F种具有梯状链结构有机模板硫酸/的合成、结构表征

!Œ != Œ J $
!"$! Ž J 
R
w
‘
‘
’
!!
;<M>)B) eCR]>KL Cf M>C]OK>M; ;<)cMB@]S
dU-#!= >U$J
$'JJ!$'=!
!"#$%&'()$*+,-./012!()3456789:
!
"#
#
$#
%
&#
'
(!
'
)!##
9$ *+,-./0/0,/1!230/,456789:;!*<
9! =>?@ABCDEFGHIJKL!?@ $!'&$&:
!$&&&%:
;<" =>?@ABCDEFGHIJKLMNOP/QKRSTUVWX!9;!<=>:?@A9BC':!$<!CD 9!: %Y8Z E! [\][&^
_&C`abcdefghiGjk' lmnopqrm;%!!$F" stu" gv #G&5H(= $9I: /* %$G$5%J! J9$&: /* %%G&5=(! J9':
/* %!G%&5(H=9(:" %&G&5%(( J9=: /*I%'G' " wEx ! QyzOP{ @AC= |}n~ BC' }nPF" B9$:~ B9!:€ @A9$:‚ƒ%8
Z I „ B!C!@A ‚…PF†N%‡ˆQ†N8Z "I!C9CH: ‚ƒ‰FH„/QLMN"
=>?" ABCD( UVWX( mnOP( Š‹
@ABCD" C($'5I'$
EFGHI" K
EJKD" $&&$!'=($9!&$!:&J!$'JJ!&(
"#$%#&'()*+$ ",-&'(./.0 1),.&+$ "&)23&2)( +-4 52*/-(.3(-3( #6 + 7)8+-/3
9*/-( :(*;$+&(4 :()</2* "2$6+&( =/&' 5+44()!5/>( 1'+/-.
LM <1,$ N<)>O L6,# N<K>O P6/Q# ER E,/! ER S+/!T$
9$()**+,+ )- (.+/01234 5"6 (.+/0%5* 7",0"++30",8 9252+ :+4 ;5$)352)34 )- <52+305*1!)30+"2+6
(.+/0%5* 7",0"++30",8 =#">0", ?"0@+31024 )- A+%.")*),48 =5">0", !$&&&%8 (.0"5:
9!B+5@4 C0* ()/D5"48 ;05).+ !+23)*+E/ F0*05*+8 (=!(8 !5">0"8 ;05)"0", $!'&$&8 (.0"5:
9<.)+3&? K UVQ+/,8 +*,/6 46*W-+467 #P 46VA,1* X1-Y+46 9;!<=>:?@A9BC':!$<!CD 9!: Z+X A66/ X./4Z6X,[67 1/76V
XU-\U4Z6V*+- 8U/7,4,U/ +/7 X4V1841V+--. 8Z+V+846V,[67 A. X,/Q-6!8V.X4+- E!V+. 7,YYV+84,U/T M]T @OK +/7 M;^5 @Z6
X,/Q-6!8V.X4+- E!V+. +/+-.X,X UY 8U*WU1/7 ! V6\6+-X 4Z+4 4Z6 8V.X4+- A6-U/QX 4U *U/U8-,/,8T XW+86 QVU1W !!$F" _,4Z
5G"5H(= $9I: /*T $G$5%J! J9$": /*T %G"5=(! J9': /*T !G%"5(H=9(:"T GG"5%(( J9=: /*IT HG'5 @Z6 X4V1841V6 UY
YV+*6_UV` ! ,X 8U/X4V18467 YVU* @AC= WU-.Z67V+ +/7 BC' 464V+Z67V+5 B9$: +/7 B9!: 8U//684 @A9$: +/7 ,4X 8V.X4+!
