Rochester Institute of Technology RIT Scholar Works Theses Thesis/Dissertation Collections 1971 Lusters and the slab form in raku Richard Hirsch Follow this and additional works at: http://scholarworks.rit.edu/theses Recommended Citation Hirsch, Richard, "Lusters and the slab form in raku" (1971). Thesis. Rochester Institute of Technology. Accessed from This Thesis is brought to you for free and open access by the Thesis/Dissertation Collections at RIT Scholar Works. It has been accepted for inclusion in Theses by an authorized administrator of RIT Scholar Works. For more information, please contact [email protected]. LUSTERS AND THE SLAB FORM IN RAKU Richard A. Hirsch Candidate for the Master in the College of of Fine and the Rochester Institute of Fine Arts Applied Arts of Technology 1971 Advisor: Professor Hobart Cowles -1- CONTENTS Index of iii Slides Introduction v Reasons for the Investigation 1 Background 2 4 Error Period Chapter I Trial Chapter II Further Technical Research and Chapter III Correlation of Lustered Glazes on Slab Forms 15 18 Some Observations Chapter IV 10 Continued Glaze Research 20 Appendix 26 Conclusion 27 Bibliography 28 ii SLIDE LIST 1. Lusterd Plate "Rainbow" RICHARD HIRSCH 1/2" 20 21" 2. Gold Luster Plate 3. - Plate 18 long long 1/2" long 10" high Lustered Plate 18" long 6. Lustered Plate 19" long 7. Bowl 9 8. "Landscape" 9. Lustered Bowl 4. Footed Bowl 5. Plate 10. Big Bowl 11. 12. "Walking" 1/2" high 20 1/2" long 10 1/2" high 28 1/2" long Goblet Luster Goblet 11" high 10" high 1/2" 13. Spray Luster Goblet 12 14. Raku Goblet 10 1/2 high high 12" high 15" ht. 17. Gold Goblet 16" ht. 18. Gold Goblet 15" ht. 19. Crackle Bottle 10 1/2 ht. 20. Luster Bottle 8" 15. Footed Goblet 16. "Mother 21. of Pearl" Goblet Precious Object Box ht. (Orange) 4x4x5" 22. Object Box 4x4x5" 23. Black Box 4x4x5" 24. Gold Precious Box 5x5x5" 25. Shell Box 6x5x5" 26. Gold Coil Box 14x4x3" 27. Gold Box 28. Raku Box with flocking 16 1/2" ht. 15 1/2" ht. Ill 6" high 1/2" 29. Covered Form 21 30. Covered Form 21" ht. 31. Covered Form 22" ht. 32. Covered Form 26" ht. 33. Covered Form 30" ht. iv ht. INTRODUCTION My thesis is break-through in with Raku that not one ceramics. slab the thesis was to built forms using rather begin to investigate Pride Failures were not pottery in Raku process. a and was Trial develop depressing, and A major goal was of This lustered concentrate and error seemed long to The pur glazes with in fit my hours because in them knowledge inquiry led of to give one area, me a person testing. was acquired. experience and understanding. accomplished was to to be the only way to approach for new my involvement particular process. I decided to techniques. to be a better What understand general. Throughout my Cowles a report on my investigations correlate the involvement actually of it is nor professes of accomplishment was a reward Experimentation ing Basically, knowledge in this than dabble in many. ality. point, The School for American Craftsmen. at attain practical and usable pose of proves a entire primarily into the Raku process. learning responsible More experience at for directing importantly, -v- he SAC Professor Hobart my insights offered me and discoveries inspiration. REASONS FOR THE INVESTIGATION When I was limited to weeks at at to the School for American Craftsmen my background SAC I Sale I had Strange potter colors made only display seen a the Frisenda. known Raku. as A few 9. pottery and from lusters of aesthetic goals relied heavily an The seen. obtained and expressed a willingness became joint run, but my interest. Drew Krouse venture started out as a I had all glazes were metallic Frisenda were which stimulated graduate students were Both Krouse tests glaze the first few the Rochester Clothesline Show During work stand apart that the What Raku. of mentioned a process During reduction stoneware. continued with cone Included among the in 9 some cone the time I lacked enthusiasm. and by came to individual John try effort self expression. Achievement During my siderations. were dealt with. three sists of after all to his ideas. on slab like most other main components: these the technical Raku, investigation all aspects of Eventually phase forms grew pottery elements of a forms naturally of technical con Raku process con pottery making, the clay, the glaze, and the fire. are understood can a person give aesthetic concerns had been upon comprehended. out of dominated my thoughts The use of metallic my involvement with a Only form after lusters Raku process. BACKGROUND Before starting the experimentation, the many Associated were examined. philosophies of Raku Raku is the Oriental Zen tradition with of the tea ceremony. "The tea masters, in the unique pleasure of clay. In influenced Zen Buddhist philosophy, took by to direct conscious return a treatment and primitive n1. this is the accord with emphasis on the simple, beauty, and the natural. "The tance cult of tea Teaism, or and veneration of is a way the imperfect in place surroundings with great of an attempt and meaning life that the inherent the beauty of the beauty. It derives its phenomena, transitory and middle American different from the Raku pots "Nothing pots. shown style potters strict Japanese is home grown, Potter's Arts, 1967), 2Hal Reigger, Co., 1970), 3Rose Slivka, (New York: Raku: p. Art