Material Safety Data Sheets Version 1 Date 12.09.2014 Section 1 : Identification of the substance/mixture and society/company Warning 1.1 Product identifiers : Product name : (4Z.9Z.14Z.19Z)-2.2.7.7.12.12.17.17-Octamethyl-4.9.14.19-cycloicosatetraene1.3.6.8.11.13.16.18-octone Product Number : MC005 1.2 Relevant identified uses of the substance or mixture and uses advised agains : Identified uses : For laboratory use only 1.3 Details of the supplier of the safety data sheet : Company : ADIONICS 103 rue de Grenelle, 75007 Paris, France. Tel.: + 33 1 69 19 41 68 e-mail address (competent person): Emergency phone : [email protected] I.N.R.S : + 33 (0)1 45 42 59 59 Section 2 : Hazards identification 2.1 Classification of the substance or mixture: Risk class and category code in accordance with regulation (EC) No 1272/2008 [EU-GHS/CLP] : No data avaible Risk class and code category according to EU Directives 67/548/EEC or 1999/45/EC : No data avaible 2.2 Label elements : Labelling according Regulation (EC) No 1272/2008 [EU-GHS/CLP] : Pictogram : Signal word : GHS07 Warning 4 avenue du président François Miterrand, 91 380 Chilly-Mazarin Tèl. : +33 1 69 19 41 68 Page 1 sur 6 En cas d’urgence : + 33 9 88 99 06 38 According to Directive 67/548/EEC as amended. Hazard symbol : Section 3: Composition/information on ingredients Synonyms : 2.2.7.7.12.12.17.17-octamethylcycloicosa-4.9.14.19-tetraen-1.3.6.8.11.13.16.18 -octaone Formula : C28H32O8 Section 4 : First aid measures 4.1. Most important symptoms and effects, both acute and delayed : To our knowledge, the chemical, physical and toxicological properties have not been thoroughly investigated. 4.2. Description of first aid measures Inhalation Eye Contact Skin Contact Ingestion If inhaled, move person into fresh while ensuring their own safety during the operation area. If necessary, consult a doctor. Ush eyes with plenty of water for at least 15 minutes and consult a doctor. Remove contaminated clothing in contact with the skin. Wash with soap and plenty of water. Consult a doctor. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth water. Consult a doctor. 4.3 Indication of any immediate medical attention and special treatment needed : No data available Section 5 : Firefighting measures 5.1 Extinguishing media : Suitable extinguishing media : In case of fire outbreak, use of alcohol-resistant foam, dry chemical or CO2. For large fires, apply water as quickly as possible. Use large quantities of water applied as a mist or spray. 5.2. Special hazards arising from the substance or mixture : If this product is involved in a fire, the following can be released: carbon oxides, oxyd nitrogen. Heat decomposition may cause gassing and irritating vapors. 5.3. Advice for fireghters : Special protection equipment for firefighters : If necessary, wear self-contained breathing apparatus (SCBA) for fire fighting. Wear chemical resistant protective products and prevent contact with skin and eyes. 4 avenue du président François Miterrand, 91 380 Chilly-Mazarin Tèl. : +33 1 69 19 41 68 Page 2 sur 6 En cas d’urgence : + 33 9 88 99 06 38 Section 6 : Accidental release measures Personal protective equipement See section 8 Personal precautions Environnemental precautions Methods and materials for containment and cleaning up Avoid breathing vapors, mist, gases or dust. Outdoors, do not stand downwind. Do not discharge into drains or rivers. Provide bunding to contain any spills. Contain and collect spillage with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Keep in suitable, closed containers for disposal. Absorb into dry earth or sand. Transfer to a sealed container and labeled for disposal by appropriate means. Section 7 : Handling and storage 7.1. Precautions for safe handling : Avoid contact with skin and eyes. Avoid breathing vapor or mist. Work under hood. Provide adequate ventilation. Do not handle in a confined space. Keep away from open flame or sources of ignition - No smoking. Take measures to prevent electrostatic charging. For precautions, see section 2.2. 7.2. Conditions for safe storage, including any incompatibilities : Store in a cool place. Keep container tightly closed in a well ventilated container. Carefully resealed container started and kept upright to prevent leakage. Section 8 : Exposure controls/personal protection 8.1. Contrôle parameters : Components with occupational exposure limits: Contains no substances with occupational exposure limit values. 