--UQV+WZ,8 W+V4/6VX A. 1X,/Q 4ZV66 B!C!@A -,/`+Q6X 4U Q6/6V+46 7U1A-6 8Z+,/XT _Z6V6+X 4Z6 +73+86/4 7U1A-6 8Z+,/X
+V6 8U//68467 A. "I!C 9CH: 4U YUV* + /U\6- -+776V!-,`6 8Z+,/X5 ;;P;a ==$'!$5
@(, =#)4? XU-\U4Z6V*+- X./4Z6X,Xb 46VA,1* X1-Y+46b 8V.X4+- X4V1841V6b -1*,/6X86/86
]686/4 .6+VXT *18Z +446/4,U/ Z+X A66/ W+,7 4U
4Z6 *64+- XU-,7 X4+46 *+46V,+-X _,4Z $PT !P +/7 IP
X4V1841V6X /U4 U/-. YUV 4Z6,V ,/4V,Q1,/Q +V8Z,46841V6X
+/7 4UWU-UQ,6XT A14 +-XU YUV 4Z6,V WU46/4,+- +WW-,8+4,U/X
,/ 8+4+-.X,X?$!'DT X6W+V+4,U/T ,U/ 608Z+/Q6?H!=DT +/7 *+Q/64,8
WVUW6V4,6X?%D5 @Z6 _UV` *+,/-. YU81X67 U/ WZUXWZ+46X
+/7 X,-,8+46XT ,/46/X,\6 V6X6+V8Z V6X1-467 ,/ -U4X UY
/6_ ,/UVQ+/,8 YV+*6_UV`X *+46V,+-X _,4Z 7,\6VX6
!!!!!!!!! !"#$!!"#$!$!!$% " !%&'($!!&$!!&'!!( "
)*+,-./01234567"
!
89:;<" )!*+,- !.+/012/314567158/
X4V1841V6X +/7 8U*WUX,4,U/X5 >6_ XU-,7 X4+46 *+46V,+-X
_,4Z /U\6- 4UWU-UQ,8+- X4V1841V6X +/7 ,/46V6X4,/Q
WVUW6V4,6X 8+/ A6 YUV*67 A. 6*W-U.67 B!C!c -,/`+Q6X
,/ 4Z6 BC' 464V+Z67V+ +X +/ 6YY684,\6-. A1,-7,/Q 1/,4?$"!$'D5
;U*W+V67 _,4Z U4Z6V 4V+/X,4,U/ *64+-XT 4Z6 -+/4Z+/,76
86/46VX Z+\6 Z,QZ 8UUV7,/+4,U/ /1*A6VX +/7 + \+V,64.
UY 8UUV7,/+4,U/ 6/\,VU/*6/4X +--U_ 4Z6 YUV*+4,U/ UY
/U\6- 4UWU-UQ,8+- X4V1841V65 @U 6*W-U. + XW68,+-
#
@M["
$
%
&
&
! !" "
'
&'/ ,.95.$() &)(/ 0@:ARZ ! %; \"]4; (' & *#9&$ $&-(# #5
#$%&'() &*('+ &, ,-$.)-.$+!/($+)-('% &%+'- 01234 (,
#'+ #5 -6+ ,-$&-+%(+, 76()6 .,+/ (' -6+ ,8'-6+,(, #5
9&'-6&'(/+ ,.95&-+,: 1# 5&$; ,+<+$&9 #$%&'()!-+*=9&-+/
,#9(/ ,-&-+ 9&'-6&'(/+ ,.95&-+, *&-+$(&9, 6&<+ >++'
$+=#$-+/ ?@A!!!B: C+$>(.* (, &' (*=#$-&'- *+*>+$ (' -6+
$&$+!+&$-6 +9+*+'-, >+)&.,+ #5 -6+ +D)+99+'9.*('+,)+')+ =$#=+$-8: C# -6+ >+,- #5 #.$ E'#79+/%+;
-+$>(.* ,.95&-+, -+*=9&-+/ >8 #$%&'() &*('+, 6&<+
9+,, >++' $+=#$-+/ ?@FB: G' -6(, 7#$E; 7+ +*=9#8+/
,#9<#-6+$*&9 *+-6#/ &'/ & '+7 @2 -+$>(.* ,.95&-+
0H!I"JK ?C> 01LMK!!I!LB 0!K 7&, ,.))+,,5.998 =$+=&$+/
(' -6+ =$+,+')+ #5 /(*+-689&*('+:
#.- .'/+$ & *()$#,)#=+ &'/ %9.+/ &- -6+ -(= #5 & -6('
!
%9&,, 5(>+$ 7(-6 )8&'#&)$89&-+ &/6+,(<+: 1('%9+!)$8,-&9
"#$%&'(%)*+,
!-!
