.9
46.9
36.5
34.1
32.2
79.2
19.4
41.3
33.3
93.3
125.5
50.3
53.1
37.7
35.0
52.0
50.5
54.6
41.7
54.4
37.0
41.7
47.5
28.4
58.8
48.1
49.5
64.5
54.3
45.0
40.8
37.6
63.5
31.8
91.6
75.9
53.0
43.8
67.8
100.4
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.59
THERMODYNAMIC PROPERTIES
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
Dichloroacetyl chloride
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
2,6-Dichlorobenzoquinone
2,2⬘-Dichlorobiphenyl
4,4⬘-Dichlorobiphenyl
1,2-Dichlorobutane
1,4-Dichlorobutane
Dichlorodifluoromethane
Dichlorodimethylsilane
Dichlorodiphenylsilane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethylene
cis-1,2-Dichloroethylene
trans-1,2-Dichloroethylene
2,2-Dichloroethyl ether
Dichlorofluoromethane
1,2-Dichlorohexafluoropropane
1,2-Dichlorohexane
Dichloromethane
1,2-Dichloro-4-methylbenzene
1,2-Dichloropentane
1,5-Dichloropentane
(⫾)-1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,3-Dichloro-2-propanol
1,2-Dichlorotetrafluoroethane
Dicyanoacetylene
Dicyclopentadienyliron
Dicyclopropyl ketone
Diethanolamine
1,1-Diethoxyethane
1,2-Diethoxyethane
Diethoxymethane
1,3-Diethoxypropane
2,2-Diethoxypropane
Diethylamine
1,2-Diethylbenzene
1,3-Diethylbenzene
1,4-Diethylbenzene
Diethyl carbonate
Diethyl disulfide
Diethylene glycol diethyl ether
Diethylene glycol dimethyl ether
Diethylene glycol monoethyl ether
Diethylene glycol monomethyl ether
Diethyl ether
⌬Hm
⌬Hv
12.93
12.64
17.15
39.7
38.6
38.8
33.9
4.14
8.84
8.83
6.51
7.20
11.98
6.00
10.68
⌬Hs
39.3
50.2
48.6
49.0
69.9
96.2
103.8
39.6
46.4
20.1
28.9
32.0
26.1
30.2
28.9
38.4
25.2
26.3
28.1
36.5
6.40
31.8
35.2
29.3
6.32
23.3
34.3
69.5
30.6
35.2
26.5
31.0
29.3
26.9
48.2
28.8
43.9
50.7
36.0
40.8
32.6
66.9
400 K
600 K
800 K
1000 K
142.8
143.0
143.3
184.4
184.5
184.8
210.4
210.4
210.7
227.7
227.7
227.9
82.4
93.6
99.1
100.0
91.4
92.1
78.7
77.0
77.7
113.7
112.6
93.9
93.0
93.2
128.8
127.2
103.4
102.9
102.9
139.8
138.1
110.0
109.8
109.8
70.2
82.4
89.6
94.2
59.6
72.4
80.8
86.8
119.7
120.0
127.9
152.6
151.5
159.2
175.6
173.9
179.9
192.8
190.4
194.8
143.9
234.4
230.2
228.8
197.2
316.6
314.6
313.1
235.0
374.6
379.7
372.5
263.2
416.3
415.8
414.9
171.1
218.6
251.8
276.0
138.1
183.8
218.7
244.8
28.8
73.6
53.7
25.10
16.8
11.0
10.6
9.4
13.60
7.27
65.2
36.3
36.3
31.3
37.2
29.1
39.4
39.4
39.4
36.2
37.6
49.0
36.2
47.5
46.6
26.5
43.2
43.2
35.7
45.9
31.8
31.3
52.8
52.5
52.5
43.6
45.2
58.4
44.7
27.1
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.60
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
cap height
base of text
Cp
Substance
Diethyl malonate
Diethyl oxalate
Diethyl peroxide
3,3-Diethylpentane
Diethyl 1,2-phthalate
Diethyl sulfide
Diethyl sulfite
Diethyl sulfone
Diethyl sulfoxide
Diethylzinc
1,2-Difluorobenzene
1,3-Difluorobenzene
1,4-Difluorobenzene
2,2⬘-Difluorobiphenyl
4,4⬘-Difluorobiphenyl
1,1-Difluoroethane
1,1-Difluoroethylene
Difluoromethane
9,10-Dihydroanthracene
Dihydro-2H-pyran
5,12-Dihydrotetracene
2,3-Dihydrothiophene
2,5-Dihydrothiophene
2,4-Dihydrothiophene-1,1-dioxide
1,4-Dihydroxybenzene
1,2-Diiodobenzene
1,2-Diiodoethane
Diiodomethane
Diisobutylamine
Diisobutyl ether
Diisobutyl sulfide
Diisopropylamine
Diisopropyl ether
Diisopropylmercury
Diisopropyl sulfide
Diketene
1,2-Dimethoxybenzene
1,1-Dimethoxyethane
1,2-Dimethoxyethane
Dimethoxymethane
2,2-Dimethoxypropane
N,N-Dimethylacetamide
Dimethylamine
Dimethylaminomethanol
N,N-Dimethylaminotrimethylsilane
N,N-Dimethylaniline
1,4-Dimethylbicyclo[2.2.1]heptane
2,3-Dimethylbicyclo[2.2.1]-2-heptene
2,2-Dimethylbutane
⌬Hm
⌬Hv
54.8
42.0
10.09
34.6
11.90
31.8
11.1
8.58
32.2
31.1
31.8
21.6
33.2
34.8
27.11
44.80
42.5
34.0
11.03
10.4
16.04
30.4
29.1
33.8
36.8
48.2
12.60
8.33
32.4
10.42
5.94
43.4
26.4
0.58
33.3
34.9
26.3
⌬Hs
63.5
30.5
42.0
88.3
35.8
48.5
86.2
62.3
40.2
36.2
34.6
35.5
95.0
91.2
19.1
93.3
32.2
115.9
37.7
40.0
62.8
99.2
64.9
65.7
51.0
39.3
40.9
48.7
34.6
32.1
53.6
39.6
42.9
66.9
30.5
36.4
35.1
29.4
50.2
25.0
50.2
31.8
52.8
38.9
42.2
27.7
400 K
600 K
800 K
1000 K
145.0
192.9
229.7
258.5
137.1
137.0
137.4
181.3
180.5
180.1
209.7
207.8
207.8
229.0
225.6
225.7
83.4
71.8
51.1
107.5
89.2
65.8
124.3
100.2
76.2
136.3
107.7
83.7
96.0
65.9
116.8
76.9
131.3
83.9
141.6
89.1
196.2
262.0
311.3
348.0
211.9
277.1
322.7
356.6
87.4
118.9
142.0
159.8
182.8
251.0
298.7
333.5
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.61
THERMODYNAMIC PROPERTIES
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
⌬Ht ⫽ 5.4
⌬Ht ⫽ 0.3⫺132.3
2,3-Dimethylbutane
⌬Ht ⫽ 6.5⫺137.1
2,2-Dimethyl-1-butanol
2,3-Dimethyl-1-butanol
3,3-Dimethyl-1-butanol
2,3-Dimethyl-2-butanol
(⫾)-3,3-Dimethyl-2-butanol
3,3-Dimethyl-2-butanone
2,3-Dimethyl-1-butene
3.3-Dimethyl-1-butene
⌬Ht ⫽ 4.3⫺148.3
2,3-Dimethyl-2-butene
⌬Ht ⫽ 3.5⫺76.3
Di(3-methylbutyl) ether
Dimethylcadmium
1,1-Dimethylcyclohexane
⌬Ht ⫽ 6.0⫺120.0
cis-1,2-Dimethylcyclohexane
⌬Ht ⫽ 8.3⫺100.6
trans-1,2-Dimethylcyclohexane
cis-1,3-Dimethylcyclohexane
trans-1,3-Dimethylcyclohexane
cis-1,4-Dimethylcyclohexane
trans-1,4-Dimethylcyclohexane
1,1-Dimethylcyclopentane
⌬Ht ⫽ 6.5⫺126.4
cis-1,2-Dimethylcyclopentane
⌬Ht ⫽ 6.7⫺131.7
trans-1,2-Dimethylcyclopentane
cis-1,3-Dimethylcyclopentane
trans-1,3-Dimethylcyclopentane
cis-2,4-Dimethyl-1,3-dioxane
4,5-Dimethyl-1,3-dioxane
5,5-Dimethyl-1,3-dioxane
Dimethyl disulfide
Dimethyl ether
N,N-Dimethylformamide
Dimethylglyoxime
2,2-Dimethylheptane
2,6-Dimethyl-4-heptanone
2,2-Dimethylhexane
2,3-Dimethylhexane
2,4-Dimethylhexane
2,5-Dimethylhexane
3,3-Dimethylhexane
3,4-Dimethylhexane
cis-2,2-Dimethyl-3-hexene
⌬Hm
⌬Hv
⌬Hs
0.80
27.4
29.1
56.1
1.1
42.6
47.3
46.4
40.4
43.9
33.4
27.4
25.7
5.46
29.6
400 K
600 K
800 K
1000 K
181.2
247.7
314.6
331.0
37.9
29.2
27.1
178.2
162.8
231.8
223.4
272.0
266.1
302.1
297.1
32.5
156.8
216.7
262.7
297.7
⫺147.3
51.0
35.2
2.06
32.5
38.0
37.9
212.1
310.0
379.5
427.6
1.64
33.5
39.7
213.8
309.6
377.0
424.3
10.49
10.82
9.86
9.31
12.33
1.1
33.0
32.9
33.4
33.3
32.6
30.3
38.4
38.3
39.2
39.0
37.9
33.8
217.2
214.2
213.8
213.8
215.9
182.2
312.1
310.5
308.8
308.8
312.1
262.6
378.7
378.7
375.7
375.7
378.9
318.7
425.5
426.8
423.0
423.0
425.7
359.1
1.7
31.7
35.7
182.7
262.4
317.9
358.0
7.2
7.4
7.3
30.9
30.4
30.8
182.9
182.9
182.9
262.2
262.2
262.2
317.3
317.3
317.3
357.4
357.4
357.4
9.19
4.94
16.15
33.8
21.5
38.4
34.6
34.2
34.5
39.9
42.5
41.3
37.9
18.5
46.9
97.1
110.3
79.6
137.4
105.3
157.6
125.7
172.8
141.4
8.90
6.78
12.95
6.98
39.9
32.1
33.2
32.5
32.5
32.3
33.2
50.9
37.3
38.8
37.8
37.9
37.5
39.0
37.2
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.62
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
cap height
base of text
Cp
Substance
trans-2,2-Dimethyl-3-hexene
1,1-Dimethylhydrazine
1,2-Dimethylhydrazine
3,5-Dimethylisoxazole
Dimethyl maleate
Dimethylmercury
6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptane
2,4-Dimethyloctane
Dimethyl oxalate
3,3-Dimethyloxetane
2,2-Dimethylpentane
2,3-Dimethylpentane
2,4-Dimethylpentane
3,3-Dimethylpentane
2,2-Dimethyl-3-pentanone
2,4-Dimethyl-3-pentanone
2,4-Dimethyl-1-pentene
4,4-Dimethyl-1-pentene
2,4-Dimethyl-2-pentene
cis-4,4-Dimethyl-2-pentene
trans-4,4-Dimethyl-2-pentene
2,7-Dimethylphenanthrene
4,5-Dimethylphenanthrene
9,10-Dimethylphenanthrene
2,3-Dimethylphenol
2,4-Dimethylphenol
2,5-Dimethylphenol
2,6-Dimethylphenol
3,4-Dimethylphenol
3,5-Dimethylphenol
Dimethyl 1,2-phthalate
2,2-Dimethylpropane
⌬Ht ⫽ 2.6⫺133.1
2,2-Dimethylpropanenitrile
2,2-Dimethyl-1-propanol
2,3-Dimethylpyridine
2,4-Dimethylpyridine
2,5-Dimethylpyridine
2,6-Dimethylpyridine
3,4-Dimethylpyridine
3,5-Dimethylpyridine
Dimethyl sulfate
Dimethyl sulfide
Dimethyl sulfite
Dimethyl sulfone
Dimethyl sulfoxide
2,2-Dimethylthiacyclopropane
Dimethylzinc
Dinitromethane
⌬Hm
⌬Hv
10.1
32.6
35.2
14.7
40.2
36.5
6.69
7.07
11.18
47.1
46.9
44.5
49.7
49.3
22.7
21.8
32.4
9.6
39.1
38.5
37.3
30.9
29.2
30.5
29.6
29.6
36.1
34.6
21.02
23.38
18.90
18.13
18.00
162.7
3.10
10.04
37.5
40.0
39.5
7.99
27.0
14.37
43.1
400 K
600 K
800 K
1000 K
211.0
211.0
211.0
211.0
285.9
285.9
285.9
285.9
340.7
340.7
340.7
340.7
381.6
381.6
381.6
381.6
157.1
218.5
254.3
283.7
88.4
113.0
132.2
147.2
37.3
35.0
39.3
45.2
44.3
34.6
46.4
47.1
47.4
33.9
32.4
34.3
32.9
33.0
42.3
41.5
33.2
29.0
34.4
32.7
32.7
106.7
104.6
119.5
84.0
65.0
85.0
75.3
85.0
82.0
21.07
5.86
⌬Hs
47.7
47.5
47.8
45.4
50.5
49.5
48.5
27.7
40.2
77.0
52.9
35.8
29.5
46.0
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.63
THERMODYNAMIC PROPERTIES
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
2,4-Dinitrophenol
2,6-Dinitrophenol
1,1-Dinitropropane
1,3-Dioxane
1,4-Dioxane
⌬Ht ⫽ 2.4⫺0.3
1,3-Dioxolane
Diphenylamine
Diphenyl carbonate
Diphenyl disulfide
Diphenyl disulfone
Diphenylenimine
1,2-Diphenylethane
1,1-Diphenylethylene
Diphenyl ether
6,6-Diphenylfulvene
Diphenylmercury
Diphenylmethane
1,3-Diphenyl-2-propanone
Diphenyl sulfide
Diphenyl sulfone
Diphenyl sulfoxide
1,2-Dipropoxyethane
Dipropylamine
Dipropyl disulfide
Dipropyl ether
Dipropylmercury
Dipropyl sulfate
Dipropyl sulfide
Dipropyl sulfite
Dipropyl sulfone
Dipropyl sulfoxide
Divinyl ether
Divinyl sulfone
Dodecane
Dodecanedioic acid
Dodecanenitrile
Dodecanoic acid
Dodecanol
1-Dodecene
⌬Ht ⫽ 4.6⫺60.2
1,2-Epoxybutane
1,2-Epoxypropane
Ergosterol
Ethane
Ethane-d6
1,2-Ethanediamine
1,2-Ethanediol
1,2-Ethanediol diacetate
1,2-Ethanedithiol
⌬Hm
12.85
⌬Hv
⌬Hs
34.4
34.2
104.6
112.1
62.5
39.1
38.6
27.48
17.86
23.4
51.5
17.22
48.2
18.2
13.8
8.83
33.5
41.9
31.3
12.1
36.6
36.55
44.5
36.64
31.4
17.42
63.5
44.0
35.6
89.1
90.0
95.0
161.9
84.5
91.4
73.2
67.0
104.6
112.8
67.5
89.1
67.8
106.3
97.1
50.6
40.0
54.1
35.7
55.2
66.9
44.2
58.6
79.9
74.5
26.2
56.5
61.5
153.1
76.1
132.6
92.0
60.8
400 K
600 K
800 K
1000 K
126.5
181.8
218.2
243.3
186.2
196.2
298.3
262.0
350.2
311.3
390.0
348.0
201.7
272.5
328.2
372.6
356.2
481.3
572.2
656.5
341.8
460.0
545.6
608.8
65.5
81.7
89.3
108.5
108.0
127.4
122.6
140.5
113.2
136.9
166.9
30.3
21.6
2.86
14.7
118.4
5.2
22.58
11.23
38.0
50.5
45.5
37.9
45.0
67.8
61.4
44.7
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.64
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
cap height
base of text
Cp
Substance
Ethanethiol
Ethanol
Ethanolamine
Ethoxybenzene
2-Ethoxyethanol
2-(2-Ethoxyethoxy)ethanol
2-(2-Ethoxyethoxy)ethyl acetate
2-Ethoxyethyl acetate
1-Ethoxy-2-methoxyethane
N-Ethylacetamide
Ethyl acetate
Ethyl acrylate
Ethylamine
N-Ethylaniline
Ethylbenzene
2-Ethylbenzoic acid
3-Ethylbenzoic acid
4-Ethylbenzoic acid
2-Ethyl-1-butanol
Ethyl butanoate
2-Ethylbutanoic acid
2-Ethyl-1-butene
Ethyl trans-2-butenoate
Ethyl chloroacetate
Ethyl 4-chlorobutanoate
Ethyl chloroformate
Ethyl trans-cinnamate
Ethyl crotonate
Ethyl cyanoacetate
Ethylcyclobutane
Ethylcyclohexane
1-Ethylcyclohexene
Ethylcyclopentane
1-Ethylcyclopentene
Ethyl dichloroacetate
Ethyl 2,2-dimethylpropanoate
Ethylene
Ethylene-d4
Ethylene carbonate
2,2⬘-(Ethylenedioxy)bis(ethanol)
Ethylene glycol (see 1,2-Ethanediol)
Ethylene glycol diacetate
Ethylene oxide
Ethylenimine
N-Ethylformamide
Ethyl formate
2-Ethylhexanal
2-Ethylhexane
Ethyl hexanoate
2-Ethylhexanoic acid
⌬Hm
⌬Hv
⌬Hs
400 K
600 K
800 K
1000 K
4.98
5.02
20.50
26.8
38.6
49.8
40.7
39.2
47.5
91.2
27.3
42.3
88.2
81.2
113.9
107.7
133.2
127.2
148.0
141.9
137.4
182.6
213.4
234.5
90.6
119.6
141.8
158.5
170.5
236.1
281.0
312.8
170.3
228.0
269.5
300.8
215.9
310.0
377.0
423.8
183.6
258.2
314.7
356.3
53.1
63.9
70.7
82.3
83.8
95.6
93.9
104.9
62.6
70.4
86.3
98.6
102.9
117.7
114.9
131.6
34.3
10.48
9.18
31.9
34.7
28.0
35.6
43.2
35.5
51.2
28.8
40.4
51.0
48.2
52.7
39.8
64.9
35.6
26.6
52.3
42.2
100.7
99.1
97.5
63.2
42.7
31.1
44.4
49.5
52.7
42.3
58.6
44.3
8.33
6.9
3.35
64.4
28.7
34.0
32.0
38.5
34.5
13.5
13.19
50.1
71.4
5.2
25.5
30.3
9.20
29.9
33.6
56.0
31.2
40.6
43.3
36.4
50.6
41.2
73.2
79.1
61.4
24.8
34.6
58.4
32.0
49.0
39.6
51.7
75.6
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.65
THERMODYNAMIC PROPERTIES
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
2-Ethyl-1-hexanol
2-Ethylhexyl acetate
2-Ethyl hydroperoxide
Ethylidenecyclohexane
Ethylidenecyclopentane
Ethyl isocyanide
Ethyl isopentanoate
Ethyl isopentyl ether
Ethylisopropylamine
Ethyl isopropyl ether
Ethyl isopropyl sulfide
Ethyl lactate
Ethyllithium
Ethylmercury bromide
Ethylmercury chloride
Ethylmercury iodide
1-Ethyl-2-methylbenzene
1-Ethyl-3-methylbenzene
1-Ethyl-4-methylbenzene
Ethyl 2-methylbutanoate
Ethyl 3-methylbutanoate
2-Ethyl-3-methyl-1-butene
1-Ethyl-1-methylcyclopentane
Ethyl methyl ether
3-Ethyl-2-methylpentane
3-Ethyl-3-methylpentane
3-Ethyl-2-methyl-1-pentene
Ethyl 2-methylpropanoate
Ethyl methyl sulfide
Ethyl nitrate
1-Ethyl-2-nitrobenzene
1-Ethyl-4-nitrobenzene
3-Ethylpentane
Ethyl pentanoate
Ethyl pentyl ether
2-Ethylphenol
3-Ethylphenol
4-Ethylphenol
Ethylphosphonic acid
Ethylphosphonic dichloride
Ethyl propanoate
Ethyl propyl ether
Ethyl propyl sulfide
Ethyl trichloroacetate
S-Ethyl thiolacetate
Ethyl 2-vinylacrylate
Ethyl vinyl ether
Fluoranthrene
9H-Fluorene
Fluorobenzene
⌬Hm
⌬Hv
45.2
43.5
⌬Hs
400 K
600 K
800 K
1000 K
202.9
198.7
197.5
275.3
273.6
272.0
326.8
325.5
324.7
363.6
363.2
362.2
109.1
144.7
172.3
193.2
116.4
120.2
152.3
155.1
179.6
178.7
200.6
195.4
211.0
285.9
340.7
381.6
173.3
232.7
279.0
315.6
125.5
171.0
200.1
220.0
48.1
43.1
42.0
18.1
33.5
8.7
8.7
10.0
7.6
13.4
43.9
33.0
29.9
28.2
32.7
46.4
38.9
38.5
38.4
37.0
11.34
10.84
33.2
26.7
32.9
32.8
9.8
8.5
33.7
29.5
33.1
9.55
31.1
37.0
34.4
10.6
33.9
28.9
34.2
34.4
40.0
18.87
19.58
11.31
39.0
33.1
30.1
37.8
49.4
116.7
76.6
76.1
79.5
47.7
46.9
46.6
44.4
43.9
34.5
38.9
38.5
38.0
37.5
39.8
31.9
36.3
59.8
62.8
35.2
47.0
41.0
63.6
68.2
80.3
50.6
42.7
39.2
31.4
40.0
51.0
26.2
48.5
26.6
99.2
31.2
34.6
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.66
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
cap height
base of text
Cp
Substance
4-Fluorobenzoic acid
Fluoroethane
Fluoromethane
1-Fluorooctane
1-Fluoropropane
2-Fluoropropane
2-Fluorotoluene
4-Fluorotoluene
Fluorotrichloromethane
Fluorotrinitromethane
Formaldehyde
Formamide
Formic acid
Formyl fluoride
Fumaric acid
Fumaronitrile
Furan, ⌬Ht ⫽ 2.1⫺123.2
2-Furancarboxaldehyde
2-Furancarboxylic acid
Furanmethanol
Glutaric acid
Glycerol
Glyceryl triacetate
Glyceryl tributanoate
Glyceryl trinitrate
Heptadecane, ⌬Ht ⫽ 11.011.1
Heptadecanoic acid
1-Heptadecene
1-Heptanal
Heptane
1-Heptanenitrile
1-Heptanethiol
Heptanoic acid
1-Heptanol
2-Heptanol
3-Heptanol
2-Heptanone
4-Heptanone
1-Heptene, ⌬Ht ⫽ 0.3⫺136
trans-2-Heptene
Heptylamine
Heptyl methyl ether
Hexachlorobenzene
Hexachloroethane, ⌬Ht ⫽ 8.071.3
Hexadecafluoroethylcyclohexane
Hexadecafluoroheptane
Hexadecane
Hexadecanoic acid
1-Hexadecanol, ⌬Ht ⫽ 16.634
1-Hexadecene
⌬Hm
⌬Hv
⌬Hs
400 K
600 K
800 K
1000 K
74.1
44.2
98.6
57.9
116.4
68.8
129.7
77.2
102.7
103.5
137.3
138.7
162.7
163.8
181.5
182.2
152.4
207.9
245.2
271.3
39.2(g)
48.2
55.9
62.0
53.8
46.4
67.0
56.2
76.8
63.1
83.5
67.9
88.7
122.6
164.9
158.5
501.4
676.8
803.7
897.9
486.9
213.4
211.0
655.5
283.3
285.9
777.1
333.9
340.7
866.9
371.1
381.6
233.5
312.1
372.0
418.4
224.4
300.9
357.0
392.5
196.5
264.6
314.1
351.0
201.2
151.5
233.4
166.6
250.9
173.6
260.8
177.3
472.3
687.7
757.4
846.0
485.7
457.9
652.7
616.4
773.6
731.82
863.2
815.0
91.2
16.7
40.4
9.4
35.4
34.1
25.0
49.7
39.4
34.7
23.3
6.69
12.7
22.7
21.7
3.80
14.35
27.1
43.2
13.13
20.9
18.28
53.6
21.87
40.5
58.8
31.4
23.6
14.16
61.0
52.9
51.8
31.8
25.4
39.8
13.2
48.1
49.8
42.5
38.3
36.2
31.1
12.66
11.72
23.85
9.8
51.8
42.04
34.29
30.2
45.9
51.2
50.4
60.2
20.1
136.0
72.0
27.5
50.6
108.5
64.4
85.8
85.7
107.1
100.0
86.0
85.0
47.7
36.6
51.9
50.6
74.0
66.8
47.2
35.5
50.0
46.9
92.6
59.0
38.5
36.4
81.4
154.4
169.5
80.3
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.67
THERMODYNAMIC PROPERTIES
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
Hexadienoic acid
Hexafluoroacetone
Hexafluoroacetylacetone
Hexafluorobenzene
Hexafluoroethane, ⌬Ht ⫽ 3.7⫺169.2
cis-Hexahydroindane
trans-Hexahydroindane
Hexamethylbenzene
⌬Ht ⫽ 1.1⫺156.7
⌬Ht ⫽ 1.8110.7
1,1,1,3,3,3-Hexamethyldisilazane
Hexamethyldisiloxane
Hexamethylphosphoric triamide
Hexanal
Hexanamide
Hexane
1,6-Hexanedioic acid
1,6-Hexanediol
Hexanenitrile
1-Hexanethiol
Hexanoic acid
1-Hexanol
2-Hexanol
3-Hexanol
2-Hexanone
3-Hexanone
1-Hexene
cis-2-Hexene
trans-2-Hexene
cis-3-Hexene
trans-3-Hexene
Hexylamine
Hexyl methyl ether
1-Hexyne
Hydrazine
2-Hydroxybenzaldehyde
2-Hydroxybenzoic acid
2-Hydroxy-2,4,6-cycloheptatrienone
2-Hydroxy-1-isopropyl-4-methylbenzene
4-Hydroxy-4-methyl-2-pentanone
3-Hydroxypropanonitrile
2-Hydroxypyridine
3-Hydroxypyridine
4-Hydroxypyridine
8-Hydroxyquinoline
Icosane
Icosanoic acid
1-Icosene
Indane
Indene
⌬Hm
⌬Hv
⌬Hs
19.8
27.1
31.7
16.2
21.3
30.6
35.7
400 K
600 K
800 K
1000 K
183.6
125.6
219.9
149.0
241.1
160.7
253.7
166.8
310.4
406.4
474.9
525.3
184.2
243.9
287.4
319.7
181.9
246.8
294.4
330.1
204.5
273.1
325.1
366.7
195.3
261.8
310.7
346.9
167.5
161.5
166.1
161.1
168.2
225.5
221.8
223.4
222.6
225.5
267.9
165.3
266.1
265.7
267.4
299.3
297.9
297.9
297.9
298.7
158.5
207.5
243.3
270.1
588.5
794.0
942.6
1052.7
574.0
772.7
916.0
1021.7
13.6
11.58
2.7
20.6
48.2
57.5
56.1
74.7
41.4
37.2
14.28
25.1
13.08
34.85
25.5
18.0(1)
15.40
15.40
44.3
14.90
13.49
9.35
8.86
8.26
8.25
11.08
12.7
28.9
38.0
37.2
71.1
44.5
41.0
46.0
36.4
35.4
28.3
29.1
28.9
28.7
28.9
36.5
34.9
43.1
42.5
30.6
32.2
31.6
31.4
31.7
45.1
42.1
45.3
38.2
28.5
56.1
69.88
72.0
34.3
98.7
31.6
129.3
83.3
47.9
45.8
72.2
61.6
58.5
57.5
55.9
39.6
95.1
83.7
91.2
47.7
86.6
88.3
103.8
108.8
100.8
199.6
99.8
48.8
52.9
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.68
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
cap height
base of text
Cp
Substance
Indole
Iodobenzene
Iodobenzoic acid
1-Iodobutane
2-Iodobutane
Iodocyclohexane
Iodoethane
1-Iodohexane
Iodomethane
1-Iodo-2-methylpropane
2-Iodo-2-methylpropane
1-Iodonaphthalene
2-Iodonaphthalene
1-Iodopentane
1-Iodopropane
2-Iodopropane
3-Iodo-1-propene
2-Iodotoluene (also 3-, 4-)
Isobutanonitrile
Isobutyl acetate
Isobutylamine
Isobutylbenzene
Isobutylcyclohexane
Isobutyl dichloroacetate
Isobutyl formate
Isobutyl isobutanoate
Isobutyl isopropyl ether
Isobutyl methyl ether
Isobutyl propyl ether
Isobutyl trichloroacetate
Isobutyl vinyl ether
2-Isopropoxyethanol
Isopropyl acetate
Isopropylamine
Isopropylbenzene
Isopropylcyclohexane
Isopropylcyclopentane
Isopropylmethylamine
1-Isopropyl-2-methylbenzene
1-Isopropyl-3-methylbenzene
1-Isopropyl-4-methylbenzene
Isopropyl methyl ether
2-Isopropyl-5-methylphenol
Isopropyl methyl sulfide
Isopropyl nitrate
Isopropylpropylamine
Isopropyl propyl sulfide
Isopropyl trichloroacetate
Isoquinoline
Ketene
⌬Hm
⌬Hv
9.76
39.5
34.7
33.3
29.4
14.5
27.3
33.5
31.4
32.1
30.7
12.51
32.4
35.9
30.6
37.8
33.6
38.2
31.6
28.0
28.3
7.33
7.79
10.0
13.7
9.7
30.7
40.4
32.9
27.8
37.5
33.6
28.7
38.4
38.1
38.2
26.1
9.4
30.7
34.9
32.1
35.1
7.45
49.0
⌬Hs
69.9
47.7
87.9
40.6
38.5
47.3
31.9
49.8
28.0
38.8
35.4
72.4
90.8
45.3
36.2
34.1
38.1
54.4
37.2
400 K
600 K
800 K
1000 K
130.1
173.3
201.1
220.1
80.3
103.1
119.9
132.4
51.6
63.9
73.1
80.2
148.8
191.7
221.1
242.3
109.9
111.2
142.7
144.7
166.5
168.2
184.2
185.5
119.5
156.4
183.0
202.5
200.8
277.0
328.9
365.3
138.0
184.8
220.4
247.2
145.1
150.5
192.5
195.9
229.9
226.5
260.6
247.9
59.5
70.7
78.7
86.4
33.9
47.9
47.6
52.3
46.4
36.6
30.1
30.3
53.1
34.6
50.1
37.2
28.4
45.1
44.0
39.4
30.9
50.6
50.0
50.2
26.4
91.2
34.2
38.8
37.2
41.8
51.9
60.3
20.4
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.69
THERMODYNAMIC PROPERTIES
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
(⫺)-Leucine
(⫹)-Limonene
Maleic acid
Maleic anhydride
Malononitrile
D-Mannitol
Methacrylonitrile
Methane
Methane-d4
Methanethiol, ⌬Ht ⫽ 0.22⫺135.6
Methanol, ⌬Ht ⫽ 0.6⫺115.8
4-Methoxybenzaldehyde
Methoxybenzene
2-Methoxybenzoic acid
3-Methoxybenzoic acid
4-Methoxybenzoic acid
3-Methoxy-1-butanol
2-Methoxyethanol
2-(2-Methoxyethoxy)ethanol
2-Methoxyethyl acetate
2-Methoxy-1-propoxyethane
2-Methoxytetrahydropyran
1-Methoxy-2,4,6-trinitrobenzene
N-Methylacetamide
Methyl acetate
Methyl acetoacetate
Methyl acrylate
Methylamine
4-Methylaniline
Methyl benzoate
2-Methylbenzoic acid
3-Methylbenzoic acid
4-Methylbenzoic acid
1-Methylbicyclo[4.1.0]heptane
1-Methylbicyclo[3.1.0]hexane
2-Methyl-1,3-butadiene
3-Methyl-1,3-butadiene
2-Methylbutane
3-Methylbutanenitrile
2-Methylbutanethiol
3-Methyl-1-butanethiol
2-Methyl-2-butanethiol
⌬Ht ⫽ 8.0⫺114.0
Methyl butanoate
2-Methylbutanoic acid
3-Methylbutanoic acid
2-Methyl-1-butanol
3-Methyl-1-butanol
2-Methyl-2-butanol, ⌬Ht ⫽ 2.0⫺127.2
3-Methyl-2-butanol
⌬Hm
⌬Hv
⌬Hs
400 K
600 K
800 K
1000 K
40.5
48.6
58.7
51.4
52.2
63.4
73.5
67.0
62.9
74.8
85.0
79.7
71.8
83.0
94.1
89.5
60.2
78.9
93.9
105.7
133.1
129.7
152.7
173.2
168.6
208.7
200.8
197.5
249.8
221.3
219.2
280.8
179.0
236.7
279.4
308.8
150.6
48.1
110.0
71.5
79.1
22.6
0.94
5.91
3.18
31.8
8.2
24.6
35.2
56.8
39.0
50.8
37.5
46.6
43.9
36.3
9.72
6.13
18.22
9.74
20.17
15.72
22.73
4.79
5.15
7.5
0.6
4.45
45.2
50.3
43.7
42.7
133.1
59.4
30.3
36.0
33.1
25.6
29.2
24.4
43.2
55.6
31.1
25.9
27.2
24.7
35.1
33.8
31.4
33.8
7.32
23.8
37.4
64.5
46.9
104.7
107.4
109.8
43.2
45.2
44.1
39.0
41.8
32.3
39.2
34.8
26.8
28.0
24.9
41.7
39.5
39.4
35.7
39.3
46.9
57.5
55.2
55.6
50.1
53.0
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.70
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
cap height
base of text
Cp
Substance
3-Methyl-2-butanone
2-Methyl-1-butene
3-Methyl-1-butene
2-Methyl-2-butene
Methyl 2-butenoate
3-Methyl-1-butyne
2-Methylbutyl acetate
Methyl chloroacetate
Methyl cyanoacetate
Methyl cyclobutanecarboxylate
Methylcyclohexane
1-Methylcyclohexanol
cis-2-Methylcyclohexanol
trans-2-Methylcyclohexanol
cis-3-Methylcyclohexanol
trans-3-Methylcyclohexanol
cis-4-Methylcyclohexanol
trans-4-Methylcyclohexanol
1-Methylcyclohexene
Methylcyclopentane
1-Methyl-1-cyclopentene
3-Methyl-1-cyclopentene
4-Methyl-1-cyclopentene