form. from awareness It celebrates nature inspired spontaneous creative process receive much attention their of own contribution Japanese potters. in the Twenty-Third Ceramic ^Bernard Leach, A Transatlantic made interpretation Japan in s common " have of the Raku pottery the fifties Raku didn't would amaze a Our a part of though it may be. Until the Recently it becomes developing character accep places great emphasis non-perfect asymmetrical excitement of surface which man' to imbue on meditation and quiet contemplation as a means of of expresses an potter and spite of Book, p. and more, has little the name. (3rd ed; National, however, or in this country. in Raku quite Describing the a critic wrote than these Raku nothing in common with uU' Hollywood-by-the-Sea, Florida: 29. Technique, (New York: Van Nostrand Reinhold 9. "The Twenty-third Ceramic American Craftsmen's -2- " Craft Horizons National, Council, January-February, 1965) p. 21. Daniel Rhodes feels "The original meaning Raku has of The more immediate response from the fire has pottery making the ideals of traditionally, and brought a new excitement but to seek my tions the Tea-Zen philosophy involvement, Daniel own forms, would Rhodes, Kilns : Chilton Book Co. , 1969), 181. * up the While I was made not After process of considered to use some the Raku restric investigation and develop. Design, Construction, p. " been forgotten. and experiment without impose. a personal concept would speeded to it. the Japanese potters, the decision almost and Operation, (Philadelphia: CHAPTER I TRIAL AND ERROR PERIOD The investigation began simply Charles Lakofsky describes application of fired pieces, heated says and that Raku is rapidly and when Most because after the melted kiln was with built glazes are were was a just Within and as one comedy smooth and the low biscuit into a pre and rapidly. Black Raku were and of errors ! period the and then kiln, In firing, are observed ten pots are minutes. that all at once were made they From then as one or drawn the out use glazes of from plumbing Several lead were ! A top loading- glazed, based on in any glazes all were What I knew that fundamentals other method or technique. was experienced: Iowa: (W. M. Brown Co. Glaz Glazes for the a "" the best to glazes were notes with through the gas pressure was turned up. following 192-193. hot red lead based. the fuel. After way, but in the usual melted. about ELeach Burners to the ware. a specific color or shiney, the usually takes important in this process Rhodes, Clay 1957) pp. , Book Co. has The pots tongs. firebrick. 5Charles Lakofsky, Pottery, Daniel glaze felt that lead base into the hot kiln firing than this knowledge it was decided to fire out of soft directly followed firing smoothly were mixed and applied placed with the and propane gas was used as supplies, involving directly glazed pieces glazing, directly in the in the kiln the traditional Red Raku Armed process was. to porous, glazes a procedure rather sources researched they bearing the pottery is bisqued in the The glaze the tongs. with Raku what a Japanese technique freshly cooled as soon as pots are placed spy hole reading "5* fire it is placed, drawn the of placing "In making raku, effect. two and a usually lead firing, hot kiln. red Rhodes glaze low it "as by , 1968) p. 25. Potter, (Philadelphia Chilton 1. Glaze exploded off 2. Glaze melted and ran off 3. The the pot when placed the in the if slightly ware glaze surface was pitted and scarred hot kiln. red over-fired. from the combustible material. glazes were melted while others were still immature on the same 4. Some piece. 5. The clay ody in the hot kiln. cracked when placed In addition to these technical difficulties there smoking or reducing aspects of little while others received duced, was while the dangerous There firings. there was a began The clay By and clumsy a the and For the first time in my and a need for the reasons body first to do that The of use of a the pot was re top-loading kiln ware with involvement tongs. with in pottery, technical experimentation. contribute the black, same awful results continued short some I to the failures. used was a regular cone 9 stoneware. volume: Jordan 2 Cedar Heights Redart 1 North American Fire 1 Clay XX Sagger Unfortunately, shock. pots were smoked few cases, half unloading the hot when beginner 's luck desire looking Ih other remained unaffected. was no other Some the process. smoke. was no control over 1 this clay Raku clay formulas contraction sand added in the rapid to the clay to escape, preventing body couldn't withstand need sufficient heating and body keep cooling the pores cycles.. of cracks and explosions. one-third non-plastic material added these needs the non-clay following clay to material the clay Usually a white Clay Cedar Heights Goldart #5 Ball Clay to lessen the Grog, flint, and fine open and allow moisture a Raku clay recipe. recipe was used. North American Fire Tennessee the tremendous thermal 100 120 60 body has about To comply with Spodumene 20 Flint 20 Grog 80 The only problem first cone 04 tried was into the kiln exploded Next it in that, was the Most glazes. They that to find and the 08, at cone was porous was were also a before the and enough, the produced some blues, what temperature dull to biscuit fire. disastrous. results were or cracked disappointing greens and glazes biscuited body was firing galena when browns, heavily garish reduced. White White lead 60 Flint 20 Frit 25 20 3 Orange White lead 60 Frit 25 40 Lead 4 chromate Blue Frit 529 Gerstley 70 Borate 5 Flint 10 Soda Ash 10 Kaolin Copper 5 carbonate 3 Black White lead 60 Flint 20 Frit 529 20 Cobalt Copper 2. 