Shipping Regulations and Guidance December 2012 Safe shipment of coal introduction The shipment of coal, the industrial revolution and the start of a modern shipping era beyond the sail, all go hand in hand together. While no longer used as a common ship fuel, coal remains a major cargo with hundreds of millions of tons being shipped every year for power consumption and industrial uses like steel production. The vast majority of coal traded is moved by sea. Shipping this cargo safely is a key concern for the dry bulk industry. The cargo can self-heat, it can give off explosive gasses, ooze corrosive chemicals, and it can liquefy. Done well, the cargo is taken safely from load to discharge Port without incident, but if not done well, the shipment can lead to loss of life and serious vessel damage. Christian Ott Vice President Claims/ Loss Prevention and Recurring Claims Assuranceforeningen SKULD (Gjensidig) Prepared with Technical advice from Nico Zurcher and Dr Thomas Hill of Hannaford Forensic Services www.skuld.com Today coal production, use and shipment are greater than at any time in recorded world history. the cargo and its nature Coal was formed from dead vegetation, deposited around 300 million years ago, through a combination of biochemical and geological processes. One of the difficulties with transporting large quantities of coal in bulk is that it is a cargo capable of self-heating to the point of ignition, which has often posed a serious challenge to those carrying it. Self-heating is defined as the initiation of exothermic reactions leading to a rise in temperature in the combustible material. This occurs when the rate of heat production exceeds that of heat loss, leading to a rise in temperature which then accelerates the rate of oxidation, potentially leading to ignition and a fire. The conditions that are required for self-heating cargoes to progress to ignition include: A ready supply of oxygen from the air A large surface area over which the oxidation reaction can take place The presence of moisture Insulation against heat loss As well as self-heating, coal emits methane, a flammable gas with a low explosive limit (LEL) of 4.4% in air. Explosions resulting from the ignition of methane in cargo holds can result in damage to vessels, personal injuries and loss of life. Bituminous Coal has a low methane content, whereas Anthracite Coal can contain several orders of magnitude more. Whilst it is acceptable to transport coal capable of emitting methane, the Shipper should provide the vessel with details on its safe carriage. By ventilating the holds, the methane concentration can be managed so that these are well below the LEL, although, unfortunately, whilst ventilating the cargo removes methane, it also reintroduces oxygen into the hold, thereby creating a situation conducive to self-heating. It is essential that gas readings for carbon monoxide and LEL are accurate, so that informed decisions can be made about how much ventilation to allow. As with all bulk cargoes, rules regarding their safe carriage are given by SOLAS and the IMSBC Code, as briefly outlined for coal below. solas and imsbc code requirements Under SOLAS, coal is defined as dangerous goods in solid form in bulk. Documents In all documents relating to the carriage of dangerous goods in solid form in bulk by sea, the bulk cargo shipping name of the goods shall be used. Each ship carrying dangerous goods in solid form in bulk shall have a list/manifest setting forth the dangerous goods on board and location. A copy of one of these documents shall be made available before departure to the person or organisation designated by the Port State Authority. 62 Shipping Regulations and Guidance December 2012 Stowage and requirements When the coal is loaded it must accordance with the nature of the to spontaneously heat or combust, unless adequate precautions have the likelihood of the outbreak of fire. If there is a fire or self-heating has progressed to an advanced state, the Vessel should: be done safely and in cargo. As coal is liable it should not be carried been taken to minimise Close all ventilation to the holds C ommence boundary cooling of the affected holds and consider heading towards the nearest port as a refuge Coal is a cargo covered by the International Maritime Solid Bulk Cargo (IMSBC) Code, which provides regulations for its loading and carriage. T he P&I Club should be notified without delay as an emergency response may need to be triggered including the attendance of an expert The IMSBC Code requires Shippers to provide cargo details including moisture content, sulphur content, particle size, and information on whether the cargo is liable to emit methane, self-heat, or both. The IMSBC Code requires that the Vessel has the following: E nsure all spaces adjacent to the holds are checked prior to entry and that no-one enters confined spaces without confirming that it is safe to do so P rovide Owners and the P&I Club with all temperature and gas monitoring records for the voyage A n instrument capable of measuring oxygen, carbon monoxide and methane The best Loss Prevention: if the Master is in any way concerned prior or during loading, or he is not provided with proper cargo documentation: do not load the cargo. Gas sampling ports on all holds A means of measuring the pH values of bilge water samples gas detectors and thermal detectors Further, the Code recommends that the vessel has a means of measuring cargo temperature, both during loading and the voyage, such as an infra-red heat detector. The IMSBC Code requires vessels carrying coal to carry gas detectors, and that their crew are trained in their use. The gas detector should first be checked in a gas-free area, before entering enclosed spaces or taking hold measurements. Most gas detectors are fitted with electrocatalytic sensors to detect flammable gases and are capable of operating reliably in atmospheres with more than 15% oxygen. Below 10%, readings of flammable gas levels using electrocatalytic sensors should be regarded as unreliable. Vessels carrying coal should consider obtaining a gas detector with an infrared sensor which does not require oxygen to provide accurate flammable gas readings. The IMSBC code states that coal should not be loaded if its temperature exceeds 55°C. After loading, and unless advised otherwise, the holds should be ventilated for the first 24 hours or until the methane concentration is acceptably low, i.e. below 20% LEL. Once the cargo has been loaded and hatch covers closed, evidence of self-heating can easily be checked by monitoring carbon monoxide levels. The atmosphere in each hold should be monitored daily. If the cargo is being ventilated to remove methane, then ventilation should be stopped at least four hours prior to sampling. According to the IMSBC Code, carbon monoxide levels above 50 ppm, or a steady rise of the cargo’s temperature over three consecutive days, indicate that selfheating is taking place, and the Master should contact Owners and the Shipper. As coal is a good insulator, hot spots within the bulk of the cargo can still go undetected, even if the crew take bilge well temperature readings or surface temperature measurements. Although not required by the IMSBC Code, having an infrared thermometer can greatly assist the crew in monitoring the surface of the cargo prior to and during loading, to ensure that it is not loaded above 55°C. summary When transported in bulk, coal is capable of self-heating to the point of ignition. Nevertheless, the majority of vessels carry coal cargoes without incident, and adhering to the requirements and recommendations in the IMSBC Code greatly reduces the risks. Using the correct gas and temperature detecting equipment provides the necessary information needed to manage the transportation of coal cargoes safely. However, to be effective, detection equipment must be used correctly, maintained in good working order and any limitations understood in subsequent analysis. Prior to departure, and during the voyage, the Master should also ensure that: The cargo is trimmed flat to reduce its surface area G as monitoring equipment on board is well maintained and calibrated in accordance with the manufacturer’s instructions A ll enclosed spaces adjacent to the holds are regularly monitored and adequately ventilated N o one should enter confined spaces without first confirming that it is safe to do so If the cargo behaves differently from that specified in the cargo declaration, the Master should report this to the Shipper, his Technical Managers and P&I 63
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