ALUMINIUM AND ZINC ANODES
AL / ZN / IN Composistion:
Specification Code
Fe
Si
Cu
Zn
In
Others (each)
Alluminium
A Guard
0.09%
0.08 – 0.120%
0.003%
4.5 – 5.5%
0.015 – 0.020%
0.02% max
Remainder
Electro Chemichal:
Potential Ag/AgCI
-1.05 Volts
Min Capacity
2500 Ampere. hour / kg
Zinc Composition:
Specification Code
Cu
Al
Fe
Cd
Pb
Others (total)
Zn
US Mil Spec 118001 K
0.05% max
0.010 – 0.50%
0.05% max
0.025 – 0.07%
0.006% max
0.10% max
Remainder
Electro Chemical:
Potential Ag/AgCI
-1.05 +/- 0.05V
Capacity
780 Ampere. Hour / kg min.
1
25x3
165
0.7/
0.8
160
88
44
240
-
-
25x3
245
AGW5
0.7/
0.8
160
88
50
240
-
-
25x3
245
AGW5R
1.1/
1.25
170
83
41
245
-
-
25x3
250
AGW7R
1.75/
2
305
80
44
380
-
-
25x3
385
AGW10
1.75/
2
305
78
44
380
-
-
25x3
385
AGW10R
2.25/
2.5
305
114
25
380
-
-
25x3
385
AGW12
2.5/
2.75
230
152
32
295
-
-
25x3
300
AGW13
H – Insert Length (mm)
F – Fixing Centres (mm)
-
G – Insert Size (mm)
E – Diameter (mm)
D – Overall Length (mm)
-
C – Height (mm)
160
B – Width (mm)
22
Aluminium Weld-on Hull
Anodes
A – Length (mm)
76
Ned Marine
Net/GrosWeight (Kg)
0.35/
0.45
108
AGW2
Product
Code
2
-
-
40x5
405
4/
4.5
350
152
38
460
-
-
40x5
465
AGW20
4.45/
5.2
355
152
38
460
-
-
40x5
465
AGW22
5.6/
6.5
457
120
70
580
-
-
40x5
585
AGW30
5/6
450
115
60
580
-
-
40x5
585
5.6/
6.5
457
120
70
570
-
-
40x5
575
6/7
457
120
80
570
-
-
40x5
575
7/8
550
130
50
700
-
-
40x5
705
H – Insert Length (mm)
F – Fixing Centres (mm)
400
G – Insert Size (mm)
E – Diameter (mm)
D – Overall Length (mm)
B – Width (mm)
32
Aluminium Weld-on Hull
Anodes
C – Height (mm)
A – Length (mm)
152
Ned Marine
Net/GrosWeight (Kg)
3/
3.5
297
AGW15
Product
Code
AGW30R
AGW30RS
AGW36R
A8
3
-
-
40x5
705
7.5/
9
813
102
38
913
-
-
40x5
918
AGW35
10.5/
11.5
813
102
50
913
-
-
40x5
918
AGW45
19/
20.5
990
90
80
1120
-
-
40x5
1125
AGWS50
9/10
305
100
40
-
-
-
40x5
250
3.5/
4
300
150
25
300
-
-
40x5
250
AGW24
4/
4.5
305
152
32
-
-
-
40x5
250
AGW25
7.5/
8
711
102
38
711
-
-
40x5
210
AGW42
H – Insert Length (mm)
F – Fixing Centres (mm)
700
G – Insert Size (mm)
E – Diameter (mm)
D – Overall Length (mm)
B – Width (mm)
65
Aluminium Weld-on Hull
Anodes
C – Height (mm)
A – Length (mm)
130
Ned Marine
Net/GrosWeight (Kg)
10/
11
550
A11
Product
Code
AGW21
4
H – Insert Length (mm)
F – Fixing Centres (mm)
D – Overall Length (mm)
160
-
-
25x3
Galv
165
ZGW5
2/2.2
160
88
44
240
-
-
25x3
Galv
245
ZGW5R
2/2.1
160
88
50
240
-
-
25x3
Galv
245
ZGW7R
2.8/3
170
83
41
245
-
-
25x3
Galv
250
ZGW10
4.25/
4.5
305
80
44
380
-
-
25x3
Galv
385
ZGW10R
4.25/
4.5
305
78
44
380
-
25x3
Galv
385
ZGW12
5.25/
5.5
305
114
25
380
-
-
25x3
Galv
385
ZGW13
5.8/6
230
152
32
295
-
-
25x3
Galv
300
-
G – Insert Size (mm)
22
E – Diameter (mm)
76
ZGW2
C – Height (mm)
A – Length (mm)
108
Zinc Weld-on Hull
Anodes
B – Width (mm)
Net/GrosWeight (Kg)
Ned Marine
0.9/1
Product
Code
5
H – Insert Length (mm)
F – Fixing Centres (mm)
D – Overall Length (mm)
400
-
-
40x5
405
ZGW20
9.4/
10
350
152
38
460
-
-
40x5
465
ZGW22
11.25/
12
355
152
38
460
-
-
40x5
465
ZGW30
14.5/
15.5
457
120
70
580
-
-
40x5
585
ZGW30R
13/14
450
115
60
580
-
-
40x5
585
ZGW30RS
14/15
457
120
70
570
-
40x5
575
ZGW36R
15.45/
16.4
457
120
80
570
-
-
40x5
575
Z20
19/20
550
130
50
700
-
-
40x5
705
-
G – Insert Size (mm)
32
E – Diameter (mm)
152
ZGW15
C – Height (mm)
A – Length (mm)
297
Zinc Weld-on Hull
Anodes
B – Width (mm)
Net/GrosWeight (Kg)
Ned Marine
7.3/8
Product
Code
6
H – Insert Length (mm)
G – Insert Size (mm)
F – Fixing Centres (mm)
E – Diameter (mm)
D – Overall Length (mm)
B – Width (mm)
Z25
24/
25.1
550
130
55
700
-
-
40x5
705
ZGW35
18/20
813
102
38
913
-
-
40x5
918
ZGW45
25/27
813
102
50
913
-
-
40x5
918
ZGWS50
48/50
990
90
80
1120
-
-
40x5
1125
ZGW21
9/10
305
100
40
-
-
-
40x5
250
ZGW24
6/7
300
150
25
300
-
40x5
250
ZGW25
10/11
305
152
32
-
-
-
40x5
250
ZGW42
19/20
711
102
38
711
-
-
40x5
210
Zinc Weld-on Hull
Anodes
C – Height (mm)
A – Length (mm)
Ned Marine
Net/GrosWeight (Kg)
Product
Code
-
7
-
-
20x3
180
MA15
1.3/
1.5
150
100
38
250
-
-
20x3
250
MA25
2.1/
2.5
305
102
40
365
-
-
20x3
365
MA50
4.3/
5
445
125
40
505
-
-
40x5
505
MA80
7/8
640
125
43
700
-
-
40x5
700
MA116
10/
11.6
800
125
50
880
-
-
40x5
880
MA155
14/
15.5
920
125
50
-
-
-
40x5
1020
MA210
20/
21
650
110
105
-
-
-
40x5
750
H – Insert Length (mm)
F – Fixing Centres (mm)
180
G – Insert Size (mm)
E – Diameter (mm)
D – Overall Length (mm)
20
C – Height (mm)
70
B – Width (mm)
140
Aluminium Hull Anodes
A – Length (mm)
0.4/
0.45
Ned Marine
Net/GrosWeight (Kg)
MA5
Product
Code
8
-
-
20x3
180
MZ18
1.7/
1.8
160
80
30
205
-
-
20x3
205
MZ30
2.8/3
250
80
25
300
-
-
20x3
300
MZ51
4.6/
5.1
300
32
80
350
-
-
40x5
350
MZ85
8.1/
8.5
400
97
35
450
-
-
40x5
450
MZ108
10.2/
10.8
395
125
43
455
-
-
40x5
455
MZ160
15.1/
16
550
127
43
620
-
-
40x5
620
MZ220
20.6/
22
680
127
45
760
-
40x5
760
-
H – Insert Length (mm)
F – Fixing Centres (mm)
180
G – Insert Size (mm)
E – Diameter (mm)
D – Overall Length (mm)
20
C – Height (mm)
70
B – Width (mm)
140
Zinc Hull Anodes
A – Length (mm)