Methyl cyclopropanecarboxylate
2-Methyldecane
4-Methyldecane
Methyl decanoate
Methyl dichloroacetate
Methyldichlorosilane
Methyl 2,2-dimethylpropanoate
2-Methyl-1,3-dioxane
4-Methyl-1,3-dioxane
4-Methyl-1,3-dioxolan-2-one
Methyl dodecanoate
N-Methylethanediamine
1-Methylethyl acetate
1-Methylethyl thiolacetate
N-Methylformamide
Methyl formate
Methyl 2-furancarboxylate
Methylglyoxal
2-Methylheptane
3-Methylheptane
4-Methylheptane
Methyl heptanoate
2-Methylhexane
3-Methylhexane
Methyl hexanoate
5-Methyl-1-hexene
cis-3-Methyl-3-hexene
⌬Hm
⌬Hv
⌬Hs
7.9
5.4
7.6
32.4
25.5
24.1
26.3
36.8
25.9
23.8
27.1
41.0
25.8
6.75
6.93
26.2
37.5
39.2
48.2
37.1
31.3
79.0
48.5
53.0
29.1
35.3
40.3
40.7
39.3
33.4
46.7
61.7
44.7
35.4
80
63.2
63.2
65.3
65.3
65.7
66.1
37.9
31.6
32.6
31.0
32.2
41.3
54.3
53.8
66.7
47.7
28.0
38.8
38.6
39.2
400 K
600 K
800 K
1000 K
138.9
147.5
133.6
187.1
192.1
181.7
222.4
225.3
217.8
248.7
250.3
245.0
130.1
169.9
198.3
219.2
185.6
269.7
329.5
371.5
151.1
136.0
136.4
136.4
219.4
195.8
197.1
196.7
267.8
238.5
239.3
238.4
303.1
269.0
269.9
269.5
81.6
105.4
121.8
133.9
211.0
212.0
285.9
285.9
340.7
340.7
381.6
381.6
9.62
37.6
32.9
35.7
7.45
27.9
11.88
11.38
10.84
33.3
33.7
33.4
8.87
30.6
30.9
38.6
77.2
45.2
37.3
42.3
56.2
28.4
45.2
38.1
39.7
39.8
39.7
51.6
34.9
35.1
48.0
34.3
36.5
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.71
THERMODYNAMIC PROPERTIES
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
trans-3-Methyl-3-hexene
Methylhydrazine
Methyl isobutanoate
Methyl isocyanide
1-Methyl-4-isopropylbenzene
3-Methylisoxazole
5-Methylisoxazole
Methylmercury bromide
Methylmercury chloride
Methylmercury iodide
Methyl methacrylate
Methyl 2-methylbutanoate
Methyl-3-methylbutanoate
1-Methylnaphthalene
⌬Ht ⫽ 5.0⫺32.4
2-Methylnaphthalene
⌬Ht ⫽ 5.615.4
Methyl nitrate
Methyl nitrite
1-Methyl-4-nitrobenzene
2-Methylnonane
3-Methylnonane
5-Methylnonane
2-Methyloctane
Methyl octanoate
Methyl oxirane
2-Methylpentane
3-Methylpentane
2-Methyl-2,4-pentanediol
3-Methylpentanenitrile
Methyl pentanoate
2-Methylpentanoic acid
2-Methyl-1-pentanol
2-Methyl-2-pentanol
2-Methyl-3-pentanol
3-Methyl-1-pentanol
3-Methyl-2-pentanol
4-Methyl-1-pentanol
4-Methyl-2-pentanol
3-Methyl-3-pentanol
2-Methyl-3-pentanone
3-Methyl-2-pentanone
4-Methyl-2-pentanone
2-Methyl-1-pentene
3-Methyl-1-pentene
4-Methyl-1-pentene
2-Methyl-2-pentene
cis-3-Methyl-2-pentene
trans-3-Methyl-2-pentene
cis-4-Methyl-2-pentene
⌬Hm
⌬Hv
⌬Hs
10.4
36.1
32.6
35.9
40.4
37.3
30.8
9.60
400 K
600 K
800 K
1000 K
212.3
292.0
345.1
381.6
38.2
36.0
41.0
41.0
67.8
64.4
65.3
60.7
41.8
41.0
6.94
45.5
11.97
46.0
61.7
211.2
290.0
343.2
381.2
8.2
31.6
20.9
32.1
22.6
79.1
49.6
49.7
49.3
91.5
76.3
115.2
97.7
131.7
112.8
143.1
123.5
184.1
181.9
211.7
246.9
296.2
294.6
331.4
330.1
170.7
177.8
162.8
163.2
163.2
163.2
167.6
227.6
232.6
221.3
222.6
222.6
222.6
226.4
269.5
272.8
264.0
245.2
265.3
265.3
267.8
300.4
302.5
296.2
297.5
297.5
297.5
299.2
38.2
38.3
38.1
18.00
6.27
5.30
27.4
27.8
28.1
57.3
35.1
35.4
52.1
50.2
39.6
41.8
46.3
43.4
44.5
44.2
41.8
33.8
34.2
34.5
28.1
26.9
27.1
29.0
28.8
29.3
27.6
56.4
27.9
29.9
30.3
41.6
43.1
57.5
55.7
54.8
54.4
62.3
56.9
60.5
50.6
39.8
40.5
40.6
30.5
28.7
28.7
31.6
31.2
31.5
29.5
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.72
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
cap height
base of text
Cp
Substance
trans-4-Methyl-2-pentene
4-Methyl-3-penten-2-one
Methyl pentyl ether
Methyl pentyl sulfide
3-Methyl-1-phenyl-1-butanone
2-Methyl-1-phenylpropane
Methyl phenyl sulfide
Methyl phenyl sulfone
Methylphosphonic acid
2-Methylpiperidine
2-Methylpropanal
2-Methylpropane
2-Methylpropanenitrile
2-Methyl-1-propanethiol
2-Methyl-2-propanethiol
⌬Ht ⫽ 4.1⫺121.6
⌬Ht ⫽ 0.7⫺116.2
⌬Ht ⫽ 1.0⫺73.8
Methyl propanoate
2-Methylpropanoic acid
2-Methyl-1-propanol
2-Methyl-2-propanol
⌬Ht ⫽ 0.813
2-Methylpropene
Methyl propyl ether
Methyl propyl sulfide
2-Methylpyridine
3-Methylpyridine
4-Methylpyridine
1-Methyl-1H-pyrrole
Methyl salicylate
␣-Methylstyrene
cis-␤-Methylstyrene
trans-␤-Methylstyrene
Methyl tetradecanoate
2-Methylthiacyclopentane
4-Methylthiazole
2-Methylthiophene
3-Methylthiophene
Methyl trichloroacetate
Methyl tridecanoate
Methyl undecanoate
5-Methyluracil
Morpholine
Naphthalene
1-Naphthalenecarboxylic acid
2-Naphthalenecarboxylic acid
1-Naphthol
2-Naphthol
1,4-Naphthoquinone
⌬Hm
12.5
4.66
5.0
2.5
⌬Hv
⌬Hs
28.0
36.1
32.0
37.4
30.0
37.8
21.3
32.4
31.0
28.5
32.2
5.02
6.32
6.79
5.93
9.9
9.72
14.18
11.57
41.8
39.1
22.1
26.8
32.1
36.2
37.4
37.5
400 K
600 K
800 K
1000 K
171.1
214.0
229.3
269.9
300.4
203.6
272.2
324.6
366.0
36.9
45.2
59.5
49.5
54.3
92.0
48.1
40.5
31.5
19.3
37.1
34.6
30.8
124.6
169.5
202.9
227.6
147.7
151.2
193.6
199.2
225.0
232.3
247.6
256.2
35.9
35.3
50.8
46.7
142.9
189.8
222.9
247.5
111.2
138.1
144.9
133.6
133.1
147.7
183.8
191.9
186.4
186.1
175.1
218.7
227.8
222.6
222.3
196.0
244.8
255.8
243.3
247.8
187.4
187.4
189.1
254.0
254.0
256.1
300.4
300.4
301.3
333.9
333.9
334.7
123.1
122.9
165.6
164.6
194.3
192.3
214.6
211.7
180.1(g)
251.5
297.3
329.2
20.6
27.6
36.2
42.5
44.4
44.6
40.8
46.7
9.20
10.53
36.4
37.6
33.9
34.2
18.98
37.1
43.2
23.33
17.51
37.0
41.8
43.8
38.9
39.4
48.3
82.7
71.4
134.1
44.0
72.6
110.4
113.6
91.2
94.2
72.4
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.73
THERMODYNAMIC PROPERTIES
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
1-Naphthylamine
2-Naphthylamine
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
1-Nitrobutane
2-Nitrobutane
Nitroethane
Nitromethane
(Nitromethyl)benzene
2-Nitrophenol
3-Nitrophenol
4-Nitrophenol
1-Nitronaphthalene
1-Nitropropane
2-Nitropropane
2-Nitroso-1-naphthol
4-Nitroso-1-naphthol
1-Nitroso-2-naphthol
2-Nitrotoluene
3-Nitrotoluene
4-Nitrotoluene
Nonadecane, ⌬Ht ⫽ 13.822.8
1-Nonadecene
1-Nonal
Nonane, ⌬Ht ⫽ 6.3⫺56.0
1-Nonanethiol
Nonanoic acid
1-Nonanol
2-Nonanone
5-Nonanone
1-Nonene
cis-Octadecafluorodecahydronaphthalene
trans-Octadecafluorodecahydronaphthalene
Octadecafluoropropylcyclohexane
Octadecafluorooctane
Octadecane
Octadecanedioic acid
Octadecanoic acid
Octadecanol
1-Octadecene
cis-9-Octadecenoic acid
Octafluorocyclobutane
Octafluorotoluene
Octamethylcyclotetrasiloxane
Octanal
Octanamide
Octane
1,8-Octanedioic acid
⌬Hm
16.11
23.68
21.1
11.59
9.85
9.70
⌬Hv
40.8
38.9
36.8
38.0
34.0
⌬Hs
90.0
88.3
90.0
96.7
109
55.0
48.6
43.8
41.6
38.3
53.6
400 K
600 K
800 K
1000 K
157.5
157.4
99.0
70.3
210.1
211.1
131.6
91.7
247.0
248.7
154.0
106.9
273.6
276.0
170.2
117.9
128.5
129.2
171.0
172.3
200.7
201.8
222.0
222.8
559.4
545.0
271.1
269.0
291.6
754.9
733.7
361.5
364.1
390.3
896.3
869.7
426.4
433.3
464.6
1000.8
969.9
474.5
484.9
521.5
282.4
379.1
449.6
501.7
17.44
19.2
18.25
38.5
36.8
16.81
45.82
33.5
15.47
33.5
20.28
16.5
15.0
15.5
56.0
54.6
36.9
44.4
54.4
24.93
18.08
61.39
56.6
56.59
32.6
2.77
11.58
36.3
35.6
35.8
24.5
33.4
54.5
53.3
64.7
23.2
107.1
43.4
41.3
56.5
87.4
86.6
47.2
49.9
50.2
95.8
94.9
72.3
46.4
82.4
76.9
56.4
53.3
45.5
45.2
45.4
43.1
41.1
152.8
254.6
342.8
406.8
454.0
530.4
715.8
850.0
949.4
166.5
113.4
90.0
516.0
694.5
823.4
918.4
186.1
225.3
245.4
257.3
242.3
322.2
380.3
422.6
240.0
325.0
387.0
433.5
45.6
20.65
34.4
110.5
41.5
143.1
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.74
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
cap height
base of text
Cp
Substance
Octanenitrile
1-Octanethiol
Octanoic acid
1-Octanol
(⫾)-2-Octanol
(⫾)-3-Octanol
4-Octanol
2-Octanone
1-Octene
1-Octyne
2-Octyne
3-Octyne
4-Octyne
Oxalic acid
Oxaloyl chloride
Oxamide
Oxetane
2-Oxetanone
2-Oxohexamethyleneimine
4-Oxopentanoic acid
1,1⬘-Oxybis(2-ethoxy)ethane
2,2⬘-Oxybis(ethanol)
Paraldehyde
Pentachloroethane
Pentachlorofluoroethane
Pentachlorophenol
Pentacyclo[4.2.0.02,5.03,8.04,7]octane
Pentadecane, ⌬Ht ⫽ 9.2⫺2.25
Pentadecanoic acid
1-Pentadecene
1,2-Pentadiene
cis-1,3-Pentadiene
trans-1,3-Pentadiene
1,4-Pentadiene
2,3-Pentadiene
Pentaerythritol
Pentaerythritol tetranitrate
Pentafluorobenzene
Pentafluorobenzoic acid
Pentafluoroethane
Pentafluorophenol
2,3,4,5,6-Pentafluorotoluene
Pentamethylbenzene
⌬Ht ⫽ 2.023.7
2,2,4,6,6-Pentamethylheptane
Pentanal
Pentanamide
Pentane
1,5-Pentanediol
⌬Hm
24.3
21.36
42.30
24.42
15.57
⌬Hv
⌬Hs
41.3
42.3
58.5
46.9
44.4
36.5
40.5
56.8
34.1
35.8
37.3
36.9
36.0
40.4
42.3
44.5
43.9
42.7
98.0
31.8
113.0
29.9
47.0
83.3
28.7
16.2
9.22
54.8
52.3
11.34
1.9
36.9
81.7
71.0
58.4
57.3
41.4
45.6
400 K
600 K
800 K
1000 K
262.6
351.3
418.3
469.9
253.4
340.0
403.3
450.1
225.6
216.5
303.7
285.7
360.5
336.0
402.5
410.9
133.7
152.1
162.0
168.1
443.3
598.6
711.1
794.5
428.9
131.4
123.4
130.5
131.0
125.1
577.3
170.7
166.9
171.1
170.2
164.9
684.5
199.6
196.7
199.6
220.5
195.0
763.6
220.9
218.4
220.1
113.8
137.8
151.1
158.9
272.0
360.2
423.8
470.0
155.2
205.0
241.4
267.8
152.8
207.7
248.1
278.5
67.4
34.8
50.2
28.9
6.14
10.85
12.85
12.99
12.3
8.42
49.5
48.7
27.6
27.6
27.0
25.2
28.2
92
32.2
34.8
45.1
25.8
60.7
80.3
76.1
162.7
75.1
28.7
28.3
27.8
25.7
29.5
143.9
151.9
36.3
91.6
67.4
41.1
60.8
49.0
38.8
89.3
26.4
217.6
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.75
THERMODYNAMIC PROPERTIES
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
1,5-Pentanedithiol
2,4-Pentanedione
Pentanenitrile
1-Pentanethiol
Pentanoic acid
1-Pentanol
2-Pentanol
3-Pentanol
2-Pentanone
3-Pentanone
1-Pentene
cis-2-Pentene
trans-2-Pentene
cis-2-Pentenenitrile
trans-2-Pentenenitrile
trans-3-Pentenenitrile
Pentyl acetate
Pentylamine
Pentylcyclohexane
Pentyl propyl ether
1-Pentyne
2-Pentyne
Perylene
␣-Phellandrene
Phenanthrene
9,10-Phenanthrenedione
Phenazine
Phenol
Phenyl acetate
Phenylacetonitrile
Phenylacetylene
(⫺)-3-Phenyl-1-alanine
␣-Phenylbenzeneacetic acid
Phenyl benzoate
Phenylboron dichloride
Phenylcyclopropane
N-Phenyldiacetimide
Phenyl formate
Phenylhydrazine
1-Phenyl-1-propanone
1-Phenyl-2-propanone
Phenyl salicylate
Phenyl vinyl ether
Phthalamide
1,3-Phthalic acid
1,4-Phthalic acid
Phthalic anhydride
Phthalonitrile
Piperidine
Propadiene
⌬Hm
4.73
17.5
14.16
9.83
10.63
11.59
5.81
7.12
8.36
⌬Hv
34.3
36.1
34.9
44.1
44.4
41.4
43.5
33.4
33.5
25.2
26.1
26.1
36.4
37.8
37.1
41.0
34.0
35.0
27.7
29.3
⌬Hs
59.3
41.8
43.6
41.2
62.4
57.0
54.2
54.0
38.4
38.5
25.5
26.9
26.8
43.2
44.9
44.8
40.1
53.9
42.8
28.4
30.8
400 K
600 K
800 K
1000 K
175.4
234.0
279.4
315.1
166.3
222.8
264.4
295.4
152.4
202.2
239.0
266.1
138.5
132.1
136.7
186.4
182.5
184.2
221.5
218.8
219.5
247.7
245.9
246.1
130.1
122.2
169.0
161.9
197.1
192.1
218.4
215.1
135.8
182.2
211.8
232.2
150.4
200.9
233.4
255.9
72.0
92.1
106.4
117.2
31.75
16.46
55.7
11.29
45.7
50.6
75.5
91.6
99.9
57.8
54.8
52.9
41.8
155.2
31.27
16.43
14.85
31.7
18.6
99.0
33.9
50.2
90.0
52.9
61.7
58.5
49.0
92.1
49.9
57.3
106.7
98.3
88.7
86.9
39.3
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.76
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
cap height
base of text
Cp
Substance
Propanal
Propanamide
Propane
1,2-Propanediamine
1,3-Propanediamine
Propanedinitrile
1,2-Propanediol
1,3-Propanediol
1,2-Propanedione
1,2-Propanedithiol
Propanenitrile, ⌬Ht ⫽ 1.7⫺96.2
1-Propanethiol, ⌬Ht ⫽ 4.0⫺131.1
2-Propanethiol
1,2,3-Propanetriol triacetate
1,2,3-Propanetriol trinitrate
Propanoic acid
Propanoic anhydride
1-Propanol
2-Propanol
Propanolactone
2-Propenal
Propene
2-Propenenitrile
Propenoic acid
2-Propen-1-ol
cis-1-Propenylbenzene
2-Propoxyethanol
Propyl acetate
1-Propylamine
Propylbenzene
Propyl benzoate
Propyl carbamate
Propyl chloroacetate
Propylcyclohexane
Propylcyclopentane
Propylene oxide
Propyl formate
Propyl nitrate
Propyl propanoate
Propyl trichloroacetate
Propyl vinyl ether
Propyne
2-Propyn-1-ol
Pyrazine
Pyrene
Pyridazine
Pyridine
Pyrimidine
1H-Pyrrole
Pyrrolidine, ⌬Ht ⫽ 0.5⫺66
⌬Hm
17.6
3.53
⌬Hv
⌬Hs
400 K
600 K
800 K
1000 K
28.3
29.6
85.9
14.8
44.2
50.2
79.1
58.0
37.1
38.1
49.7
36.0
31.9
29.5
85.7
96.6
126.4
148.3
164.0
94.0
128.7
154.8
174.6
88.6
116.6
118.6
114.7
153.6
154.9
134.5
182.4
181.0
149.4
205.1
200.5
108.2
112.0
144.6
149.6
171.7
176.3
192.2
195.9
80.5
108.0
128.7
144.4
95.4
187.4
126.0
254.0
147.6
300.4
163.4
333.9
119.3
200.1
159.0
275.6
188.0
327.6
210.1
364.7
247.3
212.7
92.7
350.6
297.2
125.8
423.4
361.0
149.3
474.5
407.9
166.5
149.8
194.5
225.4
247.2
72.5
91.2
105.2
115.9
106.4
149.5
177.8
197.4
114.4
168.7
206.5
233.6
19.0
40.9
54.1
57.9
5.05
5.5
5.7
21.9
10.66
5.20
5.37
3.00
6.23
11.16
10.97
9.27
10.37
10.0
6.5
31.8
29.5
27.9
57.8
32.3
41.7
41.4
39.9
28.3
18.4
32.1
52.6
47.4
45.4
47.0
31.3
14.2
40.0
47.3
41.4
33.9
29.6
38.2
49.8
52.1
39.7
31.3
46.2
51.9
81.2
48.5
45.1
41.1
28.3
37.5
40.6
43.5
53.1
29.3
36.1
34.7
27.4
33.6
35.9
35.5
22.1
42.1
56.3
17.11
8.28
7.91
8.58
35.1
49.8
38.8
33.0
53.5
40.2
50.0
45.1
37.6
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.77
THERMODYNAMIC PROPERTIES
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
Quinoline
Salicylic acid
5,5⬘-Spirobis(1,3-dioxane)
Spiro[2.2]pentane
cis-Stilbene
trans-Stilbene
Styrene
Succinic acid
Succinic anhydride
Succinonitrile
p-Terphenyl
1,1,2,2-Tetrabromoethane
Tetrabromomethane
Tetrabutyltin
Tetracene
Tetrachloro-1,4-benzoquinone
1,1,2,2-Tetrachloro-1,2-difluoroethane
1,1,1,2-Tetrachloro-2,2-fluorooctane
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
Tetrachloromethane
⌬Ht ⫽ 4.6⫺47.9
Tetracyanoethylene
Tetracyanomethane
Tetradecane
Tetradecanenitrile
Tetradecanoic acid
1-Tetradecanol
1-Tetradecene
Tetraethylene glycol
Tetraethylgermanium
Tetraethyllead
Tetraethylsilane
Tetraethyltin
1,1,1,2-Tetrafluoroethane
Tetrafluoroethylene
Tetrafluoromethane
⌬Ht ⫽ 1.5⫺196.9
Tetrahydrofuran
Tetrahydrofuran-2,5-dimethanol
Tetrahydrofuran-2-methanol
1,2,3,4-Tetrahydronaphthalene
Tetrahydropyran
Tetrahydropyran-2-methanol
Tetrahydrothiophene
Tetrahydrothiophene-1,1-dioxide
Tetraiodomethane
Tetramethoxysilane
1,2,3,4-Tetramethylbenzene
⌬Hm
⌬Hv
⌬Hs
10.66
49.7
5.8
26.8
53.9
95.1
72.8
27.5
69.0
99.2
43.9
117.5
27.4
11.0
32.95
20.41
3.92
35.5
38.7
48.7
45.1
3.70
3.99
10.56
3.28
45.6
45.38
49.0
27.6
70.0
110
19.8
125.5
98.7
400 K
600 K
800 K
1000 K
119.5
167.8
200.5
223.9
160.3
218.2
256.9
284.2
97.1
102.6
106.7
105.9
118.7
116.7
105.0
91.7
139.2
137.7
116.6
99.7
151.6
150.0
122.6
103.1
159.7
158.0
125.8
104.8
414.3
559.5
664.8
743.1
399.8
538.2
638.2
712.1
104.2
91.9
72.4
128.7
106.8
86.8
143.1
115.5
94.5
152.1
120.8
98.8
100.4
104.4
105.9
106.7
237.7
316.7
374.1
416.2
35.0
37.6
34.7
29.8
47.6
46.9
62.6
45.7
39.7
32.4
81.2
61.1
71.3
85.3
139.8
102.2
70.2
98.7
44.8
56.9
13.01
51.0
7.7
0.7
16.8
12.6
8.54
29.8
63.6
45.2
43.9
31.2
44.4
34.7
12.45
32.0
51.6
55.2
34.6
39.4
1.43
11.2
194.6
45.0
57.2
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.78
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
cap height
base of text
Cp
Substance
1,2,3,5-Tetramethylbenzene
1,2,4,5-Tetramethylbenzene
2,2,3,3-Tetramethylbutane
⌬Ht ⫽ 2.0⫺120.7
Tetramethylene sulfone
Tetramethyllead
2,2,3,3-Tetramethylpentane
2,2,3,4-Tetramethylpentane
2,2,4,4-Tetramethylpentane
2,3,3,4-Tetramethylpentane
Tetramethylsilane
Tetramethyltin
1,1,3,3-Tetramethylurea
Tetranitromethane
Tetraphenylmethane
Tetraphenyltin
Tetrapropylgermanium
Tetrapropyltin
1,2,3,4-(1H)-Tetrazole
Thiacyclobutane
Thiacycloheptane
Thiacyclohexane
⌬Ht ⫽ 1.1⫺71.8
⌬Ht ⫽ 7.8⫺33.1
Thiacyclopentane
Thiacyclopropane
Thioacetamide
Thioacetic acid
1,2-Thiocresol
2,2⬘-Thiodiethanol
Thiophene, ⌬Ht ⫽ 0.6⫺101.6
Thiophenol
Thymol
Toluene
o-Toluidine
m-Toluidine
p-Toluidine
Triacetamide
2,4,6-Triamino-1,3,5-triazine
Tribromomethane
Tributoxyborane
Tributyl phosphate
Trichloroacetic acid
Trichloroacetonitrile
Trichloroacetyl chloride
1,3,5-Trichlorobenzene
Trichlorobenzoquinone
1,1,1-Trichloroethane
⌬Ht ⫽ 7.5⫺49.0
1,1,2-Trichloroethane
⌬Hm
⌬Hv
⌬Hs
10.7
21.0
7.54
43.8
45.5
31.4
53.7
53.4
42.9
1.4
61.5
400 K
600 K
800 K
1000 K
233.3
232.2
313.0
311.2
371.5
369.9
414.3
413.0
175.7
149.4
272.0
219.1
330.5
267.8
368.2
302.7
39.5
30.3
83.3
37.2
51.5
121.1
69.2
167.5
92.0
199.4
107.2
222.3
118.0
93.1
111.8
127.2
136.5
34.7
47.6
96.3
137.1
129.5
184.6
150.7
215.9
165.4
237.6
38.0
56.7
57.3
140.1
197.5
236.9
264.9
78.7
88.0
93.3
96.7
38.1
2.33
0.50
9.75
9.00
6.88
32.5
38.5
33.1
14.10
45.6
40.7
32.3
2.5
36.0
7.4
34.7
29.2
5.09
11.5
17.27
6.85
3.89
18.22
66.8
31.5
39.9
33.2
44.6
44.9
44.3
39.7
56.1
61.4
49.9
150.6
66.3
61.5
66.9
97.5
36.0
47.3
42.6
60.4
124.3
46.1
52.3
72.0
5.88
34.1
41.0
18.2
2.73
29.9
88.7
32.5
107.6
128.4
141.1
149.8
11.54
34.8
40.2
104.7
126.1
139.2
148.2
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.79
THERMODYNAMIC PROPERTIES
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
Trichloroethylene
Trichloromethane
Trichloromethylsilane
1,2,3-Trichloropropane
1,1,1-Trichlorotrifluoroethane
1,1,2-Trichlorotrifluoroethane
1,1,1-Trichloro-3,3,3-trifluoropropane
Tricyanoethylene
Tridecane, ⌬Ht ⫽ 7.7⫺18.2
Tridecanenitrile
Tridecanoic acid
1-Tridecene
Triethanolamine
Triethoxyborane
Triethoxymethane
Triethylaluminum
Triethylamine
Triethylaminoborane
Triethylarsine
Triethyl arsenite
Triethylbismuthine
Triethylborane
Triethylenediamine
⌬Ht ⫽ 9.679.8
Triethylene glycol
Triethylphosphine
Triethyl phosphate
Triethyl phosphite
Triethylstibine
Trifluoroacetic acid
⌬H(dimer dissoc) ⫽ 58.8100
Trifluoroacetonitrile
1,1,1-Trifluoro-2-bromo-2-chloroethane
1,1,1-Trifluoroethane
2,2,2-Trifluoroethanol
Trifluoroethylene
Trifluoromethane
(Trifluoromethyl)benzene
Triiodomethane
Triisopropylborane
Triisopropyl phosphite
Trimethoxyborane
1,1,1-Trimethoxyethane
Trimethoxymethane
2⬘,4⬘,5⬘-Trimethylacetophenone
2⬘,4⬘,6⬘-Trimethylacetophenone
Trimethylaluminum
Trimethylamine
Trimethyl arsenite
Trimethylarsine
⌬Hm
8.8
8.94
8.9
2.47
⌬Hv
⌬Hs
400 K
600 K
800 K
1000 K
31.4
29.2
34.5
31.3
91.2
74.3
104.9
85.3
112.7
91.5
117.8
95.5
31.7
38.9
43.8
47.3
385.2
520.4
618.5
691.2
370.8
499.1
592.0
660.2
203.8
276.6
328.7
367.4
95.2
118.7
133.8
144.1
81.1
61.1
169.8
82.0
97.5
76.0
226.8
90.0
107.5
85.1
262.6
94.7
113.9
91.0
286.4
97.8
117.5
160.4
190.9
213.3
37.1
26.9
27.0
32.2
28.50
45.7
43.1
22.83
27.2
45.0
67.5
31.0
6.1
71.4
33.3
28.1
28.4
36.8
81.2
66.4
85.3
146.4
65.3
43.9
46.0
73.2
34.8
60.7
43.1
50.6
46.0
36.8
61.9
79.1
39.8
57.3
41.8
43.5
38.5
5.0
6.19
28.1
19.2
40.0
4.1
13.46
16.3
16.7
32.6
6.55
22.9
29.6
37.6
69.9
41.8
46.0
34.7
39.2
38.1
63.2
62.3
63.2
21.7
42.3
28.9
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.80
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
cap height
base of text
Cp
Substance
1,2,3-Trimethylbenzene
⌬Ht ⫽ 0.7⫺54.5
⌬Ht ⫽ 1.3⫺42.9
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
2,6,6-Trimethylbicyclo[3.1.1]-2-heptene
Trimethylbismuthine
Trimethylborane
2,2,3-Trimethylbutane
⌬Ht ⫽ 2.5⫺151.8
2,3,3-Trimethyl-1-butene
cis,cis-1,3,5-Trimethylcyclohexane
Trimethylene oxide
Trimethylene sulfide
⌬Ht ⫽ 0.7⫺96.5
Trimethylgallium
2,2,5-Trimethylhexane
2,3,5-Trimethylhexane
Trimethylindium
2,4,7-Trimethyloctane
2,2,3-Trimethylpentane
2,2,4-Trimethylpentane
2,3,3-Trimethylpentane
⌬Ht ⫽ 7.7⫺109.0
2,3,4-Trimethylpentane
2,2,4-Trimethyl-1,3-pentanediol
2,2,4-Trimethyl-3-pentanone
2,4,4-Trimethyl-1-pentene
2,4,4-Trimethyl-2-pentene
Trimethylphosphine
Trimethylphosphine oxide
Trimethyl phosphate
2,3,6-Trimethylpyridine
2,4,6-Trimethylpyridine
Trimethylsilanol
Trimethylstibine
Trimethylsuccinic anhydride
Trimethylthiacyclopropane
Trimethyltin bromide
2,4,6-Trinitroanisole
1,3,5-Trinitrobenzene
Trinitromethane
2,4,6-Trinitrophenetole
2,4,6-Trinitrotoluene
1,3,6-Trioxacycloactane
1,3,5-Trioxane
Triphenylarsine
Triphenylbismuthine
Triphenylborane
Triphenylene
⌬Hm
⌬Hv
⌬Hs
8.37
40.0
49.1
9.51
39.3
39.0
2.20
28.9
47.9
47.5
44.8
34.7
20.2
32.0
400 K
600 K
800 K
1000 K
196.2
267.8
320.9
359.4
196.5
194.2
269.0
268.1
321.9
321.5
360.2
360.1
212.7
291.3
346.1
386.3
242.9
351.2
427.6
482.0
91.6
127.4
152.3
170.2
32.2
8.3
28.7
32.3
6.2
10.00
33.7
34.4
8.62
9.04
0.86
38.2
31.9
30.8
32.1
9.27
8.6
9.53
32.4
55.7
35.6
31.4
32.6
40.0
39.9
16.7
32.6
15.11
29.9
36.0
38.1
40.2
41.4
48.5
49.9
36.9
35.1
37.3
37.7
43.3
35.8
37.5
28.0
50.2
36.8
50.6
50.3
45.6
31.4
74.1
39.3
47.3
133.1
99.6
46.7
120.5
104.7
48.8
56.6
99.3
110.9
81.6
118.0
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.81
THERMODYNAMIC PROPERTIES
TABLE 6.2 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
Organic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
⌬Hm
Substance
Triphenylmethane
Triphenylphosphine
Triphenylstibine
Tripropoxyborane
Tris(diethylamino)phosphine
Tris(trimethylsilyl)amine
Tropolone
Undecane
⌬Ht ⫽ 6.9⫺36.6
Undecanenitrile
Undecanoic acid
1-Undecene, ⌬Ht ⫽ 9.2⫺55.8
Uracil
Urea
(⫺)-Valine
Vinyl acetate
Vinyl benzene
Vinylcyclohexane
4-Vinyl-1-cyclohexene
1,2-Xylene
1,3-Xylene
1,4-Xylene
22.32
⌬Hv
⌬Hs
41.5
100.0
96
106.3
49.4
60.7
54.4
83.7
56.4
25.9
16.99
40.9
15.1
87.9
34.4
13.61
11.55
16.81
33.5
36.2
35.7
35.7
71.1
121.3
55.4
126.5
162.8
34.8
39.6
39.7
38.3
43.4
42.7
42.4
400 K
600 K
800 K
1000 K
327.1
442.7
525.9
588.3
312.7
421.1
499.3
557.3
171.7
167.5
166.1
234.2
232.2
230.8
278.8
277.9
276.7
311.1
310.6
309.7
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds
Substance
Actinium
Ac
Aluminum
Al
Al3⫹ std. state
Al6BeO10
Al(BH4)3
AlBr3
std. state
Al4C3
Al(CH3)3
Al(OAc)3
AlCl3
std. state
AlCl3 · 6H2O
AlF3
std. state
Physical
State
⌬fH⬚
kJ · mol⫺1
c
0
c
g
aq
c
lq
c
aq
c
lq
c
c
aq
c
c
aq
0
330.0(40)
⫺538.4(15)
⫺5624
⫺16.3
⫺527.2
⫺895
⫺216
136.4
⫺1892.4
⫺704.2
⫺1033
⫺2692
⫺1510.4(13)
⫺1531.0
⌬fG⬚
kJ · mol⫺1
0
S⬚
J · deg⫺1 · mol⫺1
56.5
0
289.4
⫺485.3
⫺5317
145.0
⫺488.5
⫺799
⫺203
⫺10.0
28.30(10)
164.554(4)
⫺325.(10)
175.6
289.1
180.2
⫺74.5
89
209.4
⫺628.8
⫺878
⫺2269
⫺1431.1
⫺1322
109.29
⫺152.3
377
66.5(5)
⫺363.2
C⬚p
J · deg⫺1 · mol⫺1
27.2
24.4
21.4
265.19
194.6
100.58
155.6
91.13
75.13
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.82
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
AlF3 · H2O
AlH3
AlI3
std. state
AlK(SO4)2 · 12H2O
AlN
Al(NO3)3 std. state
Al(NO3)3 · 6H2O
Al(NO3)3 · 9H2O
