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Abbreviations and Symbols
Information on purity and application
컄
see
[]
Chemical Abstracts Registry Number (CAS)
>
more than
<
less than
min
minimum
max
maximum
µm
0,001 mm
~
approximate
[α]a
specific rotation
+4°C
-20°C
®
ë
í
CHR
A compound in this catalogue is designated as being
thin-layer chromatographically pure (CHR) if no
impurities can be detected during test conditions
with 20 µg sample.
~CHR
For products with impurities which under our
conditions, (see CHR), allow the main compound
to be designated; such products can be identified
as being "almost thin-layer chromatographically
pure" (~CHR).
storage in refrigerating room
C.I. No
colour index number
storage in deep-freeze room
conc.
concentrated
registered symbol, registered trade mark
cP
centipoise
corrosive
cryst.
crystallized
explosive
cSt
centistoke
è=/ è+
highly flammable / extremely flammable
D
density
ç
fire-activating, oxidizing
DAB
ê=/ ê+
toxic / very toxic
Deutsches Arzneibuch
(German Pharmacopoeia)
én
harmful
DAC
éi
irritant
Deutscher Arzneimittel-Codex
(German Drugs Codex)
f
dangerous for the environment
m
l
o
k
h
i
g
n
j
GHS01 exploding bomb
GHS09 environment
Flp
flash point
Å
Ångström = 10-10 m
g
gramme
ACS
American Chemical Society
GC
gas chromatography
ADR
European agreement on international road transport
of hazardous goods
(GC)
content defined by gas chromatography
H
AW
atomic weight
Hazard statement acc. to regulation
(EC) No 1272/2008 (CLP, GHS)
Amp.
ampoule
HPLC
high performance liquid chromatography
aq
water
IE
international unit (Internationale Einheit)
art.
artificial
ISO
International Organization for Standardization
asym.
asymmetrical
IU
international unit
AT
argentometric titration
JP
Japanese Pharmacopoeia
BP
British Pharmacopoeia
kg
kilogramme
bp
boiling point, boiling range
l, ltr
litre
bp12
boiling point at 12 torr
Lit.
literature
c
amount-of-substance concentration
LSC
liquid scintillation counting
CAS
Chemical Abstract Service
lyophil.
lyophilized (readily soluble form)
CELLPURE®
suitable for cell culture
M or mol/l
molarity, amount-of-substance concentration
DC
thin-layer chromatography
dec.
decomposition
depur.
depuratum, purified quality
GHS02 flame
dest.
distilled
GHS03 flame over circle
DIN
German Industrial Standards
E No
number codes for food additives that have been
assessed for use within the EC
GHS05 corrosion
EC No
the official number of a chemical substance that is
commercially available within the EC
GHS06 skull and crossbones
extra pure
suitable for laboratory use
GHS07 exclamation mark
F
melting point, melting range
FCC
Food chemical codex
FIP
Fédération Internationale Pharmaceutique
GHS04 gas cylinder
GHS08 health hazard
GB_25_Abkuerzungen_Symbole_2015.fm Seite 2123 Montag, 2. Februar 2015 10:10 10
Abbreviations and Symbols
M
molecular weight or molar mass
mg
milligramm
ml
mililitre
Mol.%
molar percent
nat.
natural
nD
refractive index
o.r.
on request
P
Precautionary statement acc. to regulation (EC) No
1272/2008 (CLP, GHS)
ROTICUBE®
Combi-box of 5 litre or 10 litre, consisting of a stable
outer card box with inner bag made of PE; comes with
stopcock.
ROTIDRY®
dried solvents, filled under protective gas
ROTIDRY®SEPT
dried solvents, in a septum bottle
ROTIGEN®
product is suitable for DNA-synthesis
ROTIPHORESE®
product is suitable for electrophoresis
ROTIPURAN®
highly pure product
ROTISOLV®
solvent for specific use - brand name Roth
ROTITAINER®
Stackable containers which can also be handled
easily by female workers. Matching safety pumps are
available. Solid substances are delivered in plastic
buckets.
Pa s
Pascal second
p.a.
pro analysi = for analytical purposes
Pestilyse®
solvent, suitable for residue analysis
(environmental, water and food analysis)
S
Safety statement acc. to regulation 67/548/EEC
pH
pH value
sec.
secondary
pKa
pKa value
sicc.
dry, anhydrous (siccus)
pharm.
pharmaceutical quality, for pharmaceutical purposes
sine H2O
water free
Ph.Eur.