0.95/
1
Ned Marine
Net/GrosWeight (Kg)
MZ10
Product
Code
9
Product
Code
MZ270
Zinc Hull Anodes
27/
30.4
800
125
50
40x6
H – Insert Length (mm)
G – Insert Size (mm)
F – Fixing Centres (mm)
880
E – Diameter (mm)
D – Overall Length (mm)
C – Height (mm)
B – Width (mm)
A – Length (mm)
Net/GrosWeight (Kg)
Ned Marine
880
10
H – Insert Length (mm)
G – Insert Size (mm)
F – Fixing Centres (mm)
E – Diameter (mm)
D – Overall Length (mm)
C – Height (mm)
B – Width (mm)
Magnesium Hull
Anodes
A – Length (mm)
Ned Marine
Net/GrosWeight (Kg)
Product
Code
MGR2
0.25/
0.55
-
-
25
-
100
-
M12
0
MGR5
0.75/
1.65
-
-
25
-
138
-
40x5
100
MGW2
0.4/
0.5
108
76
22
-
-
-
25x3
0
MGS5R
0.5/
0.75
164
88
44
245
-
200
25x3
250
MGW7R
0.75/
0.95
185
83
41
245
-
-
25x3
250
MGW10R
1.1/
1.5
305
88
44
-
-
-
25x3
390
MGS10R
1.1/
1.3
305
88
44
-
-
200
30x3
255
MGW15
2/
2.75
305
152
32
-
-
-
40x5
405
11
D – Overall Length (mm)
E – Diameter (mm)
F – Fixing Centres (mm)
Product
Code
MGW20
2.6/
3.5
355
152
32
40x5
460
MGS25R
11.5/
12
457
102
64
457
229
40x5
363
MGW30R
3.5/
4.5
457
120
70
40x5
580
Magnesium Hull
Anodes
H – Insert Length (mm)
G – Insert Size (mm)
C – Height (mm)
B – Width (mm)
A – Length (mm)
Net/GrosWeight (Kg)
Ned Marine
12
F – Fixing Centres (mm)
2675
-
-
60mm
DIA
2675
M1760PA
175/
191
1735
200
200
2035
-
-
60mm
DIA
2035
M2400PA
240/
260
2365
200
200
2665
-
-
60mm
DIA
3225
M3300PA
330/
390
2375
250
250
2675
-
-
114mm
DIA
2675
M4350PA
435/
505
2985
250
250
3285
-
-
114mm
DIA
3285
M5650PA
565/
645
2975
283
283
3275
-
-
114mm
DIA
3275
M5660PA
566/
633
2440
305
305
2740
-
-
114mm
DIA
2740
H – Insert Length (mm)
E – Diameter (mm)
160
M1480PA
G – Insert Size (mm)
C – Height (mm)
D – Overall Length (mm)
B – Width (mm)
160
Aluminium Stand Off
Anodes
A – Length (mm)
2375
Ned Marine
Net/GrosWeight (Kg)
148/
167
Product
Code
13
M33TA
3.3/
4.4
D – Overall Length (mm)
55
800
-
-
12mm
DIA
1225
305
63
70
800
-
-
12mm
DIA
1025
H – Insert Length (mm)
50
G – Insert Size (mm)
335
C – Height (mm)
F – Fixing Centres (mm)
2.5/
3.2
E – Diameter (mm)
M25TA
B – Width (mm)
Aluminium Tank Anodes
A – Length (mm)
Ned Marine
Net/GrosWeight (Kg)
Product
Code
M45TA
4.5/
5.5
600
50
55
1100
-
-
12mm
DIA
2125
M58TA
5.8/
6.5
3.5
80
95
800
-
-
12mm
DIA
1100
M70TA
7.0/
8.0
600
63
70
1100
-
-
12mm
DIA
1250
M75TA
7.5/
9.0
1000
50
55
1500
-
-
12mm
DIA
1350
M87TA
8.7/
10
762
63
70
1225
-
-
12mm
DIA
1500
M100TA
10/
11
525
80
95
1025
12mm
DIA
1750
14
-
12mm
DIA
2125
M121TA
12.1/
13.0
600
80
95
1100
-
-
12mm
DIA
1100
M150TA
15/1
6.1
750
80
95
1250
-
-
12mm
DIA
1250
M170TA
17/1
8.2
850
80
95
1350
-
-
12mm
DIA
1350
M200TA
20.0/
21.3
1000
80
95
1500
-
-
12mm
DIA
1500
M252TA
25.2/
26.7
1250
80
95
1750
-
-
12mm
DIA
1750
M309TA
30.9/
32.7
1525
80
95
2125
-
-
12mm
DIA
2125
M340TA
34/
36.4
1515
80
105
2115
16mm
DIA
2115
H – Insert Length (mm)
F – Fixing Centres (mm)
-
G – Insert Size (mm)
E – Diameter (mm)
D – Overall Length (mm)
2125
C – Height (mm)
55
M114TA
B – Width (mm)
50
Aluminium Tank Anodes
A – Length (mm)
1525
Ned Marine
Net/GrosWeight (Kg)
11.4/
13.3
Product
Code
15
C – Height (mm)
D – Overall Length (mm)
E – Diameter (mm)
F – Fixing Centres (mm)
100
1800
-
-
20mm
DIA
1800
M445TA
44.5/
47.5
2000
80
105
2600
-
-
16mm
DIA
2600
M480TA
48/
54
1480
110
110
2080
-
-
25mm
DIA
2080
M570TA
57/
64
1750
110
110
2350
-
-
25mm
DIA
2350
M650TA
65/
74
2000
110
110
2600
-
-
25mm
DIA
2600
M700TA
70/
80
1555
130
130
2155
-
-
25mm
DIA
2155
M800TA
80/
90
1775
130
130
2375
-
-
25mm
DIA
2375
M900TA
90/
101
2000
130
130
2600
25mm
DIA
2600
M350TA
H – Insert Length (mm)
B – Width (mm)
100
Aluminium Tank Anodes
G – Insert Size (mm)
A – Length (mm)
1300
Ned Marine
Net/GrosWeight (Kg)
35/
39.5
Product
Code
16
E – Diameter (mm)
F – Fixing Centres (mm)
-
-
25mm
DIA
2820
M1100TA
110/
118.5
1595
160
160
2195
-
-
25mm
DIA
2195
M1200TA
120/
129
1740
160
160
2340
-
-
25mm
DIA
2340
M1265TA
126.5/
136.5
2000
117.5
200
2600
-
-
25mm
DIA
2600
M1300TA
130/
139.5
1885
160
160
2485
-
-
25mm
DIA
2485
M1350TA
135/
148
3000
130
130
3600
-
-
25mm
DIA
3600
M1400TA
140/
150
2030
160
160
2630
-
-
25mm
DIA
2630
M1500TA
150/
160
2000
160
160
2920
25mm
DIA
2920
H – Insert Length (mm)
D – Overall Length (mm)
2820
G – Insert Size (mm)
C – Height (mm)
130
M1000TA
B – Width (mm)
130
Aluminium Tank Anodes
A – Length (mm)
220
Ned Marine
Net/GrosWeight (Kg)
11/
110
Product
Code
17
Product
Code
M1600TA
Aluminium Tank Anodes
D – Overall Length (mm)
160
160
2920
25mm
DIA
H – Insert Length (mm)
G – Insert Size (mm)
F – Fixing Centres (mm)
C – Height (mm)
2320
E – Diameter (mm)
B – Width (mm)
160/
171
A – Length (mm)
Net/GrosWeight (Kg)
Ned Marine
2920
18
-
-
12mm
DIA
800
M101T
10.0/
11.0
600
50
50
1100
-
-
12mm
DIA
1100
ZGRE13
13/
13.5
1525
35
35
-
-
-
12mm
DIA
1550
M150T
15.0/
16.5
900
50
50
1500
-
-
12mm
DIA
1500
M205T
20.5/
22.0
1225
50
50
1825
-
-
12mm
DIA
1825
ZGT22
22/
23.5
1525
55
50
1100
-
12mm
DIA
0
M265T
26.5/
27.5
500
80
95
1000
-
-
12mm
DIA
1000
M318T
31.8/
32.7
600
80
-
12mm
DIA
1100
95
1100
-
-