5 oxide Red Iron 4 oxide carbonate -6- satisfactory, from the lead base tried: Tin Oxide seemed too brittle. poor result obtained uninteresting piece put cycle was completed. this temperature yet not Every At 2 oranges, weak Some lead Most over of fired. This Color burnt have glazes these lead glazes a nice smooth resulted in developes if but because other kinds I had I use. of of quickly in the surface, they a poor surface soft glaze surface. scum out High lead the melted and ran off quality short firing While lead range. remain soft and set if slightly easily reduced, Some luster yet a was produced by dirty reasons stated and the fact that lead is extremely low firing investigated. acquired a list of alkaline glazes the experimented with that Paul Soldner is the metallic these the glazes were slowly. up very when sawdust pitted and scarred glazes are over-reduced. ware even glazes, toxic, reputed to following formulas, Basic Gerstley 50 Borate Borax 50 Runny Iron Gerstley Yellow Borate 50 Borax 50 Iron 10 Rutile 3 Yellow Gerstley Borate 80 Burnt Umber 20 Brown Gerstley Borate 80 Yellow Ochre 20 Glass Red Gerstley Borate 50 oxide 10 Borax 50 Red Iron Copper These firing scarring duced glazes melted at a range was longer, occurred. a reddish 5 carbonate higher temperature than the lead bases. and while they were fairly soft, Glass Red was most successful. copper; if left to air -7- cool, it less pitting and When smoked, it remained copper green. Their pro the Japanese do Traditionally, the kiln. outside of the process. Practical are used Clay, break" Reoxidation pine part of step in the needles, sawdust, create an atmosphere subjected the of to this glaze, is as well as occur because change temperature. to Pottery carbon. a chemical change. face does this leaves, materials such as straw, containing free out of important ware en no substitute and control was had experience or most their Raku time. Combustible paper and in America it is the However, It is the critical point, the "make tire process. gained with not smoke or reduce the of this reducing atmosphere, while still oxygen and Only reducing time take hot in atmosphere undergoes affected. short glazes will lacking news place if the to enough on the and ware sur low is taken effect a chemical change. is Practically speaking, timing the hottest kiln will reduce to Paul Soldner at Geneseo last quick reduction is critical the ware glaze with Heavy Cooling should reducing should be January 21, 1970, he reduction be done slowly and a reducing should not of Raku. Reliance of Raku. During developes. "What The Lakofsky, the in the form this dramatic period romantic nature of remains emphasis on 7 upon nature minutes is a philosophy discovery Pottery, p. of 37. things a the is the of fire "feel" is not on be to scar the direct is entire contact necessary. removed longer good While getting atmosphere chamber until a chemical change can no Contained:in these few hurried that "a lusters". depend always the pot When I talked said a main concern doesn't Only of which are from the hot removed immediately. for the development combustible material. Surfaces important. atmosphere to the reducing atmosphere, surface. the Pots the best. in the reducing and placed most from the occur. Zen philosophy and smoke is the; essence for the captivating whole process or a state of mind not planned. " ' process is realized. that for me places Four Ware bers months was glazed were cooled duced. had gone days in Less Unexpected and advance many individual techniques to allow for complete down considerably before the Sometimes only results. by and less one pot at a control was obtained by develpoed. Kiln drying. cham next cycle of pots were time was fired in order combustible material was used and accidental effects were were taken into to get intro maximum in the smoking stage. consideration and a certain practical experience and knowledge of the entire pro cess. Still, Also, the development of metallic the forms were not in evidence of a need for more luster accord with technical glazes had the spontaneity not yet of been Raku. realized. There was research and aesthetic considerations. 9- CHAPTER II FURTHER TECHNICAL RESEARCH Glaze The process, Most trol. its by its own glazes never be effects can with in Raku effects to this time, many variable certain elements conditions, impossible to con although some colors and However, "happenings", because absolute of the process, duplication is impossible. in different effects. result very few Now, effects. upon fire exactly the same, margin of so called desired of the glazes experimented. with produced the formulation own glazes was the necessary to of my A saturated amount was the kind I wanted. produce I first lieved to added nature, has controlled and repeated. Individual techniques Up dependent are experimented with copper. to cause some glazes to this base student at glaze which develop I a metallic acquired luster. from Robert The Jarvis, first be copper was a graduate S. A. C. Base C. M. Frit P-25 