.+*%&'+,/ +)0 (%*120/
399 )6+*()&9, =.$)6&,+/ 7+$+ #5 $+&%+'- %$&/+
&'/ .,+/ 7(-6#.- 5.$-6+$ =.$(5()&-(#': C6+ +9+*+'&'&98,(, 5#$ C> 7&, =+$5#$*+/ #' N++*&' ('/.)-(<(-8
)#.=9+/ =9&,*& OGHPK ,=+)-$#*+-+$; 76(9+ -6+ H; I
&'/ J &'&98,+, 7+$+ =+$5#$*+/ #' & P+$E('!Q9+*+$
!MRR +9+*+'-&9 &'&98S+$: GT ,=+)-$.* 7&, $+)#$/+/
#' & J()#9+- G*=&)- M@R UCGT ,=+)-$#*+-+$ .,('% VW$
=+99+-, (' M RRRXMRR )* Y@ $+%(#': C6+$*#%$&<(*+-$()
&'&98,+ 7&, )&$$(+/ #.- (' J! &-*#,=6+$+ #' &
2(&*#'/ -6+$*#%$&<(*+-$() &'&98S+$ 5$#* AR -# @ RRR
" 7(-6 & 6+&-('% $&-+ #5 @R "!*('Y@:
!-3 45)*1%/'/ +)0 61+&+6*%&'7+*'2)
3 *(D-.$+ #5 C>!LZ 0R:@"" @ %K; (,#=$#=89 &9)#6#9
0A:RZR F %K; /(*+-689&*('+ 7&-+$ ,#9.-(#' 0!:@R[ F %K
:+;,% !
@ #@MZ:" #Z!:! #!A:\; 7&, ,-($$+/ 5#$ @ 6: C6+ 5('&9 =I
7&, !: C6+' -6+ *(D-.$+ 7&, E+=- (' & !M *N C+59#'!
9('+/ &.-#)9&<+ &'/ 6+&-+/ &- @FR " 5#$ M /: C6+
&.-#)9&<+ 7&, ,9#798 )##9+/ -# -6+ $##* -+*=+$&-.$+;
&'/ -6+' -6+ =$#/.)- 7&, 5(9-+$+/; /$(+/ (' &($ 5#$ #'+
/&8 -# #>-&(' -6+ )#9#$9+,, >9#)E )$8,-&9,: 3'&9: H&9)/:
O]4^ C>; Z":![_ H; A:["_ J; Z:Z[_ I; !:M@: U#.'/ 0]K^
C>; Z":!Z; H; A:"R_ J; Z:ZF_ I; !:MM:
!-8
4*&96*9&% 0%*%&(')+*'2)
C6+ )$8,-&9 #5 )#*=#.'/ ! 7&, )&$+5.998 ,('%9+/
,-$.)-.$+ /+-+$*('&-(#' 7&, =+$5#$*+/ #' & W$.E+$
1*&$- 3=+D ! HH2 /(55$&)-#*+-+$ &- !\Z V .,('% !!
!" ,)&' *+-6#/; ,+&9+/ -.>+ `!$&8 ,#.$)+ 0a# !#
$&/(&-(#'; $ bR:R[@ R[Z '*K #=+$&-('% &- AR Ec &'/
ZR *3: C6+ )$8,-&9 ,-$.)-.$+ 7&, ,#9<+/ >8 -6+ /($+)*+-6#/ &'/ $+5('+/ #' " ! >8 5.99!*&-$(D 9+&,-!,d.&$+,
.,('% -6+ 1IQN`\[ =$#%$&* =&)E&%+ ?!ZB: 399 '#'!
68/$#%+' &-#*, 7+$+ $+5('+/ &'(,#-$#=()&998: I8/$#%+'
&-#*, 7+$+ ('-$#/.)+/ (' )&9).9&-+/ =#,(-(#', &'/
(')9./+/ (' -6+ $+5('+*+'-; $(/('% #' -6+($ $+,=+)-(<+
=&$+'- &-#*,: U.$-6+$ /+-&(9, #5 -6+ `!$&8 ,-$.)-.$&9
&'&98,+, 5#$ )#*=#.'/ ! (, %(<+' (' C&>9+ @ &'/
,+9+)-+/ >#'/ 9+'%-6, &'/ &'%9+, &$+ 9(,-+/ (' C&>9+ !:
HH2H^ ""@M!@:
<&5/*+, 0+*+ +)0 /*&96*9&% &%=')%(%)* =2& 62($29)0 !
Q*=($()&9 5#$*.9&
H!I@RJL\1!C>
3>,#$=-(#' )#+55()(+'- e **Y@
U#$*.9& 7+(%6-
M@A:@A
"0RRRK
[\!