H – Insert Length (mm)
F – Fixing Centres (mm)
800
G – Insert Size (mm)
E – Diameter (mm)
D – Overall Length (mm)
50
C – Height (mm)
50
B – Width (mm)
300
Zinc Tank Anodes
A – Length (mm)
5.2/
6.0
Ned Marine
Net/GrosWeight (Kg)
M52T
Product
Code
19
E – Diameter (mm)
F – Fixing Centres (mm)
Product
Code
M400T
40/
41.2
750
80
95
1350
20mm
DIA
1350
M500T
50/
51.3
940
80
95
1540
20mm
DIA
1540
Zinc Tank Anodes
H – Insert Length (mm)
G – Insert Size (mm)
D – Overall Length (mm)
C – Height (mm)
B – Width (mm)
A – Length (mm)
Net/GrosWeight (Kg)
Ned Marine
20
12mm
DIA
370
3.2/
4.2
430
50
55
500
-
-
12mm
DIA
500
M32TPA
4.5/
5.6
605
50
55
665
-
-
12mm
DIA
665
M45TPA
5.5/
6.4
275
80
95
335
-
-
12mm
DIA
335
M55TPA
7.0/
7.9
350
80
95
410
-
-
12mm
DIA
410
M70TPA
9.0/
10.0
450
80
95
510
-
-
12mm
DIA
510
M90TPA
H – Insert Length (mm)
F – Fixing Centres (mm)
-
G – Insert Size (mm)
E – Diameter (mm)
D – Overall Length (mm)
-
C – Height (mm)
370
B – Width (mm)
55
Aluminium Pit Guard
Anodes
A – Length (mm)
50
Ned Marine
Net/GrosWeight (Kg)
2.2/
3.1
310
M22TPA
Product
Code
21
-
-
12mm
DIA
350
M100TP
10/
11.1
580
50
50
640
-
-
12mm
DIA
640
M120TP
12/
13
395
63
70
455
-
-
12mm
DIA
455
M150TP
15/
15.9
280
80
95
340
-
-
12mm
DIA
340
M170TP
17/
17.9
315
80
95
375
-
-
12mm
DIA
375
M200TP
20/
21
370
80
95
430
-
-
12mm
DIA
430
H – Insert Length (mm)
F – Fixing Centres (mm)
350
G – Insert Size (mm)
E – Diameter (mm)
D – Overall Length (mm)
50
C – Height (mm)
50
B – Width (mm)
290
Zinc Pit Guard
Anodes
A – Length (mm)
5.0/
5.9
Ned Marine
Net/GrosWeight (Kg)
M50TP
Product
Code
22
Product
Code
Aluminium Disc Hull
Anodes
H – Insert Length (mm)
G – Insert Size (mm)
F – Fixing Centres (mm)
E – Diameter (mm)
D – Overall Length (mm)
C – Height (mm)
B – Width (mm)
A – Length (mm)
Net/GrosWeight (Kg)
Ned Marine
AGR2
0.35/
0.4
25
100
M12
0
AGR5
0.75/
0.8
35
138
40x5
100
AGR15
2.85/
3
25
225
M16
100
AGWL16
7.1/
8.5
30
345
40x5
500
23
H – Insert Length (mm)
G – Insert Size (mm)
F – Fixing Centres (mm)
E – Diameter (mm)
D – Overall Length (mm)
C – Height (mm)
B – Width (mm)
Zinc Disc Hull
Anodes
A – Length (mm)
Ned Marine
Net/GrosWeight (Kg)
Product
Code
ZGR250g
0.2/
0.25
-
-
20
-
65
-
M10
0
ZGR1
0.4/
0.5
-
-
25
-
70
-
M10
0
ZGR2
0.7/
0.8
-
-
-
95
-
M10
0
ZGR2S
0.9/1
-
-
25
-
100
-
M10
ZGR5
2.3/
2.5
-
-
35
-
138
-
M16
100
ZGR15
6.8/7
-
-
25
-
225
-
M16
100
ZGSR23
10.95/
11.15
-
-
50
-
230
-
M16
100
ZGWL16
18.4/
20
-
-
30
-
345
-
40x5
500
25
0
24
F – Fixing Centres (mm)
75
ZGST6
0.5/
2.55
152
44
15
-
-
-
ZGST6D
0.5/
2.55
152
44
15
-
-
-
ZGST12
0.9/
1.1
305
44
15
-
-
-
ZGST12D
0.9/
1.1
305
44
15
-
-
-
ZGST15
1.1/
1.4
381
44
15
-
-
ZGST15D
1.1/
1.4
378
44
15
-
-
-
ZGST18
1.3/
1.65
457
44
15
-
-
-
25x3
OR
AL
TOP
HAT
25x3
OR
AL
TOP
HAT
25x3
OR
AL
TOP
HAT
25x3
OR
AL
TOP
HAT
25x3
OR
AL
TOP
HAT
25x3
OR
AL
TOP
HAT
-
25x3
OR
AL
TOP
HAT
25x3
OR
AL
TOP
HAT
H – Insert Length (mm)
E – Diameter (mm)
-
G – Insert Size (mm)
D – Overall Length (mm)
-
C – Height (mm)
15
B – Width (mm)
44
Zinc Strip Anodes
A – Length (mm)
125
Ned Marine
Net/GrosWeight (Kg)
ZGST5
0.6/
0.65
Product
Code
100
152
152
305
305
380
378
457
25
F – Fixing Centres (mm)
-
ZGST36
2.7/
3.3
915
44
15
-
-
-
ZGST39
2.9/
3.5
990
44
15
-
-
-
ZGCP4
0.5/
0.55
112
40
12
-
-
-
25x3
OR
AL
TOP
HAT
25x3
OR
AL
TOP
HAT
25x3
OR
AL
TOP
HAT
M16
H – Insert Length (mm)
E – Diameter (mm)
-
G – Insert Size (mm)
D – Overall Length (mm)
-
C – Height (mm)
15
B – Width (mm)
44
Zinc Strip Anodes
A – Length (mm)
610
Ned Marine
Net/GrosWeight (Kg)
ZGST24
1.8/
2.2
Product
Code
610
-
970
-
26
-
None
0
ZR12
0.4/-
500
-
-
-
12
-
None
0
ZR16
0.7/-
500
-
-
-
16
-
None
0
ZR20
1.25/-
500
-
-
-
20
-
None
0
ZR25
1.8/-
500
-
-
-
25
-
None
0
ZR30
2.5/-
500
-
-
-
30
-
None
0
ZR40
4.5/-
500
-
-
-
40
-
None
0
ZR50
7/-
500
-
-
-
50
-
None
0
H – Insert Length (mm)
10
G – Insert Size (mm)
D – Overall Length (mm)
-
F – Fixing Centres (mm)
C – Height (mm)
-
ZR10
E – Diameter (mm)
B – Width (mm)
-
Zinc ROD Anodes
A – Length (mm)
500
Ned Marine
Net/GrosWeight (Kg)
0.3/-
Product
Code
27
-
None
0
ZR70
13.7/-
500
-
-
-
70
-
None
0
ZR80
17.7/-
500
-
-
-
80
-
None
0
ZR90
22.7/-
500
-
-
-
80
-
None
0
ZR100
27.7/-
500
-
-
-
100
-
None
0
ZR200
45/-
250
-
-
-
200
-
None
0
ZR125
46.5/-
500
-
-
-
125
-
None
0
ZR150
66.5
500
-
-
-
150
-
None
0
H – Insert Length (mm)
60
G – Insert Size (mm)
D – Overall Length (mm)
-
F – Fixing Centres (mm)
C – Height (mm)
-
ZR60
E – Diameter (mm)
B – Width (mm)
-
Zinc ROD Anodes
A – Length (mm)
500
Ned Marine
Net/GrosWeight (Kg)
10/-
Product
Code
28
MATERIAL SAFETY:
Aluminium Alloy
MSDS-001
Revision No.:
B
Issue Date:
25/08/2010
Pages:
1 of 3
Section 1: Product Information and Company Identification
Product Name:
Synonym:
Chemical Name:
Chemical Formula:
Hazchem Code:
Aluminium Alloy
Al/In/Zn
None Allocated
None Allocated
None Allocated
Contact Information:
NedMarine Services B.V.
Tinstraat 109
2984 AN Ridderkerk
The Netherlands
Tel: +31 (0) 180 420 055
Fax: +31 (0) 180 499 810
Email: [email protected]