43.6 Frit 3134 26.3 Lithium Copper Kaolin 10.2 Flint 14.0 Unfortunately, a because there very dense were attained except where of tests, reduced, were Red Copper better. It In a gas a gas kiln it seemed heavy mixes copper, it to greenish black. reduction occurred. poorly This form No 5%-25%. reoxidized metallic During of copper with water and other the easily, lusters next series is already partially chemicals, results to luster more successfully. realized produced kiln there is green was so much oxide was used. and although At this time I Using to the base in these percentages: carbonate was added thus producing 9.9 carbonate the difference in results using two kinds better lusters from a slight reducing copper than atmosphere in the -10- of an electric firing stage. kilns. kiln. This helps to develop the Less Red Copper Inquiry a type was now made as decoration of ration rather lusters is than and luster. they I form for It media. saw a from the kiln. produce metallic to what other ceramic chemicals on metallic lusters Lusters centuries. to be the firing of metallic luster as a transparent, over a the culmination of in the Royal Ontario Museum in examples were final deco the development ceramicists used in a final copper that lusters were employed as a Persian was employed lusters. beside the revealed Historically, wares are reputed few removed over- art of Toronto, are magnificent. this form Describing a to to the Islamic potters. These alkaline glaze. glaze was needed Literature used before it is even as a complete glaze. credited purely decorative glaze in the oxide develop luster. oxides luster metallic of decoration decoration, of one source states on ceramics and glass consisting of that "Luster constitutes extremely thin films of Q metal which are as being method. deposited on the surface of either colored or colorless and ^' The most expensive of the ware. their " Hainbach preparation these lusters are what by he classifies either calls the dry lusters or wet "The Noble Metal Lusters". For the preparation with pine resin and heat, ited carbon on the these lavander formed glaze of by the oil. over-glaze In this lusters, method resin and oil reduces a metallic during the an salt is combined oxidizing fire to metallic salt, which red is depos surface. Q Shaw, Ceramic Praeger., 1968), p. Kenneth A. Colors and Pottery Decorations (New York: 80. ^Rudolf Hainbach, Pottery Decorating, (London: Scott Greenwood p. Frederick 202. 11- and Son. , 1924) Preparation of these kinds Expensive and procedures. banding of Most this quality chemical compounds such as adapted to A in the "noble lusters", manners are Luster solutions of are expensive and produce a the metal now, ornamental ware and are used dinnerware. was not formulas my intention. metallic salts, were this type flat luster. However, the investigated in De use of the and my Raku technique. partial lusters souvenir, common mass-produced veloping lusters entails complicated Lusters developed in these associated with are sold commercially. lusters materials are used such as gold and platinum. unfortunately, of list of metallic salts associated" generally with over-glaze was acquired. Metallic Salts 1. Silver Nitrate 2. Bismuth Sub-nitrate 3. Gold Chloride 4. Ferric Chloride 5. Zinc Acetate 6. Tin Chloride In addition tested. All the put through a to these metallic range Raku process the other metallic compounds were metallic colorants were added failed to develop any luster 1-10% salts, following including by to the C. M. the smoking themselves or or base, reducing phase. in combination. chemicals were added and then They Within the to the base. 1. Cobalt Carbonate 2. Cobalt oxide 3. Chromium 4. Red Iron oxide oxide 5. Iron Chromate 6. Nickel oxide 7. Manganese dioxide 8. Tungstic 9. Sodium acid uranate 10. Potassium dichromate After testing those, a few metallic sulfates were process. -12- tried with the same Copper Sulfate Cobalt Sulfate Nickel Sulfate Manganese Sulfate With the noticeable tallic new luster. glaze was Sulfate, I began to Finally, in the salts used base Copper exception of over-glaze tested being none of these developed any experiment with some of luster and all me At this time preparations. the the salts were added a directly to it. C Base Soda Ash 44. 2 Frit W-15 30. 9 Borax 18. 6 Kaolin 24. 0 Flint 65. 0 All the tests Silver Nitrate stage. ivory to metallic yellowish luster. with a was added golden Raku process combined with luster was in color along modulation and awhile people (See Slide with a purple "Beatrice" pearly results were quite 1% Silver Nitrate and 1% glaze was yellowish Smoking over-all was also provided color irridescence. because of (For this glaze!) tried with Red Copper oxide. irridescence to the copper luster to prevent the duced every These two called me produced an 2) Bismuth Sub-nitrate parted an with irridescence. the reducing alone produced a At its best this the Bismuth developed the in the shop It Silver Nitrate the developed Bismuth Sub-nitrate in the C base. gold including to the C base in 1-2%. Bismuth Sub-nitrate luster. When A satisfactory. done were # copper from metallic color glazes were my reoxidizing. and The helped standard as a stabilizer result was a glaze imaginable from copper. (See Slides in the investigation. -13- It im that pro 1, 3, 6) Base Soda Ash 44. 2 Frit W-15 30. 