European Pharmacopoeia
stab.
stabilized
ppb
parts per billion = 1 µg per kg
subl.
sublimated
ppm
parts per million = 0,0001 %, 1 mg per kg
sym.
symmetrical
ppt
parts per trillion = 1 ng per kg
synth.
synthetic
prim.
primary
techn.
PUFFERAN®
can be used as buffer
pulv.
pulverised
pure
suitable for synthesis and laboratory use
technical quality. Products with the purity designation
"technicum" feature a different content. They are
generally mass produced and may have a slightly
foreign odour and colour. They are used for general
technical purposes.
puriss.
purissimum, especially pure quality. Products with
such designation have a content of at least 99%,
unless a different content is stated in %. Their
appearance and characteristic data correspond to the
appertaining literature or deviate only slightly from it.
They are suitable for purposes requiring a high degree
of purity. With a number of products having this
degree of purity, analysis certificates plus guarantee
will be supplied or attached to the container. Delicate
products are packaged under protective gas.
tert.
tertiary; standard for thin-layer chromatograhy (TLC)
TLC
thin layer chromatography
U
unit
USP
United States Pharmacopoeia
WGK
water hazard class
WGK 1
generally not water hazardous
WGK 2
water hazardous
WGK 3
extremely water hazardous
purum
chemically pure quality. Products having the purity
designation "purum" have a content of at least 97%,
unless a different content is stated, and their colour
and characteristic data, apart from minor deviations,
correspond to the literature. This degree of purity is
recommended for laboratory work such as syntheses,
which are subject to purity requirements.
Delicate products are packaged under protective gas.
R
Risk statement acc. to regulation 67/548/EEC
rect.
rectification
redest.
redistilled
resubl.
resublimated
ROTICHROM®
suitable as standard in chromatography
ROTICHROM®GC
reference substance for gas chromatography,
delivered with GC chromatogram
ROTICHROM®HPLC
reference substance for HPLC, delivered with HPLC
chromatogram
ROTICHROM®TLC
reference substance for thin-layer chromatography,
delivered with thin-layer chromatogram
GB_26_R_und_S_Kennzeichnung_2015.fm Seite 2124 Montag, 2. Februar 2015 10:11 10
Labelling acc. to Regulation 67/548/EEC
Symbols
ê
ê
é
ë
é
í
ç
è
è
f
Risk-phrases
Safety-phrases
T+
Very toxic
26, 27, 28, 39
1, 4, 13, 20, 21, 22, 27, 28, 29,
35, 36, 37, 38, 45
T
Toxic
23, 24, 25, 39, 45, 46, 48, 49, 60, 61
1, 4, 13, 20, 21, 22, 27, 28, 35, 36, 37, 38, 45
Xn
Harmful
20, 21, 22, 40, 42, 46, 48, 60, 61, 62, 63, 64, 65, 68
2, 13, 36, 37, 45
C
Corrosive
34, 35
2, 18, 20, 25, 26, 27, 28, 37, 39, 45
Xi
Irritant
36, 37, 38, 41, 43
2, 18, 24, 25, 26, 27, 28, 37, 39, 45
E
Explosive
1, 2, 3, 4, 5, 6, 16
1, 2, 3, 4, 35,
(7, 9, 14, 25, 27, 39, 50)
O
Oxidizing
7, 8, 9
2, 14, 25, 40, 50
F+
Extremely flammable
12
2, 3, 9, 15, 16, 29, 33, 43
F
Highly flammable
11, 15, 17
2, 3, 9, 16, 29, 33
N
Dangerous for the
environment
50, 51, 52, 53, 54, 55, 56, 57, 58, 59
29, 56, 57, 59, 60, 61
GB_26_R_und_S_Kennzeichnung_2015.fm Seite 2125 Montag, 2. Februar 2015 10:11 10
R+S-Phrases
R-Phrases
R 1:
Explosive when dry.
R 2:
Risk of explosion by shock, friction, fire or other sources of
ignition.
R 3:
Extreme risk of explosion by shock, friction, fire or other
sources of ignition.
R 48:
Danger of serious damage to health by prolonged exposure.
R 49:
May cause cancer by inhalation.
R 50:
Very toxic to aquatic organisms.
R 51:
Toxic to aquatic organisms.
R 52:
Harmful to aquatic organisms.
R 53:
May cause long-term adverse effects in the aquatic
environment.
R 4:
Forms very sensitive explosive metallic compounds.
R 5:
Heating may cause an explosion.
R 54:
Toxic to flora.
R 6:
Explosive with or without contact with air.
R 55:
Toxic to fauna.
R 7:
May cause fire.
R 56:
Toxic to soil organisms.
R 8:
Contact with combustible material may cause fire.
R 57:
Toxic to bees.