Web: www.nedmarine.com
Section 2: Composition and Information on Elements
Alluminium
Alloy
Elements %
Zinc
Indium
Silicon
Iron
Copper
Mercury
Tin
Cadmium
Others
Aluminium
A-Guard®
G3
MIL-DTL24779A(SH)
DNV-RP-B401
ISO 15589-2
NORSOK M-503
4.000%-5.000%
0.015%-0.020%
0.080%-0.120%
max. 0.090%
max. 0.003%
max. 0.100%
Remainder
2.500%-0.500%
0.010%-0.020%
0.080%-0.150%
max. 0.120%
max. 0.006%
max. 0.020% (ea.)
Remainder
4.000%-6.500%
0.014%-0.020%
0.080%-0.200%
max. 0.090%
max. 0.004%
max. 0.001%
max. 0.001%
max. 0.100%
Remainder
2.500%-5.750%
0.015%-0.040%
max. 0.120%
max. 0.090%
max. 0.003%
max. 0.002%
Remainder
2.500%-5.750%
0.016%-0.040%
max. 0.120%
max. 0.90%
max. 0.003%
max. 0.002%
max. 0.020% (ea.)
Remainder
2.500%-5.750%
0.015%-0.040%
max.0.100%
max. 0.90%
max. 0.003%
max. 0.020% (ea.)
Remainder
Section 3: Hazards Identification
Potential Acute Health Effects:
Slightly hazardous in case of skin contact (irritant). Non-irritating to the eyes. Non-hazardous in case of ingestion.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS:
MUTAGENIC EFFECTS:
TERATOGENIC EFFECTS:
DEVELOPMENTAL TOXICITY:
Not available.
Not available.
Not available.
Not available.
The substance is toxic to lungs.
Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to a highly toxic material may produce general
deterioration of health by an accumulation in one or many human organs.
Section 4: First Aid Measures
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
attention if irritation occurs.
Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.
Serious Skin Contact: Not available.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Serious Inhalation: Not available.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities
of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband.
Serious Ingestion: Not available.
29
MATERIAL SAFETY:
Aluminium Alloy
MSDS-001
Revision No.:
B
Issue Date:
25/08/2010
Pages:
2 of 3
Section 5: Fire and Explosion Data
Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not available.
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: Some metallic oxides.
Fire Hazards in Presence of Various Substances: Not available.
Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion
of the product in presence of static discharge: Not available.
Fire Fighting Media and Instructions: SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.
Section 6: Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated
surface and dispose of according to local and regional authority requirements.
Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and
allow evacuating through the sanitary system.
Section 7: Handling and Storage
Precautions: Do not ingest. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or the label. Keep away
from incompatibles such as oxidizing agents, acids, alkalis.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Moisture sensitive.
Section 8: Exposure Controls / Personal Protection
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure
limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Gloves.
Personal Protection in Case of a Large Spill: Safety glasses. Lab coat. Gloves.
Exposure Limits: Consult local authorities for acceptable exposure limits.
Physical state and appearance: Solid.
Section 9: Physical and Chemical Properties
Specific Gravity: Density: 2.7 (Water = 1)
Odour: Odourless.
Vapour Pressure: Not applicable.
Taste: Not available.
Vapour Density: Not available.
Molecular Weight: 2700 - 2750 kg/m3
Volatility: Not available.
Colour: Silver-white
Odour Threshold: Not available.
pH (1% soln/water): Not applicable.
Water/Oil Dist. Coeff.: Not available.
Boiling Point: 2327°C (4220.6°F)
Ionicity (in Water): Not available.
Melting Point: 660°C (1220°F)
Dispersion Properties: Not available.
Critical Temperature: Not available.
Solubility: Insoluble in cold water, hot water. Soluble in alkalies, Sulphuric
acid, Hydrochloric acid. Insoluble in concentrated Nitric Acid, hot Acetic
acid.
30
MATERIAL SAFETY:
Aluminium Alloy
MSDS-001
Revision No.:
B
Issue Date:
25/08/2010
Pages:
3 of 3
Section 10: Stability and Reactivity Data
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Incompatible materials, exposure to moist air or water.
Incompatibility with various substances: Reactive with oxidizing agents, acids, alkalis.
Corrosivity: Not available.
Special Remarks on Reactivity: Moisture sensitive. Aluminium reacts vigorously with Sodium Hydroxide. Aluminium is also incompatible with strong
oxidizers, acids, chromic anhydride, iodine, carbon disulfide, methyl chloride, and halogenated hydrocarbons, acid chlorides, ammonium nitrate, ammonium
persulfate, antimony, arsenic oxides, barium bromate, barium chlorate, barium iodate, metal salts.
Special Remarks on Corrosivity: In moist air, oxide film forms which protects metal from corrosion. Aluminium is strongly electropositive so that it corrodes
rapidly in contact with other metals.
Polymerization: Will not occur.