9 Borax 18. 6 Kaolin 24. 0 Flint 65. 0 Gold Luster 1% Silver Nitrate 1% Bismuth Sub-Nitrate Copper Luster 2% Red Copper 2% Bismuth Sub-Nitrate Along with these two luster glazes a vitreous englobe was Tennessee #5 Ball Clay 20 Flint 30 Frit 3191 25 Talc 10 Borax 7 White Opax 10 Red Red Copper 5% Red Iron 5% oxide -14- developed. CHAPTER III CORRELATION OF LUSTERED GLAZES ON SLAB FORMS Development display After At them. in Glazes of the tongs led glazes easily a Large, round shapes unless grabbed I tended to once vertical had would new glazes. the glazes. influenced the form. The forms. they This middle. was comprehended and disadvantage hard to maneuver to tendency was one of Size had only Ware firing. glaze major were an even greater round shapes. the process forms that surviving the that was exactly in the large, avoid chance of forms of seek as significant as process also better large on these types with limitations, the Raku had to me became test tiles for the shapes aspects of reoxidized tongs. sons first, a single piece working with these luster involvement the forms became some Technical made of roll off the rea reasonable facility with the tongs acquired. Clay investigated to slabs were Slab forms of stoneware. lent themselves to many The investigation form and the with forms not associated with to the Raku process the philosophies was an attempt excitement of surface, to hand-building Raku. of correlate supplied and those by the asymmetrical slab the metallic luster glazes the Raku process. Slab forms exhausted, a were new, and glaze was of of quality was achieved clay mattness of be rolled, form and developed in the by With After begun. clay body. of Throughout, urging shiney Soft squashed, pressed, gentle most possibilities were primary importance to the juxtaposition smoked bent, folded, texture. series. related sequence was quality dull of related create -15- A me. surface metallic glazes and and malleable impressed, and good the tactile timing clay and slabs could joined to the clay the create slab could be shaped using its vitality to The procedure Each Molds Soft clay casts. slabs were tubular shapes. natural it tendencies was part of tion draped wet of soft my philosophy for my order clay basic form to work in the or canvas. support biscuit pots, domes, on or burlap molds or wrapped around inside slabs were rolled Forms than force. were created I tended to Organic by work with to be disassociated from the boxes. cardboard were guided and controlled. Raku. of the wet and plaster slabs were utilized and encouraged clay and modification rather forms in slabs on either clay -metal Sometimes clay Qualities inherent in the a visual strength. of armature or from were made the form roll out kind series used some clay. to was give and because direc subtle large fairly the small scale of traditional Japanese Raku. Glaze forms eager were to smoked entirely clay body shape was became the platters, slab plates and and color bare gently fields negative space of form. The luster thrown same treatment the rather Large of metallic unglazed and less was At the first, because I was so The glaze was used. These areas their final and consideration of more than to dominate. to visually separate When the best in the to the the upon the inter pools of raw glaze were poured clay body. fired, They use of of the were enhanced important, top from the 16- covered rest of goblets and had the forms. glaze was used With the large the a soft malleable Although the next series of covered independent, by 1-6) the slab as slab was into this produced large (See Slides : decoratively. the treatment proceeded solely dependent lusters. glazes were used elements were rolled around. As the forms became used less in painting bowls clay. goblet series was some them, Perhaps it important "negative space". negative space action of glaze and The an dipping. important. The large modulating Eventually, or pouring covered with glaze. them all. display treated like were by was almost always applied to describe forms the form. glaze was (See Slides 29-30) Shiney glaze zones were employed unglazed, smoked Each kind of with duced by themselves size and were intricate the piece, were the seemed enough. smoking techniques. shape of of Detailed brushwork 31, 32) required special the The intensity factors in devel it some nice effects. be proved to glaze thrown on the It However, sawdust was more readily pro available easier to control. surface, the the ware. Occasionally, they pine needles and grasses were used. To prevent pitting the glazes the blackness certain methods. Initially, and form of smoke, along oping the contrast with (See Slides areas. since unnecessary to and scarring from direct plates and unglazed area. created a bowls A large contact with sawdust on Sawdust turned over. were dome metal was then placed over the smoke, contained reducing atmosphere, was and prevented reoxidation. With the goblets and small or sawdust was made. small heap. A The red short can or boxes, hot barrel little a mound of shredded paper piece was placed was then placed in the over center of the ware to the con tinue the reducing process. Most difficult to Smoke A patterns Best Sawdust This of broke up the verticality monochromatic form. smoke and control were tone in the the covered destroyed the unglazed areas was needed