AlO⫺2 std. state
Al2O3 corundum
Al(OH)3
Al(OH)⫺4 std. state
AlP
AlPO4 berlinite
Al2S3
Al2Se3
Al2SiO5 andalusite
Al2(SO4)3
std. state
Al2Te3
Americium
Am
Am3⫹
Am4⫹
Am2O3
AmO2
Ammonium
NH3
undissoc; std. state
ND3
NH⫹4 std. state
NH4OH undissoc;
std. state
ionized; std. state
NH4OAc
std. state
NH4Al(SO4)2
std. state
NH4AsO2 std. state
NH4H2AsO3 std. state
NH4H2AsO4
std. state
(NH4)2HAsO4 std. state
(NH4)3AsO4 std. state
NH4Br
std. state
NH4BrO3
NH4 carbamate
NH4Cl
std. state
NH4ClO3 std. state
Physical
State
⌬fH⬚
kJ · mol⫺1
c
c
c
aq
c
c
aq
c
c
aq
c
c
aq
c
c
c
c
c
c
aq
c
⫺2297
⫺46.0
⫺313.8
⫺699
⫺6061.8
⫺318.1
⫺1155
⫺2850.5
⫺3757.1
⫺930.9
⫺1675.7(13)
⫺1284
⫺1502.5
⫺166.5
⫺1733.8
⫺724.0
⫺565
⫺2592.0
⫺3435
⫺3790
⫺326
c
aq
aq
c
c
0
⫺682.8
⫺511.7
⫺1757
⫺1005.0
g
aq
g
aq
aq
aq
c
aq
c
aq
aq
c
c
aq
aq
aq
c
aq
aq
c
c
aq
aq
⫺45.94(35)
⫺80.29
⫺58.6
⫺133.26(25)
⫺361.2
⫺362.50
⫺616.14
⫺618.52
⫺2352.2
⫺2481
⫺561.54
⫺847.30
⫺1059.8
⫺1042.07
⫺1171.1
⫺1286.7
⫺271.8
⫺254.05
⫺199.58
⫺657.60
⫺314.5
⫺299.66
⫺236.48
⌬fG⬚
kJ · mol⫺1
⫺2052
⫺300.8
⫺640
⫺5141.7
⫺287.0
⫺820
⫺2203.9
⫺2929.6
⫺830.9
⫺1582.3
⫺1306
⫺1305.3
⫺1618.0
⫺640
S⬚
J · deg⫺1 · mol⫺1
209
30.0
159.0
12.1
687.4
20.14
117.6
467.8
569
⫺36.8
50.92(10)
71
102.9
90.79
116.85
⫺2444.8
⫺3507
⫺3205
93.2
239.3
⫺583.3
0
⫺671.5
⫺461.1
⫺1678
950.2
62.7
⫺159.0
⫺372
154.7
96.2
⫺16.4
⫺26.57
⫺26.0
⫺79.37
⫺254.0
192.776(5)
111.3
203.9
111.17(40)
165.5
⫺236.65
102.5
⫺448.78
⫺2038.4
⫺2054
⫺429.41
⫺666.60
⫺833.0
⫺832.66
⫺873.20
⫺886.63
⫺175.2
⫺183.34
⫺60.84
⫺448.07
⫺202.9
⫺210.62
⫺87.40
200.0
216.3
⫺168.2
154.8
223.8
172.05
230.5
225.1
177.4
113.0
194.97
275.10
133.5
94.6
169.9
275.7
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
40.2
98.7
651.0
30.10
433.0
79.15
93.1
93.18
105.06
122.76
259.4
35.65
38.23
79.9
⫺68.6
73.6
226.44
151.17
96.0
⫺61.9
84.1
⫺56.5
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.83
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
NH4ClO4
std. state
NH4CN
std. state
NH4CNO cyanate
std. state
(NH4)2CO3 std. state
(NH4)2C2O4 oxalate
(NH4)2CrO4
std. state
(NH4)2Cr2O7
NH4 dithiocarbonate
NH4F
std. state
NH4 formate std. state
NH4HCO3
NH4I
std. state
NH4IO3
std. state
NH4N3 azide
NH4NO2
NH4NO3
std. state
NH4H2PO4
std. state
(NH4)2HPO4
std. state
NH4H3P2O7
NH4HS
NH4HSO3
NH4HSO4
std. state
(NH4)3PO4
std. state
(NH4)4P2O7 std. state
(NH4)2PtCl6
NH4ReO4
(NH4)2S
NH4SCN
NH4HSeO4 std. state
(NH4)2SeO4
(NH4)2SiF6
(NH4)2SO3
(NH4)2SO4
std. state
(NH4)2S2O8
std. state
NH4VO3
Physical
State
⌬fH⬚
kJ · mol⫺1
c
aq
c
aq
aq
⫺295.3
⫺261.84
0.4
18.0
⫺278.7
aq
c
c
aq
aq
c
c
aq
aq
c
aq
c
aq
c
aq
c
aq
aq
c
aq
c
aq
c
aq
aq
c
aq
aq
c
aq
c
aq
aq
c
c
aq
aq
aq
aq
c
aq
c
aq
c
aq
c
⫺942.15
⫺1123.0
⫺1167.3
⫺1144.3
⫺1755.2
⫺126.8
⫺463.96
⫺465.14
⫺558.06
⫺849.4
⫺824.5
⫺201.4
⫺187.69
⫺385.8
⫺354.0
115.5
142.7
⫺237.2
⫺365.56
⫺339.87
⫺1145.07
⫺1428.79
⫺1556.91
⫺1557.16
⫺2409.1
⫺156.9
⫺150.2
⫺758.7
⫺1026.96
⫺1019.85
⫺1671.9
⫺1674.9
⫺2801.2
⫺803.3
⫺945.6
⫺231.8
⫺56.1
⫺714.2
⫺864.0
⫺2681.69
⫺900.4
⫺1180.9
⫺1174.28
⫺1648.08
⫺1610.0
⫺1053.1
⌬fG⬚
kJ · mol⫺1
⫺88.8
⫺87.99
S⬚
J · deg⫺1 · mol⫺1
186.2
295.4
top of rh
base of rh
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
128.1
134.0
92.9
⫺177.0
207.5
220.1
⫺686.64
169.9
226.0
⫺886.59
⫺1459.5
277.0
488.7
⫺348.78
⫺358.19
⫺430.5
⫺665.9
⫺666.1
⫺112.5
⫺130.96
71.97
99.6
205.0
120.9
204.6
117.0
224.7
⫺207.5
274.1
268.6
⫺111.6
⫺184.01
⫺190.71
⫺1210.56
⫺1209.76
⫺1248.00
⫺2102.6
⫺50.6
⫺67.2
⫺607.0
231.8
112.6
221.3
236.4
151.08
259.8
151.96
203.8
188.0
193.3
326.0
97.5
176.1
253.1
⫺835.38
245.2
⫺1256.9
⫺2236.8
117
335
⫺774.9
⫺72.8
13.4
⫺531.6
⫺599.8
⫺2365.3
⫺645.0
⫺901.70
⫺903.37
232.6
212.1
257.7
262.8
280.7
280.24
197.5
220.1
246.9
⫺1273.6
⫺888.3
471.1
140.6
65.27
⫺26.8
⫺7.9
81.8
⫺62.3
⫺17.6
139.3
⫺6.7
142.26
⫺3.8
237.7
39.7
228.11
187.49
⫺133.1
129.33
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.84
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
Antimony
Sb
SbBr3
SbCl3
SbCl5
SbF3
SbH3
SbI3
Sb2O3
Sb2O5
Sb2S3
Sb2Te3
Argon
Ar
Arsenic
As gray
AsBr3
AsCl3
AsF3
AsH3
AsI3
AsO⫺2
AsO34⫺
As2O5
As4O6 octahedral
As2S3
Astatine
At
Barium
Ba
Ba2⫹ std. state
Ba(OAc)2 acetate
std. state
BaBr2
std. state
BaBr2 · 2H2O
Ba(BrO3)2
BaC2O4 oxalate
BaCl2
BaCl2 · 2H2O
Ba(ClO3)2
Ba(ClO3)2 · H2O
BaCO3 witherite
BaCrO4
BaF2
std. state
Ba(HCO3)2 std. state
Physical
State
c
g
c
g
c
lq
c
g
c
c
c
c
c
g
c
g
lq
g
lq
g
g
c
aq
aq
c
c
c
c
c
aq
c
aq
c
aq
c
c
c
c
c
c
c
c
c
c
aq
aq
⌬fH⬚
kJ · mol⫺1
0
262.3
⫺259.4
⫺194.6
⫺382.0
⫺440.16
⫺915.5
145.11
⫺100.4
⫺708.8
⫺971.9
⫺174.9
⫺56.5
0
0
⫺130.0
⫺305.0
⫺261.5
⫺821.3
⫺785.8
66.44
⫺58.2
⫺429.0
⫺888.1
⫺924.87
⫺1313.94
⫺169.0
0
0
⫺537.64
⫺1484.5
⫺1509.67
⫺757.3
⫺780.73
⫺1366.1
⫺752.66
⫺1368.6
⫺855.0
⫺1456.9
⫺762.7
⫺1691.6
⫺1213.0
⫺1446.0
⫺1207.1
⫺1202.90
⫺1921.63
⌬fG⬚
kJ · mol⫺1
0
222.1
⫺239.3
⫺223.9
⫺323.7
⫺350.2
147.74
⫺829.2
⫺55.2
0
0
⫺159.0
⫺259.4
⫺248.9
⫺774.2
⫺770.8
68.91
⫺59.4
⫺350.0
⫺648.4
⫺782.3
⫺1152.52
⫺168.6
0
0
⫺560.74
S⬚
J · deg⫺1 · mol⫺1
45.7
180.3
207.1
372.9
184.1
301
232.8
215.5
123.01
125.1
182.0
234
154.846(3)
35.1
363.9
216.3
327.06
181.2
289.1
222.8
213.05
40.6
⫺162.8
105.4
214.2
163.6
C⬚p
J · deg⫺1 · mol⫺1
25.2
20.8
80.2
107.9
41.05
97.57
101.25
117.61
117.74
20.79
24.64
79.16
133.5
75.73
126.2
65.6
38.07
105.77
116.5
191.29
116.3
121.3
62.48
9.6
⫺1299.55
⫺736.8
⫺768.68
⫺1230.5
⫺577.4
182.8
146.0
174.5
226
243
⫺806.7
⫺1293.2
123.67
202.9
⫺1270.7
⫺1134.4
⫺1345.3
⫺1156.8
⫺1118.38
⫺1734.4
cap height
base of text
393
112.1
158.6
96.4
⫺17.0
192.1
28.10
77.0
75.14
161.96
86.0
71.20
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.85
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
Ba(H2PO2)2
BaI2
std. state
Ba(IO3)2
std. state
BaMnO4
BaMoO4
Ba(NO2)2
Ba(NO3)2
std. state
BaO
BaO2
Ba(OH)2
Ba(OH)2 · H2O
BaS
BaSe
BaSeO3
BaSiF6
BaSO3
BaSO4
BaTiO3
Beryllium
Be
Be2⫹ std. state
BeAl2O4 chrysoberyl
BeBr2
Be2C
BeCl2 ␤ form
BeCO3
BeF2 ␣ form
BeI2
Be3N2 cubic
BeO ␣ form
BeO22⫺
3BeO · B2O3
Be(OH)2 ␤ form
BeS
BeSeO4
std. state
Be2SiO4
BeSO4
std. state
BeSO4 · H2O
BeWO4
Bismuth
Bi
BiBr3
BiCl3
BiH3
Physical
State
⌬fH⬚
kJ · mol⫺1
c
c
aq
c
aq
c
c
c
c
aq
c
c
c
c
c
c
c
c
c
c
c
⫺1762.3
⫺602.1
⫺648.02
⫺1027.2
⫺980.3
⫺1548
⫺1507.5
⫺768.2
⫺988.0
⫺952.36
⫺548.0
⫺634.3
⫺944.7
⫺3342.2
⫺460.0
⫺372
⫺1040.6
⫺1952.2
⫺1179.5
⫺1473.19
⫺1659.8
c
g
aq
c
c
c
c
c
c
c
c
c
aq
c
c
c
c
aq
c
c
aq
c
c
0
324.(5)
⫺382.8
⫺2301.0
⫺353.5
91
⫺490.4
1025.0
⫺1026.8
⫺192.5
⫺588.3
⫺609.4(25)
⫺790.8
⫺3105
⫺902.5
⫺234.3
⫺1205.2
⫺982.0
⫺2117
⫺1200.8
⫺1290.0
⫺2423.75
⫺1513
c
g
c
c
g
0
207.1
264
⫺379.1
277.8
⌬fG⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
165.1
232.2
249.4
246.4
138
144.3
⫺792.6
⫺783.41
⫺520.4
213.8
302.5
72.07
151.38
⫺859.5
⫺2793.2
⫺456.0
107
427
78.2
101.6
⫺968.2
⫺2794.1
167
163
⫺1362.2
⫺1572.4
132.2
108.0
⫺379.7
⫺2178.5
⫺337
⫺88
⫺445.6
⫺979.4
⫺187
⫺532.9
⫺580.1
⫺640.1
⫺2939
⫺815.0
⫺233.0
⫺1093.8
⫺820.9
⫺2003
⫺1089.4
⫺1124.3
⫺2080.66
⫺1405
0
168.2
234
⫺315.1
9.50(8)
136.275(3)
⫺129.7
66.29
108.0
16.3
75.81
52.0
53.35
121.0
34.13
13.77(4)
⫺159.0
100
45.5
34.0
77.9
⫺75.7
64.19
77.97
⫺109.6
232.97
88.4
56.7
187.0
226
177.0
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
⫺601.4
⫺663.92
⫺864.8
⫺816.7
⫺1439.7
⫺1439.7
0
top of rh
base of rh
77.49
187.4
140.6
114.7
47.28
49.37
101.75
102.47
16.38
105.38
69.4
43.2
62.43
65.0
51.82
71.1
64.36
25.56
139.7
62.1
34.0
85.7
95.6
85.70
216.61
97.3
25.5
20.8
109
105.0
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.86
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
BiI3
Bi2O3
BiOCl
Bi2S3
Bi2(SO4)3
Bi2Te3
Boron
B
BBr3
B4C
BCl3
BF3
BF⫺4 std. state
BH3
BH⫺4 std. state
B2H6 diborane(6)
B5H9 pentaborane(9)
B10H14 decaborane(14)
BN
B3N3H6 borazine
BO2⫺ std. state
B2O3
B(OH)⫺4 std. state
B3O3H3 boroxin
B2S3
Bromine
Br atomic
Br⫺ std. state
Br2
Br⫺3 std. state
BrCl
BrF
BrF3
BrF5
BrO⫺ std. state
BrO⫺3 std. state
BrO4⫺
Cadmium
Cd
Cd2⫹
CdBr2
std. state
CdCl2
std. state
CdCl2 · 5/2H2O
Physical
State
⌬fH⬚
kJ · mol⫺1
c
c
c
c
c
c
⫺100.4
⫺574.0
⫺366.9
⫺143.1
⫺2544.3
⫺78.24
c
g
lq
c
g
g
aq
g
aq
g
lq
c
c
lq
g
aq
c
aq
c
c
0
565.(5)
⫺239.7
⫺62.7
⫺403.8
⫺1136.0(8)
⫺1574.9
100.0
48.16
35.6
42.7
⫺29.83
⫺254.4
⫺541.0
⫺510
⫺772.37
⫺1273.5(14)
⫺1344.03
⫺1262
⫺240.6
g
aq
lq
g
aq
g
g
lq
g
lq
g
aq
aq
aq
111.87(12)
⫺121.41(15)
0
30.91(11)
⫺130.42
14.6
⫺93.8
⫺300.8
⫺255.6
⫺458.6
⫺428.9
⫺94.1
⫺67.07
13.0
c
g
aq
c
aq
c
aq
c
0
111.80(20)
⫺75.92(60)
⫺316.18
⫺318.99
⫺391.6
⫺410.20
⫺1131.94
⌬fG⬚
kJ · mol⫺1
⫺175.3
⫺493.7
⫺322.2
⫺140.6
0
⫺238.5
⫺62.1
⫺388.7
⫺1119.4
⫺1487.0
111
114.27
86.7
171.8
212.9
⫺228.4
⫺392.7
⫺389
⫺678.94
⫺1194.3
⫺1153.32
⫺11.56
82.4
⫺103.97
0
⫺107.07
⫺0.96
⫺109.2
⫺240.5
229.4
⫺351.9
⫺351.6
⫺33.5
18.6
118.1
0
⫺296.31
⫺285.52
⫺343.9
⫺340.12
⫺944.08
S⬚
J · deg⫺1 · mol⫺1
C⬚p
J · deg⫺1 · mol⫺1
151.5
120.5
200.4
113.5
260.91
152.21
5.90(8)
153.436(15)
229.7
27.18
290.1
254.42(20)
179.9
187.9
110.5
232.1
184.2
234.9
14.80
199.6
288.61
⫺37.24
53.97(30)
102.5
167
100.0
175.018(4)
82.55(20)
152.21(30)
245.468(5)
215.5
239.91
229.0
178.2
292.5
225.1
323.2
42.0
161.71
199.6
51.80(15)
167.749(4)
⫺72.8(15)
137.2
91.6
115.3
39.8
227.2
cap height
base of text
122.2
11.1
128.03
53.76
62.7
50.45
36.22
56.9
151.13
221.2
19.72
96.94
62.8
98.3
111.7
20.8
⫺141.8
75.67
34.98
32.97
124.6
66.6
99.6
25.9
20.8
76.7
74.7
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.87
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
Cd(CN)2
std. state
CdCO3
Cd(OAc)2 std. state
CdF2
std. state
CdI2
std. state
CdI⫺4 std. state
Cd(NH3)42⫹ std. state
Cd(NO3)2
std. state
CdO
Cd(OH)2
CdS
CdSO4
std. state
CdSO4 · 8/3H2O
CdSeO4
std. state
CdTe
Calcium
Ca
Ca2⫹ std. state
Ca(OAc)2
std. state
Ca3(AsO4)2
Ca(BO2)2
CaB4O7
CaBr2
std. state
CaC2
CaCl2
std. state
CaCl2 · 2H2O
CaCN2 cyanamide
Ca(CN)2
CaCO3 calcite
aragonite
CaC2O4
CaC2O4 · H2O
CaCrO4
CaF2
Ca(formate)2
CaH2
CaHPO4 · 2H2O
Ca(H2PO2)2 hypophosphite
Ca(H2PO4)2 std. state
Physical
State
⌬fH⬚
kJ · mol⫺1
c
aq
c
aq
c
aq
c
aq
aq
aq
c
aq
c
c
c
c
aq
c
c
aq
c
162.3
225.5
⫺750.6
⫺1047.9
⫺700.4
⫺741.15
⫺203.3
⫺186.3
⫺341.8
⫺450.2
⫺456.3
⫺490.6
⫺258.35(40)
⫺560.7
⫺161.9
⫺933.4
⫺985.2
⫺1729.30(80)
⫺633.0
⫺674.9
⫺92.5
c
g
aq
c
aq
c
c
c
c
aq
c
c
aq
c
c
c
c
c
aq
c
c
c
c
aq
c
c
c
c
aq
0
177.8(8)
⫺543.0(10)
⫺1479.5
⫺1514.73
⫺3298.7
⫺2030.9
⫺3360.3
⫺682.8
⫺785.9
⫺59.8
⫺795.4
⫺877.13
⫺1402.9
⫺350.6
⫺184.5
⫺1207.6
⫺1207.8
⫺1220.0
⫺1360.6
⫺1674.9
⫺1379.1
⫺1228.0
⫺1208.1
1386.6
⫺181.5
⫺2403.58
⫺1752.7
⫺3135.41
⌬fG⬚
kJ · mol⫺1
267.4
⫺669.4
⫺816.4
⫺647.7
⫺635.21
⫺201.4
⫺180.8
⫺315.9
⫺226.4
⫺300.2
⫺228.7
⫺473.6
⫺156.5
⫺822.7
⫺822.2
⫺1465.3
⫺531.8
⫺518.8
⫺92.0
0
⫺553.54
⫺1292.35
⫺3063.1
⫺1924.1
⫺3167.1
⫺663.6
⫺761.5
⫺64.9
⫺748.8
⫺816.05
S⬚
J · deg⫺1 · mol⫺1
115.1
92.5
100
77.4
⫺100.8
161.1
149.4
326
336.4
219.7
54.8(15)
96.0
64.9
123.0
⫺53.1
229.65(40)
164.4
⫺19.3
100.0
41.59(40)
154.887(4)
⫺56.2(10)
120.1
226
104.85
134.7
130.0
111.7
69.96
108.4
59.8
top of rh
base of rh
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
80.0
43.4
55.5
99.6
213.3
25.9
103.98
157.9
75.04
62.72
72.9
738
⫺1129.1
⫺1128.2
⫺1081.4
91.7
88.0
⫺110.0
83.5
82.3
⫺1514.0
⫺1277.4
⫺1175.6
⫺1111.2
156.5
134
68.6
⫺80.8
152.8
⫺142.5
⫺2154.75
41.4
189.45
⫺2814.33
127.6
67.0
41.0
197.07
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.88
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
Ca(H2PO4)2 · H2O
CaI2
std. state
Ca(IO3)2
Ca[Mg(CO3)2] dolomite
CaMoO4
Ca3N2
Ca(NO2)2
Ca(NO3)2
std. state
CaO
Ca(OH)2
Ca3P2
Ca3(PO4)2
Ca2P2O7
Ca10(PO4)6F2
fluoroapatite
CaS
CaSe
CaSiO3
Ca2SiO4
3CaO · SiO2
CaSO3 · 2H2O
CaSO4
CaSO4 · 1⁄2H2O
CaSO4 · 2H2O
Ca(VO3)2
CaWO4
Carbon
C graphite
diamond
CN⫺
(CN)2 cyanogen
CNBr
CNCl
CNF
CNI
CNN3 cyanogen azide
OCN⫺
CO
CO2
undissoc; std. state
CO23⫺
C3O2 suboxide
COBr2
COCl2 phosgene
COClF
COF2
Physical
State
⌬fH⬚
kJ · mol⫺1
⌬fG⬚
kJ · mol⫺1
c
c
aq
c
c
c
c
c
c
aq
c
c
c
c
c
c
⫺3409.67
⫺533.5
⫺653.2
⫺1002.5
⫺2326.3
⫺1541.4
⫺439.3
⫺741.4
⫺938.2
⫺957.55
⫺634.92(90)
⫺985.2
⫺506
⫺4120.8
⫺3338.8
⫺13,744
⫺3058.42
⫺528.9
⫺656.7
⫺839.3
⫺2163.6
⫺1434.7
c
c
c
c
c
c
c
aq
c
c
c
c
c
g
c
aq
g
g
g
g
c
g
c
aq
g
g
aq
aq
g
g
g
g
g
⫺482.4
⫺368.2
⫺1634.9
⫺2307.5
⫺2929.2
⫺1752.7
⫺1425.2
⫺1451.1
⫺1576.7
⫺2022.6
⫺2329.3
⫺1645.15
0
716.68(45)
1.897
150.6
306.7
186.2
137.95
⫺742.8
⫺776.22
⫺603.3
⫺897.5
⫺3884.8
⫺3132.1
⫺12,983
⫺477.4
⫺363.2
⫺1549.7
⫺2192.8
⫺2784.0
⫺1555.2
⫺1309.1
⫺1298.1
⫺1436.8
⫺1797.5
⫺2169.7
⫺1538.50
0
2.900
172.4
297.2
165.3
131.02
166.2
225.5
387.4
⫺146.0
⫺110.53(17)
⫺393.51(13)
⫺413.26(20)
⫺675.23(25)
⫺93.7
⫺96.2
⫺219.1
185.0
196.6
⫺97.4
⫺137.16
394.39
⫺386.0
⫺527.9
⫺109.8
⫺110.9
⫺204.9
⫺639.8
⫺623.33
S⬚
J · deg⫺1 · mol⫺1
C⬚p
J · deg⫺1 · mol⫺1
259.8
142.0
169.5
230
155.18
122.6
105.0
258.82
77.16
193.3
239.7
38.1(4)
83.4
149.37
236.0
189.24
775.7
227.8
187.8
751.9
56.5
67
81.92
127.7
168.6
184
108.4
⫺33.1
130.5
194.1
179.1
126.40
47.4
5.74(10)
158.100(3)
2.377
94.1
241.9
248.36
236.2
224.7
96.2
256.8
106.7
197.660(4)
213.785(10)
119.36(60)
⫺50.0(10)
276.4
309.1
283.50
276.7
258.89
cap height
base of text
157.53
114.3
113.0
42.0
87.5
85.27
128.8
171.9
178.7
99.0
119.4
186.0
166.8
114.14
8.517
6.116
56.9
46.9
45.0
41.8
48.3
29.14
37.13
67.0
61.8
57.70
52.4
46.8
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.89
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
COS carbonyl sulfide
CS2
CTe2
Cerium
Ce ␥, fcc
Ce3⫹ std. state
Ce4⫹ std. state
CeCl3
std. state
CeF3
CeI3
Ce(NO3)3
CeO2
Ce2O3
CeS
Ce2(SO4)3
std. state
Ce2(SO4)3 · 8H2O
Cesium
Cs
Cs⫹ std. state
Cs acetate
CsBO2
CsBr
std. state
CsCl
std. state
CsClO4
Cs2CO3
std. state
CsF
std. state
Cs formate
CsHCO3
CsHF
CsHSO4
CsI
std. state
CsIO3
CsNO3
std. state
Cs2O
CsOH
std. state
Cs2PtCl6 std. state
Cs2S
Cs2Se
Physical
State
⌬fH⬚
kJ · mol⫺1
⌬fG⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
g
lq
g
lq
⫺142.0
89.0
117.7
164.8
⫺166.9
67.1
237.8
c
aq
aq
c
aq
c
c
c
c
c
c
c
aq
c
0
⫺696.2
⫺537.2
⫺1060.5
⫺1197.5
⫺1635.9
⫺669.3
⫺1225.9
⫺1088.7
⫺1796.2
⫺459.4
⫺3954.3
⫺4176.9
⫺5522.9
0
⫺672.0
⫺503.8
⫺984.8
⫺1065.7
⫺1556
⫺674
72.0
⫺205.0
⫺301.0
151.0
⫺38.0
115.1
209
c
lq
g
aq
aq
c
c
aq
c
aq
c
c
aq
c
aq
aq
c
c
c
aq
c
aq
c
c
aq
c
c
aq
aq
aq
aq
0
2.087
76.5(10)
⫺258.00(50)
⫺744.3
⫺972.0
⫺405.8
⫺379.8
⫺442.8
⫺425.4
⫺443.1
⫺1139.7
⫺1193.7
⫺553.5
⫺590.9
⫺683.8
⫺966.1
⫺923.8
⫺1158.1
⫺1145.6
⫺346.6
⫺313.5
⫺525.9
⫺506.0
⫺465.6
⫺345.8
⫺417.2
⫺488.3
⫺1184.9
⫺483.7
⫺1024.7
⫺1706.2
⫺451.5
⫺3652.6
⫺5607.4
0
0.025
⫺292.0
⫺661.3
⫺915.0
⫺391.4
⫺396.0
414.4
⫺423.3
⫺314.3
⫺1054.4
⫺1111.9
⫺525.5
⫺570.8
⫺643.0
231.56
62.30
150.6
78.2
top of rh
base of rh
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
41.50
74.6
45.4
26.9
87.4
99.3
61.63
114.6
50.0
⫺318
85.23(40)
92.1
175.601(3)
132.1(5)
219.7
104.4
113.05
215.5
101.18
189.4
175.1
204.5
209.2
92.8
119.2
226.0
⫺858.9
135.2
⫺1047.9
⫺340.6
⫺343.6
⫺433.9
⫺406.6
⫺403.3
⫺308.2
370.7
⫺449.3
⫺1066.9
⫺498.3
454.8
264.8
123.1
244.4
155.2
279.5
146.9
98.7
122.3
485.8
251.0
32.20
32.4
⫺10.5
80.6
52.93
52.44
⫺146.9
108.3
123.9
51.1
87.3
52.8
⫺152.7
167
⫺99.2
76.0
67.9
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.90
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
Cs2SO4
std. state
Chlorine
Cl atomic
Cl⫺ std. state
Cl2
ClF
ClF3
ClF5
ClO
ClO⫺ std. state
ClO2
ClO⫺2 std. state
ClO⫺3 std. state
ClO3F perchloryl fluoride
ClO⫺4 std. state
Cl2O
Cl2O7
Chromium
Cr
Cr2⫹ std. state
CrBr2
CrCl2
CrCl3
Cr(CO)6 hexacarbonyl
CrF2
CrF3
Cr2FeO4
CrI2
CrI3
CrN
CrO2
Cr2O3
Cr3O4
CrO2Cl2
CrO24⫺ std. state
HCrO⫺4 std. state
Cr2O72⫺ std. state
Cr2(SO4)3
Cobalt
Co
Co2⫹ std. state
Co3⫹ std. state
CoBr2
std. state
CoCl2
std. state
CoCO3
CoF2
CoF3
Physical
State
c
aq
g
aq
g
g
g
g
g
aq
g
aq
aq
g
aq
g
lq
g
⌬fH⬚
kJ · mol⫺1
⫺1443.0
⫺1425.8
121.301(8)
⫺167.08(10)
0
⫺50.3
⫺163.2
⫺239
101.8
⫺107.1
102.5
⫺66.5
⫺104.0
⫺23.8
⫺128.10(40)
80.3
238.1
1138
c
aq
c
c
c
c
c
c
c
c
c
c
c
c
c
g
aq
aq
aq
c
0
⫺143.5
⫺302.1
⫺395.4
⫺556.5
⫺1077.8
⫺778.0
⫺1159
⫺1444.7
⫺156.9
⫺205.0
⫺117
⫺598.0
⫺1140
⫺1131.0
⫺538.1
⫺881.15
⫺878.22
⫺1490.3
⫺609.6
c
aq
aq
c
aq
c
aq
c
c
c
0
⫺58.2
92
⫺220.9
⫺301.3
⫺312.5
⫺392.5
⫺713.0
⫺692
⫺790
⌬fG⬚
kJ · mol⫺1
⫺1323.6
⫺1328.6
⫺131.3
0
⫺51.84
⫺123.0
⫺147
98.1
⫺36.8
120.5
17.2
⫺8.0
48.2
⫺8.62
97.9
0
S⬚
J · deg⫺1 · mol⫺1
211.9
286.2
165.190(4)
56.60(20)
233.08(10)
217.9
281.6
310.74
226.6
41.8
256.8
101.3
162.3
279.0
184.0(15)
266.2
C⬚p
J · deg⫺1 · mol⫺1
134.9
⫺136.4
33.95
32.08
63.85
97.17
31.5
42.00
64.9
45.4
23.8
23.43
⫺356.0
⫺486.1
115.3
123.0
293.01
71.2
91.8
226.23
⫺1088
⫺1343.8
93.9
146.0
78.7
133.6
38
52.7
⫺93
cap height
base of text
⫺1058.1
81.2
118.7
⫺501.6
⫺727.85
⫺764.84
⫺1301.2
329.8
50.21
184.1
261.9
269.9
84.5
302.6
0
⫺54.4
134
30.0
⫺113
⫺305
24.8
⫺262.3
⫺269.8
⫺316.7
50
109.2
0
78.49
82.4
95
68.9
92
79.5
⫺647
⫺719
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.91
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
CoI2
Co(NH3)62⫹ std. state
Co(NH3)63⫹ std. state
Co(NO3)2
std. state
CoO
Co3O4
Co(OH)2
CoS
Co2S3
CoSO4
std. state
CoSO4 · 7H2O
Copper
Cu
Cu⫹ std. state
Cu2⫹ std. state
Cu(OAc)2 acetate
std. state
Cu3(AsO4)2 std. state
CuBr
CuBr2
CuCl
CuCl2
Cu(ClO4)2 std. state
CuCN
CuCNS std. state
Cu(CNS)2 std. state
CuF
CuF2
Cu(formate)2
CuI
Cu(NH3)42⫹ std. state
Cu(NO3)2
std. state
CuO
Cu2O
Cu(OH)2
CuS
Cu2S
CuSe
Cu2Se
CuSO4
std. state
CuSO4 · 5H2O
CuWO4
Dysprosium
Dy
Dy3⫹ std. state
Physical
State
⌬fH⬚
kJ · mol⫺1
⫺88.7
⫺168.6
⫺584.9
c
aq
aq
aq
c
aq
c
c
c
c
c
c
aq
c
⫺420.5
⫺472.8
⫺237.7
⫺891
⫺539.7
⫺82.8
⫺147.3
⫺888.3
⫺967.3
⫺2979.93
c
g
aq
aq
c
aq
aq
c
c
c
c
aq
c
aq
aq
c
c
aq
c
aq
c
aq
c
c
c
c
c
c
c
c
aq
c
c
0
337.4(12)
71.67
64.9(10)
⫺893.3
⫺907.25
⫺1581.97
⫺104.6
⫺141.84
⫺137.2
⫺220.1
⫺193.89
95.0
138.11
217.65
⫺280
⫺542.7
⫺786.34
67.8
⫺348.5
⫺302.9
⫺349.95
⫺157.3
⫺168.6
⫺450
⫺53.1
⫺79.5
⫺39.5
⫺59.4
⫺771.4(12)
⫺844.50
⫺2279.65
⫺1105.0
c
aq
0
⫺699.0
⌬fG⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
⫺157.7
⫺157.3
⫺189.5
109.0
146
⫺277.0
⫺214.0
⫺774
⫺454.4
180
53.0
102.5
79.0
⫺782.4
⫺799.1
⫺2473.83
118.0
⫺92.0
406.06
0
50.00
65.52
⫺673.29
⫺1100.48
⫺100.8
33.15(8)
166.398(4)
40.6
⫺98.(4)
73.6
⫺804.2
96.2
⫺119.9
⫺175.7
48.28
108.4
142.67
250.87
⫺260
⫺492
⫺636.4
⫺69.5
⫺111.3
86.2
108.09
264.4
90.00
184.93
189.1
64.9
77.45
84
96.7
273.6
⫺157.15
⫺129.7
⫺149.0
⫺373
⫺53.7
⫺86.2
193.3
42.6
93.1
108.4
66.5
120.9
⫺662.2
⫺679.11
⫺1880.04
0
⫺665.0
157.3
109.2(4)
⫺79.5
300.4
75.6
⫺231.0
top of rh
base of rh
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
55.3
123.4
103
390.49
24.44
54.7
48.5
71.88
61.04
51.9
65.55
54.1
42.2
63.6
95.19
47.8
76.3
88.70
98.87
280
27.7
21.0
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.92
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
DyCl3
DyF3
Dy2O3
Erbium
Er
Er3⫹ std. state
ErCl3
Er2O3
Europium
Eu
Eu2⫹ std. state
Eu3⫹
EuCl2
EuCl3
EuF3
Eu2O3 monoclinic
Eu3O4
Eu(OH)3
Fluorine
F atomic
F⫺
F2
FNO3
FO
F2O
F2O2
Francium
Fr
FrCl
Fr2O
Gadolinium
Gd
Gd3⫹ std. state
GdCl3
std. state
GdF3
Gd2O3 monoclinic
Gallium
Ga
Ga3⫹
GaAs
GaBr3
GaCl3
GaF3
GaI3
Ga2O3 rhombic
Physical
State
⌬fH⬚
kJ · mol⫺1
c
aq
c
c
⫺1000
⫺1197.0
⫺1711.0
⫺1863.1
c
aq
c
aq
c
0
⫺705.4
⫺998.7
⫺1207.1
⫺1897.9
c
aq
aq
aq
c
aq
c
c
c
c
0
⫺527.0
⫺605.0
⫺862.0
⫺936.0
⫺1106.2
⫺1571
⫺1651.4
⫺2272.0
⫺1332
g
aq
g
g
g
g
g
79.38(30)
⫺335.35(65)
0
10.5
109.0
24.7
18.0
c
c
c
0
⫺439
⫺338
c
aq
c
aq
lq
c
0
⫺686.0
⫺1008.0
⫺1188.0
⫺1297
⫺1819.6
c
lq
g
aq
c
c
c
c
c
c
0
5.6
272.0
⫺211.7
⫺71.0
⫺386.6
⫺524.7
⫺1163.0
⫺238.9
⫺1089.1
⌬fG⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
⫺1059.0
⫺61.9
⫺1771.5
149.8
0
⫺669.1
73.18
⫺244.3
⫺1062.7
⫺1808.7
⫺75.3
155.6
0
540.2
⫺574.0
77.78
⫺8.0
⫺222.0
⫺856
⫺967.7
144.1
⫺54.0
⫺1556.9
⫺2142.0
⫺1195
146
205.0
119.9
62.3
⫺278.8
0
73.7
105.0
41.9
0
158.751(4)
⫺13.8(8)
202.791(5)
292.9
216.8
247.4
C⬚p
J · deg⫺1 · mol⫺1
100.0
⫺389.0
116.27
28.12
21.0
100.0
⫺389.0
108.49
27.66
8.0
⫺402.0
122.2
22.7
⫺106.7
31.30
65.22
30.5
43.3
31.80
53.56
299.2
95.40
113.0
156.9
0
⫺661.0
⫺933
⫺1059.0
68.07
⫺205.9
151.4
⫺36.8
37.03
⫺1730
150.6
0
40.8
233.7
⫺159.0
⫺67.8
⫺359.8
⫺454.8
⫺1085.3
⫺998.3
169.0
⫺331.0
64.2
180.0
142.0
84
205.0
84.98
cap height
base of text
88.0
⫺410.0
106.7
26.06
25.3
46.2
100
92.1
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.93
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
Ga(OH)3
GaSb
Germanium
Ge
GeBr4
GeCl4
GeF4
GeH4
GeI4
GeO2 tetragonal
GeP
GeS
Gold
Au
AuBr
AuBr3
AuCl
AuCl3
AuCl⫺4 std. state
Au(CN)⫺2 std. state
AuF3
AuSb2
AuSn
Hafnium
Hf hexagonal
HfC
HfCl4
HfF4 monoclinic
HfO2
Helium
He
Holmium
Ho
Ho3⫹ std. state
HoCl3
std. state
HoF3
Ho2O3
Hydrogen
H atomic
H⫹ std. state
H2
H2H
2
H2 (D2) deuterium
HAsO⫺2 undissoc;
std. state
Physical
State
c
c
c
g
lq
g
lq
g
g
g
c
g
c
c
c
c
c
c
c
c
aq
aq
c
c
c
c
c
c
c
c
g
c
aq
c
aq
c
c
g
aq
g
g
g
aq
⌬fH⬚
kJ · mol⫺1
⫺964.4
⫺41.8
0
372.0(30)
⫺347.7
⫺300.0
⫺531.8
⫺495.8
⫺1190.20(50)
90.8
⫺141.8
⫺56.9
⫺580.0(10)
⫺21.0
⫺69.0
0
⫺14.0
⫺53.3
⫺34.7
⫺117.6
⫺322.2
242.3
⫺363.6
⫺19.46
⫺30.5
0
⫺230.1
⫺990.4
⫺1930.5
⫺1144.7
0
0
⫺705.0
⫺1005.4
⫺1206.7
⫺1707.0
⫺1880.7
217.998(6)
0
0
0.321
0
⫺456.5
⌬fG⬚
kJ · mol⫺1
⫺831.3
⫺38.9
0
331.2
⫺331.4
⫺318.0
⫺462.8
⫺457.3
⫺1150.0
113.4
⫺144.4
⫺106.3
⫺521.4
⫺17.0
⫺71.6
0
⫺237.32
285.8
0
⫺901.3
⫺1830.5
⫺1088.2
0
S⬚
J · deg⫺1 · mol⫺1
100.0
76.07
31.09(15)
167.904(5)
280.8
396.2
245.6
347.7
301.9(10)
217.02
271.1
428.9
39.71(15)
63.0
71
48.53
23.3
30.7
101.8
96.1
81.84
45.02
104.1
52.1
25.36
92.9
148.1
266.9
172
114.2
119.2
93.7
48.74
94.81
43.56
41.21
190.8
113
59.3
25.69
34.43
120.46
91.29
77.40
49.41
60.25
20.786
0
⫺673.7
75.3
226.8
⫺1067.3
⫺57.7
27.15
17.0
88
⫺393.0
⫺1791.2
158.2
115.0
203.3
0
0
⫺1.463
0
⫺402.71
114.717(2)
0
130.680(3)
143.80
144.96
125.9
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
47.4
126.153(2)
top of rh
base of rh
20.8
0
28.84
29.20
29.19
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.94
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
H2AsO⫺3 undissoc; std.
state
H3AsO3 undissoc; std.
state
HAsO24⫺ undissoc; std. state
H2AsO⫺4 undissoc; std.