Section 11: Toxicological Information
Routes of Entry: Not available.
Toxicity to Animals: Not available
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant). Non-hazardous in case of ingestion. Non-hazardous in case of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects:
Skin: Exposure to Aluminium may cause skin irritation.
Eyes: Not expected to be a hazard unless Aluminium dust particles are present. Exposure to Aluminium dust may cause eye irritation by mechanical action.
Aluminium particles deposited in the eye are generally innocuous. Inhalation: Not expected to be an inhalation hazard unless it is heated or if Aluminium dust is
present It heated or in dust form, it may cause respiratory tract irritation. Heating Aluminium can release Aluminium Oxide fumes and cause fume metal fever
when inhaled. This is a flu-like illness with symptoms of metallic taste, fever, chills, aches, chest tightness, and cough.
Ingestion: Acute Aluminium toxicity is unlikely.
Chronic Potential Health Effects:
Skin: Contact dermatitis occurs rarely after Aluminium exposure. Most cases of Aluminium toxicity in humans are in one of two categories: patients with
chronic renal failure, or people exposed to Aluminium fumes or dust in the workplace. The main source of Aluminium in people with chronic renal failure was
in the high Aluminium content of the water for the dialysate used for dialysis in the 1970's in America. Even though this problem was recognized and corrected,
Aluminium toxicity continues to occur in some individuals with renal who chronically ingest Aluminium-containing phosphate binders or antacids.
Inhalation: Chronic exposure to Aluminium dust may cause dyspnoea, cough, asthma, chronic obstructive lung disease, pulmonary fibrosis, pneumothorax,
pneumoconiosis, encephalopathy, weakness, in-coordination and epileptiform seizures and other neurological symptoms similar to that described for chronic
ingestion. Hepatic necrosis is also a reported effect of exposure to airborne particulates carrying Aluminium.
Ingestion: Chronic ingestion of Aluminium may cause Aluminium Related Bone Disease or Aluminium-induced Osteomalacia with fracturing Osteodystrophy,
microcytic anemia, weakness, fatigue, visual and auditory hallucinations, memory loss, speech and language impairment (dysarthria, stuttering, stammering,
anomia, hypofluency, aphasia and eventually, mutism), epileptic seizures(focal or grand mal), motor disturbance (tremors, myoclonic jerks, ataxia, convulsions,
asterixis, motor apraxia, muscle fatigue), and dementia (personality changes, altered mood, depression, diminished alertness, lethargy, 'clouding of the
sensorium', intellectual deterioration, obtundation, coma), and altered EEG.
Section 12: Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
Transport: Aluminium is considered stable under normal handling conditions. Keep Aluminium metal clean and dry during transport.
DISCLAIMER
The information above is believed to be accurate and represents the best information currently available to NedMarine Services B.V.
However, NedMarine Services B.V. make no warranty of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall NedMarine Services B.V. be liable for any claims, losses, or damages of any
third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if NedMarine
Services B.V. has been advised of the possibility of such damages.
31
MATERIAL SAFETY:
Copper
MSDS-003
Revision No.:
B
Issue Date:
25/08/2010
Pages:
1 of 3
Section 1: Product Information and Company Identification
Product Name:
Synonym:
Chemical Name:
Chemical Formula:
Hazchem Code:
Copper
Copper Metal
Copper
Cu
None Allocated
Contact Information:
NedMarine Services B.V.
Tinstraat 109
2984 AN Ridderkerk
The Netherlands
Tel: +31 (0) 180 420 055
Fax: +31 (0) 180 499 810
Email: [email protected]
Web: www.nedmarine.com
Section 2: Composition and Information on Elements
Copper: % by weight – 100%
Section 3: Hazards Identification
Potential Acute Health Effects: Very hazardous in case of ingestion. Hazardous in case of eye contact (irritant), of inhalation. Slightly
hazardous in case of skin contact (irritant).
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
The substance is toxic to lungs, mucous membranes.
Repeated or prolonged exposure to the substance can produce target organs damage.
Section 4: First Aid Measures
Eye Contact: Check for and remove any contact lenses. Do not use an eye ointment. Seek medical attention.
Skin Contact: After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with
running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover the irritated skin with an
emollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing.
Serious Skin Contact: Not available.
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation: Not available. Ingestion: Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the
victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
Serious Ingestion: Not available.
Section 5: Fire and Explosion Data
Flammability of the Product: May be combustible at high temperature.
Auto-Ignition Temperature: Not available.
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: Some metallic oxides.
Fire Hazards in Presence of Various Substances: Not available.
Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not
available.
Fire Fighting Media and Instructions: SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not
use water jet.
Special Remarks on Explosion Hazards: Not available.
32
MATERIAL SAFETY:
Copper
MSDS-003
Revision No.:
B
Issue Date:
25/08/2010
Pages:
2 of 3
Section 6: Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow evacuating through the sanitary system. Be careful that the product is not present at a concentration level
above TLV. Check TLV on the MSDS and with local authorities.
Section 7: Handling and Storage
Precautions: Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a
fume hood. Ground all equipment containing material. Do not breathe dust. Avoid contact with eyes Wear suitable protective clothing In
case of insufficient ventilation, wear suitable respiratory equipment If you feel unwell, seek medical attention and show the label when
possible.
Storage: Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly closed. Keep in a
cool, well-ventilated place. Combustible materials should be stored away from extreme heat and away from strong oxidizing agents.
Section 8: Exposure Controls / Personal Protection
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing
apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Exposure Limits: TWA: 1 (mg/m3) from ACGIH [1990]
Consult local authorities for acceptable exposure limits.
Section 9: Physical and Chemical Properties
Physical state and appearance: Solid.
Specific Gravity: 8.94 (Water = 1)
Odour: Not available.
Vapour Pressure: Not applicable.
Taste: Not available.
Vapour Density: Not available.
Molecular Weight: 8960 kg/m3
Volatility: Not available.
Colour: Pinkish-red
Odour Threshold: Not available.
pH (1% soln/water): Not applicable.
Water/Oil Dist. Coeff.: Not available.
Boiling Point: 2595°C (4703°F)
Ionicity (in Water): Not available.
Melting Point: 1083°C (1981.4°F)
Dispersion Properties: Not available.
Critical Temperature: Not available.
Solubility: Insoluble in cold water.
Section 10: Stability and Reactivity Data
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Not available.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.
Polymerization: No.
33
MATERIAL SAFETY:
Copper
MSDS-003
Revision No.:
B
Issue Date:
25/08/2010
Pages:
3 of 3
Section 11: Toxicological Information
Routes of Entry: Absorbed through skin. Eye contact. Inhalation. Ingestion.
Toxicity to Animals: Not available.
Chronic Effects on Humans: The substance is toxic to lungs, mucous membranes.
Other Toxic Effects on Humans: Very hazardous in case of ingestion. Hazardous in case of inhalation. Slightly hazardous in case of skin
contact (irritant).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Passes through the placenta, excreted in maternal milk.
Special Remarks on other Toxic Effects on Humans: Not available.
Section 12: Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products
may arise.
Toxicity of the Products of Biodegradation: The products of degradation are as toxic as the original product.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal:
Section 14: Transport Information
Special Provisions for Transport: Marine Pollutant
DISCLAIMER
The information above is believed to be accurate and represents the best information currently available to NedMarine Services B.V.
However, NedMarine Services B.V. make no warranty of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall NedMarine Services B.V. be liable for any claims, losses, or damages of any
third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if NedMarine
Services B.V. has been advised of the possibility of such damages.
