Water related environmental problems at Sinop peninsula in the Black Sea, Turkey 1. Study area: overview of waste water and sea pollution situation along the Turkish Black Sea Coast and Sinop peninsula The Black Sea is the world’s largest inland sea and widely perceived to be polluted. Almost one-third of the entire land area of continental Europe drains into it and the Black Sea environment has suffered degradation from waste from approximately 17 countries (Fig. 1). The Black Sea is located between the latitudes 40055’ and 46042’ N and the longitudes 27027’ and 41042’ E. The Black Sea has been historically one of the most biologically and ecologically productive marine ecosystem in the world. Fig. 1. The Black Sea and its discharge points (Bat et al., 2009) Environmental problems faced in Black Sea basin may be both local and cross border based. The Black Sea being polluted by air pollution borne from Middle Europe, Russia, and Balkan countries by air masses and regional scale air pollution resulting from this and acid 1 rains put the local community under threat (Anonymous, 2004a). Considering the fact that the Black Sea is the basin used for the international waste transportation, we can once more underline the importance of cross border pollution of the Turkish coast of the Black Sea. Fig. 2. Black Sea coastal towns and major rivers location points (Bat et al., 2009) In addition to crossborder problems of the Black Sea basin, numerous vital local and regional problems are encountered. These problems can be categorised as follows: Problems resulting from the solid waste management, Urban and industrial air pollution, Marine pollution, Noise, Surface and underwater pollution, Land misuse and land pollution, Dangerous waste problems (Anonymous, 2004a). Pollution burden of the Black Sea basin is high for both natural reasons and wastes the rivers in various countries bring. Heavy metal values flowing into the Black Sea from Turkey are shown in Table 3. The most prominent problem of the provinces located along the Black Sea coast is the uncontrolled discharge into the coastal areas of waste waters and solid wastes. In addition to the local pollution of various resources of the Turkish Black Sea coast, local pollution has a crucial importance in views of coastal use for recreation purpose, because local pollution influences the health of the people swimming in the sea in the summertime. Urban waste waters of all settlement areas along the coastline is discharged into the sea 2 untreated. The most notable example of this was observed in Samsun, Ordu, Giresun and Sinop until recently. Domestic discharge is the greatest source of organic substances discharged into coastal zone. In Turkey, in many towns and cities situated on the coast, however, sewage is discharged untreated. Organic substance is an important nutrient, as it is a source of food for many benthic invertebrates in the marine ecosystem (Bat et al., 2009). For example, Sinop is the smallest city and located on the Southern coast of the Black Sea. Gökkurt (Gökkurt, 2007) showed that some pollutant loads from Sinop city domestic discharge point to the Black Sea coast and Table 2 shows participation of pollutants load from Turkish coast of the Black Sea and especially in Samsun, total load of pollution higher than other cities of Turkish coast of Black Sea (Table 1; Table 2). The calculations were done according to the flow of the discharge 52 litres per second (Anonymous, 2004b). Some of the parameters are exceeded the Turkish Environmental Regulations’ criteria. In the last decade, the local population in Sinop is about 30.000; however, the population increases up to 80.000 in summer. Thus, untreated domestic wastes and human activity along the coastal zone increase in summer and probably give rise to high pollution. Table 1. Participation of land based sources pollutants load from Turkish Coast of the Black Sea (Sarıkaya et al., 1999) No Stations Cumulative load (t.yr-1) Total load (t.yr-1) % 1 Samsun 9249.66 20.6 2 Trabzon 17508.10 39.1 3 Giresun 25112.00 56.0 4 Zonguldak 30644.51 68.4 5 Ordu 34154.31 76.2 6 Bafay 36644.31 81.8 vegetable liquid oil plant. (Samsun) 7 Rize 38598.79 86.1 8 Bul-Co fish plant (Giresun) 40020.79 89.3 9 Sinop 40907.97 91.3 10 Bartın 41611.75 92.9 11 SEKA paper plant (Giresun) 42125.05 94.0 12 Slaughterhouse 42619.41 95.1 of meat and fish 3 Association (Sakarya) 13 Artvin 43008.79 96.0 14 Kastamonu 43360.69 96.8 15 Bolu 43606.05 97.3 16 Dogan Biscuit and Chocolate (Sakarya) 43838.75 97.8 17 SEKA Paper Plant (Zonguldak) 43949.02 98.1 18 Caroglu Slaughterhouse (Sakarya) 44043.19 98.3 19 Koy-Tur Chicken Plant (Sakarya) 44043.19 98.5 20 Mankap Vegetable Liquid Oil Plant 44201.64 98.7 (Zonguldak) 21 Karsu fish bait Plant (Trabzon) 44253.44 98.8 22 Bekar Textile Plant (Samsun) 44302.21 98.9 23 Akova Flour Plant (Sakarya) 44347.98 99.0 24 Dokap Flour Plant (Zonguldak) 44389.59 99.1 25 Sinop Textile Plant 44426.91 99.2 26 Acid Industry. – Ethyl Alcohol Plant 44464.01 99.2 (Sakarya) 27 İpek Flour Plant (Zonguldak) 44500.75 99.3 28 Elif Flour Plant (Trabzon) 44536.89 99.4 29 Cargill Flour Plant (Sakarya) 44570.25 99.5 30 Ketas Food Make with Milk Plant 44602.16 99.5 (Trabzon) 31 Ak A. Textile Plant (Zonguldak) 44633.16 99.6 32 Ahenk Turkish Delight and Sugaring 44663.76 99.7 44688.19 99.7 Plant (Samsun) 33 Kebir Food Make with Milk Plant (Trabzon) 35 Ansan Beverages Plant (Trabzon) 44711.08 99.3 34 Camadan Flour Plant (Samsun) 44725.78 99.3 36 Ünsan Flour Plant (Ordu) 44739.93 99.9 37 Entas Chicken Plant (Sakarya) 44753.31 99.9 38 Terme Metal Industry Plant (Samsun) 44765.99 99.9 39 Yıldız Resine Plant (Samsun) 44775.99 99.9 4 40 Özkasapoglu Feed Plant (Zonguldak) 44805.67 100.0 41 Bizon Lumber Plant (Sakarya) 44805.68 100.0 44805.68 100.0 Total Table 2. Pollutants discharged through domestic waste waters into the Black Sea (Bakan and Büyükgüngör, 2000) Discharge TSS BOI KOI o-P Total P NH3-N NO3-N NO2-N TKN (km3/yıl) (t/yr) (t/yr) (t/yr) (t/yr) (t/yr) (t/yr) (t/yr) (t/yr) (t/yr) (t/yr) Sinop 0.004 596 827 1635 32.7 37.3 85.9 7.3 0.13 114.6 4.7 Samsun 0.008 1600 2054 3037 46.9 62.4 25.6 12.3 1.04 132.0 48.1 Ordu 0.010 886 1946 820 54.9 68.1 19.3 17.1 0.14 44.8 51.8 Giresun 0.004 473 2063 2249 27.9 50.8 16.5 9.5 0.13 128.5 36.2 Trabzon 0.010 1489 2099 2221 69.3 49.8 9.6 30.2 0.13 208.5 118.5 Rize 0.009 276 1477 1282 32.7 43.9 41.8 14.2 0.15 285.5 30.5 City Kızılırmak and Yesilirmak, the two most important rivers of Black Sea Region, and a lot of big and little industries (food, cement, fertilizer, pesticides, resin, plastic, textile, cigarette manufacturing) exist in the Middle Black Sea Region of Turkey. Most of these factories have no treatment plant and they have a considerable potential to create local pollution problem (Altas et al, 2001). On the other hand, the eastern part of the Black Sea Region has no important industrial factories, but only hazelnut facilities, floor manufacturing and fish-oil factories. Besides, small industrial activities, pulp and paper factory present in this region is one of the important industries. Heavy metals in marine environment are caused by discharge of especially industrial pollutants (Table 3). 5 Detergent Table 3. Annual load of heavy metals in rivers and streams along the Black Sea Coast of Turkey (Altaş ve Büyükgüngör, 2006) Pollutants (t.yr-1) Discharge (km3.yr-1) Total Chrome Cadmium Lead Sakarya River 6.02 128.595 781.144 - Cark Stream 0.31 4.086 12.867 - Melen Stream 1.57 95.96 28.726 - Alapli Stream 0.27 - 11.520 13.927 Gülüc Stream 1.19 - 20.378 - Catalagzi Stream 0.13 2.627 3.115 - Kozlu Stream 0.02 - 0.053 - Zonguldak Stream 0.13 0.791 0.885 - Filyos Stream 3.22 - 262.824 - Bartin Stream 0.36 16.230 0.773 18.196 Kizilirmak River 7.39 427.101 1234.239 722.303 Kurtun Stream 0.16 22.588 2.084 1.239 Mert River 1.06 19.214 98.761 - Yesilirmak River 10.26 2549.228 1505.295 - Milic Stream 0.43 - 3.067 0.459 Civil Stream 0.6 3.140 0.117 - Melet River 0.83 128.298 124.780 5.045 Aksu Stream 0.97 3.608 8.326 - Fol Stream 0.20 - - - Sögütlüdere Stream 0.12 - 2.633 - Stream of Degirmen 0.87 - - - 6 In coastal zone of Sinop suspended solid matter concentrations are very high in respect to “Turkish Environmental Regulation, 2004 table 3: General Quality Criteria of Marine” (Anonymous, 2004c). The reasons of this situation are untreated domestic discharges and erosion problem in coastal zone of Sinop peninsula (Bat et al, 2009). Present Industrial Pollution in the Region There is little industry located in the locality. The wastes of these plants flow into the Black Sea untreated through the rivers directly or indirectly. Besides, breakwaters and ports built in Black Sea without the proper estimation of currents and tides cause in vital destruction to marine environment (Anonymous, 2003). Land Misuse and Land Pollution There are limited number of fields appropriate for agriculture and settlement because of the location of the mountain ranges horizontal to the sea in the Blak Sea region. Wrong practices carried out in these limited number of fields (both agricultural fields and industrial purpose areas) cause these areas to be destructed (Anonymous, 2003). 2. Problem definition Sinop is a pretty city located right at the middle of the Turkish Black Sea coast and on the northernmost tip of Turkey. Sinop is located on a geographical area on Boztepe Peninsula of 6 km length, which extends northward and is surrounded by the sea on three sides. The most most important factor leading to marine pollution in the city is uncontrolled discharges into the sea of the domestic waste waters. Marine pollution upsets the balance of the nature and negatively influences any kind of life, and the main reasons of the marine pollution in Sinop are as follows: - Domestic waste waters - Pollution by the sea vessels - Domestic solid wastes - Pollution caused by the fisheries activity ( Anonymous, 2004b) Our research was aimed at revealing in what way waste waters discharged into the sea untreated influence the physico-chemical properties of the sea waters, particulary used for recreational purpose and having an economic value for the city (Gökkurt et al., 2007). 