results were achieved when a was packed around wedged and the large the form after combustible material clay it 17- visual impact. to describe the sewer pipe was used. was placed between the form the pipe. forms. inside the pipe. and the inside SOME OBSERVATIONS "Craftsmen of all the difficulties with of times have battled the techniques, sion. While in more primitive in times technical our form of always main the be must short experience with been important. Clay for any responsible difficulties the fire and myself. is each pot lay lie and expres in the technique, wholly in almost Creating trend. unique objects Many its intrinsic and shows is in the past Other few Shows the reality nature of his materials and influenced of by thought. reach object-ness. n11* the idea restore "Objects U. S. A. rather commodities, and Paul (Geneseo: 12Rose Slivka, (New York: pp. object. it is the to the " and object "Coffee, directly designing as he is the degree to obsessed which he for by can 19 " "Raku 1970) the than any individual. Wildenhain, Pottery; Form and Expression, Publishing Corp. , 1962), p. 10. Soldner, of Actually, today Marguerite Reinhold A feel Due in the process. have tried to such as himself, artist uniqueness of each piece. have influenced my ideas of machine made com seek, is inherent in the "The contemporary American Craftsman is less function, Each media. immediacy years for material interaction between the material, the not an original value and power. Cups" and the best it may have. which we all through the to this I have been interested me have aesthetic concerns another art a complete Individuality, acquired pottery, be for to Hand-building furthers Raku process. the have used, form problems of real problems ultimate value With Raku there has been ing for seems "I consider clay to be just munication. Tea times the the they material and expression. "h). Throughout my part with advancement the with p. Invitational, "A Catalogue for an (New York: Exhibition; 20. " "The Object: American Craft Horizons Function, Craft, and Art, Craftsmen's Council, September-October 1965) 10-11. -18- When my independent work of is their function. using them becomes a person and more conscious of it is nice to know "The Raku tual to 13 orbit renew Craft successful the the They to this very objects The itself in the energies, have an intrinsic value, nature, in that on a precious the function themselves. the Zen tea day. take more aware of some objects are ware of objects In irreplacable, our even they serve, throw-away society, by their masters still shows us object truly made into its -19- pp. spiri for itself has the memories and actions of men. Horizons, (September-October 1965) maker. 10-11 " power CHAPTER TV CONTINUED GLAZE RESEARCH Work ical compounds traditionally in used Other forms developed. continued on glazes while slab luster overglaze chem were researched and explored. Gold a Chloride, famous and in complex "Purple of Cassius". color called fired in hundredths shades of Raku, it yields some red with tinges nately, gold, chloride, because lab! luster testing ferric Three and exotic colors. to the base glaze produced Unfortu its expense, is impractical, even stock it in the except Chemistry when added sawdust a luster and the light fuming irridizing adherent form layer surface. to the C base. in took place. Both A when heated an atomized the light of noticeable to was When the hot However, of the and placed spray of metal the mix a piece hit again no noticeable in in connection with contact with a metal salt salt is formed solution, on the a reflected from it. This succession Materials, Publishing Co. " Ceramic -20- strongly glass or ceramic the irridized film may be gauged to the well known Newton rings. Cahners step compounds are mentioned of an oxide of "Ceramic Raw second kind glass. The thickness ent color of analogous or developed any compound metallic salt with sawdust. "Glass surfaces, vapor Neither directly was achieved. fuming chloride and stannous chloride a new developed. was weak solution of ^ to my C base Nuts!!) technique in of added produces of a purple opalescence. (They don't experimentation. While the incredible When of a percent of gold chloride added strawberry in limited luster preparations, when used by the appar of colors is 14 * " Industry, January 1961, Chicago, My Just before the glaze it was pulled in Glaze Luster defining means appearance of the peculiarities of in that colors or shiney, but "Mother of not may By a not the been Areas tions the where not in surface and quality a difficult to describe gloss or sheen. by or 2. the dependent upon Luster implies a shiney ' of surface changing. " that shows more An irridescent often used than of one many surface can be for irridescence is the terminology, Experimentation As yet, results were all desirable the possibilities have will continue after this paper is written. soluble salts provided me with an element of control. luster or luster the light: " and rewarding. irridescence the spray contact with amount of Usually exciting the are " reached. Spraying was either air cooled irridescence. and Another term not always. method about six be irridescent. Aside from the differences in and held definition irridescence is "a showing constantly Pearl. immediately the pot gun was surface of a mineral as affected a prism. are this technique a glow of reflected Irridescence implies color as by the terms luster "1. onto The spray its reflecting qualities. that may surface directed metallic barrel. effects produced first without was After spraying the pot, it a sawdust the saturated solution of hot, from the hot kiln. inches from the piece. or smoked a melted, A fine spray salt was prepared. after fire it up to temperature. procedure was to glaze the ware and raw or light spray body produced received by the best results. Dictionary, Dictionary, I on a given surface. were enchanced ^5 Webster's Third International 16 Webster's New World desired remained uneffected. irridescence clay was elem. -21- Sec could control Both the glaze certain solutions. A heavy 3rd ed. 1965 ed. the spray. 