C+*=+$&-.$+ e V
!\F0!K
H$8,-&9 ,(S+ e **
R:@Z$R:@!$R:@R
f&<+9+'%-6 e '*
R:R[@R[Z
" $&'%+ e 0%K
!:RFX!A:RR
H$8,-&9 ,8,-+*
a#'#)9('()
#e$e%
YA; F e Y!Z; !Z e Y@R; @R
1=&)+ %$#.=
&!@e'
T+59+)-(#', )#99+)-+/
M \@Z
[:["@
( e '*
R:AF" @0ZK
G'/+=+'/+'- $+59+)-(#', 0)('-K
@ FFZ 0R:RMA RK
* e '*
@:\[! [0@RK
2&-& e $+,-$&('-, e =&$&*+-+$,
@ FFZ e !@ e @M!
+ e '*
R:"F! [0MK
g##/'+,,!#5!5(- #' " !
@:RRM
% e 0%K
\R:FA"0FK
); ,) ('/()+, 0-h!&0-KK
R:RF" F; R:@F@ @
Z
. e '*
R:\FF [0"K
); ,) ('/()+, 0&99 /&-&K
R:R"\ @; R:@F[ M
/
M
N&$%+,- /(55: P+&E &'/ 6#9+ e 0+!'*YZK
! @@"; Y! A!F
0) e 0%!)*YZK
!:"A!
#
!!"
$%!&'()*+,-.)/01234567"-.89:;<=>?
4(5&# !
7E!K
0#&#,'#* 5-)* &#)6'7$ 8)9: ()* ()6&#$ 8!: ;-1 ,-9<-%)* /
:=I7L!CITL-
G966H 7IHL
:=I7L!CI7UL
G96MH HITL
"I6L!CI7L
G97EB TIHL
:=I7L!CIBL=
G96M7 6I!L
:=I7L!CIBL
G96HB BIKL
"I6L!CI6L
G97EH MIHL
:=I7L!CI6L
G96MM KIHL
"I7L!CIML
G97EE 6I!L
"I6L!CIBL
G97EK !IHL
:=I7L!CIEL
G96ME GI!L
"I7L!CI!L
G97E! TIKL
"I6L!CIHL
G97B7 6IKL
=
G96ME HIHL
"I7L!CIEL
G97EH !IHL
QI7L!VI7L
G97EE 7I7TL
:=I7L!CIHL(
G96MH GIHL
"I7L!CITL
G97BG 6IKL
QI6L!VI7L
G97EE MI7!L
BM9!I6L
CIML!"I7L!CIEL
77G96IBL
!H9TI6L
CIML!"I7L!CITL
7769GIBL
:=I7L!CI!L
CITL-!:=I7L!CIBL=
H69BIML
CI6L!:=I7L!CIBL
-
7ET9KIML
CITL !:=I7L!CI7UL
=
CIBL !:=I7L!CI6L
76H9TIML
CI6L!:=I7L!CI7UL
TH9!I6L
CI!L!"I7L!CITL
7G!9!IBL
CITL-!:=I7L!CIEL
76M9KIML
CIEL!:=I7L!CI7UL
7M!9TI6L
CI7L!"I6L!CI6L
77M9!IBL
CITL !:=I7L!CI6L
-
=
CI6L!:=I7L!CIEL
HG9BIML
CI!L !:=I7L!CI7UL
!79KIML
CI6L!"I6L!CIBL
7GT9HIBL
CIEL!:=I7L!CI!=
7ME9BIML
CIHL(!:=I7L!CI7UL
!!97IML
CI6L!"I6L!CIHL
7GH9EIBL
7B796I6L
CIML!"I7L!CI!L
QI7L!VI7L!QI6L
77T9KI7GL
-
CITL !:=I7L!CIBL
-
7GK9EIBL
=
(
"*44',)* ,)-$+01)4-,#1$+ 2+'/ ,1 %'$')-,' 'W2#;-&'$, -,14+X F#Y Z$A Z%[7\ F#[7Y F$Y F%[7\ #F7Y $Y %9
!