state
H3AsO3
undissoc; std. state
HBO2
H3BO3
undissoc
HBr
std. state
HBrO undissoc; std. state
HBrO3 std. state
HCl
std. state
2
HCl deuterium chloride
HClO
undissoc; std. state
HClO2 undissoc; std. state
HClO3 std. state
HClO4
std. state
HClO4 · H2O
HClO4 · 2H2O
HCN
ionized; std. state
undissoc; std. state
HCNO ionized; std. state
undissoc; std. state
HCNS ionized; std. state
HCOO⫺ formate
CH3COO⫺ acetate
HCO⫺3 std. state
H2CO3 std. state
HC2O⫺4
H2C2O4
C2O24⫺
H2CS3 trithiocarbonic
acid
HF
undissoc; std. state
F⫺
2
HF
HF⫺2 std. state
H2F2 dimer
H2Fe(CN) 26⫺ std. state
Physical
State
⌬fH⬚
kJ · mol⫺1
⌬fG⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
aq
⫺714.79
⫺587.22
110.5
aq
⫺742.2
⫺639.90
195.0
aq
aq
⫺906.34
⫺909.56
⫺714.70
⫺753.29
⫺1.7
117
⫺766.1
⫺723.4
⫺968.9
184
38
89.95(60)
162.4(6)
198.700(4)
82.4
142
161.71
186.902(5)
56.5
192.63
236.7
142
188.3
162.3
c
aq
c
c
aq
g
aq
aq
aq
g
aq
g
g
aq
aq
aq
lq
aq
c
lq
lq
g
aq
aq
aq
aq
aq
aq
aq
aq
aq
aq
c
aq
lq
⫺906.30
⫺902.5
⫺794.3
⫺1094.8(8)
⫺1072.8(8)
⫺36.29(16)
⫺121.55
⫺113.0
⫺67.07
⫺92.31(10)
⫺167.15
⫺93.35
⫺78.7
⫺120.9
⫺51.9
⫺103.97
⫺40.58
⫺129.33
⫺302.21
⫺677.98
108.87
135.1
150.6
107.11
⫺146.0
⫺154.39
76.44
⫺425.6
⫺486.0
⫺689.93(20)
⫺699.65
⫺818.4
⫺821.7
⫺825.1
25.1
g
lq
aq
aq
g
aq
g
aq
⫺273.30(70)
⫺299.78
⫺320.08
⫺332.63
⫺275.5
⫺649.94
⫺572.66
455.6
⫺53.4
⫺103.97
⫺82.4
18.54
⫺95.30
⫺131.25
⫺95.94
⫺66.1
⫺79.9
5.9
⫺8.03
⫺8.62
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
54.4
86.1
29.1
⫺141.8
29.12
⫺136.4
29.17
37.15
182.0
124.93
124.7
172.4
119.66
⫺97.5
⫺117.2
92.68
⫺351.0
⫺369.3
⫺586.85
⫺623.16
⫺698.3
⫺723.7
⫺673.9
27.82
112.84
201.81
94.1
124.7
106.7
144.8
144.4
92.0
86.6
98.4(5)
187.4
149.4
109.8
45.6
233.0
⫺275.4
75.40
⫺296.86
⫺278.8
⫺277.27
⫺578.15
⫺544.51
658.44
173.779(3)
51.67
88.7
⫺13.8
179.70
92.5
238
218
70.63
35.86
⫺40.2
⫺87.9
⫺6.3
91.0
149.8
29.14
⫺106.7
29.14
44.89
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.95
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
HFO
HI
std. state
HIO undissoc; std. state
HIO3
H2MoO4
HN
HN3
H2N
2
H2N2 cis-diazine
HNCO isocyanic acid
HNCS isothiocyanic acid
HNO2
HNO3
std. state
H2N2O2 hyponitrous acid
HO hydroxyl
HO⫺
HO2
HO⫺2 std. state
H2O
1
H2HO
H2O deuterium oxide
H2O2 hydrogen peroxide
2
undissoc; std. state
HOCN undissoc; std. state
OCN⫺ cyanate std. state
HPO3
HPO42⫺ std. state
H2PO⫺4 std. state
HPH2O2 hypophosphorous
acid
H3PO3
H3PO4
ionized; std. state
undissoc; std. state
HP2O73⫺
H2P272⫺
H4P2O7
undissoc; std. state
HReO4
HS
HS⫺ std. state
H2S
undissoc; std. state
Physical
State
⌬fH⬚
kJ · mol⫺1
g
g
aq
aq
c
c
g
lq
g
g
g
g
g
g
lq
g
aq
aq
g
aq
g
aq
c
lq
g
g
g
lq
g
aq
aq
aq
c
aq
aq
98
26.50(10)
⫺55.19
⫺138.1
⫺230.1
⫺1046.0
351.5
264.0
294.1
184.9
207
⫺116.73
127.61
⫺79.5
⫺174.1
⫺133.9
⫺207.36
⫺57.3
39.0
⫺230.015
10.5
⫺160.33
⫺292.72
⫺285.830(40)
⫺241.826(40)
⫺245.37
⫺249.20
⫺187.78
⫺136.3
⫺191.17
⫺154.39
⫺146.02
⫺948.51
⫺1299.0(15)
⫺1302.6(15)
c
c
c
lq
aq
aq
aq
aq
c
aq
c
g
aq
g
aq
⫺604.6
⫺964.4
⫺1284.4
⫺1271.7
⫺1277.4
⫺1288.34
⫺2274.8
⫺2278.6
⫺2241.0
⫺2268.6
⫺762.3
142.7
⫺16.3(15)
⫺20.6(5)
⫺38.6(15)
⌬fG⬚
kJ · mol⫺1
⫺86
1.7
⫺51.59
⫺99.2
345.6
327.2
328.1
194.6
241
⫺107.36
112.88
⫺46.0
⫺80.7
⫺73.54
⫺111.34
36.0
34.2
⫺157.28
22.6
67.4
⫺237.14
⫺228.61
⫺233.18
⫺234.54
⫺120.42
⫺105.6
⫺134.10
⫺117.2
⫺97.5
⫺1089.26
⫺1130.39
S⬚
J · deg⫺1 · mol⫺1
226.8
206.590(4)
111.3
95.4
181.2
140.6
239.0
195.0
224.09
238.11
248.03
254.1
155.60
266.9
146.4
218
183.64
⫺10.90
229.0
23.9
69.95(3)
188.835(10)
199.51
198.33
109.6
232.7
143.9
144.8
106.7
top of rh
base of rh
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
35.93
29.16
⫺142.3
29.2
43.7
33.9
39.02
44.85
46.40
45.5
109.9
54.1
⫺86.6
30.00
⫺148.5
34.9
37.11
75.35
33.60
33.79
34.25
89.1
43.14
⫺33.5(15)
92.5(15)
⫺1124.3
⫺1123.6
⫺1018.8
⫺1142.65
⫺1972.2
⫺2010.2
110.5
150.8
222
158.2
46.0
163.0
⫺2032.2
⫺656.4
113.3
12.05
⫺33.4
⫺27.87
268
158.2
195.7
67.(5)
205.81(5)
126.(5)
106.1
145.06
32.3
34.19
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.96
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
2H S
2
H2S2
HSbO2 undissoc; std. state
HSCN undissoc; std. state
SCN⫺ std. state
HSe⫺ std. state
H2Se
HSeO⫺3 std. state
H2SeO3
undissoc; std. state
HSeO⫺4 std. state
H2SeO4
H2SiO3
undissoc; std. state
H4SiO4
undissoc; std. state
HSO⫺3 std. state
HSO⫺4
HSO3Cl
HSO3F
H2SO3 undissoc; std. state
H2SO4
std. state
H2SO4 · H2O
H2SO4 · 2H2O
H2SO4 · 3H2O
H2SO4 · 4H2O
H2S2O7
H2Te
H2WO4
Indium
In
In3⫹
InAs
InBr3
InCl3
InF
InH
InI
InI3
InOH2⫹
In(OH)⫹2
In2O3
InP
InS
In2S3
In2Se3
InSb
Iodine
I atomic
Physical
State
⌬fH⬚
kJ · mol⫺1
g
g
aq
aq
aq
aq
g
aq
c
aq
aq
c
c
aq
c
aq
aq
aq
lq
lq
g
aq
lq
aq
lq
lq
lq
lq
c
g
c
⫺23.9
15.5
⫺487.9
76.4
76.44
15.9
29.7
⫺514.55
⫺524.46
⫺507.48
⫺581.6
⫺530.1
⫺1188.67
⫺1182.8
⫺1481.1
⫺1468.6
⫺626.22
⫺886.9(10)
⫺601.2
⫺795.0
⫺753
⫺608.81
⫺814.0
⫺909.27
⫺1127.6
⫺1427.1
⫺1720.4
⫺2011.2
⫺1273.6
99.6
⫺1131.8
c
aq
c
c
c
g
g
c
c
aq
aq
c
c
c
c
c
c
g
0
⫺105.0
⫺58.6
⫺428.9
⫺537.2
⫺203.4
215.5
⫺116.3
⫺238.0
⫺370.3
⫺619.0
⫺925.27
⫺88.7
⫺138.1
⫺427
⫺343
⫺30.5
106.76(4)
⌬fG⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
⫺35.3
215.3
⫺407.5
97.7
92.68
43.9
15.9
⫺411.54
46.6
144.3
144.5
79.0
219.0
135.1
⫺426.22
⫺452.3
207.9
149.4
C⬚p
J · deg⫺1 · mol⫺1
35.76
51.5
⫺40.2
⫺40.2
34.7
⫺1092.4
⫺1079.5
⫺1333.0
⫺1316.7
⫺527.8
⫺755.9
134.0
109
192
180
139.8
131.7(30)
⫺691
⫺537.90
⫺689.9
⫺744.63
⫺950.3
⫺1199.6
⫺1443.9
⫺1685.8
297
232.2
156.90
20.1
211.5
276.4
345.4
414.5
138.9
293
214.3
261.5
319.1
386.4
⫺1003.9
228.9
145
35.56
113
0
⫺98.0
⫺53.6
57.8
⫺151.0
75.7
26.7
190.3
⫺120.5
⫺313.0
⫺525.0
⫺830.73
⫺77.0
⫺131.8
⫺412.5
⫺25.5
70.2
207.53
130.0
⫺84.0
75.24
47.78
29.58
⫺88.0
25.0
104.2
59.8
67
163.6
118.0
86.2
49.5
180.787(4)
cap height
base of text
92
45.44
20.8
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.97
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
I⫺ std. state
I2
std. state
I⫺3 std. state
IBr
ICl
ICl3
IF
IF5
IF7
IO
IO⫺ std. state
IO⫺3 std. state
IO⫺4 std. state
I2O5
Iridium
Ir
IrCl3
IrF6
IrO2
IrS2
Iron
Fe alpha
Fe2⫹ std. state
Fe3⫹ std. state
FeBr2
std. state
FeBr3
Fe3C ␣-cementite
FeCl2
FeCl3
std. state
Fe(CN)36⫺ std. state
Fe(CN)46⫺ std. state
FeCNS2⫹ std. state
FeCO3
Fe(CO)5
FeCr2O4
FeF2
std. state
FeF3
FeI2
std. state
Physical
State
⌬fH⬚
kJ · mol⫺1
⌬fG⬚
kJ · mol⫺1
aq
c
g
aq
aq
c
g
c
lq
g
c
g
lq
g
g
g
aq
aq
aq
c
⫺56.78(5)
0
62.42(8)
22.6
⫺51.5
⫺10.5
40.8
⫺35.4
⫺23.93
17.8
⫺89.5
⫺95.7
⫺864.8
⫺822.5
⫺961.1
175.1
⫺107.5
⫺221.3
⫺151.5
⫺158.07
⫺51.59
0
19.37
16.40
⫺51.5
c
c
c
c
c
0
⫺245.6
⫺579.65
⫺274.1
⫺138.0
c
aq
aq
c
aq
c
aq
c
c
aq
c
aq
aq
aq
aq
c
lq
c
c
aq
c
aq
c
aq
0
⫺89.1
⫺48.5
⫺249.8
⫺332.2
⫺286.2
⫺413.4
25.1
⫺341.8
⫺423.4
⫺399.4
⫺550.2
561.9
455.6
23.4
⫺740.6
⫺774.0
⫺1446.0
⫺711.3
⫺754.4
⫺1042
⫺1046.4
⫺113.0
⫺199.6
S⬚
J · deg⫺1 · mol⫺1
106.45(30)
116.14(30)
260.687(5)
137.2
239.3
⫺142.3
54.44
36.86
258.8
97.93
135.1
247.6
167.4
236.3
⫺751.5
⫺835.8
149.8
⫺38.5
⫺128.0
⫺58.6
327.7
347.7
245.5
⫺5.4
118.4
222
0
180
⫺461.66
35.48
113
247.7
57.3
25.06
27.32
⫺137.7
⫺315.9
140.7
27.2
25.09
⫺316.7
20.1
⫺302.3
⫺341.3
⫺333.9
⫺398.3
729.3
694.9
71.1
⫺666.7
⫺705.3
⫺1343.9
⫺668.6
⫺636.5
⫺972
⫺840.9
⫺111.7
⫺182.1
⫺68.6
104.6
118.0
⫺24.7
142.34
⫺146.4
270.3
95.0
⫺130
92.9
338.1
146.2
86.99
⫺165.3
98
⫺357.3
167.4
84.9
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
3.7
⫺14.05
⫺13.6
⫺5.5
⫺22.34
⫺118.5
0
⫺78.87
⫺4.7
⫺238.1
⫺286.81
top of rh
base of rh
36.4
55.23
35.6
33.4
99.2
134.5
32.9
57.32
80.2
105.9
76.7
96.65
82.1
240.6
133.8
68.12
91.0
83.7
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.98
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
FeI3
FeMoO4
Fe2N
Fe(NO3)3 std. state
FeO
Fe2O3 hematite
Fe3O4 magnetite
FeOH⫹ std. state
Fe(OH)2⫹ std. state
Fe(OH)2
Fe(OH)3
FeS
FeS2 marcasite
FeS2 pyrite
FeSiO3
Fe2SiO4
FeSO4
std. state
Fe2(SO4)3
std. state
FeTiO3
FeWO4
Krypton
Kr
Lanthanum
La
La3⫹
LaCl3
std. state
LaCl3 · 7H2O
LaI3
La(NO3)3
std. state
La2O3
La2(SO4)3
La2Te3
Lead
Pb
Pb2⫹
Pb(OAc)2
Pb(BO2)2
PbB4O7
PbBr2
Pb(CH3)4
Pb(C2H5)4
PbCl2
PbCl4
PbClF
Physical
State
aq
c
c
aq
c
c
c
aq
aq
c
c
c
c
c
c
c
c
aq
c
aq
c
c
g
⌬fH⬚
kJ · mol⫺1
⫺214.2
⫺1075.0
⫺3.8
⫺670.7
⫺272.0
⫺824.2
⫺1118.4
⫺324.7
⫺290.8
⫺574.0
⫺833
⫺100.0
⫺167.4
⫺178.2
⫺1155
⫺1479.9
⫺928.4
⫺998.3
⫺2583.0
⫺2825.0
⫺1246.4
⫺1155.0
0
c
aq
c
aq
c
c
c
aq
c
c
c
0
⫺707.1
⫺1072.2
⫺1208.8
⫺3178.6
⫺668.9
⫺1254.4
⫺1329.3
⫺1793.7
⫺3941.3
⫺724
c
g
aq
c
c
c
c
aq
lq
lq
c
aq
lq
c
0
195.2(8)
0.92(25)
⫺964.4
⫺1556
⫺2858
⫺278.7
⫺244.8
97.9
52.7
⫺359.4
⫺336.0
⫺329.3
⫺534.7
⌬fG⬚
kJ · mol⫺1
⫺159.4
⫺975.0
⫺338.5
⫺251.4
⫺742.2
⫺1015.4
⫺277.4
⫺229.4
⫺490.0
⫺705
⫺100.4
⫺156.1
⫺166.9
⫺1379.0
⫺820.8
⫺823.4
⫺2262.7
⫺2243.0
⫺1054.0
0
0
683.7
⫺1077.4
⫺2713.3
⫺1705.8
⫺714.6
0
162.2
⫺24.4
S⬚
J · deg⫺1 · mol⫺1
18.0
129.3
101.3
123.4
60.75
87.40
145.27
⫺29
⫺142
87.9
104.6
60.32
53.87
52.92
87.5
145.18
107.5
⫺117.6
307.5
⫺571.5
105.9
131.8
164.085(3)
56.9
⫺217.6
144.4
⫺50.0
462.8
127.32
280
231.63
64.80(30)
175.375(5)
18.5(10)
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
118.5
70.0
49.91
103.9
143.4
97.1
101.7
50.52
62.39
62.12
89.4
132.9
100.6
264.8
99.5
114.4
20.786
27.11
⫺13.0
108.8
⫺423.0
431.0
108.78
132.13
26.84
20.8
⫺1450
⫺2667
⫺261.9
⫺232.3
131
167
161.5
175.3
107.1
168
80.1
⫺314.1
⫺286.9
464.6
136
123.4
307.4
77.1
⫺488.3
121.8
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.99
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
PbCO3
PbC2O4
PbCrO4
PbF2
PbF4
PbI2
PbMoO4
Pb(N3)2 monoclinic
Pb(NO3)2
PbO litharge
PbO2
Pb3O4
Pb3(PO4)2
PbS
PbSe
PbSeO4
PbSiO3
PbSiO4
Pb2SiO4
PbSO3
PbSO4
PbSO4 · PbO
PbTe
Lithium
Li
Li⫹ std. state
Li3AlF6 cryolite
LiAlH4
LiAlO2
LiBeF3
LiBH4
LiBH4 · tetrahydrofuran
Li2BeF4
LiBO2
Li2B4O7
LiBr
std. state
LiBrO3
std. state
LiCl
LiClO4
std. state
Li2CO3
LiF
std. state
Physical
State
⌬fH⬚
kJ · mol⫺1
⌬fG⬚
kJ · mol⫺1
c
c
c
c
aq
c
c
aq
c
c
c
aq
c
c
c
c
c
c
c
c
c
c
c
c
c
c
⫺699.2
⫺851.4
⫺930.9
⫺664
⫺666.9
⫺941.8
⫺175.5
⫺112.1
⫺1051.9
478.2
⫺451.9
⫺416.3
⫺219.0
⫺277.4
⫺718.4
⫺2595.3
⫺100.4
⫺102.9
⫺609.2
⫺1145.7
⫺2023.8
⫺1363.1
⫺669.9
⫺919.97(40)
⫺1182.0
⫺70.7
⫺625.5
⫺750.2
131.0
146.0
87.40
105.4
⫺617.1
⫺582.0
110.5
⫺17.2
72.3
⫺173.58
⫺127.6
⫺951.4
624.7
174.9
233.0
166.1
148.1
77.4
c
g
aq
c
c
c
c
c
c
c
c
c
c
aq
c
aq
c
aq
c
aq
c
aq
c
aq
0
159.3(10)
⫺278.47(8)
⫺3317
⫺116.3
⫺1188.7
⫺1651.8
⫺190.8
⫺415.5
⫺2274
⫺1032.2
⫺3362
⫺351.2
⫺400.03
⫺346.98
⫺345.56
⫺408.6
⫺445.6
⫺381.0
⫺407.81
⫺1215.9
⫺1234.1
⫺616.0
⫺611.12
⫺246.9
⫺188.9
⫺217.3
⫺601.2
⫺2432.6
⫺98.7
⫺101.7
505.0
⫺1062.1
⫺1909.6
⫺1252.6
⫺813.0
⫺69.5
0
⫺293.30
⫺3152
⫺44.7
⫺1126.3
⫺1576.3
⫺125.0
⫺220.5
⫺2171
⫺976.1
⫺3170
⫺342.00
⫺397.27
⫺274.89
⫺384.4
⫺424.6
⫺254
⫺302.1
⫺1132.12
⫺1114.6
⫺587.7
⫺571.9
S⬚
J · deg⫺1 · mol⫺1
303.3
66.5
68.60
211.3
353.1
91.3
102.5
167.8
109.6
84.01
186.6
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
119.70
45.8
64.6
146.9
256.3
49.4
50.2
90.04
98.66
137.2
148.50(60)
225.06
110.0
103.2
150.16
50.5
29.12(20)
138.782(10)
12.24(15)
238.5
78.7
53.3
89.2
75.9
289
130.6
51.5
156
74.27
95.81
24.8
174.9
59.3
69.9
126
195.4
90.4
⫺29.7
35.66
⫺0.4
top of rh
base of rh
68.6
215.7
83.2
67.78
91.8
82.6
135.3
59.8
183.0
48.91
⫺73.2
48.03
⫺67.8
105
⫺7.5
99.1
41.6
⫺38.1
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.100
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
LiH
LiI
std. state
LiIO3
std. state
Li3N
LiNO2
LiNO3
std. state
Li2O
Li2O2
LiOH
std. state
Li3PO4
Li2SiO3
Li2Si2O5
Li2SO4
std. state
Li2TiO3
Lutetium
Lu
Lu3⫹
LuCl3
std. state
LuI3
Lu2O3
Magnesium
Mg
Mg2⫹ std. state
MgAl2O4
MgBr2
std. state
MgBr2 · 6H2O
MgCl2
std. state
MgCl2 · 6H2O
Mg(ClO4)2
std. state
Mg(ClO4)2 · 6H2O
MgCO3
MgC2O4
std. state
MgF2
Mg2Ge
MgH2
MgI2
std. state
Mg3N2
MgNH4PO4 · 6H2O
Mg(NO3)2
std. state
Physical
State
⌬fH⬚
kJ · mol⫺1
c
c
aq
c
aq
c
c
c
aq
c
c
c
aq
c
c
c
c
aq
c
⫺90.5
⫺270.4
⫺333.67
⫺503.38
⫺499.82
⫺164.6
⫺372.4
⫺483.1
⫺485.9
⫺597.9
⫺634.3
⫺484.9
⫺508.40
⫺2095.8
⫺1648.1
⫺2561
⫺1436.4
⫺1466.2
⫺1670.7
c
aq
c
aq
c
c
0
⫺665.0
⫺945.6
⫺1167.0
⫺548.0
⫺1878.2
c
g
aq
c
c
aq
c
c
aq
c
c
aq
c
c
c
aq
c
c
c
c
aq
c
c
c
aq
0
147.1(8)
⫺467.0(6)
⫺2299
⫺524.3
⫺709.94
⫺2410.0
⫺641.3
⫺801.15
⫺2499.0
⫺568.90
⫺725.51
⫺2445.6
⫺1095.8
⫺1269.0
⫺1292.0
⫺1124.2(12)
⫺108.8
⫺75.3
⫺364.0
⫺577.22
⫺461.1
⫺3681.9
⫺790.65
⫺881.6
⌬fG⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
C⬚p
J · deg⫺1 · mol⫺1
⫺68.45
⫺270.3
⫺344.8
20.04
86.8
124.7
27.96
51.0
⫺73.6
⫺421.33
⫺128.6
⫺302.0
⫺381.1
⫺404.5
⫺561.2
⫺578.9
⫺439
⫺451.9
131.4
62.59
96.0
90.0
160.2
37.6
56.5
42.82
7.1
⫺55.2
75.27
⫺18.0
⫺1557.2
⫺2417
⫺1321.7
⫺1331.2
⫺1579.8
79.8
125.5
115.1
7.3
91.8
99.1
138.1
117.6
⫺155.6
109.9
0
⫺628.0
50.96
⫺264.0
⫺1021.0
⫺96.0
⫺1789.1
0
⫺454.8
⫺2177
⫺503.8
⫺662.8
⫺2056.0
⫺591.8
⫺717.1
⫺2115.0
⫺472.0
⫺1863.1
⫺1012.1
⫺1128.8
1071.1
⫺105.9
⫺35.9
⫺358.2
⫺558.1
⫺400.9
⫺589.5
⫺677.4
109.96
32.67(10)
148.648(3)
⫺137.(4)
89.0
117.2
26.8
397
89.63
⫺25.1
315.1
225.4
520.1
65.7
⫺92.5
57.2(5)
86.48
31.1
129.7
84.5
87.9
164.0
154.8
cap height
base of text
70.6
49.7
26.86
25.0
⫺385.0
101.75
24.87
116.20
73.16
71.38
75.51
61.5
69.54
35.4
74.8
104.5
141.9
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.101
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
Mg(NO3)2 · 6H2O
MgO microcrystal
Mg(OH)2
std. state
Mg3(PO4)2
MgS
MgSeO4
std. state
Mg2Si
MgSiO3 clinoenstatite
Mg2SiO4 forsterite
Mg3Si4O10(OH)2 talc
MgSO3 · 3H2O
MgSO3 · 6H2O
MgSO4
std. state
MgSO4 · H2O kieserite
MgSO4 · 7H2O epsomite
MgTiO3
Mg2TiO4
MgTi2O5
Mg2V2O7 triclinic
MgWO4
Manganese
Mn
Mn2⫹ std. state
MnBr2
std. state
Mn3C
MnCl2
std. state
MnCO3
Mn2(CO)10
MnF2
MnI2
Mn(NO3)2
std. state
MnO
MnO2
Mn2O3
MnO⫺4
MnO24⫺
Mn3O4
Mn3(PO4)2
MnS
MnSe
MnSiO3
MnSiO4
MnSO4
std. state
MnTiO3
Physical
State
⌬fH⬚
kJ · mol⫺1
c
c
c
aq
c
c
c
aq
c
c
c
c
c
c
c
aq
c
c
c
c
c
c
c
⫺2613.3
⫺601.6(3)
⫺924.7
⫺926.8
⫺3780.7
⫺346.0
⫺968.51
⫺1066.1
⫺77.8
⫺1548.9
⫺2174.0
⫺5922.5
⫺1931.8
⫺2817.5
⫺1284.9
⫺1376.1
⫺1602.1
⫺3388.71
⫺1497.6
⫺2164.0
⫺2509
⫺2835.9
⫺1516
c
aq
c
aq
c
c
aq
c
c
c
c
aq
c
aq
c
c
c
aq
aq
c
c
c
c
c
c
c
aq
c
0
⫺220.75
⫺384.9
⫺464.0
⫺4.6
⫺481.3
⫺555.05
⫺894.1
⫺1677.4
⫺795.0
⫺242.7
⫺331.0
⫺576.26
⫺635.6
⫺385.2
⫺520.1
⫺959.0
⫺541.4
⫺653.0
⫺1387.8
⫺3116.7
⫺214.2
⫺106.7
⫺1320.9
⫺1730.5
⫺1065.3
⫺1130.1
⫺1355.6
⌬fG⬚
kJ · mol⫺1
⫺2080.7
⫺569.3
⫺833.7
⫺769.4
⫺3538.8
⫺341.8
S⬚
J · deg⫺1 · mol⫺1
452
26.95(15)
63.24
⫺149.0
189.20
50.3
top of rh
base of rh
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
37.2
77.25
213.47
45.6
⫺896.2
⫺77.1
⫺1462.0
⫺2055.1
⫺5543.0
⫺84.1
81.6
67.8
95.1
260.7
⫺1170.6
⫺1199.5
⫺1428.8
⫺2871.9
⫺1420.1
⫺2048
⫺2369
⫺2645.29
⫺1404
91.6
⫺118.01
126.4
372
111.08
115.0
135.6
200.4
101.2
91.88
129
146.9
203.47
109.1
0
⫺228.1
⫺372
⫺409.2
5.4
⫺440.5
⫺490.8
⫺816.7
32.01
⫺73.6
138.1
26.30
50
75.31
98.7
118.20
38.9
85.8
93.51
72.9
⫺222
81.5
⫺749
92.26
150.6
67.99
75.35
⫺451.0
⫺362.9
⫺465.2
⫺881.2
⫺447.3
⫺500.8
⫺1283.2
218.0
59.8
53.1
110.5
191.2
59
155.6
⫺121.0
45.4
54.1
107.7
⫺82.0
⫺218.4
⫺111.7
⫺1240.6
⫺1632.1
⫺957.42
⫺972.8
78.2
90.8
89.1
163.2
112.1
⫺53.6
105.9
50.0
51.0
86.4
129.9
100.4
⫺243
99.8
67.9
81.9
118.5
321.8
96.5
139.7
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.102
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
Mercury
Hg
Hg2⫹
Hg⫹
HgBr2
Hg2Br2
Hg(CH3)2
Hg(C2H5)2
HgCl2
Hg2Cl2
Hg(CN)2
Hg2CO3
HgC2O4
HgF2
Hg2F2
HgI2
Hg2I2
Hg2(N3)2
HgO
HgS
HgSO4
Hg2SO4
HgTe
Molybdenum
Mo
MoBr3
MoCl4
MoCl5
MoCl6
Mo(CO)6
MoF6
MoO2
MoO3
MoO24⫺ std. state
MoS2
Mo2S3
Neodymium
Nd
Nd3⫹ std. state
NdCl3
std. state
NdF3
Nd(NO3)3
Nd2O3
Neon
Ne
Neptunium
Np
NpF6
NpO2
Physical
State
⌬fH⬚
kJ · mol⫺1
⌬fG⬚
kJ · mol⫺1
lq
g
aq
aq
c
c
lq
lq
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
0
61.38(4)
170.21(20)
166.87(50)
⫺170.7
⫺206.9
59.8
30.1
⫺224.3
⫺265.37(40)
263.6
⫺553.5
⫺678.2
⫺405
⫺485
⫺105.4
⫺121.3
594.1
⫺90.79(12)
⫺58.2
⫺707.5
⫺743.09(40)
⫺42.0
c
c
c
c
c
c
lq
c
c
aq
c
c
0
⫺284
⫺477
⫺527
⫺523
⫺982.8
⫺1585.66
⫺588.9
⫺745.2
⫺997.9
⫺235.1
⫺270.3
0
⫺259
⫺402
⫺423
⫺391
⫺877.8
⫺1473.17
⫺533.0
⫺668.1
⫺836.4
⫺225.9
⫺278.6
c
aq
c
aq
c
c
c
0
⫺696.2
⫺1041.0
⫺1197.9
⫺1657.0
⫺1230.9
⫺1807.9
0
⫺671.5
71.6
⫺206.7
⫺1065.7
⫺37.7
27.5
⫺21
113
⫺431
⫺1720.9
158.6
111.3
0
31.8
S⬚
J · deg⫺1 · mol⫺1
C⬚p
J · deg⫺1 · mol⫺1
⫺153.1
⫺181.1
140.2
75.90(12)
174.971(5)
⫺36.19(80)
65.74(80)
172.0
218.0
209
⫺178.6
⫺210.7
146.0
191.6(8)
⫺468.1
180.0
⫺362
⫺469
⫺101.7
⫺111.1
746.4
⫺58.49
⫺50.6
⫺594
⫺625.8
134.3
161
180.0
233.5
205
70.25(30)
82.4
74.86
100.4
77.75
105.9
200.70(20)
131.96
28.71
175
224
238
255
325.9
259.69
46.3
77.8
27.2
62.57
181.2
24.13
105.4
128
155.6
175
242.3
169.8
56.0
75.0
g
0
0
c
c
c
0
⫺1937
⫺1029
0
⫺979
146.328(3)
cap height
base of text
28.00
20.8
75.3
104.6
73.9
102.0
44.06
48.4
63.56
109.3
20.786
29.46
80.3
66.1
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.103
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
Nickel
Ni
Ni2⫹ std. state
Ni(OAc)2 std. state
NiBr2
NiCl2
std. state
Ni(CN)24⫺ std. state
Ni(CO)4
NiC2O4
NiF2
NiI2
Ni(NO3)2
std. state
NiO
Ni2O3
NiOH⫹
Ni(OH)2
NiS
Ni3S2
NiS2
NiSO4
std. state
NiSO4 · 7H2O
NiWO4
Niobium
Nb
NbBr5
NbC
NbCl5
NbF5
NbI5
NbN
NbO
NbO2
Nb2O5
NbOCl3
Nitrogen
N atomic
N2
N⫺3
NCl3
NF2
NF3
H2NOH
N2F2 cis
trans
Physical
State
⌬fH⬚
kJ · mol⫺1
c
aq
aq
c
aq
c
aq
aq
lq
g
c
c
aq
c
aq
c
aq
c
c
aq
c
c
c
c
c
aq
c
c
0
⫺54.0
⫺1025.9
⫺212.1
⫺297.1
⫺305.3
⫺388.3
367.8
⫺633.0
⫺602.9
⫺856.9
⫺651.5
⫺719.2
⫺78.8
⫺164.4
⫺415.1
⫺468.6
⫺240.6
⫺489.5
⫺287.9
⫺529.7
⫺82.0
⫺216.0
⫺131.4
⫺872.9
⫺963.2
⫺2976.3
⫺1128.4
c
c
c
c
c
c
c
c
c
c
c
0
⫺556
⫺138.9
⫺797.5
⫺1813.8
⫺268.6
⫺236.4
⫺405.8
⫺796.2
⫺1899.5
⫺879.5
g
g
aq
lq
g
g
c
g
g
472.68(40)
0
275.1
230.0
43.1
⫺132.1
⫺114.2
69.5
82.0
⌬fG⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
29.87
⫺128.9
44.4
⫺253.6
⫺259.0
⫺307.9
472.0
⫺588.2
⫺587.2
36.0
97.7
⫺15.1
218
313
410.6
⫺604.2
⫺603.3
73.6
⫺156.5
⫺149.0
93.7
⫺268.6
⫺211.7
164.0
38.00
44.31
⫺227.6
⫺447.3
⫺79.5
⫺210
⫺124.7
⫺759.8
⫺790.3
⫺2462.2
⫺71.0
88.0
53.0
133.9
72
92.0
⫺108.8
378.94
118.0
47.1
117.7
70.6
138.0
327.9
364.59
136.0
0
⫺508
⫺136.8
⫺683.3
⫺1699.0
36.4
258.8
34.98
210.5
160.3
343
34.5
48.1
54.5
137.3
159
24.67
147.9
36.23
148.1
134.7
155.6
39.0
41.3
57.45
132.0
120.0
26.1
71.66
404.6
145.2
64.1
153.301(3)
191.609(4)
107.9
29.124
57.8
⫺90.6
249.9
260.8
41.0
53.37
109
120.5
259.8
262.6
49.96
53.47
0
348.2
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
0
⫺45.6
⫺784.5
⫺205.9
⫺392.6
⫺740.5
⫺1765.8
⫺782
top of rh
base of rh
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.104
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
N2F4
N2H4 hydrazine
N22H4 hydrazine-d4
N2H5⫹ std. state
N2H5Br
std. state
N2H5Cl
std. state
N2H5Cl · HCl
N2H5OH
undissoc; std. state
N2H5NO3
std. state
(N2H5)2SO4
std. state
NO
NOBr
NOCl
NOF
NOF3
NO2
NO⫺2
NO2Cl
NO2F
NO3
NO⫺3
N2O
N2O2
N2O22⫺ hyponitrite
N2O3
N2O4
N2O5
NSF
Osmium
Os
OsCl3
OsCl4
OsF6
OsO4
Oxygen
O atomic
O2
O3
OF2
O2F2
OH⫺
Palladium
Pd
Pd2⫹ std. state
Physical
State
⌬fH⬚
kJ · mol⫺1
g
lq
g
aq
c
aq
c
aq
c
lq
aq
c
aq
c
aq
g
g
g
g
g
g
aq
g
g
g
aq
g
g
aq
g
lq
g
g
g
⫺8.4
50.6
81.6
⫺7.5
⫺155.6
⫺128.9
⫺197.1
⫺174.9
⫺367.4
⫺242.7
⫺251.50
⫺251.58
⫺215.10
⫺959.0
⫺924.7
91.29
82.23
51.71
⫺66.5
⫺163
33.1
⫺104.6
12.6
⫺109
69.41
⫺206.85(40)
81.6
170.37
⫺17.2
86.6
⫺19.5
11.1
11.3
c
c
c
g
c
g
g
g
g
g
g
aq
c
aq
⌬fG⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
301.2
121.2
248.86
151
⫺21.8
233.1
⫺71.6
⫺49.0
207.1
⫺66.1
⫺109.2
207.9
73.2
322
210.76
273.7
261.68
248.02
278.40
240.1
123.0
272.19
260.2
252.5
146.70(40)
220.0
287.52
27.6
314.7
209.20
304.38
355.7
259.8
0
⫺190.4
⫺254.8
0
⫺121
⫺159
⫺394.1
⫺337.2
⫺305.0
⫺292.8
32.6
130
155
358.1
143.9
293.8
24.5
18.0
⫺230.015(40)
0
149.0
231.7
0
142.7
41.8
61.42
⫺157.28
0
176.6
79.2
98.84
55.52
70.3
297
⫺579.9
87.60
82.42
66.10
⫺51.0
⫺96
51.3
⫺32.2
54.4
⫺66
114.35
⫺111.3
103.7
202.88
138.9
142.4
97.5
99.8
117.1
249.18(10)
0
C⬚p
J · deg⫺1 · mol⫺1
79.9
149.3
150.9
82.4
⫺28.91
cap height
base of text
161.059(3)
205.152(5)
163.2
247.5
268.11
⫺10.90(20)
37.61
⫺184.0
⫺151
29.85
45.48
44.7
41.3
67.86
37.2
⫺97.5
53.19
49.8
46.9
⫺86.6
38.62
63.51
72.72
142.71
79.2
95.30
44.1
24.7
120.8
74.1
21.9
29.4
238.92
57.11
54.06
⫺148.5
25.94
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.105
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
PdBr2
PdBr24⫺ std. state
PdCl2
PdCl42⫺ std. state
Pd2H
PdO
PdS
PdS2
Phosphorus
P white
red, V
P2
P4
PBr3
PBr5
PCl3
PCl5
PF3
PF5
PH3
std. state
PH4Br
PH4Cl
PH4I
PH4OH undissoc; std. state
PI3
PO2
PO⫺3
PO34⫺ std. state
P2O74⫺ std. state
(P2O3)2 dimer
P4O10
POBr3
POCl3
POClF2
POCl2F
POF3
PSCl3
PSF3
P4S3
Platinum
Pt
PtBr2
PtBr3
PtBr4
Physical
State
c
aq
c
aq
c
c
c
c
c
g
c
g
g
lq
g
c
lq
g
c
g
g
g
g
aq
c
c
c
aq
c
g
aq
aq
aq
c
c
c
g
lq
g
g
g
g
g
g
c
c
c
c
c
⌬fH⬚
kJ · mol⫺1
⫺104.2
⫺384.9
⫺171.5
⫺550.2
⫺19.7
⫺85.4
⫺75
⫺81.2
0
316.5(10)
⫺17.46
144.0(20)
58.9(3)
⫺184.5
⫺139.3
⫺269.9
⫺319.7
⫺227.1
⫺443.5
⫺374.9
⫺958
⫺1594.4
5.4
⫺9.50
⫺127.6
⫺145.2
⫺69.9
⫺295.35
⫺45.6
⫺279.9
⫺977.0
⫺1277.4
⫺2271.1
⫺1640.1
⫺3009.9
⫺458.6
⫺389.11
⫺597.1
⫺558.5
⫺970.7
⫺765.7
⫺1254.0
⫺363.2
⫺1009
⫺155
0
⫺82.0
⫺120.9
⫺156.5
⌬fG⬚
kJ · mol⫺1
⫺318.0
⫺125.1
⫺416.7
⫺5.0
⫺67
⫺74.5
0
280.1
⫺12.46
S⬚
J · deg⫺1 · mol⫺1
247
105
167
91.6
56.1
46
80
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
31.5
24.4
⫺175.5
⫺162.8
41.09(25)
163.1199(3)
22.85
218.123(4)
280.01(50)
240.2
348.15
⫺272.4
⫺267.8
217.2
311.8
⫺305.0
⫺937
⫺1520.7
13.4
25.31
⫺47.7
364.6
273.1
300.8
210.24
120.1
110.0
112.8
58.69
84.8
37.10
0.8
⫺211.88
123.0
190.0
109.6
⫺281.6
252.1
39.5
⫺1018.8
⫺1919.2
⫺220.5
⫺117.0
⫺2723.3
top of rh
base of rh
23.83
20.8
21.19
67.16
76.02
71.8
228.78
211.71
⫺390.91
⫺520.9
⫺512.9
⫺924.1
⫺721.6
⫺1206
⫺347.7
⫺985
⫺159
⫺359.84
222.46
325.5
301.68
320.38
285.4
337.23
298.1
201
89.87
138.82
84.94
68.83
79.32
68.82
89.83
74.55
146
41.63
25.87
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.106
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
PtCl2
PtCl3
PtCl4
PtCl42⫺
PtCl24⫺ std. state
PtCl26⫺ std. state
PtF6
PtI4
PtS
PtS2
Plutonium
Pu
Pu3⫹
Pu4⫹
PuBr3
PuCl3
PuCl4
PuF3
PuF4
PuF6
PuH2
PuH3
PuI3
PuO
PuO2
Pu2O3 beta
Pu(SO4)2
PuS
Pu2S3
Polonium
Po
PoO2
Potassium
K
K⫹ std. state
KOAc acetate
KAg(CN)2
KAgCl2
K2AgI3
KAlCl4
K3AlCl6
K3AlF6
KAl(SO4)2
K3AsO4 std. state
KBF4
std. state
KBH4
std. state
Physical
State
⌬fH⬚
kJ · mol⫺1
c
c
c
c
aq
aq
g
c
c
c
⫺123.4
⫺182.0
⫺3218
⫺231.8
⫺499.2
⫺668.2
c
aq
aq
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
0
⫺579.9
⫺579.9
⫺831.8
⫺961.5
⫺1381
⫺1552
⫺1732
25.48
⫺139.3
⫺138
⫺648.5
⫺565
⫺1058.1
⫺1715.4
⫺2200.8
⫺439.3
⫺989.5
c
c
c
lq
g
aq
c
aq
aq
aq
aq
c
c
c
c
aq
c
aq
c
aq
⫺72.8
⫺81.6
⫺108.8
0
⫺251
0
2.284
89.0(8)
⫺252.14(8)
⫺723.0
⫺738.39
18.0
⫺497.4
⫺686.6
97
⫺2092.0
⫺3358.1
⫺2470.2
⫺1645.27
⫺1887
⫺1827.2
⫺227.4
⫺204.22
⌬fG⬚
kJ · mol⫺1
⫺134
⫺172
⫺361.5
⫺482.8
⫺76.2
⫺99.6
0
⫺587.9
⫺1490
⫺804.6
⫺892.7
S⬚
J · deg⫺1 · mol⫺1
C⬚p
J · deg⫺1 · mol⫺1
117
151
176
155
220.1
348.3
55.06
74.68
51.5
⫺163
122.8
43.39
65.90
35.5
192.88
159.00
107.86
102.84
⫺1478.8
⫺1644.7
27.2
⫺101.7
⫺82.4
⫺643.9
⫺538.9
⫺1005.8
⫺1632.3
⫺1969.5
⫺436.7
⫺985.5
112.97
161.9
222.59
59.8
64.9
214.2
70.7
82.4
152.3
163.18
78.24
192.46
96.82
120.8
167.36
39.0
43.2
111.8
51.3
68.6
131.0
181.96
53.97
129.66
0
⫺197
62.8
71
26.4
61.5
0
0.264
⫺283.26
⫺652.66
22.2
⫺498.7
⫺720.5
⫺1094
⫺1938
⫺2240.1
⫺1498.29
⫺1785
⫺1770.3
⫺160.2
⫺168.99
cap height
base of text
64.68(20)
71.46
160.341(3)
101.20(20)
29.60
32.72
189.1
297
333.9
458.1
197
377
284.5
204.47
144.8
133.9
285
106.31
212.97
15.5
21.8
156.4
248.9
221.1
192.92
114.48
96.57
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.107
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
KBO2
std. state
K2B4O7
KBr
std. state
KBrO3
KBrO4
KCl
std. state
KClO std. state
KClO2 std. state
KClO3
std. state
KClO4
std. state
KCN
std. state
K2CO3
std. state
K2C2O4
K2CrO4
std. state
K2Cr2O7
K2CuCl4 · 2H2O
KF
std. state
K3Fe(CN)6
std. state
K4Fe(CN)6
std. state
K formate
std. state
K glycinate
KH
K2HAsO4 std. state
KH2AsO4
std. state
KHCrO4 std. state
KHCO3
std. state
KHC2O4 std. state
KHF2
KHgBr3
std. state
K2HgBr4
std. state
KHgCl3
std. state
Physical
State
c
aq
c
c
aq
c
aq
c
c
aq
aq
aq
c
aq
c
aq
c
aq
c
aq
c
aq
c
aq
c
c
c
aq
c
aq
c
aq
c
aq
aq
c
aq
c
aq
aq
c
aq
aq
c
aq
c
aq
c
aq
c
aq
⌬fH⬚
kJ · mol⫺1
⫺981.6
⫺1024.75
⫺3334.2
⫺393.8
⫺373.92
⫺360.2
⫺319.45
⫺287.86
⫺436.5
⫺419.53
⫺359.4
⫺318.8
⫺397.73
⫺356.35
⫺432.8
⫺381.71
⫺113.1
⫺101.7
⫺1151.0
⫺1181.90
⫺1346.0
⫺1329.72
⫺1403.7
⫺1385.91
⫺2061.5
⫺1707.1
⫺567.2
⫺585.01
⫺249.8
⫺139.4
⫺594.1
⫺554.0
⫺679.73
⫺677.93
⫺722.16
⫺57.72
⫺1411.10
⫺1180.7
⫺1161.94
⫺1130.5
⫺963.2
⫺944.33
⫺1070.7
⫺927.7
⫺902.32
⫺550.20
⫺545.6
⫺963.6
⫺935.5
⫺671.1
⫺641.0
⌬fG⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
⫺923.4
⫺962.19
⫺3136.8
⫺380.7
⫺387.23
⫺271.2
⫺264.72
⫺174.47
⫺408.5
⫺414.51
⫺320.1
⫺266.1
⫺296.31
⫺291.29
⫺303.1
⫺291.88
⫺101.9
⫺110.9
⫺1063.5
⫺1094.41
79.98
65.3
208
95.9
184.9
149.2
264.22
170.01
82.55
159.0
146
203.8
143.1
264.9
151.0
284.5
128.52
196.7
155.5
148.1
⫺1295.8
⫺1294.36
⫺1882.0
⫺1492.9
⫺537.8
⫺562.08
⫺129.7
⫺120.5
⫺453.1
⫺438.11
200.12
255.2
291.2
355.43
66.5
88.7
426.06
577.8
418.8
505.0
⫺634.3
⫺598.23
⫺53.01
⫺1281.22
⫺1036.0
⫺1036.54
⫺1048.1
⫺863.6
⫺870.10
⫺981.7
⫺859.7
⫺861.40
192
221.8
50.21
203.3
155.02
218
286.6
115.5
193.7
251.9
104.3
195.0
⫺542.7
360
⫺937.6
515
⫺592.5
314
top of rh
base of rh
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
66.7
170.5
52.3
⫺120.1
105.2
120.2
51.29
⫺114.6
100.3
112.41
66.3
114.44
145.98
219.2