R 9:
Explosive when mixed with combustible material.
R 58:
May cause long-term adverse effects in the environment.
R 10:
Flammable.
R 59:
Dangerous for the ozone layer.
R 11:
Highly flammable.
R 60:
May impair fertility.
R 12:
Extremely flammable.
R 61:
May cause harm to the unborn child.
R 14:
Reacts violently with water.
R 62:
Possible risk of impaired fertility.
R 15:
Contact with water liberates extremely flammable gases.
R 63:
Possible risk of harm to the unborn child.
R 16:
Explosive when mixed with oxidizing substances.
R 64:
May cause harm to breastfed babies.
R 17:
Spontaneously flammable in air.
R 65:
Harmful: may cause lung damage if swallowed.
R 18:
In use, may form flammable/explosive vapour air mixture.
R 66:
Repeated exposure may cause skin dryness or cracking.
R 19:
May form explosive peroxides.
R 67:
Vapours may cause drowsiness and dizziness.
R 20:
Harmful by inhalation.
R 68:
Possible risk of irreversible effects.
R 21:
Harmful in contact with skin.
R 22:
Harmful if swallowed.
R 23:
Toxic by inhalation.
R 24:
Toxic in contact with skin.
R 25:
Toxic if swallowed.
R 26:
Very toxic by inhalation.
R 27:
Very toxic in contact with skin.
R 28:
Very toxic if swallowed.
R 29:
Contact with water liberates toxic gas.
R 30:
Can become highly flammable in use.
R 31:
Contact with acids liberates toxic gas.
R 32:
Contact with acids liberates very toxic gas.
R 33:
Danger of cumulative effects.
R 34:
Causes burns.
R 35:
Causes severe burns.
R 36:
Irritating to eyes.
R 37:
Irritating to respiratory system.
R 38:
R 39:
Combination of R-Phrases
R14/15:
Reacts violently with water, liberating extremely flammable
gases.
R 15/29:
Contact with water liberates toxic, extremely flammable gas.
R 20/21:
Harmful by inhalation and in contact with skin.
R 20/22:
Harmful by inhalation and if swallowed.
R 20/21/22:
Harmful by inhalation, in contact with skin and if swallowed.
R 21/22:
Harmful in contact with skin and if swallowed.
R 23/24:
Toxic by inhalation and in contact with skin.
R 23/25:
Toxic by inhalation and if swallowed.
R 23/24/25:
Toxic by inhalation, in contact with skin and if swallowed.
R 24/25:
Toxic in contact with skin and if swallowed.
R 26/27:
Very toxic by inhalation and in contact with skin.
R 26/28:
Very toxic by inhalation and if swallowed.
R 26/27/28:
Very toxic by inhalation, in contact with skin and if
swallowed.
Irritating to skin.
R 27/28:
Very toxic in contact with skin and if swallowed.
Danger of very serious irreversible effects.
R 36/37:
Irritating to eyes and respiratory system.
R 40:
Limited evidence of a carcinogenic effect.
R 36/38:
Irritating to eyes and skin.
R 41:
Risk of serious damage to eyes.
R 36/37/38:
Irritating to eyes, respiratory system and skin.
R 42:
May cause sensitization by inhalation.
R 37/38:
Irritating to respiratory system and skin.
R 43:
May cause sensitization by skin contact.
R 39/23:
R 44:
Risk of explosion if heated under confinement.
Toxic : danger of very serious irreversible effects through
inhalation.
R 45:
May cause cancer.
R 39/24:
R 46:
May cause heritable genetic damage.
Toxic : danger of very serious irreversible effects in contact
with skin.
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R+S-Phrases
R 39/25:
Toxic : danger of very serious irreversible effects if
swallowed.
R 50/53:
Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
R 39/23/24:
Toxic : danger of very serious irreversible effects through
inhalation and in contact with skin.
R 51/53:
Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
R 39/23/25:
Toxic : danger of very serious irreversible effects through
inhalation and if swallowed.
R 52/53:
Harmful to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
R 39/24/25:
Toxic : danger of very serious irreversible effects in contact
with skin and if swallowed.
R 68/20:
Harmful : possible risk of irreversible effects through
inhalation.
R 39/23/24/25:
Toxic : danger of very serious irreversible effects through
inhalation, in contact with skin and if swallowed.
R 68/20/21:
Harmful : possible risk of irreversible effects through
inhalation and in contact with skin.
R 39/26:
Very toxic : danger of very serious irreversible effects
through inhalation.
R 68/20/21/22:
Harmful : possible risk of irreversible effects through
inhalation, in contact with skin and if swallowed.