"#$%&'$ ()* *+$,%$$+-)
!./
0'1%,'%1# ()(&2$+$
"#$%&' ()*+,-& .!)-* /#00)-(,#1$ +,2/* #$/#(-,'+
,3-, (14512$/ 3 #+ #$ 41$1(&#$#( +5-(' %)125 !678"9
:3' +,)2(,2)-& -$-&*+#+ )';'-&+ ,3-, (14512$/ 3 #+ /#4',3*&-4#$' ,'45&-,'/ 7< ,')=#24 +2&0-,' >#,3 $1;'& +,)2(,2)'9 ?+ +31>$ #$ @#%97A ,3' -+*44',)#(
2$#, 10 (14512$/ 3 (1$,-#$+ 7B $1$!3*/)1%'$ -,14+A
#$(&2/#$% 1$' ,')=#24 -,14A ,>1 +2&0-,' %)125+ -$/
1$' (11)/#$-,'/ >-,') -$/ 1$' 0)'' /#4',3*&-4#$'9
:3' := -,14 #+ '#%3,!(11)/#$-,'/ =* +';'$ C -,14+
0)14 +#D "CE6F %)125+ -$/ 1$' C -,14 0)14 ,3' >-,')
41&'(2&'9 :3' :=!C /#+,-$('+ )-$%' 0)14 G966H 7 IHJ
,1 G96HB BIKL $4A >3#&' ,3' -;')-%' ;-&2' 10 :=!C =1$/
:3')4-& '&&#5+1#/+ -)' /)->$ -, BG] 5)1=-=#&#,*\ "*44',)*
(1/'+X - Z#Y Z$Y Z%[7\ = Z#[7Y Z$Y Z%[7\ ( #Z7Y $Y %
@#%97 Q11)/#$-,#1$ '$;#)1$4'$,+ 10 :=M[ #$
PQ6^HVLN:=I"CEL6#^6CO
&'$%,3 #+ G96EG BI!L $49 :3' -$%&'+ 10 C!:=!C -)'
=',>''$ BM9!I6L" -$/ 7B796I6L"A +#4#&-) ,1 1,3')
&-$,3-$#/' (14512$/+ )'51),'/ '-)&#') N7M!66O9 :3' "!C
/#+,-$('+ )-$%' 0)14 G97EE 6P!L ,1 G97B7 6IKL $4A >3#(3
#+ +#4#&-) ,1 ,31+' )'51),'/ )-)'!'-),3 +2&0-,'+N7M!6GO9
Q145-)'/ ,1 1,3') )-)'!'-),3 +2&0-,'+A #$ ,3'
+,)2(,2)'+ 10 ,')=#24 +2&0-,'+A "CE -$/ :=CD 51&*3'/)-)' 41+,&* (1$$'(,'/ =* !6!CA >3#(3 15'$ 25 ,3'
51++#=#&#,* ,1 +3-5' 7< 1) 6< #$1)%-$#( 0)-4'>1)R9 ?+
+31>$ #$ @#%96-A "I7L 4-R'+ ,3)'' N:=!C!"O &#$R-%'+A
-$/ (1$$'(,'/ ,>1 -/S-('$, := =* 2+#$% ,3)'' !6!C ,1
%'$')-,' - N!:=!C!"!C!O" (3-#$9 ?$/ "I6L ,3)12%3 1$'
!6!C -$/ ,>1 !M!C ,1 4-R' ,3' +#$%&' N!:=!C!"!C!O"
(3-#$ +,-=&'A >3#&' !M!C (1$$'(,'/ -/S-('$, N!:=!C!"!
C!O" (3-#$+ ,1 01)4 - $1;'& &-//')!&#R' (3-#$ I@#%96=L9
7< (3-#$+ -$/ 6< &-*')'/ &-$,3-$#/' +2&0-,'+ #$(&2/#$%
@#%96
I-L _-&&!+,#(R ;#'> 10 N!:=!C!"!C!O" (3-#$ #$
(14512$/ /\ I=L ?/S-('$, /12=&' (3-#$+
(1$$'(,'/ =* !M!C -,14+ ,1 01)4 $1;'&
&-//')!&#R' (3-#$+ #$ (14512$/ /
#
47"U
1384( 0
$
%
&
&
! !" "
'
9(4()*(: 26:+.;(5 8.5:& /.+ ).-'.,5: !
