How can we represent matter? Particle Model Copyright © 2008 by Pearson Education, Inc. Publishing as Benjamin Cummings 1 Matter Matter • Is the material that makes up all things. • Has mass and occupies space. Copyright © 2008 by Pearson Education, Inc. Publishing as Benjamin Cummings 2 Matter is made of particles, which we can think of as small round spheres or BBs. 3 A few particles far apart Many particles crowded together Increasing Density lighter particles less massive 4 heavier particles more massive How can we Quantify Matter? Density Copyright © 2008 by Pearson Education, Inc. Publishing as Benjamin Cummings 5 Density Density • Compares the mass of an object to its volume. • Is the mass of a substance divided by its volume. • Note: 1 mL = 1 cm3 • Is expressed as D = mass = g or g = g/cm3 volume mL cm3 6 Densities of Common Substances Copyright © 2008 by Pearson Education, Inc. Publishing as Benjamin Cummings 7 Learning Check Osmium is a very dense metal. What is its density In g/cm3 if 50.0 g of osmium has a volume of 2.22 cm3? 1) 2.25 g/cm3 2) 22.5 g/cm3 3) 111 g/cm3 8 Solution Given: mass = 50.0 g volume = 22.2 cm3 Plan: Write the density expression. D = mass volume Express mass in grams and volume in cm3 mass = 50.0 g volume = 22.2 cm3 Set up problem using mass and volume. D = 50.0 g = 22.522522 g/cm3 2.22 cm3 = 22.5 g/cm3 (3 SF) 9 Volume by Displacement • A solid completely submerged in water displaces its own volume of water. • The volume of the solid is calculated from the volume difference. 45.0 mL - 35.5 mL = 9.5 mL = 9.5 cm3 Copyright © 2008 by Pearson Education, Inc. Publishing as Benjamin Cummings 10 Density Using Volume Displacement The density of the object is calculated from its mass and volume. mass = 68.60 g = 7.2 g/cm3 volume 9.5 cm3 Copyright © 2008 by Pearson Education, Inc. Publishing as Benjamin Cummings 11 Learning Check What is the density (g/cm3) of 48.0 g of a metal if the level of water in a graduated cylinder rises from 25.0 mL to 33.0 mL after the metal is added? 1) 0.17 g/cm3 2) 6.0 g/cm3 3) 380 g/cm3 25.0 mL 12 33.0 mL object Solution Given: 48.0 g Volume of water = 25.0 mL Volume of water + metal = 33.0 mL Need: Density (g/mL) Plan: Calculate the volume difference. Change to cm3, and place in density expression. 33.0 mL - 25.0 mL = 8.0 mL 8.0 mL x 1 cm3 1 mL Set up Problem: Density = 48.0 g = 8.0 cm3 13 = 8.0 cm3 6.0 g = 6.0 g/cm3 1 cm3 Sink or Float Copyright © 2008 by Pearson Education, Inc. Publishing as Benjamin Cummings • Ice floats in water because the density of ice is less than the density of water. • Aluminum sinks because its density is greater than the density of water. 14 Learning Check Which diagram correctly represents the liquid layers in the cylinder? Karo (K) syrup (1.4 g/mL), vegetable (V) oil (0.91 g/mL,) water (W) (1.0 g/mL) 15 1 2 3 V W K W K V K V W Solution 1) V W K 16 vegetable oil 0.91 g/mL water 1.0 g/mL Karo syrup 1.4 g/mL Density as a Conversion Factor Density can be written as an equality. • For a density of 3.8 g/mL, the equality is: 3.8 g = 1 mL • From this equality, two conversion factors can be written: Conversion 3.8 g factors 1 mL 17 and 1 mL 3.8 g Learning Check The density of octane, a component of gasoline, is 0.702 g/mL. What is the mass, in kg, of 875 mL of octane? 1) 0.614 kg 2) 614 kg 3) 1.25 kg 18 Solution 1) 0.614 kg Given: D = 0.702 g/mL V= 875 mL Need: mass in kg of octane Unit plan: mL g kg Equalities: density 0.702 g and = 1 mL 1 kg = 1000 g Setup: 875 mL x 0.702 g x 1 kg = 0.614 kg 1 mL 1000 g density metric factor factor 19 Learning Check If olive oil has a density of 0.92 g/mL, how many liters of olive oil are in 285 g of olive oil? 1) 2) 3) 20 0.26 L 0.31 L 310 L Solution 2) 0.31 L Given: D = 0.92 g/mL mass = 285 g Need: volume in liters Plan: g mL L Equalities: 1 mL = 0.92 g 1 L = 1000 mL Set Up Problem: 285 g x 1 mL x 0.92 g density factor 21 1L = 1000 mL metric factor 0.31 L Learning Check A group of students collected 125 empty aluminum cans to take to the recycling center. If 21 cans make 1.0 lb aluminum, how many liters of aluminum (D=2.70 g/cm3) are obtained from the cans? 1) 1.0 L 22 2) 2.0 L 3) 4.0 L Solution 1) 1.0 L 125 cans x 1.0 lb x 454 g x 1 cm3 x 1 mL x 1L 21 cans 1 lb 2.70 g 1 cm3 1000 mL = 1.0 L 23 Learning Check Which of the following samples of metals will displace the greatest volume of water? 1 25 g of aluminum 2.70 g/mL 24 2 45 g of gold 19.3 g/mL 3 75 g of lead 11.3 g/mL Solution 1) 25 g of aluminum 2.70 g/mL Plan: Calculate the volume for each metal and select the metal sample with the greatest volume. 1) 25g x 1 mL = 9.3 mL aluminum 2.70 g 2) 45 g x 1 mL = 2.3 mL gold 19.3 g 3) 75 g x 1 mL = 6.6 mL lead 11.3 g 25
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