R 39/27:
Very toxic : danger of very serious irreversible effects in
contact with skin.
R 68/20/22:
Harmful : possible risk of irreversible effects through
inhalation and if swallowed.
R 39/28:
Very toxic : danger of very serious irreversible effects if
swallowed.
R 68/21:
Harmful : possible risk of irreversible effects in contact
with skin.
R 39/26/27:
Very toxic : danger of very serious irreversible effects
through inhalation and in contact with skin.
R 68/21/22:
Harmful : possible risk of irreversible effects in contact
with skin and if swallowed.
R 39/26/28:
Very toxic : danger of very serious irreversible effects
through inhalation and if swallowed.
R 68/22:
Harmful : possible risk of irreversible effects if swallowed.
R 39/27/28:
Very toxic : danger of very serious irreversible effects in
contact with skin and if swallowed.
R 39/26/27/28:
Very toxic : danger of very serious irreversible effects
through inhalation, in contact with skin and if swallowed.
R 42/43:
May cause sensitization by inhalation and skin contact.
R 48/20:
Harmful : danger of serious damage to health by prolonged
exposure through inhalation
S-Phrases
S1:
Keep locked up.
S2:
Keep out of the reach of children.
S3:
Keep in a cool place.
S4:
Keep away from living quarters.
Keep contents under ... (appropriate liquid to be specified by
the manufacturer).
R 48/21:
Harmful : danger of serious damage to health by prolonged
exposure in contact with skin.
S5:
R 48/22:
Harmful : danger of serious damage to health by prolonged
exposure if swallowed.
S6:
Keep under ...(inert gas to be specified by the manufacturer).
S7:
Keep container tightly closed.
R 48/20/21:
Harmful : danger of serious damage to health by prolonged
exposure through inhalation and in contact with skin.
S8:
Keep container dry.
S9:
Keep container in a well-ventilated place.
R 48/20/22:
Harmful : danger of serious damage to health by prolonged
exposure through inhalation and if swallowed.
S12:
Do not keep the container sealed.
R 48/21/22:
Harmful : danger of serious damage to health by prolonged
exposure in contact with skin and if swallowed.
S13:
Keep away from food, drink and animal feeding stuffs.
S14:
Harmful : danger of serious damage to health by prolonged
exposure through inhalation, in contact with skin and if
swallowed.
Keep away from ... (incompatible materials to be indicated by
the manufacturer).
S15:
Keep away from heat.
S16:
Keep away from sources of ignition - No smoking.
R 48/23:
Toxic : danger of serious damage to health by prolonged
exposure through inhalation.
S17:
Keep away from combustible material.
S18:
Handle and open container with care.
R 48/24:
Toxic : danger of serious damage to health by prolonged
exposure in contact with skin.
S20:
When using do not eat or drink.
R 48/25:
Toxic : danger of serious damage to health by prolonged
exposure if swallowed.
S21:
When using do not smoke.
S22:
Do not breathe dust.
Do not breathe gas/fumes/vapour/spray (appropriate
wording to be specified by the manufacturer).
R 48/20/21/22:
R 48/23/24:
Toxic : danger of serious damage to health by prolonged
exposure through inhalation and in contact with skin.
S23:
R 48/23/25:
Toxic : danger of serious damage to health by prolonged
exposure through inhalation and if swallowed.
S24:
Avoid contact with skin.
S25:
Avoid contact with eyes.
R 48/24/25:
Toxic : danger of serious damage to health by prolonged
exposure in contact with skin and if swallowed.
S26:
In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
R 48/23/24/25:
Toxic : danger of serious damage to health by prolonged
exposure through inhalation, in contact with skin and if
swallowed.
S27:
Take off immediately all contaminated clothing.
S28:
After contact with skin, wash immediately with plenty of ...
(to be specified by the manufacturer).
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R+S-Phrases
S29:
Do not empty into drains.
S30:
Never add water to this product.
S33:
Take precautionary measures against static discharges.
S35:
This material and its container must be disposed of in a safe
way.
S36:
Wear suitable protective clothing.
S37:
Wear suitable gloves.
S38:
In case of insufficient ventilation, wear suitable respiratory
equipment.
S39:
Wear eye/face protection.
S40:
S41:
S42:
S43:
Combination of S-Phrases
S 1/2
Keep locked up and out of the reach of children.
S 3/7
Keep container tightly closed in a cool place.
S 3/9/14
Keep in a cool, well-ventilated place away from ...
(incompatible materials to be indicated by the manufacturer).
S 3/9/14/49
Keep only in the original container in a cool, well-ventilated
place away from ... (incompatible materials to be indicated
by the manufacturer).