34
MATERIAL SAFETY:
Zinc Alloy
MSDS-002
Revision No.:
B
Issue Date:
25/08/2010
Pages:
1 of 4
Section 1: Product Information and Company Identification
Product Name:
Synonym:
Chemical Name:
Chemical Formula:
Hazchem Code:
Zinc Alloy
Zn/Al
None Allocated
None Allocated
None Allocated
Contact Information:
NedMarine Services B.V.
Tinstraat 109
2984 AN Ridderkerk
The Netherlands
Tel: +31 (0) 180 420 055
Fax: +31 (0) 180 499 810
Email: [email protected]
Web: www.nedmarine.com
Section 2: Composition and Information on Elements
Zinc Alloy
MIL-A-18001K
ASTM B 418 Type II
ASTM B 418 Type I
0.100% - 0.500%
0.025% - 0.070%
max. 0.005%
max. 0.005%
max. 0.006%
max. 0.100%
min. 99.314%
max. 0.005%
max. 0.003%
max. 0.0014%
max. 0.002%
max. 0.003%
Remainder
0.100% - 0.500%
0.025% - 0.070%
max. 0.005%
max. 0.005%
max. 0.006%
max. 0.100%
Remainder
Elements %
Aluminium
Cadmium
Iron
Copper
Lead
Others
Zinc
Section 3: Hazards Identification
Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged exposure is not known to aggravate medical condition.
Section 4: First Aid Measures
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Get medical attention if irritation occurs.
Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.
Serious Skin Contact: Not available.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or
waistband.
Serious Ingestion: Not available.
35
MATERIAL SAFETY:
Zinc Alloy
MSDS-002
Revision No.:
B
Issue Date:
25/08/2010
Pages:
2 of 4
Section 5: Fire and Explosion Data
Flammability of the Product: Flammable.
Auto-Ignition Temperature: 480°C (896°F)
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames and sparks, of heat, of
oxidizing materials, of acids, of alkalis, of moisture. Non-flammable in presence of shocks.
Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not
available. Risks of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media and Instructions: Flammable solid. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray or
fog. Cool containing vessels with water jet in order to prevent pressure build-up, auto-ignition or explosion.
Special Remarks on Fire Hazards: Zinc + NaOH causes ignition. Oxidation of zinc by potassium proceeds with incandescence. Residues
from zinc dust /acetic acid reduction operations may ignite after long delay if discarded into waste bins with paper. Incandescent reaction
when Zinc and Arsenic or Tellurium, or Selenium are combined. When hydrazine mononitrate is heated in contact with zinc, a flaming
decomposition occurs at temperatures a little above its melting point.
Contact with acids and alkali hydroxides (sodium hydroxide, postasium hydroxide, calcium hydroxide, etc.) results in evolution of
hydrogen with sufficient heat of reaction to ignite the hydrogen gas.
Zinc foil ignites if traces of moisture are present.
It is water reactive and produces flammable gases on contact with water. It may ignite on contact with water or moist air.
Special Remarks on Explosion Hazards: Not available.
Section 6: Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Flammable solid that, in contact with water, emits flammable gases. Stop leak if without risk. Do not get water inside
container. Do not touch spilled material. Cover with dry earth, sand or other non-combustible material. Prevent entry into sewers, basements
or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Finish cleaning by spreading water on the
contaminated surface and allow evacuating through the sanitary system.
Section 7: Handling and Storage
Precautions: Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not breathe dust.
Keep away from incompatibles such as oxidizing agents, acids, alkalis, moisture.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Keep from any possible contact with water. Do not
allow water to get into container because of violent reaction.
Section 8: Exposure Controls / Personal Protection
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing
apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Exposure Limits: Not available.
36
MATERIAL SAFETY:
Zinc Alloy
MSDS-002
Revision No.:
B
Issue Date:
25/08/2010
Pages:
3 of 4
Section 9: Physical and Chemical Properties
Specific Gravity: Not available.
Physical state and appearance: Solid. (Lustrous solid. Metal solid.)
Odour: Not available.
Vapour Pressure: Not applicable.
Taste: Not available.
Vapour Density: Not available.
Molecular Weight: 7103 kg/m3
Volatility: Not available.
Colour: Bluish-grey
Odour Threshold: Not available.
pH (1% soln/water): Not applicable.
Water/Oil Dist. Coeff.: Not available.
Boiling Point: 907°C (1664.6°F)
Ionicity (in Water): Not available.
Melting Point: 419°C (786.2°F)
Dispersion Properties: Not available.
Critical Temperature: Not available.
Solubility: Insoluble in cold water, hot water, methanol, diethyl
ether, n-octanol, acetone.
Section 10: Stability and Reactivity Data
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Excess heat, incompatible materials, moisture
Incompatibility with various substances: Reactive with oxidizing agents, acids, alkalis. Slightly reactive to reactive with moisture. The
product may react violently with water to emit flammable but non toxic gases.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity: Incompatible with acids, halogenated hydrocarbons, NH4NO3, barium oxide, Ba(NO3)2, Cadmium, CS2,
chlorates, Cl2, CrO3, F2, Hydroxylamine, Pb(N3)2, MnCl2, HNO3, performic acid, KClO3, KNO3, N2O2, Selenium, NaClO3, Na2O2,
Sulfur, Te, water, (NH4)2S, As2O3, CS2, CaCl2, chlorinated rubber, catalytic metals, halocarbons, o-nitroanisole, nitrobenzene, non
metals, oxidants, paint primer base, pentacarbonoyliron, transition metal halides, seleninyl bromide, HCl, H2SO4, (Mg +Ba(NO3)2
+BaO2), (ethyl acetoacetate +tribromoneopentyl alcohol. Contact with Alkali Hydroxides(Sodium Hydroxide, Potassium Hydroxide,
Calcium Hydroxide, etc) results in evolution of hydrogen. Ammonium nitrate + zinc + water causes a violent reaction with evolution of
steam and zinc oxide. May react with water.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
37
MATERIAL SAFETY:
Zinc Alloy
MSDS-002
Revision No.:
B
Issue Date:
25/08/2010
Pages:
4 of 4
Section 11: Toxicological Information
Routes of Entry: Inhalation. Ingestion.
Toxicity to Animals: Not available.
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects:
Skin: May cause skin irritation. Dermal exposure to zinc may produce leg pains, fatigue, anorexia and weight loss.
Eyes: May cause eye irritation.
Ingestion: May be harmful if swallowed. May cause digestive tract irritation with tightness in throat, nausea, vomiting, diarrheal, loss of
appetite, alaise, abdominal pain. fever, and chills. May affect behaviour/central nervous system and autonomic nervous system with ataxia,
lethargy, staggering gait, mild derangement in cerebellar function, light headiness, dizziness, irritability, muscular stiffness, and pain. May
also affect blood.
Inhalation: Inhalation of zinc dust or fumes may cause respiratory tract and mucous membrane irritation with cough and chest pain. It can
also cause "metal fume fever", a flu-like condition characterized appearance of chills, headache fever, maliase, fatigue, sweating, extreme
thirst, aches in the legs and chest, and difficulty in breathing. A sweet taste may also be present in metal fume fever, as well as a dry throat,
aches, nausea, and vomiting, and pale grey cyanosis.
The toxicological properties of this substance have not been fully investigated.
Section 12: Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products
may arise.
Toxicity of the Products of Biodegradation: Not available.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
Transport: Zinc is considered stable under normal handling conditions. Keep Zinc metal clean and dry during transport.