253.22
48.98
⫺84.9
322.2
⫺66.1
37.91
126.73
76.94
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.108
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
K2Hg(CN)4
std. state
K2HgI4
std. state
KH2PO4
std. state
K2HPO4 std. state
K2H2P2O7
K3HP2O7
KHS
std. state
KHSO3
KHSO4
std. state
KI
KIO3
KIO4
KMnO4
K2MoO4
std. state
KNH2 amide
KNO2
std. state
KNO3
std. state
K2Ni(CN)4 std. state
K2O
KO2
K2O2
KOCN cyanate
std. state
KOH
std. state
K2PdBr4
std. state
K3PO4
std. state
K4P2O7
K2PtBr4
std. state
K2PtBr6
std. state
K2PtCl4
std. state
K2PtCl6
std. state
K2ReCl6
std. state
Physical
State
c
aq
c
aq
c
aq
aq
c
aq
aq
c
aq
aq
c
aq
c
aq
c
aq
c
aq
c
c
aq
c
c
aq
c
aq
aq
c
c
c
c
aq
c
aq
c
aq
c
aq
aq
c
aq
c
aq
c
aq
c
aq
c
aq
⌬fH⬚
kJ · mol⫺1
⫺32.2
21.8
⫺775.0
⫺739.7
⫺1568.33
⫺1548.67
⫺1796.90
⫺2815.8
⫺2783.2
⫺3032.1
⫺265.10
⫺269.9
⫺878.60
⫺1160.6
⫺1139.72
⫺327.9
⫺307.57
⫺510.43
⫺473.6
⫺467.23
⫺403.8
⫺837.2
⫺1498.71
⫺1502.5
⫺128.9
⫺369.82
⫺356.9
⫺494.63
⫺459.74
⫺136.8
⫺361.5
⫺284.9
⫺494.1
⫺418.65
⫺398.3
⫺424.7
⫺482.37
⫺938.1
⫺889.5
⫺1950.2
⫺2034.7
⫺3280.7
⫺915.0
⫺872.8
⫺1021.3
⫺975.3
⫺1054.4
⫺1003.7
⫺1229.3
⫺1171.8
⫺1310.4
⫺1266.92
⌬fG⬚
kJ · mol⫺1
51.9
S⬚
J · deg⫺1 · mol⫺1
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
510
⫺778.2
⫺1415.95
⫺1622.85
⫺1655.78
565
134.85
192.9
171.5
⫺2576.9
⫺2822.1
368
351
⫺271.21
⫺811.07
⫺1131.4
⫺1039.26
⫺324.9
⫺334.85
⫺418.4
⫺411.3
⫺361.41
⫺341.8
⫺737.6
165.3
242.3
138.1
234.3
106.3
213.8
151.46
220.9
175.7
322
171.71
⫺1402.9
232.2
116.57
75.3
⫺306.60
⫺315.5
⫺394.93
⫺394.59
⫺94.6
⫺322.1
⫺239.4
⫺425.1
152.09
225.5
133.05
249.0
423
94.1
122.5
102.0
⫺380.7
⫺378.7
⫺440.53
209.2
78.9
91.6
⫺884.5
452
⫺1868.6
⫺3052.2
87.9
293
⫺828.4
326.4
⫺898.7
368
⫺63.0
52.9
⫺120.5
106.48
117.6
107.40
96.4
⫺64.9
83.7
77.53
110
64.9
⫺126.8
180.2
⫺928.0
⫺1078.6
⫺1049.4
⫺1172.8
⫺1156.0
360
333.9
424.7
371.71
460
205.60
214.68
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.109
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
KReO4
std. state
K2S
std. state
K2S2
KSCN
std. state
K2SeO3
std. state
K2SeO4
std. state
K2SiF6
std. state
K2SiO3
K2SnBr6
K2SnCl6
K2SO3
std. state
K2SO4
K2SO6
std. state
K2S2O3
std. state
K2S2O4
K2S2O7
K2S2O8
std. state
K2S4O6
std. state
KSO3F
K2UO4
KVO4
std. state
K2Zn(CN)4
std. state
Praseodymium
Pr
Pr3⫹ std. state
Pr(OAc)3 std. state
PrCl3
std. state
Pr(NO3)3
Pr2O3
Promethium
PmCl3
Protactinium
Pa
Pa4⫹
PaBr4
PaBr5
Physical
State
⌬fH⬚
kJ · mol⫺1
c
aq
c
aq
c
aq
c
aq
c
aq
c
aq
c
aq
c
c
c
c
aq
c
aq
c
aq
c
aq
aq
c
c
aq
c
aq
c
c
c
aq
c
aq
⫺1097.0
⫺1039.7
⫺380.7
⫺471.5
⫺432.2
⫺474.5
⫺200.16
⫺175.94
⫺979.5
⫺1013.8
⫺1110.02
⫺1103.7
⫺2956.0
⫺2893.7
⫺1548.1
⫺1218.0
⫺1477.0
⫺1125.5
⫺1140.1
⫺1437.8
⫺1414.0
⫺1437.7
⫺1414.02
⫺1173.6
⫺1156.9
⫺1258.1
⫺1986.6
⫺1916.10
⫺1849.3
⫺1780.7
⫺1728.8
⫺1159.0
⫺1921.3
⫺1154.8
⫺1140.6
⫺100.0
⫺162.3
c
aq
aq
c
aq
c
c
0
⫺704.6
⫺2147.52
⫺1056.9
⫺1206.3
⫺1229.3
⫺1809.6
c
⫺1054.0
c
aq
c
c
0
⫺619.2
⫺824.0
⫺862
⌬fG⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
167.82
303.8
105.0
190.4
⫺487.0
⫺178.32
⫺190.58
233.5
124.26
246.9
88.53
⫺18.4
⫺936.4
⫺1002.9
⫺1007.9
⫺2798.7
⫺2766.0
⫺1455.7
⫺1160.2
⫺1333.0
218.0
222
259.0
225.9
327.2
146.1
443.1
366.5
118.4
246.0
246.0
⫺1053.1
⫺1321.4
⫺1311.1
⫺1319.6
⫺1311.14
176
175.6
225.1
175.5
225.1
131.5
⫺251.0
131.3
⫺251
⫺1089.1
⫺1166.9
⫺1791.6
⫺1697.41
⫺1681.6
⫺1613.43
⫺1607.1
272
297
255
278.7
449.4
309.66
462.3
⫺1066.9
155
⫺119.7
431
0
⫺679.1
⫺1805.56
73.2
⫺209.0
164.9
⫺42.0
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
⫺994.5
⫺977.8
⫺364.0
⫺480.7
⫺1072.8
top of rh
base of rh
122.55
8.4
74.7
213.2
230.79
⫺24.3
27.20
⫺29.0
100.0
⫺439.0
117.40
0
⫺787.9
⫺820
51.8
234.0
289
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.110
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
PaCl4
PaCl5
Radium
Ra
Ra2⫹
RaCl2 std. state
Ra(NO3)2
std. state
RaSO4
std. state
Radon
Rn
Rhenium
Re
Re⫺ std. state
ReBr3
ReCl3
ReCl26⫺ std. state
ReO2
ReO3
Re2O7
Rhodium
Rh
RhCl3
Rh2O3
Rubidium
Rb
Rb⫹ std. state
Rb acetate
RbBO2
RbBr
std. state
RbBrO3
Rb2CO3
std. state
RbCl
std. state
RbClO3
std. state
RbClO4
std. state
RbF
std. state
Rb formate
RbHCO3
std. state
RbHF2
std. state
Physical
State
⌬fH⬚
kJ · mol⫺1
⌬fG⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
c
c
⫺1043.1
⫺1144.7
⫺953.0
⫺1034.3
192.0
238.0
c
aq
aq
c
aq
c
aq
0
⫺527.6
⫺861.9
⫺992
⫺942.2
⫺1471.1
⫺1436.8
0
⫺561.5
⫺823.8
⫺796.2
⫺784.1
⫺1365.7
⫺1306.2
71
54.0
167.0
222
347.0
138
75.0
g
0
c
g
aq
c
c
aq
c
c
c
g
0
769.9
46.0
⫺167.0
⫺264
⫺761
⫺423
⫺605.0
⫺1240.1
⫺1100.0
c
c
c
0
⫺299.2
⫺343.0
c
g
aq
aq
c
c
aq
c
c
aq
c
aq
c
aq
c
aq
c
aq
aq
c
aq
c
aq
0
80.9(8)
⫺251.12(10)
⫺737.2
⫺971.0
⫺394.59
⫺372.71
⫺367.27
⫺1136.0
⫺1179.5
⫺435.35
⫺418.32
⫺402.9
⫺355.14
⫺437.19
⫺380.49
⫺557.7
⫺583.79
⫺676.7
⫺963.2
⫺943.16
⫺922.6
⫺901.11
0
C⬚p
J · deg⫺1 · mol⫺1
176.235
20.79
0
724.6
10.1
36.9
188.9
230.0
25.5
20.8
⫺188
⫺590
⫺368
⫺531
⫺1066.1
⫺994.0
123.9
251
172
257.3
207.1
452.0
92.4
0
31.51
110.9
0
53.1
⫺283.97
⫺653.3
⫺913.0
⫺381.79
⫺387.94
⫺278.11
⫺1051.0
⫺1095.8
⫺407.81
⫺415.22
⫺300.4
⫺291.9
⫺306.9
⫺292.59
⫺562.79
⫺635.1
⫺863.6
⫺870.82
⫺855.6
⫺862.11
76.78(30)
170.094(3)
121.75(25)
207.9
94.3
109.96
203.93
161.1
181.33
186.2
95.90
178.0
151.9
283.68
161.1
303.3
75.3
107.53
213.0
121.3
212.71
120.08
213.8
cap height
base of text
166.1
24.98
104.0
31.06
20.8
74.1
52.84
117.61
52.41
103.2
50.5
79.37
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.111
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
RbHSO4
std. state
RbI
std. state
RbNO2
RbNO3
std. state
Rb2O
Rb2O2
RbOH
std. state
Rb2PtCl6
std. state
RbReO4
std. state
Rb2S
Rb2SeO4
std. state
Rb2SO4
std. state
Ruthenium
Ru
RuBr3
RuCl3
RuI3
RuO2
RuO4
Samarium
Sm
Sm3⫹ std. state
SmCl2
SmCl3
std. state
SmF3
SmF3 · 1⁄2H2O
SmI3
Sm(IO3)3
Sm(NO3)2
Sm2O3
Sm2(SO4)3
Scandium
Sc
Sc3⫹ std. state
ScBr3
ScCl3
ScF3
ScOH2⫹
Sc2O3
Physical
State
⌬fH⬚
kJ · mol⫺1
c
aq
c
aq
c
c
aq
c
c
c
aq
c
aq
c
aq
aq
c
aq
c
aq
⫺1159.0
⫺1138.51
⫺333.8
⫺306.35
⫺367.4
⫺495.05
⫺458.52
⫺339
⫺472.0
⫺418.19
⫺481.16
⫺1245.6
⫺1170.7
⫺1102.9
⫺1038.5
⫺469.4
⫺1114.2
⫺1101.7
⫺1435.61
⫺1411.60
c
c
c
c
c
c
lq
0
⫺138.0
⫺205.0
⫺65.7
⫺305.0
⫺239.3
⫺228.5
c
aq
c
c
aq
c
c
0
⫺691.6
⫺815.5
⫺1025.9
⫺1193.3
⫺1778.0
⫺1825.1
c
c
c
c
c
⫺620.1
⫺1381
⫺1212.1
⫺1823.0
⫺3899.1
c
aq
c
c
c
aq
c
0
⫺614.2
⫺743.1
⫺925.1
⫺1629.2
⫺861.5
⫺1908.8
⌬fG⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
⫺1039.98
⫺328.9
⫺335.56
⫺306.2
⫺395.85
⫺395.30
253.1
118.4
232.6
172.0
147.3
267.8
⫺441.24
⫺1109.6
⫺1056.6
⫺996.2
⫺978.6
⫺482.0
110.75
406
464
167
322.6
228.4
⫺1009.2
⫺1316.96
⫺1312.56
297.1
197.44
263.2
134.06
28.53
24.1
0
top of rh
base of rh
53.18
102.1
⫺152.3
⫺152.3
146.4
183.3
0
⫺666.5
69.58
⫺211.7
⫺1060.2
⫺42.7
⫺1734.7
151.0
0
⫺586.6
34.64
⫺255.0
25.52
121.3
92
⫺134.0
76.99
93.64
⫺1555.6
⫺801.2
⫺1819.41
29.54
⫺21
⫺431
114.5
94.2
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.112
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
Selenium
Se
SeBr2
SeCl4
SeF6
SeO
SeO2
SeO3
SeO23⫺ std. state
SeO24⫺
Silicon
Si
SiBr4
SiBrCl3
SiC alpha
beta
SiCl4
SiClBr3
SiClF3
SiF4
SiH4
SiHBr3
SiHCl3
SiHF3
SiH2Cl2
SiH3Cl
SiH3F
Si2H6
SiI4
Si3N4
SiO
SiO2 quartz
high cristobalite
SiOF2
SiS2
Silver
Ag
Ag⫹ std. state
Ag2⫹ in 4M HClO4
AgAt
AgBr
AgBrO3
AgCl
AgClO2
Physical
State
c
g
g
c
g
g
c
c
aq
aq
c
g
lq
g
g
c
c
lq
g
g
g
g
g
g
lq
g
g
g
g
g
g
c
lq
c
g
c
c
g
c
c
g
aq
aq
c
c
c
c
c
⌬fH⬚
kJ · mol⫺1
0
227.1
⫺21.0
⫺188.3
⫺1117.0
53.4
⫺225.4
⫺166.9
⫺509.2
⫺599.2
⌬fG⬚
kJ · mol⫺1
41.97
174.8
24.98
22.1
⫺1017.0
26.8
313.8
234.0
110.5
31.3
⫺369.9
⫺441.4
13
54.0
⫺433.9
⫺431.8
⫺62.8
⫺65.3
⫺686.93
⫺657.0
⫺60.2
⫺62.8
⫺620.0
⫺617.0
⫺1318
⫺1615.0(8)
34.3
⫺317.6
⫺539.3
⫺513.0
⫺1280
⫺1572.7
56.8
⫺328.5
⫺482.5
⫺482.0
0
284.9(8)
105.79(8)
268.6
⫺45.2
⫺100.37
⫺10.5
⫺127.01(5)
8.79
C⬚p
J · deg⫺1 · mol⫺1
0
187.0
0
450.(8)
⫺457.3
⫺415.5
⫺320.5
⫺142
⫺377
80.3
⫺189.5
⫺174.60
⫺743.5
⫺99.6
⫺910.7(10)
⫺905.5
⫺967
⫺213.4
S⬚
J · deg⫺1 · mol⫺1
0
⫺295.0
⫺119
⫺353
127.2
⫺191.6
⫺187.49
⫺642.1
⫺126.4
⫺856.4
⫺853.6
⫺951
⫺212.6
0
77.12
269.0
⫺96.90
71.3
⫺109.8
75.7
18.81(8)
167.981(4)
277.5
377.9
350.1
16.49
16.61
239.7
330.7
377.1
309
282.76(50)
204.65
348.6
227.6
313.7
271.9
285.7
250.8
238.4
272.7
258.1
294.30
101.3
211.6
41.46(20)
50.05
271.3
80.3
42.55(20)
172.997(4)
73.45(40)
⫺88
133.1
107.11
151.9
96.25(20)
134.56
cap height
base of text
20.00
146.4
97.1
90.9
26.76
26.9
145.3
90.26
95.3
79.4
73.62
42.83
80.8
75.8
60.5
60.5
51.10
47.20
80.79
108.0
159.79
99.5
29.9
44.4
26.58
53.69
77.5
25.4
21.8
55.7
52.38
50.79
87.32
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.113
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
AgClO3
AgClO4
std. state
AgCN
Ag(CN)⫺2 std. state
Ag2CrO4
Ag2CO3
Ag2C2O4
AgF
AgF2
AgI
AgIO3
AgN3
Ag(NH3)2⫹ std. state
AgNO3
std. state
AgO
Ag2O
Ag2O3
Ag2S argentite
Ag3Sb
AgSCN
Ag2Se
Ag2SO4
std. state
Ag2Te
Sodium
Na
Na⫹ std. state
NaAg(CN)2 std. state
NaOAc
std. state
NaAlCl4
Na3AlCl6
NaAlF4
Na3AlF6
NaAlH4
NaAlO2
NaAl(SO4)2 std. state
NaAlSiO4
NaAsO2
std. state
Na3AsO4
std. state
NaAu(CN)2
NaBF4
std. state
NaBH4
std. state
Physical
State
c
c
aq
c
aq
c
c
c
c
c
c
c
c
aq
c
aq
c
c
c
c
c
c
c
c
aq
c
c
g
aq
aq
c
aq
c
c
g
c
c
c
aq
c
c
aq
c
aq
aq
c
aq
c
aq
⌬fH⬚
kJ · mol⫺1
⫺30.3
⫺31.13
⫺23.77
146.0
270.3
⫺731.74
⫺505.9
⫺673.2
⫺204.6
⫺360.0
⫺61.84
⫺171.1
308.8
⫺111.29
⫺124.4
⫺101.80
⫺12.15
⫺31.1
33.9
⫺32.59
⫺23.0
87.9
⫺38
⫺715.9
⫺698.10
⫺37.2
0
107.5(7)
⫺240.34(6)
30.12
⫺708.81
⫺726.13
⫺1142.0
⫺1979.0
⫺1869.0
⫺3361.2
⫺115.5
⫺1137.3
⫺2590
⫺2092.8
⫺660.53
⫺669.15
⫺1540
⫺1608.50
2.1
⫺1844.7
⫺1812.1
⫺188.6
⫺199.60
⌬fG⬚
kJ · mol⫺1
64.5
68.49
156.9
305.4
⫺641.83
⫺436.8
⫺584.1
⫺66.19
⫺93.7
376.1
⫺17.24
⫺33.47
⫺34.23
13.83
⫺11.21
121.4
⫺40.67
101.38
⫺44.4
⫺618.4
⫺590.36
⫺43.1
0
⫺261.88
43.5
⫺607.27
⫺631.28
⫺996.4
⫺1829
⫺1827.5
⫺3136.7
⫺1069.2
⫺2238
⫺1978.2
S⬚
J · deg⫺1 · mol⫺1
142.0
162.3
254.8
107.19
192
217.6
167.4
209
83.7
115.5
149.4
104.2
245.2
140.92
219.2
58.5
121.3
100.0
143.9
171.5
131.0
150.71
200.4
165.7
154.8
51.30(20)
153.718(3)
58.45(15)
251
123.0
145.6
188.3
347.0
345.7
239.5
70.40
⫺222.6
124.3
⫺611.91
99.6
⫺1434.19
23.9
⫺1750.1
⫺1748.9
⫺123.9
⫺147.61
14.2
230
145.31
243
101.3
169.5
top of rh
base of rh
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
66.73
142.26
112.26
51.92
56.82
102.93
93.05
⫺64.9
44.0
65.86
76.53
101.7
63
81.76
131.4
⫺251
87.5
28.15
46.4
79.9
40.2
154.98
244.1
105.9
215.89
73.64
120.3
86.8
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.114
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
NaBO2
std. state
NaBO3 · 4H2O
Na2B4O7
std. state
Na2B4O7 · 10H2O
NaBr
std. state
NaBr3 std. state
NaBrO std. state
NaBrO3
std. state
NaBrO4 std. state
Na2[Cd(CN)4]
NaCl
std. state
NaClO std. state
NaClO2
std. state
NaClO3
std. state
NaClO4
std. state
NaCN
std. state
Na3[Co(NO2)6]
Na2CO3
Na2CO3 · H2O
Na2CO3 · 10H2O
Na2C2O4
std. state
Na2CrO4
std. state
Na2Cr2O7
std. state
Na ethoxide
NaF
std. state
Na3[Fe(CN)6] std. state
Na4[Fe(CN)6] std. state
Na formate
std. state
NaH
Na2HAsO4 std. state
NaH2AsO4 std. state
NaHCO3
std. state
NaHCrO4 std. state
NaHF2
std. state
Physical
State
c
aq
c
c
aq
c
c
aq
aq
aq
c
aq
aq
aq
c
aq
aq
c
aq
c
aq
c
aq
c
aq
c
c
aq
c
c
c
aq
c
aq
c
aq
c
c
aq
aq
aq
c
aq
c
aq
aq
c
aq
aq
c
aq
⌬fH⬚
kJ · mol⫺1
⫺977.0
⫺1012.49
⫺2114.2
⫺3291.1
⫺3271.1
⫺6298.6
⫺361.08
⫺361.66
⫺370.54
⫺384.3
⫺334.09
⫺307.19
⫺227.19
⫺52.3
⫺411.2
⫺407.27
⫺347.3
⫺307.02
⫺306.7
⫺365.77
⫺344.09
⫺383.3
⫺369.45
⫺87.5
⫺89.5
⫺1423.0
⫺1130.7
⫺1157.4
⫺1431.26
⫺4081.32
⫺1318.0
⫺1305.4
⫺1342.2
⫺1361.39
⫺1978.6
⫺1970.7
⫺413.80
⫺576.6
⫺572.75
⫺158.6
⫺505.0
⫺666.5
⫺666.67
⫺56.34
⫺1386.58
⫺1149.68
⫺950.81
⫺932.11
⫺1118.4
⫺920.27
⫺890.06
⌬fG⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
⫺920.7
⫺940.81
73.54
21.8
⫺3096.0
⫺3076.9
⫺5516.6
⫺349.00
⫺365.85
⫺368.95
⫺295.4
⫺242.6
⫺243.34
⫺143.93
⫺16.3
⫺384.1
⫺393.17
⫺298.7
⫺244.8
⫺262.34
⫺269.91
⫺254.9
⫺270.50
⫺76.4
⫺89.5
189.0
192.9
586
86.82
141.4
274.5
100
128.9
220.9
⫺258.57
439
72.1
115.5
100
115.9
160.3
123.4
221.3
142.3
241.0
115.6
153.1
⫺1044.4
⫺1051.6
⫺1285.41
⫺3428.20
135.0
61.6
168.11
564.0
⫺1197.9
⫺1235.0
⫺1251.64
163.6
176.61
168.2
⫺1825.1
379.9
⫺546.3
⫺540.70
⫺56.5
⫺352.63
⫺600.00
⫺613.0
⫺33.55
⫺1238.51
⫺1015.16
⫺851.0
⫺848.72
⫺1026.8
⫺852.20
⫺840.02
51.11
45.2
447.3
231.0
103.76
151
40.02
116.3
176
101.7
150.2
243.1
90.92
151.5
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
65.94
186.8
614.5
51.38
⫺95.4
50.51
⫺90.0
111.3
70.4
112.3
145.60
550.32
142
142.13
46.85
⫺60.3
82.68
⫺41.4
36.39
87.61
75.02
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.115
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
Na2H2[Fe(CN)6]
NaH2PO4
std. state
Na2HPO4
std. state
Na2H2P2O7
NaHS
std. state
NaHSeO3
std. state
NaHSeO4
std. state
NaHSO4
std. state
NaI
std. state
NaI3
NaIO3
std. state
NaIO4
std. state
Na methoxide
std. state
NaMnO4 std. state
Na2MnO4
std. state
Na2MoO4
std. state
Na2Mo2O7
NaN3
std. state
NaNH2
NaNbO3
std. state
NaNO2
std. state
NaNO3
std. state
Na2[Ni(CN)4]
NaO2
Na2O
Na2O2
NaOCN cyanate
std. state
NaOH
std. state
Na3PO4
std. state
Na4P2O7
std. state
Physical
State
aq
c
aq
c
aq
c
c
aq
c
aq
c
aq
c
aq
c
aq
aq
c
aq
c
aq
c
aq
aq
c
aq
c
aq
c
c
aq
c
c
aq
c
aq
c
aq
aq
c
c
c
c
aq
c
aq
c
aq
c
aq
⌬fH⬚
kJ · mol⫺1
⫺24.7
⫺1536.8
⫺1536.4
⫺1748.1
⫺1772.38
⫺2764.8
⫺237.23
⫺257.73
⫺759.23
⫺754.67
⫺821.40
⫺821.74
⫺1125.5
⫺1127.46
⫺287.9
⫺295.31
⫺291.6
⫺481.79
⫺461.50
⫺429.28
⫺391.62
⫺367.8
⫺433.59
⫺781.6
⫺1156.0
⫺1134
⫺1468.12
⫺1478.2
⫺2245.05
21.71
35.02
⫺123.9
⫺1315.9
⫺1265.7
⫺358.65
⫺344.8
⫺467.85
⫺447.48
⫺112.6
⫺260.2
⫺414.2
⫺510.9
⫺405.39
⫺386.2
⫺425.6
⫺469.15
⫺1917.40
⫺1997.9
⫺3188
⫺3231.7
⌬fG⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
134.64
⫺1386.2
⫺1392.27
⫺1608.3
⫺1613.06
⫺2522.5
335
127.49
149.4
150.50
84.5
220.20
⫺249.83
121.8
⫺673.41
194.1
⫺714.2
⫺992.9
⫺1017.88
⫺286.1
⫺313.47
⫺313.4
⫺389.95
⫺323.09
⫺320.49
⫺294.80
⫺332.46
⫺709.2
208.4
113.0
190.8
98.50
170.3
298.3
135.1
177.4
163.0
280
110.58
17.6
250.2
⫺1024.7
⫺1354.30
⫺1360.2
⫺2058.19
93.76
86.2
⫺64.0
1233.0
⫺1194.1
⫺284.60
⫺294.1
⫺367.06
⫺373.21
⫺51.9
⫺218.4
⫺375.5
⫺449.6
⫺358.2
⫺359.4
⫺379.4
⫺419.20
⫺1788.87
⫺1804.6
⫺2969.4
⫺2966.9
176
159.70
145.2
250.6
96.86
166.9
76.90
117
155
103.8
182.0
116.52
205.4
335
115.9
75.04
94.8
96.7
165.7
64.4
48.1
173.80
⫺46
270.29
117
top of rh
base of rh
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
116.86
135.31
198.15
⫺38
52.1
⫺95.8
92.1
69.45
141.71
217.15
76.61
66.15
⫺51.0
92.88
⫺40.2
72.14
69.10
89.3
86.6
59.5
⫺102.1
153.47
241.12
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.116
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
NaReO4
std. state
Na2S
std. state
Na2S2
std. state
NaSCN
std. state
Na2Se
Na2SeO3
std. state
Na2SeO4
Na2SiF6
Na2SiO3
Na2Si2O5
NaSnBr3
NaSnCl3
Na2SO3
std. state
Na2SO4
std. state
Na2SO4 · 10H2O
Na2S2O3
std. state
Na2S2O3 · 5H2O
Na2S2O4 dithionate
std. state
Na2S2O7
Na2S2O8
Na2Te
Na2TeO4
Na2TiO3
Na2UO4 beta
Na3UO4
NaVO3
std. state
Na3VO4
Na2V2O7
Na2WO4
Na2[Zn(CN)4]
Strontium
Sr
Sr2⫹ std. state
Sr(OAc)2
Sr3(AsO4)2
SrBr2
SrCl2
std. state
Sr(ClO4)2
std. state
Physical
State
⌬fH⬚
kJ · mol⫺1
c
aq
c
aq
c
aq
c
aq
c
c
aq
c
c
c
c
aq
aq
c
aq
c
aq
c
c
aq
c
c
aq
c
aq
c
c
c
c
c
c
aq
c
c
c
aq
⫺1057.09
⫺1027.6
⫺364.8
⫺443.3
⫺397.0
⫺450.2
⫺170.50
⫺163.68
⫺341.4
⫺958.6
⫺989.5
⫺1069.0
⫺2909.6
⫺1554.9
⫺2470.1
⫺615.1
⫺727.2
⫺1100.8
⫺1115.87
⫺1387.1
⫺1389.51
⫺4327.26
⫺1123.0
⫺1132.40
⫺2607.93
⫺1232.2
⫺1233.9
⫺1925.1
⫺1825.1
⫺349.4
⫺1270.7
⫺1591.2
⫺1893.3
⫺2025.1
⫺1145.79
⫺1128.4
⫺1757.87
⫺2918.84
⫺1544.7
⫺138.1
c
aq
c
c
c
aq
c
aq
c
aq
0
⫺545.8
⫺1487.4
⫺3317.1
⫺717.6
⫺788.89
⫺828.9
⫺880.10
⫺762.69
⫺804.46
⌬fG⬚
kJ · mol⫺1
⫺953.74
⫺956.5
⫺349.8
⫺438.1
⫺392
⫺444.3
S⬚
J · deg⫺1 · mol⫺1
C⬚p
J · deg⫺1 · mol⫺1
151.5
260.2
83.7
103.3
151
146.4
133.89
⫺169.20
203.84
6.3
⫺893.7
130
⫺2754.2
⫺1462.8
⫺2324.1
⫺608.8
⫺692.0
⫺1012.5
⫺1010.44
⫺1270.2
⫺1268.40
⫺3647.40
⫺1028.0
⫺1046.0
⫺2230.1
207.1
113.8
164.1
310
318
145.94
87.9
149.6
138.1
592.0
155
184.1
⫺1124.2
⫺1722.1
⫺1638.9
209.2
202.1
362.3
⫺1496.2
⫺1777.78
⫺1901.2
⫺1064.12
⫺1045.6
⫺1637.83
⫺2712.52
⫺1429.8
⫺77.0
121.67
166.02
198.20
113.68
109
190.0
318.4
160.3
343
0
⫺559.44
55.0
⫺32.6
⫺3080.3
⫺697.1
⫺767.39
⫺781.1
⫺821.95
255
135.1
132.2
114.9
80.3
⫺576.68
331.4
cap height
base of text
82.8
187.1
111.9
157.0
120.25
128.2
⫺201
125.65
146.65
173.01
97.57
164.85
269.74
139.8
26.79
75.3
75.59
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.117
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
SrCO3
SrC2O4
SrF2
Sr formate
SrHPO4
Sr(H2PO4)2
SrI2
std. state
Sr(IO3)2
SrMoO4
Sr(NO2)2
Sr(NO3)2
std. state
SrO
SrO2
Sr(OH)2
Sr3(PO4)2
SrS
SrSe
SrSeO3
SrSeO4
SrSiO3
Sr2SiO4
SrSO3
SrSO4
Sr2TiO4
Sulfur
S rhombic
monoclinic
S22⫺
S2
S8
S2Br2
SCl2
SClF5
S2Cl2
SCN⫺
SF4
SF6
S2F10
SO
SO2
SO3
SOCl2
SOF2
SO2Cl2
SO2ClF
SO2F2
Physical
State
⌬fH⬚
kJ · mol⫺1
c
aq
c
c
c
c
c
c
aq
c
c
c
c
aq
c
c
c
c
c
c
c
c
c
c
c
c
aq
c
⫺1220.1
⫺1222.9
⫺1370.7
⫺1216.3
⫺1393.3
⫺1821.7
⫺3134.7
⫺558.1
⫺656.18
⫺1019.2
⫺1561.1
⫺762.3
⫺978.22
⫺960.52
⫺592.0
⫺654.4
⫺959
⫺4122.9
⫺472.4
⫺385.8
⫺1047.7
⫺1142.7
⫺1633.9
⫺2304.6
⫺1177.0
⫺1453.1
⫺1455.1
⫺2287.4
c
c
g
aq
g
g
lq
lq
lq
lq
aq
g
g
g
g
g
g
g
g
g
g
g
0
0.360
277.17(15)
33.1
128.60(30)
101.25
⫺13.0
⫺50.0
⫺1065.7
⫺59.4
76.4
⫺763.2
⫺1220.5
⫺2064
6.3
⫺296.81(20)
⫺395.7
⫺212.50
⫺544
⫺364.0
⫺556
⫺759
⌬fG⬚
kJ · mol⫺1
⫺1140.1
⫺1087.3
⫺1164
⫺1688.7
⫺557.7
⫺662.62
⫺855.2
⫺780.0
⫺782.12
⫺561.9
S⬚
J · deg⫺1 · mol⫺1
97.1
⫺89.5
82.1
81.42
70.0
121
159.1
190.0
234
128.9
77.95
117.07
149.87
⫺881
⫺467
68.2
48.7
⫺1549.8
⫺2191.2
96.7
153.1
88.53
134.26
⫺1341.0
⫺1304.0
⫺2178.6
117.0
⫺12.6
159.0
107.78
85.8
49.16
⫺28.5
⫺39
92.7
⫺722.0
⫺1116.5
⫺1861
⫺19.9
⫺300.13
⫺371.02
⫺198.3
⫺502
⫺320.0
⫺513
⫺712
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
194.56
260.2
54.4
54
97
0
⫺0.070
top of rh
base of rh
32.054(50)
33.03
167.829(6)
⫺14.6
228.167(10)
430.20
184
224
144.3
299.6
291.5
397
222.0
248.223(50)
256.77
309.8
278.7
311.9
303
284.0
45.0
79.45
74.9
143.68
22.60
23.23
156.06
91.0
124.3
⫺40.2
77.60
96.96
176.7
30.2
39.88
50.66
66.5
56.81
77.01
71.6
66.0
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.118
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
SO32⫺
SO24⫺
S2O32⫺
S2O42⫺
S2O82⫺
Tantalum
Ta
TaB2
TaBr5
TaC
Ta2C
TaCl5
TaF5
Ta2H
TaI5
TaN
TaO2
Ta2O5
TaOCl3
Technetium
Tc
Tc2O7
Tellurium
Te
TeBr4
TeCl4
TeF6
TeO2
Te(OH)⫹3
Terbium
Tb
Tb3⫹ std. state
TbCl3
std. state
TbO2
Tb2O3
Tb2(SO4)3 std. state
Thallium
Tl
Tl⫹ std. state
Tl3⫹ std. state
TlBr
std. state
TlBr3
TlBrO3
std. state
TlCl
std. state
TlCl3
std. state
TlClO3
Physical
State
⌬fH⬚
kJ · mol⫺1
⌬fG⬚
kJ · mol⫺1
aq
aq
aq
aq
aq
⫺635.5
⫺909.34(40)
⫺652.3
⫺753.5
⫺1344.7
⫺486.5
⫺744.5
⫺522.5
⫺600.3
⫺1114.9
c
c
c
c
c
c
c
c
c
c
g
c
g
0
⫺209.2
⫺598.3
⫺144.1
⫺197.5
⫺859.0
⫺1903.6
⫺32.6
⫺490
⫺251
⫺201
⫺2046
⫺780.7
c
c
0
⫺1113
c
c
c
g
c
aq
0
⫺190.4
⫺326.4
⫺1318.0
⫺322.6
⫺322.6
c
aq
c
aq
c
c
aq
0
⫺682.8
⫺997.1
⫺1184.1
⫺971.5
⫺1865.2
⫺4131.7
c
aq
aq
c
aq
aq
c
aq
c
aq
c
aq
aq
0
5.36
196.6
⫺173.2
⫺116.19
⫺168.2
⫺136.4
⫺78.2
⫺204.10
⫺161.80
⫺315.1
⫺305.0
⫺93.7
0
S⬚
J · deg⫺1 · mol⫺1
⫺29.0
18.50(40)
67.0
92.0
244.3
C⬚p
J · deg⫺1 · mol⫺1
⫺293.0
41.47
44.4
305.4
42.37
83.7
222
195.0
79.1
343
50.6
280
143.1
361.5
25.40
48.12
155.73
36.79
60.96
148
130.46
90.8
155.6
42.1
44.0
135.0
98.53
0
33.47
24.27
0
49.70
25.70
⫺270.3
⫺496.1
209
335.77
79.5
111.7
138.5
116.90
63.89
0
⫺651.9
73.22
⫺226.0
28.91
17.0
⫺1045.6
⫺59.0
⫺142.7
⫺746
⫺69.0
⫺209
⫺1911.0
cap height
base of text
⫺393.0
115.9
⫺3597.4
0
⫺32.38
214.6
⫺167.36
⫺136.36
⫺97.1
⫺53.14
⫺30.5
⫺184.93
⫺163.64
64.18
125.5
⫺192.0
120.5
207.9
54.0
168.6
288.7
111.30
182.00
⫺179.1
⫺35.6
⫺23.0
287.9
26.32
50.50
50.92
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.119
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
Tl2CO3
TlF
std. state
TlI
std. state
TlNO3
Tl2O
TlOH
std. state
Tl2S
Tl2Se
Tl2SO4
std. state
Thorium
Th
Th4⫹ std. state
ThBr4
ThC1.94
ThCl4
ThF3
ThF4
undissoc; std. state
ThH2
ThI4
ThN
Th3N4
Th(NO3)4
ThO2
ThOCl2
ThOF2
Th(OH)3⫹
Th(OH)22⫹
Th3P4
ThS2
Th2S3
Th(SO4)2
Thullium
Tm
Tm3⫹ std. state
TmCl3
std. state
Tm2O3
Tin
Sn white
gray
Sn2⫹ in aqueous HCl
Sn4⫹ in aqueous HCl
SnBr2
Physical
State
c
c
aq
c
aq
c
aq
c
c
aq
c
c
c
aq
⌬fH⬚
kJ · mol⫺1
⫺700
⫺324.6
⫺327.27
⫺123.9
⫺49.83
⫺243.93
⫺202.0
⫺178.7
⫺238.9
⫺224.64
⫺97.1
⫺59.0
⫺931.8
⫺898.56
c
g
aq
c
c
c
g
c
aq
c
c
c
c
c
c
c
c
aq
aq
c
c
c
c
0
602.(6)
⫺769.0
⫺965.3
⫺146
⫺1186.2
⫺1166.1
⫺2097.8
⫺2115.0
⫺139.8
⫺664.8
⫺391.2
⫺1315.0
⫺1441.4
⫺1226.4(35)
⫺1232.2
⫺1665.2
⫺1030.1
⫺1282.4
⫺1140.2
⫺626.3
⫺1083.7
⫺2542.6
c
aq
c
aq
c
0
⫺697.9
⫺986.6
⫺1199.1
⫺1888.7
c
aq
c
aq
aq
c
0
301.2(15)
⫺2.09
⫺8.9(10)
30.5
⫺243.5
⌬fG⬚
kJ · mol⫺1
⫺614.6
⫺311.21
⫺125.39
⫺83.97
⫺152.46
⫺143.7
⫺147.3
⫺195.8
⫺189.66
⫺93.7
⫺59.0
⫺830.48
⫺809.40
0
S⬚
J · deg⫺1 · mol⫺1
155.2
83.3
111.7
127.6
236.8
160.7
272.0
126
88
114.6
151.0
172.0
230.5
271.1
⫺705.1
⫺927.2
⫺147.7
⫺1094.1
⫺1160.6
⫺2003.4
⫺1947.2
⫺100.0
⫺655.2
⫺363.6
⫺1212.9
51.8(5)
190.17(5)
⫺422.6
230
68.49
190.4
339.2
142.05
⫺105
50.71
255
56.07
201
⫺1169.20
⫺1156.0
⫺1589.5
⫺920.5
⫺1140.9
⫺1112.9
⫺620.1
⫺1077.0
⫺2310.4
65.23(20)
123.4
105
⫺343.0
⫺218.0
221.8
96.2
180
159.0
0
⫺661.9
74.01
⫺243.0
⫺1055.6
⫺1794.5
⫺75.0
139.8
0
0.13
⫺27.2
2.5
51.08(8)
168.492(4)
44.14
⫺16.7(40)
⫺117
top of rh
base of rh
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
54.77
52.51
99.50
27.32
56.69
120.3
73.3
110.7
36.69
45.2
155.90
61.76
91.25
173.47
27.03
25.0
⫺385.0
116.7
26.99
25.77
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.120
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
SnBr4
SnCl2
std. state
SnCl4
SnH4
SnI2
SnI4
SnO tetragonal
SnO2 tetragonal
Sn(OH)⫹
Sn(OH)2
SnS
SnS2
Titanium
Ti
TiB
TiB2
TiBr2
TiBr3
TiBr4
TiC
TiCl2
TiCl3
TiCl4
TiF3
TiF4
TiH2
TiI4
TiN
TiO
TiO2
Ti2O3
Ti3O5
Tungsten
W
WBr5
WBr6
W(CO)6
WCl4
WCl5
WCl6
WF6
WO2
WO3
WO24⫺
WOCl4
Physical
State
c
g
c
aq
lq
g
g
c
g
c
c
aq
c
c
c
⌬fH⬚
kJ · mol⫺1
⌬fG⬚
kJ · mol⫺1
⫺377.4
⫺314.6
⫺325.1
⫺329.7
⫺511.3
⫺471.5
162.8
⫺143.5
⫺350.2
⫺331.4
⫺280.71(20)
⫺577.63(20)
⫺286.2
⫺561.1
⫺100
⫺167.4
⫺251.9
⫺515.8
⫺254.8
⫺491.6
⫺98.3
c
g
c
c
c
c
c
c
c
c
lq
g
c
c
c
c
c
c
c
c
c
0
473.(3)
⫺160
⫺280
⫺402
⫺548.5
⫺616.7
⫺184
⫺513.8
⫺720.9
⫺804.2
⫺763.2(30)
⫺1435
⫺1649
⫺144
⫺375
⫺265.8
⫺519.7
⫺944.0(8)
⫺1520.9
⫺2459.4
c
c
c
c
c
c
c
lq
g
c
c
aq
c
0
⫺312
⫺348.5
⫺953.5
⫺443
⫺515
⫺602.5
⫺1747.7
⫺1721.7
⫺589.9
⫺842.9
⫺1075.7
⫺671
⫺299.6
⫺440.2
⫺432.2
188.3
0
⫺160
⫺275
⫺383
⫺523.8
⫺589.5
⫺180
⫺464.4
⫺653.5
⫺737.2
⫺726.3
⫺1362
⫺1559
⫺105.1
⫺371.5
⫺243.8
⫺495.0
⫺888.8
⫺1434.2
⫺2317.4
0
⫺270
⫺290.8
⫺360
⫺402
⫺456
⫺1631.4
⫺1631.4
⫺533.86
⫺764.1
⫺549
S⬚
J · deg⫺1 · mol⫺1
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
264.4
411.9
130
172
258.6
365.8
227.7
136.44
103.4
79.33
446.1
57.17(30)
49.04(10)
50.0
155.0
77.0
87.4
105.4
44.31
52.59
30.72(10)
180.298(10)
35
28.5
108
176.6
243.5
24.2
87.4
139.7
252.3
353.2(40)
88
133.96
29.71
249.4
52.73
50.0
50.62(30)
78.8
129.3
25.0
165.3
98.3
48.95
49.25
70.12
29.7
44.3
78.7
101.7
131.5
33.81
69.8
97.2
145.2
95.4
92
114.27
30.09
125.6
37.08
39.9
55.0
97.4
154.8
32.6
272
314
331.8
198.3
217.6
238.5
251.5
341.1
50.5
75.9
24.3
155
181.4
242.5
129.7
155.6
175.4
173
146
119.0
56.1
73.8
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.121
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
WOF4
WO2Cl2
Uranium
U
U3⫹
U4⫹
UB2
UBr3
UBr4
UBr5
UC
UCl3
UCl4
UCl5
UCl6
UF3
UF4
UF5
UF6
UH3
UI3
UI4
UN
UO2
UO22⫹ std. state
UO3 gamma
U3O7
U3O8
U4O9
UOBr2
UOCl2
UOF2
UO2(OAc)2
UO2Br2
UO2Cl2
std. state
UO2CO3
std. state
UO2C2O4
UO2F2
std. state
UO2(NO3)2
std. state
UO2(OH)2 std. state
UO2SO4
std. state
US2
US3
Physical
State
⌬fH⬚
kJ · mol⫺1
c
c
⫺1407
⫺780
c
g
aq
aq
c
c
c
c
c
c
c
aq
c
c
c
c
c
c
c
c
c
c
c
aq
c
c
c
c
c
c
c
c
c
c
aq
c
aq
c
c
aq
c
aq
aq
c
aq
c
c
0
533.(8)
⫺489.1
⫺591.2
⫺161.6
⫺699.2
⫺802.5
⫺810.9
⫺98.3
⫺866.5
⫺1019.2
⫺1259.8
⫺1058
⫺1092
⫺1502.1
⫺1921.2
⫺2075.3
⫺2197.0
⫺127.2
⫺460.7
⫺512.1
⫺290.8
⫺1085.0(10)
⫺1019.0(15)
⫺1223.8(12)
⫺3427.1
⫺3574.8(25)
⫺4510.4
⫺973.6
⫺1066.9
⫺1499.1
⫺1963.55
⫺1137.6
⫺1243.9
⫺1353.9
⫺1691.2
⫺1696.6
⫺1796.94
⫺1653.5
⫺1684.0
⫺1349.3
⫺1434.3
⫺1479.5
⫺1845.1
⫺1928.8
⫺527
⫺549.4
⌬fG⬚
kJ · mol⫺1
⫺1298
⫺703
0
S⬚
J · deg⫺1 · mol⫺1
176.0
200.8
⫺476.2
⫺531.9
⫺159.4
⫺673.6
⫺767.8
⫺769.9
⫺99.2
⫺799.1
⫺930.1
⫺1056.8
⫺950
⫺962
⫺1433.4
⫺1823.3
⫺1958.6
⫺2068.6
⫺72.8
⫺459.8
⫺506.7
⫺265.7
⫺1031.8
⫺953.5
⫺1145.7
⫺3242.9
⫺3369.8
⫺4275.1
⫺929.7
⫺996.2
⫺1428.8
50.20(20)
199.79(10)
⫺188.0
⫺410.0
55.52
192
238.0
293
59.20
159.0
197.1
⫺184.0
242.7
285.8
123.43
151.67
199.6
227.6
63.68
222
264
62.43
77.03(20)
⫺98.2(30)
96.11(40)
250.5
282.55(50)
334.1
158.00
138.32
119.2
⫺1066.5
⫺1146.4
⫺1215.9
⫺1562.7
⫺1481.6
169.5
150.5
15.5
138
⫺154.4
⫺1557.4
⫺1551.3
⫺1105.0
⫺1176.1
⫺1267.8
⫺1683.6
⫺1698.3
⫺526.4
⫺547.3
135.56
⫺125.1
243
195.4
⫺118.8
154.8
⫺77.4
110.42
138.49
top of rh
base of rh
cap height
base of text
C⬚p
J · deg⫺1 · mol⫺1
133.6
104.4
27.66
55.77
108.8
128.0
160.7
50.12
102.5
122.0
144.6
175.7
95.10
116.02
132.3
166.8
49.29
112.1
134.3
47.57
63.60
81.67
215.5
238.36
293.3
98.00
95.06
107.86
103.22
145.2
74.64
95.60
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.122
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
Vanadium
V
VBr4
VCl2
VCl3
VCl4
VF5
VN
VO
VO2
VO2⫹ std. state
VO22⫹ std. state
VO⫺3 std. state
V2O3
V2O4
V2O5
V3O5
VOCl3
VOSO4
Xenon
Xe
XeF2
XeF4
XeF6
XeO3
XeOF4
Ytterbium
Yb
Yb2⫹ std. state
Yb3⫹ std. state
Yb(OAc)3 undissoc; std.