1961 application was devoid surface irridescence of be maximum control could there was more the irridizing would destroy, variety in depth were achieved red hot sawdust barrel the glaze atmosphere low). to appearance of acquired by the use of These different effects A the ware. metallic salt sprays. in the to crackle. to let the the pot Periodically smoke. great colorants Glazes This of great It Finally, smoke the develop a piece was in the was placed spray in a of cold water left inside the smok glaze crackle. Most (1800 F and be not work within the Raku heat range fused to the glaze surface but only compounds after from the was removed Sometimes cool air. done was important factor in the spray technique. an tested did would get because these me glaze created another variation. Temperature is chemicals not appeal pot was sprayed with the metallic salt. barrel to the did different inside a kiln chamber, this technique. by and moved about caused ing with along be fuming gun method The possibility everything than enhance, the rather glaze Crackling the vapor With the spray With factor. of glaze effects could base a lustering luster. attained. of a chance or or dry result was often a The the metallic substance. an overload of really produced white crystals. Melting they points of the might work within the Raku temperature range. cases, less temperature ticularly it just with stannous volatilized and chemicals The that left the Dr. Fred A. Institue of to in However, some to produce desireable results. surface of less cancel out most the glaze was Oddly enough, glaze unaffected. worked well alone were separate metallic ester was needed chloride, if the combination seemed to whether metallic salts provide some clue as too Par hot, some successful when combined. identifying traits of each salt. Elder, Assistant Professor Technology, calls of this deposit "Thin film Phenomena". -22- Chemistry, at the Roofa?^ of metallic compound a Metallic the in solutions are either the glaze. surface of bond, a chemical A spray is the metallic salt mechanical bond is a reaction between there is acid while feels that most metallic salts would deposited was Patterns of essary to to obtain a develop an Absolute control of thin enough film in He irridescence. on a ceramic surface that was that different kiln atmospheres acid and a related totally for Dr. Elder as "Interference solution would be nec some chemical compounds the idea of vacuum plating metals 'Also he feels clean and smooth. might produce The base. irridescence if the film an the spray order Atmospheres effects of metallic salts. an. whereas by heat, is the base. glaze develop caused He defines irridescence thin enough. Light". the mechanically bonded to or chemically distinctive changes in the have been of nitrogen and argon suggested. Within my were in investigation, form. chloride The chlorides is stronger the nitrates. than chlorides no oxygen oxygen, Inhalation their toxicity. tilation somewhat of a by acid produced glaze surface when the by of on these Care bond. is introduced to the Nitrates the the metal in its glaze glaze surface. oxide form when the spray surface. compounds was the spray hits the hot a chemical as well as a mechanical and produce is deposited solution for this is metallic salts other acids such as nitric acid produced the surface, producing contain actual reason the Professor Cowles feels that hydrochloric acid from the metallic chloride etches With most successful of Dr. Elder believes that hydrochloric mystery. glaze the is extremely dangerous because taken when spraying and use of a strong of ven system was necessary. Using icals did the methods described in the spray not work within technique, the Raku temperature conditions : 1. Cobalt Chloride 2. Nickel Chloride -23- these chem range or atmospheric 3, Manganese Chloride 4. Barium Chloride 5. Zinc Nitrate 6. Ferric Nitrate 7. Aluminum Nitrate 8. Chromium Nitrate 9. Barium Nitrate 10. Strontium Nitrate 11. Antimony Tri-chloride 12. Molybolic Acid 13. Tungstic Acid 14. Potassium Chrom Alum 15. Cobalt Sulfate 16. Nickel Sulfate 17. Antimony Nitrate 18. Cadmium Nitrate The following compounds atmospheric conditions have the Raku heat worked within range and using the spray technique: 1. Tin Chloride 2. Zinc Acetate 3. Ferric Chloride 4. Zinc Chloride 5. Cuprous Chloride 6. Cupric Acetate 7. Cupric Nitrate Tin Chloride gave a glossy irridescence. produced a handsome "Mother variation. The ture, of glaze used with Pearl", Over extremely Tin Chloride a white it glaze in depth rich melted at a base and lower