S 3/9/49
Keep only in the original container in a cool, well-ventilated
place.
To clean the floor and all objects contaminated by this
material, use ... (to be specified by the manufacturer).
S 3/14
Keep in a cool place away from ... (incompatible materials to
be indicated by the manufacturer).
In case of fire and/or explosion do not breathe fumes.
S 7/8
Keep container tightly closed and dry.
During fumigation/spraying wear suitable respiratory
equipment (appropriate wording to be specified by the
manufacturer).
S 7/9
Keep container tightly closed and in a well-ventilated place.
S 7/47
Keep container tightly closed and at a temperature not
exceeding ... °C (to be specified by the manufacturer).
In case of fire, use ... (indicate in the space the precise type
of fire-fighting equipment. If water increases risk, add
- ’Never use water’).
S 20/21
When using do not eat, drink or smoke.
S 24/25
Avoid contact with skin and eyes.
S 27/28
After contact with skin, take off immediately all
contaminated clothing, and wash immediately with plenty of
- (to be specified by the manufacturer).
S45:
In case of accident or if you feel unwell, seek medical advice
immediately (show te label where possible).
S46:
If swallowed, seek medical advice immediately and show
this container or label.
S 29/35
S47:
Keep at temperature not exceeding ... °C (to be specified by
the manufacturer).
Do not empty into drains; dispose of this material and its
container in a safe way.
S 29/56
S48
Keep wet with ... (appropriate material to be specified by the
manufacturer).
Do not empty into drains, dispose of this material and its
container at hazardous or special waste collection point.
S 36/37
Wear suitable protective clothing and gloves.
S 36/37/39
Wear suitable protective clothing, gloves and eye/face
protection.
S 36/39
Wear suitable protective clothing and eye/face protection.
S 37/39
Wear suitable gloves and eye/face protection.
S 47/49
Keep only in the original container at a temperature not
inhalation and in contact with skin.
S49:
Keep only in the original container.
S50:
Do not mix with ... (to be specified by the manufacturer).
S51:
Use only in well-ventilated areas.
S52:
Not recommended for interior use on large surface areas.
S53:
Avoid exposure - obtain special instructions before use.
S56:
Dispose of, this material and its container at hazardous or
special waste collection point.
S57:
Use appropriate container to avoid environmental
contamination.
S59
Refer to manufacturer/supplier for information on recovery/
recycling.
S60:
This material and its container must be disposed of as
hazardous waste.
S61:
Avoid release to the environment. Refer to special
instructions/Safety data sheets.
S62:
If swallowed, do not induce vomiting : seek medical advice
immediately and show this container or label.
S63:
In case of accident by inhalation : remove casualty to fresh
air and keep at rest.
S64:
If swallowed, rinse mouth with water (only if the person is
conscious).
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Classification & Labelling acc. to (EC) 1272/2008
Hazard Pictograms
Hazard Statements H Codes
The hazard pictogram on the designation label indicates the main hazard
arising from a substance. If there are several hazardous qualitiies, several
symbols are necessary.
Hazard statements for physical hazards
H200
Unstable explosives.
Each pictogram is allocated a hazard designation and coding
that do not appear on the designation label.
H201
Explosive; mass explosion hazard.
GHS01
exploding bomb
GHS02
flame
GHS03
flame over circle
GHS04
gas cylinder
GHS05
corrosion
GHS06
skull and crossbones
GHS07
exclamation mark
GHS08
health hazard
GHS09
environment
H202
Explosive, severe projection hazard.
H203
Explosive; fire, blast or projection hazard.
H204
Fire or projection hazard.
H205
May mass explode in fire.
H220
Extremely flammable gas.
H221
Flammable gas.
H222
Extremely flammable aerosol.
H223
Flammable aerosol.
H224
Extremely flammable liquid and vapour.j
H225
Highly flammable liquid and vapour.
H226
Flammable liquid and vapour.
H228
Flammable solid.
H229
Pressurised container: May burst if heated.
H230
May react explosively even in the absence of air.
H231
May react explosively even in the absence of air at elevated pressure
and/or temperature.
H240
Heating may cause an explosion.
H241
Heating may cause a fire or explosion.
H242
Heating may cause a fire.
H250
Catches fire spontaneously if exposed to air.
H251
Self-heating; may catch fire.
H252
Self-heating in large quantities; may catch fire.
H260
In contact with water releases flammable gases which may
ignite spontaneously.
H261
In contact with water releases flammable gases.
H270
May cause or intensify fire; oxidiser.
H271
May cause fire or explosion; strong oxidiser.