state
YbCl2
YbCl3
std. state
Yb(NO3)3 std. state
Yb2O3
Yttrium
Y
Y3⫹ std. state
YCl3
YF3
Y2O3
Y(OH)3
Zinc
Zn
Zn2⫹ std. state
Physical
State
⌬fH⬚
kJ · mol⫺1
c
g
c
c
lq
lq
g
c
c
c
aq
aq
aq
c
c
c
c
lq
g
c
0
⫺336.8
⫺452
⫺580.7
⫺569.4
⫺1480.3
⫺1433.9
⫺217.15
⫺431.8
⫺717.6
⫺649.8
⫺486.6
⫺888.3
⫺1218.8
⫺1427
⫺1550
⫺1933
⫺734.7
⫺695.6
⫺1309.2
g
c
c
c
g
c
lq
0
⫺164.0
⫺261.5
⫺360
⫺297
402
146
c
aq
aq
aq
⫺674.5
⫺2105.0
c
c
aq
aq
c
⫺799.6
⫺959.8
⫺1176.1
⫺1296.6
⫺1814.6
c
aq
c
c
c
c
0
⫺723.4
⫺1000
⫺1718.8
⫺1905.31
⫺1435
c
g
aq
0
0
130.40(40)
⫺153.39(20)
⌬fG⬚
kJ · mol⫺1
0
⫺406
⫺511.3
⫺503.8
⫺1373.2
⫺1369.8
⫺191.08
⫺404.2
⫺587.0
⫺446.4
⫺783.7
⫺1139.3
⫺1318.4
⫺1419.3
⫺1803
⫺668.6
⫺659.3
⫺1169.9
0
S⬚
J · deg⫺1 · mol⫺1
C⬚p
J · deg⫺1 · mol⫺1
28.94
24.90
97.1
131.0
255.0
175.7
320.9
37.28
39.0
51.5
⫺42.3
⫺133.9
50.2
98.3
103
130
163
244.4
344.4
108.8
72.22
93.18
161.7
169.685(3)
cap height
base of text
98.58
38.00
45.5
62.59
103.2
115.4
130.6
150.62
89.9
20.786
⫺123.0
0
⫺527.0
⫺643.9
⫺1772.84
238.0
183.3
25.0
⫺1037.6
⫺71.0
⫺385.0
⫺1726.7
133.1
115.35
0
⫺693.7
44.4
⫺251.0
136.8
100
99.08
99.2
26.51
⫺1644.7
⫺1816.65
⫺1291
0
⫺147.1
59.87
41.63(15)
160.990(4)
⫺109.8(5)
26.74
75.0
102.51
25.40
46.0
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.123
THERMODYNAMIC PROPERTIES
TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
and Inorganic Compounds (Continued)
Substance
ZnBr2
std. state
ZnCl2
std. state
Zn(CN)24⫺ std. state
ZnCO3
ZnF2
std. state
ZnI2
Zn(NO3)2
ZnO
Zn(OH)2
std. state
ZnS sphalerite
wurtzite
ZnSe
ZnSO4
Zn2SiO4
Zirconium
Zr
ZrB
ZrBr2
ZrBr4
ZrC
ZrCl2
ZrCl3
ZrCl4
ZrF2
ZrF4
ZnH2
ZrI2
ZrI3
ZrI4
ZrN
ZrO2
ZrSiO4
ZrSO4
Physical
State
⌬fH⬚
kJ · mol⫺1
c
aq
c
aq
aq
c
c
aq
c
aq
c
aq
c
c
aq
c
c
c
c
aq
c
⫺328.65
⫺396.98
⫺415.05
⫺488.19
342.3
⫺812.78
⫺764.4
⫺819.14
⫺208.03
⫺264.3
⫺483.7
⫺568.6
⫺350.46(27)
⫺641.91
⫺613.88
⫺205.98
⫺192.6
⫺163
⫺982.84
⫺1063.2
⫺1636.7
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
0
⫺322
⫺405
⫺760.7
197
⫺502.0
⫺714
⫺981
⫺962
⫺1911.3
⫺169.0
⫺259
⫺397.5
⫺488
⫺365
⫺1100.6
⫺2033.4
⫺2217.1
⌬fG⬚
kJ · mol⫺1
S⬚
J · deg⫺1 · mol⫺1
C⬚p
J · deg⫺1 · mol⫺1
⫺312.13
⫺354.97
⫺369.45
⫺409.53
446.9
⫺731.57
⫺713.3
⫺704.67
⫺208.95
⫺250.2
138.5
52.72
111.46
0.84
226
82.4
73.68
⫺139.8
161.1
110.5
65.7
⫺238.0
71.34
⫺226.0
⫺369.6
⫺320.52
⫺553.59
⫺461.62
⫺201.29
180.7
43.65(40)
81.2
⫺133.5
57.7
⫺163
⫺871.5
⫺891.6
⫺1523.2
84.0
110.5
⫺92.0
131.42
0
⫺318.2
⫺382
⫺725.3
⫺193
⫺386
⫺646
⫺890
⫺913
⫺1810.0
⫺128.8
⫺258
⫺394.9
⫺485.4
⫺336.7
⫺1042.8
⫺1919.1
39.0
35.94
116
224
33.32
110
146
181.4
75
104.7
35.0
150.2
204.6
260
38.86
50.36
84.1
top of rh
base of rh
cap height
base of text
79.71
65.7
⫺167.0
65.69
⫺238.0
⫺126.0
40.25
⫺251
46.02
99.2
⫺247.0
123.3
25.40
48.24
86.7
124.8
37.90
72.6
96
119.8
66
103.6
31.0
94.1
103.8
127.8
40.44
56.19
98.7
172.0
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.124
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds
cap height
base of text
Abbreviations Used in the Table
⌬Hm, enthalpy of melting (at the melting point) in kJ · mol⫺1
⌬Hv, enthalpy of vaporization (at the boiling point) in kJ · mol⫺1
⌬Hs, enthalpy of sublimation (or vaporization at 298 K) in kJ · mol⫺1
Cp, specific heat (at temperature specified on the Kelvin scale) for the physical state in existence (or specified:
c, lq, g) at that temperature in J · K⫺1 · mol⫺1
⌬Ht, enthalpy of transition (at temperature specified, superscript, measured in degrees Celsius) in kJ · mol⫺1
Cp
Substance
Aluminum
Al
Al(BH4)3
Al6BeO10
AlBr3
Al4C3
AlCl3
AlF3 , ⌬Ht ⫽ 0.56455
AlI3
AlN
Al2O3 corundum
AlOCl
Al2SiO5 andalusite
kyanite
sillimanite
Al6Si2O13 mullite
Al2S3
Al2TiO5
Americium
Am
Ammonium
NH3
ND3 ammonia-d3
NH4Br, ⌬Ht ⫽ 3.22138
NH4Cl, ⌬Ht ⫽ 1.046⫺30.6
⌬Ht ⫽ 3.950184.6
NH4ClO4
NH4I, ⌬Ht ⫽ 2.93⫺13
NH4NO3
Antimony
Sb
SbBr3
SbCl3
SbCl5
SbH3
SbI3
Sb2O3, ⌬Ht ⫽ 7.1573
Sb2S3
Argon
Ar
⌬Hm
10.7l
402
11.25
35.4
98
15.9
⌬Hv
294.0
30
⌬Hs
326.4
23.5
116
32.2
112
111.4
55
400 K
600 K
800 K
1000 K
25.8
27.9
30.6
34.9(lq)
324.3
125.0
138.5
100.1
86.3
108.5
36.7
96.1
64.3
149.6
148.3
147.5
390.7
115.0
162.0
380.6
125.0
159.2
117.7
97.3
121.3
43.5
112.5
72.6
174.5
176.2
173.0
459.8
124.1
182.8
407.8
125.0
169.7
135.2
98.5
425.2
125.0
176.1
152.8
100.8
46.8
120.1
76.9
186.1
188.3
185.0
494.1
129.7
192.9
48.5
124.8
79.3
194.0
196.2
193.5
513.4
134.0
200.0
38.7
42.9
45.3
51.5
51.1
58.6
56.2
64.3
103.3
117.7
14.39
5.66
23.35
19.86
103
168.5525
20.9
6.40
19.87
14.6
12.7
10.0
22.8
54.4
1.12
193.43
59
45.2
48.4
21.3
68.6
74.6
6.43
148.7
89.0
25.9
125.5(lq)
123.4(lq)
106.6(lq)
108.5
123.3
20.8
27.7
81.6(g)
81.6(g)
29.5
82.2
82.2
143.5(lq) 82.2(g)
122.8
137.1
134.4
145.4
20.8
20.8
31.4
82.5
82.5
82.5(g)
150.6
20.8
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.125
THERMODYNAMIC PROPERTIES
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
Arsenic
As
AsBr3
AsCl3
AsF3
AsF5
AsH3
AsI3
As2O3
Barium
Ba
BaBr2
BaCl2, ⌬Ht ⫽ 16.9925
BaCO3, ⌬Ht ⫽ 18.8806
BaF2, ⌬Ht ⫽ 2.671207
BaH2
BaI2
BaMoO4
BaO
Ba(OH)2
BaS
BaSO4
BaTiO3, ⌬Ht ⫽ 0.06775
Beryllium
Be
BeAl2O4, chrysoberyl
BeBr2
Be2C
BeCl2, ⌬Ht ⫽ 6.8403
BeF2, ⌬Ht ⫽ 0.92227
BeI2
Be3N2
BeO, ⌬Ht ⫽ 6.72100
BeS
Be2SiO4
BeSO4, ⌬Ht ⫽ 1.113590
⌬Ht ⫽ 19.55635
BeWO4
Bismuth
Bi
BiBr3
BiCl3
BiI3
Bi2O3, ⌬Ht ⫽ 116.7717
Bi2S3
Bi2Te3
Boron
B
BBr3
B4C
⌬Hm
24.44
11.7
10.1
10.4
⌬Hv
⌬Hs
25.6
41.8
35.0
29.7
20.8
16.7
59.3
133.5(lq)
45.4
18.4
140.3
46
16
63
40
246.4
285.4
405.1
43.9
302.5
330.6
424.3
297
291
100.0
515
105
199.4
70.5
136.0
125
6
11.30
21.7
10.9
151
75.4
72.6
20.9
27.5
29.3
88.3(g)
88.3
53.2
58.8
1000 K
63.9
33.9(c)
83.5
80.4
113.0
80.3
87.9
84.3
124.2
84.9
79.5
129.5
49.9
112.6
83.5
143.5
53.2
122.7(c)
87.5(c) 113.0(lq)
152.2
159.3
55.4
57.1
141.0(lq)
119.4
111.5
131.6
121.8
135.9
126.1
20.0
130.3
70.6
47.6
68.7
62.5
76.9
84.4
33.8
120.8
103.9
103.9
23.3
155.0
77.6(c)
51.9
75.8(c)
67.5
84.2
106.5
42.4
149.2
126.8
126.8
25.5
27.3
166.8
174.2
113.0(lq) 113.0
64.7
73.2
121.4(lq) 121.4
74.1(c)
85.6(lq)
117.6
46.7
166.0
149.8
149.8
123.6
49.3
174.1
174.4
174.4
113.0
131.3
142.9
153.0
31.8
31.8
123.6
136.2
179.7
130.3
141.3
192.3
137.0
146.4
20.8
77.6
98.4
23.4
79.8
107.7
25.0
81.1
114.3
116.9
131.1
164.3
120.5
105
800 K
33.2
79.2
77.3
99.0
75.9
27.0(c)
28.5
50.2
600 K
116.4
7.12
32.2
15.85
40
17.8
25
26.5
7.895
170.0
18
75.3
8.66
4.77
18
129.3
86
400 K
480
30.5
552
15.7
72.6(g)
76.4
31.8(lq)
39.1(lq)
92.2
89.5
134.6
94.6
137.9
128.7
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.126
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds (Continued)
cap height
base of text
Cp
Substance
⌬Hm
BCl3
BF3
F2B-BF2
BH3
B2H6
B4H9
B4H10
B5H11
B10H14
BI3
BN
B3N3H6 borazine
B2O3
B3O3H3 boroxin
Bromine
Br2
BrCl
BrF
BrF3
BrF5
Cadmium
Cd
CdBr2
CdCl2
CdF2
CdI2
Cd(NO3)2 · 4H2O
CdO
CdS
CdSO4
Calcium
Ca, ⌬Ht ⫽ 0.934
Ca(BO2)2
CaB4O7
CaBr2
CaC2 carbide
CaCl2
CaCN2 cyanamide
CaCO3
CaF2, ⌬Ht ⫽ 4.81151
CaH2
CaI2
Ca[Mg(CO3)2] dolomite
CaMoO4
Ca3N2
Ca(NO3)2
CaO
Ca(OH)2, ⌬Hdec ⫽ 99.2
Ca3(PO4)2, ⌬Ht ⫽ 15.51100
CaS
2.10
4.20
23.8
19.3
28
4.44
6.13
14.3
28.4
27.1
31.8
48.5
40.5
32.5
⌬Hv
81
24.56
⌬Hs
400 K
23.1
57.5
76.7
728
32.1
390.4
44.8
10.57
10.4
12.05
5.67
6.19
20.9
48.58
22.6
15.3
32.6
29.96
34.7
25.1
47.6
30.6
30.9
99.9
115
124.3
214
115
21.4
79.5
70
154.7
200
800 K
1000 K
68.4(g)
67.1
75.0
72.6
78.2
75.8
79.8
38.9
74.3
130.2(g)
45.4
101.3
187.6
52.3
121.7
227.4
58.4
136.4
254.4
250.0(lq)
351.6(g)
417.2
460.4
26.3
126.9
77.9
120.1
35.2
169.4
98.1(c)
162.8
40.5
44.3
197.2
216.6
129.7(lq) 129.7
194.6
214.2
36.7(g)
72.6
113.0
225.1
209.6
8.54
74.1
113.4
29.1
32
28.05
0.432
36
29.3
6.7
41.8
600 K
298.3
235
37.3
37.6
37.8
78.0
123.2
80.1
127.3
81.2
129.3
27.1(c)
29.7(lq)
29.7
29.7
79.8
86.3
92.7
104.6
43.8
55.5
108.3
45.6
56.2
123.8
47.3
57.0
139.2
49.1
57.7
154.7
26.9
125.0
202.0
78.0
30.0
144.9
243.0
80.5
33.8
157.2
267.7
83.5
39.7
176.2
287.8
88.6
75.6
78.2
80.9
85.8
308.9
441
73.9
78.5
83.9
90.1
179.4
243
79.2
143.3
131.3
122.2
173.7
46.6
98.4
255.1
49.2
83.1
163.3
144.9
140.8
210.5
50.5
107.4
295.6
51.5
87.1
176.8
153.5
159.2
243.4
52.4
91.0
188.3
150.6
331.3
53.0
365.7
54.1
53.7
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.127
THERMODYNAMIC PROPERTIES
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
⌬Hm
Substance
CaSiO3, ⌬Ht ⫽ 7.1
Ca2SiO4, ⌬Ht ⫽ 4.44675
⌬Ht ⫽ 3.261420
3CaO · SiO2
CaSO4
CaSO4 · 1⁄2H2O
CaSO4 · 2H2O
CaTiO3, ⌬Ht ⫽ 2.301257
Ca(VO2)2
CaWO4
Carbon
C graphite
(CN)2 cyanogen
CNBr
CNCl
CNI
CO, ⌬Ht ⫽ 0.632⫺211.6
CO2
C2O3
COCl2
COF2
COS
CS2
Cerium
Ce, ⌬Ht ⫽ 3.01730
CeCl3
CeI3
CeO2
Cesium
Cs
CsBr
CsCl, ⌬Ht ⫽ 3.77470
CsF
CsI
CsIO3
CsOH, ⌬Ht ⫽ 1.30137
⌬Ht ⫽ 6.1220
Cs2SO4, ⌬Ht ⫽ 4.3667
Chlorine
Cl2
ClF
ClF3
ClF5
ClO
ClO2
ClO3F
Cl2O
Cl2O7
Chromium
Cr, ⌬Ht ⫽ 0.000838.5
1190
⌬Hv
⌬Hs
56.1
28.0
117
8.1
23.3
19.7
45.4
11.4
59.4
0.837
9.02
5.40
5.74
7.73
4.40
5.46
54.4
51.9
2.09
23.6
15.9
21.7
23.9
13.0
4.56
6.04
15.8
26.943.5
24.4
16.1
18.6
26.7
398
170.1
63.9
151
115.1
115.5
150.2
7.61
3.83
21.0
27.5
419
326
76.6
120
35.7
6.406
25.2
20.41
24
27.5
22.9
600 K
800 K
1000 K
100.4
146.4
113.0
162.8
119.2
179.2
123.8
184.0
196.4
109.7
147.4
260.7
112.3
182.9
127.6
218.4
129.5
167.2
280.3
123.1
206.7
140.2
230.8
149.2
186.9
300.0
127.7
230.5
147.3
240.4
169.0
206.7
319.8
130.4
254.4
152.8
12.0
61.9(g)
50.19(g)
48.7
50.8
29.3
41.3
75.0
63.9
54.8
45.9
49.7
16.6
68.2
53.7
52.8
53.7
30.4
47.3
85.5
71.1
64.9
51.3
54.6
19.7
72.9
56.2
55.7
55.8
31.9
51.4
92.7
75.0
70.8
54.7
57.4
21.7
76.4
58.1
57.7
57.4
33.2
54.3
97.7
77.4
74.4
57.0
59.3
30.6
30.8
32.1
33.8
66.9
69.0
71.1
73.2
31.5
52.9
54.7
53.8
51.9
31.0
55.0
59.1
57.4
57.8(c)
30.9(lq)
57.2(c)
63.7(c)
60.9(c)
65.5(lq)
20.8(g)
77.4(lq)
77.4(lq)
74.1(lq)
67.8
74.4(c)
81.6(lq)
81.6
81.6
76.5
112.1
132.2
163.2
194.2
17.65
35.3
33.8
70.6(g)
110.0
33.2
46.1
75.9
51.4
36.6
35.6
76.8
121.6
35.3
51.4
89.2
54.7
37.1
36.5
79.4
126.3
36.3
54.2
96.1
56.2
37.4
37.0
80.7
128.6
36.9
55.8
100.0
56.9
27.7
29.4
31.9
30
19.33
25.9
34.69
339.5
400 K
397
25.2
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.128
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds (Continued)
cap height
base of text
Cp
Substance
CrCl2
CrCl3
Cr(CO)6
CrN, ⌬Hdec ⫽ 112
CrO2Cl2
CrO2F2
CrO3
Cr2O3
Cr2(SO4)3
Cobalt
Co, ⌬Ht ⫽ 0.452427
CoCl2
CoF2
CoF3
CoO
Co3O4
CoSO4, ⌬Ht ⫽ 2.1691
Copper
Cu
CuBr, ⌬Ht ⫽ 5.86380
⌬Ht ⫽ 2.9465
CuCl
CuCl2, ⌬Ht ⫽ 0.700402
⌬Ht ⫽ 15.001598
CuCN
CuF
CuF2
CuI
CuO
Cu2O
CuS
Cu2S, ⌬Ht ⫽ 3.85103
⌬Ht ⫽ 0.84350
Cu2Se, ⌬Ht ⫽ 4.85110
CuSO4
Dysprosium
Dy
Erbium
Er
Europium
Eu
Fluorine
F2, ⌬Ht ⫽ 0.728⫺227.6
FNO3
Gadolinium
Gd
Gd2O3
Gallium
Ga
GaBr3
⌬Hm
32.2
⌬Hv
⌬Hs
196.7
237.7
72.0
49.1
23.4
15.77
129.7
400 K
600 K
800 K
1000 K
72.6
93.1
233.9
50.4
77.0
99.0
81.5
104.9
85.9
110.7
51.7
53.0
63.9
112.7
316.9
72.5
120.5
345.2
76.7
124.3
373.5
78.8
127.0
401.8
26.5
81.7
75.7
97
52.9
143
119
29.7
84.6
80.8
100
54.3
163
141
32.4
86.8
82.9
102
54.8
185
152
37.0
88.2
84.2
104
56.0
210
158
35.1
34.3
16.2
45
59
377
146
202
424
219
315
13.26
9.6
300.4
337.7
25.3
56.5
26.5
59.8(c)
27.4
66.9(lq)
10.2
20.4
54
241.8
56.9
76.3
61.5(c)
80.2(c)
66.9(lq) 66.9
82.4(lq) 100.0
78.0
55.5
72.4
55.4
46.8
67.6
48.8
97.3
66.7
59.6
81.9
57.8
50.8
73.3
51.0
97.3
73.1
268
261
87.0
60.2
53.2
77.6
53.2
85.0
90.4
66.9
55.0
81.5
55.4
85.0
90.9
114.9
91.7
136.3
92.5
147.7
93.4
153.8
33.0
75.1
35.2
87.8
36.3
94.8
37.1
98.9
36.6
113.4
35.5
120.1
34.5
124.4
33.5
127.9
26.7
26.6
26.6
12
55
10.9
11.8
64.8
156
10.9
11.06
280
290.4
19.90
280
317.2
9.21
176
178
0.510
6.62
10.05
301.3
5.59
12.1
254
38.9
27.1(lq)
28.7
66.9
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.129
THERMODYNAMIC PROPERTIES
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
GaCl3
GaI3
Ga2O3
GaSb
Germanium
Ge, ⌬Ht ⫽ 37.03938.3
GeBr4
GeCl4
GeH4
Ge2H6
Ge3H8
GeO2
Gold
Au
AuSn
Hafnium
Hf, ⌬Ht ⫽ 5.91750
HfCl4
HfO2, ⌬Ht ⫽ 10.51700
Helium
He
Holmium
Ho
Hydrogen
H2
1 2
HH
2
H2
HBO2
H3BO3
HBr
HCl, ⌬Ht ⫽ 1.188⫺174.77
2
HCl
HClO
HCN
HF
2
HF
H2F2 dimer
HFO
HI
HNCO isocyanic acid
HNCS isothiocyanic acid
HNO2 cis
trans
HNO3
HN3
H2O
1 2
H HO
2
H2O
H2O2
2
H2O2
⌬Hm
⌬Hv
11.13
12.9
100
25.1
23.9
56.5
36.94
334
41.4
27.9
14.1
25.1
32.2
⌬Hs
43.9
12.55
25.6
27.2
75
104.6
0.0138
16.8
0.117
14.3
22.3
2.406
1.992
324
571
618.4
99.6
0.0829
242.1
12.7
9.1
8.406
4.58
25.22
2.87
19.77
17.4
10.47
39.46
30.5
40.66
39.1
6.009
12.50
12.68
44.0
51.63
52.4
800 K
1000 K
112.5
133.5
24.3
25.4
26.2
26.9
100.7
104.6
106.1
106.8
61.39
69.1
72.4
75.0
25.8
54.1
26.8
63.3(c)
27.8
60.6(lq)
28.8
26.7
125.4
67.7
280
0.904
600 K
91.4
20.79
71
17.61
16.14
400 K
28.6
105.8
73.9
20.79
30.3
106.7
77.3
31.9
107.1
79.9
20.79
20.79
317
29.2
29.2
29.2
61.5(c)
29.3
29.4
29.6
29.6
29.9
30.5
30.2
30.7
31.6
29.2
19.2
29.4
40.0
39.4
29.1
29.2
49.7
38.6
29.3
50.6
53.2
51.4
52.1
63.1
29.8
29.2
30.6
44.0
44.2
29.2
29.5
56.5
42.8
30.3
58.3
61.0
59.9
60.3
76.8
31.1
29.6
32.1
46.6
47.9
29.5
30.5
61.0
45.7
31.8
63.5
65.9
65.4
65.6
85.0
32.3
31.6
33.5
48.5
51.0
30.2
31.6
64.4
47.9
33.1
67.5
69.3
69.2
69.3
90.4
34.3(g)
34.8
35.6
48.5
36.4
37.5
38.8
55.7
38.8
40.4
42.2
59.8
41.4
43.3
45.4
66.7
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.130
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds (Continued)
cap height
base of text
Cp
Substance
HPH2O2
H3PO3
H3PO4
H2S, ⌬Ht ⫽ 1.531⫺169.61
H2S2
H2Se
HSO3F
H2SO4
H2SO4 · H2O
H2SO4 · 2H2O
H2SO4 · 3H2O
H2SO4 · 4H2O
H2Te
Indium
In
InBr
InBr3
InCl
InCl3
InF3
InI
InI3
In2O3
InSb
Iodine
I2
ICl
IF
IF5
IF7
Iridium
Ir
IrF6
IrO2
Iron
Fe, ⌬Ht ⫽ 0.90911
⌬Ht ⫽ 0.8371392
FeBr2
FeBr3, ⌬Ht ⫽ 0.418377
Fe2C, ⌬Ht ⫽ 0.75190
FeCl2
FeCl3
FeCO3
Fe(CO)5
FeCr2O4
FeF2
FeF3
FeI2, ⌬Ht ⫽ 0.8377
Fe3N
FeO
⌬Hm
9.67
12.84
13.4
23.8
10.71
19.46
18.24
24.0
30.64
⌬Hv
⌬Hs
18.67
33.8
19.7
14.1
50.2
400 K
600 K
800 K
175.7
38.9
236.0
42.5
296.2
45.8
87.5
158.2
228.5
294.6
347.8
410.3
102.6
111.0
197.0(lq) 125.9(g)
1000 K
365.5
116.3
132.7
19.2
3.28
15
26
21.3
27
64
17.3
18.5
105
25.5
231.8
92
150.66
11.60
41.6
243.1
28.5(c)
13.81
231.8
36
340
50.2
50.2
51.5
43.01
43.1
26.3
43.76
13.23
33.72
62.4
52.9
79.6(lq)
98.3(lq)
35.1
476.1(g)
152.0(g)
243.1
415.5
207.5
51.9
224.4
45
104.6
24.06
30.1
30.1
37.6(g)
90.0
36.6
516.7
167.6
37.9
81.6
37.3
533.0
173.9
38.1
73.2
37.7
541.4
177.0
28.5(c)
30.1(lq)
30.1
30.1
63.8
76.5
89.2
102.0
27.4
32.1
38.0
54.4
90.8
41.3
41.12
8.40
30.1(lq)
316
274
192
83.0
115.7
79.7
106.7(c)
93.5
189.0
152.0
72.0
96.4
83.9
72.6
51.8
87.0
114.7
83.1
133.9(lq)
115.9
209.8
167.7
77.1
96.8
84.4
77.7
54.9
91.4
117.2
85.5
82.3(g)
138.3
223.1
175.9
80.3
99.3
110.9
82.8
57.3
95.9
119.8
101.2
81.5
232.2
182.2
82.1
101.8
113.0(lq)
87.9
59.4
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.131
THERMODYNAMIC PROPERTIES
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
⌬Hm
Substance
Fe2O3, ⌬Ht ⫽ 0.67
Fe3O4
Fe(OH)2
Fe(OH)3
FeS, ⌬Ht ⫽ 0.40138
⌬Ht ⫽ 0.095325
FeS2 marcasite
pyrite
FeSiO3
Fe2SiO4
FeSO4
Fe2(SO4)3
FeTiO3 ilminite
Krypton
Kr
Lanthanum
La, ⌬Ht ⫽ 2.85868
LaCl3
La2O3
Lead
Pb
Pb(BO2)2
PbB4O7
PbBr2
Pb(CH3)4
Pb(C2H5)4
PbCl2
PbCO3
PbF2, ⌬Ht ⫽ 1.46310
PbI2
PbMoO4
PbO, ⌬Ht ⫽ 0.17488
PbO2
Pb3O4
PbS
PbSiO3
Pb2SiO4
PbSO4, ⌬Ht ⫽ 17.2866
PbSO4 · PbO
Lithium
Li
Li2AlF6, ⌬Ht ⫽ 9.5562
LiAlO2
LiBH4
LiBeF3
Li2BeF4
LiBO2
Li2B4O7
LiBr
LiCl
⌬Hv
⌬Hs
677
138.1
243.5
31.5
92
90.8
1.37
111.4
122.0
402.1
192.1
4.77
179.5
195.2
16.44
10.86
8.80
21.9
133
173
127
185.3
14.7
23.4
157
104
172
25.5
207
18.8
26.0
51.0
40.2
230
27.2
44.0
33.8
121
17.6
19.9
600 K
800 K
1000 K
120.1
171.1
102.1
118.0
89.2
141.2
212.5
111.3
140.6
62.0
158.2
252.9
118.9
154.8
58.6
150.6
69.2
68.9
100.8
150.9
116.7
307.0
128.1
74.6
74.3
114.3
168.5
138.0
363.3
132.8
78.7
78.3
124.5
179.7
149.4
393.3
82.8
82.5
133.9
189.1
28.5
105.8
117.3
29.8
110.1
124.7
31.2
114.3
128.9
32.5
118.7
132.3
27.7
129.7
207
81.3
29.4
162.3
265
88.8
30.0
29.4
305
330
112.1(lq) 112.1
80.1
99.7
76.1
78.9
135.3
50.4
67.6
173.1
50.5
101.5
152.0
108.7
157.3
85.9
123.6
82.5
83.7(c)
148.9
55.4
111.5(lq) 111.5
147.6
89.1
95.6
108.6(lq) 108.6
159.0
168.2
55.0
57.8
190.8
52.4
113.5
173.3
128.6
182.5
199.2
54.3
125.6
184.2
152.4
211.7
56.2
138.4
189.1
177.3
242.0
29.5(lq) 28.9
262.8
290.8
92.7
98.2
28.8
318.6
102.0
129.7(c)
180.2(c)
85.1
241.1
56.1
55.6
159.0
232.1
108.3
300.2
65.3(lq)
123.4
164.9
59.0
409.2
9.08
6.20
43.1
3.00
110.5
87
400 K
147.1
265
107.1
159.3
27.6(c)
236.4
81.5
91.0
104.6
150.5
81.1
197.6
51.3
51.0
159.0(lq)
232.1(lq)
96.9
274.4
64.5(c)
65.8
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.132
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds (Continued)
cap height
base of text
Cp
Substance
LiClO4
Li2CO3, ⌬Ht ⫽ 0.561350
⌬Ht ⫽ 2.238410
LiF
LiH
LiI
LiIO3, ⌬Ht ⫽ 2.22260
Li3N
LiNO3
Li2O
Li2O2
LiOH
Li2SiO3
Li2Si2O5, ⌬Ht ⫽ 0.941936
Li2SO4, ⌬Ht ⫽ 28.5575
Li2TiO3, ⌬Ht ⫽ 11.511212
Lutetium
Lu
Magnesium
Mg
MgAl2O4
MgBr2
MgCl2
MgCO3
MgF2
MgH2
MgI2
Mg3N2, ⌬Ht ⫽ 0.46550
⌬Ht ⫽ 0.92788
Mg(NO3)2
MgO
Mg(OH)2
Mg3(PO4)2
MgS
Mg2Si
MgSiO3, ⌬Ht ⫽ 0.67630
⌬Ht ⫽ 1.63985
Mg2SiO4
MgSO4
MgTiO3
Mg2TiO4
MgWO4
Manganese
Mn, ⌬Ht ⫽ 2.23727
⌬Ht ⫽ 2.121101
⌬Ht ⫽ 1.881137
MnBr2
Mn3C, ⌬Ht ⫽ 14.941037
MnCl2
Mn2(CO)10
⌬Hm
⌬Hv
⌬Hs
29
41
27.09
22.6
14.6
400 K
130.0(c)
112.2
146.8
276.1
231.3
24.9
58.6
250.6
600 K
800 K
161.0(lq) 161
149.4
159.0
1000 K
161
46.5
34.8
51.6
46.4
55.7
57.3
59.6
87.1
106.4
124.4
141.0
64.0
82.7(c)
58.0
118.8
174.9
139.2
127.4
73.8
80.2(g)
68.2(c)
134.3
205.7
168.5
141.5
80.6
81.4
87.1(lq)
144.4
222.6
196.1
149.0
86.2
82.1
87.1
152.3
235.4
223.4
153.9
28.2
157.9
81.4
79.9
109.0
75.3
30.5
169.5
84.5
82.5
122.3
78.6
96.3(c)
123.8
20.88
28.0
53.8
7.50
110.7
187.9
(22)
414
8.48
192
39.3
43.1
59
58.5
14
26
128
147
149
156.2
222
249.2
274.1
399.5
26.1
138.0
77.3
75.7
89.9
68.5
206
107.6
78.4
113.8
83.0
119.9
168.5
42.6
91.7
240.2
225.5
47.4
49.7
51.2
282.2
320.6
351.5
73.8
94.2
79.8
107.0
83.9
115.8
87.4
120.3
137.6
110.0
105.2
146
123.4
156.4
127.6
118.5
164
137.0
167.1
140.5
125.4
175
146.1
174.6
151.7
129.9
184
154.8
37.5
77
121
63
85.8
71
14.6
12.9
221
28.5
31.9
34.9
33
113
30.7
149.0
77.8
104.4
77.2
82.8
115.0
81.8
87.7
121.7
85.1
62.8
178.7
131.8
80.5
100.4(lq)
127.4
96.2(lq)
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.133
THERMODYNAMIC PROPERTIES
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
MnF2
MnI2
MnO
MnO2
Mn2O3
Mn3O4, ⌬Ht ⫽ 20.791172
MnS
MnSiO3
MnSO4
MnTiO3
Mercury
Hg
HgBr2
Hg2Br2
HgCl2
Hg2Cl2
HgF2
Hg2F2
HgI2, ⌬Ht ⫽ 2.52129
Hg2I2
HgO
HgS, ⌬Ht ⫽ 4.2386
Molybdenum
Mo
MoBr3
MoCl4
MoCl5
Mo(CO)6
MoF6, ⌬Ht ⫽ 8.17⫺9.65
MoO2
MoO3
MoS2
Mo2S3
Neodymium
Nd, ⌬Ht ⫽ 2.98862
Nd2O3
Neon
Ne
Neptunium
Np, ⌬Ht ⫽ 8.37280
Nickel
Ni
NiCl2
Ni(CO)4
NiF2
NiO
NiS, ⌬Ht ⫽ 6.4379
Ni3S2, ⌬Ht ⫽ 56.2556
NiS2
NiSO4
⌬Hm
⌬Hv
⌬Hs
23.0
42
54.4
26.4
66.9
2.29
17.9
59.1
58.9
19.41
58.9
23.0
92
18.9
27.8
59.2
37.48
17
18.8
4.33
48
617
61.5
62.8
72.5
27.2
61.4
664
69.9
28.0
138
130
7.14
0.335
3.20
17.48
71.2
13.8
30.1
19.7
65.7
289
400 K
600 K
800 K
80.7
89.0
52.4
75.1
129.4
179.7
53.7
119.5
147.7
125.7
1000 K
70.6
78.1
47.5
63.4
109.0
157.3
50.7
100.9
119.0
111.7
75.7
83.6
50.3
71.1
120.8
169.5
52.2
113.1
136.7
121.2
85.9
108.8
54.2
27.4
78.3
109.6
77.0(c)
106.0
77.0
104.7
82.0(c)
110.4(c)
48.3
48.0
27.1(lq) 20.8(g)
102.1(lq) 102.1
115.6
102.9(lq)
112.1
81.2
85.4(c)
111.7
116.9
84.1(lq) 62.2(g)
136.4(lq)
54.1
51.0
54.1
25.1
106.9
135.0(c)
167.4(c)
26.5
27.4
109.8
112.7
146.4(lq)
175.7(lq) 175.7
175.7
133.1
63.5
83.1
68.9
117.5
145.3
71.2
91.8
73.6
127.4
150.4
76.5
100.0
76.2
135.2
153.0
81.4
109.0
78.2
142.3
28.2
120.3
32.1
130.0
36.9
137.7
42.0
144.4
30.0
79.9
173.2
78.5
51.8
13.2
139.9
70.0
150.8
31.0
80.9
182.1
82.6
53.6
13.7
150.7
81.0
159.2
32.2
137.2
189.3
55.2
124.2
128.8
20.8
102.1
102.9(lq)
62.2
28.4
1.71
336
34.8
377.5
231.0
29.3
28.5
76.3
160.4(g)
76.4
52.2
12.1
127.1
72.8
142.6
188.6
55.2
15.1
188.6
85.2
167.4
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.134
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds (Continued)
cap height
base of text
Cp
Substance
NiWO4
Niobium
Nb
NbBr5
NbCl5
NbF5
NbI5
NbN, ⌬Ht ⫽ 4.21370
NbO
NbO2, ⌬Ht ⫽ 3.42817
Nb2O5
Nitrogen
N2, ⌬Ht ⫽ 0.230⫺237.53
NF3
N2F2 cis
trans
N2F4
NH3 (see Ammonium)
N2H4
NO
NOCl
NOF
NOF3
NO2
NO2Cl
NO2F
NO3
N2O
N2O4
N2O5
NSF
Osmium
Os
OsF6
OsO4
Oxygen
O2, ⌬Ht ⫽ 0.092⫺249.49
⌬Ht ⫽ 0.745⫺229.38
O3
OF2
O2F2
Palladium
Pd
PdCl2
PdO
Phosphorus
P
P4, ⌬Ht ⫽ 0.521⫺77.8
PBr3
PClF2
⌬Hm
30
24.0
38.3
12.2
37.7
46.0
85
92
104.3
0.720
15.4
14.2
12.66
2.30
⌬Hv
689.9
50.2
52.7
52.3
58.6
⌬Hs
726
112.5
618
598.0
5.577
11.6
91.6
87.9
13.3
41.8
13.83
25.8
19.3
44.7
16.53
38.12
62.3
600 K
800 K
1000 K
138.9
144.6
150.3
155.9
25.4
147.9(c)
170.7(c)
43.5(lq)
182.0(c)
45.4
44.0
63.5
145.0
26.3
27.2
147.9(lq)
127.9(g) 129.8
28.0
130.7
49.9
47.2
71.7
160.7
51.6
49.5
70.5
170.0
53.2
51.5
87.5
175.5
30.1
71.4
68.3
68.9
31.4
76.0
73.6
73.8
32.7
78.4
76.6
76.7
77.6
31.2
50.7
48.9
90.9
46.4
68.1
66.4
67.4
48.4
104.0
128.4
88.2
32.8
53.2
51.7
97.0
50.4
73.1
71.9
73.3
52.2
113.4
137.0
96.4
34.0
54.9
53.5
100.5
53.0
76.1
75.3
76.5
54.9
119.2
141.4
25.1
25.9
26.7
27.4
30.11
32.09
33.74
34.88
43.74
64.3
49.86
72.4
53.15
76.4
55.02
78.6
26.5
27.7
28.8
30.0
37.6
49.5
61.3
14.2
73.3(g)
78.9
78.4
81.2
80.4
82.0
29.2
61.9
58.2
60.2
25.7
18.0
6.54
14.65
400 K
61.7(g)
29.9
47.1
44.6
78.7
40.5
59.6
57.0
55.9
42.7
88.5
110.9
22.2
57.85
9.8
0.444
738
28.62
39.54
6.820
8.204
10.84
11.09
19.1
16.74
40.1
0.659
362
0.66
56.5
38.8
17.6
12.4
58.9
81.4
82.4
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.135
THERMODYNAMIC PROPERTIES
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
PClF3
PCl2F
PCl3
PCl5
PF3
PF5
PH3
P2H4
PI3
P4O6
P4O10
POBr3
POCl3
POClF2
POCl2F
POF3
PSCl3
PSF3
P4S3
Platinum
Pt
PtS
PtS2
Plutonium
Pu, ⌬Ht ⫽ 13.4122
⌬Ht ⫽ 2.9206
⌬Ht ⫽ 3.3319
⌬Ht ⫽ 66.9480
PuBr3
PuCl3
PuF3
PuF4
PuF6
PuI3
PuO2
Polonium
Po
Potassium
K
KAlCl4
K3AlCl6
K3AlF6
KBF4, ⌬Ht ⫽ 14.06283
KBH4
KBO2
K2B4O7
KBr
KCl
KClO4, ⌬Ht ⫽ 13.77299.6
KCN, ⌬Ht ⫽ 1.167⫺104.9
⌬Hm
7.10
1.130
14.06
27.2
38
13.1
⌬Hv
17.6
24.9
30.5
9.2
19.58
59.8
55.2
63.6
59.8
65.3
17.6
50.2
32.1
64.9
76.0(g)
120.1(g)
66.3(g)
99.2(g)
41.8
79.7
126.8
74.0
114.7
50.9
81.2
129.5
77.6
121.9
58.5
81.9
130.7
79.5
125.6
64.3
172.1
260.3
200.8
336.0(c)
213.5
220.0
92.0(g)
79.3
87.7
79.1
96.5
84.5
184.1
99.1
91.6
96.6
91.2
102.4
95.3
184.1(lq)
102.5
97.7
100.9
97.4
104.8
100.3
155.0(g)
108.5
101.1
103.2
100.9
105.9
102.9
155.0
106.0
15.06
2.82
400 K
16.5
17.2
14.60
28.8
43.9
43.43
34.3
25.4
30.96
23.22
22.17
⌬Hs
469
38.6
21.1
545
333.5
236.4
241.0
29.9
600 K
800 K
1000 K
26.4
51.4
69.9
27.5
53.8
75.9
28.5
56.2
8l.9
29.6
58.6
87.9
39.5
46.9
40.6
40.6
30.1
183.2
279.5
269.4
142.1
106.0
89.8
250.5
56.4
55.9
165.3
66.4
29.8
196.6
295.8
286.8
150.9
118.4
98.5
271.1
60.4
59.2
30.7
202.1
292.5
304.6
374.9
299.6
48.5
559.8
102.91
2.321
76.90
17.7
31
104
25.5
26.53
238.9
149.2
124.3
14.6
157.1
88.8
31.5(lq)
165.5
259.2
244.5
130.8
100.9
76.7
206.3
53.8
53.0
138.5
66.3
66.5(c)
302.0
167.2
283.3
68.0
64.0
66.5(lq)
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.136
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds (Continued)
cap height
base of text
Cp
Substance
K2CO3
K2CrO4
K2Cr2O7
KF
KH
KHF2, ⌬Ht ⫽ 11.22196.7
KI
KNO3, ⌬Ht ⫽ 5.10128
K2O, ⌬Ht ⫽ 6.20372
KO2, ⌬Ht ⫽ 0.302⫺79.7
⌬Ht ⫽ 0.157⫺42.3
K2O2
KOH, ⌬Ht ⫽ 6.4243
KPO3
K3PO4
K2P2O7
KReO4
K2S
K2SiO3
K2SO4, ⌬Ht ⫽ 8.45584
K2WO4
K2ZrCl6
Praseodymium
Pr
Promethium
Pm
Protactinium
Pa
PaCl3
Radium
Ra
Radon
Rn
Rhenium
Re
ReF5
ReF6
ReF7
ReO2
ReO3
Re2O7
ReOCl4
ReOF4
ReOF5
Rhodium
Rh
Rh2O3
Rubidium
Rb
RbBr
⌬Hm
27.6
29.0
36.7
27.2
6.62
24.0
10.1
8.60
8.8
37.2
58.6
85.4
16.15
50
34.39
19.5
23.0
⌬Hv
⌬Hs
141.8
231.8
190.9
202.4
142.7
77.3
192
82.5
6.89
331
356
7.13
289
328
12.34
92.9
8.5
3.247
60.43
4.6
7.5
21.8
64.2
13.5
400 K
600 K
800 K
170.0