@PL! Y
!O@!LJ Z 1<
!OL! YJ Z 1<
!O@ ! YJ Z 1<
!@LY Z O#J
C4[PL4[Y ! CS
U:U"8O!J
U:!!TO5J
U:!R8 RO44J
45RO5J
V4PL4@ ! C4
U:UR
U:!55
U:54R SO4"J
4T!:U
V4PL4\ ! C4
U:UR
U:!!7
U:5U" 4O4"J
48T:U
V4PL4\ ! C7
U:UR
U:!88
U:5U7 8O47J
44T:U
C4[PL4[G ! C"
U:U"8O!J
U:!7SO5J
U:5!U 5O4UJ
477O5J
]!PL!G ! C5
U:URT
U:!7!
U:55U 5O4"J
485:U
]!PL!] ! C5
U:URT
U:!8U
U:55T UO4"J
47R:U
#$%%&'!()*& +(',-(,'& .$/& 0&&1 '&*2'(&%3456!7!!89: ;.& /$+(
<$=2'>() 2? '&*2'(&% 4@ #$1(.$1>%& +,#?$(&+ -21($>1 (.&
A>BA$B 3;0!C!D9 -.$>1: ;.& >12'B$1>- ?'$<&E2'F 2?
-2<*2,1% ! -$1 $#+2 0& %&+-'>0&% $+ ?2,'!<&<0&'&%
'>1B 0,>#%>1B ,1>(+6 &$-. 2? (.&< ?'$<&% ?'2< (E2 DC7
(&('$.&%'$ $1% (E2 ;0C" *2#).&%'$: G) +.$'>1B (.&
&%B&+6 (E2 $%=$-&1( ?2,'!<&<0&'&% '>1B+ $'& -211&-(&%
(2 &$-. 2(.&' (2 ?2'< $ 4@ #$%%&'!#>F& -.$>1 2? !: ;E2
$%=$-&1( #$%%&'!#>F& -.$>1+ ?2'< $ !@ #$)&' 0)
.)%'2B&1 021%>1B >1(&'$-(>21+ HI>B:5J: ;.& *'2(21$(&%
2'B$1>- $<>1& -$(>21+ $'& >1+&'(&% 0&(E&&1 (.&
#$%%&'+6 $1% >1/2#/>1B .)%'2B&1 021%>1B E>(. (.& C
$(2<+ ?'2< 3DC79 B'2,*+ >1 (.& >12'B$1>- ?'$<&E2'F (2
B&1&'$(& $ +2?( 5@ +,*&'<2#&-,#$' ?'$<&E2'F HI>B:7K:
L)%'2B&1 021%+ ?2' -2<*2,1% ! $'& *'&+&1(&% >1
;$0#& 5:
"#" $% &'()*+,- ./ !
MN 2? ! O-<P4KQ 5 75"H+K6 ! RSTH/+K6 ! S"UH/+K6 4 8""
H<K6 4 7SUH+K6 4 44"H/+K6 T7"H+K6 T4T H+K HI>B:8K: M1 (.&
MN +*&-(',< 2? -2<*2,1% !6 (.& E>#% 0$1% $( 5 75"
-< P4 -$1 0& $(('>0,(&% (2 (.& *'&+&1-& 2? E$(&': ;.&
0$1%+ $( ! RST $1% ! S"U -< P4 $'& %,& (2 C!L $1%
V!L />0'$(>21+: ;.& ()*>-$# +.$'* *&$F+ ?2'
%><&(.)#$<>1& $'& >1 (.& '&B>21 4 5"U W4 TUU -< P46
$1% -.$'$-(&'>+(>- 0$1%+ %,& (2 (.& DC7!P $'& >1 (.& 4
44" $1% T4T -< P4 '&B>21: ;.& $0+2'*(>21 $( T7" -< P4
-$1 0& $(('>0,(&% (2 ;0!C />0'$(>21:
I>B:5 ;E2 $%=$-&1( #$%%&' -.$>1+ ?2'<&% !@ #$)&'
+(',-(,'& 0) .)%'2B&1 021%>1B
I>B:8 MN +*&-(',< 2? -2<*2,1% !
"#0
I>B:7
5@ 2*&1 ?'$<&E2'F >1 -2<*2,1% !
12(+-34 35346&7&
;.&'<$# $1$#)+>+ +.2E+ (.$( (.& (2($# E&>B.( #2++
2? ! >+ 8T:U7X 6 E.>-. >+ $B'&&<&1( E>(. (.&
-$#-,#$(&% /$#,& O88:R7X J: Y+ +.2E1 >1 I>B:T6 (.&
E&>B.( #2++ 2? 4U:5UX >1 (.& '$1B& 2? 8UW!RU " -$1
0& $(('>0,(&% (2 (.& '&<2/$# 2? 2'B$1>- $<>1& O-$#-%:
4U:"7X J: ;.& E&>B.( #2++ 2? 78:S7X >1 (.& '$1B& 2?