8.2. Exposure controls : Hygiene and general protection : Wear protective gloves / protective clothing / eye / face protection. The standard precautions must be observed when handling. Wash hands before breaks and at the end of the handling of materials. Engineering measures : Use only outdoors or in a well ventilated area (fume hood) area. Ensure adequate ventilation of the area. Eye and face protection : Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (U.S.) or EN 166 (EU). Hand protection : Handle with gloves. Gloves must be inspected prior to use. Discard contaminated after use in accordance with applicable laws and good laboratory practices gloves. Wash and dry hands. The 4 avenue du président François Miterrand, 91 380 Chilly-Mazarin Tèl. : +33 1 69 19 41 68 Page 3 sur 6 En cas d’urgence : + 33 9 88 99 06 38 selected protective gloves have to satisfy the specifications of the EU89/686/CEE Directive and standard EN 374 derived from it. Respiratory Protection : Avoid breathing dust / fume / gas / mist / vapors / spray. Skin Protection : Wear protective clothing. And other personal protection advice : None Section 9 : Physical and chemical properties Information on basic physical and chemical properties Appearance Physical state at 20 ° C / 101.3 kPa Color Odour Odor Threshold pH Melting point/freezing point [°C] Initial boiling point and boiling range [°C] Critical temperature [°C] Upper/lower flammability or explosive Vapour pressure [20°C] Relative density [20°C] Water solubility [mg/l] Auto-ignition temperature [°C] Oxidizing properties Viscosity Solid - Others informations Others data - Molecular weight [g/mol] Flash point [°C] Partition coefficient: n-octanol/water [log Kow] Evaporation rate (ether=1) Others data Section 10 : Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Stable under normal conditions of use Stable under normal conditions of use Data not available Data not available Strong oxidizers, strong acids, and strong bases HF and CO combustion in the event of 4 avenue du président François Miterrand, 91 380 Chilly-Mazarin Tèl. : +33 1 69 19 41 68 Page 4 sur 6 En cas d’urgence : + 33 9 88 99 06 38 Section 11 : Toxicological information Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitisation Carcinogenicity Germ cell mutagenicity Reproductive toxicity Potential health effects No data available No data available No data available No data available No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human by RCA. No data available No data available No data available Section 12 : Ecological information No data available No data available No data available No data available No data available No data available Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vPvB assessment Other adverse effects Section 13 : Disposal considerations 13.1. Waste treatment methods : Product : Replace surplus and non-recyclable solutions to a licensed disposal company waste. Liaise with a company Specializing in the disposal of waste to have of this product. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging : Dispose of as unused product. 13.2. Additional information: No data available. Section 14 : Transport information Road transport : no dangerous Shipping : no dangerous Air transport : no dangerous 4 avenue du président François Miterrand, 91 380 Chilly-Mazarin Tèl. : +33 1 69 19 41 68 Page 5 sur 6 En cas d’urgence : + 33 9 88 99 06 38 Section 15 : Regulatory information This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture: Data not available. 15.2. Chemical Safety Assessment : Data not available. Section 16: Other information Indication of changes: Material safety data review by commission regulation (EU) No 453/2010. Note : This Safety Data Sheet has been prepared in accordance with the applicable legislation of the European Union. Paper copies for internal use only. DISCLAIMER: Despite the care taken in preparing this document, no ADIONICS Liability can not be accepted for damage or injury resulting from its use. The information in this document is believed to be correct at time of printing and have been prepared on the basis of the most reliable information available. They do not purport to be all inclusive and shall be considered as a guide. Before using this product in any new process or experiment, a compatibility study materials and a risk analysis must be made. 4 avenue du président François Miterrand, 91 380 Chilly-Mazarin Tèl. : +33 1 69 19 41 68 Page 6 sur 6 En cas d’urgence : + 33 9 88 99 06 38
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