H272
May intensify fire; oxidiser.
H280
Contains gas under pressure; may explode if heated.
H281
Contains refrigerated gas; may cause cryogenic burns or injury.
H290
May be corrosive to metals.
Hazard statements for health hazards
H300
Fatal if swallowed.
H301
Toxic if swallowed.
H302
Harmful if swallowed.
H304
May be fatal if swallowed and enters airways.
H310
Fatal in contact with skin.
H311
Toxic in contact with skin.
H312
Harmful in contact with skin.
H314
Causes severe skin burns and eye damage.
H315
Causes skin irritation.
H317
May cause an allergic skin reaction.
H318
Causes serious eye damage.
H319
Causes serious eye irritation.
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Classification & Labelling acc. to (EC) 1272/2008
H330
Fatal if inhaled.
H331
Toxic if inhaled.
H332
Harmful if inhaled.
H334
May cause allergy or asthma symptoms or breathing difficulties
if inhaled.
H335
May cause respiratory irritation.
H336
H340
Supplemental Hazard Information
H Codes
EUH001
Explosive when dry.
EUH006
Explosive with or without contact with air.
EUH014
Reacts violently with water.
May cause drowsiness or dizziness.
EUH018
In use may form flammable/explosive vapour-air mixture.
May cause genetic defects.
EUH019
May form explosive peroxides.
H341
Suspected of causing genetic defects.
EUH029
Contact with water liberates toxic gas.
H350
May cause cancer.
EUH031
Contact with acids liberates toxic gas.
H350i
May cause cancer by inhalation.
EUH032
Contact with acids liberates very toxic gas.
H351
Suspected of causing cancer.
EUH044
Risk of explosion if heated under confinement.
H360
May damage fertility or the unborn child.
EUH066
Repeated exposure may cause skin dryness or cracking.
H360F
May damage fertility.
EUH070
Toxic by eye contact.
H360D
May damage the unborn child.
EUH071
Corrosive to the respiratory tract.
H360FD
May damage fertility. May damage the unborn child.
EUH201
Contains lead. Should not be used on surfaces liable to be chewed
or sucked by children.
Warning! Contains lead.
H360Fd
May damage fertility. Suspected of damaging the unborn child.
H360Df
May damage the unborn child. Suspected of damaging fertility.
H361
Suspected of damaging fertility or the unborn child.
H361f
Suspected of damaging fertility .
EUH203
Contains chromium (VI). May produce an allergic reaction.
H361d
Suspected of damaging the unborn child.
EUH204
Contains isocyanates. May produce an allergic reaction.
H361fd
Suspected of damaging fertility.
Suspected of damaging the unborn child.
EUH205
Contains epoxy constituents. May produce an allergic reaction.
EUH206
Warning! Do not use together with other products.
May release dangerous gases (chlorine).
EUH207
Warning! Contains cadmium. Dangerous fumes are formed during
use. See information supplied by the manufacturer. Comply with the
safety instructions.
EUH208
Contains (name of sensitising substance). May produce an allergic
reaction.
EUH201A
EUH202
Cyanoacrylate. Danger. Bonds skin and eyes in seconds.
Keep out of the reach of children.
H362
May cause harm to breast-fed children.
H370
Causes damage to organs.
H371
May cause damage to organs.
H372
Causes damage to organs through prolonged or repeated exposure.
H373
May cause damage to organs through prolonged or repeated
exposure.
H300+H310
Fatal if swallowed or in contact with skin.
EUH209
EUH209A
Can become highly flammable in use.
Can become flammable in use.
H300+H330
Fatal if swallowed or if inhaled.
EUH210
Safety data sheet available on request.
H310+H330
Fatal in contact with skin or if inhaled.
EUH401
To avoid risks to human health and the environment, comply with the
instructions for use.
H300+H310+H330 Fatal if swallowed, in contact with skin or if inhaled.
H301+H311
Toxic if swallowed or in contact with skin.
H301+H331
Toxic if swallowed or if inhaled.
H311+H331
Toxic in contact with skin or if inhaled.
H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled.
H302+H312
Harmful if swallowed or in contact with skin.
H302+H332
Harmful if swallowed or if inhaled.
H312+H332
Harmful in contact with skin or if inhaled.
H302+H312+H332 Harmful if swallowed, in contact with skin or if inhaled.
Hazard statements for environmental hazards
H400
Very toxic to aquatic life.
H410
Very toxic to aquatic life with long lasting effects.
H411
Toxic to aquatic life with long lasting effects.
H412
Harmful to aquatic life with long lasting effects.
H413
May cause long lasting harmful effects to aquatic life.