!8UW4 UUU " -2''&+*21%+ (2 (.& #2++ 2? (.& -22'%>1$!
(>21 E$(&' $1% DC5 O-$#-%: 78:4UXJ: ;.& ?>1$# '&+>%,&
>+ ;0!C5:
*
!!"
$+",-./01234/56789:;<=#>?@ABCDEFG
2
:%08F
!"#
>[ &4).+ *< &*3#*4-5 1
#)*#+)$,
%-.+/$%0'$%*-
3&,/().+&,.
A- /433'),; 2+ 1'.+ /4&&+//<4((, /,-$1+/%R+5 '
-+2 $+)7%43 /4(<'$+ STMULVWN>7DQ"CWM!UM"P 7, 4/%-0
%/*#)*#,( '(&*1*( '/ /*(.+-$8 >1+ &*3#*4-5 +61%7%$/
'- %-$+)+/$%-0 OX ('55+)!(%=+ /$)4&$4)+; 21%&1 %/
&*-/$)4&$+5 <)*3 <*4)!)%-0 74%(5%-0 4-%$/8 T*3#*4-5 1
5+3*-/$)'$+/ $1+ #*//%7%(%$, *< /,-$1+/%R%-0 -+2
*)0'-%&!$+3#('$+5 /4(<'$+!7'/+5 %-*)0'-%& 3'$+)%'(/
$1)*401 /*(.*$1+)3'( 3+$1*5/8 >1+ (43%-+/&+-$
/#+&$)' *< $1+ &*3#*4-5/ )+.+'( $1'$ $1+ )')+!+')$1
*)0'-%& $+3#('$+5 /4(<'$+/ &'- 7+&*3+ #)*3%/%-0
#1*$*(43%-+/&+-&+ 3'$+)%'(/8
$%&'&()*+,-./-,/"#$%&'(
OCLO
/1*2/
$1'$
&*3#*4-5 0 +61%7%$/ +6&+((+-$ (43%-+/&+-$ #)*#+)$,8
4-5-6-,/-.7
9/ #)+/+-$+5 %- :%08!; $1+ #1*$*(43%-+/&+-&+ /#+&$)'
*< &*3#*4-5 1 #*//+//+/ $1+ +3%//%*- &1')'&$+)%/$%&
#+'=/ *< >7?@ %*-8 A$ %/ '$$)%74$+5 $* B!C!!"# D#EF; B;
C; ?G $)'-/%$%*-/H CIJ -3; B!C!!"FK BCC -3; B!C!!"BK
BLB -3; B!C !!"CK FMM -3; B!C !!"?8 97*.+ (43%-+!
/&+-&+ #)*#+)$, %/ %- '0)++3+-$ 2%$1 $1+ )+#*)$+5 >7
?@
&*3#*4-5/8 A$ &'- #)+5%&$ $1'$ $1+ <*4) +6&%$'$%*7'-5/ ')+ '(( $1+ +<<+&$%.+ +-+)0, +6&%$'$%*- <*) $1+
(43%-+/&+-&+ *< >7?@ %*-/8 >1+ (43%-+/&+-&+ %-$+-/%$,
*< &*3#*4-5 1 %/ 34&1 /$)*-0+) $1'- *$1+) )+#*)$+5
NOFP
>7 &*3#*4-5 8 >1+ +-1'-&+5 +<<%&%+-&, *< 1 %/
'$$)%74$+5 $* $1+ &**)5%-'$%*- +-.%)*-3+-$ '-5 /$)*-0
1,5)*0+- 7*-5/ 7+$2++- %-*)0'-%&
N>7!"!QP &1'%-/
'-5 #)*$*-'$+5 *)0'-%& '3%-+ &'$%*-/ %-&)+'/+ $1+
?@
)%0%5%$, *< >7 %*-/ +<<+&$%.+(,; '-5 )+54&+ $1+ (*// *<
NOP Y*-5* Z; "=47* Z; 9/'3% >; +$ '(8 $%&'() *+',) -%.) /0);
1888;29HOCJ!OC?
