Stoichiometry CFA Review Learning Goal: Identify and use mole ratios. *** Have to have a balanced equation to determine the mole ratio. The ratios come from the compounds’ coefficients. N2 + 3H2 2NH3 The ratio between nitrogen and hydrogen is 1 N2 to 3 H2 The ratio between hydrogen and nitrogen is 3 H2 to 1 N2 *** Make sure you put them in the order the way the question is worded Practice Problems: 1. H2SO4 H2O + SO3 a. Ratio between water and sulfite? b. 2. 3Mg + N2 Mg3N2 a. Ratio between nitrogen and magnesium? b. 3. Ratio between sulfuric acid (H2SO4) and sulfite? Ratio between magnesium and nitrogen? As2O3 + 3H2O 2H3AsO3 a. Ratio between arsenic trioxide and water? b. Ratio between water and arsenous acid (H3AsO3)? Learning Goal: Able to use units to convert between moles and mass. N2 + 3H2 2NH3 To convert between moles of two different compounds you must use a mole ratio. If you have 5 moles of N2, how moles of H2 would you have? 5 moles N2 3 mole H2 = 1.67 mole H2 1 mole N2 How many grams are in 5 moles of N2? If you need to convert moles to grams, follow your units. *** Notice you cancel out the units you do not need and remain with the units you do need to answer the problem. 5 moles N2 28.0 g N2 = 140 g N2 1 mole N2 If you have 5 grams of N2, how many moles would you have? (This problem is set up opposite to the one above) 5 grams N2 1 mole N2 = 0.18 mol N2 28.0 g N2 Practice Problems: 3Mg + N2 Mg3N2 Molar Mass: Mg = _________________ N2 = _______________ Mg3N2 =___________________ 4. If you have 10 moles of magnesium, how many moles of nitrogen would you have? 5. If you have 15 moles of nitrogen, how many moles of magnesium would you have? 6. If you have 15 moles of nitrogen, how many grams of magnesium would you have? 7. If you have 15 grams of nitrogen, how many grams of magnesium would you have? As2O3 + 3H2O 2H3AsO3 Molar Mass: As2O3 =____________________ H2O= _________________ H3AsO3= ___________________ 8. If you have 32 moles of arsenic trioxide, how many moles of water would you have? 9. If you have 47 moles of water, how many grams of arsenous acid (H3AsO3) would you have? 10. If you have 32 grams of arsenic trioxide, how many grams of water would you have? Learning Goal: Use stoichiometry to determine Limiting Reactants, Amount of Excess Reactants, % Yield. Sample Problem: There are 6.0 g of Mg and 10.0 g of N2. What is the limiting reactant and how much excess is there? 3Mg + N2 Mg3N2 Molar Mass: Mg = 24.3 g/mol 6.0 g Mg 1 mol Mg 24.3 g Mg 1 mol Mg3N2 3 mol Mg 101 g Mg3N2 1 mol Mg3N2 24.9 g Mg3N2 10.0 g N2 1 mol N2 28.0 g N2 1 mol Mg3N2 1 mol N2 101 g Mg3N2 1 mole Mg3N2 = 36.1 g Mg3N2 6.0 g Mg 1 mol Mg 24.3 g Mg 1 mol N2 3 mol Mg 28.0 g N2 1 mole N2 = 2.3 g N2 N2 = 28.0g/mol The top equation produced LESS Mg3N2, therefore, Mg is the limiting reactant! 1. Complete two stoichiometry problems (convert both reactants to a SINGLE product); the REACTANT with the least amount of product is the Limiting Reactant a. Once you know the limiting reactant, NEVER, and I mean NEVER, look at those 2 stoichiometry problems again!!!!!!!!! 2. To continue on to find the Amount of Excess Reactant, do a stoichiometry problem starting with the limiting reactant (Mg), and ending with the OTHER reactant (N2). a. This OTHER reactant is called the EXCESS reactant (N2). 3. In this example, that means if we use 6.0 g of Mg, we will also use 2.3 g of N 2. In the original problem you were given 10.0 g of N2, but only used 2.4 g of N2. How much N2 is left in Excess? 10 g N2 – 2.3 g N2 = 7.7 g N2 in Excess 4. Lastly, theoretical yield! If we would theoretically produce 24.9 g Mg3N2, but when you actually did the experiment you got 21.8 g Mg3N2, what is your theoretical yield? Theoretical yield = 21.8 𝑔 Mg3N2 24.9 𝑔 Mg3N2 Theoretical yield = 87.55 % x 100 Practice Problems: 3Mg + N2 Mg3N2 11. Given 23 g of Magnesium and 15g of Nitrogen. What is the limiting reactant and how much excess is there? As2O3 + 3H2O 2H3AsO3 12. Given 23 grams of As2O3 and 20 grams of H2O. What is the limiting reactant and how much excess reactant is there? 13. Based on your limiting reactant, how many grams of H3AsO3 would you have? 14. If you calculated that after this reaction that you should have 43.8 grams of H 3AsO3, but when you massed your product you had 21.8 grams of H3AsO3. What was your % yield? Practice Problems: 3Mg + N2 Mg3N2 15. Given 23 g of Magnesium and 15g of Nitrogen. What is the limiting reactant and how much excess is there? As2O3 + 3H2O 2H3AsO3 16. Given 23 grams of As2O3 and 20 grams of H2O. What is the limiting reactant and how much excess reactant is there? 17. Based on your limiting reactant, how many grams of H3AsO3 would you have? 18. If you calculated that after this reaction that you should have 43.8 grams of H 3AsO3, but when you massed your product you had 21.8 grams of H3AsO3. What was your % yield?
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