H420
Harms public health and the environment by destroying ozone
in the upper atmosphere.
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Classification & Labelling acc. to (EC) 1272/2008
Classification
Hazard class
Category codes
Unstable
explosives
Unst. Expl.
Divisions 1.1
Expl. 1.1
Labelling
Pictogram, code Signal word
Hazard statements
H200
Unstable explosives.
H201
Explosive; mass explosion hazard.
H202
Explosive, severe projection hazard.
H203
Explosive; fire, blast or projection hazard.
Warning
H204
Fire or projection hazard.
Danger
H205
May mass explode in fire.
Danger
Explosive
Divisions 1.2
Expl. 1.2
Divisions 1.3
Expl. 1.3
Divisions 1.4
Expl. 1.4
Divisions 1.5
Expl. 1.5
No pictogram
Divisions 1.6
Expl. 1.6
No pictogram, no signal word, no hazard statement
Category 1
Flam. gas 1
GHS01
Danger
H220
Extremely flammable gas.
Warning
H221
Flammable gas.
Danger
H222
Extremely flammable aerosol.
Warning
H223
Flammable aerosol.
Danger
H270
May cause or intensify fire; oxidiser.
H280
Contains gas under pressure; may explode if heated.
H281
Contains refrigerated gas; may cause cryogenic burns or injury.
H224
Extremely flammable liquid and vapour.
H225
Highly flammable liquid and vapour.
H226
Flammable liquid and vapour.
H228
Flammable solid.
Flammable gas
GHS02
Category 2
Flam. gas 2
Category 1
Flam. aerosol 1
Category 2
Flam. aerosol 2
Category 1
Ox. gas 1
No pictogram
Flammable
aerosol
Oxidising gas
GHS02
GHS03
Compressed gas
Gas under
pressure
Dissolved gas
Press. gas
Warning
Liquefied gas
Refrigerated
liquefied gas
Category 1
GHS04
Flam. Liq. 1
Danger
Flammable liquid
Category 2
Flam. Liq. 2
Category 3
Flam. Liq. 3
Category 1
Flam. Sol. 1
Flammable solid
Warning
Danger
GHS02
Category 2
Flam. Sol. 2
Warning
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Classification & Labelling acc. to (EC) 1272/2008
Classification
Hazard class
Category codes
Labelling
Pictogram, code Signal word
Hazard statements
Self-react. A
Type A
H240
Heating may cause an explosion.
H241
Heating may cause a fire or explosion.
H242
Heating may cause a fire.
Org. Perox. A
GHS01
Self-reactive
substance or
mixture
Self-react. B
Type B
Org. Perox. B
Organic peroxide
Danger
GHS01 + GHS02
Self-react. CD
Type C and D
Danger
Org. Perox. CD
Self-react. EF
Type E and F
Warning
Org. Perox. EF
GHS02
Self-react. G
Type G
No pictogram, no signal word, no hazard statement
Org. Perox. G
Pyrophoric liquid
Category 1
Pyr. Liq. 1
Pyrophoric solid
Category 1
Pyr. Sol. 1
Self-heating
substance or
mixture
Category 1
Substance or
mixture which in
contact with
water emits
flammable gas
Danger
H250
Catches fire spontaneously if exposed to air.
Self-heat. 1
Danger
H251
Self-heating; may catch fire.
Category 2
Self-heat. 2
Warning
H252
Self-heating in large quantities; may catch fire.
Category 1
Water-react. 1
Danger
H260
In contact with water releases flammable gases which may
ignite spontaneously.
Category 2
Water-react. 2
H261
In contact with water releases flammable gases.
Category 3
Water-react. 3
H271
May cause fire or explosion; strong oxidiser.
H272
May intensify fire; oxidiser.
H290
May be corrosive to metals.
H300
H310
H330
Fatal if swallowed.
Fatal in contact with skin.
Fatal if inhaled.
H301
H311
H331
Toxic if swallowed.
Toxic in contact with skin.
Toxic if inhaled.
H302
H312
H332
Harmful if swallowed.
Harmful in contact with skin.
Harmful if inhaled.