NMP :")+, [; \'$)*&1+ Z; Q+))+ T; +$ '(8 *+',) *1,,2%); !:;2H
MI!F!MI!!
N?P ]55'*45% Z; Y%3 ^; _*/% V; +$ '(8 345'%4'; !;;!;!8<HCFI!
C!M
NCP Q+* ^ Q; `1'-0 X; \++ U; +$ '(8 67.28'; !;;;;#;#HILM!ILF
NBP X'.%/ Z ]8 67.28'; !;;!;#1=HLO?!LMO
NFP a'01% " Z; \% U8 #) $,) *+',) 314); 188>;119HMIB!MIF
N!P T1++$1'3 9 Y; :")+, [; \*%/+'4 >; +$ '(8 9%&'() *+',) -%.)
/0); 1888;29H?MFL!?MIM
NLP _*7%-/*- :; b'2*)*$=* Z ^8 *+',) *1,,2%); 188<HMCO?!
MCOC
NIP [4$/&1=+ Q "; c)%&+ X ^; c*2+(( 9 Y; +$ '(8 $%&'() *+',)
-%.) /0); !;;1;#;HOIMJ!OIM?
NOJPc'4( [; T1*4514), 9; _'* T V8 *+',) 97.'8); !;;2;1<H
OO!C!OO!L
NOOPT1*4514), 9; Y)%/1-'3**)$1, ^; _'* T V8 *+',) *1,,2%);
+-+)0,8
!;;1HMFOJ!MFOO
NOMPa4'- a; `'-0 _; Y*-0 X; +$ '(8 #) 31:50 3.7.' *+',);
!;;<;1=9HMJ?J!MJ?B
NO?Pb1*4 ` \; X%-0 d _; b1'-0 b e; +$ '(8 ;) $%18&) $::&)
*+',); !;1;;>2>HLLM!LLB
NOCP\A U4%S # $ W; bUf a'!\%- S % & ' W; bU]V[ \+%S ( ) W;
+$ '(8 *+5%'<' #) -%18&) *+',); !;11;!=HMCB?!MCBL
NOBPb1+-0 \; d4 a; b1'-0 d \; +$ '(8 *8=<./%&*1,,; !;1;;1!H
FIC!FIF
NOFPb1+-0 \; g%4 d Z; d4 a; +$ '(8 *8=<./%&*1,,; !;11;12H
M!OC!M!MJ
:%08!
Q*(%5!/$'$+ +3%//%*- /#+&$)' *< 1 '$ )**3
$+3#+)'$4)+
NO!Pb1+-0 \; g%4 d Z; b1'-0 b e; +$ '(8 -%18&) *+',) *1,,2%);
!;11;1#HIJF!IJI
$J"!
#
$
%
&
&
'
! !" "
#$"%&'( )*+,!-.+,/ ( ) * 01 23(4 5*+,/ + , 61 7-8 49:+,!
#!$%M:?:*@@> N1 G.9>O PA <; B2C(? B/1/* ="*$;1 !""(1%''B$!KL!$!JK
;<:+= -./ 61 >? :@A !"#$% &% '"()*+* ,)(-*.+(/(#+=0123*)4
#!!%P.O:+ )1 (.OQ9*R? 3 S1 T-:O> PA ="*$; =2$$6);1 !""!B
56*7(82 96876* 56*:8261 !""#1!$B!CCD!!CCE
#$E%4F 4>+!29= 0 1 2 01 G'8 )>*!H*+= 3 4 5 01 (' 7<*!4:+,
= 6 7 8 01 >? :@A '"*$; <% ="()*+* >)(-*.+(/(*+ =012?*)4
@6*7(12 96176* @6*A1201 !"%%1&!BIJJ!IJE
#!C%&*+, 51 G*9 51 ;<* 71 >? :@A <; B2C(? B/1/* ="*$;1 !""&1
%'(BK"$!K"L
!EJI!!EJD
#!K%;<>@UO*VW 4 )A B9DE@FE G*.+(2) LA$C1 MO9W>O 3&; '+VA
):UR*.+1 2*RV.+R*.+1 8;31 %))'A
#!J%&*+, 51 ;<* 71 G* 41 >? :@A H1C/2) F.1)+;1 !""&BEJC!EJK
#!L%7<9 51 ;9+ &1 7<9 P1 >? :@A I)2.4; '"($; JK/11 !"")1&$!B
!LIL!!LI"