1000 K
128.1
150.7
51.0
44.1
86.1(c)
53.9
108.4
79.1
83.9
54.3
57.4
51.9
104.6(lq)
57.3
62.6(c)
120.5
100.0
100.0
90.2
107
72.5
121
79.0(c)
87.7
135.6
147.6
157.7
172.5
170.7
199.6
179.1
226.1
26.0
26.9
28.0
29.1
26.0
109.9
28.0
121.4
30.0
133.0
32.0
144.5
31.7
52.8
30.9
54.9
83.0(lq)
189.0
61.2
72.4(lq)
100.0
83.0
481
61.3
113
18.10
704
58.1
28.7
38.3
779
274.6
208.4
74.1
45.6
61.0
32.0
26.59
494
2.19
15.5
75.77
154.8
37.4
556
30.7
57.1(c)
66.9(lq)
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.137
THERMODYNAMIC PROPERTIES
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
RbCl
RbClO4, ⌬Ht ⫽ 12.59284
RbF
RbI
RbNO3
RbOH
Ruthenium
Run, ⌬Ht ⫽ 0.131035
⌬Ht ⫽ 0.961500
Samarium
Sm, ⌬Ht ⫽ 3.11917
Sm2O3, ⌬Ht ⫽ 1.05922
Scandium
Sc
ScCl3
Sc2O3
Selenium
Se, ⌬Ht ⫽ 0.75150
SeF4
SeF6
SeO2
SeOCl2
Silicon
Si
SiBr4
SiC beta
SiCl4
SiClF3
SiCl2F2
SiF4
SiH4
Si2H6
Si3H8
SiH3Br
SiH2Br2
SiHBr3
SiH3Cl
SiH2Cl2
SiHCl3
SiH3F
SiH2F2
SiHF3
SiI4
Si3N4
SiO2 cristobalite
SiO2 quartz
⌬Ht ⫽ 0.73574
⌬Ht ⫽ 2.0806
SiOF2
SiS2
⌬Hm
⌬Hv
⌬Hs
400 K
600 K
800 K
1000 K
18.4
165.7
52.3
54.3
56.4(c)
64.0(lq)
17.3
12.5
5.61
6.78
177.8
150.6
51.9
57.9
55.1
64.9
57.3(c)
72.3
66.9(lq)
38.59
591.6
24.5
25.7
27.0
28.2
33.3
125.2
39.1
135.3
44.3
141.4
49.3
146.3
96.7
106.4
102.7
111.1
108.7
115.8
114.6
120.5
8.62
14.1
6.69
165
207
332.7
376
95.48
47.2
8.4
4.23
28.1(c)
26.8
359
37.9
7.60
28.7
18.7
21.2
0.67
12.1
21.2
28.5
24.4
31
34.8
21
25.2
26.6
18.8
16.3
16.2
56.9
450
29.7
25.7
8.51
7.7
20.9
35.1
127.9
141.3
147.1
150.7
22.3
146.4(lq)
34.1
96.9(g)
88.3
24.5
104.9(g)
41.8
102.6
97.5
25.7
106.2
45.9
104.8
101.7
26.5
106.2
48.4
106.0
103.8
94.5
42.7
50.21
19.7
35.2(lq)
24.2
25.7
79
600
83.1
51.5
94.1
65.9
99.4
76.7
102.3
84.5
60.7
71.5
83.7
57.2
74.0
82.9
92.5
71.8
83.1
90.0
97.2
81.7
89.4
94.6
100.2
88.3
106.9
145.8
107.3
158.2
164.0(lq)
110.7
106.0(g)
129.7
53.5
64.4
76.2
68.94
61.3
78.6
70.4
81.7
75.0
83.4
77.6
85.4
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.138
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds (Continued)
cap height
base of text
Cp
Substance
Silver
Ag
AgBr
AgCl
Ag2CO3
AgF
AgI, ⌬Ht ⫽ 6.15147
AgNO3, ⌬Ht ⫽ 2.5160
Ag2O
Ag2S, ⌬Ht ⫽ 5.86176
⌬Ht ⫽ 5.86586
Sodium
Na
NaAlCl4
Na3AlCl6
Na3AlF6, ⌬Ht ⫽ 8.37565
⌬Ht ⫽ 0.42880
NaAlO2, ⌬Ht ⫽ 1.297467
NaBH4, ⌬Ht ⫽ 0.999⫺83.3
NaBO2
Na2B4O7
NaBr
NaBrO3
NaCl
NaClO3
NaClO4, ⌬Ht ⫽ 13.98308
NaCN
Na2CO3, ⌬Ht ⫽ 0.690450
NaF
NaH
NaI
NaIO3, ⌬Ht ⫽ 35.1422
NaNO3
NaO2, ⌬Ht ⫽ 1.464⫺76.7
⌬Ht ⫽ 1.548⫺49.9
Na2O, ⌬Ht ⫽ 1.76750.1
⌬Ht ⫽ 11.92970.1
Na2O2, ⌬Ht ⫽ 5.73512
NaOH, ⌬Ht ⫽ 72299.6
Na2S
Na2S2
Na2SiO3
Na2Si2O5, ⌬Ht ⫽ 0.42678
Na2SO4, ⌬Ht ⫽ 10.91241
Na2TiO3
Na2WO4, ⌬Ht ⫽ 30.85587.7
⌬Ht ⫽ 4.113588.9
Strontium
Sr, ⌬Ht ⫽ 0.84547
SrBr2, ⌬Ht ⫽ 12.2645
⌬Hm
⌬Hv
11.95
9.12
13.2
258
198
199
16.7
9.41
11.5
179.1
143.9
⌬Hs
25.7
59.0
56.9
54.1(c)
64.7
112.5
73.0
86.6
14.1
2.60
97.42
107.5
107.28
36.2
76.9
26.11
28.11
28.16
22.1
8.79
29.64
33.35
400 K
239.7
322.2
160.7
217.5
148.1
172.8
176.1
284.9
23.60
600 K
800 K
1000 K
26.8
71.8(c)
54.4
122.6
58.4
56.5
128.0
28.4
62.3(lq)
54.4
30.0
62.3
54.4
56.5
58.6(lq)
90.5
90.5
90.5
31.5(lq)
164.8(c)
254.4
234.6
29.3
29.9
29.0
273.0
261.8
196.8
282.8
83.4
94.6
75.4
221.7
53.5
94.3
108.6
88.6
268.6
56.1
98.7
102.3
52.3
55.5
59.3
72.5
68.8
163.3
52.7
50.7
56.2
69.0
153.3
55.7
179.8
59.5
76.3
84.5
92.6
75.8
85.7
91.3
136.0(c)
68.7
125.1
49.6
42.5
53.8
97.2
103.2
444.9(lq)
58.6
61.1
58.5(c)
64.9(lq)
15
47.7
6.60
19.3
175.3
228.2
51.8
35.6
23.6
70.3
23.80
7.43
10.1
136.9
194.1
164.0
310
97.7
64.9(c)
20.1
104.3
127.8
183.4
145.1
108.4
86.1(lq)
20.9
115.4(c)
147.1
217.6
175.3
113.6
84.9
21.5
124.7(lq)
159.7
235.2
187.3
155.3
178.2
198.7
27.8
79.0
29.8
82.7
31.9
87.6(c)
94.9
83.7
22.0
124.7
169.4
292.9
200.3
34.1
116.4(lq)
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.139
THERMODYNAMIC PROPERTIES
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
⌬Hm
Substance
SrCl2, ⌬Ht ⫽ 6.0
SrCO3, ⌬Ht ⫽ 19.7924
SrF2, ⌬Ht ⫽ 0.041148
⌬Ht ⫽ 0.041211
SrI2
SrH2
SrMoO4
SrO
SrO2
Sr(OH)2
SrS
SrSO4
Sulfur
S monoclinic
⌬Ht ⫽ 0.40095.2
S8
SCl2
S2Cl2
SF4
SF6
S2F10
SO2
SO3
SOCl2
SOF2
SO2Cl2
SO2ClF
SO2F2
Tantalum
Ta
TaB2
TaBr5
TaC
Ta2C
TaCl5
TaF5
TaI5
TaN
TaO2
Ta2O5
Technetium
Tc
TcF6
TcO3F
Tellurium
Te
TeCl4
TeF4
TeF6
Te2F10
727
⌬Hv
⌬Hs
17.5
40
28.5
248.1
356
320
19.67
23
189.7
451.0
83.7
107.1
79.8
286.6
80.7
86.3
131.5
48.5
81.3
88.5
50.2
113.5
23
63
36
1.727
45
5.02
32.4
36.0
26.4
17.1
24.94
40.7
31.7
21.8
31.38
62.2
9.0
22.92
43.14
31
30.1
20.0
36.57
83.7
45.6
105
732.8
41.6
18.8
41.8
67
54.8
56.9
64.9
778
62.3
94.1
120
33.29
4.72
22.5
585.2
31.1
39.5
17.49
18.8
114.1
77
34.3
23.2
167.1
53.6
124.3(lq)
87.5
116.4
211.4
43.43
57.7
71.3
64.3
85.2
81.1
76.5
25.8
57.6
168.2
41.7
66.7
148.(c)
182.0(lq)
164.6
45.4
47.7
147.5
25.1
28.2
39.5
600 K
78.9
95.1
74.7
81
7.40
8.60
400 K
145.4
52.0
85.0
115.0(c)
53.2
124.6
23.3(lq)
177.9
56.0
80.8(g)
97.3
136.1
246.4
48.9
67.3
76.4
72.4
94.5
92.1
89.3
800 K
90.8
116.1
81.0
91.8(c)
154.0
54.3
1000 K
105.8
124.0
85.8
110.0(lq)
161.2
56.1
157.8(lq) 157.8
54.9
56.2
135.7
146.9
21.8(g)
21.5
186.7
56.9
82.6
101.7
144.8
261.8
52.3
72.8
78.9
76.4
99.4
97.9
96.1
193.6
57.4
83.5
103.8
149.3
269.2
54.3
76.0
80.3
78.6
102.1
101.1
99.9
26.8
66.6
27.5
72.2
27.9
83.3
46.5
72.4
129.(g)
49.1
76.2
131
51.1
79.5
132
182.0(c)
51.9
52.3
164.4
120.0(g)
58.5
54.6
175.2
120.6
65.0
55.7
182.8
26.8
28.5
30.1
28.0
138.9(c)
32.3(c)
37.7(lq) 37.7
222.6(lq) 108.8(g) 108.8
132.2
143.8
148.7
151.7
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.140
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds (Continued)
cap height
base of text
Cp
Substance
TeH2
TeO2
Terbium
Tb
Thallium
Tl, ⌬Ht ⫽ 0.38234
TlBr
TlCl
Tl2CO3
TlF
TlI
TlNO3
Tl2O
Tl2O3
Tl2S
Tl2SO4
Thorium
Th, ⌬Ht ⫽ 2.731360
ThBr4
ThCl4, ⌬Ht ⫽ 5.0406
ThF4
ThI4
Th3N4
ThO2
ThOCl2
Th(SO4)2
Thullium
Tm
Tin
Sn white, ⌬Ht ⫽ 2.0913
SnBr2
SnBr4
SnCl2
SnCl4
SnH4
SnI2
SnO
SnO2, ⌬Ht ⫽ 1.88410
⌬Ht ⫽ 1.26540
SnS, ⌬Ht ⫽ 0.67602
SnS2
Titanium
Ti, ⌬Ht ⫽ 4.2893
TiB
TiB2
TiBr2
TiBr3
TiBr4
TiC
TiCl2
⌬Hm
⌬Hv
⌬Hs
400 K
600 K
800 K
1000 K
67.9
72.5
76.1
79.2
27.5(c)
53.5
53.6
30.1(lq)
59.5(c)
55.2(c)
30.1
75.5(lq)
59.4(lq)
30.1
67.8
59.4
53.9
66.8(lq)
60.6(c)
67.3
72.0(lq)
72.0
28.4
30.5
32.7
34.4
126.7
132.7
136.4
139.6
169.5
67.4
97.0
197.0
196.5
72.4
102.5
243.2
222.7
75.3
105.9
289.4
77.7
108.6
23.9
29.1
10.15
4.14
16.4
15.56
18.4
13.87
14.73
9.56
30.3
53
12
23.0
13.81
66.9
40.2
44.0
61.4
293
389
165
99.6
102.2
181
115.9
104.7
154
514
146.4
258
56.9
1218.0
16.84
7.03
7.2
11.9
12.8
9.20
14.15
247
232.2
296.1
102
43.5
86.8
34.9
19.1
105
425
28.9
158.0(lq)
83.3(c)
469
100.4
206.2
138.8
12.9
71
44.4
232
212
28.9(c)
28.7(lq)
106.8(g) 107.3
92.1(lq) 92.1
28.7
107.5
92.1
45.8
64.4
48.7
73.9
51.7
78.5
54.6
81.8
50.5
71.9
55.5
75.4
61.3
79.0
82.5
29.5
50.9
72.1
84.4
147.3
106.9
49.9
82.2
32.1
51.9
76.9
86.7
156.7
107.3
51.2
85.9
26.9
40.3
54.9
79.9
105.8
151.9(lq)
40.7
73.4
28.6
48.6
66.2
82.1
125.5
106.1(g)
47.7
78.4
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.141
THERMODYNAMIC PROPERTIES
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds (Continued)
top of rh
base of rh
cap height
base of text
Cp
Substance
TiCl3
TiCl4
TiF3
TiF4
TiH2
TiI2
TiI3
TiI4, ⌬Ht ⫽ 9.9106
TiN
TiO, ⌬Ht ⫽ 4.2992
TiO2 rutile
Ti2O3, ⌬Ht ⫽ 1.138197
Tungsten
W
WBr5
WBr6
WCl4
WCl5
WCl6, ⌬Ht ⫽ 4.1177
W(CO)6
WF6, ⌬Ht ⫽ 2.067⫺8.5
WO2
WO3, ⌬Ht ⫽ 1.49777
WOCl4
WOF4
WO2Cl2
Uranium
U, ⌬Ht ⫽ 2.93672
⌬Ht ⫽ 4.791772
UBr3
UBr4
UC
UCl3
UCl4
UCl5
UCl6
UF3
UF4
UF5
UF6
UH3
UI4
UN
UO2
UO3
U3O8
UOCl2
UO2Cl2
UO2F2
⌬Hm
9.97
⌬Hv
124
36.2
⌬Hs
166.3
222
97.9
217
19.8
66.9
41.8
58.0
105
58.4
673
52.31
17.1
806.7
81.5
20.5
6.60
68.1
52.7
4.10
27.05
73.4
45
5.0
9.14
76.6
67.8
56
417.1
43.9
55.2
119.2
46.4
44.8
35.6
20.9
193.0
141.4
75.3
50.2
42.7
33.5
19.19
221.8
70.7
130.6
28.90
851
100
79.2
72.0
26.65
666.3
550.2
525
48.20
400 K
600 K
800 K
1000 K
98.6
146.2(lq)
93
126.7(c)
39.3
87.0
117.5
148.1(c)
43.8
45.0
63.6
117.5
102.0
104.4(g)
98
100.2(g)
53.8
88.4
119.0
156.6(lq)
48.7
50.8
70.9
136.4
104.4
106.0
103
103.3
63.1
89.9
120.4(c)
25.7(g)
50.6
55.2
73.9
143.0
106.7
106.7
109
104.9
68.5
91.3
20.6(g)
27.8
52.1
59.1
75.3
146.4
24.9
166.(c)
192.5(c)
135.3
167.4(c)
192.5(c)
25.9
182.(lq)
156.3(g)
146.2(c)
129.5(g)
200.8(lq)
26.7
132.2(g)
157.0
106.7(g)
131.0
155.8(g)
27.6
132.5
157.4
107.2
131.8
156.6
132.4(g)
63.4
82.2
157.(c)
107.8
115.1
145.0
71.3
93.1
123.2(g)
119.8
135.6(c)
150.3
75.5
98.2
127.0
125.0
153.0
78.2
101.7
129.1
127.8
41.6
41.8
29.0
131.4
64.6
102.8
126.1
150.9
182.8
99.0
119.1
136.4
140.5(g)
50.9
140.6
52.2
72.7
88.9
266.0
101.9
118.1
113.9
34.8
140.1(c)
58.3
107.7
134.4
159.8(c)
214.0
104.9
125.0
143.1(c)
148.7
57.4
149.5(c)
56.3
79.8
95.3
290.7
109.6
126.2
122.5
163.2(lq)
60.3
113.6
142.0
186.7(lq)
158.8
111.0
130.9
166.6(lq)
152.2
66.1
165.7(lq)
58.3
83.2
99.0
304.2
115.1
130.0
126.7
163.2
62.2
119.9
162.5
134.5(g)
168.0
117.2
136.8
154.4
165.7
59.8
85.5
129.5
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.142
INTERACTIVE
top of rh
base of rh
SECTION 6
TABLE 6.4 Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
the Elements and Inorganic Compounds (Continued)
cap height
base of text
Cp
Substance
Vanadium
V
VCl4
VF5
VN, ⌬Hdec ⫽ 227.62346
VO
VO2, ⌬Ht ⫽ 4.2172
V2O3, ⌬Ht ⫽ 1.623⫺104.3
V2O4, ⌬Ht ⫽ 9.067
V2O5
VOCl3
Xenon
Xe
Ytterbium
Yb
Yttrium
Y, ⌬Ht ⫽ 4.971485
Y2O3, ⌬Ht ⫽ 1.301057
Zinc
Zn
ZnBr2
ZnCl2
ZnF2
ZnO, ⌬Ht ⫽ 13.41020
Zn2SiO4
ZnSO4, ⌬Ht ⫽ 20.3740
Zirconium
Zr, ⌬Ht ⫽ 4.02862
ZrB2
ZrBr2
ZrBr4
ZrC
ZrCl2
ZrCl3
ZrCl4
ZrF2
ZrF4
ZrI2
ZrI3
ZrI4
ZrN
ZrO2, ⌬Ht ⫽ 5.021205
ZrSiO4
6.2
⌬Hm
21.5
2.30
50.0
63
56.9
117.2
112.1
64.5
1.81
⌬Hv
459
41.4
44.5
400 K
600 K
516
42.5
26.2
161.7(lq)
27.5
100.1(g)
28.7
102.6
30.1
104.7
741
43.3
49.6
67.2
117.5
135.3
151.0
48.2
53.5
74.3
127.3
148.4
168.3
51.2
57.1
77.8
132.6
155.5
177.3
53.7
60.5
80.2
138.0
160.7
183.7
263.6
36.8
12.64
7.66
159
11.42
105
365
7.32
16.7
10.25
⌬Hs
20.79(g)
425
123.6
118
126
190.1
52.3
21.00
104.6
63
79.5
27
50
33
64.2
25.1
573
610.0
131.5
230
45.0
289
190
110.5
404
237.7
113
176
126.4
67.4
87.0
624
20.79
800 K
20.79
1000 K
20.79
27.3
113.3
28.5
121.3
29.9
124.7
31.5
126.9
26.3
70.1(c)
69.9(c)
66.9
49.4
129.4
116.0
28.6(c)
78.8(lq)
100.8(lq)
69.1
52.4
141.4
137.4
31.4(lq) 31.4
113.8
61.5(g)
100.8
100.8
71.4
73.7
54.1
55.5
153.4
165.4
139.7
142.0
25.9
57.5
87.9
129.3
43.6
76.0
101
125.4
70
113.5
95.0
105.9
131.0
44.8
63.9
114.6
27.3
65.8
90.2
133.3(c)
49.4
80.0
106
131.1(c)
76
124.0
96.6
106.7
134.6(c)
48.7
70.2
133.7
29.0
69.7
92.5
107.2(g)
52.3
83.1
109
106.5(g)
81
129.4
106.1
107.1(c)
107.6(g)
50.9
73.5
142.7
31.1
72.1
94.8
107.6
53.4
85.9
112
107.1
84
134.1
123.6
82.9(g)
107.6
52.7
75.7
147.3
CRITICAL PHENOMENA
The critical temperature, Tc , of a gas is the temperature above which the gas cannot be liquefied no
matter how high the pressure.
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.143
THERMODYNAMIC PROPERTIES
The critical pressure, Pc , is the lowest pressure which will liquefy the gas at its critical temperature.
The critical volume, Vc , is the volume of 1 mol at the critical temperature and the critical pressure.
It can be computed from the critical density, ␳c , as follows:
top of rh
base of rh
cap height
base of text
Molecular weight (in g · mol⫺1 )
⫽ Vc (in cm3 · mol⫺1)
␳c (in g · cm⫺3)
The critical pressure, critical molar volume, and critical temperature are the values of the pressure,
molar volume, and thermodynamic temperature at which the densities of coexisting liquid and gaseous phases just become identical. At this critical point, the critical compressibility factor, Zc , is:
Zc ⫽
PcVc
RTc
TABLE 6.5 Critical Properties
Substance
Acetaldehyde
Acetic acid
Acetic anhydride
Acetone
Acetonitrile
Acetophenone
Acetyl chloride
Acetylene
Acrylic acid
Acrylonitrile
Air
Allene
Allyl alcohol
Aluminum tribromide
Aluminum trichloride
2-Aminoethanol
Ammonia
Aniline
Anthracene
Antimony tribromide
Antimony trichloride
Argon
Arsenic
Arsenic trichloride
Arsine
Arsine-d3
Benzaldehyde
Benzene
Benzoic acid
Benzonitrile
Benzyl alcohol
Biphenyl
Bismuth tribromide
Bismuth trichloride
Boron pentafluoride
Boron tribromide
Boron trichloride
␳c , g · cm⫺3
Tc , ⬚C
Pc , atm
Pc , MPa
Vc , cm3 · mol⫺1
193
319.56
333
235.0
272.4
436.4
235
35.2
342
263
⫺140.6
120
272.0
490
356
341
132.4
426
610
631.4
521
⫺122.3
1400
318
99.9
98.9
422
288.90
479
426.3
422
516
946
906
205
308
178.8
55
57.1
39.5
46.4
47.7
38
58
60.6
56
45
37.2
54.0
56.4
28.5
26
44
111.3
49.5
28.6
56
5.57
5.786
4.0
4.700
4.85
3.85
5.88
6.14
5.67
4.56
3.77
5.47
5.71
2.89
2.63
4.46
11.28
4.89
2.90
5.67
154
171.3
290
209
173
386
204
113
210
210
92.7
162
203
310
261
196
72.5
287
554
0.286
0.351
0.352
0.278
0.237
0.311
0.325
0.231
0.343
0.253
0.313
0.247
0.286
0.860
0.510
0.312
0.235
0.324
0.322
48.1
4.87
270
74.6
0.84
0.536
58.4
63.3
5.91
6.41
252
133
0.720
0.588
45.9
48.31
41.55
41.55
42.4
38.0
4.65
4.895
4.21
4.21
4.3
3.85
11.96
324
255
341
339
334
502
301
261
0.327
0.306
0.358
0.304
0.324
0.307
1.49
1.21
4.87
3.87
272
266
0.921
0.441
118
48.1
38.2
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.144
INTERACTIVE
top of rh
base of rh
SECTION 6
cap height
base of text
TABLE 6.5 Critical Properties (Continued)
Substance
Boron trifluoride
Bromine
Bromobenzene
Bromochlorodifluoromethane
Bromoethane
Bromomethane
Bromopentafluorobenzene
1-Bromopropane
2-Bromopropane
Bromotrifluoromethane
1,2-Butadiene
1,3-Butadiene
Butanal
Butane
Butanenitrile
Butanoic acid
1-Butanol
2-Butanol
2-Butanone
1-Butene
cis-2-Butene
trans-2-Butene
3-Butenenitrile
1-Buten-3-yne
Butyl acetate
1-Butylamine
sec-Butylamine
tert-Butylamine
Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Butyl benzoate
Butyl butanoate
Butylcyclohexane
sec-Butylcyclohexane
tert-Butylcyclohexane
Butylcyclopentane
Butyl ethyl ether
2-Butylhexadecafluorotetrahydrofuran
Butylisopropylamine
tert-Butyl methyl sulfide
1-Butyne
2-Butyne
4-Butyrolactone
Carbon dioxide
Carbon disulfide
Carbon monoxide
Carbon tetrachloride
Carbon tetrafluoride
Carbonyl chloride
Carbonyl sulfide
Cesium
␳c , g · cm⫺3
Tc , ⬚C
Pc , atm
Pc , MPa
Vc , cm3 · mol⫺1
⫺12.3
315
397
158.8
230.8
173.4
397
⫺1.8
⫺14.2
67.1
170.6
152
264.1
151.97
312.3
351
289.9
263.1
263.63
146.5
147.5
147.5
312.3
182
306.7
258.8
241.2
210.8
387.4
391
387
450
338
394
396
385.9
357.9
257.9
227.1
49.2
102
44.6
41.98
61.5
85
44.6
4.98
10.3
4.52
4.254
6.23
8.61
4.52
124
135
324
246
215
156
0.549
1.184
0.485
0.672
0.507
0.609
290.5
296.7
190.6
215.5
436
31.1
279
⫺140.2
283.3
⫺45.7
182
102
1806
39.2
44.4
42.7
42.6
37.34
38.3
39.8
43.56
41.47
41.52
39.7
40.5
40.5
38.3
49
31
41.9
41.4
37.9
28.5
29.1
29.3
26
3.97
4.50
4.33
4.32
3.784
3.88
4.03
4.414
4.202
4.207
4.02
4.10
4.10
3.88
4.96
3.14
4.25
4.20
3.84
2.89
2.94
2.97
2.63
200
219
221
258
255
285
290
275
269
267
240
238
238
265
202
400
277
278
292
497
510
490
561
31.1
26.4
26.3
3.15
2.67
2.66
534
0.462
0.462
0.76
0.247
0.245
0.279
0.228
0.242
0.304
0.270
0.276
0.270
0.234
0.240
0.236
0.253
0.258
0.290
0.264
0.263
0.250
0.270
0.263
0.273
0.318
0.292
0.63
30
15.86
3.04
1.607
390
588
0.262
0.707
46.5
50.2
4.71
5.09
220
221
0.246
0.246
72.8
78.0
34.5
45.0
36.9
56
58
7.38
7.90
3.50
4.56
3.74
5.67
5.88
94.0
173
93.1
276
140
190
140
300
0.468
0.41
0.301
0.558
0.629
0.52
0.44
0.44
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.145
THERMODYNAMIC PROPERTIES
cap height
base of text
TABLE 6.5 Critical Properties (Continued)
Substance
Chlorine
Chlorine pentafluoride
Chlorine trifluoride
Chlorobenzene
1-Chlorobutane
2-Chlorobutane
1-Chloro-1,1-difluoroethane
2-Chloro-1,1-difluoroethylene
Chlorodifluoromethane
1-Chloro-2,3-epoxypropane
Chloroethane
Chloroform
1-Chlorohexane
Chloromethane
2-Chloro-2-methylpropane
Chloropentafluoroacetone
Chloropentafluorobenzene
Chloropentafluoroethane
1-Chloropentane
1-Chloropropane
2-Chloropropane
3-Chloropropene
Chlorotrifluoromethane
Chlorotrifluorosilane
Chlorotrimethylsilane
1,2-Cresol
1,3-Cresol
1,4-Cresol
Cyanogen
Cyclobutane
Cycloheptane
Cyclohexane
trans-Cyclohexanedimethanol
Cyclohexanethiol
Cyclohexanol
Cyclohexanone
Cyclohexene
Cyclohexylamine
Cyclopentane
Cyclopentanethiol
Cyclopentanone
Cyclopentene
1-Cyclopentylheptane
1-Cyclopentylpentadecane
Cyclopropane
p-Cymene
Decafluorobutane
cis-Decahydronaphthalene
trans-Decahydronaphthalene
Decane
Decanenitrile
1-Decanol
1-Decene
top of rh
base of rh
␳c , g · cm⫺3
Tc , ⬚C
Pc , atm
Pc , MPa
Vc , cm3 · mol⫺1
143.8
142.6
153.5
359.3
268.9
247.5
137.1
127.5
96.1
351
187.3
263.3
321.5
143.1
234
137.6
297.9
80.1
295.4
230
212
241
29
35.4
224.7
424.5
432.7
431.5
126.7
186.8
316
280.4
451
390.9
376.9
379.9
287.33
341.5
238.6
360.4
353
232.9
406
506.9
124.7
379
113.3
429.2
414.0
344.6
348.8
413.9
343.3
76.1
51.9
7.71
5.26
124
230.9
0.573
0.565
44.6
36.4
39
40.7
44.0
49.1
4.52
3.69
3.95
4.12
4.46
4.98
308
312
305
231
197
165
0.365
0.297
0.303
0.435
0.499
0.525
52.0
54.0
5.27
5.47
199
239
0.324
0.504
65.9
39
28.4
31.8
31.9
6.679
3.95
2.88
3.22
3.229
139
295
0.353
0.314
252
0.613
45.2
46.6
47
38.98
34.2
31.6
49.4
45.0
50.8
62.2
49.2
36.7
40.2
34.85
4.58
4.72
4.76
3.946
3.47
3.20
5.01
4.56
5.15
6.30
4.99
3.72
4.07
3.531
254
230
234
180
0.309
0.341
0.336
0.579
282
309
277
145
210
390
308
0.384
0.346
0.391
0.360
0.267
0.252
0.273
42.0
39.5
42.9
4.26
4.0
4.35
327
312
292
0.306
0.315
0.281
44.49
4.508
260
0.27
53
5.37
268
0.314
19.2
10.1
54.2
2.80
22.93
31.6
31
20.8
32.1
22
21.89
1.94
1.02
5.49
2.84
2.323
3.20
3.14
2.11
3.25
2.23
2.218
649
1096
170
492
378
480
480
624
0.260
0.256
0.248
0.273
0.629
0.288
0.288
0.228
600
585
0.264
0.240
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.146
INTERACTIVE
top of rh
base of rh
SECTION 6
cap height
base of text
TABLE 6.5 Critical Properties (Continued)
Substance
Decylcyclohexane
Decylcyclopentane
Deuterium (equilibrium)
Deuterium (normal)
Deuterium bromide
Deuterium chloride
Deuterium hydride (DH)
Deuterium iodide
Deuterium oxide
Diallyl sulfide
Diborane
1,2-Dibromo-2-chlorotrifluoroethane
Dibromodifluoromethane
1,2-Dibromoethane
Dibromomethane
1,2-Dibromotetrafluoroethane
Dibutylamine
Dibutyl ether
Dibutyl sulfide
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
Dichlorodifluorosilane
1,2-Dichloroethane
1,1-Dichloroethylene
cis-1,2-Dichloroethylene
trans-1,2-Dichloroethylene
Dichlorofluoromethane
1,2-Dichlorohexafluoropropane
Dichloromethane
1,2-Dichloropropane
Dichlorosilane
1,1-Dichlorotetrafluoroethane
1,2-Dichlorotetrafluoroethane
Dideuterium oxide (D2O)
Diethanolamine
1,1-Diethoxyethane (Acetal)
Diethylamine
1,4-Diethylbenzene
Diethyl disulfide
Diethylene glycol
Diethyl ether
3,3-Diethylhexane
3,4-Diethylhexane
3,3-Diethyl-2-methylpentane
3,3-Diethylpentane
Diethyl sulfide
Difluoroamine (HNF2)
1,2-Difluorobenzene
cis-Difluorodiazine
␳c , g · cm⫺3
Tc , ⬚C
Pc , atm
Pc , MPa
477
450
⫺234.8
⫺234.7
88.8
50.3
⫺237.3
148.6
370.9
380
166
287.6
13.4
15.0
16.28
16.43
1.36
1.52
1.650
1.665
60.4
60.3
0.0668
0.0669
14.64
1.483
62.8
0.0481
213.8
21.66
55.6
0.360
39.5
4.00
40.8
71.1
71
33.49
30.7
29.7
24.7
40.5
38
39
40.82
50.0
34.5
53
51.3
4.13
7.2
7.19
3.393
3.11
3.01
2.50
4.10
3.85
3.95
4.136
5.07
3.50
5.4
5.20
54.4
51.1
5.51
5.18
60.2
44
46.1
32.6
32.1
215.7
32.3
6.10
4.49
4.67
3.30
3.252
21.86
3.27
37.3
27.7
198.3
309.9
310
214.7
334.4
311.0
377
424.2
411
412
111.80
250
95.8
288
222
271.1
234.4
178.43
172.9
237
304
176
145.5
145.63
371.0
442.0
254
226.84
384.8
368.9
408
193.59
354.7
345.7
366.8
337
284
130
284.2
⫺1
Vc , cm3 · mol⫺1
249
242
0.843
0.776
329
517
500
537
360
359
372
217
236
0.790
0.250
0.260
0.272
0.408
0.408
0.395
0.558
0.419
225
218
224
224
196
0.440
0.445
0.433
0.433
0.522
193
226
0.440
0.500
294
297
349
0.582
0.582
0.363
0.301
3.758
2.81
301
480
0.243
0.280
46
35.9
23.8
23.0
25.0
26.4
39.1
93
4.66
3.638
2.41
2.33
2.53
2.67
3.96
9.42
316
280
510
519
501
0.336
0.265
0.279
0.274
0.284
318
0.284
300
0.381
70
7.09
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.147
THERMODYNAMIC PROPERTIES
cap height
base of text
TABLE 6.5 Critical Properties (Continued)
Substance
trans-Difluorodiazine
1,1-Difluoroethane
1,1-Difluoroethylene
Dihexyl ether
Dihydrogen disulfide
Dihydrogen heptasulfide
Dihydrogen hexasulfide
Dihydrogen octasulfide
Dihydrogen pentasulfide
Dihydrogen tetrasulfide
Dihydrogen trisulfide
Diisopentyl sulfide
Diisopropyl ether
1,2-Dimethoxyethane
Dimethoxymethane
N,N-Dimethylacetamide
Dimethylamine
N,N-Dimethylaniline
2,2-Dimethylbutane
2,3-Dimethylbutane
3,3-Dimethyl-2-butanone
2,3-Dimethyl-1-butene
3,3-Dimethyl-1-butene
2,3-Dimethyl-2-butene
1,1-Dimethylcyclohexane
cis-1,2-Dimethylcyclohexane
trans-1,2-Dimethylcyclohexane
cis-1,3-Dimethylcyclohexane
trans-1,3-Dimethylcyclohexane
cis-1,4-Dimethylcyclohexane
trans-1,4-Dimethylcyclohexane
1,1-Dimethylcyclopentane
cis-1,2-Dimethylcyclopentane
trans-1,2-Dimethylcyclopentane
cis-1,3-Dimethylcyclopentane
Dimethyl disulfide
Dimethyl ether
N,N-Dimethylformamide
2,2-Dimethylheptane
2,2-Dimethylhexane
2,3-Dimethylhexane
2,4-Dimethylhexane
2,5-Dimethylhexane
3,3-Dimethylhexane
3,4-Dimethylhexane
1,1-Dimethylhydrazine
2,4-Dimethyl-3-isopentane
2,3-Dimethyloctane
2,4-Dimethyloctane
2,5-Dimethyloctane
2,6-Dimethyloctane
2,7-Dimethyloctane
Tc , ⬚C
Pc , atm
Pc , MPa
⫺13
113.6
29.8
384
299
742
707
767
657
582
465
391
227.17
263
242.1
364
164.07
414
215.7
499.9
289.8
228
217
250.9
318
333.0
323.0
317.9
325
325.0
317.0
274
291.7
277.2
318.9
59.5
126.9
376.5
303.7
276.8
290.4
280.5
277.0
289.0
295.8
250
341.3
55
44.4
44.0
18
58.3
33
36
32
38.4
43.1
50.6
5.57
4.50
4.46
1.82
5.91
3.34
3.65
3.24
3.89
4.37
5.13
27.9
38.2
44.2
38.7
52.7
35.8
30.49
30.90
2.832
3.87
4.48
3.92
5.340
3.63
3.090
3.131
32.0
32.1
33.2
29.3
29.0
29.3
29.3
29.3
29.0
29.0
34.0
34.0
34.0
340.1
326.3
330
330
329.8
top of rh
base of rh
Vc , cm3 · mol⫺1
␳c , g · cm⫺3
181
154
720
0.365
0.417
0.259
386
271
0.265
0.333
187
0.241
359
358
0.240
0.241
3.24
3.25
3.36
2.97
2.94
2.97
2.97
2.97
2.94
2.94
3.44
3.44
3.44
343
340
351
416
460
460
450
460
460
459
360
368
362
0.245
0.248
0.240
0.378
0.244
0.244
0.249
0.244
0.244
0.249
0.273
0.267
0.271
53.0
51.5
23.19
25.0
25.94
25.22
24.54
26.19
26.57
53.6
23.1
5.37
5.22
2.350
2.529
2.628
2.556
2.487
2.654
2.692
5.43
2.34
190
262
519
478
468
472
482
443
466
230
521
0.242
0.279
0.247
0.239
0.244
0.242
0.237
0.258
0.245
0.261
0.273
21.6
21.1
21.2
21.1
20.7
2.19
2.14
2.15
2.15
2.10
567
566
569
576
590
0.251
0.251
0.250
0.247
0.241
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.148
INTERACTIVE
top of rh
base of rh
SECTION 6
cap height
base of text
TABLE 6.5 Critical Properties (Continued)
Substance
3,3-Dimethyloctane
3,4-Dimethyloctane
3,5-Dimethyloctane
3,6-Dimethyloctane
4,5-Dimethyloctane
4,5-Dimethyloctane
Dimethyl oxalate
2,2-Dimethylpentane
2,3-Dimethylpentane
2,4-Dimethylpentane
3,3-Dimethylpentane
2,3-Dimethylphenol
2,4-Dimethylphenol
2,5-Dimethylphenol
2,6-Dimethylphenol
3,4-Dimethylphenol
3,5-Dimethylphenol
2,2-Dimethylpropane
2,2-Dimethyl-1-propanol
2,3-Dimethylpyridine
2,4-Dimethylpyridine
2,5-Dimethylpyridine
2,6-Dimethylpyridine
3,4-Dimethylpyridine
3,5-Dimethylpyridine
Dimethyl sulfide
N,N-Dimethyl-1,2-toluidine
1,4-Dioxane
Diphenyl ether
Diphenylmethane
Dipropylamine
Dipropyl ether
Docosafluorodecane
Dodecafluorocyclohexane
Dodecafluorocyclohexene
Dodecafluoro-1-hexene
Dodecafluoropentane
Dodecane
1-Dodecanol
1-Dodecene
Dodecylbenzene
Dodecylcyclopentane
Ethane
1,2-Ethanediamine
1,2-Ethanediol
Ethanethiol
Ethanol
Ethoxybenzene
Ethyl acetate
Ethyl acetoacetate
Ethyl acrylate
Ethylamine
Ethylbenzene
␳c , g · cm⫺3
Tc , ⬚C
Pc , atm
Pc , MPa
Vc , cm3 · mol⫺1
339
341
333.2
335.2
333.8