DISCLAIMER
The information above is believed to be accurate and represents the best information currently available to NedMarine Services B.V.
However, NedMarine Services B.V. make no warranty of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall NedMarine Services B.V. be liable for any claims, losses, or damages of any
third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if NedMarine
Services B.V. has been advised of the possibility of such damages.
38
MATERIAL SAFETY:
Mild Steel
MSDS-004
Revision No.:
B
Issue Date:
25/08/2010
Pages:
1 of 3
Section 1: Product Information and Company Identification
Product Name:
Synonym:
Chemical Name:
Chemical Formula:
Hazchem Code:
Mild Steel
Carbon and Alloy Steel, AISI-SAE
None Allocated
None Allocated
None Allocated
Contact Information:
NedMarine Services B.V.
Tinstraat 109
2984 AN Ridderkerk
The Netherlands
Tel: +31 (0) 180 420 055
Fax: +31 (0) 180 499 810
Email: [email protected]
Web: www.nedmarine.com
Section 2: Composition and Information on Elements
Elements %
% by weight
Elements %
% by weight
Aluminium
<0.01% - 0.50%
Lead
<0.15% - 0.35%
Bismuth
<0.20% - 0.50%
Manganese
<0.04% - 0.70%
Boron
<0.01% - 1.00%
Molybdenum
<0.15% - 1.10%
Carbon
<0.10% - 1.50%
Nickel
<0.10% - 10.00%
Chromium
<0.40% - 100%
Phosphorous
<0.04% - 0.12%
Columnium
<0.15% - 0.35%
Silicon
<0.15% - 2.00%
Copper
<0.30% - 1.90%
Sulphur
<0.05% - 0.35%
Iron
<86.50% - 99.50%
Vanadium
<0.01% - 0.15%
The above is a summary of elements used in alloying steel. Various grades of steel will contain different combinations of these elements. Trace elements may
also be present in minute amounts.
Section 3: Hazards Identification
Potential Acute Health Effects: Excessive inhalation of metallic fumes and dust may result in irritation of eyes, nose and throat. High concentrations of fumes
and dust of iron-oxide, manganese, copper, zinc and lead may result in metal fume fever. Typical symptoms last from 12 to 48 hours and consist of a metallic
taste in the mouth, dryness and irritation of the throat, chills and fever.
Potential Chronic Health Effects: Chronic and prolonged inhalation of high concentrations of fumes or dust of the following elements may lead to the
conditions listed opposite the element.
Aluminium: May initiate fibrotic changes to lung tissue.
Manganese: Bronchitis, pneumonitis, lack of coordination.
Bismuth: No chronic debilitating symptoms indicated.
Molybdenum: Respiratory tract irritation, possible liver and kidney damage,
bone deformity.
Boron: No chronic debilitating symptoms indicated.
Chromium: Lesions of the skin and mucous membranes, possible cancer of
the nose or lungs-bronchogenic carcinoma
Nickel: Lesions of the skin and mucous membranes, possible cancer of the
nose or lungs-bronchogenic carcinoma.
Phosphorous: Necrosis of the mandible.
Copper: No chronic debilitating symptoms indicated.
Sulphur: (as Sulphur Dioxide) Edema of the lungs.
Iron: Siderosis, pulmonary effects.
Vanadium: (as Vanadium Pentoxide) Emphysema, pneumonia.
Lead: Anemia, urinary dysfunction, weakness, constipation, nausea, nervous
disorder.
Zinc: Gastrointestinal inflammation reported in animal studies.
Section 4: First Aid Measures
Eye Contact: Flush thoroughly with running water to remove particulate; obtain medical attention.
Skin Contact: Remove particles by washing thoroughly with soap and water. Seek medical attention if condition persists.
Serious Skin Contact: Not available.
Inhalation: If inhaled, remove to fresh air; if condition continues, consult a physician..
Serious Inhalation: Not available.
Ingestion: If significant amounts of metal are ingested, consult a physician.
Serious Ingestion: Not available.
39
MATERIAL SAFETY:
Mild Steel
MSDS-004
Revision No.:
B
Issue Date:
25/08/2010
Pages:
2 of 3
Section 5: Fire and Explosion Data
Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not available
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not available Non-flammable in presence of shocks.
Explosion Hazards in Presence of Various Substances: Steel products do not present fire or explosion hazards under normal conditions. Fine metal particles
such as produced in grinding or sawing can burn. High concentrations of metallic fines in air may present an explosion hazard.
Fire Fighting Media and Instructions: SMALL FIRE: Use DRY chemical powder or sand.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.
Section 6: Accidental Release Measures
Small Spill: Fine turnings and small chips should be swept or vacuumed. Scrap metal can be reclaimed for reuse.
Large Spill: Fine turnings and small chips should be swept or vacuumed. Scrap metal can be reclaimed for reuse.
Section 7: Handling and Storage
Precautions: Keep away from heat and direct sunlight. Do not breathe dust.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Keep from any possible contact with water.
Section 8: Exposure Controls / Personal Protection
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure
limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection: Appropriate dust/mist/fume respirator should be used to avoid excessive inhalation of particulates. If exposure limits are reached or
exceeded, use NIOSH approved equipment. Safety glasses should be worn when grinding or cutting. Face shields should be worn when welding or cutting.
Protective gloves should be worn as required for welding, burning or handling operations.
Exposure Limits: Not available.
Physical state and appearance: Solid.
Section 9: Physical and Chemical Properties
Specific Gravity: (H2O = 1): Approx. 1.47.
Odour: Odourless.
Vapour Pressure: Not applicable.
Taste: Not available.
Vapour Density: Not available.
Molecular Weight: 7850 kg/m3.
Volatility: Not available.
Colour: Silver-grey
Odour Threshold: Not available.
pH (1% soln/water): Not applicable.
Water/Oil Dist. Coeff.: Not available.
Boiling Point: Not applicable
Ionicity (in Water): Not available.
Melting Point: 1,426–1,538°C (2,599–2,800°F)
Dispersion Properties: Not available.
Critical Temperature: Not available.
Solubility: Not applicable.
40
MATERIAL SAFETY:
Mild Steel
MSDS-004
Revision No.:
B
Issue Date:
25/08/2010
Pages:
3 of 3
Section 10: Stability and Reactivity Data
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Steel at temperatures above the melting point may liberate fumes containing oxides of iron and alloying elements. Avoid generation
of airborne fumes and dust.
Incompatibility with various substances: Reacts with strong acids to form Hydrogen gas.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity: Metallic dust or fumes may be produced during welding, burning, grinding and possible machining.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
Section 11: Toxicological Information
Routes of Entry: Inhalation. Ingestion.
Toxicity to Animals: Not available.
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects:
Skin: May cause skin irritation. Eyes: May cause eye irritation. Ingestion: May be harmful if swallowed.
Inhalation: Inhalation of steel dust or fumes may cause respiratory tract and mucous membrane irritation with cough and chest pain.
The toxicological properties of this substance have not been fully investigated.
Section 12: Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation: Not available
Toxicity of the Products of Biodegradation: Not available.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
Transport: Mild Steel is considered stable under normal handling conditions. Keep Mild Steel clean and dry during transport.
DISCLAIMER
The information above is believed to be accurate and represents the best information currently available to NedMarine Services B.V.
However, NedMarine Services B.V. make no warranty of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall NedMarine Services B.V. be liable for any claims, losses, or damages of any
third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if NedMarine
Services B.V. has been advised of the possibility of such damages.