tempera thus preventing the tin from completely volatilizing. P. White Glaze Frit P-25 36 Frit 3124 28 Kaolin 8 12 Flint Lithium Carbonate 8 Opax Zinc Acetate blue 10 produced an and green glazes. The irridescent, main rainbow effect and was used over difference between Zinc Acetate -24- and Tin Chloride was that the zinc produced a mat while surface, the tin was very glossy. Ferric Chloride was the only irridescence reddish (See Slide brown. in which glossy surface, The luster luster. and a 20) tested that some cases produced both color range was yellow orange Ferric Chloride Sometimes it completely neath. compound produced an destroyed the color of the base glaze as obscured an to extremely the glaze in the be case this glaze: with Red Glaze Ceramic Color Ceramic Color and and If Ferric Chloride of or irridescence. the was sprayed on Best clear and the Co. Chemical Mfg. This thin deposit iron. up over Chemical Mfg. Co. was , , Inc. Red Stain 3352 thickly brown in there 7 was a noticeable devoid color and results were gotten when yellow 100 Inc. Special Frit 441 of build any luster Ferric Chloride was used base glaze. Clear Base 74 Soda Ash 310 Frit W-15 38 Kaolin 144 Flint Yellow Potassium Bi-chromate Using the yellow glaze underneath range was yellow Along tested. surface. with to red orange. these Actually, If left to by the Ferric Chloride spray, the Both had luster air the spray and color irridescence. metallic compounds some soluble salts of copper were the spray just deposited the tion was necessary to achieved 1/2-1% cool, the copper would produce a metallic method. -25- metal substance on stay luster. a A familiar the green. glaze Reduc copper yellow was APPENDIX Melting Points Chemical of some chemical compounds Melting Temperature Boiling Poi 220.2 Antimony Chloride 73. 4C SbCl3 Barium Chloride 925 Bismuth Sub-Nitrate 260 , Cadmium Chloride 568 Cobalt Chloride Cupric Chloride Cupric Nitrate 114. Molybdium Chloride Nickel Chloride Platinum Chloride Selenium Chloride Silver Nitrate Silver Chloride Stannous Chloride Tungstic Acid 960 498 422 Manganese Chloride - - Cuprous Chloride Ferric Chloride 1560 - 1366 5 - 282 315 650 1190 - - 973 - 581 - 288 - 212 444 455 1550 246.8 623 1473 - -26- CONCLUSION I have heard Raku described believe it is feel it is a fad soon to as luck. I that this is true in many submit "In every culture, success of the have been a common. giving up to the are those seem, in texture dict. firing, ceramic processes on kiln gods, and Placing one's pieces forces coming from the kiln and beyond quite color, luck prayer the sticks, leveL studio and offerings in the kiln is 9, kind "17. as strange involved, has been involked power the fire. of Others ceramic scene. certain amount of may be sure, divine we metamorphic one meets there is a will admit Many Some say Raku depends too a valid use of ceramic materials. While I flamboyant. quick and from the American vanish much on for the being "The to surrender, greatest pots objects; one's power of they may visualize or pre "18* Inevitably, Hopefully slighted be will for how it is made. two years past glazes on slab process. My the term Raku America, this pottery For the luster in given merit I have forms. for fade into the background. what worked almost Many for the enthusiasm will techniques process is it looks like rather than exclusively incorporating were developed using a Raku further still undiminished and exploration will continue. which was "Raku, become a vehicle the power of Zen originally for the still at sudden work, With Raku I have been fire as it transforms clay 17Rhodes, Kilns, pp. able an aspect of a thrust perhaps. Ibid, p. intuition and raw chemicals 189-190 181 27- and the playing of hunches: " to understand 18 Ibid 19 of Zen-inspired tea cult, has more into intimately the power ceramic objects. of BIBLIOGRAPHY "Ceramic Raw Material, " Ceramic Cahners Industry, Chicago: Publishing 1961 Co., Earhart, W. H. Florida: Koenig, and College Offset J. H. Literature Abstracts , of Glazes, Ceramic 1951. Press, Scott Greenwood London: Hainbach, Rudolf, Pottery Decorating, Son, and 1924. A Potter's Leach, Bernard, Transatlantic Nelson, Glen C. Raku Kilns: Co., Invitational, A Art Rhodes, Daniel, Clay Co., 1957. , and and Technique, Hollywood-by-the-Sea, Florida: Reinhart an and and Winston, 1960. Exhibition, Geneseo, Van Nostrand Reinhold Potter, Philadelphia: Chilton Book Operation, Philadelphia: Chilton 1969. H. , The World of Japanese and Pottery Decoration, "The Twenty-third Ceramic 1965) "The Object: 1965) Ceramics, Tokyo: Kodansha 1967. uary-February October , New York: Glazzes for the Shaw, Kenneth, Ceramic Colors erick A. Praeger, 1968. , ed. Catalogue to Design, Construction, Sanders, Herbert International, Slivka, Rose, 3rd Ceramics, New York: Holt, Reigger, Hal, Raku: Co., 1970. Book Book, 1968. , 1967. Arts, , Peterson, Allan, W. M. Brown Co. Iowa: Lakofsky, Charles, Pottery, pp. Webster's New World p. National, " New York: Fred Craft Horizans (Jan 21. Function, Craft, and Art, " Craft Horizons 10-11. Dictionary, elementary -28- ed. , 196 1. (September- Webster's Third New International Dictionary, Wildenhain, Marguerite, Form Pottery: America Craftsmen's Council, and Reinhold -29- 3rd ed. , 1965. Expression, New York: Publishing Corp., 1962. 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