7 Figure 3. Sampling stations regarding the research conducted on Sinop coasts (Gökkurt, 2007) As a result of discharge of the domestic waste waters into the sea untreated, decrease, migration, and even death in marine lives can be noticed. Organic substances are predominantly present among the domestic waste waters. Oxygen consumption of these substances in the receiving sea environments has a great importance in views of water quality. Organic substances present dissolved in the sea water are composed of natural origins, mainly animal and herbal, and unnatural compounds accompanying untreated urban and industrial waste waters. According to our results of an ongoing study, the data obtained from the organic substances have been found above the maximum tolerable amount. This situation is due to the deep structure of the stations high in organic substances and the uncontrolled discharge of the domestic waste waters (Bat ve Gökkurt, 2008). Nitrite and nitrate nitrogen known to result from the domestic waste waters generally in Sinop coastal zone may have various effects in views of marine pollution. Oxygen value in the environment being affected and the threat to the life in case of an extreme increase. Nitrogen intake into the sea in natural ways may be possible with the dissolving from the atmosphere and rain waters. In addition, drainage directed to the sea environment untreated increases the nitrite and nitrate nitrogen amount. The result of our research is that this value has been exceeded in the coastal areas in general, in the points in particular where a fecal pollutant discharge is conducted, in the areas where landslides, which can be regarded as one of the most important problems of Sinop, take 8 place, in the areas close to the agricultural fields, and thus water quality suffers. Pollution load values belonging to some parameters are shown in Table 4 (Bat and Gökkurt, 2008). Particularly the waste waters merging into the sea environment with the human and animal excrements should be properly disinfected prior to the discharge into the receiving environment in the zones like inner port having a low potential of dissolving. The most important one of the measures to be taken in order to prevent marine pollution in the city will be to treat / refine the waste waters with the most appropriate method. Long term plans necessary for the conservation of our marine resources can be effectively prepared and implemented only when the exact amount of the pollutants have been determined. 9 Table 4 Pollution load values of some parameters (Gökkurt et al., 2007) Station No (in Fig. 3) 1 2 3 4 5 6 7 8 BOI5 (ton/yr) 3,95 12,44 4,42 3,36 4,40 6,89 6,15 3,76 NO2-N (ton/yr) 0,153 0,25 0,166 0,161 0,16 0159 0,151 0,158 NO3-N (ton/yr) 17,24 39,58 17,384 18,54 17,71 16,91 9,62 16,73 Organic matter (ton/yr) 39,27 54,43 40 33,99 32,85 33,76 28 38,36 10 Lack of infrastructure and absence of waste water treatment system in the city have caused problems. Figure 4. Discharge into the coastal zone of surface waters through a closed channel (Gökkurt Baki, 2011). All surface waters in the city are ultimately discharged into the sea in the city (Figure 4). Waste water collection system of Sinop was designed by the Bank of Provinces. However, due to the system still not in operation, the waste waters of Sinop are discharged into the sea at three points without taken into any treatment facility (Gökkurt Baki, 2011; Figure 5; Figure 6; Figure 7). Work is done in order to put the wastewater treatment system into practice as soon as possible. 11 Figure 5. Discharge of the wastewater into the sea from the main collector Çukurbağ district (Original, March, 2010; Gökkurt Baki, 2011). Figure 6. Discharge of the wastewater into the sea (Original, March, 2010; Gökkurt Baki, 2011) 12 Figure 7. Discharge of the wastewater into the sea (Original, Eylül, 2006; Gökkurt Baki, 2011) 3. Need for drainage and treatment systems In order to prevent the local marine pollution in the other coastal cities where the drainage system is inadequate, drainage and treatment/discharge systems are built. (Gökkurt Baki, 2011). Depending on the determined infrastructure problems, the existing slope in the city causes the flood waters and waste waters to be directed to coastal zone and sea. This constitutes a non-point polluting source for the city coasts. It will be possible to prevent the pollution in these areas by operating the waste water treatment facility in order to decrease the coastal/marine pollution in