41
MATERIAL SAFETY:
Magnesium Alloy
MHP-005
Revision No.:
B
Issue Date:
25/08/2010
Pages:
1 of 3
Section 1: Product Information and Company Identification
Product Name:
Synonym:
Chemical Name:
Chemical Formula:
Hazchem Code:
Magnesium Alloy
Mg/Al/Zn
None Allocated
None Allocated
None Allocated
Contact Information:
NedMarine Services B.V.
Tinstraat 109
2984 AN Ridderkerk
The Netherlands
Tel: +31 (0) 180 420 055
Fax: +31 (0) 180 499 810
Email: [email protected]
Web: www.nedmarine.com
Section 2: Composition and Information on Elements
Elements %
M-Guard Alloy
Alluminium
Zinc
Copper
Silicon
Iron
Maganese
Nickel
Lead
Magnesium
5.30% - 6.70%
2.50% - 3.50%
max. 0.080%
max. 0.300%
max. 0.005%
max. 0.250%
max. 0.003%
max. 0.030%
Remainder
Section 3: Hazards Identification
Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged exposure is not known to aggravate medical condition.
Section 4: First Aid Measures
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
attention if irritation occurs.
Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.
Serious Skin Contact: Not available.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Serious Inhalation: Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult,
administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical attention.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities
of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband.
Serious Ingestion: Not available.
42
MATERIAL SAFETY:
Magnesium Alloy
MHP-005
Revision No.:
B
Issue Date:
25/08/2010
Pages:
2 of 3
Section 5: Fire and Explosion Data
Flammability of the Product: Flammable.
Auto-Ignition Temperature: Not available.
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: Some metallic oxides.
Fire Hazards in Presence of Various Substances: Highly flammable in presence of open flames and sparks, of heat. Flammable in presence of acids, of
moisture. Non-flammable in presence of shocks.
Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion
of the product in presence of static discharge: Not available. Explosive in presence of acids, of moisture.
Fire Fighting Media and Instructions: Flammable solid. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray or fog. Cool containing
vessels with water jet in order to prevent pressure build-up, auto ignition or explosion.
Special Remarks on Fire Hazards: Magnesium turnings, chips or granules, ribbons, are flammable. They can be easily ignited. They may reignite after fire is
extinguished. Produces flammable gases on contact with water and acid. May ignite on contact with water or moist air. Magnesium fires do not flare up
violently unless moisture is present.
Special Remarks on Explosion Hazards: Reacts with acids and water to form hydrogen gas with is highly flammable and explosive
Section 6: Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill: Flammable solid. Stop leak if without risk. Do not touch spilled material. Use water spray curtain to divert vapour drift. Prevent entry into sewers,
basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal.
Section 7: Handling and Storage
Precautions: Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not breathe dust. Keep away from
incompatibles such as oxidizing agents, acids, moisture.
Storage: Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition
(spark or flame). Moisture sensitive. Dangerous when wet.
Section 8: Exposure Controls / Personal Protection
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure
limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to
avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
Exposure Limits: Not available.
Physical state and appearance: Solid. (metal solid)
Section 9: Physical and Chemical Properties
Specific Gravity: (H2O = 1) : Approx. 1.74.
Odour: Odourless.
Vapour Pressure: Not applicable.
Taste: Not available.
Vapour Density: Not available.
Molecular Weight: 2431 kg/m3
Volatility: Not available.
Colour: Silver-white
Odour Threshold: Not available.
pH (1% soln/water): Not applicable.
Water/Oil Dist. Coeff.: Not available.
Boiling Point: 1100°C (2012°F)
Ionicity (in Water): Not available.
Melting Point: 651°C (1203.8°F)
Dispersion Properties: Not available.
Critical Temperature: Not available.
Solubility: Slightly soluble in hot water. Insoluble in cold water. Insoluble in
chromium trioxides, and mineral acids, alkalis. Soluble in concentrated
hydrogen fluoride and ammonium salts.
43
MATERIAL SAFETY:
Magnesium Alloy
MHP-005
Revision No.:
B
Issue Date:
25/08/2010
Pages:
3 of 3
Section 10: Stability and Reactivity Data
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Heat, incompatible materials, water or moisture, moist air.
Incompatibility with various substances: Reactive with oxidizing agents, acids, moisture
Corrosivity: Non/corrosive in presence of glass
Special Remarks on Reactivity: Violent chemical reaction with oxidizing agents. Reacts with water to create hydrogen gas and heat. Must be kept dry.
Reacts with acids to form hydrogen gas which is highly flammable and explosive. Magnesium forms hazardous or explosive mixtures with aluminium and
potassium perchlorate; ammonium nitrate; barium nitrate, barium dioxide and zinc; beryllium oxide; boron phosphodiiodide; bromobenzyl trifluoride; cadmium
cyanide; cadmium oxide; calcium carbide; carbonates; carbon tetrachloride; chlorine; chlorine trifluoride; chloroform; cobalt cyanide; copper cyanide; copper
sulphate(anhydrous), ammonium nitrate, potassium chlorate and water; cupric oxide; cupric sulphate; fluorine; gold cyanide; hydrogen and calcium carbonate;
hydrogen iodide; hydrogen peroxide; iodine; lead cyanide; mercuric oxide; mercury cyanide; methyl chloride; molybdenum trioxide; nickel cyanide; nitric acid;
nitrogen dioxide; oxygen (liquid); performic acid; phosphates; potassium chlorate; potassium perchlorate; silver nitrate; silver oxide; sodium perchlorate;
sodium peroxide; sodium peroxide and carbon dioxide; stannic oxide; sulphates; trichloroethylene; zinc cyanide; zinc oxide.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
Section 11: Toxicological Information
Routes of Entry: Inhalation. Ingestion.
Toxicity to Animals: Not available.
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects: Skin: May cause skin irritation by mechanical action. May get
mechanical injury or embedding of chips/particles in skin. The particles that are embedded in the wounds may retard healing.
Eyes: May cause eye irritation by mechanical action. Mechanical injury may occur. Particles or chips may embed in eye and retard healing.
Ingestion: Low hazard for usual industrial handling. There are no known reports of serious industrial poisonings with Magnesium. Ingestion of large amounts
of chips, turnings or ribbons may cause gastrointestinal tract irritation with nausea, vomiting, and diarrhoea. Acute ingestion may also result in Hypermagnesia.
Hypermagnesia may cause hypotension, bradycardia, CNS depression, respiratory depression, and impairment of neuromuscular transmission (hyporeflexia,
paralysis).
Inhalation: Low hazard for ususal industrial handling. It may cause respiratory tract irritation. However, it is unlikely due to physical form. When Magnesium
metal is heated during welding or smelting process, Metal Fume Fever may result from inhalation of magnesium fumes. Metal Fume Fever is a flu-like
condition consisting of fever, chills, sweating, aches, pains, cough, weakness, headache, nausea, vomiting, and breathing difficulty. Other symptoms may
include metallic taste, increased white blood cell count. There is no permanent ill-effect.
Section 12: Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
Transport: Magnesium Alloy is considered stable under normal handling conditions. Keep clean and dry during transport.
DISCLAIMER
The information above is believed to be accurate and represents the best information currently available to NedMarine Services B.V.
However, NedMarine Services B.V. make no warranty of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall NedMarine Services B.V. be liable for any claims, losses, or damages of any
third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if NedMarine
Services B.V. has been advised of the possibility of such damages.
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