Category 1
Oxidising liquid
Category 2
Oxidising solid
Category 3
Substance or
mixture corrosive
to metals
Category 1
GHS02
Warning
Ox. Liq. 1
Danger
Ox. Sol. 1
Ox. Liq. 2
Danger
Ox. Sol. 2
Ox. Liq. 3
Ox. Sol. 3
Danger
GHS03
Met. Corr. 1
Warning
Warning
GHS05
Category 1
Acute Tox. 1
Category 2
Acute Tox. 2
Category 3
Acute Tox. 3
Category 4
Acute Tox. 4
Danger
GHS06
Acute toxicity
Warning
GHS07
GB_27_GHS_und_H_Saetze_2015_sw.fm Seite 2132 Montag, 2. Februar 2015 10:12 10
Classification & Labelling acc. to (EC) 1272/2008
Classification
Hazard class
Skin corrosion/
irritation
Category codes
Category 1A
Skin Corr. 1A
Category 1B
Skin Corr. 1B
Category 1C
Skin Corr. 1C
Category 2
Skin Irrit. 2
Labelling
Pictogram, code Signal word
Hazard statements
Danger
H314
Causes severe skin burns and eye damage.
Warning
H315
Causes skin irritation.
Danger
H318
Causes serious eye damage.
Warning
H319
Causes serious eye irritation.
Danger
H334
May cause allergy or asthma symptoms or breathing difficulties
if inhaled.
Warning
H317
May cause an allergic skin reaction.
Danger
H340
May cause genetic defects. (*)
Warning
H341
Suspected of causing genetic defects. (*)
Danger
H350
H350i
May cause cancer. (*)
May cause cancer by inhalation.
Warning
H351
Suspected of causing cancer. (*)
GHS05
GHS07
Category 1
Eye Dam. 1
Serious eye damage/
eye irritation
GHS05
Category 2
Eye Irrit. 2
GHS07
Respiratory
sensitization
Category 1
Category 1A
Category 1B
Resp. Sens. 1
Resp. Sens. 1A
Resp. Sens. 1B
GHS05
Skin sensitization
Category 1
Category 1A
Category 1B
Skin Sens. 1
Skin Sens. 1A
Skin Sens. 1B
Category 1A
Muta. 1A
Category 1B
Muta. 1B
Category 2
Muta. 2
Category 1A
Carc. 1A
Category 1B
Carc. 1B
Category 2
Carc. 2
GHS07
Germ cell
mutagenicity
Carcinogenicity
GHS08
(*) state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard
Reproductive
toxicity
Category 1A
Repr. 1A
Category 1B
Repr. 1B
Category 2
Repr. 2
Danger
Warning
GHS08
Additional
category for effects
on or via lactation
Lact.
No pictogram
No signal word
H360
H360F
H360D
H360FD
H361
H361f
H361d
H361fd
May damage fertility or the unborn child. (*)
May damage fertility. (*)
May damage the unborn child. (*)
May damage fertility. May damage the unborn child. (*)
Suspected of damaging fertility or the unborn child.
Suspected of damaging fertility.
Suspected of damaging the unborn child.
Suspected of damaging fertility. Suspected of damaging the
unborn child.
H362
May cause harm to breast-fed children.
(*) state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard
GB_27_GHS_und_H_Saetze_2015_sw.fm Seite 2133 Montag, 2. Februar 2015 10:12 10
Classification & Labelling acc. to (EC) 1272/2008
Classification
Hazard class
Category codes
Category 1
STOT SE 1
Category 2
STOT SE 2
Labelling
Pictogram, code Signal word
Hazard statements
Danger
H370
Causes damage to organs. (*)
Warning
H371
May cause damage to organs. (*)
H335
May cause respiratory irritation.
H336
May cause drowsiness or dizziness.
GHS08
Specific target
organ toxicity –
single exposure
Category 3
STOT SE 3
Warning
GHS07
Specific target
organ toxicity –
repeated
exposure
Category 1
STOT RE 1
Danger
H372
Causes damage to organs through prolonged or repeated
exposure. (*)
Category 2
STOT RE 2
Warning
H373
May cause damage to organs through prolonged or repeated
exposure. (*)
GHS08
(*) state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard
Aspiration hazard
Category 1
Asp. Tox. 1
Danger
H304
May be fatal if swallowed and enters airways.
Aquatic Acute 1
Warning
H400
Very toxic to aquatic life.
Chronic 1
Aquatic Chronic 1
Warning
H410
Very toxic to aquatic life with long lasting effects.
Chronic 2
Aquatic Chronic 2
No signal word
H411
Toxic to aquatic life with long lasting effects.
H412
Harmful to aquatic life with long lasting effects.
H413
May cause long lasting harmful effects to aquatic life.
H420
Harms public health and the environment by destroying
ozone in the upper atmosphere.
GHS08
Acute aquatic hazard Acute 1
Long-term
aquatic hazard
GHS09
Chronic 3
Aquatic Chronic 3
No pictogram
Hazardous for the
ozone layer
Chronic 4
Aquatic Chronic 3
Category 1
Ozone 1
No signal word
Warning
GHS07