Sinop. However, the problems resulting from various material restrictions, demanding official procedures and lack of infrastructure remain unsolved. We found out that it negatively affects both the water quality of the coastal areas and in the long run the sediment quality and bentic and pelagic life cycles, and also noticed that the discharge of the waste waters can negatively affect the city tourism. (Table 4). From the visuals and findings of the coastal areas taken at various points and times, it can be noticed that all surface waters in the city coasts are discharged into coastal zone for now. This situation is the most important factor affecting the coastal zone of the city and city tourism, but work for bringing into operation the treatment plant considered as a solution to 13 this problem continues. Waste water management is one of the priority issues for the city. Domestic waste waters discharged into the coastal zone of the outer port can be said to be stuck on the coastal zone of Akliman and even Hamsilos Bay owing to the currents in the outer port. The effects of the wastewaters discharged into the coastal zone of the city at three points can be seen at any part of the coastal zone because of the currents (Gökkurt Baki, 2011). It is necessary to determine scientifically the environmental problems of the city, to build environmental protection infrastructure, to ensure the management of surface and underground water resources in the planning field, most important of all to promote and valorise the infrastructure unity among the local authorities, to facilitate the waste water and solid waste management, a part of the integrated coastal zone management, by the relevant authorities. 4. Public Participation We didn’t determined the inclusion public participation because of the undeveloped industrial activities or any activities about public participation at the province of Sinop. 5. Conclusions Sustainable development of the Black Sea requires continued international cooperation. Solutions to the Black Sea environmental problems demand that uniform strict rules be adopted by each country. It means that the regulations should also cover those countries which influence the Black Sea environment through the rivers, mainly Danube, Dnieper and Dniester and another land based pollution sources. Different types of pollutants in domestic and/or industrial discharges have different effects on human health and ecosystems at the point of discharge and in the surrounding environment. This surrounding environment may be very large and may extend beyond international borders. The risks increase proportionally with the quantity of the wastewater and concentration of the pollutant. Turkey is developing countries where industrial and urban developments mostly occur in coastal areas through increased input of wastes impose a further stress on the Turkish coasts of Black Sea. The application of the agreements requires that each country which has a coast to the Black Sea, concerned creates an environmental policy. Harmonization of legislation and 14 standards, preparation of effluent discharge inventories and mapping of major pollution sources and establishment of water monitoring programmers. These components are stated in the activities of the Black Sea Environmental Programme but the legislative frame for their realization still does not exist in all countries in the region (Bat et al., 2009). The most important point regarding the marine pollution is the determination of the present state of pollution and regular monitoring of pollution by measuring the parameters concerned. Utilisation of the sea in Turkey, surrounded by the sea on three sides, and its protection from pollution have a crucial importance in views of thhe sustainability of the ecosystem, human health, and country economy (Anonymous, 2004b; Gökkurt et al., 2007). Pollution resulting from land based pollutants on Sinop coastal zone started locally, and long term solutions should be determined as soon as possible. Determining the present state in the area is one of the most important steps in order to commit to a rearch for sustainable solution. Therefore, the present study is considered to shed light on future research and possible solutions. REFERENCES Altas L, Orhan Y, Büyükgüngör H. (2001) Investigation of landbased pollution parameters in the surface water and shores through the Samsun city. In: Third Black Sea international conference, environmental protection technologies for coastal areas, Bulgaria, paper 535 Atlaş L., Büyükgüngör, H., (2006). Heavy Metla Pollution in the Black Sea Shore and offshore of Turkey, Environ Geol, 8 s. Anonim, (2003). Türkiye’nin Çevre Sorunları, Türkiye Çevre Vakfı Yayını, Ankara, 472 s. Anonim, (2004a). Orta Karadeniz’de Çevre Yönetimi Eğitim Semineri, Türkiye Çevre Vakfı, 7-8 Ekim 2004, Samsun, 83 s. 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