339.1
355
247.4
264.3
246.7
263.3
449.7
434.5
433.8
427.9
456.7
442.5
160.7
276
382.3
373.9
371
350.7
410.7
394.1
229.9
395
314
493.7
494
282.7
257.5
269
184.1
188.7
181.3
149
385
405.9
384.5
501
477
32.3
319.8
445
225.5
240.9
374.0
250.2
400
279
183
344.00
21.9
22.1
21.6
21.6
21.8
22.1
39.2
27.4
28.70
27.01
29.07
48
43
48
42
49
36
31.55
39
2.22
2.24
2.19
2.19
2.21
2.24
3.97
2.773
2.908
2.737
2.946
4.86
4.36
4.86
4.26
4.96
3.65
3.197
3.95
557
551
555
562
548
546
0.255
0.258
0.256
0.253
0.260
0.261
416
393
418
414
470
509
470
509
552
611
307
319
0.241
0.255
0.240
0.242
0.26
0.24
0.26
0.24
0.27
0.25
0.238
316
0.339
201
0.309
238
0.370
407
0.249
754
718
0.226
0.260
1000
0.246
148
206
186
207
167
0.203
0.292
0.334
0.300
0.276
286
0.308
320
182
374
0.313
0.248
0.284
54.6
30.8
51.5
31
29.4
35.8
29.91
14.3
24
5.53
3.12
5.21
3.14
2.98
3.63
3.028
1.45
2.43
20.1
18.0
19
18.3
15.6
12.8
48.2
62.1
76
54.2
60.57
33.8
38.31
2.03
1.82
1.92
1.85
1.58
1.30
4.90
6.29
7.7
5.49
6.137
3.42
3.882
37.0
55.5
35.61
3.75
5.62
3.609
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.149
THERMODYNAMIC PROPERTIES
cap height
base of text
TABLE 6.5 Critical Properties (Continued)
Substance
Ethyl benzoate
Ethylbutanoate
2-Ethyl-1-butanol
Ethyl crotonate
Ethylcyclohexane
Ethylcyclopentane
3-Ethyl-2,2-dimethylhexane
4-Ethyl-2,2-dimethylhexane
3-Ethyl-2,3-dimethylhexane
4-Ethyl-2,3-dimethylhexane
3-Ethyl-2,4-dimethylhexane
4-Ethyl-2,4-dimethylhexane
3-Ethyl-2,5-dimethylhexane
3-Ethyl-3,4-dimethylhexane
Ethylene
Ethylene glycol dimethyl ether
Ethylene glycol ethyl ether
acetate
Ethylene glycol monobutyl
ether
Ethylene oxide
Ethyl formate
3-Ethylhexane
2-Ethyl-1-hexanol
Ethyl isopentanoate
Ethyl isopropyl ether
2-Ethyl-1-methylbenzene
3-Ethyl-1-methylbenzene
4-Ethyl-1-methylbenzene
Ethyl 3-methylbutanoate
1-Ethyl-1-methylcyclopentane
Ethyl methyl ether
3-Ethyl-2-methylheptane
4-Ethyl-2-methylheptane
5-Ethyl-2-methylheptane
3-Ethyl-3-methylheptane
4-Ethyl-3-methylheptane
5-Ethyl-3-methylheptane
3-Ethyl-4-methylheptane
4-Ethyl-4-methylheptane
Ethyl methyl ketone
3-Ethyl-2-methylpentane
3-Ethyl-3-methylpentane
Ethyl 2-methylpropanoate
Ethyl methyl sulfide
2-Ethylnaphthalene
Ethyl nonanoate
3-Ethyloctane
4-Ethyloctane
Ethyl octanoate
3-Ethylpentane
1,2-Ethylphenol
1,3-Ethylphenol
␳c , g · cm⫺3
Tc , ⬚C
Pc , atm
Pc , MPa
Vc , cm3 · mol⫺1
424
293
145.7
326
336
296.4
338.6
321.5
353.7
344.2
343.0
347.8
330.4
351.4
9.3
263
334.2
32
30.2
3.24
3.06
451
421
0.111
0.28
29.9
33.5
22.8
21.9
23.9
23.1
23.1
24.4
22.1
23.9
49.7
38.2
31.25
3.03
3.39
2.31
2.22
2.42
2.34
2.34
2.47
2.24
2.42
5.036
3.87
3.166
450
375
526
539
516
524
522
524
537
511
129
271
443
0.249
0.262
0.271
0.264
0.276
0.271
0.273
0.271
0.265
0.278
0.218
0.333
0.298
424
0.279
360.8
196
235.4
292.4
367.5
315
217.2
378
364
367
314.9
319
164.8
337.8
328.7
333.6
347.0
341.2
333.5
342.4
342.4
262.4
294.0
303.5
280
260
502
401
340
337
386
267.6
429.9
443.3
top of rh
base of rh
71.0
46.8
25.74
27.2
7.275
4.74
2.608
2.76
140
229
455
494
0.314
0.323
0.251
0.264
30.0
28.0
29.0
3.04
2.84
2.94
460
490
470
0.26
0.24
0.26
29.5
43.4
22.0
21.6
21.6
22.8
22.5
22.0
22.5
22.8
41.0
26.65
27.71
30
42
31.0
2.99
4.40
2.23
2.19
2.19
2.31
2.28
2.23
2.28
2.31
4.154
2.700
2.808
3.04
4.26
3.14
221
544
545
555
532
530
541
533
525
267
443
455
410
0.272
0.262
0.261
0.256
0.267
0.269
0.263
0.267
0.271
0.270
0.258
0.351
0.28
521
0.300
21.6
21.5
2.19
2.18
561
552
0.241
0.258
28.53
2.891
416
0.241
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.150
INTERACTIVE
top of rh
base of rh
SECTION 6
cap height
base of text
TABLE 6.5 Critical Properties (Continued)
Substance
1,4-Ethylphenol
Ethyl propanoate
Ethyl propyl ether
m-Ethyltoluene
o-Ethyltoluene
p-Ethyltoluene
3-Ethyl-2,2,3-trimethylpentane
3-Ethyl-2,2,4-trimethylpentane
3-Ethyl-2,3,4-trimethylpentane
Ethyl vinyl ether
Fluorine
Fluorobenzene
Fluoroethane
Fluoromethane
4-Fluorotoluene
Formaldehyde
Formic acid
2-Furaldehyde
Furan
Germanium tetrachloride
Glycerol
Hafnium tetrabromide
Hafnium tetrachloride
Hafnium tetraiodide
Helium (equilibrium)
Helium-3
Helium-4
Heptadecane
1-Heptadecanol
Heptane
1-Heptanol
2-Heptanol
3-Heptanol
2-Heptanone
1-Heptene
Heptylcyclopentane
Hexadecafluoroheptane
Hexadecane
1-Hexadecene
Hexadecylcyclopentane
1,5-Hexadiene
Hexafluoroacetone
Hexafluorobenzene
Hexafluoroethane
Hexamethylbenzene
Hexane
Hexanenitrile
Hexanoic acid
1-Hexanol
2-Hexanol
␳c , g · cm⫺3
Tc , ⬚C
Pc , atm
Pc , MPa
Vc , cm3 · mol⫺1
443.3
272.9
227.1
364.0
378.0
367
372.9
33.18
32.1
28.1
30.1
29.0
25.4
3.362
3.25
2.837
3.04
2.94
2.57
345
244
490
460
479
503
0.296
0.361
0.245
0.261
0.256
0.283
342.2
23.4
2.37
518
0.275
369.2
25.1
2.54
506
0.281
202
⫺129.0
286.94
102.2
44.7
316.4
135
315
397
217.1
276.9
453
473
450
643
⫺267.96
⫺269.85
⫺267.96
460
736
267.1
359.5
335.2
332.3
338.4
264.2
406
201.7
444
444
518
234
84.1
243.6
19.7
494
234.5
360.7
389
337.2
312.8
40.17
51.47
44.91
49.6
58.0
4.07
5.215
4.551
5.03
5.88
260
66.2
357
169
124
0.277
0.574
0.269
0.284
0.274
65
6.6
105
0.286
58.1
54.3
38
66
5.89
5.50
3.85
6.69
57.0
5.86
218
330
255
415
304
528
2.261
1.13
2.24
13.0
14.0
27.0
30.18
29.81
0.2289
0.1182
0.227
1.32
1.42
2.74
3.058
3.021
0.312
0.650
0.361
1.20
1.05
1.30
0.06930
0.0414
0.0698
0.140
0.267
0.232
0.267
0.269
33.91
28.83
19.2
16.0
14
13.2
9.6
34
29.0
32.30
3.436
2.921
1.945
1.62
1.42
1.34
0.97
3.44
2.94
3.273
29.85
32.57
31.6
33.72
32.67
3.025
3.30
3.20
3.417
3.310
72.5
57.3
1006
960
428
435
432
421
402
0.271
0.246
664
930
933
0.584
0.243
0.241
328
329
335
224
600
368
0.250
0.505
0.505
0.617
0.271
0.233
381
0.268
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.151
THERMODYNAMIC PROPERTIES
cap height
base of text
TABLE 6.5 Critical Properties (Continued)
Substance
3-Hexanol
2-Hexanone
3-Hexanone
1-Hexene
cis-2-Hexene
trans-2-Hexene
cis-3-Hexene
trans-3-Hexene
Hexylcyclopentane
Hydrazine
Hydrogen (equilibrium)
Hydrogen (normal)
Hydrogen bromide
Hydrogen chloride
Hydrogen cyanide
Hydrogen deuteride
Hydrogen fluoride
Hydrogen iodide
Hydrogen selenide
Hydrogen sulfide
Icosafluorononane
Icosane
1-Icosanol
Indane
Iodine
Iodobenzene
Iodoethane
Iodomethane
1-Iodopropane
Isobutyl acetate
Isobutylamine
Isobutylbenzene
Isobutyl bromide
Isobutyl butanoate
Isobutylcyclohexane
Isobutyl formate
Isobutyl isobutanoate
Isobutyl 3-methylbutanoate
Isobutyl propanoate
Isopentyl acetate
Isopentyl butanoate
Isopentyl propanoate
Isopropyl acetate
Isopropylamine
Isopropylbenzene
Isopropylcycloheptane
Isopropylcyclohexane
Isopropylcyclopentane
4-Isopropylheptane
Isopropylmethylamine
2-Isopropyl-1-methylbenzene
3-Isopropyl-1-methylbenzene
4-Isopropyl-1-methylbenzene
top of rh
base of rh
Tc , ⬚C
Pc , atm
Pc , MPa
309.3
313.9
309.7
231.0
245
243
244
246.8
387.0
380
⫺240.17
⫺239.91
89.8
51.40
183.5
⫺237.25
188
150.7
137
100.4
251
494
497
411.8
546
448
281.0
255
323
288
246
377
294.1
338
386
278
329
348
319
326
346
338
258
198.7
357.9
334.5
367
328
334.5
217.6
397
393
380
33.2
32.8
32.76
31.64
32.4
32.3
32.4
32.1
21.1
14.5
12.77
12.8
84.4
82.0
53.2
14.64
64
82.0
88
88.2
15.4
10.3
12.0
39.0
115
44.6
3.36
3.32
3.320
3.206
3.28
3.27
3.28
3.25
2.14
1.47
1.294
1.297
8.55
8.31
5.39
1.483
6.5
8.31
8.9
8.94
1.56
1.04
1.22
3.95
11.7
4.52
Vc , cm3 · mol⫺1
␳c , g · cm⫺3
348
351
351
350
350
0.242
0.240
0.240
0.240
0.240
96.1
65.4
65.0
100.0
81.0
139
62.8
69
131
0.333
0.0308
0.0310
0.809
0.45
0.195
0.048
0.29
0.976
98.5
0.31
1190
0.237
381
155
351
0.310
0.164
0.581
65
6.59
190
0.75
31.2
40.2
30.1
3.16
4.07
3.05
414
284
480
0.281
0.258
0.280
30.8
38.3
3.12
3.88
350
0.29
44.8
31.67
4.54
3.209
221
429
0.267
0.281
28
29.6
22.0
2.84
3.00
2.23
537
0.265
28.6
29.0
27.9
2.90
2.94
2.83
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.152
INTERACTIVE
top of rh
base of rh
SECTION 6
cap height
base of text
TABLE 6.5 Critical Properties (Continued)
Substance
3-Isopropyl-2-methylhexane
Isopropyl methyl sulfide
Isoquinoline
Isoxazole
Ketene
Krypton
Mercury
Mercury(II) bromide
Mercury(II) chloride
Mercury(II) iodide
Methane
Methanethiol
Methanol
Methoxybenzene
Methyl acetamide
Methyl acetate
Methyl acrylate
Methylamine
N-Methylaniline
Methyl benzoate
2-Methyl-1,3-butadiene
3-Methyl-1,3-butadiene
2-Methylbutane
2-Methyl-1-butanethiol
2-Methyl-2-butanethiol
Methyl butanoate
3-Methylbutanoic acid
2-Methyl-1-butanol
3-Methyl-1-butanol
2-Methyl-2-butanol
3-Methyl-2-butanol
3-Methyl-2-butanone
2-Methyl-1-butene
3-Methyl-1-butene
2-Methyl-2-butene
Methylcyclohexane
Methylcyclopentane
Methyl dodecanoate
N-Methylethylamine
Methyl formate
2-Methylfuran
2-Methylheptane
3-Methylheptane
4-Methylheptane
2-Methylhexane
3-Methylhexane
Methylhydrazine
Methyl 2-hydroxybenzoate
Methyl isobutanoate
Methyl isocyanate
1-Methylnaphthalene
2-Methylnaphthalene
2-Methyloctane
␳c , g · cm⫺3
Tc , ⬚C
Pc , atm
Pc , MPa
Vc , cm3 · mol⫺1
359.3
276.4
530
278.9
380
⫺63.75
1477
789
700
799
⫺82.60
196.8
239.4
372.5
417
233.40
263
157.6
428
438
211
223
187.3
318.8
297.0
281.3
356
302.3
304.1
270.6
283.0
280.3
196.9
191.6
207.9
299.1
259.58
439
223.5
214.1
254
286.6
290.6
288.7
257.3
262.2
294
436
267.7
218
499
488
313.9
22.6
2.29
529
0.269
50.3
5.10
374
0.345
64
54.3
1587
6.5
5.50
160.8
145
91.2
0.290
0.9085
45.44
71.4
79.78
41.9
4.604
7.23
8.084
4.25
99.0
145
118
0.162
0.332
0.272
0.321
46.9
42
75.14
51.3
36
38.0
40.6
33.4
4.75
4.26
7.614
5.20
3.65
3.85
4.11
3.38
228
265
140
373
396
276
267
306
0.325
0.325
0.222
0.287
0.344
0.247
0.255
0.236
34.3
33.6
38.9
38.8
36.6
38.2
38.0
34.0
34.7
34.0
34.26
37.35
3.475
3.40
3.94
3.93
3.71
3.87
3.85
3.445
3.52
3.445
3.471
3.784
340
0.300
322
329
319
0.274
0.268
0.276
36.6
59.20
46.6
24.52
25.13
25.09
26.98
27.77
79.3
3.71
5.998
4.72
2.484
2.546
2.542
2.734
2.814
8.035
310
294
300
318
368
319
758
243
172
247
488
464
476
421
404
271
0.278
0.239
0.234
0.221
0.267
0.264
0.283
0.243
0.349
0.333
0.234
0.246
0.240
0.238
0.248
0.170
33.9
55
35.5
34.6
22.80
3.43
5.57
3.60
3.51
2.310
339
0.301
445
462
0.320
0.308
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.153
THERMODYNAMIC PROPERTIES
cap height
base of text
TABLE 6.5 Critical Properties (Continued)
Substance
2-Methylpentane
3-Methylpentane
2-Methyl-2,4-pentanediol
Methyl pentanoate
2-Methyl-2-pentanol
2-Methyl-3-pentanol
3-Methyl-3-pentanol
4-Methyl-1-pentanol
4-Methyl-2-pentanol
3-Methyl-2-pentanone
4-Methyl-2-pentanone
2-Methyl-2-pentene
cis-3-Methyl-2-pentene
trans-3-Methyl-2-pentene
cis-4-Methyl-2-pentene
trans-4-Methyl-2-pentene
2-Methylpropanal
2-Methyl-1-propanamine
N-Methylpropanamide
2-Methylpropane
2-Methyl-1-propanethiol
2-Methyl-2-propanethiol
Methyl propanoate
2-Methylpropanoic acid
2-Methyl-1-propanol
2-Methyl-2-propanol
2-Methylpropene
2-Methylpropyl acetate
Methyl propyl ether
Methyl propyl sulfide
2-Methylpyridine
3-Methylpyridine
4-Methylpyridine
1-Methyl-2-pyrrolidinone
1-Methylstyrene
2-Methyltetrahydrofuran
2-Methylthiophene
3-Methylthiophene
Methyl vinyl ether
Morpholine
Naphthalene
Neon
Niobium pentabromide
Niobium pentachloride
Niobium pentafluoride
Nitric oxide
Nitrobenzene
Nitroethane
Nitrogen-14
Nitrogen-15
Nitrogen chloride difluoride
Nitrogen dioxide (equilibrium)
Nitrogen trideuteride (ND3)
top of rh
base of rh
␳c , g · cm⫺3
Tc , ⬚C
Pc , atm
Pc , MPa
Vc , cm3 · mol⫺1
224.6
231.4
405
294
286.4
302.9
302.5
330.4
301.3
298.8
298
245
245
248
217
220
240
246
412
134.70
286.4
257.0
257.5
332
274.6
233.1
144.73
288
203.2
301.0
347.9
371.9
373
448.7
381
264
333.1
337.7
163
345
475.3
⫺228.71
737
534
464
⫺92.9
459
284
146.94
146.8
64.3
158.2
132.4
29.91
30.85
33.9
3.031
3.126
3.43
367
367
0.235
0.235
34.1
34.7
3.46
3.52
42.4
4.30
380
0.269
32.3
32.4
32.4
32.3
30
30
41
40.2
3.27
3.28
3.28
3.27
3.04
3.04
4.15
4.07
371
351
351
350
360
360
274
278
0.270
0.240
0.240
0.240
0.234
0.234
0.263
0.263
35.83
3.630
263
0.221
39.5
36.5
42.39
39.20
39.48
31.2
4.00
3.7
4.295
3.972
4.000
3.16
282
292
273
275
239
414
0.312
0.302
0.272
0.270
0.235
0.281
45.4
44.2
46.4
4.60
4.48
4.70
33.6
37.1
47.9
48.9
47
54
39.98
27.2
3.40
3.76
4.85
4.95
4.76
54.7
4.051
2.77
62
64.6
6.28
6.55
292
288
292
311
397
267
275
275
205
253
407
41.7
469
400
155
58
0.319
0.323
0.319
0.319
0.298
0.322
0.356
0.356
0.283
0.344
0.31
0.4835
1.05
0.68
1.21
0.52
37
33.5
33.5
50.8
100
3.75
3.39
3.39
5.15
10.1
89.5
90.4
0.313
0.332
170
0.557
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.154
INTERACTIVE
top of rh
base of rh
SECTION 6
cap height
base of text
TABLE 6.5 Critical Properties (Continued)
Substance
Nitrogen trifluoride
Nitromethane
1-Nitropropane
2-Nitropropane
Nitrous oxide
Nitrosyl chloride
Nitryl fluoride
Nonadecane
Nonane
Nonanoic acid
1-Nonanol
1-Nonene
Nonylbenzene
Nonylcyclopentane
Octadecafluorooctane
Octadecane
1-Octadecanol
1-Octadecene
Octafluorocyclobutane
Octafluoronaphthalene
Octafluoropropane
Octamethylcyclotetrasiloxane
Octane
Octanenitrile
Octanoic acid
1-Octanol
2-Octanol
1-Octene
cis-2-Octene
Octylcyclopentane
Osmium tetroxide
Oxygen
Oxygen difluoride
Ozone
Pentachloroethane
Pentadecane
1-Pentadecene
Pentadecylcyclopentane
1,2-Pentadiene
cis-1,3-Pentadiene
1,4-Pentadiene
Pentafluorobenzene
2,3,4,5,6-Pentafluorotoluene
2,2,3,3,4-Pentamethylpentane
2,2,3,4,4-Pentamethylpentane
Pentanal
Pentane
Pentanenitrile
Pentanethiol
Pentanoic acid
1-Pentanol
2-Pentanol
␳c , g · cm⫺3
Tc , ⬚C
Pc , atm
Pc , MPa
Vc , cm3 · mol⫺1
⫺39.3
315
402.0
344.8
36.434
167
76.3
483
321.5
438
404
319
468
437.4
229
472.3
474
466
115.31
399.9
72.7
313
295.6
401.3
422
379.4
356.5
293.6
307
421
132
⫺118.56
⫺58.0
⫺12.10
373.0
433.9
431
507
230
223
205
258.9
275.5
370.7
44.7
57.9
4.53
5.87
173
0.352
71.596
90
7.2545
9.12
97.4
139
0.4525
0.471
11.0
22.6
23.7
1.12
2.29
2.40
23.1
18.7
16.3
16.4
12.73
14
11.2
27.48
2.34
1.89
1.65
1.66
1.29
1.42
1.13
2.784
26.5
13.2
24.6
28.1
26.1
27.41
27.18
26.40
27.3
17.7
170
49.77
48.9
53.8
1130
555
0.238
0.231
546
580
790
0.264
0.218
0.259
1070
0.238
325
0.616
2.69
1.33
2.49
2.85
2.64
2.777
2.754
2.675
2.77
1.79
17.2
5.043
4.95
5.45
299
970
492
0.628
0.306
0.232
490
494
464
0.266
0.278
0.242
15
14.4
10.1
40.2
39.4
37.4
34.7
1.52
1.46
1.02
4.07
3.99
3.79
3.52
880
0.241
276
275
276
0.248
0.248
0.248
25.5
2.58
508
0.280
354.2
23.7
2.40
521
0.273
281
196.6
337.2
324.6
370
315.0
287.3
35
33.26
35.3
3.55
3.370
3.58
333
311
0.259
0.237
35.3
38.38
36.27
3.58
3.889
3.675
340
326
0.300
0.270
73.4
97.7
88.9
0.436
0.553
0.540
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.155
THERMODYNAMIC PROPERTIES
cap height
base of text
TABLE 6.5 Critical Properties (Continued)
Substance
3-Pentanol
2-Pentanone
3-Pentanone
1-Pentene
cis-2-Pentene
trans-2-Pentene
Pentyl acetate
Pentylbenzene
Pentyl formate
1-Pentyne
Perchloryl fluoride
Phenanthrene
Phenol
1-Phenylhexadecane
1-Phenylpentadecane
1-Phenyltetradecane
Phosgene
Phosphine
Phosphine-d3
Phosphonium chloride
Phosphorus
Phosphorus bromide difluoride
Phosphorus chloride difluoride
Phosphorus dibromide fluoride
Phosphorus dichloride fluoride
Phosphorus pentachloride
Phosphorus trichloride
Phosphorus trifluoride
Phosphoryl chloride difluoride
Phosphoryl trichloride
Phosphoryl trifluoride
Phthalic anhydride
Piperidine
Propadiene
Propanal
Propane
1,2-Propanediol
1,3-Propanediol
Propanenitrile
1-Propanethiol
2-Propanethiol
Propanoic acid
1-Propanol
2-Propanol
2-Propenal
Propene
2-Propen-1-ol
Propyl acetate
Propylamine
Propylbenzene
Propyl butanoate
Propylcyclopentane
Propylcyclohexane
Propylene oxide
Tc , ⬚C
286.5
287.93
288.31
191.63
202
198
332
406.8
303
220.3
95.3
596
421.1
535
526.9
519
182
51.3
50.4
49.1
721
113
89.2
254
189.9
372
290
⫺1.9
150.7
329
73.4
537
321.0
120
231.3
96.68
352
385
288.2
262.5
244.2
331
263.7
235.2
233
91.9
272.0
276.6
223.9
365.20
327
358.7
336.7
209.1
top of rh
base of rh
␳c , g · cm⫺3
Pc , atm
Pc , MPa
Vc , cm3 · mol⫺1
36.46
36.9
34.81
36.4
34.7
3.694
3.729
3.527
3.69
3.52
301
336
293
0.286
0.256
0.239
304
0.231
25.7
2.60
550
0.269
40
53.0
4.05
5.37
60.5
12.7
13.3
14.0
56
64.5
6.13
1.29
1.35
1.42
5.67
6.54
278
161
554
229
1200
1140
1110
190
0.245
0.637
0.322
0.41
0.252
0.253
0.247
0.52
72.7
7.37
44.6
4.52
49.3
5.00
260
0.528
42.7
43.4
4.33
4.40
41.8
47
48.8
54.0
52.0
41.92
60
59
42.0
4.24
4.76
4.94
5.47
5.27
4.248
6.08
5.98
4.26
368
288
162
204
200
237
241
230
0.402
0.296
0.247
0.285
0.217
0.321
0.316
0.240
44.7
51.01
47.02
51
45.6
4.53
5.169
4.764
5.17
4.62
33.2
46.6
31.58
3.36
4.72
3.200
222
218.5
220
197
181
208
345
233
440
0.32
0.275
0.273
0.285
0.233
0.279
0.296
0.254
0.273
29.6
27.7
48.6
3.00
2.81
4.92
425
0.264
186
0.312
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.156
INTERACTIVE
top of rh
base of rh
SECTION 6
cap height
base of text
TABLE 6.5 Critical Properties (Continued)
Substance
Propyl formate
Propyl 2-methylpropanoate
Propyl 3-methylpropanoate
Propyl propanoate
Propyne
Pyridine
Pyrrole
Pyrrolidine
Quinoline
Radon
Rhenium(VII) oxide
Rhenium(VI) oxide tetrachloride
Rubidium
Selenium
Silane
Silicon chloride trifluoride
Silicon tetrabromide
Silicon tetrachloride
Silicon tetrafluoride
Silicon trichloride fluoride
Spiro[2.2]pentane
Styrene
Sulfur
Sulfur dioxide
Sulfur hexafluoride
Sulfur tetrafluoride
Sulfur trioxide
Tantalum pentabromide
Tantalum pentachloride
1,2-Terphenyl
1,3-Terphenyl
1,4-Terphenyl
1,1,2,2-Tetrachlorodifluoroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
Tetrachloromethane
Tetradecafluoro-1-heptene
Tetradecafluorohexane
Tetradecafluoromethylcyclohexane
Tetradecane
1-Tetradecene
Tetradecylcyclopentane
Tetraethylsilane
Tetrafluoroethylene
Tetrafluorohydrazine
Tetrafluoromethane
Tetrahydrofuran
1,2,3,4-Tetrahydronaphthalene
Tetrahydropyran
Tetrahydrothiophene
1,2,4,5-Tetramethylbenzene
2,2,3,3-Tetramethylbutane
2,2,3,3-Tetramethylhexane
Tc , ⬚C
264.9
316
336
305
129.3
346.9
366.6
295.1
509
104
669
508
1832
1493
⫺3.5
34.5
390
234
⫺14.0
165.4
233.3
363.8
1041
157.7
45.6
91.7
217.9
701
494
617.9
651.7
652.9
278
388.00
347.1
283.5
205.1
174.5
213.7
420.9
416
499
330.6
33.4
33.3
⫺45.5
267.0
447
299.1
358.9
402
294.7
350.0
␳c , g · cm⫺3
Pc , atm
Pc , MPa
Vc , cm3 · mol⫺1
40.1
4.06
285
0.309
55.5
55.96
62.6
55.2
48.0
62
5.62
5.67
6.34
5.59
4.86
6.28
164
243
200
238
437
139
334
161
250
0.245
0.325
0.335
0.300
0.300
1.6
0.95
0.34
47.8
34.2
4.84
3.47
37
36.7
35.3
3.75
3.72
3.57
326
0.521
36.3
116
77.8
37.1
3.68
11.7
7.88
3.76
347
0.300
122
198
0.5240
0.734
81
8.2
38.5
34.6
32.8
34
3.90
3.51
3.32
3.44
130
461
400
755
768
762
371
0.633
1.26
0.89
0.305
0.300
0.302
0.549
44.3
44.57
4.49
4.516
290
276
0.572
0.557
18.8
23
16
15.4
11.1
25.68
38.9
37
36.9
51.22
36.0
47.1
1.90
2.33
1.62
1.56
1.12
2.602
3.91
3.75
3.74
5.19
3.65
4.77
830
0.239
175
0.58
140
224
408
263
0.629
0.322
0.324
0.328
29
28.3
24.8
2.94
2.87
2.51
480
461
573
0.280
0.248
0.248
short
standard
long
DEAN #37261
(McGHP)
RIGHT
INTERACTIVE
6.157
THERMODYNAMIC PROPERTIES
cap height
base of text
TABLE 6.5 Critical Properties (Continued)
Substance
2,2,3,4-Tetramethylhexane
2,2,3,5-Tetramethylhexane
2,2,4,4-Tetramethylhexane
2,2,4,5-Tetramethylhexane
2,2,5,5-Tetramethylhexane
2,3,3,4-Tetramethylhexane
2,3,3,5-Tetramethylhexane
2,3,4,4-Tetramethylhexane
2,3,4,5-Tetramethylhexane
3,3,4,4-Tetramethylhexane
2,2,3,3-Tetramethylpentane
2,2,3,4-Tetramethylpentane
2,2,4,4-Tetramethylpentane
2,3,3,4-Tetramethylpentane
Tetramethylsilane
Thiacyclopentane
2-Thiapropane
Thiophene
Thiophenol
Thymol
Tin(IV) chloride
Titanium tetrachloride
Toluene
1,2-Toluidine
1,3-Toluidine
1,4-Toluidine
Toluonitrile
Tributoxyborane
Tributylamine
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethylene
Trichlorofluoromethane
Trichlorofluorosilane
Trichloromethane
Trichloromethylsilane
1,2,3-Trichloropropane
1,2,2-Trichlorotrifluoroethane
Tridecane
1-Tridecene
Tridecylcyclopentane
Triethanolamine
Triethylamine
Trifluoroacetic acid
Trifluoroamine oxide (NOF3)
1,1,1-Trifluoroethane
Trifluoromethane
(Trifluoromethyl)benzene
Trimethylamine
1,2,3-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
2,2,3-Trimethylbutane
2,2,3-Trimethyl-1-butene
top of rh
base of rh
␳c , g · cm⫺3
Tc , ⬚C
Pc , atm
Pc , MPa
Vc , cm3 · mol⫺1
347.3
328.2
337.1
325.4
308.4
360.0
337.0
353.5
340.1
373.6
334.6
319.6
301.6
334.6
175.49
358.8
230.0
306.3
416.4
425
318.7
365
318.60
434
434
433
450
472
365.3
272
329
271.1
198.1
165.4
263.3
244
378
214.2
402
401
488
514.3
262.5
218.2
29.5
73.2
25.8
286.8
159.64
391.4
376.0
364.2
258.1
260
23.4
22.4
22.2
21.9
21.6
24.5
22.9
23.9
23.1
25.4
27.05
25.68
24.52
26.80
27.84
2.37
2.27
2.25
2.22
2.19
2.48
2.32
2.42
2.34
2.57
2.741
2.602
2.485
2.716
2.821
525
540
535
544
573
514
531
518
530
506
0.271
0.263
0.266
0.262
0.248
0.277
0.268
0.275
0.269
0.281
362
0.244
54.6
56.16
5.53
5.69
201
219
0.309
0.385
37.0
46
40.54
43.1
42.2
45.2
3.75
4.66
4.108
4.37
4.28
4.58
351
340
316
343
343
0.742
0.558
0.292
0.312
0.312
19.6
18
42.4
41
49.5
43.5
35.3
54.0
32.4
39
33.7
16.6
16.8
11.9
24.2
29.92
32.15
1.99
1.82
4.30
4.15
5.02
4.41
3.57
5.47
3.28
3.95
3.42
1.68
1.70
1.21
2.45
3.032
3.258
863
0.267
294
256
248
0.454
0.513
0.554
239
348
348
325
780
0.500
0.430
0.424
0.576
0.236
37.1
47.7
3.76
4.83
389
204
169
194
133
0.26
0.559
0.593
0.434
0.525
40.34
34.09
31.90
30.86
29.15
28.6
4.087
3.454
3.232
3.127
2.954
2.90
254
430
430
433
398
400
0.233
0.280
0.280
0.278
0.252
0.245
short
standard
long
DEAN #37261
LEFT
(McGHP)
6.158
INTERACTIVE
top of rh
base of rh
SECTION 6
cap height
base of text
TABLE 6.5 Critical Properties (Continued)
Substance
1,1,2-Trimethylcyclopentane
1,1,3-Trimethylcyclopentane
cis,trans,cis-1,2,4-Trimethylcyclopentane
cis,cis,trans-1,2,4-Trimethylcyclopentane
2,2,3-Trimethylheptane
2,2,4-Trimethylheptane
2,2,5-Trimethylheptane
2,2,6-Trimethylheptane
2,3,3-Trimethylheptane
2,3,4-Trimethylheptane
2,3,5-Trimethylheptane
2,3,6-Trimethylheptane
2,4,4-Trimethylheptane
2,4,5-Trimethylheptane
2,4,6-Trimethylheptane
2,5,5-Trimethylheptane
3,3,4-Trimethylheptane
3,3,5-Trimethylheptane
3,4,4-Trimethylheptane
3,4,5-Trimethylheptane
2,2,3-Trimethylhexane
2,2,4-Trimethylhexane
2,2,5-Trimethylhexane
2,4,7-Trimethyloctane
2,2,3-Trimethylpentane
2,2,4-Trimethylpentane
2,3,3-Trimethylpentane
2,3,4-Trimethylpentane
2,2,4-Trimethyl-1,3-pentanediol
2,3,6-Trimethylpyridine
2,4,6-Trimethylpyridine
2,4,6-Trimethyl-1,3,5-trioxane
Tungsten(VI) oxide tetrachloride
1H-Undecafluoropentane
Undecane
1-Undecene
Uranium hexafluoride
Vinyl acetate
Vinyl chloride
Vinyl fluoride
Vinyl formate
Water
Xenon
1,2-Xylene
1,3-Xylene
1,4-Xylene
Zirconium tetrabromide
Zirconium tetrachloride
Zirconium tetraiodide
␳c , g · cm⫺3
Tc , ⬚C
Pc , atm
Pc , MPa
306.4
296.4
298
29.0
27.9
27.7
2.94
2.83
2.81
306
28.4
2.88
338.6
321.4
325.0
320.3
344.4
340.6
339.7
331.0
327.2
333.8
317.2
329.8
349.4
336.5
347.8
339.7
315
300.6
295
335.7
290.4
270.9
300.5
293.4
398
381.4
379.9
290
509
22.4
21.4
21.4
21.0
22.9
22.6
22.1
21.6
21.9
22.1
21.2
21.9
23.4
22.9
23.4
22.1
24.6
23.4
23.0
2.27
2.17
2.17
2.13
2.32
2.29
2.24
2.19
2.22
2.24
2.15
2.22
2.37
2.32
2.37
2.24
2.49
2.37
2.33
546
552
559
573
538
538
547
560
541
544
560
550
526
579
524
547
0.261
0.258
0.256
0.248
0.265
0.265
0.260
0.254
0.263
0.262
0.254
0.259
0.271
0.246
0.271
0.261
519
0.247
26.94
25.34
27.83
26.94
25.6
2.730
2.568
2.820
2.730
2.59
436
468
455
461
364.6
0.262
0.244
0.251
0.248
0.4010
338
1.01
657
0.238
0.240
1.41
0.325
0.370
0.320
0.343
0.325
1.105
0.288
0.282
0.280
0.99
0.730
1.13
170.8
365.7
364
232.7
228.4
156.6
54.7
202
374.2
16.583
357.2
343.9
343.1
532
505
687
19.4
19.7
45.5
22.4
55.3
51.7
57
217.6
57.64
36.83
34.95
34.65
1.97
2.00
4.61
2.27
5.60
5.24
5.78
22.04
5.84
3.732
3.541
3.511
56.9
5.77
Vc , cm3 · mol⫺1
250
265
169
114
210
56.0
118
370
375
379
415
319
528
short
standard
long